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AM ERICAIM PETROLEUM
1801 K STREET, NORTHWEST
Division of Refining
W. L. Walker. Vice President for Refining P. D. Dennstedt, Vice Chairman, General Committee C. W. Shouse, Secretary. General Committee C. T. Sawyer, Director
RECEIVED s
JUN 3 1974
INSTITUTE
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WASHINGTON, D.C. 26od6WOELLER 2
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(202) 833-5680
OSH 1.12
To the Members of the Interdivisional Committee OSH Petroleum Industry Representative OSH
Gentlemen:
Enclosed is a section from the'May 10 Federal Register (29 CFR Part 1910), VINYL CHLORIDE. Please give us your com ments not later than June 3.
Also enclosed are:
1. May 3 Federal Register, Part 1952, Approval of Wyoming Plan.
2. May 10 Federal Register, National Advisory Com mittee on Occupational Safety and Health, Notice of Meeting.
3. Court Upholds OSHA in Key Points Challenged by Union.
Very truly yours,
elt Enclosures
cc: API Staff OSH API Ex VP, VP (A), VP (IA), VP VP (PD), and Secretary Officers, General Committee
(PA),
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MAY 1 7 1974
H. R. BRQWfi
Interoffice Communication
To L. N. Vernon, Saddle Brook
From
D. V. Porchey, Ponca City
Date Subject
June 6, 1974
VINYL CHLORIDE SEMINAR--GEORGE D. CLAYTON & ASSOCIATES -- JUNE 4 AND JUNE 5
CHEMICALS^ * -RSSABCHa----
JUN6 137<?3}
I attended about 50 percent of the subject seminar to extract information useful to Chemicals in our effort to solve our VCM health problem. The seminar was,of no value. Most information presented is common knowledge to us. In fact, a number of errors were made. Conoco could easily prepare a seminar to teach this environmental consulting firm about the VCM problem. Clayton and Associates plan other seminars this summer at various locations in the United States. I strongly recommend that Conoco not be represented at these seminars.
A partially completed notebook was given as a handout. I will route sections to people whose initials are shown on the attached list of notebook contents. I will also supply a copy of any other section to interested Conoco people on request. The original notes will be placed in the files of the Engineering Research Section unless directed otherwise.
Clayton and Associates provide environmental sampling, survey and analytical service, including activated charcoal dosimeter tubes. (R. E. Laramy is familiar with their services.) Conocofs resin customers could be referred to these people for dosimeter analyses. The charcoal tubes and analyses cost about $12 each.
Some interesting results are claimed by this firm with regard to their charcoal techniques. They claim VCM loadings up to about 58 percent, very rapid breakthrough, and ..ability to detect exposures at 5 ppb. These results differ with ours significantly. I question their accuracy, but don't feel that it is worth pursuing. If their numbers are correct, it merely demonstrates again the great variations in effectiveness between charcoals. Details are included in the writeup in Section VI.
Dave Porchey Research Group Supervisor Engineering Research Chemicals*Research Division
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TABLE OF CONTENTS
PAPER
TITLE
I Introduction to the Problem
AUTHOR(S) W.A. Cook
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IX Development of the Polyvinyl Chloride
Industry and Associated Operations
T.A. Loch, Ph.D.
III
Effects of Exposure
H.L. Gordon, M.D.
IV A Recommended Medical Surveillance
Program
H.L. Gordon, M.D.
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V Evaluation of Airborne Concentrations
of Vinyl Chloride - Direct Reading
Instruments
R.D. Soule
VI Evaluation /of Airborne Concentrations
of Vinyl Chloride - Integrated Sampling
Methods and Analytical Procedures
R.R. Keenan, Ph.D.
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Potential Air Pollution Problems from Vinyl Chloride and Polyvinyl Chloride
J.E. Mutchler and T.A. Loch, Ph.D.
VIII
Review of Past Developments and Discussions of Anticipated Actions
R.D. Soule
VRD
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POTENTIAL AIR- DILUTION PROBLEMS FROM
VINYL CHLORIDE AND POLYVINYL CHLORIDE J,E. Mutchler and T.A. Loch, Ph.D.
I.INTRODUCTION II. SOURCES AND TYPES OF EMISSIONS
A. Monomer Production B. Polymerization Processes C. Compounding and Fabrication III. FATE AND EFFECTS OF EMISSIONS A. Unreacted Monomer B. Oxidized Monomer C. Particulate Resin D. Thermally Degraded and Oxidized Resin IV. POTENTIAL REGULATORY STANDARDS A. Current EPA Investigations B. Material Substitution
C. Ambient Air Standards D. Emission Limits V. SAMPLING AND ANALYTICAL METHODS A. Ambient Air Surveillance B. Source Sampling VI. EMISSION CONTROL METHODS A. Process and Work Practice Changes B. Atmospheric Diffusion C. Control Equipment VII. FIGURES AND TABLES VIII. BIBLIOGRAPHY *