Document reyMBqLKoDeJYwDpRBMv2b527
ACUTE AQUATIC TOXICITY
TEST SUBSTANCE
Identity:A mixturecontainingperfluorooctanesulfonatweh,ich may also be referredtoas PFOS, FC-95, or as a component of FC-203. (1Octanesulfoniaccid)(CAS # 2795-39-3).
Remarks: The 3M productionlotnurtiberwsere 4 and 6. The testsample isFC-203. Currentinformationindicatesitisa mixtureof 1.34% PFOS, 35% diethyleneglycolbutylether,37.85% water,20% ethyleneglycol,2.66 % Sultonefoamer, 3% sodium octylsulfate0,.1% sodium laurylsulfatea,nd 0.05% tolyltriazole.
The followingsummary applies to a mixture with incompletely characterized concentrations of impurities.Data may not accurately reflecttoxicityof the fluorochemical component of the testsample.
METHOD:
Method: Not given. Type: Various staticand Continuous flowscreening GLP: No Year completed: 1973 - 1974 (5studiesconducted) Species: Not given. Supplier:Not given. Analyticalmonitoring:Temperature,and DO Exposure period:96-hours,10 days,and 18 days Statisticamlethods: TL50/LC50 valuescalculateudsinggraphicinterpolation. Test organism age: Not given. Pretreatment:Not given. Test conditions:Various. Lighting:Not given Concentrationsdosing rate:Various Stabilitoyfthe testchemical solutions:Not noted Exposure vessels: Not given Number of replicates:1 Number of organisms per replicate:Not given. Number of concentrations:fiveplusa blankcontrol Water chemistry during the study:Various
RESULTS
Nominal concentrations: Bk controland variousconcentrations
Element values:
Study 1 (w/3% concentrateLot4):
96-hour LCm = 0.75 mL Study 2 (w/3% concentrateLot 6):
96-hour LC50 = 0.075% conc. Study3 (Lot4):
96-hourLC50 = > 1000 mg/L Study4(Lot 4):
96-hourLC50 = 0.061% Study5 (Lot4):
96-hourLC50 = 0.1875% Study6 (Lot4):
4-7day LC50 = 1875 mg/L 8 day LC50 = 1525 mg/L 9-10 day LC50 = 1250 mg/L Study7 (Lot4): 96-hourTL50 = 0.0438 (no units,assume % concentrate)
Element values based on nominal concentrations
Remarks: Testingwas conducted on the mixtureas describedinthe Test Substance Remarks field.The values reportedapplyto thatmixtureand not the fluorochemicalproportionalone.
CONCLUSIONS
The testsample LC50 variedamong the studiesdepending on thetesttype and duration.
Submifter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133
DATA QUALITY
Reliability:Klimischranking= 3. Testinglacksrecordof methodology used. Sample puritywas not propedy characterizedand the study lacksanalytical confirmationofthe amount offluorochemicalproportioninthe solution.
REFERENCES
This studywas conducted by the 3M Ccmpany, EnvironmentalLaboratory, St.Paul,MN, Lab Request number 2002 and 2009, 1973-1974.
OTHER
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FORM 10620-PWO
Z:c:LAB REQUEST BOOK - 42-BW
Water and Wastewater REQUEST FOR LABORATORY
WORK
File: Lab RequestNo.
TO: ENVIRONMENTAL
ENGINEERING LABORATORY
- BUILDING 53-6N
Requestor
Lab Personnel
Name:
Request Date
Date Rec'd.Sa I
ProjectNo.
Prob.No.-Code
Analyst:.
Description: 1: )t=
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Sample Date:
Date Needed:
Date Completed:
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HoldSample For-Days
Est.Time:
Hrs.
Hrs.Spent:
Sample Description
Total Hardness,mg/i as CaC03
Calcium Hardness,mgA as CaC03
"P" Alkalinitym,g/i asCaC03
"M" Alkalinitym,g/l asCaC03
pH
Sulfate,mg/i as S04
Nitrate,mgA as N03
Chloride,mg/l as Cl
SilicaM,g/i asSi02
Flu-oridem,g/i as F
Ortho Phosphate,mg/i as P
Total Phosphate,mg/l as P
Total Chromium, mg/i asCr
Hex. Chromium, mg/l asCr
Total Cyanide, mg/las CN
Ferrocyanide,mg/l as CN
Iron,mg/i as Fe
Manganese, mg/i as Mn
Surfactant,mg/ias LAS
Phenol,mg/l
BOD, mg/i
COD, mg/i (Short,Long, Dilute)
Total Suspended Solids,mg/i
Vol tileSuspended Solids,mg/i
Turbidity,mg/i Silica
TotalSolids,mg/i
Total VolatileSolids,mg/i
Conductivity,mhos
TotalBacteriaN,o./100 ml
TotalColiform,No./100 mi
FecalColiform,No./100 mi
FecalStreptococcus,No./100 mi Ammonia Nitrogen,mg/i asN KiedidahlNitrogen,mg/i asN
eq-
Oil and Grease,mg/i
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FORM 10620-PWO i
cc: LAB REQUEST BOOK - 42-5W
Water and Wastewater REQUEST FOR LABORATORY WORK TO: ENVIRONMENTAL ENGINEERING LABORATORY-
Requestor
File:
Lab RequestNo. VM6-&,@
BUILDING 53-6N
Lab Personnel
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Name:
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ProjectNo
Prob. No.
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Sample Description
Total Hardness,mg/l as CaC03 Calcium Hardness,mg/l asCaC03 "P" Alkalinitym,g/l asCaC03 7'M" Alkalinitym,g/i asCaC03 pH Sulfate,mg/l.as S04 Nitrate,mg/l as N03 Chloride,mg/i as Cl Tilicam,g/l asSi02 Fluoride,mg/i as F Ortho Phosphate,mg/l as P TotalPhosphate, mg/i as P TotalChromium, mg/ias Cr 'Pex.Chromium, mg/i as Cr Total Cyanide,mg/las CN Terrocyanide,mg/i as CN Iron,mg/i as Fe Manganese, mg/i as Mn Surfactant,mg/l as LAS @henol, mg/i BOD, mg/i ZOD, mg/l(Short,Long, Dilute) TotalSuspended Solids,mg/i VolatileSuspended Solids,mg/i Turbidity,mg/l Silica *fotalSolids,mg/i Total VolatileSolids,mgA Conductivity,mhos TotalBacteriaN,o./100 ml TotalColiform,No./100 mi FecalColiform,No./100 mi FecalStreptococcus,No./100 mi Ammonia Nitrogen,mg/i asN KjedidahlNitrogen,mg/l as N Oil and Grease,Mg/i
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cc: LAB REQUEST BOOK - 42-5W
File:
Water and Wastewater REQUEST FOR LABORATORY WORK
LabRequestNo.
TO: ENVIRONMENTAL ENGINEERING LABORATORY - BUILDING 53-6N
Requestor
Lab Personnel
Name:
RequestDate
Date Rec'd.Sample:
ProjectNo.
Description:
Prob. No.
Code
Analysta:&
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Sample Date:
Date Needed:
Date Completed:
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Hrs.
Hrs.Spent: N.!:@
Sample Description
TotalHardness,mg/iasCaC03 Calcium Hardness,mg/i asCaC03 "P" Alkalinitmyg,/iasCaC03 7,M" Alkalinitmyg,/lasCaC03 pH Sulfatem,gllasS04 Nitratem,gllas N03 Chloride,mg/lasCl ilicam,g/iasSi02 -Fluoridem,g/las F Ortho Phosphate,mg/iasP TotalPhosphate,mg/l asP TotalChromium, mg/iasCr Hex. Chromium, mg/iasCr TotalCyanide,mg/iasCN Ferrocyanidem,g/iasCN Iron,mg/ias Fe Manganese,mg/i asMn Surfactantm,g/las LAS Thenol,mg/i BOD, mg/l COD, mg/l(ShortL,ong,Dilute) TotalSuspendedSolidsm,gll VolatilSeuspended Solidsm,g/l Turbiditym,g/lSilica TotalSolidsm,g/i TotalVolatilSeolidsm,g/l Conductivitym,hos TotalBacteriaN,o./100ml TotalColiformN,o./100mi FecalColiform,No./100ml FecalStreptococcusN,o./100 ml Ammonia Nitrogen,mg/lasN KjedidahlNitrogen,mg/ias N Oiland Grease,mg/i
Al-7 A&Y e OlAy
9-/ALAV
Comments:
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