Document rBwp9owjkQERwGNQ6xjpRJR90
SECTION V - HEALTH HAZARD DATA
EFFECTS OF OVEREXPOSURE: ACUTE (Short Term): SKIN: Irritant.
CHRONIC (Long Tem): Hay cause skin sensitization.
MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: Chronic diseases of the skin.
PRIMARY ROUTES OF ENTRY:
x Oermal
x Inhalation
Ingestion
EMERGENCY AND FIRST AID PROCEDURES: SPLASH (EYES): Flush eyes (Mediately with large amounts of water for at least 15 minutes. Take to a physician for medical treatment. SPLASH (SKIN): Wash affected skin areas with soap and water. Remove contaminated clothing. Consult a physician If Irritation persists. INGESTION: Drink one or two glasses of water to dilute. Do not Induce vomiting. Consult physician or poison control center limedlately. Treat symptomatically. INHALATION: Remove person to fresh air.
SECTION VI . REACTIVITY DATA STABILITY: ____ Unstable _x_ Stable HAZARDOUS POLYMERIZATION: CONDITIONS TO AVOID: High temperatures, sparks, and open flame. INCOMPATIBILITY (Materials to Avoid): Strong oxidizing agents.
____ May Occur _x_ Will Not Occur --
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of Ignition (flame, hot surfaces, and electrical, static or frictional sparks). Use self-contained breathing equipment. Ventilate area. Contain and remove with Inert absorbent material and non-sparking tools. Avoid contact.
WASTE DISPOSAL WTHOD: Disposal should be done In accordance with Federal (40CFR Part 261), State and Local regulations. Before attempting clean-up, refer to hazard caution Information In other sections of the MSDS form. Use licensed hazardous waste disposal concern.
SECTION VIII - SAFE HANDLING AMD USE PROCEDURES
RESPIRATORY PROTECTION: Use approved chemical/mechanical filters designed to remove a combination of particulates and organic vapor In open and restricted ventilation areas.
VENTILATION: All application areas should be ventilated In accordance with OSHA regulation 29CFR Part 1910.94, Sufficient ventilation. In pattern and volisae, should be provided to Keep the air contaminant concentration below applicable exposure limits.
PROTECTIVE GLOVES: Use neoprene or rubber gloves to prevent skin contact.
EYE PROTECTION: Use safety glasses with side shields as mlnlmim protection.
OTHER PROTECTIVE EQUIPMENT: Use protective cream If skin contact Is likely. Use disposable or Impervious clothing If work clothing contamination Is likely.
HYGIENIC PRACTICES: Wash hands before eating, smoking or using the wash room. Do not smoke In any chemical handling or storage area. Food or beverages should not be consumed anywhere this product Is handled or stored.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Do not store or use near heat or open flame. Refer to OSHA 79CFR Part 1910.106 for specific storage requirements.
OTHER PRECAUTIONS: Ewpty drums should not be reused. Do not get In eyes. Avoid skin contact. Do not handle until the manufacturer's safety precautions have been read and understood.
PA/0872m/ac/2
DO 086420 CONFTDFNTTAt
MATERIAL SAFETY DATA SHEET
PH:_. 7/2/87
MANUFACTURER'S NAME.
BURTON RUBBER PROCESSING. INC.
ADDRESS (NumMr, Street, City, State and zip Coda)
14330 Kinsman Road. Burton. Ohio 44021
CHEMICAL NAME AND SYNONYMS
CPE Compound
CHEMICAL FAMILY
Polymeric
SECTION 1
EMERGENCY TELEPHONE NUMBER
216-834-4644
TRADE NAME AND SYNONYMS
87016-7B
FORMULA
Proprietary - generated by Cow Chemical
SECTION II - HAZARDOUS INGREDIENTS Materials listed in this section are in concentrations of 0.1% or more if carcinogenic and 1% or more if toxic. irritant, etc. per 29CFR 1910.1200.
W-Butyl-4,lt'-bis-(t-butylperoxy)valerate, irritant, CAS 995~33"5
(Jmti) NE
BOILING POINT [F.) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER APPEARANCE AND ODOR
SECTION III - PHYSICAL DATA
NA
SPECIFIC GRAVITY (H20=*1)
NA
PERCENT, VOLATILE BY VOLUME {%)
NA E(-V--A-P--O--R--A-T--IO--N---R--A-T--E-- *1)
NU Black,
Rubbery solid; characteristic odor
1.37 NA NA
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method Uted)
NA
FLAMMABLE LIMITS
NA
1
|
Lei
EXTINGUISHING MEDIA
Water spray, protein type air foam, ABC dry chemical
SPECIAL FIRE FIGHTING PROCEDURES
Wear self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Combustion releases HC1 fumes (TLV - oppm).
ul
OO p. M/..
stability
UNSTABLE
SECTIO N V - REACTIVITY DATA
CONDITIONS TO AVOID
STABLE
INCOMPATABILITY {Materials to avoid)
Strong oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS
C0,C02,HC1
X
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
None
CONDITIONS TO AVOID
X None
SECTION VI - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
NA ENTRY ROUTE: Inhale Y_ Incest .. Skin Y Eve
EFFECTS OF OVEREXPOSURE
Containment in a rubber binder greatly reduces risk of contact with hazardous materials. May liberate irritant vapors at processing temperatures; avoid vapor, and skin contact.________________________________________
eye.
EMERGENCY AND FIRST AID PROCEDURES
Flush eyes/skin with plenty of water - consult physician if irritation persists.
If inhaled, remove to fresh air.
If ingested, consult physician.
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Collect: Return to container.
WASTE DISPOSAL METHOD
Dispose of in accordance with local, state and federal regulations._____________ ________
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)
Organic vapor respirator recommended if ventilation is inadequate.
VENTILATION
LOCAL EXHAUST
Yes
SPECIAL
MECHANICAL (General)
OTHER
PROTECTIVE GLOVES
Recommended
(,
(Cloth)
OTHER PROTECTIVE EQUIPMENT
EYE PROTECTION
Recommended
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store below ISO F away from direct sources of heat and sunlight.
DO 08642?
other precautions
CONFIDFNTTAL
Wash thorouglily after handling._________________________________________ ________________________________________
As the conditions or methods of use ere beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with applicable federal, state and local laws and regulations remains the responsibility of the user.
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Tin c
Chemist
MATERIAL SAFETY DATA SHEET
-------------------------------------------------------------------------------------------------------- s&___7/g/ftl
__________________________________________ SECTION 1__________ ___________________
MANUFACTURER'S NAME.
BURTON RUBBER PROCESSING. INC.
EMERGENCY TELEPHONE NUMBER
216-8344644
____
ADDRESS (Number, Street, City, Stete and Zip Code)
14330 Kinsman Road. Burton. Ohio 44021
CHEMICAL NAME AND SYNONYMS
CPE Compound
TRADE NAME AND SYNONYMS
86017-35G
CHEMICAL FAMILY
Polymeric
FORMULA
Proprietary - ecnerated bv nTM
SECTION II - HAZARDOUS INGREDIENTS Materials listed in this section are in concentrations of 0.1% or more if carcinogenic and 1% or more if toxic. irritant, etc. per 29CFR 1910.1200. Triallyl Trimellitate, toxic, CAS 269b~5k-b Antimony Oxide, cancer suspect, CAS 1309-6lt-^ (NTF) Liquid Chlorinated Paraffin, hepatoxin, CAS 6l788-76-9
Dicumyl Peroxide, irritant, CAS 80-h3-3
TLV (L nits)
50ppm ,50mg NE lOmg/i i
BOILING POINT (F.) VAPOR PRESSURE (mm H9.) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER APPEARANCE AND ODOR
SECTION III - PHYSICAL DATA
NA NA NA
SPECIFIC GRAVITY (H20=1)
PERCENT, VOLATILE BY VOLUME (%)
EVAPORATION RATE (---------------------------------------*1)
Nil
Black,
Rubbery solid; characteristic odor
l.kk
NA NA
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method Used)
NA____________________
FLAMMABLE LIMITS
NA
I
Lei
EXTINGUISHING MEDIA
Water spray, protein type air foam, ABC dry chemical
SPECIAL FIRE FIGHTING PROCEDURES
Wear self-contained breathing apparatus.____________
ul
UNUSUAL FIRE AND EXPLOSION HAZARDS
Combustion releases HC1 fumes (TLV -- 5ppm).
00 086423 CONFIDENTIAL
stability
UNSTABLE
SECTIO N V - REACTIVITY DATA
CONDITIONS TO AVOID
STABLE
INCOMPATABILITY (Materials to avoid) Strong oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS
C0,C02,HC1
X
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
None
CONDITIONS TO AVOID
X None
SECTION VI - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
NA ENTRY ROUTE: Inhale_Y._. Ineest
Skin Y
Fv*
EFFECTS OF OVEREXPOSURE
Containment in a rubber binder greatly reduces risk of contact with hazardous materials.
Contains cancer suspect/liberates irritant vapors; refer to Sect. VIII. ..... Prolonged exposure to Antimony Oxide dust can-result in liver tumors.
Contains a toxic material: Prolonged exposure to liquid chlorinated paraffins may result in liver disorders.
Prolonged exposure to Triallvl Trimellitate may be fatal if inhaled, ingested.
or absorbed through tne skin.
---------------------------------------
EMERGENCY AND FIRST AID PROCEDURES
Flush eyes/skin with plenty of water - consult physician if irritation persists.
If inhaled, remove to fresh air.
If ingested, consult physician.
______ __________________SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Collect: Return to container.
WASTE DISPOSAL METHOD
Dispose of in accordance with local, state and federal regulations.______________________
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)
Organic vapor respirator recommended if ventilation is inadequate.
(NIOSH)
VENTILATION
LOCAL EXHAUST
Yes
SPECIAL
MECHANICAL (Gentral)
OTHER
PROTECTIVE GLOVES
Recommended
(impervious)
OTHER PROTECTIVE EQUIPMENT
EYE PROTECTION
Recommended
__ SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store below 70 F away from direct sources of heat and sunlight._____________
OTHER PRECAUTIONS
Wash thoroughly after handling.______________________________________________________________
[DO 086424 CONFIDENTIAL
As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for
any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without
warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be
obtained from the use thereof. Compliance with applicable federal, state and local laws and regulations r -mains the responsibility of the user.
n.CICMATI IOC V
-y /->' /0 r:
A
titi e
Chemist
MATERIAL SAFETY DATA SHEET DATE: 12-19-8?
MANUFACTURER'S NAME
SECTION 1
EMERGENCY TELEPHONE no.
MACH_-^COMPOUNDING Division of Burton Rubber
216-467-8108
ADORESS (Ntjmoer, Street, City* Stats ana ZtP Coast
775_E. _Highiand. Roadx_Macedonjaj_Ohio 44056
CHEvirCAll NAME ANO SYNONYMS
Polyethylene__________________ ________
TRAOE NAME AND SYNONYMS
_____ CPE.24-?__________
chemical family
Polymeric________________________
formula
Proprietary
SECTION II - HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES & SOLVENTS
% TLV (Units)
ALLOYS ANO METALLIC COATINGS
pigments
None
base metal
None
catalyst vehicle
SOL'/eNTS
None
None None
"LL0VS
metallic coatings
F'LLE* METAL PLUS COATING OR CORE FLUX
None None
None
additives
None
others
% TLV ft imtrt ------- -
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES
Dibasic lead phthalate - Toxic
% TLV , IUnit5|,,
< 4.0
Antimony Trioxide - Cancer suspect
6.0
--1 |
1I
BCIL'NG "DINT (F ) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR-1) SOLUBILITY in water flPOCJRANC: AND ODOR
SECTION
III PHYSICAL DATA
|1Nri SPECIFIC GRAVITY (H,0*1)
NA
PERCENT. VOLATILE 9v VOLUME (%)
E/APORATION RATE
NA (
=D
Nil !
Black pellet
1.28 '
NA
NA
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH point iMeihoa U$ea)
NA
flammable limits NA
EXTINGUISHING MEDIA
Water spray, protein-type air foam, ABC dry chemical.
SPECIAL FIRE FIGHTING procedures Wear self-contained breathina aDD aratus,
Let
uei
UNUSUAL FIRE AND EXPLOSION HA7ARQS
Combustion releases acl tumes (TLV-5ppm).
O86425 conftdfntiai
r^-^ruYbLA'd Ps/f
SIGNATURE
Lonnie S. Porter
TITLE.
(CONTINUED ON REVERSE SIDE:
Technical Manager
________________ ________ SECTION V HEALTH HAZARD DATA___________
threNsAh-o--l--d----l-i-m---it----v--a--l--u--e-----E--N---T-R---Y----R--O---U--T--E--:------I-n--h--ale-------- inz5est ------- Skin--------*Ey-e EFFECTS OF E RE. \P'JSU HE
EMERGENCY AND ^1^57 AiO ^^UCtDURES
Flush eves/skin with plenty of watar-consult physician if irritation persists. If innaled-cemove to fresh air__________________________________________________________
If ingested consult physician.
STABILITY
SECTION VI REACTIVITY DATA
UNSTABLE
CONDITIONS TO AVOID
stable
X
,inc^^a -a*?! li rw
mrt .t.-kt*
Strons oxidizine asents
hazardous decomposition products
CO, C0-, HC1
HAZARDOUS POLYMERIZATION
MAY OCCUR will not OCCJR
None. X
CONDITIONS TO AVOID
None.
573S TO
SECTION VII - SPILL OR LEAK PROCEDURES
TAKEN iTI CASE \1ATERIRL IS RE--EASED OF 5P1 I__0
Collect: return to container
WASTE OI5POSf-<- ME-HOC Dispose of in accordance with local, state and federal regulations.
SECTION VIII - SPECIAL PROTECTION INFORMATION
respiratory protection iSoecny :yoci
Organic vsnor resoirator recommended if ventilation is inadecuate.
VENTILATION
LOCAL exhaust
LPLLI/I.
MECHANICAL
3t)
or,,*-
PROTECTIVE GLOVES Recommended
OTnfep PROTElr V L fjUl PMtN
V E O P lj " l I f)M
,, Recommended
|
1 B 3
8 1 1
SECTION IX SPECIAL PRECAUTIONS
precautions to se take;* in hancl no and storing
CPE 24-2 will emit vapors during processing with other materials.
Exposure
may produce acute health effects in_.some sensitive individuals. Good ventilatior
is needed to avoid breathing vapors.
As the conditions or methods of use are bevond our control, we do not assume anv responsibility and expressly disclaim any liaoility for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarcmg accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with applicable federal, state and local laws and regulations remains the responsibility of the user.
DO 086426 CONFIDENTIAL
MATERIAL SAFETY DATA SHEET DATE: 08-12-86
MANUFACTURER'S NAME
SECTION 1
EMERGENCY telephone no.
MACH-1 COMPOUNDING Division of Burton Rubber
216-467-8108
ADDRESS (Numoer, Street, City. State ana ZIP Coeei
775 E. Highland Road, Macedonia, Ohio
44056
CHEMICAL. NAME AND SYNONYMS
Polvethvlene.
._
.......
TRADE NAME AND SVNONVMS
546-85028-20-1
CHEMICAL "FAMILY
Polymeric
FORMULA
Proprietary
SECTION 11 - HAZAFIDOUS INGREDIENTS
PAINTS. PRESERVATIVES & SOLVENTS
TLV % (Unit,)
ALLOYS AND METALLIC COATINGS
pigments
None
base metal
None
catalyst
VEHICLE SOLVENTS
None None
None
AL-0VS
metallic coatings filler metal
plus coating OR Core flux
None None
None
additives
None
others
OTHERS
%
TLV fUniMI
--
Materials listed in this section are in concentrations of 0.1% or more
TLV ., iy ni*i_
if carcinogenic and 1% or more if toxic, irritant, etc. per 29CFR 1910.12 00
Dibasic Lead Phthalate - Toxic Antimony Oxide - Cancer Suspect
1.0 > oJl
I
1.
BOLING POINT (F.) VAPOR PRESSURE (mm Ho.) VAPOR DENSITY (AlR*l) SOLUBILITY IN WATER
appearance and odor
SECTION III - PHYSICAL DATA
_ ' NA SPECIFIC GRAVITY
NA
PERCENT, VOLATILE BY VOLUME (%)
EVAPORATION RATE
NA i
*1)
Nil I
Black Pelhet
1.33
NA
NA
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Metnoc US*d)
NA
Extinguishing media
Water spray, protein-type
air
FLAMMABLE LIMITS
NA foam, ABC dry chemical.
L*i
____
t Uti
1
1 _________ i
special fire fighting procedures
Wear self-contained breathing atDarat-js.
UNUSUAL fire and explosion hazards
,
,
Compustion releases HCl lumes (a-LV-oppm).
D0 086477 OONF TOENT JA(
1
-/
SIGNATURE.
VU/ -
Lonn ie S. Porter
TITLE.
(CONTINUED ON REVERSE SIDE)
Technical Manager
"
threshold limit
SECTION V HEALTH hAZAHU DA l A
ENTRY ROUTE: Inhale
Ingest
Skin
Eye
"eF^Tcrs-op overexposure
~
Contaminant in the polvmer matric greatly reduces risk of contact with
hazardous materials.
`viE^(jNCV AMO pJrtST aiC Flush eves/skin with oler-tv of us:;:-consult physician if irritation persists.
If inhaled-remove Co fresh air
15 invested consult physician.
5TABILJTV
SECTION VI - REACTIVITY DATA
UNSTABLE
CONQlTtONS TO AVOID
STASlE
X None.
Scrons oKidizins asents
HAZARDOUS DECOMPOSITION PBOOUCTS
CO, CO, HC1
HAZARDOUS POLYWER12 AT ION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOlO
X None.
SECTION VII * SPILL OR LEAK PROCEDURES
S7ESE TO 3E TAKEN IN CASE MATtSlAL IS RELEASED OK SPH__ SO
Collect: return to container
WASTE 01 SPOSAL MS'hOD
Dispose of in accordance with local, state and federal regulations.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPI ra 7 or y PROTECTION iSoecnv IVBCI
Organic vapor respirator recommended if ventilation is inadequate.
VENTILATION
LOCAL EXHAUST
special
MECHANICAL (UC'Mfrjl)
OTnEfi
PROTECTIVE GLOVE;
Recommenaec
PROTECTIVE tUUlPWLNi
EYE oPuTECTtON
_Recommena, ed,
SECTION IX --SPECIAL PRECAUTIONS
g^Tdg-2?-f^i11^em?tHvaport during0 processing. Exposure may produce acute health effects in some sensitive individuals. Good ventilation is needed to avoid breathing vapors. Wash thoroughly after handling.
As the conditions or methods of use are bevond our control, we do not assume any responsibility and exoressly disclaim any liaotiity for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are maoe without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with applicable federal, state and local laws and regulations remains the responsibility of the user.
0864h>8 confidential
...^icrilAL SAFETY DATA SHcEi
DATE: 08-12-86
MANUFACTURER'S namc
SECTION 1
EMERGENCY TELEPHONE NO.
. MACHr1_C0MP0JNDING Division of Burton Rubber
216-467-8108________
"aOORESS (Numor. Slrect. City. Sl ina ZIP Coa.i
"
775 E. Highland Road, Macedonia. Ohio
CHEMICAL NAME AND SVNONVMS
TRADE NAME AND SVNQNVMS
Polyethylene. .
CHEMICAL FAMILY
.
. 546-85028-20-1
FORMULA
Polymeric
Proprietary
SECTION II - HAZARDOUS INGREDIENTS
PAINTS. PRESERVATIVES & SOLVENTS
TLV
% lUnuil
`ALLOYS ANO METALLIC COATINGS
- pigments
None
base metal
None
catalyst
None
AU-ovs
None
vehicle
None
tveNT*............................ None...........
metallic, coatings
FILLER METAU
coEonplus coating
flux
None
Mone
additives
None
OTHERS
others
% TLV
--
Materials listed in this section are in concentrations of 0.1% or more
TLV
,iynits)_
if carcinogenic and 1% or more if toxic, irritant, etc. per 29CFR 1910.11 00
O1
r i!__
Dibasic Lead Phthalate - Toxic....................................... ......... ' Antimony Oxide - Cancer Suspect
S > OJL
.
BOILING POINT (F.| VAPOR PRESSURE (mm Ho.) /APOR OENSITV (AIR1)
0LU8KJTY IN WATER SBSSRANCS ANO OOOR
SECTION III - PHYSICAL DATA
NA. NA
NA Nil
SPECIFIC GRAVITY <H,D1) PERCENT, VOLATILE BV VOLUME EVAPORATION RATE
( *1)
!
Black PelHet
1.33
NA
NA
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
ash point (Mtnoa ustai
NA
FLAMMABLE LIMITS
NA
ANGUISHING MElblA
r,,,,rr,rr
rrr,...
Water spray, protein-type air foam, ABC dry chemical.
UAL FIRE FIGHTING PROCEDURES
Wear self-contained breathing apparatus.
Lei
Dei
ual'(=V4e ano explosion HAZ,4'RdS
____ ' .
*
Comoustion releases Hcl ruroes (TLV-oppm).
T^-iA/YI a/ J. $
RE,
Lonnie S. Porter
g
I
Techni ea(CTOMNTaINnUaEgDerON REVERSE SIOE)
Tt-neSH.ci.3 limit value EliTRY ROUTE: Ir.naie na. ________________________________ -
Ingest
S ri in
ive
6ff*T^7SOFOV5i<*'OiuM6
Contaminant in the polymer matric greatly reduces risk of contact with
hazardous materials.
MCaOt'MC'' ANQ PiRST AiC PROCSDUREi
Flush eves/skin wtch olar-tv of wata r-consult physician If irritation persists.
Ir inhaled-rentove co fresh air
15 invested consult Dhvsician.
stability
SECTION VI REACTIVITY DATA
unstable
CONDITIONS TO AVOIO
stable
X None.
Serous oaiiaiains asents
HAZARDOUS DECOMPOSITION PRQOUCTS
CO, CO, HC1
MAZAAOOUS POLVM6SI2AT10N
MAY OCCUR Will NOT OCCUR
CONDITIONS TO AVQiO
X Norte.
)
SECTION VII! - SPECIAL PROTECTION INFORMATION
RtiPiRAroRv PROTECTION tSoecnv -.voci
Organic van or respirator recoaaer.ded if ventilation is inadeouate.
VENTILATION
LOCAL E<HAL*ST
SPELiAl
MECHANICAL lUc'ivrJl}
DT rtE A
PROTECTIVE GLOVE;
Rec3T-T.er.aea
UTinqA JROTf-TlVt
EYE oRUTECTiON
,,
Recommenoed
SECTION IX *-SPECIAL PRECAUTIONS
i-^^-2^fEwi11eemitHvapors during0 processing. Exposure may produce acute
health effects in some sensitive individuals. Good ventilation is needed to
avoid breathing vapors.
Wash thoroughly after handling.
As the conditions or methods of use ere bevond our control, we do not assume any resoonsibiiity and exoressly disclaim any liaoiiity for any use of this material. Information contained herein is believed to be true ana accurate but all statements or suggestions are made without warranry. exoressed or implied, regaraing accuracy of the information, the hazards connected with the use of the material or the -nsults to be obtained from the use thereof. Compliance with applicable federal, state and local laws and regulations remains die
-nsibility of the user.
DO 086430 CONFIDENTIAL
UNIROYAL Material Safety Data Sheet
CHEMICAL
Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723-3670
World Headquarters
CHEMTREC Transportation Emergency Phone: 1-800-424-9300
J
Middlebury, CT 06749
SAFETY DATA Information (203) 573-3303
MSDS Nn C212005--
Date Issued:
8/28/86_
IDENTIFICATION ----------------------------------
Trade Name: NAUGARD SUPER Q
CAS Number: 26780-96-1
Chemical Name: Polymerized 1,2-dihydro-2,2,4tri-methylquinoline
Chemical Family: Quinoline
SPECIAL REGULATORY HAZARDS
Ingredient
CAS No.
Exposure Limit
Product
26780-96-1
ND
OSHA (1910.1200) Not hazardous
EEC* Not hazardous
Hazard assessment based on available data. Transportation: NA
PHYSICAL DATA
Appearance and Odor: Brown powder or flakes; characteristic odor
Solubility: Insoluble in water. Soluble in acetone
benzene, ethanol & chloroform Melting Point: NA; Softening Pt. 115-130"C
Specific Gravity (H2O = 1): 1.03 -1.09
Vapor Pressure @ 20C. NA Vapor Densjty (A|r = 1); NA
Boiling Point: NA Other Data: NA
Volatility @ 70F: Low
FIRE AND EXPLOSION HAZARD DATA ---------
Flashpoint: 429F (2210C) COC
Autoignition Temp; ND
Extinguishing Media: Water spray, dry chemical
Flammable Limits: ND
Special Fire Fighting Procedures: Protect against inhalation of combustion products.
Unusual Hazards: May form explosive dust-air mixtures.
REACTIVITY DATA ------------------------------------
Stability: Stable at ambient temperatures and pressures.
Incompatibility: Strong oxidizing agents.
CO O86431 confidential
Decomposition Products: Oxides of carbon and nitrogen under burning conditions.
NA = Not Applicable
ND = Not Determined
'European Economic Community
Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet. The information is however, as of this date provided, true and accurate to the best of Uniroyal's knowledge. This list of information is not intended to be all inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein.___________ ___________________
SPECIAL PROTECTION INFORMATION ------------------------
Engineering Controls: Sufficient ventilation to minimize dust exposure. Protect closed handling systems against possible dust explosions. Avoid dust accumulation on building or equipment surfaces.
Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHcertified dust cartridge respirator.
STORAGE, SPILLS AND DISPOSAL INFORMATION --
Storage: Store away from sources of direct heat in a dry area. Keep containers closed when not in use.
Spills: Sweep or vacuum up. Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined above.
Disposal: In accordance with any applicable local, state, or federal regulation regarding organic waste.
Environmental Information: Environmental effects have not been determined.
HEALTH RELATED DATA -------
Specific Hazard(s): Contact with eyes may cause irritation.
primary Route(s) of Entry: Powder, inhalation or skin absorption. First Aid Procedures: Eye contact: Flush with water for 15 minutes. Get medical attention.
Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air.
Toxicology Information:
Oral toxicity: LD50 (rats) - 4.6 g/kg Dermal toxicity: LD50 (rabbits) - 20 g/kg
Irritation: eye (rabbits) - slight skin (rabbits) - negative
Chronic: The administration of polymerized 1,2-dihydro-2,2,4-trimethylquinoline by three routes, 0.5% in the diet of rats, skin painting in mice and intratracheal injection in hampsters, did not produce an increased tumor incidence.
Do 086432 coimp ro^TXAt
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U. S. DEPARTMENT OF LABOR
Occupational Safety & Health Administration MATERIAL SAFETY DATA SHEET
SECTION I
MANUFACTURER'S NAME
E.I. du Pont de Nemours & Co., Inc.
EMERGENCY TELEPHONE NO.
302-774-2421
ADDRESS (Xumbtr, Street, City, State, and 7.1P Codr)
Polymer Products Dept., Elastomers Division, Wilmington, DE 19898
ChemiCal name and synonyms
trade name and synonyms
Nickel dibutyldithiocarbamate_________________
NBC
chemical family
FORMULA
Rubber accelerator
SECTION II PHYSICAL DATA
BOILING POINT ("F.) VAPOR PRESSURE (mm Hfl.) VAPOR DENSITY (AIR * 1) SOLUBILITY IN WATER
not applicable not applicable not applicable
insoluble
SPECIFIC GRAVITY (HjO - 1)
PERCENT VOLATILE BY VOLUME (%)
EVAPORATION RATE
( - 1)
Melting Point
APPEARANCE AND ODOR
Dark green flakes. Mild odor.
1.26 not applicable not applicable 86C (187F)
SECTION III FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method u*ed)
Above 263C (505F)--open cup method
EXTINGUISHING MEDIA
Use standard fire extinguishers
FLAMMABLE LIMITS
-------- ci-------- -------- era--:
SPECIAL FIRE FIGHTING PROCEDURES
None
UNUSUAL FIRE AND EXPLOSION HAZARDS
None
THRESHOLD LIMIT VALUE
None established.
EFFECTS OF OVEREXPOSURE
SECTION IV HEALTH HAZARD DATA
Approx, lethal dose (ALD) is greater than 17,000 mg/kg body weight for male rat. May cause skin irritation although not considered a skin sensitizer.
EMERGENCY AND FIRST AID PROCEDURES
Wash skin immediately. Flush eyes in running stream of water. Call a physician.
DO 086433 CONFIDENTIAL
NOTICE FROM DU PONT
The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process.
UNSTABLE
STABILITY
TTaHT
TRtOMPAtABILITY (Material! to avoid)
X
SECTION V REACTIVITY DATA
CONDITIONS TO AVOID
HAZARDOUS DECOMPOSITION PRODUCTS
MAY OCCUR
CONDITIONS TO AVOID
HAZARDOUS POLYMERIZATION
WILL NOT OCCUR
X
SECTION VI SPILL OR LEAK PROCEDURES
steps 16 BE tAKW IN Case material IS fttLEA4ED6R Spilled-------------------------------------------------Clean up. Avoid contact with skin.
WASTE DISPOSAL METHOD
Dispose in a secure landfill, according to federal, state and local regulations.
SECTION VII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Sptcfy type)
~~
LOCAL EXHAUST
Yes
MECHANICAL (General)
SPECIAL
Use with adequate ventilation.
other
i
Yes
PROTECTIVE GLOVE
Recomme nded
OTHER PROTECTIVE EQUIPMENT
EYE PROTECTION
Safety glasses recommended.
Non-porous or heavy work clothing to protect from skin exposure.
SECTION VIII
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
SPECIAL PRECAUTIONS
Store in cool, dry place for best storage conditions. Avoid skin contact.
OTHER PRECAUTIONS
Before using, read the bulletin "Toxicity Information Related to Handling and Processing HYPALON" HP-110.1.
December, 1981
DO 086434 CONFTDFNTTAl