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CHAPTER? 40^ ' r
v
' 1965 Guide And Data Book
they are carried out nor how small the temperature dif ference between the evaporator and the tyinHono^'
absorber may be. It should be noted, however, that the (CP) fells off slowly as these temperature differences are tncr?ififnj This assists in maintaining high part-load efficiencies. These characteristics are very different from those of compression
Ti(Tt r,)
(CP) T<(Tt - TO-
(1),
.:7V, " evaporator temperature, Rankine.. 7t ".condenser temperature, Rankine. Tt * absorber temperature, Rankine. Tt " generator temperature, Rankine.
- : < : -...............
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Actual cycles are never as efficient as the ideal cycle. Every difference between the actual and ideal cycle producesa ther
modynamic loss. As a result,"the (CP) of actual absorption cycles is generally less than' one, no matter how efficiently
Influence of Condenser Water Temperatures.'
An analysis of the cycle shows that unit efficiency improves with a reduction in condenser water temperature. The con densing temperature is almost a direct function of the condenser water temperature; hence, an increase in .the con denser water .temperature will result in an almost* identical increase in the condensing temperature. With a fixed evapo rator temperature, an increase in the condensing' temperature will result in a higher temperature condensate having a greater enthalpy. This condensate, upon'its return .to-the evaporator, has a reduced refrigerating effect The net result of an increase in condenser water temperature is a reduction in capacity, and an increase in the energy input requirements.
If the condenser, water temperature continues.to rise, the capacity of the unit continues to' decrease. Since the lithium bromide unit is operating under a high vacuum,- no pressures higher than atmospheric can develop. This eliminates the need for a high head-pressure safety cut-out. Absorption machines using the lithium bromide-water cycle continue to pro duce some refrigeration even with unusually high cooling water temperatures.
On the other hand, if the temperature of the condenser water should decrease, the capacity of the .unit would increase. It is desirable to limit variations in capacity resulting from vari ations in-the temperature of the entering condenser water, as may .exist with a cooling tower. The installation of an auto matic 3-way valve between the cooling tower and the con denser is recommended. Tliis valve will either recirculate
fig. 6 .. Diagram of One-Shell Lithium Bromide Cycle Water Chiller.'-'
fig. 7 .... Performance Characteristics of Lithium Bromide Cycle Water Chiller '
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Absorption Air-Conditioning and Refrigeration Equipment
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water, mix condenser and cooling tower water, or
deliver(100 percent tower water, to.hold the water tempera
ture within design limits;
: :- '
In the modem lithium bromide absorption system, the con
denser water'flow'rate is held constant throughout the entire
operating, range of the chiller. Fig. 7 shows the performance
of a typical lithium bromide cycle water chiller with respect to condenser cooling water temperatures.
Influence'of Chilled Water Temperature
'
.-Further.analysis of.the lithium bromide-water cycle also
reveals the advantage of maintaining the chilled water tem
perature as high as the load will permit. The chilled water
temperature follows evaporator: temperature- very closely;
hence an increase.in the required temperature of .the chilled
wa& requires ah almost identical increase in the evaporator
temperature. With/a fixed .condenser temperature,' the en-
ti&lpy of tire refrigerant to the evaporator remains unchanged.'
If the, evaporator, temperature rises,1 the leaving enthalpy'
increases,' thereby increasing the refrigerating effect. This
results in ah increase in the refrigerating capacity of the unit,,
and at' the same time a reduction of `energy input'require
ments.
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.., '
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The chilled water temperatures may be dictated by the de-:
humidification 'requirements of the load. .High' chilled water
temperature, if otherwise acceptable, will increase the ca
pacity1'of the machine for sensible cooling, but will reduce
the capadty of the machine for latent cooling. .
If required, chilled water temperatures as low as 38 F can'
readily be produced in chillers using the'lithium bromide-
water'cycle. Fig. 7 illustrates the performance'of a typical
lithium broinide^cycie water chiller with respect to chilled
water temperatures.
Influence of Temperature of the Heat Source
, The absorption cycle requires heat for operation. This heat may be supplied by direct firing, or it may be supplied indi-, rectly by steam, hot water, or a number of other hot fluids. At any giveu.load, the heat input requirement is' fixed, without regard to the nature of the hot medium. ' With a decrease in the temperature of the source,;there is a' decrease in'the'amount of refrigerant water vapor boiled out of the strong solution in the generator. This reduces the re frigerating capacity of the unit:' Fig. 8 shows the performance of a typical lithium bromide cycle water chiller with respect to steam pressure. (Steam pressure is generally used to indi-
* For UfWu Broewl*. Cydo W<rf*r Chflter
_ ...
fig. 8 .... Effect, of Steam Pressure,on Capacity*
cate steam conditions.) When the unit is-to be operated on hot water, or other hot fluids, the manufacturer should be consulted for specific performance, information.
Because direct-fired units are generally operated m-off, the temperature of the heat source is not significant with respect to capacity control. The unit will run a greater or leser portion of the time, corresponding closely to the ratio of the actual load to the unit capacity. This kind of operation is primarily used in residential and small commercial applica
tions.
AMMONIA-WATER CYCLE
Thermodynamically, the ammonia-water absorption cycle
is identical to the lithium bromide cycle discussed earlier in
this chapter. In the ammonia-water cycle, however, water
plays a different role. Here it acts as the absorbent. Ammonia
is the refrigerant, and consequently lower temperatures may be
reached. The other principal operating difference between the
two cycles is the pressure range in which the cycles operate.
The lithium bromide-water cycle operates under a very high
vacuum, while the ammonia-water cycle operates in a pressure
range comparable to that of compression systems. Fig. 19 of
Chapter 1 shows the properties of aqueous-ammonia solu
tions.
Although the major components of all absorption systems
are the same, the characteristics of specific refrigerant-'
absorbent combinations may require auxiliary devices in order'
to improve the operating efficiency of the cycle. In the am
monia-water cycle, the volatility of water under the genera-;
tor conditions is the major consideration.
The proportion of water in the ammonia-water. vapor
leaving the generator depends on the composition of the
liquid and its temperature. In a simple cycle, no provision is
made for removing water from the vapor before it enters the
condenser. Hence, the water passes through the condenser to
the evaporator and, being almost nonvolatile under evapo
rator conditions, it concentrates as evaporation proceeds,
thus raising the boiling point of the remaining refrigerant:
To keep such an evaporator operating, the accumulated water
would have to be purged to the absorber, either continuously
or periodically, as a liquid of High ammonia content.
Two devices commonly used to reduce the amount of water
reaching the condenser and evaporator in the actual ammonia
absorption cycle are the analyzer and the rectifier. The'
analyzer consists of a chamber through which the vapors
leaving the generator pass in oouriterfiow contact with the
weak solution flowing to the generator. A bubble column^
parking, or a series of baffle plates, may be used to make the'
vapor-liquid contact more effective. As the vapor passes up
ward through the analyzer it is enriched with ammonia, as
well as cooled, and the solution is heated. Thus,, the vapor
going to the condenser is cooler and richer in ammonia, and
the, heat input required at the generator is decreased. The
vapor flows from the analyzer into the rectifier. The rectifier
is a heat exchanger set before the condenser (or it may be toe
inlet to the'condenser) arranged in a manner to enable'! ite
condensate to drain to the analyzer or the' generator^ The'
warm refrigerant vapor from the analyzer is cooled by the
weak solution flowing to the generator.
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As in toe case of the lithium bromide-water cycle, it is uni
versal practice to conserve heat in the cycle by the use of a
beat exchanger which uses the hot strong solution from' the
generator to preheat the weak solution from the absorber.
This improves the .cycle efficiencyby reducing the heat input
required. Less beat has to be carried away, reducing heat
rejection requirements.. Still .further improvements! in toe
efficiency of the operating cycle may '.be obtained, by! sub1.