Document v1eVDJ5N1LvBg2pZQ4k0ngdbm

ABD00091673 / Material Safety Data Sheet May be used to comply with OSHA's Hazara Communication Standard. CFR 1910.1200. Standard must be ^Bjonsulted lor specific requirements. ^4287 Yellow Section 1 Manufacturer's Name HARWICH CHEMICAL CORPORATION Address (Number, Street, City, State, and ZIP Code) 60 South Seiberling Street Akron, OH 44305 ., U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved 1 OMB No. 1216-0072 * Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Emergency Telephone Number (216) 798-9300 Telephone Number for Information Same Date Prepared . - - ' Auqust 5, 1988 Signature of Preparer (optional) Section II -- Hazardous Ingredients/ldentity Information Hazardous Components (Specific Chemical Identity; Common Name(s)) OSHA PEL Titanium Dioxide CAS #13463-67-7 15rog/m_ Iron Oxide CAS #1309-37-1_______________________lOmg/m **Lead (as Pb) __________________________________.05mq/m **Chrornate (as Cr)__________________________________lmg/m ACGIH TLV *5mg/m^ r5mq/m~ 15mg/rrT . 5mg/nf Other Limits Recommended______ % (optional) >1 ________ _________>1 .45mg/mJ STEL >1 *TLV for respirable nuisance dust. Not likely in product form. Contained in Cl Pigment Yellow 34, Cl #77603, CAS #1344-37-2. Section III -- Physical/Chemical Characteristics (.toiling Point Vapor Pressure (mm Hg.) Vapor Density (AIR 1) Solubility in Water N/A N/A N/A Specific Gravity (HzO - 1) calculated Melting Point Evaporation Rate (Butyl Acetate - 1) Nil Appearance and Odor Yellow grannlp VT. nr rnarsP pnwrfer VCP - slight ndnr Section IV -- Fire and Explosion Hazard Data Flash Point (Method Used) N/A Flammable Umits N/A Extinguishing Media C02r dry chemical, water spray Special Fire Fighting Procedures Wear self-contained breathing apparatus and protective clothing. 2.42 N/D N/A LEL UEL Use water spray to cool fire exposed surfaces and to protect fire fighting personnel. I Unusual Fire and Explosion Hazards Fire conditions produce HCl, In the presence of heat and organic matter, lead chrcmate can cause an oxidation reaction resulting in fire. (Reproduce locally) N/A =Not Applicable N/D = not Determined OSHA 174. Sept. 1985 ABD00091674 Section V -- Reactivity Data stability Unstable Stable X incompatibility (Materials to Avoid) strong oxidizers F^jt^dou^Q^mposition or Byproducts Conditions to Avoid Do not neat . above __. 200C to avoid possible release of HC1 (toxic and corrosive). Ignition sources. Hazardous Poiymorization May Occur Will Not Occur Conditions to Avoid None known X Section VI -- Health Hazard Data Routofs) of Entry: Inhalation? Skin? Ingestion? ___________________________Not likely__________________Yes_______________________________Yes Health HazardsJAajto and Chronic), , ,. Acute; If dusty may irritate the eyes, skin and respiratory tract. Contains PVC Resin. Refer to the OSHA Standard Vinyl Chloride 29CFR.1910 for a full discussion of possible nealth errects. Chronic: Prolonged oVSfexpoSUre way cause lead"puibuiliily invulviny delayed effects in the blood, gastrointestinal, nervous and reproauctory systems. Carcinogenicity: Lead Chranate NTP? IARC Monographs? SuspectSuspectNo OSHA Regulated? Lead chrcmate is an AOGIH suspect carcinogen. Signs and Symptoms of Exposure ... ... ^ ,,. Early symptoms of lead poisoning are fatigue, disturbance of sleep and constipation. With more severe exposure; colic, anemia and nueritis._______________________________________ Goneraiiy^AMravaled by Exposure Respiratory and skin disorders aggravated by dust. Emergency aqd First Aid Procedures.... . _. . , ... Inhalation: Move to fresh air, give artificial respiration if necessary, call a doctor. t.yes: Flush with water tot 15 minutes,""call a doctor1. Skin:--Wash willi soap and-water. Ingestion: Induce vomiting, call a doctor. Section VII -- Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Released or Spilled prevent additional discharge of material. Recover spilled material and place in a suitable container for recycle or disposal. Depending on the quantity spilled, notifica tion of the National Response Center (800*424-8802) may be necessary. Waste Disposal Method Dispose of in accordance with all Federal, State and Local regulations. Lead chronate pigments are a hazardous waste on the basis of EP Toxicity. Test waste mixture for EP Precautions to Be Taken in Handling and Storing -- . 'Vdkiclty1. Do not store near flame or heat. Refer to the OSHA Standard mentioned in Section VI. Heated material may cause thermal bums. Other Precautions None Section VIII -- Control Measures Respiratory Protection (Specify Typo) g. H-lA- Ventilation Local Exhaust To maintain PEL & TLV Spe8one & TLV n5one Protective Gloves Eye Protection Ttrpervious____________________________________________ Safety glasses Other Protective Clothing or Equipment None Work/Hvai ic.practices .. Was ore eating or smoking. Page 2 UtUPO 'M-49I-M9/4W7)