Document wD6BdkRQ5QjzoBn7DQLr6ZLN4

XULbE- AND RECOimTlDN' commonwealth or Pennsylvania department ot health Chapter 4 Article 432 ryuUtia&c> Establishing Threshold Limllti is Plscca of Employment Under the provisions of the Administrative Code Act of April 9, 19291 P. h> 177, the following i*ule* and Regulations of the Department m Health are adopted this 27th day of October, 1941. approved As to legality of content this day of 1 19^/. it* "?J r<jLHi>nrt r' f I^smi ->'t t ir, d 3B3 Noith 8tr%Kf Ivmivj^r 17120^090 Rft 11 f.'.iT r Coin "i*irr t,- r G, LaciU vtadktlwa ' aball tv#*w that type of veutlUtiati fan. i'^ikU traction Is applis? ut tlw p<.tnt of generation if justa, iiur,e, g*r <?, vapors, md rrUt*. H, t' ist ibaU <vi*4n Ifajuid droplet*. cuapcnuded bi *ix. I, '''Uc of er<>picr!ttt shall uan j. location or sits whsre on individual (tni00t43 U* trad#, occupation, or pr^'soion for Siiktt <4 T, ditt, J# Throw hold iuiur.it Value p~J <**ir*iu?n ;,Uv>wttbb C(tcontr..tl`;wj, tac) shall r^Mii tha t.;iwimuw *vra$o uV : ^apberic c ontouftrutioa a ^ctst-*v inunt to which workers may be exposed for *a cl|lt hour working day, (T!w4 vuiueo are eat iorth fan Table 1 hereof, -//hich table is e part of teas# ra^uktfauw), K* 'Vapor'1 ahull vVvan ouay liquid, Mcnpt water, which svfoen held ia suspending in air will revert to lie original liquid Mate after release trw heat, cbe `ilod acUcru ss pressure rctuiiti>^ne, -ectiem 4, Ssnplciyer'o '.Attlee - Kvcry employer ahull install and provide ouch control ^oueurea and protective equipment as U required fur kbe nrocectioa of wulfb. 3. Svttrv enr.picyer shall inform and periodically i>itrurt ui* u'^plnyeeu ^OtT&rding Wwn buturdo and proper r.ethode for utilitix^ industrial byyida control treasure* vblrh are provided, C* V. baa It i* necessary wr an employer to provide protective equipment, each employ#? ekwll provide aa approved ir-stan for cluardn^ and tJteri** Using such proWvCivc equipment. and the employer shall cause such equitr.^ect tc be rj aAutainod in o cloun and sanitary c -taoiUott. c^espira* tor/ (tqui^iTUMl skull sot be pas sod front one man to another until such equipment is clean and sterilised. v ocn illtcr or eurtridjjo type respirators are used, such e^r-pioyu* ohsll have such roaplrdor inf his Jrmm eaclu^ive use, ft empire! cry e-^ilp'riat *<ad rapiece a-unite oiwll bo staled, when nit in u0, in apprised t; autsiwera. id. V'buo tiu* st occupaiiocAl cieause haw occurred or when cooesnciatkna of efc-toepburic GutArrdb&*nta ia cxcees of threshold li mits Have been found to exist* the repartees* -ay require any em ployer to have fclo employs#* enanuned at periodic intervals. These 3Uo- buttiers* rray Include X-ray ufcomfawtica* and Lifc-.-rstory studies wUan indicated. actios 5. Threshold Lirr.it VsWu No e'rrpluyaa shall be cuprosarf to aitr ospharlc concept tili'xn* .if contaminants which concenlruticca -nay give rfaj. to occupational diaoaae. Table I shell be used or the deter filiation, of per'. isaihW levels. S Liep^aures to atmospheric coata/nimnte at adverse environ' vot-sd cooililwa not referred t*>in vctixi 5.\ shall be r,nxtr >lleJ %ben ftscssaary to protect health. jg'iniducfrv i * Ur PA SAAT^ HOKorSlSW* ( V JO U ULA. J -vKT? , :.QU L..-- TiON C: , LTH PN Yi.Y-.NL-. t-'SPAKtVEMT Cf H&ALTH wliu^ttr 4 4iZ S*{b)AtU;i hir./ Tfo*~bald Lir. itt b -yt C' play var.l 'JttvJ.Tf '. u, 177, tb* A.rn vivp\w thi `vi^ST^ ttri i 'infot-.ilivc. Cc*li: , ct /; April % i'-Ci* and : the <*$>&? t -i: Heated v fth tte ? -if *..rC-Vor*, Ivnl, ^rtion l. "'urp^se liw purpnao t*T tWbre result*tfon.H* awi -jt-tzsJ*.''*, tc* ; iui u - reipiir^r* unt - Ati4 f-ar tin* utlnfctfiiijtii c i-i -c tMi,ijtffoaal in i>li, oei Jf ^ *r ploy :n<mt ( T" < -'icti ^ Z. .^Uatli.m TLe-^a ^e^uikHv*' and utajariurd* apytlv tn -jiy^ir plsjji; >f -. piay-- 11 I . ' "v <initiator . At: aapbtrit: c^ftta-1 ii*uitt i^jitJ : nsvto>~lfel in air u$4dlv it* vujrar* 4t . ,bt, U uU>wec a i.-i > ji n daat, far er B, ' Dv pa r*TOttt j b*Ul .-.<**i tnt * po rtr. ij t of hi - lf i* C)rv ' mt* alth or Pui*jrlviiiii. C. Punt chilli rt'e*n ffogl'j d\vhJod s;-lid iihj h*vt*ig &ae*J by aritani-^jd crubof, r>d thiflfog, ^ 4Uplrlr(ied in iiIt cveh a 3. ^riurifog, L1* >'u^a T ilmll TMomXk ^ilid pi* :*ticL*jrt cii*por*{fd in *i; rcsultis,^ 7*1iv chc^iaul vir ouyyic*L praca** fcW bvAvad ^ cfctin^e St>b, iTtjvb up CAnbnatiofi, oabli-r *tiori* nt *.n-, ;' >d(n^.ti^i, E- 0-^.n & h*il .1 for W* fluid <n copying tha . fenrl.^ure,. F. Gonufol ut tiUuitfon s?tll a^n vvmil^zloii prnvidud t^i dilute the of duetd* &- '<], ?<iws, rjpu"^( : tU ix\ tho st tli c,' ^ ?bc pls-re ef crr-fti&y .^aut. - Ch* 4-43Z .i. HrpruducMon ef n Onsfoi flosd ^ PA STATE ARCHIVES -'. '; rrn Slj ..: \ F^ ! '! V-',: rf- V. l| ... -,.. . .: .,. ^'. b* Aix and is churg* . Ho xir frttm Atjy local esbauJt vm&U-lUou y*t*rc *V ! roc ir>'ukit*d without ciqjrc jj epprttntl by tine H^avt^tOL 13* Thi) diach^rgvi oX *tr frum any v^au-it shall be inch th^t - air fatili'nimitiMi will an*r my window, doer, oi othair ap+uls^j of fray work Are* ir. nuentiti*** ^Icknt to erMta a fceaj&h baxur<j to or in ducb ere*. *1 Action T, ajik'j and Veev^tlc i. " ' t _ ' , < w No iodlvidtul shell bu per i:itt*(t to utar * Unit or clofcedWflt;clasfU It has b*c*n ascertained.' thai the utn;o*phr* In the tank or va<Htl. ctunteW en Ade<juotts cpjutetty a!' oocy^cis and that r*t'!i^tr>&aric c ^atacnlnant* have bwnt dilated to i>ite ct30vo(4-r*liane* & IX the Miygea cetttont of the and the ciaiH^v of ut . :,$photic um* UmiMlion ere no* drtsmliawJ, :otfy to the tank or vw*sol ilmli im prohibited unkits the wocSl m if *4(Uipped with m *lr line reopii'aiOT, * ubiety btrstit ami atifuty line, tiiat smother erT.plo /tu he atootoned outside thu tank or mttol to remove the w^rlirAa in tha or vatul elvuld he experience difficulty. -iiction I-t'.Mittikueplag The interiors, exteriors, And envir^iv* of huiUUr^a where luurdDUA vjtorlilit era itotod, w lunulod, bail be i;lAid and cuila. toitttd in swh u ri`iii!ur as to prevent hdcrrriul ^tp^tiro to harardou? nieterUde, . lijr.pleyees engaged In ouch Mpsriduie one all Uhere who roy be expaeed ctull wo*r protective equips nw uh b- '.required. The downing operation* should be done by auction afp&rtfo* . C. V-here wet processes ere Gaod, rueeoaeblo dramege should be j.-udn- tftlwd, Fsliwiloot*, plitfoy^'K, irmte, or other -jf #*j footing should b* provided. Section 9* uebollsg ^d^uu*e identification^ wemJng, and ceutk'c iebt-lr shall be applied to eii cttnfcelnere of kiiATdout cbs^TiwU* A ' Hnvoctc^f T :r *=n w'"- fivUi or< PA STATE ' -' . Oubst--ce Table 1 Threshold Li-nt Values ttlfc-J Vapors! P.P.M.* etelilehyd* ftfetif i-cW . icetic anhydride JtCflaM Acetylene tetr^rortUQ -\tr4in _ ^cytcntsril* - ^ U*ri ^k'vhjl - ,:taJka Attyl sMaridt i lly1 ptopyl disulfide -vmyl acetate Amyl iilcolia) (lo^myl elcahol) Aniline * Stein torefei* kanoi (Lxrnc&l) Siu>l chloride Boron trifluorW* BrcRxdon * JBtttedWtrtj (l,3~eufcadi*iw) Z*Butuuuer (rAtkyl ethyl ketone) Bu$yi acetate {rv-Autyl acetate) Butyl olc vhol {n-btu^nwi) tort. Butyl slruitoi iiutyUt'-iiu iiulyt cclloeolve (2-buii*xy*thaxti>l) pau-a4* rt buSylljlueue C*vb*5. tUoacitie -. Curbed Ji suitWo - >Kin Corb jn munASlde - Carbon tetrnehlQrtd* >bin CeUcHceUve (a^thmyethanol) Cellos olve acetate (2-ethcrxyetoyI acetate) Chlorine Cttoriae dio&dd* Chlorino triSluorida Chi or sriomi^tr ic laW on^ttsene) l-Calt>ro*-l-nltc*cpropatw Chios-optorio -- .. - Chlorofurane (2-chlor.a-i, 3-butadiene) Crcsol (uU h^tera) - .itir. 200 to 5 1,000 i C.3 20 Z .3 2 iWJ 200 100 5 0* 03 ZB 1 1 0-1 1,000 200 200 100 100 5 59 10 3,000 23 100 29 200 100 1 0.1 9.1 73 30 20 o.i as 0 r,pproe. Mg per Cu. , 300 2S 20 2,400 14 1*2 40 5 IS U ?0 1,030 360 If 0,2 30 3 3 0.7 2,200 590 950 300 300 15 240 60 9,000 60 11G 160 740 340 3 0*3 9.4 330 240 1&0 0.7 90 22 HOTJSi The ward VV&cttt u c<mpstaad's nar.e Indicates that the liquid cv. '-pvuaod can aenctruto (bo efcia to cu*e syjto ' tc.- effects. -4 - JtikBt ft PlfMi* 0^ PA STATr 9iD "rt*Stt*d.H- 1 " t*'2V.S" ' jubilance PhanyJhydraslaa - ^ki* 9 PbocgM* (crbooyl chlorfcia) l Pbtjopliliu 0,05 Phaupfoarua trichloride 0,5 Propyl acat&ta 200 Propyl alcohol {Isopropyl alcohol] 400 Propyl other {isopropyl other) 500 Propylene diehloride (1,2--dicbloropropantj 75 Propylacm imfn* - Skta 25 Prnpylww cjctda ICO Pyridino 5 Quinaitc 0,1 StSfctfoo 0,1 ^todtfurd solvent 500 %r) monoivor (phaxxyla&yleuo) 100 Sulfur dloxida 5 Sulfur hoxsitaarldo 1,000 SuU4i` iHLjtt^cUorisio l 3ulfur platit Hunrlda -- 0,025 ti l*-l ctr*cldoro&thane - kin 5 Tatxuhyd t 4fti*aa 200 To tranlt r sometheac 1 Tcifoom {U?Wl) ,, 200 ortbo*ToLaltiina * Skin 5 T aJ-yJoiui -3, C-diU o^'^niU 0.02 T ricblo r owthylera too TviothylaiiiiTM 2$ Thnueyor-, on^Tijt.1 1,000 Tujpoutjpg 100 Vinyl chl^rid* fchiocroathylene) 500 Vinyl tchvenr 100 Xylene (vy lol) 200 Xylidinc - jldn 5 AppvoWf Mg. par ca. M, 22 4 0. s $40 930 l, 100 250 60 240 15 0. 0. 2,900 420 15 6,000 6 0. 35 590 6 7S0 22 0, 520 100 6,100 560 1,300 430 $70 25 -- 4Pirti of vapfcr or gaa par miiliao part* of air by volume at 25 C and 760 mm, )]t. kV*pp3 OKimatfi mllligrame par cubic rioter of air. -7 * Mr sr in v-;. - f~ " - PA STATE c 3W N<*rh O' >;7 " t I '- Cff[ !* `I*