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J 9 LEI 2NIN a IME J IX TEIC GATIOOFN Ca EE YL adeUT TD] A ariel pL EC CN SR A 2 Lo|)Ta / >. 7 REPELLENTS SP a FY [3403 Do. 0 LY TC SE TR FAT J 3LTALKR OI K N: : iWR By Sa www.midwor-life.eu LIFE14 ENV/ES/000670 Ei em {QAC LETET a Guts CONTRIBUTORS: AEITEXTILS, LEIAT, CETIM, CS-POINTEX,CLUTEX, GSICIQAC PROJECT DURATION: 01/09/2015-31/08/2018 EU CONTRIBUTION: 554608 EUR PROJECT BUDGET:931850 EUR [Te [LT a) LE WDhWaOtRsaDurreaDblWeOWRaste?andOiRepellents cc xe sing WNehinatnawrreontmheentplrocbolnecemns?ase by sorted DWORs {prpoeduocrtsocmhaermyicmaodteo pofroovnegfhabarinc wfiohrohcyrobpohnobpioclymaenrds btaectkbonre ieansiangcpheairnrs oasy bessuetvaernecdesroPmFtAhetpotodgy orclophotic properties detoperfocrdsaFnANtS WWhhiechbDWoORrasnageltoefrDnWaOtRisvrees aavrielaabvleaitlhoasbelaer?e sty dsiied beeen Printed and orn ee coArmiooncnigganotnehesudlsiffuoeniriecdna:tciPedFrPAuOo.Stt)owowochctoiamncpcruheucnwddesl(ekFtnOhoRw)nafmnodstPecproelnr FLleoardatbeydsWkORcrheasi luebntiB,Cp,uCch.r) ocornbdonpsechoarr. wtoerndce ahenfoboldocchuam,ldartinikningatweartebreianngddhetuemcatned around th 2 Wliceonspweifthorsimmialanrscnprdeopervteieso.l MeopsetleflnucoyrpirnoapteerdtDieWsOR present Florineprs have sousd ers ring th st d2Plo0Fic8One0Atmsceaenntpdrtnsdrtefiorcritmvpiaeaordnkrpesortotodnw(uiacplntrnsboeex(tieVnbccaNltnuodnftienedgRxAtpseCotlHaayLrmpiehnrpgcsr)oaodownunectrusieyowinhnceo4lrnut-edh Ccoondceprnsexpnretssbaypnoltymsakaevrrs futed WOR fe the. thnis postponed und ly fh 2023 P`Steerinats SEE L2X shone 3vS sti- 5 ZCrh CCuarheonrtssaruebsaiisteasndi rtthhe meackuet,omrosatyrbuasedsoonmeCrartioonal RtEAhCHtestihcotvoensoatted the proce onde the ta the T165hanrdeuptdheoretshaneiemvpnetsisvtekenhodldeirsdndapdlyemaskesrsion haned bheesstthvaimlpalcet ecole with migted evronmentl Themain objectiveof MIDWOR-LIFE was themitigationofthe Specific objectives: enrvmiartoinvmeeDnutarla,blheeWalattheranadndsOafietRyepiemlplaecnttssoOf WcuOrrRentBanyd aol- ri5aervahlouamteitehesenvironmental impactofcurrent DWORs and rinrg thoeireensvireolnmeemntal impact and otnecthhnicbael ah. performances in, 7"5eavatlueatthheeekrissks pPosseddtobhuumranranrddeenivinroenmental Rologies for repellent finishing. +To compare the technical performance between current and -- TTihveenMeOnwWrOaReiLgF,nE preetmofdmotwno min ammo. same oy reminn I i --r -- mcormsmiseo mrotoatm Ye om ten JI RO OUS SO AEEAS CE A pr---- a ML oAwarrheneeoss raraisyimng mr andot co1m0mungs iecnate-r RKASSESHENT ToHOWE ootyhereoxcwoammrennibnor,prsoenof poe avout ext a oun CcFoomrpmeptciatisvenmeissofdtehre eEudrowpehan ttoeoxotiktlge RES J-- -assessmentsoftheavailableDWORs. Se, EERO eWnIvDirWoOnRmeLnItFal hiamspasctkudciaeudsehdowbytcourmriatnitgaDtWeOtRhSe (Durable Water and Oil Repellents) used inthetex. tilefinishing industry by analyzing their non-toxic oY Action 2lienatives ereeanarion 01 ti lis dpi. 8 ndDWedOndfRfresnt @ Tete rereenensD ormonsruamion A ENVIRONMENTAL i IMPACT Action :. __* ACTION [IETS enn Republc (2. Fibers al Life Cycle Analysis . S SEe--e -- s2 MUnOiWonORanLdFtEhsenEE+roFpernaprnojenctocmoefunndtedbhyttheesEueroEpeos ronment Policy and Governance and under the Grant Agreement 1 LIFE14 ENV/ES/000670. oeAeErIltvToEinXeTIeLlcS,oamenptoonle-nrepersofoitamoirrngcSanphioozaotpiEosuTnAnraTeprTte3sheeeeoncetpirnhnrgitetheteTCoCeaeotcanlnotanen ETM rd th IntofuAbtened ChaorfCitrsa om CSIC plus 2 technical textile clusters, CS-POINTEX from tly and `CLUTEX from theCzechRepublic. SeMIWDWwORLsIFE rperojeecteosannieexamcrplae opfceolrlbosratoifotnboetweeenmcus 5 sociocconomic . RB ACTION IMPACT : 04 oon : kemate DWORS pac :3 H . eon wore kers comd munity 3:I cosreamncr .esccsccsese Epon 3 icy 05 dAucsteslewcatisonpeorfftohremeddifberaentsotneetxdhtermesautletrioaflss uanrd vfiwesihytihngexptrol-e fThre efatbricsecsteolresctoifonthceontseixstitlse oifndufsoturry:fawborircks wreeaprresuetnotmiontgivfev,e tchoempdaunriabelsehwoatmerprtaniciopiatinigshcilunsgtperrospoernttihees.sneedsnregardto hometextile,fasanhdspiotowena. oSoa Carpeas Sd pYiopoen AUTOMOTIVE wom wean Qaokies We mm sg T0asi asteyd some TR Home TEXTILES 4Clg, tAirtser ( Yor = of Vsgw sTiws o LE iFnoculrutdeienng urecpreillneanttefdinainsdhinugorpriondeucftrseavpraoidaubclteson the marke were selected cs 5 EET [2 [EE r PFSi LLnL EEE Fionstthoef lditfehresnetlescelteecdtreedpfealbreitcsfibnyisphiangcipnrgoduotctpsiwtersecaplep.liTehde ipnrtooctewsocosnqsuiesetzsionfgirmollps,rewgerneatthietnhegexcfaebsriocfatnderthen eihnmsienrotitnegd. ThTehfeacbhraircacstetrhizatciroinedofnthdecruersetdendasastmepnltes miancclhuidnees.the spray desetrt(oUNevEaElNuIaSt0e0t4he9w20a)tearndatnhdeoolfreesptel(iUenNcEyEgNrIaSdOe,1r4e4s1p9e)ctnivrel.y. Thhiensge(teUsNtEs hEaNvIeSObe63n30,per10focrymcleedsoant 3o0rig)inosr sdraympcilcesa,riafntger(UwNaE EN1S031a7nd5r.on2in,g .am " SPRCHBRPUBLIC INOTEX NANO CLe--l e ) ----- ME EMBRD ANE @ mo SPAIN 2 hidroc4olor acme Lwl on. ) LL as spoar ITALY rao BzEtT,TS|| (CEILS| a Trheesispraodupctlsotshcatle,acwhieeevedselbeectteerd re a phiae Siing hsttcehieseesoltecentded toproodlucyt,obny Tuhenconmpainieos wtohaotconlmabproeratEtred ming the industrial demonstrations ofrrom CtonoatcehxRenpdubliNcanBoemleamMbarannaet, 2u0r0e0.Tfersoim layn. TanodrEa iFiniassnagglo roc rom"Span . ine | i iEe(e Sa H t oS | 4 fv0 bs e pSSs fm | if a 7 Ai7o ) n -7|) J) a "by k ATO SPORT/WORK HOME pasion Hifiomn ener | tors | pee | wets] a ---- 5! r= I-- |: CTE Ld eer LU ie | FEET pCri Sirs | : mei] BH1cll ar : ER i [ mi- r} EI ayes metoiuntan mt wety UTRoe IymE sfbesser em ett Thereisusonnwadtransdod seepage hohe thot srheohualdb also be more accurate and Rtheagtarifdionigrtehpeelrleesnuclyts,sittrcualny nbeeedseede,n oTro afpelfotrhosriecqouinreemceanntb,eesnvoouignhg ohewueseroffonog chwinecrpocrubons roecrdeeaseimaptarvteiscraynonapcohileyveesvieerry nootnhftlhueortienssiteed.procduhcetmsi.stTrhieersefocraen, pCrhoduucttsefortwhaetfeororrienpateeld lOnwWicOtyRh etieoCBpnbearafsoelrdmapnrcoedutchta.n coven teT aTvt--eeIon ihTo--si--ea s pm--ediie--l teSe m--ocremw--spte cupnCtTgsspThasfeoeotdy scdlhonn wasnotreportedintheSafety Data Sheet Questionnairetocollectdataonoperationalconditionsandriskmitigationmea: EH rerare atm ates amare sata Assumpwterieboansesd on public Characteristics determining exposure e eeS e i | GideIL : ; ces of thecomesponding chemical family Con et ote ~ m : a usedintextile applications. sed on harmonized classifications and, if onceation ProodmuPhcysitcsateofthe rod | 4" ed [---- i Aol J oT EsreennoSow mkaemehwey} 3(2 | iortiis [2 i a ee polymers, based on the properotfitehse i mre Si Cr sorsor degradation products). oductsofthe textefishingprocess Risk ManagementMeasases(PFE) hmmm, Rertastion ofStefenmattaerfamed Chassfor yesandinhalation, SN DS erivattiono of ffenHazm ardCa lassfnoreya esangdine halatr ion ppppp monger hazard dss per product armen Fi En oiidl 42800]andschpolymersare resetin hepat. HigEr rESemrEsreoEenee Paes eo py prey acveiogedent | handasesment a | [ me [i] RB rFtyrd [Core [Ceaend| ww [io Sin) Stn071) wee | [ree] wim ee| Challenges in the comparative risk asm proces 8 Inthe commercl products evlunted the chemical deny IS p mpe l ao ed y ebgyy `ents thatarenot triggering the hazardous classificatioofn the WFeEhr o hme ae n aTCap OSeTS The potential human health and environmental impacts of pti all polymeric alternatives. However, these aspects could inde- `edbedetermining the differences in terms of humanor enviose Conclusions. eat yds the he ec i ton take ntoconsiderastaifeotny spect associated 0 S ea ee pee fbi nln, Sohconsserdl isn]ios t cones. I eTeRi Ten dI n i products), but precursors and degradation products may be. *8 poFeeteaEsrgoeth Stuy roimiAt-s dients during the drying and curing steps after the padding Te emer. and the hazard properties of such kr y i W Duetothe large number of assumptionsmade during the risk SFpieenrrclueuoo2ar0co0hc0eh5e,rmimicacaanllysblBatseeArdatODiWvOe(RsCSrh,CavbeBbaseeaednipnorotlptosPesdRhCotIoretrnecphulalcien Eonevpiroconfmenemthal Cosathermativs (products show in geen) re ee pe ame ee rs tpaenrfcoersmwaannceesa,nsdiieonnveisr,ondmeenitnalerim,paictcmuHsotwbeevearssbeostshedel1ea. tcrhaaned)e.ndSrcimoerbbaasseeddreeppeelliennttssp.rae 5fappospe rsepeltlhentssarmee successful substitution process. `much cheaper compatrotehde fluorinated treatments, but requi- mpLirefoesdCuoyccntlseo(ArCsOsaMe.ses(meUsnDt9(3tL0ChA2)pohftaeosnbmteieaalnceponrmipoorpnemhoeesnneastidsavlethieamppbpaercsottasfcrhoa,-f 'heapghrnioghfeersdossagei. Tihe pcHrighaioefrctthneehnpteCroflynuodroCsiibconse aspsreosdsuecdtisn Covering all he stages ofits He {aw matters, ansporiaton FA] 2mperonhdtuaclthisoinm,bpeuaescnet adonefdvetdlhioesppoedsdiaflie)n.reoAnstpraDrWt0dOoeRfvsMaeIlDsuWtaruOtdRei-etLdhI.eFTEehniPvrsiojrLeocCntA:, 4i2d0 oipfnecftlhcurdreeoesfslsiuicoxorsinneca)teeadnnDdWthau OourRceoSimr p(oaCrBsePAi tChfe&eeneCvn aiOtrPeoFnmCmae etcnihteeasmlisf(tohrotyopnraienn.dt Senderand para. 231000, 0 | n mno,2 iSmepascst, swihtehsa rtheonttCeEffPeWctERo,verbhoumiaenhtoerty ecmuisvedembeyntshle teease of PEC related compounds such PFOA, and PFOS. I pactof C6DOR s significantlylower, approximately 1/3 of ts oSCPCSdePvtativesteooveerenveinrvoinomnemnetntaanndshhuhummraanneraeeicliybao4ncd5 hReegsamradilnlgstfhoeotfpurcirntinaemfosnsgOtWhOeRDsWsOtRudsietd.hDeenodloewesdhboywse.d CcaommapnodupatrafwfiithwiatrhebdaurcetliyonnoofditfhfeergelnocbeabletImwpeaecnttohefse97t.h9r5e%e CpormepcarceomwpiotshitCi5o-nOdWoOeRsThnoet aalclkowof freolrambalteioconmrpeagrairsdoinngbet.s Treenthese ree compounds. SF27 oF Js SL OOFxhas cots late to he C bardproduct Ieneavn dadedtneitraomptifunrceivhanoosdrinnemgccnocsttostl,sceohxtmaepvrlenaelbmieeteinentsaeirsynmdianitfeeodcrmobayttciohooonns rainyglthiempeancvtirsosnmeesnutmaelntImmpacttshintsoemdonfoertacryotcerams Tthhee immeptahctosdoEfC,ex20t1e0ntTsh iessCtiimaet,edwihnidcihneft covtlsdofnpdrordaucbilneg n1 akegdofprWodOucRtsp(aCdhuCcatnrdepsehrofwanroinsithconierheavbeehloiwg:heruiodt Corevctacdotsthhaenruwrhionnemfmeeeanpnrtdodaumctasnduhee0ltht higher pact ao ewan ons0m0 ww EE --- _ GUEGONR ebm She Dd un B Blth mti r) 88eehdmciney 2 nz 0 v 08s. 5 - un CESS R&A R? TehnetMOiWnOdRu.sLyFbEouwtebthteoelnvaimrdotomraeinsdneatanwaaarlenehsesat0h ti he taatdthe1iunaindeexoerrsntofaunsnardnsxipdenrtgfsonproeeslsonaaslstesemreenstteidn ThecttosooflpdiidfeeDthrWeOeRnsedttdavisstallzawAtinothhninpgcptroocgeasmess0.a|cl: mtoelreaammvaolroeesaobbotuatintheids methodoalnodgdey deeper then Calculationofenvironmental&human healthindicators Availableat: https://www.midwor-life.eu/ Cnponotro Ronan53 OP easoal os Hoe Pefirosiicone EBYBEE We Pesfuoosibone AA, AA A bots B| bnlols A reResultsforthe amount of textile treated Cbeent eo oe oe} --- ao 1-1 C0) Tmm odeioote nAnnrseerteteeoertrmpsenes RECOMMNDATION FORUPRAINGTHESHEEFOR eR moTan tt en an for theTextile Industry and it covers the industrial activities naor eam com rs h`eachirneg,atamnedntmecracpearciiztayteixonc)eoerddsy1e0inognosfpefirbrdeosyo'r texties where RECOMMENDATION FOR UPDATING REACH ANNEXES All selected DWOR proardepu olycmertsasnd thereafreonroet T aa DTe eo eti h bn ned hSn eSg rtpa imm teasaaemn osrreatepmeeaaorebmiss ssiblereleaseofmonomersandotherdegradationproducts.No ii] || Oeste | h Er E ed a TE Shekel. GEeLsr a dahac he, 5= fag cbmc S petnereS onrancov -Presenceof funcrteaictiovengroaupls. FowslHoosddfsiadbbi e ECD reieom oaytoms RECOMMENDATIONSFOR UPDATING 2 VOLUNTARY SCHEMES t r=T Sieonrnm|| S r S Spe| T am rs| I |a nmn r e rer n [N(HEESime | N =She IeE, ccna mateldye gt . ty by the implementation of the proposed altematives and the relatedenvironmentanadl risk management measures into EU Ean3% = 2 kes project tte Tussin) | pes Salehddersieahed|More than200 MWnirndiReeseasch 6Policy /Governmentbodies | "Themainactors involvedin theprojectare: ~Teaxndtchiemliceal companies. ~Researchcentersand Universities Platorms/Associatons. PmPSypmparaoeratsyepery of Perfluorinatedcompoundsboth to humans and animals. EE a "Increasethe qualityofand quantity of OWOR information :e--Si v"oS oprve[yy tiomrcgemihnrrra) e Wagorgies Organisat/iNGoOnSs. TS hancatins Maethan20 Compares ir50epartas than 15.000people fos os ineomate thesearch for innovatriisivneg products r mea ai t e do ryoi ~Optimize thedomestic economybymeansofmore. diseminatioactivites sescccscsscsscsscsscssnse PROJECT DISSEMINATION AND COMMUNICATION RT prt oid LETET , Em | KER --_--"] a A rd fl ie REY i nl = va ~ ' 2 ] pl J iW gE -- SOI | SUSIE ap I neocon r= ~~ Crea J IY. / agi @l f g ie ' of Vs 4 J === . CONTACT: ) BD HONORA S$ = INFO@MIDWOR-LIFE.EU h p. oo. . C0 T Let's make a more NUS Elat=le)le world 3: MR J ihe iv FX " BE ALY J : VJ XE yo Oper? a . & o P97 :Y -v} . " ; yf po ; 9 Tr) Fd 3 Li 3 Re)l geoo, EA 2 pou Be > RR y on ? > 5, gp TALE N a. Al nm . i, i 4 ie} yf . 3a - 4 or ? ef ECE 5 PS : C5 2 $ > `> i 9 ag = ; Py --f. ETEF ME . + 3 % Le Bea TM ot Fo 3 ti v A L is Edie - oOR R An LES ie Bl : 23 + J B RXSd 5 i] re bd = et. R3 AN5 3 y3 el . PEA os ny : ; AREA ip Re CR " oil =x AFEi a cerm Biter QAC LETET a BB