Document v410BjzqoVpRVgrKy8Dj3xeE

FILE NAME: Warning Labels (WL) DATE: 1946 DOC#: WL012 DOCUMENT DESCRIPTION: MCA Guide for the Preparation of Warning Labels for Hazardous Chemicals STATE OF PENNSYLVANIA CITY OF PHILADELPHIA, to wit: NOW COMES JAKE LAUGHLIN, who after being duly sworn, makes oath as follows: 1. I am a paralegal employed by the Locks Law Firm of Philadelphia, Pennsylvania. 2. On November 18, 2014 I traveled to the Othmer Library of Chemical History, located at 315 Chestnut Avenue, Philadelphia, Pennsylvania. 3. While at the library, I reproduced the following publications: Warning Labels, 1946, Pages 1-63 4. These digital images were captured from the original publications housed at the archival section of the Othmer Library of Chemical History. The original publications are the property of the Othmer Library o f Chemical History, and were returned to their custody following their reproduction. Each o f these documents is over 20 years old and were found at a library of chemical history, where they would be expected to be maintained. I declare under penalty of perjury under the laws of the State of Pennsylvania that the foregoing is true and correct. Executed this 19thday of November, 2014. NOTARY: Subscribed and sworn to this 19thday ofNovember, 2014, before me, the undersigned, a notary public in and for the City o f Philadelphia and State of Pennsylvania, and as witnessed by my hand and official seal. /> My commission expires the 20 Notary Signature and # COMMONWEALTH OF PENNSYLVANIA NOTARIAL SEAL INIECE D. GOSHA, Notary Public City of Philadelphia, Phila. County My Commission Expires June 14,2016  I* 48 ML-1anual PART I MANUAL L-l--A GUIDE FOR THE PREPARATION OF WARNING LABEI-S FOR HAZARDOUS CHEMICALS Adopted 1945 Revised April 1946 everTwhiededneinvgelfoipelmdsenhtasofacnceewntuchateemdicthale pnreoeddufcotsr faunrdnhthhme ginatrpopdruocptriioanteoinf fcohrmemaitcioaln pinrotcheossseescaisnetfol wanhdersetosrpaegceialanpdrefcoaruttihoensseaprerondeuccetsssanroyprMecaanuytiocnhaermyiclaalbseplsreasreentnencoeshsaazrayrds in normal handling sibiliTtyheofedtuhceaitrioenmopfloeymerpsl.oyHeeoswreevgear,rdsiuncghchhaezmaircdasl ahraezanrodts ciso,nfainndedmtousetmrepmloayiene,sthaleondeir,eacntdreisnpfoonr smtoartiionng cchoenmceircnailnsg Tthheemmsohsotuplrda,cstoicaflamr aeasnpsrfaocrticthabeles,elilcearctho deivsesreympinearsteonthuissiinngf,ortmraantsiopnoratipnpge,arn*r tsotatbeembeyntlsabaenlBd ianfsfitxruecdtitoonscosntatateinderass osfimhpalzyaradnodusbricehfelmy iacsalcs,ircbuemarsitnagncaepspproeprmriaitt.e precautionary turinIgnCthheemiinsttes'reAsstsoocfiautnioifnohrmasitpyreapnadremd othreisaMdeaqnuuaatlefloarbethliengbeonfecfihteamnidcaglupidroadncuectos,f tihtse mMeamnubfearcs. sAtosoedneshiofadddeiftiinointiotnostihseingcelnuedreadl irnecSocmhemdeunleda1tiIonnsorcdoenrtathinaetdthheerteeirnm, sthueseMdCmAayhabse cplreeapralyreudnsduegr gmeesnteteddlafrboemls ftoimr espteocitfiimc epraosdaudcdtsi.tioTnhaelsreechoamvembeenednedprlainbteelsd aarae Mdeavneuloapl eId.-2, which will be supple airlinAe prerescpairuattioornsa,rygalasbeml adsokess, ncolotthtainkge, thsheoepsl,aceetcof safety equipment such as suitable goggles, incluIdneddivoinduaallabsetal tourtetsh,atreagusplaetciiofincslaobrelobrdeianfafnixceeds tomaaycornetqauinireer thInateapcahrtcicausela, rthienfroerqmuiarteimonenbtse ionf tahdedsietiolanwtso,shoorumld aclosmo bbienasttuiodniewd ithT,haenwyalranbienlglelaqbimelesrstubgygelastwed*in tins Manual should be used * Federal statutes include SuptIntoefrsDtaotceuCmoemntme,erGceovCtomPmriinstsiinogn R0etgriucela,tiWonassfhoinrgTtowni,spDo.i-tCaticn of Explosives and Ocher Dangerous Articles WashFiendgetroanl, DCaCu,stic Poison Act and regulations. Food and B u g AdmlmstiaUon, Federal Sccuiity Agency, of AFgerdiceurlatlurIen,seWctaicsihdiengAtocnt, oDf 1C910 and legulatlona Agricultural Marketing Administration, V S Department AgenFceyd,eWralasFhionogdt,onD, rDug. CB.nd Cosmetic Act and regulations' Food and Drug Administration, Federal Security InsecRtiecliadteedAscttast.utes of the 48 States and the District of Columbia include Cuuatic Acid, Pharmacy, Poison, ond AUG 1 51948. W CHEMISTS' CLUB ----------- LlfifMW---------- WARNING LABELS PART 1 A G U ID E FOR THE P R EP A RA TIO N OP W A R N IN G LABELS FOR H AZA RDO U S CHEMICALS PART 2 ILLUSTRATIVE W ARN IN G LABELS FOR H AZARDOUS C H E M IC A LS THEOTHMER LIBRARYOF CHEMICAL HISTORY CHEMICAL HERITAGE FOUNDATION a V IllS H IB IT M ANU FACTU RING CHEMISTS' A SSO C IA T IO N OP THE UNITED STATES 6 0 * W o o d w a r d B i d a - * W a s h i n g t o n 5 , D. C. C#yleM tees by Maw<cturt*s CHamMl' AiltdSfkfl 4f Mis UtUfaS Ite' .he Unii! ML a1nual PREPARATION OF PRECAUTIONARY LABELS (incluTdhiengbamsiicxtcuornessi)deariaet,ions in the preparation of a precaulioiuty label for any chemical product 1) Determination of the hazards present in the particular chemical product 2) Selection of appropriate statements for each significant hazard inherent in the product. 3) Arrangement of statements in the order of emphasis desired listedThme Smcohsetdufrleeq2uenStelyt oepnpcoosuinteteeraecdhhcalzaassrdasrehasvtaetebmeeenntcslaislsluifsietrdatbinygthcehaMraCcAteriinsttioc 1p0retcyapuetisonass usually required for that type of hazard. statemMeanntys cfhoermeiaccahl psirgondiufcictsanwt itlylpheavsheoumlodrebethinacnluodneed toynpethoef lhabaezlardM, omst wchheicmhiccaalsepraopdpurcotsprciaonte ttiaoinnairmypmureiatiseusresWshheonuldthebsee ianrcelupdreedseonnt itnhehalaimbeflusl quantities, appropriate warnings and precau the ilAlubsetraacthivcehesmtaitceaml epnrotsduwciltlmnousttbbeeatprpelaitceadbleindeiivthideurablleyc,authsee>rethweyilldobenomtaancycuinrasttealnyceesxpinreswshtihche dsteagtreemeeonftshaszhaorudldorbebescealeucsteedthefryomfailSctohecdouvleer3theTphaisrtiSccuhleadruclehaprraecsteenritsstiacsmofnrescuocmh pcraeshees,nssiuvietablilset of statement arranged in columnar form and grouped aa follows* A Signal Word B Hazards C PreMcaeuatsiuorneas ry D CIanssetroufctAiocncsidemnt Cisotlwumo-nfoAld--tToheinddeicgaretee toof thhaezarerdadcearnthbee ceoxmprpeassraetdivoenslyeriIonursenleastsivoeftethrme sdanTgehre ipnuvroplvoesde isnhohualnddilminmg eadigaitveelyn fporlolodwuct Tanhde t"osicganlallawtteonrdtiso''nrteocotmhempenredceaduatiroen,airny tihnestorurdcetiroonfs dwimhiicnh ishing severity of hazard, (1) DANGER, (2) WARNING, (3) CAUTION Example: WARNING! CraotelulymndeBsc--ribFerosmthethpir9inccoilpuamlnhaszhaorudld bTehsiseliesctpeldactehdeopnhtrhaesesa(moer lpihnreaassest)heth"saitgmnaolswt oacrdcu" Example. WARNING! FLAMMABLE hIfazoatrhde.r significant hazards are present, they should be tabulated under the principal fCioomlumCnolCu--mnTCheaanpdpsrhoopurlidatfeolsltoawteomnesnutbosfe"qpureenctaluinteiosnary measures*' should be chosen Example: WARNING' FLAMMABLE Keep away from heat and open flame. Keep container closed Use with adequate ventilation Avoid prolonged breathing of vapor Avoid prolonged or repeated contact with skin 3 Manual L 1 GENERAL PRINCIPLES siderIend.the preparation of any precautionaiy label the following principles should first be con 1) Etraecahtecdheinmdiicvailduparloldy,ucmt (itnhceluldiginhgt omfixittsuroesw)npcrehsaernactstearisdtiisctsinct problem and must be 2) bErxietrfemanedcasirme pslheould be exercised in the choice of terminology Statements should be 8) Oisnmlaobset ldsefsoirradbilfefeInrenotrdperrodtoucgtsa,inungirfeoarmterityunmdelrasntagnudaignegtothrionduigchatestathnedasradmizeathioanza. rds ( 4) cPlreeacralyutdioefnianreyd tsetramtesm. eTnotsbemeuffsetctbivee athcecyursahteo,uldsebleectuivseedlyonclhyoswehne, nanandd etoxptrheesseexdtenint nouesc,esassawryellLaasbtehlienfgaoilfuareretolagtiivveelyadheaqrumalteessnoptrioceduocftasohaazaatrod,inwdiilcladteevtehlaotpiat idsishraezgaarrdd for labels and defeat their purpose bFeorapepxlaiemdpelex,cliufstihveelywtoordth"oPsOe IfSffOodNu"ctais (tIo) rwethaiicnh iatsreupseofiusolnnesssacocnordainlagbetol, aitdsehfoinuiltde ftooxr iwcihtytchstaintsdaursde*,isorpre(2sc)riwbeitdh bwyhilcahw it Iins aasllsooctihaeterdctahsreosutghhe croemlamtivoen duesgagreee, oorf t(h3e) choavzearrdexctarenmbeelybeacttneoruisndhiaczaaterddsb, y"WthAeRuNseINoGf''sitgonacl owveorrdlsesssucsheraiosus"DhAazNaGrdEs,R"antod "hCazAaUrdTION'' to cover minor hazards, together with a descriptive statement of the 5) Chemical names should be those recommended by the American Chemical Society. 6) oTfhea uhsaezoafrdaounsonc-hdeemseicnapltisvhcocuolddebdeesaivgoniadteidon oIfr tfroardeannyamreeasaosnt,heit oinslyuniddeenstiirfaibcaletiotno 'v sehxocweptthtoe tchheemtriacianlendamchee,moirsti,fththeelacbheelmsihcoaulldnasmtaeteisthseo tcyopmepolefxchasemtoicable, emgea,n"ienogrlpeoss- slvc acid," "lead compound " 7) lTahbeel:following subject matter should be considered for inclusion on a precautionary 1 Chemical name 2 "hSaizganradl (Cwoolurdm"n A(D, SAcNheGdEuRle-3W)ARNING-CAUTION) designating degree of 3 Affirmative statement of "hazard" (Column B, Schedule 3) 4 "(PCroelcuamuntioCn, aSrcyhemduelaes3u)res" covering actions to be followed or avoided 5. "Instructions m case of accident," where advisable (Column D, Schedule 3) 8) rWapahrny,inlgayloaubte,lsorshcoouloldr wbeithprainntyedothinereapsuilnyteledgimblaettteyrpoe,nwthheiclhabieslianncdosnhtorausldt bbye tpylapcoegd ccoonastipnigcuously on containers Legibility may be preserved with e suitable piotective t*oTioncplruodveidoenly pCiahcemtieicaallswcoarpkainbglesotafncdaaursdinfgoraclaubteelienfgfecptu*rpboysemsg1ePetO/oInSOaNnd' iunhdaelfaitnioedn mtheScphreindcuilpea1l matodthe*isoMf aennutrayl cinhtroontihceobvopdoyaurTehib*ydienfhinailtaiotinone,xbcleucdaeussechtehmeicvaalnacbafpeabalcetioonfscaaunsdingeffiencjtusrioefs cah*ema irceaslultwoitfh skthienabcsohrnprtaiocnlerouriioeif preclude a piaetlcal means of measuring thir hazards. 2 M unlintnni Chcmim' AvxxiJrion oi ihe United Soto .Schedule 1 DEFINITIONS __________________MbU*! H FlammabdleetLeirqmuiinde1d2*--bAynfliansfhlampominatblfero'mliqTuaidglilsabauney'ahoypoeidn-wtuhpicthengtievre, sasoffusiendflafmormtaebslet ovfapbourr9ni(nags oils) at or below a temperature of 80* F Extremelmy aFbllaemvmapaobrlse (Laisqudiedte'--rmAinnedexbtyrefmlaeslhy pfolaimntmfarobmle lTiqaugihdabisuea's lioqpueind-cwuphictehstgeirv,eassouffsefdlafmorteat of burning oils) at or below a temperature of 20" F Corrosivem*--ore(Pohrylseiaoslosgeivcearl)e--deAstcrourcrtoiosniveofist&isnsuaegebnyt wchheimchicianl caocntitoanc.t with living tissue will cause Irritant7--eit(hPehryismiomloegdiicataell)y--oArnafitrerritparnotloisngaendaogrernetpweahtiecdh cmonctaocnttaactmworietholrivleinssgsteisvseuree wloiclallintidssuucee reaction not leading directly to destruction of tiseue. Sensiftzern*e--ces(Psahryilsyiocloaugsiceaal)n--y Adissceenrsniitbizleerreiasctaiomn ainterliiavlinwghtiicshsuaesbourtdwinhaircihlyahftaenrdlienditiadloeosr nroet pinefaltaemdmcoatnotrayctrweaicthtiothneotnisscuoentoafcts,oemveeninidnivmidiunaultsemaamyo, uanttsa, lwatiethr dthatee,tipsrsoudeucoef athperosammpet individuals. Duets --dSeoclirdeppiatarttiiocnlesofgeonregraanteicd boyr hinaonrdglainngic, cmruastheirniagl,s gsruincdhinags, rroacpkid, oimrep, acmt,etdale,tocnoaotli,onwoaondd, dgirfafiuns,eemtc. aiDr ubsutst dseottnleotutnednedrtothefloicncfululaetneceexocfepgtrauvnidteyr electrostatic force; they do not Fume3--zaStoiolind pfraormticlmesoglteennemraetetadlsb,yectocn, daenndsatoifotnenfraocmcotmhepagnaiseedoubsysatatceh,egmeincearlalrleyacatfitoenr svuoclahtilais oxidation. Fumes flocculate and aometimea coalesce. Afists*--Sour sbpyenbdreedakliiqnugidudproaplleiqtsuigdeninetroatead dbisypceorsneddensstaattieo,n sfurcohmatshebygasspeloausshitnog,thfeoalimquinidg,staantde atomizing. Gases *--tNootrhmeallilqyuifdoromrlseoslsidflsutiadtsewonhliychbyoctchuepcyomthbeinsepdaceeffoefcteonfclIonscurreeasaenddpwrehsiscuhrecaanndbedecchraenagseedd temperature. Gases diffuse Vapors '--wThihceh gcaasneobueschfoarnmgedoftosuthbesstaen3cteasteBwheiicthhearrbeynionrcmreaalslyinginththeeprseoslisduroerolriqdueicdresatsaitneg atnhde the temperature alone. Vapors diffuse. Poison7--gPraomisso)n omrelaensss, aorswubhsetnanicnehawlehdicmh, cwohnecnenttarkateinonbsyofmloeussththianna2m0o0unptasrtosfp6e0r mgrialliinosn b(y4 vcaolluomrepihnytshiceaalira,crtiaopnidly (within 6 or 10 minutes) jeopardizes life by other than mechani >M8otaen Taihdismdefdientietiromninoifng``,Pogiseonne'r'al1ly,bawsehdenonthperawctoicrdal "cPoonissiodne"ratsiohnosuldonlhye, included on a warning label See General Principles 4 Mixture 5p--roApoprhtyiosnicatol coonmemaninogthlienrgaonfdtwwohoicrhmhoarvee snuobtstraenaccteesdwchhiecmhicmaallyy owritmh aoynenaont obtehaerr a fixed t1hIiCs CMdaRnfuiamltlon While the term `'inflammable'' is used by the ICC, the prefe-red form "flammable'' Is used in 2 MCA definition Ds ABs rdaenfdint,edDISncC) hpaapgtoee19I8I ,"' EMnagninuealeroinf gInCduonsttrroiall oHfytghieenAe,i"r UCSoPnHtaSm, ination of the Woiking Environment'' (Allen 5 ML-ln.l Mmuliciuiini QitnjiKi Aumisikia cJ ,k> Un.ird Som sCtaotluemmnenDts--mWahyenbeitsiesleacdtvedisafbrloemtotIhnicslucdoeluImnsntrucItniosntrsucintiocansseionf caacsceidoenft,acthceideanptprtoopriniadtie vsiimdupalelsmaertchovdasluaanbdlecohmutmsohnoluyldavbaeilalibmleitmedatteoriraelscogInnizsetrducftiirostnsaifdorprsotrciecdtluyrems ebdaicseadl truepaotn amnedntlasshtionugldefbfeecotsmtihttaetdmexacyepretswulhtefnrosmpeceiyfiecainlljyurrieeqsu, i&rerdecboymJmawendaBtieocnautoseoobftatihne mseerdioicuasl aIfttethnetiostnatsehmoeunldtsafcrcoommpSacnhyedaunlye 3spfeaciilfitcoinmsetreutctthieonexdaircetcnteededtso, tthheeytrsehaotumldenbte omfothdiefieedyetso suit In the example shown, toluene, no phrase from this column appears to be necessary possiWblehicleonevtienrgyenccoympoonunadlcabaerrliesEsfofmoretshaszhaorudl,difbeimdpirroecpteerdlytuosweadr,ditniasmiminpgratchteicaslertiooucosvherazeavredrsy, daintdionwsa. rnTinhgeraegaarinesstcsaurcchelyabaunsyesmaenadnsacocfidmenetassuarsinagreinlikaeblsyoltuotebeteernmcsouthnteerreedlatuinvdeesrernioorumsnae) scsoonf hdaezgarerdess,oafndintthenesrietycomItmfeonlldoawtisonths aint oSfchtwedoulceo8mopnoluyndcsonotneemmplaaytebteheleisrsdhivaizsaiordnouinstothtawnothoer tohthreeer and yet may carry the 9ame warnings and cautions cate Itnhsetirrucnteieodns fTohresheanindlsitnrugcatinodnsstsohroaugled otfakceonitnationecrosnsshidoeurladtiboen ibnocltuhdethdewchhearreacctoenridsittiicosnsofintdhie chemical product and the limitations of the type or types of container m which it is packed regarSdcihnegduhlaez4arpdrsesaernetsnostugygeetsktendowlanbels for samples of experimental products for which full data case Socfhteodluuleene5, itlhluestsrtaatteesmtehnetsapupselidcaatiroensoimf iclaaur ttioonthsotasteemgievnetns itno tShcrheeeduspleec2ififcopr raodcuocmtspouInndthoer maacriidxdt,sutrraeetperhmeaseveninntstgs. haTavzheaerrydthssipriendciecaxllaascmsaipsfeilceawtiishoetnrhseaItth-BoefpaanardlatibIceVullaforTrhhaaezpasrreodcspornrieedqtauerxiyraemcmopmloedp,iofauiqcnuadteiooounrsomhfyixtdhtrueorfesltuaonrdic 4 Muvftauiint Q kiuish Ausciu.oa ol tbe UnuM Sam L IXl.mial V Gases and Vapors PhyaioiogicaUy Inert VI. Harmful Dusts. VII Skin Irritants--Corrosive, VIII Materials Causing- Skin Irritations after Repeated or Continued Contact IX. Materials Toxic through Vapor Inhala tions or Skin Absorption. X TteorxiaiclsifcoTvaekreend IbnytesrntaatlulytoryApdpelfieinsittioonmoaf paodiuslotns "inliadbolesetso obfe d60estgrruacitnivseoorf lheussma(n4 agmmaou)n"ts olriketoly atony bematatekreinal intotexrincalliyn through easily anticipated errors. CAUTION! VAPOR REDUCES OXYGEN AVAILABLE FOR BREATH ING Use with adequate ventilation. Keep container closed. CAUTION! HARMFUL DUST Avoid repeated breathing or skin contact. Wash thoroughly before eating or smoking Keep away from feed or food products DANGER!CAUSES SEVERE BURNS Do not get in eyes Do not get on skin Do not get on clothing Inecyaesse wofitchonptlaecntt,yimofmwedaiateterl,yffolrusehyesks,mgoert minegdibceafloarteternet-iuosne. Remove and wash cloth CAUTION! MAY CAUSE SKIN IRRITA TION Avoid prolonged or repeated contact. WARNINGl ABSORBED THROUGH SKIN VAPOR HAZARDOUS Avoid contact with skin or clothing Avoid breathing vapor InImcamseedoiafteelyxpwosausrhe,wirtehmsoovaep taondfrpelsehntyaiorf rwe-auteaer Remove and wash clothing before POISON Ifenrsolt Pcorivnecriepdlebsy4r)egsutlyaptiiocnaloIrsbdeelfimniitgiohnt r(esesde Gen DANGER! MAY BE FATAL IF SWALLOWED Do not take internally 7 HLjnInul] ____ _____________ MinufKimmi CKt/riiu ^tKKUHMi of 1)1 Uftlirt ton Schedule 2 CLASSIFICATION OF HAZARDS Class Typical Label I FwlhaimchmSabulpepLoriqt uCiodms banudstiOonxid(iFzliansghApgoeinnttss fOoprelni-qCuuidpsMareethdoedt)e.rmined by Taghabue'a A Flash point 20 F or below. DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame Keep container closed B. Fclluassihvep. oint above^O" to 80* F in WARNING! FLAMMABLE. Keep away from heat and open flame. Keep container closed . 11 Flammable Solids and Oxidizing Agents as Classified by the ICC CAUTION! EXPOSURE MAY CAUSE FIRE OR CREATE FIRE HAZARD Keep away from heat and open flame Keep container closed. Inpcleansety ooff wcoanttearc,t,remimomveedainadtelwyasfhlucslhotwhiinthg before re-use III Vapors Immediately Toxic or Extremely Irritating Even on Exposure for a Short Time or to Low Concentrations. DANGER! VAPOR EXTREMELY HAZARDOUS Do not breathe vapor Do not get on akin Do not get in eyes Keep container closed and away from heat. Keep away from feed or food products Hapvreovaedir blyineU reSspBiruarteoaruoorf gMasinemsasspkecaifpi ceamlleyrgfeonrcy(name of chemical) available for IV Vapors Hazardous from Prolonged or Repeated Exposures, or Exposure to Higher Concentrations WARNING t VAPOR HARMFUL Uae only with adeiuate ventilation Avvoaidpopr rolonged or repeated breathing of Keep container closed and away from heat M inuftoiiti* etern iv i AiscIjiuv) c l ihc Sui Schedule 1 LABELS FOR EXPERIMENTAL SAMPLES Ml-lanus) propTerhtieeslaobrelpinogssoibfleexupseersimofeantpalrosdaumcptlaerseosfelndeowm pkrnoodwunct.s TphreesfeonltlsowuinnugsusaaflepgruoabrldesmasreAthlleoreffothree recommended: comm1e. rcSiaaml sphleipsmoefnat product already on the market should carry the same warning label as a cial p2r.oTduhcetifoonllouwnilnegssla(b1e)l itshseumggaetsetreidalfoisr skanmowplnestoofbaenywhmoalltyeriinanlotchuaotuhsa, sonre(v2e)r btheeendianncgoemrsmaerre limited to known hazards and appropriate cautions are submitted SAMPLE Name or Description of Product FOR EXPERIMENTAL USE ONLY CnoAtUbeTeInONfu!llyThinevecshteigmaitceadl,apnhdyistiscahlanadnldingtooxricuosloegmicaaly pbreonpaeirutiredsouosf. tEhxiesrcpirsoedduucet chearvee Whe3revTehrefeiadseibnlteit,yitosfhothueldsabme pthlee, ninamdiecaotefdthme cpoamrepnotuhnedseosr ambioxvteu,res,hoaunldd mbeaansy cclaesaer iatsshpoouslsdiblbee. the best possible identification to aid the user in knowing with what he is concerned. 4. Where there are significant known hazards they should be so indicated 5. The above label may be used m the case of old products being considered for new uses Schedule 6 SPECIMEN PRODUCT LABELS set foTrhthe ifnoltlhoiwsiMngansupaelc*i.men labels illustrate the application to specific products of the principles P rodHuaczt aCrdosmobfining Cl(aSsschI-eBdualend2)IV Chemicals TOLUENE WARNINGl FLAMMABLE Keep away from heat and open flame Use with adequate ventilation Avoid prolonged breathing of vapor Avoid piolonged or repeated contact with skin L. Mimi.'ll L-l Miimfiaurini Chemira Auocumoa ol ite Umica Sem " Schedule 3 RECOMMENDED LABEL CAUTIOUS A. B. c. D. Signal Words Hazard Precautionary Measure InstructiAoncscidiennt Case of Epoxitnret m2e0ly FFlaomrmbaeblolewffl)osh b.aFblaomvem2a0b*leto(H80a*shFp Ioncilnut c sEivxep)osure May Cause Fire or Create Fire Hazard ab. HVoiglahtliyleV(oSloaltivleent or Liquid) a DANGERI b. WARNING' e. CAUTION! a HVaazpaorrdoEuxstremely cb VMaapyorbeHaFramtaful lif Inhaled d e AVHvaaapriomlrafbulReleDdtouucrsetsBrOeatxhyingge n t NCoasueseasndIrrTithartoioant. to Eyes, Flammability a (Ksepeaprkss)waandy opf reno mDamheeat b sKweaepy fcroonmtaibneesrtd) osed (and Volatility a fKroemep ohueat to. f sun and away b Keweeepr cforommbinheeract)loueq (and Inhalation a DAavonidotbburaetahthmegvvapaopror(or) cLi.eUAdsveobirde(oapntrhloyiln)ognwgoeidfthvoaarpdroeerqpueaatte d vAevnotiidlatpioronlonged breathing of dust Contact t(on efrsessehofaierxposure remove b gHeaeveouatisrit[ianpsprreosvpeidratboyr Uor 3calBlyurfeoaro (orrsmMeineosf scpheecmifil Mgeni)cy available for emer ab CCaourrsoessive(SLeviqeureid) Bunn e Didalyn)geArobussorbBeedcaTuhsreou(gRhap d CSkaiunses Skin Irritation e May Causa Skin Irritation. a. oDno snkoint ,ge(8t )(1o)nincloeytheisn,g(,2) b rAyveosi.d(2c)onsktainc,t (w3)ithclo(t1h)ing C. eWaatisnhgthoorrosmugohkliyngbefore Ingestion n I(n1)eIamsemeodficaotenlytafcltush (skin wuotraetsee)rye(s(f)Forowrateitylheesa,sptglee1n6ttymmeidnof t(e2a)l Imatmtenedtiioante)ly wash with sc(o3loa)tphRinaengmdobvepefloearnentydrewofuassewh. ater a bPooniseosn) (akul) A cross- b Mav be Fatnl if Swallowed a Dc not tako Internally, General ab SCtornotnngctOwxiidthantCombustible Mateuol May Cause Fire a, fKoeoedppiowdauyctsfrom feed or bc SKteoerpe dinrycool piece d tKibeleen maawteaiytalfsrom enmbus sb GInetcamseediocfal amttielnagtieo,n flush c Jwoitchaspeleonftyspoifllawgaet,erabsorb with sand, oehes or oarth gTrhoeupuesde oTf haenygiwouarpnmingg more oetth/eirnsdtiactaetmesenthtolistytepde aobfovheaziasidnottopewcheiscshaugliyvelnimsittaedtemtoenthtse mhaozsat idfreuqnudeenitlwyhaicphplyit la Tcohleumsnmsabllutlertuteers/oioiiedennotitficInatteionndeodnltyo indicate a condition botween amuteily lettered statements in adjacent The parenthetical words indicate optional statements Manual L I M am iftaanoi O w aunt A ueom so of ihe U icifi S ara Product Requiring Modified Cautions and F irst A id HYDROFLUORIC ACID, AQUEOUS DANGER I CORROSIVE LIQUID VAPOR HAZARDOUS CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE Do not breathe vapor Do not get m eyes, on skin, on clothing InaImcpapmseeaerdosi,fatecploaynytiRancugtshopraskrstiiuncsupwliaciritohnatptoleefnnttciyoonnotafctotw*astkeirn unutnidl ewr hnitaeilnsessSdoaisk aafrfreivcteesd aFreluasshweiythescrwuisthhedpliecnetyino7f0%waetethryfloarlcaothloelausnt ti1l5pmhyinsiuctieasn Ibnefoarlle rceasuesse geAtvomideduicsaelofatgterenatisoyno. inRtmemenotvse and wash clothing Proprietary Product (e g . containing fluorine salts) (PROPRIETARY NAME) Contains Fluorine Compounds WARNING! POISONOUS IF TAKEN INTERNALLY Avoid breathing dust Flush spillage to sewer with water P LM-2anual PART II MANUAL L-2 -- ILLUSTRATIVE WARNING LABELS FOR HAZARDOUS CHEMICALS Adopted 1945 Revised 1946 PREFACE to coTvehristhMe asnigunailficcoannttahinaszawrdasrnininhgerleanbtelisn sauglagregsetendubmybetrheofMinadnuusfatrcitaulricnhgemCichaelmpirstosd'uActsss.ociTahtieosne pchroemduiccatsl whahviechbeisenofsecloecmtemderscoiaalsimtopoprrtoavnidcee. illIunstmraatnivye claasbeeslsthfoesreelaacbhelms aajroeratpyppleicaobflehatzoarodthouers products which are listed only in the index with appropriate cross references. few iTnhsteasnecleasb, edlso dnootniontclcuodveerpriemcapuutriiotnieasrywhinicfohrmmaatyiobnerpegreasrednint ginthtehehapnrdoldinugctsanadndst,oerxacgeeptofinthae cinognstationecrosv.erTthhee hmaaznaurdfascdtuureetrooirmppaucrkietiresshwohuilcdhinmaeyacbhecparseeseinnctluindehaornmhfiusl lqabuealnatidtideistioannda,l wwhaerrne the facts so indicate, to cover container handling and storage. aid tSreuagtgmesetnetdffoirrstotahidertrperaotdmuecntst hshaosubledennoitncilnudaendyfocrasae fbeewinptreordpurcettsedontloy. mTeahne othmaitssiitonmoafyfinrostt be desirable. incluIdneddivoinduaallabstealtourtetsh, arteagusplaetciiofnics laobrelorbdeinaaffnixceeds tmo aaycorneqtauiinreer tahsatinptahreticcuaslaerofintfhoermInatteiornstabtee CInomeamcherccaesCe,otmhme irsesqiounirRemegeunltastioofntshfeosre TlarwansssphoorutladtioanlsoofbEe xsptulodsiievde.s aTnhdeOwtahrenriDnganlgaebreolsussuAgrgteicslteesd. in this Manual should be used in addition to or in combination with any label required by law. ManuTahleLse-lla"bAelsGhuaivdee-bfeoerntphreepParreepdariantiaocncoordf aWncaernwiintgh tLhaebeplrsocfeodrurHeazoaurtdlionueds CinhePmarictaIls,."M.CT.hAe. utasienredshionulMd afnaumailliaLr-i2zetohhimisseplrfodwuitchts.Manual L-l before adapting any of the label statements con illustIrtatiisveanlatbiceilpsaaterde stuhgagtesMteadnuoarl reLv-i2siownisll abree msuapdpel.emented from time to time as additional 12 Min4/O4/i0| ChOMKi AuaowiM of ife l/nid Sacs ACETALDEHYDE DANGER1 EXTREMELY FLAM M ABLE Keep way from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Chill thoroughly before opening. CARBOV LABEL ACETIC ACID, GLACIAL DANGER! CAUSES SEVERE BURNS Do net get liquid or vapor in eyes, on skin, on clothing. In case o f contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. CARBO Y H A N D LIN G A N D STO RA G E Glacial Acetic A c id f r o at M * F , forming hard lumps which may break carboy whan moved. Store in area maintained above 6 2 'F , If froien, thaw by carefully moving carboy to warm area ALUMINUM DRUM LABEL ACETIC ACID, GLACIAL DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at feast 15 minutes; for eyes, get medical attention. DRUM H A N D LIN G A N D STO RAG E Glacial Acetic Acid freeiei et 62ep, forming hard lumps. Store m area maintained ebova 42F. If freien, thaw by moving to warm area 12 r V L M/igfaaufia Chc Ufot S-ilu BARREL labe l ACETIC ACID (80%) DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor n eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. BARREL BA N D U N G AN D STORAGE Keep out of sun and wy from heat. Store with bilge bung up. Never use pressure to empty. Drain completely. Keep berrel moist; shrinkage may M use leaks. In ease of spillage, flush with plenty of water. B A R R E L LABEL ACETIC A C ID (56% and 70%) W ARNING! M A Y CAU SE BURNS Avoid contact with eyes, skin, or clothing. In case of contact, immediately flush skin or yet with plenty of water for at least )5 minutes; for eyes, get medical attention. BARREL H A N D LIN G A N D STO RAG E (U*t tam e instructions m for Acetic Acid 80% ) BARREL LABEL ACETIC ACID (28%) CAUTION! M A Y CAU SE BU RNS Avoid contact with eyes, skin, or clothing. In ease of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention BARREL H A N D LIN G A N D STO RAG E (Ute tam e intlruclwm ai for Acetic 4cid 80% ) 13 L aM a n u *! LM-2a n u l MflU/Kit/rint O w n m -luodiijoo ol the United Ju in ACETIC ANHYDRIDE DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eye, on skin, on clothing. Do not breath vapor. In case with of of contact, immediately flush skin or eyes plenty water for at least 15 minutes; for eyes, get medical attention. ACETONE DANGER1 EXTREMELY FLAM MABLE Keep away from heat and open flame. Keep container doted. Use with adequate yentilation. A vo id prolonged or repeated contact with skin. ACETONYLACETONE CAUTION! VOLATILE SOLVENT Keep away from heat and open flame. Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. Note: Contact with this material stains the skin. ACETYL CHLORIDE DANGER! FLAMMABLE CAUSES SEVERE BURNS Do not allow water to get in container. Keep away from heat and open flame. Keep container closed. Do not get in eyes, on skin, on clothing. of Avoid exposure to In case contact, concentrated vapor. immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical aftention. 14 c r Lo MouhPrm,t Cht ACRYLONITRILE DANGER! FLAM M ABLE POISON Do not breathe vapor. Do not get in eyes, on skin, on clothing. Use with adequate yentilation. Keep away from heat and open flame. Keep container dosed. L-: ( t # POISON # FIRST A ID TREATM ENT Carry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start the following first aid treatment immediately end C A L L A PH YSIC IAN . I If patient is conscious and breathing. II) Break an amyl nitrite pearl in a cloth and hold lightly over the nose for not more than 15*20 seconds. Repeat every 5 minutes for 25 minute* ?f recovery is not forthcoming. l (2) If this product has been S W A L L O W E D , give patient one pint of 1 % Sodium Thiosulfate solution (or soapy water or mustard water) by mouth every 15 minutes until vomiting occurs. If patient has stopped breathing: G ive artificial respiration until breathing starts. Break an amyl pitrite pearl in a cloth and hold lightly over nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes or until breathing starts. If patient Is unconscious but breathing: Break an amyl nitrite pearl in a doth and hold lightly over nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes if recovery is not forthcoming. Give oxygen from an inhalator. r Never give anything by mouth to an unconscious person. In all cases ti keep patient quiet and warm until a physician arrives. IS I ALLYL ALCOHOL DANGER! RAPIDLY ABSO RBED THROUGH SK IN VAPOR EXTREMELY HAZARDOUS FLAMMABLE Do not get In eyes, on skin, on clothing. Do not breathe vapor. Keep away from heat and open flame. Keep container closed. In case of contact, immediately flush skin or eyes with plenty of water for at feast 15 minutes; for eyes, get medical attention Remove and wash clothing before re-use. Do not take internally. ALLYL CHLORIDE DANGER! HARMFUL AND FLAMMABLE Do not get in eyes, on skm, on clothing. Do not breathe vapor. Keep away from heat and open flame. Keep container closed. VAPOR carboy label A M M O N IA , AQUA W ARNING! LIQUID CA U SE S BURNS VAPOR EX TREM ELY IRRITATIN G Avoid breathing vapor. Avoid contact with eyes, skin, or clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. CARBO Y H A N D LIN G A N D STORAGE Refer* moving carboy bo ure cloture li teeuraly Loosen clenwe carefully. Keep out of sun and away from heat. Mover w e pressure to empty. Completely dram e*rboy before returning. In case o f (pillage, flush with plenty o f water. fastened. ( I( LU a d Uie United Sain AM M O N IA, AQUA W ARNING! LIQUID CAU SES BURNS VAPOR EXTREM ELY IRRITATING Avoid breathing vapor. AInvociadsecoonftaccotntwaictfh, eyes, skin, or clothing. immediately flush skin or yes attention. with plenty of water for at least for eyes, get medical 15 minutes; DRUM H A N D LIN G A N D 5T0RAG E Keep plug up to provent leakage. Keep drum out of $un and away from haat. Before removing plug, loosen slowly to relieve pressure. Never use pressure to empty. Keep Drum lights, fire and sparks away must not be washed out or from used fordrum openings. other purposes. Replace plug after each withdrawal and return with empty (n case o f spillage, flush with plenty of water. drum. CYLINDER LABEL AM M O N IA, ANHYDROUS W ARNINGS HAZARDO U S LIQUID AN D VAPOR UNDER PRESSURE LIQUID CAU SES BURNS VAPOR EXTREM ELY IRRITATIN G Do not breathe vapor. Do not get in eyes, on skin, on clothing, in case of contact, immediately flush skin and eyes with plenty of water for at feast IS minutes. Call a physician at once in case of burrs, especially to the eyes, nose and threat, or if the victim is unconscious. c y l in d e r h a n d l in g a n d s t o r a g e Keep away from heat. D o not flora in sunlight. Never drop cylinders. Be sure connections ere tight. Never refill cylinder. I C C Regulations prohibit refilling without permission of owner hr H ave gas mask approved specifically ammonia by U. S. Bureau service available of for Mines emergency. 17 L-2 Minuiwturini ChuiuHi Auoqkiob of eke Uaacd Soie A M M O N IU M BICHROMATE W ARNING! FLAM MABLE HARMFUL OUST MAY CAUSE RASH OR EXTERNAL ULCERS KEEP A W A Y FR O M HEAT, SPARKS, A N D FL A M E KEEP C O N TAIN ER C LO SED , Avoid contact with skin or eyes. Avoid breathing dust or solution spray. Do not fake infernally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes: for eyes, get medical attention Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. AM YL ACETATE CAU TIONI VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ANILINE DANGER! RAPID LY ABSO RBED VAPOR HAZARDOUS THROUGH S K IN # POISON # Do not get on skin, on clothing. Avoid breathing vapor. Use with adequate ventilation. In case o f contact, Immediately flush skin with plenty of water. Remove and wash clothing before re-use. 10 Manual L-2 o-ANISIDINE W ARNING! HAZARDOUS LIQUID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing vapor. p-ANISIDINE W ARNING! HAZARDO U S SO LID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing dust or vapor ANTIM O N Y TRICHLORIDE I DANGER1 CAU SES SEVERE BURNS VAPOR HAZARDOUS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. Keep container closed. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes: for eyes, get medical attention Remove and wash clothing before re-use. A R O M A T IC INDUSTRIAL SOLVENT (F or oli>enti having an initial boiling point not below 100 C. find' having a flash point 80*P. or BELOW, Tngliabue Open Cup Method at specified by Interstate Commerce Committiotu) W ARNING! FLAM M ABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ML.2tnul bltnuhwjiin Q uain A uogttia ol (lit Uoucd S u ARO M ATIC INDUSTRIAL SOLVENT (lFaothr tpoolvinent iAt hBaOvVinEg o8n0*iFni.,tiaTlabgaliulbinugepOoipnetnnoCtubpelMowet1h0o0dnCa, atnpdechtfaiveidngbay Interkite Commerce CammUsion) CAUTION! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ARSENIC TRICHLORIDE DANGERl CORROSIVE LIQUID VAPOR EXTREMELY HAZARDOUS % POISON Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep container closed. in case of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medieal attention. Remove and wash clothing before re-use. BARIUM NITRATE CAUTION! STRONG O XIDAN T CONTACT W ITH CO M BUSTIBLE M A T ER IA L M A Y CAU SE FIRE Keep container closed and away from combustible material and heat. Sweep up and carefully remove spiled material Avoid repeated contact with skin. D o not take internally. 20 ( 1( M touUqurlat O ieaitti Auoctuiea o< (he Ui Suit L-i BARIUM OXIDE CAUTION! M AY CAU SE SK IN IRRITATION Avoid contact with skin. Keep away from feed or food products. Do not take internally. BARIUM PEROXIDE CAUTION! STRONG OXIDANT CONTACT WITH CO M BUSTIBLE M ATERIAL M AY CA U SE FIRE Keep container closed and away from combustible material and heat. Sweep up and carefully remove spiled material. Avoid contact with skin. Do not take internally. BENZENE (BENZOL) DANGER! EXTREMELY FLAMMABLE VAPOR H ARM FUL -- POISON Keep away from heat and open flame. Keep container closed. Use with adequate ventilation Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. BENZIDINE W ARN IN G ! H AZAR DO U S SOLID A N D VAPOR RAPIDLY ABSORBED THROUGH SKIN Avoid breathing dust or vapor. Avoid contact with skin. In case of contact, immediately wesh with soap and plenty of water. 2i w*" 1 M m uA nvnnc U ieiutu Aiwcmiop al he Ueud S om CARBOY LABEL BENZOYL CHLORIDE W ARNING] CAU SES BURNS VAPOR IRRITATIN G Avoid contact with item or eye. Avoid in case breathing vapor. of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. C A R B O Y H A N D LIN G A N D STO RAG E Bator moving carboy be iur cloture It ucuroty fastened. Loosen cloture carefully. Keep out o f sun and away from heat. Never use pressure to empty. ; Completely drain carboy before returning In case of spillage, flush with plenty o f water. CARBOY LABEL BENZYL CHLORIDE W ARNING! CA U SES BURNS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. In case of contact with liquid, immediately wash o f skin with soap and plenty water; flush eyes with for weter at least )5 minutes and get medical * attention. Do not transfer to ordinary metal containers without first adding stabilizer. Get instructions from manufacturer. flR l/A f LABEL BENZYL CHLORIDE W ARNING! CA U SES BURNS Avoid contact with eyes, skin, or clothing. Avoid in case ofbreathing vapor, contact with liquid, immediately wash skin with soap and plenty of water; flush eyes with weter for at least 15 minutes and get medical attention The Benzyl Chloride in this drum contains e stabilizer. Before transferring, get instructions from manufacturer. 22 r / QM Aitcam ii ibe Uonci Sana BROMINE DANGER! CAUSES SEVERE BURNS Do not get on skin or in eyes. Do not breathe vapor. in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; keep skin area wet with crushed ice in 7 0 % ethyl alcohol until physician arrives. BUTYL ACETATE (normal) CAU TIO N I VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. BUTYL ALCOHOL (normal or secondary) CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. BUTYL ALCOHOL (tertiary) W ARNING! FLAM MABLE Keep away from heat end open flame. Keep container closed. U se w ith ad eq u ate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 23 LM-3anu) MI.-2inuti Muuiiamm Cbcffutfa ioa of iSc Uautd Sum BUTYLAMINE (normal) W ARNING: FLAM M ABLE M A Y CAU SE SK IN IRRITATION Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin or eyes. In case of contact, immediately flush skin or eyes with plenty of water for at feast 15 minutes; for eyes, get medical attention. p-tert. BUTYLCATECHOL W ARNING! CA U SES SK IN IRRITATION CA U SES BU RN S W HEN MOIST Do not get in eyes, on skin, on clothing. In case of contact, immediately wash slnn with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. BUTYL CHLORIDE (normal) DANGER! EXTREMELY FLAMMARLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. BUTYL ETHER (normal) W ARNING] VO LATILE SOLVENT Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin C A U T IO N : Dry ethers tend to form explosive peroxides. Do not use materia) if it liberates iodine from acidified aqueous iodide solutions 24 C (' ' ` o Cfctiaitt M iniai CALCIUM CYANIDE DANGER! LIBER A TES POISONOUS G AS Avoid breathing gas or dust. Avoid contact with skin. Keep away from acids. Store away from feed or food products. Keep container tightly closed and dry. p o is o n FIRST A ID TREATM ENT (Ve am Jint aid treatment at recommended for inorganic Cyantdet) CARBON DISULFIDE DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE ^ POISON ^ Keep away from fire, sparks, or heated surfaces. Store in cool place and keep container closed, Avoid breathing vapor. Avoid contact with skin. CARBON TETRACHLORIDE W ARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLORINATED NAPHTHALENE Avoid repeated contact with skin. Avoid repeated inhalation of the fumes and dust. 25 MHtnui CAUSTIC SO DA (SODIUM HYDROXIDE) W ARNING! CAUSTIC SO D A IS CORROSIVE BURNS SKIN AND EYES Avoid contact with body Of clothing. Do not take internally. P R E C A U T IO N S When handling Sodium Hydroxide wear goggles or face shield and avoid all contact with skin. While making solutions, add Sodium Hydroxide slowly to surface of solution to avoid violent Spattering In Case of accidental contact with skin, immediately flush affected parts with water and wash with vinegar. For eyes, flush freely with water for at least 15 minutes and get medical attention. m THE C.4SE OF P RCOAPVRSITEITCA RAYL KCAOLIM: POUNDS CONTAINING l ) Name of Product W ARN IN G I CO NTAINS CA U ST IC A L K A L I W HICH IS C O R R O SIV E BURNS SKIN A N D EYES Avoid contact with body or clothing. Do not take internally. P R E C A U T IO N S (V*e tame precaution* at for Sodium Hydroxide, HlbllllllUng name of product for Sodium Hydroxide.) CHLOROBENZENE, M O NO W ARNING! VAPOR HARM FUL Use with adequate ventilation. Avoid contact with skin or clothing. Avoid prolonged breathing of vapor. ni dw U dntd S aia Miaut CHLOROFORM W ARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLOROTOLUENE, M O NO CAUTION! VAPOR HARM FUL Use with adequate ventilation. Avoid prolonged breathing of vapor. CHROMIC ACID W ARN IN G ! CO NTACT W ITH CO M BUSTIBLE M A T E R IA L M A Y CA U SE FIRE CAUSES SEVERE BURNS KEEP C O N T A IN ER CLOSED. Avoid contact with skin or eyes. Avoid breathing dust or solution spray. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. COAL TAR CREOSOTE (CREOSOTE OIL) CAUTION! M A Y CAU SE SK IN IRRITATION U Use only with adequate ventilation. Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of vapor. ML-a2nual M tnv/iaunni O icm la AunriuioA nf die (failed S ato CYANIDES, INORGANIC (excluding Liquid Hydrocyanic Aetd and Calcium Cyanide) Name of Product DANGER! CONTACT W ITH A CID LIBER ATES POISONOUS G A S Avoid breathing gas or dust. Avoid contact with skin. Keep away from feed or food products. Keep container closed and store in a dry place. ^ POISON ^ FIRST A ID TREATM ENT Carry patient to fresh air, Have him lie down. Remove contaminated clothing but keep patient warm. Start the following first aid treatment immediately and C A L L A P H YSIC IAN . If patient is conscious and breathing: (1) Break an amyl nitrite pearl in a cloth and hold lightly over the nose for not minute* imf orreecotvhearny 1is5-n2o0t seconds. Repeat forthcoming. every 5 minutes for 25 (2) If this product has been S W A L L O W E D give patient one pint of 1 % Sodium Thiosulfate solution (or soapy water or mustard water) by mouth every 15 minutes until vomiting occurs. (Eliminate this for liquid HCN }. If patient has stopped breathing; Give artificial respiration until breathing starts. Break an amyl nitrite pearl in a cloth and hold lightly over nose for not mora than 20 sec* onds, repeating overy 5 minutes for 25 minutes or until breathing starts. If patient is unconscious but breathing: Break an amyl nitrite pearl in a cloth and hold lightly ovor nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes if recovery is not forthcoming. Give oxygen from an mhalator. Never give anything by mouth to an unconscious person In all eases keep patient quiet and warm until a physician arrives. 28 ( I( I C 0 t- o Chemin, Amoouim </ the to n e d S um CRESOL (CRESYLIC ACID) DANGERI RAPID LY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get on slcin or in eyes. Do net breathe vapor. Do net take internally. In ease of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-usa. CYCLOHEXANE DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. CYCLOHEXANOL CAUTION! VAPOR HARM FUL Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. DICHLOROETHYLENE W ARNING! FLAM MABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. 29 Manual L-2 Mtnu/scianoi AuoaUiofl o d,c tfa/icd Satei DICHLOROETHYL ETHER W ARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take Internally. DICHLOROPHENOL (For nil itomerlo dichUirophenols) W ARNING! M A Y CA U SE BURNS Avoid contact with sltm. Avoid breathing vapor. Do not take internally. In case of contact, immediately wash with soap and plenty of water. DIETHYLAMINE DANGER! EXTREMELY FLAMMABLE M AY CAU SE S K IN IRRITATION Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin or eyes. In ease of contact, immediately flush skin or eyes wifh plenty of water for at least 15 minutes,* for eyes, gat medical attention. 30 {aW icwciat Chnuiii Autamaa et tir Danni Sam Manual L.J D IO X A N E (1,4-DIETHYLENE DIOXIDE) W ARNING! FLAM MABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. C A U T IO N ! Dry ethers tend to form explosive peroxides. Do not use material if it liberates Iodine from acidified aqueous iodide solutions. ETHYL ACETATE W ARNING! FLAM M ABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ETHYL BROMIDE W ARNING! VAPOR HARMFUL Use with adequate ventilation Avoid prolonged breathing of vapor. Keep out of sun and away from heat. Keep container closed. ETHYL CHLORIDE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. U$e With ad eq uate ventilation Keep container closed, out of sun and away from heat. ML-anual Mmaf.cwnlni Q um nq AiianMiaa ai rkt UautJ S u is ETHYLENE CHLOROHYDRIN DANGERS RAPIDLY A BSO RBED THROUGH SK IN VAPOR EXTREMELY HAZARDOUS Do not gat on skin or clothing. Do not breaths vapor. Do not taka internally. In case of contact, immediately wash with soap and . plenty of water; remove ana wash clothing before re-use. POISON ^ FIRST A ID TREATM ENT If swallowed, make patient vomit immediately (finger down throat) or giva warm mustard water or salt water freely. General: Keep patient warm; if conscious give black coffee. Call physician. Note: Do not give adrenalin. ETHYLENE DIBROMIDE W ARNING! VAPO R HARM FUL Avoid breathing vapor. Avoid contact with eyes, skin, or clothing, 1n ease of contact, immediately wash skin with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. Remove and wash clothing before re-use. Do not take internally. ETHYLENE DICHLORIDE W ARNING! FLAM M ABLE VOLATILE SOLVENT VAPOR HARMFUL Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. 32 ( I I uC Muiuiiogun* Chtmiu Altounina at ibt (.mod taie* Xinaol L-Z ETHYLENE GLYCOL MONOMETHYL ETHER CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ETHYL ETHER DANGER! EXTREMELY FLAMMABLE HIG H LY VOLATILE Keep away from heat and open flame. Keep container tightly closed. C A U T IO N ! Dry ethers tend to form explosive peroxides. D o not use material if it liberates iodine from acidified aqueous iodide solutions. ETHYL FORMATE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of yapor. ETHYL METHACRYLATE MONOMER W ARNINGI FLAMMABLE Keap away from heat and open flama. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid contact with skin or clothing. 33 LM-Jinuti chi Henni Sexes FORMALDEHYDE W ARNING! CAU SES IR RIT ATIO N OF SKIN, EYES, NOSE AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. POISON ^ CALL A PH YSICIAN AT ONCE FIRST A ID InternaNy: Give milk freely, or one glassful of water containing I table spoonful of ammonium acetate. Produce vomiting with a pint or more of warm salt water (I cupful per quart) or warm soapy water. Repeat three times. Follow with milk end raw eggs. BARREL LABEL FORMIC A CID W ARNING! CA U SES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. BARREL H A N D LIN G A N D STO RA G E Keep out of sun and away from heat. Store with bilge bung up. Never use pressure to empty. Drain completely Keep berrel moist; shrinkage m ay cause leaks In case of spillage, flush wtfh plenty o f wafer. 34 oG Chcnli of the UsmH Saia CARBOY LABEL FORMIC ACID W ARNING! CAU SES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In case o f contact, Im m ediately flush skin o r eyes w ith plenty o f w ater fo r a t least 15 minutes; for eyes, get medical attention CARBO Y H A N D U N G A N D STORAGE Before moving carboy be sure closure Is securely fastened Keep out of sun and away from heat N e var use pressure to empty Completely drain carboy before returning In case of spillage, flush with plenty of water. CARBOY LABEL HYDROCHLORIC ACID W ARNINGI CAUSES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention CARBO Y H A N 01IN G AN D STORAGE Before moving carboy, be sure closure Is securely fastened. Loosen closure carefully. Keep out of sun and away from heat Ne ve r use pressure to empty. Completely drain carboy before returning In case of spillege, flush with plenty of water. 35 1M2anual [ ^ 1 j ' j > i j I I 1 I t LM-thu*l Mvtuiinoclai CbtiDtKi Atuouion HYDROCYANIC ACID, LIQUID DANGER! PO ISON G AS Do not breathe gas, Avoid contact with stein. Do not drop container. Keep cool and away from open flame. # POISON # FIRST A ID TREATM ENT (Vie tame first atd treatment its recommended for inorganic Cyanide) HYDROGEN PEROXIDE (stronger than 25 volume and not exceeding 130 volume) CAUTION! STRONG O XIDANT Avoid contact with eyas or skin-- wear goggles and rubber gloves. Avoid contact with combustible materials. Drying of this concentrated product on clothing or other combustible materials may cause fire. In case of contact, Immediately flush slun or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Avoid contamination from any source, including metals, dust, etc. Such contamination may cause rapid decomposition, generation of farge quantities of oxygen gas, and high pressures. CO N TAIN ER H A N D LIN G A N D STORAGE SKtotirpe in original out o f run dosed container. and away from heat. 1 sure that the container vent rs working satisfactorily. D o not ad d any other product to this container W han empty, rinse thoroughly with dean water. 36 i I ( ! t ( O (J MMu/icnir.ai Qtcmint HYDROGEN PEROXIDE (25 volume) CAUTION! STRONG OXIDANT Avoid contaet with eyes or skin-wear goggles and rubber gloves. Avoid contamination from any source, including metals, dust, etc. Such contamination may cause rapid de composition, generation of large quantities of oxygen gas, and high pressures CO N TA IN ER H A N D LIN G A N D STORAGE ' S to re in origins) d o s e d c o n tain er Be sure that the container vent is working satisfactorily. Do not add any other product to this container W h e n empty, rime thoroughly with clean watar. ML i2niiaJ HYDROFLUORIC ACID, AQUEOUS DANGER! CORROSIVE LIQUID VAPOR HAZARDOUS CA U SES SEVERE BU RNS W HICH M A Y NOT BE IM M ED IATELY PAINFUL OR VISIBLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. In ease of contact or suspicion of contact: Immediately flush skin with plenty of water until whiteness disappears, paying particular attention to jkm under nails. Soak affected areas with crushed ice n 7 0 % ethyl alcohol until physician arrives Flush eyes wHh plenty of water for at least 15 minutes In all cases get medical attention Remove and wadi clothing before re-use. Avoid use of greasy ointments. 37 LM-aaual ofikeCJautd Sat LEAD ACETATE W ARNING! HARM FUL DUST Avoid breathing dust. W ear dust mask approved by U. S. Bureau of Mines for this purpose. W ash thoroughly before eating or smoking. Keep away from feed or food produets. MALEIC ANHYDRIDE W ARNING! CAU SES BURNS Avoid contact with eyes, skin, or clothing Avoid exposure to concentrated vapor In case of contact, immediately flush skin or eyes with plenty of water for at (east 15 minutes; for eyes, get medieal attention. MERCURY BICHLORIDE (MERCURIC CHLORIDE) DANGER! M A Y BE FATAL IF SW ALLOW ED POISON Do not breathe dust. Keep away from feed or food products. W ash thoroughly before eating or smoking. Use fresh clothing daily. Take hot shower after work using plenty of soap. METHYL n-AMYL KETONE CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin sa ( I Cln.itd METHYL BROMIDE DANGER! HIGHLY VOLATILE CAUSES BURNS VAPOR EXTREMELY HAZARDOUS Keep away from heat. Keep container closed. Avoid breathing vapor. Avoid contact with skin, eyes, or clothing. ON CAN LABEL ADD: # POISON #<?S FIRST. A ID Remove to fresh air. Keep lying down and warm. Use artificial respiration if breathing has stopped. Get immediate medical attention. Oxygen mhalator should be used only at the direction of a physician. C A U T IO N 1 The contents of this can are under pressure. Do not use ordinary can opener. Special handling equipment Is available. Contact ( . _ ) for Name of Manufacturer information on equipment and proper use. METHYLENE CHLORIDE CAUTION! VOLATILE SOLVENT Ueo with adequate ventilation. Avoid prolonged' or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. 3? Mh ai rniti nf ih linieri Sarti METHYL ETHYL KETONE W ARNING! FLAM M ABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. U$e with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. METHYL METHACRYLATE MONOMER W ARNING) FLAM M ABLE M A V CAU SE SK IN IRRITATIO N Keep away from heat and open flame. Keep container closed. Usa with adequate ventilation. Avoid prolonged breathing of vapor. Avoid contact with skin or clothing. METHYL iso-PROPYL KETONE W ARNING! FLAM M ABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 40 ( i j 1 j O O Otcnuio A w u< ie6 ih< L nnri S am C ^ltBO y LABEL MIXED ACID (Sulfuric and Nitric) DANGER! CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CAU SE NITRO US G A S POISONING Do not breathe vapor. Do not get in eyas, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention c a r b o y h a n d l in g a n d st o r a g e Before moving carboy bo turo datura U ttcurobf iattentd Loosen cloture carefully. Keep out o f sun and away from heat. N ever use pressure to empty. Completely drain carboy before returning. In cast of spillage, flush with plenty of water. f(oUrn dmeirx eld Ca.ciCd . cRoengtauilnaitniogn !n oc(a rmb oayre at hr e a n p e1r7m%U nNbilter i c hAipvpidin g a ncdo nat t a i ner feast water.) ORUiU LABEL MIXED ACID (Sulfuric and Nitric) DANGER! CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CAU SE NITROUS G A S POISONING Do not breathe vapor. Do rot gat in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. DRUM H A N D LIN G A N D STO RAG E Keep plug up to prevent leakage. Keep drum out of sun and away from heat. Relieve internal pressure when received and at least weekly thereafter by slowly loosening plug. Ret'ghten Immediately. Never use pressure to empty Keep lights, fire and sparks away from drum openings. Drum must not be washed out or used for other Replace plug after each withdrawal and return purposes. with empty drum. In case of spillage, flush with plenty of water. 41 ML-2anali Manual L-J Miu/tniln| Oku AtlMNivi) uf th* Uniicd Suie MORPHOLINE W ARNING! HAZARDO U S LIQ UID AN D VAPOR M A Y CAU SE SK IN IRRITATION Use with adequate ventilation. Avoid exposure to vapor. Avoid confect with slim or eyes. b-NAPHTHYLAMINE CAUTION! CONTENTS HARM FU L REPEATED ABSORPTION IN BL A D D E R TU M O RS MAY RESULT Avoid breathing dust or vapor. Avoid contact with skin. Do not take internally. t.ARBOY LABEL DANGER! NITRIC ACID CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CA U SE N ITRO U S G A S POISONING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of wafer for at least 15 minutes! get medical attention. C A R BO Y H A N D LIN G A N D STORAGE Before moving carboy bo sure cloture Is securely foster*! Looser closure carefully Keep out of sun end away from heat Never use pressure to empty Completely drain carboy before returning In case of spillage, flush with plenty of water 42 ! ; ( * ^ J United Sait Manu' DRUM LABEL DANGER! NITRIC ACID CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CAU SE NITROUS G A S PO ISONING Do not braatha vapor. Do not get in eyes, on skin, on clothing. In ease of contact, immediately flush skin or ayes with plenty of water for at least 15 minutes; get medical attention. DRUM H A N D LIN G A N D STORAGE Keep plug up to prevent leaU gs. Keep drum out at tun end away from heat. Relieve internal pressure when received and et least weekly thereafter by slowly loosening plug Retlghten Immediately Never use pressure to empty Keep light!, fire and sparks away from drum openings. Drum must not ba washed out or used for other purposes. Replace plug after each withdrawal and return with empty drum In ease of spillage, flush with plenty of water. m-NITROANILINE W ARNING! HARM UL BECAUSE ABSORBED THROUGH SKIN Avoid contact with skm. Avoid breathing dust. In case of contact, immediately wash thoroughly with soap and plenty of water; remove and wash clothing before re-use. NITROPHENOL, M O N O W ARNING! M A Y BE ABSORBED THROUGH Avoid breathing dust. Avoid contact with skin. In case of contact, immediately wash with soap and plenty of water. S K IN 43 Marnili L-l M muhautlfti Chm im A uaium n U ii< Uniirl iuici DRfJM LABEL OLEUM DANGER! CAUSES SEVERE BURNS Avoid breathing vapor. Do not get in eyas, on skin, on clothing, in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. Do not add water to contents while in a container because of violent reaction. DRUM H A N D LIN G A N D STO RAG E Keep plug up to prevent leakage. Keep drum out of tun in d away from heel. Relieve internal pretture when received end et least weekly thereafter b y tlowJy loosening plug. Retighten Immediately. Never use pressure to empty. Keep lights, fire end sparks away from drum openings. Drum must not be washed out or used for other purposes. Replace plug after each withdrawal and return with empty drum. In case ot spillage, flush with plenty of water. I , \j ^r'J\ , \ J^ OXALIC ACID W ARN IN G ! H ARM FUL IF T A K E N IN T ERN A LLY CAU SES SK IN IRRITATIO N Avoid breathing dust. Avoid contact with skin. in casa of contact, immediately flush with plenty of water. Do not take internally. Keep away from feed or food products. PARALDEHYDE CAUTION! VAPO R HARM FU L Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Do not take internally. Solidifies at about 54 r. (I2 `C.) and may break container. Store in a moderately Wttftn place. Oo Manulidurini Oit iim<4 Suie PENTACHLOROPHENOL W ARNINGI HARM FUL DUST Avoid breathing dust. Avoid contact with skin or clothing. In case of contact with dry materiel or its solution, wash at once with soap and plenty of water. Do not take internaly. M inu ti L 2 PENTACHLOROPHENOL, OIL SOLUTIONS OF CAUTIONI CA U SES SK IN IRRITATION ABSORBED THROUGH SKIN Avoid breathing vapor. Avoid eontaet with skin or clothing. In ease of contact with skin, wash at once with plenty of soap and warm water. Do not take Internally. See instructions for use before handling. PETROLEUM NAPHTHAS A N D SOLVENTS, INDUSTRIAL (For solvents having a flash paint 20 'F, or BELOW, Tngllabue Open Cup Method at specified by interstate Commerce Commission) Name of Product DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 45 Manu! Minili* L- PETROLEUM NAPHTHAS A N D SOLVENTS, INDUSTRIAL (For solvent having a /lath point ABOVE 20P. but not above 800 F., Tagiiabue Open Cup M ethod ns specified b f Interstate Commerce Commission) Name of Product W ARNING! FLAM M ABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PETROLEUM NAPHTHAS A N D SOLVENTS, INDUSTRIAL (For solventi having a flaih point ABOVE 60F., Tagiiabue Open Cup M ethod a* specified by intentate C om m erce C om m ission) Name of Product CAUTION! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. p-PHENETIDINE CAUTION! H AZAR DO U S LIQ U ID AN D VAPO R ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing vapor 46 ( i i i, OO o Ml^[0.ncn Cktt UaicW Saia DANCER! PHENOL RAPIDLY ABSORBED THROUGH CAUSES SEVERE BURNS S K IN POISON ^ Do not get on skin or in eyes. Avoid breathing vapor. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use, p-PHENYLENEDIAMINE CAUTION! M A Y CAU SE SK IN IRRITATION Avoid breathing or contact with dust. CARBOY LABEL PHOSPHORIC ACID CAUTION! CA U SES SK IN IR RIT ATIO N Avoid contact with skin or eyes, in cate of contact, immediately flush skin or eyes with plenty of water for at least 16 minutes; for eyes, get medical attention. C ARBO Y H A N D LIN G A N D STORAGE Before moving carboy be sure closure is securely fastened. Loosen closure carefully Keep out of sun and away from heat. Never use pressure to empty Completely drain carboy before returning. In cate of spillage, flush with plenty of woter, 47 Manul I 2 PHOSPHORIC ANHYDRIDE W ARNING! CA U SES BURNS Avoid contact with skin or eyes. When using, protect eyes with goggles and wear In ease rubber gloves. of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. Open carafglly. PHOSPHORUS DANGER! CAUSES SEVERE BURNS ^ POISON Contents packed under water and will ignite if water is removed. Keep drum out of sun and away from heat. Do not get on skin or in eyes. Protect eyes with goggles or face shield and wear heavy rubber gloves. In ease of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; keep skin area wet until medical attention is obtained. PHOSPHORUS PENTACHLORIDE W ARNINGI H AZARDO U S DUST CAUSES BURNS Do not breathe dust. Do not get on skin or in eyes. Protect eyes with goggles and wear rubber gloves. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. Open carefully. 49 { O O lM- lanual PHOSPHORUS OXYCHLORIDE DANGER] CAUSES SEVERE BURNS VAPOR EXTREM ELY IRRITATIN G Do not breathe vapor. Do not get on skin or in eyes. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. CONfAiNER HAN0UN6 AND SrORASE D o not open unless you have been instructed in the proper manner, Never use pressure to empty Do not use this container for any other product In ease of spillage, flood carefully with L A R G E V O L U M E of water end provide adequate ventilation iso-PROPYL ACETATE W ARNING! FLAM MABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PYRIDINE W ARNING! FLAM MABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. 49 i SAMPLE* i Name or Description of Product FOR EXPERIM ENTAL USE ONLY C A U T IO N ! The chemical, physical and toxicological properties of this product have not been fully investigated and its handling or use may be hazardous. Exercise due care. *St*e M.C.A. Manual H . SILVER NITRATE W ARNING! CA U SES BU RNS POISON ^ Stains skin. Do not gat on skin or in eyes. in case of contact with eyes, get medical attention. SODIUM CHLORATE W ARNING! CONTACT W ITH COMBUSTIBLE M A T E R IA L M A Y CA U SE FIRE All clothing contaminated with chlorates s D A N G E R O U SL Y FLA M M A B LE . Remove and wash thoroughly with water. Do not get on floor. Spillage may cause fires with combustible material. Sweep up and remove Immediately. When not in use keep tightly closed in original metal container. Keep away from fire. Store separately from flammable material. FOR PACKAGES OF AGRICULTURAL CHLORATES, ADD: Keep Animals O ff Freshly Treated Areas The label must be securely affixed to the exterior of each package. Litho graphed or tram fer label are preferred. 50 1 i l Oo Mu>uI*cftflA| Owmias A ustin Manuil L 2 SODIUM BICHROMATE W ARNING! HARM FUL DUST MAY CAUSE RASH OR EXTERNAL ULCERS KEEP C O N TAIN ER CLOSED. Avoid breathing dust or solution spray. Avoid contact with skin or eyes. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. SODIUM FLUORIDE W ARNING! POISONOUS IF TAKEN INTERNALLY Avoid breathing dust. Rush spillage to sewer with water. DIRISCTLHOESUCRAESEISONFOPTRMOAPDREIEOTANRTYH ECOLMAPBOEUL,NDS W HERE FORMULA Name of Product Contains Fluorine Compounds W ARN IN G ! PO ISO NO U S IF TA K E N IN TERN ALLY Avoid breathing dust. Flush spilage to sewer with water. NO TE, Aarlle iancourtgealynitcoxfliucotroinme ncnomihpoouulnddbetoclodlofroerd.intectktdal use which SODIUM HYDROSULFITE CA U TIO N I SUBJECT TO FIRE IF ALLOW ED TO BECOME DAMP Keep container tightly closed. Use only dry, clean utensils in handling Store in a cool, dry place. 51 MmuU M iiuhauim f CkcauBt Anoclsrion of the United Sacci SODIUM SULFIDE (Granular] DANGER! CONTACT W ITH A C ID LIBER A TES POISONOUS G A S BURNS SKIN AND EYES FLAMMABLE EXPOSURE M A Y CAU SE FIRE OR CREATE FIRE H A ZA R D Avoid breathing dust. Avoid contact with skin and eyes. Keep container closed and away from acids, com* bustible materia! and heat. Sweep up spillage. Do not flush to sewer which may contain acid. STYRENE M O NO M ER W ARNING! VAPOR H A RM FU L Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. DRUM LABEL SULFUR CHLORIDE DANGER! CAUSES BURNS VAPOR IRRITATIN G Avoid contact with eyes, skin, or clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. DRU M H A N D LIN G A N D ST O RA G E Keep plug up to prevent leakage. Keep drum out or sun end away from heat. RaFlav# internal pressure when received and et least weekly thereafter by slowly lessening plug ReKghten immediately Never use pressure to empty Keep lights, fire and sparks away from drum openings Drum must not ba washed out or used for other purposes Replace plug after each withdrawal and return with empty drum In case of spillage, flush with L A R G E V O L U M E of wafer. S2 ( . o MiuifKiM,e| Qiaid United CARBOY LABEL SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do net get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. CARBO Y H A N D LIN G A N D STORAGE Before moving carboy be sure closure is securely fastened. Loosen closure carefully. Keep out o f sun end away from heat, Naver use pressure to empty. Completely drein carboy before returning. In case of spillege, flush with plenty o f water _____________________ DRUM LABEL SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do not get n eyes, on skin, on clothing, in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, gat medical attention. Do not add water to contents white in a container because of violent reaction. DRUM H A N D LIN G A N D STO RAG E Keep plug up to prevent leakage. Keep drum out of sun end away from heat Relieve internal pressure whan received end et least weekly theraaftar by slowly loosening plug. Retighten Immediately. Never use pressure to empty. Keep lights, the and sparks away from drum openings. Drum must not be washed out or used for other purposes. Raplace plug after each withdrawal and return with empty drum. In case of spillage, flush with plenty of water. 53 LM-2i n a i ML-aanual 'C C htsum Altoat Vttiifi S o ra SULFUR DIOXIDE (Under Pressure) W ARNING! EXTREM ELY IR RIT A TIN G G A S A N D LIQ U ID Avoid breathing gas. Do not drop cylinder. Do not allow cylinder temperature to reach I30'F. TETRACHLOROETHANE DANCER! VAPOR EXTREMELY HAZARDOUS VOLATILE LIQUID POISON ^ Use only in completely enclosed system. Do not breathe vapor. D o not get on skin or clothing. Do not take internally. TETRACHLOROETHYLENE (PERCHLORETHYLENE) W A RN IN G l VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. TOLUENE (TOLUOL) W ARNING! FLAM MABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 54 ( !i O O ! *dai Chtiaixi Auodauoa ML-a2naal m-TOLUIDINE W ARNINGl HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SK IN Avoid contact with skin and clothing. D o not breathe vapor Use with adequate ventilation. In ease of contact, immediately wash thoroughly with soap and plenty of water; remove and wash clothing before re-use. TRICHLOROETHYLENE W ARNINO! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor Avoid prolonged or repeated contact with skin. D o not take Internally. TRICHLOROPHENOL (For all isomeric Trichoraphenols) CAUTION! M A Y CAU SE SK IN IRRITATION Avoid prolonged or repeated contact. Do not take internally. VINYL CHLORIDE DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor 55 MtRQ) L-2 M inljctu(if| Cbcffliui A uedKian oi ih U w iri S um XYLENE (XYLOL) W ARNING! FLAM M ABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation, Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ZINC CHLORIDE (Granular, Fused or Solution) CAUTION! M A Y CAU SE SK IN IRRITATIO N Avoid prolonged or repeated contact. 54 ( ( o o u o M i^ .a u n n i Cherniy. o u ,! of chc U onrt Sutn MANUAL L>2 INDEX Many of the product lifted in thu index do not appear specifically m the Jn6el listings. The labels applicable to tuch products are indicated by the crott-reference " i./.n." (sam e label ai-- ) . ML-at ru il Acetaldehyde Acetic Acid Glacial Carboy Drum 80% 5 6 % and 7 0 % 28% Acetic Anhyride Acetone Acetonylacetone Acetyl Chloride Acrylonitrile Aliyl Alcohol Ally! Chloride Ammonia, Anhydrous Aqua Carboy Drum Ammonium Bichromate Ammonium Hydroxide-- See Ammonia, Aqua Amyl Acetate Aniline O'Armidine p-Anisidine Antimony Trichloride Aromatic Industrial Solvent Arsenic Trichloride . -- B-- Barium Hydroxide-- s.la. Barium Oxide Barium Nitrate Barium Oxide Barium Peroxide Benzene . 57 12 12 . 12 _ 13 (3 13 14 14 14 14 15 16 16 . 1176 18 16-17 . 18 . 18 19 19 19 19-20 20 21 20 21 21 21 Minai] L*2 Mmufutufifn Chnitu Auomiton ol rt* fiutd Suif Benzidine 21 Benzol-- See Benzene . . 21 Benzoyl Chloride 22 Benzyl Chloride Carboy 22 Drum 22 Bichloride of Mereury-r-See Mercury Bichloride 36 Bichromates-- See Sodium Bichromate 51 Bromine 23 Butyl Acetate (Normal) 23 Butyl Alcohol Normal or Secondary 23 Tertiary 23 Butylamine (Normal) 24 P'tert, Butylcatechol 24 Butyl Chloride (Normal) 24 Butyl Ether (Normal) 24 Butylidene Acetone-- s.I.a. Butyl Acetate 23 Butyraldhyde-- s.I.a. Ethyl Acetate ' 31 -- C-- Calcium Cyanide 25 Carbon Disulfide 25 Carbon Caustic -- s 1 Tetrachloride Potash a. Caustic Soda 25 26 Caustic Soda 26 Chlorinated Diphenyl-- s.I.a. Chlorinated Naphthalene 25 Chlorinated Diphenyl Oxide-- s.I.a, Chlorinated Naphthalene 25 Chlorinated Naphthalene . 25 Chlorobenzene, Mono 26 Chloroform 26 Chlorophenol, Mono, Ortho, Meta, or Para-- s.I.a. Phenol 47 Chlorotoluene, Mono 27 Chromates and Bichromates of Sodium end Potassium See Sodium Bichromate 51 Chromic Acid 27 Coal Ter Creosote 27 Corrosive Sublimate-- See Mercury Bichloride 38 Creosote O il- S e e Coal Tar Creosote Cresol 2297 Cresylic Acid-- See Cresol 29 Cyanides, Inorganic 28 Cyclohexane 29 5 Go * (\ K'iiuf Cyelohexanol Cyclohexanone-- s.l a. Cyelohexanol -- D-- Diacetone Alcohol-- s.I.a. Ethyl Acetate Dichloroethylene Dichloroethyl Ether Dichlorophenol Diethylamine f,4-Diefhylene Dioxide-- See Dioxane Diethylenetriemine-- s.I.a. Morpholine Diisobutyl Ketone-- s.I.a. Butyl Acetate Dimethylanilme-- s.I.a. Aniline Dioxane Dipropyl Ketone-- $.l.a. Butyl Acetate ---CE-- Ethyl Acetate Ethyl Acetoacetate-- s.I.a. Butyl Acetate Ethyl Bromide Ethyl Butanol-- s.I.a. Butyl Acetate Z-Ethyibutyl Acetate-- s.I.a. Butyl Acetate 2*Ethylbutyra!dehyde-- s.l.a. Ethyl Acetate Ethyl Chloride Ethylene Chlorohydrin Ethylenediamine-- s.I.a. Morpholine Ethylene Dibromide Ethylene Dichloride Ethylene Glycol Monomethyl Ether Ethyl Ether Ethyl Formate 2-Ethyihexanol-- s.I.a. Butyl Acetate 2-Ethylhexyl Acetate-- s l.a. Butyl Acetate Ethyl Methacrylate Monomer Formaldehyde Formic Acid Barrel Carboy -- F-- 59 Mmul L 2 29 29 31 29 30 30 30 31 42 23 18 31 23 31 23 31 23 23 3t 31 32 42 32 32 33 33 33 23 23 33 34 34 _ 35 MtQual u iiau n tif Chemin, itrinn ni At tlcied $! -- G-- Glycol Diacetate-- *J.a Butyl Acetate Glycol Diformate-- s.I.a. Butyl Acetate -- H-- Heptanoi-2-- j.l a. Butyl Acetate Hexanol-- s.I.a. Butyl Acetate Hydrochloric Acid . Hydrocyanic Acid, Liquid Hydrofluoric Acid Aqueous Hydrogen Peroxide Stronger than 25 volume andnot exceeding 25 Volume 130 volume Industrial Petroleum Naphthas and Solvents See Petroleum Naphthas and Solvents, Industrial Industrial Solvent, Aromatic Inorganic Cyanides (See Cyanides, Inorgenic) Isophorone-- s l.a. Butyl Acetate Lead Acetate Litharge-- s.l a. LeadAcetate -- M-- Maleic Anhydride Mercuric Chloride-- SeeMercury Bichloride Mercury Bichloride Mesityl Oxide-- s.La. Butyl Acetate Methyl Acetoacetate-- s l.a. Butyl Acetate Methyl Amyl Acetate-- *.La. Methyl n-Amyl Ketone Methyl Amyl Alcohol-- s.I.a. Methyl n-Amyl Ketone Methyl n-Amyl Ketone Methyl Bromide Methyl iso-Butyl Ketone-- sJ.a. Methyl Ethyl Ketone Methyl Cyclohexanol-- s.I.a. Cyclohexanol Methyl Cyclohexanone-- s.La. Cyclohexanol Methylene Chloride Methyl Ethyl Ketone 0 23 23 23 23 35 35 37 36 37 45-46 19-20 28 23 38 38 38 38 38 23 23 38 38 38 3? 40 2? 29 39 40 ( ( GO oO rafa Manual L 2 Methyl Methacrylate Monomer _ Methyl Morpholine-- s.I.a. Morpholine Methyl iso-Propyl Ketone Mixed Acid (Sulfuric and Nitric) Carboy Drum Monochlorobenzene-- See Chlorobenzene, Mono Monochlorophenol-- s.I.a. Phenol Monochlorotoluene-- See Chlorotoluene, Mono Mononitrophenol-- See Nitrophenol, M ono Morpholine Muriatic Acid -- See Hydrochloric Acid -- N-- Naphthas, Industrial Petroleum, and Solvents See Petroleum Naphthas and Solvents a-Naphlhylamine (containing 5 % b-Napbthylamine) s.I.a. b-Naphthylamine b-NaphthyUmine . ~ Nitric Acid Carboy Drum m-Nrtroamfine p-Nitroaniline-- s La. m-Ntroaniline Nitrobenzene-- s i a. Aniline m -Ntro-p-Anisdine-- s.l.a. m-Nitroaniline p-Nitro-e-Toluidine-- s.I.a. m-Nitroaniline Nitrophenol, M ono -- O-- Oil of Vitriol-- See Sulfuric Acid Oil Solutions of Pentachlorophenol-- See Pentachlorophenol, O il Solutions of Oleum Oxalic Acid -- P-- Paraldohyde Pentachlorophenol Oil Solutions of Perchlorethylene-- See Tetrachloroethylene 40 42 40 41 41 26 47 27 43 42 35 45-46 42 42 42 43 _ 43 43 18 43 43 43 53 45 44 44 44 45 45 54 LM-$u>ul of (he Unite Petroleum Naphthas and Solvents, Industrial o-Phenetidine-- s l.a, p-Phenetidine p-Phenetidine Phenol p-Phenyknediamine Phosphoric Acid Phosphoric Anhydride Phosphorus Phosphorus Oxychloride Phosphorus Pentachloride Phosphorus Trichloride-- sj.a. Phosphorus Oxychloride Potassium Chlorate-- s ia . Sodium Chlorate Potassium Chromate and Bichromate-- See Sodium Bichromate Potassium Hydroxide-- s.I.a. Caustic Soda iso-Propyl Acetate Propylene Chlorohydrin-- s.I.a. Ethylene Chlorohydrm isopropyl Ether-- s.I.a. Ethyl Ether Pyridine . . 45-46 46 46 47 47 47 48 48 49 48 49 50 51 26 49 32 33 49 -- s-- Sample-- Label tor Experimental Products Silver Nitrate Sodium Chlorate Sodium Bichromate Sodium Fluoride Sodium Hydrosulfte Sodium Hydroxide-- See Caustic Soda Sodium Orthosilicate-- s.I.a. Caustic Soda Sodium Sesquisiiicat^--s.I.a. Caustic Soda Sodium Sufftiydrate-- s.l a. Sodium Sulfide Sodium Sulfide (Granular) Solvents Aromatic Industrial Industrial Petroleum Naphthas and Solvents Styrene Monomer . Sulfur Chloride Sulfur Dichlorlde-- s.I.a. Sulfur Chloride Sulfur Dioxide Sulfuric Acid Carboy Drum Sulfuryl Chloride-- s.I.a. Sulfur Chloride 50 50 50 51 51 51 26 26 26 52 52 19-20 45-46 52 52 52 54 53 53 52 62 G iG ! ion of eh Unirai Sisifi ML-2tnunl Tar Acids-- s.I.a. Cresol Tetrechioroethane Tetrachloroethylene Tetrachlorophanol-- s.I.a. Pentachlorophenol Tetraethylenepentamme-- sia . Morpholine Thionyl Chloride-- sJ.a. Sulfur Chloride Toluene m-Toluidine o-Toluidine-- s.I.a. m-Toluidine p-Toluidine-- s.I.a. m-Toluidine Toluol-- See Toluene _ Trlchloroethykne Trichlorophenol Triethyknetetramine-- s.I.a. Morpholine . Trimethylcydohexanof-- s.I.a. 8utyl Acetate -- V-- Vinyl Chloride -- X-- Xylene Xylidines-- tJ.a. m-Toluidin* Xylol-- See Xylene -- z-- Zinc Chloride (Granular, Fused or Solution) 29 54 54 45 42 52 54 55 _ 55 55 54 55 55 42 23 55 56 55 56 56 ClIwncaliultdteineAMUxlclMaltiodBUatt, iUh*tuUpneltloMd ShUyWi MWl nWiMooadpwtotnld5 DDullCil.ot HRINTbO IN V IA 63