Document v2onYDrrkXoRJ89amjZG6Qzw

FILE NAME: US Government Contractor Regulations Including Shipyard Regulations (GCR) DATE: 1969 June 20 DOC#: GCR020 DOCUMENT DESCRIPTION: Military Standard - Symbols for Packages and Containers for Hazardous Industrial Chemicals and Materials HIL-STP-13M1 W W l BTEiD'i 2^5 MIL-STD-13^1(S A ) 20 June 1969 MILITARY STANDARD SYMBOLS FOR PACKAGES AND CONTAINERS FOR HAZARDOUS INDUSTRIAL CHEMICALS AND MATERIALS JH IS D O CU M EN T C O N TA IN SA fjLP A G ES niL-s Ti>-i3m w m i 03^2510 t d ? MIL-STD-13^l(S A ) 20 June 1969 DEPARTMENT OF DEFENSE NAVAL SUPPLY SYSTEMS COMMAND ( WASHINGTON, D. C. 20390 Symbols for Packages and Containers for Hazardous Industrial Chemical and Materials MIL-STD-13^l(SA) 1. This standard has been approved by the Naval Supply Systems Command. 2. Recommended corrections, additions, or deletions should be addressed to the Naval Supply Systems Command (SUP 0442), Washington, D. C. 20390. 1414 ii < Provided by IHS No reproduction or networking permitted without license from IHS Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not tor Resale,2011/2/4 14 31.30 GMT HIL-STD-1341 n n n i QBTSSll 143 FOREWORD MIL-STD-13^l(SA) 20 June 1969 Hie purpose of this standard is to establish a uniform symbol to warn users of the potential dangers involved with the use of the mate rial in containers. Hie materials to be marked are those having one or more hazardous characteristics defined herein. This standard prescribes marking of unit, intermediate and shipping containers, unit loads and containers that are components of kits or sets. It also provides criteria for application of symbols and for submission of data. Exceptions. The symbols of this standard are not intended to cover or conflict with the following conditions, regulations or categories of material: 1. macies. Chemicals or drugs used or dispensed by medical department phar 2. Chemicals used by clinical or chemical laboratories. exempted laboratories will be those designated by the departments, bureaus, offices and the Marine Corps.) (The 3. Explosives, fuels and compressed gases adequately covered by statute, regulation or current instructions. 4. Magnetic materiels requiring shielding or marking or both for air shipment. 5. Items and containers which require marking to conform to Depart ment of Transportation or Shipping Regulations. 1415 Provided by IHS No reproduction or networking permitted without license from (HS iii Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01S44492 Not for Resale,2011/2/4 14 31 30 GMT niL-STD-1341 ' m i n i 0332512 T CONTENTS MTL-STD-13^1(SA) 20 June 1969 Paragraph Page 1. 2. REFERENCED DOCUMENTS....................................... 1 3. DEFINITIONS................................................ 2 h. GENERAL REQUIREMENTS....................................... 2 5. DETAILED REQUIREMENTS...................................... 2 5.1 Size of Symbols............................................ 2 5.2 5.3 Marking and Design........... .............................. 2 5.^ Posters and Signs................... ...... ................ 3 5.5 Criteria for Application of Symbols.............. .......... 3 5.5.1 Application................................... ......... 3 5.6 Data Submission............................................ 3 1 FIGURES Figure 1. Hazard Identification System....... ................ it- 1 2. Color Format........ ..................................... 5 1 3. Alternate Color Format.................. . 6 1 4. Dimensions.... ............................................ 7 1 5. Small Size Marking...... ................................... 8 1 6. Posters.................................................. 9 7. Form LSB OOS-lt- .................................... lB 1016 ly j Provided by IHS No reproduction or networking permitted without license from IHS Sold toPATTEN, WORNOM, HATTEN & D1AMO, 01844492 Not for Resale011/2/414:31 30 GMT flIL-STD-lBMl W = m i 0312513 71b MIL-STD-13**i( SA ) 20 June 1969 APPENDICES Appendix Page A. HAZARDOUS MATERIAL SYMBOL APPLICATION CRITERIA............. 10 B. INSTRUCTIONS FOR PREPARING DEPARTMENT OP LABOR MATERIAL SAFETY DATA SHEET FORM LSB OOS-4......................... 12 1417 Provided by IHS No reproduction or networking permitted without Beerue from IHS v Sold to PATTEN. WORNOM. HATTEN & DIAMO, 01844492 Not for Resale,2011/2/4 14 31 30 GMT MIL-STD-1341 R W l l 03^2514 tS2 1. SCOPE MXL-STD-134l(SA) 20 June 1969 1.1 Scope. This standard covers design, colors, sizes and require ments for warning symbols to be affixed to packages and containers con taining hazardous industrial chemicals and materials. 2. REFERENCED DOCUMENTS 2.1 The issues of the following documents in effect on the date of invitations for bids form a part of this standard to the extent specified herein. SPECIFICATIONS Military MIL-M-I959O STANDARDS Marking of Commodities and Containers to indicate Radioactive Material Federal FED-STD-595 Colors (Requirements for individual color chips) (3 X 5 supplements) should be submitted to the Naval Supply Depot, Philadelphia, Citing FED-STD-595 together with appropriate chip number as shown therein (Copies of specifications, standards, drawings and publications required by contractors in connection with specific procurement functions should be obtained from the procuring agency or as directed by the contracting officer.) OTHER PUBLICATIONS Recommended System for the Identification of Fire Hazards of Mate rials, NFPA No. 704M: Fire Protection Guide on Hazardous Materials (contains NFPA 3^5A, 325M, 49, 4-91M and 704m ) (Copies may be purchased from the National Fire Protection Association, 60 Battery March Street, Boston, Massachusetts 02110.) 1418 Provided by IHS No reproduction or networking permitted without license from IHS 1 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011/2/414:31 30 GMT MIL-STD-1341 w n i i 03*12515 sss MIL- STD-13 (SA ) 20 June 1969 3. DEFINITIONS 31 Fire Hazard. The definition of Fire Hazard, which includes Flam mability Hazard, Reactivity and Health Hazard, of the National Fire Pro tection Association, NFPA No. 704m , shall apply. 3*2 Radiation Hazard. Any commodity that must be labeled in accordance^ with requirements and criteria of MIL-M-19590. j 3.3 Reactivity. The definition of reactivity of NFPA No. 70hM shall apply. 3 .^ Health Hazard. The definition of health hazard of NFPA No. 704M shall apply. 3.5 Oxidizing Material. A substance such as chlorate, permanganate, peroxide, nitro carbo nitrate, or a nitrate that yields oxygen to stimu late the combustion of organic material. 3.6 Corrosive Material. Acids, alkali or other material that will cause severe damage to living tissue or to other material it contacts. k . GENERAL REQUIREMENTS i-.l Symbols covered by this standard shall be applied to each unit, intermediate, and shipping container, unit loads and individual compo nents within kits and sets. Symbols shall be in accordance with Figures 1 through 5> and may be applied by stencilling, painting, printing, lithographing or labelling with water resistant materials. Marking of commodities containing radioactive material shall be in accordance with MIL-M-19590. 5. DETAILED REQUIREMENTS 5.1 Size of Symbols. Symbols shall be the sizes designated in NFPA No. 704m summarized in Figures 1 through h of this standard. Smaller size symbols commensurate with surface available may be used on containers having two or more dimensions less than 6 inches, such as small cans, bottles, tubes, or individual components of kits or sets. (See Figure 5.) 1419 Provided by IHS No reproduction ex networking permitted without ficensefrom IHS 2 Sold to.PATTEN, WORNOM, HATTEN & DIAMO. 01844492 Not for ResalB.2011/2/4 14 31*30 GMT MIL-STD-1341 "m n i l OB'fSSlb 42S MIL-STD-134l(SA) 20 June 1969 5*2 Color. The colors indicated for the symbols in Figures 1 through 6 shall acceptably match in shade the applicable color of FED-STD-595, as follows: Color Class Black Red White Yellow Blue I7O38 IUO5 17875 I3538 I 5I O 2 5*3 Marking and Design. Each symbol shall conform to the applicable markings and design, as indicated in Figures 1 through 5. 5^ Posters and Signs. Posters and signs illustrating the hazard shall be prepared in accordance with Figure 6 . Activities requiring posters should state the size required, weight and quality of paper or other material required, and surface finish required. Posters and signs are intended for display in work and storage areas. 5.5 Criteria for Application of Symbols. Symbols shall be applied to containers whenever the contents has hazardous characteristics defined in this standard. Specifically, any material listed as hazardous in National Fire Protection Association publications, or having similar characteris tics shall be so labeled. Application criteria for Federal Supply Groups and Classes are given in Appendix A. Application. These requirements shall apply to all material sup plied to the Navy directly or indirectly through the Defense Supply Agency, General Services Administration, jobbers, dealers and contrac tors, sub-contractors and other channels. 5.6 Data Submission. Contractors shall provide data described in the U. S. Department of Labor Material Safety Data Sheet (Form LSB OOS-^) as required in the contract or order. Once data has been submitted for a particular commodity, no change in formulation affecting its hazardous characteristics is permitted without prior approval by the contracting officer. Instructions are provided in Appendix B. Suppliers are encour aged to submit the same information to the National Fire Protection Asso ciation, 60 Batterymarch Street, Boston, Massachusetts 02110. 1420 Provided by IHS No reproduction or networking permitted without license from IHS Preparing Activity Navy - SA Project No. PACK N0l6 3 Sold to.PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011 4 14:31.30 GMT MIL-STD-I341 MIL-STD-13^l(SA) 20 June 1969 HEALTH HAZARD 4 * Deadly 3 - Extreme danger 2 * Hazardous 1 Slightly hazardous 0 - Normal material cicm ciii Danesi? 3bi FIRE HAZARD Flosh Points 4 - Below 80F 3 - Below 100F 2 - Bolow 200F 1 - Above 200F 0 - Will not burn SPECIFIC HAZARD Oxidizer Acid Alkali Corrosive Use NO WATER REACTIVITY May detonate Shock and heat may detonate Violent chemieal change 1 Unstable if heated Symbol arrangement and text shall be as above. Color formats are provided in Figures 2 and 3 Dimensions are shown in Figure h. The following specific hazard symbols shall be used: TERM SYMBOL REFERENCE Oxidizer Acid Alkali Corrosive Fire Fighting Use No Water Hazard OXY ACID ALK COR -W- ,, 3.5 3.6 3.6 3-6 NFPA No. 70UM Combinations of specific hazard symbols shall be as follows: OXY OXY OXY OXY ACID ACID ACID ALK COR -w~ COR -W- ALK ALK COR COR -W- Figure 1. Hazard Identification System 4 1421 Provided by IHS No reproduction or networking permitted without Bcense from IHS Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011/2/4 14*31*30 GMT ML-STD-1341 W R R l l 03*i2ia MIL-STD-134-1(SA) 20 June 1969 Numerals shall be white and may have a black border. Letters G L S or combinations thereof may be used in the center circle to shoV that the contents are a gas liquid or solid at the proper condition of storage. The letters may be white with black border or all black. The letter W in the "Use No Water" symbol --W-- shall be white with a black border. All other printing shall be black on a white background (see Figure l). Figure 2 . Color Format 1422 Provided by IHS No reproduction or networking permitted without license from IHS 5 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011/2/4 14 31 30 GMT fflL-STD-13^l(SA) 20 June 1969 MIL-STD-1341 W I S H QB'iSSn 134 Backgrounds shall be white. Borders shall be black. Numerals shall be the color Indicated and may have a black border. The letter W in the "Use No Water" symbol W~ shall he black wi^h a black border. All other printing shall be black on white (see Figure l). Figure 3. Alternate Color F o m a t 1423 Provided by IHS No reproduction or networking permitted without license from IHS Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011/2/4 14 31 30 GMT MIL-STD-1341 ' m n i l 03=12520 RSb MIL-STD-134l(SA) 20 June 1969 > A B C D W T BORDER 4 2- 1/2 3 A 3/8 5 / 8 5/32 All Borders shall he k 2-1/2 1 1/2 3A 5/32 1/ 6 V 6 3-3A 1- 1 / 2 3 / 14 1 7/32 8 5 2 1 I - 1/2 5/16 Dimensions are in inches. Tolerance I/32 in unless otherwise note. TYPE SIZE POINTS MIH MAX 7 8 7 8 10 12 14 16 Figure 4. Dimensions 142** Prwkted by IHS No reproduction or networking permitted without license from IHS 7 Sold to-PATTEN. WORNOM, HATTEN & DIAMO, 01844492 Not for Resale011/2/4 14-31-30 GMT MIL-STD-1341 MIL-STD-134l(SA) 20 June 1969 G a ^ a i 0^2 This illustration shows acceptable application for containers too small for symbols having dimensions specified in Figure U. Further reduction is permissible, providing printed information is legible. Figure 5* flmall Size Marking 1425 Provided by IHS No reproduction or networking permitted without license from IHS 8 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011/2/4 14*31*30 GMT MIL-STD-13H1 ' H W 11 03^2522 72^ HAZARD IDENTIFICATION SYSTEM MIL-STD-l34l(SA) 20 June 1969 Identification o f H ealth H azard Color C ode: B L U E Identification of F lam m ability Color C ode: R E D Identification of R eactiv ity , (Stability) Color Code: Y E L L O W T y p e of Possible In ju ry Susceptibility of M aterials to B urning Susceptibility to R elease of E n ergy S ig n a l S ig n a l S ig n a l M aterials w hich on very 4 sh o rt e xp o su re c o u ld cau se death or m ajor residual in ju ry even though prom pt m edical treatm en t were g iv e n . M aterials w hich w ill rapidly 4 or c o m p le te ly v a p o riz e a t atm ospheric pressure and norm al am bient tem pera ture, or w hich are readily dispersed in air an d w hich M aterials w hich are readily capable of detonation or of explosive decom position or reaction a t norm al tem peratures and pressures. w ill burn readily. g g g M aterials w h ich on sh o rt ex posure could cau se serious tem porary or residual in ju ry even though prom pt m edical treatm ent were given. Liquids and solids th a t can be ignited under alm ost all am bient tem perature condi tions. M aterials w hich are capable of det onation or explosive reaction b u t re quire a strong in itiatin g source or w h ich m u st b e heated under confine m ent before initiation or w hich react explosively w ith water. M aterials which on intense or continued exposure could cause tem porary incapacita tion or possible residual in ju ry unless p ro m p t m edical treatm en t is given . & M aterials th at m ust be m od erately heated or exposed to relatively high am bient tem peratures before ignition can occur. & M aterials w hich are norm ally unstable and readily undergo violent chem ical change b u t do n ot detonate. Also m aterials w hich m ay react violently w ith w ater or w hich m ay form poten tia lly explosive m ixtures w ith w ater. a M aterials w hich on exposure w ould cause irritation but on ly m inor residual in ju ry even if no trea tm en t is given . a M aterials th at m ust be pre heated before ignition can occur. a M aterials w hich are norm ally stable, b u t w h ich can becom e unstable a t ele vated tem peratures and pressures or w hich m ay react w ith w ater w ith some release of en ergy b u t not violen tly. M aterials w hich on exposure under fire con dition s w ould offer no hazard beyond th at of ordinary com bustible m a terial. M aterials th at will n ot b u m . M aterials w hich are norm ally stable, even u nd er fire exposu re conditions, and w hich are not-reactive w ith w ater. Copyright 1966 by the National Fire Protection Association and pub lished in the "Recommended System for the Identification of the Fire Hazards of Materials (NFPA No. 704m )." Reproduced vith permission. Posters in color (1 6 " X 4 ") may be purchased from the National Fire Pro . tection Association, 60 Batterymarch Street, Boston, Massachusetts 02110 Decals in color (6 " X 4") are also available. Figure 6. Poster for use with Hazardous Material Symbols 1426 Provided by IH8 No reproduction or networking permitted without Scnse from IUS Sold tO.PATTEN, WORNOM, HATTEN & DIAMO. 01844492 Not for Resete,2011/2/4 14 31 30 GMT MIL-STD-1341 9444411 0342523 bbS MIL-STD-134l(SA ) 20 June 1969 APPENDIX A i HAZARDOUS MATERIAL SYMBOL APPLICATION CRITERIA The Application Criteria of this Appendix are mandatory for all material supplied to the Navy. 10. HAZARDOUS MATERIAL IDENTIFICATION APPLICATION GUIDE 10.1 Hazardous Identification Symbols shall be applied to containers of material in the following Federal Supply Groups and Classes: FEDERAL SUPPLY GROUP 68 FEDERAL SUPPLY CLASS 3^39 Welding and Brazing Supplies 68lO Chemicals 6820 Dyes 6830 Gasesj Compressed and Liquified 6840 Pest Control Agents and Disinfec tants 685O Miscellaneous Chemical Specialties 79 7930 Cleaning and Polishing Compounds and Preparations 80 8010 Paints, Dopes, Varnishes, and Related Products 8030 Preservative and Sealing Compounds 8040 Adhesives 85 85IO Perfumes, Toilet Preparations, and Powders 8520 Toilet Soap, Shaving Preparations, and Dentifrices 87 8720 Fertilizers 91 (Packaged Products Only) 99 9110 9130 9135 9140 9150 9160 Fuels, Solid Liquid Propellants and Fuels, Petroleum Base Liquid Propellant Fuels and Oxidi zers, Chemical Base Fuel Oils Oils and Greases: Cutting, Lubri-cating, and Hydraulic Miscellaneous Waxes, Oils, and Fats 992 Smokers' Articles and Matches Lighter Fuel Only 1427 10 Provided by IHS No reproduction or networking permitted without Bcense from IHS Sold to'PATTEN, WORNOM, HATTEN & DIAMO. 01844492 Not for Resele.2011/2/4 14*31 *30 GMT MIL-STD-iam 03=12524 5T1 MIL-STD-134l(SA) 20 June 1969 10.2 Symbols shall be required for items that would ordinarily be cata loged under one of the above lasses, but are stocked numbered in another class because of their specific use. 10.3 Symbols shall be required for all items listed in National Fire Protection Association NFPA No. 325A, 325M and 49 and for items having similar characteristics. 1A28 Provided by IHS No reproduction or networking permitted without license from IHS 11 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011/2/4 14 31 30 GMT M i L - s T D - i a m *h h r i i o s o s a s mba APPENDIX B INSTRUCTICR8 TOR PREPARING DEPARTMENT OP LABOR MATERIAL SAFETI DATA SHEET FORM LSB OOS-4 Instructions in this appendix are mandatory to the extent specified elsewhere in this standard, or as specified in contracts or orders. M IL-S a3)-X 34l(S A ) 20 June 1969 20. INSTRUCTIONS 20.1 Material Safety Data Explanation of Tarns and Instructions. Fora LSB 003-*, or one essentially similar, approved by t!be Bureau of Labor Standards, is required to he filled out only on Materials vhich, vhen not provided with special attention or controls, will constitute a hasard. If inforaatlon is inapplicable to the naterial under consideration, the Initials "n.a." (not applicable) shall be inserted. 20.1.1 Definition of an Essentially Slnllar Fora. An essentially siai- lar foza Is interpreted as being ona in which Section H is modified to Indicate only the product or group of products which it is Intended to cower. The reaalnlng sections of the foza will list the lteas of infor mation in the sequence shown on Foza Q08-I4, but the apace given to those entire sections which are inapplicable nay be reduced to that necessary to enter the Initials "n.a." (not applicable). 29.1.2 Definition of one or more of the f0 Hazardous Material. A haxardoua aaterlal has jog characteristics: (a) has a flastyoint, or la subject to spontaneous heating; (b) has a threshold limit value below 500 ppm for gases and vapors, and below 25 mppcf for dusts; (c) a single dose coal U)c q below 500 ag/kg; (d) is subject to polymerization with the release of large amounts of energy; (e) Is a strong oxidizing or reducing agent; (f) causes first degree burns to skin in short time exposure, or is eyateaically toxic by skin contact; or (g) in the course of normal operations, may produce dusts, gases, fumes, vapors, mists, or smokes which have one or more of the above characteristics. 20.2 Instructions for Section I. 142 9 Provided by IH$ No reproduction or networking permitted without license from IH$ 12 Sold to'PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not for Resale,2011/2/4 14-31 -30 GMT i niL-sT3>-i3m 03=12531, 374 KXL-B>-13itl(SA) 20 June 1969 t 20*2.1 Manufacturer's Kane and Address. Mailing address, including ZIP code, the Federal Supply Code for Manufacturers (PSGM), and name of certi fylng caepaay official. 20.2.2 Bnergency Telephone Bomber. Show area code, telephone nunber(s) and extension^ and ijours o? operation at which further information nay he obtained in the event of an emergency involving the material. 20.2*3 Chemical game and Synonyms. Applies only to products consisting of a single element or compound, such as oxygen, or methyl-ethyl Ketone. 20.2.V Trade Mama and Syno n y m . Include formula number or other defi nite designation of the product. 20.2.3 Chemical Family. State generic name of single elements and com pounds, suck as aei!d or ketone. 20.2.6 Formula. Refers only to the chemical formula for single ele ments or compounds, not to the formulation of a mixture. Example: O2 and C2H5 COCH3 . 20.3 Instructions for Section II-Hazardous Ingredients. 20*3.1 Ingredients. A hazardous ingredient is a hazardous material in ^ a mixture in sufficient concentration to produce enough flawsable vapor W or gas to ignite, or to produce acute or chronic adverse effects in doses which could result from normal use or predictable misuse of the mixture containing it. Ingredients of a hazardous nature shall be noted by chemi cal name in one of the three divisions of Section II, viz., Paints, Preservatlves, and Solvents} Alloys and Metallic Coatings; and Hazardous Mix tures of other liquids, solids, or gases. She listing of Ingredients in the first division is self-explanatory. Metallic coatings listed in the second division refer to coatings such as plating, cladding, and metallizlng; and filler metal ia any metal added in making a brazed, soldered, or welded Joint, f i n e r metals shall be considered with the ingredients of rod coatings and core fluxes as single mixtures. The third division refers to other hazardous mixtures, such as abrasive blasting materials. 20.3*2 Composition. The approximate percentage of each hazardous in gredient by weight or volume shall be shown to the nearest 3 percent. The percentages of any substance constituting less than 3 percent may be indicated as such. For mixtures, such as filler metals and their coat ings and core fluxes, in which the hazardous ingredients constitute very small proportions of the mixture, the hazardous ingredients shall be stated to the nearest 0.3 percent, and ingredients constituting less than 0.3 percent may be indicated as such. 13 > 1430 Provided by (HS No reproduction or networking permitted without license from IHS Sold to PATTEN, WORNOM, HATTEN & DIAMO, O1B44402 Not for Resale,2011/2/4 14 31 30 GMT HIL-STD-1341 T W I l l 03^2527 2Q0 20.3.3 Threshold Limit Valve. The threshold limit value ( W f ) for truth fcas- i ardors ingredient in a mixture vill be entered in the column provided, in accordance with instructions given in Section V. 20.3.4 Additional Information. If more space is needed in the first or second division, use the lines provided in the third division. Normally this space will be used for mixtures not falling in the other two divi sions. In addition, addenda sheets may be added to the form. 20.4 Instructions for Section Ill-Physical Data. 20.4.1 Boiling Point. State the temperature at which the liquid bolls, in degrees F., at a pressure of 760 mm Hg. For mixtures, a boiling range is acceptable. 20.4.2 Vapor Pressure. State the pressure of saturated vapor above the liquid in mm of Big, at 20C. 20.4.3 Vapor Density. State the relative density or weight of a vapor or gas (with no air present) compared with an equal volume of air. Val ues should be given in the ambient temperature range of 60 - 90F. to facilitate field usage. 20.4.4 Solubility in Water. Use the following terms to describe the solubility of the product by weight in distilled water at 50F: Negligible. Slight.... Moderate... Appreciable Complete... less than 0 .1 percent 0 .1 - 1 percent 1 - 1 0 percent more than 10 percent in all proportions 20.4.5 Specific Gravity. State the ratio of the weight of a volume of material to the weight of an equal volume of water at 392F. This deter mines whether the material floats or sinks in water. 20.4.6 Percentage Volatile by Volume. State the percentage of the liquid or solid by volume that evaporates at the ambient temperature of 70F. T^iis applies to solids such as Napthalene. 20.4.7 Evaporation Rate. State the ratio of the evaporation rate to that of either Butyl Acetate or Diethyl Ether. Insert the name of which ever is used. 20.4.8 Appearance and Odor. Give a brief description, e.g., viscous, colorless liquid with aromatic odor. Provided bylHS No reproduction or networking permitted without license from IHS Sold to PATTEN. WORNOM, HATTEN & DIAMO, 01644492 Not for Resale,2011/2/4 14 31 30 GMT i MIL --STJ>--1341 W i ^ l l 0352520 147 M3X-S0!D-13ia(SA) 20 June 1969 20.5 Instructions for Section IV-Fire and Explosion Hazard Data 20.5*1 Flash Point. State the temperature in degrees F., at which a liquid will give off enough flammable vapor to ignite when tested by the open cup method. When multi-component paint systems are used and mixed in the field, the flash point of the individual components shall be noted. 20.52 Flammable or Explosive Limits. State the range of gas or vapor concentrations (percent by volume in "air) which will b u m or explode if an ignition source is present. T.FT, means the lower explosive limit, and UEL means the upper explosive limit. Knowledge of the LEL will aid in determining the volume of ventilation needed for an enclosed space to prevent fires and explosions. 20.5*3 Extinguishing Media. List the firefighting media suitable for use on the burning material. For certain specific chemicals, special formulations, in addition to the standard agents, are available for extin guishing fires. These should be indicated by generic name. The standard firefighting agents are water fog, foam, alcohol foam, COg, and dry chemi cal. 20.5^ Special Firefighting Procedures. If water is unsuitable, specify the firefighting media to be used. Also list any necessary per sonal protective equipment. > 20.5*5 Unusual Fire and Explosion Hazards. Specify such hazards and/or any special conditions that govern them. 20: 6 Instructions for Section V-Health Hazard Data. 20.6.1 Threshold Limit Value. Threshold limit value (TLV) refers to current figures of the American Conference of Governmental Industrial Hygienists. The TLV for single elements and compounds shall be entered here. For mixtures, the threshold limit value for each significant ingre dient shall be noted, in the column provided in Section II of the form. (See Section II above for explanation.) Express these value in millions of particles per cubic foot of air (mppcf), or in milligrams of particu late per cubic meter of air (Mg/lH) for dust) and in milligrams of par ticulate per cubic meter of air (Mg/M^), or in parts per million parts of air by volume (ppm) for gases, vapors, mists, fumes, and sill other con taminants except dusts. State the units in which the TLV is expressed. 20.6.2 Effects of Overexposure. Describe most common sensations that exposed person will feel, and his appearance. 1432 Provided by IHS No reproduction or networking permitted without license from IHS 15 Sold to PATTEN. WORNOM, HATTEN & DIAMO. 01644492 Not for Resale,2011/2/4 14 31 30 GMT nii_-sTD-i3m siese'i ob3 m t l -s t d -13 ^i (s a ) 20 June 1969 20.6.3 Emergency and First-Aid Procedures, state emergency procedures to be used.. Only Inhalation and skin or eye eont&ct should he considered in recommending first-air measures. The victim should he examined by a doctor as soon as possible after exposure. 20.7 Instructions for Section VI-Reactivity Data. 20.7*1 Stability. Indicate, by cross or check, whether stable or un stable under reasonably foreseeable conditions of storage, use, or misuse. If unstable, list those conditions which may cause a dangerous reaction. Examples: Shock from dropping; temperature above 150F. 20.7*2 Incompatability. Provide information on such common materials and contaminants with which the product may reasonably come into contact, producing a reaction which would release large amounts of energy. If none, so state. State whether oxidizing material, acid, caustic alkali or corrosive* 20*7*3 Hazardous Decomposition Products. List hazardous materials pro duced in dangerous amounts by burning, oxidation, or by heating in weld ing or burning. Thermal decomposition products, such as CO, CO2, and hydrochloric acid from vinyl chloride plastics are examples. 20*7*k Hazardous Polymerization. Hazardous polymerization is that which takes place at a rate which releases large amounts of energy. Indi cate by check or cross whether or not hazardous polymerization can occur. If so, list those reasonably foreseeable storage conditions which would start polymerization. Include the expected time period in which the inhibitors may be used up. 20.8 Instructions for Section VH-gplll or leak Procedures. Indicate any applicable precautions as: avoiding breathing gases and vapors; con tact with liquids and solids; removing sources of ignition; any special equipment used for cleaning 19, such as glass or plastic scoops; and dis posal of spilled solids or liquids, such as flushing with water, returning material to container, burning, etc. 20.9 Instructions for Section YIII-8pecial Protection Information. Indicate the type of personal protective equipment, ventilation, and such precautions to be taken when using the product for its intended purpose, as elimination of ignition sources* 20.10 Instructions for Section IX-Special Precautions. Indicate any special precautions to be taken, such as in handling or storing, to avoid reaction hazards. When applicable, indicate safe storage life of product in relation to reactivity* Also indicate any other general precautions to be taken. 16 1433 ( Provided by IHS No reproduction or networking permitted without license from IHS Sold to PATTEN, WORNOM, HATTEN & D1AMO, 01S44492 Not for Resale,2011/2/4 14'31'30 GMT MIL-STD-13^1(SA) 20 June 1969 m L - S T D - i 3 m 3333311 0332530 ats 20.11 Federal Stock Number, and Package Dimensions and Weight. Indicate the Federal Stock Number (FSN) at the bottom of page 1. Also indicate the outside dimensions of the unit package in inches and tenths thereof. Example: For a container 4J" in diameter and 6-3/8" high, enter: Package Dimensions 4.5 X 4.5 X 6.4. The gross weight of the unit package shall he indicated in pounds and tenths. Example: For a container weighing 44 pounds 12 ounces, enter: 44.8 lbs. gross. 20.12 Submission of Data. Mail completed form as directed in the con tract or order. In the absence of specific mailing instructions, mark the contract or order number under the FSN and mail to the Commanding Officer, Navy Fleet Material Support Office, Mechanicsburg, Pennsylvania 17055. > > Provided by IHS 1434 17 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01&44482 MIL-STD-1341 l l i m i QBTESBL 731 Form Approved Budget Bureau N o. 44-R1387 A p p ro v a l E xp ire s A p r il 3 0 , 1971 U .S . D EPARTM ENT OF LABOR W A G E A N D LABOR S TA N D A R D S A DM INISTRATIO N > Bureau of Labor Standards MATERIAL SAFETY DATA SHEET Forn N o . LSB*OOS*4 May 1969 MU>STD-134I(SA) Figure 7 MANUFACTURER'S NAME ADDRESS (Number, Street, Cityt State, and ZIP Code) CH EM IC AL NAME AND SYNONYMS C H EM IC AL FAMILY SECTION I EMERGENCY TELEPHONE NO. f o r m u l a TRADE NAME AND SYNONYMS pvTJ 'V i *^ PAINTS, PRESERVATIVES, & SOLVENTS P IGMENTS CATALYST I; VEHICLE SOLVENTS A D D IT IV E S OTHERS TLV (Unit) ALLOYS AND METALLIC COATINGS BASE METAL ALLOYS METALLIC CO ATIN G S FILLER METAL PLUS C O A T IN G OR CORE FLUX OTHERS : > HAZARDOUS MIXTURES OP OTHER LIQUIDS, SOLIDS, OR GASES TLV (Units) VAPOR OENSITY IA IR = 1 ) SOLUBILITY IN WATER APPEARANCE A N D ODOR SPECIFIC G R AV ITY (H 20 = 1 | PERCENT V O LA T ILE BY VO LUM E (%) EVAPORATION RATE ---------- =D t ES Fkg. Pia. 1435 II I Provided by IHS No reproduction or networking permitted without license from IHS Gross Vgt.: Sold to PATTEN. WORKJOM, HATTEN & DIAMO, 01644492 Not fo r Resale,2011/2/4 14 31 30 GMT MIL-STD-13M1 R R W l l D3R2532 fc>7fi EFFECTS OF OVEREXPOSURE EMERGENCY AN D FIRST A ID PROCEDURES UNSTABLE STABLE INCO M PATABILITY (M aterials to avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS p o l y m e r iz a t io n MAY OCCUR WILL NOT OCCUR II C O N D ITIO N S TO A V O ID CO ND ITIO NS TO A V O ID STEPS TO BE TAKEN IN CASE M ATE R IA L IS RELEASEO OR SPILLED ( WASTE DISPOSAL METHOD RESPIRATORY PROTECTION (S pecify type) VENTILATIO N LOCAL EXHAUST M ECHANICAL (General) PROTECTIVE GLOVES 3 OTHER PROTECTIVE EQUIPMENT EYE PROTECTION S P E C IA L OTHER Figur* 7 (Continued) 1436 ^. Provided by IHS No reproduction or networking permitted without license from IHS 19 *U .S. GOVERNMENT PRINTING OFFICE : 1969-393-087/S37 SoW to PATTEN, WORNOM, HATTEN & DIAMO, 01&44492 Not for Resale,2011/2/4 14*31 30 GMT