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TOXICITY TO AQUATIC PLANTS TEST SUBSTANCE Identity:A mixturecontainingperfluorooctanesuftnatew,hich may alsobe referredtoas PFOS, FC-95, oras a component ofFX-3104. (1Octanesulfoniaccid)(CAS # 2795-39-3). Remarks: The 3M productionlotnumber was notnoted.The testsample isFX-3104, 6%. Currentinformatioinndicatesitisa mixtureof0.48% PFOS, 14.09% diethyleneglycolbutylether,59% water,17.6% ethyleneglycol, 1.44% sodium octylsulfate4,% inhibito2r.,0% polyoxyethylene monooctylphenylether,1.25% propane sultonefoanier,0.03% sodium lauryl sulfatea,nd 0.1% benzotdazole. The following summary applies to a mixture with incompletely charactedzect concentrations of impurities.Data may not accurately reflectthe toxicityof the tluorochemical component of the testsample. METHOD: Method: Not given. Type: Acute static GLP: No Year study performed: 1985 Species: Selenastrumcapricomutum Source: Not given. Element basis: AJgalcellcounts(cells/mL). Exposure period:96 hours StatisticaMlethods: lCw valuescalculateudsingprobiatnalysisorother regressionmodels. Analyticalmonitoring: Not given. Test Conditions: AlgalNutrientMedium: Not given. Stock and testsolutionprepamtion: Not given. Exposure vessels: Not given. Agitation:Not given. Number of replicates:2 Initiaclellloading:2.05x 104 cells/mL Number of concentrations:fiveplusa blankcontrol Lighting:Not given. Water Chemistry: Not given. RESULTS Nominal concentrations: Blank control,100, 180,320, 560, and 1000 mg/L AlgalGrowthResponse NominalConc. (mg/L) Control 100 180 320 1 560 1 1 1000 1 Mean Coll-Count (colls/mL) 1,790,000 1,730,000 1,620,000 1,160,000 980,000 210,000 Element values: 96-hour IC50= 576 mg/L PercentInhibition -- 3 9 35 45 88 7:1 Element valuesare based on nominal concentrations. Reversibilityof Growth Inhibition:Not given. Remarks: Testingwas conducted on a mixtureas describedinthe Test Substance Remarks field.The valuesreportedapplytothatmixtureand not the fluorochemicalproportionalone. CONCLUSIONS The testsubstance exhibitsa 96-hourIC5oof576 mg/L. Submitter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133 DATA QUALITY ReliabilityK:limischranking3. Study lacksdescriptionand recordsofthe method followed.There isno characterizabonofthetestsubstance purity, and the studylacksconfirmationoftheamount offluorochemicalproportionin the solution. REFERENCES Thisstudywas conducted by the3M Company, EnvironmentalLaboratory, St.Paul,MN, Lab Request number Cl 111-2,1985. OTHER Last changed: 6/26/00. ENVIRONMENTAL LABORATORY LR FRESHWATER ALGAE GROWTH INHIBITION TEST ALGAL CELL COUNT, no./mi HEMOCYTOMETER METHOD* TEST* DAY. TEST TYPE DATE MATERIAL TESTED: 1,5@cl-Ir ALGAL SPECIES'! Qreen Algae. Selenastrum capricarnutum ANI@LYST TREATMENT TOTAL OF 25 FIELDS COUNTED BC lis no./ml MEAN + SD eCO IOC)(D I1-15clio0c) -37,C 1-3 2--17D -4 (cc) i!sIt-j Ioc" Z-0 Lo;?,IoCoo I ISO,()C)o I I@0c) coo QUO)OCO. I OCC)10C)o ac) @'iot C)O 0 0.1 mm deep Hemocytometer; area of field 1 x 1 and 0.1 mm deep. ci ENVIRONMENTAL LABORATORY TABLE 1. PUMMA OF ACUTE TOXICITY 0F ItX- 4U I:y 4 _VCP TO FRESHIQATER ALGAE (SELENASTRUM CAPRICORNUTUM) Chemical Concentration (mg/1) Control Percent Inhibition in Standing Crop (2) 48-Hr. Based on Cell-Count Based on Cell-Count 96-Hr. Based on Cell Dry Wt. E38 ic (95% Confidence 50 Limits) mg/l (3) Acceptability of Test The Selenastrum capricornutum following quality criteria: control cultures have met the - Exhibited log phase growth within _qjp@7 hours (max. 48 hr.) - Attained a 96-hr. standing crop of l,t7qxl cells/ml 5 (min. 10 cells/ml) Loci "Dkase @qmwNR%,-&4 4?)- @x@. 4-4,S)OC)o (1) Data were averages concentration. of two replications for each test (2) Based on cell-count (no./mi) and/or cell-dry weight (mg/1). (3) IC50 values were calculated using Probit Analysis regression models of experimental data. or other