Document rx44qJY3RMYmDN712q4OEoY0V
ASBESTOS
-CIA .. -X*
UNION CARBIDE HIGH-PURITY ASBESTOS A NEW WHITE FIBROUS FILLER AND RETENTION AID
FOR PRINTING PAPERS
IT PROVIDES:
IMPROVED SHEET FORMATION
IMPROVED Ti02 RETENTION
INCREASE DYE RETENTION
WTTHO'PT ATBSTTO-'
VT?H AfBEfTor
PLUS
Opacity Brightness Reduced Show-Through
Cellulose Fines Retention
Printability Improvements
Reduced Static Electricity Buildup
M 7063
SEE ATTACHED MILL TRIAL DATA
UCC 003656
RETENTION OF TITANIUM DIOXIDE IN BOND PAPER
Purpose of Trial: Improve Titanium Dioxide Retention to effect either material cost savings or improve the opacity of 37 lb. Bond produced by this paper company.
Type of Paper Machine: Open Fourdrinier -- 126" Trim -- machine speed 700 ft./min.
Production rate: 70 tons per day.
Furnish (in use):
18% Hardwood-Sulfite ... 26% Softwood-Sulfite .... 56% Softwood-Kraft......
Additives* 1.6% Talc.....................
13.0% Gay............. ........ 0.4% Emulsified Wax ... 3.0% Titanium Dioxide
Furnish Change During Trial:
no change no change no change
2.4% Asbestos no change to 10.6% Gay no change to 2.4% (Post trial retention data indicated that 1% Ti02 could have been removed without a loss in opacity).
Savings Resulting From Improved TiOa Retention: Reduction of Ti0a: 1 % of 70 tons of paper per day = $350/day savings. Cost of 2.4% asbestos (3e/lb. due to 24/lb. clay reduction) $100/day Net savings per day due to asbestos retention of Ti0a........................ $250 or $3.60/ton paper Annual Savings ...................................................................................... $37,800 These savings are for this one grade being produced 150 days per year. Actually this company has other grades where the same results may be obtained.
Other Gains associated with this mill evaluation:
1. Saveall Effluent was improved in clarity. This unit was handling an estimated one million gallons of excess white water per day and the use of 2.4% asbestos allowed a 35% reduction of solids passing to the sewer. This amounts to reduced stream polution and more tons of paper per 100 tons of stock.
2. Closure or more uniform formation was indicated by porosity readings.
3. Opacity values increased during the use of asbestos even though clay and TiO: quantities were reduced as shown above.
4. Smoothness values were improved.
Physical Characteristics of the Bond Paper produced:
Percentage Asbestos: Basis Weight (lbs./300 Ft*) Machine Direction Tensile Cross Direction Tensile Mullen Tear Smoothness (Gain) Opacity (Gain) Brightness Wax Pick Caliper % Ash in the Bond Paper (gain)
`Based on 5050 lb. batch of cellulose fiber
0% 55T 12.6
8.3 20.6 32/33
53 82.5
83 18/16
3.23 10.2
UCC 003657
1% TH5 13.0
8.0 20.8 30/33
32 83 82-83 18/18 3.09 11.3
a.4% "50
13.8 6.5 22.0 34/36 31 84-84.5 82 18/18 3.10 12.4
A 1 7064
APPLICATION RETENTION AID IN PAPER MILL SAVEALL OPERATION
OBJECT: REDUCE SOLIDS LOSSES AND REDUCE RIVER POLLUTION
TYPE OF SAVEALL: OLIVER DRUM TYPE FILTER WITH STAINLESS 60/40 MESH WIRE USING FRESH CELLULOSE PULP AS A FILTER AID.
MATERIAL TO BE RECLAIMED FROM EXCESS WHITE WATER RETURNED FROM THE PAPER MACHINE
1. Titanium Dioxide 2. Clay 3. Cellulose fines
4. Starch 5. Dye particles
Data for the operation:
Production rate of Paper Machine: 60 tons/day Machine Speed: 800 fpm Wire mesh -- 75x58
Total Filler Content: 6.25% (1.25% Ti0L.; 2.5% clay; 2.5% starch) Furnish: 50% Magnifite Hardwood
30% Softwood Draft-Spruce 20% Broke pH 5.0 with Alum
REDUCTION OF SOLIDS LOSSES USING HIGH PURITY ASBESTOS:
% Asbestos
Flow Rate (GPH) Average Solids in lbs./1000 gals. Number of days/year for this particular condition Value of Material $/ton
1,000,000 3.25 200 100
1,000,000 0.55 200 100
ANNUAL SAVINGS RESULTING FROM THE USE OF ASBESTOS: S2T000
UCC 003658 A 1706b
APPLICATION--RETENTION OF FlUBtS Novel Paper No. 22 for Color Books
Purpose: Improving Retention of Fillers for Improved Opacity, and for Material Savings.
Type Paper Machine: Open-Fourdrinier
1 Machine Trim: 132"
Production Rate: 150 tons per day
j Machine Speed: 804 F.P.M.
Systems pH: 4.5 - 5.0
Basis Weight: 32 lb./1000 ft.1
Furnish:
Prior to nw of Atbwlm
80% Groundwood 20% Unbleached sulfite
5% Georgia clay 0.3% Tetrasodium Polyphosphate 0.4% Zinc Hydrosulfite 0.3% Alum 2.8% Zeolex
0% Asbestos
with 2% Aibwlw
80% 20%
5% 0.3% 0.4% 0.3%
0% 2.2% -- added
Other additives to the headbox: Kymene 557 -- 1.7%.
Retention Results: % Asbestos % Clay % Total ash % Increase due to asbestos (clay retention) % Increase due to asbestos (total ash)
0
24 30
39 43 62% 43
\ f
Paper Tests with and without Asbestos:
Basis Weight (lbs./3000 ft.2) % Ash % Opacity Two-sidedness
0% Aabtilm
32 4.4
92.9 1 pt.
2.2% AabeitM
32 6.5
93.6 0 - 0.5 pts.
Economic Gain and Quality Improvements: 1. High Purity Asbestos (2.2%) replaced 2.8% Zeolex with an immediate cost advantage. With a production rate
of 140 ton/day, Zeolex was being used at a cost of $548/day white its replacement. High-Purity Asbestos, cost $308/day, yielding a savings of $240/day. The asbestos also caused an increase in clay retention: a 0.7 pt. opacity gain was achieved allowing either improved quality, or an additional estimated savings of $390/day if normal specifications are held. Final result was a total daily savings of $680/day.
2. Reduced two-sidedness during the use of High-Purity Asbestos also gave an improved paper product.
A 17066
UCC 003659