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MATERIAL SAFETY DATA SHEET NALCQ PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical {70S) 920-1 510 (24 hours) g SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: TRI-ACT 1800 INHIBITOR DESCRIPTION: An aqueous solution of amines NFPA 704M/HMIS RATING: 3/3 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3=High 4=Extreme 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Cyclohexylamine Ethanolamine Methoxypropylamine 108-91-8 141-43-5 5332-73-0 10-20 10-20 10-20 SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes burns to skin and eyes. Combustible. Do not get in eyes, on skin, or on clothing. Wear goggles and face shield and rubber gloves when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * * * * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician at once. Remove to fresh air. Treat symptoms. Call a physician at once. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. SAL 000009735 PAGE 1 OF 9 IMALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 700-305- 1 OOO NGS82 NALCO MATERIAL SAFETY DATA SHEET PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (70S) 920-1510 (24 hours) SECTION 4 FIRST AID INFORMATION ( CONTINUED ) CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Corrosive to the skin, possibly resulting in third degree burns depending on the length of exposure and on the first aid action given. Can cause allergic contact dermatitis in susceptible individuals. Can be harmful or fatal. Can be corrosive to the mucous membranes and the lungs. Can cause an allergic reaction in susceptible individuals. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have been conducted on this product along with acute toxicity studies on the hazardous ingredient(s) in Section 2. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LD50 = 1267 mg/kg 95% Confidence Limit = 1,047 to 1,532 mg/kg COMMENTS: Excessive salivation, squinting of the eyes, loss of muscular coordination, prostration and irregular breathing were observed. ACUTE DERMAL TOXICITY (ALBINO RABBITS): LDS0 - Greater than 2,000 mg/kg PAGE 2 OF 9 sM_ 000009736 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1196 MATERIAL SAFETY DATA SHEE NALCO PRODUCT tri-act isoo inhibitor Emergency Telephone Number Medical (708) 920-1 510(24 hours) g SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED ) COMMENTS: Redness, swelling, and blanching of the skin were noted. Scab formation was due to the corrosive action of the product. However, no systemic signs of toxicity were observed. SKIN SENSITIZATION: Cyclohexylamine can cause sensitization in susceptible individuals. PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: Corrosive COMMENTS: Severe redness, swelling, and blistering of the conjunctiva were observed. Opacification of the cornea was also noted. Due to the extreme corrosive action of the test material, no Draize index rating could be assigned. OTHER TOXICITY RESULTS: Cyclohexylamine. A battery of tests including the * Ames test, sister chromatid exchange, cell transformation, mouse lymphoma and * rat hepatocyte/DNA repair provided inconclusive evidence of mutagenic activity.* SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: FREEZE POINT: FLASH POINT: FORM: Liquid 8.2 lbs/gal. Completely 0.99 @ 77 Degrees F 12.6 pH (at 1%) 11.2 5 cps 77 Degrees F 8 Degrees F 135 Degrees F (PMCC) ODOR:: Amine ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 135 Degrees F (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. PAGE 3 OF 9 sal 000009737 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AC5EA 706-305-1 COO MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510(24 hours) SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: N-nitrosamines, many are cancer causing agents to laboratory * animals, may be formed when certain amines are mixed with nitrous acid, organic* or inorganic nitrites or atmospheres with high nitrous oxide concentrations. * Avoid contact with strong acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) which can generate heat, splattering or boiling and the release of toxic fumes. * * * THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C02, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. * SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors or mists may be released. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles. A full slicker suit is recommended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into PAGE 4 OF 9 SAL 000009738 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 709-30E;- ' ODO MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510 {24 hours) S 5 82 SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. For large indoor spills, evacuate employees and ventilate area. responsible for control and recovery should wear the protective equipment specified in Section 10. Those DISPOSAL: if this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001 & D002. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTAT ION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O.S. CORROSIVE MATERIAL UN 1760 CONTAINS - CYCLOHEXYLAMINE * * * SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: * * OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Cyclohexylamine - Corrosive, combustible Ethanolamine - Corrosive, combustible Methoxypropylamine - Corrosive, combustible Cyclohexylamine = TWA 10 ppm, 41 mg/m3 ACGIH/TLV Ethanolamine = TWA 3 ppm, STEL 6 ppm ACGIH/TLV 7.5 mg/m3 15 mg/m3 ACGIH/TLV PAGE 5 OF 9 SAL OOOOO9739 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 GS582 MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (70S) 920-1510(24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Cyclohexylamine = TWA 10 ppm, 40 mg/ra5 0SHA/PEL Ethanolamine = TWA 3 ppm, STEL 6 ppm OSHA/PEL 8 mg/m3 15 mg/m3 OSHA/PEL Methoxypropylamine = TWA 10 ppm, 20 ppm (15 minute exposure) AIHA/WEEL CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product contains cyclohexylamine, which is listed in Appendix A and B as an Extremely Hazardous Substance. The statuatory threshold planning quantity for this substance is 10,000 pounds. A release of 10 pounds of product will require a notification to your State Emergency Response Commission. You may also be required to notify the NATIONAL RESPONSE CENTER - See CERCLA/SUPERFUND, above. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local * emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: * - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. * * * SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): PAGE 6 OF 9 SAL 000009740 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1100 A<=>= 70? 3CP-" OOn MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510 (24 hour*) GS5 82 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) This product does not contain ingredients (at a level of 1% or greater) on the * List of Toxic Chemicals. # TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). * RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). * * * FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. * * CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: * * Ethanolamine - Section 111 Cyclohexylamine - Section 111 * * STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. CALIFORNIA AIR TOXIC 'HOT SPOTS' INFORMATION AND ASSESSMENT ACT OF 1987 (CALIFORNIA STATUTE AB2588): This product does not contain ingredients listed on either Appendix A-I or A-II of the Air Toxic Information and Assessment Act. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Cyclohexylamine Ethanolamine Methoxypropylamine Water 108-91-8 141-43-5 5332-73-0 7732-18-5 PAGE 7 OF 9 SAL 000009741 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 A=PEA 7OF -305- 1 300 MATERIAL SAFETY DATA SHEET IMALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J.( Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds,, John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE PAGE 8 OF 9 SAL 000009742 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B MATERIAL SAFETY DATA SHEET NALCO PRODUCT tri-act isoo inhibitor Emergency Telephone Number Medical (706) 920-1510 (24 hour*) GS582 SECTION 17 BIBLIOGRAPHY ( CONTINUED > WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA`s Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 07/03/90 DATE PRINTED: 07/14/90 PAGE 9 OP 9 SAL 000D09743 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 AREA 700-305-1 OOO w NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (708) 920-1510 (24 hours) $41 00009744 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1108 V* NALCO MATERIAL SAFETY DATA SHEET PRODUCT SOLUTION S0260 SPECIAL INDICA' Emergency Telephone Number Medical (708) 920-1510(24 hours) M G S 6 05 SECTION I PRODUCT IDENTIFICATION TRADE NAME: SOLUTION S0260 SPECIAL INDICAT DESCRIPTION: Special indicator, (M) indicator - brom cresol green and methyl red dissolved in isopropanol * * NFPA 704M/HMIS RATING: 1/1 HEALTH 3/3 FLAMMABILITY 0/0 REACTIVITY 0lnsignificant lSlight 2-Moderate 3=High 4=Extrerae 0 OTHER* * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Isopropanol 67-63-0 SECTION 3 PRECAUTIONARY LABEL INFORMATION 99+ WARNING: FLAMMABLE. Keep away from heat, sparks and flame. May cause irritation to skin and eyes. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Do not take internally. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * * * * * * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: Flush with water for 15 minutes. Call a physician. Flush with water for 15 minutes. Do not induce vomiting. Give water. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation SAL 000009745 PAGE 1 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1193 AKEa 70B-305-1000 GS605 NALCO MATERIAL SAFETY DATA SHEET PRODUCT SOLUTION S0260 SPECIAL INDICA4 Emergency Telephone Number Medical (708) 920-1510 (24 hour*) SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) EYE CONTACT: SKIN CONTACT: INHALATION: Can cause moderate irritation. Can cause moderate irritation. Prolonged inhalation of mist or vapor may cause nausea, dizziness, light-headedness, vomiting or unconsciousness depending on the length of exposure and the first aid action given. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but toxicity studies of the ingredient(s) in Section 2 have been reviewed. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LDS0 = 5,000 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): LD,0 = 13 gm/kg ACUTE INHALATION TOXICITY (ALBINO RATS): LCS0 * 16,000 ppm (8-hours) SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear amber to orange FORM: Liquid SOLUBILITY IN WATER: Completely SPECIFIC GRAVITY: 0.79 60 Degrees F BOILING POINT: 160 Degrees F 8 760 mm Hg FLASH POINT: 56 Degrees F (TCC) PERCENT VOLATILE BY WEIGHT: Greater than 99% ODOR: Isopropanol ASTM D-1298 ASTM D-86 ASTM D-56 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 56 Degrees F (TCC) ASTM D-56 AUTOIGNITION TEMPERATURE: 360 Degrees F (ASTM D2155-66) UEL 12.0% LEL 2.0% SA 000009-r PAGE 2 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS BD5B3-119S MATERIAL SAFETY DATA SHEE1 NALCO PRODUCT solution S0260 special ihdica1 Emergency Telephone Number Medical (708) 920-1510 (24 hour*) 605 SECTION 8 FIRE AND EXPLOSION INFORMATION { CONTINUED ) EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: Not applicable SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides,* chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which* can generate heat, fires, explosions and the release of toxic fumes. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent organic vapor cartridge respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. * * * * * * PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. * * * * a SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) * SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Keep the spill away from heat, sparks, flames and welding operations. Ventilate area and evacuate employees from exposure if the airborne * * * * PAGE 3 OF 7 SAL 000009747 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B AO = A 708-305-i OCT G S605 N ALGO MATERIAL SAFETY DATA SHEET PRODUCT SOLUTION S0260 SPECIAL INDICA Emergency Telephone Number Medical (708) 920-1510 (24 hour#) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) concentration exceeds the TLV. Refer to Section 14. DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified before disposal in a landfill (Hazardous Waste Treatment, Storage and Disposal facility). Can be incinerated in accordance with local, state and federal regulations. Empty product containers should be punctured, if plastic, and placed in the garbage collection container. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - ISOPROPANOL FLAMMABLE LIQUID UN 1219 * SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Isopropanol - Flammable Isopropanol = TWA 400 ppm, STEL 500 ppm ACGIH/TLV 985 mg/mJ, 1230 mg/mJ ACGIH/TLV Isopropanol =* TWA 400 ppm, STEL 500 ppm OSHA/PEL 980 mg/m3, 1225 mg/m3 OSHA/PEL CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: PAGE 4 OF 7 sfrt 000009-* NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 19B ARE* 700-305- ` Of" MATERIAL SAFETY DATA SHEET NALCO PRODUCT SOLUTION S0260 SPECIAL INDICA' GS 605Emergency Telephone Number Medical (708) 920-1510 (24 hours) _ SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Isopropanol - Section 111 PAGE 5 OF 7 SAL 000009749 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60583-1190 AREA 708-3D5-1DDD *6 S 6 05 NALCO MATERIAL SAFETY DATA SHEET PRODUCT SOLUTION S0260 SPECIAL INDIC* Emergency Telephone Number Medical (706)920-1510(24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: Regulated in those states using the TLV for isopropanol as a criteria for listing. SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H.f and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. PAGE 6 OF 7 ^ oOOOO9750 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 198 NALCO MATERIAL SAFETY DATA SHEET PRODUCT SOLUTION S0260 SPECIAL INDICA' Emergency Telephone Number Medical (708) 920-1510(24 hours) 6 Q 5 SECTION 17 BIBLIOGRAPHY { CONTINUED ) IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D,, Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 07/11/90 DATE PRINTED: 08/11/90 PAGE 7 OF 7 SA1" 0000975i NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-119B APFi 709-305-1000 MALCO MATERIAL SAFETY DATA SHEET Emergency Telephone Number Medical (708) 920-1510 (24 hours) SAL 000009752 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 (CONTINUED) tt./W UU J IK LUKt SECTION IX - SPECIAL PROTECTION INFDRMAT1DPAGE : 05 PROTECTIVE GLOVES * RUBBER GlOVEi SHOULD BE WORN BY SENSITIVE INDIVIDUAL DEPENDING ON SEVERITY OF EXPOSURE. EYE PROTECTION SAFETY GOOGLES SHOULD BE WORN DEPENDING ON SEVERITY OF EXPOSURE. OTHER PROTECTION CLEAN, PROTECTIVE CLOTHING SHOULD BE WORN. GS606 SECTION X - STORAGE AND HANCLlNG INFORMATION STORAGE TEMPERATURE 1 INDOOF ioof<*-max30f<--min;x IHEATEC ; PRECAUTIONS TO BE TAKEN IN HANO LING 6 STORING AVOID CONTACT WITH EYES. SKIN ANO CLOTHING. OTHER PRECAUTIONS WASH THOROUGHLY AFTER HANDLING. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH EYES. SKIN AND CLOTHING |REFRJGERATED| OUTDOOR |x , SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S NUMBER UPPER % LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHOR 12ATI ON ACT OF 1986 ANC 40 CFR PART 372. IF UE (USE EXEMPTION* APPEARS UNDER UPPER % LIMIT. ENC USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED ANC LABELED FOR ROUTINE JANITORIAL WORK. DR THE PRODUCT IS USED ANO LABELED PCR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION - (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--IMCO <--TARIFF 6 D <--IATA <--MlLITARY AIR (AFR 71-4) (CONTINUED) M/M QUICK CURE SECTION XII - TRANSPORTATION * (FOR FUTURE USE) PAGE : 06 SHIPPING NAME HA2ASD CLASS | ID NUMBER ! REPORT QTY LABELS ! LIMITED QTY UNIT CONTAINER DOT SPS CONTAINER { NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) SECTION XIII REFERENCES 1 . OANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION. N. IRVING SAX. 2. THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE 3 . WORK ENVIRONMENT. 2ND EDITION. ACGIH, 1985. VENDOR'S MSOS INGREDIENT PERCENTAGE IS A TRADE SECRET; MASS TRADE SECRET NUMBER 99-127-002 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSED OK IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TC BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEAftCH 01V. OF NCH CORK ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSEC EV THE USE . STORAGE CR DISPOSAL OF THE PRODUCT IK A MANNER NCT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE, OR DISPOSAL OF THE PRODUCT SAL 000009753 MATERIAL SAFETY DATA SHEET M/M QUICK CURE (006339-0157P -0021638-5974 ) iDATE OF ISSUE 12/13/89 6 S 6 06RAGE : 01 SUPERSEDES 11/ 1 1/B7 I SECTION 1 - GENERAL INFORMATION CHEMICAL NAME 5 SYNONYMS N/A TRADE NAME 8 SYNONYMS M/M QUICK CURE CHEMICAL FAMILY E PCX V STICK FORMULA X<--MIXTURE MANUFACTURERS nameNATICNAL CHEMSEARwH DIV. OF NCH COR9 ADDRESS (NUMBER. STREET. CITY, STATE 8 ZIP CODE ! BOX 1 E2170 IRVINS, TEXAS 75015 PREPARED BY CHANDA 6. HILL/T.S. CHEF ! PRODUCT CODE NUMBER ! EMERGENCY TELEPHONE NUMBER SS74 2 14-438*1381 SECTION II- HAZARDOUS INGREDIENTS THE HA2AR0S PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) { HAZARD BASE: DIGLYCIDIAL ETHER OF BIS IRRITANT PHENCL A 2.4.6 TRI(DIMETHYLAMINO METHYL PHENOL) * IRRITANT \ TLV5 MG/M3 2. J PEL* N/A -PPM 3. NOT EST | CASA 25085-99-8 90-72-2 SECTION 11A - NON-HAZARDCUS INGREDIENTS NCN-HAZAROOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NJ TRADE (CONTINUED) SECRET REGISTRY * M/M QUICK CURE SECTION Hi - NON-HA2AROOUS INGREDIENTS 409363-5O43P SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) VAPCR PRESSURE (MM HG). VAPOR DENSITY (AIR-1) PH 10014 PERCENT. VOLATILE BY VOLUME (fc) SOLUBILITY IN WATER VISCOSITY `B : >250 F ! SPEC GRAVITY (H20- 1 ) >1 ! n/a ; COLOR A : LT.GRAY B: DRK GRAY {> i ; ODOR MERCAPTAN LIKE |n/a { CLARITY OPAQUE |NIL 1 | NEG. | EVAPORATION RATE <8U AC - 1 > |N/A j PUTTY PAGE : 02 SECTION IV - FIRE ANO EXPLOSION HAZARD FLASH POINT (METHOD USED) A:>2S0 FCLOSED CUP } FLAMMABLE LIMITS ] ! LEL [N/A ! UEL JN/a EXTINGUISHING MEDIA 'ALCOHOL* X<--FOAM X<--FOAM X<--C02 DRY X<--CHEMICAL WATER <--SPRAY <--OTHER SPECIAL FIRE FIGHTING PROCEDURES WEAR MOSH/MSHA APPROVED RESPIRATOR WHEN FIGHTING FIRES IN CONFINED AREAS TC PROTECT FRAOM ACRID SMCKE. FUMES AND HAZARDOUS DECOMPOSITION PRODUCTS. UNUSUAL FIRE 6 EXPLOSION HAZARDS NONE KNOWN NFPA HAZARD RATING (O-I NS 1 SNIP I CANT;1-SLIGHT;2-M00ERATE:3-HIGH:4-EXTREME): 2 <--HEALTH 1 c--FLAMMABILITY O <--REAtTIVJTY <--SPECIAL SECTION V - HEALTH HAZARD DATA SAL 000009754 GS606 (CONTINUED) SECTION V M/M QUICK CURE HEALTH HA2ARD DATA PAGE : 03 THRESHOLD LIMIT VALUE : MOT ESTABLISHED FOR KIXUTRE SEE SECTION II EFFECTS OF OVEREXPOSURE * - ACUTE - (SHORT TERM EXPOSURE) PROLONGED OR REPEATED EXPOSURE MAV CAUSE SKIN SENSITI2AT ION - IN SENSITIVE INDIVIDUALS CONTACT MAV CAUSE SKIN IRRITATION. THIS PRODUCT IS BOTH MECHANICALLY IRRITATING AND CHEMICALLY IRRITATING TO THE EYES. INHALATION IS NOT A HAZARD IN NORMAL USE HOWEVER THIS PROOUCT GIVES OFF TOXIC FUMES WHEN BURNED OR WELDED. INGESTION MAV LEAD TO GASTRIC IRRITATION WITH NAUSEA AND VOMITING. - CHRONIC - (LONG TERM EXPOSURE) PROLONGED SKIN CONTACT CAN CAUSE SENSITIZATION. PRIMARY ROUTE OF ENTRY INHALATION INGESTION <-- ABSORPTION EMERGENCY & FIRST AID PROCEDURES INHALATION . GENERALLY NCT A HAZARD. MOVE TO FRESH AIR AND TREAT SYMPTOMATICALLY. GIVE CXYGEN IF BREATHING IS DIFFICULT AND ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. GET MEDICAL ATTENTION. EYE CONTACT. FLUSH WITH WATER FOR 10 MINUTES. LIFTING UPPER AND LOWER LIDS OCCASONALLY. GET MEDICAL IRRITATION IF IRRITATION PERSISTS. TREATMENT IS MOST EFFECTIVE WITHIN ONE MINUTE. SKIN CONTACT WASH WITH SOAP AND WATER. SENSITIVE INDIVIDUALS SHOULD APPLY AN EMOLLIENT RICH CREAM AND SHOULD SEE A PHYSICIAN IF IRRITATION PERSISTS- INGESTION : DO NOT INDUCE VOMITING. GIVE ONE OR TWO GLASSES OF WATER AND CALL PHYSICIAN ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. NOTES TO PHYSICIAN ; GASTRIC LAVAGE IN INDICATED. DO NOT INDUCE VOMITING. SECTION VI TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN 8Y I ARC <- - YE S X< - -NO <--YES X<--NO <- - YE S X<--NC < --YES OTHER < * - YES X <--NO X< --NO 2.4.6 TRKOIMETHYLAMINO METHYL CRL-RAT LD50: 2.5 G/KG SKN-RBT L050: 1.2G/KG DIGLYCDIAL ETHER OF BISPHENOL SKN-RBT 500 MG OPEN MILD 1. PHENOL) SKN-RAT SKN-RBT EVE-RBT LD50: 1280 MG/ KG BOOMG/24H SEVERE 500MG/24H/SEVERE 1. 1. 1. (CONTINUED) M/M QUICK CURE SECTION VI - TOXICITY INFORMATION EYE-set 2 MG/24 H SEVERE 1. ORL-RAT 1050: 11 G/KG 1 . SECTION VII - REACTIVITY DATA PAGE : 04 STABILITY j X<--STABLE <--UNSTABL | CONOIDTIONS TO AVOID 'open flames, long-term exposure to high temperatures. INCOMPATIBILITY (MATERIALS TO AVOIO) STRONG OXIDIZING AGENTS OR STRONG BASES OR MINERAL ACIDS HAZARDOUS DECOMPOSITION PRODUCTS OXIDES OF CARBON. NITROGEN. AMMONIA AND ACRID SMOKE AND FUMES. HAZARDOUS WILL NOT X <--OCCUfi POLYMERIZATION N/A MAY ! CONDITIONS TO AVOID -OCCUR ! SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED DUE TC THE NATURE OF THE PACKAGING OF THIS PRODUCT A SPILL IS UNLIKELY. WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH FEDERAL. STATE AND LOCAL POLLUTION REGULATIONS. NEUTRALIZING AGENT N/A SECTION IX - SPECIAL PROTECTION INFORMATION REOUIRED VENTILATION LOCAL EXHAUST RECOMMENDED TO CONTROL VAPOR LEVELS IF BURNNED OR WELDED GENERAL EXHAUST IS MORE THAN AOEOUATE TO PROTECT WORKER FROM EXPOSURE TO LEVELS ABOVE PERMISSIBLE EXPOSURE LIMITS. RESPIRATORY PROTECTION WEAR NIOSH APPROVED RESPIRATOR TO PROVIDE ADEOUATE VENTILATION WHEN BURNING. WELDING OR MACHINING(GRINDING) . SAL 000009755 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALC0 5270 PROCESS ANTIFOULANT Emergency Telephone Number Medical {708) 920-1510 (24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5270 PROCESS ANTIFOULANT DESCRIPTION: A blend of an amine salt of alkyl phosphates in a hydrocarbon solvent NFPA 704M/HMIS RATING: 2/2 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3-High 4Extreroe 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous. One or more is being claimed as a trade secret under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Heavy aromatic naphtha Naphthalene Ethylbenzene Xylene Amine alkyl phosphate salts 68603-08-7 91-20-3 100-41-4 1330-20-7 Proprietary 10-20 1-5 1-5 1-5 70-100 SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes irritation to skin and eyes. Combustible. Prolonged inhalation of vapor may be harmful. Do not get in eyes, on skin or on clothing. Wear goggles or face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the PAGE 1 OF 9 SAL 000009756 EB&d NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 19S MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5270 PROCESS ANTIFOUL Emergency Telephone Number Medical (708) 920-1510(24 hours) SECTION 4 FIRST AID INFORMATION ( CONTINUED ) individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INHALATION: Can cause moderate irritation. Can cause moderate irritation. Prolonged inhalation of vapor may be harmful. SYMPTOMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of product can cause nausea, dizziness, vomiting, stupor or unconsciousness. CHRONIC: Prolonged skin contact with product can cause dry skin and defatting resulting in irritation and dermatitis. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but acute studies have been conducted on a similar product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LD50 = Approximately 5,000 nig/kg COMMENTS: Four of the ten rats died within three days at a dosage of 5,000 mg/kg. Lethargy, loss of muscular coordination, tremors, diarrhea, and labored respiration were observed. ACUTE DERMAL TOXICITY (ALBINO RABBITS): LD90 = Approximately 2,000 mg/kg COMMENTS: Five of the ten rabbits died by the end of seven days after a dosage of 2,000 mg/kg. Loss of appetite, emaciation, lethargy, decreased PAGE 2 OF 9 SAL OOOOO9757 NALCO CHEMICAL. COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 * NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALC0 5270 PROCESS ANTIF0ULAN7 Emergency Telephone Number Medical (708) 920-1510(24 hours) 6 S 6 57 SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED ) muscular coordination and salivation were noted. Dermatitis, sloughing of the epidermis and scab formation were also noted in the surviving animals. PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 4.1/8.0 Moderately irritating COMMENTS: Well defined redness and slight to moderate swelling were observed immediately after the removal of the occluded dressing (4-hour contact). These reactions decreased in severity after 24-hours and continued to lessen through the remainder of the study (7 days). PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: 19.0/110.0 37.5/110.0 25.8/110/0 1-hour exposure 24-hours exposure 72-hours exposure COMMENTS: Corneal opacities, iritis and conjunctivitis were observed within one hour. Blistering of the conjunctival tissues and pannus formation were also noted. Peak ocular injury was noted at 24-hours. This condition then slowly subsided through the end of the study. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear light amber FORM: Liquid SOLUBILITY IN WATER: Insoluble SPECIFIC GRAVITY: 0.95 60 Degrees F VISCOSITY: 139 cst 8 100 Degrees F POUR POINT: Less than -30 Degrees F FLASH POINT: Minimum 120 Degrees F (PMCC ODOR: Hydrocarbon ASTM D-1298 ASTM D-445 ASTM D-97 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: Minimum 120 Degrees F (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. PAGE 3 OF 9 $AL 000009758 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET NALCO PRODUCT HALCO 5270 PROCESS ASTIFOULAN! Emergency Telephone Number Medical (708) 920*1510(24 hours) SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C0W NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed. If significant vapors or mists are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements and selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained' breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.) when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent* Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery PAGE 4 OF 9 OQo 09rs 9 nB NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5270 PROCESS ANTIFOULANT NALCO Emergency Telephone Number Medical <706) 920-1510 (24 hours) 6 S6 57 SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - COMBUSTIBLE LIQUID, N.O.S. COMBUSTIBLE LIQUID NA 1993 CONTAINS - AROMATIC HYDROCARBONS, NAPHTHALENE SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Heavy aromatic naphtha - Combustible, skin irritant Naphthalene - Irritant Amine alkyl phosphate salts - Eye/skin irritant Naphthalene = TWA 10 ppm, STEL 15 ppm ACGIH/TLV 52 mg/m1, 79 mg/m1 ACGIH/TLV Ethylbenzene = TWA 100 ppm, STEL 125 ppm ACGIH/TLV 434 mg/m1, 543 mg/m1 ACGIH/TLV Xylene = TWA 100 ppm, STEL 150 ppm ACGIH/TLV 434 mg/m1, 651 mg/m1 ACGIH/TLV Naphthalene = TWA 10 ppm, STEL 15 ppm OSHA/PEL 50 mg/m1, 75 mg/m1 OSHA/PEL Ethylbenzene = TWA 100 ppm, STEL 125 ppm OSHA/PEL 435 mg/m1, 545 mg/m1 OSHA/PEL PAGE 5 OF 9 SAL 000009760 BM--^^-- NALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE. ILLINOIS 60563-1190 t- -- -.*. ,C=-~G5-''OQO 7 NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALC0 5270 process antifoui Emergency Telephone Number Medical (708) 920*1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Xylene = TWA 100 ppm, STEL 150 ppm OSHA/PEL 435 mg/m*, 655 mg/m* OSHA/PEL Heavy aromatic naphtha = 100 ppm TLV Manufacturer' s recommendation CERCLA, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ) substance and if 10,000 pounds of product are released. It requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. (1-800-424-8802). SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. After October 17, 1989, MSDS(s), or a list of product names for all hazardous substances between zero (0) and 10,000 pounds, not previously reported, must be submitted. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following ingredient(s), (with CAS # and % range) PAGE 6 OF 9 SAL 000009761 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 N NALCO MATERIAL SAFETY DATA SHEET PRODUCT MALC0 5270 process antifoulant Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATOR? INFORMATION ( CONTINUED ) which appear(s) on the List of Toxic Chemicals. Naphthalene Ethylbenzene Xylene 91-20-3 100-41-4 1330-20-7 1-5 1-5 1-5 TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) , 40 CFR 261 SUBPART C & D: rf this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CPR (consult section 11). FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): This product contains the following ingredients covered by the Clean Water Act: Naphthalene - Section 307, 311 Ethylbenzene - Section 307, 311 Xylene - Section 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Ethylbenzene - Section 111 Xylene - Section 111 STATE REGULATIONS: CALIFORNIA PROPOSITION 65: Substances known to the State of California to cause cancer may be present as an impurity or residue. MICHIGAN CRITICAL MATERIALS: This product contains the following substance(s) identified on the Michigan Critical Materials Register: Ethylbenzene, Xylene STATE RIGHT TO KNOW LAWS: Regulated in those states using the TLV for naphthalene, ethylbenzene, and xylene as a criteria for listing. PAGE 7 OF 9 SAL 000009762 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 G S 6 57 Af NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALC0 5270 process antifoulani Emergency Telephone Number Medical (708) 920-1510(24 hour*) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) INTERNATIONAL REGULATIONS: This is a WHMIS controlled product under The House of Commons of Canada Bill C-70. The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name CAS # % Concentration Range Heavy aromatic naphtha Naphthalene Ethylbenzene Xylene Amine alkyl phosphate salts 68603-08-7 91-20-3 100-41-4 1330-20-7 Proprietary SECTION 15 ADDITIONAL INFORMATION 10-20 1-5 1-5 1-5 70-100 F 308632 SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CA5ARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed.r Van PAGE 8 OF 9 SA,_ 00009763 NALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE. ILLINOIS 60563-1190 inr * "'^9-3^5 - * Don MATERIAL SAFETY DATA SHEET PRODUCT NALC0 5270 PROCESS ANTIFOUL NALCO SECTION 17 BIBLIOGRAPHY Emergency Telephone Number Medical (708) 820-1510 (24 hours) GS657 ( CONTINUED ) Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 09/25/89 DATE PRINTED: 05/19/90 PAGE 9 OF 9 SAL 000009764 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 GS NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (708) 920-1510 (24 hours) $4L Q0 9?6s ------a-- NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19S A October 1, 1990 Fire Chief Westlake Fire Department 2401 Guillory Street Westlake, LA 70669 ADDENDUM TO SUBMITTAL OF MSDS UPDATES - THIRD QUARTER 1990 Dear Sir: Enclosed please find additional MSDS'e to be added to your file along with the larger packet mailed to your office for the third quarter. Please accept my apologies for the oversight. David L. Tinker, Safety Supervisor Conoco Refinery enc. COM. S4L 0009766 October 1, 1990 Louisiana Emergency Response Commission Office of State Police Hazardous Substance Control Section Right-To-Know P.o. BoX 66614 Baton Rouge, LA 70896 ADDENDUM TO SUBMITTAL OF MSDS UPDATES - THIRD QUARTER 1990 Dear Sir: Enclosed please find additional MSDS's to be added to your file along with the larger packet mailed to your office for the third quarter. Please accept my apologies for the oversight. David L. Tinker, Safety Supervisor Conoco Refinery enc. COM.408 SAL 000009767 October 1, 1990 Mr. Samuel H. Russell Calcasieu Parish Local Emergency Planning Committee P.O. Box 1391 Lake Charles, LA 70602-1391 ADDENDUM TO SUBMITTAL OF MSDS UPDATES - THIRD QUARTER 1990 Dear Sir: Enclosed please find additional MSDS's to be added to your file along with the larger packet mailed to your office for the third quarter. Please accept my apologies for the oversight. David L. Tinker, Safety Supervisor Conoco Refinery enc. COM.409 sal 009768