Document reaQp2N1NoE7ZOE4oR6dvk9dG

\ o o o I4 o Largest Selection of Plasticizers From One Source ! | o MwiSdrs o offers you th largest a, ortmcnt of plasticizers-- ^ofit in numbu and variety--in the world. This broad lino has unique advantages: you can sated from Q one source the plasticizing system that offers you the optimum in processing and performance; you can obtain impartial technical guidance; you can take advantage G of the savings in combined shipments; you can simplify your purchasing procedure. The need for a selection of plasticizers is readily apparent. In the 1930's--when m Monsanto pioneered the technology of plasticization--performance demandswere relatively mild. Plasticizing was simple because applications were few and resins m fewer. In the intervening years, many new resins were commercialized, countless applications have developed, and today there are rigorous specifications and a variety of needs for ease of processing, speed of cure, and particular perform m ance qualities. o Confronted with the multiplicity of end-use requirements on one hand and a multitude of plasticizer and resin choice on the other---even the most experienced formulator is bewildered by the maze of possibilities of from which to select the one e best system for his particular application. This catalog has been designed to serve as one tool to help you solve the often perplexing problems of what plasticizer to use. It contains complete descriptions Of the performance and processing characteristics of each of Monsanto's more than eighty plasticizers. It also includes tabulations of performance data of various plasticizers in several end-use applications and guides to superior plasticizers to ci develop compounds with special performance. This catalog is not the final guide to plasticizer selection. It is primarily a guide to ..i performance of types. However, if these data are used as a guide to plasticizer selection, Monsanto technical bulletins on individual plasticizers and on certain end- use applications will provide more complete information. Specific consultation services are offered by Monsanto's Plasticizer Council. We j hope these three sources of information will be helpful to you in your manufacture G of plastics products, surface coatings, and adhesives. O TOWOLDMON0033017 WATER_PCB-00017486 ma p i. a s t i c- i. z m ms r the Widest Choice in the WorId '. - The followsng am tractemafks of Monsanto Company, Mistered in the U.S. Patent Office: Araetor, SetTM, >*xlafto, H840, Mod-Epos, Monur. Option, Phosgart, Santicizir, Santolite. .' m m W a f TOWOLDMON0033018 WATER_PCB-00017487 II7 page 2 o # 9 # To give rapid delivery and multi-product shipments, Monsanto maintains bulk station inventories at strategic industrial centers along the east coast, the south and southwest, the midwest and the west coast. These bulk stations are another customer service that enables plasticizer users to save money in the following ways; lowest cosl/lb. With ri^r<';arit<-!sdjtributi->r>.corn- tan reduce their rnatero*.> costs by pur<t"i mg to t.'.nk i'in-s <ht**ct from the producing | bn.t or by orderJ!g ,jnk truck zhipment* from the merest balk storage Bulk prices are about v lower than car- and truck-lot drum prices. Conservation of plant storage space Smee the >1 msanto bulk stations are strategically located *l-*se to major manoiai iurmg centers, minimum j-M'-Uvher storage space Is needed Supplies are utmost mentor fast, .,hort~haut delivery. Com pa rtmented shipments With such & broad line *T p!astk*t7.ors. eompounderscsn take the savings of hulk purchasing by ordering as many as three hSercnt piasitcirersms single-nder, Thedsffeicut }Ia'4k;zcra are shipped in compartmented tank trucks. Multi-product combined shipments from 'bulk stations cart also reduce in-plant inventory costs. Mixed Car- and Truck-lot Shipments By offering such a lull line of plasticizers, Monsanto can load out mixed drum orders in a single car or truck. This gives the buyer the cost economy of full carriers. Ordering, invoicing simplified With this efficient distribution system, compounders can make ad ditional savings by fewer shipments, fewer orders, and reduced paper work in clerical handling of invoices. Monsanto is always ready to work with customers to establish and maintain convenient bulk station distribution centers wherever volume justifies a mutually convenient storage station.. 0476049 TOWOLDMON0033019 WATER_PCB-00017488 specifications and physical characteristics of Monsanto plasticizers Monsanto plasticizers comprise both liquids and. solids representing a variety of distinct chemical types, including phthalate esters adipate esters permanent plasticizers glycollates sulfonamides phosphate esters aroclor plasticizers .,. plus a variety of "specialty" compounds and extenders, Each of these, in themselves, but primarily in combination offer special processing or end product quality advantages in particular applications. Specific plasticizers and specially researched combinations have been developed for formulation of plastisols for slush molding, fabric and paper coating; for adhesives and surface coat ings; for extrusions both profile and cross section; for floor tile; and for cast or cal endered free film. V o o o o o m m The feSmrtog pages feserfts physical properties of the vartas plasticizers of choice available frets Monsanto. 047605 TOWOLDMON0033020 WATER_PCB-00017489 w 0 m processing specialty color improver for atkyd'resins :^ tiI/pateS4 9 m m Q G o o o o o 0 o m m a General Description L_ Trip)"-? yl jhcophite $: v/kk-Iy Mgc-d es n staoi- li/ i >n chloride <-ompoi4Uor.%, It .serves a i ,.il funcHon* /a)Whcni rudneumcompounds are f*> r 'sf ibc (r/rv'-|X/>4t`o`n triphenyl phosphite vr/n- hit,4 /?- and lem-r.vs the hur.e developed by the cad- run o chki do ftH'msiton; <bj When chlorine it ns ;u- "p'it from p>!yvmyl chloi ide, douhl^bondssu** <c-H hi*2 to oxygen-darkening at e kft behind on the |v. c*r.m; inphunyl p**o&jphH* ar.s os an 00 * -md contributes to better light stability [This f lo'/ion. also valuable tn other resins. is covered by rr k Patents 2,572 5?; {Monsanto) and 2/54,6-16 (A i jo# Chemical Company) ] Ut, elkyd resms ipphenyl phosphite improves th>- roior of the rrpim which tend to oxidise at the 49*1 540*K. prrcessing ternpemtures due to presence of I -ee peroxidej m iron soluble salts. If coir him 1 y irexKte is u-*ed an akoholy&s catalyst, the p$-4 ,v?nee of biphenyl phosphite wJl improve the .nn.hed ream's clarity by solubilising the calcium ph d a late precipitate which fr*? ms in polyester re-r- /o rmof.'icfnre, --m'dl amount '/ tnpht-nyl phos- ph,v reduce the teaekm t>mu and w,pfo*'o the reu'-'-: The C'*kr improvement \.< ob* tar* die *n *hv noth ^{e'.t^ie vf halted oils made by th<' '.}n* ,< ,-iova hroeed, and tail oils A'.th rut \( onbydivi* or ftmv*rm a-sd in punnolif re'.in m <f uTjcttife, If ipho.yi pho- j.bite promote* the fotr .aturn of permanently Iijht colored liquid pho no formaldehyde compositions (U. S. Patent 2,*' I 6,676, Mensnnto Co.). R Properties . Chemical formula'' [<=>-]r IVofecuiar weight appearance Neutraliratioo number '-oor 1 `j/drolyzabie chlorine 1 rm phono! ^sfractive index # 25*. Specific gravity ^a/15.5sa height per gallon @25*C. Ending point, 760 mm Hg Crystallizing point Flash point (C.O.C.) Fire point (C.O.C.) Vaoor pressure @ 22S5C, V",cosity@253C. Colubility In water @ 25`C. General solubility 310.28 Oily liquid or fight yefiow solid 0.08 mg. KOH/gm. max. APHA 50 max. 0.010% max. 0,5% max. L5875-L59Q0 1.176 to 1.182 9.83 fb. 36SSC, 25*C, 375aF. 525sF, 11 mm Hg 17.5 cks Hygroscopic Soluble in common solvents * Specifications Tophenyi phosphite if considered only slightly to;, u: from the standpoint of oral ingestion and is not readily absorbed :n lethal doses through the t<idok*n skin Ri.-|nyaicd or prolonged skm contact fJb-old be avoided, however,-to prevent skin ixritatier, material may cause irritation if there is 4-e* okntal contact with eye tissues but no permaufr'A damage sf ould result Prompt flushing of the f.y ">with watet will reduce the degree of irritation. In laboratory studies, no deaths occurred among ra n exposed for ax hours to a saturated atmosph'. u-. of atomued triphenyl phosphite. 0476051 TOWOLDMON0033021 WATER PCB-00017490 TOWOLDMON0033022 WATER_PCB-00017491 J 1 ^; mam plasticizers AND RESIN EXTENDERS w> o o o o o o o o o o Q & m m m m Tl > /~i">clcr y/stychhrimUxl po)yph<,nyl-> umgv m to ; '#H'J ap$tf'rumr*i horn mohih? `My liquids to fn - v:\i\U; crystals r.d hard yellow transparent jz'.hu Th`- Aroclor pi * ducts are useful as iow-co'-d, nt p\n.>U<-,'/< *,,* i.ud ret lr v*d coders for mnyh, t-f ', and rublv i uMteriais, The hutclot cnm~ po iu-'i, mo eomfoUbU; with most oi the common phc w rif"iirJ.s ami sp^rJA i e;-*.ns. 11''" -r permanently t-urmoplanbc materials are ne-f o rr>n'CO!rosive to irwuiis, and net h>`h<,jy/aWe by wa^f. alkaliet, or adds, They f-xci-lkmi thru i-icai pi**pcTi.e:<. The vtacons lice >0, and reruns w.ll not support cembusuon v/lscn heater! alone 11m flexibility they Impart to rears' Irwreese.- wkh the mobility of the poriiculor Aro-dot cot j pound. o/JiTe the decree of hardness * tqo.t led Increases v/hh the viscosity of the Aroclor WVWh'Zi'i in and stofnre '`gating;:, the Arock-t 5 impa ~t ojUt*ndu>g adhossv>* qualities, g?>od reshtarre to v/h%r-x and chemieei acHon. and resistance to ba/'wia and fungi attach. fn *n-j/1 reunx. she Aroclors are used mainly as co p'osttcj/.ers with trrere&yl pheof hate, diovtyl phd'fs;^U;andothor Tlen'impartpb/.siidzmgaction, <h -mwai and eorr>v,p,r resistance, flame resistance. <-r. - idv'f ' ,; /%'- * %!> S ui; uv*'Vblo'e k>- qw(S. th d ,vt*h<k . u/, rhtb J'AI_,, and S'ittimzi r 141, tbe At -* I'n p. tf S '-I5 ' `-ut .^)A >r ,,! yl <)>- i'.a , -ylif-. p." : IVS' !rr> f>5 fro* 6k?,-;, ar;d to .:b and i ^U the ,V- Hibsrc jmp.ut .I-.5 Ih 0 !<-' -dcnco 'jud serve ith M-fc'leni gr * nlmg 41ml dlSf*-. rsing me<ha for pigments. fn ^yhjiinyl acetate, the liquid Aiodur compounds mm.e excellent low-cost, quick-tack adhesives. The m<c a vlseou* and cohd Arcelor compounds ore v/sd'd r usect in bo? melt adhesives, T> m Aroclors arc highly compatible with eth^f celIn ;r;e 'jle hqiods impart gieai flexibility; and the re in;-, impart great hardness. Aroclor 548b con* tr.hates huh gloss and exceptional weathering qt jlitii'S to coatings h r rigid surfaces in `cllntone wHatt'buiyratP, tho Arodor comjx-uo'W, are useful m making flarae-renstau? lowcod formulation! for applications `. *h $s paper ctMUngs, Jacquors.and slrippable costings In nitrocellulose, the Aroclors function both as pU-.tieiren* and resin;.. They may ho usc-tl alone vr wifhoth^r plo-itioizers and resms to impart v/eadier resists.ot e, Foster, adhernm.and dr-ci Crired burnmg c ai of thm' evc'dlont clcrtricru chorscte; iftic'.. thigh dielf`Ctno r.trengih mri re.-.iutivily and low power factor) and theii prepu ly of retarding the p-r.sage of meistuic end gase*. through mtrucelloloro c.hlorinio<| rubber, and other similar plastics films, thev are e>*>eeially ereful m coat'.ng^. for electrical insulating material. fn chlorinated rubber (Parian) a? d cofx>lymers of xiyrene-huiaditne (PUohie S-5), Aroclnt 1254 is an excellent plasticizer; and Aree'.or 5i0(t acts as a film fortifk'i m protective and decorative coatings for concrete and masonry structme5?, steel struc tures, railway tank and gondola earr, wood, and metal niaritime equipment. Aroclor in these types of coatings imparts excellent resistance to dame, corrosion, acids, alkalies, and water; as well as good electrical Insulating properties. The Aroclors are most useful in natural and syn thetic rubbers. The liquid Aroclors 1221, 1232,-1242 and 1248 provide a strong plasticizing action. Small amounts of Aroclor 1280 plasticize hard rubber and reduce brittleness. Milled into rubber. Aroclor 1254 and 1260 impart permanent tackiness and adhesion. As a plasticizer for crepe-rubber resin (formulated into paints). Aroclor 1282 increases the gloss and alkali resistance of the film and its adhesiveness toward steel. Arcelor 1268 has excellent working qualities at 225-325T. as a plasticizer in injection moldings. Ground Into powder and milled into rub ber at a temperature below its melting point, Aroclor 1268 can he dispersed through the rubber and acts as an efficient Same retardant. In epaxy resin coatings, the Aroclor compounds with their excellent chemical resistance, oxidation resistance, and adhesion enable the formulator to reduce costs without detracting from the saleable features of the epoxy resins. In plastic applications, a combination of an Aroclor compound plus anti mony oxide make low-cost non-burning formula tions, The Aroclor compounds are also useful with phenolic resins, polyester resins, polyisobutylene, waxes, and rosin. o 0^76053 TOWOLDMON0033023 WATER_PCB-00017492 M *iihm'V ten {totKtim*-. the Aroetar ^bhnrmlKf ;-''tv phonyin have ti jrt matted train Ui;d U>xi- s When ArciVo </> poutoin are * tut j,i t').';V;Hc4 tu/ rr>n* *.'<?* )*. >'t !<* nppitml, -ith<*r by the u-e of clos'd ipm- or by kntol-exht cm I v.-*;*Ihrion tr>- P'Hht-r wtf h p< noral * thrown t-xhnu4 'iho lhrv~b<'!! liwit,- frnnvmHm nlhv^u-Je <*or-cenoption b<r Hti &-hour ^.rn'l-.ir.g: day) -td l>y Hie A?mifkbn 7 onf'H'er.ce of {hr.nm'.inm-t ||y>rkni'W l,0 rmhu'ram of the f-.'.y*r-r*1,!<>'*> i**-'- AroeJor t >ri{^ttrd; pi r todhc mH'-rof ah nrnl<i -r>mr]jyrarn of |he uv>rt>.%Ayh\y~(',h\'n-iM`i/'i\ cmn\><>nn>\*. <ch as Aro-ilor 1204, |*rr cubic motor uf /*ir. In *kin pa'f li font*, Kcith'-m Arcelor izhi alone or tn a pclyvhij'l KhrUk Him UJ.a p*jr An? Aroclor) / or Aroclor m an aikyd re^in moling- (17 per Arwlu*) or* c&ovn.- h ritatmi >y m>nt itized the a&m. r<ntfiueo(S or related rMn c< irtad with the Aroolot eonripnonda mod avoided Vcum^ of the p <r*4hj<> ^u^renee of chtrr8cn* Properties Aroclor 1248 * Appearance * mmty * Ctoer * Moisture Refractive index @ 28*C, - Specific gravity 6S*/15.5"C Weight per gallon 25*0, Soiling point; 760 mm Mg f^w point, CASTM D-97) flash point iC.O.C.1 fire Point CC.O.e.) Viscosity #3?.8*C. 544*a* mrc,'. Clear, mobile oil 8.010 mg. KOH/gm. max. APHA 180 max. 50 ppm max. 1,630 to 1.631 1465 to 1,415 12.04 lb, 340 to 375*> * ~?*c. 3?9to3$44f. None to boiling point 18$ to 240 SUS n to so sus 36 to 3? SUS Q Aroclor 1221 Properties , , Appearance * Acidity .' * Color Pefractive index @ 2QC, Specific gravity 2S,il5J'. Chlorine, % Weight per gallon } 25SC. Boding point. 7^5 mm Hg Pour point (ASTM D-97) flash point {C.aC.S fire point (C.O.C.) Viscosity @3?.8iC.'* 54.4SC. S8.9*C. Clear, mobile oil 0X514 mg. KOH/pn. max. APHA 100 max. 1617 to 1.618 1182 to 1192 21.0 * 05 9^5 ibs. 275-320`C. Crystals St 1*C. 2ll-3025f. 349f. 38 to 41 SUS 35 to 37 SUS 30 to 31 SUS ltSi:eci`scatK:;n^| O m m @ JD Properties Aroclor 1254 Appearance Acidity Color Moisture Refractive index @ 20*C. Specific gravity S5*/!5.5"C. Weight par gallon @ 25C. Boiling point, 760 mm Hg Pour point, (ASTM D-975 flash point fC.0,C3 fire point {C.O.C.) Viscosity <S> 3?.8'C. $4.4*C. 98.9aC. tight-yellow viscous liquid Q.G10 mg. KOH/gm. max. APHA 100 max. SO ppm max. 1.639 to 1.641 1.495 to 1-505 12.82 lb. 365 to 390`C, 10*C. None to boiling point None to boiling point 1800 to 2500 SUS 260 to 340 SUS 44 to 48 SUS (Spedfl'catio'ns'l m c o o m m 0476054 TOWOLDMON0033024 WATER_PCB-00017493 o o o. Aroclor 1232 0 o o Ap ,5 z'y.:z& ,-V, ;Hv V,v Oo!s sr i>vf- u<d*r < 70`C f.c /yaruy 26</15.$*'C. i'n - Aw*, % W*ng:t per gallon % Zr/C Bo smgpom>, 769 mm Hg fo ,r point, {A51M D-9?l H/a> pomt :60.w Uru x-mt ICOC| Viscosity 18? 37.SC.* SC4*C. awe. Clear, mostly o-l 0014 mg. KCH gn max. APHA ICO max 1 6?0-l 62? i^/OloiJa1.' 28 - 05 10.55 lb. ?9&to3?5'C, -35.5*0. 3Q5-310*f. 46TF. 44 to 51 SUS 39 to 41 SUS 31 to 32 SUS |n*Spegiile8igs| a. o ' Propwlm Aroclor 1260 0 . *V f'A* . 5dhfg Index @ 26*C- Sp^-of..; gr**,*y 30'/15JaC. m m We .ght per gel-on < 2*C. Bodr# pwnt, 76C mm Hg 5 oomi, /ASTM D-971 Pt* pcm! 10 0.C ) * f*r* pont tC 0 C4 m. v. . 54 4*C. 98J`C. ,. Ught-yellow, soft, sticky resin 0.014 mg. K0H/gm, max. APHA 158 max. 50 ppm max. 1.647 to 1X49 1.555 to 1.SM 13.50 lb. SVC. Nenftte belting point Nose to boiling point 3200 to 4508 SUS 72 to 78 SUS m {*Specificatio'ns"l fii;paK Properties Aroclor. 1242 1'i Ap<v-!7inee 1 * Acuity i Color 1 * S/ortium $] Kaf'acfrve index { 20*0. * SpeoV gravity 25s/!5.5*C. > v.'esgl t per gallon ( 25*C. j 8o> mg r>oint, 760 mm Hg ii 1 Poo' c**int {ASTM D-975 Flash point (C.O.C.5 i F-re- point {C.O.C.I Viscosity @ 37.8*0. 54.4*0. 98.9*0. Clear, mobile oil .015 mg. KOH/gm. max. APHA 100 max. 58 opm max. 1.627-1,629 U8i to i.m IIM lb. 325 to 366'C. 13s, 348 to 356*F. None to boiling point 82 to 92 SUS 49 to 56 SUS 34 to 35 SUS f'^eTfIcSli3ns| Properties Aroclor 1262 Appearance light-yellow, sticky viscous resin * Acidity 0.014 mg. KOH/gni. max. * Color APHA 150 max. Chlorine, % Refractive index t? 20`C. 61,5 to 62.5 1.6501 to 1.6517 Specific gravity 90/15.5*0. 1.572 to 1.583 Weight per gallon < 25*0. 13.72 Its. Boiling point, 7S0 mm Hg 390 to 425'C. Pour point 35 to 309C. Flash point (C.G.C.) None to boiling point Fire point {C.O.CJ Nona to boiling point Viscosity @ 71.0*C, 98.9*C.* 680 to 05O SUS 86 to 100 SUS f*'sp'^HiCatio'ns'| m m 0*T&O*5 % TOWOLDMON0033025 WATER PCB-00017494 ukucuh' Aroclor 1288 M ?. m as r d*, gravity 2V//VU hi per gallon ,a 'S'C, > *; i*, it, 7M) mm Mg ,nvf {.'fit OVM 1 frvnt (( (jC! Vs-\ fC<Kt} White to off prHVde' 0.05 mg, K0H.gr?>. rw/ 1 S liPA 1487 mm ib. 435 o 450*0, ISO to l?u*C. N&m to fop!i*ng pomt Nons to boiin> po>nt r*$g-tdfStion$''] Aroclor 5442 A .pesrenc# A'isfiV *"tosr {molten} S~acific gravity 25*. 25*C. %e gtot per gallon <oj 25*0, *S po.nt (ASfM 628 51T) & r mg po>nt, 4 mm Hg fW pomt IA5IM D-97) F`'hpomt(0GC) Fmp.yntfCOC) V aciry { 98.9*C. Clear, yellow, sticky resin 0. mg. KOH/grrs, max. 2 NPA max. 1.475 12.24 IP. 46 to 52*0. 215 to 30Q*C. 46*C. 477-F. >662*F, 300 to 406 SUS Specifications ] Properties Aroclor 4465 Appearance Acuity * Color (molten) Retractive index @ 2D*C, Specific gravity 25*f25`C. Weight per gallon @ 2$*C. Soiling point, 4 mm Hg Softening point (ASTM E2S-51T) Flash point (C.G.C4 . Fire point (C.O.C.) Viscosity @ 130*0. Ciear, tight-yellow resin 0.85 mg. KOH/gm. max. 2 NPA max. 1.664 to 1.667 1,670 13,91 lb. 230 to 320*C, 60to66'C- None to boiling point Nona to boiling point 90 to 150 SUS Specifications j Aroclor 5460 Properties Appearance Clear, yellow to amber. brittle resin or flakes Acidity * Color (molten) 0.05 mg. KOH/gm. max. 2 NPA max. Refractive index @ 20`C. 1.660 to 1.665 Specific gravity 25*/2S9C. 1.670 . Chlorine, % 59,5 Weight per gallon @25*C. 13.91 Boiling point, 5 mm Hg 280 to 335*0. * Softening point (ASTM E2S-51T) 98 to 105-C. flash point (C.O.C.) None to boiling point Fire point (C.O.C.) None to boiling point Specifications j m m o o m o o 0 0 m o 0**6056 # TOWOLDMON0033026 WATER PCB-00017495 !O ;O ;D !O i So Summary of Specifications and Typical Properties For your convenience the following chart lists Monsanto's Permanent, Sulfomonid*, and Miscellaneous pjasticteere. If a specific property is ideally suited tor a specific application simply find the optimum value ol that property in the vertical column, the name of the plasticizer offering this value nay be read, from the left hand listing. 04760*7 i TOWOLDMON0033027 WATER_PCB-00017496 MOMsl PERSW..ENT AMiSss*' OTHER lM Ssmtciar UrhciMf** Unticker m ; S#ncfo#r4 ; SniHiciMm ' S*rttWw2 ' : $anticizer4S3 j -- * IM - *m -- *u -- * to -- * 0.24 -- * 0.60 -- * && - *U - * 8.24 ` Cl^tr, Viacom liquid * ciasf, oily liquid * Clear fiquitf * Light yetlew, viscous liquid soma sefids on standing * Clear, oily liquid * Cl*r, oily liquid * Clear, oily liquid Clear oily liquid * Clear* oily liquid * 250 Mmt. 58mij 95% Ethanol * m (60mL. 53mU 95% Ethanol * m (50ml.- 50mU 95% Ethanol * i/5 (50ml, 53mM 95% Ethanol * 158 * 200 * 300 *m *m * U3 * S,t5 * 0,15 * 0.15 * 8.15 0.1S * 0.15 * 0.15 * 0.15 ; Santfefter 1-H ; SanticUerS > Santtefcr8 SanticaerS ; Saniofit* MHP Santcfit M$-80% ism WM nu _ 5 ............... ? Aroclor 1221 ' Afoctor 1232 ' Arocior 1242 ' Aroclor 1243 a Arcelor 1254 ; Aroctof 12S0 Arcelor I2S2 ^ , Arcelor 1258 Arcelor 4465 .; Arcelor 5442 5 Arcelor 5468 _ _ - _ ~ ~ - 1 J HS-40 -.! Mw$-z,p(M ) Phosgard C-22-ft i Triphenyl Phosphite 1 -- _ 6m 310.28 - * Yellow-ferovm fused mass . * 300 (molten) . * 0,15 * 4*60 * Practically white solid * 60 (molten) . _* 0.25 4 * 0J0 pH 40 (min.) L0 (mg KOH/g) - * light-yellow, viscoui liquid * 200 (molten) ; -c * Pine, white to light-cream granular particles * 85 (33-1/3 wt. % . in acetone) * i.0 : ' Hard, practically eetortess resin * 50 (2%75g butyl acetate) * Light-colored, viscous liquid. Free flowing above 20*C ' 30 (2Sg:35g butyl acetate) " - _ * .014 (mg KOH/g) * M4 (m KOH/g) * iiS (mg KOMfg) * -010 (mg KOH/g) * O.10 (mg KOH(g) * 0.14 (ntg KOH/g) * .014 (mg KOH/g) * 05 (mg KOH/g) 0.5 (mg K0H/) * .05 (mg KOH/g) .05 (mg KOH/g) Clear, mobile oil Clear, mobile oil * Clear, mobile oil * Clear, mobile oil tight-yellow viscous liquid * Light-yellow, soft, sticky resin * Light-yellow, sticky, viscous resin * White to off-white powder * Clear, light-yellow resin * Clear, yellow, sticky resin * Clear, yellow-to-amber brittle resin or flakes * ISO `m * 100 * 100 * 108 * 150 * 158 * 1.5 NPA (molten) 2 NPA max. (molten) * 2 MPA max. (molten) * 2 MPA max. (molten) * 50 (ppm * 50 (ppm * 50 (ppm * 50 (ppm - - - - - - Clear, oily liquid * 100 ' ' * 125 p *m (mg KOH/g) * Oily liquid or light-yellow solid * 50 '- M.0 * Clear, viscous liquid * 50 - * 0.8 (m- KOHg) * Oily liquid or light-yellow solid * 58 - o<>?6osa TOWOLDMON0033028 WATER_PCB-00017497  TOWOLDMON0033029 WATER_PCB-00017498 Surm-rsary c: Specifications and Typical Propsrtfsi o. ** O W/ , *. ArfS w i-ii? 941 9.03 * (3 - *8*4 n 901 92Q ____ !' iO.'itftlO j* WJS t 895 *>?2 !* is;;?', im ^ * 1787 U53 916 r^* I 045 r J65? 874 ' II -- - -- ,, - r- i +. ji - i2U 28 1 IS IS -31 . '' -if,'/., 'f f., ^SvxxatumH)A _ ... - -. - -_ - _~ - -,, __ -_ .- - - ~ '- .... f"" I' " y. wm toijsw : - SKta 9Kf . - 2900 to 3MB j _ 9000 to *00 f - 291 ; - 556 1 - 38?8 - 6422 , - 156 : [ *"* . i v.u (3 ;.i?s | (O -'Cf /-fcl n* ^ j I,V>. (f%! SJS w I 12H ,, 9.92 10-5 (so vacwan jackeil * 828 mm. * 588 mm. <49 105 12 - 340 - 35G ' 340 ,, 0.8 U60"C) 0.45 3SS {approx.}. 025 -: '- 5-5 32 _ _ _ I0J500 _ - -j -! 358.8 1 -! -; -J -0+- - * n*"o us? ^ * 1,1 '> I.J92 ev isxi M40)bm tl ntL. * |<r. ^ 1 *ar, m . iwo 1.566 * > 0// -Q 1 5*1 (X'.ISS'C? M jjci 1055 1150 12.04 U.82 1350 U.72 15.09 ' O %m !4,; 1191 12.24 o 16?) 13.91 - ~ _ - - Crystals# 1" mm 0-97} 2?5to3 ~>B{A$TMD-9?} 290 to 325 --19 (ASTM 0-97} 325 to 366 -7 (ASTM 0-97} 340 to 375 10 (ASTM 0-97} 365ta 390 31 (ASTM 0-97} 385 to 420 ' 35 to 38 390 to 425 ._ -- 435 & 450 230 to 320 (4 mm. Hg} 215 to 300 (4 mm. Hg) 280 to 335 (5 mm. Hg) - _ * 38 to 41 SUS - (3.78*0 35to3fSU? SM4>Ci - - _ * 44 to 51 SUS P7.8*C5 39 to 41 $US (54,4*C| _ 82 to 92 SUS 49 to 56 SU^ -- (373*0 (54.4*0 _ - - 185 to 240 SUS (37.8*0 73 to 80 SUS *(54.4'C} - - - imtozm sus ^0 to 3# SUS (37S*0 (54,4*C - -- 32ttHo45G0 SU - (54.4' - -- g^to 858 SUS - {71.0*C - -_ - - - _- - - _ ~- _ - - --- - - ! 1301 ^1.907 <** i ors-m*o fjS r* i il is u$2 PO' i$i.'0 137 9.83 f) 11?5 ?o U82 ^ ry 165'C3 119 m .dm *9 1 -- 25 Norn-glassy 25 -as -- - 345 to 396 2 360 _ Not DlstiihsMe _ m_ IS n (220'C) _ 11 (220*0 230 _ - 70.5 80 07J*C: - -T - -: - 17.5 ; --TfeOfcO i TOWOLDMON0033030 WATER_PCB-00017499 :ls. Ate um iM ...... - ,_ >6 to WK> m 556 m& [ iA'il m ,, ~ " - * * U '' .. ~ - fsfe~ ; ' . '^LUt (a-:: _. . tmn ~ ~~ ~ 55S SB m 540 475 45 525 ' 405 Specification */> -| - - -' m- _ _ -535 -- 535 ~ 588 525 ' _ /. . - - -- - Practically insoluble \ Practically ftrol jble ? i Practically insoluble! Practically insoluble t Practically insoluble 1 Practically insoluble; Practically insoluble Practically insoluble* Practically insoluble f -- MM - ~ - -- - -- 6.3 44,5 mC) - - -- -- - -- -m- - 345 - - 4^ - . - _ - - -- - 463 37 61(5 . rfo4| SUS (54X5| itobbSiiS (SM*C) * to *) sos f 38 to 31 SUS 3Uo32SUS 34 to ^ ^US j/^us .-to 24, y,,6 {54 4*',,t ' to AVm VJp !S4,4!C> it**fiQ*>*t* m $*c. 44t',*3SUS * ?r v, n sus ae to ioo s'js --_ fc ISO SUS {130*0 * 0Oto49O5U5 ~- "1mri........1 - (15*40*0 29516 302 349 "Ismi - (254004C) 305 to 310 m - Qjm 545*0 348 to 356 None to boiling point - ws {25*65*0 379 to 384 None to boiling point 0 00066 None to None to - (25-65*0 boiing point boiling point o>wm? * None to * None to - (20-100*0 boiling point boiling point - 8.W4 (2545*0 None to boiling point None to boiling point - 0.000*7 (20-100*0 None t boiling point None to boiling point _ 0.MM None to None to < boiling point boiling point " 0,00123 (2549*0 477 >m _ 0,00179 (25*125*0 None to boiling point None to boiling point _ -- -- - 3J ~- * 46 to 60 175 - 40.1 (25*C) _ - - 345 m 375 525 No seif supporting combustion 375 525 -- - - 0.08045 {30*0 - Slight j - 0*13 (23-O -- 1(34*C) : \ - Practically insolubles? - Nil ? _ Practically insoluble! - Practically insoluble? - Practically insoluble! - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble' - Practically insoluble - Practically insoluble' -,, Hygroscopic - Nil - Hygroscopic : : : 0476061 TOWOLDMON0033031 WATER_PCB-00017500 I I I i ^ ' sf - .] '' ' . . .i TOWOLDMON0033032 WATER_PCB-00017501 O' o m m m o m o o o m m o with POP with - OOA with SANTIC1ZER 141 t I Fire retardant plastics materials are growing in favor in many end uses. Recent Underwriters Laboratories' rulings on air conditioners, the California fire laws on plastics film, and the specifications of end-product users mark a trend toward greater safety consciousness. This awareness for possible dangers will increasingly put a limit upon the flammability of materials of manufacture, construction, and decoration. Monsanto supplies a variety of plasticizers which provide molecular structures with tightly linked chlorine and phosphorus, to impart fire resistance to compositions containing them. These plasticizers represent a range of properties, In addition to the Imparting of fire resistance, that make them efficient plasticizers for a variety of resins for uses in a large number of diverse applications. These plasticizers offer a choice of price and compatibilities; many offer outstanding chemical resistance, extraction resistance, and good permanence. By selecting a one, two, or three component plasticizer system based on these products, the formu lator can develop fire-resistant compositions using a number of resins, offer a variety of end product characteristics, in range of costs. 0^7606** TOWOLDMON0033034 WATER_PCB-00017503 ftmmmmmm mmmsm The following are liquid and solid fire-retardant modifiers: TRICRESYL PHOSPHATE THcresy! phosphate is a standard flame retarding liquid pkixiktzer for polyvmvf chloride, cellulose (excepting acetate), end synthetic rubber. It ho4 low volatility and offeix good permanence; it is especially recommended for electrical insulation applications, it is also compatible with phenolic*, impart* a degree of flexibility to phenolic electrical laminates. TRIPHENYL PHOSPHATE Triptwjyi phosphate U h solid plasticizer, part.cuhrly suited for producing flame retardant cellulose compositions and coating*. R may also oe us*d with synthetic rubber and with a variety of vinyl ref-ins in conjunction with a solvating type plasticizer. SANTICIZER 140 S&nticfe&r 140 Is a phosphate type liquid plasticizer. It makes an excellent general purpose plasticizer &s well as a means of making Same resistant products. On a pound for pound basis it is more efficient than tricresy! phosphate in vinyl resins and imparts a superior flexibility. SANTICIZER 141 S&ntidzer 141 is a liquid, phosphate-type general purpose plasticizer which is non-toxic. It imparts good low temperature flexibility, has low odor and Improves the processing characteristics of most formulations because of'its excellent resin solvating power. . AROCLOR PLASTICIZERS .mai MONTAR PLASTICIZERS The Aroclor polychlorinated biphenyls' and terphenyls are particularly effective in reducing fiameout time and the glow termed "ptmking." The Aroclor compounds are compatible in varying degrees with vinyls, cellufosics, rubbers, polyethylene, and epoxies. r~T ims These polychlorinated polyphenyls are similar to Aroclors except for their dark color and lower cost. Although slightly compatible with vinyls (for use as low-cost, extender plasticizers where color can be tolerated), they are especially effective in asphalt, to which they impart instant flameout when present in concentrations of 25 to 30 per cent. , PHOSGARD C-22-R Fhosgard C-22-E is a flame-retardant organophosphorus polymer for urethane foams, polymethylmethacrylate, phenolies, polyester resins and epoxies with optimum performance properties: high efficiency through high phosphorus and chlorine content, essentially non-volatile for lasting flame-retardant service life, excellent color stability on XJV and heat exposure, easy formulating and non-compHcated handling, long storage stability ("per se" or in formulation), and good hydro lytic stability. 0*7606$ / :> 4 m 0 O a m m m 0 m m o m m m TOWOLDMON0033035 WATER PCB-00017504 iU'.Ll " '""V"TM* '*" < '**te,,U.:/^M#*tfa>*'%~'>- '.*A***,,i*M^ SOLID PLASTICIZERS mtmpsw Solid plasticizers perform unusual functions In adhesives, coatings and lacquers, foams, rigid compositions and films. Many times solid plasticizers are overlooked In solving processing problems or in obtaining unique product properties. A solid plasticizer often transforms a deficient product into a completely different, high performance product HOT PROCESSING Solid plasticizers offer processing advantages in hot processing applications. For example. In Banbury mixing, a solid plasticizer will melt at or below the processing temperature and function as a solvating or fluxing liquid; the lowered viscosity of the Banbury charge improves the flow resulting in faster and easier processing. Upon cooling, the plasticizer returns to a solid form producing a rigid or semi-rigid film or molded product. The solid plasticizer thus reduces processing costs as well as imparting unique, properties to the finished product. SOLVENT PROCESSING , Certain solid plasticizers enable successful formulation of higher solids content in lacquers. This means fewer coats to build a surface and, there fore, reduced application costs. As the lacquer dries, the presence of the solid plasticizer helps reduce blushing, sweating and separation. j I 0476066 ......... ,..... . ] -I TOWOLDMON0033036 WATER_PCB-00017505 SOUD PMSTICtZERS (continued! Description of Monsanto Solid Plasticizers n ,M 11 . Plasticizer j | Description Armlor 5442 Triphcnyf Phosphate ............ i 4 j ; {| clear, yellow resin white flakes R ?r 1 ' * ii f: | Melting Point or 1? 11i Softening Range (C) 1 Melting Point : Softening Range : 46 to 62 4 j ms MoMar % Sntici2er 3 fopdor44S5 SamoMte MNP black resin [ practically white solid : r dear, yellow resin | hard, colorless resin I t- ' l . t .............1 ' !" | 58 62 54 to 3.60 60 to 66 Oscycfahexyi Phthaiatc Diphenyl Phihalate Mentar 2 Santidzer !-H Umt&r3 white solid j white solid black resin yellow mass black solid ' . !??. f | s |, i f. | 63 63 82.5 ?o to no 86tol68 Mmim 4 Aroctor 4 Santidzer 9 _ linear 9 Aroclor 12S8 Mooter 5 brown solid yellow-to-amber resin white particles i - brown solid white flakes ' brown solid . II 1 h i f: i; r.1 1:: U 105 2 to 206 98 to im 130 to 175 150 to 170 155 to m 9*?601>7 e m m m m m o o # a o # o m m TOWOLDMON0033037 WATER_PCB-00017506 o cr O' 0 Q o Q m 9 9 m m m 0 0 FOR ADHESIVES *.. mmm\ properties ' Lvbt>*w!4ack and hfsLseal arthejbv**? owe their to solid plmthimr%> because it h the H>lk\ pbmUciz&r that mhk&% delayed-tai> and heal sealing possible. B!ayed4&ek adhesives are activated by heat, aod once activated, reamin tacky long enough to permit handling before the adfo'rfive cools and *"<*. The rhnrp melting point of sdid plasticizers provides & sharp activa- Uvn \mw*. foi the adhesive- This activation tern^nature varies with different solid plasticizers, hml spec-al adhesive?8 can h* easily formulated to fit handling methods by selecting the proper -solid pfasikiwr, Delayed-taek adhesives are covered by several U.S. Patents. FOR FILMS ... no blocking Solid plasticizers can be used with other primary plasticizers to produce tough, dear films that fed dry and separate easily. Liquid plasticizers used alone often cause blocking due to a slight surface tackiness. Solid plasticizers also add resilience to films and impart exceptional resist- Mice to extraction by kerosene, oils and grease. . . FOR RIGID PRODUCTS .,. easier processing , Processing of rigid vinyl products can be made eaaier by using solid plasticizers . , . without changing present equipment or methods. With heating, the solid melts and acts as a solvating liquid plasticizer for the resin. Upon cooling, the article becomes rigid because, the pl&aticizmg effect of the solid plasticizer Is slight at room temperature. Used strictly as a processing aid, the solid plasticizer pays its own way by lowering processing costs. FOR HEAT-SEAL COATINGS ... sharp activation temperature Like adhesives, heat-seal coatings require the sharp melting points of solid plasticizers to give them the hcaWeai property. By themselves, liquid plasticizers cannot endow coatings with si sharp activation temperature Instead, the coatings tend to block and be tacky at tempera- cores beneath 1h** activation temperature, in this type of coating, solid plasticizers can be <:btvsen to provide an txaci temperature at which t^e heat-seal property is activated. And be- fjeaih that critical temperature, the coating does not block or have tackiness. , FOR RIGID FOAMS .. . toughness In the chemiealiy-blown foam*, solid plasticizers can be used to add' toughness to the finished foam. In the plastiso! foam process, solid plasticisers thicken the starting formulation to make pos sible more uniform ceil formation m the gas is released. A uniform cellular structure makes the foam tough end provides uniform dimensional stability. In eheeatoaBy-btovra vinyl foams made by milling or Banburying, the solid plasticizer acts as a liquid solvating pl&sticieer at the process temperature to make possible easy processing. At room temperature, the solid plasticizer's inefficiency results in a higher compression-resistant foam. FOR IMPREGNANTS ... better flow To get even disperwment of impregnating powders, solid .plasticizers can be used as a flow aid for producing brake band linings. The flow aid property is.also useful in certain types of adhesives, phenolic moldings, thermosetting ureas, and melamine coatings. oe?t06 *. i .; , " ; .> : c ' ; ; = : TOWOLDMON0033038 WATER_PCB-00017507 Hsst-seaJmg seating* Dicyciohaxyi phth^lote (DCHP}, Diphenyl phthalate, Santoiite* MHP, Santtcker* 1-H, SaMlcUer 9 Rigid extrusions Dipfrenyf phthatate, Arocfor* 5460, Trlphenyf phosphate Santicizer 1-H, DCHP Moldings and rigid foams Trlphenyl phosphate, Diphenyl phthalate, Arocior 5460 and 1268, DCHP Breakaway "glass" Santolfte MNP Phtnolic brake linings Santicizer % Arocior 1268 Surface ceatlnp and composition wallboard Cellules* acetate Triphenyl phosphate Nitrocellulose DCHP, Diphenyl phthaiate, Santoiite MHP, Arocior 5468 Melamine Santicizer 9 Thermosetting resins Santicizer % Santicizer 1-H, Triphenyl phosphate, Arocior 5460 and 1268 Urea molding compounds Santicizer 9 Melamine molding compounds Samicizer 9 Fire-resistant cellulose acetate Triphenyi phosphate Crystallizing lacquers Sanlieizer 1-H Polyamides Santicizer 9. Santicizer 1-H Vinyl and ether hot melts Triphenyi phosphate, DCHP, Diphenyl phthalate, Arocior 5460 and 1268, Montar* 4'x 5, and 9 Deiayed-taek adhesives Diphenyl phthalate, Santicizer J-H DCHP Bookbinding adhesives Trlphoftyf phosphate, DCHP, Diphenyl phthalate, Arocior 5460 and 1268, Santeiite MHP, Santicizer 1-H @ m u "Registered U,S. Pat. Off., Monsanto Company O^*06' ^mjji TOWOLDMON0033039 WATER_PCB-00017508 o o m * 0 o m m m m m m o T Nlpasp 1 PLASTICIZER-RESIN compatibility; guide The following table shows a close approximation of the upper limit of compatibility of each of Monsanto's plasticizers with a particular type of resin, 0*1&70 0 TOWOLDMON0033040 WATER_PCB-00017509 4 -1 SaM m u d r l/v-nyl r.h'-vkU. , Jf, , >> , < .09 1 /J .1(5 .1 r m 5<0 100 1M 1'4 1 ISO j M IjU jg P/Ifr.y! 7-/.ta j m | (0 r . . 1 1 1 ' ( 70 , 1 W 1 | 19 I i 40 75 --...... r--@ K/'S'fififi ' iSi f 5& V I 25 I *5 ' fr IS | 1*> f 50 25 ' K0 iC 50 s 20 30 a 75 9^ ............... . 7 ** ' ! 1` ` Chloride* | 75 ! 20 r 10 25 59 as as ?o 10 j n so | a j 10 r a * # P* N u,* aMuUKie | 130 | iyQ & m j 'oc jpq !)) so * IGO ( 10C 130 i 1 .oc it, ;oo 1 ;n i /< jj Jv& '50 75 ec 1 us m m ', m v , O m 100 H fHyl Oslkla** ^ C* iy?<^ Acttate 1 1QQ 3 50 ioo s loc m {icu m m , |8 I 1 b i l a m l'Q 100 1 75 1 1 Jm I I t> 100 ICO f?5 Q i1\ l ^ CthifkAeAirttMe Butyrate ISO [ 100 50 50 -10O 50 m 20 50 m 50 40 a 40 50 75 ft) Unic*e Achate Propionate 30 IQ j 100 15 m peso m 2D 10 15 m m m 5 1 a " a CWs-rtmiM & >bfef %2$i 'lyrePH Bt-te'jsfH* sXa S 2 Pf >te* <% . ... II rr. ... 3S| rn.JHI ?yp* Po'rumfe* Po r**ter m 20 25 100 160 25 m 33 20 ISO 80 m 25 25 100 30 50 50 20 25 50 50 a m 50 20 50 SO sc 40 40 40 m 3# 3 I m i 1n i l 1 i 10 i 1; 1 \ i i 5 15 i j5I 1 1 I 1 f 1 i I ', i 70 25 100 8 25 ISO 25 25 25 25 a 25 15 i a 70 M Q 25 10 1 20 25 i 23 25 10 20 25 23 l 5 a is. Q 20 20 10 15 20 . 5 20 m a 15 23 : a 5 5 5 is ^ ip*;?? is; Ffewiffi g Af*jn$ s 10 10 f ii J i id 1 25 10 I i i 15 15 # ' 50 3 25 25 25 25 25 25 30 25 50 50 a 25 25 25 30 """ 70 25 2$ 25 25 a 25 25 25 25 56 so 25 25 a 25 30 Q S ><e S'K'ie I I 1 1 1 1 1 j I l 1 1 1 i i 1 US HPniteihaoe 8 10 15 25 25 IS 25 25 10 25 25 25 m a 20 25 15 *44 ?teo$>'oe Rypk#rs 100 ! 50 100 33 100 109 1 WO 30 50 33 m 50 50 50 40 a ; eo 0\ 0476071 {J} TOWOLDMON0033041 WATER_PCB-00017510 3 9 Plasticizer Mr Compatibility Guide I 3 Cj) j 1 >j j u ; m 100 100 80 m 50 75 75 100 I 100 80 j 100 20 s 1 I ! I 15 15 25 ; ' 1,, \ !j | li * i t , ,j i r s 1 1 S 40 S8 40 40 8Q 50 SO 10S 58 50 SO 100 ' 1C ' * -4,,_____ _ ^ j ?> r, ; n r> m 25 5 1 2D i i 25 1 m ! m 58 m 56 100 50 m 50 106 : JO C% ' : ' * a> 10 25 20 : 10 10 is j is 75 75 58 75 20 m 25 50 20 a 25 75 j 1 i i O'* ' 1* ! IB I:iI 75 ; SOI) 60 | 75 25 100 j a 15 50 too 15 20 10 ID 20 10 to 10 38 : :* 'l TMi w j IOC * m SO | 65 o too 40 3$ 35 3 IW 100 186 ISO 75 75 83 80 50 100 IflO too ; it 3 1 n Tm SO 75 100 100 m 78 XQQ 50 78 30 m &r 60 75 75 n 75 [ 1 i i 11 i * i i s i i 1 I i i 3S 20 10 15 35 20 45 90 30 25 25 108 j I i | 30 m m 2S 50 25 25 30 80 25 30 SO 48 40 50 3 50 50 ids ; i _ j 50 M S ! K> j S j ' S j 5 1 s S 48 100 40 48 50 50 8 100 50 50 50 100 I I \ m 52 ; 100 ; ico 25 ' 100 M0 i 25 100 100 100 100 100 100 108 50 25 25 50 25 50 50 80 ; ; 1 !1 @ : % w : wTM m w 35 j 40 20 31 20 50 50 59 j 50 20 25 28 as as 28 25 SO : - i Mil Mi i i 1 i } i s 1 s o 25 10 30 18 30 30 58 40 25 a 23 ' - &b~- - -- -4-- , i. , MiMt* !. f * t { s s f ? f 25 25 40 8 25 as 10 : - Mk ! 1 m ;o; 11 i i j i! W` f l! |1 i S 1 2S 100 25 3 a 25 a 25 25 3 25 50 1 i 23 25 ` lit! 1 ' 2D | 25 j ! 25 25 25 15 25 10 50 . '. * * . i.......... 50 as 80 50 ' t ! ^ ' !> 15 5 5 ! 5 ID 5 j 5 I * 1 m 20 m i m 10 5 5 10 s a m 5 ' . . ;. . ii`. | * 10 * t - J 1 1 l Mi i 1 s 25 25 3 | 25 10 m 20 50 58 2$ 25 3 * ~ "?------- i 1 75 25 25 : 25 25 ! 25 75 j ' 25 25 25 , 50 58 50 j 50 so 50 50 50 SO SO 50 SO . S'', j, .i ? s it & | r r 50 25 78 78 50 70 so 48 30 3 25 3 25 70 1 if f i i* j i i t ! t j t t i 1 l 1 I *F4 1 25 25 50 80 25 25 ' . ill JW r, ' 20 ' - 20 ' 25 : 20 iB 15 8 25 25 25 18 10 10 20 10 25 a as - g*| ! 09 ' 50 S ~ 50 i 05 50 33 i 20 j 33 ! 33 48 50 55 j 50 50 50 50 SO 50 so 88 #*y6* TOWOLDMON0033042 WATER_PCB-00017511 ms ' , >'i '' 150 1 20 ; loo 1 109 s 100 *08 V/> 1"i j Mi tos ; % j o'gT; i :'<** 100 100 i" f 0 1 11X3 15 r 25 r 59 J 100 3 ! 50 i Vj| '<.*, ICO !" 4S ' 40 15 30 ' 30 \ 50 25 | i>\ j n : n j is 10 ! iof 10 j % ' ' * 10 25 j 10 j 25 j 10 1 i 58 \ i i 50 i 40 10 [ 15 ?5 so f i t ?> 10 10 Vi 10 r so W 53 * 20 ; 1 ; 1m0 j i JO I 1 , 100; iooi m m r> ' n m i so 1' , j 50J ISO $ SO ; got' 50| `W I 50 ioo f m m m iim : m `m , m , jog wt\ im , is 1 - ,i,, _ i, 1, , ~ i~~.- 35 ^ 10 , 10 f 33 ! 19 * 103 j % 75 | 25 I looj' ' 75 j WO i * tUoJ 15 lOfTT i I' 5' ! ' {' \ 109 j tt*> 100 j 50 ISO IGQ , 1U . 50 , 7i &J : 89 50 i IQ 50 l 23 . 40 40 50 ` 11 '1JL1 50 j 50 ; 30 5 , 10 20* 10 f ! ! ' \ j f 5 i 1 50 , 51! 69 ; 89 100 | SO 50 ; 50 50 , 50 s 70 50 ' 50 ! 50! 100 100 10 0*?6#?3 TOWOLDMON0033043 WATER PCB-00017512 e^trt monomeric and polymeric pfashcizers that wntairs onsaturatmn often become ttoxmwtohie because of chemical insta&frty. Epoxy stabilizers scceierate this exudation so that tack and hrt phsk'ttp are frequently observed m a month or two. C-smpfeteif saturated polymeric plasticizers, such as S&nbchter 409, remain tack free upon exposure to N&rth Indirect daylight tar more than one year. good homiddy eompai*thty do not exede from Elm specimens n 18 weeks* exposure at 60'C end 100'per cent m`%Vmh fwwmdrty. # Patents pimimmrz are qotcwy screened for compatibility with polyvinyl chloride by com* pressing loops of plasticized vinyl specimens for one week at 23*C and SO per cent relative humidity. The amount of plasticizer squealed out, rf any, is determined by wiping the inside of the fold with cigarette paper. 0476074 2 TOWOLDMON0033044 WATER_PCB-00017513 TOWOLDMON0033045 WATER_PCB-00017514 (tesiN L:. . MP Cellules* Nitrate ;......:............. :....... ^ fMMvm . .. -- CaiNitese AcetateBatyrats C#Batee.Ppfiat cellules* AO^tiC Polystyrene rSiyviyi MijmWv Polyvinyl Btilyrai Wjwwl teatat* &ni'*Knluntht,Aai+m, chloride :-r, Ws$miwm$m% Santicuer 1H Samic?zer tiO ' Mf&MimWZ ' ' " .- atom*MHP Diphenyl Ptsttatei* ' fc#icIz*fkM ' fantkizerB umat&u-n SwtotfteftNP ' ' 5mail* bH $antc*zer t $nmim m? CMcyduhesyl Pfiibdstss SaRtkizer bH Santfcfzer B Santidzer M*I? Santicuer 1-H Santdite MHP 0l>heKt PMhafete Oieyclcbe*yt Phthefete Dkydohexy! Phthaiate iknikm* l-M Diphenyl PHhalat* Diphenyl Phihatate SentkizerB Areolar Diphenyl Phthdate Trkresy* Phosphate mmcirnr m Santleker2?8 Sftfttiefe* 160 $aht!Czer262 Diphenyl PMbalate Okydohexyt Phthafate Tricmyl Phosphate $*ntkiz*r m Aroclof Tfkresyl Phosphate umkzm 846 , Stettfeia** SanticfzerB SantUzizm UA7 AfpClPF hanUuierg ` | Banticizer 160 1 SM%kiMfWZ- ' \ Iricresyi Phosphate SaMielier IS5 " AfPClOf Santohte MNP SsnhcijerS CA-'SSbZ'c! i: .tf; . Dihutyl Phihal^f DiOCtyl PhtlwU^s. 1 SaotJvizer UO ^r.Uuer 165 Saoticizef m. J | | Santkkart' 3er4d*?r -16 , Saatlazer 8 Diethyl PhtMate | $antczer -16 1 Samkszer % Diethyl Pdhatete Santici2f -15 $ant<dm 9 Otpbenyl Pbthakte iarttzaerB Santictzer W-l? Sanitizer IS) *ntlci2* 141 Santictzer 8*16 Santicizer 262 Santfcizar 8-16 Santtcuer160 Sunticizw 160 Santicizer 141 Diocfyi Apjpate Oi!iH>ct)'l, n-decjrt) Adipate Seaticizerg ' Saetidzer M47 Saetehte MHP Saotehte WS-30% . . oanhdzer # Saatidzer M4? Sa-itolite MNP Afsctoz .. s Swtisi 8 Santscuer M-l? Santdite MNP Sahtohte MS-60% Saits cizar 8 Saitid'zef 9 Saitohte MBP Afoclof Sartt'-azer 8 Santahte MHP S4bt.cer 180 Santiozef 262 LKcyciohexy! Phihaiate Saoticizer S $aahc? 9 Santofite MBP Aroclor Santielzer 1# - , Arocior ytijl Santicizer m Santicizer 262 Dsethyl Phthafete I 1 Saafidzer 6 .1 SantrJzer M-17 j ? I j SatiCfZr 141 i Dwctyl Phthalate s i Dibulyl Phthalate 1 . Santfcizer B Santicize? -1/ i ? t1 ` Dicctyl Adipate , Diiso^ecyl Adipate 1 D(n-octyt, rvdecyi) Adieate Sahtio/ef 160 Santiozer 141 SantiCizer 8-16 Sanbozer 262 I Oibutyl Phthalate Santicizer 141. i t t Oioctyl Adipate DKn-octyt, n-decyl) Adipate Dusoctecyi Adipate Sr i Santicizer ISO Santicize? 141 Saoticizer 160 Santicizer 8*16 SanticiJ Ul Santidzer 8-16 * SantldzerS Tncresyl Phosphate Santicizer 8-16 Sanlkizerg Santieizar M-t? Santidzer g Arocior Diethyl Phthalate Dimethyl Phthalate Sarttldzer 9 Santtelzer 8*16 Santkizer 160 Arocior Dibutyl Phthalate Santicizer 141 si Bmlkmr M-17 SarUicizef 45 Sentidzer 141 Dibutyl Phthalate Santicizer 8-16 Smtksmr l Iw \ Chlorinate# ftubim CPariowJ Styrene-Butadiene Rubber ?PiteHte m6 Mattson) ^ Casern, Zmn . Areclw MotHEs*# Santidzer* TriphenyS Phosphate Saottetetr 148 Arooior Tffcresyl Phosphate Arodor Dibutyl Phtealate Saniidzer B-16 Dibutyl Phthalate Santieizar 160 SanticHW M47 Santieizar Itt Ssntkizer 141 Saniiclzer* lifed-Epox Areckf Santtcizer 8-1S 4 j Arocior S Santicszer 160 Triphenyi Phosphate Trkresyt Phosphate Aroctsr Tfimsyl Rwptata Tfipheiryl Phosphate 1 SBStfSeew* Santidzer 9 Santicizer Ml Dibutyl Phthalate Santiozer l&S . I. Santicizer 160 3antict? Ml i Santicizer 8-1$ ... i j Snia'TMr* | 1 iMbitlb. TOWOLDMON0033046 WATER_PCB-00017515 ...rnmumam :U^mmrnM^ ; D>bntyt Phthalate I- $amtei2*ri& ; .? - | Sawue*er$ . :mtekmM?} <. ?r>p*wy) PiKK$tet :`4!felwil -;.' f s 0*cyciobe*yt Pbthfctete thpnebyi PMbaiate Trtcresyl Phosphate $&*ticmr 409 m? Santieker 8-1$ Santidzer # Diphenyl Phthalate Santehi MMP Aiodof T.rictesyl f^osphate Sjntkiier Hi Tiphenyl Phosphate (fcocttf Phthdat# Santkaez 165 . 5atk.z^ 169 $K>5trees' ?$2 CHfeutyi Phthalate TzfH,*`yl Phosphate Sanhdzer 9 [TaMcim I -: i Saw ,u*r 8 ; UanHclzer l-H \w$x&mm-m ' j ?mU*ner t-l* ' Tr.pbanyl Phosphate Satohte MNP T^pher-yl Phosphatej fsarstsd/er Ml I'm.iyi Pfcthatat# I $*>otC*zer 150 1 Tnphenyl Phosphate ; ibdyt nmmm i $-r*hC>ter 0 \ D>phe?} PntviSale j AhtrWodiiQor srnmmm S mVmmr Ml? ; f *>ipf.e*'yl Phosphate I \ Santimer 140 I Senhcszer 8 i ; tkxitf A-dipat# | feantfcurar AH? ; Mssd&cyf Adtfate | Diphenyl FMbalate j Sanhcizer 3 l Mlmt Santidzer 160 Santidzer 846 Sanridzer 2S2 Sa/Hidz^ I H Diphenyl Phthalate Oicyeohexyl Fhtbaigte Diphenyl Phthalate Santfciaer Hi Samicizer 3.60 Samfcizer 8-16 Diphenyl Phthalate Trlphenyl Phosphate Santidzar Smittuef AH? Sanhc./gr 3 S*nt",*r $-15 Santehte MHP __ Triphenyl Phosphate Saniidzer 143 Santkizer 149 Sanhcizer 8 Sanbcizer At-!? Sanifccrsr -35 Sated te VHP | Santiate* Hi Trtcresyi Pho^pi'ate I Tnphsnyl Plio>p .ate 1 .Amck>r I Sartticizer 8 Sanhc.zw M-17 Sate-sw '35 SantoliteteHP____ Inphonyl Ph^phat ,Sant!C(fr 140 Santiazer S Diphenyl Phthalate rricresyl f^osphate ijantlcizer 143 Arocier Trlpheny! Phosphate Santldzer 8 Santidzer 8-1$ Saoticizer 165 Santidzer 262 DicycSphexyi Phthalate Trioresyl Phosphate SafiHclzef 141 Santidzer 149 Phosgard C-22-f? SanticUer 3 Santscize#-? $&ntkiz$r 8-16 Arodor Tricresyl l^osphat Santlcizer 141 Sanmarn M3? Saotktzer 45 . Cseihvt Phthalate 1 CrnW/t Fh'.halate r Sanhcfzer M-17 ) Saiticizer 409 I Sar.tici-of 8-16 | Oioctyt Phthalate Santjczer MI? Santrciier E45 Diethyl Phthalate Dioctyl Adipate Diln-octyl, n-decyl) Adipate Dioctyl Phthalate' Sanbdzer 160 Santicizer 8-16 Santidzer 262 Dibotyl Phthalate Santicizer 160 . flfeefy! Adoate I Dioctyl Adipate m^m, j Ditn-cctyJ. rntecyi) I Adipate Adipate | Dhsodecyi Adipate Diphenyl phthalate i Santicizer 213 ] Areeiof l $3i{icjrer 409 Santidzef 8-36 Saiticizer 141 Santiozef ISQ Tricresyl Phosphate Santicizef 140 Santfawtm Aroclor Dioctyl Phthalate Dilsodecyl Phthalate Sanhcizer 4 Swrtictoer HI Santkizer 360 Sarrhdzer 8-16 [ Diphenyl Phthalate I Dicydchexyl Phthalate [ Trstmsyf Phosphate Santscizer 8-16 Santicizer 160 Diiwtyl Smtitimrm Sauted' M-i? SenttCtter t- 5 S*tki2er U. fhfeetyl SazMieizer SMI Santicner 1&> Santicize? 3 Diphenyl Phthalate I ?pher?yl Phosphate | Smftdzer l-H | $at>ctzet 8'16 ! Triphenyl Phosphate | Qihtityl Phthalate | Dfcydohexyl Phthalate Tsantkizer M-l? I Santlcizer 9 | SantSeker -15 Triphenyf Phosphate T"5Styn>hthaiate I Smticizw 160 Bmticizer $ Dibutyl^Phthaiate Samidzer ISO Santicizer 8 $anticizer 9 Santldzer 1SI Diethyl Rtthatete Trtcresyl Phosphate Santicuer HI Santidzer 140 Artxlor Trtcresyl Phosphate Triphenyl Phosphate Seotfcizet 141 Triphenyl Phosphate Trtcresyl Phosphate Arocloz Santicizer 141 Tricresyl Phosphate Santicizer 160 Sanhcizer 8-1$ Dicyclohexyl Phthalate Dibutyl Phthalate Sanlicizer 160 Diethyl Phthalate Sanficizer 8-1$ Saniicizer MI? Sanhcizer 45 Santicizer 8-16 Santidzer 6-1$ Santidzer -15 Diethyl Phthalate Sewtcet 8 .$ i SanticiZer 8-1$ ( IWod-CDOK Santicizet 8 I Aractor Santtctzgf Hi ^ Zzntmier 8-15 Diteityi Phtho ate 5 Ofeuivi Phthalate Santtdte# lt-0 ' 5aohcir 141 __ __ i Tficresyt ^osphate TI-Urtk&nr b& fsjrtKteerm ' i Santidre*- HI 5 Saotic^er 14i | Saotlciz< 8 IS ; Santicizer B46 | Santkl/s^ 3 "~j"Santldzer 8 Afoclor Idphenyl Phosphate Tfkzesyi Phosphate Santsdzer UQ ^ Tnpresyl Phosphate Santicizer 140 TrlpheoyJ Phosphate Aredor Saot-dzer $ Smticn& Santicizer 160 Mod-pox Dibutyl Phthalate Santfdzsr 8-16 Santicizer M47 Santldze*-160 Santidzer 8-1$ Santidzer 141 Sanhcszer S SanHcjzer 9 Arodor Mod-pox Tricresyl Phosphate Sanitcizer m Atador Tricmyl Phosphate Santicteer Hi Arodor Tricresyl Phosphate Bmticmr HI Santiciz^- B-16 Santfdrer 8-1$ Ssntlcizer 1$0 Dibutyl Phthalate Santicizer 169 Santicizer 8-16 Olbuiyi Phthalate 0^160*? TOWOLDMON0033047 WATER_PCB-00017516 ..Jk.. iJkiiL i ' * * " I Tncresys Phosphate \ Arccfer 1 Sams/'sjyr 0.J6 .. [ S/*n< wits141 . i $mduu%z: i# ..-! I * Aptpai Santicizer Hi SanticUer Zt D.'octyj Phrhatete Ptecty! Phthtitte } Sw.. ?<*f.W J Seztiiolztr 141 . Santidzerfl .. M4? Santklzer -ff : Diethyl Phthaiat Santiazer 160 j Ctactyf Pnthalate I ncresy? Phosphate Santieizer itu Sanhc zer 8 Sanbeker 141 Samsozer Pb4 banticizer 262 SantiCfzer M-J? Samite MhP AAOtlor SarvtsczerM-l? Sanftcizer 45 SarsticizerS Santidxer 8 my s&tmm mhp Dibutyl wphaiate $a?*c.i2er 160 D octyi Phthaiace SasviciZer 165 Sanncizer 262: Samoine MHP 5artt.`C.?*r -1$ Stniidzer M4? Santoiite MHP 45 Sanfidzor 846 Sanfcetoer 141 Pketyl PMfcaiate* Tricresyl Phosphate Santidzer 40 . Areder - OiOGtyi Pfcthaiate Trlcreayt Phosphate Santrcizef M47' Santtdzer I ' Triphenyi Phosphate Serrticizer 409 Santidzer 1'40Santidzer & Saniidzer M47 Santidzer M4? Santicizer 45 Santkizer -15 PietM PMbaiate Qkklfl Sent*'cmm ms 45 141 Dtocl^l Fhtt^late* Santicizer 846 Sttsticl&tr 141 Smtidzm 8 Saotidzer M4? Sarvtidzer #09 141 III 262 Static?!* 140 Diethyl PMhafMe - $ f Sartitfe* l# M-17 f Santtcizer 8 Triphenyl Phosphate * Senticizer M47 footer oioctyi mmm Trteresyi Phosphate Santicizer 160 Trkrttyf Phosphate Santicizer 265 SarHlcizer M-l? SaMidzer 45 Triphenyi Phosphate Sticizef 5 Santicizer M-17 Staticizer 8 Santicizer 160 Statk&tr262 Dioctyt Phthafate SantidzeriCO Diisocctyl >thalat* Santlclzer 160 Santidzer ill Santsazer %2 Samicizer M 17 Santiozer E-15 rI fnpbanyl Phosphate - SenticiZer l-H \ Santiazsr S j Santicizer 8-16 Sanhcizer ISO Dibutyl Phthalate Samidzer 262 -u-r B45 Sant c-zer 141 Dk^d Adipate Sanhciwr 141 Diphenyl Phtbatet Santloaer 160 Aroctor Staticizer 141 Santicizer 9 Sanbctzef 160 Diphenyl Pthatate OicycMtexyi Phthaiate Santkizer 160 Sanltcizer 160 Samicizer 8-16 Saot c m in j Sanbozer 409 Still c zr 8-16 * Santiazer 282 Sanhc zw 160 | Dnsooecyt Pnthelate -`tody Phthaiate* j Tcre?yi Pnospnate Dhsotetyi Phthaiate | Samicizer 140 OtrrU Adpats I Saat C'ter 8-15 $ane/ =zyr 141 Dk-.-V* Ad<pate fncmyl Phosdiate Santicizer 141 ' | 5aotiCfZ#r 140 Saoticizer 166 OMfiZv; Phthaiate Saot'c m m% $#m<c m 45 zw 160 Twresyi Phosphate SamiciMr 141 Dspherr/i PMhatste Tnpiwnyl Wmiplate Sant=c zer 45 D-tvl Adipate Phthaiate Sentsv zr 645 Sa^ts-, zej 846 Drccrzi Adipate SaoPozcr Ml JMhbc* zer 160 SHci2 B-l Trijjhwyf Phosphite Tficresyl Pty^sphate Tflcresyi Phosphate Sanhcszer 141 Sarrtkizer 8-16 Sauricker 8-16 5atf^zef-15 Mod-pos Aroclor Sawiictz^ 8 ^-oclof D<octyi Phthalate Tricresyf Phow>hate Tncresyl Phosphate Santicuer 160 Arocior Trkreayl Phosphate Diethyl Phtheiate Santicizer -15 Arocloz Santidler 141 Aroctor Mod-Epo* Santicizer il Tficresyi Phosphate Santicizer 40S Sanhcizer 262 Dnspde^t Phtha!ate Santicfzsr 409 Dioctyi Phthaiate Samczer262 T> cresyl Phosphate Santicizer 140 Saotidzer 8-16 Sanhcirer 141 Saniicizer 8 Samiazer M-l? Tfiphenyl Phos^tate Santicizer HI Santicizer iffl Trtcreeyj Phosphate Santicizer 8 Sanhcizer 8*18 Triphenyi Phosphate 3aotkizer 6 Santicizer M-17 Santiazer 8 Santkizer M-17 Santscizer M-17 Santrcizer -15 ZmliGize! 160 Sntrcizer 141 Aroctor Sentidzer 141 Tricresyl Phosphate Sant'cizer -15 Mod-Epsx Mpo-pox Arachr Dioctyl Phthelete Semicizer HI Samicizer B-16 Santiciztr 1^ Santiciz^ 160 hmttcizer 141 Santicizer 8*16 D*butyt Phthelete Semidzer 8-16 Semiazer HI Santiazer 8-16 5mticker M47 Santicizer 160 Seniicuer 45 $mdzer 8-16. Saeth,,//:, Hi $a0ts-^/Oi- 8-16 Ddf Adipate SBrtwm 141 Dioctyi Adipate f Tficmsyl Phtadtate t SantiCfzer 140 "' 141 Trscieiyt Rtosphate Hi Aroclof Triciesyl Fhmphate Santicizer 141 ^oclor Tneresyt Phosphate Aroclor Santicizer M-17 Tricresyi Phosphate Santicizer 141 Sanhcizer M-17 Sehtrctzer 140 Arocior Tocresyl Phosphate Santkixer 143 Afocior Santicizer 141 Tricresyi Phosphate Santidze? HI Sahticizer 8-16 Sentk*zer 8 Sentkker 8 $#ntcizer9 Santiazer 8-16 Santiazer 160 Santiazer Hi pibotyt Phthelaie Santicizer 8-16 Santiazer 160 Santiazer 140 Oibttvl Phthalate Senticizer 8 0476078 TOWOLDMON0033048 WATER PCB-00017517 VI':-: ' V :'V Wj.flfHS flllfclvi A-' ** ... '%' / i/,r-.--Tf V .................................................... _ ^-------- - * 22m irff^fini rSpsliSS Sentteiztf | Imparts- flexibility without advertA? affecting tensile strength, abrasior- resistance, or oil resistance, Smimtm- % Santiciter i*H and $mMM MHP each impart property< improvements in particular applications, Pofy*t* Awier compounds impart fbsme resistance and improve adhesion* chemical and oxidation resistance. i -'Hiil^illfi iiiii rBff$Lf.t0..fIr0fff?u3ffiStn8lnyUSA0 Santicizer 8 and Santicizer 9 improve flow and adhesion. Iricresyl Phosphate, Santidzer 160, Dibutyi Phlhaiate, Santicizer 140 and liquid Arocior compounds improve punehebihty erf laminates. Tricresyl Phosphate, Santicizer 140, Santicker 141 and Arocior compounds impart llama resistance. f^alL * S&ntK u&r "} improves solution and color StUb hly, gloss, flew, adnasion, and imp#i '-stance of mtlarmne coMsng?,, Urea-FfflmmMetrsrtt Santicizer $ improves ftow and acts as a hardening agent AlkytJs Arodor plasticisers impart improved adhesion, chemical and oxidation resistance. % 4 1' TOWOLDMON0033049 WATER_PCB-00017518 o 0 0 0 0 0 0 O O' 0 0 0 0 0 0 0 0 0 PLASTICIZER PERFORMANCE m MOLDING AND EXTRUDING The following table will assist compounders select plasticizers for formulation evaluation on the basis of those properties most critical in the final molded part or extrusion. The plasticizers shown provide the optimum effect for each designated property when used with the resin shown. When the same plasticizer appears under two or more of the properties desired in the final product--that plasticizer definitely merits evaluation. i i I 8 0*760* TOWOLDMON0033050 WATER_PCB-00017519 m mmm mmtznmmm . ti&WH mn>4* ...... .................... ~^$4didz&f J60 SertHwllj Sentklz#? 3#f! , Tths&>yf Ptt'WhMe SfScittr2M Dloctyi Adipate Oitooctyl. n-decyfl Adipate Qi sodeyl Adipate . . d | Diphenyl `, Santicizer 10 *1 ? SanbeiTCflAO 1 SaUazerl41 iM| f Santteta* 409 ' { Orcetyl Adipate ......... 9 f TWcnasyl Phosphate } Sanh'dzer 262 j Sadkker262 '' } I m.mnytitem mm&t Pom<nyt m&ms 0 ethyl PhtfwMete Sisntkizssr E4S ____ __ _ : Santtazer 9 ta>nuct7*tr 8 &mtkiZ%riM7 Santicizer 141 1htsvtyl Phthaiate %&r<tidzQr 8-16 : ' 1 Santicizer M-i? Santicizer E45 | Arador { f . * . . - ' '! '' -r Sanhcizer 141 Santicizer 8-1$ Santicizec 3 . Santicizer 8 Sadidler Ml? Santicizer 8 Santidzer M*S7 . __________ . iajrrM i m i UPl ...m Pelyityr6;n6 Santicizer 160 Dibutyl Phthaiate . Dibutyl Phthaiate Santicinet 14! . Diphenyl Phthaiate d ! zmwim# . Aselaie ' SsntkkerM47 Diethyl Phtbeief* ' . Santicizer E45 . Diethyl Phthaiate Santicizer 8 Santicizer M47 Santicizer 8 Santicizer 1-H Triphenyl Phosphate . Diphenyl Phthaiate Dimethyl Phthaiate Diethyl Phthaiate Santidzer E*15 Santicizer 8 lljll 1 . AmfMM - Santicizer 1 Santicizer 141 Santicizer 45 Santicizer 1*47 Santicizer 27$ Santicizer M2 Santicizer 141 Diociyl Phthaiate Dibutyl Phthaiate Trlphenyl Phosphate ' . Santicizer & Diphenyl Phthaiate ` Aroclor Oibutyi Phthaiate . Trtcrssyl Phosphate | Santicizer 140 0m TMiiM&m wmm Dibutyi Phthaiate Santicizer 165 Santicizer . Santicizer 278 Santicizer 212 Dibutyi Phthaiate Dioctyl Phthaiate Santicizer 16$ Dieyciohexy! Phthaiate Diphenyl Phthaiate Trlcreeyl Phosphate Arcelor .' Dloctyl Phthaiate Dibutyi Phthaiate Santicizer 10 |p| 1 _| Santicizer 160 - Oibutyi Phthaiate '' I^IC*al95* . " Santiciwr#* Santicizer 262 Dioctyl Adipate Dhsodecyl Adipate DKn-octyl, n-decylj Adipate Trkresyl Phosphate Dioctyl Phthaiate $Wmm Butadiene _ JtKitheHGR&l Oibotyf Phthaiate Aroclor Santicizer MO Oioctyl Adipate Santicizer 141 ' Santicizer 278 Santicizer 262 Santidzer 1-H . Diphenyl Phthaiate Dtcyciohexyf Phthaiate Santicizer 8 Dfoctyi Phthaiate Santidzer 10 Trlcresyl Phosphate Dibutyi Phthaiate Santicizer 10 Santicizer 141 1 .gfc. ,i Santicizer 10 CHoctyl Adipate Trlcresyi Phosphate Dlisodecyl Adipate Ht . " Santicizer 141 . DKn-octyl, n-becyfj Adipate Triphenyl Phosphate Trlcresyl Ptxrsphate Dlpher^t Phthaiate Santidzer 10 Santicizer 141 Santicizer 8-16 0( | ! ."* Santicizer 10 Aeftife . , - . Santicizer 141 Santicizer 282 Santicizer 846 Safttieizer l Santicizer 262 Oicyclohexyt Phthaiate Santicizer 1-H Diphenyl phthaiate Santicizer 1 Santicizer 141 Santicizer 8*16 Santiciz^ 262 '1 JM *P| Santkizer* SantidzerS SantitiMr* Santicizer 3 StntfciMr* J ' Santkker 9 SantfckerlSO V / &* +r*Fmr")* r" <**'*#!%** TOWOLDMON0033051 WATER_PCB-00017520 lrcres/f phosphate Samicsrer 160 ' . ' S*f*Ctteri4 fjl Wm&f> Ptmfstet*. Sanheizer 141 :;fMtk!ier:MI. ' - Trietesyl Pheapfcal* fmmtmm ' . Am&'mt ; . ' .Santicizer 262 1 lbnt4f$r'3fl ". Sa^|cker27i I baHru/er 168 i Sanhdzer ill . j $mihizm W.' SaotteizwZTS . . mmSrn^Pmrnmit ' :.i mifoeo^tPhthaiate* ~.4 $mtkirn?m ':} Santicizer 160 .4 Santicizer 846 Dioctyl Adipate 1 %sdw 1 # Suntic /~ir S 1|F Triph#%f ! ' &msteg ' Samtfcteer 141 ; Ttkmtf nm&m : ' :' .: Triphyi phosphate Trisrosyi phc&e^te I |' j. . Santidz^ 846 Samlcizer 45 .- Dkthyl Phthalat Switici^f mi Santicizer 45 ' Santictzer 846 Diethyl Phthalat# Santicizer 45 Santicizer B*i6 Santicizer 141 Dioctyl Adipate Santicizer -15 Santicizer 846 Dioctyl Adipate | _| I | f TM1 J 1 J-d--_ ! Diphenyl Phthalate .Arcelor Triphe^ Pimphat Tdcresyl Phosphate * Santicizer 141 Dibutyl Phthalat# Santicizer 160 Santicizer 141 Santicizer 8-16 Santicizer E45 Diett^i Phthalat Dioctyl Adipate ! \ I f -j Santicizer ' Santicizer 1H | Tripheff! Phosphate #% .................. W Sssrrtieilff? | SanUefeer t*H Diphenyl Phthalate fUr Aroefo? 4 Irip&mtf Phosphate Santicizer 141 Santicizer 143 Triphenyi Phosphate DMhyi Phthalat Santicizer 141 Jricmyl Phosphate Triphenyf Phosphate Arocfor Triphenyi Phosphate Diphenyl Phthalat Santicizer 160 Santiel*ar278 Santicizer m.7 Santicizer 45 Diethyl Phthaiate Dim^hyi Phthalat# Sentlciz- M-17 Santicizer 409 Santicizer 8*16 Dbctyf Phthalat# Santicizer 45 Diethyl Fhthafate Santicizer 141 Santicizer 8-16 Santicizer 141 Dbctyl Phthalate* Diisooctyl Phthalate* Oioc^f Adipate j | J I \ 1 | 1 i f^P Diryek^ryi Phthalate i Diphenyl Phthalate ! Trkretyi Phosphate Areekt? Trfcresyl Phosphate Santieizerl# gantteizer Hi Diphenyl PMhafate Dieydehej^l Phthalate 160 $nticizer 278 Santtctzef 160 Oibutyl Phthalate Dloctyl Phthalat# Santicizer US Santicizer 160 Dtbutyl Phthalat# ! Ssmiefet; I-H Diphenyl Phthatete . Trteresyi Phosphate Santicizer 140 Santidzer 141 feeder Dioctyl Adipate Ditrvociyi, fKlecyl) , Adipate . DiocM Phthalat Santicizer 141 Oioctyl Phthalate* Diisooctyl Phthalate* Santicizer 8-16 Dioctyl Adipate Santicizer 141 Santicizer 8-16 Dioctyl Phthalate* Diisooctyl Phthalate* 1 j f | | THcre&yi Phpspbste | Tdpbtny! Phosphate Diphenyl Phthalate Hip Arocter - -. Tffcresy! Phosphate Triphenyi Prsosphate Santicizer 141 Arcelor (3 DipbrV hthalate ! Dkycfotessyt Phthalate 1 Trtptmftfl Pho&phate * "N ! ti$ ' ' '--r| OteycWtworf fWlu mgtmmi Wtftslate Trteresyf Phosphate Santteizer 140 , Santicizer Ml . ' Aroefor Triemsyt Phosphate 5*nticizr 141 SanticizerMT - Mcysloiwi^l mttwiate 1 SantfsteMr? Dioctyl Phfiiafate Santicizer 141 Santicizer 1SJ . Dioctyl Phthalate* Santicizer 8-16 ;; Diisooctyl Phthalate* | Dioctyl Adipate j Dioc^l Phthalat# Santicizer 8-16 Santicizer ^9 Santicizer 160 Santicizer 262 Santicizer 141 Santicizer 8-16 Dioctyl Phthalate* Diisooctyl Phthalate* Santicizw 141 Santicizer 8-16 f | | 4 j | Santicizer 141 Santicizer B*l$ j 1 9*ntkfnr9 IP Andor .' 1 Arcelor Thereby! Phosphate Santicizer 149 ` Santicizer 141 0x,7bOW ^ TOWOLDMON0033052 WATER_PCB-00017521 octyi Pfttfadate* hbib-s '*,** mtmwf Ml ' , aMMmiM ' M&hsfmr SPIi : 'hctyt Adptte hetfcyi Ptflfcatete *ftl&ar E-X5' 4*ntid*er H4i *n&ckm 141 hoetyl Adipate . - mmw E4S ' >ant!Car 846 *Cfyi Adipate ' Gantidzer 2S2 $**tkizv 2$2 409 Santiei2r 409 ?rie**syt' Pfm0m$m mirnkeytmmm'i . -isiiireigwtsi. umMwe-my- : mk$zm-m,, : ' : Sm&zimrmiSafit2dtefS46 : Santidtef 4$ ; Santidzer E-25 ' Santldeer 8-1$ ' Xriphenyl Phosphate Santicizer 8 Santieixar HI? Tripteiyf Phosphate Arodor - ' , $rnmrn Mi ArooNar - Trlcresyf Phosphate Santicizer &!$ Santicizer S - Santicizer HI? . Santidw 8-26-Santicizer 645 Santicizer M47: Santlciter 141 .-. * Santicizer HI? Santicizer B-ifi Santicizer E45 *sk&er HI >antidzr 846 iffiidm t15 Jtetftyi Phtftatete ApC%2 Adipate MtfMztem 4$ x*$ys mmm'rn *8tmiW X4| Mid^r 846 ted*er 241 ?&sety2 Ptsthaiate* "Mmmkfi Ptithetete* }&$$ Adipate teetidzer 141 iHiooctyf PfctftiHate* 84 ?iss%t Adipate 3arttidzsr Hi $*tdzer 846 Dbctyl Pfcthefate* pliteoctyf Ptehsiste* Sanfidtef 141 OioeiyI Pbthatete* Santicizer m$ Diteoeetyi Pbth&iate* OjetylAdipte mtk&mm mmrnt Pwmi&u* mwtxtyi pmi*t* Ssw*r Mi SwiticfaswMi, Tricksy} phosphate Santicizer 241 Santicizer 160 Santiciiw <*-17 Saniictew 45 Aroctor THcresyf Phosphate Trlcresyl Phosphate Santicizer 141 Santicizer 8-16 Dtbutyi Phthalate ' Santicizer 141 Triphenyt Phosphate Serttfeizer 6-B Santidzar i 53tidtef409 Trlowf Phosphate Santicizer 148 Santicizer Ml S*ntfCer409 Trlcreeyt Phosphate Dioctyi Phihatate Santicizer140 Santicizer # Santicizer HI? Saoticizer 2-H Santicizer 27$ Santfciwr* Santidzer HI? Santicizer 160 Santicizer 2-H Stemldzer 262 Santicizerm Santicizer Santicizer M-t? Dlefchyi Phthaiate Diethyi f'h^salate SanJicizer 141 Afoelor . Qioctyl Pftthatate Trfcr&syl Phosphates Arodor -- Dlocty! Phtttafata ' Tncresyf phosphate Sanilclzer E-15 Santicizer Hi? . Diethyl Phihafate Santicizer bH Santicizer 262 Dkfctyf mtiateta Tricre^yi Phosphate Sarrticlz^ 14i Santiciw 160 Santicizer 278 . Dioctyl Phthalate TriciwI Phosphate Arodor - Santicizer M-17 Santicizer E-15 Diethyl Phthdete Oioctyl Phthalate Dibutyl Phthalate Santicizer 241. Santicizer 8-16 Dioctyt Phihslate Dibutyi Pftthaiate Santicizer 241 Santicizer 265 Smtkim 409 Trteresyi Phosphate Dhsodecyi Phthaiate Samteiztf 8 Santidzer Hi? Triphenyl Phosphate Arocior ' Dipctyi Phthalate Trtcresyi Phosphate Saitticixar^ Tricresyl Phosphate Santicizer M-17 Santicizer 141 Tncresyl Phosphate Arodor Oioctyl Phthafate _ 7ricrmyi Phosphate Oioctyl Phthelate .. Oiisodeqri Phthaiate Santicizer Santidter 166 Santicizer 278 Dioctyl Phthatete Santicizer 241 Santicizer 265 Santicizer m Santicizer 278 Oioctyl Phthalate Oioctyl Adipate DI(n-octyi, n-decyl} Adipate Santicizer 846 Dioctyt Phthalate Santicizer 241 Santicizer 403 Trteresyt Phosphate Diodyi Phiheiate . Safttidzer 141 SanUciiarMl Safltfciar 168 Santicizer 262 %mlmmr % Santicizer 9 Santicizer HI? Trtcresyl Phosphate Santicizer I4S Aroclc^ ' Tricresyl Phosphate Oiodyl Phtftafcte Sswtkim mi Seottelzer $ Santldzer 260 Santidzer ^2 SssntlclswS Tricresyt Phmphate Santterzerlfil Sarttfclmtm SantlcizefS Dioctyi Phthalate Trlcresyl Phosphate SSfttldtef 241 Santldzer 241 Santicizer 168 Santicizer 262 Santicizer 8 SaoticixerS Otoodyi Phthalate Santicizer 1^ Santicizer 141 Santicizer 268 Santicizer 262 Arodor frfaisyf Phosphate | 1 ` Arodor A/oclor '. frkrmyt Phosphate ' TOWOLDMON0033053 WATER_PCB-00017522 'J t- m. J f O- I 0 o'S3?ft*';ar9 Trpr**l P1*o*,pf*a 1 0>pf**-;>s PftfnaJatr X(tpnfrtfi **K^,ph3 o Saf.ciom 9 1H ' ?<fp*Krl Ph<xp>h&' 5iMnu9 oi HHhalat* Awip* 0*cycf.hMrf PMha I Pbttoixte "inc't'yl P>hmph$u | %anm>ur 409 SaniK ;/r 1 H | Dipftfe *y PMbdiat* ^ Pnospnafc Tr;p***r/i Phptftiai Ptohaiai* f Arprkf I1 . .. 1$i mph*<v?i mh*\*Ui 0Jc>ef>tte*yl f^tha ***ft*i . sam^;/f m t)icrci-4ui*jft Phtha ZHpbmrfl PMftafaie PtAET.CIZEft PERFORMANCE IN MOLDING AND EXTRUDING (contimmfl Q lift flap for chart 8 & &i ssi sM SsnUcim 9 meM for tmpmisg ptelsTM.. Sssifejisf i-H, g\m, flaw etemctmstm, mi m ' SssMer $ and Mi MP a hifd&ft&f. B l MW. sr 9 KS84 fer impresTlng s and as | S*m\tu m Santiom % fatKky- ' "~1 0476084 TOWOLDMON0033054 WATER PCB-00017523 04/6085 0 I TOWOLDMON0033055 WATER_PCB-00017524 o o m m m m l*F;pega4-j ,......... --... m -W^V fP j o iSssl&u2 o PLASTICIZER PERFORMANCE IN FILM AND SHEETING ' The following table will assist resin compounders select plasticizers for formulation evaluation on the basis of those properties most critical in the finished film or heavy sheeting. The plasticizers shown provide the optimum effect for each designated property when used with the resin shown. When the same plasticizer appears under two 0 or more of the properties desired in the finished film or sheeting-- that plasticizer definitely merits evaluation. " 0 O' 0 o^ifeoae 0 TOWOLDMON0033056 WATER PCB-00017525 2?a D><-ctyl Ad>pate Santt~i/er 262 Sanlciter 1$0 - . %mmw m ::;v-' ' Dith-octyl, fvdeeyD Diphenyl Phthalate Santicizer Ml: ' ' ...Sfr0eiarMi i V; ' Adip*t ' Sanlfcixer 1#' ' ' , CHoctyf Adipate ; ' - Sasthsizar 146 ''; - ' . Trfc?syi DiiSociacylAdipit*. 43S - Tffcesyl Phosphate Senticizer m . '. Q .: Sanfieize? ZM . r Of#*M Phmtete Sweeter 141 AmcJsr ' P3fyyieyttd8 Santictzer -15 Oifcutyl Phthaiaie . ... Santicwsr 8-16 Sanhetzer 141 Santtciz^ 8*16 i 1 } Polyeloyl . Atari*! *! fcetata* Sotynrtt %wiiCit*r 9 Sanhdze? i 3emicfctr M4? Sa*tci*f 168 Pehutyl Phthatste SanHcl** M-U Diethyl PhtheSate Samctm -XS .Sifttietxerltt ' Santicizsrllt Sstic#r*i5 Semidzerm? . Santicizer M4? Santfcfcw *15 Dihutyl Phihafat* ' Sntic!ze? 141 Sanhcizer 3 Sartfrcizer 8 Samhcizer *l? . tfcphehyi Phthaiste Santtcizer 4 SaMcizer -27 . I j *1 01 m Dtethyl Phtfcaiate Ssmkriier * Santtozer M-17 Santiclze-f 141 Di&etyi Phthaiate Dtbutyi Pftthaiate ` Samietear* Santidzer 1*H Dimethyl Phthaiete ' Dieihyi Phthaiate rmn_ l) Triphenyf Phosphate Samtcizez 4 Diphenyl Phthafate Santiclzer S . ..................................... ^fny - Triphenyf Phosphate Santidzer $ Oifeutyi F^thalate Tricresyi Phosphate ^ : Diphenyl Phthalate Amciof . 0| I C 'IMese 1 **r?M OftsuJyt miuut* . ms#bci>w Samidw 5 DIbtftyi Phthalate Dioctyl Phthaiata Saoiieizef 165 Dieylohexyi Phihatate Diphenyl Phthefete Triemyi Phosphate Afocior Dioctyi Phthalate Oihwtyi Phthalate Saotteizer 165 jk: lihyt C*tt**to* ' Santfctetr m Oibwiyi Phthaiat# DioetyJ Adipate Ditsofecyi Adipate OI{?octyi, n*deeyil Atps?e S&mklzer 1-M Dipftenyi Phthaiate . mcyktexyl Phihatete Sarrticizer 8 Dioctyl Phthalate Samiciz^ 160 f| Ki&&*r CBR$> THcreeyi f^'mnfcate Oifeutyt Phtfcsiate Aradof ^ twwrticizer 160 Otoctyi Phthalate Oioctyl Adipats Saniicizer 141 - Tricresyl Phosphate Phthaiate Santicizer 160SmfJcizzr 141 Setsdim* mggmi&umH} fhWyagsiti* SwUeiwr 160 . T/icmsyl Ptosf^ate Saetidzer 141 Dioctyl Adipate SMisoctacyT Adipate CHtivoctyl, n-decyi) Adipate tfipheM Ptwjsphate Tricresyl Phj^phate Diphenyl Phthaiate Sahtfcto 166 Samtciaer 141 Santicizer 8-16 | ^4 ' fgg 'I Smttco*t I s #i most sHWsnt plastieteer. $*nticiur JH SwitkiMt 9 sod Santofrt* MHP are *lo useful 4^ a* VH&1 TOWOLDMON0033057 WATER_PCB-00017526 | m {(.pa* !>. i-Bthaiat* hm$w 1mm$fl Phosphate QL1 F 1 AfO'.U f o ! . ------- Q * Tops* vi b-ospoate F Trkresyi Phosphate Santidzer 1# Saniidzer 141 Arodor Af&ck# SanliCszer 141 Trscfesyl Pfrasphete fnpheny} Phosphate Tncwzyt Phosphate 04ph^ v: Pr-fnalate 7np'n^4 P(,?*,pht* _________________ fjJ %'*' "< i-M f>*K*M Pfa*ph*t* 0 uxK.*v<> l-H jgJ 0*6*r -s Prolate Amcie" Arocior fricresyi Phosphate Sanltcszer 141 Triphenyi Phosphate Saotiazef 141 Santictzer 140 Santictzer 141 Tritresyl Phosphate fnphenyl Phosphate Aroctor Santidzer 262 Santidzer 160 Santfdzer Ml Trieresyl Phosphate &*tidzer 2?6 Tflphfcoyi Phosphate Diethyl Phthalate Tnphenyl Phosphate Diphenyl Phthalale `Jamsclzer 160 0>ck* 4*e*yi Phthalate C3 8 -y late '**'1 TffCf* fi P '/`CyfihM# s Sects',-;-,* 409 ^ .. - %8PrU .i'V I'M O.^bf. -,. prtcal*te Triaw/t Phosphate Sfitczer 146 Santtcsz^f 141 Iticrmyi Phosphate Sanficfeer 140 Santicizef 141 Arociry Diphenyl Phthalate Dtcyobhexyl Phthalate SantiCrm 160 *l ?rph*<vl Phosphate | 0>ph& t?i jg||i^[ AjfiC'< ` Tricresyi Phosphate Tripitenyi Phosphate Semicizer 141 Ansdor | Dtphe-*-,- Phtnaiale agj D.cyd^'y1 Phtr.aiate Phosphate i $a?**> *,?<!>? 469 Tricresyl Phosphate Semiciier 140 Sentieizez 141 Arodor $atid*r 262 Saotidzer 160 Santldzer 141 Santscizer 270 Dlpctyi Phthalate mm&icyi Finhaiaie Saniidier 409 Dioctyl PlUhaiate* * Dusooct/l Phthalate $ah';C<zer Ml Santfazer 8-16 . &ant*cizef 160 2 SaiHimer 8-16 SantiCfzer -15 Diethyl Phttalete SaMicizer M-l? Santlcizer *15 Santiclzef 8*16 Dibutyl Phthalate Santidzer 160 Senticize* m7 Santicizer -15 Diethyl Phthalate Dimethyl Phthalate Samicizer w-i? Santiciaw 469 Santidzer 8-16 OioclyF Phthalate Smitcmr im Dibuty! Phthalate Dioctyl Phthalate Santicfzer 16$ Santidze/ 1&8 Dibutyi Phthalate PieU-yl Phth:ete $ant>d?e> 15 Santicizer B-1& Santicizer 141 2 Santicjzar *15 Santfcizer 8-1$ Sant.ev^f 141 Santictzer 8*16 : Santicizer -1$ Diethyl Phthalate Santseize*- 8*15 Diethyl Phsalate , Sahtiazer 141 : Santicizet 8-16 Santicizer 141 1 Oioctyl Phthalate* 2 OiisooftyF FhthalaQr Sapt MI D.v.t/i Phtha ate* D> sc<Ktyl Phlhslat- SantiCizer 8-16 Oioctyl Adipate Di{n-octyl, n-decyl) Adioate Oloctyl Phthalate Dioetyi Phthalate Santicizer 160 Dioctyl Phthalate $antlcizer 8*16 Santidzer 409 Santlclzer 141 Santlcizef' 8*16 Dioctyl Phtha at* Dnsooctyi Phthalab- Santicizer 141 Dioctyl Phtha ate* Santidzet 8-16 Diisooctyl PHthaiabt Santidzer 141 * Santlcizer 8-16 Dioctyl Phtha'ate" Diisooctyl Phlhaia 047606S TOWOLDMON0033058 WATER_PCB-00017527 !J s -R M*A'!ksT v r- r .\ Prpdy / C`f>,<Sarc' Sanireaer 278 Sadrdzer 278 ,e ih-t.rs't' ( ^ntt*Ah\c' Ssmtscsg^f 4C# $**ttti*er 439 Hi Saoncfzer 262 Tricresyl Phosphate Smuoz-' 3 16 Tncresyi Phcnprme SaMdzef 10 SMOOCH,' 166 Dosodeoyl Phthalate Santidzer 466 Santicizer 40$ Santidzer 411 Santidzerlfl Santiclzer M2 Afoclor Dioctyl Phthakte Trlcresyi Phosphate SaMidzer 282 Dtisod&cyl Phthalate Srnmtztm mrnm Phthalate Aroclor Safttidzer 406 Dfoctyl Phthalate Oitsodecyl Phthalate Santidzer 141 D*e*'JV * ,(*h.f#tr> %-Wt>' ./* ' ! 16 S2?'t.', 2 ; A j.6 i" HI Sontici?*f 141 Tzdicszer 8*16 Sadidzer M-1.7 Santicizer -1 5 Aroctof Saniicizer 141 Aroclor . Santicizer B-16 Santidzer -15 Santicizer M-17 Santicizer 141 Sant <. /n 7 i*f %9>Mh /*f ^-L& Sad'Cfzer -15 Sadie.*zer 8-16 Tr*pH*nyf Pho^fccte Senile'mx 8 ' Santicizer M-17 Tr?phenyl Phosphate Tficresyi Phosphate S8ntici2Sf 846 Santidzer 8 Santidzer M-l? Santicizer M*17 Santicizer 8-16 Sanficiter E-I5 Sara'.f'' 'it Sardsc r< 846 SanD-w- ' ."45 * *Sft ^ate Tnciesyl Pfwnphate Sad*c.tzer 141 SsnHdzer 160 Santiclzer M47 Santidzer E-l$ Aroclor Trictesy! Phosphate Trieresyl Phosphate Santidzer 141 Santicizer 8-16 Oibutyf Phthalate S*r->k'Z'f 45 Onrt*y: I'O'Ca'afe S*h-. r HI Sant'C'zef 141 fnphmyt Pfmphofe fdnhr.szer 5 15 Santtctzer 8 Sanhclzer 8 $mltetzist M-U Santicizer bH Diethyl Phthalate Samidzer 141 Santlcizer 45 Santicizer M-l? Diethyl Phthafate Santidzer 1-H Santicizer M-l? Santicizer -15 Diethyl phthalate Sadie,? ; 3 16 Saotn u-f Hi D>octyi 1 Mhafate' Omco:tA Sant*c*zer 409 Tncresyl Fbos-phate Sadsctzer H6 SediOZ*' HI : Sad'' Hi i Ut'St/ f 'ft,i'.'M' 0v/>..t . P/maiar--S46 Sgn'irt.zpf 109 T'H'es^f Pv.-=,r! &?<? Ofc, V 'dhH-U' 14? tanuc,/*t 41! SanUcizer 8 Santicizer M-17 Santicizer 160 Santicizer 1-H Santicizer 409 Santicizer 8 Santicizer M47 Diethyl Phlhalate Santicize? 411 Arodor Dioctyf Phthalate Tricresyi Phosphate Aroclor Dioctyf Phthalate Tricresyl Phosphate Dioctyf Phthalate Trieresyl Phosphate Santidzer Ml Santicizer 10 Dioctyl Phthalate Trieresyl Phosphate Aroclor Dioctyl Phthalate Dtbutyl Phthalate Santicizer 141 Santicizer &46 Dioctyf Phthalate Dibutyl Phthsfate Santicizer .141 Santicizer 165 f4<*!,h: S^r-i-i.' /f f 3 *6 OwV f vhdate* P*wt4 PMhafate' Sad.c z*r 10 fr>c'es>y' Pho^'-nte Dnsodecyf Phthalate $entictzr41i Santicizsr 8 Santidze/ M-l? Trit^ier^i Phosphate Arocior Dioctyf Phthalate . Trieresyl Phosphate Dioctyl Phthalate Oissodecyl Phthalate Santicizer 165 . Santlclzar 10 Dioctyi Phthalate Dioctyl Adipate Di(n-octyl, n-decyl) Adipate Sadh -zw 141 0xM f-^rMfate* Sant'C'Z -r 8 16 0ovx>ct -1 Pnthatate* Sm<c*rer 409 Trtcnssyf Phosphate Santidzer mi Santlclzer 141 ' T>trey! Phosphate Aroclor Dioctyf Phthalate Trieresyl Phosphate Dioctyf Phthalate Santicizer 141 Santicizer 16S Santidzer 10 Santicizer 8-16 Dioctyl Phthalate Santicizer 141 141 Sa<4H,z,-? & 16 0Aty> * ?#sh4Ht* Oosonct '8 Phthalate* SaotidzerlOS Tricresyf Phosphate Dioctyf Phthalate Sadidzer 141 Santidzer M-l? THcfesyl Phosphate Santlcizef 140 Aroclor ' Trieresyl Phosphate Dioctyi Phthalate Dioctyl Phthalate Trieresyl Phosphate Santidzer 141 Dioctyf Phthalate Santicizer 165 Santicizer 141 <H?6Q8 TOWOLDMON0033059 WATER_PCB-00017528 TOWOLDMON0033060 WATER_PCB-00017529 PLASTICIZER PERFORMANCE IN ADHESIVES The following table will assist formulators of adhesives select plas ticizers for evaluation on the basis pf those properties most critical in the finished formulation. The plasticizers shown provide the optimum effect for each property when used with the particular resin shown. When the same plasticizer appears under two or more of the desired properties important to the finished adhesive--that plasticizer definitely merits evaluation. v ...... ....... . . ...... i* j :. j TOWOLDMON0033061 WATER_PCB-00017530 PIASTICISER IN M'r^VES :- ifii^ -. Sfeifufc** titrate fm'MMm Acetate Sefl&iase Acetate* butyrate g#iftsse preptcnate PdyrifiyiefiJefhte Petyyh^yt Acetate m$&m Aieeftei Ptlpinfltdane ' ..^ ,, ,,/..'./.*. 7<*iphr>nyi Pnooptvite Sanbeizar 144 . - Santidzer 180 "v. P?|4i^i ffitbilite ' t Santicizffr 8 SanUcrzer 140 . Tricresyl Phosphate Santscizec - %w&mm 14$ SeRfi Mdrn P4? SamdittMHP SamicizerS Diethyl PMhalat* Santidzer 4S SSHtiOZef l-M Sanhoze* 8 Santidzer M4? Dtcydobeyyl Phtt state $#niJf?*r Diethyl Pbibaiata Santidzer E-15 Santi&zer 1 it SanbtiZer 8 Santidzer M1? Santidzer S Diethyl Pbtha'ate Sonhdzer -15 Stnitdzer l-H Santatiie MHP Diphenyl Phibalata Diryttehexyl Pbthafate Dtcydoha^yi Phthatete $nttet*r l-H Diphenyl Phthalate Diphenyl Phiodaie SMMfCtnr 9 Arocior Diphenyl PhtbaJaie D-cydohex/i Phthalate Ttfcrmyi Phosphate SanMctzer 160 D.pMmyl PhtMate Oseydohexyi Phthalate Tricre&yt Phosphate Santiazer 1# Aroclor Tricrmyi Prto&phate Santicjzer 8*16 Ssnnctrm 560 Santidzer 9 Diphenyl PWhafat# Sanhcizer 8 fantf^iznr M-17 Santidzer 160 Sadidzer 14! Santidzer 8-1$ SaoDazer 8-15 Santicizer 166 Sentfcizer 1 Santidzer 141 Oiodyl Adipate DKn-octyi, n-decyl) Adipate Santidzer 168 Santidzer 141 Santidzer 8 Trteresyf Phosphate Senticizer 846 Santicizef 166 SentJCizer S Santlcizer 9 Santlcizer M-17 Amelcr Mhtjcizer ifey Santlcizer 8 Santlcizer M-17 Samidzw 846 Santiclzw 160 Dibutyl Pbtnaiate i Aroclur Sanfecizer 145 - Santohte MHP Santidzer S" V ' .. Santidzer 8 ' Trtphenyi Phosphate Santidzer 846- THpheoyl Phosphate SafsliC-^ 8 Santidzer 45 :. SentlcizerS Santidzer M47 Santoiite MHP Santdste MS-80% Tripbeny! Phosphate Santidzer 340 Santidzer 8 Santidzer % Santidzer M4? Ssotolite MHP Arocior Triphenyl Phosphate Saotldzcr 140 Santidzer 8 Santidzer Sanhcizer M47 SarvtoHte MHP Santolite MS-80% SanMdrer M-17 Diphenyl PftthaSate Santidzer h Sanllcizer 8 Sanhcizer Santohte MHP Arodof Santidzer 160 Santidzer 8-16 Santidzer $ Santohte MHP Santidzer ISC Sanhdzer 141 Santiazer 166 Santidzer &.& Samic&erS Santidzer 9 Santohte MHP Arocfor Dioctyi Adipate DiCo-cetyl, n4ecyll Adipate Oiissxfceyt Adipate Santidzer 166 Arcelor Santolite MHP Santidzer 141 Santidzer 168 Santidzer 8-16 Santidzer 168 Santidzer 8-16 Senticizer 8 Triphenyl ^osphets Santicizer 8-16 Dibutyt Phthelate Santieizer 160 Santlcizer M-17 ^nticizer -15 Samicixer 3 Aroclor Diethyl PhthsfMe Dimetf^l Phthalete Santlcizer 1 Santlcizer 9 Dihutyl Phthalate Senticizar 160 1 d d w HW CPriel Stynjpie-finta^idfe MbertriMeapa Utrienl C^iein, 2eia ArocNr Mpd-po Se^ldzer 8 Triphwtyl Phespttate Santidzer 140 Tflcresyl PlKKf^tate Amdor Dibu^i Phthalate Santidzer 9 Santlcizer 8-15 Di&utyl Phthatate Santidzer 141 Santlcizer 150 Santidzer M-17 Santidzer Santidzer 141 Santidzer 8 - c>' --~-y Santlcizer 8-1$ Mod-pK Arocler Saniidzer B-16 ... Dibutyl Phthalate Santlcizer 141 Tricresyl Phosphate Santlcizer 160 Santidzer 14! Santidzer 8-16 Aroclor Santidzer 160 Triphenyl Phosphate Tricresyl Phosphate Aroclof Tricresyl Phosphate Triptservyl Phosptete Santicizw S Sanficijftf 8 Sgfilsetzar 9 04 76004 TOWOLDMON0033062 WATER PCB-00017531 ;a . SartKt/cr -15 SafdCiZf* 8-lfe 1 ml: 1 S^fdter4$/: - Dtetfeyf ' . Sr.-:.} Aroctef TntiMift Kwipmste Pofnaiate m .. 9m#k&M&v&Safftlciacr 8-1$ Santkz*rl41 Dloctyl Phtedate*.. , " Trktesyl Ptes^hafee - Santidtef 45 Otethyl Pttfhstm SsHficw i DMWMiliti :%2&&^ :T?3ELJ - 1 Santfeszet 150 Oioctyl Pht>-alate Tncresyl Phosphate 1 fncre&yi Phosphate Szniidw 150 Santtozer 140- 1 " $.: ' / .vf .: S&ftikitef: 341: "T ' ... urntimm- : 1 \ ZmMtim 1447:-r ' .'Afadssr;"". 'V '-i' .. Dioctyl mhglate | ' S^tidzsr 45 Santidxer g $antetite MHP - ' ' .Santidztrt ", ' . . ' ' Sai^icizer M-l?; .. . :- Santieizer W-i? - -' Ssfftldxef IW - Untieittrft .. . .' ' $mtieh&r $ ".. Triphenyl Phosphate Saotic*2f te~17 Santidzer40S ` ' '. Saottei^r 8 Santleizar M4? ' Sanheizer E-15 Santteiz^ 140 'Tfloresyi Phosphate Santfdzer #9 a i i 8 1i i Staticizer 8 Saotlclx^ 140. Santteizer 140 Santicizar J447 . Santldzort . Santicizer $ Trlphenyf Phosphate Saoticker SSir Saticizr M-17 I m m 0 Santteizar B-n - Sartfcir 45 m OU&tfi fhmaiate* - S4tiri2er 6-16 - SantfctoerMl Saotidzer 141 Santlcszar 8-16 .. Santidtef 141 SantidzerS-lS - Otectyl Phlhatete* Oilxoodyi Phtfcatete* Arodor - ' PlsJCtjfl Phthalate Trtefesyl Phosphate Trlctesyf Ph$ptiate ' SaRttefzarlSe Arocior Sanlieteef 141 Sam\m mr Sarmim 4$ Tripheny1 Phosphate SantictaerS Santicfzer M4? Staticizer S Santidxer 166 Santicizsr 8 Santicixor ISO `' Dlodyl Phthalate Santidz@r439 Dhsooctyl Phthaiate . Santicizer ISO Santicker 141 - Oiphaf^jf} Phthalate Olcyclohexy} f^thalate Sanilclzer 150 AfOdOf Oloefyt Phthatete Trkaesyi f^&sphate Sartticizer 1S0i ncreSyt SrnUnsA^,*KMkia4wM. SanticiJMM* 439 . niif ii.lifi -nif l*-*T*t't-fi-s*fS9UP Satldzer 409 . Dioefyl Phthalate ' Trictesyl Phosphate Dkjctyl Phthalate Santiclzer 409 Santidztr 141 Saotidzar 141 Santicszer 160 | Santteizer 141 Oiphanyl Phthalate Santidzar 409 Dilsodecyl Phthalate lrlcrm.fl Phosphate Santidzer 140 0 tfi w 0 SwKidasr 94* Santldiar 141 ' ihathyi Phthafate Saotteizac 6-16 .. SSteSSurnmm1m4? SantidwrMS . Upr 0 Dtethyi Phthatete Saotidzer 45 Saotid*** 8-16 Sarrtlsizar 141 0_ _ SantidierS-lS Santteteer 45 Sifitkftcr 141 Santteiter 6-16 v-. # Sentlctfer 8-16 Santtetear 141 0 0 iztetesyt rhosphste Sentfetar 160 Anwtor * OCfSjr{ FTHOSpnaw yjeffqf? rmnasaie mmcirnm SanBrtwC-tS Arador Saatleiaar 111 fefcd-Epo* Aroeter - tester jfierssyt rTsiSpuaie Sadldzerl4i Atedor TriCteSf* PhOSphat Smtimsm* - . THctesyl F^phats SaitMcIzd- 3^ Sahticizar 81S Santicirer 141 Saoticlzefg umicizw mr TtipMtifi Phosphate Safitici^ar 160 Oafttlcizer S Saolidzef 14-17 Ssfttklzr m? Santlcker -15 SantickerUf Tffcfssyl l^osphate Santictzar .15 mM.p&x Afpcl&t SSwntSi&lmftlm?t*9**' $mrnrnrmf Santldz^ m Arocter . Safkldier 8 Ssnticiwf Ml Santictzw 10' Tffassyt Phowhitt Sarttkizer 8 Satefesze? B-16 Triphenyl Phosphate Santicizar 160 Santiciier 8 Samttekar M47 Arocior Santicker 141 Trkresyl Phosphate Santicizer 141 Santicizer 346 Santicizer 160 1 f TrlcrMyi Phosphate Santielz#rl41 Diphohyt Phthaiata Triphe^l Pho^iate . - *1t Sapticlzar 8-1$ ' Triphersyi Phosd^te Tricresyl Phosphate S| Tncresyl Phosphate Santiclter 141 Sarrtldwsr 6-15 a ?4od~p0X Aroclor .' ' Mad-Epc*: Araclor SafTtidzer S i rseresy! rffospnat Santfctzwl AHjetor Smtkiztr 1 Arodor THcresyl Phosphate-' - Santtcisef 140 ; Santicizer 141 Trtemsyt Phosphate Sgfiticizar 141 .. Santickef84S Samlcizsr 8 S&ntitiz&r t " TrtefesjFt Phphate.. SanHde Sahtidaw' 141 Aroclor Santldzar 8 i, Santfeizar 9:, - , o a&o'** TOWOLDMON0033063 WATER PCB-00017532 PLAS'H-.fK PERFORMANCE. iN ADHESIVES (cont.nuid) t, . ........ 1 " ^, V* |p '' ' . ' `- ;: ;m '= o o o s'*8 ' 3*" Kr' ' V\, "V; >>r" y'^.- f> ' ; ?A i 1 1 r * kidM^. mii.iiftru'tiiiiiiii Oiethyl PtrihaSate Imparts Quick tack to polyvinyl *ctat--emuisior^| adhesives, including ontoxic ones. ' %Jr jctUMtitE* rOSMAiSEHYM 5**itr&f t Mpms eofs? sta&8% #w,sed s4hsjfl. i mmm.~ FftlBHY&E Ss*!tkfcr I ttd Sastk#r 9 imfrv Pew etm&temtks. mmmmm Saaticizw' tmprem fi&# ami acts sgefti. o o o 9MMI TOWOLDMON0033064 WATER PCB-00017533 o p b o o o o o o In formulating piastisols for various kinds of coatings, slush molding, rotational casting---the selection of the plasticizer system is critical. Storage life, speed of cure, the hardness and tensile strength of the cored compound can all be developed to the optimum values through selection of the right plasticizer or plasticizer blend. the following chart shows, for quick comparison purposes, the characteristics of a "standard" 65 PHR plastisoi formulated with the various Monsanto plasticizers, using Qpaton 410 resin without stabilizer. These values can be used as a guide to the performance of a particuter-type plasticizer. However, closer values to the particular property most important to you may be obtainable by a blended plasticizer system...which can be recommended to you by Monsanto's Plasticizer Council. ' G"?609S TOWOLDMON0033065 WATER PCB-00017534 HI | in BrmkfM4 HM #6 Spindle 50 8fkt ae fhitli) ' 1 Dsp M m*c Initial 1 Ba^s M &?% ' . S6*C tnM&t ' 1 &$$% , 281Hm% %mm & Wmi r 0 p&l ' 8 K-psl ' ' *F$sw Intim Yield Valuer dynes/cm* PlftioR tm&, * Time, mlmtm inches reboimd (Stamens steel bail dropped 48~ 4 Oftfe O.r tnldc specimen <g> 23*0} *~mi Science, tmtw rebound (** Vttt d Mil dropped W t& surface) 7.700 10.700 13,800 11,700 10,900 3,600 5,400 6460 14000 17,000 26,500 2,400 4,460 5,100 3,580 7,700 8,900 6,290 9,900 8,500 13,000(01 164,0000}t 164X30(4)1 196,800(7)* 18,000(5)1 292,0000}$ 5,000 11J00 13^0 6,200 5,380 930 6,000 10,900 14,100 im 6400 7J00 10,400 170,900 Gel - i,m i,m 13,006 3,400 vm %ism 4,003 6,200 6m 7,400(4)) 17,830(4),* 20.600(5)) 3W6)i 624XXK6U 84.O0OC6)) 3 3 4,a 20,608 32,300 538 IUQQ iuoq 6,200 20.4O0 33,106 2,800 12408 15,400 20,000 Gel 2,200 vm m 9,100 Gel 3,700 7,000 7,500 7,7(30(4)t 22,000(6}) 74,00005}* 69,000(6}$ msmm 111000(7)$ i 7,600 533 10506 8,003 6,300 8400 8400 6400 3400 3,180 2,400 20,900 31,400 294X30 4,m 4,900 .4,000 5,500 6,300 $.200 22m n:m 16,600 304.000 243.000 145.000 U 8.8 14 0.? tz 2.0 IM U 64 465 373 m 32 40 16 255 17 95 IS _m 9Syr 9 127 138 9 ' 11 AS M 127 IS 46 - a 119 105 146 - 30 HI 14 7 ~ u 5.1 44 6,4 9S - 122 _ - 18 18 -- 15 HI 0476096 TOWOLDMON0033066 WATER PCB-00017535 tv/pager" \1 % im | MW 12308 | MO0 %m mm ; itm \ \%m 12300 tom nm 3,440 4,480 4m 24,000 27,m 3:1m 30,808 38308 42300 5380 u,m 15,400 4,400 5,200 6,400 5,008 5,600 5,608 2300 3,000 3,400 . JO3O0 1630Q 23,000 97,000 93,000 2,600 *4,690 73,009 63.408 J %m ism 1r~ | 4,7m | 17300 I H500 T , ) 5m u,m npm j 53O0 . l 3m2/(5m0Q 6,m n,m 13308 64*30 39,200 3; nm \ im | simm i i U400 9,30D MOO , V r~~ i 12 | in : t~ .............. 24# ; m r U2 j m li* 3 132 ) ' " 5 5 1 5,1 4S I ) _| _! _ |J 6,403 nm mm 6,108 26,600 44.000 3W 8,100 4200 03 464 6 4$ - 3m i%m 4m 54,400 km lOW 19,200 nm m 7,100 250,900 Gel %m mn mjm wjm QtJ ~ 25,608 Gel ". 15,900 Gei " 4130 ,280 4330 40,909 72,700 73309 53JOO 119400 139300 5300 S,400 5,808 13 33 33 * LI m 224 440 72 m 92 100 105 18 25 24 15 43 1,7 O 5J - 27 3,800 km om 4m 8,160 12,080 \m 900 70Q 8.2 785 IB 7 103 34 4,000 4,0904,200 2,100 4309 4,600 9,600 159388 Gel 42,400 41,000 mm mud 30,400 30| 3300 5,200 5300 2,708 5,200 6,200 2G6.e1l00 ~~ 35300 32,000 mm sim 2n7mm. 2,500 2,008 1.500 15,100 14m 11,700 16300 21,400 1*388 98,500 E5.000 &0,500 iB,art 77,000 72,508 04 6.1 2.1 0.9 as 640 m 48 160 m m 100 7 7 ._ ~ m 4 J 104 92 ,, - -4 26 - _ 04760V? TOWOLDMON0033067 WATER PCB-00017536 mm *?.m itm nm nm nm j mm j nm mm mm utm J M,m mm mm urn nm nm nm nm mm mm 117,680 mm mm mm 216,000 tm 11,400 14,505. zm 4m 4,700 7,500 18580 2Q$00 12,080 20,000 mm |i III 1 aas : i2.m mm um m mm 33m ; 13360 mm > 2im mm {15,106 mm nm nm 5,200 i2m mm mm tm 6im wm 7tm i4m 3./3X3 4,900 6,600 6,080 12.CK7D 35,080 8,000 42,000 z&m 31^6 nm nm Am 11,200 313^00 urn %jm 2,900 16^0 20500 m am nm ism nm 112,166 17300 zim Asm iim nm >100,600 >100*000 mm nm nm nm 10,106 mm Mtm 54,606 nm >\mm a# Gel mm nm mm nm ttm $r>.m IS mm nm 31*110 nm nm mm mm i&m mm mm mm z z -- - m i m m S3 , 8J mm m LS - I - mm o 0 m 96 -m - - |- - - -- - m _ - - - - - - ,, -u _ _- - - - \ tm - 4,800 ' I 23 - - 60 - --' 13$ - - 4- 4.5 45 - --. -- -- --- -- : i TOWOLDMONOQ33068 WATER_PCB-00017537 Wttli SanMcizar 213 '' Inclusion of Sartlcteer 213 greatly Improves old release of vinyl plastisois. With Woetyl Phthalaie 1 i 444 1 04 26099 4 TOWOLDMON0033069 WATER_PCB-00017538 m Plasticizer Perfcrwtance in Other Resins m- \ PLASTICIZER PERFORMANCE IN ' ETHYL CELLULOSE FILM m 49.5% Eihokj? Content) *' " ISP!**' m 1 1 .=} | a ekf Tssite Ptini Strength m O 0" Control (no plasticizer) Db-ityl Phthalate Diphenyl Phthalate 6755 8960 3625 ' 5120 ' 5405 7680 Tr cresyl Phosphate 4550 7470 , Santicizer 140 Triphenyi Phosphate ' 5405 4550 8535 66 Santicizer E-15 4265 6685 w Santicizer B-16 Sentfcizer M-l? m Santicizer 1-H 3485 " 4125 5475 4905 7965 7750 Santicizer 8 # Santicizer 9 # Arodor 1242 4625 4625 4905 # Aroclor 1248 Aroelor 1254 , N 5475 6185 Aroclor 1262 7110 # Arocior 4465 8535 *rWd Point Plasticized Film # YMd Point Unplastiekwt Film 6900 7325 7395 7540 7825 , 8035 9030 m 30 38 38 48 38 30 40 '36 38 32 34 40 36 30 28 22 22 index'*' , 100 Resistance ^siilizaiion less Re*its$ty Mmim on ligfi! txpmsg EE ,,j ' 55 G E' 80 E G ' t % 70 E ~ _4 80 E E 70 E E i 65. G E. ' 50 G E ' 60 G E 80 E E 70 G E . 70 G E 75 P Q 80 P G 90 G G ; 105 E G s 125 . G p J E = total fi =-tod ..*-= PW 1 o<<fbicm i TOWOLDMON0033070 WATER_PCB-00017539 Per t .VP.? n Ct;vi Pf..n5 PLASTICIZER PERFORMANCE IN NITROCELLULOSE FILM (12 Mil) il&ikutf : ' Jctaswr ' V ; E ftfefCjda ;. : .;.. is m . m rm :: Ts$ii, p.$i .jsphr mrm Etotpiiw m B$f*t fsrs*i!ty (%) ( 25 PB*: 59 PHR .. :., 25 PHB :,, Control (no plasticizer) 20 20 8533 8533 Saitticizer 1H 26 10 ---- 3270 _ 7 45 41 Sariticizer 8 Santicizer 9 . . 22 " 27 16 -- 2275 _ 11 ... .... - ' --~~~ 31 63 60 -- Sarticizer ISO 11 14 -- 3555 _ 10 10 19 Dibutyl Phthalate . ' 25 10 -- 2700 _ 4 36- 65 - Triphenyf Phosphate 29 24 4410 _ g - 52 56 : Tricresyl Phosphate 20 -- . 1210 _ 24 16 28 . Camphor -- -- -------- -5405 _ 6 . & | .... J/'J 1 PLASTICIZER PERFORMANCE IN CELLULOSE ACETATE (LOW ACETYL) * MOLDING COMPOSITIONS (52.5-53.5%) ,* 'j'a . ..... . . ' - (51 5 PHR unless otherwise specif:JS ,.,<.. : ntttksm Solytfofl twh^c H*riteessst?0'C. Rockwell "M" Seale Ftattral Strength (p.si.) Per Cent Water AtewM 48 tee. Dimethyl phthalate 120 32 5840 1.14 Diethyl phthalate 140 . is 5680 1.20 - SarticizerM-17 148 , 65 7110 0.77 Santicizer E-15 148 - SO 6930 0.97 Sarlicixer 8 ' '.. 133 75 ,. 6860 0.94 . . Sartcizer 9 , 153 90 ; 9160 0.85 , Tfipltenyl phosphate (42.5 PHR) 180 . 81 9020 1.17 1 & j i m 4 A m r G # d 1 J f 1 $ 047610JL TOWOLDMON0033071 WATER PCB-00017540 0, : O PtASTICttER PERFORMANCE IN CELLULOSE ACETATE-BUTYRATE FILM <37% Butyrate, 13% Acstate) " f (50PH81 ' HiifUter (p/. i s Oanpiion (.%) Q Dimethyl Phtfialate 1 46 4200 14 Dibutyl Phthalate o Santicizer 160 o Dioctyl Phthalate j | Dicyclohexyl Phthalate @ Diphenyl Phthalate . Santicizer E-15 ' Santicizer B-16 - 38 1800 12 42 . 44 2700 2900. ' 9J | 19 4 30 . 3900 31 .4 i42 3800 ' 28 ii 34 2000 14 40 , 1800 : 15 i Santicizer M-17 Santicizer 140 52 i : 42 1800 . 2700 18 13 w Santicizer 141 , . 44 2300 ' 15 | Tricresyl Phosphate Triphenyl Phosphate * 54 40 3000 2500 20 j 10 | Dioctyf Adipate \ , 28 2100 ' 12 Santicizer 1-H : 46 3900 46 Santicizer 3 i 34 ' 1800 27 0476104 TOWOLDMON0033072 WATER PCB-00017541 ' *~ 'iO/tit Conti o! Oibo*-/S phthalate Di-2-f*thyl hexyl phthalate Direo isey! phthalate DiisodecyS adipate Santcizer E-15 Santbizer M-17 Safitb:tr 846 Tricresyi phosphate Santio-aer 140 * SantbiZer 141 HB-40 Arocbr 1248 Arocfsr 1221 Mod-rpox _ Room !00 t Temperature for 1 ' Uspd Core Hew Cure cc c cc c CI/P.S. c CUPS. c Cl cc cc cc cc c c* cc c' SICI c .c cc cc c SICI SICI w c c c c c c SICI c c c c = Compatible u = Cloudy O/P s. = Cloudy, Pdas# Separation SiO = Slightly Cloudy V.' = White VISCOSITY 8?e^- >A IVf i?4wr,;U cnip-tyitsssoltr wise opened) Q a Before Adding After Curing Ag->it Curing Ajjeftt a 12,800 (30 rpm) 1,550 2,650 3,250 1,200 3,050 3,150 2,300 3,750 2,850 1,500 3,900 7,700 1,650 1,650 7,900 a 1,300 2,700 | 2,450 1,100 2,100 2,450 d i i 2,000 3,000 W , 2,200 ......... M 1,400 2,300 d 4,300 ...... ....-.*m. Wjjjyf 1,200 1,250 g&t 9 04761,03 TOWOLDMON0033073 WATER PCB-00017542 IN EPOXY RESINS 0 V/,= 200)...................... 0 0 0 O 0 a_ # w 0L . #: fir # 0 JL fwacsi Samples ear'd SO a-"! <r> 513' C Kiftlp'irtrfri..'1'.'-'!* tetatnire ited tep-c: teseiiaate 0,2 CW* % Itffc: Mlm&d . 3.0 ' State 0 Hardness <10 Set) 78 ------0.54.9 05*0.8 05-0.8 ---- 0.5-0.6 --0.6 O.S-OJ , 3.5 8.0 7,0 94,0 2.5 3.0 4.5 3.5 ' 3,5 4.0 4.0 3.0 3.0 4.0 , ' 10 31 48 56 10 6 7 15 22 5 27 40 8 84 nwsi mm:"', m a&freted z&tbm Stare B Hardees (10 Set.) - 86 % Weight .. Change -0.012 78 . 82 83 ' 82 80 85 85 86 79 82 84 88 81 88 -0.734 -0.368 -0.168 -0.181 +0.119 -0.131 -0.013 -0.222 -0.284 -0.425 -0.648 -0.682 -2.118 . +0.134 j j i I 1 { \ i. : i O^tbtQ4* TOWOLDMON0033074 WATER_PCB-00017543 in Other Kmim (susies*# | PLASTICIZER PERFORMANCE IN POLYVINYL ACETATE-EMULSION ADHESIVES 11 parts plastielasr in 100 parts Selva S-88 (polyvinyl acetate) emulsion. Film thickness 0.040 inch VWatititv 24 ars jt 8?5 C. Ifeliwted Carftonl (Iter cast) U-Tep. Flfilblify {Sodding Ciosli & Berg rest) {'' C.) Oil LYfractlon--WsigM Loss Affsr 24 Hyrs at Rscm Tefnpsrstiire (per cent) hnv lor 1221 Ar<xJar 1232 Ar<.dor 1242 1 riphenyl Phosphate Tngresyl Phosphate Direethyl Phthalate OHhyl Phthalate Dihulyl Phthalate Diphenyl Phthalate Satficizer B16 Sa iticizer M-17 Sanitizer 1-H Sanitizer 8 Saitkizer 9 Sanitizer 140 Sa tiiUzer 141 Sanitizer 160 5,2 " 4.8 L 4.4 2.0 0.75 % Ii 5.6 4.8 1 i 4.4 5.9 2.2 i 3.6 l.S 3.6 3.1 1 1.2 1.8 2.1 -5.0 4,0 5.3 5.7 3.6 ---1.6 --5.0 --6.1 -- - --3.9* 1.5 -- 6.4 -- 5.0 --3.3 1.9 0.63 0.54 0.57 0.02 0.16 0.92 0.85 0.59 1.31 0.08 0.19 0.96 0.43 1.13 0.15 0.17 ' 0.20 -- -- -- - ------- 0.37 0.38 0.38 0.75 . 0.63 0.51 0.90 0.46 0.93 0.82 0.59 0.98 a jmrn Q m 0.46 0.50 0.36 0.36 0.48 0.53 m a 0.60 0.64 0.57 0.34 0.42 0.39 0.63 0.36 ' 0.31 0.34 m o ... AH* m .a o+?6tas 4 TOWOLDMON0033075 WATER PCB-00017544 m m 0 0 0 # m m m m f 0 0 m TECHNICAL LITERATURE ABOUT MONSANTO PLASTICIZERS f i S.^I31 Ttt following technical bulletins and brochures give complete technical informatisn about the properties end applications ot the Monsanto plasticizers that are mantiontd m this catalog. Monsanto technical literature is continuously revised to contain th most recent sad reliable Information possible. Your request for any lit erature will b promptly and cheerfully filled -- without obligation, of course. Title Technical Bulletin No. ,,, , Phthafate Plasticizers Dibutyl Phthafate Otcycfohexyl Phthalate Diethyl Phthafate and Dimethyl Phthafate Dfisodecyl Phthafate DM2 ethylhexyO Phthalate (OOP) Diphenyl Phthalate Ditrfdecyi Phthafate Di{rvoctyl(n*decyi5 Phthalate SafiiSe&ef 160 (butyl benzyl) Phthafate Ssnticizer 165 Santicizer 213 and Santicizer 214 Santidzer 215 Santicizer 218 Santicizer 262 Santicizer 6C and Santicizer $36 Santicizer 603 Sanbcfzer 630 and Sentlclzer 631 Santicizer 632 and Santicizer 683 Santicizer 611 Adipate Plasticizers Diisodecyf Adipate B!in-tyi,fKleeytS Adipate Oloctyl Adipate PL-362 PL-312 Pt-383 PL-300 PL-31.8 . PL-319 PL-329 PL-330 PL-160 PL-165 0/PL-213 PL-215 PL-218 PL-262 PL-602 PL-603 PL-630 PL-632 PL-681 . ' PL-3G8 PL-316 PL-304 Phosphate Plasticizers Trientsy? Phosphate PL-305 Thphehyi Phosphate Santicizer 140 . PL-301 n.~m # Santicizer 141. O/PL-141 0%ffeJ.Ob (eentimted) TOWOLDMON0033076 WATER_PCB-00017545 TECHNICAL LITERATURE (eairthnwi) Title Technical Bulletin No. Phthatyt Glyceliate Plasticizers ' Santicizer 45 (Cthyi phtbalate ethyl glycolfate} Sarttidzer 84M8utyl Pfcthalyl fcutyl g!ycoiiat?} Sa'itivier M47 !Melhyl phthaiate ethyl glycoiiatej ' Pi-15 PL-16 . PL-17 Sulfonamide Plasticizers Santicizer I'M Santicizer 3 Santicizer 8 Santicizer 9 Santo!ite MNP and Santollt# MS-S0% PL*20/PL-l-H H.4O/Pl-33 0/ 0/PL-320 . '` Permanent Plasticizers Santicizer 405 Santicizer 406 Santicizer 400 Snt)dzr 411 Santicizer 462 Permanent Plasticizer Selector pl-m FirmPL-406 Pt-411 PL-4620 0/PL-344 ' Other Plasticizers Arocior Plasticizers H8-40 {partially hydrogenated terphenyi* Modafiow Mod-Epox (epoxy-resin modifier) Montar Compounds Phoigstrd C-22-R Triphenyl Phosphite 0/PL-386 Pt-48 0/PL-330 PL-313 PL-328 0/PL-22 PL-317 , Genera! Monsanto Solid Plasticisers \ Monsanto Plasticizers in Synthetic-Resin Adhesives '"- Monsanto Plasticizers in Protective Coatings Sulk Receiving of Plasticizers Monsanto Modifiers for Thiokel* Polysulfide Liquid Polymers Monsanto Plasticizers for Food Packaging Applications Monsanto Plasticizers for Hard-to-Piastieize Resins Chemical Resistance of Plasticizers in Piastisols 0/PL-345 n.-m PL-327 PL-314 PL-331 PL-500 PL-332 PL-333 0%Tfciai' "] Of 4 d d d q d d TOWOLDMON0033077 WATER_PCB-00017546