Document rBprV4rvbL69wV62Yxkq61rJ0

CHEMICALS RECEIVED ,ja:i 12 1990 --t pmimmi nvironmenta) Attain INTEROFFICE / LAKE CHARLES TO FROM Distribution S. L. White^i/u^ DATE SUBJECT January 9, 1990 OHC/VCM/Dioxin Attached is the Lake Charles information regarding the OHC/VCM/Dioxin R. J. Samelson requested in his memo dated January 4, 1990. bb Attachments Distribution G. Winter D. Magill R. J. Samelson UcM 0(Q Xfa t9 U4- SL 105543 From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1939 To: Mr. Jim Busnak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01092 Sample location: PPG PPG Sample No. Outfall 201 Collected by: JIM RUSNAK Collection date: 03/07/39 Time: COMP Laboratory submittal date: 03/13/39 Time: 14:00 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/15/89 Time started: 4:00 Date finished: 03/15/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/16/39 Time started: 7:.31 Date finished: Analyst: RLH 03/16/39 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/15/39 Date finished: Time started: 3:03 Analyst: RLH 03/15/39 SL 105544 Mr. Jim Rusnak Page: 2 AAbJolZ March 29, 1989 Parameter: PESTICIDES AND FCBs Method reference: EPA 625 Result: see appended report Date started: 03/14/89 Time started: 4:24 Date finished: 03/14/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, M thod reference: EPA 625 Result: lees than .01 ug/L Date started: 03/15/39 Time started: 1:21 total Date finished: Analyst: RLH 03/15/39 Data for Chlorinated Hydrocarbons Component Name 1,3-Dichlorobensene 1,4-Dichlorobensene 1,2-Dichlorobensene Hexachloroethane 1,2,4-Trichlorobensene Hexachlorobutadiene Hexachlorocyclopentadiene 2-Chloronaphthalene Hexachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride .Tr if luorochlorome thane Chloroethane Methylene Chloride 1, 1-Dichloroethene 1, 1-Dichloroethane .trans-1,2-Dichloroet.hene Chloroform 1.2-Dichloroethane 1,1.1-Trichloroethane Carbon Tetrachloride Concentration Trace . 08 .05 . 27 .21 4.10 Not Det Not Det 3.50 Compo; ri/i , 05 .05 .05 .05 . 05 . 05 . 05 . 05 . 05 Concentration AM Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 240. 30 . Not Det Not Det Compel M9/L 10 10 10 10 10 5 5 5 5 5 5 5 5 SL 105545 * Mr. Jim Rusnak Page: 3 AAomz March 29, 1989 Bata for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane .-trans-l,3-Dichloropropene -Trichloroethene -Dibromochloromethane 1,1,2-Trichloroethane Benzene eis-1,3-DichIoropropene -2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total (continued) Concentration t*$/L Not Bet Not Det. Not Det Trace 6. Not Det Not Det Not Det Trace Trace Not Det Not. Det Not Det Not Det Not Det Component MBL wjL 5 5 5 5 5 5 5 10 5 5 5 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name Phenol bis( 2-Chloroet.hyl) Ether 2-Chlorophenol 1,3-Diehlorobensene 1.4-Dichlorobensene 1,2-Dichlorobenzene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine . Hexachloroethane /Nitrobenzene Isophorone .2-Nitrophenol i2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol . 2-Chloronaphthalene / Concentration f*3/L Not Det 40. Not Det Trace Trace Trace Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Not Det Not Det Compc M3/L 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105546 Mr. Jim Rusnak Page: 4 AAotelX March 29, 1989 Data for Base/Neutral Acid Extractablea (continued) Dimethyl Phthalate Acenaphthalene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chloropheny1-phenylether Fluorene 4,6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromopheny1-phenylether H xachlorobensene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbensylphthalate 3,3'-Dichlorobensidine Benso(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benso(b)fluoranthene Benzot k)fluoranthene Benso(a)pyrene Indeno(1,2,3-c,d)pyrene Dibenso(a,h)anthracene Benso(g,h,i)perylene Benzidine m/l Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 10 10 10 50 50 10 10 10 10 . 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC Concentration AS/l Not Det Not Det Not Det Not Det Not Det Component *3/1 05 . 05 . 05 , 05 . 05 SL 105547 Mr. Jim Fusnak Page: 5 AAO/412* March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone M thoxychlor Endrin Aldehyde continued) Concentration Not. Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det PSjl .1 .1 .1 .1 . 05 .1 .1 .1 . 05 . 05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Semi-Vol sample is 24 hr composite, VOA samples (2 ea) at 6:15, 12:50. 13:30. 1 voa (0:10) sample rec. broken MDL If there are any m.u'._1 mis r-i: -rding this data, please call. SL 105548 From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1989 To: Mr. Jim Rusnak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AAQ1110 Sample location: PPG PPG Sample No. Outfall 201 Collected by: J RUSNAK Collection date: 03/09/89 Time: comp Laboratory submittal date: 03/15/39 Time: 18:30 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/18/89 Time started: 13:38 Date finished: 03/13/89 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/20/39 Time started: 6:23 Date finished: Analyst: RLH 03/20/39 Parameter: Base/Neutral Acid Extractables Method reference; EPA 625 Result: see appended report Date started: 03/18/39 Date finished: Time started: 11:46 Analyst: RLH 03/13/39 SL 105549 Mr. Jim Rusnak Page: 2 AAoHf* March 29, 1989 Parameter: PESTICIDES AND PCBs Method reference: EPA 625 Result: see appended report Date started: 03/17/89 Time started: 9:43 Date finished: 03/17/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference: EPA 625 Result: less than .01 ug/L Date started: 03/20/89 Tim started: 19:37 total Date finished: Analyst: RLH 03/20/39 Data for Chlorinated Hydrocarbons Component Name 1,3-Dichlorobensene vl,4-Dichlorobensene ,1,2-Dichlorobensene Hexachloroethane >1,2,4-Trichloroben2ene Hexachlorobutadiene Hexachlorocyclopentadiene 2-Chloronaphthalene -Hexachlorobensene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane ,Vinyl Chloride Trifluorochloromethane -Chloroethane Methylene Chloride A ,1-Dichloroethene 1,1-Dichloroethane . trans-1,2-Dichloroethene ^'Chloroform 1,2-Dichloroethane 1,1,1-Trichloroet.hane 'Carbon Tetrachloride Concentration *3/1 Not Det Not Det Not Det . 19 Trace 1.70 . 10 Not Det .83 Component.MDL .05 .05 .05 . 05 .05 .05 . 05 . 05 .05 Concentration *3/1 Not. Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 160. Not Det Not Det Not Det Compc *sA 10 10 10 10 10 5 5 5 5 5 5 5 5 SL 105550 Mr. Jim Rusnak Page: 3 AAoH/b March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name `Bromodichlorome thane l-1,2-Dichloropropane :trans-l,3-Dichloropropene ^Trichloroethene .Dibromochloromethane '1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene ,2-Chloroethylvinylether Bromoform ,Tetrachloroethene 1,1.2,2-Tetrachloroethane Toluene Chlorobenzene -Ethylbenzene Xylene, total (continued) / Concentration *j/ 6. Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Compo *3/2. 5 5 5 5 5 5 5 5 10 5 5 5 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name ,Phenol ^bis(2-Chloroethyl) Ether `2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 'bis(2-Chloroisopropyl) Ether 'N-Nitroso-di-n-propylamine Hexachloroethane -Nitrobenzene Isophorone .2-Nitrophenol >2,4-Dimethylphenol bis(2-Chloroethoxy) Methane ,2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorobutadiene - 4-Chloro-3-met.hylphenol Hexachlorocyclopentadiene -2,4,6-Trichlorophenol < 2-Chloronapht-halene ,/ Concentration *9/1 Not Det 47. Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Trace Not Det Not, Det Compc *sJL 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 MDL SL 105551 SL 105552 Mr. Jim Rusnak Page: 4 AAdtUo March 29, 1989 Data for Base/Neutral Acid Extractables (continued) Component Name Concentration Dimethyl Phthalate Acenaphthalene Acenaphthene 2.4-Dinitrophenol 4-Nitrophenol 2.4-Dinitrotoluene 2.6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4.6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenylether >Hexachlorobenzene Pentachlorophenol Ph nanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene -Butylbenzylphthalate ,3,3'-Dichlorobenzidine Benzo(a)anthracene bis : 2-Ethyl:i.-xyi Phtna =.t Chrysene .Di-n-octyl Phthalate Benso(b)fluoranthene Benso(k)fluoranthene Benso(a)pyrene Indenof1,2,3-c,d)pyrene Dibenso(a,h)anthracene Benso(g,h,i)perylene ,Bensidine Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not. ;;t, Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component. f*3/L 10 10 10 50 50 io 10 10 10 10 50 10 10 10 50 10 10 10 10 10 1 `> J 0 m 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC Concentration Not Det Not Det Not Det Not Det Not Det Compon' X3/L . 05 .05 . 05 .05 .05 SL 105553 f Mr. Jim Rusnak Page: 5 AAOH/o March 29, 1989 Data for PESTICIDES AND FCBs Component Name 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Hept-achlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde (continued) Concentration HJ}/L Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Compc .1 .1 .1 .1 , 05 .1 .1 .1 . 05 .05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Extractables is 24hr composite. VOAs (2ea) at 7:55, 12:36, 13:27, 0:20, Reference Lab Report No. R489. If there are any questions regarding this data, please call. SL 105554 *ft From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1989 To: Mr. Jim Rusnak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01123 Sample location: PPG PPG Sample No. Outfall 201 Collected by: J RUSNAK Collection date: 03/13/89 Time: comp Laboratory submittal date: 03/17/89 Time: 16:30 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/23/89 Time started: 17:53 Date finished: 03/23/89 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/13/39 Time started: 22:11 Date finished: Analyst: RLH 03/13/39 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/23/39 Date finished: Time started: 17:07 Analyst: RLH 03/23/89 SL 105555 # r Mr. Jim Rusnak Page: 2 AAOitf? March 29, 1989 Parameter: PESTICIDES AND PCBs Method reference: EPA 625 Result: see appended report Date started: 03/21/39 Time started: 15:01 Date finished: 03/21/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference: EPA 625 Result: less than .01 ug/L Date started: 03/24/89 Time started: 04:29 total Date finished: Analyst: RLH 03/24/39 Data for Chlorinated Hydrocarbons Component Name 1,3-Dichlorobenzene A,4-Dichlorobenzene a,2-Dichlorobenzene -Hexachloroethane 1,2,4-Trichlorobenzene .Hexachlorobutadiene Ai xachlorocyclopentadiene ,2-Chloronaphthalene flexachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride .Tr if luorochlorome thane Chloroethane -Methylene Chloride 1,1-Dichloroethene 1, 1-Dichloroethane /trans-1,2-Dichloroethene --Chloroform ''1,2-Dichloroethane -4,1, 1-Trichloroethane -Carbon Tetrachloride Concentration Trace . 15 .09 .35 . 46 3.60 Trace Not Det 4.30 Component .05 .05 .05 .05 .05 .05 .05 .05 . 05 y Concentration A)/l Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not. Det 93 . 7. Not Det. Not Det Component. MDL 10 10 10 10 10 5 5 5 5 5 5 5 5 SL 105556 Mr. Jim Eusnak Page: 3 flAttuZ March 29. 1989 Data for VOLATILE ORGANIC ANALYSIS Component. Name -Bromodichloromethane A., 2-Dicnioropror i.;. _ '.rsns* 1 , 3-Dir *i : 'ropropene ^rich 1oroethene ./Dibromochlorome thane '1,1,2-Trichloroethane Benzene "bis-1,3-Dichloropropene '2-Chloroethylvinylether 'Bromoform -Tetrachloroethene 1,1.2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total ( cent.inuea ; 3onCv;:'r-- ... ~ No-: Je ll or. Det Not Det Trace Trace Not Det Not Det Not Det Trace Trace Not Det Not Det Not Det Not Det Not Det 5 r, F, F, 5 10 5 r 5 5 o 5 5 Data for Base/Neutral Acid Extractables Component Name Ph nol bis(2-Chloroethyl) Ether .2-Chlorophenol ^1,3-Dichlorobenzene .1,4-Dichlorobenzene 1.2-Dichlorobenzene .bis(2-Chloroisopropyl) Ether t N-Nitroso-di-n-propylamine diexachloroe thane Nitrobenzene 'dsophorone -2-Nitrophenol ^2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol ,2-Chloronaphthalene y Concentration /</// 50. 43. Not Det Trace Trace Trace Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Trace Trace Not, Det Comp 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 DDL MDL SL 105557 Mr. Jim Rusnak Page: 4 AAoiffl March 29, 1989 Data for Base/Neutral Acid Extractables Component Name -Dimethyl Phthalate 'Acenaphthalene Acenaphthene 2.4-Dinitrophenol 4-Nitrophenol 2.4-Dinitrotoluene 2.6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4.6-Pinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenylether Hexachlorobenzene -'Pentachlorophenol -Phenanthrene '-'Anthracene ^Di-n-Butylphthalate fluoranthene t/Pyrene futylbenzylphthalate `3,3' -Dichlorobenzidine -Benzo(a)anthracene bis(2-Ethylhexyl) Phthalate vOhrysene 'Di-n-octyl Phthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-c,d)pyrene ^Dibenzo(a,h)anthracene .Benzo(g,h,i)perylene -Benzidine (continued) Concentration ty/L Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component M9jL 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC Concentration Not Det Not Det Not Det Not Det Not Det Component MDL . 05 . 05 . 05 . 05 . 05 SL 105558 Mr. Jim Rusnak Page: 5 **0tU3 March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4'-DDE 4,4' -DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde (continued) Concentration M?/jL Not Det. Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component MDL .i .i .i .i , 05 .1 .1 .1 . 05 .05 1 1 1 .1 .5 .1 Comments: Semi-vol sample is 24hr composite. VOAs (2ea) at 0:15, 7:00, 12:40. 13:30. Reference Lab Report No. R489. If there are any questions regarding this data, please call. SD 105559 From: American Laboratories and Research Services. Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1939 To: Mr. Jim Rusnak PPG Industries Chemicals Division P.O. Box 1000 Lake Charles, LA 70602 The following analytical results nave been obtained for rhe indicated sample wnich was submitted to this laboratory: Sample I.D. AA01153 Sample location: PPG PPG Sample Outfall 201 Collected by: J RUSNAK Collection date: 03/16/39 Time: comp Laboratory submittal date: 03/21/39 Time: 16:40 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/24/39 Time started: 10:31 Date finished: 03/24/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/22/39 Time started: 21:14 Date finished: Analyst: RLH 03/22/39 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/23/89 Date finished: Time started: 1:15 Analyst: RLH 03/23/39 SL 10556o Mr. Jim Rusnak Page; 2 AAoltfi March 29, 1989 Parameter: PESTICIDES AND PCPs Method reference: EPA 625 Result: see appended report Date started: 03/22/39 Time started: 19:38 Date finished: o3/2 2/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference: EPA 625 Result; less than .01 ug/L Date started; 03/24/89 Time started: 05:35 total Date finished: Analyst: RLH 03/24/89 Data for Chlorinated Hydrocarbons Component Name I.3-Dichlorobenzene A, 4-Dichlorobenzene A ,2-Dichlorobenzene Hexachloroethane A >2,4-Trichlorobenaene /Hexachlorobutadiene -Hexachlorocyclopentadiene >2-Chloronaphthalene ^Hexachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane 'Bromomethane ^J/inyl Chloride Trifluorochloromethane >Ihloroethane ^Methylene Chloride 1.1-Dichloroethene 1.1-Dichloroethane -"trans-1,2-Dichloroethene /Chloroform 1, 2-Dichloroet.hane A , 1.1-Trichloroethane /Carbon Tetrachloride Concentration . 09 . 37 . 19 .52 . 52 8.40 Trace Not Det 5.60 Component MDL . 05 .05 .05 .05 .05 . 05 . 05 .05 .05 y Concentration AV/2 Not Det Not Det 38. Not Det 12. Not Det 17. 44. Not Det 170. 540 . 31. Not Det Component MDL 10 10 10 10 10 s SL 105561 i. t y Mr. Jim Rusnak Page : 3 A A O HS3 March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name ^-Bromodichlorome thane -'i, 2-Dichloropropane ^trans-1,3-Dichloropropene Trichloroethene --Dibromochlorome thane -1,1,2-Trichloroethane Benzene -cis-1,3-Dichloropropene -2-Chloroethylvinylether ^Bromoform "Tetrachloroethene 1,1,2,2-Tetracnloroethane -"Toluene Chlorobenzene -Ethylbenzene ^Xylene, total (continued) Concelvtrat ion 6. Not Det Not Det 40. Trace Trace Not Det Not Det Not Det Trace 310. Not Det Not Det Trace Not Det Not Det "omponent MDL 0 10 Data for Base/Neutral Acid Extractables Component Name Phenol bis(2-Chloroethyl) Ether "2-Chlorophenol "1.3-Dichlorobenzene l, 4-Dichlorobenzene 1,2-Dichlorobenzene -bis(2-Chloroisopropyl) Ether -N-Nitroso-di-n-propylamine Hexachloroethane -Nitrobenzene Isophorone .'2-Nitrophenol -2,4-Dimethylphenol jDis( 2-Chloroethoxy) Methane 2.4-Dichlorophenol 1.2.4-Trichlorobnezene Naphthalene Hexachlorobutadiene 4-Chloro-3-methylphenol 'Hexachlorocyclopentadiene '2,4,6-Trichlorophenol -2-Chloronaphthalene y Concentration SO. 67, Not Det Trace Trace Trace Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Trace Trace Not Det Component MDL 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105562 Mr. Jim Rusnak Page: 4 frA*HS'3 March 29, 1989 Data for Base/Neutral Acid Extractables (continued) Component Name Concentration `-Dimethyl Phthalate -Afcenaphthalene -Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol .2,4-Dinitrotoluene 2,6-Binitrotoluene Diethylphthalate -4-Chlorophenyl-phenylether fluorene 4.6-Dinitro-2-methylphenol N-Nitrosodiphenylamine -4-Bromophenyl-phenylether /Hexachlorobensene Pentachlorophenol -Fhenanthrene Anthracene ^Di-n-Butylphthalate /fluoranthene Ayrene .JJutylbenzylphthalate , 3,3'-Dichlorobensidine -Benzo(a)anthracene - bis(2-Ethylhexyl) Phthalate Chrysene --'Di-n-octyl Phthalate Benzo(b)fluoranthene ^Benzo(k)fluoranthene Benzo(a)pyrene -Indeno(1,2,3-c,d)pyrene JHbenzo (a, h) anthracene Benzo(g,h,i)perylene Aenzidine Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Bet Not Det Not Det Not Det Not Det Not Det Trace Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Comp*: SV/J- 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC Concentration Not Det Not Det Not Det Not Det Not, Det Component Mf/l . 05 . 05 . 05 . 05 . 05 SL 105563 Mr. Jim Rusnak Page: 5 AAoJJSV March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde ( continued') Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Comp' wl .1 .1 .1 .1 . 05 .1 .1 .1 . 05 . 05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Semi-vol sample is 24hr composite. VOAs (2 ea) at 6:26, 14:00, 18:33, 0:24. Reference Lab Report No. R489. If there are any questions regarding this data, please call. SL 105564 From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1989 To; PPG Industries Chemicals Division P.O. Box 1000 Lake Charles, LA 70602 ATTN: Mr. Jim Rusnak The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01090 Sample location: PPG Outfall 001/Mobil #2 Bridge Collected by: J RUSNAK Collection date: 03/07/39 Time: comp Laboratory submittal date: 03/11/89 Time: 10:30 Received by: RLH Validated by: FLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/13/39 Time started: 17:24 Date finished: 03/13/39 Analyst: FLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/16/89 Time started: 6:25 Date finished: Analyst: RLH 03/16/39 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/13/39 Date finished: Time started: 16:27 Analyst: RLH 03/13/89 SL 105565 z ^ I PPG Industries Page: 2 AACt/Olo March 29, 1989 Parameter: PESTICIDES AND PCBs Method reference: EPA 625 Result: see appended report Date started: 03/11/39 Time started: 22:58 Date finished: .'13/11/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference: EPA 625 Result: less than .01 ug/L Date started: 03/12/39 Time started: 11:33 total Date finished: Analyst: RLH 03/12/39 Data for Chlorinated HydrocarDons Component Name --1,3-Dichlorobenzene 1,4-Dichlorobenzene - 1,2-Dichlorobenzene Hexachloroethane 1,2,4-Trichlorobenzene -- Hexachlorobutadiene --Hexachlorocyclopentadiene --2-Chloronaphthalene -Hexachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride Trifluorochloromethane Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1,1,1-Trichloroethane Carbon Tetrachloride / Concentration . 09 . 21 . 12 1.00 .63 5.40 Not Det Not Det -.57 Component . 05 .05 .05 . 05 . 05 .05 .05 . 05 . 05 Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 29. 6. Trace Not Det Component MDL 10 10 10 10 10 5 5 5 5 5 5 5 5 SL 105566 r( PPG Industries Page: 3 AAo/olo March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total (continued) Concentration Trace Not Det Not Det e. Trace 10. Not Det Not Det Not Det Trace 11. 20. Not Det Not Det Not Det Not Det Component MDL 5 5 5 5 5 5 5 5 10 5 5 5 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name Phenol bis(2-Chloroethyl) Ether 2-Chlorophenol --1,3-Dichlorobenzene 1,4-Dichlorobenzene - 1,2-Dichlorobenzene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene --Hexachlorobutadiene 4-Chloro-3-methylphenol -- Hexachlorocyclopentadiene 2,4,6-Trichlorophenol -2-Chloronaphthalene Concentration Not Det Trace Not Det Trace Trace Trace Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Not Det Not Det Component MDL Attfc 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105567 K PPG Industries Page: 4 March 29, 1989 Data for Base/Neutral Acid Extractables Component Name Dimethyl Phthalate Acenaphthalene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4,6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenylether --Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-c,d)pyrene DibenzoC a,h)anthracene Benzo(g,h,i)perylene Benzidine ( cont inued) Cone:entrat ion *3/1 Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC Concentration *3/1 Not Det Not Det Not Det Not Det Not Det Component MDL 3/l . 05 . 05 . 05 . 05 . 05 SL 105568 PPG Industries Page: 5 AAotofo March 29, 1989 Data for PESTICIDES AND PCBs :ontinued) 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone M thoxychlor Endrin Aldehyde Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det .1 .1 .1 ,l , 05 .1 .1 .1 . 05 . 05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: CO roo 24hr. composite. VOA grab times: 6:55, 12: 21 0:25. 1 of each VOA vials and both of 0:25 vials b] Reference Lab Report No. R489. If there are any questions regarding this data, please call. Sh 105S69 From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1989 To: PPG Industries Chemicals Division P.O. Box 1000 Lake Charles, LA 70602 ATTN: Mr. Jim Rusnak The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01091 Sample location: PPG Outfall 001/Mobil 1*2 Bridge Collected by: J RUSNAK Collection date: 03/09/39 Time: comp Laboratory submittal date: 03/11/89 Time: 10:30 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/13/89 Time started: 13:30 Date finished: 03/13/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/16/89 Time started: 6:59 Date finished: Analyst: RLH 03/16/89 Parameter: Base/Neutral Acid Extractables Method reference; EPA 625 Result: see appended report Date started: 03/13/39 Date finished: Time started: 17:33 Analyst: RLH 03/13/89 SL 105570 PPG Industries Page: 2 AAO/HI March 29, 1989 Parameter: PESTICIDES AND FCBs Method reference: EPA 625 Result: see appended report Date started: 03/12/89 Time started: 0:15 Date finished: 03/12/39 Analyst: RLH Parameter: Dioxin Screen Method reference: EPA 625 Result: less than .01 Date started: 03/12/89 Time started: 12:07 TCDD, total ug/L Date finished: 03/12/39 Analyst: RLH Data for Chlorinated Hydrocarbons Component Name 1.3-Dichlorobenzene 1.4-Dichlorobenzene 4,2-Dichlorobenzene Hexachloroethane 1.2.4-Trichlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene -2-Chloronaphthalene Hexachlorobensene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Dr..vcmetnane --'Vi r'hloride Trifluorochloromethane Chloroethane Methylene Chloride 1, 1-Dichloroethene 1, 1-Dichloroethane trans-1.2-Dichloroethene Chloroform 1,2-Dichloroethane 1,1,1-Trichloroethane Carbon Tetrachloride Concentration /V/l .08 .23 . 13 1.50 .71 5.20 Not Det Not Det . 34 Component MDL m. .05 .05 .05 .05 .05 .05 . 05 . 05 . 05 f*S/i Not, Det. Not Det Not Det Not Det Not Det Not. Det. Not Det, Not Det Not Det 13. Not Det Not Det Not Det 'omp'-: nen t MPL 10 10 , 10 10 10 5 5 5 5 5 5 5 F, J SL IQSS71 PPG Industries Page: 3 March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Bensene eis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total (continued) Concentration Mt/L Trace Not Det Not Det Trace 9. Trace Not Det Not Det Not Det 29, m ), 8, Not Det Not Det Not Det Not Det Com? 5 5 5 5 F. 5 5 r. 10 5 a, 5 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name Phenol bie(2-Chloroethyl) Ether 2-Chlorophenol ~i,3-Dichlorobensene -1,4-Dichlorobenzene 1,2-Dichlorobensene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene ~Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2-Chloronaphthalene Concentration Not Det Trace Not Det Trace Trace Trace Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Not Det Not Det Comi 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105572 PPG Industries Page: 4 A^O/ofi March 29, 1989 Data for Base/Neutral Acid Extractables Component Name Dimethyl Phthalate Acenaphthalene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4,6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Ph nanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyr ne Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benso(a)pyrene Indeno(1,2,3-c,d)pyrene Dibenzo(a,h)anthracene Benzo(g,h,i)perylene Benzidine (continued) / Concentration #3/L Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC / Concentration Not Det Not Det Not Det Not Det Not Det Component #9/1 . 05 . 05 . 05 .05 .05' SL 105573 PPG Industries Page : 5 AAa /of/ March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone M thoxychlor Endrin Aldehyde continued) / Concentration M/L Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component .1 .1 .1 .1 . 05 .1 .1 .1 . 05 ,05 .5 ,5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: 24 hr composite. VGA grabs at: Reference Lab Report No. R489. 8:25, 13:00, 13:46, 0:10. If there are any questions regarding this data, please call. V' Ricky H/ Hatton, Ph.D. Vice President *-rt**'v Reviewed By: James W. Pinson, Ph.D. President SL 105574 From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1939 To; Mr. Jim Rusnak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01117 Sample location: PPG PPG Sample No. Outfall flOl Collected by: J RUSNAK Collection date: 03/14/89 Time: comp Laboratory submittal date: 03/16/89 Time: 10:30 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/18/89 Time started: 13:04 Date finished: 03/13/39 Analyst: RLH Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/18/89 Date finished: Time started: 5:10 Analyst: RLH 03/13/39 Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/13/89 Time started: 21:05 Date finished: Analyst: RLH 03/13/89 SL 105575 Mr. Jim Rusnak Page: 2 /?Aa///7 March 29, 1939 Parameter: PESTICIDES AND PCBs Method reference: EPA 625 Result: see appended report Date started: 03/17/39 Time started: 10:31 Date finished: 03/17/39 Analyst: RLH Parameter: Dioxin Screen Method reference: EPA 625 Result: less than .01 Date started: 03/20/39 Time started: 20:12 TCDD, ug/L total Date finished: Analyst: RLH 03/20/39 Data for Chlorinated Hydrocarbons Component Name 1.3-Dichlorobenzene 1.4-Dichlorobenzene 1,2-Dichlorobenzene Hexachloroethane 1.2.4-Trichlorobenzene Hexachlorobutadiene H xachlorocyclopentadiene 2-Chloronaphthalene Hexachlorobenzene Concentration Not Det Not Det Not Det .38 .30 1.40 Not Det Not Det .21 Component- . 05 . 05 . 05 .05 . 05 . 05 .05 .05 .05 Data for Base/Neutral Acid Extractables Component Name Phenol bis(2-Chloroethyl) Ether 2-Chlorophenol 1.3- Dichlorobensene 1.4- Dichlorobenzene 1.2-Dichlorobenzene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2.4- Dimethylphenol / Concentration Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Component MDL W/L 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105576 Hr. Jim Rusnak Page: 3 AAonn March 29, 1989 Data for Base/Neutral Acid Extractables Component Name bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2-Chloronaphthalene Dimethyl Phthalate Acenaphthalene Ac naphthene 2,4-Binitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4,6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbensylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-c,d)pyrene Dibenso(a,h)anthracene Benzo(g,h,i)perylene Benzidine (continued Concentration W/l Not Det Not Det Trace Not Det Trac:e Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det 14. Not Det Not Det Not Det Not Det Not Det Not Det Not Det Comp' 10 10 10 10 10 10 10 10 10 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 SL 10557J Mr. Jim Rusnak Page: 4 AAoUtl March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride Trifluorochloromethane Chloroethane Methylene Chloride 1.1- Dichloroethene 1.1- Bichloroethane trans-1,2-Dichloroethene Chloroform 1.2- Dichloroethane 1,1,1-Trichloroethane Carbon Tetrachloride Bromodichloromethane 1.2- Dichloropropane trans-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1.1.2- Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1.1.2.2- Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total' Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC 4,4'-DDT 4,4'-DDE // Concentration *3/c Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Oq . Not Det Trace Not Det Trace Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det 3. 5. Not Det Not Det Not Det Not Det Not Det Component MDL M 10 10 10 10 10 5 5 5 o5c 5 5 5 5 5 5 5 5 5 5 5 10 5 5 5 5 5 5 5 ./ Concentration MIL Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component MDL Ml .05 .05 .05 .05 .05 ,1 ,1 $1j X05578 Mr. Jim Rusnak Page: 5 A#a/U7 March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde / (continued) Concentration /tf/X Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component MDL ty/L .l .l . 05 .1 .1 .1 . 05 .05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Extractables sample is 24hr composite. VOAs (2 ea) at 6:50, 12:20, 13:25, 0:10. Reference Lab Report No. R489. If there are any questions regarding this data, please call. Hatton, Ph.D. Vice President Reviewed By: James W. Pinson, Ph.D. President SL 105579 Prom: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1989 To: Mr. Jim Rusnak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 Th following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01140 Sample location: PPG PPG Sample No. Outfall 001 Collected by: J RUSNAK Collection date: 03/16/89 Time: comp Laboratory submittal date: 03/13/89 Time: 11:00 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/23/89 Time started: 12:34 Date finished: 03/23/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/18/89 Time started: 22:43 Date finished: Analyst: RLH 03/18/89 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/23/89 Date finished: Time started: 8:26 Analyst: RLH 03/23/39 SL 105580 Mr. Jim Rusnak Page: 2 fyAOMo March 29, 1989 Parameter: PESTICIDES AND PCBs Method reference: EPA 625 Result: see appended report Date started: 03/21/89 Time started: 16:00 Date finished: 03/21/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference: EPA 625 Result: less than .01 ug/L Date started: 03/24/89 Time started: 03:05 total Date finished: Analyst: RLH 03/24/89 Data for Chlorinated Hydrocarbons Component Name 1,3-Dichlorobenaene 1,4-Dichlorobenaene 1,2-Dichlorobenaene H xachloroethane 1,2,4-Trichlorobenaene -flexachlorobutadiene -H xachlorocyclopentadiene --2-Chloronaphthalene H xachlorobenaene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride Trifluorochloromethane Chloroethane M thylene Chloride 1.1- Dichloroethene 1.1- Dichloroethane trans-1,2-Dichloroethene Chloroform 1.2- Dichloroethane 1,1, l-Trichloroet,hane Carbon Tetrachloride Concentration W/L Trace . 12 .06 .40 .32 1.82 Not Det Not Det .74 Component MDL .05 .05 .05 .05 .05 .05 . 05 . 05 .05 / Concentration /y/l Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 8 7 Not Det Not Det Component MDL Ml 10 10 10 10 10 SL 105581 Mr. Jim Rusnak Page: 3 March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cic-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total (continued) Concentration Trace Not Det Not Det Trace 6. Trace Not Det Not Det Not Det 11. Not Det Not Det Not Det Not Det Not Det Not Det Compo; AW 5 5 5 5 5 5 5 5 10 5 F, 5 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name Phenol bis(2-Chloroethyl) Ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobensene 1,2-Dichlorobenzene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2.4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene "Sexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2-Chloronaphthalene / J Concentration Mpk Not Det Trace Not Det Trace Trace Trace Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Not Det Not Det Compo My/l 10 10 in 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105582 Mr. Jim Rusnak Page: 4 frAo//o March 29, 1989 Data for Base/Neutral Acid Extractables Component Name Dimethyl Phthalate Acenaphthalene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylet.her Fluorene 4.6~Dinit.ro--1 :'ierhy Lphenoi -Nitrosodiphenylamme 4-Bromophenyl-pnenylether Hexachlorobensene Fentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-c,d)pyrene Dibenzo(a,h)anthracene Benzo(g,h,i)perylene Benzidine ('continued') '/ Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det. Not Det Not Det Not Det. Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 41. Not Det 20. Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component. MDL Ml 10 10 10 50 50 10 10 ' 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC Concentration *$/l Not Det Not Det Not Det Not Det Not Det Compor K/L . 05 . 05 . 05 .05 .05 SL 105583 Mr. Jim Rusnak Page: 5 AAO//W March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde (contylued) Concentration Mt/L Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component MDL .1 .1 .1 .1 . 05 .1 .1 .1 .05 . 05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Semi-Vol sample is 24hr composite. VOAs (2 es) at 6:15, 13:50, 13:17, 0:10. Reference Lab Report No. R489. If there are any questions regarding this data, please call. Reviewed By: James W. Pinson, Ph.D. President SL 105584 F rom: American Laboratories and Research Services, Inc. P.9. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1939 To: Mr. Jim Rusnak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 The following analytical resuits have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01093 Sample location: PPG PPG Sample No. Outfall 101 Collected by: JIM RUSNAK Collection date: 03/07/39 Time: COMP Laboratory submittal date: 03/13/89 Time: 14:00 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/15/89 Time started: 2:53 Date finished: 03/15/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/20/39 Time started: 13:06 Date finished: Analyst: RLH 03/20/39 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/15/39 Date finished: Time started: 1:57 Analyst: RLH 03/15/39 SL 105585 Mr. Jim Rusnak Page: 2 frA&l * 13 March 29, 1989 Parameter; PESTICIDES AND FCBs Method reference: EPA 625 Result: see appended report Date started: 03/14/39 Tim started: 5:16 Date finished: 03/14/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference: EPA 625 Result: less than .01 ug/L Date started: 03/15/39 Time started: 2:15 total Date finished: yst: RLH 03/15/89 Data for Chlorinated Hydrocarbons Component Name 1.3- Dichlorobenzene 1.4- Dichlorobenzene 1,2-Dichlorobenzene Hexachloroethane 1.2.4- Trichlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene 2-Chloronaphthalene H xachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride Trifluorochloromethane Chloroethane Methylene Chloride 1.1- Dichloroethene 1.1- Dichloroethane trans-1,2-Dichloroethene Chloroform 1.2- Dichloroethane 1,1,1-Trichloroethane Carbon Tetrachloride i/ Concentration Not Det Not Det Not Det 19 Not Det 25 22 Not Det 13 Component . 05 .05 .05 .05 . 05 .05 . 05 . 05 . 05 Concentration njL Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 36 . Not Det 24. Not Det Component ft/L 10 10 10 10 10 5 5 5 5* 5 c; 5 SX. 105586 Mr. Jim Rusnak Page: 3 AAot013 March 29. 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichlorcpropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total / (continued) / Concentration *3/1 Not Det Not Bet Not Bet Trace Not Bet Not Bet Not Bet Mot Bet Not Bet. Not Det. Not Bet Not Bet Not Det Not Det Not Det Not Det Data for Baee/Neutral Acid Extractables Component Name Phenol bis(2-Chloroethyl) Ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobensene 1.2-Dichlorobenzene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorebutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2-Chloronaphthalene / Concentration *i/L Not Det Not Det Not Det Not Det Not Bet Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Bet Not Det Not Det Not Det Not Det Trace Not Pet Trace Not Det Not Bet Co mi 5 5 F 5 5 F, 5 5 10 F. F, F 5 5 5 5 Corn] m 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 MDL MBL SL 105587 I Mr. Jim Fiusnak Page: 4 AftoldfS March 29. 1989 Data for Base/Neutral Acid Extractables Component Name Dimethyl Phthalate Acenaphthalene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrot.oluene 2,6-Dinit.rotoluene Diethylphthalate 4-Chloropheny1-phenylether Fluorene 4.6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenyiether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benso(b)fluoranthene Benzo(k)fluoranthene Benzof a)pyrene Indenof1,2,3-c,d)pyrene Dibenzo(a,h)anthracene Benzo(g,h,i)perylene Benzidine : continued) / Concentration MS// Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Mot Det Trace Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component M/l 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC / Concentration MS// Not Det Not Det. Not Det, Not Det Not Det Component MDL M9/C . 05 . 05 . 05 . 05 . 05 SL 105588 Mr. Jim Rusnak Page; 5 March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4 r-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde (continued) Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Compo .1 .1 .1 .1 , 05 .1 .1 .1 , 05 . 05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Semi-Vol sample is 24 hr composite. VOA sample (2 ea) taken at 6: 10, 12:40, 13 : 25 , 00:15. Reference Lab Report No. R489. If there are any questions regarding this data, please call. Ricky ]/. Hatton, Ph . D . V ice^Preeident Reviewed By: James W. Pinson, Ph.D. President SL 105589 From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1989 To: Mr. Jim Rusnak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01109 Sample location: PPG PPG Sample No. Outfall 101 Collected by: J RUSNAK Collection date: 03/09/39 Time: comp Laboratory submittal date: 03/15/39 Time: 13:30 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/13/89 Time started: 11:36 Date finished: 03/13/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/18/39 Time started: 19:59 Date finished: Analyst: RLH 03/13/59 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/13/39 Date finished: Time started: 10:39 Analyst: RLH 03/13/39 SL 105590 Mr. Jim RusnaK Page: 2 AA-oUef March 29, 1989 Parameter: PESTICIDES AND FCBs Method reference: EPA 625 Result: see appended report Date started: 03/17/89 Time started: 3:22 Date finished; 03-'17 '39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference; EPA 625 Result: less than .01 ug/l Date started: 03/20/39 Time started: 13:43 total Date finished: Analyst: RLH 03/20-'89 Data for Chlorinated Hydrocarbons Component Name 1,3-Dichlorobensene 1,4-Dichlorobensene 1,2-Dichlorobensene Hexachloroethane 1,2,4-Trichlorobensene Hexachlorobutadiene Hexachlorocyclopentadiene 2-Chloronaphthalene Hexachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride Trifluorochloromethane Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1.1,1-Trichloroethane Carbon Tetrachloride / Concenter at ion Not Det. Not Det Not Det .26 Not Det . 16 . 15 Not Det . 12 Component. MDL Wl , 05 . 05 .05 .05 .05 .05 .05 . 05 . 05 Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det. Not Det Not Det 33 . Not Det. Trace Not Det Component MDL /Q/L 10 10 10 10 10 5 5 5 5 5 5 5 5 SL 105591 { Mr. Jim Rusnak Page: 3 Aft 0 HOI March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xyl ne, total 1 continued ) Concentration Not Det Not Det Not Det Trace Trace Not Det Not Det Not Det Not Det 5. Not Det Not Det Not Det Not Det Not Det Not Det Compo. /MJ/Z 5 5 5 5 5 5 5 10 5 F, rx 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name Phenol bis(2-Chloroethyl) Ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis{2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorobutadiene 4-Chloro-3-methy1phenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2-Chloronaphthalene J Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not/ Det Compo M3/l 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105592 Mr. Jim Rusnak Page; 4 AAa//^i March 29. 1989 Data tor Base/Neutral Acid Extractables Component Name Dimethyl Phthalate Acenaphthalene Acenaphthene 2.4-Dinitrophenol 4-Nitrophenol 2.4-Binitrotoluene 2.6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4.6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenyiether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-ri-Butylphthalate Fluorant:. Pyrene Butylbensyiphthalate 3,3'-Dichlorobenzidine Benzola )anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Fhthalate Bento(b)fluoranthene Benzolk)fluoranthene Benzol a)pyrene Indenol1,2,3-c,d)pyrene Dibenzo(a,h)anthracene Benzo(g, h, i)perylene Benzidine 'continued) Concentration /"jA Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Trace Trace Not Det Not Det No t I . Not Det Not. Det. Not Det Not Det Not Det Not E)et Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component Pt/l 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldriri alpha-EHC beta-EHC delta-BHC gamma-BHC / Concentration M/l. Not Det Not Det Not Det Not Det Not Det Component &A . 05 . 05 . 05 .05 . 05 SL 105593 Mr. Jim Rusnak Page: 5 March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4.4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde 1 cont inued ' Concentration f*3/l Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Compc . . 1*1 .1 .1 . 05 .1 .1 .1 . 05 . 05 . 5C, ,,5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Extractables sample is 24hr composite. VOAs (2ea) at 7:55, 12:52, 13:24, 0:25. Reference Lab Report No. R489. If there are any questions regarding this data, please call. SL 105594 From: American Laboratories and Research Services, Inc. P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1989 To: Mr. Jim Ruenak PPG Industries Chemicals Division P.0. Box 1000 Lake Charles, LA 70602 The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01122 Sample location: PPG PPG Sample No. Outfall 101 Collected by: J RUSNAK Collection date: 03/13/39 Time: comp Laboratory submittal date: 03/17/89 Time: 16:30 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EPA 612 Result: see appended report Date started: 03/23/89 Time started: 13:21 Date finished: 03/23/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/13/39 Time started: 21:33 Date finished: Analyst: RLH 03/13/39 Parameter: Base/Neutral Acid Method reference: EPA 625 Result: see appended report Date started: 03/23/39 Time started: 9:21 Extractables Date finished: Analyst: RLH 03/23/39 SL 105595 Mr. Jim Rusnak Page: 2 flfroffXX March 29, 1989 Parameter: PESTICIDES AND FCBs Method reference: EPA 625 Result: see appended report Date started: 03/21/89 Time started: 13:57 Date finished: 03/21/39 Analyst: RLH Parameter: Dioxin Screen - TCDD, Method reference: EPA 625 P suit: less than .01 ug/L Date started: 03/24/89 Time started: 03:47 total Date finished: Analyst: RLH 03/24/39 Data for Chlorinated Hydrocarbons Component Name 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Hexachloroethane 1,2,4-Trichlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene 2-Chloronaphthalene Hexachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride Trifluorochloromethane Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane trans-1,2-Dichloroethene Chloroform 1,2~Dichloroet,hane 1,1,1-Trichloroethane Carbon Tetrachloride Concentration Not Det Not Det Not Det . 17 Not Det . 19 Trace Not Det .23 Component .05 . 05 . 05 . 05 . 05 . 05 . 05 . 05 / / Concentration *3/1 Not Det Not Det Not Det Not Det Not Det 12. Not Det Not Det Not Det 34 . Not Det Not Det Not Det Component 10 10 10 10 10 5 5 5 5 5 5 5 5 SL 105596 Mr. Jim Eusnak Page: 3 AbotUO. March 29, 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total icontinued) Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Trace Not Det Not Det Not Det Not Det Not Det Compc 5 5 5 5 5 5 5 5 10 5 5 5 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name Phenol bis(2-Chloroethyl) Ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene bis(2-Chloroisopropyl) Ether N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2-Chloronaphthalene / Concentration Wll Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Comp' MJ/I 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105597 Mr. Jim Rusnak Page: 4 AA& //2JMarch 29, 1989 Data for Base/Neutral Acid Extractables Component Name Dimethyl Phthalate Acenaphthalene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4.6-Pinitro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenylether Hexachlorobensene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indenof1,2,3-c,d)pyrene Dibenzo(a,h)anthracene Benzo(g,h,i)perylene Benzidine (continued) / Concentration Not Pet Not Pet Not Pet Not Pet Not Pet Not Pet Not Pet. Not Pet Trace Not PetNot Pet Not Pet Trace Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Compon M/l 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC y Concentration m/I Not Det Not Det Not Det Not Det Not Det Compel /?/ . 05 . 05 . 05 . 05 .05 SIi 105598 Mr. Jim Rusnak Page: 5 4Aot<Xi- March 29, 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor Heptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde ontinued) Concentration M/I Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Co mp< .1 .1 .1 .1 , 05 .1 .1 .1 . 05 . 05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: Semivol sample is 24hr composite. VOAs (2ea) at 0:30, 7:10, 12:36, 13:33. Reference Lab Report No. R489. MDL If there are any questions regarding this data, please call. Ricky Hatton, Ph.D. Vice President Reviewed By: James W. Pinson, Ph.D. President SL 105599 From: American Laboratories and Research Services, Inc. P.G. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320 Date: March 29, 1939 To: Mr. Jim Rusnak PPG Industries Chemicals Division P.O. Box 1000 Lake Charles, LA 70602 The following analytical results have been obtained for the indicated sample which was submitted to this laboratory: Sample I.D. AA01152 Sample location: PPG PPG Sample Outfall 101 Collected by: J RUSNAK Collection date: 03/16/39 Time: comp Laboratory submittal date: 03/21/89 Time: 16:40 Received by: RLH Validated by: RLH Parameter: Chlorinated Hydrocarbons Method reference: EFA 612 Result: see appended report Date started: 03/23/39 Time started: 21:59 Date finished: 03/23/39 Analyst: RLH Parameter: VOLATILE ORGANIC ANALYSIS Method reference: EPA 624 Result: see appended report Date started: 03/22/39 Time started: 20:42 Date finished: Analyst: RLH 03/22/39 Parameter: Base/Neutral Acid Extractables Method reference: EPA 625 Result: see appended report Date started: 03/23/39 Date finished: Time started: 21:12 Analyst: RLH 03/23/89 SL 105600 Mr. Jim Rusnak Page: 2 March 29, 1989 Parameter: PESTICIDES AND PCBs Method reference: EPA 625 Result.; see appended report Date started: 03/22/89 Time started: 18:42 Date finished: 03/22/89 Analyst: RLH Parameter: Dioxin Screen *- TCDD, Method reference: EPA 625 Result: less than ,01 ug/L Date started: 03/24/89 Time started: 05:11 total Date finished: Analyst: RLH 03/24/39 Data for Chlorinated Hydrocarbons Component Name 1.3- Dichlorobenzene 1.4- Dichlorobenzene 1,2-Dichlorobenzene Hexachloroethane 1.2.4- Trichlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene 2-Chloronaphthalene Hexachlorobenzene Data for VOLATILE ORGANIC ANALYSIS Component Name Chloromethane Bromomethane Vinyl Chloride Trifluorochloromethane Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1,1,1-Trichloroethane Carbon Tetrachloride Concentration Not Det Not Det Not Det 30 Not Det 33 25 Not Det 93 Component MDL /</A .05 .05 .05 . 05 .05 .05 .05 .05 . 05 Concentration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 110. Not Det Not Det Not Det Component /*?/ 10 10 10 10 10 5 5 5 5 5 5 5 5 SL 105601 'tf 4 fir. Jim Rusnak Page : 3 AAt> USX March 29. 1989 Data for VOLATILE ORGANIC ANALYSIS Component Name Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Xylene, total (continned) Concentration MM. Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Component MM 5 5 5 5 5 5 5 5 10 5 5 5 5 5 5 5 Data for Base/Neutral Acid Extractables Component Name Phenol ,bis(2-Chloroethyl) Ether -2-Chlorophenol 1,3-Dichlorobenzene A, 4-Dichlorobenzene X ,2-Dichlorobenzene bis(2-Chloroisopropyl) Ether -N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy) Methane 2,4-Dichlorophenol 1,2,4-Trichlorobnezene Naphthalene Hexachlorobutadiene 4-Chlorc-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2-Chloronaphthalene / Concentration MM Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Trace Not Det Not Det Component MM 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 SL 105602 Mr. Jim Rusnak Page; 4 faoHCZMarch 29, 1989 Data for Base/Neutral Acid Extractables Component Name Dimethyl Phthalate Acenaphthalene Acenaphthene 2.4-Dinitrophenol 4-Nitrophenol 2.4-Dinitrotoluene 2.6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4.6-Dinitro-2-methyiphenol N-Nitrosodiphenylamine 4-Bromophenyl-phenyletner Hexachlorobensene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbensylphthalate 3,3'-Dichlorobensidine Benso(a)anthracene bis(2-Ethylhexyl) Phthalate Chrysene Di-n-octyl Phthalate Benso(b)fluoranthene Benso(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-c,d)pyrene Dibenso(a,h)anthracene Benzo(g,h,i)perylene Benzidine (conti Conwcekntration Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Trace Not Det Not Det Not Det 12, Trace Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 12. Not Det 18. Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component MDL 10 10 10 50 50 10 10 10 10 10 50 10 10 10 50 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 30 Data for PESTICIDES AND PCBs Component Name Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC Concentration Not Det Not Det Not Det Not Det Not Det Componi . 05 , 05 . 05 .05 .05 SL 105603 \ < Mr. Jim Fusnak Page: 5 AAtUtn March 29. 1989 Data for PESTICIDES AND PCBs Component Name 4,4'-DDT 4,4'-DDE 4,4'-DDD Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Heptachlor H ptachlor Epoxide Aroclor-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 Toxaphene alpha-Chlordane gamma-Chlordane Endrin Ketone Methoxychlor Endrin Aldehyde (continued) Concentration w/i Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Component. MDL 1 , j- .1 .1 .1 . 05 .1 .1 .1 .05 .05 .5 .5 .5 .5 .5 1 1 1 .5 .5 .1 .5 .1 Comments: 3emi-vol is 24hr composite. VOAs (2 ea) at 6:30, 14:05, 13:28, 0:19. Reference Lab Report No. R489. If there are any questions regarding this data, please call. SL 105604