Document rp2ge3YrzEmxGzap3jLZbeJOa

> PAGE I MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION PLASTICS & ADDITIVES DIVISION THREE SKYLINE DRIVE HAWTHORNE, NEW YORK 1053Z EMERGENCY PHONE NUMBERS. SAFETY/HEALTH. (914) 347-4700 AFTER HOURS i (800) 334-9481 SECTION I-IDENTITY INFORMATION V IDENTITY (TRADENAME)i IRGANOX 565 FAMILY/CHEMICAL NAMEi 4-((4,6-BIS(OCTYLTHIO)-S-TRIAZIN-2-YL)AMINO)-Z,6-DI-TERTBUTYLPHENOL, CAS REG. NO. 991-84-4 PRODUCT TYPE: ANTIOXIDANT/STABILIZER. IMPORTANT: PLEASE NOTE: REVISION 07 - SECTION VII REVISED. XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX x THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X X FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X X ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X X SPECIFICALLY INTENDED. BECAUSE OF THEWIDE RANGE OF X X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE x X TO RECOMMEND THIS MATERIAL AS SAFE ANDEFFECTIVE FOR X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX HAZARD STATEMENT : XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X x PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X COMMUNICATION STANDARD 29 CFR 1910.1200. X X X THIS PRODUCT IS NOT CONSIDERED TO BE A HAZARDOUS X x CHEMICAL UNDER THAT STANDARD. x XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX SECTION II-HAZARDOUS INGREDIENTS NONE KNOWN IRGANOX 565 D 085141 CONFTDFNTIAI PAGE 2 SECTION III-PHYSICAL DATA APPEARANCE. WHITE TO OFF-WHITE, CRYSTALLINE POWDER. ODOR. ODORLESS. BOILING POINT. NOT DETERMINED. MELTING POINT. 91-96C DECOMPOSITION TEMPERATURE. >220C. EVAPORATION RATE. NOT APPLICABLE. PERCENT VOLATILE. < 0.5X. VAPOR DENSITY. NOT APPLICABLE. VAPOR PRESSURE. AT 20C, CA. 1 X 10(-10) (MM HG) SOLUBILITY IN WATER. AT 20C, INSOLUBLE PH. NOT APPLICABLE. SPECIFIC GRAVITY. 1.1 CH20 = 1) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT. 545F (MARCUSSON) FLAMMABLE LIMITS IN AIR-LOWER. NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER. NOT DETERMINED. NFPA CODE. NONE. EXTINGUISHING MEDIA. CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL. USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS. DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ________________________ SECTION V-REACTIVITY DATA ______________ STABILITY. STABLE. INCOMPATIBILITY. STRONG OXIDIZING AGENTS. .HAZARDOUS DECOMPOSITION PRODUCTS. THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON IRGANOX 565 DO 08514? CONFIDENTIAL, ! PAGE 3 g MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES AND SULFUR OXIDES. V HAZARDOUS POLYMERIZATIONi MILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE: DERMAL, INGESTION, AND INHALATION. THRESHOLD LIMIT VALUEt NONE ESTABLISHED. ORAL LD50 > (RATS) >5000 MG/KG DERMAL LD50i (RABBITS) >2000 MG/KG SKIN IRRITATION! (RABBITS) MINIMAL (DRAIZE SCORE 0.1/8) EYE IRRITATION! (RABBITS) MINIMAL (DRAIZE SCORE Z.7/110) SENSITIZATION: (GUINEA PIGS) MILD SENSITIZER IN A MODIFIED MAXIMIZATION TEST (3/20 ANIMALS POSITIVE). RIPT (HUMANS) NOT A PRIMARY IRRITANT AND NO EVIDENCE OF SENSITIZATION UNDER THE CONDITIONS OF THE STUDY; A 0.5% SOLUTION IN DIMETHYL PHTHALATE WAS TESTED. INHALATION LC50: (RATS) >1 MG/L AIR FOR A 4-HOUR AEROSOL EXPOSURE WITH 9OF PARTICLES <7 MICRONS. TERATOGENICITY: (RATS)i ND EVIDENCE OF TERATOGENICITY OR OF SIGNIFICANT EFFECTS ON EMBRYO-FETAL DEVELOPMENTS. MUTAGENICITY: AMES TEST: NEGATIVE NUCLEUS ANOMALY TEST, CHINESE HAMSTERS: NO EVIDENCE OF MUTAGENIC EFFECTS SISTER CHROMATID EXCHANGE STUDY, CHINESE HAMSTERS: NO INDICATION OF MUTAGENIC EFFECTS CELL TRANSFORMATION ASSAY: NO TRANSFORMATIVE PROPERTIES OBSERVED SIGNS AND SYMPTOMS OF EXPOSURE-ACUTE: NO IDENTIFIED HEALTH EFFECTS. SIGNS AND SYMPTOMS OF EXPOSURE-CHRONIC: NO IDENTIFIED HEALTH EFFECTS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN. EMERGENCY AND FIRST AID PROCEDURES-EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKIN: WASH WITH MILD SOAP AND WATER. EMERGENCY AND FIRST AID PROCEDURES-INGESTION< IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATION. IRGANOX 565 085143 confidential PAGE 4 REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHER. WASH CONTAMINATED CLOTHING PRIOR TO REUSE. ________________________ SECTION VII-SPILL OR LEAK PROCEDURES SPILL PROCEDURES! SWEEP OR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. THOROUGHLY FLUSH RESIDUE WITH WATER. WASTE DISPOSAL METHODS DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. EFFLUENT DATA-BOD MODIFIED STURM TESTi NOT BIODEGRADABLE AEROBIC SEWAGE OECD COUPLED UNITS TEST NO. 303Ai AVERAGE ELIMINATION MEASURED BY SPECIFIC ANALYSIS WAS 47.3% OF THE INITIALLY MEASURED CONCENTRATION. EFFLUENT DATA-CODi 2.41 G. COD/G. FISH TOXICITY: ZEBRA FISH, LC50 96 Hi >100 PPM INVERTEBRATE TOXICITYi DAPHNIA MAGNA, EC50 24 Hi >37 PPM ________________________ SECTION VIII-SPECIAL PROTECTION INFORMATION VENTILATIONi USE LOCAL EXHAUST FOR DUSTY USE CONDITIONS. PROTECTIVE GLOVESi WEAR IMPERVIOUS GLOVES AS A STANDARD HANDLING PROCEDURE. EYE PROTECTION! WEAR SAFETY GLASSES OR GOGGLES TO PROTECT AGAINST DUST PARTICLES. RESPIRATORY PROTECTION: USE NIOSH APPROVED DUST MASK, IF REQUIRED. OTHER PROTECTIVE EQUIPMENTi WEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HANDLING PRECAUTIONS! IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE, HANDLE WITH CARE AND AVOID UNNECESSARY PERSONAL CONTACT. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED SKIN CONTACT. AVOID CONTINUOUS OR REPETITIVE BREATHING OF DUST. USE ONLY WITH ADEQUATE VENTILATION . FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS: KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENEi WASH THOROUGHLY AFTER HANDLING. IRGANOX 565 DO 085144 CONFIDENTIAL PAGE 5 SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OF TRANSPORTATION (DOT) A9 CFR 172.101 HAZARDOUS MATERIALS TABLE. DOT CLASS: NONE. DOT NUMBER: NONE. RCRA STATUS: NOT A HAZARDOUS HASTE UNDER RCRA (AO CFR 261). CERCLA STATUS: NOT LISTED. TSCA INVENTORY STATUS: CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. ISSUE DATE: 06/03/86 REVISION: 07C FOR FURTHER INFORMATION, PLEASE CONTACT: BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. IRGANOX 565 00 085]45 CONFTDFNTrA!,. MAR-06-'92 FRI 10:55 ID:DOU OEM I CAL POLY A TEL NO: FAX 504 389 8765 8800 P06 PAGE 1 MATERIAL SAFETY DATA SHEET C1BA-GEIOY CORPORATION ADDITIVES DIVISION SEVEN SKYLINE DRIVE HAWTHORNE. NEW YORK 1QS32 (914) 347-4700 EMEROCNCY PHONE NUMBERi (500) 535-5372 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME)i XRGANOX 1076 FAMILY/CHEMICAL NAME* OCTADECYL 5, iCAS REG. NO. PRODUCT TYPE* ANTIOXIDANT IMPORTANT* UTYL-4-HYDROXYHYDROCINNAMATE PIEA5E NOTE* REVISION 05 - SECTION XX REVISED. XXKXXXXXXXKXXXXXKKXXXXKXXXXXK X THIS MATERIAL WILL NOT 3E SOLD FOR USE IN PRODUCTS x FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X ABRADED SKIN. OR IMPLANTATION WITHIN THE HUMAN BODY. IS X SPECIFICALLY INTENDED. BECAUSE OF THE WIDE RANGE OF X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE X TO RECOMMEND THIS MATERIAL AS SAFE AND EFFECTIVE FOR X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. XXXXXXXKXXXKXRXXXKXXXKXXXXRXK HAZARD STATEMENT * XKXXXXXXXKXKXXXXXKXXXXXXKXKXX X THIS MATERIAL SAFETY DATA SHEET (N5DS) HAS BEEN X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X COMMUNICATION STANDARD 29 CFR 1910.1200. X THIS PRODUCT IS NOT CONSIDERED TO BE A HAZARDOUS X CHEMICAL UNDER THAT STANDARD. XKXXXXXXKXXXXXXMXKKXXKKXXXXKX SECTION II-HAZARDOUS INGREDIENTS NONE KNOWN IRGANOX 1076 MAR-06-'92 FRI 10:54 ID: DOLJ CHEMICAL POLY A TEL NO:FPX 504 389 6765 8800 P05 PAGE 2 SECTION III-PHYSXCAL DATA APPEARANCE! WHITE TO OFF-HHITE, CRYSTALLINE POWDER. ODOR* ODORLESS. BOILING POINTi NOT DETERMINED. WELTING POINTi 50-55C DECOMPOSITION TEMPERATURE! >220C. EVAPORATION RATE* NOT APPLICABLE. PERCENT VOLATILE* <1 VAPOR DENSITY* NOT APPLICABLE. VAPOR PRESSURE* AT 20C# CA. 2 X IOC-9) CMM HO) SOLUBILITY IN HATERi AT 25C# INSOLUBLE PH* NOT APPLICABLE. SPECIFIC ORAVITYi CA. 1.02 (H20 1) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT* 523F (MARCUSSON) FLAMMABLE LIMITS IN AIR-LOWER* NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER* NOT DETERMINED. NFPA CODE* NONE. EXTINGUISHING MEDIA* CARBON DIOXIDE# FOAM# DRY CHEMICAL# WATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL. USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS* THE PRODUCT CAN FORM AN EXPLOSIVE DUST/AIR MIXTURE. AVOID DUST FORMATION AND CONTROL IGNITION SOURCES! EMPLOY GROUND ING# VENTING AND EXPLOSION RELIEF PROVISIONS IN ACCORD WITH ACCEPTED ENGINEERING PRACTICES IN PROCESS OPERATIONS CAP ABLE OF GENERATING DUST AND/OR STATIC ELECTRICITY. SECTION V-REACTIVITY DATA STABILITY. STABLE. IRGANOX 1076 DO 085147 CONFIDENTIAL. MAR-06-*92 FRI 10:54 ID:DOU CHEMI CAL POLY A TEL HO: FAX 504 389 8765 8800 P04 PAGE 3 INCOMPATIBILITY! STRONG OXIDIZING AOENTS. HAZARDOUS DECOMPOSITION PRODUCTS. THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE. HAZARDOUS POLYMERIZATION! HILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE! DERMAL, INGESTION. AND INHALATION. THRESHOLD LIMIT VALUEt NONE ESTABLISHED. ORAL LD50i (RATS) >10,000 HQ/KO INTRAPERITONEAL LDSOi (RATS) >1000 MO/KQ DERMAL LD50i (RABBITS) >2000 MG/KO SKIN IRRITATION! (RABBITS) MINIMAL (DRAIZE SCORE 0.95/8) PHOTOTOXICITY! NEGATIVE. EYE IRRITATION! (RABBITS) MINIMAL (DRAIZE SCORE 4/110) SENSITIZATION! (GUINEA PIGS) CONSIDERED TO POSSESS NO SKIN SENSITIZING POTENTIAL. RIPT (HUMANS) IN 4 SEPARATE STUDIES, A TOTAL OP 5 OF 183 SUBJECTS EXHIBITED REACTIONS INDICATIVE OF SENSITIZATION/ CONCENTRATIONS RANGED FROM 25X IN PETROLATUM (25 SUBJECTS), IN DIMETHYL PHTHALATE (58 SUBJECTS), TO NEAT MATERIAL (100 SUBJECTS). INHALATION LCSOi (RAT5) >1.8 MG/L AIR FOR A 4-HOUR DUST EXPOSURE HITH APPROX. 90% OF PARTICLES <7 MICRONS DIAMETER. TERATOGENICITY! (RATS) NO TERATOGENIC EFFECT SEEN. (MICE) NO TERATOGENIC EFFECT SEEN. MUTAGENICITY! AMES TEST: NEGATIVE DOMINANT LETHAL TEST (MOUSE)i NO EVIDENCE OF A DOMINANT LETHAL EFFECT. SIGNS AND SYMPTOMS OF EXPOSURE-ACUTEi CAUTION!! MAY CAUSE IRRITATION TO SKIN, ESPECIALLY AFTER PROLONGED OR REPEATED EXPOSURE, AND ESPECIALLY IN BODY AREAS OF HEAVY PERSPIRATION, BASED UPON USE EXPERIENCE. SIGNS AND SYMPTOMS OF EXPOSURE-CHRONIC! NO IDENTIFIED HEALTH EFFECTS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE! SKIN CONDITIONS. EMERGENCY AND FIRST AID PROCEDURES-EYESi 0.5X IRGANOX 1074 00 085148 CONFTOFNTTAi > MflR-0G-'92 FRI 10:53 JD:DOLJ OEMICflL POLY A TEL NO:FAX 504 389 8765 4800 P03 PAGE A FLUSH EYES HITH HATER FOR AT LEAST IS MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKIN> HASH HITH MILD SOAP AND HATER. EMERGENCY AND FIRST AID PRDCEDURE5-INQE3TI0N* IF CONSCIOUS, GIVE LARGE QUANTITIES OF HATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATION1 REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHER* REMOVE AND HASH CONTAMINATED CLOTHING PRIOR TO REU5E. _______________________ SECTION VII-SPIll OR LEAK PROCEDURES _ SPILL PROCEDURES* PREHET MATERIAL HITH HATER TO AVOID DUST FORMATION. SHEEP OR VACUUM AND PLACE IN CLQSABLE CONTAINER FOR DISPOSAL. HEAR PROTECTIVE EQUIPMENT SPECIFIED BELOH. FLUSH RESIDUE HITH HATER. HASTE DISPOSAL METHODS* INCINERATE IN A CHEMICAL INCINERATOR EQUIPPED HITH AN AFTER BURNER AND SCRUBBER. FOLLOH ALL FEDERAL, STATE AND LOCAL REGULATIONS. EFFLUENT DATA-BOD* (STURM TEST) PARTIALLY BIODEGRADABLE. SEHAOE BACTERIAL TOXICITY* INHIBITORY CONCENTRATION ON RESPIRATION OF AEROBIC HASTE HATER BACTERIA* IC20, IC50, IC80 >100 PPM FISH TOXICITY* BLUEGILL LC 50 (96 HOURS)* >100 PPM RAINBOH TROUT LC 50 (96 HOURS)* >100 PPM INVERTEBRATE TOXICITY* DAPHNIA MAGNA EC50 (24 HOURS)* >100 PPM _______________________ SECTION VIII-SPECIAL PROTECTION INFORMATION ____ VENTILATION* USE LOCAL EXHAUST. GOOD VENTILATION IS REQUIRED TO PRFVENT DUST BUILDUP HHICH MAY RESULT IN HORKER IRRITATION. PROTECTIVE OLOVES* HEAR RUBBER OR PLASTIC OLOVES. EYE PROTECTION* HEAR SAFETY GLASSES OR GOGGLES. RESPIRATORY PROTECTION* USE NIOSH APPROVED DUST MASK. OTHER PROTECTIVE EQUIPMENT* HEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HMIS CODE* HEALTH * 2 HANDLING PRECAUTIONS* FIRE 1 REACTIVITY 1 0 IRGANOX 1076 DO 085149 C0NFTDENTIA1 MAR-06-' 92 FRI 10:53 ID:ECU CHEMICAL POLY A TEL HD:FAX 504 389 8765 #800 P02 PAGE 3 AVOID CONTACT HITH EYES AND PROLONGED OR REPEATED SKIN CONTACT. AVOID CONTINUOUS OR REPETITIVE BREATHINO OF DUST. GOOD INDUSTRIAL ENGINEERING CONTROLS MUST BE EMPLOYED TO PREVENT EXCESS DUSTING IN THE WORK AREAS. DO NOT HANDLE IN SUCH A MANNER AS TO CAUSE EXCESSIVE DUSTING. USE ONLY HITH ADEQUATE VENTILATION. FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS* XEEP CONTAINER TIGHTLY CLOSED HHEH NOT IH USE AND DURING TRANSPORT. PERSONAL HYGIENE* HASH THOROUGHLY AFTER HANDLING. _________________________ SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME* NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OP TRANSPORTATION (DOT) 49 CFR 172.10) HAZARDOUS MATERIALS TABLE. DOT CLASS* NONE. DOT NUMBER* NONE. RCRA STATUS* NOT A HAZARDOUS HASTE UNDER RCRA (40 CFR 261). CERCIA STATUS* NOT LISTED. SARA/TXTLE III - TOXIC CHEMICALS LIST. THIS PRODUCT DOES NOT CONTAIN A TOXIC CHEMICAL FOR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SEC. 515 (40 CFR 572). TSCA INVENTORY STATUS* CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. CALIFORNIA PROPOSITION 65* THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS. MASSACHUSETTS RIQHT-TO-KNOW ACT* CONTAINS NO COMPONENTS ON THE MASSACHUSETTS LIST AT A THRESHOLD LEVEL. NEH JERSEY RIGHT-TO-KNOW LABELING INFORMATION* THIS PRODUCT CONTAINS THE FOLLOHING * CHEMICAL NAME OCTADECYL 5.5-DI-TERT-BUTYL-4-HYDR0XYHYDR0CI NNAMATE CAS NUMBER > 2082-79-3 MMM PENNSYLVANIA RIGHT-TO-KNOH ACT* THE FOLLOHING IS REQUIRED COMPOSITION INFORMATION. CHEMICAL NAME > BENZEHEPROPANOIC ACID. 5.S-B15(1>1-DIMETHYLE THYL)-4-HYDROXY-, OCTADECYL ESTER CAS NUMBER * 2062-79-5 COMMON NAME OCTADECYL 5.5-DI-TERT-BUTYL-4-HYDR0XYHYDR0CI IRGANOX 1076 085150 CONFIDfr NTTA( MAR-06- ' 92 FT? I 10:52 ID:DOU OEM I COL POLY A TEL NQ: FAX 504 309 6765 B000 P01 PAGE < ( NNAMATEf IRGAHOX 1076 COMMENTS NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. UxX ISSUE DATE) 04/05/90 REVISION. 09C FOR FURTHER INFORMATION* PLEASE CONTACT. BRUCE SCMWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER. NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. X IRGANOX 1076 00 085151 ^ONrTDENTTfiil MATERIAL SAFETY DATA SHEET AMOCO ( MANUFACTURER/SUPPLIER: Amoco Chemical Company 200 East Randolph Drive Chicago, Illinois 60601 AMOCO RESIN 1S-290 MSDS NO: 05001096 EMERGENCY HEALTH INFORMATION: (800) 447-8735 EMERGENCY SPILL INFORMATION: (800) 424-9300 CHEMTREC, U.S.A. OTHER PRODUCT SAFETY INFORMATION: (312) 856-3516 IMPORTANT COMPONENTS: Polyalphamethyl styrene (CAS 25014-31-7). No exposure limit established. EARNING STATEMENT: This product has been evaluated and does not require any hazard warning label under the OSHA Hazard Communication Standard. HMIS/NFPA CODES:(HEALTH;0)(FLAMMABILITY;1)(REACTIVITY;0) APPEARANCE AND ODOR: Odorless white pellets. ____________________ HEALTH HAZARD INFORMATION ____________________________ EYE EFFECT: No significant irritation expected other than possible mechanical irritation. FIRST AID: Flush eyes with plenty of water. Get medical attention if irritation persists. PROTECTION: Use dust goggles if high dust concentration is generated. SKIN EFFECT: No significant health hazards identified. FIRST AID; Hash exposed skin with soap and water. PROTECTION: None required; however, use of protective gloves/clothing is good industrial practice. INHALATION EFFECT: No significant health hazards identified. FIRST AID: If adverse effects occur, remove to uncontaminated area. Get medical attention. PROTECTION: None required; however, use of adequate ventilation is good industrial practice. EFFECT: FIRST AID: INGESTION Expected to be relatively non-toxic. If a large amount is swallowed, get medical attention. OO 0851.52 CONFIDENTIAL AMOCO RESIN l;-:?0 MSDS NO: 05001036 PAGE 02 OF 04 _________________________________ FIRE AND EXPLOSION INFORMATION_______________ FLASHPOINT: 475F, (246*0 ASTM D13X0 EXTINGUISHING MEDIA: Agents approved for Class A hazards (e.g., halogenated agents, foam, steam) or water fog. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. ______________________________________ REACTIVITY INFORMATION_________ DANGEROUS REACTIONS: None identified. HAZARDOUS DECOMPOSITION: Polymerization will not occur. Incomplete burning can produce carbon monoxide, carbon dioxide, and other harmful products. STABILITY: Stable. CHEMICAL AND PHYSICAL PROPERTIES SOLUBILITY IN WATER: Negligible, below 0.1%. SPECIFIC GRAVITY (WATER 1): 1.08 SOFTENING POINT: 266F (141'C) ASTM E28 STORAGE AND ENVIRONMENTAL PROTECTION STORAGE REQUIREMENTS: No special requirements. SPILLS AND LEAKS: Contain and remove by mechanical means. WASTE DISPOSAL: Disposal must be in accordance with applicable federal, state, or local regulations. Determine waste classification at time of disposal. Conditions of use may render the spent product a hazardous waste. Enclosed-controlled incineration is recommended unless directed otherwise by applicable ordinances. ____________________________________ TOXICOLOGICAL INFORMATION __________________________________ INGESTION: Acute oral toxicity: LDSO greater than 5000 mg/kg (rats). No death or signs of toxicty were seen at 5000 mg/kg. no component of this product is identified as a carcinogen by NTP, IARC or OSHA. ______________________________________ REGULATORY INFORMATION _____ CERCLA REPORTABLE QUANTITY: This product is not reportable under 40 CFR Part 302.4. DOT PROPER SHIPPING NAME: Not regulated. 0851r^roFNn,,,. t PAGE 03 OF 04 REGULATORY INFORMATION - CONTINUED FDA STATUS: This product is approved for use by the FDA under the following sections(s) of 21 CFR: Part 175.105 as a component of adhesives in food packaging when used in accordance with the specifications of this subpart. Part 175.300 as a component of resinous and polymeric coatings for food contact surfaces when used in accordance with the specifications of this subpart. Part 175.320 as a component of resinous and polymeric coatings of polyolefinic food contact surfaces when used in accordance with the specifications of this subpart. Part 175,380 as a component of certain condensed epoxy resins for the coating of food contact surfaces when used in accordance with the specifications of this subpart. Part 175.390 as a component of zinc-silicon dioxide matrix coatings of food contact surfaces when used in accordance with the specifications of this subpart. Part 176.170 as a component of paper and paperboard in contact with aqueous and fatty foods when used in accordance with the specifications of this subpart. Part 176.180 as a component of paper and paperboard in contact with dry food when used in accordance with the specifications of this subpart. Part 177.1210 as a component of closures with sealing gaskets of food containers when used in accordance with the specifications of this subpart. OSHA HAZARD COMMUNICATION STANDARD: Not hazardous per 29 CFR 1910.1200(d). RCRA STATUS: This product is not subject to the 40 CFR Part 268.30 land ban on the disposal of certain hazardous wastes. SARA STATUS: This product is not regulated under SARA Title III, 42 USC 9601. TSCA STATUS: All of the components of this product are listed on the TSCA Inventory. ISSUE INFORMATION BY* Richard A. Symuleski Director, Product Safety ISSUED: February 15, 1989 SUPERSEDES: June 21, 1988 Do 085354 CNFTOFNTTAi amcco resin :;-2?o MSDS NO: 05001096 PAGE 04 OF 04 This material safety data sheet and the information it contains is offered to you in good faith as accurate. We have reviewed any information contained in this data sheet which we received from sources outside our company. We believe that information to be correct but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations, it is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as a permission or recommendation for the use of any product in a manner that might infringe existing patents. No warranty is made, either express or implied. Do 085155 oonftdfnttal --------- Alto Product. ` , w---in *i*nw -*-- --nmn in dir tt " (CH3)2NCH2CH2N (CH3)CH2CH2N(CH3)2 tentron Division material safety data sheet hi" ------1 iir~ r" 'ROOUCT NAME: N,N,NjN",N" Pentamethyldiethylerietriamine CHEMICAL NATURE: Alkyl Amine % ACTIVITY: 97+7. I1)1 I" . V v1^1 #11395 1,1 BOILING POINT, 760 mm Hg SPECIFIC GRAVITY VAPOR DENSITY PERCENT VOLATILES BY WEIGHT APPEARANCE AND ODOR 198 - 199C 0.828 No Data FREEZE POINT 1 VAPOR PRESSURE AT20*C. SOLUBILITY IN HjO No Data No Data Soluble No Data IONIC NATURE Yes Colorless to pale yellow liquid, strong ammoniacal odor 4. ' A.V-ls.- i*.J/iCATJ-il...a;-SAMWU j; U,\~ . :-;w; +M*. MATERIAL ^.N.NjNVN" Pentamethyldiethylenetriamine ACUTE T0X DATA: Oral-Rat: LD50*1630 mz/ke Skin - Rabbit: LDLO= 280 mg/kg NI0SH/RTECS: 1979 % 97+7. TLV (Unit*) Not Established W.'nui**r!',n ' ' FLASH POINT (test method) 218F AUTOIGNITION TEMPERATURE No Data FLAMMABLE LIMITS IN AIR, % by volume LOWER N.D. UPPER I N.D. EXTINGUISHING MEDIA Combustible Liquid, it involved in a tire, use water, carbon dioxide, dry chemical extinguishing agents, dry sand, or dry ground dolomite. SPECIAL FIRE FIGHTING PROCEDURES it lnvoiyea in a tire, wear n lUSH/MSHA Appfbvea sen-con twined breathing apparatus, flame & chemical resistant clothing; hats, boots & gloves. If without risk, remove material from fire area. Cool containers with water from maximum distance. ^ .USUAL FIRE ANO No unusual hazards known. cXPLOSION HAZARDS DO 085156 CONFTDFNTTAL 4^/ Vfitron Division Alfa Products, 152 Andover Street, Danvers. Massachusetts 01923 (617) 777*1970. (415) 836-1777 Telex: 94-0378 ALFA DARS v>; ....... sr THE BURDEN OF SAFE USE OF OUR MATERIALS MUST REST ENTIRELY WITH THE USER. WE CANNOT ASSUME RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY F ANY INFORMATION SUPPLIED BY US CONCERNING THE HAZARDS OR RECOMMENDED USE OF THE CHEMICALS. \- ikL.. limit value Not Established EFFECTS OF OVEREXPOSURE Material can cause irritation & possible burns to akin & eyes. "In gestion may cause severe damage to gastr-Intestinal tract. Inhala tion can cause irritation & swelling. EMERGENCY AND FIRST AID PROCEDURES . * , # A STABILITY UNSTABLE STABLE "51------- INCOMPATIBILITY (materials to avoid) Remove from exposure.Eves: Flush with copious amount* of uarr fnr at least 15 minutes. Skin: Remove contaminated clothing. Flush affected area with copious amounts of water for at least 15 minut s. In both above cases, seek prompt, competent medical attention. In gestion/Inhalation: Seep prompt, competent medical attention V !*.*,' `-sag? V- iD/* 1 J- CONDITIONS TO AVOID Avoid Incompatabilities Acids, moisture, carbon dioxide, non-ferrous metals. HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION May Occur I Will not Occur STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED No Data CONDITIONS TO AVOID Not Applicable "ri^.ivren sr 1' .1- ), "``r Wearing full respiratory protection & clothing. (See S c VII), stop leak if without risk. Cover spill with bisulfate & carefully place in a well-marked container. Submit or retain for disposal. WASTE DISPOSAL METHOD Consult state, local, and federal regulations for proper disposal Alkyl Amines. v.(. n -1 RESPIRATORY PROTECTION (specify type) For ordinary use wear a NIOSH/MSHA approved high efficiency amnonia hvraapaor-rM-cra'grtraidppgaeTarfenespirator & for emergency use, wear self-contained VENTILATION -OCAL EXHAUST MECHANICAL Fume Hood Not Adequate SPECIAL OTHER Not Required PROTECTIVE GLOVES OTHER PROTECTIVE EQUIPMENT Butyl Rubber EYE Chemical safety goggles with Neeoopprene or vinvli PROTwECvT ION full face shield. Lab coat&/or neoprene apron, boots, safety drench shower, eye wash capable of sustained flushing & hygienic washing facilities. 'RECAUTIONARY labeling / DOLING AND STORAGE conditions ti-)r t' 1 ^ i.4 - _ 1 >Y'-1- DANGER! Corrosive & causes severe burns & ulceration on contact with skin & eyes. Toxic upon ingestion & inhalation. 085157 CONFIDENTIAL, Keep container tightly closed when not in use. Store in a cool, dry, well ventilated area. Wash thoroughly after use.