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SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE SECTION 1- PRODUCT AND COMPANY IDENTIFICATION Material Name: ARCTIC U.S. TYPE 3 (3%) MILSPEC AFFF FOAM CONCENTRATE, ARCTIC 3% MILSPEC AFFF FOAM CONCENTRATE Synonyms: ARCTIC U.S. TYPE 3 (3%) MILSPEC; ARCTIC U.S. TYPE 3 MILSPEC AFFF; ARCTIC U.S. TYPE 3 MILSPEC; ARCTIC TYPE 3 (3%) MILSPEC, ARCTIC 3% MILSPEC AFFF; ARCTIC 3% MILSPEC; 3% MILSPEC AFFF Product Description: Mixture. Product Use: Fire Suppression Agent, Liquid Concentrate. Restrictions on Use: None known. Details of the supplier of the safety data sheet: The Solberg Company 1520 Brookfield Avenue Green Bay, Wisconsin 54313 USA Phone:+1 920 593 9445 Emergency Phone: +1 920 593 9445 E-mail: sds@solbergfoam.com SECTION 2 - HAZARDS IDENTIFICATION Classification in accordance with paragraph (d) of 29 CFR 1910.1200.: Serious Eye Damage/Eye Irritation - Category 2A GHS Label Elements: Symbol(s) Signal Word Warning Hazard Statement(s) Causes serious eye irritation. Precautionary Statement(s) Prevention Wear eye protection/face protection. Wash thoroughly after handling. Page 1 of 11 S-017 Issue date: 2016-01-01 Formulation No: 2232015 US00005616 SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage None needed according to classification criteria. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS CAS Not available 112-34-5 142-31-4 64-17-5 107-21-1 Component Name Non-hazardous ingredients Diethyleneglycol butyl ether Sodium octyl sulfate Ethyl alcohol Ethylene glycol Percent 60-90 10-20 1-10 1-5 1-5 Description of Necessary Measures: No special measures are necessary. Inhalation: If adverse effects occur, remove to uncontaminated area. Call a POISON CENTER or doctor if you feel unwell. Skin: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Eyes: Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. If eye irritation persists: Get medical advice/attention. Ingestion: If swallowed, get medical attention. Do NOT induce vomiting. Most Important Symptoms/Effects: Acute Causes serious eye irritation. Delayed No information on significant adverse effects. Page 2 of 11 Issue date: 2016-01-01 Revision 1.0 Formulation No: 2232015 US00005617 SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE SECTION 5 - FIRE FIGHTING MEASURES Extinguishing Media: Suitable Extinguishing Media Not applicable as this is a fire suppression agent. Unsuitable Extinguishing Media None known. Special Hazards Arising from the Chemical Negligible fire hazard. Hazardous Combustion Products Under certain extreme conditions there may be release of toxic and/or corrosive gases: oxides of nitrogen, oxides of carbon, oxides of sulfur, hydrogen fluoride. Fire Fighting Measures Move container from fire area if it can be done without risk. Cool containers with water. Dike for later disposal. Avoid inhalation of material or combustion by-products. Special Protective Equipment and Precautions for Firefighters Wear protective clothing and equipment suitable for the surrounding fire. SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures: Wear personal protective clothing and equipment, see Section 8. Methods and Materials for Containment and Cleaning Up: Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if safe to do so. Collect spilled material in appropriate containerfor disposal. Environmental Precautions: Prevent entry into waterways, sewers, basements, or confined areas. Dispose of waste in accordance with environmental legislation. SECTION 7 - HANDLING AND STORAGE Precautions for Safe Handling: Wear protective eye/face protection. Wash thoroughly after handling. Conditions for Safe Storage, Including any Incompatibilities: None needed according to classification criteria. Further information on storage conditions: Keep only in original packaging or containers approved by the manufacturer. Do not mix with other extinguishing agent unless otherwise approved by the manufacturer. Page 3 of 11 S-017 Issue date: 2016-01-01 Formulation No: 2232015 US00005618 SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE Incompatible Materials: Electrically energized equipment, strong oxidizing agents, water-reactive materials. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits: Diethvlene glycol butyl ether ' 112-34-5 ACGIH: 10 ppm TWA inhalable fraction and vapor Europe: 10 ppm TWA; 67.5 mg/m3 TWA 15 ppm STEL; 101.2 mg/m3 STEL Ethvl alcohol 64-17-5 ACGIH: 1000 ppm STEL NIOSH: 1000 ppm TWA; 1900 mg/m3 TWA 3300 ppm IDLH (10% LEL) OSHA (US): 1000 ppm TWA; 1900 mg/m3 TWA Mexico: 1000 ppm TWA LMPE-PPT; 1900 mg/m3 TWA LMPE-PPT Ethvlene elvcol 107-21-1 ACGIH: 100 mg/m3 Ceiling aerosol only Europe: 20 ppm TWA; 52 mg/m3 TWA Possibility of significant uptake through the skin 40 ppm STEL; 104 mg/m3 STEL Mexico: 100 mg/m3 Ceiling aerosol EU - Occupational Exposure (98/24/EC) - Binding Biological Limit Values and Health Surveillance Measures There are no biological limit values for any of this product's components. ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI) There are no biological limit values for any of this product's components. Engineering Controls Ensure compliance with applicable exposure limits. If necessary, use appropriate local exhaust ventilation to keep exposures below the regulated limits. Individual Protection Measures, such as Personal Protective Equipment Eye/face protection Wear splash resistant safety goggles. Page 4 of 11 Issue date: 2016-01-01 Revision 1.0 Formulation No: 2232015 US00005619 SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE Skin Protection Wear suitable protective clothing such as coveralls or long sleeve shirt and pants. Respiratory Protection No respirator is required under normal conditions of use. Glove Recommendations Wear suitable gloves: nitrile, latex, rubber gloves. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear light yellow liquid Physical State Liquid Odor Odor Threshold Mild Not available Color pH Light yellow 7-8 Melting Point Not available Boiling Point Not available Freezing point Not available Evaporation Rate Not available Boiling Point Range Not available Flammability (solid, gas) Not available Autoignition Not available Flash Point Does not flash Lower Explosive Limit Not available Decomposition Not available Upper Explosive Limit Not available Vapor Pressure Not available Vapor Density (air=l) Not available Specific Gravity (water=l) 1.009-1.049 WaterSolubility Complete Partition coefficient: n-octanol/water Not available Viscosity 2 - 20 cSt Solubility (Other) Not available Density Not available Molecular Weight Not available Other Information: No information is available. SECTION 10 - STABILITY AND REACTIVITY Reactivity: No hazardous reaction when handled and stored according to provisions. Chemical Stability: Stable under normal conditions of use. Conditions to Avoid: None known. Page 5 of 11 S-017 Issue date: 2016-01-01 Formulation No: 2232015 US00005620 SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE Incompatible Materials: Electrically energized equipment, strong oxidizing agents, water-reactive materials. Hazardous decomposition products: None known. Thermal decomposition products Under certain extreme conditions there may be release of toxic and/or corrosive gases: oxides of carbon, oxides of sulfur, oxides of nitrogen, hydrogen fluoride. SECTION 11 - TOXICOLOGICAL INFORMATION Acute and Chronic Toxicity: Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published: Diethvlene glycol butyl ether (112-34-5) Oral LD50 Rat 5660 mg/kg Dermal LD50 Rabbit 2700 mg/kg Sodium octyl sulfate (142-31-4) Oral LD50 Rat 3200 mg/kg Water (7732-18-5) Oral LD50 Rat >90 mL/kg Ethyl alcohol (64-17-5) Oral LD50 Rat 7060 mg/kg Inhalation LC50 Rat 124.7 mg/L 4 h Ethylene glycol (107-21-1) Oral LD50 Rat 4700 mg/kg Dermal LD50 Rat 10600 mg/kg Immediate Effects Causes serious eye irritation. Delayed Effects No information on significant adverse effects. Irritation/Corrosivity Data Causes serious eye irritation. Causes mild skin irritation. Respiratory Sensitization No information available for the product. Dermal Sensitization No information available for the product. Component Carcinogenicity: Ethyl alcohol 164-17-5 ACGIH: i A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans Page 6 of 11 Issue date: 2016-01-01 Revision 1.0 Formulation No: 2232015 US00005621 SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE DFG: i Category 5 (low carcinogenic potency) Ethylene glycol 107-21-1 ACGIH: A4 - Not Classifiable as a Human Carcinogen Germ Cell Mutagenicity No information available for the product. Tumorigenic Data No information available for the product. Reproductive Toxicity No information available for the product. Specific Target Organ Toxicity - Single Exposure No information available for the product. Specific Target Organ Toxicity - Repeated Exposure No information available for the product. Aspiration hazard No information available for the product. Medical Conditions Aggravated by Exposure No information available for the product. SECTION 12 - ECOLOGICAL INFORMATION Component Analysis - Aquatic Toxicity: Fish: Algae: Invertebrate: Ethyl alcohol Fish: Invertebrate: Ethylene glycol Fish: LC50 96 h Lepomis macrochirus 1300 mg/L [static] EC50 96 h Desmodesmus subspicatus >100 mg/L IUCLID EC50 48 h Daphnia magna >100 mg/L IUCLID 64-17-5 LC50 96 h Oncorhynchus mykiss 12 -16 mL/L [static]; LC50 96 h Pimephales promelas >100 mg/L [static]; LC50 96 h Pimephales promelas 13400 - 15100 mg/L [flow-through] LC50 48 h Daphnia magna 9268- 14221 mg/L IUCLID; EC50 48 h Daphnia magna 2 mg/L [static] EPA 107-21-1 LC50 96 h Oncorhynchus mykiss 41000 mg/L; LC50 96 h Oncorhynchus mykiss 14 -18 mL/L [static]; LC50 96 h Lepomis macrochirus 27540 mg/L [static]; LC50 96 h Oncorhynchus mykiss 40761 mg/L [static]; LC50 96 h Pimephales promelas 40000 - 60000 mg/L [static]; LC50 96 h Poecilia reticulata 16000 mg/L [static] Page 7 of 11 S-017 Issue date: 2016-01-01 Formulation No: 2232015 US00005622 SOLBEIG SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE Algae: Invertebrate: i EC50 96 h Pseudokirchneriella subcapitata 6500- 13000 mg/L IUCLID i EC50 48 h Daphnia magna 46300 mg/L IUCLID Persistence and Degradability No information available for the product. Bioaccumulative Potential No information available for the product. Mobility No information available for the product. Other Toxicity No additional information is available. SECTION 13 - DISPOSAL CONSIDERATIONS Disposal Methods: Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 14 - TRANSPORT INFORMATION US DOT Information: UN/NA #: Not regulated as dangerous goods. IATA Information: UN#: Not regulated as dangerous goods. IMDG Information: UN#: Not regulated as dangerous goods. TDG Information: UN#: Not regulated as dangerous goods. SECTION 15 - REGULATORY INFORMATION U.S. Federal Regulations: Diethvlene glycol butyl ether SARA 313: Ethylene glycol SARA 313: 112-34-5 1 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substituted phenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, Chemical Category N230) (related to Glycol ethers) 107-21-1 1 % de minimis concentration Page 8 of 11 Issue date: 2016-01-01 Revision 1.0 Formulation No: 2232015 US00005623 DcmULDDCttDxuC SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE CERCLA: : 5000 lb final RQ; 2270 kg final RQ U.S. State Regulations: The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA Diethyleneglycol butyl ether 112-34-5 No No No 1^es Yes Water 7732-18-5 No No No No Yes Ethyl alcohol 64-17-5 Yes Yes Yes Yes Yes Ethylene glycol 107-21-1 Yes Yes Yes Yes Yes The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer and/or reproductive/developmental effects: 'I................................................................................................. Ethyl alcohol 64-17-5 Care: i carcinogen , 4/29/2011 (in alcoholic beverages) Repro/Dev. Tox developmental toxicity, 10/1/1987 (in alcoholic beverages) Ethylene glycol 107-21-1 Repro/Dev. Tox developmental toxicity, 6/19/2015 (ingested) Canadian WHMIS Ingredient Disclosure List (IDL): Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL. Diethvlene elvcol butyl ether 112-34-5 1% Ethyl alcohol 64-17-5 0.1 % Ethylene elvcol 107-21-1 1% Page 9 of 11 S-017 Issue date: 2016-01-01 Formulation No: 2232015 US00005624 acmULDDCtiDtlCl SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE Component Analysis - Inventory: Diethyleneglycol butyl ether(112-34-5) US CA EU AU PH J P - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX TW Yes DSL EIN Yes Yes : Yes : Yes i Yes No Yes Yes Yes Yes Sodium octyl sulfate (142-31-4) US CA EU AU PH JP-ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX TW Yes DSL EIN Yes Yes : Yes No i Yes No Yes Yes No Yes Water (7732-18-5) US CA EU AU PH JP-ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX TW Yes DSL EIN Yes Yes No No i Yes No Yes Yes Yes Yes Ethyl alcohol (64-17-5) US CA EU AU PH JP-ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX TW Yes DSL EIN Yes Yes : Yes No i Yes No Yes Yes Yes Yes Ethylene glycol (107-21-1) US CA EU AU PH JP-ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX TW Yes DSL EIN Yes Yes ; Yes No ( Yes No Yes Yes Yes Yes SECTION 16 - OTHER INFORMATION HMIS Rating Health: 2 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard NFPA Ratings Health: 2 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Summary of Changes New SDS: 01-January-2016 Key / Legend ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CLP - Classification, Labelling, and Packaging; CN - China; CPR Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD Dangerous Substance Directive; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F Fahrenheit; IARC - International Agency for Research on Cancer; IATA- International Air Transport Association; ICAO International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Page 10 of 11 Issue date: 2016-01-01 Revision 1.0 Formulation No: 2232015 US00005625 DcmULDDCttDxuC SAFETY DATA SHEET- ARCTICTM U.S. TYPE 3 (3%) MIL SPEC AFFF FOAM CONCENTRATE Explosive Limit; LLV - Level Limit Value; LOLI - List Of ListsTM - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA- National Fire Protection Agency; NIOSH National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA- Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US United States. Other Information: Disclaimer: Safety data sheet is for concentrate as received NOT for end-use solution. Page 11 of 11 S-017 Issue date: 2016-01-01 Formulation No: 2232015 US00005626