Document rBmkXer9G4ye7YejjJ62kkXG

From fh dtik ai PAULA CLINE, THE ARCHIVES OFFICE First Printing 1942 see "Monsanto Magazine" June, 194*2 - last page 0663*3 TOWOLDMONOOO6613 WATER_PCB-00003123 0683739 TOWOLDMON0006614 WATER_PCB-00003124 0683740 TOWOLDMON0006615 WATER_PCB-00003125 MONSANTO CHEMICALS 0683741 TOWOLDMONOOO6616 WATER_PCB-00003126 T District Officr* \kl)Y OHIO Jnd National HniMin<! Telephone: IIEmlcrk til'll I OS XNGEI.I S. (, U IF. 00> \\ et < )|\ iMpir Bl\ d. I elephnne: XILhigan MUX lilHMINUI XXL M.\. Ilrovm Mar\ H m l< I in ^ I l*[ Inni: 7-iiKTT MoNTKi; XL, <; \ \ \D \ d7H St. Paul Street XX ct Telephone: \| Xrket IJ Wi I't >SToN. \| \S>. lAer.-u Suiimi I'fli'jihon**: I \ Lre t 'ill]il M AX A < IKK. V X . AH Rockefeller Pla/a Telephone: ( Irele 7.1,1 'O charlotte. v <: Johnston Building Telephone: J-U.U CHICAGO, ILI.. Tribune Tower Telephone: \X Hltehall 67*0 DETROIT, MICH, 127 Fisher Building Telephone: TRinit. 2*.>72K LONDON, ENGLAND Victoria Station House ST. I,( )l IS. Mi i, 1 700 South Second >|r*< t Telephone: ( I ntral 0J t t SX.N FRANCISCO. CXI IK. 101 * Mii>li Street Telephone: Douglas HJ0 TORONTO, CAYW) V 18A Front Street Ka-u Telephone: XX \verl\ I I t 1 MELBOURNE. .U STM MIX Somerville Road Brayhrook ^. 19 MANCHESTER. ENGLAND King's H<m*c King's Street ^ est If orks. ANNISTON, ALA BAM V CARONDELET, MISSOLRI CAMDEN, NEW JERSEY DAYTON. OHIO EVERETT, MASS. KARNACK. TEXAS MONSANTO, ILLINOIS MONSANTO, TENNESSEE N1TR0, W EST VIRGIN V NORFOLK. \ IRGIM V TEXAS CITY. TEX XS TRENTON. MIC1IIG VN SPRINGFIELD. MASS. ST. I.ut'IS, MISSOLRI MONTREAL. CAN ADA Rl'ABON, N. W ALES SUNDERLAND, F.\CL\M> MEI.BOl'RNE. AUSTR U I X MO >* \ \ To 0663742 TOWOLDMONOOO6617 WATER_PCB-00003127 Divisions and Associated Companies MERRIMAC DIVISION, Everett Station, Boston, Mass. ORGANIC CHEMICALS DIVISION, 1700 S. Second St., St. Louis. Mo. PHOSPHATE DIV ISION, 1700 S. Second St,, St. Louis, Mo. PLASTICS DIVISION, Springfield. Mass. TEXAS DIVISION. Karnack. Texas. RUBBER SERVICE DEPARTMENT, 2nd National Building, Akron, Ohio. CENTRAL RESEARCH DEPARTMENT, Dayton, Ohio. NEW ENGLAND ALCOHOL COMPANY, Everett Station. Boston, Mass. SHAWINTGAN RESINS CORPORATION, Springfield, Mass. MONSANTO (CANADA), LTD., 378 St. Paul St. West, Montreal, Quebec. MONSANTO CHEMICALS LTD., Victoria Station House, Victoria St., London, S. W. 1, England. MONSANTO (AUSTRALIA) PTY. LTD., Somerville Road, Bravbrook W. 19, Melbourne, N. S. W., Australia. Cable Address "Monsanto'' St. Louia Code*: ABC, 6th and 7th Acme, Bentley'* and Bentley'* Second 26TH edition Page 3 0683743 TOWOLDMONOOO6618 WATER_PCB-00003128 CONTENTS Mow To Lse This Book. . A Vtord About Containers............... Monsanto--The Organization. . Industries Served by Monsanto.................................................... li Monsanto Products ......................................................................IT Monsanto Literature........................... 145 General Data.....................................................................................149 Testing Liquids With the Hydrometer...................................... 149 Dilution and Concentration of Liquids.................................... 151 Sulfuric Acid Tables................................................................... 152 Hydrochloric Acid Table*......................................................... 154 Nitric Acid Tables..................................................................... 156 Acetic Acid Tables ...................................................................153 Aqua Ammonia Tables............................................................. 159 Anhydrous Ammonia Tables................................................... 161 Aluminum Chloride Tables ..................................................... 162 Aluminum Sulfate Tables ....................................................... 163 Sodium Bisulfite Tables........................................................... 165 Merclor Tables............................................................................. 166 Weights Per Gallon................................................................... 167 Conversion Tables for Volume and Weight.............................. 163 Page 4 MONSANTO CHEMICALS 06837AA TOWOLDMONOOO6619 WATER_PCB-00003129 HOW TO USE THIS BOOK This is an entirely new book, designed to bring together in toe most convenient and useful form possible, sufficient information on all Monsanto products to serve as a buying guide and to enable users of chemicals to determine whether a material unfamiliar to them is of sufficient interest to merit further consideration. Those desiring more detailed information on specific products are referred to the Mon santo literature listed on page 14o or to their nearest Monsanto din. irici office. Locations of these offices are given on page 2. All products are listed alphabetically in the main section of the book according to their common chemical names or Monsanto trade names. Where a product has more than one common name, or both a trade name and a chemical name, it has been attempted to list all of these along with proper cross references, thus making the book self indexing and eliminating the trouble of referring to an index first and then to a given page number. To assist users of chemicals in acquainting themselves with the Monsanto products applicable in their particular industry, a classi fication of products according to industries is given on page 11. This classification should not be considered final or complete. New uses for Monsanto chemicals and plastics are opening up dailv, some in fields entirely unsuspected a snort: time before. Likewise, no product should be considered as limited to the uses mentioned in this book. The general data section beginning on page 149 contains a varietv of physical and chemical information which will be useful in connec tion with certain products described in the alphabetical section. Specific reference to this data is made under products to which any ot it applies. If as you use this book suggestions come to mind as to how it might be made more helpful we would appreciate your passing them along to us. In this way we will be able to make our next edition even more useful to you and the many other users of Monsanto products. A WORD ABOUT CONTAINERS Because of the rapid changes taking place in the availability of con tainers at the time this book was compiled, no attempt was made to include container data of any kind. Users of Monsanto products mav rest assured, however, that at all times their orders will be shipped in the highest quality and most satisfactory containers available. For current container information write your nearest Monsanto district office. CAUTION: The products described in this book are primarily for manufacturing use. They should not be used on the human bodv, either internaflv or externally, until their safety for the use intended is clearly established, and then not unless under competent direction. 26TH EDITH PageS 0663746 TOWOLDMON0006621 WATER_PCB-00003131 MONSANTO -- The Organization Monsanto Chemical Company, founded in 1901 by John Francis Queeny and given his wife s maiden name, today is one of the major American producers of chemicals and plastics. Stemming from broadly diversified chemical raw materials such as coal tar. petroleum, phos phorus. cellulose, salt and sulfur. Monsanto products number in ihe hundreds and find use in virtually every branch of manufacturing industry. The company's five divisions and Canadian affiliate operate four teen plants in North America, and subsidiary companies operate three overseas. Four government plants are in operation or under construction. ORGANIC CHEMICALS DIVISION The Organic Chemicals Divsion is the lineal dependent of the original Monsanto works. To considerable extent, the division's products, too, derive from the research program begun in the firs! days. The original Monsanto product, saccharin, is now one of man> made and sold by the division. Others fall in a wide varietv of classi fications including pharmaceuticals, drug intermediates, dve inter mediates, petroleum additives, flavorings, plasticizers, resins, insect icides and heavy chemicals. The division's largest plant is on the site of the original works at St. Louis. Here are manufactured the fine chemicals, many derived from coal tar, that established Monsanto's earlv reputation, as well as numerous other classes of products. Across the Mississippi River from St. Louis, in Monsanto, Illinois, the Organic Chemicals Division operates a large plant producing heavy chemicals and organic inter mediates. At Norfolk, Virginia, the division operates a plant manufacturing intermediates. Rubber Service Department Monsanto's Rubber Service Department, part of the Organic Chem icals Division, specializes in supplying the needs of one industrv. It provides the rubber industry with many chemicals sucb as accelera tors, antioxidants, mold lubricants, pigments, colors, preservatives, softeners and plasticizers. A modern laboratory is maintained for solving compounding problems. The facilities of this laboratory and the help of its trained and experienced staff is available without cost to users of Rubber Service materials. The Rubber Service headquarters are at Akron, Ohio, in the 26TB BDITtON P.ge7 06837*2 TOWOLDMON0006622 WATER_PCB-00003132 heart of the rubber manufacturing district. The plant is at .Vitro, West Virginia. MERRIMAC DIVISION Monsanto's Merrimac Division, headquartered at Everett Station, Boston, manufactures a diversified line f heavv and industrial chem icals. Included among its products are acids, lacquers, alcohol, sol vents, intermediates, tanning chemicals, commercial gases and lampblack. The division operates thr<e plants, the largest being at Everett Station, Boston. Adjoining this are the facilities of the New England Alcohol Company, a partly owned subsidiary of Monsanto. At Camden, New Jersey, Monsanto lampblack is manufactured. Some of the products of the Merrimac Division duplicate those made at other plants of the company and thus provide an eastern source of supply for Monsanto customers. PHOSPHATE DIVISION The phosphates and other compounds of phosphorus are, as a class, increasing in importance. They are finding use in such varied fields as medicinals, water treatment, dentifrices, soaps, metal treatment, and foods. Operations of Monsanto's Phosphate Division are based on the production of elemental phosphorus at Monsanto, Tennessee. At this location, phosphate earth is dug from large open pit mines and charged into huge electric furnaces where the phosphorus is freed in elemental form. From elemental phosphorus comes phosphoric acid, the parent of the large family of phosphates which are made in the division's other plants at Anniston, Alabama, Carondelet, Missouri, and Trenton, Michigan. At Anniston, in addition to phosphates, those products of the division not derived from phosphorus, such as diphenyl, Aroclors, Santowax, calcium carbide and. aluminous abrasives are made. Head, quarters for the division are at St. Louis. PLASTICS DIVISION Monsanto's Plastics Division has attained a leading position in the new and growing plastics industry. The development of new plastics and their application is a continuing and accelerating process, a fact Page 8 IONS4STO CHEMICALS 0683746 TOWOLDMON0006623 WATER_PCB-00003133 Monsanto, Tennessee, phosphorus furnace plant at night which guides the policies o{ the division from research through pro duction to sales and advertising. Monsanto's plastics operations are consolidated at Springfield. Massachusetts. As a result ol a construction program begun in 1938 there have been several major additions at Springfield, including a plant for the production of Kesinox phenol-formaldehvde resins and molding materials, and the plant of the Shawinigan Resine Corpora tion, a Monsanto affiliate manufacturing vinyl resins. TEXAS DIVISION In 1941 Monsanto was requested by the Rubber Reserve Company, a government agency, to design, construct and operate a plant to manufacture an important raw material for svnthetic rubber. The same year, at the request of the Ordnance Department of the United States Army, the company contracted to operate a major plant for the manufacture ol munitions. The Texas Division was created to operate these two plants. The division makes no products for general sale. CENTRAL RESEARCH DEPARTMENT Research at Monsanto is both a divisional and a centralized function. Each division maintains its own research laboratories--Organic 26TH EDITION Page q 0683749 ] TOWOLDMON0006624 WATER_PCB-00003134 Chemicals Division at St. Louis and Nitro, Phosphate Division at Anniston and Carondelet, Plastics Division at Springfield, and Merrimac Division at Everett. Jn each, the reasearch function is kept separate from other laboratory operations, such as analytical control and testing. The work of the divisional research laboratories is supplemented and augmented by the Central Research Department at Davton, Ohio. It is here that much of the fundamental research of the com pany is carried out. The Central Research laboratories are equipped with the latest type of research aids, including such equipment as the electron microscope and X-ray. The department carries on special investigations in cooperation with the operating divisions ami also carries out studies of an exploratory nature that mav not he related to the company's present products. TECHNICAL SERVICE Each of the Monsanto divisions maintains a technical service staff comprised of qualified personnel who are experienced in the chemical prohlems and requirements of a wide variety of industries. Industrial users of chemicafs are invited to- make use of these men. Their func tion is to provide sound technical counsel on problems relating to the use of chemicals. Plant of the Shawinigan Resins Corporation, Monsanto affiliate 0683750 TOWOLDMON0006625 WATER_PCB-00003135 SOME INDUSTRIES SERVED BY MONSANTO AND PRODUCTS SUPPLIED AGRICILI l HAL M>raives Calcium p|,,mphare. Mi f Sulfate EiTrir Chloride I '-rn.phosphorus I.JliJUffS Muriatic Arid Nitre Cake N ii ric Acid Phnsilage Phosphoric Acid Plastics Sodium Sulfate Sulfur Sulfuric Acid W etting Agent* (Santomerse) APPLIANCES Abrasives Cresol Ferric Chloride Lacquers Lampblack Maleic Anhydride Muriatic Acid Nitric Acid Phosphoric Acid Phlhalic Anhvdride PlaBiics Solvents Sulfuric Acid AUTOMOTIVE Abrasives Acetic Acid Alcohol Aluminum Sulfate Amyl Acetate Aroclors (Chlorinated Diphenyl) Battery Acid Benzene Butyl Acetate Butyl Alcohol CauBtic Soda Chlorine Cresol Diacetone Alcohol Dibutyl Phihalate Diethyl Phthalate Ethyl Acetate Ferric Chloride Ferrophosphorus Lacquers Muriatic Acid Nitric Acid Phenol Phoiph >ric \cid Phlhali Anlmlride Plasties Bone Ash Muriatic Acid Phosphoric \nd Salt Cake Sodium P\ rophosphate, Tetra Sulfuric Acid Rubber Accelerators Wetting Agent Rubber \nti*Oxilants Santicizer ) (Santomerse) Sodium Acetate Sodium Phosphates CHEMICAL Sodium Sulfate Sulfur Sulfuric Acid Tannirq Chemicals Thinner* Trirr> l Phosphate PROCESS Acetic Acid para-Acetv |. \rnino-Ben. zenesulfonerh Inride Alcohol Aluminum Sulfate AVIATION Ammonia, A (pin Abrasiv c Amyl Acetate Alcohol ortho-Anisidine \mvl Acetate Butyl Acetate Butyl A'etate Calcium Pvrophogphate Ethvl A'etate Caustic Soda Finishes Chlorine Lacquer* meta-Cresol Phosphoric Acid ortho-Cresol Plastics para'Cresol Primers Cresylic Acid Solvents Diacetone Alcohol Sulfuric Acid Dinitrorhlorobenzrnr Snrfaoern Ethyl Acetate Thinnen Mersol (Solvent) Methvl Salicvlate CARPET and RUGS Mixed Acid ' Acetic Acid Vlonochlorobenzene Aluminum Sulfate Glauber's Salt Monsanto Salt Muriatic Acid Lacquert Nitric Acid Latex A( celeralors ortho-Nitroaniline Nitre Cake para-Nitroaniline Sodium Bisulfite, ortho-Nitroanisole Anhydrous Nitrocellulose Solution Sodium Phosphate, Tri ortho-Nitrochlorobenzene Sodium Pyrophosphate. Tetra Sodium Sulfate, Anhydrous para*Nitrochlorobenzenr para-Phenetidin Phenol Phosphoric Acid Sulfuric Arid Phosphorus Oxvehloride Wetting Agent Phosphorus Trichloride (Santomerse) Phthalic Anhydride CERAMICS Piperidine Pyridine Salicylic Acid 26TH EDITION Page II 0683751 TOWOLDMON0006626 WATER_PCB-00003136 >a11 Cake Sodium Muininaie Sodium Bisulfite Sodium Pyrophosphate, Tetra Sodium Sulfite Solvents Sulfuric Acid Sulfiiryl (!lilorirlr Thiourea I ri< reey I Phosphate p.irj I nluetu-sulfonamide p.ira-Toluene-.ulf<>n- chloride Calcium Pyrophosphate ('rysalhd ` Methyl Salicylate Plasti Phosplu Acid Bcnznaie DYESTUFF M A.N t FACTLRE Acetic \r d Muminurn Sulfate ortho- Vminndiivhenvl Vniline Oil ' ` .Sodium Bi-ullite Sodium Sulfate Sttlfury I Chloride Thiourea para-Tolucncsulfonaniide para-Toliienestilfnn- chloride para-Tolueuesu Iff mic Acid Wetting and Spreading Agent* (\reskap. " \resket. Vresklene. Sanionierse) W '(line \geu t* COSMETICS AND PERFUMES Mcoliol Benzoic Acid Benzyl Chloride ..... Phosphate, Di Calcium Phosphate, Tri < Rustic Soda ort ho- \ui; idine para- Miisuline Henzotrtrliloride Benzoyl f hloride Benzyl Chloride orilio-Cliliroaniline meta-Chlnroaniline para-Chloi oaniline para-Chloi o-meta-Cresol orlho-Chlnrophenol ELECTRICAL \ro< lors Cable Dope Lacquers Lampblack Nitric Acid Phosphoric Acid Plastics Sulfuric Acid (.onmarin trieia-Cresol Du-ihy l Phthalate Manicure Lacquer Manicure Lacquer Remover Methyl Salirvlate Phosphoric Acid Phihatic Anhydride para-Chloi ophenu! engraving Chlornstilfonic Acid ortho-Chloro-paraToluene Sodium Sulfon Acetic Acid Nitric Acid ate (Monsanto Salt) Perchloride of Iron ortho-Cresol para-Creso1 Cyolohexylamine Dichloroaniline Plastics Sulfuric Acid Wetting Agent (Santomerse) Potassium Py rophosphate. ortho-Dich'Orobenzene . Tetra ' Diohlorophenol FLORISTS AND Salicylic Acid DinitroaniLne FRUITGROWERS \ iicpak Dinitrochloco benzene Ammonia, Anhydrous ^ et ting Agent Glauber's Salt ortho-Dirhlorobenzene H Acid dairy products Mixed Acid oara-Dichlorobenzene Muriatic Acid Ammonia. Anhydrous Ammonium Phosphate. Monochlorobenzene Monsanto Salt Sodium Phosphate, Tri Vuepik Mono Coumarin F'thavan Merclor (Sodium Hvpo- _ chlorite) ` Santamine Sodium Acid Pyro phosphate Sodium Phosphate, Di Sodium Phosphate, Trl Sodium Pyrophosphate, Tetra Sulfuric Acid Vanillin DENTAL PRODUCTS Alcohol Benzoic Acid Calcium Phosphate, Di Calcium Phosphate, Tri Nitre Cake Wetting Agent ortho-Nitro aniline (Santomerse) para-Mtroaniline ortho-Nitro.anisole FOOD ortho-Nitroehlorobenzcnr Ammonium Benzoate meta-\itro< hlorobcnzene Renzoic Acid L . S. P. ara-Nitrcchlorobenzene Calcium Phosphates R itrodiehlotobenzene ortho-Nitrophenol para-Nit ropbenol Oil of Vitriol Calcium Pyrophosphate Calcium Sulfate Coumarin .Monsanto Dry Ice ortho-Phent tidin Etnavan para-Pheneiidin Phenol Phosphoric Acid Ferric Phosphate Methyl Salicylate Muriatic Acid Phosphorus Oxychloride Phosphoric Acid Phosphorus Trichloride Phthalir Anhvdride Sodium Acei ate Sodium Acid Pyro phosphate ' Phosphoric Acid Paste Saccharin Monsanto Sodium Acid Pvro- phosphate Sodium Benzoate l.S.P. Page 12 Ml NTO CHEMICU.S 0683752 TOWOLDMON0006627 WATER_PCB-00003137 Sodium Bisulfale Sodium Phosphate, Di Sodium Phosphate, Mono Sodium Phosphate, Tri Vanillin Monsanto GLASS AND VIT REOUS WARE Abrasives Hone Ash Chlorine Muriatic Acid Plastics Salt Cake Wetting Agent (Santomerse) INSECTICIDES Cresol Dibutyl Phthalate ortho-Dichlorobenzene rara-DicHlorobenzene Methyl Salicylate Sulfur Trichlorobenzene Wetting Agent (Santomerse) LAUNDRY Chloramine T Chlorine Merclor (Sodium Hypochlorite) Sodium Bisulfate Sodium Bisulfite Sodium phosphate, Tri Sodium pyrophosphate, Tetra Wetting Agent (Santomerse) Sodium Sulfide Sulfuric Acid Wetting and Spreading Agents, (Areekap, Aresket, Aresktene, .Santomerse) LEATHER AND TANKING Aluminum Sulfate Ammonia, Aqua Belt Cement Caustic Soda para-Chloro-cneta-Crcsol para-Chloro-meta-Xylenol ortho-Dirthlorobenzene Dopes Glauber's Salt Lacquers Lampblack Merclor (Sodium Hypochlorite) Mertanot (Syntan) Muriatic Acid Permacol Phenol Salicylic Acid Santotap (Basic Chrome Sulfatt) Sodium pisulfate Sodium Bisulfite, Anhydrous Sodium phosphate. Di Sodium Sulfhydrate LUMBER Lacquers Permasan Santobrite Santophen 20 METALS Abrasives Ammonia, Aqua Bone Ash C. P. Acids Caustic Soda Cresylic Acid Ferrisul (Ferric Sulfate) Ferropboephorus Hibitite Inhibited Acids Mixed Acid Muriatic Acid Nitric Acid Phosphoric Acid Sodium Phoaphate, Di Sodium Phoaphate, Tri Sodium Pyrophosphate, Tetra Sulfuric Acid Wetting Agent (Santomerse) Zinc Chloride Solutions New baking laboratory at Carondelet for research and testing of phosphates for food products. 0683753 TOWOLDMON0006628 WATER_PCB-00003138 Inspecting safety valves on tbe electrolytic chlorine cells at Monsanto, Illinois. MINING Abrasives Dane Ash C. P. Acids Flotation Agents (Xanthates) Nitre Cake Sodium Sulfide Sodium Sulfiie - OIL REFINING Caustic Soda Chlorine Creeds Muriatic Acid Phenol Phosphoric Acid Santolubea Sautopoid Santopour Sulfuric Acid PACKAGING Cast Phenolic Resin Cellulose Acetate Cellulose Nitrate Lacquers Polystyrene Santicfzer-8 Yuepak PAINT, V ARNISH AND LACQUER Amyl Acetate Antioxidants Benzoic Acid Butyl Acetate Cotton Solutions Diacetone Alcohol Dibutyl Phtl.alate Diethyl Phtbalate Dimethyl Phtbalate Ethyl Acetate Lampblack Maleic Anhydride Mertec (Chlorinated- Rubber Base Paint) Monochlorobenzene Paint Anti-SLinmng Materials Phenol Phthalic Anhydride Resins Santicizers (Phthslyl Clycollates and other Plasticizers) Santolites (Resins) Santomask (Deodorant) Solvent Alcohol (Mersol) Thinners Tricreayl Phosphate Triphenyl Phosphate PAPER Alcohol Aluminum Sulfate, Com mercial and Iron Free Ammonia, Anhydrous Ammonia, Aqua Benzoic Acid Bone Ash C. P. Acids Chlorine Coumarin Dibutyl Phthalate Ferric Sulfate Ferrisul Lacquers Muriatic Acid Page 14 MONSANTO CHEMICALS 0683754 TOWOLDMON0006629 WATER_PCB-00003139 Sail Cake Santicizers (Specialty Sulfuric Acid Santicizers plasticizers) Wetting Agent Santobrile Santolile* (Svnthrlir (Santomerse) Santnlite* resins) Santosite Thiourea TEXTILES Sodium Aluminuic Tricresyl Phosphate Acetic Acid Sodium Bisulfalc Triphenyl Phosphate Alcohol Sodium Bismlfiip. V uepak Aluminum Chloride Sodium Hypochlorite Sodium Phosphate, Tri Sodium Sulftae POWER AND Ammonium Phosphate, POWER PLANTS Mono Ammonia Siidnim Sulfite Aluminum Sulfate Amyl Acetate Sulfuric Acid ChUiriue Butyl Acetate Trivresy I Phosphate or I ho-Die hlorobenzene Calcium Phosphate, Tri Wetiinc Agenl* Ferrisul Calcium Sulfate PHARMA Santobrile Caustic Soda CEUTICAL Vceianilid L . S. I*. Aoelonhenelidin L. S. P. Acetyl Salicylic Acid (Aspirin) Benzoic Acid U. S. P. Santophen Santosite Sodium ^lumiuute Sodium Phosphates Sodium Sulfate PRINTING INKS Chlorine Cresol Dibutyl Phthalate Ethyl Acetate Ferric Sulfate Glauber's Salt Caffeine U. S. P. Calcium Phosphate, Di Aluminum Chloride Aluminum Sulfate Lacquers Merclor Chloral Hydrate V. S. P. Chloramine-T U. S. P. Dichloramine-T N. F. Clvieropbosplmle# Antioxidants Anti-Skinning Agents Aroclors Coumarin Mixed Acid Nitrate of Iron Nitre Cake Oil of Vitriol Magnesium Phosphates. Lampblack Plasticizers Mellivl Salirvlale U.S.P. Methyl Salicylate Potassium Pyrophos Phenol U. S. P. Nitrate of Iron Phenolphlhalein U. S. P. Phenol phate. Tetra Santobrile Phosphoric Acid Santocel Santophen 20 Potassium Ammonium Phosphate Santomask Sodium Aluminate Sodium Acetate Sodium Acid Pyro Potassium Phosphate, Mono Saccharin U. S. P. Salicylates Salol Sodium Benzoate U, S. P. Sulfanilamide U. S. P. PLASTICS AND RUBBER Accelerators Antioxidants Caustic St>da Cycline Oil Piperidint Sartobrito Sodium Sulfite phosphate Sodium Bisulfite Sodium Phosphate, Di Sodium Phosphate, Tri Sodium Pyrophosphate, Tetra Sodium Sulfate Sodium Sulfite Sopet SYNTHETIC Softeners Sulfuric Acid RESINS Ammonia, Aqua Benzoic Acid, Technical Sulfur Sulfuric Acid SOAPS AND Tricresyl Phosphate Wetting Agent (Santomerse) Cast Phenolic Resin Cellulose Acetate DETERGENTS Antioxidants WATER Cellulose Nitrate C. P. Acids TREATMENT Cresols Calcium Sulfate Aluminum Sulfate Dibutyl Phthalate Caustic Si*da Ammonia, Aqua Diethyl Phthalate Chlorosulfonic Acid Chlorine Dimethyl Phthalate Coumarin Ferrisul (Ferric Sulfate) Maleic Anhydride Cresol Santobrite Monsanto Plastics Phenol Santosite (Reducing Phenol Soda Ash Agent) Phthalic Anhydride Sodium Phosphate, Di Sodium Aluminate Polystyrene Sodium Phosphate, Tri Sodium Hypochlorite Polyvinyl Acetals Sodium Pyrophosphate, Sodium Phosphate, Di Resinox (Phenol* Tetra Sodium Phosphate, Tri Formaldehyde) Sopanox Sodium Sulfate 26TR EDITION Page 15 0683755 TOWOLDMON0006630 WATER_PCB-00003140 0683756 TOWOLDMON0006631 WATER_PCB-00003141 ACCELERATORS- MONSANTO PRODUCTS ABRASIVES (See Aluminum Oxide Abrasive Grain). ACCELERATORS, RUBBER _______________ > i >iJi\ -lit.il jcrelera!<irt below for perificyti<ms ami properties. It.lt. ( lus-ificuturni Rubber Accelerators NOlRN. Available Literature; \|oii>uiiio (Iheinicals for the Rubber Industry," 12 pages. "Latex Compounding." 36 page,. 'Rubber Compounding for the W ire Industry," 18 pages. "Sanlocnre-- Vn Accelerator for Rubber \ ulcanixatinn," 52 pages. **A-10"___________ Specifications! Condensation product of aniline and formaldehyde. It is neither metlnlene dianilide nor formaldehyde aniline, but probably a mixture in which the latter product predominates. White or yellowish tinted powder; 95 per cent through 200 mesh and 99 per cent through 100 mesh; loss on healing less than 5.0 per cent when heated for two hours at 105'C.; m.p.. begins to soften at 120*C.: *p. g. 1.17; tincombined reagents, no excess of free aniline and not more than traces <>f formaldehyde. -v-l *)" Specifications: Formaldehyde dematite of a condensation product of aniline and acetaldehyde, of complex chemical composition. Brown resinous powder; in p. between "o'C. and 85C.; sp. g 1.17. w-ar._______________________________________________ .. Specifications: Reaction product of buiyraldehyde and butylidene aniline. The chemical structure of such prt-durts is necessarily complex. Red yellow to orange brown oily liquid, slightly turbid when cold; sp. g. 0.98; flash point soluble in bensene, chloroform, acetone and solvent naphtha. Specifications: Light tan powder; constant composition blend of Santocure and HI Sixty. :nTH eniTio> Page 17 0683757 TOWOLDMON0006632 WATER_PCB-00003142 "A-77"_____________________________________________________________ Specifications! Condensation product of aretaldehide and aniline by a special Monsanto process. Such produos, known an aldehyde derivatives of SchifT* are of complex chemical composition. Free flowing reddish brown liquid; p. g. I.Dl: Ha>h point 55 C'.: soluble in benzene, chloroform and acetone; partly -iilntile in alcohol and gasoline. v-umi" Specification*! Aldehyde derivative of a Si-luffs base made with the use of both Uutyraldehyde. ami acetaldehyde. Dark reddish brown oily liquid; sp. g, MU: Hash point 85C.: soluble in benzene, chloroform, acetone and solvent naphtha. [ UBLT.VSAN" (Zinc Salt of Dibutvl Dithiocarbamic Acid)____ 2 ^ Specification*: Cream colored powder; sp.g., 1.21: melting point, 106C.; cur ^ at temperatures below 100C. ^ General Information! 0.5% to 1 % on rubber weight used in latex, cements, r^j for dipped goods, adhesives, coalings, etc. 2 DPG (Diphenylguanidine) Specifications! White powder, not darker than the approved color standard: no residue on 100 mesh screen; m. p. not less than 146C.; sp. g. 1.19; strength, 00.0% min. of DPG by acidimetrio titration: soluble in alcohol, benzene, chloro* form and ether; very slightly soluble in water. *'EL SIXTY" (Dibenzothiateyldimethylthiol urea) Specifications t A light cream colored powder; 99.5% min. through 200 mesh, no coarse particles; m.p. 220C. min.; sp. g. 129; very slightly soluble in acetone, alcohol and chloroform; slightly soluble in hot pyridine or orthodichlorbenzene. "ETHASAX" (Zinc Salt of Diethyl Dithiocarbamic Acid)___ Specificationst White powder; sp.g , 1.5*, melting point, 173C. General Information! 0.5% to 1% on rubber weight used in latex. Page 18 MONSANTO CHEMICALS 0683758 TOWOLDMON0006633 WATER_PCB-00003143 "Gt'ANTAL". Specifications: Ester formed by reading two molecules of diphenylguanidine and one molecule of phthalic acid; contains one-half mole of water of crystalliza tion. White powder ranging from blue white to faint gray; 99.5% min. through 201) tnrsli, no coarse particles; m. p 178C. min.; sp, g. 1.20; soluble in alcohol; insoluble in benzene and gasoline. "METHASAN** (Zinc Salt of Dimethyl Dithiocarbamic Acid) Specifications) White powder; sj .g.. 2.00; melting point, 219C.; cures at temperatures below 100aC. General Information: 0.5 to 1% on rubber weight used in latex and cements. PIP-PIP (Piperidine-pentamethylene Dithiocarbamate)_____ V) Specifications: Fluffy, cream colored powder; 98.0% min. through 200 mesh sg and 99.5 per cent through 100 mesh; m p. over 160C. at time of shipment. p Decomposes slowly in the presence of water and during storage with a corre p sponding drop in melting point. Sp. g. 1-13; soluble in alcohol and solvents con taining water. Si "R-2M CRYSTALS Specifications: Reaction product of carbon bisulfide with methylene dipiperi dine. Light brown coarse cryitallin* solid; sp. g. 1.11; m. p. between 50C. and 60C. "SANTOCURE"--------------- ----------------------------------------------------- Specifications: Condensation product of mercaptobenzothiazole with cyclohexylamine. Light tan or buff colored powder; 99.5% min. through 200 mesh; m.p. 90C. min.; sp. g. 1.27. Available Literature! S2-page booklet, "Santocure--An Accelerator for Rubber Vulcanization.'* "TACKOL" Specifications: Standardized, uniform blend of resins and oils. Viscous brown liquid. Odor is distinctive coumarone-like; sp. g. 1.0$; flash point 160C. 26TH EDITION Page 19 0683159 TOWOLDMON0006634 WATER_PCB-00003144 ACCFI FKATORS General Information! f sed a* a softener or talk producer in rubber. Available Literatures 42*page booklet: "Monsanto Chemicals for the Rubber Industry." THIOCARBAMLIDE Specifications: While powder. not darkrr than the approved color Mjntiard; 'I'l.u' 0 min. I lirmifxli 100 inenh, no ch rse partidea: ill. p. not trs (Han I *ji. jj. 1.12: insoluble in water and Many other common -Iverits; soluble in alcohol. THU'RAD*' (Tetramethyl Thiuram Disulfide) --___________ Specifications: Sp.g., 1.29; melting point, 116 l UiC.; color, white; odor, none; soluble in carbon bisulfide, benzene a'nd chloroform; insoluble in water, dilute caustic and gasoline. `TREKA1 Specifications! Constant composition blend of diphenylguanidine and 2, t* dinitrophrnyi tliiobenzoihiazole. Uniform light yellow powder; 99.5% min. through 200 mesh, no coarse particles; m. p. between 117C. and 127C.; sp. g. 1,25; soluble in alcohol and chloroform. "l REKA BLEND B" Specifications! A blend similar to "l reka" with a portion of the "DPG" re placed by "Ciiantal." Yellow to brownish powder; 99.5% min. through 200 mesh, no coarse particles; m.p. 130C. min.; sp. g. 1.33. "UREKA C" (Benzothiazylthlobenzoate) Specifications; An acyl-thiazole powder in which (be acidic hydrogen atom of mercaptobenzothiazole has been replaced by a benzoyl group. A pale ivory or yellowish powder: 100 per cent through 30 mesh: m.p. not less than 115C.; __ sp. g. 1.43; soluble in chloroform and benzene: slightly soluble in alcohol. ACETAN'ILID, U.S.P. NHCOCH* Mol. Wt. 135.16 Fage 20 Standard Forms: Crystals, powder. {Continued) MONSANTO CHEMICALS 0683760 TOWOLDMONOOQ6635 WATER_PCB-00003145 Specifications: White crystals or powder; ash 0.05% max.; conforms to I'.S.P. tests for carbonizable impurities ami heavy metals; solubility in ethvl alcohol 05%, complete; m.p. 11 V.OeC. min.; no cry stala retained on l V mesh; 3.0% mat. powder retained on 80 mesh. H.l{. Classification: Vceianilid. General Information: i'harmai eutical product. ACETIC ACID - CHjCOOll Grades: 56% CjIItOj: sp.g. 1.06?; freezing point --8.0CF. 70% CjIIjOj: sp.g. 1.074; freezing point -H'.6F. 80% QH,0j: sP-g- 1 076; freezing point -j- IT. tF. 81% CjI!40j: sp.g. 1.075; freezing point +27.3F. Glacial: 90% C}lf,Oj; sp g. 1.0576; freezing point +58.3F, K.K. Classification! Acetic Acid. Ceneral Information! L sed in dyeing where a weak acid is required in the dye bath; in the manufacture of acetate solvents; manufacture of cellulose acetate: and in the formation of oi her acetates, such us aluminum, lead, sodium, and ammonium acetate. Also used in manufacture of fish glue: as an antichlor: coagulation of rubber latex: destruction i f fungi; disinfectant in gelatine: pickling foodstuffs; giving added detergency and firmness to soap; stabilizing olive oil; protecting seedlings from injury due to root rot and damping off; hardening and developing solutions for photographic films. (See table in general data section) ACETONE C. P. Typical Analysis; Water white liquid; non-volatile matter, not more than 0.001 gram when 100 cc. are evaporated and heated to constant weight at 10UC. to 110C.; water solubility, miscible with distilled water in all proportions; dryness, no turbidity when une volume is mixed with 19 volumes of 60B6. gasoline at 20C.s sp. g., 0.791 to 0.793 at 20C , 20C.; ccidity, less than 0.002%, calculated asCOj.; purity, 99-100% dimethyl ketone; potassium permanganate test, color of added potassium permanganate retained at least two hours when 1 cc. of a 0.1% solution is added to 100 cc. of Acetone; chlorides, none; iron, none; odor, mild--non-residual; flash point, -- i8C. (--0.4F.); wt. per I'.S. gal., 6.S9 lbs. at 68F. R.K. Classification! Acetone. General Information! Acetone it< faster drying than ethyl acetate and a more active solvent. It is an important constituent of quick-drying water proof ce ments; an active solvent for celluhiee acetate; a good dye solvent; resin solvent used extensively in paint removtrs and cleaners and for various extraction, processes. 26TH BDITION Page 21 0683761 I TOWOLDMON0006636 WATER_PCB-00003146 ACETOPHENETIDIN, U.S.P NUCOCH, Mol. Wt. 179.11 Standard Forms; Crystals; powder. SpccificationasWhite crystals or crv*talline powder; Solubility in elliyl alcohol "Vo (1:13), completes m.p. 13S.0C. min.; ash .05% max. No crystal# retained >n 1 4 mesh screen; 5% powder retained on 100 meeb. K.K. Classfication: Chemicals NOlhN. General Information i Pharmaceuiii al product. paro-ACETYL-AMINO-BENZENESULFONECHLORIDE_____ NHCOCH* 0 so,a Mol. Wt. 233.59 Standard Forms Crystals. Characterislicss Light tan to brownish powder or fine crystals; assay, 97.5% K.R. Classification Chemicals NOI8N. General Informations Used as to intermediate in the manufacture of eulfa drugs. ACETYL SALICYLIC ACID, U.S.P. (Also known as Aspirin) COOH 0OCOCH, Mol. Wt. 180.06 Standard Format Crystal#, 20 mesh Crystal*. 40 mesh Powder, 80 meah Specifications t White crystals or poyder; assay 99.5% min.; solubility in ethyl alcohol 95% (1:5), complete; solubility in 10% NajCOs(l:20), complete; ash, 0.05% max.; conforms to U.S.P. test for heavy metals, earbonizable impurities, resinous products, chloride, sulfate, apd free salicylic acid. (Continued) Page 22 .NTO CHEMICALS 0683762 TOWOLDMON0006637 WATER_PCB-00003147 Retained on-- JO modi screen .50 infill screen 10 mesh screen 45 mesh screen 50 mesh screen 2U-mesh 10-mesh Trace man. 5.0% min. 10.0% min. 45.0% min. 60,0% man. Trace max. 80-mesh 60 mesh screen HO mesh screen Thru-- 100 mesh screen 140 mesh screen 70.0% min. 85.0% max. 15.0% min. 60.0% max. 10.0% max. 25.0% max. R.R. Classification! Acetyl Salicylic Acid. General Information! Pharmaceutical product. 2 0' ACETYL SALICYLIC ACID, Starch Granulations Standard Format 10%,, 12-50 mesh, while 16%, 12-50 mesh, white 20%, 12-50 mesh, w'hite 10%, 12-50 mesh, pink 10%, 20 mesh, pink 10%, 12-50 mesh, green 10%, 20 mesh, green Specifications: (Made with Acelvl Salicylic Acid L'.S.P.) White, pink or green granules. Assay: starch granulation 10%, 00.0% min. 91.0% max.; starch granulation 16%, 84.0% min. 85.0% max.; starch granulation 20%. 80.0% min. 81.0% max. Free salicylic acid conforms to L.S.P. test on Acetyl Salicylic \oid. UF.SH: Retained on-- 12 mesh screen 14 mesh screen 16 mesh screen 20 mesh screen Thru-- 40 mesh screen 26TH EDITION 12-50 mesh Trace, max. 5.0% min. [5.0% max. 20.0% min. 115.0% max. 60.0% min. 5.0% max. k0.0% max. (Continued) 20-mesh Trace, max. Page 23 0683763 TOWOLDMON0006638 WATER_PCB-00003148 ILK. Classifications Acetyl Salicy I ic Acid. General Informations Pharmaceutical product. ACID CALCIL'M PHOSPHATE (See CaWmn Ph,phate. Mono). VIBCRAFT FINISHES ______ _ Commercial Finishes: Vircraft finishes include protective and decorative coatings for every part of the aircraft structure, such as fabric dopes (clear and colors) for wines, control snr. faces and fusilage; primers, gurfacers and lacquers for aluminum and dural sheet; Hume-proof dopes for interiors, thinners, cleaning solvents. Properties of the com mercial finishes in application conform to the best modem plant practice, and properties in service meet the severe requirements of resistance to stress, sea water corrosion, weather, gas and oil. Monsanto finishes have for years been accepted as standard by manufacturers and airlines. CODE NO. TYPE OF PRODUCT For Fabric--Dopes l.-AW l L-1031 L-2194 L-760 L-3193 L-3195 I.-2591 Cleae Nitrate Dope (high solids) Clear Nitrate Dope (medium solids) Clear Nitrate Dope (comm, grade) Fully Pigmented Dopes--all colors; non-bleeding reds; matt, resist. ance to fading and chalking. Interior Fire-Resistant Clear Dope Interior Fire-Resistant Pigmented Dopes--all colors. Finish Reclaimer (Rejuveru tor) for Nitrate Dope For Metal--Primers, Surfacers, and Lacquers R-4017 Yellow 728 Zinc Chromate--Fa*t Drying. R.4063 Cray 578 Synthetic Primer Surfaces--Slow Drying. R -3552 Gray 423 Lacquer and Dope Surfacer. L-2939 Clear Aluminum Vehicle. K-3785 Fullv Pigmented Lacquers--all colors (except light shades); non. bleeding reds; mast, resistance to fading. 1,-1518 1.. 1087 1..2680 L-3196 L40S4 Page24 Thinners (Reducers)--All Types Standard lacquer and dopethinner. Retarder (anti.blush) Brush wash for general cleaning. For fire-resistant (acetate). Wax-free reuiover (dope and lacquer). (Continued) Monsanto chemicals 06831<>A TOWOLDMON0006639 WATEFLPCB-00003149 . Virnt> and Navy Specification f inishes-. I'amnuHage linislic* for ......that aircraft *ci-e added in the Monsanto line rarU in the Defense Program. These finishes are in addition to the original l\ $, Arniv ami l. S. Navy ,penlicaiinn materials of which Monsanto lias long been an approved supplier. Finilies umjer the new combined Ar. / and Navy specifiralions (WTT) are now available. \ \ .T r-i'-<> ><> \\.| I I .'.I wn-D-ooi Hill) \l -IX'.V Metal Surfaces Zinr Chromate Primer. Gloss Lacquer * :lor. (dear Aluminum Hrm\w Vehicle. Armv Camouflage Colored Lacquers. Navy Camouflage Colored Lacquers. fabric Surfaces VN-TT-D-5U \\-TT-l)-.V>6 V \ -TT-U-554 I 1106 M-198 Clear Dope. Semi-Pigmented Colored Dopes. Ftilly-Pigmemed Colored Dopes. Army CamoulUge Colored Dopes. Navy Camouflifge Colored Dopes. Thinners \ N'-TT-T.256 For use wit h above lacquers. ANNTT.T-258 Blush Retarder for above lacquers. U.U. Clasei&cationt Lacquer. ALCOHOL (See Ethyl Alcohol). ALKYL PHOSPHORIC ACIDS Properties! Amvl Phosphoric Acid (from Pentasol): fluorescent reddish amber liquid; sp.g., 1.33 at 25C'C.; alkv I acid content, approx. 99%.* n-Butyl Phosphoric Acidi fluorescent reddish amber liquid; sp.g., 1.24 at 23C.: alkyl acid content, approx. 99%.* Ethyl Phosphoric Acid) pale straw colored liquid; sp.g., 1.33 at 2SC-; alkyl acid content, apptox. 97%,* Methyl Phosphoric Acidi pale straw colored liquid; *p.g., 1.439 at 25C.; alkyl acid con tent, approx. 97%.* n-Propyl Phosphoric Acidi reddish amber liquid; sp.g.. 1.30 at 25aC.: alkyl acid content, approx. 97%.* * Balance of assay is ortho-phosphoric acid and unconverted alcohol. R.R. Classification! Phosphoric Acid. (Continued) !6TH EDITION Page 25 0683765 TOWOLDMON0006640 WATER_PCB-00003150 General information: The Alkyl Phosphoric Acids are mobile liquids which ran be neutralized with alkalis and amines with resultant water-soluble salts. The methyl, ethyl and propyl phosphoric acids are water-soluble, but the butyl anil amyl arid* are not. The salts of all are water-soluble. The methyl and riIn I plio>phnric acids and [heir salts a^e very hygroscopic (amine, sodium and pnijssinm sails) uhcreus the propyl, bi tvl aril arnyl acids are not hygroscopic and their salts only .lightly so. Alkyl Pli*|iiinrir Acids are used in textile and paper processing compounds; a. email -is mi urea n >in formation; as poly merizing agents for resins and oils. ALUM (See Aluminum Sulfate). ALUMINUM CHLORIDE AljCl* Mol. Wi. 266.7 Standard Forms: Liquid. 32a BA, Sfr% ALC1-H2 H O approx.; crystals. 97% Al.-Cls + 12H:0 approx. Typical Analysis: Neutral salt, low in ron content. Solutions have an acid re action but contain no free acid. Typical analysis as follows: Crvstal Liquid Al:CU - 12 H:0 97.2% 50.3% AhOi 20.5 10.6 C) 42.7 22.1 Fe .003-.00S .005 K.K. Classifications! Aluminum Chloride Dry or Aluminum Chloride Liquid. General Information i Used in carbonizing fine wool such as piece goods, raw slock or shoddy, resulting in an exceptionally white, lofty wool. Also in car bonizing colored goods where it has vety little stripping action. Used in soap manufacture for treatment of glycerin lyes where chloride of alumina is more desirable than sulphate. (See table in general data section) * Crystals: Resale product. ALUMINUM OXIDE ABRASIVE GRAIN (Also known as fused aluminum oxide; artificial corundum.) Specifications: Fused aluminum oxide containing 95-99% AljOj; hardness 9.6, Moh's scale. H.H. Classification*! Abrasive flour or grain. General Information: Coarse to flour grades are available for grinding wheels, polishing, refractory purposes, and for ariti-slip or tread use. Page 26 I ON SA N TO CHEMICALS 0663766 TOWOLDMON0006641 WATER_PCB-00003151 ALUMINUM SULFATE, COMMERCIAL A1,(S04),. 14.5 H,0 Standard Formi Fine to lump. Typical Analyaisi AIjO*, 17.2%; FeO, 0.35%; FejO,. 0.01%. K.K. Classification! Aluminum Sulfate. General Information! Used in paper sizing and water treatment. Monsanto also provides a slab form (6'x6*sl8') foe stock solutions; this form contains 15.5 16.0% AljOj. (See taWe in general data section) ALUMINUM SULFATE, IKON FREE___ A1,(S04)j. 14.5 HjO Standard Formi Fine to lump. Typical Analysis] A!*Oj, 17.2%; FejOj, 0.01%. R.R. Classification] Aluminum Sulfate. General Information! Used in sizing fine papers; manufacture of satin white and dry colors; tanning white leathers; dyeing operations. orfho-AMINODIPHENTL, TECHNICAL (Also known st 2*ammobipbenyl.) NH, Mol. Wt. 169.10 Standard Formi Fused solid. ' Specifications! Purplish crystalline mass; crystallising point 47.0eC. min.; assay 94.5% min. Distillation range: first drop, 29S.04C. min.; 95% (1-96 ml), 8.0'C. max.; dry point, 310.0*C. mav. R.R. Classification] Dye Intermediate. General Information] Used as an intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes: in the synthesis of rubber products; as a solvent. CAUTION: Thu product ii toxic. Avoid breathing it* vaport and avoid contact with the thin. 26TB EDITION Page 27 0683767 TOWOLDMON0006642 WATER_PCB-00003152 poro-AMINODIPHENYL, TECHNICAL (Alto known as 4-aminobipbenyl.) <( y - ( NH. Mol. Wt. 169.10 Standard Forms Fused solid. Specifications! Yellowish brown crystalline mass: crystallizing point 50.5C. min. Distillation range: First drop. 325.0eC. min.; 95% (1-96 ml), 8,0C. max.; iJrv point. 3t0*C. max. K.K. Classifications Dye Intermediate. Ceneral Informations L'sed as an intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes; as a solvent. CAUTION: Thi$ product is toxic. Avoid breathing its vapors and avoid contact ivith the skin. 2-AMINOTHIAZOLE_____________________________________ HC--------S II I HC^ /C--NHs Mol. Wt. 100.14 Standard Forms Crystals Characteristic*! Light brown crystals. R.R. Classifications Chemicals NOIBN. General Informations Used as an intermediate In organic synthesis. AMMONIA, ANHYDROUS Propertiesi At normal temperatures and pressures Ammonia Anhydrous is s colorless gss. 0.597 times as heavy as air. It is readily condensed by the ap plication of pressure below 268F. to a colorless liquid weighing 5.33 lbs. per gal., and having a boiling point of -- 28F. R.R. Clasaifieations Anhydrous Ammonia. General Information t Ammonia Anhydrous is used in refrigeration; as a con* densing agent in the formation of pbeaoUormaldehyde retina; in water treatment in connection with chlorine; partial neutralization of phosphate fertiliser; in vulcanization of rubber; nitriding of steel; ts a neutralising agent after carbon* izing; neutralizing excess carbon dioxide in water supplies; neutralizing and deodorizing rubber goods which bav# been cured with sulfur chloride; neutral* izing petroleum stocks before crackling; as a relatively inexpensive source of hydrogen or nitrogen; and as a solvent. (See table in general data section) Available Literatures Leaflet: "Monsanto Ammonia for Refrigeration.'' Page 28 MONSANTO CHEMICALS 0683768 TOWOLDMON0006643 WATER_PCB-00003153 AMMONIA, AQUA NHiOH Mol. Wt. 3S.0S Standard Forma: Commercial Aqua Ammonia 16. 18. 20. 26 B6. Propertiesi Pungent, water white liquid; wt. per gal. 7.48 lbs. (26s). K.K. Classifications Ammonia Aqou. General Information t Uses--1. Partial neutralization of phosphate fertilizers. 2. General household cleaning purposes. 3. As a condensing agent in the forma tion of phenol-formaldehyde resin*. 4. As sn anticblor. 5. After carbonizing, as a neutralizing agent. 6. Neutralization of excess carbon dioxide in wster supplies. 7. Neutralizing and deodorizing rubber goods which have been cured with sulphur chloride. 8. Neutralizing goods which have been dyed with aniline black. 9. Pre serving rubber latex. 10. Neutralizing oil before cracking. 11. Silk degumming. 12. Manufacture of cuprammoniqm silk. 13. As a solvent. 14. As a dehairing agent for bidet. 15. For reeling iil,k> 16. As a penetrant in wetting back crusted tanned leather. 17. As a penetrant for driving in fat liquor in leather making. (See table in general data section) AMMONIUM BENZOATE Mol. Wt. 139.15 Standard Formi Powder. Specificationst Fine white crystalline powder; assay 98,0% min.; solution in water (1:10) clear. R.R, Classifications Chemicals NOIBN. General Informations Used as s preservative. AMMONIUM ETHYL PHOSPHATE (Mixture of mono- and diethyl ammonium phosphates). Standard Formi 75% eolation is water. Properties: Water.white to yellow-tinged liquid of ommoniacal odor; ap. g. 1.23 at 25'C.; wt. per gal. 10.37 lbs.: pH 75% sol.; 7.0 - 7.2: viscosity at 25'C., 60 centipoiaea. Chemical constitution: 67% mono ethyl ammonium phosphite: (Continued) 26TB BDITION Page 29 0683769 TOWOLDMONOOQ6644 WATER_PCB-00003154 53% di ethyl ammonium phosphate. In thin film is liquid at relative humidities above -10%; not stable to heat; when subjected to elevated temperatures for any length of time as a solution or while on any article, will liberate ammonia with a reduction in pH; at temperatures below 1 SC. crystals will form in the solution and will dissolve with a rise in temperature or on dilution. I(.lt. Classificationi Ammonium Phosphate. (General Information i Used as flame proofing agent for paper, textiles, wood and other combustible materials. AMMONIUM HYDROXIDE C, P. __ NHOH Mol. Wt. 35.06 specificationsj Colorless liquid, free Irom suspended matter; strength (\Hj) 28.0% min.; nonvolatile matter 0.005% max.; carbon dioxide (COj) U.|,'>2% max.; total sulphur (as SO,) 0.0003% dux.; chloride (Cl) 0.00005% max.; pyri dine, to pass A.C.S. test; substances reducing (KMoO;), to pass A.C.S, test; iron 0.0001% max.; heavy metals (as !<ad) 0.0005%. R.R. Classification* Chemicals, Ammonia. General Information* Laboratory reagent. AMMONIUM PHOSPHATE, Dl (Also known as dismmonmm hydrogen phosphate, secondary ammonium phos phate, and ammonium phosphate di-basic.) (NH4),HP04 Mol. Wt. 132.068 Cradeai Food (meets all U. S. Pure Food Law requirements); special grades supplied on request. Properties* White crystalline material, stable in air and very sotuble in water; pH value of 1% solution, 7.75, At temperature* above 70C. aqueous solutions lose ammonia readily. Dissociation Pressure; According to Britxke and Dumajew (Cmelin's Handbuch der anorganiscbe Chemie, Anunoniak, p.423) and Warren (JA.CS 49,1904, l92T)i Temp. C. 98 111 125 135 147 p NHS in mm. Hg. 3.2 10.7 26.0 55.2 123.4 R.R. Classification* Phosphate of Ammonia. General Information: Used as a fire retardant in fire-proofing and as a yeast food by yeast producers and breweries. Page 30 IONSANTO CHEMICALS 0683770 TOWOLDMON0006645 WATER_PCB-00003155 fi $ o/P'emmot MiUK mmoe PhetjA9t 4 fi 43 L s\ 1 | n AMMONIUM PHOSPHATE, MONO (Also known as ammonium arid phosphate, primary ammonium phosphate, ammonium dihydrogen phosphate, ammonium phosphate mono-basic, am monium biphosphate). NH,H,P04 Mol. Wt. 115.04 Gradesi Food grade meets all U.S. Pure Food Law requirements. Special grades will be supplied on request. Properties: A white crystalline material, stable in air and soluble in hot and cold water; pH of 1% solution, 4 7. R.R. Classification! Phosphate of Ammonia. General Information i Used as a retardant in fireproofing and paper special ties, for special medicinal purposes, in the production of woven belting, and as a yeast food. AMMONIUM SALICYLATE N.F. (See Salicylates). AMYL ACETATE_______ ____________________________________ Typical Analysist Water white liquid; odor, no residual; sp. g. 0.865 0.870 at 15.5C.; shipping wt, per gal., 7.7*0 lbs.; acidity, lest than 0.01% as free acetic acid; dryness, mixes with petroleum benzine in all proportions without turbidity. Boiling range: below 110C., non<; above 130C., less than 50%; above 150C., none. Ester content, 85-90%. (Continued) 14TH EDITION Page 31 0683771 TOWOLDMON0006646 WATER_PCB-00003156 R,R. Classification: Amyl Acetate General Information! Used as a nitrocellulose solved. It is less active than ethyl or butyl acetate and more resistant to moisture. Blends of all three with appropriate diluents such as alcohols (ethyl, but>l, and amyl) yield thinners and solvent mixtures of excellent cutting power, moisture resistance, good Bow ar.d leveling, and conipatabiiity with various resins and oils. Used in the artificial leather industry and in formulating lacquer finishes for wood, metals, textiles, ami paper. Ail) L PHOSPHORIC ACID (See Alkyl Phosphoric Acids). ANILINE OIL_______________________________________ ( Man known as aminobenzene). NH* Mol. Wt. 93.13 Specifications) Slightly yellowish liquid; purity, 99.5% min.; distillstion range, 95% within 0.5C,; distillation limits, 182.0 to 185.0C. (dry point); crystallizing point, --6.2'C. min.; moisture, 0.10% max.; solution in HCI, complete; nitro benzene, none. R.R. Classifications Aniline. "Poison" label required. General Informations A basic intermediate in the dyestuff industry. It also finds application in the production of rubber accelerators, as a constituent of resins and in the manufacture of explosives. CAUTION: This product is toxic. Avoid breathing its vapors. Avoid contact with the skin. ore/to-AMSIDIXE__________ _________________________________ (Also known as <MtAo*metboxyaniliae, ortho-aminoaniaole, and l.amino-2-me- ihoxvbenzene.) OCH, Mol. Wt. 123.15 Standard Forms Liquid Specification*! Reddish brown to amber liquid; crystallizing point 5.3C. min. Distillation range: first drop 223.0C. min.; 95%, 1.2C. max.; dry point, 226.0C. max. Solution in HCI, clear. R.R. Classifications Dye Intermediate. General Informations Used as a component of azo dyes and in the manufacture (Continued) Page32 Monsanto chemicals 0663772 TOWOLDMON0006647 WATER_PCB-00003157 of dyestuff intermediates. CA (/77(W: This produa is toxic. Atoid breathing its vapors and aioid contact u ith the skin. pnra-ANISIDINE-------------------------------------------------------------------- (Also known as parc-metboxyanilioe, pora-aminoanisole, and l-amino-d-meth- oiy benzene.) OCH, Mol. Wt. 123.15 Ml. Standard Form: Fused solid Specifications: Fused, crystalline mass; crystallizing point 57.20C. min. Distilla tion range: first drop 240.OC. mitt.; 95% 2.0'C. max.; dry point 243.0C. max. Solution in HCI clear, darkens on ageing. K.R. Classification: Dye Intermediate. General Information! Used as a component of various azo dyestuffs and as an intermediate in chemical synthesis. CAUTION: This product is toxic. Avoid breathing its vapors. Aioid contact u ith the skin. ANTI-OXIDANTS, OIL (See Santolube). |-- ANTIOXIDANTS, RUBBER See individual antioxidants below for specifications. R.R. Classification! Chemicals NOIBN. Available Literature; "Monsanto Chemicals for the Rubber Industry," 42 pages. "Latex Compounding," 36 pages. "Rubber Compounding for the Wire Industry," 48 pages. "FLECTOL H" Specifications! Condensation product of acetone and aniline. Light colored powder; 99.5% min. through 200 ynesh, no coarse particles; m. p. 120C. min.; sp. g. 1.08; antioxidsnt value equal to that of the accepted standard in vulcan ized rubber, both in oxygen bomb and standard flexing tests; solubility approx. 10% in benzene, alcohol and gasoline; insoluble in water. "FLECTOL WHITE" Specifications! Light colored powder, not darker than the approved color ('Continued) 26TH edition Page 33 0683773 A N T IO X ID A N T S TOWOLDMON0006648 WATER_PCB-00003158 standard; 99.5% min. through 200 ttrsh, no coarse particles; m. p. 145C. non.; ap. g. 1.25; antioxidant value equ * io that of the accepted standard in ultra violet light tests; soluble in alcohoi. very slightly soluble in water and benzene, insoluble in gasoline. "OXYNONE" (2, 4-Diamino Oiphenylamine) Specifications! Brown crystalline powder; 99.5 per cent through 100 mesh and 95 per cent throush 200 mesh, no coarse particles; m. p. not less than 123C.; sp. g. 1.25; soluble in alcohol, chloroform and benzol; very slightly soluble in cold water and gasoline. A N T IO X ID A N T S "SANTOFLEX B" Specifications; Reaction product of acetone and para-aminodipbenyl. Waxy, dark gray, lumpy solid; crystallizing point about 80*C.; sp. g. 1.045. "SANTOFLEX BX" Specifications; Constant composition blend of Santoflex B and diphenyl-para* phenylene diamine. Waxy, dark gray, lumpy solid; sp. g. 1.11. "SANTOVAR A" Specifications; Alkylated polyhydroxy phenol. Nearly white crystalline powder, no darker than the accepted standard; m. p. not leas than 165C.; sp. g. 1.049; completely soluble in twice its weight of acetone. General Information; Used as a varnish anti-skinning agent; as an antioxidant in oils, paints, and rubber. ANTISEPTICS AND GERMIC IDES Chloramine*T U.S.P. (See under C). pora-Chloro-meto-Cresol (See under C). pora-Chloro-meto-Xylenol (Sec under C). Dichloramine*7 N.F. (See under D). Phenol U.S.P. (See under P). "Santamine** (See under S). "Santopben" (See under S). ARESKAP (Monobutyl Phenylphenol Sodium Monosulfonate) Standard Format Liquid and dry povder. (Continued) Page34 Monsanto chbhicals 0663774 TOWOLDMON0006649 WATER_PCB-00003159 K.K. Classification: Washing Compound M>IB\ General Information: Wetting, penetrating and spreading agent; used as spreading agent in insecticidal compositions, in embalming fluids and in metal pickling. AKESKKT (Monobutyl Diphenyl Sodium Monosulfonate)___ Standard Forms: I.icpiid and dry ponder. K.K. Classification: Washing Compound NOIBN. General Information: W'rtting, penetrating and spreading agcot. AKESKLENE (Dibutyl Phenylphenol Sodium Disulfonate)__ Standard Forms: Crystals and g>auboids. Typical Analysis: 43% NajSO* available. Dry AreBklene400: Tan hygroscopic powder, slightly aromatic; sulfates, trace; chlorides, trace; m. p. about 160*C.; pH, approx. 7.5 for 1% solution of dry material at 25C.; soluble (10 parts to 90 parts solvent) in alcohol, acetone, dibutyl tartrate, ethylene glycol, ethyl acetate and butyl cellosolve. Arek!ene-375: Light brown past:, slightly aromatic; sulfates, trace; chlorides, {Continued) A laboratory In the new rubber chemicals research building at Nitro, W, Va, 0683775 TOWOLDMON0006650 WATER_PCB-00003160 trace; m. p., decomposes at about ITS C.; not solutle in solvents which are immiscible will) water, H.K. Classification: Washing Compound, NOfBN. (General Information: Wetting, penetrating and spreading agent used in kicrhoiling, scouring and dying textiles, in industrial cleaners, in deodorant preparations, in insecticidal formulations, in metal cleaning and as a stabilizer ,md wetting agent in latex used to treat tord or other fabrics. `AROCLORS'' Specifications: The Aroclors are chlorinated hydrocarbons which varv from water-white mobile liquids and pale yellow viscous oils to light amber resins and opaque crystalline solids. l\on`fiammabilily: The viscous Aroclor oils and resins do not support combustion when heated alone even at their boiling points-- temperatures above 360C. Most of the Aroclors flux readily with resinous and pitch-like materials to give a product ha\ ing a decreased fire hazard. Electrical properties: The Aroclors have excellent electrical characteristics, high dielectric strength and resistivity, low power factor. Certain of the liquid Aroclors have a high dielectric constant as compared with that of mineral oils. Solubility: The Aroclor oils and resins are easily soluble hi most of the common organic solvents and drying oils. The hard crystalline materials are in general lesg soluble than the oils of resing. All Aroclors are insoluble in water. Adhesiieness: The more viscous Aroclor and Aroclor resins have excellent adhesive properties. Thermoplasticity: The Aroclors are thermoplastic, and apparently undergo no further condensation or hardening upon repeated melting and cooling. A'on-drvmg properties: The Aroclors are non-drying, and when thev are exposed to the air no noticeable oxidation or hardening takes place. Vaporization loss: The clear resins have rather low vaporization losses. At 65.8`C. (150F.) these losses are less than O.OA g. per square inch of surface per month. Odor and taste: The Aroclor viscous oils and resins are almost without odor and taste at ordinary temper atures. Refractive indices: The refractive indices of these materials are above 1.6125. Stability: The Aroclors in general are stable on long heating at 150C. and are not affected by boiling with sodium hydroxide solution. The light oils ran be distilled at atmospheric pressure without appreciable decomposition and the viscous oils and resins distill readily under vacuum. Corrosiveness: The Aroclors have practically no corrosive action when applied to metallic surfaces. General Information: Uses: Lacquer, paint and varnish: Aroclors impart resistance to moisture, gas, acids, alkalies, and ultra violet light and improve electrical insulating properties and durability. They function as both plasticizers and resins in nitrocellulose and ethyl cellulose lacquers. Sealing Waxes: Where a moisture proof, non-flammable wax or one with good electrical insulating properties is desired. Adhesives: Aroclors in adhesive application have the desirable qualities of being non-crystallitie, insoluble in water, thermoplastic, light in color, practically odorless, non-drying, and soluble in most organic sol vents. They provide excellent adhesion even to lacquered or varnished surfaces. Impregnation: Aroclors are used in impregnation of materials and articles to give them resistance to moisture, flame, alkalies and acids, and to improve electrical insulating properties. Corresponding to each clear Aroclor there is also a black Aroclor of similar properties. Flameproofing: Aroclors are used in combination with many other materials to reduce the flammability of those materials. Rubber and rubber substitutes; The liquid Aroclors have a solvent (Continued) Page 36 Monsanto chemicals 0683776 TOWOLDMON0006651 WATER_PCB-00003161 action on rubber and act as plasticizer. The solid Aroclors impart flame resist ance. P/osttcs: Tbe Aroclors are compatible with nitrocellulose, ethyl cellulose and vinyl resins. In ground powder form is an excellent organic pigment. Available Literature* 20-page Utoklel "The Arnrlors -- Physical Properties and Suggested Applications.' ASPIRIN (See Acetyl Salicylic Acid). BATTERY ACID (Electrolyte) Typical Analysis! Practically colorless liquid; HjSOt, 93.2% min.; iron, 0.003% max.; nitrogen compounds (as H\Oj), 0.001% max; sp. g. 1.210-1.833. (Acid* of lower strengths should be calculated in proportion to above specification on HjSOj content.) R.R. Classification! Sulfuric Acid. Ceneral Information! Electrolyte is sulfuric acid, especially adapted to tbe needs of the storage battery trade Various strengths can be furnished to meet the needs of the individual purchaser. BELT CEMENT General Information! Nitrocellulose base cements for cementing ply belting and laps. Characterized by strength, flexibility, rapid drying properties, and resistance to water. Specially adapted to power belting. More flexible typea are offered for wool combing aprons and paper machine dryer felts. R.R. Classification) Lacquers. BENZENE SULFONAMIDE, TECHNICAL O Mol. Wt. 157.18 O Characteristics) A brownish crystalline solid, crystallizing at 150" 152C. R.K. Classification) Lacquer Solvents, NOIBN. General Informations This product is tbe tecbincal form of Santiciser 129. It may be used in organic ayothesds, production of dyestuffs or as a plasticizer in resinous compositions where col is not a factor; is analogous to Monsanto's para-Toluenesulfonamide and can probably be used as a substitute in most applications. J0TH EDITION Page 37 0683777 TOWOLDMONOOQ6652 WATER_PCB-00003162 T BENZENE SULFONIC ACID, TECHNICAL Mol. Wt. 158.17 SO,H Characteristics) Greenish black viscous liquid or ervstailine mass; crystallizing point, 25.8C. (approx.); HjSO,, 24.0 - 25.0%; benzene sulfonic acid, 70,0 71.0%; sp.g. 25/I5.3C., 1.45 (approx.). K.R. Clasificationi Chemicals, NOIBN. General Information; Used as an intermediate in organic synthesis and as a catalyst in certain condensation reactions. BENZOATE OF SODA (See Sodium Benzoate). BENZOIC ACID ( NCOOH Mol.Wt. 122.12 Grade*< U.S.P. and Technical. Specification* of U.S.P. Grades White crystallise needle* or fine powder; assay 90.S min. (dry basis); m.p. 122.$eC. min.; solution in alcohol (1:2.5) and in 10% odium carbonate (1:6), clear and colorless; meets U.S.P. test for carboaUable impurities; 5% max. powder retained on 100 mesh screen. Specifications of Technical Grade t White to yellowish white granule# or powder; assay, 99.25% min.; odor, characteristic; solution in 10% NajCOj (1:6), slightly turbid or opalescent and practically colorless; approx. 10-20% retained on 20 mesh; approx. 100% retained on 100 mesh. R.R. Classificationi Of U.S.P. Grade--Food Preserving Compound; of Tech* ical Grade--Chemicals, NOIBN. General Information! U.S.P. Grade used in medicinal preparation# and as a preservative in foodstuffs. Technical Grade used in the manufacture of ben* zoatea and benzoyl compounds; as an intermediate in the manufacture of dyee; as a mordant in calico printing; as a nidifying agent in atkyd resins; as a color stabiliser in baking varnishes; as a dispersing agent in the grinding of pigments. P...S8 MOV9ANTO CHEMICALS 0683778 TOWOLDMON0006653 WATER_PCB-00003163 BENZOTRICHLORIDE_____ CCI. 0 Mol. Wt. 195.46 Standard Form: Liquid. Specifications: Colorless to light green or yellow liquid: crystallizing point min. Distillation range: fkst drop, 218.0C. tnin.; 95% (1-96 ml). 2.Dr. max.: <Jrv point, 223.0C. max. K.H. Classification: Chemicals NOIBN. General Information: Used as an intermediate in dyestuff synthesis. (AL110.\: Irritating to the skin, l npors are highly irritating to the eyes. Avoid breathing vaporAvoid contact with the skin. BENZYL CHLORIDE CHiCl Mol. Wt. 126.59 Standard Forms: Liquid, anhydrous; liquid wilh 10% NajCOj solution. Specifications! For anhydrous liquid and material recovered from 10% solution beloH: Colorless to light green to brown liquid; sp. g. at 1 S.d/lS.S'C.. I.104 1.108. Distillation raoge: first drop, 177.59C. min.; 95% (1*96), 3.0C. max.; dry point, 185.09C. max. l iquid with 10% NajCOj: NajCO,, in water solution, 9.0 - 11.0%. Note: 23 lbs. of 10% NajCOj solution are add'd to 450 Iba. of benzyl chloride contained in 55 gal. black iron drums. The wet material is a milky white emulsion, from which water may separate into a definite layer at either the bottom or top d. pending on the temperature and the concentration of NajCOs. Tin concentration of VtijCOj s\owly decreases on standing. II.11. Classification: Chemicals NOIBN. General Information: Used in the production of the following: Dyestuffs; perfume bases such as benzyl alcohol, acetates, benzoate and phenyl ethyl ah cohol; plasticizers; resins; wetting agents; rubber accelerators; gasoline gum inhibitors; benzyl cellulose; various pharmaceuticals. CAUTION: This product is irritating to the skin. Vapors are highly irritating to the eyes. Avoid contact with the skin. Avoid breathing vapors. BISULFATE OF SODA (See Nitre Cake) BISULFITE OF SODA (Set Sodium Bieulfite). JflTH COITION Page 39 0683779 TOWOLDMONOOQ6654 WATER_PCB-00003164 BLEACH (See Merrlor). BONE ASH___________________________________________________ General Information: Mold wash grade for coating molds used jncastingcop|>er wire bars, ingots and slabs. A siiptrior mold coating for certain steel casting operations. This product is also used in producing opal and other translucent Classes. It.It. Glawificu tlon: Hone Ash. BONE BLACK Grades: Twelve grades are available which vary in fineness, top tone, undertone, tinting strength, and color in oil. Specifications: In general, bone blacks when compared with lampblack or carbon black have greater hardness and lower oil absorption. They mix easily with water, shellacs and lacquer, and are relativ able to sunlight. Specifica tions for the various standard grades are as foil Grade No. w Moisture % P*0s 45 4.10 33.50 150 4.10 33.50 250 4.94 33.05 350 4.07 30. IS 439 4.78 32.05 439 Spec. 4.78 31.73 450 & 450-CT. 4.86 34.50 650 4.28 34.00 841 4.02 32.95 8S0 3.82 34.60 Ceco 4.95 32.30 Lbs. oil per 100 lbs. pigment. **No. 450, 99.90s No. 450-CT., 99.67 % Caro".: 9.20 9.20 9.75 13.84 14.57 15.12 9.30 8.75 8.90 8.37 9.70 Oil Absorption* 46.2 46.2 43.9 43.9 50.2 50.5 42.7 43.9 46.2 43.9 46.3 % thru 325 Screen 99.89 99.90 99.40 99.85 99.95 99.90 ** 99.73 99.90 99.90 99.95 R.R. Classification: Animal Charcoal. Other Than Spent. General Information: Chief use is as a pigment in leather finishes, artificial leather, paints, lacquers, japans, inks aod wall paper. Bone black has good jetness and is easy to wet, whereas lampblsck wets only with difficulty and has much less jetness. BRONZING LIQUIDS___________________________________ General Information! Clear lacquei base mediums for aluminum and bronze powders. Several types offered for metal, wood, fabric, and paper. Applied by spray or machine costing. Many are inhibited to retard gelling. R.R. Classification: Bronzing Liquids. Rage 40 Monsanto chemicals 0689760 TOWOLDMON0006655 WATER_PCB-00003165 'BLTASA.V' (See Accelerators, Rubber). BLTYL ACETATE_______________________________________ Typical Analysis! Water vhite liquid: sp. g. 0.872 0.877 at 2fl'20aC.: 7.3 lbs. per gal.: ester content, 88-90%. Roiling range: below 11.VC., none: below 122C.. io.i over 10%; below I25C., a.: least 90%; below 130 C, 100%. Drvness. ' *th 19 vnln, 60 Be. gasoline. I .ess than 0.01% as free aretic acid. It.It. Classification: Butyl Acetate. General Information: I'sed as a nitrocellulose solvent. Is intermediate in activity between ethyl acetate and amyl aretate. Blends of all three with ap propriate diluents surh as alcohols (ethyl, butyl, and amyl) yield thinners and advent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and comparability with various resins and oils. Lsed in the artificial leather industry and in formulat-ng lacquer finishes for wood, metals, textiles, and paper. BLTYL BENZENE SULFONAMIDE (See Santiciser 127). n-BITYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). BLTYL PHTHALATE (Se< Dibutyl Phthalate). BLTYL PHTHALYL BUTYL GLYCOLLATE (See Santiciier B-16) CABLE LACQUERS. General Information! Manufactured in clear, black and colors for application by gasket, for high tension automotive cables and primary wires. Special types are available that are flameproof, resistant to hot oil, and have high beat test ratings; also non-inflammable type sleeving lacquer of high dielectric strength. All types build well, giving a toug|b, glossy, flexible finish. R.R. Classification: Lacquers. 2STH BC'TION Page U 0683781 TOWOLDMON0006656 WATER_PCB-00003166 CAFFEINE, U.S.P. c =0 1 .CH, C-N^ I i.CH C -N ^ . UsO Mol. Wt. 212.21 Standard Forms: Powder, anhydro powder, hydrated. Specifications: White powder. Loss on drying at 80C: anhvdrous ponder 0.25% max.; hydrated flakes 5.75 6.50%. M.p. 235'C, min.; meets U.S.P. te*t fur mrbonizable impurities. MESH Retained on-- 20 mesh screen 35 mesh screen 45 mesh screen 100 mesh screen 200 mesh screen Hydrated Trace max. 12 0% max. 18 0% max. R.R. Classfication: Chemicals NOIBN. Anhydrous None 2.5% max. General Information: Pharmaceutical product. CAFFEINE, CITRATED, U.S.P.___ CH, N--C = 0 11 .CH, O C C-N^ 1 II ^CH N-C-N ^ i CH, (Caffeine) H,C --COOH ,1 + HO --C-COOH 1 H,C -- COOH (Citric Acid) Equal quantities- by weight Standard Form: Powder. Specifications: White powder; assay 48.0-52.0% anhydrous caffeine; loss on dry ing at 80C.. 0.2% max; solubility in water (1-4), complete; conforms to U.S.P. tests for sulfate and heavy metals; 15.0% max. retained on 100 mesh screen. R.R. Classification: Chemicals NOIBN. General Information: Pharmaceutical product. Page 42 MONSANTO CBIMICALS 0683782 TOWOLDMON0006657 WATER_PCB-00003167 CALCIUM GLYCEROPHOSPHATE N.F. (See Glycerophosphates). CALCIUM NITRATE Ca(NOj)j. 3 11,0 Standard Forms: White crystals; 7>% water solution. Typical Analysis: Ca(NOj)} 3 IIjO Heavy Metals Iron ra Water ITkite Crystals 98.95% none none none none Dalanre to magnesium Solution 71.21 % none none none lake up 100% is probably itrate. R.R. Classification: Calcium Nitrate. General Informations Used as a coagulant in latex dipping processes. CALCIUM PHOSPHATE, MONO (\lso known as primary calcium phosphate, calcium di-hydrogen phosphate, mono-basic calcium phosphate, calcium acid phosphate, and acid phosphate of Gradeat Regular for phosphated and self-rising flour and baking powder. Granular for baking powder. All grades meet U.S. Pure Food Law requirements. Special grades will be supplied on request. The following mixtures are carried in stock: .Xeut. Strength 52 50 50 45 45 45 Constituents Regular, Starch and 15% Calcium Sulfate. Regular anil Starch Granular a(id Starch Regular, Starch and 18% Calcium Sulfate. Regular, Starch and 30% Calcium Sulfate. Regular and Starch. Properties! A white stable material, soluble in wster, giving an acid reaction. R.R. Classification! Calcium Phosphate. General Information! Used in baktries for leavening purposes snd to prevent (he formation of "rope" in bread; as a leavening agent in biscuits and crackers and as an acid leavening agent in pancakes; as sole acid agent or mixed with sodium aluminum sulfate or sodium acid pyrophosphate in baking powders: in making self-rising, phosphated plain flour and prepared flours; to control pH of solution in malt. 76TK EDITION Pi 43 0663763 TOWOLDMON0006658 WATER_PCB-00003168 CALCIUM PHOSPHATE, DL________ (Also known as phosphate of lime, precipitated bone, secondary phosphate of lime, dicalciuDi ort/iy.phosphate and bibasic calcium phosphate.) Anhydrous Culll'O, Dihydrate CaliPO^IljO Mol. Wi. 136.068 Mol. Wi. 172.084 Standard Format Anhydrous; dihydrate. I'roprrlit't*; Insoluble in alcohol; soluble in dilute citric acid solution. Solubility in COj free water in grains per liter: Anhydrous: CaO PA Dihydrate: CaO PA 3QC. .0414 .0866 .0954 .2066 50C. .667 .1630 .2617 .6182 68C. .098$ .2234 .3409 .3245 loo.rc. .1046 .2461 ,3109 .7591 Grades! Medicinal; food; dentifrice. R.R. Classification]i Calcium Phosphate. General Informstiont Used as a mineral supplement in diets that are deficient in calcium and phosphorus; as polishing agent in tooth pastes and powders. Anniston, Alabama, plant of the Phosphate Division. 0683784 TOWOLDMON0006659 WATER_PCB-00003169 CALCIUM PHOSPHATE, TRI ,,_________________________ (Also known as (n-bamc calcium phosphate, normal calcium phosphate, neutral calcium phosphate, tertiary calcium phosphate.). Standard Formt White powder. Grades) Dentifrice, conditioner (salt, sugar, etc.), and medicinal. All material conforms to requirements of the l ,S. Pure Food Laws. Properties) White amorphous p.jwder, odorless and tasteless; practically in soluble in water. K,R. Classification) Calcium Phosphate. General Informationt Used as a mineral supplement to supply calcium and phosphorus; as a tooth paste base or polishing agent in tooth powder; as an in gredient in making milk glasses; as an antacid; as a conditioner to prevent caking in salt, sugar, talc and other powdered material. CALCIUM PHOSPHATE, X-C Generallnformation; Extra rich in calcium. Used as a mineral supplement to supply calcium and phosphorus, especially in enriched flours: to control pH of baked products in order to reduce loss of Thiamin (B|) in baking process; in phosphating plain floure. CALCIUM PYROPHOSPHATE Ca2P207 Mol. Wt 254.12 Propertiesi A finely subdivided powder; contains 43.3% CaO and 55.5% P205- General Information! Used in food fortification as a mineral supplement. CALCIUM SALICYLATE (See Salicylates). CALCIUM SULFATE (See Cryaalba). CARBOLIC ACID (See Phenol). CARBON DIOXIDE GAS____________________________________ CO, Typical Analysis) 100% CO, apptox-; sp. g. of liquefied gas. 1.057. 'Continued) 26TH EDITION Page 45 0683783 TOWOLDMONOOO666O WATER_PCB-00003170 K.R. Classification! Liquefied Carbon Dioxide. General Information: Monsanto carbon dioxide is liberated from pure soda ash. It is purified, dried and compressed to 400 lbs. per sq. io. in a multi-stage compressor, then condensed or liquefied and placed in steel cylinders. Thus pre pared, it is entirely free from odors and tastes and is widely used in carbonating beverages. It is also used as a non-oxidizing atmosphere, in rubber vulcanizing, in dry cleaning, in preserving foods, or wherever an inert oxygen-free medium is required. Liquefied Carbon Dioxide is the cheapest source of high pressure which is portable and without fire hazard. CARBON DIOXIDE, SOLID (Dry Ice) Standard Formt Blocks, 10'xl0'x)0', weighing 50 to 55 lbs. K.R. Classification: Dry Ice. General Information: A product of molasses fermentation in the manufacture of alcohol. Carbon dioxide thus produced as compared with the gat from other sources permits higher yield and a purer product, requiring less processing for purification prior to liquefying and solidifying. Used for low temperature refrig eration. CAST PHENOLIC (See Plastics, Opalon). CATECHOL (See Pyrocatecbol). CAUSTIC SODA (Also known as sodium hydroxide) NaOH Mol. Wt. 40.00 Standard Form: Solution 50%. Specifications! Practically clear, colorless or slight yellowish or greenish tinge; sodium hydroxide 48.5% min., 50.5% max.; sodium carbonate 0.20% max.; sodium chloride 1.25% max.; sodium chlorate 0.04% max.; iron 0.007% max.; sodium sulfate 0.04% max.; copper 0.0005% max. R.R. Classification! Caustic Soda. General Information! Used in petroleum refining, vegetable oil refining, tanning, soap making, textile manufacture (rayon), rubber reclaiming. CELLULOSE ACETATE (See Plastics, Fibestos). CELLULOSE NITRATE (See Plastics, Nitron). Page 46 MONSANTO CRIMtCALS 0683766 TOWOLDMONOOO666I WATER_PCB-00003171 CEMENTS General Information: Rapid-drying waterproof cement in various soluble cellulose and resin bases; also heat sealing cements. A complete line of cements is offered for adhering wood, metalK paper and fabric lo various plastic materials; also cements for packaging in collapsible metal tubes, such as household cement, model airplane cement, and library cement. H.H. Classification* Lacquer. CHLORAL HYDRATE, U.S.P, CCIjCU(OH)j .Standard Form! Crystals. Mol. Wt. 165.39 Specifications! Colorless, dry transparent crystals; assay 99.5% mio.; solubility in water (1:1), complete; water solution neutral to litmus; comforms to U.S.P. test for carbonizable impurities and chlorides. R.R. Classification! Chemicals NOIBN. General Information i Used in pharmaceutical preparations and veterinary medicines. CHLORAMINE-B________ ____________________ (Also known as N.N-eodium chlorobenzene sulfonamide) . 1H H,0 Vfol. Wt. 240.63 I N.^N''C1 Standard Form: Crystalline powder. Specifications! Nearly white crystals or crystalline powder; soluble in water; active chlorine 14.45% min. General Information! Chlotaoune-B U a water-soluble, chlorine-bearing pow der used as a germicide, disinfectant and deodorant. CHLORAMINE-T, U.S.P_________________________ ____ N. H*C0?"< JHl Mol Wt. 281.70 O Cl Standard Fonnt Crystalline powder. Specification* I White or faintly yellow powder or granules; solubility in water (2:15), complete; free alkali (as N*OH). 0.07 0.1S%; lota on drying (3 hrs. at {Continuetf) 26TB edition Page 47 0683267 TOWOLDMON0006662 WATEFLPCB-00003172 Q7C.), 18.U 20.0%; active chlorine 12.25 12.60%; assay 97.3% min. MESH Retained on 10 tnesb screen--Trace max. Retained on 35 mesb screen--1.0% min. R.R. Classification! Disinfectant other than medicinal. General Information: Chloraraine-T is a water-soluble, chlorine-bearing pow. der used as a germicide, disinfectant and deodorant. CHLORCOSANE (Chlorinated Paraffin, N.F.) Specifications! Light yellow oil: odorless and tasteless; sp. g. 1.00 to 1.07 at 25'C.; combined chlorine content 27% to 30%; reaction of water extract to lit mus. neutral; chlorides (as HC1) 0.004% max.; free chlorine, none; unchlorinated paraffin, negative (N.F. test). R.R. Classification i Chemicals NOIMN. General Information! A solvent for dichloramine-T. For uses where a product with fire-resistant, insulating and eolvint properties are indicated. CHLORINATED DIPHENYL (See ArocW.). CHLORINATED PARAFFIN, N.F. (See ChWcos.ne). CHLORINE Specifications! Ctear, amber colored liquid; about Wi times as heavy as water; conforms with American Water Work* Association specifications. K.R. Classification t Chlorine. General Information! Used for municipal water purification, sewage treatment and swimming pool sterilization, for slime control, in pulp and textile bleaching, metallurgy, bleaching and processing of flour, organic synthesis, and in the manufacture of metallic chlorides and hypochlorites. CA UT/O.V; Chlorine it toxic and highly irritating. Avoid contact with the thin and breathing the vapori, Available Literature! 20-page booklet "Monsanto Chlorine" para-CHLORO-meta-CRESOL, white transparent crystals; used as a disinfectant intenaifier; made by Monsanto Chemicals Limited. ortho-CHLORO-poro-TOLUENE-SODIUM SULFONATE (See Monsanto Salt). paro-CHLORO-meta-XYLENOL, white crystals; used as a disinfect- (Continued) Page 48 MONSANTO CHEMICALS 0683766 TOWOLDMON0006663 WATER_PCB-00003173 ant intensifier and as a preservative and preventive against mold and mildew; made by Monsanto Chemicals Limited. ortho-CHLOROAMLINE_______________________________ (Also known as ort/to-aminochlorjbenzene and 1 -araino-2-ohlorobenzene.) NH, Mol. Wt. 127.58 Standard Formi Liquid Specifications! Discolors readily on exposure to air; crystallizing point --2.3C. min. Distillation range; first drop, 208.0'C. min.; 95% (1-96 ml), 1.0C. max.; dry point, 210.0C. maxi Solution in HCI. very slightly opalescent max. R.R. Classification! Dye Intermediate. General Information! Used as an intermediate in the production of dyestuffs. CAUTION: This product is toxic Avoid breathing its vapors and avoid contact with the skin. meta-CHLOROANILINE (Also known as mefa*aminocblorobenzene and l-araino-3-chlorobenzene.) Mol. Wt. 127.58 Standard Formi Fused solid Specifications i Clear, light yellow liquid; crystallizing point approt. --10.0C. Distillation range: first drop, 228.0s. min.; 95% (1-96 ml), 1.0C. max.; dry point, 231. 0*C. max. R.R. Claaaificationi Dye Intermediate. General Information! Used as an intermediate in the manufacture of azo dyestuffs. CAUTION: This product is loxic. Avoid breathing its vapors. Avoid contact with the skin. pora-CHLOROANILINE _______________________________ (Also known as Pora-aminochlorobenzene and l-amino4-chlorobenzene.) NH, Mol. Wt. 127.58 Cl JSTH EDITION Standard Formt Fused solid. (Continued) Page 49 0683789 TOWOLDMON0006664 WATER_PCB-00003174 Specificationsi ) ellow ish, white solid; crystallizing point 6<).5:'C. min. Dietilia* turn range: first drop, min.; ^5% (l-% mi), 1.5C, coax.; dry point, 233.0C. max. Solution in HCI, slight opalescence max. It.R. Classification: Dye Intermediate. General Information t Used as an intermediate in the production of dyestuffs. CAUTfOX: This product is toxic. Avoid breathing its vapors and ovoid contact ti lth the skin. CHLOROBENZENE Cl Mol. MTt. 112.56 >/ Standard Forms Liquid. Specification*! Clear, almoet colorless liquid. Distillation range: first drop, 131.5C. min.; 95% (1-96 ml), O.S*C. max.: dry point. 133.5C. max. R.R. Classification: Monochlorobenze.ir. General Information: Major use is as an intermediate in the preparation of the various substituted chlorobenzenes which are in turn intermediates for the preparation of dyestuffs, explosives, and various other organic chemicals. Also used as an organic solvent. ort/to-CHLOROPHENOL, TECHNICAL (Also known as ortho -bydroxych lorobeozene and l^hloro-2-hydroxybenzene. OH Mol. Wt. 128.56 Standard Form: Liquid. Specification*: Clear yellow to brown liquid; roonochloropbenol (from Cl con tent), 95.0% min. Distillation range: firt drop. 173.0C. min.: 95% (1*96 ml.), 2.0C. max.: dry point, 178.0C. max. R.R. Classification! Dye Intermediate. General Information: Used as an intermediate in the production of dyestuffs snd various other organic product*. CAUTION: This product is toxic. Avoid breathing its vapors. <4void contact with the shin. para-CHLOROPHENOL_______ ______________________________ (Also known a* pom-bydroxychlorobeiuene and 1 -chioro-4-hydroxybenzene.) (Continued) Page 50 MONSANTO CBBMICAL9 0683790 TOWOLDMON0006665 WATER_PCB-00003175 OH Mol. Wt. 128.56 Standard Formi Fused solid. Specifications! Yellow to brown crystalline mass; crystallizing point 42.5C. min.; sp.g. at 4S.0/15.5C., 1.266.1.262. Il.ll. Classification: Dye Intermediate. <General Information! Used as an intermediate in the production of dyestuffs, us a germicide and in the synthesis of pharmaceuticals. CAUTION; Cart should ho exercised in handling this product. Avoid contact with the skin. CHLOROSULFONIC ACID (Also known as sulfuric cblorohydrin.) ClSOjOH Mol. Wt. 116.53 Standard Formi Liquid. Specifications! Heavy mobile liquid; tssay 98.5% min. R.R. Classification: Acid. General Information! Used in chlorosulfonation reactions. CAUTION: Chlo- rosuifonic acid reacts violently with water, forming hydrochloric and sulfuric acids. CHROME SULFATE (See Santotan). CITRATED CAFFEINE* U.S.P. (See Caffeine, Citrated). CONTACT MASS (See Vanadium Catalyst). COPPERAS NITRATE OF IRON (See Nitrate of Iron C) COTTON SOLUTIONS General Informations Made from RS (regular soluble) cotton of any desired viscosity. Viscosity, solid content, and solvent composition can be regulated to meet customer requirements. Used in manufacture of lacquers, leather dopes, fabric coatings, artificial leather finishes, etc. Composition of standard base solutions follow: (Continued) 26TB EDITION Pag* 51 0663791 TOWOLDMONOOO6666 WATER_PCB-00003176 Formula Number R-1202 R-4683 R-2816 R-1205 RI204 L-4692 Standard Nitrocellulose Solutions Viscosity Wt. NC Percent to l gal. Nitrocel. Nitrocellulose Solvents dry Active Solvent \A Seconds 64 ox. 35.9 Butyl Acetate A " 64 " 6 " 45 " 36.5 28.1 Ethyl Acetate Butyl Acetate 15-20 " 28 " 19.5 Butyl Acetate 15-20 " 28 " 19.5 Ethyl Acetate 250-400 " 16 " 13.0 Ethyl Acetate Weight one gallon 8.71 lbs 8.54 " 8.53 " 7.99 " 8.1 " 7.24 " * Usual added diluents; Toluol, xylol, ipbthas (varying aromaticity), alcohols (ethyl, butyl, amyl). R.K. Classification > Lacquers. "COUMARIN MONSANTO" `'Coumarin N. F.) Mol. Wt. 146.14 Standard Format Crystals, fine; crystals, large--4 mesh. Specification*! Fine or large white crystals: melt (liquid), clear and colorless; m.p. 68.8C. min.; solubility in ethyl alcohol (1:10), complete; lose on drying 0.03% max.; ash 0.05% max.; conforms to N.F. test for acetanilid; 5.0% max. retained on 4 mesh screen; 95.0% min. retained on 8 mesh screen. R.R. Classification! Coumarin. General Information! Coumarin is a flavor and odor principle used separately and in conjunction with vanillin, It is used in perfumes, soaps, tobacco, inks, foods and other product# where flavoring or aromatic ingredients are required. Available Literature! Folder, "Coumarin Monsanto". CREAMERY ACID (See Sulfuric Acid). meta-CRESOL* colorless liquid, assay 98*100%, crystallises at 10.5 12C.; used in the manufacture of synthetic perfumes and aitro-derivatives; made by Monsanto Chemicals Limited. orf/to-CRESOL, white crystalline mass, crystallizes 30 31C.: used in the manufacture of diaiwieala and aa a dye intermediate; made by Monaanto Chem icals Limited. Page 52 MON9A NTO CHEMICALS 0663792 TOWOLDMON0006667 WATER_PCB-00003177 para-CRESOL, looe white crystals, crystallizes 34.5C.; dye intermediate; made by Monsanto Chemicals Limited. CRESOL-CRESYLIC ACID, duty-free grades; used as a flotation agent and gasoline antioxidant and in th< manufacture of soaps, disinfectants, paint removers, textile chemicals, resins and dyestuffs; made by Monsanto Chemicals Limited. CRESYLIC ACID (See Creaol). `CRYSALBA" CaSO* Mol. Wt. 136.14 Properties! Extremely fine, white powder composed of minute particles of crystalline-shaped anhydrous calcium sulfate, standardized and apecially pre pared for use as a dentifrice base (paste or powder). R.R. Classification! Calcium Sulfaie. Principal Uses! Used as a tooth paste base or polishing agent. Suitable for preparation of neutral, acid, basic, soap, or magnesia type dentifrice. "CURODEX" A complete line of reodorants for the rubber trade; not manufactured by us but furnished for the convenience of our customers. "CYCLIIVE" OIL Specifications! Blend of mineral and vegetable oila. Clear, yellow oil with pale blue-green fluorescence; sp. g. 0.89; flash point, 185C.; viscosity, between 105 and 115 Saybolt viscosimeter at 37.$C.; soluble in benzene, gasoline, dry alcobole, ethers and acetone. R.R. Qasaiflcatlom Petroleum Oil, NOIBN. General Information! Uaed aa a rubber softener. Available Literature! 42-page booklet "Monosanto Chemicals for the Rubber Industry." 26TB IDlTlOf! Page 53 0663793 TOWOLDMONOOO6668 WATER_PCB-00003178 CVCLOHEXYLAMINE.___ (Atso known as hexahydroaniline.) NH, |1 CH YV. H.C CH* 1| 1 I IliC CH. \/ CHi Mol. Wi. 99.17 Standard Form) Liquid. Specifications) Clear, practically rolorlesa; sp. g. at 15.5/15.5C., 0.870-0.874. Distillation range: first drop, 132.0C. min.: 95% (1-96 ml.), 4.0C. max.; dry point, 137.5C. max. R.R. Classifications Chemicals N01BN. General Information t Used as a dyestuff intermediate; as an intermediate or ingredient for insecticidal compositions; as a component of corrosion inhibitors; in organic synthesis. CA UTION: This product is toxic. Avoid breathing its vapors and avoid contact with the skin. DETERGENTS (See Arealcap, Aresket, Aresklene, Santomerse). DIACETONE, TECHNICAL - -- Typical Analysis* Nearly water white liquid; acidity, neutral; odor, no residua); sp. g. 0.918 at 15.5C.; shipping wt. per gal., 7.60 lbs.; diacetone content, 85%; boiling range, theoretical b.p. 164eC. (decomposes at 130* 140C,); dryness, mixes with 5 vole, of petroleum naptha without turbidity. K.R. Classification) Diacetone. General Information) Diacetone is one of tbe most active high boiling solvents for nitrocellulose. It is a good solvent for cellulose acetate and many resins, waxes and dyes. Diacetone ia miscible and has a high tolerance for nearly all lacquer diluent*. Higher percentages of water are tolerated than with most solvents. DIAMMONIUM PHOSPHATE (See Ammonium Phosphate, EH). "D.P. SOLUTION 4519"____________ Standard Form) 40% sol. in ethyl alcohol. (Continued) Page 54 MONSANTO CBtMlCALft 0663794 TOWOLDMON0006669 WATER_PCB-00003179 Properties: Pale straw colored licfuid: 8.2 lbs. per gal. R.K. Classification: Chemicals N'OIBN. General Informations L scd as an anti-corrosion agent in lacquers and cotton solutions, and as an agent to prevent tbe settling of Santocel in fiat lacquer formulations. IMBLTYL PIITHA LATE . -C -O-C4H, -- C -- O -- C,H, II o Mol. Wt. 278.17 Specifications* Clear, oily, liquid, color (APHA) 10 max.; odor, slight; aciditv (as phtbalie acid) 0.01% max.;ep. g. at 207207:., 1.0480.00l; refrae. index at 25'C.. 1.4905 0.001; assay (ester content) 99% min.; sulfur (copper strip ter), negative. K.K. Classifications Dibutyl Phthaiate. General Informations Dibutyl Phthaiate is one of the most widely used plasticizers for nitrocellulose. It is miscible with all the common organic solvents and with oils but is soluble in water only to the extent of 0.001% at 30C. It has excellent light stability which permits its use in colorless, white or delicately tinted produets. Tbe stability of Dibutyl Phthaiate and its high solvent power for most plastic materials make it one of the most acceptable plasticizers for general use. Available Literaturei 40 Page booklet ''Plasticizers and Resina". DICALCIUM PHOSPHATE (See Calcium Phosphate, Di). DICHLORAMINE-Te N.F. O ,-------. || H,C <_____> S -NCI O Mol. Wt. 240.11 Standard Forint Crystalline powder. Specification*! Yellowish white crystalline powder; crystallizing point 80.5C. min.; assay (available chlorine) 29.25%. R.R. Classification: Chemicals NOIBN. (Continued) tSTH EDITION Page 55 0683795 TOWOLDMON0006670 WATER_PCB-00003180 General Information: Dichlorsmine-T is a Mater soluble, active chlorine bearing product. It must be stored away from light and in a cool place. . 2,5-DICHLOROANILINE___________ (Also known as l.araino*2,5-dichloiobenzene) aW Mol. Wt. 162.03 Standard Forms Fused crystalline mass. Characteristics! Light brown crystalline mast; crystallizing point, 48,6('.. min. Distillation range; start, 247*0. min.: 95%, within l.SC. R.R. Classification: Dye Intermediate. General Information: Used as an intermediate in the preparation of azo dye* stuffs. CA ITION: This product is trtc. Avoid breathing its vapon. Avoid contact n ith the skin. "Poison*' label requited. DICHLOROBENZENE (See Santochlor and ortbo-Dichlorobensene) paro-DICHLOROBENZENE (See Santochlor). orrho-DICHLOROBENZENE, TECHNICAL. (Also known as 1, 2-dichlocobnxeoe) Cl Mol. Wt. 147.00 Standard Form: Liquid. Characteristics: Colorless to slightly yellow liquid; crystallizing point, 7.0C. max.: 100% (1st drop, dry point), 14.0*0. max. 3p.g. 15.5/15.5, 1.305 1.313: composition, 75 85% ortho-dichlorobensene, 15 * 25% para-dichlorobenxene. R.R. Gasaificatfons Ortbo-dicblorobetuene. General Information: Used as a dyestuff intermediate; solvent; ingredient in cleaning preparations; and as an insecticide and fungicide. Page 56 MONSANTO CHEMICALS 0663796 TOWOLDMON0006671 WATER_PCB-00003181 2, 4-DICHLOROPHENOL ____________ (Also known as l,3*<Ucbloro4-hy<ij oxybeniene.) OH /\ ci Mol. Wt. 163.00 Standard Forms Fused solid. Specifications* Yellow to brown crystalline mass; crystallizing point 42.0C. nun. Dial illation range: first drop, 21 t.5C. min.; 95% (1-96 ml.), 2.0C. mas. R.R. Classifications Dye Intermt diate. General Informations Used as an intermediate in the production of dyestuff* and as a germicide. CA V TIO.V: Core should be exercised in handling this material. Avoid contact with the skin. Avoid breathing Us vapors. DICYCLOHEXYLAMINE . \ N-H / Mol. Wt. 181.32 Standard Forms Liquid. Characterlsticai Clear, practically colorless liquid; sp.g. 15.5V15.5aC., 0.916 0.920. Distilling range: first drop, i!52.09C. min. Flash point ("Tag" open cup), above 2008F. R.R. Classifications Chemicals NQIBN. General Information: Used as an intermediate in the manufacture of oil additives and insecticides, CA L'TtON: This product is toxic. Avoid breathing its vapors. Avoid contact wUh the skin. DIETHYL PHTHALATE _ o -C-O-C.H. 0-- C -- O -- C)H oII Mol. Wt. 222.11 Specification's Clear, water*wbi oily liquid; color (APHA), not darker than 10; odor, very slightly aromatic; acidity (as pbthalic acid) 0.01% max,; ip. g. at 20/20C., 1.1230.005; refrsc. index at 20C., 1.50300.001, sulfur (copper-strip test), negative. [Continued) 26TB IDITION Page 57 0683797 TOWOLDMON0006672 WATER_PCB-00003182 R.R. Classifications Diethyl Phthalate. General Informations Diethyl Phthalate ii a colorless liquid plasticizer gen erally used in mixture with dimethyl pbtha ate as a plasticizer for cellulose acetate. It is miscible with all the common organic solvents and dilueots. Evap oration rate of Diethyl Phthalate is too high for successful use as a regular nitro cellulose plasticizer and it is not a solvent for cellulose acetate. Thus its range of usefulness is somewhat restricted. Mixtures of Diethyl and Dimethyl Phthaiates usually give better results than can b<- obtained by either one alone. Boiling point ia 295C.; weight per gal., 9.35 lbs. Available Literature! 40 Page booklet "Plasticizers and Resins". 2, 3-DIMETHOXY BENZALDEHYDE, TECHNICAL (Also known as ort/io-veratraldehyde). ,o C-H 0 OCH, OCH, Mol. Wt. 166.0 Characteristics i Yellowish brown fused crystalline mass; solubility in sodium bisulfite, nearly complete; crystallizing point. 4?.3C. min.; sp.g. at 60C., 1.117; wt. per gal., 9.3 lbs. approx. R.R. Classifications Chemicals NOfBN. General Information, Used as a perfume fixative and as an intermediate in chemical synthesis. DIMETHYL PHTHALATE . O -- C --O --CHi -- C --O -- CH II Mol. Wt. 194.08 Specificationsi Clear, water-white (.ily liquid; color (APHA), not darker then 10; odor, not more than slightly aromatic; acidity (sa phthalic acid) 0.01% max.; sp. g. at 15.6/1S.6*C., 1.196^:0.001; refrac. Index at 20C., 1.51550.001; sulfur (copper atrip test), negative. R.R. Classification, Dimethyl Phthalate. General Information, Dimethyl Phthalate is a solvent plasticiser for cellulose acetate. It is miscible with all common organic solvents and with oils (except (Continued) MONSANTO CHIMICALS 0683798 TOWOLDMON0006673 WATER_PCB-00003183 petroleum oils) and has a solubility in water of 0.4% at 32C. It baa excellent light stability. Dimethyl Phthalate is much used but cannot he said to meet very rigid plasticizer requirements. Its use is restricted almost entirely to the cellulose acetate field, and there, as a general rule, it is used in combination with diethyl phthalate or eom; other plasticizer. Dimethyl Phthalate has a boiling point of 282C., a crystallizing point of 0JC, and weighs 10 lbs. pvt- gallon. Available Llteraturei 40 Page booklet ''Plasticizers and Resins." 2, 4-DINITROANILINE______________________ (Also known as l-ammo.2, 4-dinitrobenzene.) NH Mol. Wt. 183.12 Standard Forms Powder. Specifications! Bright yellow powder; m. p. 177,5CC. min,; chloride* (total) 0.15% max. R.K. Classification: Dye Intermediate. General Information! Used as an intermediate in the preparation of dyestuffs. CAUTION: This product is toxic. Avoid breathing in dust. Avoid contact with the skin. 2, 4-DINITROCHLOROBKNZENE, TECHNICAL (Also known aa l-chloro-2,4-dinitfobenzene.) Cl Mol. Wt. 202.56 NO Standard Formi Fused crystalline solid. Grade*! 3 grades of fused crystalline solids with crystallizing point* of 48.0#C., 46.5r,C., and 44.0C. Approximate Analysis! 2:4 dinitto* 4B.0*C. 46.5C. chlorobenzene 95%Approx. 90% * 44.0C. 85% ' isomeric dinitro* chlorobenzenes 5% Approx. 10% * 15% " R.R. Classification! Dye Intermediate. (Continued) KTH EDITION Pags 59 0663799 TOWOLDMON0006674 WATER_PCB-00003184 I General Information! Used in the production of explosives, photographic chemicals, and dinitrophenol, and as an intermediate in the preparation of dyestuffs. CAUTION: This product if toxic. Avoid breathing Us vapors. Avoid contact with the skin. DIPHENYL_____________________ (Also known as biphenyl; phenyl benzene). o-o Mol. Wt. 154.2 Properties! Technical diphenyl is a light yellow crystalline solid. Boiling point 254.9C, freezing point 68.5C. to 68.9" C. R.R. Classification! Diphenyl. Ceneral Information! Used as a high temperature, low pressure heat transfer medium. It is also the starting point for many derivatives such as Aroclors (chlorinated diphenyl) and the suifonio acid, nitro, amino and hydroxy com pounds. DIPHENYL PHTHALATE --Oo Mol. Wt. 318.31 Specifications! Essentially white fused solid; melt, clear and light yellow color: free acid (as phthalic) 0.20% max., fret: phenol 0.25% max. R.R. Classification! Lacquer Solvent. General Informations Diphenyl Phtbclate has a crystallising point of about 69C. and is readily soluble in ketones, esters and chlorinated hydrocarbons. Its solubility in slcobols, turpentine ai.d linseed oil is rather low, approx. 5.0 grams per 100 c.c. of solvent at 25SC. Diphenyl Pbthalate is compatible with nitrocellulose and with the sulfonamide, phenolic, polystyrene and vinyl types of synthetic resins. In nitrocellulose lacquers it produces bard coatings that have excellent gloea retention and weather resistance. Mixtures of Diphenyl Pbthalate with either Santolite MS or Santolite MHP are excellent plasticizers for nitro cellulose in odorless, flexible, adhesive coatings. Diphenyl Pbthalate is completely insoluble in water and gives increased water resistance to all compositions in which it is used. It is especially recommended for viuyl resins, polystyrene, ethyl cellulose, and some of the natural resins such as Damar. Available Literature! 40 Page booklet "Plasticizers sod Resins'*. Page 60 MONSANTO CBIH1CALI 0683800 TOWOLDMON0006675 WATER_PCB-00003185 DIPHENYLGUANIDINE (See DPG under Accelerator*, Robber). DIPPING LACQUERS (S Lacquer*). DISINFECTANT INTENSIFIERS <S Saotophrn, Axk.P). DISODIUM PHOSPHATE (See Sodium Phosphate, Di). DISPERSING AGENTS (See Areekap, Areeket, Areeklene, Saotomene). DRY ICE (See Carbon Dioxidf Solid). "EL SIXTY*' (See Accelerate**, Rubber). ELECTROLYTE (See Battery Acid). EMULSIFYING AGENTS (See Arwkap, Aresket, Areeklene, Santomerae). ENAMELS (See Lacquer* and Resin*). "ETHASAN" (See Accelerator*, Rubber). "ETHAVAN" (Ethyl Vanillin)------------------------------------------------- OH c=o H Standard Forms Needle*. Specification*t Fine white crystalline needle#; completely soluble in ethyl alco hol 95% (1:2); ash 0.05% max.; n-.p. 76.5C. min. R.R. Classification! Chemical* NOIBN. (Continued) 26TH EDITION Page 61 0663601 TOWOLDMON0006676 WATER_PCB-00003186 1 General Information! Ethavan it uwd as a flavoring and aromatic, and has a flavor similar to that of Vanillin but not identical with it. The relative flavoring strength of Ethavan approximates three times that of Vanillin. Available Literature) Leaflet, "Ethavan.'* ETHYL ACETATE Typical Analysis: Water white liquid: sp. g., 0.895 at 15.5C.; 7.40 lbs. per gal.; ester content, 85-90%. Boiling range: 70C. B0*C. Dryness, mixes with not less than 10 vols. of petroleum benzine without turbidity. Less than 0.02% as free acetic acid. K.lt. Classiflcationt Ethyl Acetate. General Information! Used as a nitrocellulose solvent. It is a more active solvent than either butyl or amyl acetate, evaporating the fastest, and having the least resistance to moisture blush. Blends of all three with appropriate diluents such as alcohols (ethyl, butyl, and amyl) yield thinners and solvent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and com patibility with various resins and oils. Used in the artificial leather industry and in formulating lacquers and finishes foi wood, metals, textiles, and paper. ETHYL ALCOHOL--190 Proof QH{OU (Also see Mersol, a proprietary solvent type alcohol, and Nealco Anti-Freeze.) Gradeei 1. Tax Free: 190 proof pure Ethyl Alcohol (95% by volume). May be withdrawn Under Regulations and Provisions by the U. 5. or any governmental agency thereof, or by the several states and territories, or any municipal subdivision thereof, or by the District of Columbia, or for the use of any scientific university or college of learning, any laboratory for use exclusively in scientific research, or use in any hospital, or janitarium, or for the use of any clinic operated for charity and not for profit, including use in the compounding of bona fide medicines for treatment outside of such clinics of patients thereof, but not for sale. 2. Tax Paid: 190 proof pure Ethyl Alcohol (95% by volume), (a) May be pur chased by manufacturers and others for non-beverage uae without Federal Permit or bond, but such users must sign affidavit that the alcohol so purchased is for industrial use only, as defined by Federal Alcohol Administration Regula tion 2. (b) May be purchased by blenders and rectifiers, (c) Subject to Federal Government Tax. Individual state regulations apply on tbs purchase and uae of pure Tax Paid Alcohol. 3. Specially Denatured Alcohol: May lie withdrawn for use in a great number of specialised arts and industries. The character of the denaturant or denaturants employed is such that Specially Denatured Alcohol may be sold, possesaed and used only pursuant to permit and bond approved by Internal Revenue Depart ment, Alcohol Tax Division. All application forms covering the withdrawal of (Continued) Page 62 Monsanto chemical* 0683802 TOWOLDMON0006677 WATER_PCB-00003187 Molaanes storage tanka of the New England Alcohol Company. Specially Denatured Alcohol may be obtained from tbe office of the District Supervisor, Internal Revenue Department, Alcohol Tax Division of the district in which the purchaser's plant is located. 4. Completely Denatured Alcohol: 18B proof. May be withdrawn without permit or (ax, but buyer must comply with certain Federal and State regulations govern* ing records and storage. R.R. Classification! Alcohol INOII*N or Denatured Alcohol. General Informationt Nealco ethyl alcohol is manufactured by the fermenta tion of molasses. It is offered in its pure state and in all formulas of Specially Denatured and Completely Denatured Alcohol as authorized by Federal Law under the provisions of Tide III of the National Prohibition Act. It is of high uniform quality complying with the exacting specifications of the National Formulary Viand U.S.P. XI. Available Literaturei 68-page booklet "Nealco Industrial Alcohol.** ETHYL BENZENE SULFONAMIDE (See Santicizer 128). ETHYL PHOSPHATE (See Triethyl Phosphate). 2f.TH icniTioN Page 63 0683603 TOWOLDMON0006678 WATER_PCB-00003188 ETHYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). tri'HYL PHTHALYL ETHYL GLYCOLLATE (See Samicizer E-15). ETHYL TRIETHANOLAMINE PHOSPHATE _____________________ Properties! Medium siraw colored liquid of slightly alcoholic odor: sp. g. 1.19 ill 25`C.; wt. per gal. 9.9 lbs,; liquid at all ranges of relative humidity butvery viscous when anhydrous; pH 7.0 7.4; strength, 60% solution in water. 11.11. Classification*! Chemicals NOIBN. General Information! Used as a plasticizer for water soluble materials and as a humectant. ETHYL VANILLIN (See Ethavan). FERRIC CHLORIDE SOLUTION (Iron Perchloride)______ I'eClj Standard Formt Liquid. Grades! 37B.: 40B6.; 426R Typical Analysis: Ferric Chloride 42Bf: total FejOj, 20.3%; FeO. 1.0%; combined FejOj, 19.2%; FeClj, 39.0%. R.R. Classification! Iron Chloride Liquid. General Information t Used as an acid oxidizing agent in etching, photoengrav ing, and in the manufacture of textile printnng rolls and brass signs. It is used in water and sewage treatment for it* iron content. FERRIC GLYCEROPHOSPHATE (See Glycerophosphates). FERRIC NITRATE, LIQUID (Trot Nitrate of Iron) Fe<NOj)3 Grades: 47B6,, 16.0% Fe,0 R.R. Classification: Iron Nitrate. General Informations A source of ferric hydroxide for mineral tan and buff colors on cotton; brown papers; logwood blacks on silk; shoe stains and inks. FERRIC PHOSPHATE________________________________ Sodium Ferric Pyrophosphate Na8Fei(Pj0T)j.XHi0 (Continue*') Page 64 MONSANTO CHEMICAL* 066380* TOWOLDMON0006679 WATER_PCB-00003189 Ferric Orthophosphate Ferric Pyrophosphate Ferric Acid Pyrophosphate General Information: Used in food and pharmaceutical fortification a mineral supplement. FERRIC SULFATE (See Feirisul). FERRIC SULFATE, LIQUID (Copperas Nitrate of Iron) _____ FerfSOJ. Gradeat 40BA, 13.6% Fe,0, 47B4,, 15.7% FejOj Containers: Carboys; barrels. General Informations A strong solution of ferric sulfate, containing no nitric acid. Used as a source of ferric hydroxide for mineral tan and buff colors on cotton, brown papers, logwood blacks on silk, shoe stains and inks. "FERRISLXM(Aniiydrou8 Ferric Sulfate) Fe^SOJi Standard Forms Pellets 4*40 meals. Typical Analysias 90% min. FejfSO*)*. R.R. Glassifications Dry Ferric Sulfate. General Informations An effective coagulant for the treatment of water supplies, sewage, and industrial waste. Jo solution, it is a mild oxidising agent and can be used for pickling certaujt alloys such as the stainless steels, brass and other copper alloys. It is also used in various organic reactions. Available Literature! Booklets, "Ferrisul for Treatment of Water, Sewage and Industrial Wsates" and "Ferrisul for Metal Treating." FERROPHOSPHORUS (Iron Phosphide) Standard Format Chill cast lumps, egg sise; powder. Contains 23 26% pbos* pborus. R.R. Classifications Ferropboaphonu. General Information! An alloy of iron and phosphorus. Used in iron and steel castings to increase fluidity; in sheet steel to prevent sticking of sheets in final rolling; in wire to give stiffness and better surface for drawing. Available Literature) Phoaphortts.Iron Alloy* Bulletin No. 1. A report of (Continued) 26TB iOITION Page 65 0663605 TOWOLDMONOOO668O WATER_PCB-00003190 general txploratory Testarch upon the influence of phosphorus in low carbon, low alloy steels. 36 pages. Bulletin No. 2. A report of experimental research investigation upon corrosion and mechanical influences of alloying elements in low alloy steels. 62 pages plus harts. Bulletin No. 3. Abstracts of L'.S. patents relating to phosphorus as an alloying lenient in steel and list of iron and steel patents. 54 pages. Bulletin No. 4. Re|>orts of experimental research investigation upon influence >f phosphorus in steels in elevated temperature service and in Cr-Mo steels, 2D pages. "FIBESTOS" (See Plastics). FLECTOL" H and WHITE (See under Antioxidants). FLOTATION AGENTS (See Xanthates). FUNGICIDES (See Santohrite and Santophen 20). GERMICIDES (See Antiseptics nd Germicides). GLAUBER'S SALT (Sodium Sulfate)________________ ___ NaSOt+ 10 HjO Standard Format Crystals and Glauboid*. Typical Analysis! 43% Mi|SO| available. R.R. Classification! Glauber's Salt. General Information! Used principally as a leveler in dyeing wool and silk; for the precipitation of barium sulfate or blanc fixe; neutralising of sulfonated oils; treating softened boiler feed water to prevent caustic embrittlement; salting skins. GLYCEROPHOSPHATES___ Specifications! See individual glycerophosphates below. General Information) The Glycerophoepbates are a group ofproducts contain(Continued) Page 66 monsahto chbmicalb 0683606 TOWOLDMONOOO668I WATER_PCB-00003191 ing the glycerophosphate radical and may be used advantageously to carry surh important elements as calcium, iron, magnesium, manganese, potassium, and sodium in the formulation of pharmaceutical preparations, in the case of the less soluble salts, such as calcium, iron, magnesium, and manganese, the solubility of these products may be materially increased if they are formulated with Glvcerophosphoric Acid or certain accepted food acids, such as lactic, citric and tartaric. GLYCEROPHOSPHATE. CALCIUM* N.F. CaCIUOtI),PO, Standard Formi Powder, 80 t-iesh. Mol. Vt. 210.1S Specifications! Fine white powder; assay (dry basis) 98.0% min.; #p. g. 0.42 0.50; loss on drying at 130`C., 12.0% man.; solubility in water (1:50),complete; chloride (as CaCI.) 0.1% mat.; sulfate (as CaSO,) 0.50% max.; free phosphate (as P]0) 0.02% max.: conforms to N.F. test for heavy metals; 3.0% max. re tained on 80 mesh screen; 5.0%, max. on 100 mesh screen. R.R. Classification! Chemical* NOIBN. GLYCEROPHOSPHATE, FERRIC, N.F. Fei(CiHi(OH)PO<Jj Mol. Wt. 621.90 Standard Forint Powder. Specifications) Buff or yellowish green powder; assay (dry basis), 17.0% Fe min.; moisture, 10,0% max.; chloride (as FeCh), 0.10% max.; sulfate (as Fe:(SO,)i), 0.10% max.; free phosphate (as PjO), 0.20% max.; 2.0% max. re tained on 60 mesh screen, 10.0% max. on 150 mesh screen, 30.0% max. on 250 mesh screen. R.R. Classifications Chemical) NOIBN. GLYCEROPHOSPHATE, MAGNESIUM . MgCH(OH)iPO Mol. Wt. 194.39 Standard Formi Powder, 80-toesh. Specific*tiot&at White powder; assay, 97.0% mis.; moisture, 12.5% max.', calcium (aa CaO), negative; chlotide(a* MgClj), 0.10% max.; sulfate (aa MgSO), 0.10% max.; free phosphate (aa PiO,), 0.20% max.; conform# to N.F. test for heavy metals; 2.0% max. retailed on 60 mesh screen, 1.0% max. on 80 meah screen, 10.0% max. on 100 mesh screen. R.R. Classification! Chemicals NOIBN. 26TB edition Page 67 0683607 TOWOLDMON0006682 WATER_PCB-00003192 GLYCEROPHOSPHATE, MANGANESE, N.F. MoC,H,(OH),PO, Mol. \Ft. 225.00 Standard Formi Powder, 80-mesh. Specifications> Pinkish white powder; assay (dry basis), 98.0% min.; solubility in 25% citric acid solution (1:5), complete; moisture, 10,0% max.; chloride (as MnCI:), 0.15% max.; sulfate (as MnSO,), 0.03% max.; free phosphate (as P.0,), 0.20% max.; conforms to N.F. test for heavy metals; 2.0% max. retained on 60 mesh screen, 4.0% max on 80 mesh screen, 10.0% max. oo 150 mesb screen. K.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, POTASSIUM (Solution) KjCjH*(OH)jPO< Standard Form: Solution 75%. Specifications! Clear, colorlesa or slightly yellowish solution; assay, 61.6 63.2% anhydrous salt; carbonate (as KjCOj), 0.50 % max.; chloride (as KCI), 0.10% max.; sulfate (as K;SO), 0.10% max.; free phosphate (as PsOt), 0.20% max.; conforms to N.F. test for heavy metals. R.R. Classification: Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM, N.F NaiCjH|(OH)aPO,. 5^HjO Mol. Vt. 315.15 Standard Format Crystals, 10-80 medi; powder. Specifications! 'White crystals; assay, 68.0 72.0% anhydrous salt (equivalent to 96.35 104.9% hydrated salt); solubility La wster (1:10), complete; chloride (as NaCI), 0.05% max.; free phosphate (as PjOi), 0.02% max.; conforms to N.F. test for heavy metals and sulfate (as NaiSO<); no crystals retained on 10 mesh screen, 40.0% min. crystals on 80 mesb screen. R.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM (Solution) NaCiHi(OH)J>0, Standard Formi Solution 75%. Specifications i Clear, odorless or slightly yellow solution; assay 50.0 52.0% (Continued) Page 68 Monsanto chemicals 0683808 TOWOLDMON0006683 WATER_PCB-00003193 hydrous salt; carbonate (as NajCOj) 0.5% max.; chloride (as NaCI) 0.10% max.; sulfate (as NaiSO*) 0.10% max.; free phosphate (as P]Ot) 0.15% max.; conforms to N.F. test for heavy metals. R.R. Classification] Chemicals NOIBN. GLYCEROPHOSPHORIC ACID (Solution) I!*C*H,(OH>iPO, Standard Form* Solution 35%. Mol. Wt. 172 Specifications! Clear, colorless liquid, APHA 20 max.; asaay 35.0 36.0%; chloride (as CaClj), 0.10% max.; sulfate (as CaSO<), 0.20% max.; calcium (aa CaO), 0.25% max.; free phosphate (aa PjOj), 0.35% max.; conforms to N.F. test for heavy metals. R.R. Classification! Chemicals NOIBN. ``GUANTAL" (See Accelerstocs. Rubber). H ACID (Monosodiurn-l-Amino-8-Naphthol-3,6-Disulfonate) OH NH* NaSOj SOsH Mol. Wt. 341.29 Typical Analysis! White powdet; 86-38% monoeodium salt; trace of NaCI and rSajSOi; solubility in water, complete. R.R. Classification] Dye Intertiaediate NOIBN. General Information! Used as so intermediate in the manufacture of dyestuffs. "HIBITITEn___________________________________________________________________ Standard Format Hibitite; Hibitite A, a commercial blend having half the strength of regular Hibitite. Propertiesi Derivative of an organic base; reddish brown powder; soluble in concentrated sulfuric and muriatic acids. R.R. Classificationt Iron or Steel Cleaning NOIBN. (Continued) 26TB BDtTION Page 69 0683809 TOWOLDMON0006684 WATER_PCB-00003194 General Information) Hibitite is widely employed in acids used for pickling and cleaning ferrous metals. It protects the metal by inhibiting the attack of the acid and by reducing the possibility of embrittlement caused by hvdrogen peoe (ration. Hibitite A is similar in act>on to Hibitite with the exception that it is more readily dispersed than Hibitite in making up the acid solutions. Sulfuric acid containing Hibitite is used for pickling tin plate, wire, alloy steels, sheets for galvanizing; for cleaning steel drums and sand filters; for pre paring articles for vitreous enameling; for removing metal coatings. Muriatic add containing Hibitite is used for cleaning boilers, economizers, beat exchangers, pipe lines, condensers, tanks, tubes, coils, screens, pans, drums and similar equipment. For steel pickling acid containing Hibitite, see Inhibited Acid. Available Literature: 4-page rnimtographed leaflet, "Hibitite and Its Uses." HYDROCHLORIC ACID, C.P HCI Mol. Wt. 36.46 Specificationst Colorless liquid free from suspended matter; strength 37.0 to 38.5%; non-volatile matter 0.0005% max.; sulphate 0.0002% max.; free chlorine 0.0002% max.; sulphite 0.003% max.; arsenic 0.00001% max.; iron 0.0001% max.; heavy metals (as lead) 0.0005% max. R.R. Classifications Muriatic Acid Ceneral Informations Laboratory reagent. HYDROCHLORIC ACID (See Muriatic Acid). 2-HYDROXY-3-METHOXY BENZALDEHYDE, TECHNICAL (Also known as rtA*vanillin.) A0 C--H Mol. Wt. 152.1 Characteristic*! Yellowish crystalline solid; crystallising point* 40.0C. min.; density, 1.20at60C.; wt. per gai., 10.0 lbs. R.R. Classifications Chemicals NO) BN. General Informations Used as an antioxidant and as an intermediate in chem ical synthesis. Page 70 MONSANTO CUlMIO.Lt 0683810 TOWOLDMON0006685 WATER_PCB-00003195 INHIBITED ACIDS Grades: These acids are solutioiis of Hibitile in Monsanto's commercial grades of 60cBfc. sulfuric acid, 66B. sulfuric acid, 18B. muriatic acid and 206B. muriatic acid. General Information; Addition of Hibitite to sulfuric and muriatic acids results in a decreased rate of attack of the acid on metal hut does not retard the action of the acid on surface scale on the metal. Inhibited sulfuric acid is used for pickling tin plate stock, pickling sheets for ftalvanizinz. preparing articles foi vitreous enamel, pickling wire, pickling high carbon Steel, removing metal coatings, cleaning steel drums and cleaning sand filters. Inhibited muriatic acid is ut-ed for pickling alloy wire and cleaning boiler tubes, condensers, pipes, beater coils and drums. INHIBITORS (See Hibitite). INKS, LACQUER BASE Ceneral Information; Lacquer links are rapid drying, waterproof, greaseproof, adherent, flexible, and resistant to abrasion. Colors are light, fast and opaque, glossy or dull. Adapted for printing or coating cellophane, glassine, foil and other wrapper stock. Application is by intaglio photo engraved roll printing ortlv, print roll being cleared by doctor blade. ' R.R. Classification; Lacquers. INSECTICIDES ortho-Dichlorobenzene (See under D). "Santochlor" (See under S). IRON CHLORIDE (See Fenic Chloride). IRON GLYCEROPHOSPH ATE (See Glycerophosphate, Ferric). IRON NITRATE (See Ferrie Nitrate). IRON PHOSPHATE (See Fcric Phosphate). IRON PHOSPHIDE (See Fetiopbosphorus). IRON GLYCEROPHOSPHATE N.F. (See Glycerophosphates), IRON SULFATE (See Ferrie Sulfate and Ferrisul). 2rn iditiok Pace 7) 0663811 TOWOLDMONOOO6686 WATER_PCB-00003196 IACQUERS--------------------------------------------------------------------- For information on special lacquers and related products offered by Monsanto tee tbe following listings elsewhere in this catalog: Acetone: Aircraft Finishes; Amyl Acetate: Belt Cement; Bronzing Liquids: Butyl Acetate; Butyl Alcohol; Cable Lacquers: Cements; Cotton Solutions; Diacetone; Ethyl Acetate; Inks. Lacquer Base; Leather Dopes; Manicure Lacquers; Mersol (Solvent Alcohol); Mertec; Textile Lacquers; Textile Printing Lacquers; Thirmers. General Information! The Lacquer and Sotvent Department of Monsanto has been engaged for twenty ye&ra in the development and manufacture of a wide variety of nitrocellulose base coalings for industrial use. At tbe present time Monsanto finishes for textiles, leather, paper, rubber, wood and metal are being used in practically all classes of industry. Specific information available on re quest. K.R. Classification: Lacquers. LACQUER COTTON (See Cott-on Solutions). LACQUER EMULSIFYING AGENTS (See Aresklene and Santomerse). LAMPBLACK Grades) Ten grades are available which vary in free carbon, deoaity, and oil absorption, Specifications! Grad* Ordinary Black Lampblack Bear Germantown Commercial Black Lampblack No. 10 Lampblack B*S Lampblack B*16 Lampblack BTA Lampblack S*100 Lampblack No. 8 Lampblack AA Fret Carbon 8{-.0% 97.20% 88.05% 99.11% 9V.20% 98.38% 98.23% 91.70% 91.03% 9(-.34% R.R. Classification! Lampblack NOIBN. Apparent Density Lb. per Cu. Ft. 25.4 7.76 25.4 12.11 7.76 6.75 6.30 5.72 5.15 4,77 Bensol Extract % 1.65 -- .20 1.65 .7 .6 .6 .65 .85 General Information! Used as pigment in paints, varnishes, enamels, inks, leather finishes, stencils, crayons, polishes; in pressed forms ss electrical conduc* tors and electrodes. Available Literature: Booklet, "Monsanto Lampblack." LATEX PENETRANTS (See Aresklene and Santomerse). LATEX STABILIZERS (See Aresklene and Santomerse). Page 72 tONSANTO CBBMICALS 0663812 TOWOLDMON0006687 WATER_PCB-00003197 LEATHER DOPES--------------------------------------------------------------------------------- . General Informations Nitrocellulose solutions specially formulated for the incorporation of plasticizer and pigment for use in finishing split, patent, and artificial leathers. H.H. Classifications Lacquers. LITHIUM SALICYLATE N.F. (See Salicylate*). "LUSTRON" (See Plastics). MAGNESIUM AMMONIUM PHOSPHATE (Also known as magnesium ammonium ortho phosphate.) __________________ MgNHP0t.6Hs0. Mol. Wt. 245.44 Standard Forms White powder. Properties! Insoluble in water and soluble in acids. Decomposes on heating. Gradei Technical. R.R. Classification i Chemicals NOIBN. Principal L'sesi As an ingredient In fire retarding paints for theatre scenery and curtains. General Information! A hexahydrate and a monohydrate form exist. At ordinary temperatures disaesociajion of the hexahydrate to the monohydrate takes place without appreciable loss of ammonia. Above 609C. the monobydrats loses NHj forming MgHPO4.Hj0. MAGNESIUM GLYCEROPHOSPHATE (See Glycerophosphates). MAGNESIUM PHOSPHATE, MONO -_____ _ (Also known as magnesium phosphate, monobasic; acid magnesium phosphate; magnesium tetrahydrogen phosphate; magnesium biphosphate.) MgH<(PO|)i Mol. Wt. 218.31 Standard Formi White crystals. Gradei Technical. 26TB EDITION (Continued) Page 73 0663813 J TOWOLDMONOOO6688 WATER_PCB-00003198 R.R. Classifications Chemicals NOIBN. Principal Uses* Used in pharmaceutical preparations. MAGNESIUM PHOSPHATE, TRI (Also known as neutral magnesium phosphate.) Mg<POb)i Mol. Wt. 262.88 Standard Forms White crystalline powder. Grades Technical R.R. Classificationt Chemicals NOIBN. General Informations Used in pharmaceutical products as an antacid. Page 74 MONSANTO CHEMICALS 0683BIA TOWOLDMON0006689 WATER_PCB-00003199 MAGNESIUM SALICYLATES (See Salicylates). MALEIC ANHYDRIDE 0 HC -c' Mol. Wt. 98.06 Standard Form: Fused solid. Specifications! While crystalline mass; crystallizing point 52.0C. min.; water solution (4 grams in 10 ml ), d.-ar and colorless; glyceromaleate resin, clear with slight amber color; iron 9.0005% nu *. It.R, Classification! Chemicals NOIBIS. General Information! Used alone or in combination with other acids in the manufacture of alk\d type resins. MANGANESE GLYCEROPHOSPHATE (See Glycerophosphates). MANICURE LACQUERS (Sn Lsctpun). MANICURE LACQUERS and REMOVERS______________________ General Information! Manicure lacquers are offered in two types -- tram* parent and creme. The dyes used in the transparent type are selected for stability to light,soapy water and ag*ng.The bottle appearance of tbe creme type lacquers is unusually good. There is no objectionable separation due to settling, and tbe lacquer applies without streaking. Tbe bottle color matches the applied lacquer very closely. Colors and shades are provided according to the suggestions and specifications of the customer, and the opportunity to assist in development of new shades is welcomed. For those who prefer to select from standard shades, the following are offered in Manicure Lacquer R-41H0 Creme and Transparent: Reddish Creme Shades Natural Rose Robin Red Tulip Sunrose Burgundy Old Rose Garnet Brotmiih Creme Shades Thistle Suntan Rust Chestnut Bluish Creme Shades Lilac Windsor Grape Heather (Continued) Transparent Natural Rose Garnet 26TR EDITION Page 7S 0663815 TOWOLDMON0006690 WATER_PCB-00003200 Manicure Lacquer Remover R*2522 is an active solvent and bas an agreeable i >dor. Containers) Can, 5 gal.; drums, 55 gal. Available Literature) Color cbip f<lder, "Monsanto Manicure Lacquers." "MERCLOR" (Sodium Hypochlorite)_________________ NaOCl Standard Form: Liquid. Typical Analysis: 22B6.; 12% available chlorine by volume K.R. Classification: Sodium Hypochlorite Solution. General Information: Merrlor is i>*ed as an oxidizing agent for bleaching cf vegetable fibers and as a chlorinating agent for water, organic compounds and wool. (See table in general data section) "MERSOL" Typical Analysis: Water white liquid: sp. g. 0.80 0.82 at 15.6C.; odor, mild, non*retidual; distillation range, 74s 80s C,; acidity, less than 0.005% as acetic acid. Composition: Alcobol, Special Denatured No. 1 Methyl isobutyl ketone Ethyl acetate, denatured withmethyl isobutyl ketone Gasoline 100 gala. 1 gaL 1 gat. 1 gal. R.R. Classification: Denatured Alcohol Solvent Containing Not Less Than 90% Denatured Alcohol. General Information: Mersol, a proprietary solvent alcobol, is formulated to have the advantages of Special Denatured Alcohol No. I without the necessity and burden of purchasing and operating under a government permit. It bas the mild odor of alcohol and no residual, Mersol may be used for most industrial purposes where SDA No. 1 ia indicated, as a solvent for shellac and soft manila gums, in lacquer tburners, cleaners, removers, polishes, dressings, inks, adhesives, celluloid, softeners, brighteners, and a a fuel and dye and stain solvent. Available Literature: 68 page booklet "Nealco Industrial Alcobol." "MERTANOL" Grade*: Mertanol SS; Mertanoi L; Mertanol 7L; Mertanol D; Mertanol 7D. (Omtinued) Page 76 MONSANTO CHEMICALS 0663916 TOWOLDMON0006691 WATER_PCB-00003201 Typical Analyses: Mertanol SS Mertanol L Mertanol 7L Tannin Acidity equivalent to Sp, Gr. Inorganic Salta 12% .64 .66 normal 19 20% 1.22 1.26 normal 19 - 20% neutral 2.66 2.74% Hj!5C>4 approx. 4.74% HjSOj pH 6* 8 1.176 1.178 1.205 1.212 1.214 1.225 8.2%Na,S04 11.4% (NH,),SO 18.8% (NH^O, Tannin Acidity equivalent to Sp. Gr, Inorganic Salta Mertanol D 19 20% 1.22 1.26 normal approx. 4.74% HtSO I.22 -1.23 II.4% (NH^O, Mertanol 7D 19 . 20% neutral pH 6 -8 1.23 - 1.24 18.8%(NH4),S04 Inorganic salt crystallizes out at temperatures below 40 I K.K. Classificationi Liquid Tanning Extract XOIBN. General Information* Mertanol is a synthetic tanning agent consisting of a naptbalene sulfonic acid condensation product in liquid form. The free sulfuric acid acidity has been completely neutralized and the sulfonic acidity neutralised to a definite acidity. L'sed In the manufacture of leather for bleaching of chrome tanned leather, bleaching base stock for making pastel leathers, for preplanning pickled stock before regular tan in order to maintain a lighter colored leather throughout the tannage, in vegetable tanning as an id to penetration of the extracts and solubil ization of noD>tans, in dyeing to give even dyeing and increased penetration of the dye, and as a mordant to hasten dyeing of chrome tanned and untanned leathers. "MERTEC** (Corrosion-Resistant Paint) . --. _ _ Mertec is a corrosion-resistant paint designed for use as a protective finish under severe acid and alkaline conditions. It is formulated on a chemically inert base and gives remarkable protection against acid fumes and caustie alkali attack. Mertec ia primarily for use on metal, but the inert base makes it a practical finish for concrete. It may also be used on wood surfaces. It gives a tough, glossy, oil and water resistant finish. Fire resistance is excellent; the paint does not support flsme trsvel. Heat resistance in continuous service is good up to about 200F. Mertec is supplied tn gray, rust, black, white and clear. Coverage is about 300 aq. ft. per gal. Pigmented Mertee R-3311 Gray 359 has the most desiiable general properties. It is flexible and adheres well to almost any reasonably clean surface. It should cover satisfactorily in one coat, particularly the gray color which ia recom mended for general mill use on exposed metal. Clear Mertee R-3300 is inferior t<< the pigmented type in weather resistance. It is also slightly less effective as a protective coating, and is recommended only where a pigmented finish is impractical. In using Clear Mertec R-3300 as a vehicle for aluminum, use about 1% pounds Aluminum Powder per gal. A (Continued) 26TR BDtTtON Page 77 0683817 TOWOLDMON0006692 WATER_PCB-00003202 ready mixed product, Aluminum Meitec R-3457, can be supplied. For outside exposure a prime coat of R-3137 Gray 326 iB recommended. Clear Mertec Topcoat R-3311 is a special type for application over ordinary painted surface* to give resistance to corrosion. Clear Mertec Topcoat also im parts greater resistance to corrosion when used over the Pigmented Mertec, and is especially recommended for use over Clear Mertec R-3300. Pigmented Mertec R-3799 is a special type for concrete floors. No priming oats or special preparation of the surface is necessary other tbaD cleaning off h>se grit and dirt and any accumulation of oil and grease. The surface should preferably be dry but damp surfaces can be successfully finished. From the standpoint of durability under traffic the concrete surface should be smooth. K.R. Classification! Lacquers. Available Literature! Leaflet, "Maintenance Paints.'' META-CHLOROANILINE (See meta-ChloroanUine under C). META-CRESOL (See meta-Cresot under C.) META-NITROCHLOROBEN2ENE (See meta*N'itrochlorobenzene under N). "METHASAiV* (See Accelerators, Rubber). METHYL PHOSPHORIC ACID (See Alkyl Phosphoric Adda). METHYL PHTHALYL ETHYI., GLYCOLATE(SeeSanticizer M-17). METHYL SALICYLATE U.S.P. (See Salicylates). MIXED ACID (See Nitrating Acid). MOLDING COMPOUNDS (S* Plaatics). MOLD PASTE ...................................................................................................... Specifications! Several materials blended to give a satisfactory combination of the properties necessary for use on molds for vulcanising rubber. Light brown colored paste; sp. gr., 1.54. (Continued) Page 78 Monsanto chemicals 0663818 TOWOLDMON0006693 WATER_PCB-00003203 T R.R. Classification! Chemicals NOIBN. Available Literature! 42-page booklet "Monsanto Chemicals for the Rubber Industry". MONOAMMONIUM PHOSPHATE(5ee Ammonium Phosphate, Mono). MONOCALCIUM PHOSPHATE (See Calcium Phosphate, Mono). MONOCHLOROBENZENE (See Chlorobenzene). MONOMAGNESIUM PHOSPHATE (See Magnesium Phosphate, Mono). MONSANTO PLASTICS (&* Plastic). "MONSANTO SALT" (oriVio-Chloro-para-Toluene Sodium Sulfonate)_______________ _______________________________ (Also known as 3-<hloro-4.methyI benzene sodiumsulfonate). CH. Mol. Wt. 228.63 S-ONa 'v oo Characteristicai Light gray to light tan powder; assay (from Cl content), 97.0 100.5%; NaCI, 0.5% max.; n,<oisture (HjO), 1.0% max. R.R. Classifications Dye Intermediate. General Informations Used in dyestuff synthesis. MURIATIC ACID (Hydrochloric)_______________ HCI Grades! 18 B<; 20 B4; 22" B6. Typical Analysis* 18 B., 27.9% HCI.; 20* B6., 31.5% HCI.; 22 B6., 35.2% HCI. R.R. Classifications Muriatic Acid General Informations Used extensively in the starch, glucose, steel, galvaniz ing, paper, leather and glass industries. (See table in general data section) 26TB EDITION Page 19 0683819 TOWOLDMONOOQ6694 WATER_PCB-00003204 "NEALCO" ANTI-FREEZE_______________________________________________ General Information: A completely denatured ethyl alcohol type anti-freeze fluid for automobile, airplane and other gasoline engine cooling system*. Will not mrrode the radiator, form rust, Kludge or sediment; will not cause leaks nor attack hose connections. R.R. Classification i Anti-freeze Alcohol. NITRATE OF IRON, COPPERAS (See Ferric Sulfate). NITRATE OF IRON, TRU1.I (See Ferric Nitrate), NI ATING ACID (>ILx T>1' il Analysis: Nitric Acid (HNOj) Sulphuric Acid (H,SO<) Oxides of Nitrogen (NjOj) 80.15 80.0% 15.0% 0.25% 85-12 85.0% 12.0% 0.25% i8 60.0% 38.0% 0.25% 45-53 45.0% 53.0% 0.25% R.R. Classification: Nitrating Acid. General Information: Mixed acid is used for nitrating in the chemical industry, particularly in the manufacture of explosives and dyestuffs. Special mixtures can be furnished to meet individual requirements. {See table in general data section) NITRE CAKE (Sodium Bisulfate) Standard Forma: Bulk; ground; globular. Typical Analysis: 35% HfSO available. R.R. Classification: Nitric Cake. General Information: Used to replace either sulfuric acid or combination of sulfuric acid and Glauber's salt. One buudred lbs. of Nitre Cake ia approximately equivalent to 35 lbs. of t>60 sulfuric acid and 141 lbs. of Glauber's salt. Used principally in viscose rayon spinning baths; dyeing woolen goods: re fining nickel ores; manufacture of sulfate pulp; in tanneries for pickling, deliming and making one bath tan solutions; s an acid scour for household use; in agri culture for disinfecting soil; as a bowl cleaner in sanitary trade. Page 80 MONSANTO CHEMICALS 0663820 TOWOLDMON0006695 WATEFLPCB-00003205 T NITRIC ACID IINO, Standard Format 36 B., 38 Bt*,, 40 Be., and 12 Bi. Typical Analysis! %HNOj: 36Btf., 52.3: 38B. 56.5: 40Bf, 61.4: 42B., 67.2. Sp. g. will not vary more than 0.,5* terms of B. HjSOt 0.1% max.; HCI 0.1% max. For higher strengths refer io Merrimac Division Sales Office. K.K, Classification! Nitric Acid. General Informaliont Used in the manufacture of insecticides, dyestuffs, drugs, pharmaceuticals, explosive^, photo engravings, nitrates and other nitro products. (See taWe in genera/ data section) NITRIC ACID C. P. HNOj Mol. Wt. 63.01 Typical Analyaiai Colorless Iquid, free from suspended matter; strengthfHNO*), "0.0 to 71.5%; non-volatile matter, 0.0005% max.; sulphate (SO<) 0.0002% max.; chloride (Cl), 0.00007% Qiax.; arsenic (As), 0.000003% max.; heavy metals (as lead), 0.0005% max.; heavy metals (as iron), 0.0001% max. R.R. Classification! Nitric Acid. General Information! Laboratory reagent. l-NITRO-2, 5-DICHLOROBENZENE (Also known as 2, 5-dichloronitrol-enaene.) NO* Cl Mol. Wt. 192.01 Standard Formi Fused solid. Specification*! Light yellow to light brown crystalline solid; crystallising point. 52,5SC. min. R.R. Classification! Dye Intermediate. General Information! Used as ai> intermediate in the preparation of dyestuffs. CAUTION: This product it toxic Avoid breathing it* vaport and ovoid contact with the kin. 24m IDITION Page 81 0683821 TOWOLDMON0006696 WATER_PCB-00003206 ort/io-NITROANILINE_____________________________________________ (Also known as ortfcu.aminoniirobenzene and I-aminn-2-nitmbenzrnc.) N0| Mol. Wt. 138.12 Standard Forms: Powder: powder with 0.5% triralrium phosphate. Specifications! Yellow to orange powder; m. p. 70.0'C. min. Assay: powder, min.: p<>w<ler with triraMum phosphate, 98.50% min. Ash: powder, 0.25% max.: powder with tricalrimn phosphate, 0.75% max. ICR. Classification: Dye IntertiK'diate. Ceneral Information: ortho. Mirouniline powder has a tendency to "set up" in lumps on standing. It is recommended that it be milled Jo proper fineness just before using. The addition of 0.5% tricalcium phosphate reduces the caking tendency. ortAo. Nilroaniline is used as an intermediate in the preparation of dyestuffs. CAUTION: This product is toxic. Avoid breathing its dust and avoid contact with the skin. para-NITROANILINE NHt Mol. Wt. 138.12 NO, Standard`Form: Powder, Characteristics: Bright yellow crystalline powder; soluble in HC); ns- p. lAS'C. min.; assay 99% min. R.H, Classification> Dye Intermediate. "Poison" label required. Ceneral Information: Intermediate in dyestuff syntheses. CAUTION: This product is toxic. Avoid contact with thin. Avoid inhaling vapors. ortho- NITROANISOLE___ _________________________ __ (Also known ss ortho-aminoanisole, ortho-nitrophenylmetbylether and 1-methnxy-Z.nitrobenzene. OCH, 'i NO* Mot. Wt. 153.14 Page 82 Standard Form: Liquid (Continued) MONSANTO CBS MIC A LS 0683622 TOWOLDMON0006697 WATER_PCB-00003207 Specifications! Light reddish or light amber liquid; crystallizing point, 9.6C. min., dry basis. Distillation range: first drop 270.0C. min.; 95% 2.08C. max.; dry point 273.0C. max. Nitropbeuol 0.05% max. R.R. Classification! Dye Intermediate. General Information i ortAo-NitroanisoIe is used in the production of such dye intermediates as ortho-snisidine ad dianiiidine. It is also used in various or ganic syntheses. CAUTION: Thi,t product is toxic. Avoid breathing Us vapors and avoid contact with the skin. NITROCELLULOSE SOLUTIONS (See Cotton Solutions). meta-NITROCHLOROBENZENE ____________________________ (Also known at maSa-chloronitrobeneene and 1 chloro-3-nitrobenzene.) NO, Mol. Wt. 157.50 Standard Form i Fused solid Specifications! Greenish yellow crystalline maw; clear when melted; crystallis ing point 43,9*0. min. R.R. Classification! Dye Intermediate. General Information! Used for tonversion into various dyestuff intermediates, chloroanilinse and chlorobensidines. CAUTION: This product is toxic. Avoid breathing Us vapors. Avoid contact with the skin. ort/u>-NITROCHLOROBENZENE_____________________ (Also known as ortAo-cblorooitrobrnzene and l-chloro-2-nitrobenxene.) Cl 'l NO, MoL Wt. 157.50 Standard Formi Fused solid Specifications! Creeaiah yellow crystslline mass; crystallizing point 31.7C. (on sample as received). R.R. Claeeiflcatiom Dye Intermediate. General Information! (Jecd la the preparation of dyestuff intermediates. CAUTION} This material is toxic. Avoid breathing Us vapors. Avoid contact ustk the skin. 26TH BDITION Page 85 0663623 TOWOLDMON0006698 WATER_PCB-00003208 para-NITROCHLOROBENZENE___________ __________ (Also known as ^tara-ohloroni tmbernne and l-chlor'>4'oitrobenzeiie.) NO. Cl Standard Form > Fused solid Specifications: Light greenish yellow solid; crystallizing point 82.SC. min. H.R. Classification: Dye Intermediate. General Information: />ara-Nitrob<'nzene is used in the preparation of dyestuff intermediates. CdL'T/ON: This pioducl is toxic. Avoid breathing Us vapors and avoid contact with the skin. ort/to-NITRODIPHENYL, TECHNICAL NO* I 0-0 Mol. Wt. 199 Characteristics: Light yellow to reddish crystalline solid; crystallising point 34.5C. min. R.R. Classification: Dye Intermediate NOIBN. General Information: Used as an intermediate in chemical synthesis where it is useful in some applications as an alternate for substituted nitrobeozenes. May be partially reduced and rearranged to give 22'*dipbsnyl benzidine (NH*-=1). "NITRON" (See Plastics). mira-NITROPHENOL (Also known as paro*bydroxynitrobea;eos and l-bydroy*4-nitrobeozene.) OH Mol. Wt. 139.11 NO, Standard Form Granules Specifications l Brown granular mas*,: tn. p. (dry basis) 112.0C. min.; assay, 96.5% min.; water insoluble material 0.20% max.; alcohol insoluble material 0,20% max. (Cw.ufnuf) PagS 84 MONSANTO CHEMICALS 068382< TOWOLDMON0006699 WATEFLPCB-00003209 R.H. Classification! I)ye Intermediate. General Information! paro-Nitrqphenol has the following uses: as ao inter* mediate in the production of dyestuffs and photographic chemicals such as pore* aminophenol and methyl para-aminopbenol; as a fungicide to prevent mold growth on chrome tanned leather. CAUTION: This product is toxic. Avoid breathing its tiust or vapors and avoid contact with tht skin. OIL ANTIOXIDANTS (Sre Stntolube). OIL OF VITRIOL (See Sulfuric Acid). OLEUM (See Sulfuric Acid). "OPALON" (See Plastics). ORTHO-AMINODIPHENYL (See ortho-Aminodiphenyl under A). ORTHO.ANISIDINE (See ortho*Aaieidine under A). ORTHO-CHLOROANILLNE (See ortho-Chloroaniline under C). ORTHO-CHLORO-PARA-TOtUENE-SODIUM-SULFONATE (See Monsanto Salt.). ORTHO-CHLOROPHENOL (See onho-Chloropbenol under C>. ORTHO-CRESOL (See ortbo*Cre*ol under C). ORTHO-DICHLOROBENZENE TECHNICAL (See ortbo-Dichloro. benzene Technical under D). ORTHO-NITROANILINE (See ortho-Nitroaniline under N). ORTHO-N1TROANISOLE (See ortbo-Nitroanieole tinder N). 26TB BDITION Page SS 0683825 TOWOLDMON0006700 WATER_PCB-00003210 ortho-nitrochlorobenzene (See ortbo-iNitrochloiobecueae under N). ORTHO-NITRODIPHENYL (See ortbo-N'itrodipbenyl under N). ORTHO-PHENETIDIN (See ortbo*Pbenetidin under P). "OXYNONE" (See AmioKidaote, Rubber). PAINT, acid and alkali reaiaUnt Tor plant maintenance; (See Mertec). PAINT ANTISKINNING MATERIALS* available to fit varied trade requirement*; (See Santovar A). PAPER LACQUERS (See Lacquer*). PARA-AMINODIPHENYL (See para-Aminodipbenyl under A). PARA-ANISIDINE (See pira<Aniiidine under A). PARA-CHLOROANILINE (See para-Chloroaniline under C). PARA-CHLORO-META-CRESOL (See p*fa>Cbloro.meta>Cre*oI under C). PARA-CHLORO-META-XY LENOL (See para-Chloro-meta-Xylenol under C). PARA-CHLOROPHENOL (See para-Chloropbenol under C). PARA-CRESOL (See paia>Cre*>l under C). PARA-NITROANILINE (See para-Nitroaniline under N). Page 86 Monsanto chemical* 0683826 TOWOLDMON0006701 WATER_PCB-00003211 PARA-NITROCHLOROBENZKNE (See para*i\itrochloroberuene under N). PARA-NITROPHENOL (See para-Nitrophenol under N). PAR A-PHENETIDIN (See para.l'lienriidin under P). PARA-TOLL'ENESL'LFONAM IDE (See pura-Tnluenesulfonamide under P \RA-TOLLENESULFONCH|-ORIDE (See para-T(jlueneuhfur>> chloride under T). PENETRATING AGENTS (See Areskap, Aresket. Aresklene. SantoraeraeX. PENTACHLOROPHENOL (Set Santophen 20 and Permasan). PERCHLORIDE OF IRON (S< Ferric Chloride Solution). "PERMANOL" _____________ ________________________________ Grade# t Permanol; Permanol 7. Propertleai Viscous liquid. Inorganic salt crystallizes out at temperatures below 40 F. R.R. ClasalBcatiom Liquid Tanning Extract NOIBN. General Information t Permanol is *. synthetic tanning agent in liquid form. It bas the special property of being eciremely ligbtfsst. Information on uses for Merlanol applies. See Mertaool, "PERMASAN" Gharacteristicai Consists of 5% ptotachiorophenol, min., 5% nonvolatile solvent and 90% petroleum distillate; light amber color, lesa than 4.5 NPAS; characteristic petroleum odors flash pqint, 140F. min. by Tagliabue closed cup method; sp.g. approx. 0.8785 at 1S.5C.; wt. per gal., 7.2 lbs. (Continued) 26TB edition Page 87 0663827 TOWOLDMON0006702 WATER_PCB-00003212 R.R. Classifications Liquid Wood Preservative NOIBN. General Informations Used for preservation of wood against termites, Lytxus (powder-post) beetles, decay, and wide range of other wood-attacking insects and organisms. Does not adversely affect the feel and appearance of wood, and surfaces properly treated may be satisfactorily glazed, painted or otherwise fin ished. Permasan conforms with the specifications of the Western Pine Associa tion's Bulletin No. 6 (revised) and Is accepted by the National Door Manufact urers Association. Permasan is irritating to the skit! and mucous membranes if sufficient contact is permit ted. The precautions for handling given in literature listed below should be observed. Available Literaturei 6-page Monsanto Technical Bulletin 0-20, "Permasan for the Preservation of Seasoned Wood." 5-page Monsanto Technical Bulletin 0-14, "Permasan for Lyclus (Powder-Post) Beetle Control.'* "PERMASAN 116" Characteristicst Consists of 5% pentachlorophenol, min., and 95% mixture of water repellents, organic solvents and diluents; light amber color, less than 4.5 NPAS; mild, not unpleasant odor; flash point, 10OaF. min. by Tagliabue closed cup method; up. g. approx. 0,855 at 15.5C.; wt. per gal., 7.13 lbs. R.R. Classification! Liquid Wood Preservative NOIBN. General Information! Used same as ordinary Permasan (see above) except gives added advantages of water repellency. Conforms with specifications of Western Pine Association's Bulletiii No. 6 (revised). Permasan is irritating to the skip and mucous membranes if sufficient contact is permitted. Tbe precautions for handling given in literature listed below should be observed. Available Literature! 8.page Monsanto Technical Bulletin 0-21, "Permasan 116 A Water-Repellent Preservative for Wood." PETROLEUM CHEMICALS (See Santolene, Santolubes. Saatopoid, Santopour). PHENACETIN (See Acetophenetidin). ort/to-PHENETIDIN _______ (Also known as ort/w-aminophenyIdbylether, ortAo-aminophenetole. and 1-amino-2-etboxybeiuene. (Continued) Page88 Monsanto cbiwicals 0683326 TOWOLDMON0006703 WATER_PCB-00003213 Standard Form! Liquid Specifications! Dark red liquid: crystallizing point (as received) --4.09C. min. Distillation range: first drop 231.0'C. min.; 95% (1-96 ml.), 2.0C. max,; dry l>nint. 234.0C. min. Solubility in IICI, complete. It.li. Classification! Dye Iniermtdiate. General Information! ort/io*Phnetidm is used as an intermediate in the production of dyestuffs. CA VTfO\: This product is toxic. Avoid breathing its Kiporj and contact with the skin. poro-PHENETIDIN ________ ___________________.. (Also known as paro*aojinophenyletbylether.pora-animopbenetole, and l*amino*4 dhoxybenzene.) OCH NHi Standard Formt Liquid Specifications! Dark red liquid; crystallizing point (as received) 4.09C. min. Distillation range: first drop 248.0C. min.; 95% (1*96 ml.), 2.0C. max.; dry point 251.0C. max. Solution in HO, opalescent. R.R. Classification! Dye Intermediate. General Information! para-Phepetidin is used as an intermediate in the pro* ductton of dyestuffs and pharmaceuticals. CAUTION: This product it toxic. Avoid breathing its vapors and contact with the skin. PHENOL-FORMALDEHYDE RESIN (See Plastics, Resioox). PHENOLIC RESIN, CAST (See Plastics, Opaloo). PHENOL ______________________________________________ (Also known as carbolic acid and hydroxybenzene.) OH Mol. Wt. 94.11 26TB EDITION (Continued) Page 89 0683829 I TOWOLDMON0006704 WATER_PCB-00003214 Standard Forms! Crystalline solid, U.S.P.; l:quid 85%; liquid 88%. Specifications of Crystalline Solid, U.S.P.: White crystalline solid; melt, colorless mobile liquid: solution in water (1:15), clear and colorless; non-volatile residue (100C.). 0.04% man.: crystallizing point 40.0C. min. Distilling range: first drop, 180.0C. min.; 100% (first drop to dry point), 2.0CC. max.: 50% to dry point, 0.2C. max. Specifications of Liquids: Colorless mobile liquids. Assay: liquid 85%, 85.0- W*.U%; liquid 88%. 88.0.80.0%. ' R.R. Classification! Phenol. General Information > Used as an intermediate for the production of dyestuffs; in production of resins for molding and in the preparation of varnishes, enamels, lacquers and paints; as a selective solvent in the manufacture of lubricating oils; as a disinfectant; in textile printing; in the production of explosives, synthetic tanning materials, pharmaceuticals and medicinals, antiseptics, germicides and preservatives, deodorants, soaps, embalming fluid, vermin exterminators, rubber compounds, and photographic chemicals. PHENOLPHTHALEIN, U.S.P. OH OH Mol. Wt. 318.31 Standard Form: Powder. O Specifications: White powder; m.. 259.0C. min.; solubility in alcohol (1:15), complete; acidity (cc's N/1000 IVgOli/2 g. sample), 3.0 cc. max.; tab 0.05% max.; arsenic 0.001% max.; conforms to U.S.P. test for fluorine and heavy metals; trace max. retained on 100 mesh screen: 21.0% max. on 325 mesb screen. R.R. Classification: Chemicals NOIBN. General Information: Used in pharmaceutical preparations. PHENOLPHTHALEIN, YELLOW, Not U.S.P Standard Form i Powder. Specifications: Yellow powder; ro.p. 257.0C. min.; loss on drying, 0,S0% max.; ash, 0.10% max.; acidity (cc*s N/1000 sodium hydroxide per 2 gm. sample), S.O cc max.; solution in etbyl alcohol 95% (1:15), clear; sp. g. (apparent) 0.500 0.600; none retained on 20 mesb screen. (Continued) Page 90 IONS A NTO CHBMICAI.S 0683630 TOWOLDMON0006705 WATER_PCB-00003215 K.K. Claaaification: Chemicals >OIBN. (General Information: Used in pharmaceutical preparations. PHENOL-FORMALDEHYDE (See Plastics, Resinox Molding Com* ...... nds). PHENYL SALICYLATE (See Salicylates). PHOSPHATES (See Ammonium Phosphate. Calcium Phosphate, Magnesium Phosphate, Potassium Phosphate, Sodium Phosphate) PHOSPHOLEUM (See Tetraphoephoric Acid). PHOSPHORIC ACID (Orthophosphoric Acid) HsPO Mol. Wi. 98.004 Standard Format 50%, 75% and 85% H3PO4. Other concentrations supplied in request Specifications! Clear, water-white liquid miscible with water in all proportions. Grades) U.S.P.; food, meeta al! U-S- Pure Food Law requirements; commercial, clear water white liquid; Phosilage, meets ail U.S. Food Law requirements; special. U.lt. Classification) Phosphoric Acid. General Information: Principal uses -- Ceramics; To increase translucency and improve the color of porcelains; as a vitrifying agent and flux. Chemicals and Intermediates: In manufacture of sodium phosphates, calcium phos phates, and other phosphates; in manufacture of ethylene gas; in making albumen derivatives. Aa a drying agent in th synthesis of various intermediate chemicals. Dyes: As a drying agent in the synthesis of various dyes. Engraving; In pro cess engraving and litbo trades. Envelopes.' As a penetrant to aid in the ab sorption of the gum. Fertilizers; In manufacture of double and triple auper. phosphates; in manufacture of ammonium phosphate. Gelatin: In manufacture of gelatin. Glass: Aa opacifier. Jelly and Preserves: As a substitute for tar taric and citric acida. A/etuis: For pickling and cleaning. Pharmaceuticals: In manufacture of certain pharmaceutical chemicals; in making dental cements; in manufacture and purification of hydrogen peroxide; in manufacture of glycero phosphates. Rope and Twine: For brightening the finish. Rubber: Aa a coagulant of rubber latex. Rust Proofing: In the manufacture of rust proofing compounds. Silage; For silage pteservation. Soft drinks: Aa a substitute for (Continued) 16TB EDITION Page 91 0683831 TOWOLDMON0006706 WATER_PCB-00003216 tartaric and cilric acids. Sugar: A# a defecating and clarifying agent. Textile): In brightening the color of silk; in the dyeing of cotton; in calico printing, iFoler treatment: In water softening and correction of alkalinity. !5C Density and Composition of water solutions of Orthophosnhoric Acid @ ~j-;-- Density Decrease g./cc. per 1C. %HjP04 %PA %P U0 1.150 1.200 1.250 1.300 1.339 1.350 1.400 1.450 0.00030 0.00035 0.00045 0.00050 0.00055 O.OOOS5 0.00060 0.00060 0.00060 17.52 25.25 32.52 39.22 45.51 50.00 51.22 56.85 62.27 12.69 18.29 23.55 28.41 32.96 36.21 37.10 41.17 45.10 5.54 7.98 10.28 12.40 14.39 15.81 16.19 17.97 19.68 1.500 1.550 1.581 1.600 0.00065 0.00070 0.00077 0.00075 67.35 72.11 75.00 76.7S 48.78 52.23 54.32 55.59 21.29 22,79 23.71 2 4.26 1.650 0.00075 81.30 58.88 25.70 1.693 0.00080 85.00 61.56 26.87 1.700 0.00080 85.63 62.02 27.07 1.750 1.800 1.850 0.00080 0.00080 0.00080 89.88 94.15 98.13 65.10 68.19 71.07 28.41 29.76 31.02 1.874 0.00080 100.00 72.43 31.61 The density of more concentrated acids increases approximately linearly (within the range 72.44% to 85% PjOj) with the excesa PjOj over 72.44% according to the equation: Density 1.874 + 0.0171 (%P,Oi -- 72.43). PHOSPHORIC ANHYDRIDE (See Phosphorus Pentoxide). PHOSPHORUS, ELEMENTAL ( Also known as yellow phosphorus and white phosphorus) Gradeat Monsanto process of manufacture provides over 99.9% purity. Properties! Light yellow, wax-like, semi-transparent solid; bums spontaneously in air to form PiOi; m.p. 44.1C.; insoluble in water but very soluble in carbon bisulphide. R.R. Classificationi Phosphorus, Yellow. General Informations Used in manufacture of phosphorus alloys, phosphoric anhydride, phosphorus compounds, phosphoric acid, rodent poisons, flares, smokescreens, etc. PHOSPHORUS OXYCHLORIDE _____________ (Also known as phoaphoryl chloride). POO* Page 92 Mol. Wi. 153.35 (Continued) IONSANTO CHEMICALS 0683832 TOWOLDMON0006707 WATER_PCB-00003217 Standard Forms Liquid. Specifications: Water.white to yellow liquid; crystallizing point 0.8C. min.; assay 99.0% min. Distillation range: first drop, ll)6.0C. min,; 95% (1-96 ml.), l.5C. max.; dry point, 1U8.5C. max. PCIj, 0.20% max.; PCIj, trace max.; HjPCV 0.30% max.; HCI, 0.50% max.; free chlorine, trace max.; iron, 0.0005% max. R.R. Classification: Phosphorus Oxychloride. General Information: Used ss a chlorinating agent and catalyst in the prep* aration of various intermediates and dyestuffs and as a reagent in the prepara* lion of acetic anhydride and organic phosphates. CAL'T10\: Care must be ex ercised in handling tkii product. Avoid breathing its vapors; avoid contact u ith the skin, it reacts usilh water with explosive violence. PHOSPHORUS PENTOXIDE (Also known as phosphoric anhydride; phosphoric oxide; solid PjOj.) P,0S Mol. Wt. 141.96 Standard Form: White amorphous powder. Characteristic* t Vapor Pressures: (after J. C. Southard and R. A. Nelson--J.A.C.S. 59. 911 (1937) p = vapor pressure in cm. of mercury. T =* absolute Temperature). A (low temperature form) Logiop = 9.792--(5000/T) B (high temperature form) Logtop = 11.113--(7930/7) L (liquid) Log,0/> -- 6.809--(4320/T) Atmospheric sublimation temperat ure; 358.9C. Beat of vaporization: A--22,800 calories per gm. molecule. B--36,200 calories per gm. molecule. L--19,700 calories per gm. molecule. Heat of fusion: 16,500 calories pe: gm. molecule. Probable molecular formula of vajor: P4Ou. R.R. Classification i Phosphoric Anhydride. General Information: Used in the manufacture of organic and phosphorus compounds and at a cayalyat. It is a vigorous drying and dehydrating agent. PHOSPHORUS TRICHLORIDE PCIj Mol. Wt. 137.3S Standard Form: Liquid. Specificationsi Water white liquid: sp. g. at 15.5/15.59C., 1.582*1.587. Die* (Continued) 26TB EDITION Page 93 0683633 TOWOLDMON0006708 WATER_PCB-00003218 tilling range: first drop .Tf-o'C. min.: d*v point. 79.0*C. max,; total range, 3.0C. max. K.K. Classification] Phosphorous Trichloride. General Information! Used as a chlorinating agent and catalyst in the prep* araiton of variovts intermediates and dvtstuffs; as a reagent in the preparation >f acetic anhydride and organic phosphates; in the manufacture of phosphorus oxychloride and phosphorus pentachloride; and in producing iridescent metallic deposits. C {L'TIOX: Care must be exercised in handling this product. Reacts it ah ii ntcr. -iiaid breathing its vapors; avoid contact with the skin. PHTHALIC ANHYDRIDE Mol. Wt. 148.11 Standard Formi Flakes Grades! Three grades with crystallizing points of 131.2C.. 131.0C., and 130.7C respectively. Specifications: White flakes; solution in benzene {1:20) clear: ash 0.03% max. Maleic acid: 131.2C., 0.10% max.; 131.0C., 0.15% max.; 130.7C., 0.15% max. R.R. Classification! Phthalic Anhydride. General Information i Uses: As an intermediate in the production of dyestuffs, perfume bases, alcohol denaturants, pharmaceutical products, plasticizers--such as dibutyl phthalate, dimethyl pbthalate, diethyl pbthalate, phtbalyl glycollatee --and alkyd resins. PHTHALYL CHLORIDE COCI COCI Mol. Wt. 203.03 Standard Formt Liquid, Choracteristicai Yellowish liquid; assay, 95.0% min.; crystallizing point, 7.5C. R.R. Classification! Chemicals NOIBN. Corrosive liquid (white label required). General Information! Used in the manufacture of plasticizers and resins. PICKLER'S ACID (See Inhibited Acid). Page94 Monsanto cbbmicals 0683834 TOWOLDMON0006709 WATER_PCB-00003219 PIPERIDINE ____________________ (Also known as hexaltydropyridine). Mol. Wt. 85.14 Standard Form: Liquid Specifications: Clear, water-white liquid of characteristic odor; assay, 98% min.; pyridine, 1.0% max.; sp. g. 25,25'C., 0.860 - 0.005. Distillation range: 104.0C(J. min. start; 107.0C. max. dry point. K.li. Classification: Chemicals fS'OIBN. General Information*. Ced as at.i intermediate in the manufacture of phar maceuticals, wetting agents, end getmicideB. "PIP-PIP" (See Accelerators, Rubber). PLASTICIZERS (See Santicizrrs. Dibutyl Pblhalate, Diethyl Phthalate, Dimethyl Phthalate. Diphenyl Phthalate, Tricreeyl Phosphate, Triphenyl Phosphate). PLASTICS (See individual materials below.) p-- CAST PHENOLIC (See Plastics, Opalon). CELLULOSE ACETATE (See Plastics, Fibestas). CELLULOSE NITRATE (See Plastics, Nitron). "FIBESTOS"* (Cellulose Acetate) The most widely-used thermoplastic, cellulose acetate, ia distinguished by a flexible range of properties and formulations. In the form of molding compounds, Fibestos is adapted to either compiession or injection molding. Sheets, rods, tubes and continuous length rolls ate other forms in which it is produced by Monsanto. Mechanical Properties: Specific gravity.....................................................................1.27 1.37 Specific volume, cubic inches per pound.................... 20.2 21.8 {Continued) 26TH EDITION Page 95 0683835 PLASTICS TOWOLDMON0006710 WATER_PCB-00003220 PLASTICS Hefraetivc index .\ t> ........................... ........... 1.17-1.30 Tensile strength, lbs. sq.in..................... 3,301) - 11.000 i.lnrigntion, percent ............................................ . . 3-3.3 Ihirsting sirriii'il) (rupture) lbs. sq.in., uil.. . .18.33 Mud id ns of rl a. i icily, lbs. -q.in x 105........................1-3.5 Impact strength, 1/ ul, f(. llis, in. of mid ( \.S.T. M.) .................................................... 0.7-4..' Ilrindl hardness, 2.3 mill, ball 10 kg. load . . . .0 . 13 Kockui'll hardness ............................................................ M25 * M33 Mac 11 in lie; qualities............................................................(hxxi Mnldiim Properties: 1 vpe........................................................................................ Thermoplastic Molding qualities............................................................ I'.xecllent Molding Temperature F. (aiiiiprcssinii............... .............................................210 - 350 Injection................................................................... 300 - I 10 Molding Pressure llx. sq. in. Compression.................................... ........................ 300 - 3000 Injection............................................. . . ,0l)0 - 3000(1 Preforming......................................................... Tendency toroid llou ............................... . . . Verv r'oorl Sligbl'~ PKee>`iiiK eellnlnse nt Springfield plant for manufacture of .Monsanto plastics. 0683836 TOWOLDMON0006711 WATER_PCB-00003221 w Molding methods applicable........................................... Compression, injection, triuion, aging Mold shrinkage, inches/nch: Pottive......................... 002 - .003 Semi-positive...............005 .007 Flash.............................. 008 . .009 Extruding quality.................................................................Excellent ex* Thermal Properties: Huming rate, in. min. (.060*) ......................................1.5 2.0 Slow burning Thermal conductivity, 10--* calories/sec./sq.cm./ C. cm...................................................................... 4.5 7.8 Specific heat. calories/C. gram..................................... 0.3 0.4 Thermal expansion, 10--} C........................................ . 10 16 Resistance to heat, F. (continuous)............................ 140 250 Softening point. F...............................................................140 260 Effect of heat, dry .......................................................... Little or none moist........................................................... Slight spelling Heat distortion, F. (A.S.T.M.).....................................122-212 Electrical Properties: \ tihime resistivity, ohms-ems. (5')%R.H. and 25C.)......................................................................... (0.7 1.4)xl0* Breakdown voltage, 60 cycles volts mil......................600 1.800 Dielectric constant, 60 cycles..........................................3.5 - 7.5 10 cycles........................................2.0 5.0 Power factor, 60 cvcles................................................... 0.007 0.07 10 cycles.................................................... 0.007 - 0.03 Chemical and Physical Propet ties: Odor............................................................ .... a. Taste................................................................ Effect of age......... ........................................ Effect of sunlight ....................................... Effect of ultraviolet light.......................... Effect of metal inserts............................... Effect of weak mineral acids................... Effect of strong acids............................ . Effect of weak alkalis .............................. Effect of strong alkalis ............................ Water absorption 24 hours...................... Solubility: Softens in-- ....................... Swells in-- ......................... Insoluble in--......................... None to mild aromatic None Slight Gradually become brittle-- some colors fade Gradually become brittle-- some colors fade. None Fair resistance Decomposes Slight Decomposes 1.5*3% Alcohols, esters Chlorinated hydrocarbons Aromatic and aliphatic hy drocarbons, animal, mineral, and vegetable oils, ethers Colon Available in an extremely wide variety of transparent, translucent, pastel and opaque colors, as well as in many mottles, pearls and decorative configurations. Format Sheets, rods, tubes and molding compounds. Trade Mark Reg, U. S. Pat. Ofl. 26TH EDITION Page 97 0663837 TOWOLDMON0006712 WATER_PCB-00003222 PLASTICS- T "LL'STRO.N"* (Polystyrene Molding Compounds) Lustron is Monsanto's formulation of polystyrene molding compound, Tbe rapid expansion of uses for Lustron since its introduction in 1939 is excellent proof of its versatility and broad range of useful properties. It is unexcelled among thermoplastics for electrical characteristics, chemical resistance, low moisture absorption and dimensional stability as the following table of properties indicates Molding quality .................... ............................................Excellent Compression molding temperature, F..................... .275 330 Compression molding pressure, Ibs./sq.in................... 1000 5000 Injection molding temperature, F................ ............... 300 500 Injection molding pressure, Ibs./sq.in. ...................... 10,000 and up Compression ratio.................... ........................................ -.0 2.3 Mold shrinkage.....................................................................Compression 0.002 0.005 in. per in. Injection 0.002 0.D0H in. per in. Specific gravity ...................................................... . 1.054 1.070 Specific volume, cu.in./lb........................................... 16.3 25.9 Refractive index .................................... .................. . 1.59 Tensile strength, Ibs. sq. in....................................... .5000 9000 Elongation, %................................................................ .2 -5 Modulus of elasticity, in tension, Ibs./sq in. I.7 . 2.6 x 10* Compressive strength, lbs. sq. in............................ II.500 13.500 Flexural strength, Ibs./sq. in..................................... . 14.000 19.000 Impact strength. Izod, ft. Ibs./m. of notch (A.S.T.M.)......................................................... . 0.35 0.50 ft.lbs./in. of notch Grinell hardness (2.5mm bail, 25kg. load).......... .20 30 Rockwell hardness. . .................................................... . M87 M90 Light transmission, % ......................................... .88-90 Thermal conductivity, cal./sec./sq.cm./DC./cm. 1.9 x 10--4 Specific heat, cal./'C./gram ................................ .0.32 Thermal expansion, *C.......................... .................. . (6 8) x 10-* Softening point, F........................................................ .190 - 230 Distortion under beat, F. (A.S.T.M.) ........... .170 180 Tendency to cold flow ........................................... . Slight Volume resistivity, ohm-cms. (50% R. H. and 25C.) 10*T . 101* Dieletric strength, short time, H in. thickness volti/mil.................................................................... 500.700 Dielectric constant. 60 cycles.......................................... 2.5 2.6 Dielectric constant, 10s cycles........................................2. 5- 2.6 Dielectric constant, 10* cycles................................. 2.5 2.6 Power factor 60 cycles..................................... ....... 0.0001 0.0002 Power factor 10* cycles..................................................... 0.0001 0.0002 Power factor 10* cycle*..................................................... 0.0001 0.0004 Water absorption, immersion 24 brs............................. 0.00 Burning rate.......................................................................... Moderate Effect of age........................................................................... Very slight Effect of sunlight ... .......................................................Yellows slightly Effect of weak acids and strong acids..........................None Effect of weak alkalia and strong alkalis................... None Effect of organic solvents................................................. Soluble in aromatic and chlorinated hydrocarbons Machining qualities............................................................. Fair to good (Continued) Page 98 MONSANTO CHE MIC A l r 0663638 TOWOLDMON0006713 WATER_PCB-00003223 PLASTICS- Color possibilities Effect oq metal inserts Unlimited Available Literature: 16-page booklet "Luetron--A Monsanto Plastic.'' Trade Mark Reg. U. S. Pat. Off. "NITRON"* (Cellulose Nitrate Sheets, Rods, Tubes)_______ Nitron is a cellulose nitrate plaa;:ic which continues as the most suitable material for many exacting uses such as drawing instruments, fountain pens, tool bandies, tooth brush handles, heel coverings, watch and instrument crystals. The range of colors and special effects obta inable in Nitron plastics ia unlimited. It is easy to fabricate and can be molded, drawn, or blown. .Mechanical Properties: Specific gravity....................................... .............................1.3S 1.40 Specific volume, cu.in./lb.................. ........................ .19.8 20.5 Refractive index No .........................................................1.50 Ultimate tensile strength, Ibs./sq. in............................ 5,000 10,000 Elongation, %............................................................. .. 10 > 40 Modulus of elasticity, in tension lbs./q. in...............200.000 400,000 Impact strength, Cbarpy, ft. lbs /in. of notch (A.S.T.M.)................................................................ 3-12 Brinell hardness, 2.5 m.m. ball, )0 leg. load............... 8-11 Rockwell hardness....................... ................................M25 * M60 Machining qualities............................................................ Very good Molding Properties: Type......................................................................... Molding quality............................. .............. Compression molding temperature............... Compression molding pressure, Ibs./sq- in. Preforming........................................................... Tendency to cold flow........................................ Molding methods applicable........................... .Thermoplastic . Good . 185 2S0F. .100-500 . Very good . Slight . Swaging, shearing, blowing-- All very good Thermal Properties: Burning rate......................................................................... Rapid Thermal conductivity, B.T.U./br./sq, ft./F. temp. diff./in. thickness................................................... 0.90 1.48 Specific beat, caloriea/C./gram.................................... 0.34 0.38 Thermal expansion, 10--8/F...........................................6.5 - 8.9 Resistance to heat. F. (continuous)....................... . Approximately 140 Softening point, (A.S.T.M.) .................. ....................160 195'F. Decompose* at 272F. in 30 minute* Effect of beat, dry .............................................................Discolors on continued heat ing at 212F. Electrical Properties! Volume resistivity ohms-cma. (50% R, H. and 25'C.) ...........................................................(2-30) x Id* Dielectric strength, 60 cycle*, volu/mil..................... 600 1,200 (Continued) 26TB BDITION Page 99 0683639 TOWOLDMON0006714 WATER_PCB-00003224 PLASTICS- Dielectric constant, 60 cycles................. Dielectric constant, 10 cycles............... Power factor, 60 cycles............................. Power factor, 10 cycles........................... Chemical and Physical Properties: Odor................................................................. Taste.................................................. ............. Kffect of age................................................ Effort of sunlight...................................... I'.ffeot of ultraviolet light....................... Effect of weak mineral acids................. Effect of strong acids.............................. Effect of weak alkalis............................. Effect of strong alkalis........................... Water absorption 24 hours immersion Effect of hot water..................................... Effect of cold water.................................... Effect on metal inserts.................... , , . Solubility) Soluble in.. . ....................... Insoluble in............................ ........... 6.T 7.3 ..........6.2 ............0.06 0.15 ........... 0.07 0.10 ........... None or ramphorous ........... Tasteless to alight ........... Slight hardening ........... Discolors and becomes brittle ........... Yellows and decomposes on extended exposure ........... Good resistance ...... Poor resistance, decompose* ........... Very slowly decomposes ........... Decomposes ......... 0.6 -2.0% ........... Softens, slight shrinkage ........... None ........... None ........... Alcohols, ketones, esters ...... Aromatic and aliphatic hydrocarbons, mineral, animal and vegetable oils. Colon Available in an extremely wide variety of transparent, crystal, translu cent, pastel and opaque colors, as well as in many mottles, pearls and ornamental configurations. Format Available in sheets, rods, tubes and special shapes. Trade Mark Reg. U. S. Pat. Off. "OPALON"* (Cast Phenol-Fot maldehyde) A cast phenol-formaldehyde resin. Opt.Ion is noted for its beauty and the ease with which it can be fabricated, together with the ability to take a high and tasting polish. Special shapes and castings can be produced with low investment in molds. The size of casting ranges fropt handles for brushes and razors to large parts for coin machine housings, and complete radio cabinets. Restrictions on taw materials now limit the use of Opalon to essentia) civilian needs and to military applications. Mechanical Properties) Specific gravity................................. ................................... 1.27 1.32 Specific volume, cu. in./ib. ............................................20.0*21.8 Refractive Index Np ......................................................... 1.5 1.7 Tensile strength, Ibs./sq.in............................................... 5,000 12.000 Elongation.............................. .............................................. Very Slight Modulus of elasticity, Ibs./sq.in.xlO*...................... 5-15 Compressive strength, Ibs./sq.in....................................15,000.30,000 Impact strength, Ixod ft. lbs./in. of noteh (A.S.T.M.) ................................................................. 0.1 -0.4 Brinell hardness, 2.5 nun. ball, 25 kg. load..............30-45 (Continued) Page 100 MONSANTO CHlMtCALS 0683840 TOWOLDMON0006715 WATER_PCB-00003225 Rockwell hardness.............................................................M80 M130 Machining qualities.............................................................Excellent Shrinkage, % .................................................... ..................0*1 Molding Properties: Tvpe....................................................................................... Thermosetting, non-moldable Thermal Properties: Riirning rale........................................................................ Will not support combustion Thermal conductivity, 10--4 calories/second/sq.cm C. cm.................................................................... 3*5 Specific heat, calories/C./gram....................................0.3 0.4 Thermal expansion, 10-5/C.......................................... 2.8 Resislanre to heat, F. (continous).............................. 160 Effect of heat, dry .................................... ........................ Hardens slowly moist.......................................................... Whitens Heat distortion................................................................... .Above normal temperatures Elertrical Properties! \ olume resistivity, obms-ctns. ($0% R.H. and 25C).......................................................................... 10* - 10i Dielectric constant, 60 cycles..................................... .5-10 10 cycles....................................... 5.0 T.O Power factor, 60 cycles.....................................................0.025 0.20 10 cycles. ............................................... 0.005 0.08 10 cycles................................................... 0.01 -0.045 J) Chemical and Physical Properties! Odor............................................ .................... . None Taste. ............................................................. None Effect of age............................. .................... . Hardens slightly Effect of sunlight....................................... wj A. Effect of ultraviolet light......................... . Yellows slightly on exposure Some colored materials fade .Yellows slightly on exposure Some colored materials fade Effect of weak acids................................... None or slight Effect of strong acids................................. . Decomposed by oxidizing acids. Reducing and organic acids have less effect Effect of weak alkalis................................ .Slight to marked, depending on alkalinity Effect of strong alkalis.............................. . Decomposes Water absorption, 24 hours immersion .0.01 -0.5 Effect of hot water..................................... . Softens and whitens Effect of cold water................................... . None Effect od metal inserts.............................. . Inert Solubility: Insoluble in-- ......... .. . Most organic solvents, alco* hols, ketones, esters, aro matic and aliphatic hydro* carbons, mineral, animal and vegetable oils Colon Available In an extremely wide variety of transparent, crystal, trass* lucent, pastel and opaque colors, as well as in many mottle# and orna* mental configurations. Formi Available in sheets, rods, tubes and a very extensive variety of cast shapes and objects. Trade Mark Reg. US. Pat. Off 26TB EDITION Page 101 0683BU TOWOLDMON0006716 WATER_PCB-00003226 PLASTICS- "RESINOX"* (Phenol Formaldehyde Molding Compounds)- Over period of years the range of Resinox molding materials has grown to encompass almost every important industrial demand. Shortages of metals and tbe extremely exacting requirements of the nation's armed forces have stimulated the development of new types of Resinox materials having particularly high impact atrengths. Since fillers vary I be properties of Resinox, the following table gives the range attained by the moat common fillers of wood flour, cut fabric, cotton flock, mica and asbestos. Molding quality...................................................................Fair-exeellent Compression molding temperature, "F.........................290 400 Compression molding pressure, lbs./sq.m......... 2000 4500 Compression ratio (bulk factor).....................................2,02 10.0 Mold shrinkage, inches per inch...................................... 004 * .010 Specific gravity..................................................................... 1.34 1.75 Specific volume, cu. in./lb............... ................................. 13.3 22.2 Tensile strength, Ibs./sq. in..............................................4200 9500 Modulus of elasticity, Ibs./sq. in % 10*.......................8 45 Compressive strength, Ibs./sq.in......................... ...........20,000 35,000 Flexural strength Ibs./sq. in............................................ 8,000 15,000 Impact strength, ft. lbs./in. of notch, Izod (A.S.T.M.)................................................................ 0.26 - 4.00 Rockwell hardness............................................................... M8S M12S Thermal conductivity, 10--* cal./sec./sq.cm./C./ cm.. ..............................................................................3 20 Specific beat, cal/C./gram.............................................. 0.25 - 0.36 Thermal expansion, l(h" */9C . ..................................... 2.0 7.5 Resistance to heat F. (continuous)..............................225 450 Softening point, F...............................................................None Distortion under heat F........... ................ ................. 240 285 Tendency to cold flow........................................................ None Volume resistivity, ohm-cms. (50% R. H. and 25C.)....................................... 10. 1(M * Dielectric strength, abort time, volts/mi), Y% in. thicknesa.......................................................250 * 500 Dielectric strength, step-by-step, volts/mil, M in. thickness....................................................... 200 - 400 Dielectric constant, 60 cycles......................................... 5-20 Dielectric constant, 10s cycles.......................................4-20 Dielectric constant, 10* cycles....................................... 4.5 - 20 Power factor 60 cycles........................................................0. 04- 0.30 Power factor 10* cycles.....................................................0.04 0.20 Power factor 10* cycles.......... ...................................... 0.005 0.10 Water absorption, immersion 48 hours (%)..............0. 01 1.5 Burning rate..........................................................................Very low Effect of age.......................................................................... None Effect of sunlight.................................................................Light shades discolor Effect of weak acids................. .......................................None to slight Effect of strong acids......................................................... Decomposed by oxidising acids Effect of weak alkalis.......................................................Slight to marked Effect of strong alkalis ................................................ Decomposes Effect of organic solvents.................................................None on bleed-proof materials (Continued) Page 102 MONSANTO CHEMICALS 06836^2 TOWOLDMON0006717 WATER_PCB-00003227 p la s t ic s Machining qualities........................................................... Fair Color range.......................................................................... .Limited Available Literature: 12-page booklet "Resinox--A Monsanto Plastic." Trade Mark Reg. U. S. Pat. Off. "SAFLEX"* (Laminating Plastic) Saflex is a polyvinyl acetal sheet plastic used as the interlayer in making "HiTesl" laminated safety glass. The Saflex plastic sheet, .015 gauge, acts as the bonding agent holding the two sheets of glass firmly together and prevents scattering of the glass in case one or both surfaces of the glass are broken. The tough, elastic Saflex interlayer give* full protection at all temperature ranges encountered in winter or summer driv ingFor military vehicles and aircraft, multiple-layer laminations of Saflex and glass give protection against small-caliber bullets, bomb or shell fragments and flying debris. Trade Mark Reg. U. S. Pat. Off "VUELITE"* (Embossed Fluorescent Lighting Shields)______ Vuelite is tbe trade name for embossed cellulose acetate, developed by Monsanto to serve as diffusing panels for fluc<escent lighting fixtures. Glare and brightness are eliminated by a suitable design that spreads the light evenly. Tbe excellent light transmission factor of the material assures highly efficient light distribution. Although a fluorescent fixture my be large in size, tbe addition of a Vuelite diffusing panel adds very little to its weight thereby allowing the design of a lowweight fixture. Tbe danger of breakage of Vuelite as compared with glass of tbe same size is very small. Vuelite is easily formed to sbape Fixtures (bat require more than a six-inch radius are fitted witb diffusing panels by slipping flat sheets into position. Smaller aises and intricate shapes are formed without expensive molds or tools while punching, drilling and cutting opei at ions are carried out with ordinary tools. Vuelite sheets are 20'x 50' in size, available in the following designs: Number 4B 6B 8B 9B 20B 27B 42B 44B Name "H'* Line Whipcord Silk Cobra Large Cube Mesb Axtee Glow Worm Limiting Gauge Not -Under .050' .040' .050' .050' .050' .050' .040' .040' (Continued) Direction of Size Design 20x47 Lengthwise 20x47 Lengthwise 20x49 Lengthwise 20x47 Lengthwise 20x47 Both ways 20x49 Lengthwise 20x49 Crosswise 20x49 Lengthwise 6TB BDITION P.g< 06636*3 TOWOLDMON0006718 WATEFLPCB-00003228 PLASTICS S4B 55B 65B Sahara No. 5174 Large Crackle .050' .050' .040* Trade Mark Reg. t\ S. Pat. Off. 20x47 20x47 20x49 Both v.av Both ways Both ways "VUEPAK"* (Rigid Transparent Packaging Material) _________ Vuepak is produced as a Hear iransparent sheet plastic in continuous length rolls 31'.. inches wide. It is extensively used in the manufacture of durable rigid transparent containers, packages and displays for all types of consumer goods products. Originally used chiefly for luxury items. Vuepak containers have now become a successful packaging medium for food products, candies, household appliances, beverages and dry bulk products of all tvpes. An im* portant contributing factor to the broader use of Vuepak containers has been the improved efficiency of fabricating equipment and techniques in the plants of the more than two hundred firms now established as Vuepak fabricators. The properties of Vuepak are covered by the properties of Fibestos cellulose acetate materials in (be preceding table. Standard gauges of Vuepak are .005*. .0075*, .010*, .0125*. .015* and .020*. In addition to continuous length rolls. Vuepak is sold in standard size sheets or in pieces cut to order. Vuepak ran be drawn, scored, beaded, folded or stitched. With suitable surface of Vuepak can be readily plinted in one or more colors. the For special requirements Vuepak containers can be made with metal bottoms and lids or in combinations with box-board, paper, wire frames or wood. -- "Trade Mark Reg. 1. S. Pat. Off. POLYSTYRENE (See Plastics. Lustron). POLYVINYL ACETAL SHIET (See Plastics, Salfei). POTASSIUM AMMONIUM PHOSPHATE (Also known as potassium ammonium phosphate; ammonium potassium phos phate.) KNH4n(P04), Mol. Wi. 251.128 Standard Forms White crystals. Grade i Technical crystals. Page 104 (Cotjinued) MONSANTO CHEMICALS 06838't't TOWOLDMON0006719 WATER_PCB-00003229 R.R. Classification: Potassium Salts NOIBN. General Information: L'srri in pharmaceutical products for special medicinal purposes, and in the fermentatioi of *ines. POTASSIUM AMYL YANTHATE It.It. OussiBcolion t Potassium \anihate. (-onerol Information: Flotation agent used principally in the mining industry. POTASSIUM ETHYL XANTHATE R.R. Classification) Potassium Xaotbate. General Information: Flotation agent used principally in the mining industry. POTASSIUM GLYCEROPHOSPHATE (75% SOLUTION) (See Glycerophosphates), POTASSIUM PHOSPHATE, DI _ KiHPO, Mol. Wt. 171.18 Standard Form: 60% solution in water. Typical Analysiat Bluish, odorless liquid: sp.g. 1.7 at 25*0.; 14.6 lbs. per gal.; pH 9.9 10.3: viscosity 33 centipoisee at 25C.; water solubility 71 grams per 100 gms. solution. R.R. Classification! Chemicals, NOIBN. General Information! Used as a.a antistatic agent for wool and in fermentation and nutrient solutions. POTASSIUM PHOSPHATE, MONO (Also known as potassium diphosphate and potassium biphosphate). KH,P04 Mol. Wt. 136.09 Standard Form: White crystals. Grades: Technical containing about 0.50% SO,; sulfate-free containing about 0.01% SO,. (Continued) 26TB BOITION Page 105 06638<i5 TOWOLDMON0006720 WATER_PCB-00003230 T R.R. Classificationt Potassium Salts. General Information: Used to control pH of culture media and for special medicinal purposes. POTASSIUM PYROPHOSPHATE, TETRA K,P20, Mol. Wi. 330.34 Properties! White powder, hygroscopic in air: pH value in 1% solution at 25'<\, 10 6: solubility. 190 grams in 100 grsms water at 25C. R.lt. Classification! Cleaning Cont|<ound. General Information! Used for incorporation in textile oils and soaps to increase emulsifying values and to prevent formation of insoluble bard water soaps: as clarifying agent and to improve cleansing action of soaps. POTASSIUM SALICYLATE (See Salicylates). n-PROPYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). PYRIDINE, pure water-white liquid; used as a solvent and chemical reagent, as a denaturant for alcohol, and in special medicinals; made by Monsanto Chem icals Limited. PYROXYLIN CEMENTS (Set Celluloid Cements and Belt Cements). PYROCATECHOL_______________________________________________ (Also known as brenzcatechin, catechol or 1, 2-dibydroxy benzene). OH Mol. Wt. 114.1 Specification*! Fine white needles (may contain a few dark specks); assay, 99.5% min.; odor, practically none; crystallizing point, 104.0C. min. Solution in cold water, (1:10): color, APHA 40,, max.; turbidity, essentially clear. Solution in alcohol (1:10): color, APHA 40, max. K.R. Classificationt Chemicals NOIBN. General Information! Used as a developer in fur dyes, antioxidant in priming inks, and as intermediate in chemical synthesis. Page 106 MONSANTO Ctt R MIC A LS 0683846 TOWOLDMON0006721 WATER_PCB-00003231 `*R2*' CRYSTALS (See Accelerators, Rubber). REODORANTS, RUBBER Monsanto provides, but does not manufacture, the following types of rubber reodoraots for the convenience of its customers. Curodex No. 19-- Pale yellow liquid; deodorizes: percent used in 100 lbs. of rubber, 0.1S - 0.20; standard package, 5 lb. bottle. t.urodex No. 188--Pale yellow liquid; odor, lily; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. Curodex No. 198--Pale yellow liquid; odor, musk; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. RESINS (See Santolites and Plastics). "RESINOX" (See under Piastres). RUBBER LACQUERS (Sen Lacquers). "SACCHARIN MONSANTO" Saccharin Monsanto is available in the so>called insoluble form (complies with L.S.P. requirements for Saccharin) and in the soluble or sodium form (complies with L.S.P. requirements for Saccharin, Sodium). Descriptions of both forms are given below-. SACCHARIN, U.S.P________ _________________________________________________ (Also known as saccharin insoluble; oriho-sulfobenzimide). f\-c^ IJ-S^ NH V 0, Standard Form i Powder Mol. Wt. 183.11 Specification*! White crystalline powder: assay 98% min.; m.p. 227.0C. min.; losa of drying 0.50% max., solubility in 10% NajC0j(l:5) complete. R.R. Classification t Chemicals NOIBN. General Information! Saccharin has approximately 500 times the sweetening power of sugar, Used as a sweetener in tooth pastes, mouth washes, and phar maceutical preparations, and in beverages and foodstuffs in place of sugar for diabetic*. 1ST n P.OtTION Page 107 06838*7 TOWOLDMON0006722 WATER_PCB-00003232 SACCHARIN. SODIUM, U.S.P. (Also known as soluble saccharin; sodium ortho-sulfobenzimide). f ' C^NNa.2HiO w'- 211.13 Standard Format Crystals; powder. Specifications! White crystals or j-owder; solubility in water (1:8), complete. Loss on drying at !25C.: crystals U.0% rain. --14.35% max.; powder. 5.3% K.K. Classification! Chemicals NOIBN. General Information! See under Saccharin, U.S.P. "SAFLEX" (See Plastics). SALICYLATE, AMMONIUM _ COONH, OOH Mol. Wt. 155.08 Standard Formt Powder, 80 mesh. Specification*! White crystalline powder; assay. 98.0% min.; solubility in water (1:5), complete, colorless; solubility in ethyl alcohol 95% (1:15), complete; con* forms to N. F. test for heavy metals. No powder retained on 80 mesh screen. R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. SALICYLATE, CALCIUM _ Mol. Wt. 314.16 Standard Formi Powder. Specifications! Fine white powder; solubility in water (1:50), complete, colorless; free salicylic acid. 0.25% max.; conforms to U.S.P. test for heavy metals, R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. Pago 108 MONSANTO CBKMtCALS 0663648 TOWOLDMON0006723 WATER_PCB-00003233 Pilot plant operation at St. Louis plant. SALICYLATE, LITHIUM, N.F_______ COO Li OH Mol. Wt. 143.98 Standard Form i Powder. Specifications! White or slightly grayish powder; assay 98.5% min.; solubility in water (1:20), complete, colorless; conforms to N.F. te6t for heavy metals. K.R. Classification! Chemicals N0I6N. General Information] Pharmaceutical product. SALICYLATE, MAGNESIUM Mg Mol. Wt. 298.54 Standard Form i Powder. Specifications; Fine white powder; solubility in water (1:10). complete; con forms to L'.S.P. test for heavy metals. It.K. Classification! Chemicals NOIBN. Ceneral Information; Pharmaceutict-1 product. 26TH aOITtON Page 109 0683649 TOWOLDMON0006724 WATER_PCB-00003234 SALICYLATE, METHYL, U.S.P. COOCH, OH Mol. Wt. 152.14 Standard Form: Liquid. Specifications: Clear, colorless liquid, assay 98.0% min.; solubility in 70% ethyl alrohol (1:7), complete; solubility in N KOH (1:10), complete; p. g. 25/2S9C.. 1.180 1.185; free phenols, 0.010% max.; conforms to U.S.P. test for heavy metals. R.R. Classification: Oil of Wintergraen. General Information: Used as a pharmaceutical product, as a flavoring agent in foodstuffs and beverages, and as an odorant in printing inks and insecticides SALICYLATE, PHENYL, U.S.P. (Salol) Mol. Wt. 214.21 Standard Forms: Crystals; powder, 80-mesh. Specifications (White crystals or powder; solubility in ethyl alcohol 95% (1-6), complete; m.p. 41.0C. min.; conforms to U.S.P. tests for chloride, sulfate, free acid, free phenol, and free salicylic acid . 1.0% max. retained on 60 mesh screen. R.R. Classificationt Chemicals NOU8N. General Information: Pharmaceutical product. SALICYLATE, POTASSIUM COOK 0OH Mol. Wt. 176.21 Standard Form: Powder. Specifications: White or very slightly pinkish powder; assay (dry basis), 99.0% min.; solubility in water (1:10), complete; conforms to U.S.P. test for heavy metals; free alkali, negative. R.R. Classification: Chemicals NOIHN. General Information: Pharmaceutical product. Page 110 MONSANTO CHEMICALS 0663850 TOWOLDMON0006725 WATER_PCB-00003235 SALICYLATE, SODIUM, U.S.P. COONa OOH Mol. Wt. 160.11 Standard Forms: Powder, crystals. Specifications: 'White powder or crystals; assay (as received) 99.5% min.: solubility in *ater (10:100), complete, APHA 15 max.; solubility in ethyl alcohol 05% (1:10), complete, colorless: conforms to U.S.P. tests for heavy metals and rarboniaable impurities; trace max. ponder retained on 60 mesh screen, 1.0% on HO mesh screen, 2.0% on LOO tcesb screen. R.R. Classificationi Sodium Salts. General Information: Pharmaceutical product. SALICYLATE STRONTIUM, N.F.-________________ Mol. Wt. 397.74 Standard Form: Powder. Specifications! White crystalline powder; assay (as dihydrate), 99.0% min.; solution in water (1:20), complete; conforms to N.F. test for heavy metals and barium. R.R. Classification. Chemical. NOIBN. SALICYLIC ACID, (Ortho-Hydroxybeozoic Acid). COOH OH Mol. Wt. 138.05 Grades: U.S.P. and "B" Grade. Specifications of L.S.P. Grader White needle* or powder, 100-mesh; assay 99.5% min.; m.p. 158.0C. min.; conforms to U.S.P. test for carbonizable sub* stances; ash 0.05% max.; powder trace, max. retained on 100-mesb screen. Specifications of "BM Grade: White needles; away 98.75% min.; m.p. 158.0C. at start. (Continued) 26TB KDITION Page 111 0683851 TOWOLDMON0006726 WATER_PCB-00003236 K.K. Classification: Salicylic A>'id. Ceneral Information] Lsed in the manufacture of medicinals and dvestuffs, as an industrial preservative and as an intermediate in many organic syntheses. SALOL (See Salicylate, Phenyl). SALT CAKE (Sodium Sulfate, Technical) . Na,S04 Typical Anatyaist 94 - 95% NsS04 available. R.R. Classificationt Salt Cake. Ceneral Information: Used in (he manufacture of sulfate pulp, glass, sodium sulfide, and for treatment of boilei feedwaters. "SANTAMINE"______________________________________________ Characteristics: White powder, readily soluble in water, will not decompose oo standing if kept in clean dry place. R.R. Classification: Disinfectant Other Than Medicinal NOIBN. General Information: Santsmitte is a sterilizing and deodorising agent de veloped especially for the dairy industry, where it is used in water solution for washing utensils, equipment and bottles as well as the udders and teats of the cows. It also hods use in other industries where an efficient chemical sterilizing agent is required. It contains no poison or acid and will not harm rubber or metal. "SANTICIZER 8"____________________________________________________ (Mixture of ortho- and para-toluenp ethyl sulfonamides). OH il I O- S -- N - C.H, II O Mol. Wt. 199.26 Specifications: Light yellow, viscous liquid: odor, slight, characteristic; free amide, 9% to 13%; acidity (at acetic acid) 0.1% max. R.R. Claaaificatiom Lacquer Solvents NOIBN. General InformatJoni This plasticizer is readily miscible with all common organic solvents except the petroleum hydrocarbons in which it is only very \Continued) PagC 112 MONSANTO CHEMICALS 0683852 TOWOLDMON0006727 WATER_PCB-00003237 slightly soluble. It is soluble in castor oil. slightly soluble in china wood oil and insoluble in linseed oil. In water it is soluble to the extent of about 0.13% at 23C. and 0.21% at 48C. Its solubility in water is decreased by the presence of ammonia but is increased by other alkalies. Its retentivity in acetyl cellulose is about 90 parts by weight to 100 of acetate, and it imparts a high degree of plasticity. It is a solvent for both nitrocellulose and acetyl cellulose. Santirizer 8 is an excellent plasticizer for cellulose acetate, giving a brilliance and polish not obtainable with other plasticizers. This product, being practically insoluble in petroleum hydrocarbons, is a valuable plasticiser for coatings designed to withstand gasoline and related products. Santicizer 8 has some plasticizing anion on such protein compounds as casein, glue, soybean protein and corn protein. It may be used alone or in conjunction with other materials such as glycerine or similar compounds. Santicizer 8 greatly increases the flexibility of xhellaci having at the same time a considerable softening effect. Available Literature: M)page booklet, "Plasticizers and Resina". "SANTICIZER 9" _____ ________ .___ (Mixture of ortho* and para-tolueaesulfonamidea) OH Mol. Wt. 171.16 O Specifications: Fine granular particles; m. p. 105C. min.; melt, clear and light vellow; aciditv, pH 4.6 min. in dilute acetone (2 gram sample in IS cc A. R. Acetone and 35 cc of COj free distilled water). R.R. Classification: Lacquer Solvent NOIBN. General Information: Solubility of this plasticizer is quite low in coal-tar hydrocarbons and negligible in p<troleum hydrocarbons. It is readily soluble in most other solvents, and in hot linseed, china wood, and caster oils. It is soluble in water to the extent of only about 1.0% at 3-lC., but this is increased by the presence of alkali. It is the least soluble of the Monsanto plasticizers in ethylene dichloride and in benzene, its solubility in ethylene dichloride being about 4% at 30C. and in benzene about 1.5% at 30C. Santicizer 9 differs greatly from other plasticizers in its action. Relatively small amounts impart a glosa to polished articles and give smooth working and uniform curing of molded products. It blends readily with most synthetic resins and does not impart the softening action of liquid plasticizers. It is particularly valuable to the makers of molding compositions. In some phenol-aldehyde resins it appears to act not only as a lubricant but also as a promoter, giving more uniform and thorough curijog. In amounts of about 20 parts per 100, it has a temporary plasticizing action on protein compounds such as corn protein and soybean protein. Available Literature! 40-page booklet, "Plasticizers and Resins". 26TH edition Page 113 0603853 TOWOLDMONOOQ6728 WATER_PCB-00003238 "SANTICIZER E-15" (Ethyl Phthalyl Ethyl GlycoIIate)_____ 00 II -- C -- 0---CHt--C --0--CjH / -- O -- CtH, o Mol. Wt. 280.13 Specification*: Color, (APHA), 20 max.: 8p. g. at 25*725*0, I.1800.005; refrac. index at 25C., 1.4980,002; acidity (as acetic acid) 0.02% max.; odor, slight; sulfur (copper strip test), negative. It.lt. Classification! Lacquer Solvent jNOIBN. General Information: This plasticiser ia miscible with the common organic solvents except the petroleum hydrocarbons. It is miscible with vegetable oils when heated but partially separates otn cooling. Its solubility in water is 0.0175% at 30C. Santicizer E-15 is a solvent for both nitrocellulose and acetyl cellulose rid for most resins. It is light-fast, and does not evaporate even from the thin nest films. With both acetyl and nitrocellulose it gives clear, tough, flexible films which have greatly increased (esistance to moisture penetration. It is highly recommended for use with cellulose acetate and vinyl resins. Available Literature: 40-page booklet, "Plasticizers and Resina''. "SANTICIZER B-16" (Butyl Phthalyl Butyl GlycoIIate)_____ OO Mol. Wt. 336.19 II O Specifications! Color (APHA), 45 max.; sp. g. at 25/25C., 1.0970.005; refrac. index at 25C., 1.490 0.002; acidity (as acetic acid) 0.02% max.; odor, essentially odorless; sulfur (copper strip test), negative. R.R. Classificationi Lacquer Solves! NOIBN. General Information: Santicixer B-16 is a practically colorless liquid plastic* izer which boils at 219C. at 5 mm. s(td does not crystallize at temperatures as low as --35C. Its water solubility it- 0.0012% at 30C. It ia extremely light* stable. It darkens upon heating abov< 290C. Sancticizer B-16 is a solvent for nitrocellulose and is compatible with most resins, imparting good flexibility. It prubably embodies more desirable properties (Continued) Page 114 MONSANTO CHBMICAt.3 Q68385A TOWOLDMONOQ06729 WATER_PCB-00003239 thin any other single nitrocellulose plasticizers, lire retarding action being about the only property it does not have. Santicizer B-16 is a solvent for and imparts plasticity to many resins both synthetic and natural. It has especially interesting properties when used with resins of the glycerol-phthalate and pheDol-aldcbyde tvpes in which is may be incorporated at various stages of resin formation. It is miscible with castor, linseed and china wood oils and somewhat retards gel formation in the latter on heating, it swells crepe rubber but appears to have no effect on vulcanized rubber. It is an excellent plasticizer for chlorinated rubber, from 10 to 25 parts per 100 usually being required. It is an exceptionally good plasticizer for polystyrene. Mixtures of Santicizer B-16 and Santoilte resins may be used to plasticize casein and coi'n protein. Vtaiiahle Literature: 40-page booklet, "Plasticizers and Resins". "SANTICIZER M-1711 (Methyl Phthalyi Ethyl Glycollate) _ O0 o Specifications: Color, (APHA) 20 max.; sp. g. at 25<725C., 1.2200.005; refrac. index at 25C., 1.5040.002; acidity (as acetic acid) 0.02% max.; odor, slight characteristic; sulfur (copper strip test), negative. H.R. Classification: Lacquer Solvent NOIBN. General Information: Santicizer M-17 is a solvent for both nitrocellulose and aretyl cellulose. It imparts a high degree of plasticity which is maintained tmdimi6hed even in extremely thin films exposed to air currents for a long time. It is very light stable and may be used in transparent or tinted articles without danger of yellowing. This product is not miscible with castor, linseed, or china wood oils or with petroleum hydrocarbons but is readily miscible with other organic solvents. Its solubility in vater is 0.09% at 30C. but it imparts a con siderable degree of resistance to moisture penetration to both nitrocellulose and acetyl cellulose films. Santicizer M-17 is probably the best cellulose acetate plasticizer available. It dissolves Santolite resins, and as both are very resistant to petroleum products and compatible with eo many film-forming materials, tbey make an excellent combination for producing gasoline resistant coatings. Available Literature: 40 page booklet, "Plasticizers and Resina". "SANTICIZER 127'* (Butyl Benzene Sulfonamide). OH II I O Mol. Wt. 213.29 Continued) 26TB BDITION Page 115 0683655 TOWOLDMONOOQ6730 WATER_PCB-00003240 Characteristics.' Essentially colorless, oily liquid: crystallizing point --20C. (approx.); sp. g. 1.146 at SSVSS'C ; refrac. index 1.522 at 25eC. K.R. Classification! Lacquer Solvents NOIBN. Ceneral Information! This plasticizer is almost identical in characteristics with Santicizer 8 for which it may be substituted in most formulations. It has slightly less solvent action, lower compatibility, and is less soluble in water (0.1)03% at 31C.). When used with small amounts of active solvent plasticizers it produces bard but flexible and tough compositions. "SANTICIZER 128" (Ethyl Benzene Sulfonamide) OH N^ O-S -N -C.H, O Mol. Wt. 185.25 Characteristics! White crystalline solid; m. p. 51.9C.; sp.g., 1.208 at 60C. K.R. Classifications! Lacquer Solvents NOIBN. General Information! The plasticising properties of this product are of the same general character as Sancticizer (?. It has less compatibility and should not be used in amounts greater than 50 pans by weight to 100 parts of base plastic. Its chief value is as an auxiliary plasticizer to be used with others in order to extend the supplies of less available materials and at the same time impart the properties of gloss, workability, etc., < haracteristic of the sulfonamide plasticizers. "SANTICIZER 129" (Benzene Sulfonamide) __________________ O Oil -- S-NHt 0 Mol. Wt. 157.18 . Characteristics! White crystalline solid; crystallizing point 152C. R.R. Classification! Lacquer Solvents NOIBN, General Informations Santicizer 129 is similar in properties to its toluene analog, Santicizer 9. The principal difference is a slightly lower compatibility with most plastic materials. See Benzene Sulfonamide Technical for use where color is oot a factor. "SANTOBRITE" (Sodium Pentachlorophenate Technical)___ Standard Format Powder; 1-oz. briquettes. (Continued) Page 116 MONSANTO CHEMICALS 0683856 TOWOLDMON0006731 WATER_PCB-00003241 Characteristics: Brownish gray powder; noo-volatile at ordinary temperatures; practirallv odorless; non-hvgros<opie under ordinary atmospheric conditions. Solubilities in water are: 4`C. (395F.) 20.8% by weight; 25C. (77F.) 26.1% by weight; 33'C. (955F.) 28.0% by weight. Santobrite is a stable, relatively un reactive chemical and is not spent on organic matter. Us water solutions do not attack metals and under ordinary conditions do not decompose to form acid materials. U can be supplied as substantially neutral material containing from 0.2 to 0.6% free alkali or as a more alkaline product rontaining 3 - 4% alkali. Conversion to pentachlorphenol occurs at pH's below 6.8. U.lt, Classifications Agricultura Insecticide or Fungicide NOIBN. Ceneral information: A water-soluble industrial preservative and fungicide. I sed for manufacture of termite-resistant cellulose insulating board and for control of microbiological activity nn paper, paperboard, leather, adhesives, latex and cold water paints; for control of sap slain in green lumber: and for control <>f slicue and algae in water systems where the water is not used for drinking or bathing. Santobrite and its solutions are irritating to the skins and mucous membranes of many individuals and are somewhat toxic to maa and the higher animals. For detailed information on uses rod methods of handling, write for literature listed below. Available Literature: Technical Bulletin No. 0-1, "Santobrite for the Preservation of Adhesives." Technical Bulletin No. 0*2, "Santobrite and Santopben 20 for Paint Preser vation." Technical Bulletin No. 0-5, "Santobrite for Microorganism Control in the Pulp and Paper Industry". Technical Bulletin No. 0-1S, "Santobrite for the Control of Slime and Algae." Technical Bulletin No. 0-17, "Santobrite for the Preservation of Rubber Latex." Technical Bulletin No. 0-19, "Santobrite in the Tauning Industry." Technical Bulletin No. 0-22, "Santobrite--Methods of Handling and Applica tion." "Sap Stain Control by Monsanto" (24 page booklet). "Preservation of Cellulose Insulating Material# by Monsanto" (24 page booklet). "Instructions for Handling Santobrite." "SANTOCEL". Standard Formt Light weight porous solid. Properties! Santocel is silica gel from which tbe water has been removed by a process which does not destroy the original gel structure. Apparent density 7.5 lbs. per cubic foot; bulking value in liquid 17.1 lbs. per gal. Typical Analysis: 26TH EDITION SiO, Volatile Sodium Sulfate FejOj and Aijfh 90% 5.5% 3.5 1. {Continued] Page 117 f Types: (1) Santocel 45, high oil ahsorbing. (2) Santocel 58, low oil absorbing. (3) Santocel "O' \ designed lor use as a thermal insulator. All bilit Santoce 1 "O'* are white and translucent. Cradest The three types are each available in two grades. Fine sind All Size. Thru 20 40 60 HO 100 200 Fine APPROXIMATE MESH On 20 niesh 7% 40 6% 60 12% 80 11% 100 9% 200 28% 27% Thru 3 6 10 20 40 60 100 All Size On 3 1!nesh 20.7% 6 20.7% 10 17.2% 20 14.7% 40 13.0%. 60 4.2% 80 2.5% 7.0% K.R. Classificationi Insulating Material NOIBN. General Information! Santocel 4,1* and Santocel 58 are used principally as (1) Flatting agents for paints, varnishes and lacquers. (2) Thickenin'/ :ents for volatile and non-volatile liquids; particularly useful in printing ink' >) Anti* raking agents. (4) Dry dispersing agent for pigments and dyestuffs, (3 urce of highly reactive silica. (6) Stiffening agent in crepe rubber. Santocel "O'* is designed for use as a thermal insulation material. "SANTOCHLOR" (parn-Dithlorobenzene) (Also known as 1,4-dichlorobenzene) Cl Mol. Wt. 147.00 Cl Characteristics! White crystals; crystallizing point, 52.88C. min. Standard Crystal Sizes! No. 2. (large)--For shaker top cans. No. 5 (small)--Fot peach tree boters and for insecticide and miscellaneous No. 34 (medium)--A combination of two uniformly sized crystals. For shaker top cans and for compressing into cakes. K.R. Classifications Paradichlorobetizene. General Information! Para-dichlorobenzene is used as an intermediate in the production of dyestuffa; as a deodorant; mothicide, larvacide, and in control of peach tree borera. (Continued) Page 118 MONSANTO CHEMICALS 0683858 TOWOLDMON0006733 WATER_PCB-00003243 Available Literature: 3 page Technical Bulletin No. 0-18, "Santcchlor for the Control of Peach Tree and Stone Fruit Borers." "SANTOCURE" (See under Accelerators) `SAN'TOFLEX B" (See under Antioxidants, Rubber), SA.NTOFLEX BX" (See under Antioxidants. Rubber}. "SANTOLITE BA," almost identical in properties with Santolile MS. of which it is the benzene analog. SANTOLITE BH," almost identical in properties with Saotolite MHP, of which it is the bensene analog. "SANTOLITE BK," almost identical in properties with Santolite K. of which it is the benzene analog, "SANTOLITE BK5," almost identical in properties with Santolite KS. of which it is the benzene analog. "SANTOLITE K" Specifications) Clear, light yellow sticky resin; color, not more than No. 2.5 by Monsanto Santolite K Standard (comparable in depth of color but not in shade to No. 5 of the Gardner 1933 standard); acid number, 10 max.; refractive index at 50C.. 1.5330 to 1.5390. R.R. Classificationi Synthetic Resin. General Information) Santolite K is a reainoas condensation product of toluene sulfonamide, formaldehyde , and alkyd resins. It is a soft sticky resin with the qualities of both tbs sulfonamide and alkyd types. It is compatible with cellulose esters and ethers. Santolite K hat plasticising properties itself but for most purpose* additional plasticizer is desirable and Santicizer M*17 is recom mended, although other* may be ysed advantageously. Santolite K is soluble in practically all common organic solvent* except the petroleum hydrocarbon*. It is not compatible with drying oils so cannot be used in oil Tarnishes. Santolite K has a better light stability than the other Santolite* and ia of special value for increasing the resistance to moisture penetration of celluloae ester compositions. Available Literature) 40-page bpoklet, "Plasticizers and Resins." jam IDITIOK Page 119 obfiassi TOWOLDMON0006734 WATER_PCB-00003244 SANTOLITE K5"______ General Information: A rnodiliration >>f Santolite K having the same general characteristics except that it is harder. "SANTOLITE MHP" Specifications! Hard, practically colorless resin; refractive index (25 grams in T.j grams normal Hrit>I Acetate), (.4280 to 1.4310; penetration, (200 gram load for 5 seconds at 23C.) 2.0 mm. max. K.H. Classification! Synthetic Hesin. General Information! Santolite MHP is an aryl sulfonamide-formaldehyde resin and is similar to Santolite MS in characteristics, except that it is much harder, softening at about 62CC. end being brittle at normal temperatures. It is nearly colorless and is veil adapted to specialty lacquers, fabric coatings, molding compositions and the tike. Being incompatible with drying oils it cannot be used as a varnish material. Exceptional features of this resin are the ease with which it may be worked into practically any formula using a cellulose ester and the wide variation of properties obtained by its use. Its high degree of solubility makes very concernirated solutions possible, and its extreme compatibility with plasticizers and cellulose esters removes much of the dangerof blushing, sweating and separation. Santolite MHP can be used in spraying, dipping or brushing lacquers to make clear, colorless, odorless coatings of good gloss and adhesion. It does not material ly increase the viscosity of the solution and permits the building up of a high solids content in the lacquer. It is compatible with all the common plasticiser*. Available Literaturet 40-page booklet, "Plasticizers and Resins'*. "SANTOLITE MS" Standard Format Viscous Resin; Solution T.B. Specification* of Viscous Realm Pale yellow viscous resin; solution in benzene (1:5), clear; solution in benzene (4 6), no crystalline deposit in 24 hr*.; refractive index at 50C., 1.5690 - 1,5720; color of benzene solution (25 gtns. in 50 cc.). APHA 70 maximum. Specifications of Solution TBs Light colored, viscous liquid, free flowing at temperatures above 20C. Composition: 85% Santolite MS; 15% solvent (95% toluene and 5% butyl acetate), tolerance from 14 to 16% solvents; refractive index at 2S9C., 1.563*0.002. R.R. Classification! Synthetic Resin. General Information! Santolite MS is a soft, practically colorless resin made (Continued) Page 120 HONSVNTO CHIVICALS 0683860 TOWOLDMON0006735 WATER_PCB-00003245 Looking down an aisle in one of the Monsanto warehouses. by the condensation of fonnaldel-yde with aromatic sulfonamides. Like all the Santolftes it is compatible with fcotb nitrocellulose end acetyl cellulose and, being a solvent for both, it can b< used in any proportion, It forms brittle com* positions with both these esters but tbe addition of a plasticizer makes such combinations permanently flexible. It is readily miscible with all the common organic solvents and thinners except petroleum hydrocarbons. It is not miscible with varnish and paint oils. Sanfolite MS is excellent for water-white lacquers which will not be exposed to extreme weather conditions, its high gloss and lack of color being unusual in the resit held. Available Literature! 40-page bx>klet. "Plasticizers and Resins." "SANTOMASK" Specifications! Clear, light yellow liquid; faint vanilla-like odor; sp. g. at 25/25C., 1.04- 1.06. Additional Properties: Flash point. 210F. (by Cleveland open cup method); flow point, below 0C.; ibs. per gi., 8.7. (Continued) 2 6TH EDITION Page 121 0683661 TOWOLDMON0006736 WATER_PCB-00003246 K.R. Classification: Chemicals NOIItX, Icneral Information! Odor-masking ingredient for interior paints, printing uks and similar products having objectionable natural odors. In addition to masking odors, may reduce or eliminate irritation to eyes, nose and throat caused by volatile components of some interior paints. Will not affect drying time, color durability and other characteristics of paints and inks. "SANTOMERSE" Standard Format The Santomerses are highly efficient surface active wetting agents and detergents. The Santomerse series consists of six products. Each is distinctive in character and has been developed to meet a certain industrial need. Santomerse D--neutral powder. Santomerse S--30% aqueous solution of Santomerse D. Santomerse No, 1--neutral flakes. Santomerse No. 2--alkaline flakes. Santomerse No. 3--neutral powder, Santomerse No. 3--paste (75% Santomerse No. 3 in water). R.R. Classification) Washing Compound NOIBN. General Information! The Santomerse* are the salts of a homologous series of substituted aromatic sulfonic acids. They are used as wetting, spreading, pene(rating, emulsifying agents and detergetits in the following industries: textile, paper, leather, adhesive, rubber, insecticide, dust collection, soap, cosmetic, ceramic, detergent, metal cleaning, plating, emulsions, dyes, pharmaceutical, embalming fluid, laundry, steel, paint, cement, glue, felt and color, etc. Available Literature! 32 page booklet 'Santomerse". . "SANTOPHEN 7" (ortho and pora-Benzyl Phenol.)_________ Standard Form! Fused solid. Specifications! Light yellow, semi-crystalline mass: faint phenolic odor; sp. g., 1.088 1.098 (55C./55C.); refrac. index, 1.579 1.589 (55C.); crystallizing point, 40UC. min. K.R. Classification! Agricultural Insecticides. General Information! Santophen 7 is used as the active ingredient in disin fectants and antiseptic formulations; as an industrial preservative and as an enhancing agent for coal tar and cresylic acid disinfectants. It is highly toxic to bacteria. CA UTION: Thii product is toxic. Avoid contact with the skin. Available Literature) Monsanto Technical Bulletin 0-3, "Santophen 7--A Germicide and Industrial Preservative." Page 122 MONSAftTO CHEMICALS 0683662 TOWOLDMON0006737 WATEFLPCB-00003247 "S.ANTOPHE.N 20" (Pentachlorophenol) Characteristics! Dark, ^ravith brown flakes; chlorphenolic odor: crystallizing point, i7SM80C.; bulking value, 45.45 lb*, per cu. ft.; dispersible in soaps and sulfonated oils. R.R. Classificationi Agricultural Insecticides Other Than Liquid N'OIB.V General Information: SanUrphen 20 is highly toxic to fungi and many bac teria and is used industrially where such growths must be prevented or con trolled. frequently used in oil solution (See Permasan) or as the sodium salt (see Sanlobrile). SOLUBILITY DATA Solub; iities expressed as per cent Santopben on weight of solution Water Pine Oil 95% Ethyl Alcohol (Ethanol) 100% Ethyl Alcohol Methyl Alcohol (Methanol) Orthodichlorbenzene Stoddard Solvent No. 9 Refined Oil Gas Oil Diesel Oil 09 c. 0.00049 24.5 39.0 46.0 40.5 5.5 .... 0.4 0.3 1.9 20* C. 0.0(014 32.0 47.5 53.0 57.0 8.5 1.5 1.1 2.4 3.1 40 C. 00025 39.0 56.5 60.0 72.0 15.5 3.5 2.5 5.2 5.7 Carbitol Ethylene Glycol Diethylene Glycol Benzol Cellosolve ... .... .... .... 8.0 30.0 6.0 27.5 11.0 27.0 51.0 21.0 62.0 19.5 50.0 Butyl Carbitol Dioxan Diethyl Ether U.S.P. Acetone U.S.P. Linseed Oil (Raw) Tung Oil Dipentene Turpentine Carbon Disulfide Carbon Tetrachloride Glycerin 34.5 ... 48.0 11.5 . . 52.9 ... 21.5 ... 13.9 ... 11.2 .... 8.4 .... .... 3.0 3.0 .... 2.0 0.1 at 35C. 62.0 22.0 60 C. 0.00S3 46.5 65.5 67.0 77.5 26.0 7.5 5.6 9.3 11.3 ... 38.5 .... 31.5 .... 65.0 37.5 Santopben 20 and its solutions and formulations are irritating to the skin and mucous membranes and are somewhat toxic to man and the higher animals. Precautions auggested in "Instructions for Handling Santopben 20" should be observed. Available Literaturei 3-page mimeographed bulletin "Santophen 20." Mimeographed bulletin "Instructions for Handling Santopben 20." 26TH EDITION Page 123 0603663 TOWOLDMON0006738 WATER_PCB-00003248 "S.OiTOPOID S". Standard Forms Oily, homogeneous liquid Specifications: Dark brown liquid; Jp. g. 1.20 1.30; flash, (open cup method), 250CF. min.; fire, (open cup method), 290 * 300F. min.; pour, below --35F, viwoaitv, 5.U. at 100F., 13-1.5 112.3 seconds. R.R. Classification! Chemicals NOIBN. (General Information! Used up to 10% mixed with mineral oil to form extreme pressure lubricants for hypoid and other gears. "SANTOPOCR" Specifications! Gravity, 26.7A.P.I.; flash, 485F.; pour, 10F.; viscosity, S.U. at 2U)CF., 156.4; carbon residue, 1.4; color, NPA (85 and 15), 6; neutralization number, 1.20. R.R. Classifications Petroleum Lubricating Oil. General Informations Ad improved pour point depressant for lubricating oils. Lowers tbe pour point of wax-bearing oils as much as 50F. Stable under extreme service conditions. Available Literatures Application Data Bulletin No. 120, "Santopour.'* "SAJSTOSITE** (Sodium Sulphite Anhydrous, Technical)____ Specifications! Tan to slightly pink crystalline powder; assay (NajSOj) 93.0% min.; foreign odor, very faint, max.; solution, filtrate from a 10% solution in water is not darker than APHA 150 max. R.R. Glaaaiflcation s Sodium Sulphite Anhydrous. Technical. General Informations Used as a depressant in ore flotation and rubber, paper and cordage manufacture, and aa a reducing agent for removing oxygen from boiler feed water. "SANTOTAN-KR" (Basic Chrome Sulfate) Contain* approx. 50% of Crj(SC>4),(OH>i Standard Formi Crystal*. Specificationsi Dark green crystsh ; solution in water (5:S00), clear; basicity (Cr,Oi/SOj), 101-105; basicity (Schorlemmer), 37.3% *39.7%; chromium aa CrjOj, 23.9% min. (Continued) Page 124 MONSANTO CHI MICA IS 0683864 TOWOLDMON0006739 WATER_PCB-00003249 R.R. Classification; Dry Tanning Extract NOIBN. General Information: Used in chrome tanning of calf, cow, and horse hides and sheepskins, Available Literature: 16 page b.x>L1et "Chemicals for the Tanning Industry." "SANTOVAR A" (See under Antioxidants, Rubber). SANTOWAX, REGULAR________________ ______________ ___ Standard Form: Yellow waxy solid. Properties: Roiling range: first drop, 365eC.; 80%, 402C. Freezing point: primary hold point. I40C.: secondary hold point, 56C. Apparent sp.g.. 1.10 (approx.) at 2SC. Slightly soluble in alcohol and more soluble in benzene. R.R. Classification) Coal Tar Resin. General Information: Used in compounding polishes and waxes when a high melting wax is desirable. Also a plasticizer and resin. "SANTOWAX M" Standard Form: Yellow waxy solid. Properties: Micro-crystalline hydrocarbon wax of unsual stability toward heat: melting point, 83 85C.; flash pomt, 207C.; hardness (ASTM D-5-25) 250 gm. load, 0.23 mm. R.R. Classification: Coal Tar Resin. General Information i Used as an opacifier for paraifin candles and at a partial substitute for Camauba wax. "SANTOWAX O'* Properties: Oily, crystalline hydrocarbon; hold point, less than 50C.; flash point, 171C.; flame point, 193C. Hardness (ASTM D-5-25): 50 gm. load, 0.13 mm.; ISO gm. load, 0.40 mm.; 250 gm. load, 1.07 mm. R.R. Classificationt Coal Tar Bto. General Informationt Semiaolid plasticizer for soft wax or resin compositions. 26TB KOITION Page 125 0683865 TOWOLDMON0006740 WATER_PCB-00003250 T "SA.NTOWAX PM Standard Forms Flaky crystal*. Properties! Nearly while, crystalline high-melting hydrocarbon: first crystals, 20Q - 213C.; flash point. 207*0 : flame point. 238*C.: hardness (ASTM D-3-2S) 230 gm. load, 0.33 mm. K.K. Classification! Coal Tar Res, ns. General Information t Used to raise softening point and hardness of other w axes and resina. SODIUM ACETATE CHsCOONa CHjCOONa. StijO Mol. Wi.fl2.02 Mol. Wt. 136.07 Standard Format Crystals, 60%, >. F.; anhydrous (not N.F.) Specifications of N.F. Gradei White crystals or granules: assay (as trihy. dratr), 99.5 104.0% solubility in wt>ter (1:2), complete: alkalinity (as NajCOs). 0.025% max., conforms to N.F. te*t for heavy metals; no crystals retained on 10 mesh. Specifications of Anhydrous (not N.F.)t White or grayish crystalline ma terial: assay, 99.0% min.: solubility in water (1:2), complete; carbonate (as NajCOj), 0.5% max. R.R. Classification! Sodium Acetate. General Informations Used in tht manufacture of dyestuffs as a condensing component and buffing agent in coupling reactions; in dyeing operations as a mordant; in the manufacture of pharmaceuticals; in the soap and tanning indus tries; and as a photographic chemical. SODIUM ACID PYROPHOSPHATE (Also known as disodium dihydrogen pyrophosphate and acid sodium pyro phosphate). NajHjPjOj Mol. Wt. 221.97 Grade*! Food and commercial. Fcy>d grade meets all U. S. Pure Food Law requirements. Propertiest White powder, soluble in water and having min. neutralizing value of 74; pH of 1% solution. 4.2. (Continued) Page 126 Monsanto chimicals 0663666 TOWOLDMON0006741 WATER_PCB-00003251 R.R. Classification: Sodium Phosphate. General Information: tied in oil well drilling muds and as a leavening agent in baking powder ami flour. SODIUM ALUMINATE Na AliO, Mol. Wt. 164.2 Standard Form: White soluble powder: contains 90% soluble sodium aluminate. Properties! Readily soluble in water and extremely low in iron and insoluble material. Stable for at least 21 hours in 10% solutions although contains a max. of only 5% free caustic soda. R.R. Classification! Sodium Alumioate. General Information: Used iu papermaking: With aluminum sulfate for sizing at higher pH's. Also to help sei color and filler and to improve paper formation. In treatment of municipal an<l industrial water: With aluminum sulfate as a coagulant. In the lime-soda soft<ning process for silica removal and floe formation. Miscellaneous: As an alkaline source of alumina in the manufacture of certain pigments, catalysts and casein paints; in processing glycerin lyes; in chrome tanning; in cleaning solutions; to aid set of the frit in vitreous enameling. SODIUM AMMONIUM PHOSPHATE (Also known as microcosmic sail; sodium ammonium hydrogen phosphate; salt of phosphorus; phosphorous salt; fusible salt of urine.) NsNHtRPO,.4HjO Mol. Wt. 209.09 Standard Form: Crystals. Properties! Transparent, while, efflorescent, monoclinic crystals. Gives off water and ammonia on heating, leaving NaFO*; contains above 32% P,Oj, 7.5% NHj and 14% NajO. Gradei Commercial. R.R. Clasaificationt Disodium Phosphate. Principal (Jeett Used principally in analytical laboratories for standardizing uranium solution; determination of Mg and Mn; as reagent in blow pipe analysis. SODIUM BENZOATE. Mol. Wt. 144.11 26TB EDITION Continued) Page 127 G6B366? TOWOLDMON0006742 WATER_PCB-00003252 Grades) U.S.P. and Technical. Specifications of U.S.P. Grade! Thin white flakes or white powder: solubility in water (1.0:1.8 at 25C.), compiett: solubility in 00% etbvl alcohol (1:50), com plete; N/10 alkali or acid per 2 grarn sample. 0.2 cc max.; pH 6-3 10.4: loss on drying at 110C., 0.50% max.; assay, 99.0% min.: chlorides (as iVaCI), 0.05% max.; organic chlorine, none; Bulfates (as NajSO*), 0.05% max.; nitro compounds, none. Specifications of Technical Grade: White or slightly tinted powder; assav, 09.0% min. (dry basis); solution in v, a ter (l: 1.8), essentially complete but slighljv inferior to U.S.P. quality; chlorides (as N'aCI), 0.6% max.; sulfates (as NajSOjj. 0.6% max.: phthalic acid, 0.1% max.; heavy metals, none. R.R. Classification i Food Preserving Compound. General Information) Used for preserving foods, tobacco and medicinal pre parations. SODIUM BISULFATE (See Nitre Cake). SODIUM BISULFITE Standard Forms t Liquid--33 B6. containing approx. 21% SO>; wt. per gal.. 10.78 lbs. Anhydrous (Sodium Metahisulfite)--66% SOj (approx.) Typical Analysis: SO, NajSOs Fe Liquid 21.5% '<-00 .006 Anhydrous 66% 1.5 .902 R.R. Classification: Sodium Bisulfite Dry or Sodium Bisulfite Liquid. General Information! Used in dvi manufacture, as source of SO, for reducing sodium bichromate to basic chrome ^ulphate in tanning, bleaching of vegetable tan extracts, production of hydrosulfite for vat dyeing, antichlor in bleaching of groundwool, bleaching dyes out of wo:>den coloring drums used for dyeing leather, antichlor in pulp bleaching, antichlor in laundries, bleaching of straw, rabbit fur, sugar syrups, glue, glucose. (See table in general data section) SODIUM FERRIC PYROPHOSPHATE NajFe((P,Oj)j . XH,0 Properties: A finely subdivided powder, insoluble in water, soluble in hydro chloric acid; contains min. of J5.5% iron. General Information: Used in food fortification as a mineral supplement. Page 128 won9xnto cttcwtcaLS 0683866 TOWOLDMON0006743 WATER_PCB-00003253 SODIUM GLYCEROPHOSPHATE (See Glycerophosphate#). SODIUM HYDROXIDE (See Caustic Soda)* SODIUM HYPOCHLORITE (See Merclor). SODIUM PENTACHLOKOPHENATE (See Samobrite). SODIUM PHOSPHATE, DI_ (Also known as phosphate of soil-a; sodium phosphate di basic; secondary sodium phosphate; exsiccated sodium phosphate). NajHPOj Mol. Wt. HI.982 Properties! Soluble in water, insoluble in alcohol. On exposure to air will absorb 2 to 7 mols HjO depending on humidity and temperature. Loses molecular water at 240C. forming tetrasodium pyrophosphate. pH of 1% solution at 25C., 8.8. One lb- anhydrous product ieequivalent to 2-5 lbs. of crystalline (dodecahydrate)* (Jradesi Technical, Food (Regv-Ur, Granular, Powdered), Medicinal, U.S.P. R.R. Classification: DiBodium Phosphate. General Information: Used in making glazes for potteries, porcelains and china ware; aa an emulsifier in leaking process cheese; in various chemical pro* cesses; in manufacture of dyestuffs such as Schnitzler's green; in the preparation of enamels; in tinning and solder-fog: ' leather tanning; as a bath ingredient in galvanoplastic work; in the manufacture of pigments such aa cobalt phosphate; in the weigh ting of silk and impregnating of textiles in dyeing and calico printing; in the adjustment of condensed milk; conditioning boiler water; medicinal. DCNS/TY OP PONOSOOIVM PHOSPHATP SOLUTIONS 0683669 TOWOLDMON0006744 WATER_PCB-00003254 SODIUM PHOSPHATE, MONO (Also Lnown as sodium phosphate, monobasic; sodium dihydrogen phosphate; sodium biphosphate; monosodium ortho phosphate; acid sodium phosphate.) NaHjPO, Standard Form: White powder. Mol. Wt. 119.993 I'ropcrtiesi Contains not less than 1)8% PjOj; pH value of 1% solution, 4.5. tirades; Food; commercial. It.lt. Classification: Sodium Phosphate. General Information: Used for conditioning boiler water and in electroplating. AmmV0M Mttfirfv StJr'/ntt 0663670 TOWOLDMON0006745 WATER_PCB-00003255 SODIUM PHOSPHATE, TRI ......... _ (Vlso known as normal sodium phosphate; sodium phosphate, tri-basic; tertiary sodium phosphate: T.S.P.) NajPO,. )2H}0 Mol. Wt. 380.16 Specifications: While crystalline material. uniformly sired: quickly soluble in water giving an alkaline reaction: p 11 value of 1% solution, 11.8. II.IL Classification: Trisodium Pnosphate. General Information: Used principally in cleaners and detergents for both household and industrial use. Fruit Cleaning: To remove insecticide spravs and inhibit growth of fruit uiold. Water Treatment: For softening and conditioning water. SODIUM PHOSPHATE, TRI, MONOHYDRATE NajPCVHjO Mol. Wt. 181.99 Standard Form: White powder. Properties Soluble in water: one lib. is equivalent in NajPOj content to 2.10 Ihs. of trisi- iin phosphate crystalline. Gradet Commercial. It.R. Classification! Trisodium Phosphate. Principal U'sesi Used for the same purposes as crystalline T.S.P,: in the manu* facture of compounds containing caustic soda it permits the production of dry mixtures. SODIUM POTASSIUM AMYL PHOSPHATE (Mixture of sodium and potassium salts of the amyl phosphoric acids). Standard Form: 60% solution in water. Properties: Straw colored liquid with slight Pentasol odor; sp. g. 1.339; wt. per gal. 11.2 lbs.; pH 7.0 7.3; slightly hygroscopic; anhydrous form gelatinous. It.lt. Classification! Chemicals NOIBN. General Information: Used as ingredient in vat printing pastes and as a spin ning agent for wool. SODIUM PYROPHOSPHATE, TETRA (Also known as sodium pyrophosphate, pyrophosphate of soda, normal pyro- sodium phosphate, alkaline sodium pyrophosphate and TSPP ). Grades: Crystalline and Anhydrous Properties: White crystalline material and white granular or powder; pH value of 1% solution, 10.2. R.R. Classification: Sodium Phosphate. (Continued) 26TH EDITION Page 131 0683871 TOWOLDMON0006746 WATER_PCB-00003256 Entrance to office and laboratory building at Trenton, Michigan, plant. General Information) Used in bleaching, especially for straw, and as an ink eradicator; in manufacture of iron pyrophosphate and other pyrophosphates: household and industrial cleaner and detergent: in dye bath for putting certain types of dye in complete solution; electroplating; metal cleaning; electrolytic separation of various metals; oil drilling muds; i emulsifier in process cheese manufacture; soap builder; degumming textiles. SODIUM SALICYLATE (See Salicylates). SODIUM SULFATE* ANHYDROUS Na,SO* Mol. Wt. 142.05 Typical Analyalst White granular crystals; 99% NajSO; available. For crude Sodium Sulfate, see Salt Cake. li.H. Classification! Sodium Sulfate. General Information! Differs from (rlauber's salt only in sodium sulfate cod. tent. Glauber's salt contains 43% sodium sulfate and 56% water of crystalliza tion. Anhydrous sodium sulfate contains 99% sodium sulfate and no water of (Continued) Page 132 Monsanto chemicals 0663872 TOWOLDMON0006747 WATER_PCB-00003257 c rystallization. I kpJ for diluting dry dyestuffs and io tanning. Other uses same ja for Glauber * salt. For crude Sodium Sulfate, see Salt Cake. SODIUM SULFHYDRATE* NaHS Mol. Wt. 56.06 Standard Form: 33!i% NaMS, liquid. It.lt. Classificationi Sodium Su (hydrate. General Information: Sodium Sulfbydrate is chemically similar to sodium sulfide. Where a sulfide with a lower caustic content is desirable Sodium Sulfhy. draie may be used. The main application for Sodium Sulfbydrsle is in dehairing leather where its lower caustic alkalinity makes it more desirable than sodium sulfide for certain leathers. A lower caustic alkalinity causes less swelling of the bides or skins, thus producing leather with a finer, smoother grain. It can be said that Sodium Sulfbydrate affords a means of controlling plumping (swelling). I nlike sodium sulfide, Sodium Stdfbydraie will not dehair by itself. Lime must be used with it to give a sufficiently high pH for debarring. Not manufactured by us, but furnished for the convenience of our customers. SODIUM SULFIDE Standard Forms: Crystals (Na}S.9HjO)i concentrated--flakes.* (NajS.tlHjO); liquid (20% NajS solution). Typical Analysts: Crystals, 31% NajS; concentrated, 60-62% NajS; liquid, 20% Na,S. It.R. Classification: Sodium Sulfide. General Information: Sodium Sulfide is a salt of the weak acid, hydrogen sulfide, and the strong alkali, caustic soda, and consequently its solutions are strongly alkaline. Reacta with mttal salta to form metal sulfides, nearly all of which are colored. Reacts with acfits. precipitating sulfur and liberating hydrogen sulfide. Is a reducing agent, and solutions are ready solvents of sulfur to form polysullides. Principal use is in tanning, to remove hair from calfskins and cowhides, and from sheepskins from which the v ool has already been removed. Other uses are in the manufacture and application of sulfur dyes, degumming of silk, deoitrating of nitrocellulose rayon, sodium polysulfide solutions, leaching gold ore tailings, dissolving creaols from coal tar oils, boiling out linen, and depositing mineral pigments on cotton. * Not manufactured by us but fundsbsd for the convenience of our customers. SODIUM SULFITE (See Sai>tosite) SOLVENTS (See Ethyl, Butyl and Amyl Acetates, Diacetone Alcohol). J6TH coition Page 133 06B367S SOPANOX" General Information! Sopanox is an amiDo compound, effective is minute quantities in restraining the oxidation of soap and (he resulting rancidity, die* coloration and other adverse qualities, all of which must be avoided ia pro* ducing a product of highest grade. Our experience shows that Sopanox satisfies the exacting demands of manufacturers of soaps produced from animal or vege* (able oils, filled or unfilled. It is particularly valuable in preventing discoloration i>f refined toilet soaps. R.K. Classification: Chemicals NOIBN. Available Literature! Technical bulletin "Sopanox.*' "SOPET" (Sodium Potassium Ethyl Phosphate Solution)____ Mixture of sodium and potassium salts of the ethyl phosphoric acids. Standard Form: 60% solution in water. Properties* Water white liquid with slight ester odor; 11.4 lb. per gal.; sp. g. 1.37 at 2SCC.; pH 7.0 7.4 in 60% solution; viscosity, 128 centipoises at 25C. R.R. Classification! Chemicals NOIBN. soluble* is easily removed from yarn or cloth without soap scouring. SPRAY LACQUERS (See Lacquers), SPREADING AGENTS (See Areskap, Aresket, Areeklene, Santomerse). STEEL PICKLING INHIBITORS (See Hibitite). STRONTIUM SAUCYLATK N.F. (See Salicylate*). SULFANILAMIDE, U.S.P. (joara-Aminobenzene Sulfonamide) NH. Mol. Wt. 172.20 NHi Page 134 Standard Forms! Crystals, 30-mesh; powder. 100-mesh. (Continued) MONSANTO CHE MICA LS 068387V TOWOLDMONOOQ6749 WATER_PCB-00003259 Specifications: White crystals or powder; assay (dry basis) 99.5% min.; ni.p. 165.0C. min.; solution in N/2HCI (2;30) clear; asb 6.05% max.; chlorides (as HC1) 0.011% max.; sulfate (as EUSO<) 0.04% max.; conforms to Li.S.P. test for heavy metals. Retained on-- 30 mesh screen 40 mesh screen 60 mesh screen 80 mesh screen 100 mesh screen 110 mesh screen 200 mesh screen 30-mesh Trace max. 40.0% min. 75.0% min. 90.0% min, li.K. Classification: Chemicals NOIBN. 100-mesh 0.8% max. 10.0% max. 25.0% max. 20.(1% min. 40.0% max. General Informations tsed in pharmaceutical preparations and veterinary medicines. CAUTION: Suifanilandde should be administered only under supervision of a competent physician. SULFATE OF IRON (See Ferric Sulfate and Ferrisul). SULFUR 99.5% pure sulfur. Gradesi Commercial rtibbermakers. commercial flour, 90% through 80 mesh; dueling, 93*95% through 325 mesh. R.P. Classificationt Sulfur. Genera] Information: Sulfur is a brilliant yellow crystalline substance, ap proximately twice as heavy as water and melting at about 248 F. This ready fusibility permits casting into various shapes. It is highly acid resisting and is a l>oor conductor of heat and electricity. It combines with rubber to form polysultides. Sulfur is used as a source of sulfur vapor for manufacture of carbon bisulfide and sublimed sulfur; as a source of sulfur dioxide for fumigation, bleaching and manufacture of sulfuric acidv sulfiti and bisulfite for paper manufacturing; io formation of sulfides and polysulfides for oil refining, vulcanization of rubber, smelting, and manufacture o( calcium sulfide and sodium peiyauifide*. as an acid-resistant bonding material (or brick-lined acid tanks; as a water-resistant material for water pipe joints; as a non-conductor for the manufacture of insu lators; as a fungicide; in manufacture of fireworks and railway signals; in grain mixtures for poultry; as a soil disinfectant. 26TH BDITION 0683825 TOWOLDMON0006750 WATER_PCB-00003260 C.onvMiMs used in manufacture of sulfuric acid at Everett. Mm. plant. SI LFl RIC ACID ir2so, Standard Strengths! 5B B6; 60 B6.; 66 Be.: 98% IlgSOj; Oleum. Typical Analysis i 58 B6: 74.36% freezing point, below --40F. 60 B6.: 77.67% min. H2SO4; freezing point, +12.6 F. approx. 66 Be.: 93.2% min. HjSO*; freezing point, --29 F. approx. 98%: 98.0% min. H2SO4; freezing point, 38 F. approx. Oleum--20% SO,: 104.50% tnin. HjSO<; freezing point, 22.8F. 25% SO3: 105.6% min. H$S04; freezing point,`I8.7F. 33% SO,: 107.88% min. H?SO,; freezing point, 83.5F. 40% SO,: 109.00% tnin. H.SO,; freezing point, 91.5F. 65% SO,: 114.6% H,SO<; freezing point, 38.0 F. Oleum freezing point data based on Manufacturing Chemists Association curve. 1941 R.R. Classification t Sulfuric Acid. General Information 1 Used extensively in steel mills, enameling works, oil refineries, pigment works, byproduct gts plants, fertilizer plants, tanneries, and many other industries. (SeelaWej in general data section) Page 136 Monsanto chemicals 0663076 TOWOLDMON0006751 WATER_PCB-00003261 SULFURIC ACID C.P____ HjSOi Mol. Wi. 98.07 Specifications: Colorless liquid; assay, 95.3 97.0%; non-volatile material. 0.0005% nut.; chloride (Cl), 0.(*0OU6% max.; nitrate (NOj), 0.0002% max.; ammonium (NH(), 0.0003% mat.i SOj, 0.0005% max.; arsenic, 0.000003% max.; heavy metals (as Pb). 0.0005% max.; heavy metals (as Fe), 0.0001% max. R.R. Classification i Sulfuric Ac>d. Corrosive liquid (white label required). Central Informations L sed as a laboratory reagent and where an extremely pure material is required. SULFURIC CONTACT CATALYST (See Vanadium Catalyst). SULFURYL CHLORIDE _____ SOjClj Mol. Wt. 134.97 Standard Forms Liquid. Characteristics! Light yellow liquid (may deposit precipitate on standing); sp.g. 15.5/1S.5C., 1.67 1.7V. Distilling range; first drop, SO.O'C. min.; dry point, 70.0C.{ 20% 100% range, 2.0C. max.; total condensation, 95% min. R.R. Classification: Chemicals NOIBN. Corrosive liquid (white label required). General Informations Used as a chlorinating and condensing agent. SYNTANS (See Mertaool). TETRAPHOSPHORIC ACID (Phospholeum) Properties! Clear, water white viscous liquid; PjOj content 83 84%; does not crystallize at --SOX. Sp. g.: 2.060 at 20C.; 1.983 at 100C.; 1.960 at 125C. R.R. Classification: Phosphoric Acid. General Information! Used for industrial applications where a high strength phosphoric add is desired and as t drying agent. TETRAPOTASSIUM PYROPHOSPHATE (See Potassium Pyrophoi. phate, Tetra). (Conti/tued) 26TB EDITION Page 137 0663877 TOWOLDMON0006752 WATER_PCB-00003262 TETRAS0D1LM PYROPHOSPHATE (See Sodium Pyrophosphate, Tesra). TEXTILE LACQUERS General Information! Clear and pigmented foe waterproofing garment fabrics, raincoats, shower curtains, duck and balloon cloth. Can be supplied in cellulose nitrate, acetate, aceio butyrate, ethyl cellulose, and chlorinated rubber base. Applied by machine coating. K.K. Classification: Lacquers. TEXTILE PRINTING LACQUERS General Information: Pigmented lacquers for engrsved roll and stencil print ing on finished fabrics, cotton, silk, ctlanese, rayon taffetas, crepes, aod voiles. R.R. Classificationi Lacquers. THINNERS________________________ General Information: Thinner# are supplied for reducing all lacquer products to required viscosity for spraying, dipping, and machine coating. Can be adjusted to meet special requirements for flow out, drying time, moisture resistance, and solvent power. Retarding tbinners, cleaning thinners, stripping thinner#, re movers, resins and dye solvents are also available. R.R. Claaslficationi Lacquer Thinning Compound. THIOCARBANILIDE (See under Accelerators). THIOUREA____________________ ________________________________________ (Also known as tbiocarbamide, tulfoearbamide, and sulfourea.) NHj.CS.NHj Mol. Wt. 76.12 Standard Formt Crystals. Specification*! White, tree-flowing crystals; moisture 0.50% max.; tab 0.05% nisi.; solution (10% water at 25C.) turbid. R.R. Classification! Chemcials NOIBN. General Information! Used as an intermediate in the production of dyestuffs and pharmaceuticals; in the manufacture of vulcanization accelerators; as an (Conrsnuer^ Page 138 Monsanto cbbmicals 0683876 TOWOLDMON0006753 WATER_PCB-00003263 ingredient of insecticidal compositions; moth-proofing agent in treating furs, feathers, skins and fabrics; and as an intermediate in the production of resin* and waxes. **THIL RAD" (See Accelerators) TOLUENE ETHYL SULFONAMIDE (See Santicizer 8). poro-TOLUENESULFONAMIDE (Also known as para-toluenesulfonic acid amide, para-ulfonamidotoluenr, and 4-suifonamido toluene.) CH, 0 Mol. Wt. 171.21 SOtNHt Standard Forms Crystalline powder Specifications: Light brownish crystalline powder; crystallizing point (dried material) 135.0C. min,; ash 0.60% max.; alcohol insoluble material, 0.60% max.; loss on drying, 0.50% max. R.R. Classification! Chemicals NOIBN. General Informations Used as an intermediate in the production of active chlorine bearing compounds, as an intermediate in tbe production of dvestuffs, as a plasticizer, and as a base iq tbe production of plasticizers and resins. Also see Santicizer 9, a mixture of ortho and para-toluenesulfonanudes. para-TOLUENESULFONCHLORIDE CHi Mol, Wt. 190.64 Standard Forms Crystals Characteristicst White or yellowish crystals; assay, 95% min.; crystallizing point, 65.5"C. min. R.R. Classifications Chemicals NOIBN. General Informations Used at a condensing agent and an intermediate in dyestuff synthesis. 26TB EDITION Page 139 0683829 TOWOLDMON0006754 WATER_PCB-00003264 TOLLEN ESC LFONIC ACID, TECHNICAL CH, 0 Mol. Wt. 172.19 SOjH Standard Form: Fused crystalline mass. (hararteristicst Brown lo black crystalline solid; toluenesulfonic acid, 85.0% min.; H,$04, 8.0% mat. Composition: approx. 85.0% para and 15.0% ortho; contains up to 14.0% water; may contain 1.0 2.0% toluene. R.R. Classificationi Chemicals NOIBN. Genera] Information! Used in tl-e manufacture of dyestuff intermediates and as a catalyst in certain organic reactions. TRICALCIUM PHOSPHATE (See Calcium Phosphate, Tri). TRICHLOROBENZENE, TECHNICAL _________________ Mixture of 1, 2, 3* and 1, 2, 4-tricblorobenrene Standard Formi Liquid. Mol. Wt. 181.45 Characteristics: Practically clear, colorless to light yellow liquid; sp.g. 15.5/15.5C., 1.460 1,477; acidity as RC1, 0.01% max.; crystallizing point, lO.O'C, max. Distilling range; first drop, 20S.O*C. min.; 50%, 213,0C. min.; 90%, 216.0C. min.; dry point, 2SO.O*C. max. R.R. Classification t Trichlorobensene. General Information t Used in organic synthesis, as a solvent, and as so insect icide. TRICRESYL PHOSPHATE. Page 140 Mol. Wt. 368.18 (Continued) MONSANTO CHEMICALS- 0683800 TOWOLDMON0006755 WATER_PCB-00003265 Specifications; Clear practically colorless liquid; sp. g. at2O/20C., 1.1620.005: acidity (as H3PO<) 0.01% max-i free phenols (permanganate test), a distinct purple color to be present after 30 minutes. R.R, Classification! Lacquer Solvents NOIBN. General Informations Tricresyl Phosphate is used principally as a plasticizer. It has a high boiling point and is relatively non-volatile, the evaporation loss jo 100 hours at 1003C, being less than 0.10%. The refractive index is abotit 1.556 at J0C. Viscosity increases rapidly at temperatures below normal until at about --!WC. the product is a solid transparent mass without crystalline structure. It is miscible with all the common solvents and thinners, and with linseed, china wood, and castor oils. Its solubility in water is less than 0.002% at 85C. and it imparts good moisture resistance to nitrocellulose films. Being a solvent for nitrocellulose, it has a high retentivity end can be used in large proportions without danger of sweating or separation. Tricresyl Phosphate is the standard lire retarding plasticizer for nitrocellulose. It is compatible with most lacquer resins and gives firm, tough, flexible films nf excellent weathering qualities. The ortho isomer, which is reputed to be the toxic element in normal Tricresyl Pbosphate, has been virtually eliminated from Tricresyl Phosphate Monsanto, there by reducing toxicity dangers to a minimum and making the product more suit able for many application!. Elimina tion of the ortho isomer causes no impairment in plasticizing qualities. Available Literatures 40-page booklet, "Plasticizers and Resins". TRIETHYL PHOSPHATE (QH^OjPO Mol. Wt. 182.2 Standard Formt Liquid. Characteristics: Water white liquid; acidity (cc. n/100 NaOH per 5 cc.), 3.0 cc. max.; moisture, 0.20% max. Distilling range: first drop, 200C. min.; dry point, 220C. max. R.R. Classification! Chemicals NOIB^. General Information: Used as a solvent plasticizer and as a catalyst in chem ical syntheses. Available Llteraturei 40-page booklet: "Plasticizers and Resins." TRIMAGNESIUM PHOSPHATE (See Magnesium Phosphate, Tri). 26TB BDITION page ]*! 0683661 TOWOLDMON0006756 WATER_PCB-00003266 TRIPHENYL PHOSPHATE. P=0 Mol. Wt. 326.31 Specifications! White flakes, faintly aromatic; m. p. 48.5'C. min. start; solution in alcohol (10 gms. in 50 cc), not more than faintly opalescent; permanganate test, distinct purple color to be present after 30 minutes; acidity (as HjPOj) 0.003% mat. II.R. Classification! Lacquer Solvents NOIBN. General Information! The chief uses of Triphenyl Phosphate are as a plastic izer and fire retarder. It is miscible with the common solvents and thinners and with vegetable oils. Its solubility it. water is 0.001% at 34C. and 0.002% at 54C. and it imparts some moisture resistance to cellulose acetate films. Its retentivity in cast cellulose acetate films is nearly 80%; that is, it csn be incorporsted in the proportion of 8 parte to 10 of acetate without causing separation and blooming. It imparts good flexibility and gives clear, tough compositions without tendency toward tackiness. Triphenyl Phosphate is toxic and should not be used in articles such as foil, which are to come in oontact with foodstuffs. One of the most valu able properties of Tripheoyl Phosphate is that of fire retarding. When used alone in cellulose Acetate films an amount of Tripheoyl Phosphate equal to 20% of the cellulose acetate weight produces films which will not support combustion. Available Literatures 40-page booklet "Plasticisers and Resins" TRIPHENYL PHOSPHITE Mol. Wt. 310.31 Specifications! A crystalline solid at slightly below room temperature; at higher temperatures is an oily liquid weighing 9.8$ lbs. per gal. K.R. Glassificationi Chemicals NOIBN. General Informations Used as plasticizer and aa a fire retarder for nitro cellulose. Page 142 Monsanto chimicals 0683882 TOWOLDMONOOQ6757 WATER_PCB-00003267 TRISODIUM PHOSPHATE (See Sodium Phosphate. Tri). "I'REKA". **LREKA BLEND B", "UREKA C" (See under Accele rators, Rubber). VANADIUM SULFURIC ACID CATALYST __ General Information s Used in manufacture of sulfuric acid by contact process. (Not suitable for other purposes). VANILLIN, ETHYL (See Eth*van). "VANILLIN MONSANTO" (Vanillin, U.S.P.) CHO Mol. Wt. 152.14 ) OCHi OH Standard Form: Fine Crystals. Specifications) Fine, white crystalline needles: m.p. 81.5C. min.; no foreign flavor (in sugar solution): loss on dry mg, 0 03% max.; solubility in alcobol (1:2), complete. R.K. Classification: Chemicals NOIBN. General Information: Used as a (favoring agent in foodstuffs and beverages. Available Literature: Leaflet "Vanillin Monsanto." VARNISH ANTISKINNING AGENTS (See Santovar A). "VUELITE" (See Plastics). "VUEPAK" (See Plastics). W ATER-TREATING CHEMICALS (See Aluminum Sulfate, Ammonia, Chlorine, Ferrisul, Hypochlorite of Soda. Santobrite, Santosite, Sodium Alnminate. Sodium Sulfate). 24TH KDITION Page 143 0683883 TOWOLDMON0006758 WATER_PCB-00003268 WETTING AGENTS (See Arei-tap, Areaket, Aresklene, Santomerse). XANTHATES, (See Potassium Amyl Xanthate and Potassium Ethyl Xan* (hate). ZINC CHLORIDE Grades: 23 He. and 52 B. solutions. It.It. Classification! Zinc Chloride Liquid, General Information! I *ed as a flyn in galvanizing and soldering since it has the acid properties of muriatic acid without being volatile at the temperature used. The following products are made by Monsanto Chemicals Limited, London, England, find are not at present available for sale bv Monsanto in the United States: "ACHOSYL" ANTHRACENE OIL Al'RINE BENZENE BENZENE ABSORBING OIL COLMARO-NE RESIN CREOSOTE NAPHTHA, HIGH FLASH NAPHTHA, SOLVENT NAPHTHALENE PITCH PYRIDINE BASES TAR ACID OIL TOLUENE Page 144 [ON3ANTO CHEMICALS 0663864 TOWOLDMON0006759 WATER_PCB-00003269 Kthavan. "Ethavan (Pure Ethyl Vanillin)." 4-page pocket size folder, giving properties and uses. Ferrisul. "Ferrisul for Metal Treatment.'' 12-page file size booklet, giving properties and directions for use of Ferrisul for pickling stainless steel and copper and for etching metal articles preparatory to galvanizing. Ferriaul. "Ferriaul for Treatment of Water, Sewage and Industrial Wastes. " 16-page file size booklet, giving properties and directions for use of Ferriaul for treatment of municipal water supplies, sewage and industrial wastes and for other industrial uses. Ferropbosphorus. "Phosphorus-Iron Alloys, Bulletin No. 1." 36-page file size booklet, containing a report of general exploratory research upon influence of phosphorus in low carbon, low alloy steel. Based on work done at fiattelle Memorial Institute. Ferrophoaphorua. "Phospborus-Iroo Alloys, Bulletin No. 2." 64-pagr file size booklet. A report of experimental research investigation on corrosion and mechanical influence* on alloying elements in low alloy steel, Ferrophoaphorua- Phosphorus-Iron Alloys, Bulletin No. 3." 56-page file size booklet in two parts. Part one: Digest of U.S. Patents relating to phosphorus as an alloying element. Part two-: Lisl of U.S. Patents relating to steel production and treatment. Ferrophoaphorua. "Phosphorus-Iron Alloys, Bulletin No. 4." 20-page file size booklet containing reports of experimental investigation on the influence of phosphorous in Cr.-Mo steels and ettcle in high temperature service. "Hibitite and Its Uses." 4-page mimeographed bulletin. Lacquers. "Saflex Lacquers." 4*page mimeographed bulletin on Saflex fabric coatings, J6TH EDITION 0683665 TOWOLDMON0006760 WATER_PCB-00003270 MONSANTO LITERATURE__Continued Lampblack. "Monsanto Bear Lampblack. Properties and Principal Uses.'' 12-page pocket size booklet, giving description and analyses of the various grades of Monsanto Lampblack. Latex. "Latex Compounding.** 36-page file size illustrated booklet containing comprehensive discussion of latex compounding methods and technique, com pounding materials and various test data. Manicure Lacquera, "Monsanto Manicure Lacquer." Pocket size color curd folder, containing sample chips of the standard creme ahadesof Monsanto man icure lacquera. Mertec. "Maintenance Paints." Mimeographed bulletin. Methyl Salicylate. "Methyl Salrylate Monsanto." 4-page pocket sizr folder giving specifications and uses. IVrmaian. * Chemicals for Termite Control." Monsanto Technical Bulletin No. 0-13. August 22. 1940. 4-page file size bulletin describing recommended chemicals for treatment of soil and wood. Permoaan 116. ' Permaaan 116. A Water Repellent Preservative for Wood," Monsanto Technical Bulletin No. 0-21. February 1.3. 1941. 8-page file size bulletin giving properties and application dat<. Phoailage. "Grass Silage for Moro Profitable Livestock Farming--How to Make It and How to Feed It." 32-page pocket size booklet, describing procedure for making and feeding grass silage in which Phoailage is used as the preser vative. Plasticizer* and Resina. "Plasticisers and Resina, Specifications and Applies, lion Data." Revised May, 1940. 40-page file size booklet, giving comprehensive data on properties and applications of Monsanto plasticizers and resins, which include the Stniicixert, phthalatet, phosphates, SantoUtee, xnd Aroclors. Plastics. "Resinox, A Monsanto Plastic." 12-page illustrated booklet describ ing properties, manufacture, molding, and uses of Resinox phenol-formaldehyde plastic. Plastics. "Luitron, A Monsanto Plastic." 16-page illustrated booklet describ ing properties, manufacture, molding, ana uses of Luitron, Monsanto poly styrene. Plastics. "A Wartime Guide to Monsanto Plastics." 15-page file sise booklet describing the main groups of Monsanto Plastics and some of their wartime applications. Potassium Pyrophosphate, Tetra. "Tetrapotassium Pyrophosphate." Mon santo Technical Bulletin No. P-23. January 1. 1941. 4-page file site bulletin. Rubber Chemicals. "Monsanto Chemicals for the Rubber Industry." 44-page file site booklet giving properties and general characteristics and uses of Mon santo accelerators, antioxidants, softeners and miscellaneous materials for the rubber industry. Page 146 WONSANTO CHEMICALS 0683866 TOWOLDMON0006761 WATER_PCB-00003271 MONSANTO LITERATURE__Continued Rubber Compounding. "Rubber Compounding for the Wire Industry.'' 17-page file size booklet giving specifications and testing and compounding data <>n rubber \rire coatings. Sanlobrite. "Sanlobrite for the Preservation of Adhesives." Monsanto Tech nical Bulletin No, 0-1. June I. 1940. 6-pag* file size bulletin. Santobrite. 'Sanlobrite and Santophen 20 for Paint Preservation," Mon santo Technical Bulletin 0-2. 2.page tile size bulletin. Santobrite. ' Sanlobrite for Mirn.-organism Control in the Pulp and Paper Industry." Monsanto Technical Bulletin No. 0-5. April 1, 1940. 8-page file *ize bulletin. Santobrite. Santobrite for the Control of Slime and Algae," Monsanto technical Bulletin No. 0-15, March 25, 1940. 6-page file size bulletin, describ ing Santobrite for the control of shine and algae in industrial cooling water y stems. Santobrite. "Santobrite for the Preservation of Rubber Late*," Monsanto Technical Bulletin No. 0-17. September 29, 1939. 8-page file size bulletin des cribing the use of Santobrite for preventing biological deterioration of raw latex ami latex products. Santobrite. "Santobrite in the Tanning Industry," Monsanto Technical Bulletin No. 0-19, June 20. 1940. 6-page file size bulletin describing the use of Santobrite for preserving hides, tanned leather, and tanning materials from mold and biological deterioration. Santobrite. "Santobrite--Methods of Handling and Application," Monsanto Technical Bulletin No. 0-22. 8-page file size bulletin. Santobrite. "Preservation of CellUose Insulating Materials by Monsanto." 24-page file size booklet describing the use of Santobrite for protecting cellulose insulating materials and fibre boards from attack by decay and termites. Contains much investigational and field data. Illustrated. Santobrite. "Sap Stain Control by Monsanto." Revised August, 1940. 24page illustrated file size booklet, describing the use of Santobrite for controlling sap stain and mold in green lumber. Santoehlor. "Santocblor for the Control of Peach Tree and Stone Fruit Borers," Monsanto Technical Bulletin No. 0-18, December 1. 1939. 3-page file size bulletin. Santolube. "Santolubee--Corrosion Inhibitors for Lubricating Oils." 20-page file size booklet giving properties and results of operating and laboratory tests. Santomaak. "Santomaek for After-Odor Control of Interior Paint, Printing Inks and Some Other Odoriferous Formulations." Monsanto Technical Buelltin No. 0-16, July 26, 1940. 2-page file efre bulletin, giving properties and directions for use. 26TH EDITION Page 147 0683887 TOWOLDMON0006762 WATER_PCB-00003272  MONSANTO LITERATURE--Continued Sanlomerar. "Sanicunerse."' 32-page tile size booklet, giving physical and chemical properties and applications of Sanlornerse as a detergent and wetting, spreading, penetrating, cleaning and dispersing agent. Sonlopheti T. "Sanlophen 7, A Germicide and Industrial Preservative.'* Monsanto Technical bulletin No. 0-3. August 15, 1911. 7-page file size bulletin git ing properties and application datj,. Suntopour. 'Sontopour. A Pour-Point Depressant for Lubricating Oils." 10-puge file size booklet describing properties, method of application, and tent mill field service results. Sopanox. "Sopanox--An Antioxidant for Soaps.*' Monsanto Technical Bulle tin No. P-100, May 1, 1939. 3-page fde size bulletin giving properties and direc tions for use of Sopanox, also methods of testing soap for oxidation and rancidity. Vanillin. "Vanillin Monsanto.** -1-page pocket size leaflet giving properties Vuepak. "How Vuepak Helped 21) Manufacturers to Package for Greater Sales.*' 30-page file size booklet, giving case studies of sales gains resulting from use of Vuepak. Intermediates are made at the Norfolk, Virginia, plant. Page 148 MONSANTO CHEMICALS 0683888 TOWOLDMON0006763 WATER_PCB-00003273 GENERAL DATA TESTING LIQUIDS WITH THE BAL'ME HYDROMETER Monsanto products, when made to a Bautne specification, may vary 0.2 Be. above but never below ilie specified strength. The hydrometer used should be of limited range, not more than 10 B4., and should be at lease 10' in length. Its accuracy should be certified by the manufacturer. Our own hydrometers are tested against standard glasses certified by the U. S. Bureau o{ Standards, METHOD OF READING THE HYDROMETER* The correct method of reading tlie hydrometer is illustrated in Figs. 1 and 2. The sample of liquid is placed in a rlrar glass jar or cylinder and (lie hvdrometer carefully immersed in it to a point slightly below that to which it naturally sinks, and Is then allowed to float freely. The reading should not be taken until the liquid and the hydrometer are free from air bubbles and are at rest. *9. > ;/9j Method of Reading Baume Hydrometer In taking the reading the eye should be placed slightly below the plane of the surface of the liquid (Fig. 1) and then raised slowly until this surface, seen as an ellipse, becomes a straight line (Fig. 2). The point at which this line cuts the hydrometer scale should be taken as the reading of the instrument (Fig. 2). In case the liquid is not sufficiently clear to allow the reading to be made as above described, it will be necessary to read from above the liquid surface and to estimate as accurately as possible the point to which the liquid rises on the hydro meter stem. It should be remembered, however, that the instrument is calibrated * U. S. Bureau of Standards, Clrc. No. 57 26TH EDITION Page U9 0663669 TOWOLDMON0006764 WATER_PCB-00003274 to give correct indication# when read at the principal surface of the liquid. It will be necessary, therefore, to cotrect the reading at the upper meniscus by an amount equal to the height to which the liquid creeps up on the item of the hydrometer. The amount of this correction may be determined with sufficient accuracy for moat purposes by taking a few readings on the upper and the lower meniscus in a sample of the clear liquid and noting the difference. The magnitude of the correction will obviously depend upon the length and value of the subdivisions of the hydrometer scale and must be determined in each case for (he particular hydrometer in question. CORRECTING FOR TEMPERATURE The Thermometer must be used along with (he hvdrome(er in testing anv liquid. '} Hydrometers do not indicate the correct strength of a liquid unless read at the exact temperature indicated on the spindle, that is, at 60F. Accurate readings may be obtained by bringing the liquid to this temperature by cooling or warming, but in most instance* a correction can be applied with sufficient accuracy by reference to the following tables. For all liquids listed in this booklet, except Ammonia, the correction is added when the test is made above 60aF. and subtracted when made below 60F. For Ammonia the reverse is true. CONVERSION FORMULAE FOR DENSITY SCALES Heavy Liquids Degrees Twaddell *= (Sp. Gr. --1)200 Deg. Tw. +200 Sp. Gr. b-----------------------------200 I4S Degrees Rauml = 14S----------------- Sp. Gr. 145 Sp. Gr. ---------------------------------- 14S-- Deg. B4. Light Liquids 140 Degrees Baum# -----------------------130 Sp. Gr. 140 Sp. Gr. -- ----------------------- -- 130+Deg. B6. Page 150 UONSANTO CH1MICALS 0663890 TOWOLDMON0006765 WATER_PCB-00003275 THE DILUTION AND CONCENTRATION OF LIQUIDS AND MIXTURES RECTANGLE METHOD The figures expressing the percentage concentration of two solutions (or those of one solution, and the figure 0 for water, where dilution with water is desired) are written in the two left hand corners of a rectangle, and the figure expressing the desired concentration is placed on the intersection of the two diagonals of this rectangle. the figures on the diagonals, the smaller from the larger, and write the result at the other end of the respective diago nal. These figqrea then indicate what quantities of the solutions whos< concentration is given on the other end >f the respective horizontal line, must be taken to obtain a solution of the desired concentration. For ex. f/G./ ample, to mako a 12% solution, by mixing an 8% and a 15% solution we prepare Fig. 1, which indicates that we have to take 3 parts by weight of the 8% solution, and 4 parts by weight of the 15% solution to obtain (7 parts by weight of) the 12% solution. Again, if we wish to dilute a 25% solution so as to obtain a 9% solution, we place the figure 25 in, for example, the upper left corner of a rectangle and place figure 0 (concentration of the solution in pure water) in the lower left corner, and then place the figure 9 (desired concentration) at the point of intersection of the diagonals, and subtracting across the diagonals, we obtain Fig. 2: 9 parts by weight of the 25% solution, if mixed with 16 parti by weight of water, &GZ will give 25 parts by weight of a 9% solution. In diluting to a given Bauml strength or Specific Gravity, the percentage composition, corresponding to the Bum or Specific Cravity, must be taken _ from the following tables. For instance, supposing s 32 ..................... _^$0Baum Chloride of Alumina solution is to be diluted to 8 Baum6 with water. By reference to table on page 163 6.50 a 32 Baum6 solution contains 27.88% AljCU, and an 8s Baum solution contains 6.50% AljCl*. These percentages q.......oiust be used in finding the weights of Chloride of Alumina and water to b< mixed by the above method. According to the scheme as outlined above, the percentages are arranged as in Fig. 3 and the subtractions made along the diagonals. the lower from the higher. Thus when 32 Baum6 Chloride of Alumina is mixed with water in the proportion 6.50 pounds to 21.38 pounds, 27.88 pounds of solution will be obtained at 89 Baum*. 26TH EDITION Page 151 0683691 TOWOLDMON0006766 WATEFLPCB-00003276 SULFURIC ACID* By W. C. Ferguson and H. P. Talbot Depreea H6 Specific Gravity 60760* F. Per Cent H,SO Freezing (Melting) Point Dg. F. De grees B6. Specific Gravity 60760 F, Per Cent HSO< Freezing (Melting) Poim Deg. F. 0 1.0000 0.00 +32.0 36 1.3303 42 63 --TOO 1 1.0069 1.02 2 1 0140 2.08 3 1 0211 3.13 4 1 0284 4.21 +31.2 +30.5 +29.8 +28.9 37 1.3426 43.99 --60.0 38 1.3551 45 35 --53.0 39 1.3679 46 72 --17.0 40 1.3810 48.10 5 1.0357 5.28 +28.1 41 1.3942 49.47 --35 0 42 1.4078 50.87 --31.0 6 1 0432 6.37 +27.2 43 1. 1216 52.26 --27.0 7 1 0507 7 45 +26 3 44 1 6 53.66 --23.0 3 1 0584 8 55 +25.1 45 1 55.07 --20.0 9 1 0662 9.66 +24.0 10 1.0741 10.77 +22.8 46 1. 56 48 --14.0 11 1.0821 11.89 12 1.0902 13.01 13 1.0985 14 13 U 1.1069 15.2S +21.5 +20.0 +18.3 +16 6 47 1. 48 1. 49 1.5: SO 1.52 57.90 59.32 60.75 62.18 -15.0 --18.0 -22.0 --27.0 15 1.1154 16 38 16 1.1240 17.53 17 1.1326 18.71 18 1.1417 19.89 19 1.1508 21.07 20 1.1600 22.25 21 1.1694 23.43 22 1.1789 24 61 +14.7 +12.6 +10.2 +7.7 +4 8 +1.6 --1.8 --6.0 Si 1 5426 63.36 --33.0 52 1.5591 65.13 --39.0 S3 1.5761 66.63 --49.0 54 1.5934 68.13 --59.0 55 1.1611 69.6$ | 56 1.6292 71.17 57 1.6477 72.75 58 1 6667 74.36 59 I 6860 75.99 t -7.0 23 1.1885 25.81 --11.0 24 1.1983 27 03 --16 0 25 1.2083 28 28 --23.0 60 1 7059 77.67 61 1 7262 79 43 +12.6 +27.3 62 1.7470 81.30 +39.1 26 1.2185 29.53 --30.0 63 1 7683 83 34 +46.1 27 1.2288 30.79 --39.0 64 1.7901 85.66 +46.4 28 1.2393 32.05 --49.0 64H 1 7957 86.33 +43.6 29 1.2500 S3 33 --61.0 64M 1 8012 87.04 +41 1 30 1 2609 34 63 --74 0 64 H 1.8068 87.81 +37 9 65 1.8125 88.65 +33 1 31 1.2719 35.93 --82.0 65 H 1.8182 89.55 +24 6 32 1.2832 37 26 --96 0 65 H 1.8239 90.60 +13 4 33 1.2946 38.58 --97.0 65 H 1.8297 91 80 -- 1.0 34 1.3063 39 92 --91.0 35 1.3182 41.27 --81 0 66 1.8354 93 19 --29.0 This table has been approved and adopted as a Standard by the Manufact uring Chemist*' Association of tbe United States. fBelow---40. Specific Gravity determinations wer< made at 60 F., compared with water at 60F. (Continu-td) Page 152 Monsanto cmbmicals 0683892 TOWOLDMON0006767 WATER_PCB-00003277 SULPHURIC ACID_Continued From the Specific Gravities, the corresponding degrees Baum4 were calmlatrd hy the following formula: llaume= 145--I45/Sp. Gr. ALLOWANCE FOR TEMPERATURE At 10' He.correction of .029" 86. or .00023 Sp. G. for every 1"F. At 20 B6. correction of .036 Be. or .00034Sp. G. for every 1F. At 30 Be. correction of .035" D6. or .00039Sp. G. for every I'F. At 10" Be. correction of .031 Be. or .00041Sp. G. for every 1F. At 50" B6. correction of .028 Be. or .00045Sp. G. for every I'F. At 60" B6. correction of .026' Be. or .00053Sp. G. for every 1" F. At 63" B6. correction of .026 B6. or .00057Sp. G. for every 1"F. At 66" Be. correction of .0235' B6. or .00054 Sp. G. for every 1F. For temperatures above 60F., the correction is added to the observed in dication; below 60F. subtracted. % Oleum OLEUM % Free SO, Eouiv. % HjSO, Freesing Point F. 0 0 100.00 50.5 10 10 102.25 32.0 20 20 104 49 22.0 25 25 105.62 47.0 30 30 106.75 66.0 40 40 109.0 91.9 50 50 111.25 91.9 60 60 113 5 62 0 65 65 114.62 38.0 70 70 115.75 56.0 80 80 118.0 78.0 26TB EDITION Page 153 0683893 TOWOLDMON0006768 WATER_PCB-00003278 Degrees Baum6 1.00 2.00 3.00 4.00 5.00 3 as 5.50 5. 75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8 25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.25 10.50 10.75 11.00 1125 11.50 11.75 12 00 12 25 12 50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 Page 154 HYDROCHI ORIC ACID* (Muriatic Acid) By W. C Ferguson Specific 60760 F. Gravity 1 0069 1.0140 1.0211 1.0284 1.0357 1.0375 1.0394 1.0413 1.0432 1 0450 1 0469 1.0488 1.0507 1.0526 1.0545 1 0564 1.0584 1.0603 1.0623 1.0642 1.0662 1.0681 1.0701 1.0721 1.0741 1.0761 1.0781 1.0801 1.0821 1.0841 1.0861 1 0881 1.0902 1.0922 1.0943 1.0964 1.0985 1.1006 1.1027 1.1048 1.1069 1.1090 1.1111 1.1132 1.1154 Per Cent HCI. Degrees Bauoi 1.40 2.82 4.25 5.69 7.15 15.25 15.50 15.75 16 0 16.1 7.52 7.89 8.26 8.64 9.02 16.2 16.3 16 4 16 5 16.6 9.40 9.78 10.17 10.94 17 :4 1> 1 17 A 11.32 11.71 12.09 12.48 12.87 17.2 17.3 17 4 17.5 17.6 13.26 13.65 14.04 14.43 14.83 17.7 17 a 17.9 18 0 18 1 15.22 15.62 16.01 16.41 16.81 18 2 18.3 18.4 18.5 18.6 17.21 17.61 18.01 18 41 1882 18.7 18.8 18.9 19.0 19.1 19.22 19 63 20.04 20.45 20.86 19,2 19.3 19.4 19.5 19.6 21.27 21.68 22.09 22.50 22.92 1 19.7 19.8 19.9 20.0 20.1 (Continued) Specific Gravity 60760* F. 1.1176 1.1197 1.1219 1.1240 1.1248 1.1256 1.1265 1 1274 1.1283 1.1292 1.1301 11310 1.1319 1.1328 1.1336 1.1345 1.1354 1.1363 1 1372 1.1381 1.1390 1.1399 1.1408 1.1417 1.1426 1.1435 1.1444 1.1453 1.1462 1.1471 1.1480 1.1489 1.1498 1 1508 1.1517 1.1526 1.1535 1.1544 1.1554 1.1563 1.1572 1.1581 1.1590 1.1600 1.1609 Per Cent HCI. 23.33 23.75 24.16 24.73 24.90 25.06 25.23 25.39 25.56 25 ' 25 26 26 26.,, 26.56 26.73 26.90 27.07 27.24 27.41 27.58 27.75 27.92 28.09 28 26 28 44 28 61 28.78 28 95 29.13 29.30 29.48 29.65 29.83 30.00 30.18 30.35 30.53 30.71 30.90 31.08 31.27 31.45 31.64 MONSANTO CHEMICALS 0663694 TOWOLDMON0006769 WATEFLPCB-00003279 HYDROCHLORIC ACID_Continued Degrees Baumd 20.2 20.3 20 4 20.5 20.6 20.7 TO.8 20.9 21.0 21.1 21.2 21.3 21.4 21.5 21.6 21.7 21.8 21.9 22.0 22.1 22.2 22.3 22.4 22.5 22.6 22.7 22.8 22.9 23.0 23.1 Specific 60 .60 F. Gravily l.1619 1 1628 l.1637 1.1647 1.1656 1.1666 l.1675 1.1684 l.1694 1.1703 1.1713 1.1722 . 1732 1.1741 1.1751 1.1760 1.1770 1.1779 1.1789 . 1798 1.1808 1.1817 1.1827 1.1836 1.1846 1.1856 1.1866 1.1875 1.1885 1.1895 Per Cent HC1. 31.8;! 32.01 32.19 32,38 32.56 32.75 32.9,1 33.12 33 31 33.50 33.69 33.88 34.07 34.26 34.43 3161 34.8! 35.02 35.21 35.40 35.59 35.78 35.97 36.16 36.35 36.54 36.78 36.93 37.14 37.36 Degrees Baume 23.2 23.3 23 4 23.5 23.6 23.7 23.8 23.9 24.0 24.1 24.2 24.3 24.4 24.5 24.6 25.7 24.8 24.9 25,0 25.1 25.2 25.3 25.4 25.5 Specific Gravity 608.60 F. 1.1904 1.1914 1.1924 1.1934 1.1944 1.1953 l.1963 1.1973 1.1983 1.1993 1.2003 1.2013 1.2023 1.2033 1.2043 1.2053 1.2063 1.2073 1.2083 1.2093 1.2103 1.2114 1.2124 1.2134 Per Cent HCI. 37.58 37.80 38 03 38.26 3B.49 38.72 38 95 39 18 39.41 39.64 39.86 10.09 40.32 40.55 40.78 41.01 41.24 41 48 41.72 41.99 42.30 42.64 43 01 43.40 This table baa been approved and adopted as a Standard by the Manufact* uring Chemists* Association of the l nited States. Specific Gravity determinations were made at 60F., compared with water at 60F. From the Specific Gravities. tbo corresponding degrees Baumd were calcul* ated by the following formula: 145 Baumd =145 ---------------- SP. G. allowance: for temperature At 10 to 15 At 15 to 22s At 22 to 25s Bd.correction of ) /40 Bd. or .0002 Sp. G. for every 1F. Bd.correctionof )/30 Bd. or .0003 Sp. G. for every 1 F. Bd.correction of ) /28 Bd. or .00035 Sp. G. for every 1F. 26TH EDITION Page 155 0683895 TOWOLDMON0006770 WATER_PCB-00003280 Decrees Baume 10 00 10 25 10. To 11.00 11.25 11.50 11. T5 12.00 12.25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19 50 19.75 20.00 20.35 20.50 20.75 21 00 Page 156 NITRIC ACID* By W, ('. Ferguson Specific Gravity 60 60F. 1.0711 1.0761 1.0781 1 08(11 1 0821 1 1.0841 1.0861 1.0881 1.0902 1.0922 Per Cent HNOj 12.86 13.18 13.49 13 81 14 13 14.44 14.76 15.07 15.41 15,72 Degrees 1 Daume 1 1 21.25 i 21.50 l 21.75 1 22.00 22.25 22 50 22.75 23.00 23.25 23.50 Specific Gravity 60/60' F. 1.1718 1.1741 1.1765 1.1789 1.1813 1.1837 1.1861 1.1885 1.1910 1.1934 Per Cent HNOj 28 02 28 36 28 72 29 07 29.43 29.78 30 14 30.49 31.21 1.0943 1.0964 1.0985 1.1006 1.1027 16.05 16.39 16.72 17.05 17.38 23.75 24.00 24.25 24.50 24.75 1.1959 1.1983 1.2008 1.2033 1.2058 31.58 31.94 32.31 32.68 33.05 1.1048 1.1069 1.1090 1.1111 1.1132 17.71 18.04 18.37 18.70 19.02 25.00 25.25 25.50 25.75 26.00 1.2083 1.2109 1.2134 1.2160 1.218S 33.42 33.80 34.17 34.56 34.94 1.11S4 1.1176 1.1197 1.1219 1.1240 19.36 19.70 20.02 20.36 20.69 26.25 26.50 26.75 27.00 27.25 1.2211 1.2236 1.2262 1.2288 1.2314 35.33 35.70 36.09 36.48 36.87 1.1262 1.1284 1.1306 1.1328 1.1350 21.03 21.36 21.70 22.04 22.38 27.50 27.75 28.00 28.2$ 28.50 1.2340 1.2367 1 2393 1.2420 1.2446 37.26 37.67 38.06 38.46 38.85 1.1373 1.1395 11417 1.1410 1 1462 22.74 23.08 23.42 23.77 24.11 28.75 29.00 29.25 29.50 29.75 1.2473 1.2500 1.2527 1.2554 1.2562 39.25 39.66 40.06 40.47 40.89 1.1485 1.1508 1.1531 1.1554 1.1577 24.47 24.82 25.18 25.53 25.88 30.00 30.25 30.50 30.75 31.00 1.2609 1.2637 1.2664 1.2692 1.2719 41.30 41.72 42.14 42.58 43.00 1.1600 1.1624 1.1647 1.1671 1 1694 26.24 26.61 26.96 27.33 27.67 31.25 31.50 31.75 32.00 32.25 (Continued) 1.2747 1.2775 1.2804 1.2832 1 2861 43 44 43.89 44 34 44.78 45 24 MONSANTO CBBHICALS 0683896 TOWOLDMON0006771 WATER_PCB-00003281 NITRIC ACID_Continued Degrees Baum6 32 SO 32 75 33.00 33 25 33.50 33." 34 00 34.25 34.50 34. 75 35 00 35.25 35.50 35.75 36.00 36.25 36.50 36.75 37.00 37.25 37.50 37.75 38.00 38.25 38.50 38.75 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40.75 41.00 Specific Gravity 60 60 F. 1.2889 1.2918 1.2946 1 2975 1 3004 1.3034 1.3063 1.3093 1.3122 1.3152 1.3182 1 3212 \.3242 1.3273 1.3303 1.3334 1.3364 1.3395 1.3426 1.3457 1.3488 1 3520 1.3551 1.3583 1.3615 1.3647 1.3679 1.3712 1.3744 1 3777 1.3810 1.3843 1.3876 1.3909 1.3942 Cent HN'Oj Degrees Baitme 45 68 44 N 46 58 47 04 47.49 41.25 41 50 41 75 42 00 42 25 47.95 48.42 48 90 49 3S 49.83 42.50 42. 75 43 00 43 25 43 50 50.32 50 81 51 30 51 80 52.30 43.75 44.00 44.25 44.50 44.75 52.81 53.32 53.84 54.36 54.89 45 00 45.25 4o. OO 45 75 46.00 55.43 55.97 56.52 57.08 57.65 46.25 46.50 46.75 47.00 47.2S 58.23 58.82 59.43 60.06 60.71 , 47.50 47.75 48.00 48.25 48.50 61.38 62.07 62.77 63.48 64.20 Specific Gravity 60 60'F. 1.3976 1.4010 1.4044 1.4078 1.4112 1.1146 1 4181 1.1216 1 4251 1.4286 1.4321 1.4356 1 4392 1.4428 1. 4164 4500 1 4536 1.4573 1. 4610 1.4646 1.4684 1.4721 1.4758 1.4796 1 4834 1.4872 1.4910 1.4948 1.4987 1.5026 Per Cent H\Oj 64 93 65 67 66.42 67 18 67.95 68,73 69 52 71 15 71 98 72.82 73.67 74.53 75.40 76.28 77 17 78.07 79.03 80 04 81.08 82.18 83.33 84.48 85.70 86.98 88.32 89.76 91.35 93.13 95.11 Thi# (able hat been approved and adopted at a Standard by the Mazmfacturing Cbemuta' Association of the United State*. Specific Gravity determinations weri* made at 60 F. compared with water at 60F. From the Specific Gravities, the corresponding degree* Baumd were calcu lated by the following formula: -- US Baum6145 -- ------------------ Sp. G. (Continued) 2 CTB EDITION Page \S7 0683897 TOWOLDMON0006772 WATER_PCB-00003282 .NITRIC ACID_Continued ALLOWANCE FOR TEMPERATURE At from 10 to 20 B6. correction < 1/30 B6. or .00029Sp. G. for every IT. At from 20 to 30 B6. correction of 1/23 B6. or .00044Sp. G. for every 1F. At from 30 to 40 B6. correction of 1/20 B6. or .00060 Sp. G. for every1F. At from 40 to 43.5 B<. correction nf 1/17 B6. or .00034 Sp. G. for every 1F. ACETIC ACID 60,60 F. Ouctemanns Specific Gravity 1.0000 1.0016 1.0032 1.0047 1.0062 1.0077 1.0093 1.0108 1.0123 1.0137 1.0152 1.0167 1.0181 1.0195 1.0210 1.0224 1.0238 1.0252 1.0266 1.0280 1.0294 1.0308 1.0321 1.0334 1.0347 1.0360 1.0373 1.0385 1.0398 1.0410 1.0422 1.0434 1.0446 1.0457 Per Cent CjHA 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 Specific Gravity 1.0469 1.0480 1.0491 1.050? 1.0512 1.0523 1.0533 1.0543 1.0553 1.0562 1.0572 1.0581 1.0590 1.0599 1.060? 1.0617 1.0625 1.0633 1.0641 1.0648 1.0656 1.0663 1.0670 1.0676 1.0683 1.0689 1.0695 1.0701 1.0707 1.0712 1.0717 1.0722 1,0727 1.0731 Per Cent CjHA 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 51 52 53 54 55 56 57 . 58 59 60 ! 61 62 , 63 64 65 66 67 Specific Gravity 1.0735 1.0739 1.0743 1.0747 1.0750 1.0752 1.0754 1.0756 1.0757 1.0758 1.0758 1.0758 1.0758 1.0757 1.0756 1.0754 1.0752 1.0749 1.0746 1.0741 1.736 1.0730 1.0723 1.0715 1.0706 1.0696 1.0684 1.0670 1.0654 1.0635 1.0614 1.0590 1.0563 Per Cent CjHA 72 73 77 82 83 87 92 97 98 100 PHe 153 MONSANTO CBIMICALS 0683896 I TOWOLDMON0006773 WATER_PCB-00003283 AQUA AMMONIA* liv U ('. Ferguson Degrees Baum 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 12.00 12.25 12.50 12.75 13.00 13 25 13 50 13.75 14.00 14 25 14 50 14,75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17,00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 Specific Gravity 607604. 1.0000 .9982 .9964 .9947 .9929 .9912 .9894 .9876 .9859 .9842 .9825 .9807 .9790 .9773 .9756 .9739 .9722 .9705 .9689 .9672 .9655 .9639 .9622 .9605 .9589 .9573 .9556 .9S40 .9524 .9508 .9492 .9475 .9459 .9444 .9428 .9412 .9396 .9380 .9365 .9349 Per Cent Mij j Degrees | Batiml .00 .40 .80 1.21 . 62; 1 | 1 20.00 20.25 20.50 20.75 21.00 2.0* 2.40 2.8<: 3.30 3.7$ 21.25 21.50 21 7S 22.00 22.25 4.10 4.50 5.0* 5.45 5.8* 22.50 22.75 23.00 23.25 23.50 6.3] 6.74 7.17 7.61 8.05 23.75 24.00 24.25 24.50 24.75 8.49 8.93 9.38 9.83 10.28 25.00 25.25 25.50 25.75 26.00 10.73 11.18 11.64 12.10 12.56 26.25 26.50 26.75 27.00 13.02 13.49 13.96 14.43 14.90 27.25 27.50 27.75 28.00 28.25 15.37 15.84 16.32 16.80 17 28 28.50 28.75 29.00 Specific Gravity 60/60F. .9333 .9318 .9302 .9287 .9272 .9256 .9241 .9226 .9211 .9195 .9180 .9165 .9150 .9135 .9121 .9106 .9091 .9076 .9061 .9047 .9032 .9018 .9003 .8989 .8974 .8960 .8946 .8931 .8917 .8903 .8889 .8875 .8861 .8847 .8833 .8819 .8805 Per Cent NH, 17 76 18.24 18.72 19.20 19.68 20.16 20.64 21 12 21.60 22.08 22.56 23.04 23. S2 24.01 24.50 24.99 25.48 25.97 26.46 26.95 27.44 27.93 28.42 28.91 29.40 29.89 30.38 30.87 31.36 31.85 32.34 32.83 33.32 33.81 34.30 34.79 35.28 '"This table lias been approved an<? adopted as a Standard by (be Manufac luring Chemists' Association of the Lnited States. Specific Gravity determinations wi re made at 60F, compared with water at 60F. ' (Continued) 20TH EDITION Page 15*> 0663899 TOWOLDMON0006774 WATER_PCB-00003284 AQl'A AMMONIA__ Continued ] to Rating ==------------ -- 150. Si'. I- ALLOWANCE FOK TEMPERATURE Tin* coefficient of expansion for at mioniu solutions varying with the temper* a t urr. correction must be applied according to the following table: -- Degrees I Hainne j I Corrections to be Added for Each Decree below 6<>F. IFW. 163 " 18 " 20 '* ' 20 ' 40;F. .Ol.VBc. .021 " .027 " .0.83 " .039 " .053 " 50eF. Ol.'Be, (J23 " 029 " 036=' " .012 " .057 " Correction* to be Subtracted for Each Decree Above 6fiF. 7)1*. i 8<JF. ] 90'F. .(i;:oRe. i .uta* " 1 .0^1 - ! .0^7 ** ; .043 i . Of.7 i .022IU. | .028* .033= " I .038' " ! .015' " 1 .059 ' 024Be. .030 " 035 ' .040 " 0t7 " ] 00 F. ,026B6. .032 " .037 ,f .042 " Central Research Department Laboratories* Dayton* Ohio Page 160 MONSANTO CHEMICALS 0683900 TOWOLDMON0006775 WATER_PCB-00003285 Temp. F8' --w -35 - .m -J3 --20 -- 15 -- 10 --s 0 5 10 15 20 2S 30 35 10 4S 50 55 60 65 70 To 95 100 no us 120 125 ANHYDROUS AMMONIA Specific \olunte Lb*, per Sq. In. Ab. <>:' Liquid C.a Ft. per Lb. of Sat. Vapor, Cu. Ft. per Lb. 10.12 11.74 13.56 15.61 9.0234 0.0235 0 0236 0.0238 25.45 22.14 19.35 16.95 17.91 20.46 23.30 26.46 0.0239 0.0240 0.0241 0.0242 14.89 13.15 11.63 10.32 29.95 33.79 38.02 42.67 0.0244 0.0245 0.0246 0.0248 9.19 8.20 7.34 6 583 47.75 53.50 59.39 65.91 0.0249 0.0250 0.0252 0.0253 5,920 5 336 4 820 4.364 73.03 80.75 89.09 98.03 107.7 118.1 129.2 141.1 153.9 167.4 181.8 197.3 213.8 231.2 249.6 269.2 289.9 311.6 0.02S5 0.0256 0.0258 0.0259 0.0261 0.0263 0.0264 0.0266 0.0268 0.0270 0.0271 0.0273 0.0275 0.0277 0.0280 0.0282 0.0284 0.0286 3 959 3 599 3 278 2.992 2.734 2 503 2.296 2 109 1.940 1.788 1 650 1.524 1 408 1.305 1.210 1.122 1.042 0.970 Heat of \ aporization. B.T.l. 601.9 598.3 594.7 591.1 587.4 583.6 579.9 576.1 572.2 568.3 564.4 560.4 556.3 552.2 548.1 543.9 539.7 535.3 531.0 526.5 522.0 517.5 512.8 508.1 503.4 498.5 493.5 488.5 483.4 478.2 472.9 467.4 461.9 456.3 Sp. G. Liquid 0.6364 at 32*F. 2TH EDITION Page 161 0683901 TOWOLDMON0006776 WATER_PCB-00003286 ALUMINUM CHLORIDE 60 60 F. Biwhoff I'i JL? Jfj Ij t a* Si CJ a. < .00 .50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 S.50 6.00 650 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16 00 16.50 17.00 1.0000 1.0035 1.0069 1.0105 1.0140 1.0175 1.0211 1.0247 1.0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0534 1.0623 1.0662 1.0701 1.0741 1.0781 1 0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1.1154 1.1197 1.124A 1.1284 1.1328 .00 .35 .75 1.17 1.58 2.00 2.40 2.78 3.16 3.58 400 4.38 4.81 5.20 5.63 6.05 6.50 6 92 7.32 7.75 8.13 8.57 9.00 9.46 9.90 10.28 10.70 11 15 11.60 12.05 12.50 12.95 13.37 13.83 14.30 tv is tS a. < 00 .038 113 .178 .242 17.50 18.00 18.50 19.00 19.50 .307 .370 430 .490 .557 20.00 20.50 21 00 21.50 22.00 .625 .686 .756 .820 .890 22.50 23.00 21.50 24.00 24.50 .962 1.04 1.11 1.18 1.25 25.00 25.50 26 00 26.50 27.00 1.32 1.39 1.47 1.55 1.63 27.50 1 28.00 28. SO 29.00 29.50 1.70 1.77 1 85 1 93 2.02 30.00 30.50 31 00 31.50 32.00 2 10 2.19 2 27 2,35 2.44 | 32.50 ! 33.00 i 33 50 1 34.00 1 34.50 1 1.1373 1.1417 1 1462 1.1508 1.1554 1.1600 1.1647 1.1694 1.1741 1.1789 1.1837 1.1885 1.1934 1.1983 1.2033 1.2083 1.2134 1 2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3100 14 73 15.16 15.60 16.OS 16.53 16.94 17.43 17.88 18.33 18.78 19.22 19.68 20.13 20.57 21.03 21.50 21.98 22.38 22.82 23.20 23.70 24 13 24.58 25.02 25.53 25.99 26.45 26.92 27.38 27.88 28.33 28.78 29.24 29.68 30.00 1+ "< 2.53 2 60 2.78 2.88 2.96 3.06 3.15 3 25 3.34 3.43 3 53 3 62 3.72 3.81 3.90 4.02 4.12 4 21 4.30 4.41 4.50 4 61 4.72 4.83 4.94 5 04 S 16 5 27 5.40 5 50 S 62 5 73 5 85 5.92 * MjClt +12HjO, Chloride of Alumina Crystal. For Chloride of Alumina 32B6. twice tbe above pounds per gallon of soImuoq. Page 162 MONSANTO CHEMICALS 0683902 TOWOLDMON0006777 WATER_PCB-00003287 .k * 'i s (H) 50 1.00 1.50 2.0 2,5 3.0 3.5 40 4.5 5.0 5.5 6.0 6.5 7.0 75 8.0 8.5 9.0 9.5 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 14.0 14.5 15.0 15.5 16.0 16.5 17.0 17.5 18,0 18.5 19.0 19.5 1.000 1.0035 1.0069 1 OIOS 1.0140 1,0175 1.0211 1.0247 1.0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1.1154 1.1197 1.1240 l 1284 1 1328 1.1373 1.1417 1.1462 1.1508 1.1554 2Ara EDITION ALl.MIMM SILKATE 60 60 F. Beveridge hi 13 -1 SJ a* iZ .DO .53 1.07 1.64 2.16 .00 .044 .090 .138 .181 2.70 3.28 3.79 4 40 4.97 .228 .279 .323 .376 .427 5.52 6.10 6.73 7.33 7.98 .476 .528 .585 .638 .700 8.56 9.18 9.82 10.43 11.05 .751 .808 .860 .925 .980 11.65 12.26 12.90 13.53 14.13 1 04 no 1.16 1.22 1.28 14.71 15.32 15.98 16.60 17.25 1.34 1.40 1.47 1.53 1.59 17.90 18.48 19.13 19.80 20.40 1.66 1.72 1.79 1.86 1.92 21.06 21.73 22.43 23.10 23.78 1.99 2.06 2.14 2.21 2.28 (Continued) IuSl| "Iff* i 3 "is.!? Si* gs* 4 .00 0.6 1.1 1.7 2.3 2.9 3.5 4.1 4.7 5.3 6.0 6.7 7.3 7.9 8.5 9.2 9.8 10.5 11.1 118 12.4 13.1 13.8 14 4 15.1 15.7 16.4 17.1 17.7 18.4 19.1 19.9 20.4 21.1 21.8 22.4 23.1 23.7 24.4 25.1 00 050 .092 1.50 1.95 .246 .298 .350 .403 . 456 .518 .581 .635 .690 .745 .809 .865 .931 .988 1.05 1.11 1.18 1.25 1.30 1.37 1.43 1.50 1.57 1.63 1.70 1.77 1.86 1.91 1.99 2.06 2.12 2.20 2.26 2.34 2.42 P(te 163 0683903 TOWOLDMON0006778 WATER_PCB-00003288 ALUMINUM SULFATE-Continued 20 0 20 5 210 215 22.0 22 5 23 0 23.5 24.0 24.5 25 0 25.5 26.0 26.5 27.0 27.5 28 0 28.5 29.0 29.5 30.0 30.5 31.0 31.5 32.0 32.5 33.0 33 5 34.0 34.5 35.0 35.5 36 0 36. S t.1600 1.1647 1 1694 . 1741 1.1789 1.1837 1.1885 1.1934 1.1983 1.2033 1.2063 1.2134 1.2185 1.2236 I.2288 1.2340 l.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3122 1.3182 1.3242 1.3303 1 3364 24.38 24.99 25.60 26.22 26.87 27.50 28.16 28 85 29.50 30.18 30.85 31.54 32 24 32.95 33 63 34.35 35.03 35-7S 36.46 37.20 37.90 38 58 39.30 40.02 40.73 41.49 42.20 42.96 43.71 44.48 45.20 46.00 46 80 47.58 2.35 2.42 2. 49 2.56 2.64 2.71 2. 78 2.86 2.94 3.02 3.10 3. 18 3.27 3.3S 3.44 3.52 3.61 3.70 3.79 3.88 3.98 4 06 4 16 4 25 4.35 4.45 4.54 4.64 4.75 4.86 4.95 5.07 5.18 5 29 25.7 26.4 27.1 27.7 28.4 2.79 31.7 32.4 33. 1 33.8 34 5 35.2 35.9 36.7 37.3 38.1 38.8 39.7 40.3 41.0 41.8 42.5 43.3 44.1 *4.9 45 7 46 5 47 4 48.3 49 2 50.1 3. 18 3.61 3.70 4.06 4.55 4.66 4.76 5.09 5.21 5 59 FREEZING POINTS OF 0.6% "BASIC ALUM SOLUTIONS Baum6 at 60*F. 5 10 15 20 25 30 35 Freezing Point*, degree* F. 31 30 29 27 24 38 Page 164 MONSANTO CHKMICA h$ 068390*. TOWOLDMON0006779 WATER_PCB-00003289 SODIUM BISULFITE 6(1 60 F. H. B. Bisohoff ll L2 s^ 2 * XI =3 < .00 50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15 00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 1 ortoo 1 0D34 l 0069 1 0104 1.0140 1.0175 1.0211 1.0247 1 0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0564 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1,1111 1.1154 1.1197 1.1240 1.1284 1.1328 1.1372 1.1417 1.1462 1 1508 1.1554 .00 SI 1 02 1.53 2.04 2.55 3 06 3.57 4.08 4.59 5.11 5 63 6.15 6 67 7.19 7.71 8.24 8 77 9 30 9.83 10 36 10.89 11.42 11.95 12.48 13.02 13 56 1.410 14.65 15.20 15.75 16 30 16.85 17.40 17.96 18.52 19.08 19.64 20.20 20.76 .Oil . 3i. .63 .94 1.20 1.5'' 1.88 2.2< 2.5| 2.8fc 3 . IS 3.41 3.79 41) 4.43 4.75 5.01 5.46 5.7? 6.05 6.35 6.70 7.03 7.36 7.68 8.02 8.35 8 68 9.02 9.36 9.70 10.03 10.37 10.71 11.05 11.39 11.74 12.08 12.43 12.77 If XI ij '? 2 z --< 20 00 20 50 2 L 1)0 21.50 22.00 22.50 23.00 23 50 24.00 24.50 25.00 25.50 26 00 26.50 27.00 27.50 28.00 28 50 29.00 29.50 30.00 30.50 31.00 31. SO 32.00 32.50 33 00 33.50 34.00 34.50 35.00 35 50 36.00 36.50 37.00 37.50 3B.OO 38.50 39.00 39.25 1 1600 1.1647 1.1694 1.1741 1.1789 1.1837 1 1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1 2609 1 2664 1 2719 1.2775 1 2832 1 2889 1 2946 1 3004 1 3063 1.3122 1.3182 1.3242 1.3303 1.3364 1.3426 1.3488 1.3S51 1.3615 1.3680 1.3712 22.44 23 00 23.57 24.14 24.71 25 28 25.85 26.42 26.99 27.56 28 13 28.70 29.27 29 85 30.43 31.00 31 57 32.14 32.71 33.28 33 86 34.43 35.01 35.62 36.25 36 88 37.51 38.14 38.78 39.42 40.06 40 69 41.30 41.91 42.52 43.12 43.72 44.02 13 13 13 81 14.50 14.85 15.20 15.55 15.91 16.23 16,60 16.96 17.32 17.66 18.01 18.37 18.73 19.08 19.33 19.78 20 13 20.46 20.83 21.19 21.55 21.92 22.30 22.70 23.08 23.47 23.87 24.27 24.65 25.03 25.41 25.79 26.17 26.54 26.91 27 10 26TH EDITION Page 165 0663905 TOWOLDMON0006780 WATER_PCB-00003290 B4.8 .25 .50 .75 1.00 1 25 1.50 1 75 2.00 2.25 2.50 2.75 3 on 3 25 3.50 3.75 4.00 4.25 4.50 4.75 5.00 S.25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 B.25 6 50 8.75 Tw.8 .34 .70 1.04 1.38 1.74 2.10 2.44 2.80 3.14 3 50 3 86 4 22 4.58 4.94 5.30 S.6A 6.04 6.40 6.76 7.14 7.50 7,88 8.26 8.64 9,00 9.38 9.76 10.14 10.52 10.90 11.30 11.68 12.06 12.46 12.84 MERCLOR Per Cent Available Cl by Volume j B6.' .11 9.00 .21 9.25 .32 9 SO .43 9 75 .54 10.00 .65 .76 .87 .98 1.10 10 50 11.00 11.50 12.00 12.50 1 21 1.32 1.43 1.55 1.66 13.00 13.50 14.00 14.50 15.00 1.78 1.90 2.01 2.13 2.26 15.50 16 00 16.50 17.00 17.50 2.38 2.51 2.63 2.75 2.88 18.00 18.50 19.00 19 50 20.00 3.01 3.13 3.26 3.39 3.52 20.50 21.00 21.50 22.00 22.50 3.64 3.77 3.90 4.05 4. 18 23.00 23.50 24.00 24.50 25.00 Tw.8 13.24 13.62 14.02 14.42 14.82 15.62 16 42 17.22 18 04 18 86 19 70 20 54 21.38 22.22 23.08 23.94 24.80 25 66 26 56 27.44 28.34 29.24 30.16 31.08 32.00 32.94 33.88 34.82 35.78 36.72 37.70 38.68 39.66 40.66 41.66 Per Cent Available Cl by \ olume 4.57 4.71 4.84 5.38 5 65 5.94 6.24 6 52 6.83 7.12 7.41 7.71 8.01 8.31 8.60 8.92 9.23 9.54 9.87 10.19 10.51 10.84 11.18 11.52 11.89 12.23 12.60 12.95 13.33 13.71 14.11 14.50 Page 166 MONSANTO CBKMICAL9 0683906 TOWOLDMON0006781 WATER_PCB-00003291 WEIGHTS PEK GALLON AT 60* F. Arctic Acid 28% Arctic Acid 56% . Arctic Acid Glacial . Aluminum Chloride 32 B Amyl Acetate......................... Aqua Ammonia 18 B Aqua Ammonia 20 B Aqua Ammonia 26 B4 . Batter)' Acid 1.400............. Butyl Acetate....................... Pounds 8 66 8.90 Diacetone Alcohol........... Ethyl Acetate ....................... Iron, True Nitrate 47 B<............................................................................................. 1230 Iron, Copperas Nitrate 47 B6................................................................................... 1230 [run, Perchloride 40 B4............................................................................... 11 31 Merclor............................................................................................ Muriatic Acid 18 B6. Muriatic Acid 20 Be...................................................................................................... 9^7 Muriatic Acid 22 B6. Nitric Acid 36 B6......................................................................................................... \ itric Acid 38 B6. ...................................................................................................... 11.00 11.30 Nitric Acid 40 B6......................................................................................................... 11 51 Nitric Acid 42* B6................................... . 11 74 t>lemi 25% (at IS* C.}............................................................... ] ' ' ' ^ ' ' ]' '' '' 12 Oleum 60% (at 15 C.) ............................................................................................ 16 84 Phosphoric Acid 75%.................... ............................................................................ 13 o Sodium Bisulfite 33 B<.............................................................................................. Sulfuric Acid 66 B6................................................................................................... Sulfuric Acid 98%....................................................................................................... Sulfuric Acid 100% (Monohydrate).................................................................... Zinc, Cholride 52 Bl............................................................. Zinc. Cholride 72 B<............................................................................................ . 10. 78 15.30 15.36 15. H jg 55 Weight per gallon *= Sp, Gr. x 8.337 1 Cubic Foot r= 7.480 gallons 1 Gallon := 3.785 liters 97 950 983 13.00 26th edition Page 167 0683901 TOWOLDMON0006782 WATER_PCB-00003292 INTERCONVERSION TABLES FOR TO COM ERl FROM - MCLTIPL V BY--------------- To Cu. In. To Cu. Ft. To Cu. Yd. To FI. Oz. To Pint 1 To 1 T.i Quart 1 Gallon Cu. in. Cu. Ft. Cu. Yd. FI. Oz. Pint Quart Gallon Grain Ob. Troy l.b. Troy Or, Av. l.b. Av. 1.00000 1728 00 46656 0 1.80469 28.8750 57.7500 231.000 .003954 1.89805 22.7766 1.72999 27.6799 .0,5787 1.00000 27.0000 .001044 .016710 .033420 .133681 .0*2288 .001098 .013181 .001001 .016018 0,2143 .037037 1.00000 .0,3868 .0,61*19 .001238 . 004651 . Oj84i'5 . 0,4068 .0,48^2 . 0,3708 . 0,S933 .554112 957.505 25852 6 1.00000 16.0000 32.0000 128.000 .002191 1.05173 12.6208 .958608 15.3378 034632 59.8442 1615.79 .062500 1.00000 2.00000 8 00000 0.1369 .065733 .788800 .059913 .958611 .017316 29.9221 807 896 .031250 .500000 1.00000 4.00000 .0,6850 .032867 .394400 .029957 .479306 .004329 7.48052 201 974 .007813 .125000 250000 1 00000 .0,1712 .008217 .098600 .007489 .119826 CC or Gram 061024 Liter or Kg. 61.0237 On. M. 61023 7 .0,3531 .035315 35 3146 .0,1308 .0013)8 1.3070$ .033814 33 8140 33814 0 002113 2.11337 2113.37 .001057 1.05669 1056.69 .0^642 .264172 264.172 NOTEi--The small subnumeral following a aero indicates that the aero is to be taken that number of times, thus .0,1428 is equivalent <o .0001428. Values used in constructing table: 1 inch -- 2.540001 cm. 1 cu. in, -- 16.387083 cc. -- 16.387083 g. H,0 at 4"C.(39F.) lib. av. 453.S926 g. Page 168 MONSANTO CBBMICAL9 0663908 TOWOLDMON0006783 WATER_PCB-00003293 UNITS OF VOLUME AND WEIGHT uultiplyTT To Crain To To Oz. Troy Lb. Troy 252 891 439996 436.390 .526857 24581.0 .950813 .043905 75.8674 2048.42 .079234 7302.23 1460,45 .>84! 1. y 15.2130 1.26775 2.53530 10.1420 .0*1736 480.000 5760.00 44i. 500 1.00000 .911457 .083333 1.00000 .075955 1.21528 15.4523 .032151 32.1507 32150.7 .002679 2.67923 2679.23 To Oz. Av. .5780117 998.848 26968 9 1 043)8 16.6908 33.38)6 133 527 .002286 1.097)4 13.1657 1.00000 16.0000 .035274 3S 2739 35273.9 To To To Lb. Av. CC. or C. Lilar Or Kg 036127 62.4280 1685.56 .065199 16.3871 28316.9 29.5736 016387 28.3169 .029573 1.04318 2.08635 8.34541 0jl428 473.177 946.354 3785.42 064799 . 0,6479 ,068571 .822857 .062500 1.00000 31.1035 373.342 28.3495 453.593 453593 .002205 2.20462 2204.62 1.00000 1000 00 1000000 1000 on 1 lb. av. -- 27.679886 cu. it) 11,0 at 4<*C. (39`F.). 1 lb. av. = 7000 grains 1 gal. = 8.34541 lb. 1 gallon = 58417.87 grains. 231 cu. in. = 1 gal. = 3785.4162 g. To Cu. M. .0,2957 0;6479 .0,4536 [ 00000 26TB EDITION Page 1(W PIUNTKO (N U.S.A. 0603909 TOWOLDMON0006784 WATER_PCB-00003294 0683910 TOWOLDMON0006785 WATER_PCB-00003295  Modudid Chemical Company *u one of the flrel to be awarded the INavy "E" and Bureau of Ordnance Dig and the All-Nary "E" burg** 'In recognition of production of ordnance materiel vital to out national defeoee." It waa alto one of the Rnt to bo awarded the joint Army-Navy **E" buree "represent ing recognition by both the Army and Navy of especially meritorlaua production of war materials." 0683911 TOWOLDMON0006786 WATER_PCB-00003296 0663912 TOWOLDMON0006787 WATER_PCB-00003297