Document wDaX0y8Ga4NvwpKNYGq5GjMm3
[III ge.los Angeles^JA 90040
,-rW4
MATERIAL SAFETY
DATA SHEET
sxs&m*
DATE;, APR 4 1985
SECTION I
CHEMICAL NAME AND SYNONYMS
,
...
svm. Dt-A-naphtnyi-D-pnenylenedianvine
CHEMICAL FAMILY J
Organic secondary amine
fepy^c^NH.,
TRADE NAME AND SYNONYMS AGERITE^WHITE
EMERGENCY TELEPHONE NO. 1203)853-1400_________________
MATERIAL
SECTION II INGREDIENTS
sym. Di-/^-naphthy1-p-phenylenediamine Product
% TOXICITY DATA
35 min. Acute oral LD,-n a a 'l/t'iH rate?u acute oral LDcn La g/xg micebU
SECTION III PHYSICAL DATA
BOILING POINT (F.) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER
600 None
_
DENSITY Mg/m'
PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( . =11
Negligible
appearance and odor Light grey powder with slight amine odor
SECTION IV FIRE AND EXPLOSION HAZARD DATA
[lTafg(n40T)
FLAMMABLE LIMITS
1.25 1.056 max, None
larger fires due to lack of cooling capacity which may
result in reignition. PUNoUsSiUtiAvLeFIRpErAeNsDsuEXrePLOsSeIQlNf-.HcAoZnARtaDSin. ed. ,breath. i.ng appara^tus should .be used..in..fi.gh.t.ing
fire. Ignition sensitivity: 0.41 (low); Explosion severity: 3.67 (severe); Explosibility Index: 1.50 (strong). Min. explosion concentration: 0'023 oz./cu. ft.
DO 085845 CONFIDENT! At
Information presented herein has been compiled trom sources considered to be dependable and Is accurate and reliable to the best ot our knowledge and belief but is not guaranteed to be so Nothing herein is to be construed as recommending any practice or any product in violation ot any patent or in vio lation ot any taw or regulation It is the user's responsibility to determine tor himself the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary We make no warranty as to the results to be obtained in using any material and, since conditions ot use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us
_T_H_R_E_S_H_O_L_D_L_IM__IT_V_A_L_U_E____ NrA. .
EFFECTS OF OVEREXPOSURE
SECTION V HEALTH HAZARD DATA
EMERGENCY AND FIRST AID PROCEDURES
,,1th soap a,,d mUr___________________
___________________________________ Eyes: irrigate with water - call physician Inhalation: expose to fresh air
STABILITY
UNSTABLE STABLE
SECTION VI REACTIVITY DATA
CONDITIONS TO AVOID
X
HAZffWTffl R^fifPWft^oqen.
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
aromatic X
and aliphatic hydrocarbon
conditions to avoid
decomposition temperature.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Spillinqs should be cleaned up
immediately. Sweep or vacuum into containers using care to avoid dust
generation.
WASTE DISPOSAL METHOD
As per organic compounds
SECTION VIII SPECIAL PROTECTION INFORMATION
RESWfiYffl'ECrTeIOsNp(iSrPaEtCoIFrY
TYPE). .
if dusty
....
conditions
VENTILATION
LOCAL EXHAUST rEx.haus.t ven. t.il.at.io. n
MECHANICAL (GENERAL)
SPECIAL OTHER
PROTECTIVE GLOVES ,, ..
Rubber
OTHER PROTECTIVE EQUIPMENT
eye protection
Goggles
SECTION IX SPECIAL PRECAUTIONS
ro s's<6 CnNFIDIrNTtAL
PREG
not Involve ^-naphthylamine as a raw
material. Some new techniques of analysis indicate trace quantities of^&naphthyl
OTHER PRECAUTIONS .
____ amine present.
Although we believe no abnormal hazard is involved in normal use cf
the antioxidant, normal safety handling techniques should be observed. Do not breathe processing fumes and dust. Wash hands after handling and before smoking
and eating. Wash contaminated clothing before reuse. Prevent an accumulation of potentially explosive dyst corcentrations. Use explosion proof electrical equip ment and ground processing equipment.
R.T. Vcn^erbiltXomiHiny, Inc.
IMHI iCYDUi .lilhlCDAl C AMh rUCIll^AI C . . aJ'Jr,r.
- w ..
SPECIFICATION
Rubber Department
AGERITE WHITE Antioxidant
September 15, 1977
Composition: Physical state: Color: Density: Melting range; Heating loss: Ash: Beta naphthol: Fineness (100 mesh): Standard container: Use data:
RV-77-1
Sym. di -beta-naphthyl -p-phenylenediamine
Powder
pny to light tan
1.25 0.03 Mg/m3
224 - 230 C
1.0% maximum
0.25% maximum
1.5% maximum
99.5% minimum
200 lb. drum
Antioxidant and copper inhibitor in all elastomers. 1 -2 phr provides good resistance to heat and oxidation. Used alone or in combination with other antioxidants to provide maximum service life for all rubber products. Products are nonstaining, with reference to lacquers, enamels, but discolor on light exposure. Maximum nonblooming dosage 2.0%.
DO 085847
conftdfnttai
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best ot our knowledge and belief but is not guaranteed to be so Nothing herein is to be construed as recommending any practice or any product in violation ot any patent or in vio lation ot any law or regulation. It is the user's responsibility to determine for himself the suitability of any material tor a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, Since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us
AKRON.
OKMCttf nCMCNIS MATERIAL SAFETY DATA SHEET
(BUM
(Approved by US. Department of Labor as "essentially similar" to Form LSB-OOS4)
SECTION l IDENTIFICATION OF PRODUCT
manufacturer address
AKRON CHEMICAL COMPANY Fountain St., Akron, Ohio 44304
EMERGENCY TELEPHONE NO.
216-535-2108
TRADE NAME AND SYNONYMS
AKROCHEM E-8851 DARK BROWN IRON OXIDE
CHEMICAL NAME AND SYNONYMS
` IRON OXIDE
CHEMICAL FAMILY
METAL OXIDE
CASH 1309-38-2
MOLECULAR FORMULA
COLOR INDEX NO. 77491
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
THRESHOLD X LIMIT
VALUE
(UNITS)
COMPONENT
THRESHOLD
% LIMIT
VALUE . (UNITS)
OUR INTERPRETATION OF THE OCCUPATIONAL SAFETY AND HEALTH ACT OF 1970 INDICATES THIS PRODUCT SHOULD NOT BE CONSIDERED HAZARDOUS.
t
APPEARANCE AND ODOR
BOILING POINT (DEGREES FAHRENHEIT)
VAPOR PRESSURE (MM. OF MERCURY)
VAPOR DENSITY (AIR-l)
SOLUBILITY IN WATER
. j r . . . i * SECTION III PHYSICAL DATA
BROWN, ODORLESS POWDER
^
SPECIFIC GRAVITY (WATER - 1)
PERCENT VOLATILE (BY VOLUME)
MNAA INSOLUBLE
EVAPORATION RATE (BUTYL ACETATE - 1)
EVAPORATION RATE (ETHYL ETHER - J)
.-
,.
4.4
NA NA
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLA5H POINT (SPECIFY METHOD) (DEGREES FAHRENHEIT)
NA
FLAMMABLE LIMITS (PERCENT BY VOLUME)
FIRE-EXTINGUISHING MEDIA
NONE (DOES NOT BURN)
SPECIAL FIRE-FIGHTING PROCEDURES
NONE
*
LOWER
NA
UPPER
UNUSUAL FIRE AND EXPLOSION HAZARDS
NONE
no 088848
THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OR REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSE 01 LITY FOR SAME, NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED IN VENTION WITHOUT A LICENSE. IT IS OFFEREO SOLELY FOR YOUR CONSIDERATION, INVESTIGATION AND VERIFICATION. BEFORE USING AMY PRODUCT, READ ITS LAPEL.
threshold limit value
EFFECTS OF OVEREXPOSURE
N/E
SECTION V HEALTH HAZARD DATA TREAT AS INERT OR NUISANCE DUST
N/A
EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT: FLUSH WITH PLENTY OF WATER. CONSULT PHYSICIAN SKIN CONTACT: WASH WITH SOAP AND WATER.
STABILITY
UNSTABLE STABLE
INCOMPATIBILITY (Mattrlili to ole
XX
HAZARDOUS DECOMPOSITION PRODUCTS
HAZARDOUS POLY* MERIZATiON
MAY OCCUR
WILL NOT OCCUR XX
SECTION VI REACTIVITY DATA
CONDITIONS TO AVOID
N/A
N/A N/A
CONDITIONS TO AVOID
N/A
____________________ _______________ SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEO
SWEEP OR VACUUM UP.
WASTE DISPOSAL METHOD
LANDFILL, IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Sptclfy lypt)
NIOSH APPROVED DUST RESPIRATOR
VENTILATION
LOCAL EXHAUST MECHANICAL (Qn*r<l)
^
PROTECTIVE GLOVES
RECOMMENDED
OTHER PROTECTIVE EQUIPMENT
N/A
SPECIAL
OTHER
EYE PROTECTION
_
SAFETY GOGGLES
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
N/A
OTHER PRECAUTIONS N/A
D0 085S49ai conftdfnttAL
1
DATE 10-a-8 5
SECTION X DATE AND SOURCE OF INFORMATION
NAME AND TITLE
SHEET NUMBER
J.E. PVI........ MAN.' ' r R-TE C; " '
'VICES
AKRON,
MATERIAL SAFETY DATA SHEET
CROC
(Approved by U. S. Department of Labor as "essentially simitar" to Form LSB-OOS-4)
E-5365
SECTION I IDENTIFICATION OF PRODUCT
MANUFACTURER
AKRON CHEMICAL COMPANY
ADORCSS
255 Fountain St., Akron, Ohio 44304
EMERGENCY TELEPHONE no.
216-535-2108
TRADE NAME AND SYNONYM";
AKROCHEM 5172 MED. LT. CADMIUM RED LITHOPONE
CHEMICAL NAME AND SYNONYMS ^
CHEMICAL FAMILY
C.l. PIGMENT RED 108. C.I. NO. 77196
molecular formula
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
THRESHOLD % LIMIT
VALUE
(UNITS)
COMPONENT
CADMIUM COMPOUNDS CAS CD) 27% PEL=0.2 MG CD/CU.M AIR TWA (OSHA)
SELENIUM COMPOUND CAS SE) 6% PEL=0.2 MG SE/CU.M AIR TWA COSHA)
THRESHOLC % LIMIT
VALUE
(UNITS)
appearance and odor
BOILING POINT (DEGREES FAHRENHEIT)
VAPOR PRESSURE (MM. OF MERCURY)
VAPOR DENSITY (AIR a i,
SOLUBILITY IN WATER
SECTION III PHYSICAL DATA
RED POWDER, ODORLESS
NOT APPLICABLE
SPECIFIC GRAVITY (WATER * 1)
NOT APPLICABLE
PERCENT VOLATILE (BY VOLUME)
NOT APPLICABLE NEGLIGIBLE
EVAPORATION RATE (BUTYL ACETATE 1)
EVAPORATION RATE (ETHYL ETHER 1)
APPROX. 5 NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (SPECIFY METHOD) (DEGREES FAHRENHEIT)
FIRE-EXTINGUISHING media
NOT APPLICABLE WATER
special fire-fighting procedures
flammable limits
(PERCENT BY VOLUME)
NONE REQUIRED.
LOWER
UPPER
UNUSUAL FIRE ANO EXPLOSION-HAZARDS
THIS INFORMATION is GIVEN WITHOUT a WARRANTY OR REPRESENTATION. WE DO NOT ASS
DOnf'0T10oenti_
C'-X'" _,,M|_ RESPONSI
BILITY FOR SAME. NOR DO WE GIVE PERMISSION. INDUCEMENT. OR RECOMMENDATION TO PRMo . ICE ANY PATENTED IN-
VENTION WITHOUT A LICENSE. IT IS OFFERED SOLELY FOR YOUR CONSIDERATION, INVESTIGATION ANO VERIFICATION.
fl^FOnc I.r.i' PnruivirT, READ IT"; I.Anfl
AKROCHEM 5172
SECTION V HEALTH HAZARD DATA
threshold limit value
SEE
EFFECTS OF OVEREXPOSURE
HAZARDOUS
INGREDIENTS
CAUTION: REPEATED AND PROLONGED INHALATION MAY CAUSE DELAYED -------------------------------1 N.U UR Y
EMERGENCY AND FIRST AID PROCEDURES
FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTESSKIN: WASH WITH SOAP AND WATER.
STABILITY
UNSTABLE^ STABLE
X
INCOMPATIBILITY (M*terliU to ivolrf)
NONF KNOWN
hazardous decomposition products
SECTION VI REACTIVITY DATA
CONDITIONS TO AVOID
HAZARDOUS ROLV-
merization
MAY OCCUR
CONDITIONS TO AVOID
WILL NOT OCCUR
X
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
SWEEP OR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW.
WASTE DISPOSAL METHOD
DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)
USE NIOSH APPROVED DUST MASK.
VENTILATION
I ISFlocal EXHAUST
mechanical (Genenl)
I OTA!
FXHA1IST Special
OTHER
PROTECTIVE GLOVES
RECOMMENDED
OTHER PROTECTIVE EQUIPMENT
EYE PROTECTION
PROTECT FROM DUST PARTICLES
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
DO 08585,1. CONFTDFNTT Al
AVOID BREATHING DUST OR MIST. USE WITH ADEQUATE VENTILATION.
OTHER PRECAUTIONS
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH THOROUGHLY AFTER HANDLING , BEFORE EATING^ DRINICING OR SMOKING_. KEEP JAWAY
i. __ SjzF r>- A m n c.o r\ n___nri/-\rM irtc________ CAn___ imiuc.trTiininr___ m~r ft mi y_______________
oate
4/1/8 5
SECTION X DATE AND SOURC57OF INFORMATION
NAME AND TITLE // / ,//
r I ` //
j
LV.----------------------------------------- Jf. J km,f____ SHEETNUMBER E-5365
M r.l t < ^ I - 1.1.
I'cj I: y Da t t\ S 1112 ; tl
1 HAZARD/ 0 Minlm.il INDEX 1 Slight 2 Moderate 3 Serious A Severe
HEALTH
2A
fLAHMAtJlLlTY 0
REACTIVITY PERSONAL PROTECTION
1
ASTM: D- A257
II 2 * F0 It 1 PP
IIM1S System: NrCA
*Also chronic effects - See Section VH
Date Prepared It/19/85
Section I - Product I t.l <? n t I I icat :1. o n
manijtaciunEn /\KH0N CHEMICAL COMPANY
1EMEflOENCY El.EeiIOME NO.
210-535-2108
Aoontss
255 fountain St., Akron, Ohio 44304
TflAOE NAME AND SYNONYMS
AKROCHEM^ RED LEAD 97
5'p ho
chemical NAME AND SYNONYMS
LEAD TETRAOXtDE,
CHEMICAL rAMILV
, LEAD OXIDES
LEAD
ORTIIQPLUMBATE
c.a.s.
MOLECULAfl FORMULA
r>b,o,,
Hnm-'ii-e
,
Section
Material or Component Lead Tetraoxlde
II - Hazardous Ingredients
Weight
TLV-TWA TLV-STEL
Z mR/m3-8hrs. nut/m-1
TLV-C
BLV
loo .03 0. A 5 NA 50 mmg/100 g whole blood
LEL NA
Material Is a lead compound. Refer to Federal Register Vol. A3 //220, pp 53007-5301A. Nov. 1A, 1978. Standard (OSIIA) - Occupational Exposure to Lead. Also Code of
Federal Regulation CFR Title 29 1910.1025,
Section III - Pliys ical
ta
Dolling Point 1? 760 till llg - Decomposes 1022"F Specific Gravity (1120=1)
Melting Tolnt.
- 16A7*F (Approx.) So lability In Il;j0(g/1)
Vapor Pressure (Mil Dr' - ID at 1*185*1
Evaporation Kate
Vapor Densitv
- Not. Applicable
Molecular Wt.
7, Vol.lt 1 les hv Volnini* Appeal ance ami Odor
- Not. App) icable - Plight Hed Powder; Odorless
9.1 6.85 x 10'7
Not App1(cable OR 5.6
DO 08585? CONFIDENTIAL
MS DS
Page 2
PRODUCT: U .*<! I .ci.-jhI
Section IV - Fire and Explosion Hazard Data
Flammability : NFPA FLAMMABILITY RATING = 0
Flash Point:
Hot Applicable
Autolgnltlon Temperature: Not Applicable
Flammable Limits:
Not Applicable
Extinguishing Hedla: Water Fog or Flood, Cf^and Dry Chemical
Special Fire Fighting Procedures:
Wear full body protective clothing and full facepiece, self-contained breathing apparatus operated In positive-pressure mode.
Unusual Fire and Explosion Hazard:
Fume, vapor, and/or dust may occur and are considered toxic and respiratory irritants. The product or dust can react vigorously with strong oxidizing agents. Refer to FIRE PROTECTION GUIDE ON HAZARDOUS MATERIALS by N.F..P.A. for specific Individual problem combination.
Section V -- Reactivity Data
r Reactivity: NPCA HMIS RATING = 1
Stability: Stable to 930*F Conditions to Avoid: Do not heat in presence of Al, Na, Ti, Zn.
tt
Incompatibility (Materials to Avoid):
Reacts violently with Hydrogen Peroxide.
d Hazardous Decomposition Products: High temperatures or fire may produce lead oxide
fume, vapor, or dust.
Hazardous Polymerization:
Not Applicable
Section VI -- Spill or Leak Procedures
Steps To Be Taken In Case Material Is Released Or Spilled: Clean the area of spill, returning all material possible to container. Wear gloves, goggles, respirator. Do not breathe or Ingest dust. For a SMALL spill, use a vacuum. Do not broom sweep. Recbvered material should be stored in dry containers for later disposition. Do not use compressed air for cleaning. Exclude all individuals not wearing pro tective equipment from the spill area until clean up is completed.
Waste Disposal Method: Disposal of Waste and hazardous material should be handled in a manner which complies with local, state and federal Environmental Protection Agency regulations. It Is preferable to send waste material to a recycling facility which Is approved by the state and federal F.PA. City, state and federal regulations must he followed at ell times.
Neutralizing Chemicals: Not Applicable
00 085853 CONFIDENTIAL
HSDS - Page 3
PRODUCT: Hod JL.t-tf.tcl
Section VII - Health Hazard Information
Routes of Exposure When Handling or Processing Mode of entry Into body:
Health Hazard: NPCA, HMIS RATING = 2
X- by INHALATION of dusts or fumes, the respiratory system may be irritated and both acute and chronic overexposure can result.
2. By INGESTION of lead compounds coming from dust trapped in the upper respira tory tract or introduced Into the mouth on food, tobacco, fingers or other objects, both acute and chronic overexposure can result.
3. SKIN CONTACT of dusts may cause irritation. 4. SKIN ABSORPTION does not apply, as dusts are not absorbed.
5. EYE CONTACT of dusts or fume may cause irritation.
Effects of Overexposure
ACUTE OVEREXPOSURE: Lead intoxication vill occur with accompanying symptoms of constipation, sleep disturbance, fatigue, headache, loss of appetite. Where inhalation is severe from heavy dusting or a large quantity is ingested and left untreated, colic, anemia, vomiting and neuritis will follow as evidenced by in tense periodic cramps, aching bones and muscles, uncoordinated body movements. Worst case situations could result in convulsions, stupor, coma, and encephalopathy.
CHRONIC OVEREXPOSURE: Normal ingestion of lead from the ambient air, foods and beverages is about 0.25 to 0.35 mg. per day. The normal adult metabolism can eliminate almost one mg. of lead per day. When lead ingested exceeds the body's ability to eliminate It, accumulation can reach the point where symptoms and disability occur. In this context, lead has a cumulative toxic effect.
Early effects of chronic overexposure to lead are difficult to detect, but symptoms include persistent fatigue, sleep disturbance, headache, aching bones and muscles, constipation, abdominal pains and loss of appetite. Prolonged ingestion may be indicated by intense periodic cramps and constipation, nausea and vomiting. Ex cessive exposure may affect blood, nervous, digestive systems. Synthesis of hemoglobin is inhibited and will result in anemia. Apathy and depression may be symptoms. If left untreated, neuromuscular dysfunction, possible paralysis and encephalopathy can result. Unusual occurrence of symptoms should prompt immediate contact of a physician.
For industrial exposure, a worker's lead accumulation can be detected by an increase in blood lead above the base level established upon the employee's entry to the workplace. Blood lead above the biological limit value requires job removal.
Emergency and First Aid Procedures
INHALATION - Remove from exposure. Get medical attention if experiencing effects of acute overexposure.
INGESTION - Induce vomiting in a conscious individual. Get immediate medical attention. Call a physician.
SKIN - Wash thoroughly with soap and water. EYES - Flush with copious quantities of water. Get immediate medical attention.
Notes to Physician: Lead and its inorganic compounds are nourotoxins which may produce peripheral neuropathy. For an overview of the effects of lead exposure, consult Occupa tional Safety and Health Adm. App.A of Occupational Exposure to Lead (29CFR1910.1025). "A Guide for Physicians, Health Maintenance of Workers Exposed to Inorganic Lead" is available from Lead Industries Assoclation.Inc., 292 Madison Avo., New York, NY 10017.
DO 085854 CONF TDFNT T AL
MS IDS - Page 4
- PRODUCT: Red L,eart
Section VIII -- Special Protection
SPECIFIC PERSONAL PROTECTION EQUIPMENT
RESPIRATORY: As specified by 29CFR1910.10251f) of the Federal Occupational Safety and Health Administration Standard for Occupational Exposure to Lead When handling, use a dust/fume respirator with NIOSH/HSHA approval. Respirator must be worn if TLV is exceeded.
Refer to Table II as specified in 29CFR1910.1025(f)(2)(i) for various exposure levels.
Other local, state, and federal regulations may also apply.
PROTECTIVE CLOVES: Not required, but recoimnended.
EYE PROTECTION; Not required, but recommended.
OTHER CLOTHING AND EQUIPMENT: Protective clothing is required if lead exposures exceed PEL or TLV; otherwise, full body clothing should be worn during product use and handling, be left at the work site and be properly laundered after use,' with the wash water disposed of in accordance with local, state and federal regulations. Hard hat, safety boots, and other safety equipment should be worn as appropriate for the industrial environment. Personal clothing, including shoes, should be protected from contamination.
VENTILATION REQUIREMENTS
Ventilation as described in the Industrial ventilation Manual, by ACGIH shall be provided where exposures exceed PEL or TLV specified in and in accord with OSHA Standard 29CFR1910.94. Currently 0.050 mg/m3 maximum and 0.030 mg/m3 set as trigger and action levels.
Other local and state regulations may apply.
TLV-TWA TLV-STEL TLV-C BLV LEL PEL
Section I DC -- Definitions
Threshold Limit Value-Time Weighted Average Threshold Limit Value-Short Term Exposure Limit Threshold Limit Value-Ceiling Biological Limit Value .Lethal Exposure Limit Permissible Exposure Limit
DO 085855 CONFTDFNTXAl.
MS DS - Page 5
PRODUCT: R*<1
Section X -- Special Precautions
PRECAUTIONS; There are two major means of lead absorption; namely inhalation and ingestion. Host inhalation problems can be prevented with attention to ventilation and respirator use. Ingestion can be prevented with good hygiene practices.
Do not inhale or swallow dust. Wash thoroughly after handling. Use gloves and avoid spilling on hands, face, or body, to prevent secondary contamination by ingestion or inhalation. Do not smoke, eat, or apply cosmetics in work area. Wash thoroughly before entering into eating areas. Do not wear any part of work clothing home. This includes shoes.
Keep lead materials away from feed and food products. Keep away from children. Do not reuse containers. This product is intended for industrial use only.
Section XX
Handling and Storage Requirements___________________
Store in dry area where accidental contact with acids or bases is not possible.
When a spill releases material into the environment, it may be necessary to file's report of the discharge. Contact your local environmental authorities to determine what rules apply.
Avoid Skin contact.
Adhere to all personal protection procedures and ventilation requirements when exposure'limits exceed PEL or TLV.
Before using this product, be familiar with information contained in:
The Federal Standard For Occupational Exposure To Lead (29CFR191Q.1025), first published in the Federal Register on Tuesday, November 14, 1978, by the Occu pational Safety and Health Administration, and as also later modified.
PREPARED BY:
Akron Chemicai Company
Jambs E. Myers
manager technical services
VENDEE AND THIRD PERSONS ASSUME THE RISK OF INJURY PROXIMATELY CAUSED BY THE
MATERIAL IF REASONABLE SAFETY PROCEDURES ARE NOT FOLLOWED AS PROVIDED FOR IN THE DATA SHEET, AND VENDOR SHALL NOT BE LIABLE FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE HATERIAL EVEN IF REASONABLE SAFETY PROCEDURES ARE FOLLOWED.
ALL PERSONS USING THIS PRODUCT, ALL PERSONS WORKING IN AN AREA WHERE THIS PRODUCT IS USED, AND ALL PERSONS HANDLING THIS PRODUCT SHOULD BE FAMILIAR WITH THE CONTENTS OF THIS DATA SHEET. THIS INFORMATION SHOULD BE EFFECTIVELY COMMUNICATED TO EMPLOYEES AND OTHERS WHO MIGHT COME IN CONTACT WITH THE PRODUCT.
WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE
AS OF THE DATE HEREOF. HAMMOND LEAD PRODUCTS, INC. MAKES NO WARRANTY WITH RESPECT
THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. RECIPIENTS ARE ADVISED
TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT. APPLICABLE, AND
SUITABLE FOR THEIR PARTICULAR CIRCUMSTANCES.
DO 085856
- ... -- --
(Essentially similar to Foim O^IIA '^0 - U.S. iJepai Uni-ill ut I.ali.,, ,