Document v60ejV6QQGqe8j4JGe8vZ50Rw

I Betty Boros-Russo - FW: L2535805 City of Salem PFOA/PFOS (3rd round of samples) From: To: Date: Subject: "Fred Mucci" <fmucci.salem@verizon.net> "'Betty Boros-Russo'" <Betty.Boros-Russo@dep.state.nj.us> 1/29/2008 9:40:16 AM FW: L2535805 City of Salem PFOA/PFOS (3rd round of samples) Good Morning Ms. Boros-Russo, Attached please find the PFOA/PFOS results for the 1st quarter (3rd round of samples) of 2008 for the City of Salem PWSID 1712001. Fred Mucci From: Stephen Bobbs [mailto:stebob@qclaboratories.com] Sent: Monday, January 28, 2008 11:02 AM To: histlog; fmucci Subject: L2535805 City of Salem PFOA/PFOS Fred,..please find the subcontract data for PFOA/PFOS samples, attached. Thanks, Stephen -----Forwarded M essage-----From: "ecopy" <ecopy@qclaboratories.com> To: sbobbs@qclaboratories.com Sent: Monday, January 28, 2008 11:00:11 AM (GMT-0500) America/New_York Subject: L2535805 City of Salem PFOA/PFOS This PDF file was created using the eCopy Suite of products. For more information about how you can eCopy paper documents and distribute them by email please visit http://www.ecopy.com jPage 1 DEP2-SDWB-000255 O fhi o -f ^alo/n ANALYTICAL REPORT PFOA/PFOS Analysis Lot#: D8A080154 Nicki Smith QC Laboratories, Inc. 1205 Industrial Highway Southampton, PA 18966 TestAmerica Denver Gail DeRuzzo Project Manager January 24, 2008 4955 Yarrow Street Arvada,CO 80002 tel 303.736.0100 fax 303.431.7171 www.testamericainc.com DEP2-SDWB-000256 Table Of Contents Standard Deliverables Report Contents Standard Deliverables The Cover Letter and the Report Coverpage are considered integral parts o fthis Standard Deliverable package. This report is incomplete unless allpages indicated in this Table of Contents are included. Table of Contents Case Narrative Executive Summary - Detection Highlights Methods Summary Method/Analyst Summary Lot Sample Summary Analytical Results QC Data Association Summary Chain-of-Custody TotoaflPNaugmesber DEP2-SDWB-000257 Case Narrative D8A080154 TestAmerica Denver utilizes USEPA approved methods in all analytical work. The samples presented in this report were analyzed for the parameters listed on the methods summary page in accordance with the methods indicated. Dilution factors and footnotes are provided on each datasheet to assist in the interpretation of the results. The results relate only to the samples in this report and meet all requirements of NELAC. All data have been reviewed for compliance with the laboratory QA/QC plan and have found to be compliant with laboratory protocols with any exceptions noted below. Please note that Non-Detect (ND) results have been evaluated down to the Method Detection Limit (MDL) and should be considered ND at the MDL. Unless otherwise noted, results for solids have been dry weight corrected. This report shall not be reproduced except in full, without the written approval o f the laboratory. Sample Arrival and Receipt The following report contains the analytical results for one sample received 1/8/08, according to documented sample acceptance procedures. The samples were received in good condition at a temperature of 2.5C. No anomalies were encountered during sample receipt. Standards Analytical standards were prepared using the acid form of the compound perfluorooctanoic acid (PFOA). PFOS is a commercial prepared and certified solution. Perfluoro-n-[1,2,3,4-13C4]octanoic acid was introduced at the extraction step and was used as an internal standard for quantitation of PFOA. Perfluoro-1-[1,2,3,4-,3C4]octanatesulfonate was introduced at the extraction step and was used as an internal standard for quantitation of PFOS. Sample Extraction and A nalysis The sample presented in this report was analyzed for the target analyte by TestAmerica Denver's SOP DEN-LC-0012A. For water samples a 250 mL aliquot of each sample is acidified with 1 mL o f 6N HCI solution and it is extracted using solid phase extraction technique with methanol conditioned C18 cartridges. Each sample is spiked with the internal standard, prior to extraction. After the sample is passed through the cartridge, the analytes are eluted with 4 mL of methanol. The final volume is brought to 5 mL using methanol and the extract is analyzed by LC/MS/MS. Method QC Samples The Method Blank is processed reagent water spiked with surrogate and prepared with each batch o f 20 samples o f the same matrix. The method blank was non-detect at the reporting limit. Each batch is prepared with a Laboratory Control Sample (LCS). The recoveries of two concentration levels o f Laboratory Control Samples were within control limits. DEP2-SDWB-000258 Analytical Comments No anomalies were observed. DEP2-SDWB-000259 EXECUTIVE SUMMARY - Detection Highlights D8080154 PARAMETER Ii25 35805-1 01/02/08 09:00 001 PFOA RESULT REPORTING LIMIT UNITS ANALYTICAL METHOD 0.0062 J 0.010 ug/L DEN -LC-0012 DEP2-SDWB-000260 METHODS SUMMARY D 6A.080154 ANALYTICAL PARAMETER___________________________________________ METHOD______ LC/MS/MS, PFOA DEN -LC-0012 References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. PREPARATION METHOD ____ DEP2-SDWB-000261 METHOD / ANALYST SUMMARY D8A080154 ANALYTICAL METHOD ANALYST DEN -LC-00I2 Jaqueline Bonnett References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. ANALYST ID 003601 DEP2-SDWB-000262 SAMPLE SUMMARY D8A080154 WO # SAMPLE# CLIENT SAMPLE ID KE63D 001 L25 35805-1 NOTB(S) : - The analytical results of the samples listed above are presented on (he following pages. - AH calculations are performed before rounding to avoid round-off errors in calculated results. - Results noted as H D " were not detected at or above the stated limit. - This report must dot be reproduced, except in full, without the written approval of (he laboratory. - Results for the following parameters are never reported on a dry weight basis; color, corrosivity, density, flashpoint, ignitability, layers, odor, paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight SAMPLED SAMP DATE TIME 01/02/08 09:00 DEP2-SDWB-000263 QC Laboratories Client Sample ID: L25 35805-1 HPLC Lot-Sample # __ : D8A080154-001 Work Order # __ : KE63D1AA Date sampled. 01/02/08 09:00 Date Received..: 01/08/08 Prep Date ..... : 01/08/08 Analysis Date..: 01/10/08 Prep Batch # __ : 8008408 Analysis Time..: 04:25 Dilution Factor: 1 Method.. ..... . : DEN -LC-0012 Matrix.... ___ : PARAMETER PEQ& PFOS RESULT 0 .0 0 6 2 or ND REPORTING LIMIT 0.010 0.010 UNITS ugr/L ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 102 76 RECOVERY LIMITS (50 - 200) (50 - 200) N O TB (S ) :_________________ I Estimate*! result. Result is less than RL. DEP2-SDWB-000264 QC DATA ASSOCIATION SUMMARY D8A080154 Sample Preparation and Analysis Control Numbers SAMPLE# 001 MATRIX WATER ANALYTICAL METHOD DEN -LC-0012 LEACH BATCH # PREP BATCH # 800840B MS RUN# 8008184 DEP2-SDWB-000265 METHOD BLANK REPORT HPLC Client Lot # __ : D8A080154 MB Lot-Sample #: R8A080000-408 Analysis Date..: 01/10/08 Dilution. Factor: 1 Work Order KE7731AA Prep Date..... : 01/08/08 Prep Batch # __ : 8008408 M a t r i x ......... : WATER Analysis Time..: 02:16 PARAMETER PFOA PFOS R E P O R T IN G RESULT_________ LIMIT UNITS ND 0.010 ug/L ND 0.010 ug/L METHOD_______ DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 96 77 RECOVERY LIMITS (50 - 200) (50 - 200) NOTB(S):______________________________________ Calculations an performed before rounding to avoid round-off errors in calculated results. DEP2-SDWB-000266 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot #...: D8A08Q1S4 Work Order # __ : KE7731AC LCS Lot-Sample#: R8A080000-408 Prep Date..... : 01/08/08 Analysis Date..: 01/10/08 Prep Batch # __ : 8008408 Analysis Time..: 02:32 Dilution Factor: 1 Matrix. PARAMETER PFOA PFOS PERCENT RECOVERY 86 90 RECOVERY LIMITS (70 - 130) (39 - 120) METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 100 82 RECOVERY LIMITS (50 - 200) (50 - 200) H O T S ( 8 ) :________________________________________________ Calculations a n performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters : WATER DEP2-SDWB-000267 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot # __ LCS Lot-Sample# Prep D a t e ..... Prep Batch. #... Dilution Factor D8A080154 Work Order #...; KE7731AC R8A080000-408 01/08/08 Analysis Date..; 01/10/08 8008408 Analysis Time..: 02:32 1 Matrix........ .: WATER PARAMETER PFOA PROS SPIKE AMOUNT 0.200 0.200 MEASURED AMOUNT 0.171 0.180 UNITS ug/L ug/L PERCENT RECOVERY 86 90 METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 100 82 RECOVERY LIMITS (50 - 200) (50 - 200) NOTE(S) ;____________________________________ _ Calculations arc performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters DEP2-SDWB-000268 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot #...: D8A08Q154 Work Order #... l c s Lot-Sample#: R8A080000-408 Prep Dat e..... : 01/08/08 Analysis Date,. Prep Batch # __ : 8008408 Analysis Time.. Dilution Factor: 1 KE7731AD 01/10/08 02:48 Matrix:. PARAMETER PFQA PROS PERCENT RECOVERY 116 118 RECOVERY LIMITS (70 - 130) (39 - 120) METHOD______ DEN -LC-0012 DEN -LC-0012 SORROSATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 107 96 RECOVERY LIMITS (SO - 200) (50 - 2 0 0 ) HOTE(S) ;______________________________________ Calculations are performed before rounding to avoid round-offerrors in calculated results. Bold prist denotes control parameters WATER DEP2-SDWB-000269 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot (t-- : D8A080154 Bork Order # ___ IiC S L o t - S a m p le # : R8A080000-408 Prep Date..... : 01/08/08 Analysis Date.. Prep Batcb #. .. : 8008408 Analysis Time.. Dilution. Factor: 1 KE7731AD 01/10/08 02:48 Matrix:......... : WATER PARAMETER PFOA PROS SPIKE AMOUNT 0.0200 0.0200 MEASURED AMOUNT 0.0233 0.0236 UNITS ug/L ug/L PERCENT RECOVERY 116 118 METHOD DEN -LC-0012 DEW -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 107 96 B O T E (S ) :___________________________________________________________ Calculations are performed before rounding to avoid round-offerrors in calculated results. Bold print denotes control parameters RECOVERY LIMITS (50 - 200) (50 - 200) DEP2-SDWB-000270 MATRIX SPIKE SAMPLE EVALUATION REPORT HPLC Lot-Sample D8A080154 Work Order #... MS Lot-Sample #: D8A030236-001 Date Sampled. ..: 01/02/08 13:00 Date Received.. Prep Date......: 01/03/08 Analysis Date.. Prep Batch #...: 8003408 Dilution Factor: 1 KE2QL1AC 01/03/08 01/10/08 Matrix PARAMETER PFQA PFOS PERCENT RECOVERY 91 91 RECOVERY LIMITS (70 - 130) (39 - 120) SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 98 55 HOTB(fi) ; _______ _________________________ Calculations ace performed before rounding to avoid round-offerrors in calculated results. Bold print denotescontrol parameters METHOD______ DEN -LC-0012 DEN -LC-0012 RECOVERY LIMITS (50 - 200) (50 - 200) : WATER DEP2-SDWB-000271 MATRIX SPIKE SAMPLE DATA REPORT HPLC Lot-Sample # -- : D8A080154 Work Order ft. MS Lot-Sample #: D8A030236-001 Date Sampled...: 01/02/08 13:00 Date Received Prep Date..... : 01/08/08 Analysis Date Prep Batch ft...: 8008408 Dilution Factor: 1 : KE2QL1AC : 01/03/08 : 01/10/08 M a t r i x ......... : WATER PARAMETER PFOA PROS SAMPLE SPIKE MEASRD AMOUNT AMT AMOUNT 0.14 0.209 0.326 0.057 0.209 0.247 UNITS ug/L ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 98 55 NOTS(S) :______________________________________ Calculations are perforated before rounding to avoid round-offerrors in calculated results. Bold printdenotescontrol parameters PERCENT RECOVERY 91 91 METHOD DEN -LC-0012 DEM -LC-0012 RECOVERY LIMITS (50 - 200) (50 - 200) DEP2-SDWB-000272 MATRIX SPIKB SAMPLE EVLOATION REPORT HPLC Client Lot # __ : D8A080154 Work Order #... MS Lot-Sample #: D8A080154-001 Date Sampled...: 01/02/08 09:00 Date Received.. Prep Date..... : 01/08/08 Analysis Date.. Prep Batch # __ : 8008408 Analysis Time.. Dilution Factor: 1 KE63D1AC-MS KE63D1AD-MSD 01/08/08 01/10/08 04:41 Matrix WATER PARAMETER PFOA PFOS PERCENT RECOVERY 87 87 91 92 RECOVERY LIMITS (70 - 130) (70 - 130) (39 - 120) (39 - 120) RPD RPD LIMITS 0.29 (0-20) 0.31 (0-20) METHOD DEM -LC-0012 DEN -LC-0012 DEN -iC-0012 DEM -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY RECOVERY * LIMITS 101 (50 - 2001 101 (50 - 200) 68 (50 - 200) 68 (50 - 200] MOTE(S) :______________________________________ Cafcufarions are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters DEP2-SDWB-000273 MATRIX SPIKE SAMPLE DATA REPORT HP1C Client Lot # __ : D8A080154 Work Order KE63D1AC-MS MS Lot-Sample #: D8A080154-001 KE63D1AD-MSD Date Sampled...: 01/02/08 09:00 Date Received..: 01/08/08 Prep Date..... : 01/08/08 Analysis Date..: 01/10/08 Prep Batch # -- : 8008408 Analysis Time..: 04:41 Dilution. Factor: 1 Matrix WATER PARAMETER PFOA PFOS SAMPLE AMOUNT 0.0062 0.0062 HD HD SPIKE AMT 0.200 0.200 0.200 0.200 MEASRD AMOUNT 0.181 0.180 0.182 0.183 UNITS ug/L ug/L ug/L ug/L PERCNT RECVRY RPD METHOD 87 DEM -LC-0012 87 0.29 DEN -LC-0012 91 DEM -LC-0012 92 0.31 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 101 101 68 68 RECOVERY LIMITS (50 - 200) (50 - 200) (50 - 200) (50 - 200) MOTH(St :______________________________________ Calculations areperformed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters DEP2-SDWB-000274 SAMPLE DUPLICATE EVALUATION REPORT HPLC Client Lot D8A080154 SD Lot"Sample #: D8A030236 -001 Date Sampled__ : 01/02/08 13:00 Prep Date ___ ..: 01/08/08 Prep Batch # __ : 8008408 Dilution Factor: l Work Order #... : KE2QL1AA KE2QL1AD Date Received..: 01/03/08 Analysis Da t e ..: 01/10/08 Analysis Time..: 03:36 -SMP Matrix... ___ : WATER -DUP MS Run #. ..... : PARAMETER PFOA SAMPLE RESULT 0.14 DUPLICATE RESULT 0.13 UNITS ug/L RPD RPD LIMIT 0.71 (0-20) METHOD DEN -LC-0012 SURROGATE RECOVERY 13C4 PFOA 13C4 PFOS SAMPLE % RECOVERY 101 60 DUPLICATE % RECOVERY 101 56 RECOVERY LIMITS (50 - 200) (50 - 200) DEP2-SDWB-000275 DEP2-SDWB-000276 3BI O QC L-waboratories' 1205 Industrial Blvd. Southampton, PA 189966-0514 Phone: 215-355-3900 Pax: 215-355-7231 CHAIN OF CUSTODY P a g a _____*_ of f 8IB to/Report to; (If different) Lab LIMS No: LAB USE ONLY: # Asorblc/HCI Vials . i HCI Vials Client/Acct. No. T tc & f m Address zz qyJnK City/State/Zip Phone/Fax Sampling Site Address: (il different) P.O. No. It___ NgSgOg _ i__ N a.O H /Zn acetate pH # __________ HNO3 pH _ _ rt2S04 pH - -N aO H oH u.;-- . : # _ __L' riprserved ' Client Contact j PROJECT ( F IE L D ID _ Lois' S S f b S - >f53(po QC Contact Collection G T] Number of Contains !Oats R !0 Matrix Military Time A M Code BP Totei H C 1 T t> H H H t 0 JL 1 .: Ufl ;9 1a 2c i ?t Mr T _< hfi r 7i /%" 0T- t Hj 1! 1 h .# ___ Hcl pH # :Tfnp control ID# A N A L Y S IS R E Q U E S T E D P P m 7 pf^ j MATRIX CODES DW: DRINKINGWATER GW: GROUNDWATER WW: WASTEWATER SO: SOIL SL: SLUDGE OIL: OIL SOL: NON SOIL SOLID ,, Ml: MISCELLANEOUS j Field pH, Temp (C or F), DO, Clj, S, Cond. sto. SCi i 1 SAMPLED BY: (Name/Company) Verbal/fax data due: ./ / --i-- i__ _,i... . . i,,,i,,,,i i . i,,,i, . i i Report Format: Standard Forms , | -H--a--rd--c--o-D--V---d--u-e--:---------------/--------------/-----------------------------S--t-a--n-d--a--r-d---+--Q---C---------N--J---R--e--d-u--c--e-d----- Disk ;----------------------------------- Sly 1 Please call for pricing and availability on rush (<14-21 day) turnaround and on all but standard format. Field Parameters Analyzed By: DatefTIme: S A M P LE CUSTODY EXC H A N G E S M U S T BE D O C U M EN TED BELOW . USE FU LL LEG AL SIGNATURE, DATE A N D M ILITARY TIM E (24 HOUR C LO C K , I.E. 8A M IS 0 8 0 0 ,4 PM IS 1600) iRELINQUISHED By SAMPLER DATE TIME RECEIVED BY DATE TIME JRYMEJJTOD: 0 QC COURIER 0 CLIENT Custody Seal Number 1 / / . (oj . f / ,,PELINO' IfSHEGT&f' 1 DATE 1 DATE TIME PS S TED EX OTHER_______________ OMMENTS: ' /U /M r ,fu2 S. LA- Y Js tptyt* ^RELINQUISHED BY DATE TIME TIME ( j} r mDB> '^A u Tifoi rfooRELINQUISHED 9Y DATE TIME RECEIVED BY oaVe TIME 44 RELINQUISHED BY DATE l L ________________________________ TIME RECEIVED BY 5 DATE TIME Hazardous: yes/n o For example to aid completion, see reverse side. T