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63050000008/S
Monitoring and Reduction Efforts in Decatur, AL
Daikin America
November 8, 2004
Outline of Presentation
Overall site objectives
Waste Water and Sludge
- Monitoring Results
- Reduction Project to Reduce PFOA in Waste W ater
Surface Runoff Monitoring Results
Soil and Groundwater Monitoring Results
Reduction of PFOA from
Vaporizer
Summary of Overall Site Reduction
Overall Site Objectives
Identify the major sources of PFOA through screening level monitoring
- Daikin - Other/
Implement measures to reduce PFOA releases to the environment as soon as possible
Waste Water Monitoring
Waste W ater to Tennessee River (NPDES Permit AL0064351,DSN 001)
Date 7/13/2003 9/25/2003 11/11/2003 12/10/2003
1/6/2004 2/23/2004
3/8/2004 4/12/2004 5/11/2004
6/2/2004 7/13/2004
8/5/2004 9/16/2004 10/7/2004
Sample 677
Duplicate Average' 700 689
Field Blank
Units
1.11 ng/mL or ppb
1010
997 1004
ng/mL or ppb
1130
1100
1115
ng/mL or ppb
599 599 0.282 ng/mL or ppb
1260
1310
1285
1.8 ng/mL or ppb
546 546 ng/mL or ppb
761 874 818
ng/mL or ppb
1960
2030
1995
ng/mL or ppb
1610
1630
1620
ng/mL or ppb
1520
1520
ng/mL or ppb
901 901 ng/mL or ppb
426 424 425
ng/mL or ppb
1450 852
1540 851
1495 852
ng/mL or ppb ng/mL or ppb
Type 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite
Exygen Report# L34865 L35195 L0001297 L0001445 L0001562 L0002120 L0002044 L2328 L2477 L0002651 L0003031 L0003076 L0003412 L0003561
Sludge Monitoring Results
Sludge from Utility (Sent to Subtitle D Landfill Permit # 40-08 by ADEM)
Date 9/25/2003 12/10/2003 3/8/2004 5/11/2004 8/5/2004 10/7/2004
Sample 9.4
29.1 6.43 10.40 2.55 3.97
Duplicate 9.3
28.3 6.36 10.70 2.31 4.04
Average 9.3
28.7 6.4 10.6 2.4 4.0
% Solids 46.94 48.73 55.65 54.32 49.46 56.15
Units ug/g or ppm ug/g or ppm ug/g or ppm ug/g or ppm ug/g or ppm ug/g or ppm
Type 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite 24 hr Composite
Reported on Dry Weight Basis
Exygen Report # L35195 L0001445 L0002044 L2477 L0003076 L0003561
Telomer Finishing Facility
Waste W ater from Telomer Finishing Facility to POTW (SID Permit IU 0852 00384, DSN 006)
Date
Sample Duplicate Average
Field Blank
Units
7/15/2003 153 163 158
ND ng/mL or ppb
12/11/2003 67 63 65
ng/mL or ppb
3/26/2004
15.7
15.7 ng/mL or ppb
5/12/2004
47.9
46 46.9
ng/mL or ppb
8/4/2004
54.4
54.4 ng/mL or ppb
Type Grab from tank Grab from tank Grab from tank Grab from tank Grab from tank
Exygen Report # L34865 L0001445 L2328
L0002651 L0003076
Project to Reduce PFOA in Waste Water
PFOA Reduction
Waste Water Stream
PFOA Reduction
Waste Water Stream
PFOA Reduction
Waste Water Stream
Project Schedule:
- Installation Complete: - Start-up/Commissioning - Normal Operation:
July 04 Aug-Nov 04 Dec 04
Project Status:
- Capital Cost: - Initial results shows
well. - System nearing turnover to Operations.
will work
Soil and Groundwater Results
Soil and Groundwater Data (3)
Depth
MW 1
PFOA PFOS
MW 2
PFOA PFOS
MW 3
PFOA PFOS
MW 4
PFOA PFOS
MW 5
PFOA PFOS
MW 6
PFOA PFOS
0 530
5 10 111
15
20 25
30 35 GW 11/12/03
1/5/04
6/15/04 9/24/04
1700 394
1300
1900
1030 (1) 1590 (1)
3200
2370
416
61
1980
42
48 107 39
50 133 30 79 116
76 35
66 67 (1) 77(2) 167
303 106
96 104 (1) 84
2230 155 53 17
23
333 49
3410
52
1970
74 770
377 45 5 (1) 121
5130 350
129 128(1) 99
8 205
88
259 140 136(1)
425 1800
338
399 430 413(1)
163 954 954 (1) 596
183 86
4850 1970 1980 (1) 3450
1430 372
49 58
952
969 968 (1) 981 (2) 729 710(1) 853 841 (1)
Notes:
1. La3DupliCte
2. Fitild Duplicate
data presented in * rts per bIftton b) 4 . S<j il data ccjfleeted
11^/5/2003 i ind 11/6/:2003
Soil and Groundwater Data (3)
Depth
MW 7
PFOA PFOS
MW 8
PFOA PFOS
MW 9
PFOA PFOS
MW 10
MW 11
PFOA PFOS PFOA PFOS
MW 12
PFOA PFOS
0
1920
5210
513 541 (1)
23800 27200(1)
107
5
1300
1820
599
3010
2270
585
20
10 579 291 287 913 578 463 478(1) 276(1)
15 126 108 308 868 606 539
3.7 2.2
20 56 103 592 572 336 6 0 9 (1 ) 561 (1)
25 157 179
30 GW 377 231
378(1) 239(1)
1740
Notes;
1. Lab Duplicate 2. Field Duplicate 3. Alt data presented in parts per bitfion (ppb) 4. SoH data collected in September 2004 5. N - Not Quantifiable
243 972
1.2
1.6 104 629
608
5.4 1.0 1.3
NQ 10 NQ
1.8 113 544 24
163 121
5.3 64
73
106
22 200 270
Soil and Groundwater Data (3)
Depth 0 5 10
PFOA
MW 13
PFOS
71 7 6 (1 ) 105
172
1490 1660(1) 1350
239
PFOA
MW 14
PFOS
PFOA
MW 15
PFOS
15 13 20
20 4.8 4.8 25 0.6 1.1 30 GW 228 151 28 2 6 206 190
Notes:
1. lab Duplicato 2. Field Duplicate 3. Alt data presented in parts per button (ppb) 4. Soli data collected in September 2004 5. NQ - Not Quantifiable
6, Soil Data for MW 15 pending
7. MW 14 not sampled for Soil due to proximity to MW11
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Property Line Drainage Area Limits
Pon
Storm Water Runoff
Storm Water Runoff from Facility
Date
Location Sample Duplicate
Average Units
1/24/2004 DSN 002
56
56 56 ng/mL or ppb
6/15/2004 DSN 002
69
69 ng/mL or ppb
7/25/2004 DSN 002
54.5
55 ng/mL or ppb
Type Grab Grab Grab
1/24/2004 DSN 003 6/17/2004 DSN 003 7/27/2004 DSN 003
244.0 15.9 89.0
244.0 ng/mL or ppb
Grab
15.9 ng/mL or ppb
Grab
93.4
91.2 ng/mL or ppb
Grab
1/24/2004 DSN 004 6/23/2004 DSN 004 7/25/2004 DSN 004
67.2 9.7
40.9
67 ng/mL or ppb
Grab
10
10 ng/mL or ppb
Grab
41 ng/mL or ppb
Grab
Exygen Report #
L0001714 L0002776 L0003031
L0001714 L0002776 L0003031
L0001714 L0002776 L0003031
Reduction of PFOA from Vaporizer
Reduction of PFOA from Vaporizer
Reduction of PFOA from Vaporizer
Need for more PFOA Reduction capacity due to
- Existing Vaporizer - Low PFOA Dispersion
Reduction of PFOA from Vaporizer
Processes being investigated:
Reduction of PFOA from Vaporizer
Project Timing:
Project Approval Installation Complete Normal Operation
Summary of Overall Site Reduction
PTFE Area PFOA Streams Projection
(Based on Completion of Current Projects)