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Safety Data Sheet
This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)
Product name SI-AR-NFF 3X3 BULK BLEND (R&D only -- not for commercial sale)
1. Identification
1.1. Product Identifier Product name
SI-AR-NFF 3X3 BULK BLEND (R&D only -- not for commercial sale)
1.2. Other means of identification Product code Synonyms Chemical Family
452574 None No information available
1.3. Recommended use of the chemical and restrictions on use
Recommended use
Fire extinguishing agent.
Uses advised against
Consumer use.
1.4. Details of the Supplier of the Safety Data Sheet
Company Name
Tyco Fire Protection Products
One Stanton Street
Marinette, WI 54143-2542
Telephone:
Contact point
Product Stewardship at 1-
E-mail address
@tycofp.com
1.5. Emergency Telephone Number
Emergency telephone
CHEMTREC 001-
or 001
2. Hazards Identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation - Category 1
2.2. Label Elements
Signal Word DANGER
Hazard Statements Causes serious eye damage
Precautionary Statements
Revision date 03-Feb-2021
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Prevention Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
2.3. Hazards Not Otherwise Classified (HNOC) Not Applicable.
2.4. Other Information
3. Composition/information on Ingredients
3.1. Mixture The following component(s) in this product are considered hazardous under applicable OSHA(USA)
4. First aid measures
4.1. Description of first aid measures
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Skin contact
Wash skin with soap and water. Get medical attention if irritation develops and persists.
Inhalation
Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).
Ingestion
Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.
4.2. Most Important Symptoms and Effects, Both Acute and Delayed
Symptoms
No information available.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
Note to physicians
Treat symptomatically.
5. Fire-fighting measures
5.1. Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
5.2. Unsuitable Extinguishing Media None.
5.3. Specific Hazards Arising from the Chemical No information available.
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5.4. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None.
5.5. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal Precautions
Ensure adequate ventilation, especially in confined areas.
For emergency responders
Use personal protection recommended in Section 8.
6.2. Environmental Precautions
Environmental Precautions
See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up
Pick up and transfer to properly labeled containers.
7. Handling and Storage
7.1. Precautions for Safe Handling
Advice on safe handling
Ensure adequate ventilation, especially in confined areas. Use personal protective equipment as required. Use with local exhaust ventilation. Do not breathe dust/fume/gas/mist/vapors/spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
Strong oxidizing agents. Strong acids. Strong bases.
8. Exposure Controls/Personal Protection
8.1. Control Parameters Exposure guidelines
ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the US Department of Labor) NIOSH IDLH Immediately Dangerous to Life or Health
8.2. Appropriate Engineering Controls
Engineering controls
Ensure adequate ventilation, especially in confined areas.
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8.3. Individual protection measures, such as personal protective equipment
Eye/Face Protection
Avoid contact with eyes. Tight sealing safety goggles.
Skin and Body Protection
Wear protective gloves and protective clothing.
Respiratory Protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
Ventilation
Use local exhaust or general dilution ventilation to control exposure with applicable limits
8.4. General hygiene considerations Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Physical State Odor Odor Threshold
Liquid Characteristic No data available
Color
Light yellow
Property pH Melting point/freezing point Boiling point / boiling range Flash Point Evaporation Rate Flammability (solid, gas) Flammability limit in air
Upper flammability limit: Lower flammability limit: Vapor Pressure Vapor Density Specific gravity Water Solubility Solubility in Other Solvents Partition coefficient Autoignition Temperature Decomposition Temperature Kinematic viscosity
Values 7.5 - 8.5 No data available No data available No data available No data available No data available
No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available
Remarks Method
VOC content (%)
9.715
10. Stability and Reactivity
10.1. Chemical Stability
Stable under recommended storage conditions.
10.2. Reactivity
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No data available
10.3. Possibility of hazardous reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
10.4. Conditions to Avoid
Extremes of temperature and direct sunlight.
10.5. Incompatible Materials
Strong oxidizing agents. Strong acids. Strong bases.
10.6. Hazardous decomposition products
Oxides of sulfur. Carbon oxides. Nitrogen oxides (NOx).
11. Toxicological Information
11.1. Information on Likely Routes of Exposure
Product information
No data available
Inhalation
No data available.
Eye Contact
Corrosive to the eyes and may cause severe damage including blindness.
Skin contact
No data available.
Ingestion
No data available.
Component Information Acute Toxicity
11.2. Information on Toxicological Effects
Symptoms
No information available.
11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure
Serious eye damage/eye irritation Risk of serious damage to eyes.
Carcinogenicity
No information available.
Reproductive Toxicity
No information available.
STOT - Single Exposure
No information available.
STOT - Repeated Exposure
No information available.
Aspiration Hazard
No information available.
11.4. Numerical Measures of Toxicity - Product information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
29172 mg/kg
ATEmix (dermal)
47645 mg/kg
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ATEmix (inhalation-dust/mist) 66.6 mg/l
12. Ecological Information
12.1. Ecotoxicity
Chemical name 2-(2-Butoxyethoxy)ethanol
112-34-5 1,2-Propanediol
57-55-6
Sodium chloride 7647-14-5
1-Octanol 111-87-5
Glycerol 56-81-5 Cocoamidopropyl dimethyl amine 68140-01-2 Ethylene Diamine Tetraacetic Acid, Sodium Salt 64-02-8 Sodium Hydroxide 1310-73-2 Cyclotetrasiloxane 2,2,4,4,6,6,8,8-octamethyl556-67-2 1,4-Dioxane 123-91-1
Ethylene oxide 75-21-8
Algae/aquatic plants EC50 (96h) > 100 mg/L Desmodesmus subspicatus EC50 (96h) = 19000 mg/L Pseudokirchneriella subcapitata
-
EC50 (48h) static = 14 mg/L Desmodesmus subspicatus
EC50 (72h) = 1.01 mg/L Desmodesmus subspicatus -
-
Fish
Crustacea
LC50 (96h) static = 1300 mg/L EC50 (48h) > 100 mg/L Daphnia
Lepomis macrochirus
magna EC50 (24h) = 2850 mg/L
Daphnia magna
LC50 (96h) static = 51600 mg/L EC50 (48h) Static > 1000 mg/L
Oncorhynchus mykiss LC50 (96h) Daphnia magna EC50 (24h) >
static = 51400 mg/L Pimephales
10000 mg/L Daphnia magna
promelas LC50 (96h) = 710 mg/L
Pimephales promelas LC50 (96h)
static 41 - 47 mL/L Oncorhynchus
mykiss
LC50 (96h) flow-through 4747 - EC50 (48h) Static 340.7 - 469.2
7824 mg/L Oncorhynchus mykiss mg/L Daphnia magna EC50 (48h) =
LC50 (96h) semi-static = 7050 mg/L 1000 mg/L Daphnia magna
Pimephales promelas LC50 (96h)
static = 12946 mg/L Lepomis
macrochirus LC50 (96h) static 6020
- 7070 mg/L Pimephales promelas
LC50 (96h) flow-through 5560 -
6080 mg/L Lepomis macrochirus
LC50 (96h) static 6420 - 6700 mg/L
Pimephales promelas
LC50 (96h) static = 17.68 mg/L EC50 (24h) 15 - 26 mg/L Daphnia
Oncorhynchus mykiss LC50 (96h)
magna
flow-through 11.4 - 12.9 mg/L
Pimephales promelas
LC50 (96h) static 51 - 57 mL/L EC50 (24h) > 500 mg/L Daphnia
Oncorhynchus mykiss
magna
-
EC50 (48h) = 0.4 mg/L Daphnia
magna
LC50 (96h) static = 41 mg/L
EC50 (24h) = 610 mg/L Daphnia
Lepomis macrochirus LC50 (96h)
magna
static = 59.8 mg/L Pimephales
promelas
LC50 (96h) static = 45.4 mg/L
-
Oncorhynchus mykiss
LC50 (96h) > 500 mg/L
EC50 (24h) = 25.2 mg/L Daphnia
Brachydanio rerio LC50 (96h) >
magna
1000 mg/L Lepomis macrochirus
LC50 (96h) static > 10000 mg/L EC50 (48h) Static = 163 mg/L water
Lepomis macrochirus LC50 (96h)
flea
semi-static > 10000 mg/L Lepomis
macrochirus LC50 (96h)
flow-through = 9850 mg/L
Pimephales promelas LC50 (96h)
static 10306 - 14742 mg/L
Pimephales promelas LC50 (96h) =
9850 mg/L Pimephales promelas
LC50 (96h) 73 - 96 mg/L
LC50 (48h) 137 - 300 mg/L
Pimephales promelas
Daphnia magna
12.2. Persistence and Degradability _____________________________________________________________________________________________
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No information available.
12.3. Bioaccumulation No information available.
12.4. Other Adverse Effects No information available
13. Disposal Considerations
13.1. Waste Treatment Methods Disposal of wastes
Contaminated Packaging
This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.
Do not reuse container.
14. Transport Information
DOT TDG MEX ICAO (air) IATA IMDG
NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED
15. Regulatory Information
15.1. International Inventories TSCA DSL/NDSL ENCS IECSC KECL PICCS AICS
Complies Complies Does not comply Complies Does not comply Does not comply Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances
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PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
15.2. US Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical name 2-(2-Butoxyethoxy)ethanol - 112-34-5
SARA 311/312 Hazard Categories Acute Health Hazard Chronic health hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard
SARA 313 - Threshold Values % 1.0
No No No No No
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
15.3. US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals
Chemical name Sodium O-Phenylphenate - 132-27-4
1,4-Dioxane - 123-91-1 Ethylene oxide - 75-21-8
U.S. State Right-to-Know Regulations
California Proposition 65 Carcinogen
Carcinogen
Carcinogen Developmental Female Reproductive Male Reproductive
Chemical name 2-(2-Butoxyethoxy)ethanol
112-34-5
1,2-Propanediol 57-55-6
1,4-Dioxane 123-91-1
Ethylene oxide 75-21-8
New Jersey X
X
X
X
Massachusetts -
-
X
X
Pennsylvania X
X
X
X
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16. Other information, including date of preparation of the last revision
NFPA HMIS
Health Hazards 0 Health Hazards 0
Flammability 0 Flammability 0
Instability 0 Physical Hazards 0
Physical and chemical properties Personal Protection X
Revision date 03-Feb-2021 Revision note No information available. Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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Revision date 03-Feb-2021
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