Document v6XYagX3bJOpV4aN5BMm7YLp9

oe{R~w 44 " 129 202( N) 1706- _ /ORI Gl NAL PAPER . l anruoJ fo eht Comnibust yteSico of apJn Vo. l 44 No. 21 920)( 170 16- >e gp mEaixplenrt Vesel CF31 ^ R~ ^e / Sudyt noointibihnI tcefEf fo CF31 over MrhaAenti/ Comobnuist ni an onoisEpxl J p Y 1* . c ^ 2 OHTANI CHdieo C l * NAKATA CSnhsiuke 2 t lvww@ Yokohama onal iNat T w/@ yrisrevUin C 5 79- 852041- ls y g wToki iad ayH;od[ 2 lww@Hw{ Yokohama onal iNar Uni yrisre 240 E8501 C579- wTaodik lsyJ C ayH;od[ J C Yokohama 5-97 852041- C aJpan 5-97 C Yokhan 240 E8501 CJapan 2002 N 4 C8toe 202 N 7 5 oe R/evcedi 8 120; iApr edAecpt 5yluJ 202 atcrAbts : CF C1si laiatnetop emacentplr dei lpa tsniag .er i f So 11aelbisop fo HALON er i fgnihsiugnitxe .stnega However tC i stmei yrev cixot seag when schemes 01 educr st i amount dluohs bedetaulave rof t i ot come otni laci tcarp esu CF )Br Cwchhi sah esolc alchemi sci tsiretcarahc htwi CF1 sCi known ot haev na enhanecd onocmibuts noi t ibihni tceffe when t is i mxi dhtwi some eni .sag t ls yi l isae detapicitna taht CF i 1osla sah hucs bffeC tc Ctub t i sah ton ben deiduts . tey sTih paer stroper an mal entiperx ylelos rorehlegot htwi oniosplex eruserp edverobs oniosplex eruserp vruc yduts onnoitcuder some treni .sag ni annoisolpxe bhtwi ocn noi tabrtn C ofnoisolpxe When CF 1 was lessev edasrdec was etiuq tnereff id tmii l noitartnecnoc aded ylelos nosai tartnecnoc htwi eht of r ia/enahmte eurtxmi otcirmoteaihciots eurtxmi C of CF.desaeJrcni C esac of CF B. r nl eht esac when C1F) s i ad b d of mhanet and r ia C However Cehtel i forp f o fo CFB)r Ceht noisolpxe eruserp edasrdec yl alcmoniont sa ehtnoitartneco desaercni Ct d nonoisolpxe derruco retfa ehtnoitartnecnoc ecxde eht tmii l .eulav On eht rehto hand Cni eht esac fo CIF) Ceht noisolpxe eruserp desarced sa ehtnoitartnecnoc desaercni tsuj sa ni eht esac of CF i Br Celwhi ehtnoitartneco was relmsla naht about 8% . Then eht noisolpxe eruserp desaercni sa eht C noitartneco desaercni C tJ hedacr a peak eruserp Cand edascrdec niag l i tnu ehtnoitartnecnoc hedacr eht tmii l eulav 5%51. () The enhanecd noi t ibihni tceffe was osla edvoebrs when CF 1was comnedbi htwi negortin ro bonarc edixoid Key Wodrs : HALON emacentplr CCCFdCComonibust noi t ibihni er iFrehsiugnbi txe . 1 n `CdC "C>C H"C" DOE` `\ ``LRr[^[[ dC"C OECfl{ ` i ~L>g OE~. 'Cn `A fll I] j C Q">nKL-'C I]w EB[ ^>CuI] wj gI[cL ~ C I]wj`L~w...OE. CI]w EB[ *Co b ngpsondi hoaut . r:]mE-ia pj@.acninuhy.ot 1989 N v 1992 N 11 R yn [ Q J^OE L fl ^ 1301 Cn 121 Cn 2402) l oe~SpOE. - OEflCI]wjLffC tbf n J>OECgpOE~ "CV``\C n 1301 ~>C` Kv CV``\dvA . -OEC`\ P ICn sKXCSsKX<` /" sOE~LC` l"F OEC`\ " -C` Kvn -"OE~ ]1[ C 4 Cn`(n Y" gI[c 1994 N l -OEgpOE~ 1301 1301 " , 40) ( JpY'C>egp CF31 ^R^~e/ 167 OER~}ln Q Ctbf < f <L f< Ef ` - "mOE~"CE f ~ OE~.OE ` C CF31 Jbvo[i[ ` Zx NSIT "L OE 2.3 %2][ <>CI]wjw<C `~pOE\ OE~ . OE CPgpLsKX< ~ gp /"C` KX > _L .-C CF31 sKX< KXR~ @ - LC l"'OE' '/ . 1H .2 - u - @ .1.2 - u } l {-gp-uTv.uC >eC eCQuCzCL^ ^ | v' . u rC flOC' fiS uOE~. KX R~<KXC "fOEOE C...OCro~ C" CF3 1 pOE R~<KX" `l OE/u~OCro~. eC>e - ZxfiC OE...OEe u^pZT L"" L~sC> <^ ~"L CXg[WI V XR[ v(: VC6-045) ~L ^. > 1() e > eC a 10 m mC 120 m mCoe 5 m m SUS316 ~ e .e hg\ 100 prm h@"COEL 5 cm e S M bv"> / C...a 1 m mCoed u 2 m m ,, SUS316 oedd " Ltfl OE ~.oedd ' 90 0 OE > e "L "L '-"0 1 MPa <^ (/adC PGM1-0 KE) uCXg[ WI VXR[vo. )2( Q u KX ~ CF kI pOE C KX L~\" QuCOC oeo- L S m . Q u SUS304 C \ [ _C "[UOE~.\ [_ C <"_JVEC_JVEC _ig E ' . Q u KX fl > Coe 1 m m et \ [ _C 2 u~ . nItre G@ CF31 q N2 C~ rAi q Meo ane CL .giF 1lamtneirEepx sutaArap 14( ) ~Et CR N2 168 oe{ R ~ w 44 " 129 2( 2N) .giF 2 erusePr yrotsHi rof amFlmabl b Gas eurMtxi .giF 1 : rusePr byortsHi rof Non- lF ammaebl Gas eurMtxi )3( ^pZT R~EflZx"Ll. >e e LtflOE~ ^ p sKXY`OE CsKX R~ Z TCXe Xg Xf [T [ f( }lIpCsKX"`- ^ECXc c--: AB/HP 50 51 PSAI) LRKX """C>MR~< LC`M(I--: S82 S- <C Me "- 070 )5 fW^~fW^pl ^[ --(I x" `~\OE-"mOE~.-OE [ K3TXV-DC-I)I \OE. CR~EflfMx"sKX L ...LOEC fiY`<K .2.2 -@ X R~ EZx \"-"m OE~ ,C>e mf f [ W C^|v^ C - \"l} .C>eRKXCC"Cw_ C/ '`sKXC " /- .C<C" C CF I "OE...OELZx C/I= L (X )Cj [ /C 2 "hg. C- C Y` <KXR~EZxC ClI Xg ^d>d,,( 20 )J "PY`OER~EZxC L>e <C_ fi f KX j <"". W ^Xg[WIVXR [ vL^CR~L - }'/CfC_YfC L.R~L~C 10.0 M[Pa] "`OEuR~vCC"OE usRv .} 2 R~g`C} 3 sRg`. ]3[ . ( 1) Cj j < Xj Y`< AS .3.2 KX RKX ~R~ ~"\OE^ p.Y`KX C CF I ...CsKXASACwECfC _YfCxRKX~Cp. "L>CY`K .3 -l@ .1.3 sKX< l " l ^/C<CCsK XY`~ l CCR~E"L. } 4 OE~wE/AS<KX ^/ C<CY`OEwE/ASA<KX X R 60 1555 3R~ 50 4" 5 G ~ 40 35 ~ EO2 30 B 2.0 4.0 Meol onitacFr mEixpenrt 6.0 8.0 of umHiel gFi . 4 oniosEplx cirmoteihcioSt Eq. .))1( tmiL oniatrCentoc rMAhanie/t fo Ar Hl e eurtMxi aded ot eurtxMi diSlo( :eni l onmiatiEts of )24( JpY'C>gep CF31 R^~ ^ e/ 169 A -C C ( )E 11n1n1O1un1Eu1UnunnUuEndunnzuunnuunu aEe E. . IwI C g @^SLO monoEUF3 OE| ag-- a A i C 6 F E/ U; :2: : i:FE 5 o C _A A X_4 1 E ~3 s nu 20. 40. 60. 80. Moel oniFactr of Humiel .giF 5citabAid amFle eurTematper cfoirmoteihcSiot MrAi/benaht urtxMi fl ade htwi He/Ar erutxMi ExLE E R~ 1 X O BB 20 40 60 C w E <"< <KXOE CR ~EZxfi(1)\">C-OE sKX R~}lI LC x",,Ol lOEC Concenoartint gFi .no6i taiVra fo Mamxium noisoElpx was Aded otmoihcioSt ci rte show atad rof CF1 .)Br of rusePr rAiMhane/et CF31 (%) e Oevdbesr When CF1 . 1 erutxMi detDto( eni l <" < - LCfi `Z'OOER~}l> /C )1( /P l C CF I Zx W} 6 . C CF I Y` lOE-"mF. OECsKXY`OE R~Efl ~> CF1 : 1 Zx" 7 ' <lt"-"'.C .8 5 %t C > " > CF I Zx fMx>LCfi(1)/l -'OE . 'C{/gps `,,>~ `Cs[N < I I l 5. % s R ` . } C CF Br n( KX~R~EfMxv -Cf 154 K CA S 1546 K CwE 1301) fl . -s CF3Br ` ,,~j 7 % t C CF I d 1784 KC _Yf 1652 K ` M ` - "OE~"C CF1 : Br OE L Zx > "wE OEC_ M"_vO ~,mFOE~. >CLx">C>M<x"> LL CF31 Zx } COE Z oeM<x o X"OE l OE xil -"\zOE .- . CwE ...sKX< OE - Babushok "OE< C L V~ [V fi )1( \ " l - > OE v ~ L C fi R~Eflx"OELOE C C 1( ) S(ENKNI) p~ ~ CCF I 2C 3 % Zx .)4[ OE CF1 : Br L<x x"Y`<KX<"^W `~ ",,l"COELZx OE < \zOE . AS /w E CF3Br L<x>,,-""'~. <KXY`OE R~EZxfMx sKX< LKX< l 5g.Fi . c_OE R~EY`KXZx"Kv - fMxC^w HC H2 C C" CF31 EZx ~CZx\OE 8% C OHC H20 C H02 C H202 C 0 C 02 C CC COC C02 C CH4 C N2 C NOC N02 C CFCI Cl C: f CF4 C CHFO C CFO C COF2 C HI C HFCC C1 h FC Ar C He 28 Ce w C EZx. )2( CF I sKX<OE " l^ [ C<CCsKX(fC w|eV ' tosfrMci Eecx1 \p[@\ _Yf) CF1 : 1 Y`~S l C CR p ~ .OELe >e ~ E "L .} 7 CF1 : I/ f< KX R~ E "C` R~ LCL fMx p~. C fl Z x m fi C/ CF CfI C 1( )\"Zx.} CF I _ Y f < " < OEIl lOEL .2.3 CF31 sKX< l R~E""N-C> l " )1( CF31 P OE \OE-""'.C - l "" 2.0 ," l ^[CC C C: F I Y` > CF1 : 1 "< >>\OE- ~S l C CR~E"L.R~ ' 43) ( 170 oe{R~ w 4 " 921 20( N) E NZ\ 50 w nunununu I( F \L E | I - L O U F O - o c o o d Expmeirent LR OE O ' \ 4 E ...~ ` BB .[-[ 20. 4 0. 60. 80. Moel oniFactr of CF3I gFi . 7noisoElpx irmoteihcioSt Eq. ))1( tmiiL noitartnCecno c Mhane/et fo C1ICF N2 erutxMi ad e rAi erutxMi di lSo( :eni l noimtaitEs ( OE( ) E ..CE. ntnt4qEtnnu4unEno4uaEnuuanunuhU aE 25 fl 323 - .[ ql nu 2 0. 40. 60. Moel oniFactr 8 0. of CF3I gFi . 8citabAid amFle eurTematper ciformoteihcioSt rAiMhane/et erutxMi ade htwi CFN2/CI erutxMi C C CF I "(} 5.0 L)C} 7f 6 'OE OE C CF I " Zx >"'OE"C --R~}l \OE~Zx/ R~ E\ . wIR~} C WJ l LR~ EZx x" Il ' s K XOE ~>. OE CfM x vZl} C CF I sKX< 8 'OE/s KXZx/A}"~.-OEl wIR~}~'OE . / R wI} pC G}l L Gl M[ <xL Ea " > L C x " " k = Aexp REaT-/)( " I<> -" l OE~. LCwI} p `wG}I p C> Y `}l > CR~ E fl <x"OEL OECGlM[ `'/fl x `"@OE-. ~> fMx"} ,C C CF I R~} p"G}I >~- l OE.CfM x 40. xLC OEL C CF I " C CF I " C CF I "> -" ~ C " - OE C CF I " > OEC<C M" >Il lOE. {/ C CF I f< C CF I _Yf < - lC} 7 -l - x} 8 fMxvZlW" / '"CfM x > R~ " wt Mt B OE LC d C _ /L <x_I"Kv o t f o L . . 4 {/ L OEm' . @ >e fl ^/ C < C s KX Y`R~E"LAsKX< ~ l\OE-"mFOE. A C ^/ C CF I Zx" C<C 7 ' 5.8 " ' OE>"C ~ "> / LCII l sR"'OE. CF | i Y ` OE %t_ > C CF I Zx" > C CF I R~}OEC 5. % il -""'. B C CF I sKX< - l" \ OE. fC_Yf < OE C CF I sKX<CZx 20 % t l " >LCIl \zOEZx ... " ZxR~"}OE-""'`. L CF CI s K X < ` ~ g - - pOEC I CFI g p , '`. CF CI gp" ,OECR~} > - " OEC`lOEtbfC Ef } - " . {/ C CF I r h'qC{/ s/ L C CF Br -f[^ X `h/ @Sq v . Reefernces Saso CY. CCom.btus amFle 18 E4849-9 19) ( .2 NFP A 201 . dandSart on eCanl Ag btn rFi bnghsinguiiEtx Semysts ConaliNat rFi no/itcetoPr oniatAiocs 196) ( .3 otSia CN.an d Ogawa C Y. CerFi yteSfa .J :)3(72 12805- 1( 96) 4 Babushok CV. CNot C.T CBgesur CCRD. .F Hamnsi C C.A and Tsang CW. CCom.btus amFle :701 3516-7 1( .)69 4) (