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La rone Chemicals Corp. 6100 Oak Tree Boulevard Cleveland. Ohio 44131 VINYL CHLORIDE MONOMER MATERIAL SAFETY DATA SHEET ISSUED: AUGUST, 1983 Doc. 83124 SECTION I Manufacturer13 Name LaPorte Chemicals Corp. A subsidiary of The BFGoodrich Company Telephone Number (216) 447-6490 Transportation Emergency Telephone CHEMTREC: (800)424-9300 Address 6100 Oak Tree Blvd. Cleveland, Ohio 44131 Chemical Family Vinyl Halide Trademark None Chemical Name/Synonyms Vinyl chloride. VCM. VC1. Chloroethylene. Chloroethene. Formula CH2CHC1 SECTION II - HAZARDOUS INGREDIENTS Vinyl Chloride C A* S Number 75-01-4 HOo Amount in Product ACGIH TLV-TWA 5 ppm, Ala OSHA PEL 0.5 ppm "Action Level" 1.0 ppm TWA 5.0 ppm Ceiling See Section V for further information. Vinyl chloride is a CANCER SUSPECT AGENT. Notes: TLV-TWA: Threshold Limit Value - Time Weighted Average for concentration of the chemical substance in the ambient workplace air. American Conference of Governmental Industrial Hygienists, 1982 Edition. OSHA PEL: OSHA Permissible Exposure Limit, 29CFR1910.1017. Ala means "human carcinogen with assigned TLV", ACGIH. BFG38333 IS5 cn )r* SECTION V - HEALTH HAZARD DATA Permissible Exposure Limit (29CFR1910.1017.) -Eight Hour TWA: 1.0 ppm -"Action Level": 0.5 ppm -No employee may be exposed to vinyl chloride at concentrations greater than 5.0 ppm averaged over any period not exceeding 15 minutes. -No employee may be exposed to direct contact with liquid vinyl chloride. Effects of Overexposure -Prolonged exposure may cause cancer. -Direct contact with liquid causes freeze burns (irritation, frostbite, freezing). -Prolonged exposure to high concentrations may cause degeneration of the ends of finger bones. -Exposure to concentrations of 7,500 ppm may cause asphyxiation, persistent irregular heartbeat, narcosis, nausea, or dizziness. -NOTE: The odor threshold for vinyl chloride is about 4,000 ppm. Odor does not provide an adequate warning for hazardous exposure. Emergency and First Aid Procedure IN CASE OF EYE CONTACT: (Liquid). Immediately flush eyes with plenty of water for an extended time, not less than five (5) minutes. Flush longer if there is any indication of residual chemical in the eye. See a physician. IN CASE OF SKIN CONTACT: Immediately remove contaminated clothing. Wash the affected area with plenty of soap and water. If irritation, freezing or frostbite occur, see a physician at once. i IN CASE OF INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately. SECTION VI - REACTIVITY DATA Stability Thermally stable. Hazardous Polymerization Will occur Conditions/Materials to Avoid Exposure to air (oxygen), sunlight, heat, oxidizing materials, copper, contamination with polymerization catalysts and alkali metals and their alloys may result in the formation of vinyl peroxides. This may cause heat generation (exothermic polymerization) and vaporization resulting in high pressure within vessels and potential release into the environment. Vinyl chloride is noncorrosive to metals when dry at normal ambient temperatures, but moisture at elevated temperatures accelerates corrosion. Hazardous Decomposition Products CO, CO2, HC1 and, in small amounts, phosgene on combustion. BFG38335 -3 *0 CA & K) NIOSH/MSHA jointly approved respirators under the provisions of 30CFR Part 11. Read 29CFR Part 1910.1017(g)4 for complete details for selection of respirators for vinyl chloride. Protective Equipment In regulated areas wear protective gloves, footwear, headgear, and chemical goggles where exposure to liquid is likely. Wear other protective clothing as required to prevent body contact. SECTION IX - SPECIAL PRECAUTIONS -Open, handle and use under well-ventilated conditions. -Wash thoroughly after handling. Always wash-up before eating, smoking or using toilet facilities. -Keep away from heat, sparks and flame of any sort. -Do not get in eyes, on skin or on clothing. -Do not breathe vapors. -All wiring and electrical equipment should be Class 1, Group D -Do not store or consume food or beverage in regulated areas. --Do not smoke in areas where vinyl chloride is used or stored. -Keep container closed. -Bond and ground all containers when transferring chemical. -Emptied container may contain residual liquid or vapors which may ignite or explode. Do not cut, puncture or weld on or near the container. -Prior to loading, the vapor space of tankcar, vessel, etc. should be analyzed for oxygen content; maximum limit is 500 ppm. SECTION X - TRANSPORTATION For domestic transportation purposes, the proper U.S. Department of Transportation shipping descriptionand hazard class is VINYL CHLORIDE, FLAMMABLE GAS, UN1086. (49CFR, 1982 edition.) NOTE: Uninhibited vinyl chloride monomer is not acceptable for international shipments. SECTION XI - PRECAUTIONARY LABELING Containers of vinyl chloride shall be legibly labeled either "VINYL CHLORIDE: EXTREMELY FLAMMABLE GAS UNDER PRESSURE: CANCER SUSPECT AGENT" or "CANCER SUSPECT AGENT". 29CFR1910.1017(1X5) USER'S RESPONSIBILITY A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and safety information contained herein should be passed on to your customers or employees, as the case may be. LaPorte Chemicals Corp. must rely on the user to utilize the information we have supplied to develop work practice guidelines and employee instructional programs for the individual operation. -5- &FG38337 The BFGoodrich Company Chemical Group 6100 Oak Tree Boulevard Cleveland. Ohio 44131 216-447-6000 MATERIAL SAFETY DATA SHEET VINYL CHLORIDE MONOMER ISSUED: AUGUST, 1983* Doc. 83102 SECTION I Manufacturer's Name The BFGoodrich Company Chemical Group Telephone Number (216) 447-6000 Transportation Emergency Telephone CHEMTREC: (800)424-9300 Address 6100 Oak Tree Blvd. Cleveland, Ohio 44131 Chemical Family Vinyl Halide Trademark None Chemical Name/Synonyms Vinyl chloride. VCM. VC1. Chloroethylene. Chloroethene. Formula CH2CHC1 SECTION II - HAZARDOUS INGREDIENTS C.A.S. Number Amount in Product ACGIH TLV-TWA 0SHA PEL Vinyl Chloride 75-01-4 100Z 5 ppm, Ala 0.5 ppm "Action Level" 1.0 ppm TWA 5.0 ppm Ceiling See Section V for further information. Vinyl chloride is a CANCER SUSPECT AGENT. Notes: TLV-TWA: Threshold Limit Value - Time Weighted Average for concentration of the chemical substance in the ambient workplace air. American Conference of Governmental Industrial Hygienists, 1982 Edition. OSHA PEL: 0SHA Permissible Exposure Limit, 29CFR1910.1017. Ala means "human carcinogen with assigned TLV", ACGIH. *Supersedes 7/80 C/t BFG38339 V-* sri >0 La SECTION III - PHYSICAL DATA (Typical data, not specifications) Boiling Point 7F (-13.8C) Solubility in Water 0.25 @ 68F (20C) @ 7 in. H2O pressure Specific Gravity (^0=1) 0.97 @ -13C (liquid) Vapor Pressure (mm Hg) @ 32F (0C): 1300 68F (20C): 2500 100% Volatile by Volume Vapor Density (Air 1) 2.15 @ 15C Appearance and Odor Colorless gas. Mild, sweet odor. (Transported as a liquid under pressure) Molecular Weight 62.5 SECTION IV - FIRE AND EXPLOSION HAZARD DATA (Vinyl Chloride is EXTREMELY FLAMMABLE) Flash Point -108F (-78C) Cleveland Open Cup Ignition Temperature 882F (472C) Flammable Limits in Air (Z by volume) Lower: 3.6% Upper: 33.0% National Fire Protection Association Hazard Identification (NFPA 704) Health: 2 Flammability: 4 Self-Reactivity (Stability): 1 Extinguishing Media For Small Fire: CO2 or ABC dry powder. For Large Fire: Water spray (fog) can be used to absorb heat and cool and protect surrounding exposed materials. Shut off source of fuel if safe to do so. . Note: Streams of water cannot extinguish a vinyl chloride fire. Vinyl chloride liquid floats and boils on top of water. Special Fire Fighting Procedure -Whenever possible, let fire burn itself out. Keep away. -Keep upwind. Isolate hazard area (evacuate unnecessary people at least 2,000 feet if there is danger of exploding containers). -Cool containers with water sprayed from maximum distance. Use unmanned hose holder or monitor nozzle. -Wear positive pressure self-contained breathing apparatus and full protective gear to prevent all body contact. Personnel not having suitable respiratory protection must leave the area to prevent exposure to toxic and corrosive combustion gases, including hydrogen chloride. Unusual Fire and Explosion Hazards -Vapors are heavier than air and may travel along the ground or may be moved by ventilation and ignited by flame, sparks, heaters, or other Ignition sources at distant Locations (flashback potential). -BLEVE potential (container explosion potential) -If the source of a vinyl chloride leak has not been closed off, do not attempt to extinguish a large fire as hot metal may reignite the invisible vapor cloud. -Vapors can form flammable mixtures with air. -2- BFG38340 SECTION V - HFi1T ^ HAZARD DATA Permissible Expqsore_Limit (29CFR1910.1017.) -Eight Hour TWA: 1.0 ppm -"Action Level": 0.5 ppm -No employee may be exposed to vinyl chloride at concentrations greater than 5.0 ppm averaged over any period not exceeding 15 minutes. v -No employee may be exposed to direct contact with liquid vinyl chloride. Effects of Overexposure "Prolonged exposure may cause cancer. -Direct contact with liquid causes freeze burns (irritation, frostbite, freezing). -Prolonged exposure to high concentrations may cause degeneration of the ends of finger bones. -Exposure to concentrations of 7,500 ppm may cause asphyxiation, persistent irregular heartbeat, narcosis, nausea, or dizziness. -NOTE: The odor threshold for vinyl chloride is about 4,000 ppm. Odor does not provide an adequate warning for hazardous exposure. Emergency and First Aid Procedure IN CASE OF EYE CONTACT: (Liquid). Immediately flush eyes with plenty of water for an extended time, not less than five (5) minutes. Flush longer if there is any indication of residual chemical in the eye. See a physician. IN CASE OF SKIN CONTACT: Immediately remove contaminated clothing. Wash the affected area with plenty of soap and water. If irritation, freezing or frostbite occur, see a physician at once. IN CASE OF INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is, difficult, give oxygen. Call a physician immediately. SECTION VI - REACTIVITY DATA Stability Thermally stable. Hazardous Polymerization Will occur Conditions/Materials to Avoid Exposure to air (oxygen), sunlight, heat, oxidizing materials, copper, contamination with polymerization catalysts and alkali metals and their alloys may result in the formation of vinyl peroxides. This may cause heat generation (exothermic polymerization) and vaporization resulting in high pressure within vessels and potential release into the environment. Vinyl chloride is noncorrosive to metals when dry at normal ambient temperatures, but moisture at elevated temperatures accelerates corrosion. Hazardous Decomposition Products CO, CO2, HC1 and, in small amounts, phosgene on combustion. -3 BFG38341 ft cn H a SECTION VII - SPILL OR LEAK PROCEDURE Steps to be taken in case material is released or spilled Issue warning: Extreme fire danger and toxic hazard. Flammable vapors may spread from the spill. Eliminate all ignition sources. Ventilate the area. Isolate the hazard area. Do not purposely ignite a leak. Do not flush chemical into public sewer or water system because of the explosion/toxicity hazard. Shut off leak if safe to do so. Let small spills evaporate. For large spills, dike or flush to ground and ' evaporate. Remove contaminated soil. , J "Personal protective equipment and clothing should be utilized by persons performing this work. All unnecessary personnel and individuals without proper personal protective equipment should leave the area. Be prepared to evacuate all individuals within at least 2,000 feet when danger of exploding large vessels is possible. Waste Disposal Method HAZARDOUS WASTE.** If burned, incinerator should be equipped with an HC1 scrubber. Contaminated soil and containers must be managed as a hazardous waste. *EPA Hazardous Waste Number (RCRA): U043. 40CFR261.33(f) SECTION VIII - SPECIAL PROTECTION INFORMATION Ventilation Efficient exhaust ventilation should always be provided to draw vapors away from workers to prevent routine inhalation. Ventilation should be adequate to maintain the ambient workplace atmosphere below the limits listed in Section II and Section V. Respiratory Protection* ATMOSPHERIC CONCENTRATION OF VINYL CHLORIDE 1) Unknown, or above 3,600 ppm REQUIRED APPARATUS Open-circuit, self-contained breathing apparatus, pressure demand type, with full facepiece. 2) Not over 1,000 ppm. Type C, supplied air respirator, continuous flow type, with full or half facepiece, helmet or hood. 3) Not over 10 ppm Any chemical cartridge respirator with an organic vapor cartridge which provides a service of life of at least 1 hour for concentrations of vinyl chloride up to 10 ppm. -4- BFG38342 approved respirators under the provisions or mm r . T-JjIctr part 1910.1017(g)4 for complete details for selection of roaplracors 'W1 chloride* f Tl-rf - 0O6nC In raau'laced ereas wear protective gloves, footwear, headgear, and K chemical go8les where exposure to liquid is likely. Wear other protective clothing as required to prevent body contact. SECTION XX - SPECIAL PRECAUTIONS -Open, handle and use under well-ventilated conditions. -Wash thoroughly after handling. Always wash-up before eating, smoking or using toilet facilities. -Keep away from heat, sparks and flame of any sort. -Do not get in eyes, on skin or on clothing. -Do not breathe vapors. -All wiring and electrical equipment should be Class 1, Group D -Do not store or consume food or beverage in regulated areas. -Do not smoke in areas where vinyl chloride is used or stored. -Keep container closed. -Bond and ground all containers when transferring chemical. -Emptied container may contain residual liquid or vapors which may ignite or explode. Do not cut, puncture or weld on or near the container. -Prior to loading, the vapor space of tankcar, vessel, etc. should be analyzed for oxygen content; maximum limit is 500 ppm. SECTION X - TRANSPORTATION For domestic transportation purposes, the proper U.S. Department of Transportation shipping description and hazard class is VINYL CHLORIDE, FLAMMABLE GAS, UN1086. (49CFR, 1982 edition.) NOTE: Uninhibited vinyl chloride monomer is not acceptable for international shipments. SECTION XI - PRECAUTIONARY LABELING Containers of vinyl chloride shall be legibly labeled either "VINYL CHLORIDE: EXTREMELY FLAMMABLE GAS UNDER PRESSURE: CANCER SUSPECT AGENT" or "CANCER SUSPECT AGENT". 29CFR1910.1017(1)(5) USER'S RESPONSIBILITY A bulletin such as this cannot be expected to cover ail possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and safety information contained herein should be passed on to your customers or employees, as the case may be. BFGoodrich must rely on the user to utilize the information we have supplied to develop work practice guidelines and employee instructional programs for the individual operation. -5- BFG38343 DISCLAIMER OF LIABILITY As Che conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability or any us of this material. Information contained herein is believed to be true anS accurate but all statements or suggestions are made without warranty, express or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user. 2246a/27 BFG38344 -6-