Document vkzZG4nmwELwa3kMLaakyrjm

1980-01-15 RE: ALCOA MATERIAL SAFETY DATA SHEET MANUAL Attached are AMSD Sheets No. 1-11 which cover the following eleven hazardous chemicals: No. No. No. No. No. No. No. No. No. No. No. 1 2 3 4 5 6 7 8 9 10 11 Acetone Acetylene Hydrochloric Acid Mercury Methyl Alcohol Nitric Acid (55-70%) Sodium Hydroxide (solid) Sodium Hydroxide (50% liquid) Sulfuric Acid (concentrated) Toluene 1,1,1 - Trichloroethane These sheets first had a preliminary screening by the Committee and were then revised to incorporate the various suggestions and input from the committee members. Now these sheets have had a final review and approval by the committee and are being forwarded to you for subsequent inclusion in the AMSDS Manual. J01AA--------A. B. MC KEE ABM:km Attachment cc: Members of Corporate Hazardous Materials Control Committee J. S. Boyt, Pittsburgh 07 H. P. Brueschke, Pittsburgh 19 A. E. Davis, Pittsburgh 24 R. E. Edginton, Pittsburgh 22 G. C. Heise, Pittsburgh 06 R. M. James, Pittsburgh 07 R. L. Miller, Pittsburgh 8 A. B. McKee, ATC-C B. N. Peak, Pittsburgh 18 J. R. Stemler, ATC-C R. E. Toth, Pittsburgh 03 D. A. Whitfield, Pittsburgh WPH 3 Q ALCOA MECH. ENGR. DIV. 1980 JAN 17 MATLS. & STDS. DEPT. \ SF-4563 (rev 11-ee) 411538 0121 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET 0 ALCOA HAZARD CHARACTERISTICS 0 Flammable CD Combustible CD Corrosive CD Explosive CD CDWater Reactive Radioactive CD Oxidizer CD Chemically Reactive Toxic By: CD Ingestion D Inhalation D Absorption ISlO.. PRODUCTACETONE Phone No. Date: 1979/12/21 Section I. MATERIAL DESCRIPTION Material Name: Chemical Name & Formula: Other Designation: Corporate Stock No.: Manufacturer: ACETONE CH COCH --Dimethy^l Ketone, Propanone, ASTM D329, CAS# 000 067 641 Available from many suppliers Section II. INGREDIENTS % HAZARD DATA Acetone ca 100 TLV 1000 ppm Rat, oral LD 50 9.75 q/kq Rabbit, skin LD 20 g/kg 50 Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid -56.5C (-69.70F) Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: -95C ( -139 F) mm mm If a :s-c-"i (CC14 = 1) ------------------0.8 (2 0/4 C) ------------------------0 .792 (Air = 1) ---------------------2 , 0 "Solubility In H2O": Totally miscible Color: Clear, colorless Odor: Sweet, mint-like Odor detected at 200-400 ppm (500-700 Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. Others Volatiles, % --------Molecular Weight ppm after fat-i gin ajg- Flammability Limits In Air of ca 100 58.09 nerves). olfactory Lower Upper Closed Cup 0F (-18C)|538 C (1000F) % by volume_______ 2^1*- 12.8 Acetone fires are Class B fires; use a blanketing effect to smother flame. Use CO^, dry chemical, alcohol foam, and water mist or fog to extinguish fires. Water may be ineffective in extinguishing acetone fires but may be helpful to cool fire-exposed surfaces. Explosion and fire hazards from heat, sparks or flames; can react vigorously with oxidizing agents. Use self-contained breathing apparatus when fighting acetone fire. *An authoritative source lists 2.6%; however, lower literature -Value is listed for safety. - ------- Section V. REACTIVITY DATA Acetone is a flammable material as indicated above; but it is stable under normal storage and use conditions, and it does not undergo hazardous polymerization. Avoid contact with strong oxidizing agents such as nitrates and perchlorates or concentrated sulfuric acid. Oxidation in a deficiency of air can produce carbon monoxide. 411538 0122 Section VI. HEALTH HAZARD INFORMATION TLV loop ppm or 2400 mq/ri Acetone is one of the least toxic industrial organic solvents. Irritation of mucous membranes, headache and narcosis can result from extended exposure to high vapor concentrations. Prolonged or repeated contact >-- of the liquid with the skin can have a defatting action and may result in dermatitis. Absorption through intact skin is not of great concern in industrial use, since acetone is not expected to cause systematic injury. However, possible skin absorption should be considered in meeting TLV requirements. FIRST AID: Eye Contact: Flush promptly with plenty of water and contact a physician Skin Contact: Wash off with^Water. -- f'....... Inhalation: Remove -to ffeshc'air. If effects are more severe than headache y\eontaetj a physician.' "f.d cw.-. .... Ingestion: S j?lhkcwater to dilute. Induce vomiting and contact a physician _____________________________________________________________________________ Section VII. SPILL, LEAK & DISPOSAL PROCEDURES a If spills or leaks occur, eliminate all sources of sparks and flames. Flush with water to clear area of material. Avoid breathing vapors. Avoid discharging directly into sewers and surface waters. Incineration is a recommended method of disposal for large quantities of acetone. Section VIII. SPECIAL PROTECTION INFORMATION;f '\ Use ventilation to meet TLV requirements. For higher concentrations of ^ acetone vapor, use NIOSH . approved respiratory protection as required by the acetone level. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, chemical cartridge respirator, etc.) will depend on the actual or potential concentration present. The use of safety goggles and polyvinyl gloves is recommended to avoid contact with liquid acetone. Protective creams can also be used. Section IX. SPECIAL PRECAUTIONS & COMMENTS Material should be stored in a cool, clean, ventilated, fire-resistant storage room or cabinet to meet OSHA requirements. Store in drums or safety cans with identifying labels which indicate the flammability of the material. Acetone must be stored, handled, and used away from heat, sparks, and flames it is a Class IB Flammable Liquid under the OSHA classification. Electrically interconnect and ground containers for all transfers of acetone to avoid fires from static sparks. D.Q.T. Requirements FLAMMABLE LIQUID Section X. REFERENCES ASTM No.: D329 Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: 000-067-641 S D-8 7 Other: : 411538 0123 For Internal Company Use Only - N ot To Be Distributed Outside The Company ui ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 2 0 Flammable O Combustible Toxic By: PRODUCT ACETYLENE 0 Corrosive O Explosive 0 Ingestion IH Water Reactive 0 Radioactive 0 Oxidizer O Chemically Reactive O Inhalation O Absorption Phone No. Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: ACETYLENE PH Chemical Name & Formula: 2 2 Other Designation: Ethyne, CAS# 000 074 862, Ethine Corporate Stock No.: Available from several sources, including Union Carbide. Gas obtained Manufacturer: from reaction of calcium carbide with water in an acetylene generator or from Section II. INGREDIENTS % HAZARD DATA Acetylene Gas >98 Rated as simple asphyxiant Typical % OSHA and ACGIH. NIOSH Impurities:* Carbon Dioxide Nitrogen Oxygen Phosphine Generator - 0.018 Cylinder - 0.00025 <.1.0 <1.0 <0.2 Trace proposed a 10-hour TWA of 2500 ppm because of toxic trace impurities Hydrogen Sulfide 0.004 0.0007 Trace Ammonia "Acetone , (an .. impurity 0.015,. in cylinder 0,0000 gas) and water ei liastd. i mnppuurity content should be _____determined from the supplier of the calcium carbidt or the < di Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Compressed Gas at 1.22 atm:-75C (-103F) at 1.0 atm:-84C (-119F) Others Molecular Weight: 26.04 Vapor Pressure: Evaporation Rate: Specific Gravity: Liquid: 0.613 at -80C; Vapor (Air = 1) 60F, 1 atm: 0.906 Density: "Solubility In H20": at 0C, 1 atm, Vol/Vol Water: 1.7 Color: Colorless when pure Odor: Odorless (Most commercial grades have garlic-like odor from the impurities) Section IV. FIRE AND EXPLOSION DATA Flashpoint Gaseous at Room Temp. iAuto-Ignition Temp, Flammability Limits In Air ca 290-335C (vari lie) 554-635F Volume % Lower 2.5* Upper 81* Extinguishing Media:. Extinguish fire by shutting off source of acetylene. Fires from small leaks in containers can be extinguished by plugging leak with wet waste or putty or smothering with a heavy cloth. When fire involves the inner cylinder, it must be handled by an experienced firefighter. Use water spray to cool fire-exposed cylinders. Those involved in fighting fires of acetylene should use self-contained breathing apparatus. Use water spray to "knock-down" vapors. *3-65% mixture in air can be explosive; NFPA #49 indicates upper limit of 100% Section V. REACTIVITY DATA In its free state under pressure, acetylene can decompose violently when heated or shocked to form carbon and hydrogen (no oxygen required). Pressures in excess of 15 psig should never be used for free acetylene without special engineering design. Below 15 psig or in acetone solution in its cylinder, acetylene is stable. Only approved valves and manifolds should be used. It burns in air with a sooty flame. It reacts with copper, silver and mercury to form explosive acetylides. Incomplete combustion of acetylene can form carbon monoxide in high levels. Acetylene can react explosively with oxygen, chlorine or fluorine. 411538 0124 f \4w, Section VI. HEALTH HAZARD INFORMATION TLV (See Section II) Acetylene, when pure, is classified as a simple asphyxiant; its presence'in high levels can reduce the oxygen concentration of breathed air to such a low level that uncon sciousness or death can result. No symptoms occur from the presence of 2.5% acetylene in air; at 10% a reversible narcosis can be produced; at 40%, collapse. The contaminants in commercial grades of acetylene, particularly in that generated on site from calcium'Carbide, can have toxic effects, phosphine for example. In a welding process involving acetylene, metal oxide fume and carbon monoxide may present additional health hazards when acetylene is present in the air. FIRST AID: Inhalation: Remove to fresh air. Restore breathing when necessary. Contact a physician. If acetylene from a calcium carbide generator is involved, the acute effects of phosphine and other impurities in the acetylene should be considered. Section VII. SPILL. LEAK & DISPOSAL PROCEDURES If an acetylene leak occurs, notify safety personnel! Provide maximum explosion-proof ventilation. Eliminate ignition sources. Exclude people from area except those trained persons involved in control of leakage. Shut off acetylene flow if possible. If the leakage location is found, plug leak with wet waste, putty, heavy cloth, etc. Never use a flame to find source of leakage; paint points of suspected leakage with soapy water and watch for bubbles. DISPOSAL: If practical, move leaking cylinder to a safe, outside, posted disposal area for discharge. Gas can be piped to a pit (or to a furnace when possible) and burned; or it is allowed to escape into the atmosphere. When empty, close valves; return cylinder to supplier informing him of the defect. Follow federal, state and local regulations._______________________________________________________________________________. -_______________- Section Vltl. SPECIAL PROTECTION INFORMATION Provide general ventilation and/or local exhaust ventilation to keep acetylene con- ^ centration below 2500 ppm in the workplace air. This level will control explosion hazards as well as exposure to impurities in the acetylene gas. Avoid use of acetylene in confined areas. Where this is necessary, be sure that suitable fresh air ventilation is provided for. A NIOSH approved self-contained breathing apparatus must be available for emergency work at high concentration. Section IX. SPECIAL PRECAUTIONS & COMMENTS Obtain and follow the detailed safety regulations of OSHA [Code of Federal Regulations 29, Chapter XVII, Part 1910.252 (a)] and the recommendations of suppliers for handling, manifolding, and storage of pressurized gas cylinders and the operation of acetylene generators. Store reserve cylinders away from cylinders of oxygen (and from chlorine and other oxidizing agents) in an upright position. Store in a cool, well-ventilated place away from open flames and other ignition sources. Protect cylinders, manifolds and piping from physical damage. Piping used with acetylene should be electrically bonded D.O.T. Requirements and Sanded to prevent static sparks. FLAMMABLE GAS ____________________________________________________________________________________________________________ Section X. REFERENCES ASTM No.: Other: CHRIS (1974) , Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: SD-7 ALCOA ENGR. STANDARDS: 18.6.1 NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: 411538 0125 For Internal Company Use Only - Not To Be Distributed Outside The Company G3 ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS CD Flammable CD Combustible (3 Corrosive CD Explosive 0 Water Reactive 0 Radioactive CD Oxidizer O Chemically Reactive Toxic By: 0 Ingestion 0 Inhalation 0 Absorption fJo.. PRODUCT HYDROCHLORIC ACID Phone No. Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: HYDROCHLORIC ACID Chemical Name & Formula: HC1 Other Designation: Muriatic Acid, Concentrated Hydrochloric Acid, CAS# 007 647 010 Corporate Stock No.: Manufacturer: Available from many suppliers Description:__________ Section II. INGREDIENTS % HAZARD DATA Hydrogen Chloride (HC1) <38 TLV 5 ppm (C)* Impurities (depends on acid grade) Traces Balance *C denotes a ceiling concentration that should not be exceeded in the wor)*place Section III. PHYSICAL DATA Physical Form: Liquid 18Be' ------- Boiling Temp.: 1 atm 97.7C (208F) Freeze-Melt Temp.: -42C (-43.6F) 20Be' 83.3C (182F) -53C (- 63.4F) 22 Be' 23 Be' 62.2C (144F) 50.5C (123F) -65.7C (-86.3F) -74C (-101.2F Vapor Pressure: 25 C, mm Hg 25 ^o^ion f^ci Specific Gravity: 60/60 F Density: 27.9 1.142 31.4 1.160 "Solubility In H2O": Complete, 100% Color: Colorless to light yellow fuming liquid Odor: Pungent, suffocating 35.2 1.179 Others Volatiles, %: ca 100 37.1 1.189 Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. j Flammability Limits In Air N/A|N/AIN/Ajj | Lower I Upper Extinguishing Media: Select that suitable for the surrounding fire. This nonflammable acid can react with many metals, such as iron and aluminum to produce flammable hydrogen gas. The acid can be neutralized with bases such as slaked lime or soda wash. Use a water spray to cool fire-exposed containers to prevent rupture. Firefighters should use full protective clothing and self-contained breathing apparatus when this material is involved in a fire situation. Section V. REACTIVITY DATA This material is stable when properly contained and handled. It is a strong mineral acid and is, thus, highly reactive with materials such as metals, metal oxides, hydroxides, amines, carbonates and other alkaline materials. It is highly corrosive to many materials. It can liberate significant levels of HC1 by vapor pressure at room temperature when concentrated and large amounts of HC1 when heated. Reaction with most metals will produce hydrogen gas. 411538 0126 Section VI. HEALTH HAZARD INFORMATION TLV 5 ppm Ceiiing (as HC1) Prolonged inhalation of HC1 vapors or mist just above the TLV can damage 'the teeth and irritate the nasal passages. Higher concentrations (50+ppm) will cause coughing and choking and produce severe irritation and damage of the mucous membranes of the upper respiratory tract. 1300 ppm is immediately dangerous to life. Hydrochloric acid is corrosive and causes burns of human tissue. Ingestion can produce burns of the mouth and digestive tract. First Aid: Eye Contact; Flush thoroughly with running water for 15 minutes. Get medical aid. Skin Contact: Wash affected areas thoroughly with much water. For gross contact, remove contaminated clothing under the safety shower; prolong washing for 15+ minutes. Ingestion: Give limewater or water and milk of magnesia to drink. Do not induce vomiting! Get medical aid. Inhalation: Remove to fresh air; restore breathing, if required. under proper supervision. Get medical aid. Oxygen can be given Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Large spills should be repdrted to environmental personnel. Remove sources of ignition. Supply ventilation. Stay upwind of large spills in outside areas. Those involved in clean-up of large spills must use full protective clothing, boots, and self-contained breathing apparatus. Flush large spills with water to holding area and neutralize with soda ash or lime. Flushing to sewer depends on allowable salt concentrations in effluent water. Follow local, state and federal regulations. Cover small spills with a mixture of soda ash and slaked lime. Flush the neutralized material to the sewer with much water. Section VIII. SPECIAL PROTECTION INFORMATIONf ^ Provide adequate exhaust ventilation in areas of use or storage to meet TLV requirement^^ Face velocity of hoods should exceed 100 Ifm. Use NIOSH-approved respiratory protection where the TLV is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied air mask, chemical cartridge respirator, etc.) will depend on the actual or potential concentration present. Those handling hydrochloric acid should use protective clothing and equipment to prevent body contact with the liquid. Use rubber gloves or gauntlets, rubber apron, rubber boots, long-sleeved shirt, etc. Use chemical safety goggles and/or face shield for eye protection against splashing of acid. An eye wash station and safety shower must be located near areas hydrochloric acid is handled or used._____________________________ Section IX. SPECIAL PRECAUTIONS & COMMENTS Store closed containers in clean, cool, open or well-ventilated areas. Keep out of sun. Area should have acid resistant floor and approved drainage. Keep away from oxidizing agents and alkaline materials. Protect containers from damage or breakage. Use non-sparking tools in areas around tanks and pipes where hydrogen might be generated. Avoid inhalation of HC1 vapors; if odor can be detected, workers are being over-exposed! Odor of HC1 gives adequate warning for a prompt voluntary withdrawl from the exposure area. Avoid skin contact. Provide emergency neutralization materials and equipment near storage and use areas. D.O.T. Requirements CORROSIVE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: SD-39 NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) AIA Bulletin C-30 AIHA Hygienic Guide 8-58 411538 0127 For Internal Company Use Only - Not To Be Distributed Outside The Company a ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. Flammable O Combustible Toxic By: PRODUCT MERCURY Corrosive CD Explosive E Ingestion Water Reactive Radioactive O Oxidizer CD Chemically Reactive 0 Inhalation ED Absorption Phone No. Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: Chemical Name & Formula: Other Designation: MERCURY Hg Quick Silver, CAS #007 439 976 Corporate Stock No.: Manufacturer: Available from many sources Description___________ A liquid, metallic element Section II. INGREDIENTS % HAZARD DATA Mercury 100 TLV 0.1 mg/m3* TLV 0.05 mg/3** X * Present OSHA level and proposed ceiling limit ** Present ACGIH level ^ith a proposed absolute ceiling of 0.15 mg/m Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Heavy Liquid at 1 atm: 356.9C (674F) Freeze-Melt Temp.: -38.89 (-38F) Vapor Pressure: acvt. 20Cv., mm Hg: 0.0012 at 126C, mm Hg: 1 Evaporation Rate: Specific Gravity: <h2o=d 13.54 Density: "Solubility In H20"Nil Color: Silvery Odor: None Human, oral LDL-1429 mg/kg Human, intravenous LDLC 29 mg/kg Others Atomic Weight: Atomic Number: 200.61 80 Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. | Flammability Limits In Air None|II| | Lower I Upper Mercury is nonflammable and nonexplosive in air. When exposed to high temperature, mercury vaporizes to form extremely toxic ftomes. When this material is involved in a fire, firefighters need to use self-contained breathing apparatus. Section V. REACTIVITY DATA Mercury is a stable metallic element. It will react slowly with oxygen when heated, and it reacts with halogens; for example, at 200-300C (392-572F) a flame forms when a jet of chlorine gas is directed over mercury. Mercury dissolves (reacts) in oxidizing acids, such as nitric; but it does not dissolve in hydrochloric acid. Boron phosphodiiodide will ignite in mercury vapor. The following can give explosive mixtures with mercury: acetylene, ammonia, chlorine dioxide, nitric acid plus ethanol, and methyl azide. 411538 0128 Section VI. HEALTH HAZARD INFORMATION TLV 0.1 mg/m3 If the mercury in a small clinical thermometer were dispersed in a closed 100' x 100' x 15' room, the TLV would be exceeded. Unsafe conditions are not indicated by odor. Severe poisoning can occur with less than two hours of exposure to high concentrations of .,--^ vapors. Mercury may be absorbed slowly through the skin. Repeated or prolonged contacts may result in poisoning. A single ingestion of a small amount of pure metallic mercury would not be expected to cause severe injury. However, if the mercury contained mercury compounds, poisoning could result. FIRST AID: In all cases of overexposure to mercury, get medical attention!!! Ingestion: Gastric lavage with 5% solution of sodium formaldehyde sulfoxylate, followed by 2% NaHC03, and finally leave 250 cc the sodium formaldehyde sulfoxylate in the stomach. Inhalation: Remove to fresh air. Physician: Check blood and/or urine for mercury levels. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Clean up spills promptly. (It is convenient to use a suction bottle with a capillary tube for small amounts.) Calcium polysulfide with excess sulfur can be sprinkled into cracks or other inacessible places to convert mercury globules into the sulfide. Collect picked-up or scrapped mercury in tightly sealed containers for reclaim or for disposal. Do not discharge mercury down the drain! Mercury can be purified for reuse, or it can be sold to a mercury salvage company when when large amounts are involved. Mercury is concentrated by animals, plants, and fish. Section VIII. SPECIAL PROTECTION INFORMATION______________________________________________ Areas of mercury use must have adequate ventilation to meet TLV requirements. Use > NI0SH approved respirators where the TLV is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or potential concentration present. Those frequently working with mercury must use rubber gloves. (The use of rubber gloves and eye protection is recommended for all handling of mercury.) Mercury should not be heated without proper precautions to safely handle highly toxic mercury vapors! Section IX. SPECIAL PRECAUTIONS & COMMENTS___________________________________ Store mercury in small sealed containers (preferably polyethylene) in a well ventilated area. Mercury evaporates very slowly. Spilled mercury forms many tiny globules that will evaporate faster than a single pool and can develop a significant concentration of vapors in an unventilated area. Such vapors can be poisonous, expecially if breathed over a long period of time. Avoid contact with mercury. Follow good hygienic practices. Periodic medical examinations should be arranged for those using mercury.. Good housekeeping practices and air sampling D.O.T. Requirements &re nee3ea wKere mercurY is regularly us el. F P9 (AIR) ORM-B Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 007-439-976 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: 203 Supplier Product Literature: ' Other: ~ " CHRIS (1974) AIA Bulletin C-60, AIHA Hygienic Guide 6-66 411538 0129 For Internal Company Use Only - N ot To Be Distributed Outside The Company 0 ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 5 13 Flammable CD Combustible Toxic By: PRODUCT METHYL ALCOHOL Corrosive Water Reactive CD Oxidizer D Explosive CD Radioactive Q Chemically Reactive 0 Ingestion 0 Inhalation Absorption Phone No. Date: 1979-12-21 Section 1. MATERIAL DESCRIPTION Material Name: METHYL ALCOHOL Chemical Name & Formula: CH3OH Other Designation: Corporate Stock No.: Manufacturer: Methanol, Wood Alcohol, ASTM Dll52, CAS# 000 067 561 Available from many suppliers Section II. INGREDIENTS Methyl Alcohol % ca 100 HAZARD DATA TLV 200 ppm* (Skin) or 260 mg/m^ `Current OSHA TLV; ACGIH (1977) TLV adds (skin) notati on which indicates a potential contribution to overall exposure via absorption through the skin NIOSH has recommended a 10-hour TWA of 200 ppm with i ceiling of 800 ppm (15-minute sample) Section III. PHYSICAL DATA Human, Oral LDLq 340 mq/kq Physical Form: Liquid Boiling Temp.: at 1 atm Freeze-Melt Temp.: 64.5C (148F) Others Volatiles, % - ca 100 Molecular Weight - 32.04 Vapor Pressure: Evaporation Rate: Specific Gravity: @21.2C, mm Hg - 100 (CC14=1) - 1 (20/4C) - 0.791 Density: (Air = 1) - 1.1 "Solubility In H20"Totally Miscilble Color: Clear, Colorless Odor: Characteristic alcohol odor which is detectable at 50 to 100 ppm and _____________________above in air Section IV. Flashpoint 11C (52F) FIRE AND EXPLOSION DATA I Auto-Ignition Temp. j(Closed Cup) 465C (867F) (Flammability Limits In Air I Lower \ % by Volume| 6 Upper 36.5 Extinguishing Media: C02, dry chemical, alcohol foam, and water mist or fog. Methyl alcohol fires are Class B fires; use a blanketing effect to smother fire. It is a moderate explosion hazard and dangerous fire hazard when exposed to heat, sparks or flames and can react vigorously with oxidizing agents. Firefighters should use self-contained breathing apparatus with full facepiece and full protective clothing where this material is involved in a fire in an enclosed place. Section V. REACTIVITY DATA Methyl alcohol is a flammable material, but it is stable under normal storage and use conditions. It does not undergo hazardous polymerization. Avoid contact with strong oxidizing agents such as nitrates, perchlorates or sulfuric acid. Oxidation products in air include oxides of carbon and nitrogen. 411538 0130 Section VI. HEALTH HAZARD INFORMATION | TLV 200 ppm (Skin) or 260 mg/m3 Methanol is a poisonous, narcotic chemical that may exert its effects through -inhalation, skin absorption or ingestion. Body elimination of methanol is slow, and the toxic effects can be compounded by| repeated excessive exposures oyer several, days. Toxic effects are exerted upon the nervous system, especially the optic nerve; \ Ingestion can produce blindness. Symptoms of overexposure:-1 include dizziness, blurring of vision; "" nausea, cardiac depression, muscular incoordination and narcosis^ Solvent action can dry the skin and cause dermatitis. FIRST AID: -f .. , , ' V> Inhalation: Remove victim to fresh air and prevent further exposure for 7 days. Obtain medical assistance if victim is not fully normal within 10 minutes. *: Skin Contact: Wash affected area with soap and water; apply skin lotions. Eye Contact: Irrigate with running water for 15 minutes. Get medical help. 1 , ' Ingestion; Drink 3 glasses milk, water or 4% sodium bicarbonate. Obtain immediate medical aid for gastric lavage. (NIOSH recommends inducing vomiting if victim is conscious.) Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Notify environmental personnel. Remove all sources of ignition; provide adequate ventilation. Absorb on vermiculite, paper or other absorbent. Burn in an approvedincinerator or'open ' pit away from buildings and people. : Dispose of large quantities of waste via a licensed waste solvent disposal company) or reclaim via filtration and distillation procedures. It can be incinerated- .- : ; Spills in sensitive areas may be diluted and flushed to ground with a:water spray. Do not flush to sewer. Follow federal, state and local regulations. "' Section VIII Cont. concentration present. A full facepiece is required above 2000 ppm. - Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate ventilation to meet TLV requirements. Exhaust ventilation with 100 lfm minimum should be used where vapor exposure is likely. Exhaiist fans should be., explosion-proof. No smoking in areas of use. V Prevent skin contact by wearing rubber gloves. Protective aprons, boots;!and face; shields should be used where splashing may occur. Use safety glasses in other areas of use. Remove methanol-contaminated Clothing promptly. ; . ' ;` : Eye wash stations and-safety showers should be available in areas of use. Respirator protection for emergency or exposure Situations above the TLV: Use NIOSH- approved respirators where the TLV is or may be exceeded. The selection- of the .v ! appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, etc.) will dependi upon the actual or potential (cont.; under Section!VTTl Section IX. SPECIAL PRECAUTIONS & COMMENTS Prevent skin contact! Do not breathe vapors! .This material is poisonous when introduced into the body metabolism. Do not ingest! '' . Store in a well-ventilated, fire-resistant area. Ground and electrically interconnect, containers for transfer. Use spark-proof tools. Keep awayi from heat and ignition . ` sources. No smoking| in areas'of storage or use. . "; > ; - v; NIOSH recommends preplacement medical exams for industrially exposed workers, periodic . medical surveillance and prompt eye examination for eye contact.with methanol or for any overexposure. D.O.T. Requirements \i . FLAMMABLE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: D1152 000-067-561 SD-22 Other: CHRIS (1974) . 411538 0131 For Internal Company Use Only - N ot To Be Distributed Outside The Company 0 MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. ALCOA Flammable Q Corrosive CJ Water Reactive H Oxidizer CD Combustible CD Explosive CD Radioactive CD Chemically Reactive Toxic By: S Ingestion 0 Inhalation CD Absorption PRODUCT NITRIC ACID 55-70% Phone No. Date: Section I. MATERIAL DESCRIPTION Material Name: NITRIC ACID (55--70%) Chemical Name & Formula: HNO3 Other Designation: Aqua Fortis, Hydrogen Nitrate, CAS# 007 697 372 Corporate Stock No.: Manufacturer: Available from many suppliers Description:A solution of HNO3 in water with properties dependent on concentration. Section II. INGREDIENTS % HAZARD DATA Hydrogen Nitrate (HNO 3) 55-70* TLV 2 ppm ** for nitric acid Water Balance * 68% nitric acid (42Be) is the constant boiling, concentrated nitric acid of commerce; 56.5% nitric acid (38Be) is commercially available ** NIOSH has proposed a 10-hour TWA for this same lev^l Section III. PHYSICAL DATA Physical Form: Liquid Boiling Temp.: 1 atm, deg. C (F) Freeze-Melt Temp.: deg. C (F) Vapor Pressure: mm Hg @ 25C Evaporation Rate: Specific Gravity: 20/4 C Density: Baume Scale, @ 60F 56.5% Acid -20 (-4) 1.36 38Be 68=% Acid 121.6 (251) -34 (ca -30) 1.41 42Be 100% Acid (Unstable) 83 (181) -41.6 (-43.6) ca 45 1.50 "Solubility In HoO": Complete Color: Colorless, water-like to slightly yellow, darkens to brownish color on aging and Odor: P8IH?6 t0 llght Volatiles e 122C; 100%______________ Section IV. FIRE AND EXPLOSION DATA Flashpoint Nonflammable I Auto-Ignition Temp. I N/A (Flammability Limits In Air N/A Lower U pper Nitric acid is nonflammable; however, it is a strong oxidizing agent and can react with combustible materials to cause fires. Use water spray or fog on fires involving nitric acid to dilute the acid and to absorb liberated oxides of nitrogen. It can also react with metals to liberate flammable hydrogen gas. Self-contained breathing apparatus and full protective clothing should be used by fire fighters in an enclosed area when nitric acid is involved in the fire. Section V. REACTIVITY DATA This material is stable under normal storage and handling conditions. It is hygroscopic (when concentrated), a strong mineral acid, and a strong oxidizing agent. Contact with organic materials such as wood, paper, alcohol, turpentine, etc., may cause fires. Combustible materials can have an increased flammability after contact with nitric acid. Various nitrogen oxides, including NQ, NO2, N2O3, and N2O -- all mixed with nitric acid mist and vapor -- can be produced upon decomposition or reaction of nitric acid. All are toxic. Reacts explosively with metallic powders, carbides, H2S and turpentine (NFPA #49) 411538 0132 Section VI. HEALTH HAZARD INFORMATION | TLV 2 ppm or 5 mg/m3 ~ This material is corrosive to all body tissues!j Inhalation^of nitric, acid mist of fumes at 2 to 25 ppm, over an 8-hour period, may cause pulmonary, irritation and symptoms of lung damage. The onset of symptoms following inhalation1 may be delayed for several ' hours. Concentration over 200 ppm can cause severe pulmonary damage and may be l: fatal (in 5-10 hours) after several minutes of. exposure. Eye oriskin"contact will , ~ produce immediate burns, with a yellow skin discoloration; eyes may be .permanently damaged p. Inclination will produce burns of the digestive tract. 1 7; * ' Inhalation: Remove victim to fresh air. Get medical attention. Observe for 4 to 30. hours after exposure. ! ;' , > - '/.. Skin Contact: Wash immediately with soap and wafer. (Remove contaminated clothing1; " promptly.) Get medical attention except for minor exposures to small' areas of?the skin! Eye Contact: Immediately wash with water for,at least 1-5 minutes. Get medical attention. Ingestion: 1 Give 3 or more glasses of milk or water. Get.medical attention^ ; . . -i, } ", ' 1 "' > ,' *'. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES -i,' Notify environmental personnel. Provide adequate ventilation. Eliminate sources 'of - ignition. Self-contained breathing apparatus should be used by personnel,when cleaning UP spills." Neoprene gloves and body shields should be used to prevent skin and clothing contact'. ! Surfaces contaminated from spills should be covered with-sodium bicarbonateor soda ash to neutralize the acid. Wash the neutralized slurry down thedrain with 'excess;water. Federal, state, and local regulations must always be-considered prior-.to sewer: disposal. If necessary, neutralized spill may be picked up by use of absorbants and disposed of as solid waste in a'landfill. i Section VIII. SPECIAL PROTECTION INFORMATION Use with proper ventilation to meet the TLV, requirements. Exhaust hoods should main tain a face velocity of 100 lfm minimum. Exhaust ducts should be. fiberglass or other , acid-resistant material. Use NIOSH-approved respirators where the TLV is or may be exceeded'^' The. selection of. the appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual^of potential concentration present. Neoprene gloves and body shields should be usediwhere splashing may occur". '; ; Chemical safety showers and eye wash stations must be readily available in areas of storage and handling of nitric acid. 1 : TT Section IX.___ SPECIAL PRECAUTIONS & COMMENTS- ' / ~;y:'v - . -V " ` Nitric acid is a corrosive material and will attack skin, metals and many organic sub stances. The nitrogen oxides produced from the acid sure all toxic,-and proper ventilation should always be used. .; Nitric acid can ignite certain organic substances. Store in a clean,, cool, well-ventilated area, away from organic chemicals, strong bases, metal powders, carbides, sulfides, and any readily oxidizahle material. Protect from direct sunlight. - , Neutralizing and absorbing materials such as soda .ash and sand should be readily available to areas of use and storage of nitric acid. D.O.T. Requirements OXIDIZER AND CORROSIVE LIQUID s -' . SectionX. REFERENCES ASTM No.: Chemical Abstracts No.: 007-697-372 CMA Chemical Safety Data Sheet No.: SD-5 NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: ; Other: < CHRIS (1974) ., \ (; 411538.0133 LU ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 7 CD Flammable O Combustible Toxic By: PRODUCT SODIUM HYDROXIDE 0 Corrosive O Explosive 13 Ingestion O 0Water Reactive Radioactive 13 Inhalation Phone No. 0 Oxidizer O Chemically Reactive 0 Absorption Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: SODIUM HYDROXIDE Chemical Name & Formula: NaOH Other Designation: Caustic Soda, Soda Lye, ASTM D456 Corporate Stock No.: Manufacturer: Available from many suppliers For Internal Company Use Only - N o t To Be Distributed Outside The Company Section II. INGREDIENTS Typical content: Sodium Hydroxide (NaOH) % HAZARD DATA Ceiling Limit 96 2 mg/m^ Impurities: Sodium Carbonate (Na2C03) Sodium Chloride (NaCl) Sodium Sulfate (Na2S04) Potassium, Calcium and Magnesium Silicon Dioxide (Si02> Other Metals (total) Section III. PHYSICAL DATA 0.5 -2.5 0.01-2.1 0.02-0.1 0.1 0.3 0.1 Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Flakes or pellets 1 atm 1388C (2530F) 318C (604F) mm Hg @ 1000 C -- 42 @ 1200 C --232 Others: Volatiles --------non volatile at room temp erature Viscosity at 350 C, cps -- 4.0 Specific Gravity: (20/4 C)------ 2.13 Density: "Solubility In HoO": Color- %, @ 100 White Odor: None 0 C 29.6 C -- 77.5 or off-white, hygroscopic solid Section IV. FIRE AND EXPLOSION DATA Flashpoint None - not combustible I Auto-ignition Temp. 1 n/a (Flammability Limits In Air 1 n/a Lower 1 Upper N/A 1 n/a Although it is not combustible, it can be hazardous if present in a fire area. The following should be known for fire fighting: 1) It can melt and flow when heated (m.p.318 C) 2) Hot or molten material can react violently with water (splattering). 3) Can react with certain metals, such as aluminum, to generate flammable hydrogen gas. (See also Reactivity Data, Section V). Fire fighters should wear full protective clothing. For fires involving NaOH, flood with water using care not to splatter or splash this material._____ Section V. REACTIVITY DATA It is a stable material under normal conditions of storage. No self-polymerization. No. hazardous decomposition products. Slowly it can pick up moisture from the air and react with carbon dioxide from the air to form sodium carbonate. Sodium hydroxide can react violently with strong acids and with many organic chemicals, especially with nitrocarbons and chlorocarbons. (Will react with trichloroethylene to form spontaneously flammable dichloroacetylene.) in water. It generates much heat when it dissolves Avoid contact with leather and wool and with aluminum, tin, zinc, and alloys which contain these metals. 411538 0134 Section VI. HEALTH HAZARD INFORMATION TLV (Ceiling Value) 2 mg/m3 Sodium hydroxide is a strong alkali and is dangerous when improperly handled, it can'be destructive to all human tissue it contacts, producing severe burns. Eye contact can produce severe or permanent injury. Dust or mist inhalation can injure the entire respiratory tract. FIRST AID: Eye Contact: Wash eyes immediately with plenty of running water for at least 15 minutes, including under the eyelids and all surfaces. Speed in rinsing the eyes after contact is extremely important if permanent injury is to be avoided. Contact physician as soon as possible. Ingestion-Immediately dilute chemical by drinking large amounts of water or milk, then neutralize with dilute vinegar or fruit juice. Vomiting may occur spontaneously, but do not induce it. Contact a physician promptly. Remove from exposure to mist or dust and get prompt medical help. Skin Contact-Wash contact area promptly with large quantities of water. (Dilute acetic acid, vinegar, can be used to neutralize.) Remove contaminated cloth ing under the shower. Prolong washing in serious cases until medical help arrives-even for an hour or longer. Physician should see all cases other than minor exposures to small areas of skin._____________________________________________________________ Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact Environmental Control personnel. When solid sodium hydroxide is spilled in a dry condition, it can be promptly shoveled up for recovery or disposal. (CAUTION! Avoid dusting. Avoid contact with the skin.) Control the disposal of the waste solid. (Delay in clean-up may allow absorption of moisture from the atmosphere and may increase the difficulties of clean-up.) Flush contaminated surfaces with water and neutralize with dilute acid, preferably acetic acid, to remove final traces. (Sodium bicarbonate may also be used to partially neutralize.) Finally, rinse with water. Disposal of waste is greatly dependent on local conditions and requirements. Pre-emergency plans should be made to meet legal and technical requirements. Waste caustic should never be deliberately discharged directly into sewers or surface waters. neutral salts and dilute well with water.) (First, convert to Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate ventilation to meet TLV requirements, especially where dusting or v__.: misting conditions can exist. For mist and dust protection use NIOSH approved respirators where the TLV is or may be exceeded. The selection of the appropriate respiratory pro tection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or potential concentration present. Use Chemical Safety Goggles! A plastic face shield can also be used. Use rubber gloves, rubber apron or protective clothing, rubber boots where needed to prevent contact with sodium hydroxide, especially when solutions are prepared. Eye wash fountains and safety showers must be immediately available! Section IX. SPECIAL PRECAUTIONS & COMMENTS Workers should not be permitted to handle this material without proper training or to work with it without protective equipment. Store in well-sealed containers. Avoid handling conditions that may lead to spills and leaks, or to formation of mist or dust. Wherever this material is stored, unloaded, handled or used abundant water (preferably running water) should be available for emergency use. Drains for storage or use areas for this material should have retention basins for pH adjustment and dilution of spills and flushings before discharge. The pellet form is probably the safest solid form for handling and dispensing. D.O.T. Requirements CORROSIVE SOLID Section X. REFERENCES ASTM No.: D456 Chemical Abstracts No.: 001-310-732 CMA Chemical Safety Data Sheet No.: NFPA Guides No : NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) 411538 0135 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET a ALCOA HAZARD CHARACTERISTICS CD Flammable CD Combustible 0 Corrosive CD Explosive CD Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive Toxic By: ED Ingestion 0 Inhalation D Absorption tio. 8 PRODUCT SODIUM HYDROXIDE 50% LIQUID Phone No. Date: 1979-12-21 Section 1. MATERIAL DESCRIPTION Material Name; SODIUM HYDROXIDE, 50% LIQUID Chemical Name & Formula; NaOH Other Designation; Corporate Stock No.: Liquid Caustic Soda, Lye Solution Manufacturer: Available from many sources Section II. INGREDIENTS Sodium Hydroxide (NaOH) Typical Major Impurities: % > 48.5 HAZARD DATA TLV 2 mg/m3 (C)* Carbonate (as Na2C03> -C 0.25 Chloride (as NaCl) 1.15 Chlorate (as NaC103) <. 0.25 NaOH Solution Sulfate (as Na2S04) Silica (as SiO) < 0.03 Rabbit, oral LDLo <0.01 500 mg/kg Water *ACGIH recommends no exposure above this ceiling level (C). OSHA has the same TLV but no ceiling Balance level at this time._____________________________________________ Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid 1 atm, ca 140C (284F) Others: Viscosity at 20 C, cps -- 50 Freeze-Melt Temp. Vapor Pressure: Evaporation Rate: at 60 C -- ca 13 at 82 C -- ca 60 Specific Gravity: 15.6 C -- 1.53 Density: "Solubility In H20": Complete Color: A clear liquid Odor: None Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. None - not combustible I j Flammability Limits In Air I Lower Upper Use water spray to cool containers of this material which are involved in a fire situation to help prevent rupture. Sodium hydroxide will react with metals such as aluminum, tin, and zinc to generate flammable and explosive hydrogen gas. Fire fighters should wear full protective clothing. Section V. REACTIVITY DATA This material is stable under normal storage conditions in a sealed container. No polymerization will occur; there are not hazardous decomposition products. It will react with CC>2 in the air (when exposed) to form sodium carbonate. It will react violently with acids and with many organic chemicals, especially nitrocarbons, and halocarbons. (Trichloroethylene will react to form spontaneously flammable dichloroacetylene.) Avoid contact with leather and wool and with aluminum, tin, zinc, and alloys which contain these metals. 411538 0136 Section VI. HEALTH HAZARD INFORMATION TLV 2 rog/m3 (ceiling for NaOH) When improperly handled this strong alkali is- dangerous. It is destructive of all human tissue it contacts, giving severe burns. Eye contact will produce severe or permanent injury. Inhalation of mist of spray can injure the entire respiratory tract. FIRST AID: ( Eye Contact: Wash eyes immediately with plenty of running water for 15 minutes, including under eyelids and all surfaces. Speed in rinsing out eyes is important if permanent injury is to be avoided. Get medical help immediately. Skin Contact: Promptly wash exposed area with lots of water, (Dilute acetic acid or vinegar can be used to neutralize.) Remove contaminated clothing under the shower. Prolong washing in serious cases until doctor arrives-even for an hour or longer. Get medical help for serious exposure. Ingestion: Immediately dilute by drinking water or milk and then neutralize with dilute vinegar or fruit juice. Contact physician promptly. Vomiting may occur spontaneously, but do not induce it. Inhalation: Remove from exposure to mist and get prompt medical help. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact Environmental Control personnel. Plan ahead for handling spills. Personnel working on clean-up must use protective clothing and equipment to prevent body contact with the liquid. Abundant running water should be available for emergency use. Pick up spill with vacuum equipment (alkali resistant) for disposal or flush to holding area with water. Neutralize residues with dilute acid and rinse with water. Disposal - Dispose of scrap in accordance with pre-emergency planning and local. State and Federal regulations. Waste caustic must never be discharged directly to sewers or surface waters. First convert to neutral salts and dilute well with water. Inform legal authorities of uncontrolled spills. Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate general ventilation and exhaust ventilation to meet TLV requirements, especially where possibility of mist formation exists. Use NIOSH approved respirators where the TLV is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or potential concentration present. Use chemical safety goggles for eye protection, and, in addition, use a face shield if splashing is probable. Use rubber gloves, apron or protective clothing, and rubber boots (tops covered by apron or clothing to prevent entrance of caustic). Eye wash stations and safety showers must be immediately available! Section IX. SPECIAL PRECAUTIONS & COMMENTS Do not permit workers to handle this material without proper training or without proper equipment. Store in well-sealed containers, which are protected from physical damage. Avoid handling conditions which can lead to spills or mist formation. Have abundant running water available where stored, unloaded or handled. Drains must have retention basis for pH adjustment and neutralization of spilled materials and flushings before discharge. D.O.T. Requirements CORROSIVE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: 411538 0137 For Internal Company Use Only -- Not To Be Distributed Outside The Company 0 MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS islo. ALCOA 0 Flammable 13 Corrosive O Water Reactive 0 Oxidizer 0 Combustible O Explosive O Radioactive 0 Chemically Reactive Toxic By: 0 ingestion 0 Inhalation 0 Absorption PRODUCT SULFURIC ACID, CONCENTRATED Phone No. Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: SULFURIC ACID, CONCENTRATED Chemical Name & Formula: H2SO4 Other Designation: Corporate Stock No.: oil of Vitriol, Hydrogen Sulfate, CAS# 007 664 939 Manufacturer: Available from many suppliers Section II. INGREDIENTS Hydrogen Sulfate (H2SO4) % HAZARD DATA 93-98 TLV 1 mg/m^ for sulfuric Balance* acid Material is obtained by the reaction of SO3 and water. Can contain low impurity levels, such as 0.02% max of iron as Fe. Properties vary with H9SO4 content. Section III. PHYSICAL DATA Physical Form: Liquid 93.19% H?S04 Boiling Temp.: 1 atm------------ ----------ca 281C(538F) Freeze-Melt Temp.: ------------ ----------ca-34C(-29F) Vapor Pressure: mm Hg @ 100 F------ca 1 Evaporation Rate: Specific Gravity: (60/60F) -- Dens?$f Baume------------------------------ 1.8354 66 93.33% HpSOy, ca 338C(640F) ca 3C{37F) 1.84 100% H2SO4 ca 330C(626F) 10.4C(50.7F) 1.84 Solubility In H2O": Completely miscible Color: Clear, colorless, oily liquid Odor: None Volatiles________ % at 340 C ca 100 ca 100 ca 100 Section IV. FIRE AND EXPLOSION DATA Flashpoint None-non-flammable Even though sulfuric I Auto-Ignition Temp. I N/A acid is non-flammable, Flammability Limits In Air I N/A___________________ it is hazardous when present Lower Upper N/A N/A in a fire area. Cool exterior of storage tanks of H2SO4 with water to avoid rupture if exposed to fire. Do not add water or other liquid to the acidi Use water to extinguish combustibles burning in the area. The acid, especially when diluted with water, can react with metals to liberate flammable hydrogen gas. Sulfuric acid mists and vapors from a fire area are corrosive. Respiratory protection is required when these are present, and also full protective clothing. (See also Reactivity Data, Section V.) Section V. REACTIVITY DATA Sulfuric acid is stable under normal conditions of use and storage. It does not undergo hazardous polymerization. It is a strong mineral acid reacting with bases and metals. concentrated acid is a strong oxidizing agent and can cause ignition of combustible materials on contact. The concentrated acid is also a dehydrating agent, picking up The moisture readily from the air or other materials. Much heat is generated when the concentrated acid is diluted in water. Acid should always be added slowly to water. Water added to acid can cause boiling and uncontrolled splashing of the acid. Sulfur oxides can result from decomposition and from oxidizing reactions of sulfuric acid. 411538 0138 Section VI. HEALTH HAZARD INFORMATION TLV 1 mg/m3 Concentrated sulfuric acid is a strong mineral acid, an oxidizing agent-,'..and a dehydrating agent that is rapidly damaging to all human tissue with which it comes in contact. Ingestion may cause severe injury or death. Eye contact gives severe or permanent injury. ^ Inhalation of mists can damage both the upper respiratory tract and the lungs. ; FIRST RID Ingestion: Dilute acid immediately with large amounts of milk or water, then give milk of magnesia to neutralize. Do not induce vomiting; if it occurs spontaneously, continue to administer fluid. Obtain medical attention as soon as possible. Eye Contact: Immediately flush eyes with plenty of running water for at least 15 minutes (including under the eyelids). Speed in diluting and rinsing out acid with water is extremely important if permanent eye damage is to be avoided. Obtain medical help as soon as possible. Skin Contact: Immediately flush affected areas with water, removing contaminated clothing under the safety shower. Continue washing with water and get medical attention in all cases except those involving minor damage to small areas of skin. Inhalation: Remove to fresh air. Restore breathing. Call a physician immediately. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact Environmental Control personnel. Prevent contact with the acid. Minor leaks or spills can be diluted with plenty of water and neutralized with soda ash or lime. If water is not available, cover contaminated area with sand, ashes, or gravel and neutralize with soda ash or lime. Major spills must be handled by a predetermined plan. Contact supplier for assistance in this planning and to meet local requirements and for disposing of large amounts. ; Section VIII. SPECIAL PROTECTION INFORMATION Use general ventilation to keep well below 1 mg/m3(TLV).Use NIOSH approved respirato where the TLV is or may be exceeded. The selection of the appropriate respiratory pro tection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or potential concentration present. For eye protection use chemical safety goggles or face shield to avoid splashing acid into the eyes. Use rubber gloves, rubber apron, rubber clothing, rubber suit, etc. to avoid contact of the acid with the body under use conditions. Eye wash fountain and safety showers should be readily available where this material is handled or stored. Areas of use or storage should have a neutralizing agent, such as soda ash, readily available for emergencies. Section IX. SPECIAL PRECAUTIONS & COMMENTS Dilute sulfuric acid is highly corrosive to most metals. Avoid breathing mist or vapors. Avoid contact with skin or eyes. Do not ingest. Add acid slowly to water to dilute. Do not add water to concentrated acid. Sulfuric acid received in carboys or drums should be stored in clean ventilated storage areas having acid resistant floors with good drainage. It should be stored away from reactive materials, chlorides, nitrates, carbides, metal powders, oxidizables, cyanides, etc: Sulfuric acid received in glass bottles should be stored as mentioned above with additional precaution against breakage. or lime should be kept in same general area for emergency use. D.O.T. Requirements Soda ash, sand CORROSIVE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: 007-664-939 SD-20 #325 Other: CHRIS (1979) AIA Bulletin C-12 AIHA Hygienic Guide 9-57 411538 0139 For Intornol Company Use Only - Not To Be Distributed Outside The Company Q MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 10 ALCOA (33 Flammable Q Corrosive 0 Water Reactive 0 Oxidizer O Combustible 0 Explosive 0 Radioactive 0 Chemically Reactive Toxic By: 0 Ingestion ED Inhalation 0 Absorption PRODUCT TOLUENE Phone No. Date; 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: TOLUENE Chemical Name & Formula: Methylbenzene, CH3C6H5 Other Designation: Corporate Stock No.: Toluol, Methylbenzol, ASTM D362 and D841, CAS# 000 108 883 Manufacturer: Available from many suppliers Section II. Toluene INGREDIENTS % 100 Current OSHA TLV level (1968 ACGIH TLV) **1977 ACGIH TLV level; (Skin) notation indicates a potential contribution to overall exposure via skin absorption. OSHA has proposed adoption of the more stringent ACGIH value, 100 ppm, with ceiling concentration of 200 ppm (measured over 15 minutes) HAZARD DATA TLV 200 ppm* TLV 100 ppm (Skin)** Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid 1 atm ------ 231F (110.6C) Others: Volatiles, % -- 100 Freeze-Melt Temp.: Molecular Weight -- 92.15 Vapor Pressure: 25 C -- 28 mm Hg Evaporation Rate: (BuAc=l) -- 1.9 Specific Gravity: (Water=l) -- 0.866 Density: (Air=l) -- 3.2 "Solubility In H2O'': % -- 0.05 (negligible) Color: Colorless water-like liquid Odor: Characteristic aromatic odor, which is perceptible (unfatigued) at about 50 ppm. Section IV. FIRE AND EXPLOSION DATA Flashpoint 40F (4.4C) Closed Cup j Auto-Ignition Temp. | Flammability Limits In Air | Lower | (552 C) 1026Fj % by volume| 1.27 Upper 7 Extinguishing media - carbon dioxide, dry chemical, foam. Fire fighters should wear self-contained breathing apparatus when fighting toluene fires. At room temperature, toluene emits vapors that may form explosive mixtures with air. Water may be ineffective in extinguishing fires but may be used to cool fire exposed containers. Vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Section V. REACTIVITY DATA Toluene is a stable material under normal storage and handling. It does not undergo hazardous polymerization. Since toluene is a flammable liquid, avoid contact with heat, sparks or open flames. Avoid contact with strong oxidizing agents. Nitric acid, especially in combinations with sulfuric acid, will form nitrocresols that can decompose violently upon further nitration. Oxidation in air can form oxides of carbon and nitrogen. 411538 0140 Section VI. HEALTH HAZARD INFORMATION | TLV (skin) 100 ppm or 375 mq/m3 The olfactory detection level for toluene is 50 ppm. Vapor:inhalation -Up to 100 ppm may: produce slight drowsiness and headache. Concentrations of,100-200 .ppm1may cause-fatigue, nausea, itching skin. Higher concentrations increase the degree of'fatigue,! incoor- ; '/*=>v dination and nausea and can irritate the respirator 'tract. Olfactory detection / j cannot be used for safety since toluene will fatigue the senses. Skin contact will ! cause defatting; dermatitis may result from prolonged, repeated'contact. Some absorption - can occur through skin contact. Eye contact is irritating and can result in burns. V`. ' Ingestion may cause irritation to digestive tract, with gastrointestinal absorption of toluent FIRST AID ' _ T Inhalation: Remove victim to fresh air; get medical attention "if victim is"overcome!'h Ingestion: Give water or milk (3 glasses) and induce vomiting.' Repeat 2 times and get - medical assistance. ; !. f :' Eye Contact: Immediately irrigate with water for 15 minutes. Get medical; attention. Skin Contact: Wash area with soap and water; remove and launder contaminated clothing .before reuse. Replace lost skin oils with medically^approved lotions or,-cream. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES ,, Report spills to Environmental Coordinator, remove all ignition!sources, and .ventilate area. Absorb spill on vermiculite or sand, scoop up with non-sparking tools and place in metal . covered container. Disposal by burning should be away from buildings and people. j Disposal of large amounts may be via licensed! solvent disposal- cbitpany. Section VIII. SPECIAL PROTECTION INFORMATION Ose in a well ventilated area. Exhaust hoods should have a minimum' face velocity of 100 lfm. Exhaust fans should all be non-sparking and explosion proof.! Exhaust ventilation should be sufficient to reduce exposure concentrations' below the TLV;;' UseNIOSH approved respirators where the TLV is or may be exceeded.The .selection of the appropriate respiratory protection (self-contained breathing,, apparatus supplied air respirator, etc.) will depend upon the actual or potential concentration present. Safety glass or goggles should be worn in areas;, of use. Face shields and protective clothing are required where splashing can occur'. r- Eye wash fountain should be available if splashing is. possible. Section IX. SPECIAL PRECAUTIONS & COMMENTS , ' r, ; ^ Since toluene vapors are over 3 times heavier; than air, the vapors may `flow to lower*/ areas, where ignition sources are uncontrolled. Smoking, sparks and open , flames should not be allowed in areas of toluene use. Non-sparking tools should be used in toluene " work areas. Metal containers for dispensing should be grounded and; electrically inter-., connected with the receiving container-. ;/ .' ! V- Use safety cans for handling small amounts. - ; D.O.T. Requirements FLAMMABLE LIQUID j Section X. ASTM No.: REFERENCES D362| Chemical Abstracts No.: 000-108-883 CMA Chemical Safety Data Sheet No.: SD-63 NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: ` `! ,V ; T'"~ Other: CHRIS (1974) * " ' /V ` tN ` 1 - .<.... , f ,, ... .... `' 411538 0141 For Internal Company Use Only - Not To Be Distributed Outside The Company Q ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. Flammable CD Combustible Toxic By: PRODUCT 1,1,1-TRICHLOROE- D Corrosive CD Explosive 0 Ingestion THANE Water Reactive Radioactive 0 Inhalation Phone No. CD Oxidizer CD Chemically Reactive Q Absorption Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: 1,1,1-TRICHLOROETHANE Chemical Name & Formula: CCI3CH3 Other Designation: Methyl Chloroform, CAS# 000 071 556 Chlorothene, aerothene Corporate Stock No.: Manufacturer: BLACO-THANE (Baron-Blakeslee) , CHLOROTHENE NU & NG (Dow) , DOWLCENE WR (Dow), INHIBISOL (Panetone Corp.), TRI-ETHANE (PPG Ind., Inc.), TRITHENE (SRS, INC.) Section II. INGREDIENTS 1,1,1-Trichloroethane* % HAZARD DATA 90 TLV 350 ppm** Inhibitor 10 Unknown *High purity material is commercially available (DOWCLENE WR). Other commercial materials (Tradenames, Sect. I) can contain up to 10% inhibitor and are designed for cold cleaning or vapor degreasing use or both (TRI-ETHANE). 10-hr, TWA of ?00 ppm w^th a -----entratrqn (15.min, sampling time) recommended caution in use. Human inhalation LCLo 27 g/m-* for 10 minutes TCLo 920 ppm for 70 minutes e?fectaf nervous system Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Liquid 1 atm, ca 165F -38F(-39C) (74C) at 20 C, mm Hg -- 100 Others: Vapor Density (Air=l) -- 4.55 Volatiles, % -- ca 100 Molecular Weight -- 133.41 Evaporation Rate: (CC14=1) 1 Specific Gravity: 25/25C - 1.30-1.336* Density: "Solubility In H2O": g/lOOg H2O -- 0.07g Color: Colorless liquid Properties depend on the inhibitor and inhibitor level. Odor: Mild, ether-like odor which may be just perceptible (unfatigued) at about 100 ppm in air Section IV. Flashpoint None FIRE AND EXPLOSION DATA 1 Auto-Ignition Temp. 1 932F (500C) (Flammability Limits In Air Lower I (High energy ignition source I at 250 Vol. % 8.0% Upper This material is nearly nonflammable. High energy, such as electric arc, is needed for ignition, and the flame tends to go out when the ignition source is removed. Water spray or fog may be used to fight fires and keep fire exposed containers cool. Use self-contained breathing apparatus for protection against suffocating vapors and toxic and corrosive decomposition products. Section V. REACTIVITY DATA This material can be hydrolyzed by water to form hydrochloric acid and acetic acid. It will react-with strong caustic, such as caustic soda or caustic potash to form flammable or explosive material. It requires inhibitor content to prevent corrosion of metals; and when inhibitor is depleted, it can decompose rapidly by reaction with finely divided white metals, such as aluminum, magnesium, zinc, etc. Do not use these metals for fabrications of storage containers for 1,1,1-trichloroethane. It will decompose at high temperature or under ultra-violet radiation to produce toxic and corrosive materials (phosgene and hydrogen chloride). 411538 0142 Section VI. HEALTH HAZARD INFORMATION TLV 350 ppm or 1900; mg/m? Brief exposure at 800-1000 ppm causes mild eye ^irritation and a little loss of coordination due to the anesthetic properties of 1,1,1-trichloroethane. Skin contact can cause defatting and, when prolonged or repeated, can produce irritation and dermatitis... It can absorb through the skin. Eye contact can result in pain and irritation: This material is /"'N considered low in toxicity among the chlorinated hydrocarbons.' j-" FIRST AID Eye Contact: Flush eyes well with plenty of running water for 15 minutes. Skin Contact: Remove solvent wet clothing promptly. Wash contact area with warm water ahd soap. Get medical attention for irritation. Inhalation: Remove to fresh air. If needed, apply artificial respiration.. Get medical' assistance immediately. (Note! Advise physician not to use-adrenalin. > ; ' Ingestion: Get medical assistance! (If a physician not immediately available andj the. amount swallowed was appreciable, give milk or water to drink and induce vomiting., 'Repeat several times. Estimated lethal dose for 150 lb man is 0.5 to 1 pint.) y , , PHYSICIAN: Avoid using sympathomimetic amines in treatment. [Section VII. SPILL, LEAI<& DISPOSAL PROCEDURES For small spills, mop, wipe or soak up with absorbent material using-rubber gloves. < Evaporate outdoors or in an exhaust hood. For large spills, inform Environmental personnel and evacuate area. Use protective equipment during clean-up (See Sect. VIII) Ventilate area. Contain liquid: pick up and place in closed metal containers.- Do not allow to enter water supply sources. (' DISPOSAL: Dispose of via a licensed waste solvent disposal company, or reclaim by filtration and distillation procedures. 1-- Section VIII. SPECIAL PROTECTION INFORMATION __________ ', , ^ Provide general and exhaust ventilation to meet TLV requirements. Use NIOSH approved respirators where the TLV is or may be exceeded. The selection of`the appropriate - respiratory protection (self-contained breathing apparatus, supplied air respirator, ' etc.) will depend upon the actual or potential concentration presents Gloves arid apron (of neoprene, polyethylene or polyvinyl alcohol) should be worn when needed to avoid skin contact. Remove solvent wet clothing promptly. A safety shower should be Available to use area. Chemical, goggles or a face shield should.be worn if. splashing is possible. An eye wash station should be readily available if splashing; is probable: Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in closed containers in a cool, well-ventilated area. Keep water-free. Monitor ' inhibitor level for vapor degreasing use. Use caution in cleaning operations involving [ white metal fines (see Sect. V). Trichloroethylene contamination may cause decomposition when aluminum is degreased. Provide regular medical monitoring of those'exposed,to this material in the workplace. Preclude those with CNS, liver, or, heart disease from exposure. Personnel using this solvent should avoid drinking alcoholic beverages shortly before, during, or soon after exposure. Exposure of pregnant female fats to high levels of 1,1,1-trichloroethane may have caused birth defects in offspring. D.O.T. Requirements Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: 000-071-556 SD-90 Other: CHRIS (1974) . 411538 0143 :iA. B. MC KEE ALCOA TECHNICAL CENTER - C TO MEMBERS, HAZARDOUS MATERIALS CONTROL COMMITTEE 1980-01-29 RE: Ref: ALCOA MATERIAL SAFETY DATA SHEET MANUAL AMSD Sheets No- 32-41 For Preliminary Review and Comments Return Comments by February 21 Attached are first drafts of safety data sheets for the following hazardous materials: No. NoNo. No. NoNo. No. No. No. No. 32 33 34 35 36 37 38 39 40 41 Chlorine Gasoline Hydrofluoric Acid Kerosene Methylene Chloride Oxalic Acid Potassium Hydroxide Sulfur Dioxide Asbestos Dowthern G (hydraulic fluid) If these sheets are reviewed promptly, we should have 41 completed sheets for initial inclusion when the manual is issued around the end of the First Quarter. A. ABM:km Attachment cc: Members of Corporate Hazardous Materials Control Committee J. S. Boyt, Pittsburgh 07 H. P. Brueschke, Pittsburgh 19 A. E. Davis, Pittsburgh 24 R. E. Edgington, Pittsburgh 22 G. C. Heise, Pittsburgh 06 v R. M, James, Pittsburgh 07 R. L. Miller, Pittsburgh 08 A. B. McKee, ATC-C B. N. Peak, Pittsburgh 18 J. R. Stemler, ATC-C R. E. Toth, Pittsburgh 03 D. A. Whitfield, Pittsburgh WPH3 T *-`1 .ALCOA 411538 0144 Engineering Standard i\l_CQA Materials and Standards Section-Pittsburgh HAZARDOUS MATFRIAIS - IDENTIFICATION s MATERIAL SAFETY DATA SHEETS .18,15 PAGE 1 ROUGH DRAFT WiMVr 1. SCOPE I release of a large amount of energy, under- rfVi.. .. ^. . . ,( TiE5 St!ndtr^COVe" ^ identification of | going spontaneous combustion, and/or ] generating other hazardous materials (gases, materials used and/or produced by Alcoa. 1 ,,________ _ t--r ,-- '' Those materials considered as hazardous are eurttfltsTM*01* r Partlculates> one or more of the above characteristics. Examples of documented on Alcoa Material Safety Data Sheets (AMSDS). All materials used and/or hazardous materials falling into this produced by Alcoa, whether hazardous or not/ particular classification include explosive e listed .in Engineering Standard 18.k15.-1- dusts (such.as aluminum, organic material, etc.'), oxidizing agentsf reducing , - -t-lg) A hazardous mate: material-which yjto Health and- Safety,/ H, j;C!)Ti ranniV^TlerTy </i-)ny-y ;td<iaCh.'^'Included sarem^trrjn]ri'~ttha^;i'iTi Inflammable, '.'combustible, 'fiCrrosivei^toxicV^r "explosive.^wa^tt-* esaettoe-, : chemlcalivHa&iSv-fr /reactive, radioactive..oi~arraxiJin_r. vr*Anv: gas, vapor, liquid/rtsolid, rg._inrjHjimljlCC ti.-l material having one or. more of the -following characteristics is considered a hazardous material. *ia Any liquid having -a flash point below 100OF (37.8*C). <T Radioactive Materials. Any materials , that are (Tulljf) covered by the Nuclear Regulatory Coommmmi ission.;(NRS) /regulations ,:' '/.-All Alcoa locations using.radioactive i sources have .-a radiation safetvlsu'pervl nor 3' )n~l)(Ref. Alcoa r11 | 1 in | i 1 in| HI muI I i il ' f 1.2.10 The above criteria for classifying-a'-^fl"; <[material as Hazardous are not.meahtJtb'M>e'>V;': . all-inclusive or completely :;adaptabie' to': ..''' every material which arises. ,/In such cases, the corporate Hazardous Materials/Control Committee acting through its .functional.'. . ' . members will-assign the material^toTthe most CnmHii -1 j li ll j 4 -j-, Any liquid Havingsa flash point from 100 to 200F (37.8-93 2.3 Toxic by Inhalation. Any.. having a threshold limit value ' nbelow f;*-''' " * 500 ppm fejyes.and vapors/fi>elowJ10 :;mg/mH 30-'iuppu>f lose twn / Any materialAOK-kJi'-; ;o the extent of having a singj. LD 5Q below 500 mg/kg of bod^ W weight for rats. Fvjnpio_--pnti~_ri"nn xnnnidr -v.si--s-- 2, c ji; - S.C5 -o 2.5 Toxic by Absorpti Any material that < causes visible deststfct or irreversible alterations -in hjartan Ln tissue on contact) y^fianwafe areally ii.c~hy rHn contact. Any materiallOOitaa''iving a (dose LLDD,g^ below.-- 2000 mg/kg of body weight'-'tKe isoo.*o_>i>d io era i3eftof. Examples: thiuuy 1--uhlot id*,. Hyd cafhrm--totrachlnrida-- Chronic Toxicity. Any materials having serious or irreversible chronic health or - environmental toxicity as determined by the corporate Industrial Hygiene and Medical Department or Environmental Control Department. .. ... _____________* Safety ;J y/Data Sheet is : to./assemble- on one .sheet of v:;paper key information on'each hazardous f Immaterial relating'to material description^] v\ j i//, |ingredients, . physical properties, .safe . / V jIhandling and storage, fire and explosion ; data, emergency fire fighting procedures, 'I/: health hazard information, first aid procedures, spill recovery and disposal, plus special information relative to ,pro tection and precaution data. It is 'in- ' tended that these data sheets be made [available to key persons in the Safety, ' - abJWgiene and Environmental Control , T5epirTfitef?o/at all locations who need to be j aware of tne safety and health aspects of hazardous materials. These people in cooperation with their corporate counterparts, will have the responsibility for assessing, interpreting and passing judgment on information presented in these material safety data sheets. Following is a description of the various items on the Material Safety Data Sheet to aid understanding the completed form. Haz_a_r_d__o__u__s___P__r_o__c__e_s__s______ Any mate: i -yrhich in course of normal operati, an roduce gases, vapors, or pirfjjyiLTitn having one or more of the above characteristics. mmayniSSt1 phosgene, beryllium oxide, anhydrous aluminum chloride 2.8 Chemical Reactivity. Any material that, jas a result of foreseeable storage or pro !cessing and/or as a result of interaction I with other materials has the potential of readily detonating, polymerizing with the I \____ 3.1 Emergency Telephone. It will be the responsibility of each Alcoa location to select an appropriate telephone number for emergency information in matters pertaining to hazardous materials. This number may be for one of the following location management i individuals: a) Safety Manager, b) Environ- J mental Manager, c) Fire Marshall, or d) some other person designated to handle this i responsibility. 1 411538 0145' s-:isss^ ' 0 Engineering Standard ALCOA Materials and Standards Section Pittsburgh HAZARDOUS MATERIALS ^IDENTIFICATION & MATERIAL SAFETY DATA SHEETS -18 J5. -- PAGE 2 ..... ...... .. ROUGH DRAFT 3.2 Section I - Material Description. This section lists the material name, chemical name and formula, and other designations or synonyms. In most cases, material and chemical name will be the same; for example, product name - acetone, chemical name - acetone. Also listed is the corporate stock'number Jor.,numbers;, Different con-. ! .tainer sizes -ofpthesarae material will- carry different"'stock numbers. S:' Density - The amount of matter contained in a unit volume of a substance (mass per unit volume). Expressed as pounds per cubic foot or grams per cubic centi meter. Solubility in Water - Degree in which the material will dissolve in water at ;room temperature. The following terms based on weight per cent are used. 3.3 Section II - Ingredients and Hazard px,-. -..-Data. ".This section includes ingredi ents,^composition,' -concentrations and toxicity .data ,:which indicates accep levels^pfsexposurev^piti'.j Negligible.. light...... [oderate.. ppreciable. Complete .v./ .less than 0.1 percent .0.1 - 1 percent io.1 - percent '- / more than.10 percent ih aUapropp^tiotis Threshold Limit iValue-'OfebV) - Xalue's `are ____________ Safety.and , ffealth Administration i(O^HAl^ and/er.^the American - Conference of Governmental Hindus trial Hygienists .:(ACGIH)X Threshold Limit ' Values are ri thrr inrrnptiiiM r ceiling concen trations (shnyg*=%fi?i5~exposures) or time VV weighted averages (TWA). . Time weighted averages and/or ceiling exposure values refer to the approxynatg^paximum conceiitra-. tions which most ISSfff^e exposed to after day without; adverse.|eTfocts. - The I wftrtira critoBda-TwhiaBi are the legal ts, should be JfiSesrXF'the OSHA.ee 7V:." - ? values vary from,one another. ' KCGTB' s . which jarelgyQc than the OSHA values > : should be liflEea^Cn^place of the OSHA /trcX '. exposure criteria, only ^n-those cases where - . the corppoorate Indus trial: Hygieneg.JDPesparr tmmeenntt 'fWtwf-w.-10 decides that thfrth'Cail!'valueS.M^ore '- / , appropriiaatte than the OSHA ^LV-'Vjto protectAMjtwftrt Sj r___ ^hheeaalltthh. Units 'for TTTL,VV '' s are nnm (parts per million) or mg/m3 (niiHlLHUigr. -P ;-v cubic meter) . Pst. Color -- ' 'dor For exan^le,-'colorless aromati/i odor. See Chemical Card Chemical Manufacturers Assoc.' Card number /(where ayail/able) QAcflfUWiUto Section IV - Fire and Explosion Data. Flash Point - Temperature at which the liquid mixture gives off vapor sufficient - to form an :ignitable mixture with air . near .the surface of theiiquid. .Tempera tures are assumed 'to'be for closed cup test .unless marked pc -for open cup test. . Auto-Ignition Temperature .-" Temperature '.-'.at which the material will - ignite spon taneously in air . `I'.-.-, -- .':-/''. -. .- . . - -, .vX'L'L. -. . Flammable Limits (Explosive Limits) - Volume percent range of'vapor or gas .. mixture in air in which propagation of flame or explosion can occur on' contact with source of ignition. 3.4 Section III - Physical Data. Definitions; (Both C and "F and units all other measurements are indicated.) 1. Physical Form - Gas, liquid, solid (powder, crystal). 2. Boiling Temperature - Temperature of the liquid at which its vapor pressure is ! equal to the atmospheric pressure (760 i mm Hg). I |3. Melt/Freeze Temperature - Temperature at which the liquid changes to a solid, or from a solid to a liquid. i 4. .Vapor Pressure - Pressure, measured in pounds per square inch absolute (PSIA) or mm Hg, which is exerted by a volatile liquid at room temperature. 5. Evaporation Rate - Relative rate at which material will evaporate as com pared to ether (Ether =1). Fire Fighting/Extinguishing - Indicates specific type of extinguishment material to use, procedures to follow, precautions' to take and conditions to avoid when the material is on fire or involved in a fire. Examples: Use carbon dioxide or dry chemical extinguishers. Do not use water spray. Shut off gas flow. Indicate firefighters' protective gear. 3.6 Section V - Reactivity Data. 1. j Reactivity Hazards - Indicates whether material is stable or unstable and if hazardous reactions can occur. Also lists the hazardous products produced from the reaction and the conditions and materials that should be avoided. 2. Metal Corrosion Problems - Indicates what metals are incompatible with the hazardous material so that contact can be avoided. 6. Specific Gravity - Ratio of the weight of a substance to the weight of an equal volume of water at (39.2F). This determines whether the material floats or sinks in water. 3. Additional Information - Lists any other special precautions not covered under metal corrosion or reactivity. Includes potential danger from inadvertent or accidental mixing. 411538 0146 Engineering Standard Alcoa Materials and Standards Section Pittsburgh HAZARDOUS MATERIALS - IDENTIFICATION & MATERIA! DATA SHEETS ' P#GE! ROUGH draft O'r acute/ and/or chronic adverse health effects which occur as a result of inhalation, skin contact, eye contact, -and ingestion and the levels at which these effects can occur if known. Exanples of adverse effects include such things asjtehet'tniLOj erf dizziness, liyejf-Tnjury, nervous system damage, etc. Acute: Characterized adverse effects P actual exposure. First Aid or Emergency Treatment Eves, Skin, Ingestion, Inhalation, where appropriate - Indicates the measurerto take when*.the hazardous material makes contact with an individual by one or more of the above routes of exposure. < ^ ^ r.Uj. C, X, 3.8 Section VII - Spill Recovery and Disposal Procedures. Indicates measures, procedures andprecautions to be taken for the recovery of -ama 11 spills and the appropriate disposal proce dure for that spill. Waste Disposal - Indicates the proper procedure for the safe disposal of the waste material during routine work not involving a spill. 3.9 Section VIII - Special Protection ! Information. Provides information re garding the need for protective equipment (such as goggles, face shields, gloves, japrons, respirators and related items. i o os _______________ Indicates specific guide lines regarding need for the use of: 1. Approved solvent safety cans, carrying containers for corrosives. 2. Explosion-proof electrical equipment; special ventilation, use of exhaust hoods. 3. Eye wash fountains, safety showers. Proper storage conditions including such factors as: store in a cool, dry, well-ventilated area with proper attention to separation of incompatible chemicals, avoidance of exposure to direct sunlight and any other special considerations. Appropriate information regarding proper DOT hazard class. 3.11 Section X - References. Indicates important references including volume, page number, date and other relevant information. ACGIH - American Conference of Governmental Industrial Hygienists AIA - American Insurance Association AIHA American Industrial Hygiene Association ASTM - American Society for Testing Materials CHRIS - Chemical Hazards Response Information System - U. S. Coast Guard CMA - Chemical Manufacturers Association NFPA - National Fire Protection Agency NSC - National Safety Council Occupational Safety t Health Act Do ( - C 411538 0147- FROM D. A. WHITFIELD MATERIALS AND STANDARDS SECTION PITTSBURGH OFFICE - 3 WPH H&S Industrial Hygiene TO MEMORANDUM BDD EER TBB o CO CD JD -CCD 1980-01-04 DB HGS LMN EDS RE: ALCOA HAZARDOUS MATERIALS - INDEX ENGINEERING STANDARD 18.15.1_______ The attached rough draft index includes all the items listed on the original sheets from J. Boyt 1978-06-13 (Task Group A) and A. B. McKee's letter of 1979-11-02. Are there any materials or trade names that you deal with, which are not listed? Should we include all process lubes (PL) and motor lubes (ML) in the index? There are presently some 1200 items listed, and lubes will add an additional 490 items. Please review and return to me with your comments by January 18. Also, please mark those that you believe are not Normally Hazardous (NNH). u)`n D. A T WHITFIELD Mechanical Engineering Division DAW:bv Attachments J. S. Boyt - AB 7 II. P . Brueschke - AB A. E. Davis - AB 24 R. E. Edgington - AB G. C. Heise - AB 6 R. M. James - AB 7 R. L. Miller - AB 8 A. B. McKee - ATC-C B. N. Peak - AB 18 J. R. Stemler - ATC-i R. E. Toth - AB 3 411538 0148 Engineering standard ALCOA Materials and Standards Section - Pittsburgh ALCOA HAZARDOUS MATERIALS_^_INDEX 18.15.1 PAGE 1 ROUGH DRAFT lor any recipient other than Alcoa. No warranties, guarantees or repre sentations, express or implied are made as to the u tility or effectiveness o f the methods, processes, products or procedures described or recommended herein. and must be returned on request. It shall not be reproduced or copied, in whole or in part, or used on behalf o f others than Aluminum Company o f America or its subsidiaries, w ithout permission. This engineering standard is provided solely for the purpose o f dis- NOTE: All materials used and/or purchased by Alcoa, whether hazardous or not are listed in this index so that you know the subject material has been reviewed. UR (Under Review) NNH (Not Normally Hazardous) MATERIAL I DESCRIPTION LATEST DATE AMSDS iA Abrasives Absorbant, Electrical Spray Absorbent Acetic Anhydride Acetone Acetophenone Acetic Acid Acetylene ! Acetylene Tetrabromide \ (Tetrabromoethane) i Acrawax C ' Acorbicel Bag-house Absorbent ! Acridine Acrylamide Acrylic Acid Activity Epoxy . Additive, Control Adhesive, Expansion Set Silastic Dow Corning No. 732 AD Adhesive, Dow Corning #140 Adhesive, #2 Perma Flex | Adhesive, Synthetic Rubber : Adhesive, Delta Core 200X Adhesive, High Temperature I Silastic j Adhesive, Weld-fast 220 I Epoxy ;Aerosol Paints !Aklanol Albustix - Urine Protein Strips No. 2870 Albron 209 Alcoa Joint Compound No. 2 Alcoa Stabilizer #5 Alcoa Aluminum A-5 Alcoa P-1 Red Lead Alcoa P-4 Red Lead Catalyzed Alcohol, Denatured Alcohol, Isopropyl Alcohol, Diacetone Alcohol, Ethyl Alcohol, Isopropyl Alcohol, Methyl Alkanal B.G. Alodine 47 Alodine 407 Alodine 4780 Alphacryl Alumina, Activated Alumina, Activated Alumina, Activated A.lumina, Activated Alumina, Activated Alumina, Activated Alumina, Activated F-l F-5 F-6 F-7 F- 20 H-151 H-51 Alumina Balls Alumina, Calcined Alumina, Hydrated .Alumina, Reactive Alumina, Regenerated (446) MATERIAL DESCRIPTION LATEST DATE AMSDS Alumina, Tabular T-61 Alumina, Tabular T-162 Alumina, Tabular Tabular Fines Alumina Tri-Hydrate Aluminum Chloride Aluminum Fluoride Aluminum Fluoride Solution (green liquor) Aluminum Fluoride Tri-Hydrate Aluminum Fluoride Tri-Hydrate Slurry (precipitator slurry) Aluminum Fluoride Tri-Hydrate Solution (spent liquor) Aluminum Flake Powder (Dedusted) Aluminum Flake Powder (Non- Dedusted) Aluminum Hydroxide Aluminum Ionic Standard Co-centrate Aluminum, Molten Aluminum Oxide Fumes Aluminum Paint Aluminum-Silicon Powder Aluminum Sulfate Aluminum Sulfide Amide Imide (G.E. AI-630) Aminopropyl Prophoxysilane Ammonia Ammonium Bifluoride Ammonium Chloride Ammonium Dichromate Ammonium Fluoborate Ammonium Hydroxide Ammonium Meta-Vanadate Ammonium Molybdate Ammonium Nitrate Anhydrous Ammonia Aniline Aniline Hydrochloride Anodes, Crushed Carbon Anti-Freeze, Liquid Antimony Antimony Pentoxide Antimony Trioxide Aqua Dag 137 Aquagel 70 Aquagel 80 Argon Aromatic Solvent Arsenic Trichloride Arsenic Trioxide Asbestos Asbestos Cloth Asbestos Gasket Asbestos Millboard Ascarite (Sodium Hydroxide/Asbes tos) Askarels Asphalt Asbestos Asphalt Rag Atomite Autagel ' j j j I j : j 411538 0149 a Engineering Standard ALCOA Materials and Standards Section Pittsburgh ALCOA HAZARDOUS MATERIALS - INDEX 18.15.1 PAGE 2 MATERIAL DESCRIPTION LATEST DATE AMSDS B Babbitt Bactericide Barium Carbonate Barium Chloride Barium Fluoride Bath Batteries (Filled with Electrolyte Acid) Battery Acid (Sulfuric) Bauxite Bayer Liquor Beetle 227-8 Belt Dressing Bentonite, Western (Dixie Bond) Bentonite, Southern (Dixie Bond) Benzene Benzil 150 Benzolthiozoliol, 2 (Eastman) Beryllium ;Beryllium/Copper Beryllium Hardener ;Beryllium Oxide !Bettle Resin !Binder, Truscor Cereal jBinzel 150 'Bismuth Bitumastic Paint Blasting Caps (No. 6) Blasting Fues (Sword Orange) , BLP Blip Seal |Bon Ami ;Bonderite 721A Bonderite 721S Bonderite 723C Bonderite 830 Boric Acid Boron Boron Alloy Boron Nitride Boron Trifluoride .Boron Triiodide Bowl Bryte Bowl Cleaner Brake Fluid Brass Brazing Alloys Brick (Common Building) Brick (Fire Clay) Bromoform (Tribromomethane) Brine Buffing Compound Burndy Penatrox Butane Butanol 1 Butts Butyl Carbitol Butyl Cellosolue Butyl Phthalate Butyl Stearate Byco-tox MATERIAL DESCRIPTION LATEST DATE AMSDS j C Cab-O-Sil Cadmium Cadmium Acetate Cadmium Chloride Calcium Ionic Std. Concentrate Calcium Carbonate Calcium Chloride Calcium Fluoride Calcium Hydroxide Calcium Nitrate Calcium Oxide Calciner Scrubber Solution Calgon Carbitol Acetate(Methyl Cellulose Acetate) Carbon Carbon B Carbon Brisquettes Carbon Dioxide Carbon Disulfide Carbon Monoxide Carbon Tetrachloride Carbo Wax 4000 Carbosolue Cardisorber (Carbon Dioxide Absorber) Cardox 242 Car Wash Compound Castable Refractories Cast Iron Cast Primers Castor Oil Cathode Seam Mix Caulking Compound Caustic 50% Caustic Etching Solution Caustic Soda Cellosolue Celosolue Acetate Cement, Acid-Proof Binder Cement, Acid-Proof Filler Cement, Ambroid Everfast (Airplane Glue) |Cement, Asphalt Base Roof (Cement, Calcium Aluminate (CA - 15, CA - 25, CA 250 jCement, Celanese Solvent !Cement, Contact (TATRO) Cement, Delta's Insulating Cement, Devcon B for Steel !Cement, Devcon F Plastic ; Aluminum Cement, Foster ET & ST Grade Cement, Epoxy Cement, Hydraulic Water Pad Cement, Lumnite Cement Masons Cement, No. 1 Quick Hardening :Cement, Portland Cement, Por-Rok j i | j j ' 411538 0150 0 Engineering Standard ALCOA Materials and Standards Section Pittsburgh .ALCOA HAZARDOUS.JjAIERIALS--_IflDEX.__ 18.15.1 PAGE 3 for any recipient other than Alcoa. No warranties, guarantees or repre sentations, express or implied are made as to the u tility or effectiveness o f the methods, processes, products or procedures described or recommended herein. and must be returned on request. It shall not be reproduced or copied, in whole or in part, or used on behalf o f others than Aluminum Company o f America or its subsidiaries, w ithout permission. This engineering standard is provided solely for the purpose ofdis- ' MATERIAL DESCRIPTION LATEST DATE AMSDS iCement, Pyroil Flex-o-Fix Rubber Adhesive Compound Cement, PVC !Cement, RTV Cement, Refractory I Cement, Ruberoid Roofing Ceramic Frit AL 19 :Ceramic Frit AL 28 I Ceric Sulfate ]Chlorine Chlorobenzene Chloroform Chromate Ore Chromic Acid Chromium Chromium Acetate Chromium Chloride !Chromium Fluoride ;Chromium Nitrate .Chromium 2, 4 Pentanedione jChromium Potassium Sulfate Chromium Trioxide Citric Acid jClay, Modeling I Cleaner, Dutch iCleaner, Hand (Lanolin- j Glycol) ;Cleaner, PVC Cleansing Solution No. j C731-1-6 I Cleveland Blend #2 ,Cleveland Blend #4 Cleveland Blend #5 Clinitest Urine Sugar Tablets Coal Coal Tar Pitch Coating, Perm. Mold Coating, Weldcote Mold :Cobalt Cobalt Chloride iCobalt Naphthenate 'Cobalt Nitrate :Cobalt 2, 4 Pentanedione Cobaltous Chloride Coke Dust Cold Bed Material - Alcoa Smelting Process Compressed Air Concrete Connectors, Delay MS9 Connectors, Delay MS25 Connectors, Ignitacord Connectors, Thermalite Copper, Copper Dust Copper, Scrap j Copper Sulfate :Coral Plastic |Corn Starch |Corrosion Preventative :Corrosion Preventative | Additive !Creosote ICresylic Acid (Cresol) 'Cryolite Cryolite Filtrate j cryolite Slurry Cuperic Ammonium Chloride : Cuperic Carbonate j Cuperic Chloride ! Cuperic Nitrate MATERIAL DESCRIPTION Cuperic Oxide (Black) Cuperic Sulfate Cuperous Chloride Cyclo Hexane LATEST DATE AMSDS D D300 Concentrate Dampney Apexior (Metal Paint) Dashpot Fluid (Dow Corning 500) Daxad Dearborn 66 Dearborn 157 Dearsol Fuel Additive Dearsol #30 Decahydronaphthalene Defoamer (RYCO 359A) Degreasing Solvent Delays MSI 7 Delays MS25 Delays MS42 Deoxylyte 10 Desicast No. 30 (Silica Gel) Detonating Caps Devcon Putty-Type Plastic Steel Developer, Penetrant Developer, X-Ray Film Diamond Abrasive Grit Diatomaceous Diastix-Urine Glucose Strips Dibutyl Phosphate Dichloroethylene 1-1 Dichloropentadiene Diethyl Amine Diethyl Sulfate Digester Slurry Di-Iso Butyl Ketone Dimethylformamide N-N Dimethyl Sulfoxide Disinfectants Dispersion Dag #395 Dolomite Domestic Whiting ;Don Kote iDow Corning 500 Dow Corning 804 Resin Dowtherm G (PCB) Draw Oil L-l Draw Oil L-4 Drew Gard 187 Drewsperce 738 Dross Dug Potlining DuPont Duco (Lacquer) DuPont Bond #8637 DuPont 15019 ML Dust - Baked Carbon Scrap Dust - Carbon Butts Dust From Potrooms Dust - Green Carbon Scrap 411538 0151 til ALCOA i--i ly n icci ii ly ouai luai u Materials and Standards Section - Pittsburgh ALCOA HAZARDOUS MATERIALS - INDEX 18.15.1 PAGE A MATERIAL DESCRIPTION Dust - Pot Dust - Potlining Mill Dust - Regenerator (446) Dxweld No. 200 :DX Gas !Dycote No. 6 Dye (Powder, Paste) Dykem Spray Dynamite .Dynel LATEST DATE AMSDS E Electrolyte, Copper Plating Emulsion (Dow Corning Y-30) ' Epon - 1007 Epoxy Enamel Epoxy, Catalyzed . Coat) Epoxy, Catalyzed (First (Final Coat) Epoxylite ; Ethane ! Ethanol | Ether '' Ethylene Glycol | Ethyl Acetate Ethyl Bromide Ethyl Carbamate Ethyl Sulfate Ethylene Diamine Ethyl Ether Evaporating Salt MATERIAL DESCRIPTION LATEST DATE AMSDS Fluid, Layout #303 Fluorescent Tubes Fluoride Specific Ion Ref Electrode Solution Fluorocarbon, Freon + Aerosol Propellants Fluorspar Fluosilicic Acid Flux, Brazing (Brass/Bronze) Flux, Brazing (Smith #N3) Flux, Joining (No. 66A & 67) Flux, Kester 1544 Flux, Kester 104 Flux, Kester AP-20 Flux, Neutral Hobart IH-900 Flux, Silver Soldering Flux (Skim) Dow 230 Flux, Peterson No. 1 Flux, Welding (Linde #60) Flux, Soldering Flux, Welding Cast Iron Flux Paste (Kester Soldering) Flux Paste (No Korode) Fly Spray (Insecticide) Flyash Forge Lubricant, Leaded Formvar E Foseco Napac Freon Frit Powder Fuel Gas, Bottled Fumes From Furnace Skim Fumes From Holding Furnaces Fumes From Melte Pitch Furfural (Furfuraldehyde) Furfural Alcohol Furnace Gases Furnace Slag F ' Fabric C5-A (Anti-Sieze Compound) : Fe1-Pro i Felt-Pro No. C5-1 (Anti- Sieze Compound) Felt, Refractory | Ferric Ammonium Oxalate ' Ferric Ammonium Sulfate Ferric Nitrate Ferro Dry Colorant Ferromanganese Ferrophosphorus Ferrosilicon Fertilizer Fiber Glass (Woven - Roven) Fiber Glass (Chopped Stranded) Fiber Glass Blanket (Aercore No. C-f) Filter Cloth Fixer (X-Ray Films) Floor Patch Floor Patching Resin Hardener Floor Dri (Oil Absorbent) Floor Sweeping Compound Flour, Grain Sorghum Fluid. Engine Starting Gallium G Gasoline Gases, Calibration GF-8 (Floor Tile Adhesive) Gauge, Radioactive Measuring Glass Fiber, 1/4 inch Glazing (Caulk-O-Seal) Glazing Compound (Steel Sash) Glue, Plastic Resin , Glue, Dry Powder : Glue, Tatro Cold Glycerine Glycol Ether Carbitol Glyptol Grain - Strip Mine Special Gramoxome Weed Killer Granules, Welding Graphite Dust Graphite, Blackhead Graphite Lubricator Grease (Darina EP 71522) Grease (Dow-Corning FS-3451 Fluoro Silicone) Grease Silicone Stopcock Grease Stick, Hard #6 Green Dye Green Liquor, Baker 411538 0152 a Engineering Standard ALCOA Materials and Standards Section - Pittsburgh ALCOA HAZARDOUS MATERIALS -_JNDEX 18.15.1 PAGE 5 for any recipient other than Alcoa. No warranties, guarantees or repre sentations, express or implied are made as to the utility or effectiveness o f the methods, processes, products or procedures described or recommended herein. and must be returned on request. It shall not be reproduced or copied, in whole or in part, or used on behalf o f others than Aluminum Companyof America or its subsidiaries, without permission. This engineering standard is provided solely for the purpose o f dis- material DESCRIPTION latest DATE AMSDS Green Liquor, White Gunk Solvent Gutter Sealant :Gutterseal (White Aluminum i Pigmented) 'Grit 240 (Lapping Compound) H Heating Oil No. 2 Helium Hemastix Urine Blood Strips :Herbicides |Heptane :Hex Spray :Hexachlorobenzene Hexachloroethane .Hexane Hexylene Glycol :HiSol 10 !Hydral ;Hydraulic Fluid Hydrazine, Aqueous :Hydrazine Hydrochloride I Hydraulic Fluid, Phosphate Ester ;Hydrocal, Industrial White iHydrochloric Acid Hydrochloric Acid Hydrofluorsilicic Acid Hydrogen Gas Hydrogen Chloride Gas Hydrogen Fluoride Gas iHydrogen Peroxide Hydrogen Sulfide Gas Hydrofluoric Acid ;8-Hydroxyquinoline I Indium Fluoborate Inert Gas .Inhibitor Liquid (Nep #232) .' Inhibitor Liquid (Nep #43) Initiation Units (Nonel) Ink, Bendiun Fuex, Forboro 'ink. Layout Ink, Printing (Nitro Cellulose Base) Ink, Recording Instrument .Insecticides Insulating Powder Insulation Materials Insulation, Careytemp Insulation, Insulation, :Insulation, Block Kaylo 10 Electrical Insulation, Lion Nokorode K-Kote Insulation (Fiberfrax Long Staple) Insulation (Laykold Weathercote) MATERIAL DESCRIPTION LATEST DATE AMSDS Insulation Spray Iodine Iremite 40 Iremite 60 Iridite 14-2 Iron Ionic Std. Concentrate Iron Oxide Iron Silica Dust Isobutanol (Isobutyl Alcohol) Isocure 606 Isocure Binder 306 Isocyanate Resin Isopherone Isopropanol (Isopropyl Alcohol) J Johns Manville Superex 2000 Joint Compound (Alcoa 2 Tubes) Joint Compound (Alnox Tubes) Joint Sealer, Concrete K Kaocrete C-32 Kerosene (PL 348) Ketostix-Urine Ketone Strips Kleen Bowl Korglaze Coat Chill Kraft Paper L Labstix Urine PH Strips Lacquer (Master Kincote Tatro) Lacquer, Richmond 2621, 1089, 2572 Lacquer, Richmond 2154, 2424, 2443, 78.7, 2484, 702, 2394, 771, 2336 Lanthanum Nitrate 778, 2165, Laundry Additive Lead Lead Acetate Lead Bromide Lead Carbonate Lead Chromate Lead Naphthanate Lead Oxide, Red Pb^O^ Lead Oxide Yellow PbO Lead Silicate Sulfate Lead Stearate Lecithin Lead-Plate Anti-Sieze Compound 411538 0153 a ALCOA Engineering Standard Materials and Standards Section - Pittsburgh ALCOA HAZARDOUS MATERIALS - INDEX 18.15.1 PAGE 6 MATERIAL DESCRIPTION LATEST DATE AMSDS Lighter, Hot Wire Fuse Lime Lime, Hydrated Lime Stone Linseed Oil Liquid Wrench Lithium Carbonate ;Lithium Fluoride 'Lithium Nitrate Lithium Oxide tLithium Tetraborate ; Anhydrous ' Lubricant, Belt Vantrol Lubricant XX Light Klingfast Lubricant, Power Cut HD-600 : Lubricant WD 40 Spray Lubricant, Richmond M-73 Lubricant, Richmond RSC1053 Lubricant, Richmond RSC1046 Lubricant, Richmond RSC1076 Lubricant, Richmond M-70 Lubricant, Richmond M-4000 Lubricant, Richmond M-4001 LR13P (Parting) LR13M (Parting) M Magnesium Magnesium Powder Magnesium Chloride Magnesium Fluoride Magnesium Oxide Magnesium Perchlorate Magnesium Silico Fluoride Magnesium Trisilicate Maleic Acid Manganese Manganese Acetate Manganous Chloride Mechanical Lubricant ML132 Mechanical Lubricant ML575 Mechanical Lubricant ML921 Mannite Marir.ite (Asbestos) Magnus Mercuric Chloride Mercuric Iodide Mercury Mercury Decontaminant Metalizing Metal Metal Polish Metcc 405 Metcaloy No. 1 Methane Methanol Methenamine Methyl Acrylate Methyl Amyl Butyl Ketone Methyl Ethyl Ketone Methyl Ethyl Ketone Peroxide Methyl Isobutyl Ketone Methyl Laurate Methyl Methacrylate Methyl Naphthalene Methylene Chloride ; MATERIAL DESCRIPTION LATEST DATE AMSDS Mineral Oil Mixed Hyprochloric and Nitric Acids Micarta Mineral Spirits Mobile ARMA Molasses Moldene Talc Molybdenum Molybdenum Disilicide Molybdenum Disulfide Molybdic Acid Molybdic Oxide Morpholine Mortar Motor Vehicle Gases Mud, Red Mud, Brown Muriatic Acid I [ N Nachelate 7215 Nalco 71D5 Nalco 25L Nalco Solution S0226 Nalco Solution S0222 Nalco Solution S0243 Nalco Solution SO260 Nalco Solution S0269 Nalco Solution SO270 Nalco Solution S02 71 Nalco Solution S0281 Nalco S-2 Solution S0282 Nalco Solution S0283 Nalco Solution SQ291 Nalco 347 Nalco 353 Nalco 360 Nalco Solution SO440 Nalco Solution S0441 Nalco Solution S0442 Nalco Solution S0443 'Nalco 444 NR--4 Nalco Solution S044 5 Nalco 458D INalco 464 'Nalco 7215 Nalco No. 19 Nalco No. 35 INalco No. 763 Nalco 9 37 Nalco 7312 Liquid Nalco Solution NO. 224 Nalco Solution NO. 226 Nalco Solution No. 229 Nalco Solution No. 243 Nalco Solution No. 260 Nalco Solution No. 269 Nalco Solution No. 270 Nalco Solution No. 271 Nalco Solution No. 274 Nalco Solution No. 275 Nalco Solution No. 277 Nalco Solution No. 297 Nalco Solution No. SH-355 Nalco Solution No. 5091 411538 0154 0 Engineering Standard ALCOA Materials and Standards Section Pittsburgh ALCOA HAZARDOUS MATERIALS - INDEX 18.15.1 PAGE 7 for any recipient other than Alcoa. No warranties, guarantees or repre sentations, express or implied are made as to the u tility or effectiveness o f the methods, processes, products or procedures described or recommended herein. and must be returned on request. It shall not be reproduced or copied, in whole or in part, or used on behalf o f others than Aluminum Company of America or its subsidiaries, without permission. This engineering standard is provided solely for the purpose o f dis- MATERIAL DESCRIPTION Nalco Solution No. R-420 Nalco Solution No. 418-S .Nalco Solution No. 419 Nalco Solution No. 475 i N-Methyl-2-Pyrrolidone Naphtha Naphol Spirits Natural Gas 1Nalclean 66 Descaler 1 Nalcoag 1030 (Investment Slurry) i Neutralized Slurry 1 Nickel | Nickel Acetate Nickel Formate i Nickel Carbonyl Nickel 2, 4 Pentanedione Nickelous Chloride Nickelous Fluoride N.D. 68E j Niobium Chloride Nitric Acid I Nitric Oxide ! Nitro-Carbo-Nitrate Nitrobenzene , Nitrogen Nitropropane ' Nitrous Oxide ; O-Nitroso Aniline Nopcosant-L NL Cream (Metal Cleaner) i Nylon Solution 6, 6 i Oakite I Oakite 92 i Oakite 94 1 Oakum, Tarred Octylol Oil Black Hawk Jack Blaster Penetrating Boiled Linseed Chevron K-Pale ; Diesel Fuel No. 2 Fuel No. 6 : Hydraulic i Lion Company Seal Perm 1 Machine I Mineral-Lard (Parting) i Motor SAE 30 Olive (Parting) Outboard Motor Penetrating Rigid Sulphur-Lard Cutting Rust-Inhibited Soluble Red Utility 3-In-l York Refrigeration York Vacuum Pump Oil Absorbant Oleic Acid Oleum Acid Olivine Flour Organic Peroxide Oxalic Acid LATEST DATE AMSDS MATERIAL DESCRIPTION Oxygen Oxygen Absorber Ozone, 03 (SeezOj) LATEST DATE AMSDS P Paint Aluminum Asphalt Any Brand Yellow Benjamin Moore Outside Catalyzed Epoxy Enamel Epoxy G.E. Glypel High Temperature Aluminum Indurall Activated Epoxy Latex Lavax Vista Green Oil Base Para Spray #2 Pigments Red Lead Primer Red Spray Remover PPG No. 75-2 Remover Kuhns No. 731 Selcar Type-A Thinner BLP Valspar (High Temperature) Vinyl Zinc-Chromate Primer Zinc-Rich Coating Parco 336 Parco 338 Parting, Lubrikold Parting, Petrolatum White Parting, RP803 Parting, Ramco Paste, Dow Corning Green Paste, Aluminum, Alcoa Stabilizer (5 Paste, Aluminum Hydropastes Paste, Aluminum (Leafing, Non-Leafing, Tinting) Paste, Aluminum Compound 252 Paste, Foseco #8 Core Fix Paste, P. D. George Green 2159-2189 Paste, P. D. George White 2198 Paste, P. D. George White 21105 Penetrant, Tracer Tech P133 Penetrating Oil, Fluorescent Pentane Penwalt 125 Alkaline Penwalt AE16 Caustic Pep Set 3595 (Core Binder) Pep Set 2590 (Core Binder) Pep Set 1505 (Core Binder) Perchloric Acid Perchloroethylene j I . 411538 0155 a ALCOA Engineering Standard Materials and Standards Section Pittsburgh ALCOA HAZARDOUS MATERIALS - INDEX 18.15.1 PAGE 8 material DESCRIPTION LATEST DATE AMSDS Perlite (Core Mix) Petroleum Distillate Petroleum Naphtha PH 4.00 Meter Buffering Soln. PH 7.00 Meter Buffering Soln. PH 10.00 Meter Buffering Soln. Phthalate Plasticizer Phenanthrene Phenazine Phenol Phenolic Resin Phenolic':Solution (GE 330-078) Phenolphthalein Phenyl Arsine Oxide Phenanthrene Phosal Coating Phosgene Phosphoric Acid Phosphorus Pentachloride Phosphorus Pentoxide Phosphorus Trichloride I Phthalic Anhydride Phydraulic Fluid (PCB) Pipe Joint Compound Piperidine I Pitch Pitch, Pitch, 50 Degree 110 Degree Plaster Plaster Board Plastic (Ren RP 3203) Plastic Cement Plastic Quick I i Platinic Chloride PM 25 Thermal Plastic Polybutene 30% Kerosene 70% Mix Polychlorinated Biphenyls (PCB) Polyethylene Polyester Resin Polyester Solution (G.E. 330-045) Polypropylene Polyvinyl Chloride Porox (Bolt Anchor) Potassium Bifluoride Potassium Bromide Potassium Chlorate Potassium Chloride Potassium Chromate Potassium Dichromate Potassium Fluoborate Potassium Fluoride Potassium Hydrogen Phthalate Potassium Hydroxide Potassium Oxylate Potassium Permanganate Potassium Sulfate Potassium Sulfide Potassium Thiocyanate Potassium Thiosulfate Pot Gases Pot Insulation Pot Lining Mix Pot Lining Scrap Potroom Particulate Powermax 200 (Blasting Emulsion) MATERIAL DESCRIPTION LATEST DATE AMSDS Powrkleen (Hand Cleaner) Powdered Mica Praseodyminum Nitrate Premixed Grout Premacord Primatex (Gasket Paste) Prevention Plus (Drain Cleaner) PPG Finishing Material (Surface Conditioner) Primacord (Detonating) Primacord (25 Grain-E) Primadet (Blasting Cap) Primaline (Detonating Cord) Primary Filter Dust Primers Primers Detaprimes Primer, Epoxy Primers, High Intensity Primer, Ruberoid Concrete (Asphalt Coat) Process Lube PL 145 Process Lube PL 229 Process Lube PL 242 Process Lube PL 277 Process Lube PL 289 Process Lube PL 342 Propane 1 Propanol 2 Propanol Propylene Glycol Propyene Oxide Protective Sealer Compound Putty (Steel Sash) PVF Enamel Pydraulic Fluid (PCB) Pyridene Pyrogallol Pyrrolioine i | | | j ; , j ! j , i 1 i 1 ; j 1 j Q Quarry Cord Quicklime (90% Burnt Lime) R Radioactive Waste Rat Poison Raw Sewer Sludge Reactor Bed Material Rea Bond Coat 4670, 33P Rea Nylon 850-15, 866 Rea Red Solvar 8419, 8020-40 2921-35, 8419-27 Rea Red Solvar 2921-40S Rea Red Nylon K11L Rea Burgundy Solvar 8339 Rea Thinner 3/1 Rea Formvar 1268, 205-1 411538 0156 0 Engineering Standard ALCOA Materials and Standards Section - Pittsburgh ALCOA HAZARDOUS MATERIALS - JMO __. . 18.15.1 PAGE 9 for any recipient other than Alcoa. No warranties, guarantees or repre sentations, express or implied are made as to the u tility or effectiveness o f the methods, processes, products or procedures described or recommended herein. and must be returned on request. It shall not be reproduced or copied, in whole or in part, or used on behalf o f others than Aluminum Companyof America or its subsidiaries, without permission, This engineering standard is provided solely for the purpose o f dis- MATERIAL DESCRIPTION LATEST DATE AMSDS Rea Dry Lube .Rea Green Solvar 2921-30 ,Rea Yellow Epoxy 31A W/WES :Reclaimed Aluminum Insulation !Red Mud Refrex-Kleen Flux Resin, Formvar Resin, Hetron 197-A Polyester Resin, Low Odor Laminating Resin, Ren RP 3260 Casting Resin, Ren RP 1220A IResorcinal jRidoline 34 Ring Furnace Exhaust Gases I Rock Salt Romunda Cleaner Roof Coating Roof Cement Rosin, Wood FF Grade Rouge Sticks :Royal Blue (Liquid Cleaner) 'Rodine 82A (Inhibitor) Rubber, Perma Flex Black Tuffy iRubber, Dow-Corning RTV Silastic A Rubber, Dow-Corning RTV , Silastic E Rubber, Dow Corning RTV Silastic G Rubber, Smooth-On FMC 200 ;Rubber, Smooth-On FMC 201 j Ryco 359 A Defoamer I_ Safety Solvent (Harco) Sairset (Refractory Cement) Sand, Green Sand, Olivine 200 Mesh Sand, Olivine 120 Mesh Sand, Sand, Sand, Silica Oklahoma 90 Silica Nevada 60 Zircon Sand, Masons Sand, Sandblasting Sanding Sealer Sawing Lubricant (Wynn's 951-1) Schenectady Chemical 960 j Top Coat j Schenectady Chemical 84 3 Red Dye Soln. Schenectady Chemical Isonel XWE 1092 ;Schenectady 893 Isocyanate Soln. Schenectady Isonel 678-1092 Scrap Boxes & Bags Scrap, Magnesium Ribbon Scrap Drums Scrap Rolling Coolant Scrap Iron Sealant, Roofing MATERIAL DESCRIPTION LATEST DATE AMSDS Sealant, Silicone Rubber Sealant, Permatex No. 2 Non-Hardening Sealing Compound Sealer Joint, 1/4" Diameter Sewer Gas Shellac Silica Cake Silica, Fused IP1W, P2, SI & S2 Silica, Fumed Silica Sand Silica, Submicron or Cabosil Silica Gel Silica Gel Syloid 63 Silicate Mortar Silicon Silicon Tetrachloride Silver Brazing Alloys Silver Nitrate Sinter Dust Sludge, Copper Sno Flake Cold Stripper 100 Soaps Sodium Sodium Acetate Sodium Aluminate Sodium Aluminum Chloride Sodium Bicarbonate Sodium Bichromate Sodium Bisulfite Sodium Carbonate Sodium Chlorate Sodium Chloride Sodium Citrate Sodium Citrate Dihvdrate Sodium Chromate Sodium Cyanide Sodium Hydroxide Sodium Dichromate Sodium Fluoborate Sodium Fluoride - Aluminum Fluoride Slurry Sodium Fluoride Sodium Fluoride - Silica Slurry Sodium Gluconate Sodium Hexafluroferrate j Sodium Hypochlorite [Sodium Hyposulfite Sodium Molybdate Sodium Nitrate : Sodium Oxide Sodium Oxylate Sodium Phosphate-Dibasic- Anhydrous Sodium Polysulfite Sodium Fluorosilicate Sodium Gluconate Sodium Silicate Sodium Thiocyanate Sodium Tartrate Sodium Tetraborate Sodium Silicate-Meta- Anhydrous Solder Solka Floe 411538 0157 a ALCOA Engineering Standard Materials and Standards Section Pittsburgh ALCOA HAZARDOUS MATERIALS - INDEX 18.15.1 PAGE 10 MATERIAL DESCRIPTION LATEST DATE AMSDS Soluble Cut Fluid Solvent SBS-140 or Calgon Pax Solvent Base Paints Solvent: Contact RE-NU 1, 2 Dichloroethane Methyl Naphthalene Naphtha Oakite Trichloroethane Trichloroethylene Varsol Mek Diso Uthyl Acetate E. E. Acetate Solvent Spray Solvent Grade C Solvent, A1 Co Sorbent Sorbent C Sorbent Materials Sparkleen - Biogradable Detergent Spent Enamel Spent Caustic Spent Etching Solution Spent Nitric Acid Spent Phosphoric Acid Spent Pot Lining Spent Liquor (Ft. Mead) Spent Liquor, White & Bayer Spray On Co. No. 205 Starch Steam Boiler Treatment Additive Steam Cleaning Fluid Additive Steel, Devcon Putty-Type Plastic STP Stainless Steel Polish Stannic Chloride Stannous Chloride Stannous Sulfate Stoddard Solvent Strontium Fluoride Strontium Nitrate Sulfatate B-l Sulfur Dioxide Sulfosalicylic Acid Sulfuric Acid SP (Moon Dust) Powder Super Caltemps (Insulation) Superex Block (Insulation) Sweeping Compound Steel Stubs Synasol MATERIAL DESCRIPTION LATEST DATE Tape, Tape, Tar T Asbestos Teflon Tarset (USS Chemical) Tar Epoxy Talc, Red Tamol-N Teflon, DuPont Silvertone Terasod, P. D. George 357 Terra Alba Tetra Chloroethylene Tetraethyl - O - Silicate Tetraethylenepentamine Tetrahydro Furan Tetraisopropyl Titanate Tetraisopropyl Zirconate Thermo 12 (Insulation) Thinner, Lacquer Thinner (Sterling F173) Thinner (Dow Corning Silastic RTV) Thinner (Epoxylite) Thiourea Tisab (Orion 94-09-09) Titanium Titanium-Boron Alloy Titanium Tetrachloride Titanium Potassium Fluoride Titanium Dioxide Toluene Toluene Diisocyanate Tovex 700 Tovex 800 (Watergel Explosive) Tribulylamine 1, 1, 1 Trichloroethane 1, 1, 2 Trichloroethane Trichlorethylene Trichloro Ethylene Trichloro - Trifluoroethane 50% Trichloroethylene 50% Isopropyl Alcohol Tricresyl Phosphate 2, 4, 6 Trinitro, Toluene/TNT Trimellilic Anhydride Trimethyl Dihydroquinoline Trimethylamine Tri Sodium Phosphate Tri Clenal (Glasses Cleaner) Tris Nitro Triton X-165 R & H Surfacant Tripoli Polishing Agent TRW Coating Turpentine AMSDS 411538 0158 0 Engineering Standard ALCOA Materials and Standards Section Pittsburgh ALCOA HAZARDOUS MATERIALS .r_INDEX 18.15.1 PAGE 11 for any recipient other than Alcoa. No warranties, guarantees or repre sentations, express or implied are made as to the u tility or effectiveness o f the methods, processes, products or procedures described or recommended herein. and must be returned on request. It shall not be reproduced or copied, in whole or in part, or used on behalf o f others than Aluminum Company of America or its subsidiaries, without permission. This engineering standard is provided solely for the purpose o f dis- MATERIAL DESCRIPTION LATEST DATE AMSDS U Ucon Quenchant Ultracal 30 (Non Foamed Hydrocal) Urac 110 (Urea Formaldehyde) ,Urethane Solution :Used A-445 Alumina V Vanadium Oxide Dust Vanadium Pentoxide Vanishing Oil Vani-Sol (27% Hydrogen , Chloride) Vaposector (Exterminator) Var Form Varnish, Clear Baking Varnish, Epoxy ,Varsol ; Vasoline Petroleum Jelly ' Velvoleum Cleaner, Protector , Vermiculite I Victa Wet 12 (Wetting Agent) Victamide, Ammonium Amido Vira Fluxes 2 Vinyl Pyridine Vinegar Vulcanal Cream (Parting) iW Wash, Sil-O-Cel ! Wash, Zein Waste Acid Sludge Waste Aluminum Chloride Waste Anodizine, Solution Waste Lacquers, Paints, Varnish, Coatings, Solvents Waste Oils & Lubricants Waste Oils & Lubricants Wax, Cerita 942 Wax, Nalco MD 103-8 Wax, Fillet : Wax, Johnsons Paste Wax, Red Gate & Patch Wax, Floor Wax, Stripper Wax, Kwick Remover Water Conditioner Water Softener Resin Water Soluble Oil Weather Proofing, Crystal ; Clear 1 Welding & Brazing Fluxes Welding Compound (Steel, j Lincoln 535 & 840) ' Welding Fumes MATERIAL DESCRIPTION LATEST DATE AMSDS Welding Rods & Wire Weld Crete Weld Fast 220 Epoxy Adhesive WD-40 (Spray) WP40-H (Core Binder) West All Purpose (Liquid Cleaner) Westamine X (Disinfectant) Westinghouse - B523 Isocyanate Soln. White Lead In Oil Winter Green (Deodorant) Whiting Wood & Blacktop Sealer Wyandotte Aldet Wyandotte Spray Aldet Wyandotte Tonic Wyandotte 5533-4 Desmutter Xylene Xylol X Y Y-ER-EAS (Wire Pulling Compound) Yates Soluwax F (Cores) Z Zinc Zinc Chloride Zinc Oxide Zip Slip (Parting) Zirconium Powder Zirconium Chloride Zirconium Dioxide Zirconium Diboride Zirconium Hydride Zonal A (Wetting Agent) 411538 0159 FROM RPORATE HAZARDOUS ONTROL COMMITTEE RECEIV*' MAY 71981 Industrial Hygiene For Final Review and Approval PLEASE RESPOND BY MAY 12 These sheets are needed by the Marketing Department in order to respond to requests for information from customers. Please respond promptly. When these sheets were circulated last month for a preliminary review there were two sheets on cryolite: No. 189 Alcoa Synthetic Cryolite - Fines No. 190 Alcoa Synthetic Cryolite - Pellets As Techical Manager for Alcoa Chemical Products, Arnold Davis has indicated to me that it would be acceptable to combine these two Alcoa products on a single safety data sheet. A. B. MC KEE ABM:km Attachment cc: Members of Corporate Hazardous Materials Control Committee H. P. R. L. A. E. R. E. G. C. R. M. R. L. A. B. R .T. J. R. D. A. J. D. Brueschke, Pittsburgh 19 Byers, Pittsburgh 07 Davis, Pittsburgh 24 Edgington, Pittsburgh 22 Heise, Pittsburgh 06 James, Pittsburgh 07 Miller, Pittsburgh 08 McKee, ATC-C Shillinger/R. L. Vezzani, Pittsburgh Stemler, ATC-C Whitfield, Pittsburgh WPH3 Yerger, Pittsburgh 18 03 Others R. W. Flanagan, Pittsburgh 07 ALCOA 411538 0160 For Internal Company Use Only - N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No. ES ALCOA Section I. HAZARD CHARACTERISTICS CD Flammable CD Combustible CD Corrosive CD Explosive CD Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: CD Ingestion EO Inhalation CD Absorption PRODUCT Alcoa Synthetic Cryolite Na3AlF6 Phone No. Date: Chemical Name & Formula: Aluminum Sodium Fluoride (AlF3*3NaF) Other Designation: Cryolite, Chiolite, Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa, Kaiser, Mobay Section II. INGREDIENTS A1F3-3NaF....................................................................... Free AI2O3 ................................................................. Si02 ......................................................................... Moisture LOI............... % Typical 84.0 5.0 0.55 0.10 0.10 6.00 HAZARD DATA OSHA -PEL Fluoride:. 2.5 mg/m3 Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Solid Freeze-Melt Temp.. Vapor Pressure: 1832F (1000C) Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Odor: 1.20 75 lb/cu ft Slightly soluble Tan None Typical Sieve Analysis Fines +200 Mesh - 0% Pellets +100 Mesh - 7% +325 Mesh - 10% +150 Mesh - 35% -325 Mesh - 90% +200 Mesh - 70% +325 Mesh - 98% -325 Mesh - 2% Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. | Flammability Limits In Air _________________None______________I_________None_______________I________________None Lower Upper Non Flammable Material Section V. REACTIVITY DATA Cryolite is used an an electrolyte in the production and refining of aluminum from its oxide; in ceramics; as a binder for abrasives; in electrical insulations; flux in the open hearth process; explosives; polishes. With air: None With water: See Section II With heat: See Section IV Non-corrosive 411538 0161 No. 1 RQ Alcoa Synthetic Cryolite Section VI. HEALTH HAZARD INFORMATION | TLV 2.5 mg/mJ as F Acute: Chronic: Exposure to extremely dusty conditions in the absence of a proper respirator may result in nausea and/or abdominal pains, shortness of breath, and lack of appetite. Excessive inhalation of cryolite dust for prolonged periods can result in sclerosis of the bones caused by fixation of the calcium by the fluorine. There may also be some calcification of the ligaments. The teeth may become mottled and there may be osteosclerosis and ostemalacia. The bony and ligametous changes are demonstrable by x-ray. c Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Use dry, clean up procedure. Avoid washing down with water where possible to minimize fluoride contamination. Avoid excessive dusting. Dust masks should be used during clean up and disposal activities minimize the possibility of inhalation of cryolite dust. Dispose of dry material in landfill where leaching will not occur. This material is not considered a hazardous waste under EPA definitions. EPA Hazardous Waste No. NOT REGULATED Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate ventilation to meet TLV requirements. Ventilation must be such that spots of dust accumulation are prevented. Where respiratory protection is necessary, NIOSH approved respiratory protection should be used. The selection of appropriate respiratory protection (dust respirator, supplied air respirator, self-contained breathing apparatus, etc) should be based upon the actual or potential airborne contaminants and their concentration present. Section IX. SPECIAL PRECAUTIONS & COMMENTS Chemical substance components have been reported to the EPA office of toxic substances in accordance with the requirements of the toxic substance control act (Title 40 CFR Part 710). D.O.T. Requirements N0T REGULATED Section X. REFERENCES ASTM No.: CAS No.: 15096-52-3 CMA Chemical Safety Oata Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: Other: L 411538 0162 For Interna/ Company Use O nly -- N o t To Be Distributed Outside The Company 0 ALCOA Section I. MATERIAL SAFETY DATA SHEET No. 131 HAZARD CHARACTERISTICS CH Flammable CD Combustible CD Corrosive CD Explosive D Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: D Ingestion O Inhalation O Absorption PRODUCT Alcoa 807 Solder Phone No. Date: Product Name: Alcoa 807 Solder Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS % HAZARD DATA Lead............................................................................................................................. Silver....................................................................................................................... Tin............................................................................................................................... Bismuth........................................................................................................... 80% 1.5 0.5 Remaindei OSHA PEL 8 hr. TWA 0.05 mg/mJ* (as Pb) Beginning 2/24/80, PEL is 0.05 mg/m3 with an action level of 0.03 mq/mL (Certain industrial lead uses have an extended time for compliance.) Blood samplinc and analysis must be available to every employee exposed above the action level over 30 days/year. Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.. Vapor Pressure: Solid (wire or ingot) NA 476-521F (247-272C) Low at soldering temperature Evaporation Rate: NA Specific Gravity: Density: "Solubility In H2O": Color: 11 g/mL (0.4 lb/in3) Nil Odor: Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Ignition Temp. NA I NA I Flammability Limits In Air I ------ I Lower | Upper I-- Extinguishing Media: This is a non-flammable material; use extinguishing media which are appropriate to the surrounding fire. Lead oxide can be an oxidizing agent for combustible materials when hot. Fire fighters should wear NIOSH approved self-contained breathing apparatus when this material is involved in a fire situation. Section V. REACTIVITY DATA This solder is stable and relatively inert under normal conditions of exposure. 411538 0163 No. _ 191 Alcoa 807 Solder Section VI. HEALTH HAZARD INFORMATION | TLV TWA 0.05 mg/m3 (50 pg/m3)as Pb Lead is a cumulative poison. Over a period of time a very small rate of- intake can reach a toxic level. Lead poisoning can produce symptoms such as headache, nausea, cramps, dizziness, weakness, insomnia, diarrhea, and loss of appetite. Heavy acute exposure can result in stupor, coma, and death. Employees with excessive exposure, who experience the symptoms of lead poisoning, should receive medical care and guidance promptly. Detailed biological specimen testing and evaluation of possible exposure conditions are required to diagnose lead poisoning. At normal bath temperatures, vapor pressure of lead in Alcoa 807 Solder is quite low; therefore, airborne lead concentrations would also be low. However, skimming or other surface agitation can generate airborne lead oxide. FIRST AID: Eye and Skin Contact: Flush with water to remove dust; get medical help if irritation persists. Wash all exposed skin well with soap and water. Inhalation: Remove from exposure. Get medical help. Ingestion: Contact physician promptly. Gastric lavage may be required. c Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact environmental personnel. Carefully vacuum up spilled material for recovery or disposal, avoiding dusting conditions, at all stages of handling, and place in a plastic bag-lined, tightly closed container. (Damp or wet clean-up methods may be useful in suppressing dust and can be used where more effective than vacuuming.) DISPOSAL: Follow Federal, State, and local regulations in disposing of waste material. Depositing it in an approved landfill should be evaluated as a suitable means of disposal. (Filtration of all exhaust ventilation air may be required, with filtrate disposal added to the waste problem.) EPA Hazardous Waste No. NOT regulated Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation to meet TLV requirements. Isolate Pb use area. Monitor lead exposure. Where respiratory protection is needed, use NIOSH approved respiratory protection. The selection of appropriate respiratory protection (toxic dust respirator, fume respirator, supplied-air respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. Wear goggles to prevent solder spatter from entering eyes. See OSHA Lead Standard 1910.1025 for additional safeguards related to lead exposures. c Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in closed containers in a clean area away from combustible materials. Protect containers from damage. Keep away from food or feed. Prevent dust dispersing conditions and breathing of dust. Follow good housekeeping practice and good hygienic practice. Wash thoroughly before eating or smoking after handling this material or working in its areas of use or storage. Do not allow eating, drinking or tobacco use in areas of storage or use of Pb. D.O.T. Requirements_______ NOT REGULATED_______________________ Section X. REFERENCES ASTM No.: CAS No.: CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Oata Sheets: Supplier Product Literature: Other: 411538 0164 For Internal Company Use Only - N o t To Be Distributed Outside The Company LU ALCOA Section 1. MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS Flammable CD Combustible CD Corrosive CD Explosive CD Water Reactive CD Radioactive D Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: 0 Ingestion D Inhalation CD Absorption PRODUCT Phone No. Date: Product Same: Alcoa 807 Solder No. _i!i Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS % HAZARD DATA Lead............................................................................................................................ Silver...................................................................................................................... Tin............................................................................................................................... Bismuth................................................................................................................... 80% 1.5 0.5 Remaindei OSHA PEL 8 hr. TWA 0.05 mg/m3* (as Pb) *Beginninq 2/24/80, PEL is 0.05 mg/m3 with an action level of 0.03 mq/mL (Certain industrial lead uses have an extended time for compliance.) Blood sampling and analysis must be available to every employee exposed above the action level over 30 days/year. Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.. Vapor Pressure: Solid (wire or ingot) NA 476-521F (247-272C) Low at soldering temperature Evaporation Rate: Specific Gravity: Density: "Solubility In HjO": Color: NA 11 g/mL (0.4 lb/in3) Nil Odor: Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Ignition Temp. NA I NA (Flammability Limits In Air I ------ Lower Upper Extinguishing Media: This is a non-flammable material; use extinguishing media which are appropriate to the surrounding fire. Lead oxide can be an oxidizing agent for combustible materials when hot. F^re fighters should wear NIOSH approved self-contained breathing apparatus when this material is involved in a fire situation. Section V. REACTIVITY DATA This solder is stable and relatively inert under normal conditions of exposure. 1i 411538 0165 i I No. Alcoa 807 Solder Section VI. HEALTH HAZARD INFORMATION j TLV TWA 0.05 mg/m3 <50 yg/m3)as Pbf .V r/fj r4- Lead is a cumulative poison. Over a period of time a very small rate ofintake can reach a toxic level. Lead poisoning can}produce symptoms such as headache, nausea, cramps, dizziness, weakness, insomnia, diarrhea, and losS of appetite1 Heavy acute exposure can result in stupor,[coma, and death. Employees .with ; excessive exposure! who experience the symptoms of lead poisoning; should- . c receive medical care and guidance promptly. Detailed-biological, specimen testing, and evaluation of possible exposure conditions are required..to diagnose.lead; . poisoning. At normal bath temperatures, vapor pressure of lead in Alcoa 807 Solder is quite low; therefore, airborne lead concentrations would, also -be :low. - However, skimming or other surface agitation can generate' airborne lead oxide. FIRST AID; Eye and Skin Contact: Flush with water to remove dust; get .medical help if irritation persists. Hash all exposed skin wellwith soap and water.. Inhalation: Remove from exposure. Get medical help. Ingestion.: Contact physician promptly.' . Gastric lavage may (be required. A'-.. - Section VII. SPILL, LEAK & DISPOSAL PROCEDURES v .=-;^, Contact environmental personnel. Carefully vacuum up spilled material for recovery or disposal, avoiding dusting conditions, at all stages ofhandling, and place t i in a plastic bag-lined, tightly closed container. (Damp or wet.clean-up methodsJ may be useful in suppressing dust and can bemused-where more effective than-;.; vacuuming.) ... I DISPOSAL: Follow Federal, State, and local regulations in disposing of waste material. Depositing it in an approved landfill should be evaluated as a suitable . means of disposal. | (Filtration of all exhaust'ventilation-air may.be required, with filtrate disposal added to the" waste1 problem.) ' -- EPA Hazardous Waste No. NOT REGULATED Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation to meet TLV requirements;* Isolate Pb use area. Monitor lead exposure. Where respiratory protection .is needed1,,use NIOSH approved respiratory protection. The selection of appropriate respiratory protection (toxic dust respirator, fume respirator, 'supplied-air. respirator,letc.), should be based upon the actual or potential'[airborne contaminant's and ..'their A..,- concentrations present. G Wear goggles to prevent solder spatter from entering eyes. **;. See OSHA Lead Standard 1910.1025 for additional safeguards related to lead exposures. SectionIX. SPECIAL PRECAUTIONS & COMMENTS . ; " v Store in closed containers in a.clean area away from'combustible materials. Protect containers from damage. Keep away from food or feed. Prevent dust dispersing conditions, and breathing of dust. . Follow good housekeeping, practice-and good : hygienic practice, Wash thoroughly before, eating or smoking*after handling this, material or working in its areas of use or storage. Do not allow eating, . r drinking or tobacco use in areas of storage or usd of Pb. ... . . D.O.T. Requirements________NOT REGULATED___________________________ Section X. REFERENCES ASTM No.: 1 CAS No.. CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: j \ Supplier Product Literature: Other: 411538 0166 from A. b. mc kee ALCOA TECHNICAL CENTER - C TO MEMBERS, CORPORATE'HAZARDOUS MATERIALS CONTROL COMMITTEE 1981 May 05 RE: ALCOA MATERIAL SAFETY DATA SHEETS No. 189 Alcoa Synthetic Cryolite No. 191 Alcoa 807 Solder For Final Review and Approval PLEASE RESPOND BY MAY 12 MAY 71981 industrial Hygiene These sheets are needed by the Marketing Department in order to respond to requests for information from customers. Please respond promptly. When these sheets were circulated last month for a preliminary review there were two sheets on cryolite: No. 189 Alcoa Synthetic Cryolite - Fines No. 190 Alcoa Synthetic Cryolite - Pellets As Techical Manager for Alcoa Chemical Products, Arnold Davis has indicated to me that it would be acceptable to combine these two Alcoa products on a single safety data sheet. A. B. MC KEE ABM:km Attachment cc: Members of Corporate Hazardous Materials Control Committee H. P. Brueschke, Pittsburgh 19 R. L. Byers, Pittsburgh 07 A. E. Davis, Pittsburgh 24 R. E. Edgington, Pittsburgh 22 G. C. Heise, Pittsburgh 06 R. M. James, Pittsburgh 07 R. L. Miller, Pittsburgh 08 A. B. McKee, ATC-C R .T. Shillinger/R. L. Vezzani, Pittsburgh J. R. Stemler, ATC-C D. A. Whitfield, Pittsburgh WPH3 J. D. Yerger, Pittsburgh 18 03 Others -FJ-arraga h^^P3^ecstTcrr-g 11 07--, ALCOA 411538 0167 ST45J (RV For Internal Company Use O nly -- N ot To Be Distributed Outside The Company G5 ALCOA MATERIAL SAFETY DATA SHEET No. ___ HAZARD CHARACTERISTICS CD Flammable O Combustible CD Corrosive Cl Explosive CD Water Reactive Radioactive CD Oxidizer Q Chemically Reactive Toxic 8y: CD Ingestion 0 Inhalation CD Absorption PRODUCT Alcoa Synthetic Cryolite Na3AlF6 Phone No. Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: Aluminum Sodium Fluoride (A1F3 3NaF) Other Designation: Cryolite, Chiolite, Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa, Kaiser, Mobay Section II. - " INGREDIENTS . . f MP,3*3NaF2...'.*..V....!.-...........-..-.V....................................;..t..v......................v...i.-.i..t.-..-.-..:...v.......v...o:, Free AIoOt ^i> .r TO'ca L.t-v. - 2 . ....................................................................................................................... 2 3 ....................-.............................................................................................. Moisture ------ .:V:.......V.:..................... LOI_____ kAJ; HAZARD DATA Typical ` '' ' ' . 84.0'- ;^bSHA;'^M3;- 5.0 ' 0.55 : 0.10 0.10 Fluoride:. - 2.5 mg/m3 " .0; .... - -v. i. 6.00 ' Section III. PHYSICAL DATA : q ov, ^^ Physical Form: Boiling Temp.: Freeze-Melt Temper Vapor Pressure: , Evaporation Rate: Solid ! ^"77 ' Typical^Sleve^aalysi's^' '; - Fines . l-..-,' Pellets 1832F' -(l6boC)`;" " +200 Mesh' -T 0% ` +100 Mesh - 7% ' -r- +325 Mesh10%.+150 Mesh '- 35% : _L ' ' " ' ...Ui.i.v; .. -325 Mesh - 90%-": +200 Mesh - 70% Specific Gravity: '1.20 ' ....... ` ' Density: " 75 lb/cu ft '"'7' "Solubility In H2O": Slightly soluble Color: Tan Odor: None 'r -":c J r +325 Mesh - 98%^. Mesh' - 2% Section IV. Flashpoint _____________ FIRE AND EXPLOSION DATA I Auto-Ignition Temp. None I None Flammability Limits In Air ________________ None Lower I Upper Non Flammable Material Section V. REACTIVITY DATA Cryolite is used an an electrolyte in the production and refining of aluminum from its oxide; in ceramics; as a binder for abrasives; in electrical insulations; flux in the open hearth process; explosives; polishes. With air: None With water: See Section II With heat: See Section TV Non-corrosive 411538 0168- NO. IRQ ---- Alcoa Synthetic Cryolite ____________________________________ ______________. Section VI. HEALTH HAZARD INFORMATION j TLV 2.5 mg/m3 as P ft) Acute: Chronic: Exposure to extremely dusty conditions in the absence of a proper respirator may result in nausea and/or abdominal pains, shortness of breath, and lack of appetite. Excessive inhalation of cryolite dust for prolonged periods can result in sclerosis of the bones caused by fixation of the calcium by the fluorine. There may also be some calcification of the ligaments. The teeth may become mottled and there may be osteosclerosis and ostemalacia. The bony and ligametous changes are demonstrable by x-ray. ( Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Use dry clean up procedure. Avoid washing down with water where possible: toif minimize' fluoride contamination. Avoid excessive dusting. . .Dust'. ' used during clean up and disposal activities minimize the possibility/pfj inhalation of cryolite dust. Dispose of dry material in landfill where/leaching^^|'''- i; will not occur. This material is not considered a hazardous waste under'EPA'^Tl*"'- '."^ j, ` definitions. ` , -W EPA Hazardous Waste No. NOT regulated . . .-. Section VIII. SPECIAL PROTECTION INFORMATION ~ -..qrof.;- . ' . "Provide adequate ventilation to meet TLV requirements.. --VeilLilaLiuu must Tju, sueh- Q-hnl--rTrOfqTfflf dvint. nnmirnn+ni -'r lifTIV" '"pTi V'f'n I r-d Where respiratory protecfeioSi;^:; . is necessary, NIOSH approved respiratory protection should be used.. The:.selection of. appropriate respiratory protection (dust respirator, supplied air respirator,' , . self-contained breatiling" apparatus, etc) ~should be based upon theTactuai'Jor,`'- "'.' ' potential airborne contaminants and their concentration present'. /: / Section IX. SPECIAL PRECAUTIONS & COMMENTS Chemical substance components have been reported to the EPA office of toxic substances in accordance with the requirements of the toxic substance control act (Title 4Q CFR Part 710). D.O.T. Requirements NOT REGULATED Section X. REFERENCES ASTM No.: CAS No.: 15096-52-3 CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: Other: 411538 0169 FRO" ROBERT M. JAMES PITTSBURGH OFFICE, 6AB 9 . c~ 70 MR. A. B. McKEE ALCOA TECHNICAL CENTER - C 1981 April 22 cc: R. W. Flanagan, Pittsburgh 6AB R. L. Miller, Pittsburgh 8AB "RE: ' ALCOA MATERIAL SAFETY, DATA SHEETS /(AMSDS) f - 189 - 191 ' Ref. R. W. Flanagan's letter-to A. B. McKee of 1981 April 21 - v .:: , - . . ... . In addition to R. ,W. Flanagan's comments of 1981 April 21, the'following additionalrevisions are suggested: vvvv W?:V'c ,% v: ??;>a vV .= : /i-v 1.>,'^For ' data' sheets 189 an<l 190, under Section ;VVIII,-it is suggested -A" thaa^t-the ff^irsf"t.. osaemnt*tAennncAe. Vbae reworded to i*raeqaAd as follows: A* "Provide adequate ventilation." 2. For data sheet 191, I do not believe that lead is a Poison B. Therefore, a revision under D.O.T. requirements needs to be made. 3. For data sheet 191 under .Section VI, the 5th sentence should read "Employees", instead of "Workers"./ :. . questions ..concerning .the above, .please advise. .. aa--&-r?. :A/:.. i..\ A..t 411538 0170 S * ROBERT W. FLANAGAN PITTSBURGH OFFICE, 6AB -MR. A. B. McKEE ALCOA TECHNICAL CENTER 1981 April 21 RE: AMSDS 189 - 191 Enclosed are the revisions which Bob James and I have agreed upon for these Material Safety Data Sheets. Thanks for expediting the cryolite sheets. ROBERT VI. FLANAGAN RWFrlmn cc: R. M. James, Pittsburgh 6AB 411538 0171 For Internal Company Use O nly -- N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET .NaJE ALCOA Section I. HAZARD CHARACTERISTICS Flammable D Combustible CD Corrosive CD Explosive O Water Reactive O Radioactive D Oxidizer O Chemically Reactive MATERIAL DESCRIPTION Toxic By: CD Ingestion El Inhalation CD Absorption PRODUCT Alcoa Synthetic Cryolite (Fines) Phone No. Date: Chemical Name & Formula: Cryolite (Na^AlFg) Other Designation: Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS Cryolite ^ Loss on ignition' Free A1 0. Si02 J Fe203 % HAZARD DATA OSHA PEL 3 80 (min. Fluoride - 2.5 mg/m 8 (max.' 3-6% 0.55(max ) 0.10(max ) t Section III. PHYSICAL DATA Physical Form: Fine particulate. Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Odor: Mesh size: On 200 mesh - 0%; On 325 mesh - 10%; Through 325 mesh - 90% Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Ignition Temp. | Flammability Limits In Air J Lower I Upper Section V. REACTIVITY DATA 411538 0172 No. 189 - Alcoa Synthetic Cryolite (Fines) Section VI. HEALTH HAZARD INFORMATION TLV OSHA PEL - Fluoride - 2.5 mg/m^ Excessive inhalation of cryolite dust for prolonged periods of time can result in fluoride deposition in bones and cartilage as evidenced by X-ray changes; Excessive exposure to fluoride dust for prolonged periods can subsequently result in stiffness of joints. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate TM"|,;i ->--i,*. TqiV 1 muirrmrrr-? Where respiratory protection is necessary, NIOSH approved respiratory protection should be used. The selection of appropriate respiratory protection (dust respirator, supplied-air respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. Section IX. SPECIAL PRECAUTIONS & COMMENTS Chemical substance components have been reported to the EPA Office of Toxic Substances in accordance with the requirements of the Toxic Substances Control Act (Title 40 CFR 710). D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No.: 15096-52-3 CMA Chemical Safety Data Sheet No.: NPPA Guides NSC Data Sneets: Supplier Product Literature: : Other: 411538 0173 For Internal Company Use O nly -- N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No.J! IL&i? ALCOA Section I. HAZARD CHARACTERISTICS CD Flammable CD Combustible Corrosive CD Explosive CD Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: CD Ingestion SI Inhalation CD Absorption PRODUCT Synthetic Cryolite. (Pellets) Phone No. Date: Chemical Name & Formula: Cryolite (NajAlFg) Other Designation: Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS Cryolite Loss on ignition (water) Free A1,,0_ Si02 2 3 Fe2<)3 % HAZARD DATA OSHA PEL 3 84(min.) Fluoride -- 2.5 mg/m"' 6 (max.) 3-6% 0.55(max ) 0.10(max ) ------ - 1____________________________________ Section III. PHYSICAL DATA Physical Form: Pellets. Mesh size: +150 mesh (Tyler) 90%; Boiling Temp.: -325 mesh (Tyler) 5% Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Odor: Section IV. Flashpoint FIRE AND EXPLOSION DATA j Auto-Ignition Temp. j Flammability Limits In Air j Lower j Upper Section V. REACTIVITY DATA 411538 0174 No. 190 - Alcoa Synthetic Cryolite (Pellets) Section VI. HEALTH HAZARD INFORMATION TLV OSHA PEL - Fluoride - 2.5 mg/m3 Excessive inhalation of cryolite dust for prolonged periods of time can result in fluoride deposition in bones and cartilage as evidenced by X-ray changes. Excessive exposure to fluoride dust for prolonged periods can subsequently result in stiffness of joints. c Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Section VIII. SPECIAL PROTECTION INFORMATION ___________________ Provide adequate ventilation "- I TTr*'r~iii-f rrmar~ Where respiratory I protection is necessary, NIOSH approved respiratory protection should be used. ' The selection of appropriate respiratory protection (dust respirator,' supplied-air . respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. Section IX. SPECIAL PRECAUTIONS & COMMENTS Chemical substance components have been reported to the EPA Office of Toxic Substances in accordance with the requirements of the Toxic Substances Control Act (Title 40 CFR 710). D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No.: 15096-52-3 CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: Other: 411538 0175 For Internal Company Use O nly -- N ot To Be Distributed Outside The Company ALCOA Section 1. MATERIAL SAFETY DATA SHEET No.Jli HAZARD CHARACTERISTICS CD Flammable CD Combustible CD Corrosive CD Explosive CD Water Reactive O Radioactive O Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: 3 Ingestion SI Inhalation D Absorption PRODUCT Alcoa 807 Solder Phone No. Date: Product Name: Alcoa 807 Solder Corporate Stock No.: Manufacturer: ALCOA Section II. . INGREDIENTS Lead Bismuth Silver Tin *Beginning 2/24/80, PEL is 0.05 mg/m with an action level of 0.03 mg/m . (Certain industrial lead uses have an extended time for compliance.) Blood samp11 and analysis must: be available to every employee exposed above the action level over 30 days/year. % 80% HAZARD DATA OSHA PEL 8-hr. TWA 0.05 mg/m * (as Pb) Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: -476 ~-521F Vapor Pressure: Evaporation Rate: Specific Gravity: Density: '. "Solubility In H2O": Color; . Odor: Section IV. Flashpoint NA FIRE AND EXPLOSION DATA I Auto-Ignition Temp. NA (Flammability Limits In Air ------- | Lower | Upper I-- I -- Extinguishing Media: This is a non-flammable material; use extinguishing media which are appropriate to the surrounding fire. Lead oxide can be an oxidizing agent for combustible materials when hot. Firefighters should wear NIOSH approved self-contained breathing apparatus when this material is involved in a fire' situation. Section V. REACTIVITY DATA 411538 0176 . Alcoa 807 Solder No.J^L Section VI. HEALTH HAZARD INFORMATION | TLV TWA 0.05 .,<50 as Pb, Lead is a cumulative poison. Over a period <o time a very `small rate of`intake can reach a toxic level. Lead poisoning can produce symptoms such as headache,'nausea, cramps, dizziness, weakness, insomnia, diarrhea, and lpsAoT.appetite. Heavy1 Acute . exfinfiiiifc can icauir'in ui mmw; uuma,, and* deathv j&S&SB&frwith excessive exposure, who experience the symptoms of lead poisoning, should receive, medical care and guidance promptly. Detailed |biological specimen testing and evaluation of possible exposure conditions are required to diagnose lead poisoning;^At normal bath temperatures,^, [ vapor pressure of lead in Alcoa 807 Solder is iquite low; therefore^ airborne leadCt- ioncentrations would also be low. However, skimming or other surface, agitation yean generate airborne lead oxide. ' [RST AID: Eye and Skin Contact: Flush with water to remove; dusty gcL uiudlcai help AfS-icriTatian pmsijtt. Wash all exposed skin well with soap anid water. Inhalation: Remove from exposure. Tnl nMini11iiii1~lii 1|i Ingestion: Contact physician promptly.. Gastric lavage may be required. ' .( Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact environmental personnel. Carefully vacuum up spilled material for recovery or disposal, avoiding dusting conditions, at all stages of handling, and place in a plastic bag-lined, tightly closed container. (Damp or wet clean-up methods may be useful in suppressing dust and can be used where more effective than,vacuuming.) DISPOSAL: Follow Federal, State, and local regulations in disposing of waste; material. Depositing it in an approved landfill should be evaluated as a suitable means.of . disposal. (Filtration of all exhaust ventilation air may be required,'with-filtrate disposal added to the was tefproblemT} S W Ld r?t/S b ,/( Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation foAannt TLV'Tequivoianta. Isolate Pbusearea. Monitor lead exposure. Where respiratory protection is needed,, use NIOSh;approved respiratory protection. The selection of appropriate respiratory protection .(toxic dust raspirff&Bri fume respirator, supplied-air respirator, etc.) should be based -upon the actual or potential airborne contaminants and their concentrations, present. . ( . Wear goggles to prevent solder spatter from entering eyes. . r., See OSHA Lead Standard 1910.1025 for additional safeguards related `to lead exposures^- Section IX. SPECIAL PRECAUTIONS 8c COMMENTS j Store in closed containers in a clean area .away from combustible:materialsProtect containers from damage. Keep away from food or feed. Preveuc~agSL .diapeyoing condi- "**-*--^ |_iiiirt-'-h~iinh1rr'*p1np ohantiee and ftP** ^yfjinniii (>i in r ii r Wash thoroughly before eating or smoking after handling this material or working in its areas of use <jl storage. Do not allow eating,; drinking or tobacco use in areas of .. Ftorage-^u use of Pb. D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No.: CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: X7 Other: 411538 0177 FROM A. B. MC KEE ALCOA TECHNICAL CENTER - C TO MEMBERS, CORPORATE HAZARDOUS MATERIALS CONTROL COMMITTEE 1981 April 10 RECEIVED APR 131981 INDUSTRIAL HYGIENE RE: ALCOA MATERIAL SAFETY DATA SHEETS The Sales Department has received a request from Union Carbide for safety data sheets for two Alcoa cryolite products--fines and pellets. Bob Flanagan has submitted the attached two first-draft safety data sheets for preliminary review by the committee. Bob has asked that we expedite the completion and approval of these two sheets. For this reason, please return your comments to me by April 20th. A. B. MC KEE ABM:km Attachment cc: Members of Corporate Hazardous Materials Control Committee H. P. Brueschke, Pittsburgh 19 R. L. Byers, Pittsburgh 07 A. E. Davis, Pittsburgh 24 R. E. Edgington, Pittsburgh 22 G. C. Heise, Pittsburgh 06 R. M. James, Pittsburgh' 07 R. L. Miller, Pittsburgh 08 A. B. McKee, ATC-C R .T. Shillinger/R. L. Vezzani, Pittsburgh J. R. Stemler, ATC-C D. A. Whitfield, Pittsburgh WPH3 J. D. Yerger, Pittsburgh 18 03 Others R. W. Flanagan, Pittsburgh 07 F. S. Williams, ATC-C NOTE: I just received AMSDS #191; please include this. ALCOA 411538 0179 (cv For Internal Company Use Only -- N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No.^ ALCOA Section I. HAZARD CHARACTERISTICS Flammable 0 Combustible CH Corrosive O Explosive 0 Water Reactive 0 Oxidizer 0 Radioactive 0 Chemically Reactive MATERIAL DESCRIPTION Toxic By: 0 Ingestion Si Inhalation 0 Absorption PROOUCT Alcoa Synthetic Cryolite (Fines) Phone No. Date: Chemical Name & Formula: Cryolite (Na^AlF^) Other Designation: Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS Cryolite Loss on ignition Free A1,,0, Si02 J Fe23 % HAZARD DATA 0SHA PEL 80 (min. Fluoride - 2.5 mg/mJ 8 (max. 3-6% 0.55(max ) 0.10(max ) Section III. PHYSICAL DATA Physical Form: Fine particulate. 3oiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Odor: Mesh size: On 200 mesh - 0%; On 325 mesh - 10%; Through 325 mesh - 90% Section IV. Flashpoint FIRE AND EXPLOSION DATA | Auto-Ignition Temp. | Flammability Limits In Air | Lower | Upper Section V. REACTIVITY DATA 411538 0180- No. 189 - Alcoa Synthetic Cryolite (Fines) Section VI. HEALTH HAZARD INFORMATION TLV OSHA PEL - Fluoride - 2.5 mg/m^ Excessive inhalation of cryolite dust for prolonged periods of time can result in fluoride deposition in bones and cartilage as evidenced by X-ray changes. Excessive exposure to fluoride dust for prolonged periods can subsequently result in stiffness of joints. c Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate ventilation to meet TLV requirements. Where respiratory protection is necessary, NIOSH approved respiratory protection should be used. The selection of appropriate respiratory protection (dust respirator, supplied-air respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. Section IX. SPECIAL PRECAUTIONS & COMMENTS Chemical substance components have been reported to the EPA Office of Toxic Substances in accordance with the requirements of the Toxic Substances Control Act (Title 40 CFR 710). D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No.: 15096-52-3 CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: Other: 411530 0181 For Internal Company Use Only -- N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No. 190 ALCOA HAZARD CHARACTERISTICS CD Flammable CD Combustible Corrosive CD Explosive O Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive Toxic By: CD Ingestion (El Inhalation CD Absorption PRODUCT acoa Synthetic Cryolite (Pellets) Phone No. Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: Cryolite (NajAlFg) Other Designation: Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS Cryolite Loss on ignition (water) Free A1 0, SiC>2 % HAZARD DATA 0SHA PEL 8A(min.) Fluoride - 2.5 mg/m~' 6 (max.) 3-6% 0.55(max ) 0.10(max ) Section III. PHYSICAL DATA Physical Form: Pellets. Soiling Temp.: Freeze-Melt Temp.: Mesh size: Vapor Pressure: j Evaporation Rate: j Specific Gravity: Density: "Solubility In H2O": Color: | Odor: +150 mesh (Tyler) 90%; -325 mesh (Tyler) 5% Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Ignition Temp. J Flammability Limits In Air I Lower I Upper !Section V. 1 REACTIVITY DATA : -I o c 411538 0182 No. 190 - Alcoa Synthetic Cryolite (Pellets) t Section VI. HEALTH HAZARD INFORMATION TLV OSHA PEL - Fluoride -2.5 mg/m-* Excessive inhalation of cryolite dust for prolonged periods of time can result in fluoride deposition in bones and cartilage as evidenced by X-ray changes. Excessive exposure to fluoride dust for prolonged periods can subsequently result in stiffness of joints. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Section VIII. SPECIAL PROTECTION INFORMATION __________________ Provide adequate ventilation to meet TLV requirements. Where respiratory "] protection is necessary, NIOSH approved respiratory protection should be used. The selection of appropriate respiratory protection (dust respirator, supplied-air respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. Section IX. SPECIAL PRECAUTIONS & COMMENTS Chemical substance components have been reported to the EPA Office of Toxic Substances in accordance with the requirements of the Toxic Substances Control Act (Title 40 CFR 710). D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No.: 15096-52-3 CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: Other: 411538 0183 MATERIAL SAFETY DATA SHEET ) ALCOA HAZARD CHARACTERISTICS 0 Flammable 0 Combustible CD Corrosive Explosive O Water Reactive 0 Radioactive Oxidizer 0 Chemically Reactive Section 1. MATERIAL DESCRIPTION Toxic By: 0 Ingestion IS Inhalation O Absorption PRODUCT Alcoa 807 Solder Phone No. Date: Product Name: Alcoa 807 Solder For Internal Company Use Only -- Not To Be Distributed Outside The Company Corporate Stock No.: Manufacturer: ALCOA Section II. INGREDIENTS Lead Bismuth Silver Tin , *Beginning 2/24/80. PEL is 0.05 mg/m with an action level of 0.03 mg/mL (Certain industrial lead uses have an extended time for compliance.) Blood sampli and analysis must be available to every employee exposed above the action level over 30 days/year. HAZARD DATA OSHA PEL 8-hr. TWA 0.05 mg/m3* (as Pb) Section III. PHYSICAL DATA Physical Form: 8oiling Temp.: Freeze-Melt Temp.: Vapor Pressure: 476 - 521F Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Odor: Section IV. Flashpoint NA FIRE AND EXPLOSION DATA I Auto-Ignition Temp. I NA f Flammability Limits In Air | ----- | Lower I Upper I-- I -- Extinguishing Media: This is a non-flammable material; use extinguishing media which are appropriate to the surrounding fire. Lead oxide can be an oxidizing agent for combustible materials when hot. Firefighters should wear NIOSH approved self-contained breathing apparatus when this material is involved in a fire situation. Section V. REACTIVITY DATA 411538 0184 Alcoa 807 Solder _______________________________NO-19L______ Section VI. HEALTH HAZARD INFORMATION TLV TWA 0.05 mg/m^ (50 yg/m^) as Pb. Lead is a cumulative poison. Over a period of time a very small rate of intake can reach a toxic level. Lead poisoning can produce symptoms such as headache, nausea, cramps, dizziness, weakness, insomnia, diarrhea, and loss of appetite. Heavy acute exposure can result in stupor, coma, and death. Workers with excessive exposure, who experience the symptoms of lead poisoning, should receive medical care and guidance promptly. Detailed biological specimen testing and evaluation of possible exposure conditions are required to diagnose lead poisoning. At normal bath temperatures, vapor pressure of lead in Alcoa 807 Solder is quite low; therefore, airborne lead concentrations would also be low. However, skimming or other surface agitation can generate airborne lead oxide. FIRST AID: Eye and Skin Contact: Flush with water to remove dust; get medical help if irritation persists. Wash all exposed skin well with soap and water. Inhalation: Remove from exposure. Get medical help. Ingestion: Contact physician promptly. Gastric lavage may be required. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact environmental personnel. Carefully vacuum up spilled material for recovery or disposal, avoiding dusting conditions, at all stages of handling, and place in a plastic bag-lined, tightly closed container. (Damp or wet clean--up methods may be useful in suppressing dust and can be used where more effective than vacuuming.) DISPOSAL: Follow Federal, State, and local regulations in disposing of -waste material. Depositing it in an approved landfill should be evaluated as a suitable means of disposal. (Filtration of all exhaust ventilation air may be required, with filtrate disposal added to the waste problem.) Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation to meet TLV requirements.. Isolate Pb use area. Monitor lead exposure. Where respiratory protection is needed, use NIOSH approved respiratory protection. The selection of appropriate respiratory protection (toxic dust respirator, fume respirator, supplied-air respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. TWear goggles to prevent solder spatter from entering eyes. ^See 0SHA Lead Standard 1910.1025 for additional safeguards related to lead exposures. c Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in closed containers in a clean area away from combustible materials. Protect containers from damage. Keep away from food or feed. Prevent dust dispersing condi tions and breathing of dust. Follow good housekeeping practice and good hygienic practice. Wash thoroughly before eating or smoking after handling this material or working in its areas of use or storage. Do not allow eating, drinking or tobacco use in areas of storage or use of Pb. D.O.T. Requirements POISON B Section X. REFERENCES ASTM No.: CAS No.: CMA Che~:cal Safety Data Sheet No.: N F PA Gu z^s NSC Data Sheets: Supplier P'oduct Literature: Other: 411538 0185 ROBERT W. FLANAGAN PITTSBURGH OFFICE, 6AB ! i MR. A. B. McKEE ALCOA TECHNICAL CENTER 1981 April 02 cc: R. M. James, Pittsburgh RE: ALCOA MATERIAL SAFETY DATA SHEET ON CRYOLITE Enclosed are two material safety data sheets on Alcoa Cryolite. Since these are being requested by a customer. Union Carbide, I think that we should move them through the committee as quickly as possible. Also, you might consider sending them to some of the technical experts at the Tech Center, for information on Sections III -- V with which I am not really familiar.. ROBERT W. FLANAGAN RWF:lmn Enc. 411538 0186 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No. UJ ALCOA Section I. HAZARD CHARACTERISTICS CD Flammable CD Combustible CD Corrosive CD Explosive CD Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: CD Ingestion SfInhalation CD Absorption PRODUCT Alcoa Synthetic Cryolite (Pellets) Phone No. Date: Chemical Name & Formula: Cryolite (Na3AlFg) Other Designation: Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS Cryolite Loss on ignition (water) Free Alo0_ Si02 2 3 Fe23 % HAZARD DATA OSHA PEL - 84(min.) Fluoride - 2.5 mg/in 6 (max.) 3-6% 0.55(max ) 0.10(max ) Section III. PHYSICAL DATA Physical Form: Pellets. Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Mesh size: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Odor: +150 mesh (Tyler) 90%; -325 mesh (Tyler) 5% Section IV. Flashpoint FIRE AND EXPLOSION DATA Auto-Ignition Temp. Flammability Limits In Air Lower Upper Section V. REACTIVITY DATA 411538 0187 No.. Section VI. HEALTH HAZARD INFORMATION J TLV OSHA PEL - Fluoride - 2.5 mg/m3 Excessive inhalation of cryolite dust for prolonged periods of time can result in fluoride deposition in bones and cartilage as evidenced by X-ray changes. Excessive exposure to fluoride dust for prolonged periods can subsequently result in stiffness of joints. Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Provide adequate ventilation to meet TLV requirements. Where respiratory protection is necessary, NIOSH approved respiratory protection should be used. The selection of appropriate respiratory protection (dust respirator, supplied-air respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. Section VIII. SPECIAL PROTECTION INFORMATION Chemical substance components have been reported to the EPA Office of Toxic Substances in accordance with the requirements of the Toxic Substances Control Act (Title 40 CFR 710). Section IX. SPECIAL PRECAUTIONS & COMMENTS D. O. T. Requirements Section X. REFERENCES ASTM No.. CAS No.: 15096-52-3 CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: Other: 411538 0188 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No. L2J ALCOA HAZARD CHARACTERISTICS Flammable 0 Combustible 0 Corrosive 0 Explosive O Water Reactive 0 Radioactive O Oxidizer O Chemically Reactive Toxic By: 0 ingestion El Inhalation O Absorption PRODUCT Alcoa Synthetic Cryolite (Fines) Phone No. Date: Section l. MATERIAL DESCRIPTION Chemical Name & Formula: Cryolite (Na^AlF^) Other Designation: Sodium Aluminum Fluoride Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS Cryolite Loss on ignition Free A1.0. Si02 2 3 Fe23 % 80. (min. 8 (max. 3-6% 0.55(max ) 0.10(max ) HAZARD DATA OSHA PEL Fluoride - 2.5 mg/ni - - Section III. PHYSICAL DATA Physical Form: Fine particulate. Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Odor: Mesh size: On 200 mesh - 0Z; On 325 mesh - 10%; Through 3.25 mesh -- 90% Section IV. Flashpoint FIRE AND EXPLOSION DATA | Auto-Ignition Temp. jFlammability Limits In Air | Lower I Upper Section V. REACTIVITY DATA 411538 0189 No.. Section VI. HEALTH HAZARD INFORMATION . TLVOSHA PEL - Fluoride - 2.5 mg/m3 Excessive inhalation of cryolite dust for prolonged periods of time can result in fluoride deposition in bones and cartilage as evidenced by X-ray changes. Excessive exposure to fluoride dust for prolonged periods can subsequently result in stiffness of joints. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate ventilation to meet TLV requirements. Where respiratory protection is necessary, NIOSH approved respiratory protection should be used. The selection of appropriate respiratory protection (dust respirator, supplied-air respirator, etc.) should be based upon the actual or potential airborne contaminants and their concentrations present. Section IX. SPECIAL PRECAUTIONS & COMMENTS Chemical substance components have been reported to the EPA Office of Toxic Substances in accordance with the requirements of the Toxic Substances Control Act (Title 40 CFR 710). D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No.: 15096-52-3 CMA Chemical Safety Data Sheet No.: N FPA Guides NSC Data Sheets: Supplier Product Literature: Other: 411538 0190 ' // ft) 1978 Collection or ms MATERIAL SAFETY DATA SHEETS ALPHABETICAL INDEX OF MATERIALS L-" USDS# KSDSJ :vrr5i ACCELERATOR #4------------------------------ 10018 ASTK C53. C295 --........... 39 Blucfitone-------------------- ----------- ---- Accelerator for Urethane Enaoel 1115 B13------------------------- 375 Blue Vitriol ----------------------------------- 23 Acetic Acid, Glacial ------------------ 327 0235 ----------------------- 334 285-------------------------- 327A Acetone------------------------------------------ -- 300 Acetylene----------- ----------------------------403 Acid Anhydride, Liquid, Epoxy 0303 ----------------------- 0304 ----------------0329 ..................... 0330 ----------------- 330 337 300 320 DOROL* Solvent V.KAP .'.aphtha ?*V- 3=1 DR-123 PRIMER--------- --------- ------------- 1125; Brazing Alloy (Ag/Cd/Zn/Cu) ----- t: Brazing Flux, A^id Fluoride ----- 1 :t- Curing Agent ------------------------------ 10918 D331............................ 319 BRULIH 815 MX--------------------- --------- - 1150 Acrylate Spray Costing --------------- 1059 ACR7LIC ADHESIVE Q, Part* A & B 1001A,! 0343 ----------------------- 0362 32: 317 1,4-Butar.edicarboxylic Arid----- 420 Acrylonitrile (Monomer)------- --- 381 ACTIR0N NX-3---------------------------------- 378 0363 ----------------------- 0364----------------- 332 313 1,3-Sutar.ediol ------------------------------Butanol, 1-Butanol cr Adhesive, Epoxy, Parts A A 9 -- 1172 0456 ----------------------- 3 Adhesive, Sealant, RTV-102 ------- 1142 0458----------------------- 43 Butartone or 2-Eutnnons _ 373 Adhesive (Polyacrylate and D484 ----------------------- 334, 2-Hutoxyethanol ----------------------------- 320 Monomer, Part 1 of 2)------- -- 1150 33I`A,B 2-(2'-Butoxyethoxy) Eth/1 Adipic Acid------------------------------------ 400 0538 ----------------------- 43 Acetate --------------------------------------- 355 Aerosol Spray, Acrylate Coating 1059 D578-D581 -------------- 46 n-Dutyl Acetate cr Silicone-------------1164 D500, Class B, 6% Cobalt - 363 Butyl Acetate----------------------------- 333 A1R2MSIVE POWDER /I ---------------- 7000 AIPCOSIL 45, Brazing Alloy ------- 41 Alcohol-Resin Flux ---------- 103? Alkaline Cleaner, Liquid ----------- 115ft, n. 24 J Lead -- 38 0 0605 ------------------------- 42 M o607 ----------------------- 2 \ 0740 ----------------------- 302 ji-Sutyl Alcohol--------------- ------------- 335 n-Sulyl Alcohol, Butyl Alcohol or 1-Dutyl Alcohol-------------------------337 Butyl CAP.BI70L------------------------------- 322 1159, 0770 ------------------------ 324 Butyl CARBITOL Acetate --------------- 358 1160 l D835, O&36----------------------------- 316 Butyl CELLCSOLVE--------------------------- 320 Alkaline Cleaning Agent -- 1090 Altcaline Etch (HAVlLAND SO 680 1041 Alkaline Hot Tank Cleaner, 0841 -----------------------0843, DS45, D846 D1152 --------------------- ------ 317 .-- 318 .-- 354 Butyl CIOXITOL ---------1,3-Butylene Glycol (or -Butylene Gly< -----------322 Concentrate ------------------------ 1109, 01153 --------------------- 1,3-Butylv-ne Glycol 1 1113 01719 ---------------------- -- - 3v3 acrylate ------------------- ---------- 1136 Alkaline Paint Booth Water Wash, Concentrate-------------------------------- 1112 D1763> Type I, Grade I: Class I -------------- --- 3353 1-butyl Ethanoale -- Butyl Ethyl k'etone -- ............. 333 -----------305 Alkaline Paint Booth Purging Class V ------------- ------ 335 Butyl OXITOL -------------- -----------320 Solution, Concentrate ------------- 1114 01786 ---------------------------------------- 331 t-Butyl Perbensoate Alkaline Steals Clean Compound, D1835 ---------------------------------------------363060 (or Peroxybenzcate -----------406 Liquid------------------------------------------- 1111 02116-------------------------------------- 1010 Butyric Alcohol----- ---------------------- 337 ALKAMEX Insulating Varnish 02323 -------------------------------------- 405 (9522,9637)--------------------------------- 1163 D2359 -------------------------------------- 315 C5 Kono-Alurair.ua Phosphate ---- 1' ALK-TRI ----- ---------------------------------------312 02373 -------------------------------------- 360 CAB05IL li-5, M-5, M-7-------------------- 1064 Allylchloclde-------------------------------- 374 02439 -------------------------------------- 355 Cadniua Anodes, Cacmicr Hotel - 23 ^Aloffi^Powder-------------------^ 1000 V ^Aluminum Phosphate C5-------------- -- 11 02472 -------------------------------------- 27 02627 -------------------------------------- 353 Calcium Carbonate (Calcite) ----- 1082 Calcium Hydrate (Hydroxide) --- 39 ALPHA 413-F THINKER------- ------------- 1077 02693 -------------------------------------- 323 Calcium Oxide (Calx) ------------------- 22 611 FLUX-------------------------------1080 02026 , 02827 ------------------------- 351 Carbolic Acid--------------------------------- 355 BIO THINNER ---------------------- 10?8 02916 -------------------------------------- 356 Carbor. Disulfide----------------------- -- 350 815 FLUX------------------------------ 1079 03055 -------------------------------------- 339 Carbon Monoxide --------------------- 35 MELROSE 611 FLUX---------------1080 03t26 -------------------------------------- 338 Carbor. Tetrachloride---------- ---- 410 Aminobcnzene ---------------------------------- 407 03128 -------------------------------------- 352 CARBOWAX 6000 ---------------------------------- 3S* bis(p-Afllnophenyl)methane --------- 346 D3254 -------------------------------------- 407 CARCOWAX Hand Solution -------- Vjb7 N-Aainoethyl Piperazine ------------- 403 03437 ----------------- --------------------- 353 4-Cirboxyphtnalic Anhydride --- 330 Ammonia, Anhydrous ----------------------- 1 03506-------------------------------------- 310 CAS A XXX'XXX-XX-E (ACS fernat) Ar-itoniua Chloride------------------------ 21 Ammonium Peroxydisulfate------- -- 33 Ammonium Persulfate------------------- 33 AK0C0 TMA---------------------------------------- 330 AMSC0 Rubber Solvent------------------ 371 AMSCO Special Kaphtholite --------- 391 n-A.-ayl Methyl Ketone-------------------302 AH (Acrylonitrile)----------- ------- - 381 ANCAMINE T-1 ----------------------------------- 1072B Anhydrotrimellitic Acid ------------- 330 Anhydrous Acetic Acid ---------------327 Anhydrous Anson la --------- ------ 1 Aniline ------- ----- --------------- -- 407 AKSI/AHS A5.8, Brazing Alloys: 3Ag-l-------------------------------------------- 41 Antimony Trloxi.de ---------------------- 28 Antimony (III) Oxide ------------------2ft . Antimony Sesquioxlde --------- - 23 Aqua Fortis ----------------- ----------------- - 7 A RALDUS 6005 --------------------------------- 3358 6010 --------------------------------- 335B 6084 ----------------- ---------------335 APKLCNE P--113-------------------------------- 314 ARMAFLEX PIPE INSUIATIO* ----------- 133B Mt.MSTROKG 520 ADHESIVE ----------------- 1133A Aromatic 100 ------------------------------ 1061 Aros.?tic 150 ----------------------------------- 1051A A.iheslos Tope (Crysollte)---------15 ASHLAND 190/P-3224 ----------------------- 1073 Rubber Solvent ----------- 371 A.v;-; P350.................. ................... ........... 17 Rfi-.n --------------------------------------- 23 V':r.- . 1)1,<)lI, H495 -.............- n C5, f:L, C16, C49, C53, C415 and C8?8 --- 22 03735 -------------------------------------- 391 ASTRO 3059, Parts A A B------------- 1072A, 3104 -------------------------------------- 1075 SPECIAL 3044 ----------------------- 1029 AZ-111 PHOTO RESIST --------------------- 1014 AZ-1112A REMOVER ------------------------ - 1015 BAB 3100 -------------------------------------- 1092 BAKELITE ERL 4221 ------------------------- 3ft6 BARC0 BONO MB-100X and KB-12 -- 1177 Barium Hydrate -----------------------------40 Barium Hydroxide (Octahydrate)- 40 Barium Octahydrate ----------------------- 40 Benzene (Benzol)------------------ -------316 Benzenamine -------------------- --...... 407 Benzenecarboxylic Acid --------------- 402 1,4-Benzenedicarboxylic Acxd, Dimethyl Ester---------------------------404 Benzoic Acid-----------------------------------402 Benzyldimethylomine ------- -------- 326 9EP7LCO #10------------------------- -- 32 Btphenyl-Biphenyloxlde, Eutectic Mixture ----------------- -- 1076 N, M'-bir (2-A=ii noethyl }eth/lersedlaraine ---------- ------- - 1035 Bisphenol A ---------------------- -- 369 Bisphero! A Digtycirtyl Ether -- 3353 BIWAX I4>~f (Prrt U)--------------------- 10912 !*?-R (Part A)--------------------- 1C9A BLAC*'-PrP---------------------------------------- 4 17 BL/OO-TILV.'t---------------------------- ------- 311 nr.AC9 THI -............. .................. -........... J12 W.ACO-7I5CN Tr ......................... -............3*4 HLAVKPOLA .SOLVENT------------------------ 106 3 Bl.Ui; G'JUi---------------------------------------- 1 160 000 050 000 --------000 056 235 ---------00C OfO 297 ---------000 052 533 ---------000 064 175 ---------OOO 064 197 --------000 055 850 --------0C0 067 561 -------000 067 630 -------000 067 641 --------OCO 067 663 -------000 070 553 ---------000 07 1 353---------000 071 432 -------- 000 071 556 -------00C 074 862 ---------000 074 673 --------000 074 986 000 075 01b --------000 071 092 -------------------------000 075 127 000 075 150 OCO 075 456 OCO 073 vy 000 0T5 718 000 >',77 7 30 00.9 077 7c 1 ----------------- IWO 073 07 1----------- (K2 O'..3 765 ---------- ---------------- -- oec B31-------- 000 GOT l-* 0 7U 33------------------ 16 000 'HO 057 000 OdP 197 350 410 343 407 361 327 402 354 324 300 315 106ft 337 316 311 *C3 373 380 382 310 390 350 337 309 30L 34o 4-14 V.7 .O'* 3-)5 ?'` I CtHER/Ulf^LECTRIt 411538 0104 Reissued 1979 HSUS* KSPSP USDS# CAS B CAS * Cresyl Diphenyl Phosphete ------- -- 10*1 000 090 722 ----------------------------- 378 000 095 501 358 000 098on ------------ *13 000 098 8?8.............. .................-- 395 000 100 *1*--------------------- 385 000 too 425 ------------------------------ 351 000 101 020 -------------------------------- *11 000 101 1**------------------------------ 372 000 101 779 ------------------------------ 3*6 COO 103 117--------------------------------3*5 000 103 833 ------------------------------ 326 000 10* 767------------------------------ .367 000 10635*----------------------------- 306 000 107051 ----------------------------- 37* 000 107062 ----------------------------- 359 000 107131 ----------------------------- 381 000 107153 ----------------------------- 325 000 107211----------------------------- 323 000 107879 ----------------------------- 305 000 107860 ----------------------------- 362 000 108101 ----------------------------- 30* 007 66* 393 -------------------------------- 6 007 66* *17 ................. ..................... 1 007 66* 939 ---------- --------- ----------- 9 007 697 372 ---------------------- --------- 7 007 705 OSO-------------------------------- 19 007 722 8*1 --------------------------------**A,B 007 723 1*0 -------------------------------- 25 007 727 5*0 -------------------------------- 33 007 758 998 -------------------------------- 29 007 791 200 -------------------------------- 36 KX8 006 6*2 -------------------------------- 375 008 005 206 -------------------------------- 387 008 052 *13 ------------ ------------------ 33*. 33** 010 023 156-------------------------------- 3* 010 0*3 353 -------------------------------- * 010 101 970 -------------------------------- 37 010 102 *40 -------------------------------- *7 012 125 029 -------------------------------- 21 013 *78 007 -------------- ------------------ 20 016 893 859 -------------------------------- 31 Crysotile Asbestos ------------------- -- 15 Cu-Co-Be Alloy(0.*-0.75 Be) - 3? Cumene (Cuaol) 3^5 Cupricin----- ------------------------------------- 12 Cupric Sulfate Pentahydrate --- 29 Cuprous Cyanide ---------------------------- 12 Curing Agent for Epoxy, Polyamide---------------------------------- - 39* Curing Agent for 2-Part RTV Silicone Rubber ------------------------- 1007 Cutting Oil------------------------------------- 1161, 1162 Cutting Oil, Thread------------------------ 1099 CW-3*0-1------------------------------------------- 11*7 CT 179 Epoxide------------------------------- 386 Cycloaliphatic Epoxy Resin ------- 336 Cyclohexane ------------ ----------------------389 Cyclohexanone ----- ----------------------- -- 301 Cyclopentadleoe Dimer ----------- ----- 3*9 Cyanoethylene------- ----------------------- 381 Cyclotetramethylene Oxide ---- 379 ( V 000 108883 ----------------------------- 3*7 017 19* 002 -------------------------------- *0 Denatured Spirits (Ethanol) ----- 1073 000 108907 ----------------------------- 366 000 t059*1 ---------------------------- 301 000 108952 ---------------------------- 355 0C0 10986*---------------------------- 352 025 013 15*------------- ------------------ 336 025 13* 218 -------------------------------- 1062 026 *** 72*-------------------------------- 378 DER 330 --------------------------------------------- 335B DER 331 --------------------------------------------- 335B DER 66*--------------------------------------------- 335 DETA (Diethylenetriamine) ---- 103* 000 109999 ---------------------------- 379 000 110190 ----------------------------- 396 000 110*30 ----------------------------- 302 000 1105*3 ---------------------------- 397 000 110805 ---------------------------- 319 000 110827 ---------------------------- 389 050 922 297 -------------------------------- 1130 Catalyst Powder for Urethane Foam--------------------------- ------------------- 1168 Caulking Copd, Polyurethane-based, Moisture Cure--------------------------- 1100 Caustic Baryta---------------------- ----- -- *0 Detergent Solution, Alcoholic, with Lanolin Derivative ------- 1088 Detergent Solution, Aqueous ----- 1093 Detergent Solution, Hydrocarbon Solvent----------------------------------------- 1092 Developer System, Aqueous --------- 10*9 000 110861 -----------------------------*05 000 no918---------------------------- 356 Lime-----------------------------------39 Potash ------------------------------ 2 (6 Part) (A to F) Diacetone Alcohol--------------------- 353 000 111159----------------------------- 321 000 111*00----------------------------- 103* Soda---------------------------------- 3 Soda, Liquid (50$) ------- 3A DlALA A and AX Oils--------------------- 393 1,8-Diaaino-3,6-diazooctane ----- 1935 000 111762-----------------------------320 CDA No. 820 ------------------------------------- 32 , -Diaminodiethylamine ----------- 1034 000 1122*3 ----------------------------- 1035 000 1123*5 ----------------------------- 322 000 115106 ----------------------------- 3*2 CELL0SI2E, Type W? and QP --------- *01 CELLQSOLVE Acetate ---------------------- 321 CELLOSOLVB Solvent ----------------------- 319 *,* *-Diamincdipbenylsulfone (DDS or DADPS)------------------------------ 1036 1.2-Diaainoethane ----------- -- 325 000 115866 ---------------------------- 333 Chalk------------------------------------------------ 1082 Diamaonlum Peroxydlsulfate ------- 33 000 120616 -----------------------------*0* Chinese White------------------------------- *5 Dianilinomethane --------------------------- 3*6 000 121**8 ----------------------------- 392 Chlorendic Anhydride -------- -------- 339 o-Dichioroher.zene ------ --------------- 358 000 121697 ----------------------------- 3*7 000 123*22 ----------------------------- 353 Chlorinated Hydrocarbon, Proprietary Mixture ----------------- 1131 Dichlorodifluoromethane ------------- 308 1.2-Dlchloroethane ----------------------- 359 r 000 12386*----------------------------- 338 000 123 9H------------.----------------- *12 Chlorinated Paraffin, Liquid -- 11*9 Chlorobenzene (Chlorobenzol) -- 366 Dichloromethane ----------------------------- 310 Dlcyclopentadiene ------------------------- 3*0 V 000 12*0*9 -----------------------------*00 000 12*17*----------------------------- 368 Chlorodlfluorooethane ----------------- 307 Chloroethene (Chloroethyler.e) - 382 DIELEKTR0L I----------------------------------- 1051 DIELECTROL II--------------------------------- 1052 000 12718*----------------------------- 313 Chloroform----------- --------------------------- 315 Diethylenedioxide ------------------- *12 000 1*0318 ----------------------------- *08 Chloroaethane ----------------------------- 373 Diethylene Clycol n-Butyl I OCO 1**627 ----------------------------- 328 COO 151508 -----------------------------13 3-Chloroprofylene or 3-Chloro-l-propene --------------- 37* Ether------------------- ~----------------------- 322 Diethylene Clycol Monobutyl 000 *97198 ----------------------------- *8 CHLOROTHENS NU and VC----------------- 311 Ether--------------------------------------------- 322 000 5*08*1-----------------------------383 CHL0R0WAX-40 and 100 (liquid) - 11*9 Diethylene Glycol Monobutyl 000 5**923 ----------------------------- 12 Chromate, Zinc, Basic ----------------- 1130 Ether Acetate-------------------- ------ 368 000 552307 ----------------------------- 330 Chromic Acid, Solid-------------- ---- 5 Diethylene Triamine --------------- 103* 000 579668 ----------------------------- 3*8 Chromic Anhydride ------- ----------------- 5 N,M-Dlethyl Ethanamine ---------------. 393 000 58*8*9-----------------------------331 Chromium Compounds (ELECTRO- Diethyl Ether--------------------------------- 3*3 I 000 61**59 ----------------------------- *06 000 630080 ------------------------------ 35 BRITE 2-200)------------------------------- 1155 Chromium (VI) Oxide ----- ------------- 5 (Diethylaaino) Benzene 3*9 N,N-Diethylaniline ----------------------- 3*8 Chromium Trioxide ------------------------- 5 DIFFERENTIATED KLARIFIACT--------- 1020 001 305 620 ------------------------------- 39 CIK CLEAN 30 ----------------------------------- 1090 Diglycidyl Bisphenol-A Ether -- 335B 001 305783 ----------------------------- 22 Cleaner, Alkaline Soak Dlacthacrylate Ester of 1,3- 001 3096**----------------------------- 28 (CM-15*-XTX) ------------------------------- 1135 Butanedlol -- ------- --------- } 106 001 310027 ----------------------------- 31 Cleaning Agent, Alkaline ----------- 1090 (Dimethylaalno) Benzene ---------- 3*7 001 370583 -----------------------------2 Cleaning Agent, Aqueous, -Dimethylaainotoluene----- 326 001 310732 -----------------------------3 Alkaline----------------------------------------- 1096 N,N-Dimethyl*nlllne ............. ............ 3*7 001 37*132 ----------------------------- *5 Cleaning Compound, Mineral Diaethylbenzene--------------- ----------- 318 001 317368 ----------------------------- 33 Spirits ------------------------------------------ 1095 N,N-Dlmethylbenzylaaine 326 001 317653 ----------------------------- 1082 Cleaning Powder, Alkaline --------- 1167 Dimethyl Carbinol --- --------- 32* 001 319739 ----------------------------- 336 CLE'.R VARNISH 2609 ----------------------- 116* Dimethyl Ether------- ------------ ------- 3*2 001 319773 -----------------------------*09 CLEaRTEX 120 Cutting Oil ----------- 1162 Dimethyl Ketone --------------- ----------- 300 001 330207 ----------------------------- 318 CH-15*-XTX, Alkaline Soak Dimethyl -Phthalate ------- --------- *0* 001 330785 ----------------------------- 332 Cleaner ---------------------------------- 1135 Dimethyl Silicone Fluid ------------ 3*9 CQ1 333820----------------------------- 5 CoatLng Powder, Epoxy ----------------- 1179 Dimethyl Sulfate (DMS) --------------- 3a* 001 33323*----------------------------- 329 Cobalt Nsphthenate Solution --- 363 Dimethyl Terephthalate --------------- *9* 001 6/5 5*3 -......................... --- 335 COBEHN SPRAT-CLEAN Solvent ------- 315' Dinitrogen Tetroxlde----------------- -- *7 COMPOUNDERS WAX IE-367 --------------- 113# 1 ,*-Cioxane------- ------------------------------ *12 00? 55162*----------------------------- 27 CONAP S-6 Solvent-------------------------317 Diphenyl-Dlphenyloxide, 007 *39-976 ------------- -------------- ?6 CONAP,. 1155, Parts A & B------- -- 100*A.B Eutectic Mixture ----------------------- 1076 007 **00>9----------------------------- 1118 CoNATHANE CE-H55, Parts A & B- 100*A,B *,*'-Diphenylnethane Diiso 097 ':`0V*q ----------------------------- 23 Conformal Coating, 1066, cyanate ----- ----- ------------- ---------------- 1195 00/ **0 0/7....................... -.............. 17 Urethane Solution ------------ --- 1178 Disodiua Kcxiflooro3ilicatc ----- 31 007 *8* ------------------------------ 1* Copolvner (Hcxafluoropropyle.-e- DMP-30----------------------- -------------------------378 00/ 6015'*9--------------------------- *3 Vinyl i'll r.*? Fluoride)------------- 1107 D0LPH CK-3*C-t------------------------------- 11*7 00/ 66 IV/ -.....................-- 18 097 6*7010 ....................................... 30, Copper Cy<n'.do---------------- ------- ----- 12 Copper (II) Sulfate-------------- ----- 29 DQLPH T-200X (xylene)----------------- m3 DQWAN0L DB--------------------------------------- 3?? ( 30A C0K.U. KO-TAKN...........-.....................-- 10*3 ED------------------------------3?u 907 66* 38? ............ --................ 8 Crcuol --................................................. *09 GENERAL p ELECTRIC *Sup*r!'od"5 is:^ r 411538 0105 HSDS# DOWAKOL E--------------------------------------319 EX--------------------------------------352 DOVCLENE Wit------------------------ --------- - 311 DOW CORNING CP-77 VARNISH----------- 1 i71 DOW CORKING 200 ---------------------------- 3"9 56l.................................. 3"9 DOW CORNING 1090Varnish ------------- 11&9 DOVTHERM A -------------------------------------- 1076 DOW Vinyltoluene. Grades T12 and T50 -------------------------------- 336 DRAKE Special VK4P 2*29----------------- 391 Duplicating Toners (XEROX) ---- 1023 DUPOST Y-469-D PIGMENT --------------- 1124 DURITE LD 5102------------------------------ 1103 Dust, Wood--------- ---------------------- 376 dykem layout fluids----------------------- 115* DYKEK REMOVER AND THINNER--------- 1153 EAGLE #20 (PbO)---------------------------- 33 EASY-FLO AS, Brazing Alloy------- *1 Electrical Insulating Oil --------- 393 ELECTRO-B3ITE KAZ-32------------------- 11 &6 ELECTRO-BRITE Z-200 --------------------- 1155 Emulsifier (MAKON KF-5) Alkoxylated Alkanolaaide-type 1122 EMTAL A2 and 500 -------------------------- 42 Enaoel, Alkyd Resin, Green (Exempt Solvent) (Deere & Co. JDH F2A2)---------------------------------------1174 ENSTRIP A----- r----------------------------------- 1145 Eplchlorohydrin/Bisphenol A-type Diepoxide Resin, Unmodified: Liquid, Epoxy Equiv. Wt. 175-195 -------------------------------- 3353 Solid, Epoxy Equiv. Vt. 900-1000 ------------------------------ 335 Liquid, Solution ---------------------- 1123 EPI-CURE 856 ---------------------------------- 107 A EPI-REZ 509 ------------------------------------ 335B EPI-REZ 510 ------------------------------------ 3353 335 1101 EPON Curing Agent D -------------------- 10273 EPON Curing Agents V-15, V-25, V-40---------------------------------------------- 39 335B 335 1128 335B 335B 335 EPORAL---------------------------------------------- 1036 Ep.oxy Adhesive, 2-part, Solventless--------- ---------------------- 1177 Epoxy Bond Coat, #946---------------- 1129 Epoxy Curing Agent, Liquid: Acid Anhydride Type-----------------1101 Asido-Aaine Type----- ----------------- 107A Polyamide Type---------------------------- 39A 3A-Epoxycyclohexylaethyl-3,A- epoxycyclohexylcarbcxylate -- 366 Epoxy Putty (ASTRO 3069)------------ 1072AAB Epoxy Resin: Asbestos-Filled Paste ------------- 1027 Coating Powder with curing agent----------------- 1179 Cycloaliphatic, Liquid ----------- 386 Filled -------------------------------------- 1027A Hydrated Alumina-Filled Liquid-------------------------------------- 1091A Liquid and Curing Agent (2-part)------------------------ 1181 Liquid, Dyed Green(GE 2PV-32) 1089 Liquid, w/Hardner --------- 1025. 1026 Modified, Film Fora vith Curing Agent----- ---------------------1126B Modified, Solution of ------------- 1125A Solution-------------------------------------- 1129, Epoxy Resin, Unmodified (Epi- 1129 chlorohydrln/Btophenol A-Type): Liquid, Epoxy Equivalent Vt. 175-195 ........ .............................. 3353 liquid. Solution ----------------- 1128 Solid, Epoxy Equivalent Wt. 90C-1000 -................-..............- 335 EPOXY VARNISH 7'I0?J-------------------- 1026 Epoxy Varnish, Aaido-Anin'.* Hurdner, Solvcntlesn --------------- 1075 FPL ..?2I ...................................... 386 USDS# 1,2-Ethanediamine 325 328 Ethanoic Acid 323 327 361 Ethanol, Denatured 1073 312 33 343 319 Ethyl Acetone -----------------------------Ethyl Alcohol------- ---------------------Ethyl Alcohol, Denatured -------Ethyl Benzene (Ethyl Benzol) Ethyl Butyl Ketone or 321 305 361 1073 385 Ethyl n-Butyl Ketone -------- ------- 305 Ethylene/Acrylic Copolymer, Elastomeric------- ------------------ 1104 Ethylenediamine------- --------------Ethylene Bichloride ------------- Ethylene Glycol ------------------------Ethylene Clycol Ethers: 325 359 323 n-Butyl (or Monobutyl) Ether 320 Ethyl (or Monoethyl) Ether -- 319 Ethyl Ether Acetate----------------- 321 Methyl (or Konoeethyl) Ether 352 .Ethylene Tetrachloride --------------- 313 Ethylene Trichloride ------------------- 312 Ethyl Ether------------------------------------ 3A3 2-Ethylhexanol (2-Ethyl-1- hexanol)------------------------------------ 367 2-Ethylhexyl Acrylate --------------- 3A5 Ethylhexyl Alcohol ----------------------- 367 Ethyl Methyl Ketone--------------------- 303 Ethyl Oxide--------------- :-------------------- 3A3 Ethyne-------------------------------------------- -- 403 EVANS 7050 HOT MELT-------------------- 1097 EXXON Aromatic #100 -------------------- 1061 #150 --------------------- 106U VMAP Naphtha (Rule 66 Exempt) --------- 391 FACT0QUENCH 74 ------------------------------- 1067 FEP---------------------------------------------------- 1010 Ferric Chloride 42Ee --------------- 19 FERRO Ndphthenate 6$ Cobalt --- 363 24* Lead --------- 33 Fibrous Glass (Fiberglass) ------- 45 Film, Adhesive, Modified Epcxv Resin with Curing Agent ------- 1126B FLEXISEAL, 2-?art Polysulfide Sealant ---------------------------------------- 1102A, 1102B Flour, Wood ------ --------------------------- 376 Flowers of Zinc--------------------------- A5 Fluorinated Ethylene Propylene Copolymer (FEP)----------- ------- --- 1010 Fluoroelastoser Gum, Unfilled - 1107 FL0OR0LUBE OIL-------------------------------388 FLU0R0LU8E S-30 ----------------------------- 388 Fluorotrichlorcoethane ------------- - 309 Flux, Activated-Rosin (KESTER 197)------------------------------- 1022 Flux, ALPHA 815---------------------------- 1079 Flux, ALPHA MELROSE 611------------- 1080 FW-123-5 ADHESIVE FILM --------------- 1126B FM 203W Catalyst Powder------------- 1168 formaldehyde, Aqueous ---------- 360 Formalin (37-50*) ------------------------- 360 Forsamide------- ------------------------ ---- 390 F0RKVAR 12/85 and 85T, 5/95E, 6/95S, 15/95E and 95SS----------- 399 FORKVAR/Phenolic Wire Enamel -- 1040 FREON 11------------------------------------------ 309 12------------------------------------------ 308 22 ------------------------------------------- 307 113---------------------------------------- 314 HF------------------------------------------ 309 TF-------------------------------------------314 FREUND 6060 CLUE-------------------------- 1134 FDIGEN 113 TR-T......................... .........314 2-Furancartonal -------------------------413 ?-?umlrtchyde -- ------- --------------- 413 Furfural ------------------------------------------ 413 FTRTJEL 660------------------------------------ 1175 GALAXY THREAD CUTTING OILS-------109'> GL MU-124 ---------------------------------------- !0:,5 CE RTV-102 (On*: Cccponent)------- 1 1-12 C'J RTV-577, Polymer------------ ----------- tf*?6 *979Peiss-jed - June MSD5# CE RTV-98 11 , Curing ig-r.i--------- :o07 CE SF-96. SF-97 ----------------------------- CE SS-HOO*. Prioer ---------------------- i>:5 GE S5-4155 Primer ------------------------- v.51 GE ZL-234 ----------------------------------------- '057 GE ZL-282, Epoxy Varnish ----------- 107? CE 2P7-A, Hand Cleanar --------------- i:-85 GE 2PV-32, Epoxy Resin --------------- 1039 GE 10 and 10C Oils (Discontinue * Designation) ------ ------------------- -- 395 CE 1500 Thinner ----------- -------------- 1173 GE 9522 and 9637 (ALEANEX Varnish) --------------------------- --------- 1163 CE 7303? Wire Enamel ------------------- 1040 CE 73'56 Hire Enas-l ------------------- 1003 CE 73517, PERMAFIL Polyester -- 1024 CE 74023 Epoxy Varnish ------ - 1026 GE 113011 (Parts A A 3) ------------- 1372A GE Material A2E2 --------------------------- 15 A2L1-15 --------------------- 45 A4L1--------------------------- 45 A7A8.ll.l3.lii--------- 46 A10B15 ------------- 1144 A10B16 i 16B----------- 15 A13A3-------------------------393 A13D1------------------------- 27 A13F1------------------------- 349 A15B53A A 53C1 ------- 1163 A15F6A2 --------------------- 1142 A15P1UI------------------- 1008 A15F1U4------------------- 1151 A15F1281 ------------------- 1006 A16B52 ----------------------A16B68 ----------------------- A50A194A1 (A & B) A50A231 --------------------A50A238 --------------------- 1010 1010 1072A.B 1024 15 A50A262 --------------------- 1075 A50A262 (Part B) -- 1074 A5CA311--------------------- 1026 A50CD261 ------------------- A50JL40 --------------------- A50PC73 --------------------A50PC77 --------------------- B10C11------------- ----------- 23B11G25 ----------------------B11H49 ----------------------- B20F9 ------------------------B21B8 ------------------------B21Y4 ------------------------- D4A1--------------------------D4A2------------------------D4A3-------------------------D4A4------------------------- D4A5-------------------------D4A7------------------------- 6 9 30A 7 5 6A D4B3-------------------------- 39 D4B4-------------------------- 3 D4B4A3----------------------- 3A D4B5--------------------------- 40 D4C3---------------D4C22 --------------- 45 28 D4C26------------------------- 22 D4C29 --------------D4C48 ------- 38 1064 D4C50 -------- 1021 WD5------------------------- 43 D4E7-------------------------42 D4B12----------------------- 24 D4F12-----------------------37 D4F13B,C------------------29 D4G2-------------------------21 D4C9-------------------------36 D4K1-------------------------43 D4X3------------------------- 11 D4M6------------------------- 12 D5B3------------------------ 353 D5B4-------------------------337 D5B43----------------------- 398 D5B5-------------------------337 D5B7 --------------- ---------371 D5B3-------------------------334 D5D8C----------------------- 334B D5DSD----------------------- 334A D5D9------------------------- 318 D5U11----------------------- 31 y 05315 ........................... 320 D591C-----------------------319 WB17........................... 376 D5U20A2 1 C2---------- 391 06*24........................... 300 GENERAL ^ ELECTRIC _ *1"pc,-,'<,<rS lssuc o1' **"*<* ,9M 411538 0106 MSDSA CZ Mate-ial D5C30D............................ 1061 D5330F ---.................... 106u D5338 .................. ........... 323 D5BftO ---------------------- 333 B5R50-------------------------A 10 D5D51...........................35ft D5353 --............. ........... 3^6 DSBSft --.................. -- 359 D5BS5B1 --------------------- 1073 D5B58-------------------------31? D5B56D----------------------- 1156 D5357 --......................... 3?ft D5362 ---------------------- ft 13 D5B65 .................. ........ 356 DSSS6&---------------------36ft D5.H67A------------ 1173 537 j-------------------------367 I D5373 ---------------------- 30ft | D5B76 ------------------------- 365 D5B77---------------------- 31ft D5B78 ---------------------- 309 D5B79---------------------- 3H D5B51A---------------------31ft D5B32-------------------------ft05 D>B33------------------------ ft 12 D5B3ft---------------------- 313 D5339 ---------------------- 310 D5B90 ------------------------- 322 D5C13---------------------- ftOO D5C26 ----------------------- 327 B5C33 ---------------------- 339 D5C3ft------------------------- 1052 D5D19 ----------------------- 377 D5&34----------------------- 399 D5D50 ------------------------- 351 D5D58B2-------------------335 D5D5SD & D2 ------------- 335B D50S8D5....... -- 386 D5D70 ---------------------- 386 D5D78 ----------------------- 336 D5E1A-----------------------38ft D5E19-------------------------363 D5E5------------------------ *111 I D5E7 ----- r----------------- 332 j D5E8---------------------------333 | P5E10-----------------------321 1 D5B11-------------------------338 D5E23 ---------------------- 37ft D5E29 ----------------------- 328 D5F5------------------------ 325 D5F8------------------------ 356 D3F9---------------------------407 j D5F15A1--------------------- 103ft D5F15B1----------------------- 1335 D5F17A2------------------- 107ft D5F17D---------------------39ft D5F18A1-------------------3ft6 D5F19---------------------- 378 D5H1------------ ----------- 360 DW3D & E--------------- - ft09 D5J6------------------------ 355 D5K3-------------------------3ft9 D5Y2---------------------------376 D5Y17-----------------------ft 06 D5Y28 ---------------------- 329 D27A1-----------------------1 D27A2-----------------------373 D27A4---------------------- 308 D27A?-----------------------307 D2?Al6---------------------ft03 D27A20 ----------------------- 380 D50U40A----------------------1027 D50H5*C2----------------- 378 D50H6192 ------------------- 335 CENEPOXT 925 ------------------------ -- 335 CSMESOLV D---------------------------------------31ft GENETSOS 11----------------------------------309 12----------------------------------308 22 ---------------------------------- 307 113-------------------------------- 3)1 111)-------------------------- ----- 307 Glass Fiber-------- ------------------------ 46 Clufr, COoO, Emulsion-Type --------- 113ft Glycol--------------------- --------------------- 323 CLYPTAL 1500 Alkyd Thinner ------- 1173 Cx-atn Alcohol ------------ ----------------- 36* Gum Rosin--------- -------- -- 37 H2-.S04, HYSOL TETA-------------------- 1035 H2-3V.6, HYSOL BETA........................ 1C3A lialocarbon Solvent Blend ----- 1170 HAND CLK'KEH, CS 2PV-4---------------1098 M5ESJ HANDY FLUX.............................................. 11A4 Hardner for epoxy, polyaolde -- 39ft HAVILAKD HD 68G ETCH------------------- 10ft 1 HEC (Hydroxyethyl Cellulose) -- ft01 2- Heptanone --------------------- -- 30? 3- !l*ptanone--------------------- ------ 305 lft5,6,7,7-Hexnchlorobicyclo (2.2.1) 5-heptens-2,3-dicar- boxylic Anhydride------ -------------339 Hexachloroendomethylenetetra- hydrophthallc Anhydride -- 339 Hexafiuoropropylene-Vinylldene Fluoride Copolymer ------------------- 1107 Hexahydrobenzene --------------------------- 359 Hexaaethylene --------------------------------- 3^9 Hexane (n-Hexane) ------------------------- 397 Hexanediolc Acid-------------------- ---- ftOO Hexone------------------------------------------- 30ft HP (Hydrogen Fluoride) --------------- 6 HI-TRI---------------------------------------------- 312 Hot Melt Adhesive, EVANS 7050 - 1097 HUGHS0N ACCELERATOR #4---------------10013 KYCAR *1031-50 --------------------------------- 1096 Hydraulic Fluid (Triaryl Phosphate) ----------------- 1175 Hydrazine Honobrooide or Hydrazine Honohydrobroeide -- 10 Hydrochloric Aoid -------- ----------- 30A Hydrochloric Acid, Anhydrous -- 30 Hydrofluoric Acid, Anhydrous -- 6 Hydrofluoric Acid (47-70*) ------- 6A Hydrogen Chloride, Anhydrous -- 30 Hydrogen Fluoride ----------------------- 6 Hydrogen Fluoride, Anhydrous -- 6 Hydrogen Nitrate ------------- ------------- 7 Hydrogen Peroxide ( 60*) ----------- ftftA Hydrogen Peroxide (27-52*) ------- ftftB Hydrogen Phosphate (75-85*) -- 8 Hydrogen Sulfate -------------------------- 9 Hydroxybenzene ------------------------------- 355 1-Hydroxybutane ------------- ------------- 337 Hydroxyethyl Cellulose ----------- ftOl ft-Hydroxy-ft-Methylpentanone-2 - 353 2,2-bis (4-Hydroxyphenol) Propane --------------------------------------- 369 Hydroxytoluene ---------------- 409 HYSOL DK 0295 ------------- ------------------ 1179 HYSOL EA93ft (Parts A & B)---------1011A.B H2-3404 TETA---------------------- 1035 H2-3416 BETA-----------------------103ft PC 18------------------------------------ 1056 PC 29 (Parts A A B)--------- 1173 IKIDSX E, 73156 ----------------------------- 1005 IMMUNOL S-6--------------------------------------- 1093 IHR0N K,H, ENAMEL, White (817U) 1117 INDUSTRIAL CLEANER 68-A--------------- 1096 INHIBISOL---------------------------------------- 311 Ink Cleaning Solvent --------------- 1152 Insulating Oil, Electrical --- 393 Insulating Varnish (Phenolic resln-Bodified polyester) -- 1002 IR-75 Developer System ------ 10^9 (6 Part) (A to F) Isobutyl Acetate 1-------------- - 396 Isobutyl Alcohol (Isobutanol) - 398 Isobutyl Methyl Ketone ------- -- 304 Isocyanate Solution, Pigmented - 1127 ISOKID B"----------------------------------------- 1085 IS0NEL 31-66 (XV-503) ----------------- 1002 "Isooctane"--------- ------- ------------ -- 383 Isophorone--------- ------- --------- ----- 356 Isoprene ------------- ------------3ftl Isopropyl Alcohol (Isopropanol) 324 Isopropylbenzene --------------------- 395 4,ft'-Isopropylidenedlphenol ----- .369 IS0TR0N 11-------------------------------------- 309 12-------------------------------------- 305 22 -------------------------------------- 307 1)3------------------------------------ 31ft J-13*5 basic Zinc Chromate------- 1130 JDM F2A2 GREEN ALKYD RESIN ENAMEL (Exempt Solvent) --------- 117ft KANO KROIL -------------------------------------- 1050 KAYHIDE-------------------------------------------- 31? Kerosene (Kerosine) Solvent ----- 387 KESTCR 103 THISNKH---------------------- `.023 1J7 RESIN FLUX............. 1022 KGDAFLEX TXIB--------------------------------- 103? ilfWJIL ------------------------ ---------------------------- 1050 GENERAL ELECTRIC Reissued - ??? KSL>5r KHYL0N CRYSTAL CLEAR SPRAY CCATIN1 (1?00-1305) (*.eros:>:> Wt KURIFLOC:-: FS-547--------------- --------- - 1119 THICK EASE--------------------------------------- 10ft5 LACO M-A Flux (La-Co-M-A Flux) 1018 Lacquer, Wood (MOBIL 2609) ------- 1165 LANTNAC ftlfto---------------------------------- 1009 Layout Fluid (DYKEH) ------------------- 1154 LD 2729 -------------------------------------------- 346 Lead Monoxide------- ------------------------- 33 Lead NaphthenateSolution ----------- 38ft Lead (II) Oxide----------------------------- 38 LECTON ACRYLIC RJC6323 A EK6327 ------------------------------------------ 1060 Line--------- -------------- 22 Lime, Hydrated, High Calclun -- 39 Line, Slaked-----------------------------------39 Liquid Caustic Soda---------------------3A Liquid Metal (MaK Alloy) ----------- 16 Liquified Petroleum Gas ------------- 380 Liquified Propane ------ 380 Litharge ---------------- 38 LPG A L?-Gas-----------------------------------330 LUPERSOL DDK and DELTA-X ----------- 329 Lye---------------------------------------------------- 2,3 Lye Solution (50*)----------------------- 3A M-A Soldering Flux------------------------- 1018 HACMAFLUX SKC-HP SPOTCnECK CLEANER---------------------------------------- 1031 KAGNAFLUX ZC-7-------------------------------1031 MACMAFLUX ZYCL0 DEVELOPER MAGNUS 26-N-------------------------------------1108 92-S------------------------------------- no9 2150------------------------------------- 1111 402 --------------------------------------- 1112 614---------------------------------------1113 763-NF------------------------------------1176 SC-100--------------------------------- 1110 MAGNU-SPRAY 105 ----------------------------- 1069 KAKOX NF-5---------------------------------------1122 MALLORY 100------------------------------------- 32 MAHKEH 320 CLEANER----------------------- 1152 Massicot------------------- --------------------- - 38 MDA (Kethylenediantline) ----------- 346 KDI----------------------------------------------------- 1105 HER (Methyl Ethyl Ketone) --------- 303 KEK Peroxide Solution --------------- - 329 Mercury -------------- 26 Methanal, Aqueous ------------------------- 360 Kethanamide -------------- 390 Hethane Carboxylic Acid ------------- 321 Methane Tetrachloride ---------- -- 410 Methanol -----------------------------------------35b 2-Methoxyethanol ---------- 352 Hethoxyrethane ---------- 342 Methyl Alcohol ------------------------------- 354 Methyl Aldehyde Solution ------- 3$0 Methyl n-Aayl Ketone ------- 302 Methylbenzens------------------- ------ --- 317 2-Methyl-1,3-butadiene ------- -- 341 Methyl i-Putyl Ketone ----------------- 304 Methyl CELL0S0LVE ------------------------- 352 Methylehloride ------------------------------- 373 Methyl Chloroform----- ----------------- 311 4,4'-Methylene bis(2-Chloroaniline) --------------- 372 Methylene bis(Phenylisocyanate) 1105 Methylene Chloride ----------------------- 310 Methylencdianlllne ---------------- 346 Methylene Oxide Solution ----------- 360 Methyl Ether ----------------------------------- 342 Methyl Ethyl Ketone --------------------- 303 Methyl Ethyl Ketone Peroxide Solution----------------- ------------------ 329 Methyl Isobutyl Ketone --------------- 304 -Kethylpropyl Acetate --------- -- 396 2-Mcthyl-1-propyl Ethnnoate -- 396 Methyl Oxide ----------------------------------- 342 Methyl 0XIT0L --------------------------------- 352 4-Mcthyl-2-Pcntanone -------------------- 30ft 2-Mwthy1-1-Propanol ------------- 398 Methylphenol------------- ------------ 4G9 Methyl r-Propyl Fetors** or Methyl rropyL Ketone ------- 305 Methylstyrene-------- --------------------------------3,6 Methyl Tctrahydroplithalio 1C1)IB, Anhydrid-, Epoxy Curing Ag'Mit 1101 Met-hylvinylberizen-'------------------- -- 33S rscri'.'S 'sr.iii of November 19?fl 411538 0107 HSD5P MINX---------------------------------------------------30*1 Mica Powder (Muscovite) ------------ 24 Mineral Oil, White----------------------- 1137 Mineral OH with Detergents, Soluble* in Water------------------- 113? Mineral Oil with Lube Additives 1140, 1141 Mineral Powder Slurry (PfiOTECT- 0-MS74L Ho. 2)--------------------------- 1044 Mineral Spirits ----------------------------- 334 Mineral Spirits Cleaning Compound---------------------------------------1095 MOBIL Clear Varnish 2609 ----------- 1164 Mist Lube #27 --------------------- 1041 Vaetra #2---------------------------- 1140 MOCA---------------------------------------------------372 HOD-EPOX-------------------------------------------411 MOLD RELEASE #210-55 (Paraffin) 1136 KONDUR M-------------------------------------------1105 Mono-aluminum Phosphate-------------11 Monochlorobenzene --------- ------------- 366 Monochlorodifluoronethane --------- 307 Morpholine------------------------------------ -- 35$ MPK (Methyl Propyl Ketone) ------- 305 KULTILITH DSGLAZING SOLVENT----- 310 MULTRATHAHE M - MDI---------------------1105 Muriatic Acid---------------------------------30A Muscovite Mica, Powdered ----------- 24 NADIC METHYL ANHYDRIDE --------------- 1062 NaK Alloy-----------------------------------------1$ Naphtha, High Solvency Aromatic 1061, 1061A Naphtha, VMAP (Rule 66 Exempt) - 391 Naphthenate Soap Solution: 6* C.-'balt Catalyst------------------- 363 24* Lead Catalyst---------------------334 NE0S0L-----------------------------------------------1073 NEV-TRX Solvent ----------------------------- 1156 Nickel (II) Chloride-------------------- 36 Nickel (II) Nitrate---------------------- 20 Nickel (II) Sulphate-------------------- 37 Nickelous Chloride Kexahydrate 36 Kickelous Nitrate Hcxahydrate - 20 Nickelous Sulfate Kexahydrate - 37 Nickel, Spongy or Porous, Powder-------------------------------------------1118 Nitric Acid (55-70*) ------------------ 7 Nitrocellulose Lacquer (DYKFM)- 1154 Nitrogen Dioxide --------------------------- 47 Nitrogen Peroxide ------------------------- 47 Nitrogen Tetroxide -------------------- 47 Nonylphenoxy(polyethanoxy) ethanol------------ '---------------------------1094 UO-TARN----------------------------------------------- 1043 NOVACITE 325, 1250, L-207A ------- 1021 NOZZLE KLEEN (Aerosol) --------------- 1164 NU0DSX Naphthenate Catalyst 6? Cobalt-------------------------------------363 24* Lead---------------------------------------384 OAKITE 67----------------------------------------- 1167 160 --------------------------------------- 1032 STRIPPER ANP------------------------1042 Octyl Acrylate-------------------------------345 "Octyl" Alcohol------- ----------- --- 3S7 Odorless Mineral Spirits ----------- 334B Odorless Petroleum Spirits ------- 334B Odorless Solvent--------------------------- 334B Oil of Vitriol----------------------------- 9 Oil, Transformer (or Electri cal Insulating)-------------------------393 Orthophosphoric Acid (75-35*) - 8 Oxalic Acid-------------------------------------328 OXXTOL---------------------------------------------- 319 Ozone------------------------------------------------- 34 PACO Solvent T.R. 590----------------- 1073 Paint Flocculant--------------------------- 1021 Paraffin Wax in Hin. Sp.-----------1136 r/.:'APLKX P-4')......... 1038 PAPE KASE 5C--------------- 1045 PC 10, Printed Circuit Costing 1066 PDC&U Cleaning Conpuun'i --------------- 1095 '. C .Cr.ORGE #9**0 ,Epoxy bond Coat 11 ?') VV.C 6000...... .............................................365 Pcn>' tr.irt, Ni*n-'!' ! ruct i vo Testing----------------------------------------- 1046 d-PMit.-*n<inc------------------------------------ 305 PEPCISLOR......................................-........... 313 Pcrciilnroi-thylrr"------------------------- J13 H5DSJ Perchloromethane------- ------------410 PERCLENE------------------------------------------ 313 PERCLENE D-------------------------------------- 313 PERK-------------------------------------------------- 313 PERM-A-CLOR------------------------------------ 312 PERH-A-CL0R NA-------------------------------31? PERMAFIL 73517 ------------------------------ 1024 Peroxide (HEX Peroxide) ------------- 329 Peroxybenzoic Acid, t-Butyl Ester --------------- ----------- 406 Petroleum Spirits ------------------------- 334, 334A PEX SPRAY 66------------------------------------- 1019 Phene--------- ----------- ----------------------- 316 Phenol---------------------------------------------- 355 Phenol-formaldehyde Resin, Twostage, Unfilled------------------------ 1103 Phenylamine ---------------------------------- *107 Phenyl Carboxylic Acid --------------- 402 Phenyl Chloride----------------- --------- 366 Phenylethane ----------- ---------------------- 335 Phenylethylene ------------------------------ 351 Phenylfonaic Acid---------------------- 402 Phenylhydride------- ---------- 316 2-Phenylpropana ------- ------- ----------- -- 395 PH0SFLEX 112, Plasticizer --------- 1081 Phosphorus Acid, Triphenyl Ester --------------------- -- 411 Phosphorus-------------------------------------- 25 Phosphoric Acid (75-85*) ----------- 8 Pigment, Basic Zinc Chromate -- 1130 Chrome Yellow Ked. -- 1124 Muscovite Mica-------------24 Pimelic Ketone ------------------------------- 301 Plasticizer, K0DAFLEX TXIB ------- 1039 PHCSFLEX 112--------- 1081 Plumbous Oxide -------------- 38 Polyacrylamide Powder ----------------- 1119 Polyacrylate Adhesive (2part) - 1150 Polyacrylic Elastomer ----------------- 1086 Poly(aalde-imide) Wire Enamel - 1037 Polyamide Resin, Liquid, Reactive---------------------------------------394 Poly(Dimethylsiloxaoe) Fluid -- 349 Polyester Resin In Xylene Solution (ALKANEX) ------------------- 1163 Polyester Resin, Unsaturated: Styrene-Type ------------------------------- 1024 Styrene-7ype ------------------ --------- 1038 Styrene-Type, Catalyzed --------- 1070, Polyester-iaide: 1123 Resin Solution ---------- 1125 Wire Enamel---------------- ---------------- 1005 1085 Polyethylene Clycol, Alcohol Solution-------------------------------------- 1387 Polyethylene Clycol, Solid mole. vt. ca 6000-7500)--------- 364 Polyglycol E^OOO------------------------- 364 Polyimide Resin Solution, PTFE Filled------------------------------------------ 1143 POLYISOCYANATE ACTIVATOR 192-S 1116 P0LY-S0LV DB-----------------------------------322 Ed----------------- -----------------320 EE---------------------------------- 319 Polysulfide Sealant, 2 Part ----- 1102A,B POLY-TEBGENT B-300 .----------------------- 1094 Poly(Tetrafluoroethylene-Hexa- fluoropropylene) Copolymer -- 1010 Polytrifluorochloroethylcne, liquid------------------------------------------ 338 Polyurethane-Based Caulk, Airborne Moisture Cure ------- -- 1100 Polyurethane Black Insulator Varnish------------------------------------ 1146 Polyurethane Enamel, White ------- 1117 Polyvinyl Formal Resins (FCRMVAR)-------------------------------------399 Potash Lye-------------------------------------- 2 Potassium Cyanide ----------- --------- 13 Potassium Hydroxide------------------- 2 Powdered fcooJ --...........-........... -- 376 PP-120---------------------------------------------- 1127 PR-1527 -------------------------------------------- 1139 Primer fer RTV Silicone Rubber: 33-4004 ---------------------------------------- 1005 S3-4155 --------------------------------------- 1151 Printed Circuit Coating ------------- 1066 Prou'ine, Liquified Has -------------- 380 2-IVaparol -- ------------ --------------------- 324 1979Reissued - Jtfr.g MSDS# Propanone -------------- 300 Propellant 11--------------------------------- 309 12..................... ...................308 22 --------------------------------- 397 Propenenitrile ------------------------------- 331 Proprietary Solvent #3 --------------- 1073 scc-Propyl Alcohol----------- --------- -- 324 Propylcarbinol ------------------------------- 337 PROTECT-O-METAL No. 2----------------- 1044 PROTEXULATE---------------------------------------1082 Ptx (PbO)-------------------------------------------33 PYRS-ML WIRE ENAMEL RC 5863 ----------------------------------------- 1120 Type 1 (RC 5877)------------------------ 1121 Pyridine----------------------------- -------------*05 Pyromucic Aldehyde ----------------------- 413 QUANTOfi IR-75 Developer System 1049 (6 part)----------------------------------- (A to F) Quartz, Natural, Micro- crystalline (NOVACITE)----- -- 1021 Quench Oil (Hydrocarbon) ----------- 1067 Quicklime----------------------------- ----------- 22 RACK STRIP C----------------------------------- 1017 RAM MOLD RELEASE 225 ------------------- 1046 RANEY NICKEL CATALYST #28 --------- 1118 RC 577 PYRE-ML Wire Enamel ------- 1121 RC 5863 PYRE-ML Wire Enamel -- 1120 Refrigerant 12-------------------------- -- 308 22---------------------------- 307 113---------------------------314 Remover, Thinner (DYKEM) ----------- 1153 Resin Flux 197--------- ------- --------------1022 RESIN-NT------------------------------------------- 1047 REZ-N-BOND #1--------------------------------- 1131 RISTON II DEVELOPER 20C0 (Concentrate)--------- ---- -- 1013 RISTON II DEVELOPER 2000 (Use Concentration) ------------ 1013A RISTON II STRIPPER 1000X ----------- 1012 RODINS 92A--------------------------------------- 1083 Rosin (Cum or Wood) -------------- -- 377 RTV-102 (One Component Silicone, Adhesive, Sealant) ------- --------- 1142 RTV-577 (Silicone Polymer) ------- 1005 RTV-9S11 (Catalyst) --------------------- 1007 Rubber Solvent ----------------------- --- ---- 371 Rubber, Uncured, Polyacrylic -- 1086 Rust Inhibitor for Steel ----------- 1098 Rust Inhibitor, Alkaline --------- -- 1108 Sal Anraoniac ----------------.----------------1003 Sal Soda--------------------- -------------------- *8 SAHTICIZER 9-------------------------------------- 1CS8 SART0MER SR-297 ----------------------------- 1106 Sawdust, Wood------- ------------------------- 37$ SCOTCHCAST #8 (Parts A A B) ------ 1181 SCOTCHKOTE RESIN K20O6 A X2008 1003 (No longer commercially available) SC0TCHVELD STRUCTURAL ADHESIVE - . 2216, Parts A A B ------- ------------1157A,B SF-96, SF-97 ----------------------------------- 349 Shellac, White, Alcohol-Based Solution ------- ---------------------- 370 SHELL BPA 154 or 157 ------------------- 369 PD660 Cleaning Compound - 1095 Rubber Solvent---- -371 VH4P Naphtha EC----------------- 391 SIXAFLEX 1A--------------------------------- -- 1100 SIL-B0ND 45, Brazing Alloy ------- 41 Silica: Amorphous, fumed------------- 1064 Natural, microcrystalline ----- 1021 . Silicone Fluid (Dimethyl).------- 349 Silicone Polymer (Fluid) for 2-Part RTV Rubber------- ---------- 1006 Silicone Reein Solution: DOW CORNING CP-771171 DOW CORNING 1090 Varnish--------1169 Silicone Rubber (One Component Adhesive,. Sealant) ------------- 1142 SILVALCY *5, Brazing Alloy----- -- 41 Silver Brazing Alloy------------------- 4$ "Silver Brazing Flux"----- -------- 1)1(4 SKC-Kr SPOTCHECK CLEANER (Formula B) --- -------------- ----- 1031 SKD-NF 5P0TCKECK DEVELOPER ------- 1071 Soda Ash------- --------- --------------- ------ -- 48 Soda l.yc----------- ------------------------ -------3 Sodium Carbcwvito, Anhydrous --- 48 G?JEHAL#lCTniC :;cdos Issue of November 1978 411538 0108 KSDS# Jr^U-a Fiuosiiicate-------------------- 3* 1 Soditra Hydroxide------------------------------ 3 Scc:iun Hydrc;:ide, 50" --------- }A Sodiu* phosphate Tribasic---------- 43 Sodi'J~-Fo-*-iU:ci Alloy --*----- 16 Sodiirr Silieofluoridc---------------- 31 Solder Flux, Acid------------------------ 19 Solder Fins, Alcohol-Rosin Type, Activated --------------- --------- -- 1C22, 1C81 Solder Flux Thinner ---~*----- 102} SOLUBLE OIL "C"---------------------1132 SOLVSc'SO 100 and 150 (Obsolete YraJenatea; see EXXON Aromatic 100 and*150) ------------- 1061, 1061A S5-4C01 Primer------------------------------ 1003 SS-U155 Primer------------------------------ H5* f Stannous Sulfate --------------------------1*1 Stator Compound, Putty-Like Polyester ------------- '-------------------- 11*17 S7EELCARD 1505B ---------------------------- 1098 Stoddard Solvent, Type I ----- 33** I Stoddard Solvent, Type II (;0F nin FP)-------------------------- 334* St-ddard Solvent, Type III (Odorless)---------------------------------- 334B StrippaMe Coating for Kctal -- 1110 f Stripper Cccpoend for Metal I i I (Alkaline Cyaiide-B2sed) ---- 1145 STRYP? NF----------------------------------------1016 Styrene Monomer (Styrol) ----------- 351 Sulfur Hexafluoride---------- ----- 27 Sulfuric Acid, Concentrated -- 9 "Sulfuric Ether" -------------------------- 343 p,o*-Sulfuryl Dianiline ------------- 1036 SUPER C.l/S-3---------------------------------- 1065 SfPZHLODE 1683 ------------------------------ 1057 SYMA30L PK509 6 PH3224----------- 1073 oYSTHITE EB-41------------------------------ 11*16 T-2C0Z (Xylene)---------------------------- 11*18 Talc (Talcum)-------------------------------- 42 Tcmish Remover (KO-TARM)---------10*3 | 7CE (Trichloroethylene) ------------- 312, 1156 TCP (Tricresyl Phosphate) --:-- 332 TECSOL-3---------------------------------------------1073 i'SFLGN FEP-------------------------------------- 1010 TFRASOJ #357 ---------------------------------- 1125 ! i i Tertiary Sodium Phosphate ----- 43 7ETA (Yriethylenetetraaine) -- ,1035 Tetrachloroethylene ----------------- 313 Tctrachlorooetnane ------------ -- 410 Tetrahyorofuran ---------------------------- 379 TEXACO 2223 CLEARTEX B------------- 1162 i 1157 TRANSULTEX F---------- 1161 2234 CLEARTEX 140X------------1137 SOLUBLE OIL "C"--------------- 1132 7:ISIC (Obsolete Tradename; see RESIN-NT)------------------------------------ 1047 VHP (TetrahydrofUran) ----------------- 379 1 Trtinnar, ALPHA 41J-F ----------------- 1077 Thinner, ALPHA 810------------------------ 1078 Thinner, CLTPTAL 1500 --------------- 1173 Ti.inr.er 108 ------------------------------------ 1023 Tninner ar.d Recover (DYKEM) -- H53 TJS0X2KE TA-123 (Parts A 4 3) -- 1027A THREE H, 7TPE 3 DEVELOPER--------1180 7ir. (II) Sulfate------------------------- 14 Toluene (Toluol)------------------------- 317 Toluene-2,4-diiaocyanate ----------- 331 Tolueneaulfonamlde (o- and - I Iso-v-rs )---------------------------- ----------1068 I Tolylene-2,4-diisocyanate --------- 331 1 TPP (Triphenyl Phosphate) ---- 333 7-ansTcnte1* Oil-------------------------------- 393 TPAXSfJLTEX F (1557)------ -------------1161 TtuAD &-------------------------------------------- 3*2 Triaryl Phosphate Hydraulic Fluid-------------------------------------------- H75 TR'.CuLOR ------------------------------------------ 312 fr L:h lolK-rzeno, Dielectric Lra-ij-------------------------------------------- 355 1,1,1 - Trie i.loroithane ---------------- 3*1 icilc*' **thylcne ------------------------ 312, 1156 TrV.M-j' .floor*. -.ethane................. 3C9 7r>t*.:r. hor.e -------- -- -- ------ -- 3*5 *, ` ,2- J ,2,2-tri fl-joro- ctUno ...................................-.............. 3 1*1 K3T.*i TRICLENS D-------------------------- ----------- 3*7 HD.............................. ..............3*2 Tricresyl Phosphate --------------------- 332 TRI-ETHANE-------------------------------------- 3*1 Triethylasinc---------------- -------- 392 Triethylenetetrantne ---------------- 1035 Trieeilltic Acid-1,2-Anhydride 330 Triiaellitia Anhydride-----------------330 3.5.5- Triaethy1-2-cyclohexen-1- one------------------------------------------------ 357 2.2.4- Tricethylpentane --- ------- 333 2.2.4- Trinethyl-1,3-pentanediol Diisobutyrate Ester ----------------- 1C39 TRIM TAP HEAVY--------------------------------- 1053 Triphenyl Phosphate ------------------- 333 Triphenyl Phosphite --------------- 4tl 2.4.6- trlsCDiaethylaminoaethyl) Phenol--------------------------- -------------- 373 tr1s(2-Hydroxyethyl) Isocyanurate ---------------------------- 1047 tris-(2-Hydroxyethyl)-s- Triazine-2,4,6-Trlone ------------- 104? Trisodiun Phosphate Dodeca- hydrate (TSP) ----------------------------- 43 Trisodiun Orthophosphate ------------- 43 TRITHENE-------------------------------------------3*1 TRITHERH 981 WIRE ENAMEL----------- 10J7 Tritolyl Phosphate ---------- -------- 332 Trodaloy #1------- ---------------------------- 3? T<Jir-0-k'ASH CLEARER-----------------------1170 Turpentine, Spirit orOil of -- 1142 TYPE R DEVELOPER (3M)----------------- 1l80 UC0N 11-------------------------------------------- 309 12-------------------------------------------- 308 22 -------------------------------------------- 307 113 31----------------------------------- 60 6 393UNIVOLT and H l------------------- URETHANE ENAMEL ACCELERATOR (159-S)-----------------------------------------1115 Urethane--see also polyurethane Urethane, Conformal Coating ----- 1173 Urethane Polymer, Oil Modified, Catalyzed, In Xylene Solution IKS Urethane Printed Circuit Coating solution ----------------------- 1066 U7-100 Adhesive, Parts A & B -- 1172 VACTRA #2---------------------------------------- 1140 2609 1155VAMAC B124-------------------------------------- 1104 Varnish (MOBIL )....... - Varnish, silicone: DOW CORNING CP-77---------------------1171 DOW CORNING 1090 7---------------------116s Varnish, White Shellac Cut #3 - 370 VCM (Vinyl Chloride Kononcr) -- 32 VELSICOL ChlorendLc Anhydride - 339 VEPSAKID 115, 125, 140 --------------- 394 YERSILOK 505 ----------------------------------- 1150 526---------------------------------- 1001A Vinyl Chloride (monomer) ---------- 382 Vinylbenzene-------------------------------- -- 35* Vir.ylcyanide---------------------------------- 3?1 Vinyl toluene------------- -- 336 VITON E-60---------------------------------------1107 VKAP Naphtha ---------------------------------391 Washing Soda---------------------------------- 45 Wax, Petroleum-Type in Min. Sp. 11?6 WD-40 ------------------------------------------------- 1030 VELDWOOD CONTACT CEMENT------------- 1084 WESTBLIT2 GP-500 --------------------------- 1053 WESTEAM HD-210 ------------------------------- 1054 WEST0P 505 -------------------------------- -- 1055 1883 '057WESTRSAH AS (1873)----------------------- 105S WEST SUPERLODE ----------------- Wet-Ground Mica ---------------------------- 24 Wetting Ajent (MAXQN HF-5) Alkoxylated Alkanolamide-Type 1 *22 White Shellac Solution --------------- 370 White Spirits.............. -- 334 Whiting-------------------------------------------- KB2 WHITE STAR TODY FILLER, *???. #204, #205 ------------------- >123 Wire Kra^el (RK 73035) ................. *040 Wire Erar.eL, roiy{vM:',-<..T.i,!e) 1037 Wire Zr:us"l, rojy^t cr-i.ti.tc) 1005 Wire f.rv-*l, FoIyr>.,.ur-lJ*i'le - V-1F5 Wire Era-.cl (PYP.E-FL 1!C52'3) 1120 Wire Enarel (Pjr.E-HL, RC 5'*7 7) 1121 Ko<d Alcohol -------- --------- -------------- 3.'4 Reissued MSDSJ Wood Dust or Fleur----------------------- 37fc Wood Ether------ --- ------------------- -- 3*1? Wood Rosin--------------------------------------- 377 XEROX DUPLICATING TONER: Spec. No. 6R2.fR5.6R8.6P32, 6Rl59,6RI50,6R152,6Rl62,t?.l63, 6R175.6R176.6R 177,6R178,6s5?0, and 6P202CKDS 101-2400, -3CD0, -7000)------------------------------------------- 102S XYLAN 1010---------------------------------------1143 Xylene (T-200X Tradename) ---- 1K8 Xylene (Xylol) -------------- 3*8 Y-469-D PIGMENT (Chrome Yellow Ked.)--------------------------------------------- 1124 2C-7 2YCL0 CLEANER----------------------- 1031 Zinc Chloride Soldering Flux -- 18 Zinc Chloride Solution --------------- 18 Zinc Chromate, Basie (J-13a5) - 1*30 Zinc Oxide (Zinc White) ---- 45 Zirconium Ketal/Povder----- --------- 17 ZYGL0 CLEANER (2C-7)------------------- 1031 DEVELOPER ZP-9------------------- 1071 B>- 1048 NCMBSR TISSICNATIONS 3>^. rf,.nTE R DEVELOPER-------------- 118C ' 10 and 10C Oils (Discontinued Designations) -------------------------- ~ 392 108 Thinner ---------------------------------- - 1023 190/P-3224 ----------------------------------- ~ 1073 197 Resin Flux ---------------------------- - 1022 200 Silicone Fluid -------------------- - 349 222B CLEARTEX B--------------- ------------ 1162 413-F Thinner ------------------------------ - 107? 520 Adhesive -------------------------------- - 1133A ,561 SiUcpne Fluid-------------------- - 349 611 Flux.'----------------------------------------- 1030 jBHUBCAJPjT--------------------------- 1078 a 815 Flux-------------------------------------- 1079 " 815 KX Alkaline Cleaner ---------- - 1158 815 QR Alkaline Cleaner ---------- - 1159 946 Epoxy bond Coat----------- ---- - 1129 15C0 Thinner (GLYPTAL) ------------ - 1173 1557 TRASSULT2X F ---------------------- - 1161 9522 (ALKANEX) ---------------------------- - 1163 9937 (ALKANEX) ---------------------------- - 1163 73039 Wire Enamel ---------------------- - 1040 73156 Wire Enaael ---------------------- - 10C5 73517 PERMAFIL Polyester -------- - 1024 74023 Epoxy Varnish ---------------- - 1026 113011A&3 Epoxy Sealing Putty - 1072A&3 I GENERAL -1 t n j c ArSup:. r:;cd V No/`rNwM- l');3 411538 0109 * Engineering Standard ALCOA Materials and Standards Section Pittsburgh _ ..18.15 - PAGE 1 HAZARDOUS MATERIALS - IDENTIFICATION a MATERIAL SAFETY DATA SHEETS 1980-04 Sjo S' ^ 1. SCOPE 0 a AO> c o .2 1" This standard covers the identification of most materials used and/or produced by Alcoa Those materials considered as hazardous are or will be documented on Alcoa Material Safety Data Sheets (AMSDS). Most materials c-:.......Jra 2 used and/or produced by Alcoa, whether hazardous or not, are listed in Engineering o c 2 S cCToJ S- Standard 18.15.1. 2. DEFINITION A hazardous material is defined as a material -- - - - *> SM&53 s - jl?La8g MqrScc-Tt-^:S5dd8s-o- e c. which presents an unacceptable hazard to Health Safety, or the Environment. Included are materials that are flammable, combusti ble, explosive, chemically reactive, corro sive, toxic, and radioactive. Any gas, ' e C *0 S vapor, liquid, or solid material having one rS. k * or more of the following characteristics is CU MC. C "CO >. . considered a hazardous material, i| 2.1 Flammable. Any liquid having a S|| .point below 100F (37.8"C). O2 *8> o 8 . Examples: Acetone, gasoline, hexane flash 2.2 Combustible. Any liquid having a flash :point from 100 to 200F (37.8-93C). 1 Examples: Kerosene, cresol E ro 8 -ao <_ c. *> O. *o . v-'oc o --2 Sllli '^2: * scr.1 5"-S ` -aCO 3^o 3 2 c .3...-.i;. 2:CcCSlOxMuuc a si* 2.3 Toxic by Inhalation. Any material having a threshold limit value (TLV) below 500 ppm for gases and vapors or below 10 mg/m5 (30 mppcf) for aerosols. Examples: Mercury, ammonia, carbon monoxide 2.4 Toxic by Ingestion. Any material toxic to the extent of having a single oral dose ; LD5q below 500 mg/kg of body weight for rats. Examples: Potassium cyanide, sodium j fluoride, oxalic acid . 2.5 Toxic by Absorption. Any material toxic' to the extent of having a single skin dose LDg0 below 2000 mg/kg of body weight as assessed in rabbits (Ref. 16 CFR 1500.40). Examples: Methyl alcohol, carbon tetrachloride 2.6 Toxic by Skin Corrosion. Any material that causes visible destruction or irreversi ble alterations in human skin tissue on | contact (Ref. 16 CFR 1500.41). , Examples: Hydrochloric acid, sulfuric acid ' Hze 5.S 2.7 Chronic Toxicity. Any materials having serious or irreversible chronic health or environmental toxicity as determined by the Corporate Industrial Hygiene and Medical Department or Environmental Control Department. Examples: Asbestos, lead salts^B^t^^ i 2.8 Radioactive Materials. Any materials that are fully covered by the Nuclear Regulatory Commission (NRC) regulations. All Alcoa locations using radioactive sources I have a radiation safety supervisor. (Ref. | Alcoa Engineering Standard 18.5.1.) | Examples: Radium salts 2.9 Hazardous Processes. Any material which in course of normal operations can produce gases, vapors, or particulates having one or more of the above character istics. Examples; Phosgene, anhydrous aluminum chloride \ ,2.10 Chemical Reactivity. Any material that :as a result of foreseeable storage or proicessing and/or as a result of interaction `with other materials has the potential of readily detonating, polymerizing with the release of a large amount of energy, under going spontaneous combustion, -and/or genera ting other hazardous materials (gases, vapors, or particulates) having one or more of the above characteristics. Examples of hazardous materials falling into this particular classification include explosive dusts (such as aluminum, organic material, etc.), oxidizing agents, reducing agents, ammonium nitrate, etc. j j j 2.11 The above criteria for classifying a material as hazardous are not meant to be all-inclusive or completely adaptable to every material which arises. In such cases, the Corporate Hazardous Materials Control Committee acting through its function's members will assign the material to the most appropriate category. | i i 3. ALCOA MATERIAL SAFETY DATA SHEET (AMSDS) The purpose of the Alcoa Material Safety Data Sheet is to assemble on one sheet of paper key information on each hazardous ! material relating to material description, ; ingredients, physical properties, safe handling and storage, fire and explosion data, emergency fire fighting procedures, health hazard information, first aid ! procedures, spill recovery and disposal, plus special information relative to protection and precaution data. It is ini tended that these data sheets be made j available to key persons in the Safety, \ I I Industrial Hygiene and Environmental Control : f Departments at all locations who need to be j aware of the safety and health aspects of hazardous materials. These people in cooperation with their corporate counterparts I will have the responsibility for assessing, j interpreting and passing judgment on J information presented in these material i safety data sheets. Following is a description of the various items on the Material Safety Data Sheet to ; aid understanding the completed form. 3.1 Emergency Telephone. It will be the : responsibility of each Alcoa location to select an appropriate telephone number for emergency information in matters pertaining to hazardous materials. This number may be for one of the following location management individuals: a) Safety Manager, b) Environ- j mental Manager, c) Fire Marshall, or d) some j other person designated to handle this i responsibility. 411538 0110 'rrrsTsf . 0 Engineering Standard A'CCQA Materials and Standards Section Pittsburgh HAZARDOUS MATERIALS - JDENTIFI CAT ION. & MATERIAL SAFETY DATA SHEETS __ 18.15 PAGE 2 1980-0A 3.2 Section I - Material Description. This section lists the material name, chemical name and formula, and other designations or synonyms. In most cases, material and chemical name will be the same; for example, product name - acetone, chemical name acetone. Also listed is the corporate stock number or numbers. Different con tainer sizes of the same material will carry different stock numbers. 3.3 Section II - Ingredients and Hazard Data. This section includes ingredi- ents, composition concentrations and toxicity data which indicates acceptable levels of exposure: i 3.3.1 Threshold Limit Value (TLV). Values ; are published by the Occupational Safety and ' Health Administration (OSHA), the American Conference of Governmental Industrial Hygienists (ACGIH), and the National Institute of Occupational Safety and Health (NIOSH). Threshold limit values used by , OSHA are known as Permissible Exposure | Limits - PELS. Threshold limit values j either ceiling concentrations (geak-^xpo- .. ' sures) or time weighted averages (TWA). Most jit are TWA. Time weighted--averages and/or ceiling exposure^yaldes refer to the approxii mate maximum^cottcentrations which most ___ ; employee sjn^y be exposed to day afte.jt-ddy' | withou t--Tadverse health effects----The OSHA 'PELS/which are the legail-limits, should be . / followed if the OSHA-RCGIH, or NIOSH values jvary from one another. ACGIH or N1PSH--Values which are lower than the OSHA values should j be followed in place of the OSHA PEL -Only in n those cases where the Corporate IndustrxSt-^^^i/ ; Hygiene Division decides that these values are more appropriate than the OSHA PELS to vyi{Dl * protect employee's health. Units for Thy JO-***-1 and PELS are usually ppm (parts per millipn) or mg/m3 (milligrams per cubic meter) . 3.3,2 Toxicity Terminology. 1. LD 50 - "Lethal Dose Fifty" The calculated dose of a particular chemical substance which results in the death of 50% of a given popula tion by any exposure route other than inhalation. When the percentage of population varies from fifty, it is denoted by changing the numerical j j 3. LDlq - "Lethal Dose Low" - The lowest dose of a particular chemical substance reported to have caused death in a given population when introduced by any route other than inhalation. 4. LCjjq - "Lethal Concentration Low" - The lowest airborne concentration reported to have caused death in a given population when administered by inhalation for a specified period of time. 5. TD1/3 - "Toxic Dose Low" - The lowest dose of a particular chemical sub stance which has been reported to produce a specified toxic effect in a given population when introduced by any route other than inhalation. e. TCj/j - "Toxic Concentration Low" - The lowest concentration in air for a particular chemical substance which has been reported to have produced a specified toxic effect in a given population. 7. (Skin) - The connotation of "skin" when used in conjunction with a TLV or PEL indicates that skin exposure j itself may be dangerous as a result | of systemic absorption. It is possi-j ble that even though the air con- i centration may be below the prescribed TLV limit value, a hazard may still exist as a result of skin j contact and absorption for those compounds characterized by "skin". 1 i TL 50 - "Tolerance Limit fifty" - The concentration of test material at which just 50 percent of the test animals are able to survive under test conditions for a specified period of exposure. j 9. TLM - "Tolerance Limit Median" Synonymous with TLS0. 10. TOC - Total Organic Carbon. 11. LFM - Lineal Feet Per Minute. subset value to reflect the particular lethal percentage (i.e. i j 12. STEL - Short Time Exposure Limit. LD^g would represent the calculated ; dose of a particular chemical j substance which results in the death j of 10% of a given population). , LC50 ~ "Lethal Concentration Fifty" - The calculated air concentration of ; a particular chemical substance for a specified period of time which results in the death of 50% of a given population. When the percen tage of population varies from fifty, it is denoted by changing the numerical value to reflect the particular lethal percentage (i.e. LC15 would represent the air concen tration of a particular chemical substance which results in the death of 15% of a given population) . 3.4 Section III - Physical Data. Definitions: (Both "C and *F and units for all other measurements are indicated.) 1. Physical Form - Gas, liquid, solid (powder, crystal). 2. Boiling Temperature - Temperature of the liquid at which its vapor pressure is equal to the atmospheric pressure (760 mm Hg). 3. :4. 1 | I Melt/Freeze Temperature - Temperature at which the liquid changes to a solid, or from a solid to a liquid. Vapor Pressure - Pressure, measured in pounds per square inch absolute (PSIA) or mm Hg, which is exerted by a volatile liquid at room temperature. 411538 0111 lo r any recipient titn if tnah Xicoa. no warrantiis/giiafantees 6f rtpre* sentations, express or implied are made as to the u tility or effectiveness o f the methods, processes, products or procedures described or recommended herein. A Engineering Standard ALCOA Materials and Standards Section - Pittsburgh Hft7ftRnons MATERIALS - IDENTIFICATION & MATERIAL SAFETY DATA SHEETS __________________ _ _.18.15 PAGE 3 1980-04 5. Evaporation Rate - Relative rate at which material will evaporate as com- * pared to ether (Ether = 1). |6. Specific Gravity - Ratio of the weight of a substance to the weight of an ! equal volume of water at (39.2F). This determines whether the material floats or sinks in water. ; 7. ! Density - The amount of matter contained! in a unit volume of a substance (mass ) per unit volume). Expressed as pounds ! per cubic foot or grams per cubic centi meter . 8. Solubility in Water - Degree in which the material will dissolve in water at room temperature. The following terms based on weight per cent are used. Negligible.........................less than 0.1 percent Slight.....................................0.1 - 1 percent Moderate...............................1 - 10 percent Appreciable.....................more than 10 percent Complete........... in all proportions | j l 9. Color - Odor - For example, colorless aromatic odor. See Chemical Card Number - Chemical Manufacturers Assoc. (CMA) card number (where available). 3. Additional Information - Lists any other special precautions not covered under metal corrosion or reactivity. Includes potential danger from inadvertent or accidental mixing. \3.7 Section VI - Health Hazard Information. 1. Effects of Exposure - Indicates the acute, subacute, and/or chronic adverse health effects which occur as a result of inhalation, skin contact, eye con tact, or ingestion and the levels at which these effects can occur if known. Examples of adverse effects include such things as dizziness, liver injury, nervous system damage, etc. Acute - Characterized by adverse effects ! which occur in close proximity (within ! 24 hours or less) to the actual exposure. Subacute - Characterized by adverse effects which occur after 24 hours and up to 3 months subsequent to the actual exposure. ! j j Chronic - Characterized by adverse effects which occur sometime later (in excess of 3 months) after the actual exposure. j j ; ano must oe reiumea on request, it shaii not oe reproouceo or copied, In whole or In part, or used on behalf o f others than Aluminum Com* pnny o f America or Its subsidiaries, without permission. This engineering standard Is provided solely for the purpose o f dis* 3.5 Section IV - Fire and Explosion Data. j 1. Flash Point - Temperature at which the liquid mixture gives off vapor sufficient to form an ignitable mixture with air near the surface of the liquid. Tempera tures are assumed to be for closed cup test unless marked oc for open cup test. 2. Auto-Ignition Temperature - Temperature at which the material will ignite spon taneously in air. 3. Flammable Limits (Explosive Limits) Volume percent range of vapor or gas mixture in air in which propagation of flame or explosion can occur on contact with source of ignition. | 4. Fire Fiqhtinq/Extinguishinq - Indicates specific type of extinguishment material to use, procedures to follow, precautions to take and conditions to avoid when the material is on fire or involved in a fire. Examples: Use carbon dioxide or dry chemical extinguishers. Do not use water spray. Shut off gas flow. Indicate firefighters' protective gear. 2. First Aid or Emergency Treatment j Eyes, Skin, Ingestion, Inhalation Indicates the measures to take when a I j hazardous material makes contact with an individual by one or more of the above ! routes of exposure and either has or is likely to have serious health consequen ces . 3.8 Section VII - Spill Recovery and Disposal Procedures. Indicates measures, procedures and precautions to be taken for the recovery of smali and large spills and the appropriate disposal proce dure for that size spill. Waste Disposal - Indicates the proper procedure for the safe disposal of the waste ! material during routine work not involving a spill. 3.9 Section VIII - Special Protection Information. Provides information re garding the need for protective equipment such as goggles, face shields, gloves, j aprons, respirators and related items. 3.6 Section V - Reactivity Data. 1. Reactivity Hazards - Indicates whether material is stable or unstable and if hazardous reactions can occur. Also lists the hazardous products produced from the reaction and the conditions and materials that should be avoided. 2. Metal Corrosion Problems - Indicates what metals are incompatible with the hazardous material so that contact can be avoided. 3.10 Section IX - Special Precautions and Comments. Indicates specific guide lines regarding need for the use of: 1. Approved solvent safety cans, carrying containers for corrosives. 2. Explosion-proof electrical equipment; special ventilation, use of exhaust hoods. 411538 01'12 g|. Engineering Standard ALCOA Materials and Standards Section - Pittsburgh HAZARDOUS MATERIALS IDENTIFICATION .& MATERIAL SAFETY DATA SHEETS __ 18.15 PAGE A 1980-QA : 3. Eye wash fountains, safety showers. ! 4. | Proper storage conditions including such factors ass store in a cool, dry, well-ventilated area with proper attention to separation of incompatible chemicals, avoidance of exposure to direct sunlight and any other special considerations. l i' j; j , j 15. Appropriate information listing proper j DOT hazard class only. Ij j 3.11 Section X - References. Indicates important references including volume, page . number, date and other relevant information. ACGIH - American Conference of Governmental Industrial Hygienists 1 AIA - American Insurance Association AIHA - American Industrial Hygiene Association ASTM - American Society for Testing Materials CAS - Chemical Abstracts Service CFR - Code of Federal Regulations CHRIS - Chemical Hazards Response Information System - 0. S. Coast Guard CMA - Chemical Manufacturers Association DOT - Department of Transportation NFPA - National Fire Protection Agency NSC - National Safety Council NIOSH - National Institute for Occupational Safety Health OSHA - Occupational Safety Health Act i J 1 i i j i I in n n n s rn c T T H T iT T T jn jjr^ t r 411538 0113 SUGGESTED PROCEDURES FOR IN-PLANT CONTROL OF HAZARDOUS MATERIALS Early identification of hazardous materials is vital if controlled usage is to be accomplished with minimum risk. The use of the Purchasing-Stores function as the primary control and check point seem to be logical and at locations where it has been tested, has proven to be very effective. The early participation of the requisition writer (and those who countersign requisitions) insures that the people who are closest to the in-plant users of the material are aware of the hazards. If the user is not aware of a hazard, we do have problems. It has been determined that four distinct areas of material entry into our plants and work areas needed to be controlled. They are: I) New items to be purchased or otherwise acquired. II) Materials in existing stores inventory and records. Ill) Materials not under direct stores control. IV) Controls applied to receipt, disbursement and inter-plant movement on materials including disposal of redundant, obsolete or waste materials. The following approach to handling each area is recommended: I. New items to be purchased enter our system by means of a Purchasing Department Requisition, (form number SF25) or Addition To Stores, (form number SF225). These forms are originated and approved by others and passed on to Purchasing for outside purchase or transfer into stores inventory and dispersal to the user. Recommended action by Purchasing Upon receipt of the SF25 or SF225, the known non-hazardous materials are to be processed and handled in the usual manner with no further delay. (Example - gears, shoes, nuts and bolts). If an Alcoa Material Safety Sheet has already been issued this should be noted on the Requisition and the Requisition processed. The resultant order should carry the notes as shown in 2) below. Any other materials on which there could be any question about possible hazards are to be copied and both copy and original are to be "Red Flagged" with a sticker or rubber stamp. The copy of the requisition need only be the first page as its function will be only to serve as a vehicle reminding others of their further action requirement. The copy is sent back to the requisition writer along with instruction sheets requesting more detail on material and how it will be used, etc. (These sheets are shown as attachment "A"). The "Red Flagged" original SF25 or SF225 should be promptly processed into an inquiry by purchasing in the usual manner except: 411538 0114 1) Every effort should be made in the inquiry to get the supplier to furnish full hazard information, such as, the suppliers Material Safety Data Sheets (MSDS, OSHA form 20), description of shipping name per Title 49 of Code of Federal Regulation (CFR 49), Spec. Sheets, catalogs, instructions for disposal after usage, etc. 2) No commitment is to be made until the "Red Flagged" copy information from the requisition writer and the vendor information has been assembled and a satisfactory determination made that the material is non-hazardous or that proper steps have been taken to meet the requirements of the hazard. This may or may not involve further action with the requisition writer and people from other disciplines. The purchase order for a hazardous material resultant from this action should carry a suitable basic cautionary note to the vendor such as: "All shipment documentation and outer containers shall be identified as to contents and hazards." (This could be incorporated in the item description so that it will be more surely recognized and acted upon.) If your plant has established a "plant coordinator" for Hazardous Materials, this person would have final judgment decision on what is or is not a hazardous material. All information is to be collated and entered on a Material Safety Data Sheet draft and forwarded to the individual who is responsible for editing and publishing the "Master listing" of Alcoa Material Safety Data Sheets. II. Materials in existing stores inventory will be reviewed and classified following the same basic routine as for new materials. Established standard stores items will be classified in Pittsburgh and thus avoid duplicate efforts at plants. Non-standard items in stores will be classified at the plant level. III. Materials not under direct stores control. Immediate classification control of material in this category is dependent upon the responsible action taken by the people who now have the material in their charge. As new or replacement materials are requisitioned and purchased, they would be reviewed and identified as per section I above. Question: Are any of these materials now being brought into our plants through non-purchasing controlled methods? (Via expense accounts, samples, systems contracts). These materials must be controlled by a local system. Examples of possible hazardous materials not now under direct stores control are alloy metals, medical department chemicals, laboratory chemicals, instrument mercury, direct charge operation supplies, pitch, coke, chlorine, acids, and caustic. Perhaps it will be desireable to move more of these items under stores control. 411538 0115 IV. Controls on receipt, disbursement and inter-plant movement of materials. In plants where material movement is made using public roads, it is necessary that the containers and our vehicles are properly identified according to the current D.O.T. regulations, (CFR-49). Inward shipments from our suppliers also must meet these regulations. It is required that we observe the B/L notes, package markings, and truck placarding and make sure that these words and markings are continued in the handling, storage and re-handling of the material. In case of question, advisory sources (shipper, vendor, producer, Alcoa traffic people) are to be used where necessary. Under the law, our documentation statements, package markings, and truck placarding must be correct and in agreement with each other. Overstatement of a condition is also a violation of the law although, at present, the penalties for overstatement are usually minimal. Control of materials shipped from plants. The shipment of our normal production materials is already well covered by instructions and practices established over the years and our Traffic Department has shipment controls established. The shipment of all other materials, if formalized, is usually done via a "Miscellaneous Shipping Order" or "M.S.O.". The placement of this responsibility has frequently (but not in all locations) been assigned to the stores-receiving area. The logic used for acquiring material can be reversed and used, with judgment, to ship a material from our locations. Returned goods can usually be return shipped in the same manner and the same package, however, the shipment of goods not readily identified as being returned merchandise from a specific order will require a very good and careful description from the individual desiring the shipment to be made, along with good traffic information and liaison. People who make informal shipments (direct mail or personal hand delivery) are cautioned that the same controls apply to them. Taking certain hazardous materials aboard aircraft and other public conveyances could be a prison offence. Your Traffic Department should be consulted if you have any transport questions. Disposal of redundant, obsolete and waste materials. Purchasing is normally charged with the negotiations involving the sale or other disposal to outside dealers of various plant wastes, such as, used lubricants, packaging materials etc. Under the existing or pending environmental regulations Alcoa has certain legal obligations. Be sure to directly involve the Environmental person contact at your plant to be certain the governmental controls are satisfied. Plant people should strive to segregate their waste materials so that the maximum recycle usage can be obtained for better resale value. The use of "Approved" hazardous waste disposal vendors having Federal, State, and/or Local certification is mandated for specified materials. The Environmental Control Department is responsible to know what, where, and who has been certified. 411538 0116 II ATTACHMENT A" "RED FLAG" STATEMENT & QUESTIONS There is a possibility that the material on your requisition could be defined as a "Hazardous Material". (See copy attached). Often this can be classified with more information from you. Please review the attached "Hazardous Material Definition" and supply as much of the following information as you can: 1. If your description is by trade name or catalog number, please complete the description in layman and scientific language. (Include both Generic Description & Proprietary Names) What are the ingredients? 2. Do you foresee any hazard potential? (Fire, corrosive, irritant, poisonous by ingestion, inhalation, skin absorption, etc.) 3. Does the product deteriorate when package is broken? Can or will any of the hazard shown in item 2 above occur in the presence of high humidity or rain? Does high or low transport and storage temperature create any hazard potential? 4. Any special protective equipment required for people handling or using the material? Can it be stored near other materials with safety? 5. What are you setting out to accomplish by use of the material? What is its function and how will it be used? What less hazardous alternate materials could be acceptable? 6. What disposition can be made of material after it has served your purpose? Any ecology problems? Any potential salvage? 411538 0117 ALCOA HAZARDOUS MATERIAL DEFINITION: GASES, VAPORS, LIQUIDS, SOLIDS OR PARTICULATE HAVING ONE OR MORE OF THE FOLLOWING CHARACTERISTICS: 1. Flammable Below 100F(37.8C) FLASH POINT, CLOSED CUP 2. Combustible Between 100 t 200F FLASH POINT, CLOSED CUP (37.8 & 93.3C) 3. Toxic by Inhalation Threshold Limit Value (TIV) Gas or vapor, ppm Below 500 Particulate, mg/mi Below 10 Particulate, mppcf Below 30 ft. Toxic by Ingestion Single oral dose mg/kg of body height LDso FOR RATS Eclow 500 5. Toxic by absorption Skin contact (dermal) mg/kg of body weight U)50 for rabbits 6. Chronic Toxicity Below 2000 Materials having serious or IRREVERSIBLE CHRONIC HEALTH OR ENVIRONMENTAL TOXICITY AS DETERMINED BY THE CORPORATE Industrial Hygiene and Medical Dept, or Environmental Control Dept. 7. Visible Destruction or Alterations to Tissue at Site of Skin Contact 2'i-hour test 8. Hazardous Processes 9. Chemical Reactivity 10. Radioactive Materials In course of normal operations, can PRODUCE GASES, VAPORS, OR PARTICULATE HAVING ONE OR MORE OF THE ABOVE CHARACTERISTICS. Any MATERIAL THAT, AS A RESULT OF FORSEEABLE STORAGE OR PROCESSING AND/OR AS A RESULT OF INTERACTION WITH OTHER MATERIALS, HAS THE POTENTIAL OF READILY DETONATING, POLYMERIZING WITH THE RELEASE OF A LARGE AMOUNT OF ENERGY, UNDERGOING SPONTANEOUS COMBUSTION, AND/OR GENERATING OTHER HAZARDOUS MATERIALS (GASES, VAPORS OR PARTICULATES) HAVING ONE OR MORE OF THE ABOVE CHARACTERISTICS. These materials are fully covered by the Nuclear Regulatory Commissi ox (HRC) REGULATIONS. ALL ALCOA LOCATIONS USING RADIOACTIVE SOURCES HAVE A RADIATION SAFETY SUPERVISOR. TABLE OF CONTENTS SECTION Introduction Control Procedures Plant Procedures Chemical Reactions CHEMTREC Contacts Identification AMSDS Index - Letter of 1978 June to all locations regarding formation of the Hazardous Materials Control Committee - In Plant Purchasing control procedures for hazardous materials obtained from outside vendors or other locations - Local plant procedures and requirements including contact personnel, etc. - Hazardous chemical reactions involving aluminum Names and telephone numbers of Alcoa persons to be contacted in emergencies CHEMTREC (Chemical Transportation Emergency Center) by Engineering Standard 18.15 - Identification and Description of Material Safety Data Sheets (AMSDS) Alcoa Material Safety Data Sheets covering most materials used and/or produced by Alcoa Alcoa materials used and/or produced Engineering Standard 18.15.1. Alphabetical listing of Alcoa Material Safety Data Sheets, including AMSDS number and cross referencing ACKNOWLEDGMENT We wish to acknowledge appreciation to the General Electric Company and Mr. J. 0. Accrocco, Customer Service Manager, for giving us permission to use their collection of material safety data sheets in the preparation of the Alcoa Material Safety Data Sheets (AMSDS). (Ref. letter J. 0. Accrocco to A. B. McKee 1979-10-01) 411538 0119 FROM A. B. MC KEE ALCOA TECHNICAL CENTER - C TO MR. D.A. WHITFIELD PITTSBURGH - WPH 1980 March 06 RE: ALCOA MATERIAL SAFETY DATA SHEET MANUAL Ref: Sheets No. 12-23 ________ Attached to your copy only are final drafts of the following safety data sheets. These sheets have had a preliminary review by the committee and final approval by those members who responded. No. No. No. No. No. No. No. No. No. No. No. No. 12 13 14 15 16 17 18 19 20 21 22 23 Acetic acid, glacial Ammonia, anhydrous Calcium hydroxide Calcium oxide Carbon monoxide Carbon tetrachloride Chromic acid Neu-Tri solvent (trichloroethylene) Phosphoric acid Propane, liquid . Sodium carbonate, anhydrous Trichloroethylene A.B. MC KEE ABM/rsl Attachments cc: Members of Corporate Hazardous Materials Control Committee J.S. Boyt, Pittsburgh 07 H.P. Brueschke, Pittsburgh 19 A.E. Davis, Pittsburgh 24 R.E. G.C. R.M. R.L. Edgington, Pittsburgh 22 Heise, Pittsburgh 06 James, Pittsburgh 07 Miller, Pittsburgh 08 A.B. McKee, ATC-C B.N. Peak, Pittsburgh 18 J.R. Stemler, ATC-C R.E. Toth, Pittsburgh 03 D.A. Whitfield, Pittsburgh WPH CO ALCOA 411538 0120 ST-436S (REV. 11-38) For Internal Company Use Only - Not To Do Distributed Outsldo The Company 1 m ALCDA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. i0 D Flammable O Combustible Toxic By: PRODUCT ASBESTOS Corrosive Explosive 0 Ingestion Water Reactive Radioactive Oxidizer Chemically Reactive C3 Inhalation 0 Absorption Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Materia) Name: ASBESTOS Chemical Name & Formula: Chrysolite (H^Mg^Si^Og) and Amphibole Other Designation: Amosite Corporate Stock No.: Manufacturer: Section II. INGREDIENTS Chrysolite (Serpentine Asbestos) Hydrated Magnesium Silicate (95% of commercial asbest >s is this type) % Amphibole Asbestos - Silicates of iron, calcium and magnesium with little water. Grey-brown color. Fibers have harsh, brittle acicular texture. HAZARD DATA 8-hr. TWA* (OSHA) 2 Fibers/cc of air which are greater.than 5 microns length. dSHA ceiling TLV: 10 Fibers per cc of air *0SHA has proposed this valu be reduced to 0.5 fibers/cc. Section III. ' PHYSICAL DATA Physical Form: Fibrous minerals Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O": Color: Greyish-white fibers Odor: Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. Non-combustible I I Flammability Limits In Air I j Lowe/ I Upper II Highly resistant to heat and fire. Section V. REACTIVITY DATA Chrysolite: Resistant to degradation by alkaline attack. Amosite: Heat resistance superior to chrysolite. Crocidolite (Blue): More resistant to acid attack than the above two. These asbestos materials are stable and relatively inert. In some situations, asbestos can maintain its integrity at temperatures up to 1700C (3092F). 411538 0022 No. 40 Section VI. HEALTH HAZARD INFORMATION +LV TIM (8 HR) 2 fiber/cc 5 pm length The health hazard with asbestos arises from minute fibers which have-been statistically' shown to have produced lung cancer in asbestos workers after prolonged exposure. ' Asbestos tape, especially when unsized,, will shed fibers on ; handling^. Tape mustr.be s- handled in such a way jthat the rate of air-borne fiber generatiori'andthe ventilation f provided interact to keep the 8 hour TWA and ceiling concentrations below the1 established legal limit. Plant air sampling and analysis are required to insure conformance. * * Respiratory protection is required for conditions in which the 8: hour TWA or ceiling ' ` ^ concentrations is exceeded. Good hygiene practices should be observed to avoid, ingestion of asbestos fibers. ... ^~ '-.As. . Ingestion of asbestos may lead to cancer of the digestive tract. Suspected exposures should be reported to the Industrial Hygiene Department. Special concern.'exists .during' demolition and delagging work which may release^large quantities of asbestos dust ih : the air. Asbestos is a progress disease which may develop fullyvin. 7-9 > years and cause death as early as 13 years after first exposure. ,-.i ` Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Wear dust mask, glovesjand disposable paper suit when working in area having excessive asbestos dust concentration. Contact Industrial Hygiene group for air monitoring. Scrap asbestos should be disposed in sealed plastic bags in steel drums., J Drums'must: .be marked with special asbestos label and shipped to approved disposal site. kl; * -i'-. For clean-up use special vacuum sweeper to avoid air or water-borne hazards from minute asbestos fibers. ; Section VIII. SPECIAL PROTECTION INFORMATION : General ventilation and local exhaust ventilation must be adequate to keep asbestos c fiber concentrations in work place air below the TWA and ceiling TLV limits. .. Use NIOSH approved respiratory protection where the TLV concentration is or may be exceeded. ; J The selection of appropriate respiratory protection (dust mask, self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration present. Respiratory apparatus is required for worker protection under conditions in which the 8 hour TWA Is exceeded. It is suggested.that."workers regularly.' handling large amounts of asbestos should frequently launder'.outer work clothing .and r should shower after work before changing into street clothing. v Section IX. SPECIAL PRECAUTIONS 8t COMMENTS Dust mask and disposable coveralls must be worn when working" with rasbestbs. All con taminated disposable clothing and asbestos containing wastes must be placed in sealed plastic bags and disposed in steel containers. .a Asbestos workers who are also smokers have a substantially increased health*(risk from lung cancer from asbestos exposure as compared to non-smokers.. ; V, .; ` D.O.T. Requirements 4115380023 ORM-C Section X. REFERENCES ASTM No.: D2100 Other: (l) Journal ,*bf Hazardous Materials Chemical Abstracts No.: Vol. 3, No. 2 (1979) 125-147 CMA Chemical Safety Data Sheet No.: Review of Asbestos Substitutes NFPA Guides No.: In Industrial Applications NSC Data Sheets: (2) ACW Safety Data Sheet ! Supplier Product Literature: Other: Pg. 545 OSHA Manual 2206, Subpart Z 1910.1001 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS CD Flammable CD Combustible Toxic By: No. 41 PRODUCT DOWTHERM G Corrosive O Explosive IS! Ingestion O Water Reactive CD Oxidizer D Radioactive Chemically Reactive E Inhalation (Kl Absorption Phone No. Date: Section I. MATERIAL DESCRIPTION Material Name: DOWTHERM G, A heat transfer fluid Chemical Name & Formula: Mixture of Biphenyl-Phenyl Ether and Biphenyl Oxide Other Designation: Fluid made up primarily of Di and Triaryl Ethers Corporate Stock No.: Manufacturer: Dow Chemical Co. (Product Code 25593) Section II. INGREDIENTS % Biphenyl-Phenyl Ether 70 Biphenyl Oxide 30 Trace impurities: Prior to mid-1979, product con tained typically 50-1000 ppm of MCB (Monochloro Biphetyl) Since mid-1979 supplier guarantees less than 50 ppm. (See Section VII) *TLV: 1977 ACGIH for Biphenyl-Phenyl Ether mixture (vapor) is 1 ppm (7 MG/M^) which is also the OSHA standard. HAZARD DATA TLV 1 ppm* Rat Oral LDLo 2-4 GM/Kg Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid 575F (301. 7C) Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density :- @ 25/25C------ 1.03-1.20 "Solubility In H2O": 11.4 Wt. % Color: Straw-colored Odor: Aromatic Section IV. FIRE AND EXPLOSION DATA Flashpoint Auto-Ignition Temp. 305F (151.7C) Unknown Flammability Limits In Air Unknown Lower Upper Extinguishing Media: Dry chemical, CO^, Foam, Water Fog. Vapor is easily ignited. Dissipate and cool vapor clouds with water spray or COj. NIOSH approved self-contained breathing apparatus should be worn by fire fighters. Section V. REACTIVITY DATA 1 1 This is a stable liquid. It does not undergo hazardous polymerization. It is incompatible! with oxidizing agents. At high temperatures, oxidation can produce carbon monoxide. No unusual explosion hazards. i 411538 0024 No. 41 Section VI. HEALTH HAZARD INFORMATION 1 TLV loom (vapor) ; 7 mg7ro^~ Product has Tow volatility. Inhalation is hazardous only when.misted .or heated. Nausea and headache due to odor. Repeated or prolonged, skin contact 'maY.Vcause'^deriiiat-itis.^^'-'.f'- Thermal burns from hot liquid or vapors. Eye contact may cause,i^n6r":'irritation,Ano; ^ corneal damage. Lethal dose by ingestion for 100 lb. person may be less than 6 ounces FIRST AID: 1 ;;:/V : Eve Contact: Flush with running water for 15 minutes. Go to medicaidepartmen t if ,, irritation persists. , ., : Skin Contact; Flush well with water. : -, Inhalation: If ill effects occur, remove to fresh air and-consult .physician'. Ingestion: Induce vomiting and get medical help;. (No te, to physician: No specific antidote known.) Section Vil. SPILL, LEAK & DISPOSAL PROCEDURES See special note in Section II regarding MCB. Disposal if fluid contains less than 50 ppm MCB: Soak up spills with absorbent material and collect for disposal. Should avoid contact with liquid and inhalation of vapors. Incinerate waste in approved equipment or send to approved landfill.: Do not send to sewer. If fluid contains more than 50 ppm MCB: This fluid is considered by EPA/RCRA: to:, be a PCB type material and must comply with PCB regulations for shipment, storage and disposal. ... :v-' Section VIII. SPECIAL PROTECTION INFORMATION General ventilation usually adequate. Local exhaust should be used;where material is misted or heated. Provide adequate local exhaust ventilation to meet-*TLV requirements. Use NIOSH approved respiratory protection where the TLV concentration xS or may be ` - exceeded. The selection of appropriate respiratory protection (s e1f-contained breathing apparatus, supplied-air respirator, etc.) should'be based on the actual or potential ' concentration present. Respiratory equipment not usually needed because of low vapor pressure. For emergencies, full face mask plqs an organic vapor canister may be needed. Vapor is flammable - dissipate and cool with water spray. Use gloves and protective . , equipment to avoid skin contact. Wash contaminated clothing before reuse. Use safety . glasses where splashing may occur. Eye wash fountain shall be close enough to be reached within 5 seconds. , ` ... .> \\ YK Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in cool, ventilated area away from oxidizers. * Practice reasonable care with use since chronic properties are not fully established. Avoid direct contamination of water because of possible fish toxitity. ,' No smoking or eating should be allowed in areas of use. & I .-V I. . I . D.O.T. Requirements NOT REGULATED Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No. NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: TEher: Dow Bulletin /: ' ACW Safety Data Sheet' 411538 0025 For Internal Company Uso Only - Not To Bo Distributed Outsldo Tlw Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS Ho.Ji CD Flammable CD Combustible Toxic By: PRODUCT ML-575 O Corrosive CD Explosive CD Ingestion CD Water Reactive Q Oxidizer CD Radioactive CD Chemically Reactive DD Inhalation CD Absorption Phone No. Date: 80-03-28 Section l. MATERIAL DESCRIPTION Material Name: DORTAN N 14; METAL WORKING FLUID 503; MOBILMET 27; Chemical Name & Formula: Complex mixture of petroleum hydrocarbons Other Designation: Petroleum base cutting oil Corporate Stock No.: 052-510--0575 Manufacturer: Exxon - Chevron - Amoco - Mobil - Texaco TRANSULTEX D Section II. INGREDIENTS Petroleum Hydrocarbons % HAZARD DATA 100 TWA: 5 mg/m as oil mist* 500 PPM as oil vapor *OSHA permissible exposure limit. Section 111. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid 525-900F (274-482C) Freeze-<Melt Temp.: Vapor Pressure: K. ' 111111 ^8 @ 20 C Evaporation Rate: (Ether = 1) <.01 . Specific Gravity: -91 Density: 56.7 lb. per ft. "Solubility In H2O'': Negligible Color: Clear amber Odor: Mild sulfurized petroleum odor Other Vapor Density (Air =1) > 11 Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. | Flammability Limits In Air 340F (171C)]' I z by Volume in Air| 1% I Lower I Upper {6% Extinguishing media - Foam, dry chemical, C02 and water fog. Use air-supplied breathing equipment for enclosed areas. Fire fighters should wear full-protective clothing. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Personnel engaged in fighting fires involving ML--575 should wear NIOSH approved self-contained breathing apparatus. Section V. REACTIVITY DATA This material is considered to be stable. Strong oxidants like liquid chlorine, oxygen, nitric acid and sulfuric acid could cause a reaction. Thermal decomposition may produce carbon monoxide and sulfur oxides. Fumes. 411538 0026 No. 24 Section VI. HEALTH HAZARD INFORMATION TLV TWA 5 mg/m^ as oil mist/TWA 500 PPM as oil Prolonged or repeated skin contact may cause mild skin irritation. vapor. First Aid: Skin Contact - Wash thoroughly with soap and warm water. If irritation persists, radic:aaJl. attention. Z~a Contact - Flush with clear water for 15 minutes or until irritation subsides. irritation persists, call physician. In restion - Do^ not induce vomiting. Call physician. Inhalation - Remove to fresh air. If necessary, call physician. get If ( Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Small Snills Absorb into a material such as sand, rags or sawdust. Larg_e__Snills Dike up and transfer to container. Notify local Environmental Control 5Camager. Reclaim by filtration or distillation or dispose via licensed waste solvent disposal company or via approved landfill or incinerate according to local, state and federal anti-pollution regulations. !Section VIII. SPECIAL PROTECTION INFORMATION Tse i-permeable gloves and aprons if needed to avoid prolonged skin contact. c T=e splash goggles or face shield when eye contact may occur. Tse with exhaust ventilation to maintain airborne concentration below the recommended threshold limit values (TLV). Where the TLV concentration is or may be exceeded, NIOSH approved respirators should be worn. The selection of the appropriate respirator (chemical cartridge respirator, self-contained breathing apparatus, supplied-air respirator, etc.) jshould be dictated by the actual or potential -concentration at hand. Section IX. SPECIAL PRECAUTIONS & COMMENTS________________________________ ' Seep container closed when not in use. Do not contaminate cutting fluid circulating system with foreign materials. Provide baffles on machine to minimize oil mist. D.O.T. Requirements Not. regulated. Section X. REFERENCES ASTM ,\o.: O.ervcal Abstracts No.: OVA Chemical Safety Data Sheet No.: K??A Guides j vso D:ta S-ee:s: No.: : col -r Product Literature: Exxon MSDS Other: 411538 0027 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET ALCOA HAZARD CHARACTERISTICS O Flammable Combustible O Corrosive 0 Explosive 0 Water Reactive O Radioactive O Oxidizer O Chemically Reactive Toxic By: 0 Ingestion 0 Inhalation 0 Absorption NO. 25 PRODUCT ML-921 Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: SAFETY SOLVENT Chemical Name & Formula: Other Designation: Corporate Stock No.: Manufacturer: Chlorinated hydrocarbon mix Motor Cleaning Mix; S.C. Cold Degreaser #49 052-770-0921 Standard Oil Company, Central Solvents Company, Ashland Oil Company Section II. INGREDIENTS % HAZARD DATA Stoddard Solvent Petroleum Distillate 70 TWA - 500 ppm as vapor TWA - 5 mg/m^ as oil mist Methylene Chloride CHjCl. Dichloromethane (0SHA) 25 TWA - 200 ppm* (ACGIH) i Perchloroethylene CCl^CCl^ Tetrachloroethene 5 TWA - 100 ppm* (0SHA) *OSHA PELS Methylene (zy CFK J.yi0.1U00) should be consulted Chloride and Perchloroethylene. ACGIH for TWA acceptab Le of 200 p >m ceiling concentrations for Methylene Chloride for is advised instead of 0SHA TWA of 500 ppm due to toxico .ogical c msiderations. See AMSDS Nos. Section 111. PHYSICAL DATA other Physical Form: Liquid Boiling Temp.: 105F (40. 6C) Freeze-Melt Temp.: Vapor Pressure: 286 mm Hg Evaporation Rate: Specific Gravity: (Ether = 1) 0.12 1.370 Density: "Solubility In H20": Color: Odor: 85.3 lb. per ft. Negligible Clear Sweet, etheral Vapor Density (Air = 1) 3.6 Section IV. Flashpoint 100-200F FIRE AND EXPLOSION DATA (37.8-93.3C) | Auto-Ignition Temp. J Flammability Limits In Air I Lower | Upper { __________ Jj| Extinguishing media - Use foam, CO^, dry chemical or water fog. Cool containers with water spray. Use NIOSH approved self-contained breathing apparatus for fire fighting. Section V. REACTIVITY DATA This material is considered to be stable. High temperature sources, welding arcs and open flames should be avoided because they could induce thermal-oxidative decomposition to produce toxic reaction products such as hydrogen chloride and small amounts of phosgene and chlorine. Prolonged exposure to water may cause noticeable hydrolysis. Avoid contact with alkali metals and finely powdered aluminum and magnesium. 411538 0028 No. 25 Section VI. HEALTH HAZARD INFORMATION TLV See Section II Exposure contact causes eye and skin irritation; acts as an acute anesthetic when inhaled at elevated concentrations. Acute exposures at elevated concentrations may also result in cardiac arrythmias. Methylene chloride metabolizes to produce carbon monoxide in f the body and reduces the oxygen-carrying capacity of the blood. Prolonged exposures ( to elevated concentrations of ML-921 may result in kidney and/or liver damage. First Aid: Eye and Skin Contact Flush with plenty of running water. If irritation persists, get medical attention. Inhalation - Remove to fresh air. Keep patient warm. Get medical attention. Ingestion - Do not induce vomiting. Contact physician immediately. Section VH. SPILL, LEAK & DISPOSAL PROCEDURES. Small Spill - Absorb on absorbent material such as rags, saw dust or vermiculite. Use rubber gloves and avoid breathing vapors. Evaporate off the solvent in an exhaust hood or bury in an approved landfill. Large Spill - Evacuate area; notify environmental personnel. Provide ventilation. protective equipment. Contain and recover liquid when possible. Use Reclaim waste solvent by filtration or distillation or dispose through licensed waste solvent disposal company. Section VIII. SPECIAL PROTECTION INFORMATION;f V_Use efficient ventilation to meet TLV requirements. Where the TLV concentration is or maybe exceeded, NIOSH approved respiratory protection should be worn. The selection of the appropriate respirators (chemical cartridge respirator, self-contained breathing apparatus, supplied-air respirator, etc.) should be determined by the actual or potential concentration present. Use neoprene or Viton gloves plus goggles or a face shield where splashing may occur. Eye wash fountain shall be close enough to be reached within 5 . seconds. The 10-hour TWA for CO must not exceed about 9 ppm where exposure to methylene chloride occurs unless CCI2CCI2 is also controlled to a lower level then the TLV. Section IX. SPECIAL PRECAUTIONS & COMMENTS Avoid airborne concentration buildup and exposure to high temperature. No smoking when vapors of this material are present. Store in cool, well ventilated area away from heat source. Open containers cautiously. When methyl chloride vapors are drawn into combustion chamber of space heater, acid fumes can cause severe corrosion damage even at levels below TLV. Benzene concentrations should be checked to determine that concentrations are below the acceptable TLV concentrations for benzene as defined by OSHA. D.O.T. Requirements COMBUSTIBLE LIQUID Section X. REFERENCES ASTM No.: Other Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Solvents & Chemicals Company 411538 0029 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS NO- 26 ALCOA Flammable Corrosive Combustible CD Explosive Toxic By: D Ingestion PRODUCT PL-132 Water Reactive Radioactive CD Oxidizer CH Chemically Reactive 00 Inhalation D Absorption Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: Mobilmet 160; Do-All Power Cut HD-500 Chemical Name & Formula: Hydrocarbon Mixture Other Designation: Corporate Stock No.: Manufacturer: 051--610--0132 Mobil Oil; Do-All Company Section II. INGREDIENTS Refined Mineral Oil Petroleum Sulfonate Emulsifiers Chlorinated Paraffin Rosin Oil Soaps Extreme Pressure Additives and Anti-Oxidant (Supplier Confidental) % HAZARD DATA 50 15 q 15 TWA - 5 mg/m as oil mist 10 (OSHA) 10 TWA - 500 ppm as oil vapor Acute oral toxicity LD50 greater than 5g/Kg Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid Freeze-Melt Temp.: Vapor Pressure: ^ -05 (mm HG @ 25 C) Evaporation Hate: Specific Gravity: Density: .99 61.7 lb. per ft. "Solubility In H2O": Color: Amber Odor: Mildpetroleum Other Vapor Density (Air = 1): Over 1.0 Section IV. FIRE AND EXPLOSION DATA Flashpoint > 250F (121C) I Auto-Ignition Temp. [Flammability Limits In Air j 315C (approx. 600f| | Lower [Upper Jj Extinguishing Media - Foam, dry chemical, CO2 and water fog. Use NIOSH approved self contained breathing apparatus for fire fighting. Use water spray to cool fire exposed containers. Section V. REACTIVITY DATA This material is considered to be non-corrosive and non-reactive to air, water and heat. Strong oxidizers such as chlorine, oxygen, nitric acid and sulfuric acid could cause a reaction. 411538 0030 Section VI. HEALTH HAZARD INFORMATION TLV No. 26 5 mg/m^ oil mist; TWA-500 ppm for oil vapor. First Aid: Inhalation - Remove to fresh air. If appropriate, call a physician. Ingestion - Do not induce vomiting. Call a physician. c Eye Contact - Flush with plenty of water for at least 15 minutes. Get medical attention. Skin Contact - Wash with soap and water. Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Small Spills - Absorb on a material such as vemiculate, sand, rags or sawdust. Large Spills - Dike up and transfer to container. Contact local Environmental Control Manager. Dispose of in landfill or incinerate according to local, state and federal anti-pollution regulations. Section VIII. SPECIAL PROTECTION INFORMATION Use adequate exhaust ventilation to meet TLV requirements. Where the TLV concentration1* is or may be exceeded, NIOSH approved respiratory protection should be worn. The selection of the appropriate respiratory protection (chemical cartridge respirator, self-contained breathing apparatus, r.upplied-air respirator, etc.) will depend upon actual or potential concentration present. Use impermeable gloves and apron when handling to avoid prolonged skin contact. Use splash goggles when eye contact may occur. Section IX. SPECIAL PRECAUTIONS & COMMENTS Avoid prolonged breathing of mists and sprays. D.O.T. Requirements Not regulated. Section X. REFERENCES AST.M No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: 1 1 1 Corporation MSDS Other: 411538 0031 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No__iZ______ ALCOA (Z3 Flammable Cl Corrosive CD Water Reactive CD Oxidizer O Combustible CD Explosive Cl Radioactive Cl Chemically Reactive Toxic By: Ingestion El Inhalation CD Absorption PRODUCT PLt145 Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: Kermac 100X; Mineral Spirits; Chevron 325 Solvent; Varsol 1; Sovasol 5; and more Chemical Name & Formula: Hydrocarbon Mixture Other Designation: Petroleum Spirits; Naptha; Ligroin Corporate Stock No.: Manufacturer: 051-770-0145 Kerr-McGee Refining, Ashland, Chevron, Exxon, Mobil and more Section II. INGREDIENTS Hydrocarbon Mixture % 100 HAZARD DATA 3 TWA - 5 mg/m as oil mist* (OSHA) v TWA - 500 ppm as oil vapor NOTE: Maximum Aromatic Content is 32%. *OSHA PEL for oil mist. Section III. PHYSICAL DATA Other Physical Form: Boiling Temp.: Liquid 300-400F (149-204C) Vapor Density (Air = 1): 4.8 Freeze-Melt Temp.: Vapor Pressure: 5.3 mm Hg at 100F Evaporation Rate: <1 (Butyl Ac = 1) Specific Gravity: .7645 Density: 47.6 Tb. per ft. "Solubility In H20": Negligible Color: Water white Odor: Hydrocarbon Naphtha (gasoline-type odor) Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. 100F (37.8C)| __________ [Flammability Limits In Air | I .9 [ Lower I Upper | 5.0% Extinguishing Media - Foam, dry chemical, C0_ and water fog. Use NIOSH approved self-contained breathing apparatus for fire righting. Use water spray to cool fire exposed containers. Section V. REACTIVITY DATA This material is considered to be stable. Strong oxidants like liquid chlorine, oxygen, a reaction. No special hazards from combustion products. nitric acid and sulfuric acid could cause 411538 0032 No. 27 Section VI. HEALTH HAZARD INFORMATION TLV TWA-5 mg/rn^ as oil mist; TWA-500 ppm as oil Excessive inhalation may cause local irritation, drowsiness, collapse, muscle twitching, coma and, later, pneumonia. First Aid: Skin Contact - Wash with soap and water. Eve Contact - Flush with plenty of water for at least 15 minutes. If necessary, a physician. Ingestion - Do not induce vomiting - call a physician. Tnhalation - Remove to fresh air - call a physician. vapor. r call Section VII. SPILL. LEAK & DISPOSAL PROCEDURES__________________________ ______________________ Small Spills - Absorb onto a material such as sand, rags or sawdust. Large Spills - Dike up and transfer to container. Contact Environmental Control Manager. Dispose of in landfill or incinerate according to local, state and federal anti-pollution regulations. Section VIII. SPECIAL PROTECTION INFORMATION__________________________ _______________________ ( Provide adequate explosion proof exhaust ventilation to meet TLV requirements.NIOSHv. approved respiratory protection should be worn where the TLV is or may be exceeded. The selection of the appropriate respiratory protection (chemical cartridge respirators, self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration present. Itcpemeable gloves and apron should be worn to avoid prolonged skin contact. Dse splash goggles when eye contact may occur. Section IX. SPECIAL PRECAUTIONS & COMMENTS Keep away from heat and open flames. D.O.T. Requirements COMBUSTIBLE LIQUID Section X. REFERENCES_____________________________________________ _ ^STM No.: ~" Other: CHRIS (1974) Chemical Abstracts No.: 8032-32-4 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: 1 NSC Data Sheets: ! Supplier Product Literature: Kerr--McGee C 411538 0033 For Internal Company Use Only - Not To Bo Distributed Outside The Company MATERIAL SAFETY DATA SHEET ALCOA HAZARD CHARACTERISTICS Flammable Combustible O Corrosive CD Explosive CD Water Reactive Radioactive Q Oxidizer CD Chemically Reactive Toxic By: CD Ingestion ED Inhalation CD Absorption NO._28_ PRODUCT PL-229 Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: Chemical Name & Formula: Corporate Stock No.: Manufacturer: KENSOL 51; KERMAC 616; SOLVENT 600 Mixed Petroleum Hydrocarbons; Mixture of 78% Saturates 11% Aromatics & '11% Olefins 051-620-0229 Witco (Kendall); Kerr-McGee; Drake; Ashland Section II. INGREDIENTS Saturated Hydrocarbons Aromatics Olefins % HAZARD DATA 3 78 TWA - 5 mg/m :as oil 11 (0SHA) 11 TWA -- 500 ppm as oil *0SHA PEL for oil mist. Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O" Color: Odor: Liquid 520F (271C) 10F (-12.2C) Nil Nil .82 51.1 lb. per ft.' Nil Light colored Mild petroleum Other Vapor Density (Air =1): 7.98 Section IV. FIRE AND EXPLOSION DATA Flashpoint 290F (143C) | Auto-Ignition Temp. 1 |1Flammability Limits In Air | Lower I Upper _____ L-7* _ 110.0% Extinguishing Media - Foam, CO2 and dry chemical, water fog. Precautions - Do not use water except as fog. Use NIOSH approved self-contained breathing apparatus for fire fighting. Section V. REACTIVITY DATA This material is considered to be stable. Avoid all sources of ignition (including static electricity) when stored, handled or used at temperatures over 100 F. Strong oxidizers such as chlorine, oxygen, nitric acid + sulfuric acid could cause a reaction. Thermal decomposition may produce CO^ and CO. 411538 0034 No. 28 Section VI. HEALTH HAZARD INFORMATION TLV TVA-5 mg/m3 as oil mist; TMA-500 ppm as oil Maximum concentration of the oil in air as mist is 5 mg/meter^. Nausea and central aPor- nervous system depression could occur due to overexposure to vaPors. This material has a tendency to act as a defatting agent in skin contact which might produce dermatitis. /" First Aid: Eve Contact - Flush with water for at least 15 minutes. Call Physician if irritation persists. Skin Contact - Remove oil with cloth or paPer and wash area with soap and water. Inhalation - Overexposure to vapors - remove to fresh air. Call physician. If Swallowed - Do not induce vomiting. Call physician. Section VII. SPILL. LEAK & DISPOSAL PROCEDURES_________________________________________________ Small Spills - Absorb on a material such as vemiculite, sand, rags or sawdust. Large Spills - Dike up and transfer to containers. Dispose of in landfill or incinerate according to local, state and federal anti-pollution regulations. Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate explosion proof ventilation to meet TLV requirements. NIOSH approved respiratory protection should be worn where the TLV concentration is or may be exceeded. The selection of the appropriate respiratory protection (chemical cartridge respirator, self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration present. Impermeable gloves and apron should be worn to avoid prolonged skin contact. Use splash goggles when eye contact may occur. Section IX. SPECIAL PRECAUTIONS & COMMENTS________________________________________ Handling at elevated temperatures may produce excessive vapors requiring use of respiratory equipment or ventilation. D.O.T. Requirements Not regulated. Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Witco Company MSDS Other 411538 0035 For Internal Company Uso Only - Not To Do Distributed Outsldo Tito Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 29 0 Flammable CD Combustible Toxic By: PRODUCT PL-242 CD Corrosive CD Explosive CD Ingestion Water Reactive CD Radioactive ED Inhalation Phone No. Oxidizer CD Chemically Reactive CD Absorption Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: 140 SOLVENT 66/3 CODE 1106; DRAKESOL 140 Chemical Name & Formula Petroleum Hydrocarbon Fraction Other Designation: Corporate Stock No.: Manufacturer: 051-770-0242 Union Chemicals Division; Ashland; Drake Section II. INGREDIENTS Petroleum Hydrocarbon % 100 HAZARD DATA 3 TWA - 5 mg/m as oil mist (0SHA) TWA - 500 ppm as oil vapo: Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid 365-405 F (185-207 C) Freeze-Melt Temp.: Vapor Pressure: .5 mm Hg @ 68F Evaporation Rate: Specific Gravity: Density: (Ether =1) .08 -78 48.6 lb. per ft.^ "Solubility In H2O": Negligible Color: qjq,.. clear Mild petroleum Other Vapor Density (Air =1): 5.5 Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. 284F (140C)|_____________________________________ (Flammability Limits In Air I I 1.2 I 7.% I Lower I Upper Extinguishing Media - Foam, CO^, dry chemical and water spray. Precautions - Wear NI0SH approved self-contained breathing apparatus for fire fighting. Use water spray as a cooling media. Section V. REACTIVITY DATA This material is considered to be stable. Avoid heat, sparks, open flame and fire as possible sources of ignition. Strong oxidizing agents such as chlorine, oxygen, nitric acid and sulfuric acid could cause a reaction. 411538 0036 No. 29 Section VI. HEALTH HAZARD INFORMATION TLV TWA-5.0 mg/m3 for oil mist; TWA-500 ppm for vapor. Effects of exposure are drying of skin, eye irritation. Excessive inhalation may canse anesthesia, headache, dizziness, nausea and upper respiratory irritation. first Aid: Skin Contact - Wash with soap and water and apply a mild skin cream.. c Z~e Contact -- Flush with water; call a physician. Inhalation - Remove to fresh air. Apply artificial respiration if necessary and call a pnysicran. Ingestion - Do not induce vomiting. Call a physician. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES ' _______________ Small Spills - Absorb on a material such as vermiculite, sand, rags or sawdust. large Spills - Dike up and transfer to container. Contact Environmental Manager. Dispose of in landfill or incinerate according to local, state and federal anti-pollution regulations. Section VIII. SPECIAL PROTECTION INFORMATION____________ ____________ ' ____________ f Provide adequate explosion proof exhaust ventilation to meet TLV requirements. NIOSH ^ approved respiratory protection should be worn where the TLV concentration is or may be exceeded. The selection of the appropriate respiratory protection (chemical cartridge respirator, self-contained breathing apparatus, etc.) should be based on the actual or potential concentration present. Section IX. SPECIAL PRECAUTIONS & COMMENTS leep cool and away from possible ignition sources. Use with adequate ventilation. Avoid prolonged or repeated personal contact. D.O.T. Requirements Not regulated. Section X. REFERENCES AS7M No.: D*:=m:ca! Abstracts No.: C*ViA Chemical Safety Data Sheet No.: Ur PA Guides No.: ! NSC Data Sheets: ] S_op::=f Pfoduct Literature: UNION OIL COMPANY MSDS I Other: ____ ______________________ _ ^ 411538 0037 ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 30 CD Flammable CD Combustible Toxic By: PRODUCT PL-289 CD Corrosive CD Explosive CD Ingestion CDO Water Reactive Radioactive El Inhalation Phone No. CD Oxidizer CD Chemically Reactive CD Absorption Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: UNIFLEX DOS Chemical Name & Formula: Dioctyl Sebacate (Di-2-Ethylhexl Sebacate) Other Designation: Decanedioxc Acid Corporate Stock No.: Manufacturer: 051-490-0289 Union Camp Corporation - Prochemco C26H504 Section II. INGREDIENTS Dioctyl Sebacate % 100 HAZARD DATA 3 TWA -- 5 mg/m as mist For Internal Company Uso Only - Not To Be Distributed Outside The Company Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Liquid @ 4 mm Hg -- 464-479F N/A @ 392F -- 4.5 mm Hg (240-24SC) Evaporation Rate: Nil Specific Gravity: Density: .915 = .002 57.0 lb. per ft.^ "Solubility In H20": Negligible Color- Straw Color - APHA 50. max. Odor: Mild Other Vapor Density (Air=l): 14.8 Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. I Flammability Limits In Air 440F (227C)_____________ | 500F (260C)________ J____________________ Extinguishing Media - Foam, CO^, dry chemical, water fog. Water or foam may cause frothing. Use NIOSH approved self contained breathing apparatus for fire fighting. Lower Upper Section V. REACTIVITY DATA This material is considered to be stable. Strong oxidizers such as chlorine, oxygen, nitric acid and sulfuric acid could cause a reaction. Thermal decomposition may produce carbon nonoxide and other unknown organic compounds. 411538 0038 Section VI. HEALTH HAZARD INFORMATION TLV TWA-5 mg/m^ as mist Esters generally have a low toxicity. Inhalation of ester vapor or mist may cause interference with respiratory functions when present in sufficient concentration. First Aid: Skin Contact - Wash with soap and water. Eye Contact - Flush with running water for at least 15 minutes. Call physician. Inhalation - If respiratory functions are impaired, administer oxygen and call a physician. Ingestion - Call a physician. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Small Spills - Soak up on absorbent material such as vermiculite, rags or sawdust. Large Spills - Dike up and transfer to container. Contact Environmental Manager. Dispose in approved landfill or incinerate according to local, state and federal anti-pollution regulations. Section VIII. SPECIAL PROTECTION INFORMATION________________ ( Provide adequate exhaust ventilation to meet TLV requirements. NIOSH approved respiratory protection should be worn where the TLV concentration is or may be exceeded. The selection of the appropriate respiratory protection (chemical cartridge respirator, self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration present. Section IX, SPECIAL PRECAUTIONS & COMMENTS__________________ Tank Storage - Use 316 stainless steel or 3003 aluminum tank. Blanket tank with inert gas. Drums - Use a liner. D.O.T. Requirements Not regulated Section X. REFERENCES 7SSTM No.: Chemical Abstracts No.: 122-62-3 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Union Comp. Chemical Co. Other" M5DS 411538 0039 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 31 CD Flammable 0 Combustible Toxic By: PRODUCT ALUMINUM CHLORIDE 0 Corrosive O Explosive 0 Ingestion ANHYDROUS 0 Water Reactive 0 Oxidizer 0 Radioactive 0 Chemically Reactive 0 Inhalation O Absorption Phone No. Date: 80--03--28 Section I. MATERIAL DESCRIPTION Material Name: ANHYDROUS ALUMINUM CHLORIDE Chemical Name & Formula Same, AICI3 Other Designation: Corporate Stock No.: Manufacturer: Alcoa, Allied Chemical Corporation, Pearsall Corporation, Stauffer Section II. AICI3* FeCl3 SiCl4 NaCl INGREDIENTS % 99.8 .05 .03 .02 HAZARD DATA TLV - TWA 5 mg/m3* TLV for HCL:Ceiling - ppm* Technical Grade: 98.5% *0SHA criteria Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Solid Crystals (752 mm) 361F (182.7C) Freeze-Melt Temp.: 381F (194C) at 5.2 atm. Others Sublimation Temperature: 178 C (352 F) at 1 atm Heat of Solution: 576 cal/gm Hygroscopic: Yes Vapor Pressure: Evaporation Rate: Specific Gravity: Density: N/A at 25 C solid: 2.44 Loose, 65-85 lb./ft.3; Packed, 90-100 lb./ft.3 "Solubility In H20": Not soluble** Color: Light yellow, orange, gray or white Odor: Sharp, pungent, irritating, HC1 **Reacts vigorously evolving heat and forming HC1 gas and A1(0H)3; soluble in various Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Ignition Temp. (Flammability Limits In Air organic solvents. Lower Upper Not Flammable Anhydrous AlCl^ is not flammable. However, if at all possible, remove containers from area of fire. At elevated temperatures, AICI3 has appreciable vapor pressure making container rupture possible. Water contact evolves HC1 and much heat. Avoid water to fullest extent possible. Self-contained breathing apparatus and skin protection are needed for fire fighting if release of acid gases might occur. Section V. REACTIVITY DATA Non-reactive in dry air; highly reactive in moist air. Hydrolyzes vigorously in water to liberate HC1 with much heat evolved when heated, sublimes to evolve AI2CI5 vapor. Extremely corrosive to most metals in presence of moisture because of formation of HC1. c 411538 0040 Section VI. HEALTH HAZARD INFORMATION [ TLV TWA-5 mg/m3 for dust; TWft.-5 ppm for HCL Contact with skin very irritating, causing both chemical and thermal, burns when, contacted with moisture. Causes burns and eye damage. Causes choking and- coughing; Dust inhalation very irritating to upper respiratory tract. Irritation to respiratoryubract 'and;to skin will give adequate warning prior to serious damage which-could result from ' continued exposure. i * First Aid: .^ '-..j i :t - Gently wipe away all loose material. Wash promptly with copious quantities t of water. Remove dust-contaminated clothing proaplty. If irritationpersists,! get' prompt medical attention. May cause second-degree burns after few minutes contact. '... h <, Eye Contact - Flush immediately with water for 15 minutes or more, keeping eyes open. Get . prompt medical attention. Medicate only at "direction of physician. Inhalation - Remove to fresh air. If irritation; persists, get prompt medical attention1. Ingestion - No systemic toxic effects* but causes severe burns to mouth1 If appropriate; ? ` call physician. Late Toxicity - None recbgnized. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Small Spills - (Less than two gallons) Should be promptly shoveled and swept up,-placed- in dry metal container with a quantity of about 25% greater of sodiumcarbonate added." Spread soda ash over spill area to neutralize; then flush well with water into a chemical sewer to a treatment plant. ' f V' t , Large Spills - Contact Environmental Manager. Workers should wear head covering, - full- face . respirators with approved acid gas canisters or self-contained breathing' .apparatus; rubber slickers or coveralls and rubber boots. Promptly shovel up or pickupmechanicallythe spilled material, then sweep area. Place material in dry metal contaiherscoyered with i quantity about 25% greater of sodiumcarbonate. Seal containers tightly.Spreadsqda ash over spill area to neutralize. Then flush area with water into.a. chemical ;sewer to a;waste treatment plant. Containers filled with treated waste should.be disposed;in-ah JSSE?hazardous waste disposal site. Exposed clothing Iworn during .spill- cleah-iip*(see Swtion VIII. SPECIAL PROTECTION INFORMATION .'i-'r : Use protective clothing to protect eyes and skin from dust contact.' Loosen vent screws in cover before cover is removed. `Lv r; ^ " J,yv v` Provide adequate exhaust ventilation to meet TLV requirements for AICI3 dust add HCL. NIOSH approved respiratory protection should be worn where the TLV concentrations, are or may be exceeded. The selection of the appropriate respiratory protecti6n(chemicalcartridge , respirator, self-contained breathing apparatus, supplied air-respirator,- etc.) Should.be !v based on the actual or potential concentration present. , ' - , l Eye wash fountain shall be close enough to be reached within 5 Seconds. . >' . t- Safety showers shall be available. ,"C / ''! -'J '`v ' *should be removed promptly and washed before reuse. Workers should shower thoroughly if , . there has been skin contact. . i^ V Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in air-tight containers in cool, dry, well-ventilated area away from combustible- ' material. Do not store in areas protected by automatic sprinklers. Containers must be- clean and dry. Vent containers before opening to relieve any pressure, build-up! from HC1 formation. Partially emptied containers should be purged with dry: air pr dry nitrogen before tightly reclosing. Failure to do so can result in HC1 gas formation and possible violent rupture of container. Label should contain warning --"MAY CONTAIN GAS UNDER ' PRESSURE: CONTACT WITH MOIST AIR LIBERATES HC1 GAS." ': I D.O.T. Requirements CORROSIVE. MATERIAL, DANGEROUS WHEN WET. section X. REFERENCES ASTM No.: Chemical Abstracts No.: 7446-70-0 CMA Chemical Safety Data Sheet No.: SD-62 NFPA Guides No.: NSC Data Sheets: ^*35 Supplier Product Literature: :' Other: CHRIS (1974) ACW Data Sheet ; .' bi 4^538 0041 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 32 CD Flammable CD Combustible Toxic By: PRODUCT CHLORINE ED Corrosive CD Explosive CD Ingestion O Water Reactive O Oxidizer CD Radioactive CD Chemically Reactive 0 Inhalation CD Absorption Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: Chemical Name & Formula: Other Designation: Corporate Stock No.: Manufacturer: CHLORINE CI2 Molecular Wt. 70.91 IMCO Designation 2.0;United Nations No. 1017 070--160- PPG Industries,DuPont, Dow, Hooker, Diamond Shamrock, Olin Section II. Chlorine INGREDIENTS % 99+ HAZARD DATA 1 PPM OSHA Ceiling value (29 CFR 1910.1000) Section III. PHYSICAL DATA Physical Form: 8oiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: Liquified Pressurized Gas -29.31F (-34.1C) -150F (-101C) am of Hg @ 68F (20C) 4996 (Ethyl Ether =1) Greater; 100% Volatile 1.424 at 15C (Liquid) Vapor Density (Air=i) 2.67 "Solubility In H20": Slight Color: Greenish-yellow gas at atmospheric pressure or clear. amber liquid under pressure Odor: Pungent, irritating odor. Section IV. FIRE AND EXPLOSION DATA Flashpoint Not flammable I Auto-Ignition Temp. ___ 1 - |Flammability Limits In Air Lower 1 Upper J_________ Z________________ - 1 - - NIOSH approved, self-contained breathing apparatus should be used by fire-fighting personnel. Move containers away from fire. If they cannot be moved, keep cool with water spray. Notify fire-fighting personnel that chlorine containers are in fire area. Chlorine atmosphere will support combustion. Toxic products are generated when combustibles burn in chlorine. Section V. REACTIVITY DATA Reacts readily with hydrocarbons, ammonia, hydrogen, alcohols, ethers and metals, sometimes with explosive violence. Reacts with water to form a corrosive solution. Chlorine is stable under storage conditions. C 411538 0042 Ho.; 32 Section VI. HEALTH HAZARD INFORMATION 1 TLV 1 ppm Inhalation can cause coughing, sneezing, shortness of breath,, nausea and vomiting. Nose and throat may burn. Eye irritation can occur at concentration; of 3r6 ppm. Repeated exposure can result in loss of ability to detect odor of chlorine. Exposure to gas my cause burning sensation, skin inflammation and blister formation. Exposure to high concentrations can cause immediate fatalitites as a result of suffocation. Later, fatalities can result in pulmonary edema (fluid in the -lungs). '; ; t''. v -' FIRST AID: ,,-v .'I'V. Inhalation: Remove patient from contaminated area. Keep warm and at rest until physician arrives. Give oxygen if breathing is difficult. If breathing stops, give artificial f respiration, not mouth-to-mouth resuscitation. Rest is recommended after exposure.. *;< Eve Contact: Flush eyes with water for at least 15 minutes. ; j; ..-./V7 Skin Contact: Remove contaminated clothing. Wash with soap and water. If irritation' occurs, call physician Never attempt chemical neutralization on skin. For throat irritation or coughing, drinking milk, hot coffee or tea may relieve-discomfort. Section VM. SPILL. LEAK & DISPOSAL PROCEDURES Evacuate all personnel. Only trained personnel Swearing NIOSH full-face, self-contained breathing apparatus should be permitted to re-enter spill area. 1 .Personnelf,wearing proper1 breathing apparatus should position themselves up--wind so, escaping chlorine moves away from them. For leaks in cylinders and ton containers, rotate containers so gas escapes instead of liquid. If' possible, remove to isolated area. If appropriate, use emergency; capping kits according to suppliers step-by-step instructions. ' WASTE DISPOSAL: Chlorine gas can be absorbed in alkaline solutions (caustic soda or soda ash). Place neutralized material in sealable container and dispose via approved disposal facility. . . .. : . ,i V Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation to meet TLV requirements..Use NIOSH approved respiratory protection when TLV concentration is or may be exceeded: The selection of appropriate respiratory protection (self-contained breathing'apparatus,'suppliedrair'V. / 1 * ( ! respirator, etc.) should be based on the actual or potential concentration at hand!. r In case of spill or leak, wear NIOSH approved full-face, self-contained breathing apparatus. Avoid contact with liquid or vapor. f Wear chemical, splash-proof goggles, rubber overclothing including gloves. Personnel handling chlorine should carry at all times a NIOSH approved cartridge type escape respirator and be trained in its use. 1 Section IX. SPECIAL PRECAUTIONS & COMMENTS | /-X yr_ Have available quick-opening safety shower.- Eye wash fountain shall be close enough.-to. be reached within 5 seconds. Store in well-ventilated, fire-proof,area away .from other containers. Keep away from heat and water. Use in well ventilated area to limit ; exposure at or below OSHA permissible limit. Never place a leaking chlorine cylinder ' > in water. - ; ' TM ' !: i D.O.T. Requirements NON-FLAMMABLE GAS____________________________ Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 7782^-50-5 CMA Chemical Safety Data Sheet No.: SD-80 NFPA Guides No.: NSC Data Sheets: No. 207 Supplier Product Literature: PPG DATA SHEET Other: CHRIS January, 1974 Alcoa Engr. Stds. 18-12 & 18.13 , , 411538 0043 : > ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No_33_ 0 Flammable O Combustible Toxic By: PRODUCT GASOLINE O Corrosive O Explosive 0 Ingestion (AUTOMOTIVE) 0 Water Reactive 0 Oxidizer O Radioactive 0 Chemically Reactive 0 Inhalation 0 Absorption Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION a* Material Name: c<o Chemical Name & Formula: I| Other Designation: ^<3 c * Corporate Stock No.: fh r>* Manufacturer: GASOLINE, AUTOMOTIVE Mixture of Hydrocarbons Petrol Many suppliers Section II. INGREDIENTS |o Mixture of Hydrocarbons' 5a ^4.23 g lead/gal. -5^ I cQ '-* Q> *TLV should be determined by the composition of the hydrocarbon mixture. % HAZARD DATA TLV Not established* Short time inhalation lin 500 ppm for 30 minutes Toxicity by ingestion LD50 0.5-5.0 g/kg Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid 140-390F (60-199C) Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: Specific Gravity: Density: "Solubility In H2O' Color: Odor: 0.71-0.747 at 20C Vapor 3.4 Insoluble Colorless to pale brown or pink Petroleum odor, irritating; threshold 0.25 ppm Section IV. FIRE AND EXPLOSION DATA Flashpoint j-36F (~37.8C) I Auto-Ignition Temp. 853F (456C) J Flammability Limits In Air | Lower I Upper I| % by Vol.| 1.4 7.4 Fire extinguishing agents: Foam, carbon dioxide, dry chemical. Stop discharge if possible. Shut-off ignition source. Flashback along vapor trail may occur. Cool exposed containers with water. Avoid breathing vapor or fumes. NI0SH approved self-contained breathing apparatus should be used by fire-fighting personnel. Section V. REACTIVITY DATA Stable under normal storage conditions. Not reactive with water or common materials. Keep away from heat and sources of ignition. 411538 0044 No. 33 Section VI. HEALTH HAZARD INFORMATION j TLV Not established Irritation of mucous membranes and stimulation followed by depression of central nervous system. Breathing of vapor may also cause dizziness, headache, and incoordination or in more severe cases, anesthesia, coma, and respiratory arrest. If liquid enters s lungs, it will cause severe irritation, coughing, gagging, pulmonary edema and later ( signs of broncho-pneumonia. FIRST AID: Skin Contact: Wipe off and wash with soap and water. Eye Contact: Wash with copious quantity of water. .- Inhalation: Move to fresh air. Maintain respiration and administer oxygen; enforce bed rest if liquid is in lungs. Ingestion: Do not induce vomiting; stomach should be lavaged (by doctor) if appreciable 'quantity is swallowed. Have victim drink water or milk. .-- Section VII. SPILL, LEAK & DISPOSAL PROCEDURES' ; " . ' ' ' ~" Evaluate area for large spills. Ventilate confined spaces. Provide maximum explosion- proof ventilation; remove ignition sources. . Those involved in clean up should use protection against liquid contact and vapor inhalation. Contain spill by diking. Do not send to sewer or allow to enter streams or surface water. Pick up liquid for reclaim or disposal. Add absorbent solid to small spills or residues and pick up for disposal. DISPOSAL: Burn scrap material in an approved incinerator. Follow Federal, State and local regulations. Section VIH. SPECIAL PROTECTION INFORMATION_____________________________ Use general ventilation and local exhaust ventilation (face velocity^ on conditions of use) to keep vapors and mists at a low level. If this material is heated or sprayed, higher levels of ventilation may be needed. Use NIOSH approved respiratory protection where appropriate. The selection of appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration present. Use rubber gloves to prevent repeated or prolonged contact with liquid and safety glasses for eye protection where splashing is possible. Conditions of use may require additional protection against body contact with liquid. Section IX. SPECIAL PRECAUTIONS & COMMENTS________________________________ __________________ Store in closed containers in a well-ventilated area. Keep away from sources of heat, sources of ignition, and strong oxidizing agents. No smoking in areas of use. Prevent static electric sparks. Near this material, use explosion-proof electrical equipment. Indoor use of this material requires ventilation to remove vapors and mists. Avoid skin contact and be sure that clothing that has been contaminated is free of solvent before reuse. Follow good hygienic practice in the use of this material. D.O.T. Requirements FLAMMABLE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) CG-446-2 411538 0045 For Internal Company Use Only -- Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET JIk A ALCOA HAZARD CHARACTERISTICS Flammable Q Corrosive D Combustible CD Explosive D Water Reactive [U Radioactive D Oxidizer O Chemically Reactive Toxic By: SI Ingestion ED Inhalation C Absorption No. 34 PRODUCT HYDROFLUORIC ACI AQUEOUS (47-70%) Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: AQUEOUS HYDROFLUORIC ACID (47-70%) Chemical Name & Formula: Solution of Hydrogen Fluoride Gas in water; HF Other Designation: Corporate Stock No.: 070--390- Manufacturer: Many suppliers DuPont. Harshaw. Allied Chemical Section II. INGREDIENTS Hydrogen Fluoride (HF) Water Mol. Wt. 20.01 % 47-70 Balance TLV HAZARD DATA 3 ppm (as HF)* 0SHA *NIOSH has recommended 8-hr. TWA of 2.5 mg (as F)/m Section III. PHYSICAL DATA 48% Cone. Physical Form: Boiling Temp.: Freeze-Melt Temp.: Liquid 225F (107C) -35F (-37.2C) Vapor Pressure: . mm Hg at 20 C 25 Evaporation Hate: Specific Gravity: (0/4C) 1.18 Density: "Solubility In H20": Complete Color: Nearly colorless Odor: Fuming liquid with pungent, irritating odor 70% Cone. 152F (66C) -100F (-73.3C) 125 1.27 Section IV. FIRE AND EXPLOSION DATA Flashpoint j Auto-Ignition Temp. Non-flammableJ-|-| _ J Flammability Limits In Air I Lower ] Upper |_ This material is non-flammable; however, flammable and explosive hydrogen gas may be formed when HF reacts with certain metals. Dangerous when heated; emits toxic corrosive fumes. 'A NIOSH approved self-contained breathing apparatus and complete body protection is required for fighting fires in which this material is involved. Section V. REACTIVITY DATA Hydrofluoric acid is a stable chemical when used and stored under proper conditions. This acidic material will attack glass, concrete, certain metals, silica-containing materials, natural rubber, leather, and many organics. It reacts with silica to produce SiF^, a hazardous colorless gas. 70% acid is hygroscopic, evolving heat as it picks up moisture. Keep 50% acid in tightly closed polyethylene, Teflon, lead, wax, or paraffin coated containers. ^60% HF concentrations can be handled in passivated steel containers and piping of appropriate design. 411538 0046 -No. 34 Section VI. HEALTH HAZARD INFORMATION \ TLV 3 PPM or 2 mg/m3 (as HF) HF is not detected by smell at 3 ppm but is immediately irritating to mucous membranes at over 5 ppm and may cause burns. Severe exposures give rapid inflammation and con gestion of the lungs. Breathing 50 ppm for 30-60 minutes may be fatal. Eye contact S' with liquid can cause destruction of the eye. Skin contact gives immediate burns that v. ^ intensify with continued contact. Ingestion unlikely, but would give tissue destruction in the digestive tract and severe irritation in the respiratory tract and could produce death. FIRST AID: Eye Contact: Immediately flush with water for at least 15 minutes. Get medical attention. Skin Contact: Wash acid from the skin. Continue washing 2-4 hours with water; or preferably if available, soak in iced Zephiran, epsom salt, or 70% alcohol solution for 1--4 hours, depending on severity of burn. Get medical attention! Inhalation: Remove to fresh air. Get medical attention! Ingestion: Give as much milk or water as possible to dilute acid, but do not cause vomiting. Get medical attention! Section VM. SPILL, LEAK & DISPOSAL PROCEDURES~ ___________________________ HF vapor should be passed through a packed tower scrubber. Spills should be covered with lime to form a slurry. Notify safety personnel, provide adequate ventilation, and remove ignition sources since hydrogen may be generated by reaction with metals.The neutralized slurry can be flushed down sewer (check local ordinances and conditions; flushing down sewer may not be desirable even if legal) or scraped up for disposal in an approved landfill. Liquid wastes may be neutralized in a trench with lime in a remote location away from buildings and people. Then fill the trench with earth and cover with lumber or sheet metal until the earth settles. Personnel involved in clean up of spills and disposal must use protective equipment. Section VIII. SPECIAL PROTECTION INFORMATION_________________________________________ _________ ( Provide adequate exhaust ventilation to meet TLV requirements.Exhaust hoods should be'^of non-corrosive construction with a face velocity minimum of 100 lfm. Use NIOSH approved respiratory protection where the TLV concentration is or may be exceeded. The selection of appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration at hand. Skin contact should be avoided at all times by wearing neoprene or PVC gloves. Safety glasses or goggles should be worn in areas of 'use. Where splashing may occur, full body protection should be utilized, i.e. fhce shield, boots and body apron of resistant material. An eye wash fountain shall be close enough to be reached within 5 seconds. Chemical showers shall be readily available to areas of use. Section IX, SPECIAL PRECAUTIONS & COMMENTS Porous materials absorb HF and become a hazard for an indefinite time. Clean and neutralize spills on porous surfaces, such as concrete, wood, plastic, etc., immediately. Use non-sparking tools near tanks and pipes where hydrogen gas might collect. Do not inhale HF vapors. If the sharp, penetrating odor of HF can be smelled, workers are being overexposed! Prevent skin contact. Contact with dilute HF solutions ( ^ 20% in water) may not produce immediate pain or visible damage; but after several hours the burns will be manifest. Using HF requires special materials technology for containers, pipes, valves, gaskets, etc., which is available from suppliers. D.O.T. Requirements CORROSIVE MATERIAL Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: SD-23 Other: CHRIS (1974) CG-446-2 c 411538 0047 For Internal Company Use Only - Not To Be Distributed Outside The Company H1 ALCOA 1 Section I. MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 35 O Flammable [3 Combustible CD Corrosive CD Explosive D CDWater Reactive Radioactive 1 Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: O Ingestion CD Inhalation D Absorption PRODUCT KEROSENE Phone No. Date: 80-03-28 Material Name: KEROSENE Chemical Name & Formula: CnH2n+2, Kerosene Other Designation: Corporate Stock No.: Manufacturer: Petroleum Distillate; Fuel oil No. 1, Coal oil. Jet fuels Numerous suppliers; a refined mixture of petroleum hydrocarbons mainly saturated in the CIO to C16 range. Section II. INGREDIENTS Refined petroleum hydrocarbon mixture of: Aliphatic Cycloaliphatic and Alkylated Aromatic Hydrocarbons. % HAZARD DATA TLV: a. 5.0 rag/in^ as mist (OSHA)* *A TLV of 200 ppm for vapors has been recommended by Exxon for its product. ACGIH (1977) determines TLV for vapors from the composition of the hydrocarbon mixture. A TLV of 200 ppm for vapor exposures is recommended for Alcoa use. A TLV of 5.0 mg/m3 as mist is derived from OSHA criteria. ,b. 200 .ppm for vapor exposure Aquatic Toxicity 2990 ppm/24 hr/Bluegill/ TLM fresh water Rat, oral LDLo 28 g/kg Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Liquid 345-535F (173.9 - 279.4C) -50F (-45.6C) mm Hg at 20C ) 5 Evaporation Rate: (N-Butyl Ac = 1) 0.04; 100% Volatile Specific Gravity: 0.82 Density: Vapor (Air = 1) 4.7 "Solubility In H2O": Negligible Color: Nearly water-white Odor: A mild petroleum odor; threshold, 1 ppm. Section IV. FIRE AND EXPLOSION DATA Flashpoint 130F (54.4C) Extinguish with foam, I Auto-Ignition Temp. |410F (210C) dry chemical, C0_, |Flammability Limits In Air | Lower Upper | water spray or fog. [| 0.9 6.0 Water may be ineffective. Use NIOSH approved self-contained breathing apparatus for fire fighting. Avoid breathing vapor or fumes. Cool exposed containers with water. Kerosene is a moderate fire and explosion hazard when heated. Do not store with strong oxidants like concentrated oxygen or liquid chlorine. Section V. REACTIVITY DATA Kerosene is stable under normal conditions. It does not polymerize. It is incompatible with strong oxidants like liquid chlorine, concentrated oxygen and sodium or calcium hypochlorite. Keep away from heat and sources of ignition. 411538 0048 No. 35 Section VI.HEALTH HAZARD INFORMATION TLV 5.0 mg/ra-1 as mist Inhalation of excessive concentrations of vapor ormist isirritatingto.respiratory' V passages and can cause headache, dizziness, nausea, stupor,, convulsions or loss of ' consciousness, depending on concentration and time of exposure: High vaporcqnceh-:> tration or liquid contact is irritating to the eyes.- l Liquid contact with the skin is defatting and irritating; prolonged or repeated contact^- can cause dermatitis. | Kerosene is irritating to.the mouth, throat. and"digestive tract and can be toxic on ingestion. , ' \\{>-W-'n'/- FIRST AID: Eye Contact: Flush eyes with plenty of running water for at least 15 t` minutes. If irritation persists, get medical help. | Skin Contact: Wash exposed areas of the body with soap and water. Promptly reinove contaminated clothing, j Get medical help when large areas of the body have been . exposed or if irritation persists. 'Xr ..V' Inhalation: Remove to fresh air. Restore breathing and administer oxygen if necessary.' Call a physician. .; .:.v:'U ; ingestion: Do not induce vomiting (aspiration hazard)! Call a physician immediately^ Section VH. SPILL. LEAK & DISPOSAL PROCEDURES Evacuate area for large spills. Ventilate confined spaces.Provide'-maximum explosion- proof ventilation; remove ignition sources. Those involved in clean up shouldi use protection against liquid contact and vapor inhalation. Contain spill-by diking. Do. not send to sewer or allow to enter streams or,surface water. Picku^liquldfor reclaim or disposal. Add absorbent solid to small spills or residues and pick up for- 'disposal. - ", - DISPOSAL: Bum scrap material in an approved incinerator. Follow Federal, State, and local regulations. Section VIII. SPECIAL PROTECTION INFORMATION Use general ventilation and local exhaust ventilation (face velocity \ 60 1fm,. depending'' on conditions of use) to keep vapors and mists below TLV's. If this material is heated. Or sprayed, higher levels of ventilation may be heeded. Use NIOSH', approved respiratory protection where the TLV concentration is or may be exceeded. The selection of appropriate respiratory protection (self-contained breathing apparatus, supplied-rair respirator, etc.) should be based on the actual or potential concentration present. -, ,/> t ` , j..v -.V. . Use rubber gloves to prevent repeated or prolonged contact with liquid and safety glasses' ; for eye protection where splashing is possible. Conditions of use may-require additional protection against body contact with liquid. - ? Section IX. SPECIAL PRECAUTIONS & COMMENTS' . \ ""T :" Store in closed containers in a well-ventilated area. , Keep away from sources :of . heat, *, sources of ignition, and strong oxidizing agents;. No smoking in areasiof use. r Prevent static electric sparksL Near this material, use explosion-proof electrical equipment. Indoor use of this material requires ventilation to remove vapors and imists: ; , . i;;. Avoid skin contact andibe sure that clothing that has been contaminated is free of : solvent before reuse. Follow good hygienic practice in the use of this,imaterial.' !. ;;- D.O.T. Requirements COMBUSTIBLE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 008-008-206 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Exxon OSHA --20 Form Other: CHRIS (1974) CG-446-2 "t " - , ( ''j'. ' i. 'V 411538 0049 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 36 CD Flammable CD Combustible Toxic By: PRODUCT METHYLENE CHLORIDE Corrosive CD Explosive CD Ingestion CD Water Reactive CD Oxidizer CD Radioactive CD Chemically Reactive S3 Inhalation 1X1 Absorption Phone No. Date: 80--03--28 Section I. MATERIAL DESCRIPTION Material Name: METHYLENE CHLORIDE Chemical Name & Formula: Dichloromethane, CH^C^ Other Designation: Methane Dichloride Corporate Stock No.: Manufacturer: Dow, Diamond Shamrock Section II. INGREDIENTS Methylene Chloride % Ca 100 *Current OSHA TWA remains at 500 ppm. This OSHA TWA is considered too high to afford adequate protection The 200 TWA should be followed: The OSHA ceiling TLV as defined in 29 cfr 1910.1000 for Methylene Chloride should be followed. NIOSH also warns that toxic hazards with CH^Cl^ are increased by the presence of alcohol and/or carbon monoxide and by heavy labor and smoking. HAZARD DATA 8-hr TWA 200 ppm* (ACGIH) Human, inhalation TCLo 500 ppm/8-hr (blood effects) Rat, oral LD,.q 2136 mg/kg Section III. PHYSICAL DATA Physical Form: 8oiling Temp.: Liquid 104F (40C) Freeze-Melt Temp.: Vapor Pressure: -139F (-95C) mm Hg at 20C, Evaporation Rate: (CC14=1) 1.47 340 Specific Gravity: 1.32 ' Density: Vapor (Air = 1) 2.9 . %"Solubility In H2O": 1 6 Color: Colorless liquid, water-white Odor: Ether-like, sweet; recognition threshold 214 ppm (100% of test panel) Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. ____________None_________________ | >1033F | Flammability Limits In Air j Vol. % at>100C Lower Upper 12 This material does not give a flash or fire point by the conventional test methods. It does form weakly combustible mixtures at high temperatures and high concentrations in air; and it can burn or explode in oxygen enriched air. Firefighters should use NIOSH approved self-contained breathing apparatus (with eye protection) for protection from suffocating and intoxicating vapors and from high temperature decomposition products. Section V. REACTIVITY DATA Methylene chloride is a stable compound under normal conditions of storage and use; however, exposure to high temperatures (open flames, welding arcs, etc.) can give corrosive and toxic thermal-oxidative decomposition products such as hydrogen chloride and phosgene. It does not undergo hazardous polymerization. Prolonged exposure to excess water may cause noticeable hydrolysis above 60 C. Prevent contact with alkali metals and finely powdered aluminum and magnesium to avoid possible violent reactions. 411538 0050 No. 36, Section VI. HEALTH HAZARD INFORMATION TWA 200 ppm; celling TLV 500 ppm ACGIH TLV for methylene chloride lowered from 200 ppm (1977); NIOSH has proposed , e 10--hr. TWA of 75 ppm. Present OSHA value of 500 ppm will probably be'lowered., >;7"v''7` Inhalation of high concentrations causes loss;of coordination and'equilibrium, and,, if exposure is prolonged excessively, unconsciousness!,and even tdeath. ,;- Prolonged ; skin contact can be irritating; absorbed through the skin. Eye>'contact is painful and irritating, but it is not believed likely to produce serious injury.' Methylene J chloride metabolizes to produce carbon monoxide in the: body; it Increases arid sustains carboxyhemoglobin levels in the blood, reducing;the oxygen-carrying capacity oflthe blood. FIRST AID: Eye Contact: Flush contact area with plenty of running .water. If irritation : persists, get medical attention. .* 7, < / 7 Skin Contact: Wash contact area with plenty of running water. If irritation persist^,: get medical attention. Inhalation: Remove to fresh air; give artificial respiration,! if required. Keep quiet and warm. Get medical attention; advise physician not to use .adrenalin.' - !v | Ingestion:- Get prompt medical attention. (If physicaian unavailable, give water or- milk and induce1 vomiting.)- Advise , physician not, to use adrenalin. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES For small spills, soak up with an absorbent solid, such as vOrmiculite; avoiding breathing of vapors and using gloves to avoid contact. Evaporate off solvent in an exhaust hood or bury with absorbent in a landfill. *, ' 7=77- 1--- -ivj, When large spills occur, evacuate area; notify safety personnel; provide ventilation. Use protective equipment during clean-up, such as self-contained breathing, apparatus- boots, gloves, etc. Contain and recover liquid when possible. .Pick .upVrMidne.i with:'. absorbent (as with small spills) or flush to ground (not to sewer);;,t6;;,eya`pprafel ! ; ; `7/ Reclaim waste solvent by filtration and distillation procedures or dispose of via.a . licensed, waste solvent disposal company. 77; J-" Section VIII. SPECIAL PROTECTION INFORMATION Use local exhaust ventilation to meet TLV requirements. Use N1USU approved- respirator protection where the TLV concentration is or may be exceeded., The selection of:appropriate respiratory protection |(self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration present. ^ Use neoprene or Viton gloves for skin protection and safety glasses. Chemical goggles or a face shield should be used where splashing is [ possible. An eye wash fountain; shall be ;, close enough to reach within 5 seconds. j NOTE: NIOSH indicates that carbon monoxide content and CH^C^ content of workplace air ' are additive and that both must be monitored where methylene chloride, exposures Occur.7 The 10-hr. TWA for CO must not exceed about 9 ppm where exposure to methylene chloride' occurs unless CH^Cl^ exposure is also controlled to a lower level than the TLV.; ` ; 1 Section IX. SPECIAL PRECAUTIONS & COMMENTS i-"' j. Use caution in handling this material. Avoidt.airborne concentration build-up. Avoid exposure to high temperature. No smoking where vapors of this material are present. . r Store in a cool, well-ventilated area away from; sources of heat. Open containers with 7 J caution. . : .1,; ,7 ^ "7 V 7.; When methylene chloride vapors are drawn into the combustion chamber,of a space heater, severe corrosion damage to the heater can occur, even at .levels well below TLV.: , . i Those with a history of cardiovascular disease or who are heavy drinkers or smokers should, avoid exposure to methylene chloride. D.O.T. Requirements ,/ ; -7 ^ -7;; ' ' rv Lx 7 '.-/-CV 0RM-A (Air Only) >7 7 *^ V M Section X. R E F E R ENC ES ASTM No.: I Chemical Abstracts No.: 000-075-092 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: 474 Supplier Product Literature: Other: l''. 411538 0051 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET ALCOA HAZARD CHARACTERISTICS O Flammable CD Combustible G Corrosive CD Explosive Toxic By: 0 Ingestion No._Z____ _ PRODUCT OXALIC ACID O Water Reactive Oxidizer CD Radioactive CD Chemically Reactive 0 Inhalation 0 Absorption Phone No. Date: 80-03--28 Section I. Material Name: OXALIC ACID Chemical Name & Formula: Ethanedioic Acid, HO^C-O^H, Mol. Wt. 90.04 Other Designation: Corporate Stock No.: Manufacturer: Many suppliers Section II. INGREDIENTS Oxalic Acid Technical Grade HAZARD DATA TLV 1 mg/m"* (0SHA) *Dihydrate decomposition and sublimation of oxalic acid begins at about 100 C. Above 157C deconpositin of oxalic acid becomes signigicant.. (See below) Human, Oral -LDLo 100 mg/kg Aquatic Toxicity 4000 mg/l/24 hr/Blue Gill/ TLM/Fresh water Section III. PHYSICAL DATA Physical Form: Solid Anhydrous Acid *Dihydratelj (HO)tC-C(OH)^ Ortho-Oxalic Acid Sublimation: Freeze-Melt Temp.: Vapor Pressure: (Decomposes) 315F (157C) 373F (189.5 C) 214F (101C) Evaporation Rate: Specific Gravity: 1.9 1.65 Density*. "Solubility In H2O": 8.34 wt. % ca 11.7% Color: White crystalline solid; hygroscopic when anhydrous Odor: Odorless Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. [Solid, not flammable - J Flammability Limits In Air I- I Lower I Upper I - j - This material is decomposed on heating into C02 and formic acid; the latter, a toxic, combustible material, will further decompose to produce carbon monoxide. Fire fighters should use NIOSH approved self-contained breathing apparatus for respiratory protection against poisonous vapors of oxalic acid and its decomposition products. Section V. REACTIVITY DATA This material and its dihydrate are stable at room temperature. When heated it can decompose to CO, CO , H.O and formic acid. It reacts with concentrated sulfuric acid to give CO, C02, and H20. Oxalic acid is a slightly stronger acid than phosphoric acid. It reacts vigorously with alkalies and it has been found to react explosively with chlorites and hypochlorites. It is a reducing agent. 411538 0052 No.. ;37 r- Section VI. HEALTH HAZARD INFORMATION 1 TLV 1 mg/m3 Inhalation of dust may cause irritation to mucous membranes. Eye contact;,with dust of solutions will cause [burning sensation, with severe burns >and possible, permaneLh:>Vt . 'A* damage from concentrated solutions. Ingestion ofi. concentrated solutiohs will caupe A ` 4 burns and irritation to I the digestive tract. Ingestion of 5 grams has caused death with symptoms of nausea,- shock, convulsions and collapse coming pn rapidly. Skin contact may have a corrosive action, with dermatitis and pb8sMe{(S|ge!^otfi*ftOBt|'? ,*. prolonged contact. : :ilr FIRST AID: ' lv!- u- '.Inhalation: Remove victim to fresh air; rinse mouth. Ingestion: Give 3 glasses of milk or water and induce vomiting. Repeat. Obtain medical attention: Skin Contact: Wash area with soap and water. Eye Contact: Immediately irrigate with water for 15 minutes minimum!. .Obtain | J. medical attention. ^ M'<- f. ;. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Notify safety personnel, provide adequate ventilation and avoid'dustirig. Use protective equipment. Carefully scoop up solid for recovery or disposal. . Thoroughly neutralize ;. liquid spills or residual solids with soda ash or sodium bicarbonate. 'Wash*small amounts of neutralized waste down the drain with excess water. ~ i ' '3 ' 1 Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation to meet TLV requirements. At.room temperature the low vapor pressure of solid or of solutions usually requires only general room f ventilation. Where dusting can occur with the solid form or when the solid,or solution' is heated, hood exhausts should be maintained at 100 lfm face velocity, minimum. Use v NIOSH approved respiratory protection where the TLV concentration is^ or;; may'-;befexceedeidl' The selection of appropriate respiratory protection (self-containedbreathingappafatusi supplied-air respirator, etc.) should be based oh the actual or potential concentration present. Natural or synthetic rubber gloves should be worn to.prevent sltin contact. Safety glasses or goggles should be worn to prevent eye cbntact. >; Chemical' shower shall be readily available to areas of storage or use. An eye wash fountain shall be close ' enough to be reached wijthin 5 seconds.;:_______________________ '"-A. ~ '< Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in a cool, clean, dry area. Keep separate from chlorites, hypochlorites and : ; A alkalies. ! , . ' ' , "V Prevent skin and eye contact by wearing protective equipment. . Do not eat or smoke;near areas of use. Always wash hands after working with oxalic acidi :A When solid oxalic acid is heated or when a water solution is boiled, .high/.atmpspheric; concentrations of oxalic acid can result which will require efficient exhaust ventilation to keep below the TLV. t .{ D.O.T. Requirements POISON, B Section X. REFERENCES ASTM No.: j Chemical Abstracts No.: 000-144-627 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: 406 Supplier Product Literature: Other: CHRIS (1974) CG-446r2 i " *411538:0063 For Internal Company Use Only - Not To Bo Distributed Outs/do The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No._ 38 D Flammable 0 Combustible Toxic By: PRODUCT POTASSIUM HYDROXI (3 Corrosive O Explosive 0 Ingestion O Water Reactive O Oxidizer 0 Radioactive O Chemically Reactive 0 Inhalation O Absorption Phone No. Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: POTASSIUM HYDROXIDE Chemical Name & Formula: KOH Other Designation: Caustic Potash, Potash Lye Corporate Stock No.: 070-705- Manufacturer: Many suppliers Section II. INGREDIENTS A water containing solid Typical content: % HAZARD DATA TLV Ceiling Value (OSHA) 2 mg/m^ Potassium Hydroxide (KOH) Water Potassium Carbonate (J^COj) 83 Rat, oral LD 13 365 mg/kg Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Solid flake or pellets 2400F (1315C) CA 680F (360C) For anhydrous KOH, 380C Vapor Pressure: Evaporation Rate: Specific Gravity: 2.044 Density: "Solubility In H20": at 20C, 52%; at 100C, 64% Color: Odor: Off-white, hygroscopic solid No odor Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Ignition Temp. J Flammability Limits In Air | Lower I Upper Not combustible|-|--1 - I- Though it is not combustible, it can be hazardous if present in a fire area. The following should be known for fife fighting: (1) It can melt and flow when heated (m.p. about 360 C). (2) Hot or molten material can react violently with water (splattering). (3) Can react with certain metals, such as aluminum, to generate flammable hydrogen gas. (See also Reactivity Data, Section V.) Use NIOSH approved self-contained breathing apparatus for fire fighting. Section V. REACTIVITY DATA It is a stable material under normal conditions of storage. No self-polymerization. No hazardous composition products. It is hygroscopic and, hence, will pick up moisture from the air. It reacts with carbon dioxide from the air to form potassium carbonate. Potassium hydroxide can react violently with strong acids and with many organic chemicals, especially with nitrocarbons and chlorocarbons. (Reacts with trichloroethylene to form spontaneously flammable dichloroacetylene.) It generates much heat when it dissolves in water. Avoid contact with leather and wool and with aluminum, tin, zinc, and alloys which contain these metals. 411538 0054 No. 38 Section VI. HEALTH HAZARD INFORMATION | TLV (ceiling value) 2 jng/m^ Potassium hydroxide is a strong alkali and dangerous when improperly handled. It can be destructive of all human tissue, producing severe burns. Eye contact can produce severe or permanent injury. Dust or mist inhalation can injure the entire respiratory tract. ^ FIRST AID: Eye Contact: Wash eyes immediately with plenty of running water for no f less than 15 minutes, including under the eyelids and all surfaces. Speed in rinsing V out the eyes with water after contact is extremely important if permanent injury is to be avoided! Contact a physician as soon as possible. Ingestion: Immediately dilute chemical by drinking large amounts of water or milk, then neutralize with dilute vinegar or fruit juice. Vomiting may occur spontaneously, but do not induce it. Contact a physician promptly. Inhalation: Remove from exposure to mist or dust and get prompt medical help. Skin Contact: Wash contact area promptly with large quantities of water. (Diluted acetic acid, vinegar, can be used to neutralize.) Remove contaminated clothing under the safety shower. Prolong washing in serious cases until medical help arrives--even for an hour or longer. See physician for all cases other than minor exposures to small areas of skin. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES _____________________ ______________________ When solid potassium hydroxide is spilled in a dry condition, it can be promptly shoveled up for recovery or disposal. (Caution! Avoid dusting. Avoid contact with the skin.) Control the disposal of waste solid. (Delay in clean up may allow absorption of moisture from the air and increase the difficulties of clean-up.) Flush contaminated surfaces with water and neutralize with dilute acid, preferably acetic acid, to remove final traces. (Sodium bicarbonate may also be used to partially neutralize.) Finally, rinse with water. Disposal of waste is greatly dependent on local conditions and requirements. Pre-emergency plans should be made to meet legal and technical requirements. Waste caustic should never be deliberately discharged directly into sewers or surface waters. (First, convert to neutral salts and dilute well with water.) Section VIII. SPECIAL PROTECTION INFORMATION / Provide adequate ventilation to meet TLV requirements, especially where dusting or x_ misting conditions can exist. Use NIOSH approved respiratory protection where the TLV concentration is or may be exceeded. The selection of appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration present. Use chemical safety goggles! A plastic face shield can also be used. Use rubber gloves, rubber apron or protective 'clothing, rubber boots, etc., where needed to prevent contact with potassium hydroxide, especially, when solutions,are prepared. Safety showers shall be immediately available! ` Eye wash fountain shall be cloSed enough to be reached within 5 seconds. Section IX. SPECIAL PRECAUTIONS & COMMENTS__________________________________________________ Workers should not be permitted to handle this material without proper training or to work with it without protective equipment. Avoid handling conditions that may lead to spills and leaks, dust. Wherever this material is stored, unloaded, handled or used, running water) should be available for emergency use. or to formation of mist or abundant water (preferably Drains from storage or use areas for this material should have retention basins for pH adjustment and dilution of spills and flushings before discharge. The pellet form is probably the safest solid form for handling and dispensing. D.O.T. Requirements CORROSIVE MATERIAL Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 001--310--583 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: * c 411538 0055 0 ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 39 O Flammable 0 Combustible Toxic By: PRODUCT SULFUR DIOXIDE 3 Corrosive 0 Explosive 0 Ingestion O Water Reactive O Radioactive (El Inhalation Phone No. 0 Oxidizer O Chemically Reactive 0 Absorption Date: 80-03-28 Section I. MATERIAL DESCRIPTION Material Name: SULFUR DIOXIDE Chemical Name & Formula: SO2 Mol. Wt. 64.06 Other Designation: Corporate Stock No.: Manufacturer: 070--880- Section II. INGREDIENTS Sulfur Dioxide (SO2) % HAZARD DATA * TLV 5 ppm (0SHA) Ceiling Limit 10 ppm *Refrigeration Grade 99.98% Commercial Grade 99.9% Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Non-flammable, compressed gas 14F (-10.0C) -103.9F (-75.5C) mm of Hg at 20C, 2538 Evaporation Rate: Specific Gravity: Density: "Solubility In H20": Color: Odor: 1.45 at -10C (Liquid) Vapor (Air = 1) 2.2 10.1% by wt. at 20C Colorless Highly irritating; threshold >odor: 3-5 ppm Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. non-flammable|-|-j - j - (Flammability Limits In Air Lower I Upper When fighting fire in area where S0_ cylinders are stored, wear chemical goggles and NIOSH approved self-contained breathing apparatus. Cool exposed containers with water to avoid rupture or melting of fusible plug. Section V. REACTIVITY DATA SO^ reacts with water to form corrosive sulfurous acid. This acid is corrosive to most metals. Anhydrous SC^ is not corrosive to steel. Liquified compressed SO_ gas is stable under normal storage conditions. c 411538 0056 Ho. 39 Section VI. HEALTH HAZARD INFORMATION 1 TLV 5 ppm Inhalation of gas is highly irritating to the respiratory tract; SO^ forms sulfurous acid on contact with moist membranes, causes throat irritation and coughing; burning of the eyes. It does not absorb through the skin. Liquid can cause frostbite. FIRST AID: Eve Contact: Wash promptly with copious amount of water for 15 minutes. Skin Contact: Wash thoroughly with water. Shower immediately if contacted by liquid so2. Inhalation: Remove from exposure area. Maintain respiration. Administer oxygen (by qualified medical personnel). Section VH. SPILL, LEAK & DISPOSAL PROCEDURES________________________________ _______________ Gas leaks should only be repaired by properly trained worker with proper protective equipment and NIOSH approved self-contained breathing apparatus. All Federal, State and local regulations should be observed when disposing S0_. Small amounts of S0,, remaining in small cylinders can be disposed by absorption in waste or inexpensive alkali solution and then discharged to sewer. Section VIII. SPECIAL PROTECTION INFORMATION________________________ ________ ___________ Provide adequate local exhaust ventilation to meet TLV requirements. Use NIOSH approved respiratory protection where the TLV concentration is or may be exceeded. The selection of appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc. ) should be based on the actual or potential concentration present. Eye protection must include chemical safety goggles, where maximum protection is needed> also wear full plastic face shield. When exposure to liquid SO^ might occur, wear full protective gear - rubber gloves and apron and head protection. Caution: Protective creams do not afford adequate protection. Safety showers and eye fountains should be available where S02 is used. Section IX. SPECIAL PRECAUTIONS & COMMENTS Working room and operation areas should have good ventilation. Cylinders should be stored in cool dry area. Do not permit cylinder temperature to reach 130F (54.4C). Fusible safety plugs in cylinder melt at 165 F (73.9C). D.O.T. Requirements NON-FLAMMABLE GAS_________________ Section X. ASTM No.: REFERENCES_____________________________________________ _ Other: CHRIS (1974) Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: SD-52 c 411538 0057 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 21 03 Flammable 0 Combustible Toxic By: PRODUCT LIQUIFIED PROPANE O Corrosive 0 Explosive O Ingestion O Water Reactive 0 Oxidizer 0 Radioactive 0 Chemically Reactive 0 Inhalation 0 Absorption Phone No. Date: 80--03--06 Section 1. MATERIAL DESCRIPTION Material Name: LIQUIFIED PROPANE Chemical Name & Formula: C^Hg Other Designation: Manufacturer: Liquified Petroleum Gas*, LP-Gas*, LPG*, High volatility LPG, *These terms are also used for butane-based gas. Available from many sources. Supplied as pressurized liquid in tanks Section II. INGREDIENTS Ethane (C^Hg) Propane (C^Hg) Propylene (C^Hg) % HAZARD DATA <4 65 min 8-hr TWA 1000 ppm** 0-35 and Higher Hydrocarbons <2.5 **Current OSHA standard for propane and LPG mixtures. ACGIH (1977) labels ethane, propane, propylene and butane as simple asphyxiants. Section III. PHYSICAL DATA Physical Form: Liquified Propane Boiling Temp.: @ 1 atm, (propane)-------- Freeze-Melt Temp.: Vapor Pressure: psig j| -------------------------- Evaporation Rate: -- -46.7F (-43.7C) m min max Volatile, %---------------- ca 100 (95% min at -37 F) Molecular weight ------ 44.09 Specific Gravity: -42.2/4C:-------------------------- 0.58 Density: Vapor (Air = 1) -------------------------- ca 1.5 "Solubility In H2O'': (propane) -- Very si. soluble ColoriA.colorless gas at room temperature and 1 atm pressure. It can be liquified by 0<jor. lowering the temperature, increasing the pressure, or both. It can have an odor like "natural gas" but propane is odorless when pure. Section IV. FIRE AND EXPLOSION DATA Flash point -156F( 105C) Auto-Ignition Temp. 874 F (468C) Flammability Limits In Air % by Volume (approx.) Lower | Upper "> 2 I TO Extinguishing procedure: Stop the flow of gas. Use water to cool fire-exposed tanks and surroundings and to protect personnel working on shut off. Dry powder and/or carbon dioxide can be directed at flame area, if gas flow cannot be stopped, to blanket the flame and exclude oxygen. Vapors may flow on surfaces for considerable distances, reach an ignition source, and flash back. It is a dangerous fire and explosion hazard when released in air. Those putting out fire must use self-contained breathing apparatus and protective equipment. Fire exposed tanks can rupture violently! Section V. REACTIVITY DATA This flammable material is stable when stored as a liquid in steel tanks under its own vapor pressure. Keep separate from oxidizing agents. It burns with a luminous, smoky flame; it can produce carbon monoxide when oxidized, with a deficiency of oxygen. 411538 0058 No.. 21 Section VI. HEALTH HAZARD INFORMATION 1 TLV 1000 ppm This material is an asphyxiant (and it may have anesthetic properties at very high concentrations). If this material is present in sufficient concentration to reduce the oxygen level below 18% in inhaled air, symptoms such as rapid respiration, mental dullness, incoordination, poor judgment, nausea, and unconsciousness may result. (Oxygen deficiency may occur without warning in areas where this gas may displace air.) Contact with liquified gas can produce frostbite. First Aid: Inhalation: Remove victim to fresh air. Restore breathing if necessary. Administer oxygen if exposure was serious or if oxygen deficiency symptoms persist. Get medical help . Section VH. SPILL, LEAK & DISPOSAL PROCEDURES______________________________ ________ __ Personnel involved in leak stoppage should use self-contained breathing equipment and should have protection against direct contact with liquid hydrocarbon. Evacuate area. Eliminate sources of ignition. Supply maximum air ventilation (explosion-proof equipment) to keep concentration below lower flammablility limit. Stop leak or remove leaky cylinder or tank. Place cylinder or tank in remote place and allow gas to bleed off to atmosphere or place in pit and ignite escaping gas. Incinerate waste gas by laying a pipe line to a furnace and burning with caution in accordance with Federal, state and local regulations. Section VIM. SPECIAL PROTECTION INFORMATION Provide adequate ventilation where this material is used to meet TLV requirements. Provide special ventilation in sumps and confined areas. Use NIOSH approved respiratory protection where the TLV concentration is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration. Electrical equipment should be explosion-proof'where propane is used. Where contact with liquid propane is possible, use protective clothing, gloves and face shield. Section IX. SPECIAL PRECAUTIONS & COMMENTS______________________________________ _ Store and use propane cylinders and tanks in well-ventilated areas, away from heat, direct sunlight, and sources of ignition. No smoking in areas of storage or use. Electrically bond and ground all lines and equipment used with propane. Keep away from oxidizing agents and from cylinders of oxygen or chlorine. Follow standard procedures for handling cylinders and tanks of flammable, compressed gas. Provide protection against damaging cylinders and tanks. D.O.T. Requirements FLAMMABLE GAS Section X. REFERENCES_________________ ASTM No.: D1835 Chemical Abstracts No.: 000-074-986 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: 49 NSC Data Sheets: Supplier Product Literature: \LC0A Eng'r. Standards: 18.8.1, 18.8.3 Other: CHRIS (1974) c 411538 0059 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 22 O Flammable 0 Corrosive Combustible O Explosive Toxic By: 0 Ingestion PRODUCT SODIUM CARBONATE, ANHYDROUS O Water Reactive Q Radioactive 0 Inhalation Phone No. 0 Oxidizer CD Chemically Reactive O Absorption Date: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: SODIUM CARBONATE, ANHYDROUS* *0ther forms are available: Chemical Name & Formula: Na^CO^ Other Designation: Soda Ash, . Corporate Stock No.: Manufacturer: Material available from several suppliers, Monohydrate, Na C0-.H-0, Decahydrate, Na^COylOH^, which is a^so called Sal Soda or Washing Soda including Allied Chemical Corp.. Ashland Chemical, and BASF Wva ndotte Com. Section II. INGREDIENTS % HAZARD DATA Sodium Carbonate, Anhydrous ca 99 No TLV established* *Control at least as a nuisance particulate: 0SHA 15 mg/m-1 (total dust) or 5 mg/m-1 (respirable dust); ACGIH (1978) 10 mg/m^ (total dust) or 5 mg/m^ (respirable dust). Rat, oral LDLo 4000 mg/kg Section III. PHYSICAL DATA Physical Form: Solid Begins slow decomposition at 752F (400C) Freeze-Melt Temp.: ------------------------------------- 1564F (851C) Vapor Pressure: Evaporation Rate: Specific Gravity: Density'. ________________________ 2.53 "Solubility In H20": at 8 C, Wt. % -- 7.1 Color: White, hygroscopic powder or granular solid Odor: Odorless Molecular weight --------------------- 106 pH aqueous solution -------------- 11.6 *Note: The decahydrate begins to to lose water at or below its melting point 93F (34 C) and the monohydrate at about 122F 50 C. Both will become anhydrous sodium carbonate when heated at 100 C (212F). Section IV. FIRE AND EXPLOSION DATA Flashpoint 1 Auto-Ignition Temp. N/A _______________ ______ N/A___________ J Flammability Limits In Air 1 N/A I Lower I Upper 1 1______ This is a noncombustible material. Use extinguishing media appropriate for the surrounding fire. No unusual fire or explosion hazards; no special firefighting procedures. Firefighters must wear full protective gear and use self-contained breathing apparatus with a full facepiece when this material is involved in a fire. Section V. REACTIVITY DATA This is a stable material in closed containers at room temperature. It begins to decompose slowly at 400 C on heating to give carbon dioxide and NaO. It will react with fluorine gas at room temperature, generating incandescent temperatures. It can produce an explosion if it contacts red-hot aluminum metal. It is an alkaline material that is incompatible with strong acids. 411538 0060 Section VI. HEALTH HAZARD INFORMATION TLV Ho 22 None established -(See Section,'ll),;; Exposure to airborne dust or mist (from solutions) of this alkalinemhterialcan cause irritation of eyes, skin, or upper respiratory tract on contact. Excessive contact is knovm to have caused "soda ulcers" on hands and perforation of the^nasal septum.'; Sensitivity reactions may occur from prolonged and1 repeated contact^''It: is'^mly.}'^'? T' slightly toxic by ingestion, but ingestion of large amounts can be corrosiveto,the G1 tract and produce abdominal pains, vomiting, diarrhea, and circulatory collapse. Concentrated solutions in prolonged contact with skin or eyes can destroy- tissue. First Aid: , `l-i ir"< i Eye Contact: Promptly flush eyes with plenty of running water for 15 minutes or :more including under eyelids. Consult a physician if irritation persists. ;: *; Skin Contact: Wash affected area of skin well with soap and water;] ' Get medical-help': if irritation persists. Remove contaminated clothing..-'Iiundefcjbd^re,'reused'J:--4 Inhalation: Remove to fresh air. Consult physician for observation and treatment. v' ' Ingestion: Contact a physician promptly for gastric lavage. `''Cjive'"'2-3;1 glasses-'oflwatieir!:/" to drink to dilute. Do not Induce vomiting. V Section VII. SPILL, LEAK & DISPOSAL PROCEDURES ,J' ,, ,;r-/ >,; ;i' Notify Environmental personnel if spill is large. Avoid producing dusty conditions^ : -j Scoop up solid for recovery or disposal. Flush residues and liquid spills to holding area for neutralization before-discharge. Those involved in a clean-up should use protection v . against skin contact or inhalation of dust or mist. DISPOSAL: Follow Federal, state and local regulations for disposal. After neutra lization with, for example, dilute HC1, and further dilution, liquid, wastes can , usually be flushed to drain with much water. Test for total dissolved solids prior to discharge. Solid scrap can be reserved for neutralization of acididrwastes. 7 [. ' H>`- t- Section VIII. SPECIAL PROJECTION INFORMATION Use general ventilation and local exhaust ventilation to meet TLV for nuisance dust and: to prevent irritating concentrations of dust or mist in the workplace. . Ventilation . requirements will depend on the process. Use NIOSH approved respiratory protection where the TLV concentration is or may be exceeded. The, selection, jotAppropriate | respiratory protection (half-face piece respirator, self-contained breathing apparatus', .. supplied-air respirator,- etc.) will depend on the actual or potential concentration present. Use protective rubber gloves and use protective apron and other clothing as needed where splashing may occur with alkaline solutions. ` Use safety glasses with r, ; side shields or safety goggles. An eyewash fountain shall be close enbugh to be reached within 5 seconds. A safety shower is needed where large amounts of'material (especially as solutions) are handled. \\k-7 Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in a tightly closed container in a dean, well-ventilated place away from^strong acids. Protect container from physical damage. ,,` j'''."-.* ; Avoid contact with skin and inhalation of dust or alkaline mist. Follow good hygienid practice. 1 ' D.O.T. Requirements CORROSIVE MATERIAL Section X. REFERENCES ASTM No.: D458 Chemical Abstracts No.: 000-497-198 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: i:f ; 1: j'-. C 411538 0061 A '-y-  For Internal Company Uso Only - Not To Da Distributed Outside Tho Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS NO-_ 23 CD Flammable Q Combustible Toxic By: PRODUCT TRICHLOROETHYLENE CD Corrosive CD Explosive K3 Ingestion CD Water Reactive CD Oxidizer CD Radioactive CD Chemically Reactive 0 Inhalation 0 Absorption Phone No. Date: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: TRICHLOROETHYLENE (See AMSDS No. 19) Chemical Name & Formula: CHCl^CCl^ Other Designation: TCE, Trichloroethylene, Ethylene Trichloride, Ethenyl Trichloride Corporate Stock No.: 051--770--0194 (PL-194) Manufacturer: BLACO-TRI (Baron-Blakeslee); ALK-TRI and NEU-TRI (Dow); KAYNIDE (Kraft); PEKM-A-CLOR and TRIAD (Detrex) ; TRICHLOR (PPG); TRICLENE D & MD (Diamond Shamrock Section II. INGREDIENTS % HAZARD DATA Trichloroethylene + Stabilizer* ILV 100 ppm with 200 ppm Ceiling level** *Stabilizers such as amines or epoxy compounds are use ally added at low levels to increase resistance to oxidati on and to polymerization. Vapor degreasing grades requi re higher stabilizer levels. **0SHA has proposed reducing the ceiling level to 150 ppm (measured over 10 minutes) and eliminating the 5 mint te peak level. Human, Oral LDLo 857 mg/kg Human, Inhal. TCLo 160 ppm/83 min (central nervous system) Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Liquid 1 atm deg C---------- -- 188F (87C) --------73 to -86* Volatiles %---------------------- ca 100 Molecular weight ------------ 131.39 ! Vapor Pressure: Evaporation Rate: Specific Gravity: @ 20 C, mm Hg - 58 (CC1 =1)--------------0.69 20 C---------------------- 1.45 - 1.47* *Depends on stabilizer and level used. i Density: Vapor (Air = 1) 4.54 "Solubility In H20": @ 25 C, %-------------0.1 Color: Colorless, mobile liquid, whose recognition threshold is.21. ppm in air (unfatigued,. 0dor 100% of test panel). Characteristic, sweet, ether-like odor Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. (Flammability Limits In Air None| 770 F (410 C)|% by volume (at 100C)| 2.5 | Lower I Upper | 90% i Extinguishing Media: Use that which is appropriate for surrounding fire. Trichloro ethylene is normally considered noncombustible. However, when 15% vapor in air at 33 C is exposed to intense heat (electric arc) or to ordinary flame at vapor temperatures exceeding 50 C, it can be made to burn mildly. Self-contained breathing apparatus should be used for protection against TCE vapors and their toxic and corrosive decomposition products in a fire situation. Use water spray to keep fire-exposed containers cool. I Section V. REACTIVITY DATA ICE is considered to be a stable compound under normal conditions of storage and handling. However, when it is heated (as in a vapor degreaser) or exposed to sunlight, it requires stabilization against oxidation, degradation, and polymerization. When it is exposed to high temperatures, hydrogen chloride and phosgene (highly toxic) can be produced as decomposition products. It is slowly decomposed by light when moist. ICE can react with NaOH, KOH, or other strong alkali to form explosive mixtures of chloroacetylenes. Soda ash does not react. Polymerization of TCE is catalyzed by aluminum*chloride. react with TCE. Magnesium or aluminum powder can 411538 0062 >\7- * to be reached w ith in 5 seconds. No. 23 ; Section VI. HEALTH HAZARD INFORMATION j TLV ' 100 ppm or 535: mR/ro Inhalation of TCE above the TLV can irritate nose and throat, with dizziness, -drowsiness, ,headache, nausea, unconsciousness, and even death resulting frora;excessive exposure'. :V Eye irritation and lacrymation can result from exposure to vapor or liquid. " Skin con tact causes irritation i and, when prolonged or repeated, dermatitis. Ingestion": ] ; irritates the digestive tract and may cause nausea and rapid drowsiness partial*,:?: , C.,, paralysis, unconsciousness and kidney failure can result'in'*severe cases:V 0.* ;->l FirstAid: I 1 ^ ``V; *'4 Eye Contact: Wash immediately with plenty of running water. Continue washing-tominimize discomfort. Get prompt medical attention. ` - --`t'! -^;|^ Skin Contact: Remove contaminated clothing. Wash with soap and wamiwater.^ Inhalation: Remove to fresh air; restore breathing if required. Keep at.rest and-warn.: Immediately contact physician; advise him not to give`adrenalin. ,, , ( t, Ingestion: physician. Get immediate medical help! Do not induce vomiting unless. directed by a<; ` (Authorities differ; professional decision 'required). 'M ! *i Physician should be warned not to use adrenalin ifor treatment!-. : ' r; Section VII. SPILL. LEAK & DISPOSAL PROCEDURES v ';WV-v U~": Inform Environmental personnel and evacuate area for large spills. Clean-up personnel. . should use jrespiratory and liquid contact protection. . Provide. ' selection of .the proper NIOSH approved respirator .protection, should be based on the; ; , potential exposure concentration. Confine spill to as small an area.j^^pbssibleL ^Ddv not allow run off to the sewer. Pick up spill with vacuum or on an absorbent/and:store 1 in closed container for disposal. y" DISPOSAL: Waste can be processed to recover TCE, or it can .be burned in an .appropriately! equipped, high temperature incinerator (fume scrubbing system required,to remove HC1)-. Disposal through a licensed waste disposal company should"also.be;.fconsidered-.v,!''.'js'crap solvent and distillation residues must be handled as toxic wastes....'^`Follow^Federal* State and local regulations. REFER TO LOCAL SPCC PLAN. ' ' -*/ Section VIII. SPECIAL PROTECTION INFORMATION 1 ` .\ Provide general ventilation and exhaust ventilation to keep workplace'vapor ievhistf within TLV requirements. ; Approved respiratory equipment should be available for emergency and non-rdutine use. Use self-contained breathing equipment above 1000 ppm; use full facepiece cartridge or canister respirators for limited exposures above ceiling limit or TLV. (Cartridge, V 1-2 hrs. max.) . v , >, Use neoprene gloves, aprons, etc. to prevent liquid contact with ;the skin and splash-1 : - proof goggles for eye protection. Gas-tight goggles should be`used by. maintenance and ; emergency personnel. An eye wash fountain shall be closed enough (*see left margin) > "' Ns NIOSH approved respiratory protection when the TLV concentration is or may be exceeded. The. selection of the appropriate respiratory protection (self-contained`breathing appa SUPPf-fed-air rpsplrafnr, elr : lahmild he haspH nn thp aptnal nr: pnfPnHar:pnhrpnM-aflnn I *I Section IX. SPECIAL PRECAUTIONS & COMMENTS ./ v vV' I Avoid breathing vapors and skin contact. Store in a cool,weii!^m'tiia4^p>:ar^s^vikVse>..:;- with adequate ventilation, including floor level1 ventilation. Avoid contact of'Sapors with high temperature (toxic and corrosive decomposition products from TCE above 700 C),.-No ; smoking in use or storage areas. Avoid collecting aluminum fines or chips in vapor degreaser. .t"" .".I1*" REgularly monitor.TCE . ,- "r. stabilizer level. Only trained personnel should operate vapor degreaser. ' . V' TCE has produced liver cancer in test animals and continues to be under study as a potnetial carcinogen in man. Exercise due caution. Evidence of cancer hazard, with TCE is greater D.O.T. Requirements than with perchloroethylene or 1,1,1-1 richo roe thane. (0SHA Reporter 1978, ORM-A (Regulated by Air only) ^ ?`15,65;.)^ JSection X. REFERENCES ASTM No.: STP-403 Chemical Abstracts No.: 000-079-016 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: 49 NSC Data Sheets: 389 Supplier Product Literature: Other: CHRIS (1974) t AIHA Hygienic Guide 2-64.; AIA Bulletin: C-8 s: :`"'f: J' '.1.V For Internal Company Use Only - Not To Bo Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 18 Flammable CD Corrosive O Combustible CD Explosive Toxic By: 0 Ingestion PRODUCT CHROMIC ACID Water Reactive CD Radioactive 0 Inhalation Phone No. 0 Oxidizer Chemically Reactive CD Absorption Date: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: CHROMIC ACID, SOLID Chemical Name & Formula: Cr03 Other Designation: CASit 001-333-820, Chromium Trioxide, Corporate Stock No.: Chromium Anhydride, Chromium (VI) Oxide Manufacturer: Available from many suppliers Section II. . INGREDIENTS Chromium Trioxide % HAZARD DATA ca 100 0.1 mg/m^* Dog, subcutaneous LDLC 330 mg/kg *NIOSH recommended level is 0.001 mg/m^ (as Cr) Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Solid Freeze-Melt Temp.: 387F (197C) (Decomposes @ 482F (250C) to 0^03+02) Vapor Pressure: Evaporation Rate: Specific Gravity: 20/AC----------2.7 Density: "Solubility In HjO": 62% (14lbs/gal at 60F to17.2 lbs gal at 212F) Color: Odor: Dark red None flakes or crystalswhich aredeliquescent Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. jNot combustible|None None| I Flammability Limits In Air | Lower I Upper -- |-- Ihroraic anhydride is not flammable, but it is an oxidizing-agent; will ignite many hydrocarbons when brought in direct contact. Certain inorganic chemicals will produce incandescence when mixed with chromic anhydride; i.e. arsenic, ammonia gas, hydrogen sulfide, phosphorus, potassium, sodium and selenium. Flammable materials near these reactions could be easily ignited. Containers may explode when involved in a fire. Water should be used for fire fighting; however, the decomposition material will form a hot viscous foam. Caution should be exercized against possibility of a steam explosion. fear full protective clothing._______________________________________________________________________________ Section V. REACTIVITY DATA This material is stable when properly stored and handled. It is a strong oxidizing agent, and will react with many oxidizable substances, such as oils, grease, paper, rapidly enough to ignite them. Chromic anhyride will ignite many hydrocarbons from direct contact. Incandescence is also produced from contact with the inorganics mentioned in Section IV. 411538 0064 No. 18 Section VI. HEALTH HAZARD INFORMATION TLV 0.1 mg/m Inhalation of dusts or mist may irritate the respiratory tract due to high acidity and tissue oxidation. Ulceration of mucous membranes of nose and mouth can result from inhalation. Skin contact with acid solutions or solid may cause irritation; however, the major damage occurs up to 38 hours after contact. The chromates will slowly dissolve the skin, forming clean ulcers with hard edges. Secondary infections can then occur on the broken skin. Eye contact may result in loss of vision with severe burns. Ingestion may cause severe burns of the intestinal tract with internal damage. Ingestion of 5 grams may be lethal for an adult. FIRST AID: Inhalation: Remove victim to fresh air. Eye Contact: Immediately irrigate with water for 15 minutes. Get medical attention! Skin Contact: Wash with soap and water; promptly remove contaminated clothing. Ingestion: Chromic anhydride is an emetic; however, milk or water should be given to dilute the acidity. Vomiting should be induced after fluids are taken. Get prompt medical attention. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES In case of spills, notify Environmental personnel. Provide adequate ventilation. Spread a-reducing agent, such as sodium sulfite or ferrous sulfate on liquid acid spills. The resulting slurry should be scooped into a container of water and neutralized with soda ash. Solid spills may be directly scooped into containers, but dusting should be minimized Personnel on clean-up should wear NIOSH approved respirators and protective clothing to prevent inhalation or skin contact. The selection of appropriate respirator should be based on the potential concentration at hand. Disposal should include reduction with the above agents and acid neutralization. Local, state and Federal regulations must be considered prior to any drain disposal! REFER TO LOCAL SPCC PLAN. Section VIII. SPECIAL PROTECTION INFORMATION f Provide efficient exhaust ventilation to meet TLV requirements. Use a NIOSH approved v. respirator where the TLV concentration is or may be exceeded. The selection of appropriate respirator (self-contained breathing apparatus, supplied-air respirator, etc.) will depend on the actual or potential concentration at hand. Tanks of chromic acid must be exhaust vented adequately, with chemically resistant duct work and fans. Employees should wear safety goggles to prevent eye contact. Neoprene or other synthetic rubber gloves and apron should be used; however, these materials can be attacked by chromic acid. Complete face shields should be used in areas where splashing can occur. Eyewash fountain shall be close enough to be reached within 5 seconds. Safety showers shall be readily accessible to areas of use. Section IX. SPECIAL PRECAUTIONS & COMMENTS ~ Avoid breathing mists or dusts. Avoid skin contact. No eating or smoking near areas.of use. Store in a clean, cool, dry well-ventilated area. Keep away from oxidizable materials. Wash contaminated clothing before reuse. A hot shower daily, using plenty of soap, after working with chromic acid is recommended. D.O.T. Requirements OXIDIZER Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 001-333-820 CMA Chemical Safety Data Sheet No.: SD-44 NFPA Guides No.: 49 NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) AIHA Hygienic Guide: 6-56 411538 0065 ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 19 Flammable CD Combustible Toxic By: PRODUCT NEU-TRI SOLVENT CD Corrosive CD Explosive 0 Ingestion (TRICHLOROETHYLENE) CD Water Reactive CD Radioactive JQ Inhalation Phone No. CD Oxidizer CD Chemically Reactive CD Absorption Date: 80-03-06 Section I. MATERIAL DESCRIPTION c <0 i| ^<3 > Material Name: Chemical Name & Formula: Other Designation: Corporate Stock No.: Manufacturer: NEU TRI SOLVENT (See AMSDS No. 23) 2chci=cci Stabilized Trichloroethylene; TCE, Stabilized, 051-770-0194 (PL - 194) Dow Chemical Company, Midland, MI 48640 3.-8 Trichloroethylene with up to 3% of proprietary stabiliser rrrivt-,rr ss Section II. INGREDIENTS HAZARD DATA 6-g a Trichloroethylene C2HCI3 Proprietary Stabilizer Mixture* 8-hr TWA 100 ppm** None established 1-1 *Stabilizer includes several compounds, including amines and epoxies; epichlorohyarin (ACGIH, 1978, TCE c^ Qj TLV change to 2 ppm) is present at less than 0.5% in this blend. Human, inhalation TCLo **NI0SH (1978) has requested OSHA to lower this expost level because of evidence of a potential carcinogen! hazard to man. TLV of 25 ppm was indicated as readi achievable. ____ __________________________________________________ Section III. PHYSICAL DATA 160 ppm/83 minutes (central nervous system) Physical Form: Boiling Temp.: Liquid @ 1 atm ---------------------------------------- Freeze-Melt Temp. Vapor Pressure: @ 20 C, mm Hg -------------------------- Evaporation Rate: (CC1A=1) ------------------------------------------- Specific Gravity: <? 25 C------------------------------------------------- Density: Vapor (Air = 1) ---------------------------------------- "Solubility In H20": @ 25 C, g/100----------------------------- Color: A colorless liquid 189F (87C) 66 ca 0. 7 1.46 4.5 0.1 Volatiles, %---------------------------------------Ca 100 Odor: Sweet, ether-like odor Section IV. FIRE AND EXPLOSION DATA Flashpoint None__________________________ I Auto-Ignition Temp. | 788 F (420C)[ | Flammability Limits In Air Volume % at 100C| I Lower I Upper 7.8 1 32 Extinguishing media: Water fog. This material is generally considered non-combustible; however, at vapor temperatures above 50 C (122F) in air it can be made to burn. Firefighters must use self-contained breathing apparatus when this material is involved in a fire situation. Use water spray to cool fire-exposed containers. Section V. REACTIVITY DATA This material is stable under normal conditions of handling and storage. The stabilizer content is required against oxidation, degradation and polymerization when heated (as in a vapor degreaser) or exposed to sunlight. High energy exposure, such as a welding arc or open flame can generate phosgene (toxic) and IICI. It will react with strong alkali (KOH or NaOH) to form explosive chloroacetylene, but soda ash does not react in this manner. Aluminum chloride can catalyze the polymerization of trichloroethylene. 411538 0066  .__________________________________________________________________________________________________________No. 19 Section VI. HEALTH HAZARD INFORMATION [TLV 100 ppm (See Section II) Excessive inhalation causes irritation of respiratory passages and can produce headache, dizziness, nausea, unconsciousness and even death. Eye exposure to vapor can be irritating and to liquid is irritating and causes minor corneal injury. Prolonged or / repeated contact with the skin produces irritation and dermatitis. Direct, confined skin contact can cause bums. Ingestion irritates the GI tract and produces narcosis; unconsciousness and kidney failure can occur in severe cases. \ FIRST AID: Eye Contact: Flush immediately with plenty of running water. Continue washing eyes for at least 15 minutes; then get prompt medical attention. Skin Contact: Promptly remove contaminated clothing. Wash exposed areas with soap and water. Inhalation: Remove to fresh air; restore breathing if required. Keep at rest and warm. Immediately consult physician. (Advise him not to give adrenalin.) Ingestion: Do not induce vomiting! Get immediate medical help. (Warn physician not to use adrenalin.)_____________________________! Section VII. SPILL. LEAK & DISPOSAL PROCEDURES;" ' ______________ Evacuate area; provide maximum ventilation; eliminate ignition sources. Confine spill; do not allow to run to sewer. Pick up spill with vacuum or an absorbent solid and store in closed container for disposal. Notify safety personnel for large spills. Clean-up personnel should use protection against inhalation of vapors and contact with liquid. (See Section VIII.) DISPOSAL: Send to a reclaimer to recover TCE, or dispose of absorbed material in an approved landfill, or bum waste in an approved incinerator with HC1 scrubber. Follow Federal, state and local regulations. REFER TO LOCAL SPCC PLAN. Section VIII. SPECIAL PROTECTION INFORMATION ( Provide general ventilation and local exhaust ventilation to meet TLV requirements. Do not use in confined area without proper ventilation or respirator use. Approved respirators should be available for emergency and non-routine use. Use NIOSH approved 'v- respiratory protection where the TLV concentration is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied- air respirator, etc.) will depend upon the actual or potential concentration present. Prevent prolonged or repeated skin contact by use of neoprene gloves and, where splashing is possible, an apron. Use splash-proof goggles for eye protection. Gas-tight goggles should be used by maintenance and emergency personnel. An eye wash fountain shall be close enough to be reached within 5 seconds. Provide adequate ventilation to sumps and low areas to disperse any coll erf-inn of heavy TPF. Section IX, SPECIAL PRECAUTIONS & COMMENTS vapor.! Store in a cool, dry, well-ventilated place away from high temperature sources. No smoking in storage or use areas. Store away from strong acids or bases. Only trained personnel should operate a degreaser with this material. Monitor stabilizer level (see supplier). Avoid collecting aluminum fines or chips in a vapor degreaser. TCE continues to be under study as a suspected carcinogen in man. Exercise due caution in use. Avoid skin contact. Avoid breathing vapors. Preclude from exposure those with prior disease of the lungs, liver, kidneys, or central nervous system. Medical surveillance and biological monitoring is recommended. D.O.T. Requirements * j ' ORM-A (REGULATED BY AIR ONLY) Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 000-079--016 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: 49 NSC Data Sheets: Supplier Product Literature: Other: c 411538 0067 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET b ALCOA HAZARD CHARACTERISTICS Flammable 0 Combustible jjt) Corrosive 0 Explosive O Water Reactive 0 Radioactive 0 Oxidizer 0 Chemically Reactive Toxic By: 3 Ingestion 0 Inhalation 0 Absorption INU. PRODUCT PHOSPHORIC ACID Phone No. Date: (75 to 85%) 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: PHOSPHORIC ACID (75 to 85%) Chemical Name 8t Formula: H^PO^ Other Designation: Orthophosphoric Acid (75 to 85%), 75 to 85% Aqueous Hydrogen Phosphate, Corporate Stock No.: Manufacturer: Available from many sources Section II. INGREDIENTS Hydrogen Phosphate (H_P0,) Water J4 % 75-85 Balance HAZARD DATA 3 TLV 1 mg/m for phosphoric acid (A 75-85% solution can be prepared by mixing 54.1 to 61.6% of P^O^q in water. Impurities vary for each manufacturing plant.) Rat, oral LD 1530 mg/kg Section 111. PHYSICAL DATA _ Physical Form: --H.i.--P0-4, ---c---o--n---t-e---n--t- 75% 85% 100% pH----------------- Less than 1 Boiling Temp.: 1 atm----------------Freeze-Melt Temp.:-------------------------Vapor Pressure: mm Hg /U F-----Evaporation Rate: 275F (135C) 316F (158C) 0.5F (-17.5) 70F (21C) 6.4* 2.2* ca 500F 108F (42C) 0.03 Molecular Wt. (H,P0.) 98.0 Specific Gravity: (20/4C)------------Density: "Solubility In H2O": 1.579 1.689 Completely soluble 1.83 Volatiles above 650 F, %----------------- - ca 100 Color: 75%-85% acid is a clear water-like liquid, syrup--like in viscosity at 20C. Odor: 1 *High vapor pressure is due to solvent water. Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. INone - non-flammable N/A I Flammability Limits In Air I n/A I Lower I n/A Phosphoric acid, though non-flammable, can cause hazardous conditions when involved in a fire. Avoid exposure of the skin and eyes to splashes and mists; use respiratory protection as a precaution when phosphoric acid is in a fire area. Cool sealed tanks of phosphoric acid with water spray to avoid rupture from heat generated pressure. Phosphoric acid can react with metals to liberate hydrogen, which is flammable gas that can readily form explosive mixtures with air. Section V. REACTIVITY DATA Phosphoric acid is a stable chemical under normal conditions of storage and use. It reacts with alkalis (bases) to form phosphate salts and is corrosive (especially when hot) to many metals and alloys. (It liberates hydrogen gas when reacting with metals.) It is classed as a strong mineral acid. 411538 0068 No. 20 Section VI. HEALTH HAZARD INFORMATION | TLV 1 rng/nT* As a strong mineral acid, phosphoric acid is corrosive and can cause irritation or bums on a contact with any body tissue. sulfuric acids.) (It is less hazardous in this respect than nitric or The low vapor pressure of H3PO4 at room temperature gives very little inhalation hazard^ except when the acid has been formed into a mist. V_ Overexposure results in irritation or bums of contacted body tissue. There are no reported cases of systemic effects: First Aid: It does not cause "phosphorus poisoning." . Eye Contact: Immediately flush (including under eye lids) with much running water for 15 minutes or more. Contact physician as soon as possible. Skin Contact: Flush affected areas with much water. Remove contaminated clothing under the safety shower. Get medical assistance, except when bum is minor. Inhalation: Remove to clean air. Restore breathing. Call physician immediately. Ingestion: Immediately dilute the acid by ingesting large amounts of water or milk; then give milk of magnesia. Vomiting can be induced; if it occurs, continue to administer fluid, especially milk. Get medical assistance as soon as possible. 1 Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Neutralize spilled acid with an alkaline material, such as soda ash or lime, and/or dilute with water. Flush small amounts of the neutralized or highly diluted material to the . seWer, if this is in accordance with local law. (Note that this procedure adds phosphates to surface water and may not be desirable even if it is legal.) Phosphoric acid can be absorbed on excess alkaline solid, such as soda ash; and the solid disposed of in a suitable landfill. Set up predetermined plans for handling large spills. Contact supplier for assistance in this planning to meet local requirements and to dispose of large amounts. REFER TO LOCAL SPCC PLAN. Section VIII. SPECIAL PROTECTION INFORMATION f Use general ventilation to keep below the TLV concentration of 1 mg/m3. Respiratory protection is not required at normal room temperatures, except when phosphoric acid mists are formed and ventilation is inadequate to meet the TLV limits. Under these conditions, use NIOSH approved respirators where the TLV concentration is or may be exceeded. The selection of the appropriate respiratory protection (half-facepiece respirator, selfcontained breathing apparatus, supplied-air respirator, etc.) will depend upon the actual or potential concentration present. Eye protection - Use chemical safety goggles or a face shield to avoid splashes of acid into eyes. Eye wash fountain shall be close enough to be reached within 5 seconds. Other protection - Use rubber gloves and, if necessary, rubber apron, rubber clothing,, etc. to ayoid.contact, of.acid with the bodv under the. use conditions. be -immediately available where phosphoric acid is used. ; Safety showers shall Section IX. SPECIAL PRECAUTIONS & COMMENTS____________ __________________________ Store 85% acid above 70 F, 80% acid above 40 F, and 75% acid above 0 F to prevent crystallization from occurring. (Phosphoric acid solutions will normally supercool without crystallization, but this effect is unpredicatable.) Phosphoric acids should be stored in clean ventilated storage areas with good drainage. The acid should be stored away from reactive materials, metal powders, etc. Soda ash or lime should be kept in same general areas for emergency use. Corrosion of equipment and surfaces should be considered in areas where hot or "misted" phosphoric acid is present. D.O.T. Requirements CORROSIVE MATERIAL Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 007-664-382 CMA Chemical Safety Data Sheet No.: SD--70 NFPA Guides No.: 49 NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) AIHA Hygienic Guide: 6-57 411538 0069 For Internal Company Use Only - Not To Bo Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 12 CD Flammable jp Combustible Toxic By: PRODUCT ACETIC ACID, 0 Corrosive O Explosive 0 Ingestion GLACIAL CD Water Reactive CD Oxidizer O Radioactive 0 Chemically Reactive 0 Inhalation Q Absorption Phone No. Date: 80-03--06 Section I. MATERIAL DESCRIPTION Material Name: ACETIC ACID, GLACIAL Chemical Name & Formula: CH3COOH Other Designation: Corporate Stock No.: Manufacturer: Ethanoic Acid, Anhydrous Acetic Acid, Methane Carboxylic Acid Available from many suppliers. Section II. INGREDIENTS Acetic Acid (CH^COOH) % HAZARD DATA 99.5% TLV 10 ppm ainimum Mouse (oral) LD50 5g/kg Section III. PHYSICAL DATA Physical Form: Liquid Boiling Temp.: 1 atm-------------------- Freeze-Melt Temp.: Vapor Pressure: <? 25 C, mm Hg -- 244F (118C) ____ 62F (16.6C) -- 14.8 Evaporation Bate: Specific Gravity: 20/4 C-----------------------------------------------------1.05 Molecular Wt.------------------------------60.06 Density:Vapor (Air = 1)--------------------------------------------------2.07 "Solubility In H20": Color: Clear, colorless, mobile liquid Odor: Characteristic, sharp and pungent, vinegar-like odor which is perceptible (unfatigued) above 1 ppm. Section IV. FIRE AND EXPLOSION DATA Flashpoint i Auto-Ignition Temp. (Flammability Limits In Air 112 F (44.5C) TOCj 800 F (427C)|% bv volume1 I Lower I Upper 4 1 ]6 Glacial acetic acid is a combustible liquid. Fires involving this material may be ^extinguished with water, dry chemical, carbon dioxide or alcohol foam. Water diluted acid can react with metals to produce hydrogen gas. Self-contained breathing apparatus should be used to protect against suffocating and corrosive vapors when this material is involved in a fire situation. Wear full protective clothing. Use water to keep fire-exposed containers cool. Section V. REACTIVITY DATA This material is a stable chemical when stored and handled properly. It may react violently with such chemicals as ammonium nitrate, phosphorous trichloride, potassium hydroxide and other alkaline materials, and strong oxidizing agents. 411538 0070 Section VI No. 12 HEALTH HAZARD INFORMATION I TLV 10 P?31 r 25 mg/md Inhalation of vapor concentrations over 50 ppn is intolerable to most people, resulting in nose and throat irritation. Repeated exposure to high concentrations may produce congestion of the pharynx. Neither odor nor degree of irritation are adequate to indicate vapor concentrations. Skin contact can produce deep burns, with skin destruction. High vapor concentrations may blacken the skin and produce allergenic C reactions and eye irritation. Eye contact will cause immediate burns and possible permanent damage. Ingestion is improbable as the odor would be extremely irritating; but severe intestinal irritation would result with burns to the mouth and the upper respiratory tract. FIRST AID: .................... . `" Inhalation; Eye Contact: attention! Remove victim to fresh air; rinse couth and nasal passages. Irrigate with water immediately for at least 15 minutes. Obtain medical Skin Contact? Wash immediately with copious water. vr. 'i fl Ingestion: Rinse mouth. '.Give 3 glasses milk or water. . Obtain medical attention.quickly Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Notify Environmental personnel. Provide adequate ventilation. Personnel cleaning up large spills should wear self-contained breathing apparatus and equipment to prevent contact with the liquid. Contain and pick up large spills for waste disposal. Liquid surfaces of small spills or residue should be covered with sodium bicarbonate and flushed with a large excess of water to the sewer. Dispose of waste material by incineration; or dispose of neutralized waste in a landfill or by controlled flushing down the sewer with copious water. REFER TO LOCAL SPCC PLAN. T Section VIII. SPECIAL PROTECTION INFORMATION_______________ __________________ _______________ /~ Provide adequate exhaust ventilation to meet TLV requirements. Use NIOSH approved ^ respiratory protection where the TLV concentration is or may be exceeded. The selection of appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc.) should be based on the actual or potential concentration. Exhaust hoods should have air velocity of 100 lfm minimum. Wear rubber gloves, aprons, etc. to prevent skin contact. Splash proof goggles or face shields should be worn to prevent any eye contact. Gas tight goggle's may also be required to prevent vapor irritation of the eyes. Eye wash fountain shall be close enough to be reached within 5 seconds. Safety shower shall be readily available where this material is handled. Section IX. SPECIAL PRECAUTIONS & COMMENTS___________________________________________ Use with adequate ventilation. Prevent skin and eye contact as this acid is a powerful tissue destroyer. Olfactory detection at 1 ppm is well below the TLV; however, documentation shows workers can tolerate up to 200 ppm, probably due to olfactory fatigue. Suspected areas of high acetic acid concentrations or variable concentrations should be tested before employee exposure. Exhaust ducts for ventilation should be acid resistant. D.O.T. Requirements 00EROSIVE MATERIAL LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 000-064-197 CMA Chemical Safety Data Sheet No.: SD-41 NFPA Guides No.: 49 NSC Data Sheets: 410 Supplier Product Literature: Other: CHRIS (1974) AIA Bulletin C-52 AIHA Hygienic Guide: 9-72 c 411538 0071 % For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 13 EH Flammable C3 Combustible Toxic By: PRODUCT AMMONIA, ANHYDROUS 13 Corrosive EH Explosive 0 Ingestion EH Water Reactive EH Radioactive fD Inhalation Phone No. Oxidizer EH Chemically Reactive EH Absorption Date: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: ANHYDROUS AMMONIA Chemical Name & Formula: NH3 Other Designation: CAS// 007-664--417 Corporate Stock No.: Manufacturer: Available from many suppliers. Supplied pressurized in cylinders or tanks as a liquid or gas depending on the temperature and pressure conditions._ Section II. INGREDIENTS HAZARD DATA Anhydrous Ammonia ------------------ TLV 50 ppm* TLV 25 ppm** *Current OSHA TLV. OSHA has proposed a 50 ppm ceiling limit with a 5 minute sampling time. i*Current ACGIH TLV. < Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Pressurized liquid or gas pH of 1% water solution -- 1 atm, -------- --28F . (-33.4C) Molecular weight----------------------- deg F (C)---------------------------------108F (-77.7C) Volatiles, %---------------------------------- at 60 F, mm Hg-------------- 4800 Evaporation Rate: Specific Gravity: at 60 F---------------------------------0.62 Density: Vapor (Air = 1)----------------------- 0.6 "Solubility In H20": g/!0 cc: 0C----------- 89 Color: Liquid at low temp, ' moderate pressure. Coloress gas at moderate temperature, low pressure. Strong, pungent odor which can be detected by smell below 5 ppm. --------11.7 -------- 17.03 -------- ca 100 Section IV. . FIRE AND EXPLOSION DATA Flashpoint Gas at Rm. Cond. N/A | Auto-Ignition Temp. I 1204F (651C) ca 100 IFIammability Limits In Air I percent by volume | Lower I Upper I 16 | 25 Water, spray or fog, is best fire-fighting media in presence of ammonia. Special fireprocedures: Stop flow of gas, use water to keep exposed containers cool and to protect men effecting the shut off. Wear self-contained breathing apparatus and full protective clothing. If gas is leaking or tanks are heavily exposed to heat, evacuate the immediate area and the area downwind of the fire. Heat exposed tanks can explode! 6 V Section V. REACTIVITY DATA Anhydrous ammonia itself can be considered stable; however, contact of ammonia with certain other chemicals including mercury, chlorine, iodine, bromine, calcium, silver oxide, or hypochlorite can form explosive compounds. As a basic material, ammonia will react with acids with much heat -evolution. It also reacts with carbon dioxide from the atmosphere. A water solution of ammonia is called ammonium hydroxide, indicating the basic nature of the material. 411538 0072 Ho. 13 Section VI. HEALTH HAZARD INFORMATION | TLV OSHA i>0 ppm; ACClfi 25 ppm Present OSHA TLV (1968 ACGIH) for ammonia is 50 ppm with' a proposed deiT-ing Hmir nf 50 joppra; present ACGIH TLV is 25 ppm. Nasal detection for ammonia is .reported to occur at less than 5 ppm, with irritation at 25-50 ppm. Effects of overexposure: Ammonia gas is extremely irritating to the eyes, nose; it ( may cause permanent damage or death if exposure Is prolonged :at high concentrations. Skin damage can occur from prolonged or repeated contact with this alkaline material. ;Contact with liquid ammonia will 'cause frostbite. *..* ' * ' V; FIRST AID: Inhalation: Remove to fresh air and call a physician at once. If not breathing, apply artificial respiration. " ;1 Skin Contact: Immediately flush skin with water, remove contaminated clothes at once. : Eye Contact: . Irrigate eyes for 15 minutes with copious amounts of water. .Hold eyelids <rt: apart during water flush. Speed in rinsing out the eyes with water after contact is 'extremely important if permanent `injury is to be avoided.' Contact a'physician as soon = ;as possible. . , Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact Environmental. Manager. Evacuate people in area of leak and downwind from a leak. :Eliminate ignition sources. Use a cold water spray to absorb ammonia gas. Personnel -working with ammonia'leak should use protective clothing and equipment, including either r. vi : a specific NH3 cannister gas mask approved by KIOSH or by US Bureau of Hines (below 1250 ppm) or a NIOSH approved self-contained breathing apparatus. Area should be well Ventilated prior to rehabilitation. If possible, sample air environment using approved tanalytical procedure. Well-diluted ammonia solution in water may be disposed of by flushing down the sewer. Written emergency-plans must be made ahead of time to handle massive spills. . . REFER TO LOCAL SPCC PLAN. Section VIII. SPECIAL PROTECTION INFORMATION'... , , .. Facility for anhydrous ammonia use should be mechanically exhaust vented to keep below the OSHA TLV. Use NIOSH approved respiratory protection where the TLV concentration is. or may be exceeded. The selection of the appropriate respiratory protection (selfcontained breathing apparatus, supplied-air respirator, chemical cartridge respirator, etc.) will depend upon the actual or potential concentration present'. Established emergency procedures and protective equipment should be readily available at any facility using anhydrous ammonia. Emergency equipment should include: (1) NIOSH approved self contained breathing apparatus, (2) rubber outer garments - boots, gloves, coats, and (3) chemical safety shower. An eye wash fountain shall be close enough to be reached within 5 seconds. Section IX. SPECIAL PRECAUTIONS & COMMENTS_______________, ________ Anhydrous ammonia cylinders or tanks should be stored in a cool, well ventilated, fireresistant location, away from all possible sources of ignition. Storage is preferred external to building out of direct sunlight. Storage should be separate from other chemicals, particularly oxidizing gases, such as chlorine and materials as listed in Section V. Anhydrous ammonia cylinders should not be physically shoved or dragged or be made part of an electrical circuit.. Work practices and equipment must prevent contact of liquid ammonia or ammonia solutions with the worker s body. " D.O.T. Requirements . .. NON-FLAMMABLE GAS Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 007-664-417 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: 49 NSC Data Sheets: 251 Supplier Product Literature: 0,her: CHRIS (1974) AIHA Hygienic Guide 2-71 c 411538 0073 For Internal Company Use Only - Not To Da Distributed Outside The Company 0 ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 14 Cl Flammable O Combustible Toxic By: PRODUCT CALCIUM HYDROXIDE 3 Corrosive CD Explosive ED Ingestion Water Reactive CD Radioactive CD Oxidizer 0 Chemically Reactive 0 Inhalation 0 Absorption Phone No. Date: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: CALCIUM HYDROXIDE Chemical Name & Formula: Ca(OH) 2 Other Designation: Hydrated Lime, Corporate Stock No.: Slaked-Lime, High Calcium Hydrated Lime, Caustic Lime, '' Calcium Hydrate Manufacturer: Material available from many sources, including: Harshaw Chemical Co.. Cleveland, OH 44106; Warner Co., Bellefonte, PA 16823 Section II. INGREDIENTS Typical Composition:* Calcium hydroxide, Ca (OH)2 Calcium carbonate, CaCO^ Magnesium oxide, MgO Other oxides (A^O^, Fe23> Si02> etc.) % 90 .4 3 3 HAZARD DATA 8-hr.- TWA 5 . 3** mg/m Commercial material prepared by hydration of lime. **The current level recommended by ACGIH (1978). Section III. PHYSICAL DATA Decomposition Point --------------Boiling Temp.: ------------ 1076F (580C) Freeze-Melt Temp.: Vapor Pressure: Molecular weight CaCOH^-----------------------------------------------74.1 Specific Gravity: 0^0= 1)-----------------------------------------------2.3-2.4 ph of saturated solution at 25 C------------------------12.5 "Solubility In H20": ca 0.1%, slight Color: Crystals or soft, white powder or granules Odor: Odorless Rat, oral LD*.,. 7340 mg/kg Section IV. . FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. NA_________ J________ | Flammability Limits In Air I Lower Upper 1 _________________ I Extinguishing Media: This material is non-flammable. Use extinguishing media which is appropriate for the surrounding fire. When heated above 580 C, material can decompose to produce CaO. When this material is involved in a fire situation, firefighters should wear full protective clothing, and use eye protection and self-contained breathing apparatus. Section V. REACTIVITY DATA This is a stable solid in a sealed container at room temperature. When exposed to the air it will absorb carbon dioxide and form calcium carbonate. When heated at temperatures above 580 C, it loses water to form calcium oxide or lime. Calcium hydroxide is a strongly alkaline material which is incompatible with acidic materials. It forms salts with nitroparaffins in the presence of water which are explosive when dried. It can cause the explosive decomposition of maleic anhydride. Boiling elemental phosphorus in a calcium hydroxide solution can liberate spontaneously flammable phosphines. 411538 0074 Section VI. HEALTH HAZARD INFORMATION | TLV 5 rng/m No. ' X'<76#u-.y'&T\&Z \Y"-vPfY;.x; 'kYi t-* This alkaline material in the presence of moisture, is irritating and can be-damagihg to: human tissue. Excessive skin contact, will irritate the skin and produce der^titls^"-;.':'' Eye contact gives a burning sensation with irritation and .possible anjui^if ' lnhaiation in dus.t form is irritating and can be damaging to 'the mucous membranes ppf^theTupper respiratory tract. Do not ingest. " riCvY sfe FIRST AID! I " L.; . i . ' -'!W' ; f Eye Contact: Promptly flush with plenty of running water ^including at least 15 minutes; then, get prompt medical attention.. t:. t Skin Contact: Wash exposed skin with plenty of water. Remove contaminated clothLging; promptly. Get medical help if exposed area is large or if irritatiqn persists. Inhalation: Remove to fresh air. Contact physician immediately1?'' 'j> 4 Ingestion: . Dilute by giving' 2 .glasses of water or milk to drink*< followed by fruit juice or diluted vinegar to .neutralize the alkali; then, consult physician. ..:. .. : r-i- ' .-;.V Section VII. SPILL. LEAK & DISPOSAL PROCEDURES 3 i'-jr* Those involved in dean up of spills should use; protective equipment. : * Pick up spilled powder 1avoiding dusting conditions and .place in a dean steel container for disposal. Environmental personnel should bej-involved when 1 arge ap^lTyoccuriffi'Tfaces,- of residue can be flushed to the sewer, but neutralization before flushing mayybOi-required: DISPOSAL: Follow Federal, state and local regulations for disposal. . Consider. the: : ^following methods of disposing of scrap material: Use to neutralize waste acid;' ;or spread on surface of ground in an isolated* protected area to ,i?eiac^wt't|H' ifhe'^ikr^oi'Sjsrii': CaCO^ (limestone); or disperse in water, neutralize with hydrochloric Acid, precipitate . with soda ash and flush to sewer with much water to keep below 250'mg NaCi/iiter; .; ! ]- C .) vr . uj'1 . j -"ip, Section VIII. SPECIAL PROTECTION INFORMATION 'Provide general ventilation and local exhaust ventilation for dust control (or mist. control if used as a water dispersion) to meet TLV requirements'll^e^NIOSH?appinved!'i>-lv:i`:'t.;'; respiratory protection| where the TLV concentration is or may be - exceeded. ^The' selectibh of the appropriate respiratory protection (half-facepiecerespirator,-self--cqhtaitiWd!l breathing apparatus, supplied-air respirator, etc.) will depend oh the actual ot potential : concentration present.' .X.'i j. ' ' iV'&r ' /' '*. Wear rubber gloves, protective clothing, apron,-safety glasses or;gbj^les, * face^shiieid, ij r etc. to prevent skin or eye contact with this material as required for the conditions :.V. under which it is used l An eyewash fountain shall be c!6se .ffi.ft'" ft: within 5 seconds. Safety shower shall be readily available where' this ^teriil/ur its' water dispersions, are used.;_____________________________________________` ; i- y~.j Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in cool, dry area in tightly closed container. Protect container from physical '' damage. Keep away from acidic materials and other incompatibles ,(See Section V) v-: Prevent contact with the body or inhalation of dust or mist. Use 'due caution in mixing with water and handling the alkaline water dispersions of this roaterial (milk of lime). Follow good personal hygiene practices. .:eV` ^; *r. *l '.J; "if' ' ,Y 0.0.7". Requirements Section X. REFERENCES ASTMNo.: C259, C53 Chemical Abstracts No.: 001-305-620 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: 241 Supplier Product Literature: L Other: CHRIS (1974) ' w i. Y. t- , `-N*; '' r,.. . For Intornal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 15 [U Flammable O Combustible Toxic By: PRODUCT CALCIUM OXIDE Si Corrosive O Explosive 0 Ingestion 0 Water Reactive 0 Radioactive 0 Oxidizer 0 Chemically Reactive 0 Inhalation 0 Absorption Phone No. Oate: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: CALCIUM OXIDE Chemical Name & Formula: CaO Other Designation- Time, Quicklime, Burnt Unslaked fat ria Corporate Stock No.: Cla' ........................................ Lime, High Calcium Lime, Calx, Manufacturer: Available from many suppliers, including Pfizer, MPM Division, Adams, MA 01220 Section II. INGREDIENTS Calcium Oxide** % >90% HAZARD DATA 8-hr. TWA 5 mg/m3* Magnesium Oxide 0-2.5 8-hr. TWA 15 mg/m^ (fume) *Current OSHA permissible exposure. ACGIH (1978) placed material on Intended Changes List with 8-hr. TWA of 2 mg/m^. **Purity depends on the purity of the CaC03 from whicl. it was prepared.and on the exposure to air during ^storage ana nandling. Can contain Mg02, other oxides. CaCOl and Ca(0H)2.1____ Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Solid at 1 atm-----------5162F (2850C) Color: Odor: Freeze-Melt Temp.: --------- ---------------------- 4658F (2570C) pH at 25 C (approx): 0.2 g/L water ----------- 11.7 1.2 g/L water (sat.) 12.5 White Solid* Odorless Specific Gravity: -----------------------------------3. 2-3.4 Density: "Solubility In H20": g/lOOg (reacts) : *Material commercially available in 0C-----------------------------------------0.14 50C--------------------------------------------0.097 lump, pebble, pelletized and powdered 100C-------------------------------------------------------------------------------0.054forms. Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. Not flammable{ N/A|| N/A | N/A Flammability Limits In Air Lower | Upper In small amounts, its presence in a fire does not hinder the use of any standard extinguishing medium. Wear self-contained breathing apparatus approved by NI0SH. Protect eyes from dust. In large amounts in contact with water, steam or acidic material it can evolve'much heat. Therefore, if it is necessary to use water on adjacent burning materials, flood with large amounts of water to absorb heat generated. Section V. REACTIVITY DATA It is incompatible with boric oxide, acids, fluorine, water, steam and many organic materials. This strongly alkaline material is stable in sealed containers at normal temperatures. Hazardous polymerization will not occur. Calcium oxide will swell, and generate heat when moistened and could burst containers. Fluorine will attack calcium oxide, evolving much heat and some light. When exposed to air, it will react with the moisture and carbon dioxide in the air. 411538 0076 Section VI. HEALTH HAZARD INFORMATION TLV 5 - m: No. 15 Calcium oxide is a strongly alkaline material; contact with skin and eyes will cause*: irritation and possible severe corrosion damage. Inhalation of dust may:cause,coughing; sneezing, inflammation of the respiratory passages. FIRST AID: ; :1 ... V-.." ;rV: ! ' ** Eye Contact: Wash eyes immediately with running water for 15 minutes, including under eyelids. Get prompt medical attention!. > ; ^ !;! Skin Contact: clothing. Wash Inhalation: Remove exposure area with large acounts of water. v Remove from exposure to dust and, get prompt medical help. contaminated;, b ,4- . '4 * Ingestion: Immediately dilute chemical by drinking large amounts of water or milk. Then neutralize by drinking dilute vinegar or fruit juice. Section VH. SPILL. LEAK & DISPOSAL PROCEDURES Those involved in clean up must use personal protection against skin contact with lime and inhalation of dust or mist (See Section VIII). Keep spilled material away from organic materials and water. Carefully pick up the solid with a-minimum of dusting and collect in metal containers with covers for disposal. ' DISPOSAL: Contact Environmental Manager. Waste lice can be used for neutralizing.plant acid wastes Section VIII. SPECIAL PROTECTION INFORMATION .Provide general ventilation and local exhaust ventilation to meet TLV requirements forV, lime dust. Use NIOSH approved respirators where the TLV concentration is or may be' exceeded. The selection of the appropriate respiratory protection (half facepiece- respirator, self-contained breathing apparatus, supplied-air respirator, etc.) will ; (, depend upon the actual or potential concentration present. In the absence of dust or mist, mechanical exhaust is sufficient. Wear clean,; dry rubber gloves', * clean, '-'4^ ; body-covering protective clothing, and approved eye protection selected fgr the working, -conditions. .- ' '-`b . b An eye wash fountain shall be close, enough to be reached within 5 seconds. shower shall be readily available near the work area. Safety b; v - Section IX. SPECIAL PRECAUTIONS & COMMENTS Store material in sealed containers in dry place, away from acids and organic materials. Protect containers against physical damage. Rereecber that thismateriaiwilligenerate heat by reaction with water; care should be taken to see that this heat is dissipated f safely when lime is deliberately mixed with water. b, : Avoid contact with air to maintain full reactivity of lime. If .exposed to air it will : react with water and with carbon dioxide. , ^ b; ' D.O.T. Requirements ORM-B (REGULATED ONLY BY AIR OR WATER) Section X. REFERENCES _______________ ; ASTM No.: C5,C45,C46,C53,C258,C415,C433,Cdz8 0:ner: CHRIS (1974) '.**. Chemical Abstracts No.: 001-305--788 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: 49 NSC Data Sheets: 241 * ,> ." 411538 0077 i ,l.~ , J1 Supplier Product^Literature: National Lime Association, "Chemical Lime Facts'',' Bulletin i-214!, Special Reference: 3rd Ed., Washington, DC, 1973 f J For Internal Company Use Only -- Not To Be Distributed-Outside The Company m ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No__ il 09 Flammable CD Combustible Toxic By: PRODUCT CARBON MONOXIDE CD Corrosive Explosive 0 Ingestion 0 Water Reactive D Radioactive O Oxidizer 0 Chemically Reactive St) Inhalation O Absorption Phone No. Date: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: CARBON MONOXIDE Chemical Name & Formula: CO Description: cylinders. A flammable, toxic gas which is commercially supplied under compression in (It is also generated during the partial combustion of carbon-containing materials and by various chemical reactions.) Manufacturer: Available from several suppliers, including Matheson Gas Products, Union Carbide Corp., Linde Div., and Airco, Inc., Industrial Gases Div. Section II. INGREDIENTS % HAZARD DATA Carbon Monoxide ^98* 8-hr TWA 50 ppm** Commercial grade in cylinders. Current OSHA regulation. NIOSH recommended in 1972 that an 8-hr TWA of 35 ppm be established with a 200 ppm ceiling level. '. ton, inhalation rCLo 650 ppm/45 min (central nervous system effects) LCLo 4000 ppm/30 min Section III. PHYSICAL DATA Physical Form: Gas Boiling Temp.: at 1 atm-----------------------. -314F (-192C) Freeze-Melt Temp.: Vapor Pressure: (Air = 1)-------------------- 0.97 Molecular weight ----------------------------------------- 28.01 Net heat of combustion at 25 C. J/kg -------------------------2415 Evaporation Rate: Specific Gravity: Density; at 1 atm, 0C, g/liter--------1.250 "Solubility In H20": at 0 C, Wt. %---------------------------------0.004 rnL/100 mL H20---------------------------------3.3 Odor: Odorless Color: Colorless_________________________________________________________ Section IV. FIRE AND EXPLOSION DATA Flashpoint N/A Auto-lanition Temp. 1202F (650C) (Flammability Limits In Air Volume X I Lower I Upper [ 12 { 75 Extinguishing media: Carbon dioxide or dry chemical. Stop the flow of gas. Water spray can be used for cooling fire-exposed cylinders but cannot be relied on to put out the fire. When CO is mixed with air, it is a dangerous fire and explosion hazard. Firefighters must use self-contained breathing apparatus when this material is present in a fire situation. Section V. REACTIVITY DATA This material is stable under pressure in cylinders at room temperature. It does hot polymerize. Carbon monoxide bums in air with a blue flame to produce CO2. If CO is heated in the absence of air at 400-700 C, a disassociation to C and CO2 can occur. 411538 0078 No. 16 Section VI. HEALTH HAZARD INFORMATION TLV 50 ppm The toxic effect of CO is oxygen starvation of the cells (hypoxia). CO has 200-300 times stronger attraction than oxygen for hemoglobin of oxygen to form carboxyhemoglobin (COHb), reducing blood. CO is not metabolized by the body but can and exhaled from the lungs when CO-free air or O2 the blood. At low CO levels it displaces the oxygen carrying capacity of the ~ - be gradually displaced from COHb j is breathed. CO effects on the v body are considered to be reversible as long as brain cell damage or heart failure has not occurred. Breathing 200 ppm CO in air will produce headache, mental dullness, and dizziness in a few hours; 600 ppm CO produces these same symptoms in less than an hour and unconsciousness in about 1.5 hours; 4000 ppm CO is fatal in less than an hour inhalation. Under CO exposure a headache would indicate about 10-20% COHb in the blood; while at 30-40% COHb, common symptoms are severe headache, weakness, dizziness, dimness of vision, nausea, and collapse. (Exercise increases body O2 demand and can bring on symptoms -- at lower COHb levels.) FIRST AID: Remove immediately from CO exposure! promptly administer pure O2 Restore breathing if necessary and Section VH. SPILL, LEAK & DISPOSAL PROCEDURES Evacuate people from leak area. Eliminate sources of ignition. Provide explosion-proof ventilation of area to keep CO concentration below explosion limits. Those involved in controlling CO leakage must use self-contained or air*-supplied breathing apparatus. DISPOSAL: Remove leaky cylinders to remote area to empty; then return to supplier with label indicating that repairs are needed. The waste CO can be piped to an approved incinerator or the cylinder can be placed in a pit to burn CO to CO2 under controlled conditions. Follow Federal, state and local regulations. Section VIII. SPECIAL PROTECTION INFORMATION( Provide adequate general and local exhaust ventilation to meet TLV requirements in the'~- workplace where CO is handled or used. Provide monitoring for CO in the workplace where it is used or known to be generated to be certain that exposures are properly controlled (for example, see ASTM D3162). If methylene chloride (see MSDS #36) and CO exposures occur for the same employees, the levels of both must be controlled below regular TLV levels to prevent COHb build-up in the blood. (Methylene chloride is absorbed through the lungs and stored in fatty tissue; it is slowly metabolized to CO in the body.) Those involved in controlling CO leakage must use NI0SH approved self-contained breathing apparatus. Where the TLV is or may be exceeded the selection of appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc.) Will depend upon the actual or potential concentration present._ Section IX. SPECIAL PRECAUTIONS & COMMENTS Follow the standard safety practices for cylinders of flammable, compressed gas. Store and use in well-ventilated areas. Those with a history of cardiovascular problems or heavy smokers should have greatly restricted exposure to CO in the workplace. Those using paint removers at home (methylene chloride exposure) may require reduced exposure levels to CO in the workplace. NIOSH has issued a report on the behavioral and neurological aspects of low level CO exposure, "Effects of CO on Vigilance Performance," No. 77-124 (1977). D.O.T. Requirements FLAMMABLE GAS Section X. REFERENCES ASTM No.: D3162 Chemical Abstracts No.: 000-630-080 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: 415 Supplier Product Literature: Other: AIHA Hygienic Guide: 8-65 c 411538 0079 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No__17 0 Flammable D Combustible Toxic By: PRODUCT CD Corrosive O Explosive 0 ingestion CARBON TETRACHLORIDE D Water Reactive Oxidizer 0 Radioactive 0 Chemically Reactive 0 Inhalation 0 Absorption Phone No. Date: 80-03-06 Section I. MATERIAL DESCRIPTION Material Name: CARBON TETRACHLORIDE Chemical Name & Formula: CCI4 Other Designation: Tetrachloromethane, Perchloromethane, Methane Tetrachloride Corporate Stock No.: Manufacturer: Available from several suppliers Section II. INGREDIENTS Carbon Tetrachloride % ca 100 *Current OSHA and ACGIH (1978) TLV. NIOSH (1976) has proposed a 2 ppm limit (as measured by a 45 liter sample of air, collected in less than an hour); in addition, it is recommended (based on animal testing}) that the material be labeled "cancer causing agent. ft (Skin) Notation indicates that absorption through the skin can contribute significantly to overall exposure. HAZARD DATA 8-hr TWA 10 ppm* (skin) or 65 mg/nP Human, oral LDLo 60 mg/kg________________________' Human, inhalation LCLo 1000 ppm TCLo 20 ppm (CNS) House, oral TDLo 4800 mg/kg/ over 88 days (cancer) Hamster, oral TDLo 3680 mg/k: /over 30 wks (cancer) Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Liquid @ 1 atm ------------------------------ 170F (76.7C) -9F (-23C) Volatiles, %--------------------------------------------------ca 100 Molecular Weight --------------------------------------- 153.8 Vapor Pressure: Evaporation Rate: @ 20 C, mm Hg --------------- ca 91 Specific Gravity: 25/4 C------------------ 1.585 Density: Vapor (Air = 1)------------- 5.3 "Solubility In H20":@ 20 C, Wt. Z 0.08 Color: A_clear, col9rless liquid Ouodoorr-.3d=eSfehnad5sacotnerjtgheti<i?mspwuerqittije-ssh^forodmorJ. :heThseooudrcder: re2c1o7g4npitpiomninthraeisrh, opldrep(1a0r0e%d ofrfomteCsSt2p; anel) 100 ppm in air, prepared from CH/, Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. Flammability Limits In Air Lower I Upper ___________None None N/A Extinguishing Media: Use that which is appropriate for the surrounding fire. This is a noncombustible liquid. When involved in a fire situation, this material will emit highly toxic and irritating fumes and gases. Metals, such as aluminum and magnesium, can react violently with carbon tetrachloride when hot or burning. Firefighters must wear self-contained breathing apparatus and full protective gear to fight fires involving this material. Section V. REACTIVITY DATA This material is stable under normal conditions of handling and use. It does not poly merize. Thermal--oxidative decomposition will produce toxic, corrosive fumes, including phosgene and hydrogen chloride. Violent reactions or explosion can occur with incompatible materials, such as barium, lithium, sodium, and potassium metal, powdered aluminum, magnesium, dimethylformamide (above 65 C), fluorine, etc. (See NFPA, "Manual of Hazardous Chemical Reactions.") 411538 0080 No..17 Section VI. HEALTH HAZARD INFORMATION TLV 10 DPm (skiT1) See Section TT Carbon tetrachloride is highly toxic by inhalation and ingestion and toxic by skin absorbtion. Excessive inhalation is irritating to the upper respiratory tract and can produce headache, nausea, stupor, unconsciousness, and even death depending on the * concentration and time of exposure. Kidney and liver damage can occur from severe f acute exposure or from chronic exposure. It is a suspected carcinogen in man. Skin contact can be irritating and can result in dermatitis^ Eye contact, either with vapor or liquid, is irritating. Visual disturbances may occur (haze, blind spots, narrowing of visual field, etc.) from systemic exposure. FIRST AID: Eye Contact: Flush eyes well with running water. Get medical help if irritation persists or when visual disturbances occur. Skin Contact: Wash exposed skin with soap and water. Remove contaminated clothing promptly! Get medical help if irritation persists and for all except single minor -- exposures. (Repeated exposures must have medical attention.) Inhalation: Remove to fresh air. Restore breathing if required, and give oxygen for labored breathing (qualified administration). Get medical help. Ingestion: Contact physician promptlyI Gastric lavage is needed. ____________________~ Section VM- SPILL. LEAK & DISPOSAL PROCEDURES - Notify Environmental personnel when large spills occur. Evacuate area. Provide maximum ventilation. Those involved in clean-up must use protection against liquid and vapor (see Section VIII). Pick up for disposal. Small spills and residues can be absorbed on paper, vermiculite, etc., and allowed to evaporate in a hood. DISPOSAL: Follow Federal, state and local regulations in labeling and disposal. Scrap material may be burned in an approved, high temperature incinerator with scrubber to collect effluent HC1; or it may be disposed of via a licensed waste disposal company. REFER TO LOCAL SPCC PLAN. Section VHL SPECIAL PROTECTION INFORMATION ____________ _____________ jT Provide general ventilation and local exhaust ventilation to meet TLV requirements. 1 V. Exhaust hood should have 100 lfm minimum face velocity. Use ventilation to prevent accumulation of these dense vapors in sumps or low lying areas. Use polyvinyl gloves and protective clothing as required to prevent skin contact with this material. Use safety goggles or safety glasses and a face shield for protection against splashing. An eyewash fountain shall be close enough to reach within 5 seconds. "Safety shower shall be readily available near handling or use areas. When possible, substitute a less hazardous solvent for carbon tetrachloride! Use NIOSH. approved respiratory protection where the TLV concentration is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied-air respirator, etc.) will depend on the actual or potential concentration... Section IX. SPECIAL PRECAUTIONS & COMMENTS__________ ______________________ Store in a cool, dry, well-ventilated place which is low in fire hazard. Protect con tainers against physical damage. Keep away from sources of heat, direct sunlight, and incompatible materials (see Section V). Prevent exposure of vapors to high temperature to prevent decomposition to toxic and corrosive gases and vapors. No smoking in areas where vapors may be present. Prevent contact with the skin or eyes. Avoid exposure to vapors. Provide medical surveillance for workers exposed to this material. Individuals with kidney, liver, or central nervous system disorders or who are alcoholics should not be exposed to carbon tetrachloride. CCI4 at 300 ppm has shown teratogenic effects in pregnant rats by inhalation. D.O.T. Requirements: ORM-A (REGULATED BY AIR OR WATER ONLY)_______________________ ______ Section X. REFERENCES ~ ASTM No.: Chemical Abstracts No.: 000-056--235 CM A Chemical Safety Data Sheet No.: SD-3 NFPA Guides No.: 49 & 491M NSC Data Sheets: 331 Supplier Product Literature: Other: CHRIS (1974) AIA Bulletin: C-6 AIHA Hygienic Guide: 12-61 c 411538 0081 ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. 60 Flammable CD Combustible Toxic By: PRODUCT ACETONE CD Corrosive CD Explosive CD Ingestion CD Water Reactive CD Radioactive CD Inhalation Phone No. O Oxidizer CD Chemically Reactive CD Absorption Date: 1979/12/21 Section I. MATERIAL DESCRIPTION Material Name: Chemical Name St Formula: Other Designation: Corporate Stock No.: Manufacturer: ACETONE ch3coch Dimethyl Ketone, Propanone, Available from many suppliers Section II. INGREDIENTS % HAZARD DATA Acetone ca 100 TLV 1000 ppm i --I -i For Internal Company (Jso Only - Not To Be Distributed Outside The Company Rat, oral LD 9.75 g/kg 50 Rabbit, skin LD 20 g/kg 50 Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Liquid -69.7F (-56.5C) Freeze-Melt Temp.: -139F (-95C) Vapor Pressure: Evaporation Rate: mm a ^ ; C----------226 ' 5C --400 (CC14 = 1) ______________0 8 Specific Gravity: (20/4C) 0.79 2 Others Volatiles, %---------1 Molecular Weight ca 100 58.09 Density: (Air = 1) -------------------------2.0 'Solubility In H2O": Totally miscible Color: Clear, colorless Odor: Sweet, mint-like Odor detected at 200-400 pom (500-700 Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. Closed Cup 0*F(-18C)j 1000F (538C) ppm after faH qii.ing. of Flammability Limits In Air % by volume_________ nerves) tte olfactory Lower 2.1* Upper 12,8 Acetone fires are Class B fires; use a blank eting effect to smother flame, Use CO^/ dry chemical, alcohol foam, and wat er mist or fog to extinguish fires. Water may be ineffective in extingui shing acetone fires but may be helpful to cool fire-exposed surfaces. Explosion and fire hazards from heat, sparks or flames; can react vigorously with oxidizing agents. Use self-contained b reathing apparatus when fightin* acetone fire. *An authoritative source lists 2.6%; however, lower literaturi YalUS__LS__listed for safety.__________________________________ Section V. REACTIVITY DATA Acetone is a flammable material as indicated above; but it is stable under normal storage and use conditions, and it does not undergo hazardous polymerization. Avoid contact with strong oxidizing agents s uch as nitrates and perchlorates or concentrated sulfuric acid Oxidation in a deficiency of air can produce carbon monoxide. 411538 0082 K } Section VI. HEALTH HAZARD INFORMATION \ TLV - j.. - n NOW 1 loop ppm or 2400 mg/m3 'i--Af.'..- Acetone is one of the least toxic industrial organic;solvents. Irritation of mucous membranes, headache and narcosis can result from extended; ' exposure to high vapor concentrations.] Prolonged or repeated.:conta'cti *' of the liquid with the skin can have a defatting action and may result' in dermatitis. Absorption through intact skin is not;of great concern " ); in industrial use, since acetone is no expected, to cause^systematic injury. However,! possible skin absorption should be considered in V'.'. meeting TLV requirements. FIRST AIDi , , ;V Eye Contacts Flush promptly with plenty of water and contact a'phyiiclah'. Skin Contact: Wa'h off with water.' ]' ;7 J.*- t t%nh ala>t Ingestion: (f Remove ,to fresh air. it effects are-'nore severe''-.-tiian :'a''.'.-v: headache, contact-a physician. ^ Drink water to dilute. physician. Induce vomiting- and contact'"a."V',''"< Section VII. SPILL. LEAK & DISPOSAL PROCEDURES If spills or leaks 6ccur, eliminate all sources of sparks ahd flames. Flush with water to clear area of material. Avoid breathing vapors. Avoid discharging] directly into sewers and surface waters; Incineration is a recommended method of disposal for large quantities of acetone. I",! '> !' t- . - sj:*..' ..V- ' Section VIII. SPECIAL PROTECTION INFORMATION Use ventilation to meet TLV requirements. For higher concentrations:of: acetone vapor, usp NIOSH approved respiratory protection as required by the acetone level. The selection of the appropriate respiratory ; protection (self-contained breathing apparatus, 'supplied :Vair respirator;, chemical cartridge respirator, etc.) will depend on the`actual or : potential concentration present. ' Si. The. use of safety gjoggles and polyvinyl gloves is recommended to avoid ; contact with liquid acetone. Protective creams- can* a'lso, be - used.] 1 .? Section IX. SPECIAL PRECAUTIONS & COMMENTS Material should be stored in a cool, clean, ventilated, fire-resis,.tant storage room or cabinet to meet OSHA requirements. Store-in drums or. safety cans with Identifying labels which indicate Jth`e'<:flammabilijty of-the; material. . ... -'- "v i'.'W--: Acetone must be stored, handled, and used away from heat,.'"sparks',"-ancf,~:flamesi it is a Clas6 IB Flammable Liquid under the OSHA classification Electrically interconnect and ground containers for all transfersof acetone to avoid fires from static sparks. D.O.T. Requirements FLAMMABLE LIQUID 7]" V ! 1 ;f. Section X. REFERENCES ASTMNo.: D329 Chemical Abstracts No.: CM A Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: No. 398 Supplier Product Literature: 000-067-641 SD-87 Other: 411538 0083 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. Cx! Flammable Combustible Toxic By: PRODUCT ACETYLENE O Corrosive O Explosive Ingestion Water Reactive D Oxidizer O Radioactive Chemically Reactive O Inhalation D Absorption Phone No. Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: ACETYLENE PH Chemical Name & Formula: 2 2 Other Designation: Ethyne, - . -i" Ethine Corporate Stock No.: Available from several sources, including Union Carbide. Gas obtained Manufacturer: from reaction of calcium carbide with water in an acetylene generator or from approved pressurized cylinders packed with porous solid and acetone. Section II. INGREDIENTS % HAZARD DATA Acetylene Gas >98 Rated as simple asphyxiant Typical % by OSHA and ACGIH. NIOSH Impurities:* Generator Cylinder proposed a 10-hour TWA of Carbon Dioxide Z.1.0 2500 ppm because of toxic Nitrogen <1.0 trace impurities Oxygen <0.2 Phosphine 0.018 0.00025 Trace Hydrogen Sulfide 0.004 0.0007 Trace Ammonia *Acetone , (an . .. impurity 0.015 . m cylinder 0f0000 gas) and water es Tfuld. determined from the supplier of the calcium carbidd or the Section III. PHYSICAL DATA Ijmpurity dvlliinder content should be Physical Form: Boiling Temp.: Compressed Gas at 1.22 atm: -103F (-75C) at 1.0 atm: -119F (-84C) Others Molecular Weight: 26.04 Vapor Pressure: Evaporation Rate: Specific Gravity: Liquid: 0.613 at -80C; Vapor (Air = 1) 60F, 1 atm: 0.906 Density: 'Solubility In H20": at 0C, 1 atm, Vol/Vol Watery 1.7 Color: Colorless when pure Odor: Odorless (Most commercial grades have garlic-like odor from the impurities) Section IV. FIRE AND EXPLOSION DATA Flashpoint Gaseous at Room Temp. | Auto-Ignition Temp. J Flammability Limits In Air | SS4-635F (290-335C)| Volume %|2.5 I Lower I Upper { 81* . Extinguishing Media: Extinguish fire by shutting off source of acetylene. Fires from small leaks in containers can be extinguished by plugging leak with wet waste or putty or smothering with a heavy cloth. When fire involves the inner cylinder, it must be handled by an experienced firefighter. Use water spray to cool fire-exposed cylinders. Those involved in fighting fires of acetylene should use self-contained breathing apparatus. Use water spray to "knock-down" vapors. *3-65% mixture in air can be explosive; NFPA #49 indicates upper limit of 100% Section V. REACTIVITY DATA In its free state under pressure, acetylene can decompose violently when heated or shocked to form carbon and hydrogen (no oxygen required). Pressures in excess of 15 psig should never be used for free acetylene without special engineering design. Below 15 psig or in acetone solution in its cylinder, acetylene is stable. Only approved valves and manifolds should be used. It burns in air with a sooty flame. It reacts with copper, silver and mercury to form explosive acetylides. Incomplete combustion of acetylene can form carbon monoxide in high levels. Acetylene can react explosively with oxygen, chlorine or fluorine. 411538 0084 No. 2 Section VI. HEALTH HAZARD INFORMATION | TLV (See Section II) Acetylene, when pure, is classified as a simple asphyxiant; its presence" in high levels can reduce the oxygen concentration of breathed air to such a low level that uncon sciousness or death can result. No symptoms occur from the presence of 2.5% acetylene in air; at 10% a reversible narcosis can be produced; at 40%, collapse. .1 The contaminants in commercial grades of acetylene, particularly in that generated on site from calcium'carbide, can have toxic effects, phosphine for example. In a welding process involving acetylene, metal oxide fume and carbon monoxide may present additional health hazards when acetylene is present in the air. FIRST AID: Inhalation: Remove to fresh air. Restore breathing when necessary. Contact a physician. If acetylene from a 'cai'S'ium'%atbide generator is involved,' . - . -r. - the acute effects of phosphine and other impurities in the acetylene should be considered. : - . v-? v > -- Section VII. SPILL, LEAK & DISPOSAL PROCEDURES If an acetylene leak occurs, notify safety personnel! Provide maximum explosion-proof -.ventilation. Eliminate ignition sources. Exclude people from area except those trained persons involved in control of leakage. Shut off acetylene flow if possible. If the 1 ! j leakage location is found, plug leak with wet waste, putty, heavy cloth, etc. Never use a flame to find source of leakage; paint points of suspected leakage with soapy water and watch for bubbles. . .. DISPOSAL: If practical, move leaking cylinder to a safe, outside, posted disposal area ! i ! for discharge. Gas can be piped to a pit (or to a furnace when possible) and burned; or it is allowed to escape into the atmosphere. When empty, close valves; return cylinder to supplier informing him of the defect. Follow federal, state and local regulations. .. .. - Section VIII. SPECIAL PROTECTION INFORMATION ; 'j Provide general ventilation and/or local exhaust ventilation to keep acetylene concentration below 2500 ppm in the workplace air. This level will control explosion hazards as well as exposure to impurities in the acetylene gas. Avoid use of acetylene in confined areas. Where this is necessary, be sure that suitable fresh air ventilation is provided for. A NIOSH approved self-contained breathing apparatus must be available for emergency work at high concentration. ! Section IX. SPECIAL PRECAUTIONS & COMMENTS Obtain and follow the detailed safety regulations of OSHA fCode of Federal Regulations 29, Chapter XVII, Part 1910.252 (a)1 and the recommendations of suppliers for handling, manifolding, and storage of pressurized gas cylinders and the operation of acetylene generators. Store reserve cylinders away from cylinders of oxygen (and from chlorine and other oxidizing agents) in an upright position. Store in a cool, well-ventilated place away from open flames and other ignition sources. Protect cylinders, manifolds and piping from physical damage. Piping used with acetylene should be electrically bonded D.O.T. Requirements and grounded to prevent static sparks. i i FLAMMABLE GAS Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: SD-7 NFPA Guides No.: NSC Data Sheets: No. 494 Supplier Product Literature: Other: CHRIS (1974) ALCOA ENGR. STANDARDS: 18.6.1 i / j ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- 411538 0085 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. CH Flammable Combustible Toxic By: PRODUCT HYDROCHLORIC ACID. 13 Corrosive Explosive m Ingestion O Water Reactive O Radioactive 0 Inhalation Phone No. O Oxidizer Chemically Reactive Q Absorption Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: Chemical Name & Formula: Other Designation: HYDROCHLORIC ACID HC1 Muriatic Acid, Concentrated Hydrochloric Acid, Corporate Stock No.: Manufacturer: Available from many suppliers Section II. INGREDIENTS Hydrogen Chloride (HC1) % <38 HAZARD DATA TLV 5 ppm (C)* Impurities (depends on acid grade) Traces Balance *C denotes a ceiling concentration that should not be exceeded in the workplace Section 111. PHYSICAL DATA Physical Form: Liquid 18Be' ------------ 20oBe' 22 Be' Boiling Temp.: 1 atm Freeze-Melt Temp.: 208F (97.70 43.6? (-42C) 182F (83.3C) -63.4F (-53C) 144F (62.2C) -86.3F (-65.7C) Vapor Pressure: 25 C, mm Hg -- 25 &efgfii;?n ^ftci Specific Gravity: 60/60 F Density: - 27.9 1.142 31.4 1.160 35.2 1.179 "Solubility In H2O": Complete, 100% Color: Colorless to light yellow fuming liquid Odor: Pungent, suffocating Others Volatiles, %: ca 100 23 Be' 123F (50.5C) -101'2F (-74C 37.1 1.189 Section IV. FIRE AND EXPLOSION DATA Flashpoint I I j1N/A N/A N/A | Auto-Ignition Temp. | Flammability Limits In Air I Lower (Upper Extinguishing Media: Select that suitable for the surrounding fire. This nonflammable acid can react with many metals, such as iron and aluminum to produce flammable hydrogen gas. The acid can be neutralized with bases such as slaked lime or soda wash. Use a water spray to cool fire-exposed containers to prevent rupture. Firefighters should use full protective clothing and self-contained breathing apparatus when this material is involved in a fire situation. Section V. REACTIVITY DATA This material is stable when properly contained and handled. It is a strong mineral acid and is, thus, highly reactive with materials such as metals, metal oxides, hydroxides, amines, carbonates and other alkaline materials. It is highly corrosive to many materials. It can liberate significant levels of HC1 by vapor pressure at room temperature when concentrated and large amounts of HC1 when heated. Reaction with most metals will produce hydrogen gas. 411538 0086 No.. 3 Section VI. HEALTH HAZARD INFORMATION j TLV 5 ppm Ceiling (as HC1) " '. Prolonged inhalation of HC1 vapors or mist just above the TLV can damage- the teeth and irritate the nasal passages. Higher concentrations (50+ppm) will cause coughing and choking and produce severe irritation and damage of the mucous membranes of the upper respiratory tract. 1300 ppm is immediately dangerous to life. .) Hydrochloric acid is corrosive and causes burns of human tissue. Ingestion can produce bums of the mouth and digestive tract. First Aid: Eye Contact: Flush thoroughly with running water for 15 minutes. Get medical aid. Skin Contact; Wash affected areas thoroughly with much water. For gross contact, remove contaminated clothing tinder the safety shower; prolong washing for 15+ minutes. Ingestion:Qive limewater or water and milk of magnesia to drink. Do not induce ~vomitingf~ Ge"medical aid. - . .^.r - .sr-.&r&tl- Inhalation: Remove to fresh air; restore breathing, if required. Oxygen can be given under proper supervision. Get medical aid. ................ Section VH. SPILL. LEAK & DISPOSAL PROCEDURES Large spills should be reported to environmental personnel. Remove sources of ignition. . Supply ventilation. Stay upwind of large spills in outside areas. Those involved in clean-up of large spills must use full protective clothing, boots, and self-contained breathing apparatus. y.Z Flush large spills with water to holding area and neutralize with soda ash or lime. Flushing to sewer depends on allowable salt concentrations in effluent water. Follow local, state and federal regulations. Cover small spills with a mixture of soda ash and slaked lime. Flush the neutralized material to the sewer with much water. REFER TO LOCAL SPCC PLAN. Section VIII. SPECIAL PROTECTION INFORMATION' Provide adequate exhaust ventilation in areas of use or storage to meet TLV requirements-*-' Face velocity of hoods should exceed 100 lfm. Use NIOSH-approved respiratory protection where the TLV is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied air mask, chemical cartridge respirator, etc.) will depend on the actual or potential concentration present. Those handling hydrochloric acid should use protective clothing and equipment to prevent body contact with the liquid. Use rubber gloves or gauntlets, rubber apron, rubber boots, long-sleeved shirt, etc. Use chemical safety goggles and/or face shield for eye protection against splashing of acid. Have safety shower nearby. An eye wash fountain shall be close enough to be reached within 5 seconds. Section IX. SPECIAL PRECAUTIONS & COMMENTS Store closed containers in clean, cool, open or well-ventilated areas. Keep out of sun. Area should have acid resistant floor and approved drainage. Keep away from oxidizing agents and alkaline materials. Protect containers from damage or breakage. Use non-sparking tools in areas around tanks and pipes where hydrogen might be generated. Avoid inhalation of HC1 vapors; if odor can be detected, workers are being over-exposed! Odor of HC1 gives adequate warning for a prompt voluntary withdrawl from the exposure area. Avoid skin contact. Provide emergency neutralization materials and equipment near storage and use areas. D.O.T. Requirements CORROSIVE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: SD-- 39 NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) AIA Bulletin C-30 AIHA Hygienic Guide 8-58 411538 0087 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 4 CD Flammable CD Combustible Toxic By: PRODUCT MERCURY O Corrosive CD Explosive ED Ingestion CD Water Reactive CD Radioactive O Oxidizer O Chemically Reactive EED Inhalation ED Absorption Phone No. Date: 1979-12-21 Section i. MATERIAL DESCRIPTION Material Name: MERCURY Chemical Name & Formula: Hg Other Designation: Quick Silver, - Corporate Stock No.: Manufacturer: Available from many sources Description___________ A liquid, metallic element Section II. INGREDIENTS % HAZARD DATA Mercury 100 TLV 0.1 mg/nr* TLV 0.05 mg/3** * * Present 0SHA level and proposed ceiling limit ** Present ACGIH level vpth a proposed absolute ceiling of 0.15 mg/m Section 111. PHYSICAL DATA Physical Form: Heavy Liquid Boiling Temp.: at 1 atm: 674F (356.90 Freeze-Melt Temp.: 38F (--38.89C) Vapor Pressure: Evaporation Rate: Specific Gravity: aaut 20C, mm Hg: 0.0012 at 126C, mm Hg: 1 <H20=1): 13.54 Density: "Solubility In H20"Nil Color: Silvery Odor: None Human, oral LDL0 1429 mg/kg Human, intravenous LDLC 29 mg/kg Others Atomic Weight: Atomic Number: 200.61 80 Section IV. Flashpoint FIRE AND EXPLOSION DATA | Auto-Ignition Temp. |Flammability Limits In Air I Lower I Upper Mercury is nonflammable and nonexplosive in air. When exposed to high temperature, mercury vaporizes to form extremely toxic fumes. When this material is involved in a fire, firefighters need to use self-contained breathing apparatus. Section V. REACTIVITY DATA Mercury is a stable metallic element. It will react slowly with oxygen when heated, and it reacts with halogens; for example, at 200-300C (392-572F) a flame forms when a jet of chlorine gas is directed over mercury. Mercury dissolves (reacts) in oxidizing acids, such as nitric; but it does not dissolve in hydrochloric acid. Boron phosphodiiodide will ignite in mercury vapor. The following can give explosive mixtures with mercury: acetylene, ammonia, chlorine dioxide, nitric acid plus ethanol, and methyl azide. 411538 0088 J Vi';' . if r,, No .- 4 ;-k * *-S. Section VI. HEALTH HAZARD INFORMATION 1 TLV 0.1 If the mercury in a small clinical thermometer were dispersed.' .fc }loa%*x''15> room, the TLV would be exceeded. Unsafe conditions are. not indicated:by odor^ Severe poisoning can occur with less than two hours of exposure to high. cpn^rttrations^^ vapors. Mercury may be absorbed slowly through the skin. Repeated 'or-'prolongedj contacts may result in poisoning. A single ingestion-'of .a small amount-, of.pure v metallic mercury would not be expected to cause severe -injury::4 However; if the mercury contained mercury compounds, poisoning could result. : ` v f'V" : -,r. ' FI_R__S__T____A__I_D__: In all cases of overexposure to mercury, get medical attention! ! i. '.y Ingestion: Gastric lavage with 5% solution of sodium formaldehyde sulfoxylate, followed. by 2% NaHC03, and finally leave 250 cc the sodium formaldehyde sulfoxylate in ,the stomach. ` fife e* TOO Inhalation: Physician: Remove to fresh air. Check blood and/or urine for mercury levels. -J i7 4 .v. ;>-y V-.iy*,*? P'r- * ' .j Section VII. SPILL, LEAK & DISPOSAL PROCEDURES 'r: ' Clean up spills promptly, (It is convenient to use a suction bottle with a. capillary, tube for small amounts.) Calcium polysulfide with excess sulfur can be sprinkled . Jinto cracks or other inacessible places to convert mercury globulesinto the sulfide. : Collect picked-up or scrapped mercury in tightly sealed containers forreclaim; or. for 'disposal. Do not discharge mercury down therdrsdn! . Ti. *4 Mercury can be purified for reuse, or it earn be sold to a mercury salvage company when v when large amounts are involved. "'""S',' ''''j'c "';yy*rf Mercury is concentrated by animals, plants, and fish. .y Section VIII. SPECIAL PROTECTION INFORMATION Areas of mercury use must have adequate ventilation to meet TLV requirements; - Use wssSr'y;''. NIOSH approved respirators where the TLV is or may be exceeded.- The selection of the appropriate respiratory protection (self-contained 'brea^Mngj^ij|paaal&is;l!'' respirator, etc.) will depend upon the actual''br- potentlaf' Those frequently working with mercury must use rubber glOves. (The use of rubber gloVbs: V and eye. protection is recommended for all. handli'ng ofmerchiry. )' V-.frv-r'\A*-,* Mercury should not be heated without proper precautions to safely 'handlehighlV!to^c^''ML' mercury vapors! : / -T-vl: ...T'"- cS'-V-ivfc ``if. . ,'*'J,. ,* ; Section IX. SPECIAL PRECAUTIONS & COMMENTS Store mercury in small (sealed containers (preferably polyethylene) in a well ventilated -- area. Mercury evaporates very slowly. ; .1; V iSpilled mercury forms many tiny globules that will' evaporate faster them a single pool and can develop a significlmtvcpnc^trati.pri/aE-.t-.' / >, vapors in an unventilated area. Such vapors can be poisonous^ ej^^i'ally^if'breathed *; over a long period of time. '1 "'' ` ' Avoid contact with mercury. Follow good hygienic practices. Periodicmedicairexaminatibns should be arranged_forJthi SISD.O.T. Requirements are neei Sg?l SI?aS^*isG?i|u5l?lfaill?9 air sampling ;t- Jr- - i (AIR) ORM-B Section X. REFERENCES ASTM No.: Chemical Abstracts No.: 007-439-976 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: 203 Supplier Product Literature: ` Other: '--v ' . > ; CHRIS (1974)- vV'i.'';^v- *; ; !v\ ) AIA Bulletin C- 60 >;; AX HA^ Hygieriic Guide 6-66^ 41^538 0089- U; K ! '.''I- y'- y. bc.^4.1 - la.. Not To Be Distributed Outside The Compeny MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No__ L ALCOA 0 Flammable O Corrosive 0 Water Reactive 0 Oxidizer 0 Combustible 0 Explosive O Radioactive 0 Chemically Reactive Toxic By: 0 Ingestion E Inhalation 0 Absorption product methyl alcohol Phone No. Oate: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: METHYL ALCOHOL Chemical Name & Formula: CH3OH Other Designation: Methanol, Wood Alcohol, Corporate Stock No.: Manufacturer: . Available from many suppliers Section II. INGREDIENTS Methyl Alcohol ca 100 HAZARD DATA TLV 200 ppm* (Skin) or 260 mg/m^ Current OSHA TLV; ACGIH (1977) TLV adds (skin) notat4on which indicates a potential contribution to overall exposure via absorption through the skin NIOSH has recommended a 10-hour TWA of 200 ppm with ceiling of 800 ppm (15-minute sample) Section III. PHYSICAL DATA Human, Oral LDLq 340 mg/kg____________ Physical Form: Liquid Boiling Temp.: at 1 atm Freeze-Melt Temp.: 148F (64.5C) Others Volatiles, % - ca 100 Molecular Weight - 32.04 Vapor Pressure: @21.2C, mm Hg - 100 Evaporation Rate Specific Gravity: (CC14=1) - 1 (20/4C) - 0.791 Oensity: (Air = 1) - 1.1 "Solubility In ^CV'Totally Miscilble Color: Odor: Clear, Colorless Characteristic alcohol odor which is detectable at 50 to 100 ppm and above in air Section IV. Flashpoint 52F (11C) FIRE AND EXPLOSION DATA I Auto-Ignition Temp. (Closed Cup)1867F (465C) f Flammability Limits In Air | % by Volume | Lower | Upper (6 136.5 Extinguishing Media: C02, dry chemical, alcohol foam, and water mist or fog. Methyl alcohol fires are Class B fires; use a blanketing effect to smother fire. It is a moderate explosion hazard and dangerous fire hazard when exposed to heat, sparks or flames and can react vigorously with oxidizing agents. Firefighters should use self-contained breathing apparatus with full facepiece and full protective clothing where this material is involved in a fire in an enclosed place. Section V. REACTIVITY DATA Methyl alcohol is a flammable material, but it is stable under normal storage and use conditions. It does not undergo hazardous polymerization. Avoid contact with strong oxidizing agents such as nitrates, perchlorates or sulfuric acid. Oxidation products in air include oxides of carbon and nitrogen. 411538 0090 No. 5 Section VI. HEALTH HAZARD INFORMATION 1 TLV 200 ppm (Skill) br^26pi Methanol is a poisonous, narcotic chemical that may exert its effects through: inhalation, V skin absorption or ingestion. Body elimination of methanolis slowjandthe toxieeffects can be compounded by repeated excessive exposures over several days. Toxic effects > ; are exerted upon the nervous system, especially the optic nerve. .; Ingestioncan- f v' produce blindness. Symptoms of overexposure include dizziness, blurring, of- vision, ; nausea, cardiac depression, muscular incoordination and narcosis. . Solvent'action can dry the skin and cause dermatitis. i- , . ' ,i ; : first aid: ................. ' V Inh___a__l_a__t__io__n__: Remove victim to fresh air and prevent further exposure for 7 days. medical assistance if victim is not fully normal within 10 minutest Skin Contact: Washr,affected ar^a^with^goap and water; apply skin potions ;y Eye Contact1:" Irrigaerwxth running water for 15 minutes. Get .medical,/Kelpr;^ Obtain Ingestion: Drink 3 glasses milk, water or 4% sodium sid for gastric lavage. (NIOSH recommends. inducing vomiting if victim is conscious.). r .-vWai^ivw*.- _ Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Notify environmental personnel. Remove all sources'of ignition; provide adequate:yentilatioT Absorb on vermiculite, paper or other absorbent, Burn in ah approved incinerator or-open pit away from buildings and people. Dispose of large quantities of waste via a licensed waste solvent disposal! cospany, or. reclaim via filtration and distillation procedures, it can:;beincinerated;! v Spills in sensitive areas may be diluted and flushed! to ground with ai water spray. V Do not e > O + C0O JoS> coo p <u O CO co in flush to sewer. Follow federal, state and local 'regulations. i Section VIII Cont. concentration present. .. A full facepiece is required above 2000 ppm. Section VIII. SPECIAL PROTECTION INFORMATION !_ 'j ?:.fr 1 <D C cn -h O -l 4- O H 5 0) *D 0) o at 41 Provide adequate ventilation to meet TLV requirements. Exhaust ventilation with. 100 lfm minimum should be[used where vapor exposure is likely, ExKav^L-jfahs Sh6{tf.'d;;be;i:' explosion-proof. No smoking in areas of use. Prevent skin contact by wearing rubber gloves. Protective aprons, boots and face -shields should be used where splashing may occur. Use^safety glasses in other areas of use. Remove methanol-contaminated clothing promptly. ( Eye wash stations--* Safety showers shall be available in areas of use. Respirator protection for emergency or exposure situations above the TLV: Use NIOSH-r approved respirators where the TLV is or may be exceeded. The selection of-the .; appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or. potential (cont.. under Section VIP* Section IX. SPECIAL PRECAUTIONS & COMMENTS i Prevent skin contact! Do not breathe vapors! This material is poisonous when introduced into the body metabolism. Do not ingest! Store in a well-ventilated, fire-resistant area. ,. . j . ` Ground and electrically interconnect., containers for transfer. Use spark-proof tools. Keep away from heat and .ignition:/ ! '! sources. No smoking in areas' 'of storage or lose. NIOSH recommends preplacement medical medical surveillance and prompt eye overexposure. exams for industrially exposed workers, periodic examination for eye contact with methanol or for '1 any D.O.T. Requirements FLAMMABLE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: No. 407A Supplier Product Literature: Dll 52 000-067-561 SD-22 Other: CHRIS (1974) 411538 0091 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. CD Flammable CD Combustible Toxic By: PRODUCT NITRIC ACID 55-70% 13 Corrosive CD Explosive ED Ingestion CD Water Reactive CD Radioactive 0 Oxidizer D Chemically Reactive ED Inhalation CD Absorption Phone No. Date: Section I. MATERIAL DESCRIPTION Material Name: NITRIC ACID (55--70%) Chemical Name & Formula: HNO3 Other Designation: Aqua Fortis, Hydrogen Nitrate, " ' '2 Corporate Stock No.: Manufacturer: - Available from many suppliers - .fe&s; * Description;A solution of HNO3 in water with properties dependent on concentration. Section II. INGREDIENTS % HAZARD DATA Hydrogen Nitrate (HNO 3) 55-70* TLV 2 ppm ** for nitric acit Water Balance * 68% nitric acid (42Be) is the constant boiling, concentrated nitric acid of commerce; 56.5% nitric acid (38Be) is commercially available ** NIOSH has proposed a 10-hour TWA for this same lev4l Section 111. PHYSICAL DATA Physical Form: Liquid Boiling Temp.: 1 atm, Freeze-Melt Temp.: . Vapor Pressure: mm Hg @ 25C Evaporation Rate: Specific Gravity: 20/4 C Density: Baume Scale, @ 60F 56.5% Acid -4F (-20C) 1.36 38Be 68=% Acid 251F (121.6C) -30F (-34C) 1.41 42<>Be 100% Acid (Unstable) 18IF (83C) -43.6F ' (-41.6C) ca 45 1.50 "Solubility In HnO": Complete Color: Colorless, water-like to slightly yellow, darkens to brownish color on aging and Odor: gP8!!e t0 Li9ht Volatiles 3 122C: 100% Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. Flammability Limits In Air Lower I Upper Nonflammable I Nitric acid is nonflammable; N/A however, 1 M/A it is a strong oxidizing agent and can react with combustible materials to cause fires. Use water spray or fog on fires involving nitric acid to dilute the acid and to absorb liberated oxides of nitrogen. It can also react with metals to liberate flammable hydrogen gas. Self-contained breathing apparatus and full protective clothing should be used by fire fighters in an enclosed area when nitric acid is involved in the fire. Section V. REACTIVITY DATA This material is stable under normal storage and handling conditions. It is hygroscopic (when concentrated), a strong mineral acid, and a strong oxidizing agent. Contact with organic materials such as wood, paper, alcohol, turpentine, etc., may cause fires. Combustible materials can have an increased flammability after contact with nitric acid. Various nitrogen oxides, including NQ, NO2, N2O3, and N2O -- all mixed with nitric acid mist and vapor -- can be produced upon decomposition or reaction of nitric acid. All are toxic. Reacts explosively with metallic powders, carbides, H2S and turpentine (NFPA 849) 411538 0092 No.- 6 Section VI. HEALTH HAZARD INFORMATION TLV 2 ppm or 5 mg/m3 fhis material is corros-ive to all body tissuesl Inhalation of nitric acid mist or fumes at 2 to 25 ppm, over an 8-hour period, may cause pulmonary irritation and symptoms of lung damage. The onset of symptoms following inhalation may be delayed for several hours. Concentration over 200 ppm can cause severe pulmonary damage and may be fatal (in 5-10 hours) after several minutes of exposure. Eye or skin contact will produce immediate bums, with a yellow skin discoloration; eyes may be permanently damaged. IInngestion will produce burns of the digestive tract. Firs1t,Aid: Inhalation: Remove victim to fresh air. Get medical attention. Observe for 4 to 30 hours after exposure. - Skin Contact: Wash immediately with soap and water. (Remove contaminated clothing promptly.) Get medical attention except for minor exposures to small areas of the skinT' Eve Contact^ ^'immediateiy wash with water for at-least 15 minutes. Get medical attention.' Ingestion: -_ Give 3 or more glasses of milk or water. Get medical attention. . . * .: v ~' >V ' -1 V ' : ': v'JSJj' * Section VII. SPILL. LEAK & DISPOSAL PROCEDURES XT'; Notify environmental personnel. Provide adequate ventilation. Eliminate sources of : ignition. 'v - - v.-r- - ~ - '" Self-contained breathing apparatus should be used by personnel when cleaning up spills.'. NeoDrene gloves and body shields should be used to prevent skin and clothing contact. . Surfaces contaminated from spills should be covered with sodium bicarbonate or soda ash to neutralize the acid. Wash the neutralized slurry down the drain with excess water. Federal, state, and local regulations must always be considered prior to sewer disposal, 'if necessary, neutralized spill may be picked up by use of absorbants and disposed of as solid waste in a landfill. * Section VIII. SPECIAL PROTECTION INFORMATION________________________________________ -f Use with proper ventilation to meet the TLV requirements. Exhaust hoods should main- ^ tain a face velocity of 100 Ifm minimum. Exhaust ducts should be fiberglass or other acid-resistant material. Use NI0SH-approved respirators where the TLV is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or potential concentration present. Neoprene gloves and body shields should be used where splashing may occur. Chemical safety shower shall be readily available in areas of storage and handling of nitric.acid. An eye wash fountain shall be close enough to be reached with 5 seconds. Section IX. SPECIAL PRECAUTIONS & COMMENTS. Nitric acid is a corrosive material and will attack skin, metals and many organic sub stances. The nitrogen oxides produced from the acid are all toxic, and proper ventilation should always be used. Nitric acid can ignite certain organic substances. Store in a clean, cool, well-ventilated area, away from organic chemicals, strong bases, metal powders, carbides, sulfides, and any readily oxidizable material. Protect from direct sunlight, neutralizing and absorbing materials such as soda ash and sand should be readily available to areas of use and storage of nitric acid. D.O.T. Requirements OXIDIZER AND CORROSIVE LIQUID Section X. REFERENCES________________ ASTM No.: Chemical Abstracts No.: 007-697-372 CMA Chemical Safety Data Sheet No.: SD-5 NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) 411538 0093 For Internal Company Use Only - Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No.. CD Flammable 0 Combustible Toxic By: PRODUCT SODIUM HYDROXIDE 0 Corrosive O Explosive 13 Ingestion CD Water Reactive 0 Radioactive [3 Inhalation Phone No. O Oxidizer O Chemically Reactive O Absorption Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: Chemical Name & Formula: Other Designation: Corporate Stock No.: Manufacturer: SODIUM HYDROXIDE NaOH Caustic Soda, Soda Lye, -- Available from many suppliers - j- Section II. INGREDIENTS Typical content: Sodium Hydroxide (NaOH) Impurities: Sodium Carbonate (Na2C03) Sodium Chloride (NaCl) Sodium Sulfate (Na2S04) Potassium, Calcium and Magnesium Silicon Dioxide (Si02> Other Metals (total) Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp. Vapor Pressure: Flakes or pellets 1 atm2s3QF (1388C) 604F (3180 . mm Hg @ 1000 C -- 42 @ 1200 C --232 % 96 HAZARD DATA Ceiling Limit 2 mg/m-5 ... 0.5 -2.5 0.01-2.1 0.02-0.1 0.1 0.3 0.1 :':|p J Others: Volatiles ----------non volatile at room temp- erature Viscosity at 350 C, cps -- 4.0 Specific Gravity: Density: "Solubility In H2O' Color: Odor: (20/4 C) ------- 2.13 %, @ 0 C -- 29.6 %, @ 100 C -- 77.5 White or off-white, None hygroscopic solid Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. None - not combustible I N/A (Flammability Limits In Air N/A_______________ Lower I Upper N/A I N/A j i Although it is not combustible, it can be hazardous if present in a fire area. The following should be known for fire fighting: 1) It can melt and flow when heated (m.p.318 C 2) Hot or molten material can react violently with water (splattering). 3) Can react with certain metals, such as aluminum, to generate flammable hydrogen gas. (See also Reactivity Data, Section V). Fire fighters should wear full protective clothing. For fires involving NaOH, flood with water using care not to splatter or splash this material.________ ______ ___________ Section V. REACTIVITY DATA It is a stable material under normal conditions of storage. No self-polymerization. No. hazardous decomposition products. Slowly it can pick up moisture from the air and react with carbon dioxide from the air to form sodium carbonate- Sodium hydroxide can react violently with strong acids and with many organic chemicals, especially with nitrocarbons and chlorocarbons. (Will react with trichloroethylene to form spontaneously flammable dichloroacetylene.) It generates much heat when it dissolve in water. Avoid contact with leather and wooL and with aluminum, tin, zinc, and alloys which contain these metals. 411538 0094 Section V. HEALTH HAZARD INFORMATION TLV (Ceiling Value) 2 mg/ro3 Sodium hydroxide is a strong alkali and is dangerous when improperly handled. No. 7 It can be destructive to all human tissue it contacts, producing severe burns. Eye contact can produce severe or permanent injury. Dust or mist inhalation can injure the entire .--. respiratory tract. J FIRST AID: - Eye Contact: Wash eyes immediately with plenty of running water for at least 15 minutes, including under the eyelids and all surfaces. Speed in rinsing the eyes after contact is extremely important if permanent injury is to be avoided. Contact physician as soon as possible. Ingestion-Immediately dilute chemical by drinking large amounts of water or milk, then neutralize with dilute vinegar or fruit juice. Vomiting may occur spontameousiy, but do not induce it. Contact a physician promptly. Remove from exposure to mist or dust and Vget prompt medical help. Skin Contadt^Wash contact area promptly with large quantities of water. (Dilute acetic acid, vinegar, can be used to neutralize.) Remove contaminated cloth ing under the shower. Prolong washing in serious cases until medical help arrives-even for. an hour or longer. Physician should see all cases other than minor exposures to small . ,,-- v- areas of skin.;________________________________________________________________________________________________________ -- Section VII. SPILL, LEAK & DISPOSAL PROCEDURES_______________________ Contact Environmental Control personnel. When solid sodium hydroxide is spilled in a dry. / condition, it can be promptly shoveled up for recovery or disposal. (CAUTION! Avoid dusting. Avoid contact with the skin.) Control the disposal of the waste solid. (Delay in clean-up may allow absorption of moisture from the atmosphere and may increase the ] ' difficulties of clean-up.) Flush contaminated surfaces with water and neutralize with dilute acid, preferably acetic acid, to remove final traces. (Sodium bicarbonate may also be used to partially neutralize.) Finally, rinse with water. ` Disposal of waste is greatly dependent on local conditions and requirements. Pre-emergency plans should be' made to meet legal and technical requirements- Waste caustic should never be deliberately discharged directly into sewers or surface waters. (First, convert to neutral salts and dilute well with water.) REFER TO LOCAL SPCC PLAN. Section VUI. SPECIAL PROTECTION INFORMATION> Provide adequate ventilation to meet TLV requirements, especially where dusting or misting conditions can exist. For mist and dust protection use NIOSH approved respirators where the TLV is or may be exceeded. The selection of the appropriate respiratory pro tection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or potential concentration present. Use Chemical Safety Goggles! A plastic face shield can also be used. Use rubber gloves, rubber apron or protective clothing, rubber boots where needed to prevent contact with sodium hydroxide, especially when solutions are prepared. Safety showers shall be immediately available! Eye wash fountain shall be close enough to be reached within 5 seconds. Section X. SPECIAL PRECAUTIONS & COMMENTS________________________________ Workers should not be permitted to handle this material without proper training or to work with it without protective equipment. Store in well-sealed containers. Avoid handling conditions that may lead to spills and leaks, or to formation of mist or dust. Wherever this material is stored, unloaded, handled or used abundant water (preferably running water) should be available for emergency use. Drains for storage or use areas for this material should have retention basins for pH adjustment and dilution of spills and flushings before discharge. The pellet form is probably the safest solid form for handling and dispensing. 0.0.7". Requirements CORROSIVE SOLID Section X. REFERENCES ASTM No.: 0456 Chemical Abstracts No.: 001-310-732 CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) 411538 0095 For Internal Company Use Only - Not To Be Distributed Outside The Company iff^i ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No___ !______ O Flammable Cl Combustible Toxic By: PRODUCT SODIUM HYDROXIDE 0 Corrosive 0 Explosive 0 Ingestion 50% LIQUID 0 Water Reactive 0 Radioactive 0 Inhalation Phone No. 0 Oxidizer O Chemically Reactive O Absorption Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: SODIUM HYDROXIDE, 50% LIQUID Chemical Name & Formula: NaOH Other Designation: Corporate Stock No.:. Manufacturer: Liquid Caustic Soda, Lye Solution Available from many sources Section II. INGREDIENTS Sodium Hydroxide (NaOH) Typical Major Impurities: Carbonate (as Na2C03) .................... % >48.5 HAZARD DATA TLV 2 mg/n>3 (C) * d. 0.25 Chloride (as NaCl) Chlorate (as NaC103) Sulfate (as Na2S04> Silica (as SiO) : Water - *ACGIH recommends no exposure above this ceiling level (c). OSHA nas the same TLV but no ceiling C 1.15 ^.0.25 < 0.03 < 0.01 Balance NaOH Solution Rabbit, oral LDLo 500 mg/kg ; ' level at this time. Section IIL PHYSICAL DATA Physical Form: Boiling Temp.: Liquid 1 atm, ca 284F (140C) Others: Viscosity at 20 C, cps -- 50 Freeze-Melt Temp.: Vapor Pressure: Evaporation Rate: at 60 C -- ca 13 at 82 C -- ca 60 Specific Gravity: 15.6 C -- 1.53 Oensity: "Solubility In HjO": Complete Color: A clear liquid Odor: None Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. None - not combustible I [Flammability Limits In Air I | Lower [Upper II Use water spray to cool containers of this material which are involved in a fire situation to help prevent rupture. Sodium hydroxide will react with metals such as aluminum, tin, and zinc to generate flammable and explosive hydrogen gas. Fire fighters should wear full protective clothing. Section V. REACTIVITY DATA This material is stable under normal storage conditions in a sealed container. No polymerization will occur; there are not hazardous decomposition products. It will react with CC>2 in the air (when exposed) to form sodium carbonate. It will react violently with acids and with many organic chemicals, especially nitrocarbons, and halocarbons. (Trichloroethylene will react to form spontaneously flammable dichloroacetylene.) Avoid contact with leather and wool and with aluminum, tin, zinc, and alloys which contain these metals. 411538 0096 No.' 8 Section VI. HEALTH HAZARD INFORMATION TLV 2 mg/m3 (ceiling for NaOH) When improperly handled this strong alkali is dangerous. Tt is destructive of all human tissue it contacts, giving severe burns. Eye contact will produce severe or permanent injury. Inhalation of mist of spray can injure the entire respiratory tract. FIRST AID: '' Eve Contact: Wash eyes immediately with plenty of running water for 15 minutes, including under eyelids and all surfaces. Speed in rinsing out eyes is important if , permanent injury is to be avoided. Get medical help immediately. . Skin Contact; Promptly wash exposed area with lots of water, (Dilute acetic acid or vinegar can be used to neutralize.) Remove contaminated clothing under the shower. Prolong washing in serious cases until doctor arrives-even for an hour or longer. Get medical help for serious exposure. -.f , Ingestion: Immediately dilute by drinking water or milk and then neutralize with dilute0 vinegar or fruit juice. Contact physician promptly. Vomiting may occur spontaneously, but do not induce it. ; -------//- .Inhalation:.:_Remove from exposure to. mist-and. get prompt medical help.. .- " Section VIL SPILL, LEAK & DISPOSAL PROCEDURES -, - . - i Contact Environmental Control personnel. Plan ahead for handling spills. Personnel . working on clean-up must use protective clothing and equipment to prevent body contact with the liquid. Abundant running water should be available for emergency use- Pick up spill with vacuum equipment (alkali resistant) for disposal or flush to holding area with water. Neutralize residues with dilute acid and rinse with water. Disposal - Dispose of scrap in accordance with pre-emergency planning and local. State and Federal regulations. Waste caustic must never be discharged directly to sewers or surface waters. First convert to neutral salts and dilute well with water. Inform legal authorities of uncontrolled spills. - '' .. 7\. :""! REFER TO LOCAL SPCC PLAN. Section VIII. SPECIAL PROTECTION INFORMATION_________ _________________________________________ 1 Provide adequate general ventilation and exhaust ventilation to meet TLV requirements, especially where possibility of mist formation exists. Use NIOSH approved respirators where the TLV is or may be exceeded. The selection of the appropriate respiratory protection (self-contained breathing apparatus, supplied air respirator, etc.) will depend upon the actual or potential concentration present. Use chemical safety goggles for eye protection, and, in addition, use a face shield if splashing is probable. Use rubber gloves, apron or protective clothing, and rubber boots (tops covered by apron or clothing to prevent entrance of caustic). Eve wash fountains.shall be close enough to be reached within 5 seconds. Safety showers shall7 be immediately available! _________________ ~~[ Section IX. SPECIAL PRECAUTIONS & COMMENTS Do not permit workers to handle this material without proper training or without proper equipment. Store in well-sealed containers, which are protected from physical damage. Avoid handling conditions which can lead to spills or mist formation. Have abundant running water available where stored, unloaded or handled. Drains must have retention basis for pH adjustment and neutralization of spilled materials and flushings before discharge. D.O.T. Requirements CORROSIVE LIQUID Section X. REFERENCES ASTM No.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: No .3 7 3 Supplier Product Literature: 411538 0097 For Internal tympany Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. ALCOA CD Flammable 13 Corrosive CD Water Reactive CD Oxidizer CD Combustible Explosive CD Radioactive D Chemically Reactive Toxic By: El Ingestion El Inhalation O Absorption PRODUCT SULFURIC ACID, CONCENTRATED Phone No. Date: 1979- 12-21 Section I. MATERIAL DESCRIPTION Material Name: SULFURIC ACID, CONCENTRATED Chemical Name & Formula: h2so4 Other Designation: Corporate Stock No.: ' Oil of Vitriol, Hydrogen Sulfate, Manufacturer: . . Available from many suppliers Section II. INGREDIENTS Hydrogen Sulfate (H2SO4) % HAZARD DATA 93-98 TLV 1 mg/m3 for sulfuric Balance* acid ~: `Material is obtained by the reaction of SO3 and water. Can contain low impurity levels, such as 0.02% max of iron as Fe. Properties vary with H9SO4 content. Section III. PHYSICAL DATA 93.19% H2SO4 Physical Form: Liquid Boiling Temp.: 1 atm-----------------------------ca 538F (281C) Freeze-Melt Temp.: ---------------------------ca -29F (-34C) Vapor Pressure: mm Hg 0 100 F--------ca 1 Evaporation Rate: Specific Gravity: (60/60F)---------------1.8354 Densft?: BaUme-----------------------------------------------66 93.33% H2S0,, ca 640F (338C) ca 37F (3C) -- 1.84 100% H2SO4 ca 626F (330C) 50.7F (10.4C) -- 1.84 .. "Solubility In H2O": Completely miscible . Color: Clear, colorless, oily liquid Odor: None Volatiles% at 340 C----------------------------ca 100ca 100ca 100_________________________________________________________________________ Section IV. FIRE AND EXPLOSION DATA Flashpoint jNone-non-flammable I Auto-Ignition Temp. N/A f Flammability Limits In Air 1 I |N/A N/A N/A j Lower I Upper Even though sulfuric acid is non-flammable, it is hazardous when present in a fire area. Cool exterior of storage tanks of H2SO4 with water to avoid rupture if exposed to fire. Do not add water or other liquid to the acid! Use water to extinguish combustibles burning in the area. The acid, especially when diluted with water, can react with metals to liberate flammable hydrogen gas. Sulfuric acid mists and vapors from a fire area are corrosive. Respiratory protection is required when these are present, and also full protective clothing. (See also Reactivity Data, Section V.) Section V. REACTIVITY DATA Sulfuric acid is stable under normal conditions of use and storage. It does not undergo hazardous polymerization. It is a strong mineral acid reacting with bases and metals. The concentrated acid is a strong oxidizing agent and can cause ignition of combustible materials on contact. The concentrated acid is also a dehydrating agent, picking up moisture readily from the air or other materials. Much heat is generated when the concentrated acid is diluted in water. Acid should always be added slowly to water. Water added to acid can cause boiling and uncontrolled splashing of the acid. Sulfur oxides can result from decomposition and from oxidizing reactions of sulfuric acid. 411538 0098 Noli *9" Section VI. HEALTH HAZARD INFORMATION TLV > 1 mg/m3 Concentrated sulfuric acijd is a strong mineral acia,* an oxidizing agent-,* and a dehydrating agent that is rapidly damaging to all human tissue with which it comes in contact. Ingestion may cause severe injury or death. Eye contact gives severe or permanent injury. l; Inhalation of mists can damage both the upper respiratory tract and tiie lungs. FIRST AID- ' .. "W-.'i'. l-*-'' .y fl Ingestion: Dilute acid immediately with large amounts of milk or water, then give milk * of magnesia to neutralize. Do not induce vomiting; if it occurs spontaneously, continue to administer fluid. Obtain medical, attention as soon as possible:! Eye: Contact:. Immediately i flush eyes with plenty of running water for at least 15 minutes ^(including- .under the eyelids} Speed in diluting and rinsing out acid with water is extremely important if] permanent eye r . damage is to be avoided. Obtain medical help as scion as possible. Skin Contact: Immediately flush affected areas ivith water, removing contaminated clothing under the safety shower. t .. Continue washing with water and get medical attention ini all cases, except those involving'" minor damage to small areas of skin. Inhalation: Remove to fresh air. Call a physician immediately. " " Restore breathing. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Contact Environmental Control personnel. Prevent contact with the acid, t?inor leaks or spills can be diluted with plenty of water and neutralized with soda ash or lime. ,If water - is not available, cover contaminated area with sand, ashes, or gravel and neutralize .with-' soda ash or lime. 1 .r-.- < ^- Major spills must be handled by a predetermined plan. Contact supplierfor assistance ' A- in'this planning and to meet local requirements and for disposing of large amounts i.! REFER TO LOCAL SPCC PLAN. '.i* t. - i -'jt: Section VIII. SPECIAL PROTECTION INFORMATION jUse general ventilation to keep well below 1 mg/m3 yj'r V (TLV).Use NIOSH approved respirators''' where the TLV is or may be exceeded. The selection of the appropriate respiratory pro- . tection (self-contained breathing apparatus, supplied air respirator, etc.) will;,depend upon the actual or potential concentration present. . fV' v,v ' *5'". . ..* For eye protection use chemical safety goggles or face shield to avoid splashing>acid- into the eyes. Use rubber gloves, rubber apron, rubber clothing,, rubber suit, etc; to avoid contact of the acid with the body under use conditions. Eyel wash fountain shall be close enough to be reached within 5 seconds. Safety showers shall be ..readily available ir where this material is handled or stored. Areas ,of use or storage should have a neutralizing agent, such as soda ash, readily available for emergencies. -T f- Section IX. SPECIAL PRECAUTIONS & COMMENTS Dilute sulfuric acid is highly corrosive to most metals. Avoid breathing mist or vapors. ; Avoid contact with skin or eyes. Do not ingest.! Add aclS. slowly to wkter t-dilute.'^; . Do not add water to concentrated acid. Sulfuric acid receive^ in carboys or drums'should ` be stored in clean ventilated storage areas having acid resistant floors with gbod drainage. It should be stored away from reactive materials;, chlorides, nitrates'!'.?'carbides powders, oxidizables, cyanides, etc;- Sulfuric acid received in glass bottles should.be stored as mentioned above with additional precaution against breakage-. Soda, ash, .sand ' . or lime should be kept in same general area for emergency use. * 'li-; ' D.O.T. Requirements ... ^! CORROSIVE LIQUID . Section X. REFERENCES ASTMNo.: Chemical Abstracts No.: CMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: 007-664-939 SD-20 #325 Other: CHRIS (1979) AIA Bulletin. C-12 h AIHA Hygienic Guide 9-57 v } 411538 0099 For Internal Company Use Only - Not To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET ays HAZARD CHARACTERISTICS No._ io GJ Flammable CD Combustible Dl ALCOA CD Corrosive Explosive CD Water Reactive CD Radioactive Toxic By: ED Ingestion 0 Inhalation PRODUCT TOLUENE Phone No. CD Oxidizer O Chemically Reactive SO Absorption Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: TOLUENE Chemical Name & Formula: Methylbenzene, Cf^CgHs Other Designation: Corporate Stock No.: Toluol, Methylbenzol, ;- Manufacturer: Available from many suppliers >J Section II. INGREDIENTS Toluene-----------------------------------:--------- Current OSHA TLV level (1968 ACGXH TLV) **1977 ACGZH TLV level; (Skin) notation indicates a potential contribution to overall exposure via skin absorption. OSHA has proposed adoption of the more stringent ACGIH value, 100 ppm, with ceiling concentration of 200 ppm (measured over 15 minutes) HAZARD DATA TLV 200 ppm* . TLV 100 ppm (Skin) ... A Section 111. PHYSICAL DATA Physical Form: Liquid' c Boiling Temp.: Freeze-Melt Temp.: 1 atm -------- 231F (110.60) Vapor Pressure: @ 25 C -- 28 mm Hg Others: Volatiles, % -- 100 Molecular Weight -- 92.15 Evaporation Rate : (BuAc=l) -- 1.9 Specific Gravity: Density: (Water=l) -- 0.866 (Air=l) -- 3.2 "Solubility In HnO": % -- 0.05 (negligible) Color: Colorless water-like liquid v Odor: Characteristic aromatic odor, which is perceptible (unfatigued) at about 50 ppm. Section IV. Flashpoint 40F (4.4C) FIRE AND EXPLOSION DATA Closed Cup I Auto-Ignition Temp. } 1026F (552C)- | Flammability Limits In Air 1 % by volume I Lower 1 Upper | 1.27 | 7 Extinguishing media - carbon dioxide, dry chemical, foam. Fire fighters should wear self-contained breathing apparatus when fighting toluene fires. At room temperature, toluene emits vapors that may form explosive mixtures with air. Water may be ineffective in extinguishing fires but may be used to cool fire exposed containers. Vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Section V. REACTIVITY DATA Toluene is a stable material under normal storage and handling. It does not undergo hazardous polymerization. Since toluene is a flammable liquid, avoid contact with heat, sparks or open flames. Avoid contact with strong oxidizing agents. Nitric acid, especially in combinations with sulfuric acid, will form nitrocresols that can decompose violently upon further nitration. Oxidation in air can form oxides of carbon and nitrogen. 411538 0100 No 10 Section VI. HEALTH HAZARD INFORMATION | TLV (skin) 100 ppm or ^TS ag/m3 : The olfactory detection level for toluene is 50 ppm: Vapor inhalation' up to 100 ppm -may. . .. produce slight drowsiness and headache. Concentrations' of 100-200 ppm'may'cause fatigUe/ nausea, itching skin. Higher concentrations increase the degree of fatigue, incoor-. ' ' dination and nausea and can irritate the respiratory tract. Olfactory ^detection . V; : cannot be used for safety [since toluene will fatigue the senses. Skincontact will cause defatting; dermatitis may result from prolonged, repeated,;.contactl\j Some absorption . can occur through skin contact. Eye contact is irritating and can result in burns.; b; Ingestion may cause irritation to digestive tract, with gastrointestinal absorption of tbluei FIRST AID Inhalation: Remove victim to fresh air; get medical attention1 if victim is overcome'. Ingestion: Give water or milk (3 glasses) and induce vomiting. Repeat 2 times and get 301 nfedlcalAassistancSj 5S0 MTEA Eye Contact: Immediately irrigate with water for 15 minutes Get medical attention., S Skin Contact: Wash area with soap and water; remove and launder contaminated clothing before reuse. .Replace lost skin oils with medically approved lotions or cream. . Section VII. SPILL. LEAK & DISPOSAL PROCEDURES Report spills to Environmental Coordinator, remove .all ignition, sources and ventilate area. , Absorb spill on vermiculite or sand, scoop up with non-sparking tools and place in-metal covered container. Disposal by burning should be away from buildings and people. ' f ' Disposal of large amounts may be via licensed solvent disposal company. -- ~ REFER TO LOCAL SPCC PLAN. i- . . . * / .*Vi. him. . . :v. sm-. . .~v.- JttbSsSTE f'*'*' : :. ' _ > 'i1 . \\ kV;. ' Section VIII. SPECIAL PROTECTION INFORMATION Use in a well ventilated area. Exhaust hoods should have a minimum,; face., velocity. of . 100 lfm. Exhaust fans should all be non-sparking and explosion prpof. . Exhaust ventilation should be sufficient to reduce exposure concentratioiis/.below; the .TLV. Use NIOSH approved respirators where the TLV is or may be exceeded. The selection; of. the rappropriate respiratory protection (self-contained breathing apjpafntus .'.supplied] air respirator, etc.) will depend upon the actual or potential concentration present. , Safety glass or goggles; should be worn in areas of use.. Face shields 'and protective ' clothing are required where splashing can occur:' ] ' ' Eye wash fountain shall_.be close enough to be. reached within 5 seconds. 'r Section IX. SPECIAL PRECAUTIONS & COMMENTS Since toluene Vapors are over 3 times heavier than air, the vapors may "flow to lower areas, where ignition sources are uncontrolled. , Smoking, sparks and open flaines should not be allowed in areas of toluene use. Non-sparking tools should be. used. in toluene work areas. Metal containers for dispensing should be grounded and electrically inter connected with the receiving container. -<-,A Use safety cans for handling small amounts. D.O.T. Requirements FLAMMABLE LIQUID Section X. REFERENCES ASTM No.: D362 Chemical Abstracts No.: 000-108-883 CMA Chemical Safety Data Sheet No.: SD-63 NFPA Guides No.: NSC Data Sheets: Supplier Product Literature: Other: CHRIS (1974) 411538 0101 't . Not To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HAZARD CHARACTERISTICS No. 11 O Flammable O Combustible Toxic By: PRODUCT 1,1,1-TRICHLOROE- Corrosive 0 Explosive 0 Ingestion THANE Water Reactive 0 Radioactive 0 Oxidizer 0 Chemically Reactive 0 Inhalation 0 Absorption Phone No. Date: 1979-12-21 Section I. MATERIAL DESCRIPTION Material Name: - ., .. 1,1,1-TRICHLOROETHANE Chemical Name & Formula: CCI3CH3 Other Designation: . _ .. . Corporate Stock No.: Manufacturer: '.K Methyl Chloroform, .... 'PL-278 Chlorothene, aerothene -v - >.. ". -- BLACO-THANE (Baron-Blakeslee), CHLOROTHENE NU S NG (Dow), DOWLCENE WR (Dow), INHIBISOL (Penetone Corp.), TRI-ETHANE (PPG Ind., Inc.) . TRITHENE (SRS, INC.) Section II. INGREDIENTS 1,1,1-Trichloroethane* _ ............ '- :` -------HAZARD DATA TLV 350 ppm** Inhibitor Unknown . . . . - ------- ... : .. r -- High purity material is commercially available Human inhalation (DOWCLENE WR). Other commercial materials (Trade- iq minutes names, Sect. I) can contain up to 10% inhibitor and are designed for cold cleaning or vapor degreasing use or both (TRI-ETHANE). **NIQSH has proposed a 10-hr, TWA of 200 p; with a. 35Q gpm^cejj.Iiftg ccoonneceenntrtraattiiqoni (lg.m-----i--n-. sami ilxng time anc 3 recommended caution in us I TCLo 920 ppm for 70 minutes (central nervous system effects) Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Freeze-Melt Temp.: Vapor Pressure: Liquid 1 atm, ca 165F (74C) -38F(--39C) at 20 C, mm Hg -- 100 Others; Vapor Density (Air=l) -- 4.55 Volatiles, % -- ca 100 Molecular Weight -- 133.41 Evaporation Rate: (CC14=1) 1 Specific Gravity: 25/25C - 1.30-1.336* Properties depend on the inhibitor and Density: inhibitor level. "Solubility In H20": g/100g H2O -- 0.07g Color: Colorless liquid Odor: Mild, ether-like odor which may be just perceptible (unfatigued) at about ____________________________100 ppm in air__________________________________________________________________________________ Section IV. FIRE AND EXPLOSION DATA Flashpoint I Auto-Ignition Temp. I Flammability Limits In Air I______ _.________ ((High energy ignition source None_________________________________1 932F (500C)_______________1 at 25C) Vol. %________________________ Lower I Upper 8.0% 1 10.5% This material is nearly nonflammable. High energy, such as electric arc, is needed for ignition, and the flame tends to go out when the ignition source is removed. Water spray or fog may be used to fight fires and keep fire exposed containers cool. Use self-contained breathing apparatus for protection against suffocating vapors and toxic and corrosive decomposition products. Section V. R EACTIVITY DATA This material can be hydrolyzed by water to form hydrochloric acid and acetic acid. It wil react/with strong caustic, such as caustic soda or caustic potash to form flammable or explosive material. It requires inhibitor content to prevent corrosion of metals; and when inhibitor is depleted, it can decompose rapidly by reaction with finely divided white metals, such as aluminum, magnesium, zinc, etc. Do not use these metals for fabrications of storage containers for 1,1,1-trichloroethane. It will decompose at high temperature or under Ultra-violet radiation to produce toxic and corrosive materials (phosgene and hydrogen chloride). 411538 0102 No. 11 Section VI HEALTH HAZARD INFORMATION |TLV 350 ppm or 1900 rog/roJ Brief exposure at 800-1000 ppm causes mild eye irritation and a little ;lpssJ of coordination due to the anesthetic properties of 1,1,1-trichloroethane. Skin contact'can cause: defatting and, when prolonged or repeated, can produce irritation and dermatitis. It can absorb' through the skin. Eye contact can result in pain and irritation; This materialis;^ considered low in toxicity among the chlorinated hydrocarbons. * ' ; . . FIRST AID : ; : ' I", Eye Contact: Flush eyes well with plenty of running water for 15<,minutes. . Skin Contact; Remove solvent wet clothing promptly, Wash contact airea with warm water and soap. Get medical attention for irritation. .** Inhalation; Remove to fresh air. If needed, apply artificial respiration. Get medical; ' assistance immediately.f_ (NoteI. Advise physician not) to use adrenalin* Ingestion; Get medicsfi "aSSistianc^A^ (If a physician hot immediately available and the ' ^1^'- aa.,a fa . . 1 1 A. .A^ n *1.ft.t --.V.1 A ..A 1 1-- ...A Afa a.. fa . a^. 1A a mi 1 ">4 *a JSL... a ' * fa a^a . - " Section VII. SPILL, LEAK & DISPOSAL PROCEDURES F'or small spills, mop, wipe, or soak up with absorbent material using rubber: gloves'; ^ t:"r. - ^Evaporate' outdoors or in an exhaust hood. For large spills, inform Environmental personnel Cand evacuate area.;!:Use protective equipment during; clean-up. (See Sect;' Vlil) Ventilate ?'ni- jarea. Contain, liquid:' pick up and place in closed metal containers. Do not aliqv' to.s 'enter water supply sources; -V--,-; ?' z,1' ..-:.a=??' DISPOSAI.: Dispose of via Ja'licensed waste solvent disposal company, or reclaim by ! * H i, filtration and distillation procedures. v ;t` ':-'!;I -73` - ?d^asaj!S5f .-Vi-vj.Sj, t -ttr.S'v.; -. ..**, .. .v ...v:a.y-r. - ---.fs.: .. -ssrrrr * J'XS; .= . * ,-'i- - Section VIII. SPECIAL PROTECTION INFORMATION Provide general and exhaust ventilation to meet TLV requirements. Use NIOSH approved; >. respirators where the TLV is or may be exceeded. The selection of the appropriate *j respiratory protection (self-contaj.ned breathing apparatus, supplied air respirator, , r etc.) will depend upon the actual or potential concentration present. Gloves and' apron> (of neoprene, polyethylene or polyvinyl alcohol) should be worn when needed to avoid . . skin contact. Remove solvent wet clothing promptly. A safety shower should be available to use area. Chemical goggles or a face shield should be worn if splashing is possible. An eye wash fountain shall be close enough-to be reached within 5 seconds . j, . - Section IX. SPECIAL PRECAUTIONS & COMMENTS VV : Store in closed containers in a cool, well-ventilated area. Keep water-free. Monitor inhibitor level for vapor degreasing use. Use: caution in cleaning operations involving white metal fines (see Sect. V). Trichloroethylene contamination^ when aluminum is degreased. Provide regular medical monitoringof those exposed to: this material in the workplace. Preclude those with CNS, liver, or heart disease from ` exposure. Personnel using this solvent should avoid drinking alcohblicbeverages shortly before, during, or soon after exposure. Exposure of pregnant female rats to high levels of 1,1,1-trichloroethane may have caused birth defects in offspring.!. D.O.T. Requirements il ! ' , . Section X. REFERENCES ASTM No.: Chemical Abstracts No.: GMA Chemical Safety Data Sheet No.: NFPA Guides No.: NSC Data Sbeets:No4 56A Supplier Product Literature: 000-071-556 SD-90 Other: CHRIS (1974) v.' - ) 411538 0.103 '