Document v6MRvdb8yQargR7ZZZvkGBbEY

... .a. wrt> fc. antci (Approved bv U.S. 0*prtmnt of Lebor "E*otmlv Similar" to Form LSB OOS-4) CHEMICAL NAME: DIISOPROPYLAMINE SYNONYMS: -- CHEMICAL FAMILY: Nitrogen Compounds FORMULA: [(CH3)2CH]aNH MOLECULAR WEIGHT: 101.19 TRADE NAME AND SYNONYMS: Diisopropylamine gwpti'ijyj-ey we J ,. v__________ _----------------------------- *-. .{ i ` . * , .. * BOILING POINT, 760 mm. Hg 83.9C. <183.0F.) --1* V k% -- - Ifc - * FREEZING POINT -96.3C. SPECIFIC GRAVITY (H-0 = 1) 0.7173 at 20/20 C. VAPOR PRESSURE AT 20C. GO mm. Hg VAPOR DENSITY {air - T) 3.5 SOLUBILITY IN WATER. % bv wt. at 20C. Complete* PERCENT VOLATILES BY VOLUME 100 EVAPORATION RATE (Butyl Acetate = 1)__ __ 5.8 APPEARANCE AND ODOR Water-white liquid; amine odor. Not miscible above 27C. and 30% amine by weight. 1 wy ^ ^!^;?^^|l:n;*^HA2AflppUS;INGREDIENTS':w^.*i:H MATERIAL Not applicable % TLV (Units) FTvT*; rr"1 ffgrruyW" tt* - FIRE AND" EXPLOSION HAZARD DATA FLASH POINT (test method) 21F.t Tag open cup I AUTOIGNITION I '--IEMEEi?&TUR E_________________6__0_0__F_. - FLAMMABLE LIMITS IN AIR, % by volume LOWER 0.8 UPPER EXTINGUISHING MEDIA Carbon dioxide or dry chemical for small fires. Polymer type foam for large fires. 7.1 SPECIAL FIRE FIGHTING PROCEDURES None UNUSUAL FIRE AND EXPLOSION HAZARDS None RECEIVED ` AUG 2-1976 pan'f'vTTV^ j;-v. mey py ?Jsff EMERGENCY PHONE NUMBERS y. ;tv, Dr. C. U. Dernehl, 212/551-4785; 914/946-0646 (night) Dr. K. S. Lane, 212/551-4787; 914/666-3655 (night) C. P. Carpenter, Ph.D., 412/327*1020; 412/241-7896 (night) IT J'rrrr-T SL 049795 Legal responsibility ** assumed only for the fact that all studies reported here and all opinions are those of qualified experts. UNION CARBIDE CORPORATION CHEMICALS AND PLASTICS a 270 PARK AVENUE, NEW YORK, N.Y. 10017 THRESHOLD LIMIT VALUE FFECTS OF OVEREXPOSURE IV. HEALTH HAZARDDATA 5 ppm. Vapors will be irritating, and may also cause nausea and vomiting. Contact of liquid with eyes causes severe injury. Uncovered contact with skin may be irritating, but clothing wet with the amine may cause burns. EMERGENCY AND FIRST AID PROCEDURES If inhaled, remove to fresh air. Give oxygen if breathing is difficult. Call a physician. Immediately flush eye contact with plenty of water for at least 15 minutes, and then get medical care. Flush skin contact with water. Remove contaminated clothing and wash skin. . .. lF.l i* .4 STABILITY UNSTABLE STABLE T+ . V. REACTIVITY DATA ; CONDITIONS TO AVOID Avoid heat, fires, and sparks. INCOMPATIBILITY (materials to avoid! Avoid contamination with strong acids. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition may produce nitrogen oxides, carbon monoxide and/or carbon dioxide. HAZARDOUS POLYMERIZATION May Occur F!VM,",l!r V- Will not Occur CONDITIONS TO AVOID V ---' "EW, . RHIHA . I.)'f...... ......... None - --------------- *------------------- --------------r ^ - Vl^SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN 1ATERIAL IS RELEASED 'SaPILLED Flush heavily with water. WASTE DISPOSAL METHOD Incinerate in a furnace. 1 VII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (specify type) Air>supplied mask VENTILATION LOCAL EXHAUST MECHANICAL (general) PROTECTIVE GLOVES OTHER PROTECTIVE EQUIPMENT 1 WT't"' Preferred Safety shower and eye bath. SPECIAL OTHER EYE PROTECTION VIII. SPECIAL PRECAUTIONS Monogoggles T'-'-r PRECAUTIONARY LABELING DIISOPROPYLAMINE WARNING! FLAMMABLE. LIQUID MAY CAUSE EYE INJURY AND SKIN IRRITATION. BREATHING OF VAPOR HARMFUL. Keep away from heat, sparks, and fire. Do not leave container open. Use with adequate ventilation. Do not get in eyes or on skin. Do not breathe vapor. In case of contact with eyes or skin, immediately flush with plenty of water for at least 15 minutes; for eyes, get medical attention. FOR INDUSTRY USE ONLY OTHER HANDLING AND STORAGE CONDITIONS SL 049796 F*43982 12/71-SM Printed In U.S-A.