Document rBV964O1xwXJyjaBNaKy6DOBV

^Material Safety *Data Sheet (conoco Emergency Medical Telephone (800) 441-3637 t F UX4 JET A, JET A-FSII, JET FUEL v I. MATERIAL IDENTIFICATION Name Jet A, Jet A-FSII, Jet Fuel CAS Registry Number Mixture; See Section XI Synonyms Jet A Jet Fuel Product Code 4305/4306 Chemical Family Mixed Petroleum Hydrocarbons Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) II. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for other federal and state regulatory information. Hazardous Ingredients CAS Registry Number Hydrocarbons (Aromatk & Paraffinic) Mixture Naphthalene \ 91-20-3 Concentration >90% <3% Hazardous Physical Properties Class II Combustible Liquid - NFPA 30-1987. in. PHYSICAL DATA Appearance and Odor Clear liquid; Paraffinic odor Specific Gravity (H,0 = I) 0.81 Boiling Point/Range 330 - 572F % Volatiles (by volume) Nil Vapor Pressure (mmHg) @ 68*F 2 Solubility in Water Insoluble IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Materials: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. GASC0170/October 1989 SAL 000006771 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 V. FIRE Jtpfts^AlAZARD Data LELs 05 UED 6 Flash Point (Method used): 10QF (TCP Autolgnltlon Temperature: 475* - 50Q*F Handle and store In accordance with NFPA procedure for Gass II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association fNFPA) Gosslficatlon Health 0 Fire 2 Reactivity 0 VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Proper Shipping Name: Hazard Class: UN/NA N04 DOT Label(s): DOT Placard: IATA/IMO: Proper Shipping Name: Hazard Gass: UN Ntw IMO/ICAO Label: Special Information: Packaging Group: Fuel, Aviation, Turbine Engine Combustible Liquid UN 1863 None Combustible Fuel, Aviation, Turbine Engine 3 (IMO 3.2) UN 1863 Flammable Liquid Not Restricted Over 140F III m HEALTH HAZARD INFORMATION Exposure Limits for Jet A, Jet A-FSII, Jet Fuel PEL: None Established TLV: None Established Exposure Limits for Petroleum Distillates PEL: 400 ppm; 1600 me/m3 Exposure Limits for Naphthalene PEL: 10 pom. 50 mg/m3 STEL IS ppm. 75 mg/m3 Du Pont AEL: None Established TLV: 10 ppm, 50 mg/m* STEL 15 ppm. 75 mg/m* Primary Routes of Exposure/Entry: Skin, Inhalation. GASC0170/October 1989 2 sac OOo Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, lungs or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. Naphthalene is a potential irritant to eyes, skin and lungs and may damage the blood, eyes and kidney after prolonged or repeated exposure. Carcinogenicity: This materia] is not known to contain any chemical listed as a carcinogen or suspected carcinogen by OSHA, IARC, or NTP at a concentration greater than 0.1%. VIII, EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: This material is combustible. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Piovincial, and Local regulations. GASC0170/October 1989 3 SAL 000006773 X. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH-approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VII. Proper respirator selection should be determined by adequately trained personnel and based on the contaminants), the degree of potential exposure and published respiratory protection factors. Ventilation: Normal ventilation. Protective Gloves: Should be worn when any potential exists for skin contact. NBR or neoprene recommended. Eye Protection: Chemical goggles or face shield required when exposed to oil sprays and mists. Other Protective Equipment: Coveralls if splashing is probable. Safety Precautions: Avoid contact with eyes, skin, or clothing. XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTIIORIZATION ACT OF 1986, TITLE III SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxic Chemicals (40 CFR 372) The material contains the following chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Toxic Chemical Naphthalene CAS Registry Number 91-20-3 Approx. Concentration (Upper Boundl 3.0% TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement r rn GASC0170/October 1989 4 SAL 000006774- CP U 24 RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignilable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste. Regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116, SECTION 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable FOREIGN REGULATIONS CANADIAN HAZARDOUS PRODUCTS ACT (WHM1S) The material is a WHM1S Controlled Product, and a Canadian MSDS is available. STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65") The material does not contain ingredient(s) subject to the Act. Ingredient None PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The material contains the following hazardous substances: Categories: H = Hazardous Substance (> 1.0%) S = Special Hazardous Substance (> 0.01%) E = Environmental Hazard (> 1.0%) Ingredient Aromatic and Paraffinic Hydrocarbons Naphthalene CAS Registry Number Mixture 91-20-3 Category H E Nonhazardous ingredient(s) information is withheld as trade secret in accordance with Section 11 of Pennsylvania Worker and Community Right to Know Act. MSDS Code: GASC0170 REVISION TO SECTION XI DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 10/89 - Replaces MSDS dated 6/89 Safety, Occupational Health & Environmental Affairs Hazard Communication Analyst Conoco Inc. (713) 293-5550 GASCOl/O/October 1989 5 SAL 000006775 U fu2 4 i <- The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MER CHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. GASC0170/October 1989 6 SAL 000006776 Material Safety I Data Sheet (conoco j Emergency Medical Telephone (800) 441 -3637 UNLEADED GASOLINE C P022 I. MATERIAL IDENTIFICATION Name Unleaded Gasoline CAS Registry Number Mixture; See Section XI Synonyms Automotive Unleaded Regular Gasoline, Gasoline, Unleaded Regular, Regular Unleaded Gasoline Product Code 1104/1410 Chemical Family Mixed Petroleum Hydrocarbons n. OSHA HAZARD DETERMINATION Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients Gasoline including Benzene Ethyl Benzene Cumene Pseudocumene MTBE Toluene Xylenes CAS Registry Number Mixture 71-43-2 100-41-4 98-82-8 95-63-6 1634-04-4 108-88-3 1330-20-7 Concentration 100% 0.1-4.9 wt % Approx. 2% Approx. 1% Approx. 2% < 15% Approx. 15% Approx. 12% Hazardous Physical Properties Class 1A Flammable liquid per NFPA Code No. 30-1987. PHYSICAL DATA Appearance and Odor Water white to straw yellow liquid; Gasoline odor Specific Gravity (H20 = l) 0.70 - 0.77 Boiling Point/Range 85 - 437*F % Volatiles (by volume) 100% Vapor Pressure (mmllg) @ 68*F 275 - 475 Solubility In Water May be slightly soluble Vapor Density (Air = 1.0) >1 GASC0140/January 1990 ooooo67_n 1 SAL Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 0 t* 0 33 IV. REACTIVITY DATA Stable: X Unstable:___ _ Hazardous Decomposition Materials: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Undue exposure to air, oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA T.ET-* <1 UEL: Flash Point (Method used): As low as -50F (TCQ Autoignition Temperature: 536* - 853F Handle and store In accordance with NFPA procedure for Class IA Flammable Liquid. Extinguishing Medio: Use dry chemical, CO* foam. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from areas of potential exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association fNFPA) Classification Health 1 Fire 3 Reactivity 0 VL TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Proper Shipping Name: Hazard Class: UN/NA Ntu DOT Label (s): DOT Placard: IATA/IMO: Proper Shipping Name: Hazard Class: UN Noj IMO/ICAO Label: Packaging Group: Gasoline Flammable Liquid UN 1203 Flammable Liquid Flammable Gasoline or Motor Spirit 3 (IMO 3.1) UN 1203 Flammable Liquid II vn. HEALTH HAZARD INFORMATION Exposure Limits for Unleaded Gasoline PEL: 300 ppm. 900 me/m1 (Gasolinel STEL 500 ppm. 1500 mg/m3 (Gasolinel TLV: TWA 300 ppm. 890 mg/m3 (Gasoline') STEL 500 ppm. 1480 mg/m3 (Gasoline) GASC0140/January 1990 2 SAL 000006778 Exposure Limits for Benzene PEL: 1 ppm - 8 Hr. TWA S pom - (Short-Term Exposure Limit) 0-5 ppm - Action Level TLV: 10ppm. 32 me/m1 DuPont AEL: 1 ppm 8 A 12 Hr. TWA 5 ppm - IS Min. TWA Exposure Limits for Ethyl Benzene PEL: 100 ppm. 435 mg/m3 STEL 125 ppm. S45 mg/m3 Du Pont AEL: None Established TLV: 100 ppm. 434 mg/m3 STEL 125 ppm. 543 mg/m3 Exposure Limits for Cumene PEL: SO ppm. 245 mgfln*. skin TLV: 50 ppm. 246 mg/m*, skin Du Pont AEL: None Established Exposure Limits for Pseudocumene PEL: 25 ppm. 125 mg/m3 TLV: 25 ppm. 123 me/m3 Du Pont AEL: None Established Exposure Limits for Toluene PEL: 100 ppm. 375 mg/m3 STEL ISO ppm. 560 me/m3 Du Pont AEL: 100 ppm - 8 & 12 Hr. TWA TLV: 100 ppm. 377 me/m3 STEL 150 ppm. 565 mg/m3 Exposure Limits for Xylenes PEL: 100 ppm. 435 mg/m3 TLV: 100 ppm. 434 mg/m3 STEL 150 ppm. 655 me/m3 STEL ISO ppm. 651 mg/m* / Du Pont AEL: 100 pom - 8 Hr. TWA ISO ppm - 15 Min. TWA Primary Routes of Exposure/Entry: Skin, Inhalation Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to the blood and blood-forming tissues. Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, skin and lungs after prolonged or repeated exposure. Overexposure may cause weakness, headache, nausea, confusion, bluned vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. GASC0140/January 1990 3 SAL 000006779 Vni. listed as Carcinogen or Potential Carcinogen by: NTP Benzene Yes Gasoline No 1ARC Category I Category 2B OSHA Yes No ACTHH Yes No EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least IS minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: This material is flammable. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposaL Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with dean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during dean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH-approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VIL Proper respirator selection should be determined by adequately trained personnel and based on the contaminants), the degree of potential exposure and published respiratory protection factors. Ventilation: Use sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits. Avoid sparking and explosive mixtures. Protective Gloves: Should be worn when the potential exists for prolonged or repeated skin exposure. NBR or neoprene recommended. Eye Protection: Goggles or face shield for spray/mists or if splashing is probable. Other Protective Equipment: Sufficient protective clothing to minimize skin exposure. Launder contaminated clothing before reuse. Safety Precautions: Avoid contact with eyes, skin, or clothing. GASC0140/January 1990 4 SAL 000006780 CPr 9 XL REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTIIORIZATION ACT OF 1986, TITLE III SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 31L/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE; See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - Ust of Toxic Chemicals (40 CFR 372) The material contains the following chemical(s) at a level of 1,0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Approx. Concentration Toxic Chemical CAS Registry Number (TJoner Bound) c Benzene 71-43-2 4.9% Ethyl Benzene 100-41-4 2% Cumene 98-82-8 1% Pseudocumcne 95-63-6 2% MTBE 1634-04-4 15% Toluene 108-88-3 15% Xylenes 1330-20-7 12% TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA. The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA. In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, Regulations 40 CFR 262, 263, 264 and 268 may apply. GASC0140/January 1990 5 SAL 000006781 CP022 FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, SECTION 311 The material contains the following ingredients) which is considered hazardous Ifspilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable FOREIGN REGULATION CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material is a WHMIS Controlled Product and a Canadian MSDS Is available. STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1984 (PROPOSITION 45*) The material contains ingredients) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient Benzene Unleaded Gasoline (Wholly Vaporized) PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The material contains the following hazardous substances: Categories: H = Hazardous Substance (> 1.0%) S = Special Hazardous Substance 0.01%) E = Environmental Hazard (t 1.0%) Ingredient Gasoline Benzene Ethyl Benzene Cumene Pseudocumene MTBE CAS Registry Number Mixture 71-43-2 100-41-4 98-82-8 95-63-6 1634-04-4 Category H E E H,E E E Nonhazardous ingredients) information is withheld as trade secret in accordance with Section 11 of Pennsylvania Worker and Community Right to Know Act MSDS Code: GASC0140 DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 1/90 - Replaces MSDS dated 3/89 Safety, Occupational Health & Environmental Affairs Hazard Communication Analyst Conoco Inc. (713) 293-5550 The bove data are hated oa text*, aperience, tad other information which Conoco believes reliable and are applied tor informational purposes only. However, some ingredients may have been purchased or obtained bom third-party manufacturers. In Ibeae instance*, Conooo, in good faith relies on information provided by those third parties. Since eoidibona of me are outride our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (jNCLUDINO FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE. EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. GASC0140/January 1990 6 SAL 000006782 (conoco) Material Safety I Data Sheet Emergency Medical Telephone (800) 441-3637 conoco COKER GAS OIL - HEAVY PREMIUM/INTERMEDIATE/LOW SULFUR RESID I. MATERIAL IDENTIFICATION Name CAS Registry Number Coker Gas Oil - Heavy Premium/ 64741-81-7 Intermediate/Low Sulfur Resid Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) Chemical Family Thermally Cracked Petroleum Hydrocarbon Product Code 0542^)543/0544 n. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for other federal and state regulatory information. Hazardous Ingredients Polynuclear Aromatic Hydrocarbons, L benzo(a)pyrene CAS Registry Number Mixture Concentration 5 - 50% Hazardous Physical Properties None HI. PHYSICAL DATA Appearance and Odor Brownish-green liquid; Cracked hydrocarbon odor Specific Gravity 1.1 Boiling Point 500" - 1000F % Volatiles (by volume) 0 Vapor Pressure m Solubility In Water Insoluble Vapor Density >1 IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Materials: Normal combustion forms carbon dioxide; incomplete combustion may form carbon monoxide. Conditions to Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. GASC0156/January 1990 SAL 000006783 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 CP 0 17 V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): > 200F (TCP Handle and store in accordance with NFPA procedure for Class HfB Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cooL Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA> Classification Health 0 Fire 1 Reactivity 0 VL TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Not Regulated IATA/IMO: Not Restricted Vn. HEALTH HAZARD INFORMATION Exposure Limits for Material PEL: None Established* TLV: None Established* Da Pont AEL None Established Celling Value: None Established Refer to Coal Tar Pitch Volatiles; 0.2 mg/m3 Primaiy Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Mouse skin painting studies have shown that nonsolvent-refined petroleum distillates having a distillation end-point above 700"F, and which are similar to ingredients in this product, caused skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material; the resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. Also, limited studies of carcinogenic oils have shown that washing the animals' skin with soap and water between applications greatly reduces tumor formation. These studies demonstrate the effectiveness of cleansing the skin after contact The product may contain polynuclear aromatic hydrocarbons (PNAs) which have caused cancer involving skin and internal organs in laboratory animals. The product may product a phototoxic reaction when contaminated skin is exposed to sunlight The effect is similar in appearance to an exaggerated sunburn and is temporary in duration. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, lungs or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. Listed as Carcinogen or Potential Carcinogen by: Polynuclear Aromatic Hydrocarbons, J.e., benzo(a)pyrene NTP Yes IARC OSHA Category 2B No GASC0156/January 1990 2 SAL 000006784 viil EMERGENCY AND FIRST AID INFORMATION Eyes: Io case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalations If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: All sparks, flames and ignition sources must be restricted from the area. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH-approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VIL Proper respirator selection should be determined by adequately trained personnel and based on the contaminants), the degree of potential exposure and published respiratory protection factors. Ventilation: Normal ventilation. Protective Gloves: Should be worn when any potential exists for skin contact Use insulated gloves where material is being handled hot NBR or neoprene recommended. Eye Protection: Chemical goggles required when exposed to sprays and mists or If splashing is probable. Face shield is recommended where splashing can occur. Other Precautions: Skin contact should be minimized. Complete protective clothing if material is being handled hot Launder or discard contaminated clothing. Discard extremely contaminated leather materiaL GASC0156/January 1990 3 SAL 000006785 XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCiA, 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 198*, TITLE in SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material docs not contain extremely hazardous substances at greater than 1.0% concentration; however. It is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: __ Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard __ Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - list or Toxic Chemicals (40 CFR 372) The material is not known to contain chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is in the TSCA Inventory of Chemical Substances and/or is otherwise in compliance with TSCA. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitabie or reactive according to the U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, SECTION 311 The material contains the following ingredients) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline GASC0156/7anuary 1990 4 SAL 000006786 OP 0 I 7 HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (-PROPOSITION 65") The material contains ingredient(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient Polynuclear Aromatic Hydrocarbons, i.e., Benzo(a)pyrene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced In Pennsylvania. Please notify us at the telephone number noted below if the material results in Pennsylvania commerce. MSDS Code: GASC0156 SECTIONS OF MSDS REVISED: DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: II, VII 1/90 - Replaces MSDS dated 3/89 Environmental and Occupational Health Services MSDS Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. r'\ V GASC0156/Jan.uary 1990 5 S4L 000006787 m Material Safety Data Sheet ; Emergency Medical Telephone (800) 441 -3637 NO. 6 FUEL OIL/HEAVY RAILROAD FUEL/ BUNKER "C FUEL/FUEL OIL BLEND STOCK CP 0 13 I. MATERIAL IDENTIFICATION Name No. 6 Fuel Oil/Heavy Railroad Fuel/ Bunker *C Fuel/Fuel Oil Blend Slock CAS Registry Number Mixture; See Section XI Synonyms Residual Fuel/Resid Low Sulfur Fuel Oil Product Code 0525/0563A)572A)576/U577/058lyD583/0593 Chemical Family Petroleum Hydrocarbon Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) II. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients Clarified Oil Hydrogen Sulfide CAS Registry Number 64741-62-4 7783-06-4 Concentration 5 - 50% < 1%* Hydrogen sulfide is not normally present in the material, but if the material is heated to high temperatures, hydrogen sulfide may exist in headspace of storage vessel. Hazardous Physical Properties Class II Combustible liquid - NFPA 30-1987. III. PHYSICAL DATA Appearance and Odor Brown to black liquid; Petroleum odor Specific Gravity (H,0 = 1) 0.9 - 1.1 Boiling Point/Range >350F % Volatiles (by volume) Nil Vapor Pressure Nil Solubility in Water Insoluble Vapor Density (Air = 1.0) >1 IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Materials: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Ignition sources, high temperatures. Hazardous Polymerization: Will not occur. GASC0240/November 1989 Ic SAI- 000006788 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 ct o 1 V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 130*F fTCQ Handle and store In accordance with NFPA procedure for Class n Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cooL If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) Classification Health 0 Fire 2 Reactivity 0 HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 VI. TRANSPORTATION AND STORAGE Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Proper Shipping Name: Hazard Class: UN/NA No.: DOT Labe!(s): DOT Placard: IATA/IMO: Proper Shipping Name: Hazard Class: UN No,: IMO/ICAO Label: Packaging Group: Fuel Oil or Fuel Oil No. 6 Combustible Liquid NA 1993 None Combustible Gas Oil 3 UN 1202 Flammable Liquid III vn. HEALTH HAZARD INFORMATION Exposure Limits for No. 6 Fuel Oil/Heavy Railroad Fuel/Bunker aC" Fuel PEL: None Established* TLV: None Established* Refer to Coal Tar Pitch Volatiles; 0.2 mg/m3 Du Pont AEU Celling Value: None Established None Established // / Exposure Limits for Hydrogen Sulfide PEL: 10 ppm. 14 mg/m3 STEL 15 ppm. 21 mg/m3 Du Pont AEU 10 ppm - 8 & 12 Hr. TWA TLV: 10 ppm. 14 mg/m3 STEL 15 ppm. 21 mg/m3 Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Mouse skin painting studies have shown that petroleum distillates having a distillation end-point above 700*F, and which are similar to ingredients in this product, caused skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material; the resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. Also, limited studies of carcinogenic oils have shown that washing the animals' skin GASC0240/November 1989 2 SAL 000006789 with soap and water between applications greatly reduces tumor formation. These studies demonstrate the effectiveness of deansing the skin after contact The product may contain polynuclear aromatic hydrocarbons (PNAs) which have caused cancer involving skin and internal organs in laboratory animals. The product may product a phototoxic reaction when contaminated skin is exposed to sunlight The effect is similar in appearance to an exaggerated sunburn and is temporary in duration. Rat skin painting 90-day studies have shown a clarified sluny oil to cause liver damage and death at doses as 8 beas low mg/kg/day. Carbazole derivatives are thought to the chemical component causing the liver damage. Hydrogen sulfide is not normally present in the product but can be generated and accumulate in the container headspace if the asphalt is heated at high temperatures for an extended period of time. Hydrogen sulfide can be irritating at low concentrations to the eyes, skin, and respiratory trad. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, lungs or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. Listed as Carcinogen or Potential Carcinogen by: Heavy Fuel Oil NTP No IARC OSHA Category 2B No VIII. EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: This material is combustible. Contain spill immediately in smallest possible area. Recover as much product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. GASC0240/November 1989 3 SAL 0006790 6 X. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH-approved respiratory protective equipment when exposed to sprays or mists. Proper respirator selection should be determined by adequately trained personnel and based on the contaminant(s), the degree of potential exposure, and published respiratory protection factors. In situations where the material is exposed to high temperatures for extended periods of time, hydrogen sulfide may build up in unventilated storage vessel headspace. NIOSH-approved full face air-supplied respirator or self-contained breathing equipment should be used when first opening these storage vessels. Ventilation: Normal ventilation. Protective Gloves: Should be worn when any potential exists for skin contact. Use insulated gloves where material is being handled hot. NBR or neoprene recommended. Eye Protection: Chemical goggles required when exposed to sprays or mists or if splashing is probable. Face shield is recommended where splashing can occur. Other Precautions: Skin contact should be minimized. Complete protective clothing if materia! is being handled hot Launder or discard contaminated clothing. Discard extremely contaminated leather material. XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE III SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA SECTION 313 - List of Toxic Chemicals (40 CFR 372) The material does not contain cbemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement GASC0240/Noveraber 1989 4 SAL 000006791 Z6L90Q000 1VS #r-.r - , 686l^-l^K/0raDSVa - > ^ !,vf>-^ i ;.- ; 1 . ,,. .... ,. . . ,,.. ^ .., . , ..'f'-t'.`..^'O-J-'^, '.$.+%; .*< - V 'OOONOQ OX MMOMM SI HSOdHHd AVKL HI K3AH *aSO<SHnd OUID34S AMV HGH a$fl SII HO `crasnosaa avraaivw ant viva hrl ox ioadsan hxim odonod as Oumsvn iN3ivi WOHd WOCTHHHd ONIOfYIDNl) NOLLVAN3S3Hd3H HO (AXTIiaVXNVHDHHW HO AJLNVHHVM ONiamOMl) AANVHHVM *aaLNVHVnO V HXfLULSNOO TTVHS NI3H3H OHNIV1NOD OKIHXOM -viva HAOHV HHL HO HSO HHX ViOHd &nnS3H HDIHM AHOfNI HO HOVWVa HOJ AXTHHVn AMV SWIVTDSia OOONOD Iojjboo mo apisjno areosnjo saoriipoco 9001$ -*3fjred pjiqi asoqi in popiAOid oopemjcgu] no ssnai qinj poof g] *030003 *otreisuf osaqj nj `sjarajagnireui Xjmd-pjjqj mag paunnqo jo posutpxnd uaaq a\eq fan siagipsjfoi otaos `jsaomoh *^pio sasodind icnonctoippii joj paflddns ant poo oiqeitaj SMORoq 030003 qonjA aojmnjojui joqio pa* **roauddjQ *sjsai ao paseq am mep aAoqe sqj. nourapintmiiaQ pmnH tjoviKOD NOixvraodNi xanaoHd ti^gy iBiaourocuiuia'y igfesH iroopwlteoo isasK hoh snaisNOdsan JMawiHVdaa - 68fc PWp SaSFt * 69fll v'S ~..^- -MHIAHH/NOISIAHH XS31V1 HO ElVa g^tr:-:'>c;aasiA3HX,nAJi sNOUDas /''' . *. '*?'v'- -f **---?**v ~ - Vi -rf.i'v- .1h.;>'- : '---- {f'Spoo $asw - -c-' *aaunnoo cnreApCsuudj m sgassi jBjjaistn pqj jj Mopq paioa jsqtnnu auoqdapi aqi is 030003 Xfpoa a$B9[4 'BpreAjXsuaaj 1g pooopaid 10 pfoc ton s{ jcfiomn aqj afpoiMoici mo |o isaq sqi ox . . . XOV AiONH OX XHDIH AXimWWOD aNV H3XaOA4 VlNYATASNN3d s " oooiXdC^ozimg *^07 *SQoqie30ip^H mapnaX[ox )U3IpdiiuT ' - .%. . _ - ,L": . * ii. -.", . | V '-it ^'. 1 !^7 '. ."5- J.-v* 1'r`j ' '>" v. ' 'UDHpoiid anb|bi^d u* figsa jo faixpaeq aaq^ am osa pv $ao|maJ|p t^l^t moucj ptre pead aApanpoidoi iqio jo ipqjap qujg *J*Mno asno 01 |UJo/nB3 jo am$ oqi ot DMom| (s)ia3ipoi3m stgmaco iFyajFai aqx ; -;; CS9 NOIXISOdOHdJ 9S61 AO XDV Ji@W3DHdN3 31X01 QNV H3XVM ONIXNIHa SLJYS VINHOdTIVD ;.. '.;>v'v ^-:*; '*:a- Jik.Trt^S. a 8Mourm93H axvxs ^ajqwn^lOH . . 84T`U1 ZAO f *SN0U.YTa03H NOIXVXHOdSNYHA SIYIHSIYW SAOOHVZVH 9nn9"Joqs mfa_n_mJn~ofpt jo ao^mt jgt* oqj ^ . -.Vr^'V^i . - -^ ' ^ ' - '- jo uopeiotottfp jo aodft oooqt jo tom QoqjKxup^] rnnaionox ojqmoday taafporiui ` ' ~ ' ' ''' .' *1 -i_ 'y:KttaiHML oppSpia u} p^Qds n tnopiBno pwapjrooo t cinjtt (ihimpojfm fuiMono; oqi nsjvjnoo mioira IL > ' -' - ^ J^llbSS *VT9inU3 OP`IDV H31VA1NV7X3 *i3V/10HXN03 NOUaTIOd H31VA1 IVHaaai rliddiB fan 89Z pu wz *9C HdO OP mopBjnfoH lopqa jo ptmoo pMf *9)tA snopjvnti pawn t miioo V| lamoo : HRHALDOR TOPSOE, INC. ' V ft! MATERIAL SAFETY DATA SHEET 1. GENERAL INFORMATION W * ; revised; , - . May 1989 EMERGENCY HAZARD RATING 4 - crrncMc ttm A * * NOOCHATt i-stwT 0 INSIGNIFICANT HEALTH REACTIVITY yy \/ SICC* HAIARO CAO 20 Page 1 of 2 Trade name and synonym: TK-10 (R7H) Inert Topping Material Chemical family: Spinel Major chemical constituents (CAS No.): Mg (1302-07-6) All components of the catalyst appear on the TSCA Inventory. Manufacturer's or Importer's name a address: HAL00R TOPSOE, INC. Telephone No.: N 17629 El Camlno Real Houston, TX 77058 Emergency Telephone No.: (713) 4S0-2600 (713) 474-3261 ( 2. HAZARDOUS INGREDIENTS %concentration wt tlv/twa3 ____ BflZm -- Hg (A102)2 100 10 (nuisance dust) As adopted by ACGIH Aluminum oxide, molybdenum trioxide, and all compounds containing chromium, cobalt, nickel, copper or zinc are subject to Chemical Release Reporting requirements of SARA Section 313, as codified In 40 CFR Part 372. 3. PHYSICAL DATA Appearance & odor: White 7 holed tablet shape, odorless Bulk density: 51 Ibs/cuft Vapor pressure: Not relevant Melting point: >2000 F Solubility In water: Negligible 4. FIRE & EXPLOSION, HAZARD DATA Flash Point: Not relevant Flammable Limits: Notrelevant Extinguishing Media: Not relevant Special Fire Fighting Procedures: Not relevant, Noncombustible Unusual Fire a Explosion Hazard: None SAL 000006793 cs8W i- .Dm aoaoor ROC?OAK TK-10 *1' X Pa9 2 of 2 HEALT J2AIA LEffects of overexposure: Spinel Is not considered health hazard. Exposure to large concentrations of dust nay Irritate the eyee and the-respiratory tract. Emergency a First Aid Procedures: Remove from exposed area. Listed jt*j^a canclnogen: Yes_____ No JS by OSHA _____ IARC _____ NTP e. REACTIVITY DATA Stability: Stable J(_ Incompatibility (Materials to avoid): N/A Hazardous decomposition products: N/A Hazardous polarization: may occur___ Unstable ___ will not occur JJ 7. SPILL AND WASTE DISPOSAL PROCEDURES Steps to be taken If material is spilled: Collect all spilled material by mechanical means and place in a container. Avoid dust generation/ Label container. Waste Disposal Method: In accordance with Federal, state, & local regulations. 8. PERSONAL PROTECTION INFORMATION Respiratory protection: Dust mask recommended. Eye protection: Normally not required. Ventilation of work place: Outside: Natural Inside reactor: Mechanical Hand protection: Gloves Other protection: Safety shoes recommended when handling drums. 9. SPECIAL PRECAUTIONS During storage: Keep containers dry and tightly closed. When handling containers:' Adhere to standard safety procedures. Use mechanical assistance to avoid strain. During loading: Adhere to standard safety procedures. Minimize free fall ^f material to avoid breakage. During unloading: Adhere to standard safety procedures. Spent catalyst may be pyrophoric In the presence of air. ^ SAL 000006794 The Information and recommendation* aet forth herein are believed to be correct end presented In good faith a* of the date hereof. Haldor Topaoe, Inc. however, makee no representation or warranty as to the completeness (hereof and disclaim* any liability for damage* resulting from reliance thereon. MATERIAL SAFETY DATA SHEET <0701OO-O340P -E0016293-4216 SECTION I CHEMICAL NAME & SYNONYMS N/A TRADE NAME A SYNONYMS CONQUEST CHEMICAL FAMILY TANN1C-LATEX MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEA8CH DIV. OF NCH CORP. FORMULA X<--M1XTURE ADDRESS (NUMBER. STREET, CITY, STATE A ZIP CODE) BOX S2 170 IRVING. TEXAS ?SOiS PREPARED BY: RICHARC STCLLEY/T.S CHEM. ! PROOUCT CODE NUMBER ! EMERGENCY TELEPHONE NUMBER 4216 214-430-1301 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE CHEMICAL NAME (INGREDIENTS) TANNIC ACID OXALIC ACIC ! HAZARD IRRITANT TOX/IRR. l TLV* NOT EST. 1MG/M3 | PELNOT EST. 1MG/M3 j cas* 1401-S5-4 144-62-7 SECTION 2IA - NON -HAZARDOUS INGREDIENTS NSECCNR-HEATZARRECGOIUSTSRYINGaRED4IE0N9T363N-ASM0E2S7PANC CAS NUMBERS ARE PROTECTED UNDER NU TRADE "M ( CONQUEST SECTION III - PHYSICAL DATA RAGE : 02 BOILING PT (FAHRENHEIT) VAPOR PRESSURE (MM HG) VACS DENSITY (A IR 1 ) H 100`. PERCENT. VOLATILE BY VOLUME <%) SOLUBILITY IN WATER VISCOSIT i 2 IS I 16 | SeEC GRAVITY <H201) ; COLOR |T AN ;0.6 ! ODOR {LATEX ! 1-2 ! CLARITY lOPAOUE |*2 ! ! EVAPORATION RATE !0.10 | _ (BU_AC - 1 > ! | COMPLETE ! SLIGHT-VJSCCUS 11 BO SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOO USED ) non-flam { FLAMMABLE LIMITS 1 LEL n/a ! UCL |n/a EXTINGUISHING MEDIA "ALCOHOL* X <-F OAM < - -FOAM X4--C02 DRY X<-- CHE MICAL WATER <--SPRAY < - -OTHER SPECIAL FIRE FIGHTING PROCEDURES ALTHOUGH PRODUCT IS NON-FLAMMABLE, TREAT AS ANY CHEMICAL FIRE. WEAR A SELFCONTAINED BREATHING AND FULL PROTECTIVE GEAR TO AV01C EXPOSURE TO "OSSJBLE HAZARDOUS COMBUSTION PRODUCTS. UNUSUAL FIRE & EXPLOSION HAZAROS SPRAY EXPCSEC CONTAINERS WITH WATER SPRAY TC AVOID STEAM PRODUCTION. N F P A HAZARD HATING (O-I NS IGNIFI CANT, 1 -SLIGHT:2-MODERATE 3-HIGH4-EXTREME> l <--HEALTH 0 <--FLAMMABILITY 0 < - - R E A C T I V I T Y :--SPEClAL SECTION V - HEALTH HAZARC CATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOB MIXTURE. SEE SECTION II EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE > INHALATION - MIST SITUATION MAY CAUSE IRRITATION TO RESPIRATORY TRACT 000006795 SAL PC084 (CONTINUED) CONQUEST SECTION V HEALTH HAZARD DATA CASE : 03 HAY CAUSE COUGHING ANO SNEEZING SKIN CONTACT- MAY CAUSE MILD IRRITATION. CONTACT WITH OPEN WOUNDS CAN PROMOTE ABSCR8TI0N ANO SYSTEMIC EFFECTS. IN AUTOPSIED BURNED VICTIMS. OBSERVED LIVER DAMAGE WAS ATTRIBUTED TO ABSORBTION OF TANNIC ACID THROUGH BURNED SKIN EYE CONTACT- MAY CAUSE REDDENING ANO TEARING WITH POSSIBLE PAIN ANO BLURRED VISION. INGESTION- TOXIC MAY CAUSE GASTROINTESTINAL DISORDERS INCLUDING NAUSEA AND VOMITING. MA5S1VE INGESTION CAN CAUSE SHOCK ANO COLLAPSE. - CHRONIC - (LONG TERM EXPOSURE! MARKED IRRITATION TC SKIN ANO EYES. PATHOLOGICAL FINDINGS IN EXPERIMENTAL ANIMALS SHOW EVIDENCE OF GASTRITIS AND LIVER DAMAGE. PERSONS WITH PRE-EXISTING SKIN OR EYE CISOROERS, OR IMPAIRED KIDNEY.LIVER. AND RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE SEE SECTION VI FOR MORE INFORMATION PRIMARY ROUTE OF ENTRY INHALATION <-- INGESTION X<-- ABSORPTION EMERGENCY & FIRST AID PROCEDURES INHALATION : GET TO FRESH AIR AND TREAT SYMPTOMATICALLY. IF BREATHING IS LABORED. GIVE OXYGEN OR ARTIFICIAL RESPIRATION. SEE A PHYSICIAN IN SYMPTOMS OCCUR. EVE CONTACTFLUSH WITH LARGE AMOUNTS OF WATER FOR 10 MINUTES LIFTING UPPER ANO LOWER 110S OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY. TREATMENT IS MOST EFFECTIVE WITHIN ONE MINUTE SKIN CONTACT THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. APPLY EMOLLIENT RICH CREAM. INGESTION : GIVE TWO GLASSES OF WATER TO DILUTE CONTENTS OF STOMACH. DO NOT INDUCE VOMITING . SEE A PHYSICIAN AT ONCE. NOTES TO PHYSICIAN : ADDITION OF BASIC NEUTRALIZER IS NOT RECOMMENDED OUE TO ALKALI SALTS OF OXALIC ACID ARE JUST AS TOXIC AS ACICIC FORM. SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTEC AS CARCINOGEN CR POTENTIAL CARCINOGEN BY, I ARC <- -Y E S NTP <-- YES CSHA <--YES ACGIH C--VES OTHER <--VES X<--NC X <--NO X--NC X<--NC X<--NC TANNIC ACID ORL-RAT LDLC : 200MG/KG 1. ORL-RBT LD50: 5000MG/KG 1 ORL-RAT LDEO: 2300MG/KG 0RL-R6T LDSO. 5000WG/KG 2. 2. (CONTINUED) CONQUEST SECTION VI - TOXICITY INFORMATION PAGE . 04 SCU-RAT TDLO: 4450MG/KG/1? W-l I. TUMEROGENIC DATA CITED 2. OXALIC ACID ORL-HMN LDLC; 71 MG/KG 1. ORL-RAT LDSO. 37SMG/KG 1. 5KN-RBT 500MG/24H MOO. 1 TANNIC ACID PRODUCED LIVER TUMORS IN RATS FOLLOWING SUBCUTANEOUS INJECT IONS of hydrolyzable tannins prcoucec liver tumors nc adeouate published STUDIES INVOLVING ORAL STUDIES OR CASE REPORTS ON Ep!OEWIQlOGICAL STUDIES WERE AVAILABLE. 1ARC tO.2S3.7E. IARC DID NCT INCLUDE TANNIC ACID IN THE LISTING OF SUe ST ANCE S(MONOGRAPHS 1-29)'F0R WHICH IT IS CURRENTLY CONSIDERED THAT THERE WAS SUFFICIENT EVIDENCE OF CARCINOGENICITY IN EXPERIMENTAL ANI MALS . `(SUPPLEMENT 4. 1982. APPENOIX 2) SEE SECTION XII. SECTION VII - REACTIVITY DATA STABILITY !x<--STABLE <--UNSTABL ! C0NDIDT10NS TC AVOID J.......... .................................. .......................................................................................... KEEP CONTAINER TIGHTLY CLOSED. INCOMPATIBILITY (MATERIALS TC AVOIO) STRONG OXIDIZERS(BLEACH).SILVER AND ALKALIS. HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE. ACRID SMOKE AND FUMES. HAZARDOUS ! WILL NOT MAY ! CONDITIONS TC AVOID j X <- - OCCUR <--OCCUR ! polymerization! ;n/a SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASEE CR SaIL L EC CONTAIN LEAK AND PICK UB SPILL AND BL AC E IN A LABELEC CONTAINER. CLEAN UP RESIDUE WITH DETERGENT AND WATER. WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH FEDERAL. STATE, AND LOCAL REGULATIONS. NEUTRALIZING AGENT ADD CAUTIOUSLY A SOLUTION OF SLAKED LIME OR SODA ASH WHILE STIRRING UNTIL PH IS AT 7. SAL 000006796 r CONQUEST______________ __________ __ SECTION IX - SPECIAL PROTECTION INFORMATIOPAGE : OS REQUIRED VENTILATION GENERAL EXHAUST IS MORE THAN ADEQUATE TO PROTECT WORKER FROM EXPOSURE TO LEVEL ABOVE PERMISSIBLE EXPOSURE LIMITS. RESPIRATORY PROTECTION A RESPIRATOR IS NOT REOUIRED IN THE NORMAL USE OF THE PRODUCT APPROVED MASK FOR SPRAY MISTS. USE A NiOSH PROTECTIVE GLOVES RUBBER GLOVES IF REPEATED OR PROLONGED SKIN CONTACT OCCURS. EYE PROTECTION CHEMICAL GOGGLES IF METHCO OF APPLICATION OF PRE SENT s THE LIKELIHOOD OF EYE CONTACT. OTHER PROTECTION APRON SHOULD BE WORN DEPENDING ON SEVERITY OF EXPOSURE SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE ! INDOOR 120 F . < --MAX 3* F <--MIN ! X 1HEATED ! PRECAUTIONS TO BE TAKEN IN HANDLING & STORING KEEP ORUM TIGHTLY CLOSED DTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE USING PRODUCT. I REFRIGERATED! OUTDOOR \ SECTION XI REGULATORY INFORMATION CHEMICAL NAME C.A.S NUMBER UPR % LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITlE III OF THE SUPERFUNC AMENDMENTS AND R6AUTHOR12ATI ON ACT OF 1986 AND 40 CFR PART 3"2 IF UE (USE EXEMPTION' APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND uABElEC FOR ROUTINE JANITORIAL WCRK. OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES!. OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES PCO 34 CONQUEST_________________________ \ SECTION XII * TRANSPORTATION (FOR FUTURE USE) PAGE : 06 APPLICABLE REGULATION'S <--49 CFR < - - 1MCC SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DOT SPS CONTAINER AEROSOL PROPELLANT< 5 ) <--TARIFF C <--ILTA `--MILITARY AIR (AFR 71-41 I ID NUMBER \ REORT QTY ! LIMITED CTY J NET EXPLOSIVE WT. SECTION XIII - REFERENCES 1 DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION. N IRVING SAX. 2 THRESHOLD LIMIT VALUES AND BlLOGICAL EXPOSURE INDICES. 1986-1987 3. VENDOR'S MSOS CONTINUED FROM SECTION VI GALLIC ACID. THE MAJOR HYDROLYTIC PRODUCT CF TANNIC ACIC. DID NOT INDUCE TUMORS WHEN GIVEN SUBCUTANEOUSLY. SUGGESTING INTACT TANNIC ACID IS NEC ESSARY FOR ANY TUMOR-INDUCING EFFECT DATA INDICATING THAT TANNIC ACIC IS NOT A6 SC RBED AFTER ORAL ADMINISTRATION. BUT IS FIRST HYDR0LY2ED TC GALLIC ACIC THIS MAV EXPLAIN THE NEGATIVE CARCI NOGENCITY FINDINGS FOL LOWING ORAL OR DERMAL EXPOSURE THE INFORMATION CONTAINED HEREIN IS 8ASED ON DATA CONSIDERED ACCURATE IN LIGHT CF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCM DIV OF NCH CCRP ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CauSEC BY THE USE , STORAGE OR DISPOSAL CF THE PRODUCT IN A MANNER NC T RECOMMENOEC ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENOED USE. STORAGE. CR OISPOSAL CF THE PRODUCT SAL 000006797 MATERIAL SAFETY DATA SHEET M/M QUICK CURE 8606 PAGE : 01 <078101-OS49P -E0016293-5974 )|DATE OF ISSUE l 11/11/87 | SUPERSEDES | 1 1/12/86 } J SECTION I - GENERAL INFORMATION CHEMICAL NAME & SYNONYMS N/A TRADE NAME & SYNONYMS M/M OUXCK CURE CHEMICAL FAMILY EPOXY STICK FORMULA X <--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH D1V. OF NCH CORP. ADDRESS (NUMBER. STREET, CITY. STATE * ZIP CODE) BOX 152170 IRVING, TEXAS 79015 PREPARED BY: MARK COHEN/T.S.CHEMIST j PRODUCT CODE NUMBER ! EMERGENCY TELEPHONE NUMBER 5974 214-438-1381 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) j HAZARD _ | TLV* j PEL* BASeT'dIGLYCIOIAL ETHER OF BIS IRRITANT 5 MG/M3 2. N/A PHENOL A 2.4,6 TRI(OIMETHYLAMINO METHYL PHENOL) * IRRITANT SPPK 3. NOT EST. | CAS# 25085-99-B 90-72-2 SECTION IXA - NON-HAZARDOUS INGREDIENTS NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NO TRADE (CONTINUED) SECRET REGISTRY M/M QUICK CURE SECTION IIA - NON-HAZARDOUS INGREDIENTS 409363-5043P SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) VAPOR PRESSURE (MM HG). VAPOR DENSITY (AIR-1) PH 100% PERCENT. VOLATILE BY VOLUME (%) SOLUBILITY IN WATER VISCOSITY 'B : >250 F! [N/A [ !>i j |n/a ! jML * I N/A j 1 ! N/A SPEC GRAVITY (H20- 1 ) :>1 COLOR A : LT GRAY B : DRK GRAY ODOR MERCAPTAN LIKE CLARITY PUTTY EVAPORATION RATE (BU AC - 1 ) jN/A 1 PAGE : 02 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) A:>250 FCL05ED CUP | FLAMMABLE LIMITS EXTINGUISHING MEDIA 'ALCOHOL' X<-- FOAM X<--FOAM X<--C02 DRY X<--CHEMICAL 1, !n/A WATER <--SPRAY ! UEL |N/A <--OTHER SPECIAL FIRE FIGHTING PROCEDURES WEAR NIOSH/MSHA APPROVED RESPIRATOR WHEN FIGHTING FIRES IN CONFINED AREAS TO PROTECT FRAOM ACRID SMOKE. FUMES AND HAZARDOUS DECOMPOSITION PRODUCTS. UNUSUAL FIRE & EXPLOSION HAZARDS NONE KNOWN NF PA HAZARD RATING (0*INSJGNIFI CANT; 1 *SLIGHT:2-MODERATE;3*HIGH:4-EXTREME): 2 < - -HEALTH 1 < --FLAM.MAB IL ITY O < - - REACT IVIT Y <--SPECJAL SECTION V - HEALTH HAZAHO DATA SAL 000006798 C*o .>1 r G S6 06 <CONTINUED) M/M QUICK CUBE SECTION V - HEALTH HAZARD DATA PACE : 03 THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXUTRE SEE SECTION II EFFECTS OF OVEREXPOSURE - ACUTE - {SHORT TERM EXPOSURE) PROLONGED OR REPEATED EXPOSURE MAV CAUSE SKIN SENSITIZATION. IN SENSITIVE INDIVIDUALS CONTACT MAY CAUSE SKIN IRRITATION. THIS PRODUCT IS BOTH MECHANICALLY IRRITATING AND CHEMICALLY IRRITATING TO THE EYES. INHALATION IS NOT A HA2AR0 IN NORMAL USE HOWEVER THIS PRODUCT GIVES OFF TOXIC FUMES WHEN BURNED OR WELDED. INGESTION MAY LEAD TO GASTRIC IRRITATION WITH NAUSEA ANO VOMITING. - CHRONIC - (LONG TERM EXPOSURE) NO EFFECTS OTHER THAN THOSE NOTED UPON ACUTE EXPOSURE. PRIMARY ROUTE OF ENTRY: INHALATION <-- INGESTION <-- ABSORPTION EMERGENCY & FIRST AID PROCEDURES INHALATION : GENERALLY NOT A HAZARD. MOVE TO FRESH AIR AND TREAT SYMPTOMATICALLY. GIVE OXYGEN IF BREATHING IS DIFFICULT AND ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. GET MEDICAL ATTENTION. EYE CONTACT: FLUSH WITH LARGE AOUNTS OF WATER FOR tO MINUTES. LIFTING UPPER AND LOWER LI OS OCCASONALLY. GET MEDICAL IRRITATION IF IRRITATION PERSISTS. TREATMENT IS MOST EFFECTIVE WITHIN ONE MINUTE. SKIN CONTACT: WASH WITH SOAP AND WATER. SENSITIVE INOIVIOUALSSHOULDAPPLY AN EMOLLIENT RICH CREAM AND SHOULO SEE A PHYSICIAN IF IRRITATION PERSISTS. INGESTION : DO NOT INDUCE VOMITING. GIVE ONE OR TWO GLASSES OF WATER ANO CALL PHYSICIAN ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. NOTES TO PHYSICIAN : GASTRIC LAVAGE IN INDICATED. DO NOT INDUCE VOMITING. SECTION VI * TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: IARC <- - YES NTP <--YES OSHA C--YES ACGIH <--YES OTHER <--YES X<--NO X<--NO X<-"NO X<--NO X<--NO 2.4.6 TRI (DIMETHYLAMINO METHYL ORL-RAT LD50: 2.S G/KG 1. SKN-RBT LD50: 1.2G/KG t. DIGLYCDXAL ETHER OF BISPHENOL A SKN-RBT 500 MG OPEN MILO 1. PHENOL) SKN-RAT SKN-RBT EVE-RBT LD50: 1280 MG/ KG SOOMG/24H SEVERE 500MG/24H/SEVERE 1. 1. 1. (CONTINUED) M/M QUICK CURE SECTION VI - TOXICITY INFORMATION EYE-RBT 2 MG/24 H SEVERE 1 , ORL-RAT L050: 11 G/KG 1. SECTION VII - REACTIVITY OATA PAGE : 04 j X<--STA8LE <--UNST ABL i CONOIDT IONS TO AVOID OPEN FLAMES. LONG-TERM EXPOSURE TO HIGH TEMPERATURE5. INCOMPATIBILITY (MATERIALS TO AVO 10 ) STRONG OXIDIZING AGENTS OR STRONG BASES OR MINERAL ACIDS HAZARDOUS DECOMPOSITION PROOUCTS OXIDES OF CARBON. NITROGEN. AMMONIA AND ACRID SMOKE ANO FUMES. HAZARDOUS WILL NOT X < -OCCUR POLYMERIZATION N/A MAY < - -OCCUR CONDITIONS TO AVOID SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED DUE TO THE NATURE OF THE PACKAGING OF THIS PRODUCT A SPILL IS UNLIKELY WASTE DISPOSAL METHOD PER ALL LOCAL. STATE AND FEDERAL REGULATINS CONCERNING HEALTH AND POLLUTION FOR OISPOSAL PROCEDURES. NEUTRALIZING AGENT N/A SECTION IX SPECIAL PROTECTION INFORMATION REQUIRED VENTILATION LOCAL EXHAUST RECOMMENOED TO CONTROL VAPOR LEVELS IF BURNNED OR WELDED. GENERAL EXHAUST IS MORE THAN ADEOUATE TO PROTECT WORKER FROM EXPOSURE TO LEVELS ABOVE PERMISSIBLE EXPOSURE LIMITS. RESPIRATORY PROTECTION WEAR NIOSH APPROVED RESPIRATOR TO PROVIDE ADEOUATE VENTILATION WHEN BURNING. WELDING OR MACH INING<GRIND1NG > . SAL 000006799 (CONTINUED) M/M QUICK CUBE GS606SECTION IX - SPECIAL PROTECTION INFORMATIOPAGE : 05 PROTECTIVE GLOVES RUBBER GLOVES SHOULO BE WORN BY SENSITIVE INDIVIDUAL DEPENDING ON SEVERITY OF EXPOSURE. EYE PROTECTION SAFETY GOGGLES SHOULO BE WORN DEPENDING ON SEVERITY OF EXPOSURE. OTHER PROTECTION CLEAN, PROTECTIVE CLOTHING SHOULD BE WORN. SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE j INDOOR lOO F <--MAX 30 F <--MIN | X [HEATED | PRECAUTIONS TO BE TAKEN IN HANDLING 6 STORING AVOID CONTACT WITH EYES, SKIN AND CLOTHING. OTHER PRECAUTIONS WASH THOROUGHLY AFTER HANDLING. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH EYES. SKIN ANO CLOTHING.. ! REFRIGERATED{ OUTDOOR JX \ SECTION XI - REGULATORY INFORMATION CHEMICAL NAME N/A C.A.S. NUMBER UPPER % LIMIT THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE 111 OF THE SUPERFUND AMENDMENTS ANO REAUTHORIZATION ACT OF 1966 ANO 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED ANO LABELED FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND LABELEO FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <-- IMCD <--T ARIFF 6 D <- -UTA < - -Ml L XTARY AIR (AFH 71-4) (CONTINUED) SHIPPING NAME M/M QUICK CURE SECTION XII - TRANSPORTATION (FOR FUTURE USE) PAGE : 06 HAZARD CLASS ! ID NUMBER ! REPORT OTY LABELS | LIMITED OTY UNIT CONTAINER DOT SPS CONTAINER [ NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) SECTION XIII - REFERENCES 1. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION N. IRVING SAX. 2. THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE WORK ENVIRONMENT. 2ND EDITION, ACG1H. 1985. 3. VENDOR'S MSOS. * INGREDIENT PERCENTAGE IS A TRADE SECRET; MASS TRADE SECRET NUMBER 99-127-002 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TC BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH OIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE, STORAGE. OR DISPOSAL OF THE PRODUCT. O0o6900 SAL 000006801 MATERIAL SAFETY DATA SHEET NALCO PRODUCT SOLUTION. >0 SPECIAL INDICA' 6 05 Emergency Telephone Number Medical (312) 920-1510(24 hours)* 'Elective Novemot' : ? 989. the area code v.'/ br changed to 70S SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: SOLUTION S0260 SPECIAL INDICAT DESCRIPTION: Special indicator, (M) indicator - brom cresol green and methyl red dissolved in isopropanol NFPA 704M/HMIS RATING: 1/1 HEALTH 3/3 FLAMMABILITY 0/0 REACTIVITY 0=insignificant l=Slight 2=Moderate 3=High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS 0 OTHER Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Isopropanol 67-63-0 SECTION 3 PRECAUTIONARY LABEL INFORMATION 99+ WARNING: FLAMMABLE. Keep away from heat, sparks and flame. May cause irritation to skin and eyes. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Do not take internally. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: Flush with water for 15 minutes. Call a physician. Flush with water for 15 minutes. Do not induce vomiting. Give water. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation PAGE 1 OF 7 SAL 000006802 f'ALCQ ,,:MFANV C.-.2 N'ALCC ARE?ii/n2961-9500,` * * f Itpchvp hin^rntn-- * V `PEP1 'ILl. rr. MCIF5 60566,1024 toe a<ca code ,'Md phone numbet w<n he changed to < 7081 305-1000 MATERIAL SAFETY DATA SHEET NALCO 68605 PRODUCT SOLUTION S0260 SPECIAL INDICA' Emergency Telephone Number Medical (31 2) 920-1510 (24 hours)' * E fiective November 11. 1909. Ihe area code win Be changed lo 708 SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) EYE CONTACT: SKIN CONTACT: INHALATION: Can cause moderate irritation. Can cause moderate irritation. Prolonged inhalation of mist or vapor may cause nausea, dizziness, light-headedness, vomiting or unconsciousness depending on the length of exposure and the first aid action given. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but toxicity studies of the ingredient(s) in Section 2 have been reviewed. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LDS 0 = 5,000 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): LDS,, = 13 gm/kg ACUTE INHALATION TOXICITY (ALBINO RATS): LCS0 = 16,000 ppm (8-hours) SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear amber to orange FORM: Liquid SOLUBILITY IN WATER: Completely SPECIFIC GRAVITY: 0.79 6 60 Degrees F BOILING POINT: 180 Degrees F 6 760 mm Hg FLASH POINT: 56 Degrees F (TCC) PERCENT VOLATILE BY WEIGHT: Greater than 99% ODOR: Isopropanol ASTM D-1298 ASTM D-86 ASTM D-56 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 54 Degrees F (TCC) ASTM D-56 AUTOIGNITION TEMPERATURE: 860 Degrees F (ASTM D2155-66) UEL 12.0% LEL 2.0% f PAGE 2 OF 7 ooooo^03 sM- BB NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 ape.*' GfEOO * * **r L, ??--=<3 r.v- --jJ--77 cpr-: rc c ''3-gee ,'r -c MATERIAL SAFETY DATA SHEET NALCO 6 $605 PRODUCT SOLUTION S0260 SPECIAL INDICA' Emergency Telephone Number Medical (31 2) 920-1510 (24 hours)' `Effective Novemoe' i 989. me aces cocre *'/ be changed tn TOR SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED ) EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: Not applicable SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent organic vapor cartridge respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.) when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Keep the spill away from heat, sparks, flames and welding operations. PAGE 3 OF 7 00 00 0** APE i-- i.! r- . * -- rT T"1 M S5 A TV Y -1'-' 2-i3S1 -9500 'JAi 'OO . -- NJAC^ERVIl LG. ILLINOIS 60566-102^3 h oce j-cr cho'ie nun? vjut be cnar.cja to i TOR) 305-1000 MATERIAL SAFETY DATA SHEET NALCO GS605 PRODUCT SOLUTION S0260 SPECIAL INDICA' Emergency Telephone Number Medical {31 2) 920-1 StO (24 hours)' f llvt-tivt; November 11 liJd'J 1 Hr r.ocJr wit be changed to 708 SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) Ventilate area and evacuate employees from exposure if the airborne concentration exceeds the TLV. Refer to Section 14. DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified before disposal in a landfill (Hazardous Waste Treatment, Storage and Disposal facility). Can be incinerated in accordance with local, state and federal regulations. Empty product containers should be punctured, if plastic, and placed in the garbage collection container. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCIA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - ISOPROPANOL FLAMMABLE LIQUID UN 1219 SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Isopropanol - Flammable Isopropanol = TWA 400 ppm, STEL 500 ppm ACGIH/TLV 980 mg/m3, 1225 mg/m1 ACGIH/TLV Isopropanol = TWA 400 ppm, STEL 500 ppm 0SHA/PEL 980 mg/m3, 1225 mg/m3 OSHA/PEL CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 PAGE 4 OF 7 Essa NALCO CHEMICAL COMPANY ONE NALCO CENTER .V-r A SAL 000006805 NAPERVILLI ILLINOIS 60566-1024 MATERIAL SAFETY DATA SHEET NALCO 6 05 PRODUCT "SOLUTION S0260 SPECIAL INDICA Emergency Telephone Number Medical (312) 920-1 510 (24 hours}' 'E<<tct`ve Ncvemoer 1 ' ' 989 j'ea coce m'i te tr. 7C,C> SECTION 14 REGULATORY INFORMATION ( CONTINUED ) (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local ( fire department is required after October 17, 1987 if you have: - 10,COO pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. After October 17, 1989, MSDS(s), or a list of product names for all hazardous substances between zero (0) and 10,000 pounds, not previously reported, must be submitted. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List < 40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPAPT C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): PAGE 5 OF 7 SAL 000006806 si A L. C v ~ 1. r a. ~ NIAUFOVII.I r ii.i (NO'S BCI36B-1024 c)\.` > ;v .<t 7- .'505 ! 000 MATERIAL SAFETY DATA SHEET 68609 PRODUCT SOLUTION S0260 SPECIAL INDICA NALCQ Emergency Telephone Number Medical (312)920-1510(24 hours)' 'Ettecuve November ' ' ' 989 3'$3 *" De cnaigeO fo 70S SECTION 14 REGULATORY INFORMATION CONTINUED ) None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Isopropanol - Section ill STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: Regulated in those states using the TLV for isopropanol as a criteria for listing. SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. O., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. PAGE 6 OF 7 SAL 0O006807 D aa NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVIL.L.E. ILLINOIS 60566-1024 N NALCQ 6 S 6 05 SECTION 17 BIBLIOGRAPHY MATERIAL SAFETY DATA SHEET PRODUCT SOLUTION S0260 SPECIAL INDICA Emergency Telephone Number Medical (312) 920-1510(24 hours)' '!rlfea.ve Ncvemoer ' 1 9S5 thp atea cooe *'/ oc cfimood to 708 ( CONTINUED ) CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. I ARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference Of Governmental Industrial Hygienists, OH. PREPARED BY: John J. Kasper, MSc., Manager Product Safety DATE CHANGED05/23/89 DATE PRINTED: 12/02/89 ,i it * * ' r~ 26 -T = PAGE 7 OF 7 sal oooo6308 Ai-T PVH.L.L. il.'. 'Tunis 60566-1024 . : 8' >55- WOO NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (312) 9201510(24 hours) 'Effective November M >969 ff'e area co3e wi< be changed to ?C8 f SAL 000006809 NALCO CHEMICAL COMPANY ONE NALCO CENTER rsjAPEIRVILLE. ILLINOIS 605B6-1G2-1 MATES IAL SAFETY DATA SHEET BREX CONCENTRATE sage 01 (061242-0345 *60016293-1618 )jDATE OF I$SUE 09/01/8 ! SUPERSEDES S 05/28/89 SECTION I * GENERAL INFORMATION CHEMICAL NAME 8 SYNONYMS N/A TRADE NAME & SYNONYMS 8REX CONCENTRATE 6S6 CHEMICAL FAMILY AQUEOUS ACID CESCALER FORMULA X<-"MIXTURE MANUFACTURERS NAME NATIONAL CKEMSCARCH DIV. OF NCH CORP. ADDRESS (NUMBER, STREET. CITY. STATE 8 ZIP CODE) BOX 152170 IRVING, TEXAS 75015 PREPARED BY: kevin uhl/t.s. Chemist eooe| PROOUCT number 1| EMERGENCY TELEPHONE NUMBER 1618 214 -43B-1381 SECTION II- HA2AR00US INGREDIENTS THE HA2ARCS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS TH PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHCLE. CHEMICAL NAME (INGREDIENTS) HYDROCHLORIC ACID | HAZARD CORROSIVE J TLV Sppm-(C) ; pel5PPM-1C) ! cas* 7647-01*0 SECTION IIA - NON-HAZARDOUS INGREDIENTS NON-HAZARDCUS INGRECIENT NAMES AND: CAS NUMBERS ARE PROTECTED UNDER NO TRADE SECRET REGISTRY 409363-5028P SECTION III - PHYSICAL DATA (CONTINUED) BREX CONCENTRATE SECTION III - PHYSICAL DATA BOILING PT (FAHRENHEIT) VAPOR PRESSURE (MM HG) VAPOR DENSITY ( A 1 R 1 ) PH * IOOa PERCENT, VOLATILE BY VOLUME (%> SOLUBILITY IN WATER VISCOSITY 1 1 <1 11 1 1 1 [ 1 1 k < 220.00; SPEC GRAVITY (H20-D 20 00; COLOR LIGHT AMBER 0. bo ; OCOR 1.00; CLARITY PUNGENT ACIC TRANSPARENT BB.OOj EVAPORATION RATE j <BU AC 1 ) ! COMPLETE NON-VISCOUS : 1 .OS O. 10 PAGE : 02 SECTION IV - FIRE ANC EXPLOSION HAZARD FLASH POINT (METHOD USED) NCN-FLAM ! FLAMMABLE LIMITS |n/a ! LEL |n/a EXTINGUISHING MEDIA 'ALCOHOL' X <- -F QAM X <--F OAM X - - C02 DRY X<--CHEMICAL WATER X<--SPRAY SPECIAL FIRE FIGHTING PROCEDURES PRESSURE DEMANC SELF-CONTAINED RESPIRATORY EQUIPMENT. ACIC ITSELF IS NON-FLAMMABLE. HYDROCHLORIC ; UEL |n/a --OTHER UNUSUAL F t RE 8 EXPLOSION HAZARDS A LATENT FIRE OR EXPLOSION HAZARO WHEN IN CONTACT WITH METALS DUE TC THE GENERATION OF HYDROGEN GAS- oNFPt HA2AHC RATING (O*INS1 CMF1CANT; 1 *SLIGHT.2MOOER-TE:3HIGH.A-EXTREME I 3 < -- H A L Th <--FlAMMaEILITy 0 <--REACT IVITY <--SPECIA.. SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE NOT E 5 TAEL I SHED FOR MIXTURE. SEE 5ECTICN II EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE i INGESTION CAUSES SEVERE BURNS OF THE MUCOUS MEMBRANES OF THE MOUTH. SAL 000006810 G S6 04 (CONTINUED) brex concentrate SECTION V - HEALTH HAZARD DATA AQE 03 ESOPHAGUS AND STOMACH. PAIN IN THE THROAT AND STOMACH WITH DIFFICULTY IK SWALLOWING.INTENSE THIRST, NAUSEA AND VOMITING FOLLOWED BY DIARRHEA. ARE COMMON. IN SEVERE CASES. tHIS IS FOLLOWED BY COLLAPSE AND UNCONSCIOUSNESS EVE CONTACT CAUSES SEVERl IRRITATION AND PAINFUL BURNS OF THE EVES ANO EYELIDS SKIN CONTACT WITH CONCENTRATE CAUSES DESTRUCTION OF CLOTHING AND SEVERE BURNS UNLESS PROMPTLY WASHEO OFF. REPEATED SKIN CONTACT WITH OILUTED PRODUCT WAV LEAD TO THE DEVELOPMENT OF DERMATITIS. INHALATION OF EXCESSIVE CONCENTRATION OF VAPORS PRODUCES SEVERE IRRITATION OF THE UER RESPIRATORY TRACT WITH COUGHING. BURNING OF THE THROAT AND A CHOKING SENSATION. _ CHRONIC - (LONG TERM EXPOSURE) CHRONIC INGESTION MAY PRODUCE FATAL EFFECTS FROM ESOPHAGEAL OR GASTRIC NECROSIS DENTAL DISCOLORATION ANO EROSION OF EXPOSED INCISORS OCCUR ON PROLONGED EXPOSURE TO LOW CONCENTRATIONS OF HYDROCHLORIC ACID VALORS. EVE EXPOSURES MAY RESULT IN PROLONGED OR PERMANENT VISUAL IMPAIRMENT OR TOTAL LOSS OF SIGHT. CHRONIC SKIN EXPOSURES CAN YIELC ULCERATION ANO SUBSEQUENT SCARRING THE IRRITANT EFFECT OF VAPORS ON THE RESPIRATORY TRACT MAY PRODUCE LARYNGITIS. GLOTTAL EOEMA. BRONCHITIS. PULMONARY EOEMA. ANO DEATH. PRIMARY ROUTE OF ENTRY: < - - INHALATION INGESTION X<-- ABSORPTION EMERGENCY 6 FIRST AID PROCEDURES INHALATION : GET PERSON OUT OF CONTAMINATED AREA TO FRESH AIR. IF BREATHING HAS STOPPED, ARTIFICIAL RESPIRATION SHOULO BE STARTED. OXYGEN MAY BE ADMINIStERED IF READILY AVAILABLE. SEEK MEDICAL ATTENTION IMMEDIATELY. ^ EYE CONTACT; immediately flush eyes with large amounts of water for at least is MINUTES HOLDING EYELIDS APART TO ENSURE FLUSHING OF THE ENTIRE EYE SURFACE. WASHING EYES WITHIN 1 MINUTE IS ESSENTIAL TO ACHIEVE MAXIMUM EFFECTIVENESS. SEEK MEDICAL ATTENTION IMMEDIATELY. SKIN CONTACT: IMMEDIATELY WASH CONTAMINATED SKIN WITH PLENTY OF WATER THIS MAY BE FOLLOWED WITH A RINSE WITH SODIUM BICARBONATE (3% SOLUTION) IF AVAILABLE. REMOVE CONTAMINATED CLOTHING ANO FOOTWEAR AND WASH CLOTHING BEFORE REUSE. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION : IF SWALLOWED. OC NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER IF AVAILABLE. GIVE SEVERAL GLASSES OF MILK NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION IMMEDIATELY N/A NOTES TC PHYSICIAN SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY IARC <- - YES NTP <--YS OSHA <--YCS ACGIH <--YES OTHER <--YS X<--NC X<--NC X < - *NC X <-NC X<--NC (CONTINUED) BREX CONCENTRATE SECTION VI TOXICITY INFORMATION HYDROCHLORIC ACID: TXDS INH-HMN LCLC : 1300PPM/3OM UNK-MAN LDLO: B IMG/KG 4. ORL-RBT LD50: 900MG/KG 4 MTOS CYT-GRH-PAR: 0.02ML 4. 4 SECTION VII - REACTIVITY OATA PAGE : 04 [X<--STABLE <--UNSTA6l ! CONOIDTIONS TC AVCIC 'HCL GAS IS SLOWLY RELEASED FROM UMCONFINEC ACID CONTACT WITH METALS MAY CAUSE GENERATION OF EXPLOSIVE OR FLAMMABLE HYDROGEN INCOMPATIBILITY (MATERIALS TO AVOID) STRONG ALKALIS, ALKALI METALS AND CORROSIVE MATERIALS- OXIDIZING MATERIALS MAY 6xiOIZE TO CHLORINE. METALS: AL. TIN. 2N. HAZARDOUS DECOMPOSITION PRODUCTS N/A HAZARDOUS ! WILL NOT j X <--OCCUR POLYMERIZATION'! !n/a MAY ! CONDITIONS TO AVOID <-OCCUR | SECTION Vtll - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SMALL QUANTITIES MAY BE FLUSMEC WITH COPICUS QUANTITIES CF WATER. IN CASE OF LARGER AMOUNTS. CONTAIN LI0U1D USE LIMESTONE. LIME 06 SCDi ASH TC CAUTIOUSLY NEUTRALIZE. WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL. STATE AND LOCAL REGULATIONS CONCERNING HEALTH AND POLLUTION. DISPOSE OF VIA APPROVED CHEMICAL WASTE DISPOSAL METHODS, IF REGULATIONS PERMIT. NEUTRALIZING AGENT SODA ASH - SLAKED LIME IS ADDED SLOWLY WHILE STIRRING. WITH LARGE VOLUMES OF WATER. FLUSH TC DRAIN SECTION IX - SPECIAL PROTECTION INFORMATION oO (CONTINUED) BX CONCENTRATE SECTION IX - SPECIAL PROTECTION INFORMATlOPAGE : 05 REQUIRED VENTILATION GOOD INDUSTRIAL HYGIENE PRACTICE DICTATES ISOLATED AND CONTAINED. ANO PROVIDEO WITH VENTILATION OR CTHER CONTROLS TO MAINTAIN HYDROGEN CHLORIDE BELOV TMG/M3 (5 PPM) AS THAT THE WORK AREA SHOULD AOECUATE LOCAL EXHAUST THE AIR CONCENTRATION OF REQUIRED BY CSHA. BE RESPIRATORY PROTECTION NfOSH APPROVED RESPIRATORY PROTECTION REOUIREO IN THE ABSENCE OF PROPER ENVIRONMENTAL CONTROL. FOR EMERGENCIES. A SELF-CONTAINED BREATHING APPARATUS OR A FULL FACE RESPIRATOR AS APPROVED BY NICSH IS RECOMMENDED THE IOLH LEVEL IS lOO PPM. RECOMMENDED RESPIRATOR SELECTIONS: FOR EXPOSURES* <50 PPM * CCRAG/SA/SCBA;<100 PPM - CCRABF/GMAG/SAF/SCBAF PROTECTIVE GLOVES RUBBER. SYNTHETIC ELASTOMERS SHOULD BE WORK pvc or cther plastic EYE PROTECTION CHEMICAL GOGGLES IF METHOD OF USE PRESENTS THE LIKELIHOOD CF EYE CONTACT. OTHER PROTECT]OK PROTECTIVE CLOTHING TC PREVENT SKIN CONTACT. G S 6 04 SECTION X - STORAGE ANC HANOLING INFORMATION STORAGE TEMPERATURE ! INDOOR 120 F <--MAX 32 F<--M1N | X SEATED | PRECAUTIONS TC BE TAKEN IN HANDLING A STORING PREVENT ALL CONTACT WITH EYES AND SKIN. AVCIC BREATHING IRRITATING VAPORS. OTHER PRECAUTIONS STORE IN A COOL. DRY PLACE FOLLOW LABEL DIRECTIONS. KEEP OUT OF REACH OF CHILDREN. {REFRIGERATED! OUTDOOR ; SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C . A . S. NUMBER UPPER * LIMIT HYDROCHLORIC ACID 76X7*01-O 20 THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TC THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS ANC REAUTHOR 1ZATION ACT OF 1986 ANC 40 CFP PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, EnO USERS ARE EXEMPT ( c(CONTINUED) BRSX CONCENTRATE SECTION XI REGULATORY INFORMATION PAGE 06 FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE 1SUCH AS FERTILIZERS ANC HERBICIDES I . OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES SECTION XII - TRANSPORTATION (FOR FUTURE USE I APPLICABLE REGULATIONS <--49 CF R < * - IMCC SHIPPING NAME KAZARO'CLASS LABELS UNIT CONTAINER DDT SPS CONTAINER AEROSOL PROPELLANT(S ) <--TARIFF 6 C <--JATA <*-MILlTAfiV AJR (AFR 71-4) ! ID NUMBER I REPORT QTY ! LIMITED OT Y \ NET EXPLOSIVE WT SECTION XIII - REFERENCES 1 NICSH POCKET GUIDE TC CHEMICAL HAZARD5. 1978 2 HANC60CK OF TOXIC AND HAZARDOUS CHEMICALS ANC CARCINOGENS. 2ND EDITION. MARSHALL S1TTIG i9E* 3 NICSH REGISTRY OF TOXIC EFFECTS CF CHEMICAL SUBSTANCES. 128. 4 CANGERCUS PROPERTIES CF INDUSTRIAL MATERIALS. E T i- EDITION. N IRVING SAX SAL 000006812 8REX CONCENTRATE (CONTINUED I SECTION xm REFERENCES IIcSCEuX5PKBCi"S?SEftOTi?ORgNIM?LglE?O*^r8!eg^ar#^o1NM^iSTAmI*?I`>0A.C.SK D^vATSA*. CNOCNSWIOaEIRrEaCStv OR THE RESUtTS TO BE OBTaTSec USE ?HEBofTHIS r*ge 8P0?fSa*"BW 0*V^B0^eRTT OAMAGE cauIIdmIs N0 RESPCNSIBILITV SaObTiiH^ 07 SAL 000006813 LN HREE~c MANUFACTURERS NAME Big Three industries, Inc. ISSUE DATE APRIL 1, 1984 Lincoln big three, inc. P-O. BOX J274 BATON ROUGE, LOUISIANA 70821 I -- GENERAL INFORMATION PRODUCT NAME NITROGEN, Refrigerated Liquid EMERGENCY TELEPHONE NO. (504) 357-4331 6 S 2 64 MATERIAL SAFETY DATA SHEET TRADE NAME AND SYNONYMS Nitrogen (LIN) CHEMICAL NAME AND SYNONYMS Nitrogen PRODUCT ID NO. UN-1977 FORMULA N2 CHEMICAL FAMILY Inert Gas GAS NUMBER 007 727 379 . -^-7.--- 1L-- HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF LIQUIDS AND GASES % TLV None BOILING POINT -320.4F (- 195.8C) & i ATM VAPOR PRESSURE N/A density boiling point and 1 ATM 50.49 Ib/cu ft SOLUBILITY IN WATER N/A EXPANSION RATIO (LIQUID TO GAS) Ill ---- PHYSICAL DATA I-*.**'-'- v-VI- SPECIFIC GRAVITY (H20=1) 0.8083 at 1 ATM and Boiling Point PERCENT, VOLATILE BY VOLUME (%1 N/A EVAPORATION RATE N/A MATERIAL AT NORMAL CONDITION | YYl LIQUID | [SOLID 1 : 696.5_________________________________________________ APPEARANCE AND ODOR Colorless. Odorless Liauid *'**?*''*? .3* t.V. | ] GAS - IV --^RfTe ANd" EXPLOSION HAZARD DATA - FLASH POINT (METHOD USED) FLAMMABILITY LIMITS IN AIR 1% OF VOL ) N/A | EXTINGUISHING MEDIA {CLOSED CUP ( [OPEN CUP LOWER N/A UPPER None. Nitrogen neither burns or supports combustion. Use media appropriate for the surrounding fire. rf- \ N/A SPECIAL FIRE FIGHTING PROCEDURES Nitrogen will act as a simple asphyxiant if it displaces oxygen. Liquid nitrogen when spilled will vaporize rapidly causing a vapor cloud that will create an oxygen-deficient atmosphere. Evacuate the area of this vapor cloud unless wearing self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD Contact with refrigerated liquid nitrogen may cause frostbite SAL 000006814 S3 2 64 blE^LTH Jj&ZWP. DATA THRESHOLD LIMIT VALUE UNUSUAL CHRONIC TOXICITY ROUTES OF EXPOSURE None Established None Inhalation & Skin Contact EFFECTS OF OVEREXPOSURE Nitrogen is nontoxic, but may produce suffocation by displacing the oxygen in the air. Oxygen-deficient atmospheres may cause dizziness, nausea, vomiting, diminished mental alertness, loss of consciousness and death. Contact with liquid nitrogen can cause severe frostbite and freeze burn. Prolonged breathing of very cold atmospheres can cause lung damage and hypothermia. EMERGENCY1 AfJo FIRST AIO PROCEDURES ' Persons suffering from lack of oxygen should be moved into fresh air. Assisted respiration and supplemental oxygen should be given if the victim is not breathing. Rescue workers may require self-contained breathing apparatus. If contact with cryogenic liquid has caused frostbite, contact a physician. Do not rub affected areas, as tissue damage may occur. STABILITY | ^ UNSTABLE XX STABLE INCOMPATABILITY (MATERIALS TO AVOID) Vt -- REACTIVITY DATA CONDITIONS TO AVOID None None HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID | j MAY OCCUR j XX WILL NOT OCCUR None r-;' VII -- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Shut off nitrogen source if possible. Avoid contact with liquid nitrogen or its cold boil-off gas. To increase rate of evaporation spray with large amounts of water. Self-contained breathing apparatus will be required in oxygen-deficient areas such as nitrogen vapor clouds. WASTE DISPOSAL METHOD Allow liquid nitrogen to evaporate in a wetl-ventilated outdoor location. -v --ym -- SPECIAL PROTECTIVE INFORMATION RESPIRATORY PROTECTION (SPECIFY TYPEI Use self-contained breathing apparatus in oxygen-deficient atmospheres. Respirators will not function! VENTILATION LOCAL EXHAUST SPECIAL Natural or mechanical where gas is present MECHANICAL PROTECTIVE GLOVES Thermal Insulated OTHER PROTECTIVE EQUIPMENT Long Sleeve Shirt other vents sufficient to avoid high concentrations of nitrogen. EYE PROTECTION Full face shield and safety glasses nTx^1s PEC IAL PR ECAUTI ON S IN HANETLA'JG and storing .r ... .. Store liquic '^mta? ntilate&areas. Follow general safety procedures for handling cryogenic liquids found in CGA Pamphlet P-12. DO--T--L-A--B--E-L--IN-G^ <3 Green LabeV>r - . - VALVE CONNECTION NUMBER CGA 580 FOR GAS OTHER PRECAUTIONS4'''^*-^"* Liquid nitrogen expands al a ratio of 696.5 to 1, and if trapped in a container or pipe it will produce enormous pressures which will rupture the container. Any area where liquid could be trapped must be protected by a pressure relief device. Piping must be designed for extreme cold. Many materials, such as carbon steel, will become brittle and may fracture when extremely cold. SAL 000006815 r HALDOR TOPSOE, INC. i MATERIAL SAFETY DATA SHEET revised: m'& May 1989 EMERGENCY HAZARD RATING 4EXTREME fmc A 3 MOOERATC 1 SLIGHT 0 - INSIGNIFICANT HEALTH /lVo / RACTIVfTr y V/ SPECIFIC MA2AA0 1. GENERAL INFORMATION Trade name and synonym: Hydroprocessing Catalyst, TK-710 Chemical family: Oxides of Cobalt, Molybdenum, Aluminum Major chemical constituents (CAS No.): CoO (1307-96-6) MoO (1313-27-5) Al 0 (1344-28-1) Page 1 of 2 r 2. All components of the catalyst appear on the TSCA Inventory. Manufacturer's or Importer's name & address: HALDOR TOPSOE, INC. Telephone No.: 17629 El Camlno Real Houston, TX 77058 Emergency Telephone No.: (713) 480-2600 (713) 474-3261 HAZARDOUS INGREDIENTS CoO MoO_3 concentration ______ _________ 2 6 92 TLV/JWA mm _ 0.05 5 (Mo) 10 (Nuisance Dust) *As adopted by ACGIH Aluminum oxide, molybdenum trioxide, and all compounds containing chromium, cobalt, nickel, copper or zinc are subject to Chemical Release Reporting requirements of SARA Section 313, as codified in 40 CFR Part 372. 3. PHYSICAL DATA Appearance & odor: Blue rings or cylinders, odorless Bulk density: 31 Ibs/cuft (rings) Vapor pressure: 38 Ibs/cuft (cylinders) Melting point: >1470 F Solubility In water: Not relevant Negligible 4. FIRE & EXPLOSION HAZARD DATA Flash Point: Not relevant Flammable Limits: Not relevant Extinguishing Media: Not relevant Special Fire Fighting Procedures: Not relevant, Noncombustible Unusual Fire & Explosion Hazard: None SAL 000006816  AO 46 Page 2 of 2 5. HEALTH HAZARB PATA Effects of overexposure: Inhalation of dust may cause irritation of the respiratory tract. Can cause allergic dermatitis, diarrhea, and difficulty In breathing. Emergency & first aid procedures: In case of significant Inhalation, seek medical attention. Wash off the skin with soap and water. Irrigate eyes with water. Listed as a carcinogen: Yes _____ No X by OSHA _____ IARC _____ NTP 6. REACTIVITY DATA Stability: Stable X Unstable ___ Incompatibility (Materials to avoid): Water damages catalytic properties. Hazardous decomposition products: N/A Hazardous polymerization: may occur ___ will not occur X 7. SPILL AND WASTE DISPOSAL PROCEDURES Steps to be taken If material is spilled: Collect all spilled material by mechanical means and place In a container. Avoid dust generation. Label container. Waste Disposal Method: In accordance with Federal, state, & local regulations. 8. PERSONAL PROTECTION INFORMATION Respiratory protection: Use approved respirator In confined space. Eye protection: Goggles Ventilation of work place: Outside: Natural Inside reactor: Mechanical Hand protection: Gloves Other protection: Safety shoes recommended when handling drums. 9. SPECIAL PRECAUTIONS During storage: Keep containers dry and tightly closed. When handling containers: Adhere to standard safety procedures. Use mechanical assistance to avoid strain. During loading: Adhere to standard safety procedures. Minimize free fall of material to avoid breakage. During unloading: Adhere to standard safety procedures. Spent catalyst may be pyrophoric in the presence of air. o0000<>817 sM- The information and recommendations set forth herein are believed to be correct and presented in good faith as of the date hereof. Haldor Topsoe, Inc. however, makes no representation or warranty as to the completeness thereof and disclaims any liability for damages resulting from reliance thereon. MATERIAL SAFETY DATA SHEET O25OPa*l AtQon^uin o*d O** Plain**. Rlinoi* 60017-5017 Tetaphon* 512-391*2000 FAX 312-391-2259 T#ie* 253-265 MATERIAL Silica gel PRODUCT NAME UOP^ FIA Reagent INGREDIENTS (cas no,.A (63231-67-4) mm >99 Emergency Aealtienet 24 Hour Emergency Telephone Number* USA: UOP S1I091-P123 Chemtrec tOQ/424-9300 Canada: Canutec 613/996-6666 Outside USA: Chemtrec 202/4B3-7616 Page X of 4 1988-89 ACGIH TLV-TWA _____ (OSHA PEL) 3 10 mg/m (6 mg/m^) Proprietary oil soluble dyes <1 None established Governmental Inventory Status: All components registered in accordance with TSCA. TRANSPORTATION CLASSIFICATION DOT Hazard Class: Not regulated IM0 Hazard Class: Not regulated PHYSICAL DATA Apparent Bulk Density, lbs./cu. ft.: Solubility in Water: Insoluble pH of 5% slurry in H^O: 6.5 0.65 Appearance: Light brown powder Odor: Slight pungent FIRE AND EXPLOSION DATA Flash Point, F (C): Method: Extinguishing Media: Not applicable Not applicable Product is not combustible. However, if located in a fire area, CO^, dry chemical and foam extinquishing methods are acceptable. REACTIVITY DATA Stability: Conditions to Avoid: Hazardous Decomposition Products: Hazardous Polymerization: Incompatible Materials: Stable Reacts with hydrofluoric acid None known Will not occur Hydrofluoric acid SPILL OR LEAK PROCEDURE Isolate the affected area. Wear proper protective equipment, especially eye protection. Sweep, shovel or vacuum up the spilled material and place into appropriate container(s). Dispose of spilled material in accordance with federal, state and local waste disposal regulations. See WASTE DISPOSAL section. ooooo-1" GS551 UOP FIA Page 2 of 4 WASTE, DISPOSAL General Waste: Waste material and materials from spill clean-up procedures, must be handled In accordance with federal, state and local regulations. Product and Its components are not listed by generic name or trademark name In the U.S. EPA's Resource Conservation and Recovery Act (RCRA) Hazardous Waste Management Regulations and do not possess one of the four identifying characteristics of hazardous vaste. Recommended disposal methods Include incineration for liquid waste and contaminated solids. Container Disposal: Containers should be drained as completely as possible before reuse. Dispose of containers in accordance with federal, state and local regulations. HEALTH HAZARD DATA Primary Routes of Exposure: Contact with skin. Product ingestion is unlikely but may occur if proper safety/hygiene procedures are not followed. Exposure may also occur via eye contact, inhalation or ingestion if product dust is generated during handling and/or processing. In order to minimize exposure to product, proper protective equipment should be used and proper safety/hygiene procedures should be followed. Acute Oral LD^: No data for product. Oral !!), for silica gel is greater than 5 gAg (rat). Inhalation LC^: No data for product. Repeated or prolonged inhalation of reagent dust may cause irritation of the upper respiratory tract. Dermal : No data for product. Dermal ID^ for silica gel Is greater than 2 gAg (rabbit). Primary Eye Irritation: No data for product. Not considered to be a primary eye irritant; however, reagent dust may be irritating to the eyes. Primary Dermal Irritation: No data for product. Not considered to be a primary skin irritant. However, silica gel can have a drying affect on the skin and may cause irritation upon repeated or prolonged exposure. Toxicology Summary: Based on the toxicological properties of its components, product is considered to be slightly toxic to non-toxic by dermal, oral and inhalation routes. Repeated or prolonged skin contact or inhalation of reagent dust may be irritating. Reagent dust may be irritating to the eyes. SAL 00006819 Skin: Eyes: Inhalation: Ingestion: GS551 UOP FIA Page 3 of A rx&si MB Vash contaminated skin thoroughly vith soap and vater. Rinse and repeat. Contaminated clothing should be removed and laundered before reuse. If irritation develops, obtain professional medical attention. Flush affected eye with large amounts of vater for a minimum of 15 minutes. Obtain Immediate professional medical attention. Remove affected person to fresh air. If respiratory problems develop, obtain prompt professional medical attention. Drink plenty of water immediately. Obtain immediate professional medical attention. Note To Physician: Eyes: Rinse affected eye with vater for a minimum of 15 minutes. Stain to check for corneal damage in severe cases. Skin: Treat minor cases as contact dermatitis; for severe burns, treat as any thermal burn. PROTECTIVE E0UIPMENT Respiratory: Where natural ventilation is inadequate, use mechanical ventilation, other engineering controls or a NI0SH-approved toxic dust respirator to prevent inhalation of reagent dust. Skin: Gloves and work uniform as necessary to prevent repeated or prolonged skin contact. Eye: Safety glasses or chemical goggles as necessary to prevent eye contact. SPECIAL PRECAUTIONS Store in tightly closed, properly labeled containers. Avoid repeated or prolonged contact with skin. Avoid contact vith eyes and inhalation of dust. NOTE: If further details are required, please address inquiries to: Dennis R. Sullivan Product Stewardship Coordinator Environmental Sciences Group UOP, 25 East Algonquin Road Des Plaines, IL 60017-5017 (312) 391-3189 24 Hour EMERGENCY Telephone Number: (312) 391-2123 KOTZr 512 Area Code Changes To 708 Effective 11-11-89 SAL 000006820 CSS 51 UOP FIA Page 4 of 4 The data and recommendations presented In this data sheet concerning the use of our product and the materials contained therein are believed to be accurate and are based on information which Is considered reliable as of the date hereof. However, the customer should determine the suitability of such materials for his purpose before adopting them on a commercial scale. Since the use of our products by others Is beyond our control, no guarantee, express or implied, is made and no responsibility assumed for the use of this material or the results to be obtained therefrom. Information on this form is furnished for the purpose of compliance with Government Health and Safety Regulations and shall not be used for any other purposes. Moreover, the recommendations contained In this data sheet are not to be construed as a license to operate under, or a recommendation to infringe, any existing patents, nor should they be confused with state, municipal or insurance requirements, or with national safety codes. UOP Date: January 1989 Revision: 2 Supercedes: April 1986 SAL 000006821 HATER I A SAFETY DATA ***-********'***** PREMIER INDUSTRIAL CORPORATION 4500 EUCLID AVENUE CLEVELAND. OHIO 44103 MAIL TO: CONOCO REFINERY WHSE OLD SPANISH TRAIL WESTLAKE LA 70669 B-*-**-**-*****-.*.*-**.**.**..** * EMERGENCY/INFORMATION TELEPHONE. * 216/391-B300 i- <** K -a * ft- ft ft ft ft ft ft ft * ft ft ft ft formula 47S66 DATE. 03, '2'. S .* -- MSDS EFFECTIVE: 08/28/89 BY 1Q - SUPERSEDES MSDS OF:05/09/86 i. *- COF: 552202 w. INVOICE 533003 *. }.- CDS KEY: 0746998 ft ft ft ft * ft < ft H ft ft ft ft * <- ft ft ft ft ft j> -a ' -c DEAR CUSTOMER: IN COMPLIANCE WITH THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SAFA TITLE III/ SECTION 313;. FEDERAL HAZARD COMMUNICATIONS REGULATIONS (WHMIS ALT OSHA 2? CFR 1910. 1200) AND IN THE INTEREST OF INFORMED USE OF OUR PRODUCT :-E ARE PROVIDING YOU WITH THIS MATERIAL SAFETY DATA SHEET (MSDS). THIS MSDS WILL BE UPDATED REGULARLY TO REFLECT THE MOST RECENT I NFQRMaT C; IN OUR POSSESSION. PLEASE ENSURE THAT OBSOLETE MSDS SHEETS IN YOUR FILES FOR "HIS PART NUMBER ARE DISCARDED . WE THANH YOU FOR YOUR CONTINUED PATRONAGE AND LOOK FORWARD TO PROVIDING VQU WITH ADDITIONAL QUALITY PRODUCTS AND SERVICES. ,-ftftftftftftftft^-ft-s-ftftftftftft SECTION I - PRODUCT IDENTIFICATION -********-*-**,--ft*<- ART NUMBER: PRODUCT NAME. 92180 PREMIER ETP CUTTING FLUID AiERO TRADE NAME/SYNONYMS FTP CUTTING FLUID CHEMICAL FAMILY: AEROSOL, LUBRICANT -* * -a- ft *** ft ft ft ft ftftftftftft* ft SECTION II - HAZARDOUS INGREDI ENTS *ftft**ftftftftftft ft ft ft ft ft ft ft ft ft * ft INGREDIENT ft-=ftftftftftft-a-ftft ft Sftftftftftftft s-ftft -a--* CAS NO. WT 7. TWA UNITS LC 50, PPM LD50,MG/KG ft ft ftftftftftft ft * ***** ftftftftft ftft-ftftftftftftft<- ftftftftftftftT>: - PETROLEUM OIL 64742-63-S SO--90 5 MG/M3 N/A PAT Ii3000 PAPA PO'"-C ISOBUTANE 00075-23-6 5 1000 PPM ML010000 N/A PROPANE 00074-93-6 5 1000 PPM ML010000 N/A INGREDIENTS TOTAL WT 7. ARE BELOW 1007. ONLY IF ALL OTHER 3 UNLISTED ARE >J1., ; CCNSIDERED HAZARDO US BY ANY FEDERAL (OSHA, WHMIS, S AR A) , ANY STAT tr - v. FROVINCE; OR LOCAL R IGHT-TO-KNGW REGULATIONS _____ _ SYMBOLS, ABBREVIATIONS AND NOTATIONS: rj/A=NOT AVAILABLE OR APPLICABLE, C=CEILING LIMIT, SISKIN DESIGNATION #=LISTED IN SARA TITLE III SECTION 313, *-IF FOUND AS DUST, MIST OR :UL M=HUMAN, RA3--RABBITS, GPG~GUINEA PIGS, MIC^MICE / I=INGE5TT0N/A=SKIN ABSORPTION,LD-LITTLE OBSERVABLE EFFECT,NO=NO EFFECT EL=0HA PERMISSIBLE EXPOSURE LIMIT, TLV=ACGIH THRESHOLD LIMIT. VALUE STEL-SHCRT TERM EXPOSURE LIMIT r"' SAL 000006822 ttfioev oApi 92180 PRODUCT NAME: PREMIER ETP CUTTING FLUID AERO PAGE 2 OF ********************* SECTION III - PHYSICAL DATA ************************* ILING PT DEG F/C: -44F / -42C SPECIFIC GRAVITY:0.93 VAPOR PRESSURE (MM HG):4. 7 ATM '/.VOLATILE VOLUME: 10 VAPOR DENSITY(AIR=1):1.6 EVAPORATION RATE: <WATER"1) :i SOLUBILITY IN WATER: NIL WATER/OIL DIST COEFF:Q APPEARANCE AND ODOR: TAN LIQUID, PETROLEUM ODOR. PHYSICAL STATE: LIQUID,AEROSOL FREEZE PT DEG F/C. N/A OTHER:N/A THRESHOLD ODOR,PPM: N/A PH N/A *****-****#****>** SECTION IV -- FIRE AND EXPLOSION HAZARD DATA CLASSIFICATION: FLAMMABLE AEROSOL NFPA RATING: 1,4,0 COMBUSTION PRODUCTS: CO, C02 FLASH POINT DEG F/C: -40F / -40C LELY.: 1 UEl_ */.. 9 EXTINGUISHING MEDIA- C02, DRY CHEMICAL FOAM. UN/NA/PIN#: UN1954 SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING EQUIPMENT. AUTO IGN. TEMP DEG F/C: 700F / 371C UNUSUAL FIRE AND EXPLOSION HAZARD EXPOSURE TO FIRE, HEAT OR PROLONGED SUNLIGHT MAY CAUSE BURSTING. IF USED IN CONFINED SPACES, HAZARDOUS VAPORS MAY SPREAD OR BUILD UP IN LOT AREAS. EXPLOSIVE POWER: HIGH IMPACT SENSITIVE: NO BURNING RATE: HIGH STATIC SENSITIVE: NO -s-* ******* * -a- *##** SECTION V - HEALTH HAZARD DATA ***#-*****-*** a-#**-**-*-* >-* PRODUCT GUIDE:TLV 5 MG/M3 - OIL MIST STEL: 5 MG/M3 ROUTES OF ENTRY: EYE,INHALATION EFFECTS OF OVEREXPOSURE: ACUTE: YES EYE IRRITATION CHRONIC: YES LUNGCONGEST 4USES EYE IRRITATION. VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC AND IRRITATE UPPER RESPIRATORY SYSTEM. EXCESS INHALATION MAY CAUSE DIZZINESS, GIDDINESS, AND NAUSEA. MISUSE OR DELIBERATE INHALATION MAY BE HARMFUL OR FATAL. PROLONGED AND REPEATED INHALATION MAY BE HARMFUL TO RESPIRATORY system LISTED AS A SUSPECTED CARCINOGEN: NO EMERGENCY AND FIRST AID PROCEDURES: EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MIN. & CALL PHYSICIAN. SKIN: WASH THOROUGHLY WITH PLENTY OF WATER SOAP. INHALATION: IF AFFECTED, REMOVE TO FRESH AIR. INGESTION; SEEK PHYSICIAN IMMEDIATELY, SHOW MSDS OR LABEL, DO NOT INDUCE VOMITING. *-*-*-**-a-**#*-a-******a-* SECTION VI - REACTIVITY DATA STABLE: YES CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, SPARKS, FLAMES, OR SOURCES OF IGNITION, INCOMPAT IBILITY < MATER IALS TO AVOID): YES STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: YES CO- PYROLYSIS PRODUCTS HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: M/A ^*****-*************- SECTION VII - SPILL OR LEAK PROCEDURES ***** * *## * ** -* * LISTED IN: SARA TITLE III, #302. NO #304,CERCLA: NO #333: NO STEPS ;C BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: IN CASE OF SPILL: REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA. CLEAN UP WITH ABSORBENT MATERIAL. CONTAIN AND PICK-UP WASTE MATERIALS PUT IN A SEALED APPROVED CONTAINER. REPORT QUANTITY, LB: N/A KG; N/A 'GULATIONS: WHMIS, RCRA ZARD WASTE; FLAMMABLE, AEROSOL TPQ, LB: N/A OTHER: N/A NO. DOG 1 DISPOSAL METHOD. DISPOSE GF WASTES IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS DO NOT PUNCTURE, INCINERATE (OR BURN) CONTAINERS. 5 SAL 000006823 . . C S 5 80 PART: 92180 PRODUCT NAME: PREMIER ETP CUTTING FLUID AERO PAGE 3 OF 2 ******* SECTION VIII - SAFE HANDLING AND PROTECTION INFORMATION *********** RESPIRATORY PROTECTION: USE ONLY IN WELL VENTILATED AREAS. C rILAT ION-LOCAL; RECOMMENDED MECHANICAL: REQUIRED SPECIAL: N/A OTHER: N/A PROTECTIVE GLOVES: SOLVENT RESISTANT GLOVES EYE PROTECTION: SAFETY GOGGLES OTHER PROTECTIVE EQUIPMENT IF VENTILATION IS INADEQUATE, WEAR APPROVED RESPIRATORY EQUIPMENT. ESTIMATED LD50, MG/KG: YES ORAL (RAT) 1SOOO, ABSORPTION (RABBIT) 2000 ESTIMATED LC50, PPM: NO SENSITIZATION: NO IRRITANT: NO SYNERGISTIC AGENTS: NO ****************** * SECTION IX - SPECIAL PRECAUTIONS ********************** ** PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: KEEP IN A COOL PLACE. KEEP AWAY FROM HEAT, SPARKS, FLAMES, OR SOURCES CF IGNITION. AVOID PROLONGED OR REPEATED BREATHING OF GAS, FUMES, VAPOR OR SPRAY MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WASH THOROUGHLY AFTER USING. OTHER PRECAUTIONS: DO NOT PUNCTURE, INCINERATE (OR EURN) CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ALWAYS READ AND FOLLOW DIRECTIONS ON PRODUCT LABEL. IN CASE OF ACCIDENT OR ILLNESS, SEEK PHYSICIAN IMMEDIATELY, SHOW LABEL OR MSDS. ADDITIONAL TECHNICAL DATA SHEETS AND/OR MATERIAL SAFETY DATA SHEETS (MSDS) ARE AVAILABLE UPON REQUEST. FOR PROFESSIONAL AND INDUSTRIAL USE ONLY. T, , INFORMATION AND RECOMMENDATIONS PROVIDED HEREIN ARE BELIEVED TO BE ACC:=ATr AS OF THE DATE HEREOF. HOWEVER, SUCH INFORMATION AND RECOMMENDATIONS ARE VIDED WITHOUT WARRANTY OF ANY KIND AND PREMIER INDUSTRIAL CORPORATION DECLAIMS ANY AND ALL LIABILITY GR LEGAL RESPONSIBILITY FOR USE OR RELIANCE Ur ON SAME. 00000682. A SAL sn MAY 1 8 1990 .Material Safety Data Sheet ay be used to comply with .jSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be f* A A tZ E consulted for specific requirements. V ft V IDENTITY (As Use^onJ-abp^atKl & 375 U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved OMB No. 1218-0072 Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Section i Manu'oclure^toms mcORpopATED Address tNumber, Street. Gty. State, and ZIP Code) P.O. BOX 412 SEA GIRT, NEW JERSEY 08750 Telephone Number for Information (201) 688-0303 Date Prepared Mav 15, 1990 Signature of Preparer (optional) USA Section II -- Hazardous Ingredienlsfldentity Information Hazardous Components (Specific Chemical Identity; Common Name(s)) Other Limits OSHA PELACGIH TLVRecommended______________ % (optional) ALUMINA HYDROXIDE non-soluble platinum salt 10mg/m3 dust Smg/m-* rispirable dust less than 99.5 0.5 CAS Registry Numbers for: Alumina Silicate - 1335-30-4 __________________ ______________________ Platinum - 7440-06-4 Section III -- Physical/Chemical Characteristics Boiling Point N/A c Specific Gravity (H2O - 1) 1.0., ...... Vapor Pressure (mm Hg.) N/A Melting Point ,, * ' U'/-' : [ > N/A Vapor Density (AIR = 1) N/A Solubility in Water NIL Appearance and Odor _________________________white powder, odorless Evaporation Rale (Butyl Acetate - 1) N/A J Section IV -- Fire and Explosion Hazard Data Flash Point (Method Used) non-flairmable material Flammable Limits N/A LEL N/A UEL Extinguishing Media non-flamrable material special Fire Fighting Procedures non- flairmable material___________________________________________________ SAL 000006825 N/A ___ Unusual Fire and Explosion Hazards MOT APPLICABLE. THIS IS AN INERT MATERIAL AND Inrallv) WILL NOT PRODUCE A DUST EXPLOSION. ocua 17<j 19R? C A055 action V -- Reactivity Data Stability Unstable Conditions to Avoid Stable XX Incompatibility (Materials to Avoid) N/A N/A < Hazardous Decomposition or Byproducts Hazardous Polymerization May Occur Will Not Occur Conditions to Avoid XX N/A N/A Section VI -- Health Hazard Data Routes) of Entry: Inhalation? YES Skin? NO Health Hazards (Acute and Chronic) UIL'B af MWOWi Ryaial lxrtutleni mi loon ioig-taa M* * Frsical irrltMloi it >t:ih id Urv* m\u el Aat. GSS' *> nW mi tinuatm. P*wxnoi My Mm ttmicel * *W* "a1 tnot> IWa eeorui U rl ~I 1.lull ! e Ohtft M "**" rot erafaae erfanlc diaeeae or nln llftn wit* re.iMil. -vmna. wannn w> hmrt toil eimim, Carcinogenicity: NTP? IARC Monographs? Ingestion? YES 0SHA Regulated? I Signs and Symptoms of Exposure EYES: ledical Conditions jeneralfy Aggravated by Exposure physical irritation. ANY LUNG DISORDER INHALATION: coughing Emergency and First Aid Procedures ---------------------------------------------" BCBBtCT fMD FIRST AID pfocedueeS* PfESi Flush with large arounts of water for at least 15 minutes. If irritation occurs, seek medical aid. SKDT; Flush with water. INHALATION: If exposed to excessive mounts, remove to tresh air. INC2ST1CN: Seek Medical Aid. Section VII -- Precautions for Safe Handling and Use Steps to Be Taken in Case Material Is Released or Sptfled MATERIAL SHOULD BE PICKED UP AND PLACED IN DRUMS, BINS, OR OTHER APPROPRIATE CONTAINERS. Waste Disposal Method MAY BE DISPOSED OF IN A LANDFILL ACCORDING TO LOCAL, STATE - AND "REGULATIONS, " Precautions to Be Taken In Handling and Storing . NO SPECIAL PRECAUTIONS NECESSARY N/A Other Precautions c Section VIII -- Control Measures Respiratory Protection (Specify Type) NIOSH .proved air-purifying dust respirator Ventilation Local Exhaust Special N/A Mechanical (General) M3CHANICAL VENILATI0N SHOjJ TtPther RF USED TO CrWTRDT, DUST TRVRTR IN ENCLOSED AREAS._____________________ Protective Gloves .. , NOT NEEDED Eye Protection CHEMICAL GOGGLES Other Protective Ctothinq^Eq^mtwl ^ ^ Work/Hygienic Practices NQ SPECIAL PRECAUTIONS NEEDED. Page 2 SAL 000006826 SZ MM wn IS IMZD W TOST MB D3THXDCT WICH DTTOK7I (EJIVO P*Tr mo w* arpuiE rot mkos ckly. onrsoa msoaim mm-umiutt to* was or nuw wua nau noi nr isz or nc mac mac ha mb noiusb owmicd Mien sun. cosmvB uumukito, wjwmf (Kuouc wnwn v njotwAinm) o> nnrsD/ntnot (itntonc rroxo< nm pmwt UMium bt Dnoaa mi xspict to nr ot. w* ir-wct rcnm, w sin crrm; r. r.*i. ir *iit pyjai is r- .* fat Mfr cn VT t 1990 material Safety Data Sheet be used to comply with lA's Hazard Communication Standard, 29 CFR 1910,1200. Standard must be ^ .r consulted for specific requirements. VA 0 55 IDENTITY (As Used on Label and Ust}n COP-850 & 550 & 375 U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved 0MB No, 1218-0072 * Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to irxfcate that. Section 1 Manufacturer's Name INTERCAT INCORPORATED Eme'9fKi1flcg',-W' Address (Number. Street. City. State, and ZIP Code> P.O. BOX 412 SEA GIRT, NEW JERSEY 08750 Telephone Number tor Information (201) 688-0303 Dale Prepared May 15, 1990 Signature of Preparer (optional) USA Section II -- Hazardous Ingredlenls/ldentlty Information Hazardous Components (Specific Chemical Identity; Common Name(s)) Other Limits OSHA PELACGIH TLVRecommended______________ % (optional) ALUMINA HYDROXIDE non-soluble olatinum salt 10mg/m3 dust Srrag/m^ rispirable dust less than 99.5 0.5 CAS Registry Numbers for: Alumina Silicate - 1335-30-4 ______________ ___________________Platinum - 7440-06-4___________________ Section III -- Physical/Chemical Characteristics Boiling Point N/A Vapor Pressure (mm Hg.) N/A Vapor Density (AIR - t) N/A Solubility in Water NIL Appearance and Odor _________________________ white pcwder, odorless Section IV -- Fire and Explosion Hazard Data Flash Point (Method Used) non-flanmable material Anguishing Media ron-f lantuable material Scv'-'al Rre Fighting Procedures e material Specific Gravity (H2O 1) Melting Point Evaporation Rate (Bufyt Acetate * 1) 1.0 N/A N/A Flammable Limits N/A LEL N/A UEL N/A ______________________ S4L 0ooo6e27 Unusual Fire and Explosion Hazards NOT APPLICABLE THIS IS AN INERT MATERIAL AND WILL NOT PRODUCE A DUST EXPLOSION OCHA f to-| iooc C A 0 55 tlon V -- Reactivity Data Stability Unstable Conditions to Avoid Stable XX Incompatibility (Meteriels to Avoid) Hazardous Decomposition or Byproducts Hazardous Polymerization May Occur Will Not Occur Conditions to Avoid XX N/A N/A N/A N/A Section VI -- Health Hazard Data Routefs) of Entry: Inhalation? YES Skin? NO Health Hazards (Acute end Chronic) et WPWOtMti flyileal itrltotloii a. Vnm tao ((u, P"' Wy cut I*vle4l IrTlutlOT If t ; If ----T ^t- EEB' * iwwal tkoaiMa. twunai n (m. i^yUeai v Wc fM^Uttary Thli huui i. cliittl t mlwn *-- ^ M *** *-- l<piflcM ec^Wc Hun or *"" PQSWttli Ms haiAxd tcidar mil clnnma, vitfe Carcinogenicity: NTP? IARC Monographs? Ingestion? YES OSHA Regulated? Signs and Symptoms of Exposure EYES:- 'ical Conditions totally Aggravated by Exposure physical irritation. ANY LUNG DISORDER INHALATION: coughing Emergency and First Aid Procedures emjcency wd first aid preXBXBCSt Brest Plush with large anounts of water for at least IS minutes. If irritation occurs, seek medical aid. SKIN: Flush with ------------------------------------------------------------------- water. XNHALAT1CN: If exposed to excessive amounts, rertrve to fresh air. INGESTICN: Seek Mailcal Aid. Section VII -- Precautions for Safe Handling and Use Steps to Be Taken in Case Material Is Released or Spilled MATERIAL SHOULD EE PICKED UP AND PLACED IN DRUMS, BINS, OR OTHER APPROPRIATE CONTAINERS. Waste Disposal Method MAY BE DISPOSED OF IN A LANDFILL ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. Precautions to Be Taken In Handling and Storing NO SPECIAL PRECAUTIONS NECESSARY N/A Other Precautions Sec'lon VIII -- Control Measures Respiratory Protection (Specify Type) NIOSH ^proved air-purifying dust respirator Ventilation Local Exhaust Special N/A Mechanical ('Genera/} MECHANICAL VENILATION SHOl ITOther BF. USED TO CONTROL DUST LEVELS IN ENCI/OS ED AREAS.________________ Protective Gloves _NO_T N...E...E..DED Eye Protection CHEMICAL G0GGT.ES _______ __ Other Protective Ctothing^Equipment. Work/Hygienic Practices ^ gpECiAL PRECAUTIONS NEEDED. Page 2 SAL 000006828 wnoe uueatbsdtuxubisrcw*> aDiwvmnatMwektpwkbieas aoc*r..tusmnuci udiksouasiwdjhj ixnaiurr kgmwmcntozaofnlt&intxwwamlluaoinhnsuuaj ancoxmTmwoibB, ciwrnwenwimdciiepiccwuJnMwfeiTtoonr tsc lOQiWMiun) ca mesriMiCM lanuac nnaM nrn pt>t uuiLiin ar amxxi vnv xsrcrr to rx cua. tx neon rcrmti, cn mei* aa ra* hh Wrmc r3i ir tsa* mot n nrv* y 1 h RITERION CATALYSTS MATERIAL SAFETY DATA SHEET M8D8 NUMBER : 6145-04 REVIEW DATE : November 14, 1989 24 HOUR EMERGENCY ASSISTANCE CRITERION: 800-777-6076 (IN USA) CRITERION: 713-863-3942 (GLOBAL) CHOCTREC: 800-424-9300 ON USA) CAM/TEC: 613-996-6666 (CANADA) GENERAL USDS ASSISTANCE CRITERION: 7T3-B74-2600 HEALTH 2 FIRE 0 REACTIVITY 0 LEAST-0 HAZARD RATING : M00ERATE-2 EXTREME-4 C A 056 For acute and chronic health effects refer to Section IV SECTION I NAME PROOUCT CHEMICAL NAME CHEMICAL FAMILY CRITERION 344 CATALYST C-344 METAL OXIDE CRITERION PROOUCT COOE CRITERION FILE NUMBER PRODUCT USE SECTION II-A HO. COMPOSITION 55096 40706145 55095 40706146 55101 40706144 REFINERY PROCESSING PRODUCT/INGREDIENT CAS NUMBER P CRITERION 344 CATALYST MIXTURE 1 ALUMINUM OXIDE (ALUMINA) ' **23 2 MOLYBDENUM OXIDE MoO, 3 COSALT OXIDE * CoO 4 PHOSPHOROUS OXIDE - PjOj 1344-28-1 1313-27-5 1307-96-6 1314-56*3 PERCENT 100 BALANCE 15 3 5 SECTION NO. II-B SARA TITLE III AND CERCLA SARA HI EHS RQ (lbs) (*1> SARA HI EHS TPQ (lbs) (*2) SARA III 311/312 CATEGORIES <*3) INFORMATION SARA HI SECTION 313 t*4) CERCLA 0 (lbs) (*5) 1 ai2o3 2 MoO, 3 CoO 4 P2Oj 1 H-1 H-1 H-1, H-2 10 YES YES YES, COBALT COMPOUNDS SPENT C-344 H-1, H-2, P-3 *1 REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE UNOER SECTION 302 2 THRESHHOLD PLANNING QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE UNDER SECTION 302 *3 HAZARD CATEGORY FOR SECTION 311/312 REPORTING: HEALTH H-1 IMMEDIATE (ACUTE) HEALTH KA2AR0 H-2 * DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 FIRE HAZARD P-4 * SUDDEN RELEASE OF PRESSURE HAZARD P-5 * REACTIVE HAZARD *4 TOXIC CHEMICAL UNDER SECTION 313, CATEGORY AS REQUIRED UNDER SECTION 313 (40 CFR 372.42). *5 REPORTABLE QUANTITY OF HAZARDOUS SUBSTANCE UNDER CERCU 1 SAL 000006829 CA056 SECTION MO. II-C ACUTE ORAL LD5Q (e/kg) P C-344 SPENT C-344 >5000 <RAT}* >5000 (RAT) ACUTE TOXICITY DATA ACUTE DERMAL LDSO (C/kg) PRODUCT IMC: OtlTEXiai 344 CATALYST RSDS WO. 6145-04 ACUTE INHALATION LCSO (e/K3) >1000 (RAT}* >1000 (RAT) >746 (RAT - 4 NR}* >746 (RAT - 4 HR) SECTION III WHMIS INFORMATION ACCORDING TO CRITERION'S UNDERSTANDING, THIS PRODUCT (C-344) IS CLASSIFIED UNDER HAZARDOUS MATERIALS INFORMATION STSTEM (WHNIS) AS: POISONOUS AND INFECTIOUS CUSS D DIVISION 2, SUBDIVISION I. FOR SPENT CRITERION 344 CATALTST, THE VHMJS CUSS 1FICAT ION IS: POISONOUS AND INFECTIOUS CUSS D DIVISION 2, SUBDIVISION B. FLAMMABLE AND COMBUSTIBLE CLASS , DIVISION 6. THE CANADIAN WORKPLACE SECTION IV HEALTH INFORMATION THE HEALTH EFFECTSMOTEcT BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD <29 CFR 1910.1200). ETE CONTACT PRODUCT MAT BE MILDLY IRRITATING TO THE EYES. SKIN CONTACT PROOUCT HAT BE MILDLY IRRITATING TO THE SKIN. 1NHAUTIQN THIS PROOUCT KAY CAUSE IRRITATION TO THE NOSE, THROAT AND RESPIRATORY TRACT. SENSITIZATION BASED ON COMPONENT 3 (COBALT OXIDE). KAY PRODUCE LUNG DAMAGE AND/OR INGESTION GENERALLY CONSIDERED TO HAVE A LOU ORDER OF ACUTE ORAL TOXICITY. SIGNS AW SYHPTCFtS IRRITATION AS NOTED ABOVE. LUNG DAMAGE KAY BE EVIDENCED BY SHORTNESS OF BREATH, ESPECIALLY ON EXERTION, AND KAY BE ACCOMPANIED BY CHRONIC COUGH. LUNG SENSITIZATION l.G. AUERGY, ASTHMA) HAY BE EVIDENCED BY WHEEZING WITH SHORTNESS OF 8REATK AND COUGH. AGGRAVATED MEDICAL COKHTIONS PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS KAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. IMPAIRED LUNG FUNCTION(S) FROM PREEXISTING DISORDERS MAT BE AGGRAVATED BY EXPOSURE TO THIS PROOUCT. PREEXISTING SKIN OR LUNG ALLERGIES KAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOSURE TO THIS PROOUCT. OTHER HEALTH EFFECTS NO ftEPONTS OF HEART TOXICITY HAVE BEEN ASSOCIATED WITH THIS PRODUCT, HOWEVER, COBALT IS lOiOIM TO CAUSE HEART TOXICITY (HYOCAROIOPATHY), WHICH MAY BE EVIDENCED BY EDEMA (SWELLING OF THE FEET) AND SHORTNESS OF BREATH ON EXERTION OR WHEN LYING SUPINE (ON THE BACK, WITH FACE UPWARD). SECTION V OCCUPATIONAL EXPOSURE LIMITS MO. OSHA TRANSITIONAL FINAL RUL# LIMIT/PEL LIMIT/TUA (bq/K3) (a/M3) ACOIN TLV/TUA TLV/STEL <9/K3> (*8/K3) OTHER 1 Al^ 2 HoOj 3 CoO 15 5 15 5 0.1 10 5 10 5 0.05 10 10 0.05 TOTAL DUST RESPIRABLE FRACTION INSOLUBLE COMPOUNDS, TOTAL DUST INSOLUBLE COMPOUNDS, RESPIRABLE FRACTION AS Co COMPLIANCE WITH TRANSITIONAL LIMITS REOUJRED BT ADMINISTRATIVE OR ENGINKER1NG CONTROLS ONLY, UNTIL 12/31/92. " COMPLIANCE WITH FINAL RULE LIMITS BY ANY COMBINATION OF ENGINEERING CONTROLS, WORK PRACTICES ANO PERSONAL PROTECTIVE EOU1PM6NT UNTIL 12/31/92. STARTING 1/1/93, THE FINAL RULE LIMITS MUST BE MET BY ADMINISTRATIVE OR ENGINEERING CONTROLS ONLY. 2 SAL 000006830 C A056 PRODUCT KANE: CRITERION 3tt CATALYST ~ USDS NO. 6145-04 SECTION VI EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH PLENTY OF WATER FOR IS MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT REMOVE CONTAMINATED CIOTHING/SHOES AND WIPE EXCESS FROM SKIM. SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. FLUSH SKIN WITH WATER. FOLLOW BY WASHING WITH DO NOT REUSE CLOTHING UNTIL CLEANED. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION DO NOT INDUCE VOMITING. DO NOT GIVE IIOUIDS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE. GIVE LARGE QUANTITY OF WATER. IF VOMITT1NG OCCURS, REPEAT LIQUID ADMINISTRATION. GET MEDICAL ATTENTION IMMEDIATELY. SECTION VII SUPPLEMENTAL HEALTH INFORMATION IN ONE LIFETIME INHALATION STUDY, COBALT-EXPOSED HAMSTERS DEVELOPED PNEUMOCONIOSIS; ADDITIONALLY, THERE WERE NO INCREASES IN TUMORS. STUDIES CONDUCTED ON GUINEA PIGS HAVE DETERMINED THAT SIMILAR CRITERION CATALYSTS TO C-344 ARE NOT SKIN SENSITIZERS. HOWEVER, SOME INDIVIDUALS KAY BE SUSCEPTIBLE TO COBALT SENSITIZATION. SECTION VIII PHYSICAL DATA BOILING POINT: APPROX. 4000 (DEG F) SPECIFIC GRAVITY: NOT APPLICABLE (H20*l) MELTING POINT: APPROX. 3700 (DEG F) SOLUBILITY: APPROX. 5X (IN WATER) EVAPORATION RATE (N-BUTYL ACETATE s 1): NOT SIGNIFICANT APPEARANCE AND OOOR: BLUE-GREY, CYL INDER-SKAPED EXTRUDATES. NO OOOR. VAPOR PRESSURE: NOT SIGNIFICANT (MM HG) VAPOR DENSITY: NOT APPLICABLE (AIR=1) BULK DENSITY = 0.70 G/CC SECTION IX FIRE AND EXPLOSION HAZARDS FLASH POINT METHOD: WILL NOT BURN. (SEE BELOW) FLAMWBLE LIMITS /X VOLUME IN Alt LOWER: N/AP UPPER: N/AP EXTINGUISHING MEDIA AS PRODUCED, WILL NOT CHEMICAL OR COj. BURN. IF REDUCED (SPENT) CATALYST IS INVOLVED IN A FIRE, USE WATER FOG, FOAM, DRY SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS WILL NOT BURN. WEAR FUU PROTECTIVE CLOTHING AND A CATALYST IS IN FIRE AREA. NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IF UNUSUAL FIRE AND EXPLOSION HAZARDS AS PRODUCED, THE CATALYST WILL NOT BURN. HOWEVER, IN USE, THE CATALYST IS REDUCED AND SULFIDED. THE REDUCED FORK, ESPECIALLY WHEN WARM, REACTS WITH OXYGEN ON CONTACT WITH AIR. ENOUGH HEAT CAN BE PRODUCED TO BURN COKE OR RESIDUAL ORGANIC MATERIAL LEFT ON THE CATALYST, AND COULD IGNITE FLAMMABLE MIXTURES WHICH IT KAY CONTACT. TO PROTECT AGAINST THIS POSSIBILITY, SPENT CATALYST SHOULD BE OXIOIZEO AND COOLED BEFORE REMOVING IT FROM THE REACTOR. OTHER MEASURES, SUCH AS COOLING AND BLANKETING WITH NITROGEN OR WATER WETTING THE CATALYST MAY ALSO BE USED 10 RETARD OXIDATION. SAL 000006831 3 C A056 8ECTION X STABILITY: STABLE HtOXJCT MANE: CRITERIC** 3U CATALYST KSDS SO. 6M5-OG REACTIVITY HAZARDOUS POLYMER IZAT ION: VIIL MOT OCCUR SECTION XI EMPLOYEE PROTECTION RESPIRATORY PROTECTICM USE A M1 OSH - APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IM ACCORD WITH 29 CFR ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR PARTICULATES. 1910.134, USE EITHER AN PROTECTIVE CLOTHING AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR GLOVES AND OTHER CLOTHING AS REOUIRED TO MINIMIZE CONTACT. ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION*PROOF VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS. SECTION XII ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES WEAR NIOSH APPROVED RESPIRATOR WHEN DUST LEVELS EXCEED OCCUPATIONAL EXPOSURE LIMITS. WEAR CLOVES, GOGGLES AND PROTECTIVE CLOTHING TO CONTROL EXPOSURE TO BOOT SURFACES. DO NOT DRY SWEEP OR USE HETHCCS WHICH INCREASE DUSTING. USE VACUUMING OR SWEEPING COMPOUHO FOR CLEAN-UP. DO NOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER SYSTEMS. WASTE DISPOSAL UNDER EPA - RCRA (40 CFR 261.21), SPENT UNREGEMERATED CATALYST IS A WASTE MATERIAL, IT COULD BE AN IGNITABIE HAZARDOUS WASTE, HAZARDOUS WASTE NUMBER D001. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. ENVIRONMENTAL HAZARDS DO NOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER STSTEMS. 8ECTI0N XIII SPECIAL PRECAUTIONS DO NOT EAT, DRINK OR SMOKE IN AREAS WHERE CATALYST IS PRESENT. WASH HANDS THOROUGHLY AFTER HANDLING. KEEP CONTAINERS CLOSED WHEN NOT IN USE. NOTIFY AUTHORITIES IF MATERIAL THREATENS TO ENTER OR ENTERS INTO SEWER OR PUBLIC WATER SYSTEM. ALL PRECAUTIONS GIVEN FOR FRESH CATALYST SHOULD BE OBSERVED FOR SPENT CATALYST ANO WASHINGS. SECTION XIV___________ TRANSPORTATION REQUIREMENTS________ DEPARTMENT OF TRANSPORTATION CLASSIFICATION: FRESH CATALYST NOT HAZARDOUS BY DOT REG* OTHER REQUIREMENTS: * SPENT CATALYST ONLY - FLAMMABLE SOLID N.O.S. UN1325. ^ 0000683* SECTION XV PRODUCT KMC: CSITER10N 344 CATALYST C A056 KSDS MO. 6145-04 OTKER REGULATORY CONTROL8 THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. THE INFORMATION CONTAINED HEREIN 1$ BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, CRITERION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, RECARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. CRITERION ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PROOUCT DESCRIBED HEREIN. SECTION XVI SUMMARY OF REVISIONS USDS NLN8ER 6145-01 6145-02 6145-03 6145-04 DATE NATURE OF REVISIONIST JANUARY 18, 1989 ORIGINAL ISSUE MAY 15, 1989 ADD NEW OSHA TRANSITIONAL AND FINAL RULE EXPOSURE LIMITS. ADD SECTION XVI SUMMARY OF REVISIONS. ADO REVIEW DATE TO TOP OF PAGE 1. CORRECT TYPO IN CAS NUMBER FOR COBALT OXIDE TO 1307-96-6. JUNE 23, 1989 ADD PRODUCT COOE NUMBERS TO MSDS. November 14, 1989 ADD CERCLA INFORMATION TO SECTIONS 11B AND XII WHERE APPROPRIATE. CHANGE PRODUCT CODE NUMBERS (DROP 93'S AND REVIEW DATE: November 14, 1989 v^OwaJleS. ^ c.oonaid McCulloch TECHNICAL DIRECTOR CRITERION CATALYST COMPANY L.P. OOOOO60*3 SM- CRITERION CATALYST COMPANY L.P. TWO CREENSPOINT PLAZA, SUITE 1000, 1W25 NORTHCHASE DR., HOUSTON, TEXAS 77060 5 o CRITERION catalysts MATERIAL SAFETY DATASHEET MSDS NUMBER i 6165-05 REVIEW DATE $ February 24, 1990 24 HOUR EMERGENCY ASSISTANCE ' ;:;;;ffiBEML-MSbS ASSISTANCE' OtiTERlON: 800-7774:6.0,76 (IN USA) OUTERIOI: 713-863-3942 (GLOBAL) OtEMT(tfCs600-4^^jKipO (IN USA*; l 'CAMUT6C:.613-6-6666 (CANADA) CKITLRKM; 713-674-2600 HEALTH 2 Ft R 0 REACTIVITY 0 HAZARD RATING LEAST-0 MCDEftATE-2 EXTREME-4 C A 0 57 * for cute and chronic health effect! refer to Sect fort IV SECTION 1 NAME " V'r~;:: P8Q0UCT CRITERION TRILOBE 447 CATALYST CHEMICAL NAME C~447 CHEMICAL FAMILY METAL OXIDE CRITERION PROOUCT CODE CRITERION FILE NUMBER prooucT USE ; SECTION ; II-A :.L': HO. CONDITION 55450 40706213 55460 40706165 55470 40706212 55455 REFINERY PROCESSING PRODUCT/ING REDIENT A CAS WJMBCR PERCENT P CRITERION TRI108E* 447 CATALYST MIXTURE TOO 1 ALUMINUM OXIDE (ALUMINA) * AUO, 2 M0LT80ENIM OXIDE - McO3 COBALT OXIDE - CoO 1344-29*1 13)3-27-5 1307*96-6 BALANCE 15.5 4.5 SECTION HO. II-B SARA TITLE III AND CERCLA SANA rif E.H8 M ((fat) <M> SAM III EHS TPQ (lb> <*2> SARA III 311/312 CATEGORIES <*3> INFORKATION SARA III SECTION 313 <n> 1 AUO, 2 *06, 3 CoO N* 1 N-1 H*1, H*2 YES YES, COBALT COMPOUNDS CERCLA RO (lbs) <*5> SPENT C-447 H-l. H-2, P*3 ........................................................................................... .. .................-FOOTNOTES*............................-........................*.......................................... *1 REPOSTABUE QUANTITY Of EXTREMELY HAZARDOUS SUBSTANCE UNDER SECTION 302 *2 THRESHOLD PLANNING GUAMTITY OF EXTREMELY HAZARDOUS SUBSTANCE UNDER SECTION 302 *3 HAZARD CATEGORY FOft SECTION 311/312 REPORTING; HEALTH H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD H*2 DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 - FIRE HAZARD P-4 SUDDEN RELEASE OF PRESSURE HAZARD P-5 - REACTIVE HAZARD 4 TOXIC CHEMICAL UNDER SECTION 313. CATEGORY AS REQUIRgO UNDER SECTION 313 (40 CFR 372.42). *5 REFUTABLE ttJANTITY OF HAZARDOUS SUBSTANCE UNDER CttClA 1 SAL 000006834 C A 0 57 ....Section :jt-c NO. ACUTE ORAL U50 WkS) P C-447 >9000 (RAT)* PKODUCT IWWCs CRITERION TRILONC***447 CATALYST USDS NO. 6165-OS ACUTE TOXICITY jOATA ACUTE DERMAL. LD50 (oAg) ACUTE INHALATION LC50 (a/K3) >1000 (RAT)* >74S (RAT 4 HR)* * BASED CM SIMILAR PRCOUCT TESTING. SECTION III ' WHHIO ACCORDING TO CRITERION'S UNDERSTANDING, THIS PftOOUCT (C447) IS CLASSIFIED UNDER THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) AS; POISONOUS AMO INFECTIOUS CLASS 0 DIVISION 2, SUBDIVISION 6. TOR SPENT CRITERION TRILOBE* 447 CATALYST, THE WHMIS CLASSIFICATION IS; POISONOUS AMD INFECTIOUS CLASS D DIVISION Z, SUBDIVISION B. ____________________________ FLAMMABLE AMO COMBUST I SIS CLASS 1, DIVISION 6._________________________ SECTION .'iy.:.:;-':;;:r--.-- HEALTH .INPOW4XTiON;;;;;::;-;'l'.;- ~ THE HEALTH EFFECTS NOTEO BELOW ARE CONSISTENT VIIH^RtauiBfeHENTS UNDER THE OSKA HAZARD COMMUNICATION STANDARD (29 CFR WTO.1200). EYE CONTACT PRODUCT HAY BE MILDLY IRRITATING TO THE EYES. SKIN CONTACT PRODUCT HAT BE MILDLY IRRITATING TO THB SKIN. INHALATION THIS PRODUCT MAY CAUSE IRRITATION TO THE NOSE, THROAT AMD RESPIRATORY TRACT. SENSITIZATION BASED OH COMPONENT 3 (COBALT OXIDE). MAY PROOUCE LUNG DAMAGE ANO/OR INGESTION GENERALLY CONSIDERED 10 HAVE A LOW ORDER OF ACUTE ORAL TOXICITY* SIGNS AK> SYMPTOMS IRRITATION AS NOTED ABOVE. LUNG DAMAGE MAY BE EVIDENCED BY SHORTNESS Of BREATH, ESPECIALLY ON EXERTION, AND MAT BE ACCOMPANIED BY CHRONIC COUCH. LUNG SEWSJT/2A7JON (F.fi. AllSRCT, ASTHMA) MAT BE EVIDENCED BY WHEEZING WITH SHORTNESS OF BREATH AMO COUGH. AGGRAVATHD MEDICAL CQMIITIQHS PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BT EXPOSURE TO THU PRCOUCT. IMPAIRED LUNG FUNCTIONS) FRCM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TQ THIS PRQOUCT. PREEXISTING SKIN OR LUNG ALLERGIES NAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOSURE TO THIS PRODUCT. OTHER HEALTH EFFECTS NO REPORTS OF HEART TOXICITY HAVE BEEN ASSOCIATED WITH THIS PRODUCT, HOWEVER, COBALT IS KNOWN TO CAUSE HEART TOXICITY (HYOCARD1OPATKT), WHICH HAT BE EVIDENCED BT EDEMA (SWELLING OF THE FEET) AND SHORTNESS OF BREATH ON EXERTION OR WHEW UINO SUPINE (ON THE BACK, WITH FACE UPWARD)* _________________________ ' SECTION V ~ OCCUPATIONAL EXPOSURE LIMITS - NO. OSKA TRANSITIONAL FINAL RUL^ LINIT/Pn LIKIT/TUA w> (8/*J) ACSIM TLV/TUA TLV/STEL (0/N3) (0/K5) OTHER 1 41A 2 HoOj 3 CcO 15 5 15 5 0.1 10 5 10 5 0.05 10 10 0.05 TOTAL DUST RESPIRABLE FRACTION INSOLUBLE COMPOUNDS, TOTAL DUST INSOLUBLE COMPOUNDS, RESPIRABLE FRACTION AS Co * COMPLIANCE WITH TRANSITIONAL LIMITS REQUIRED BY ADMINISTRATIVE OR CHGINNERIKG CONTROLS ONLY, UNTIL 12/51/92. ** COMPLIANCE WITH FINAL RULE LIMITS BY ANY COMBINATION OF ENGINEERING CONTROLS, WORK PRACTICES AND PERSONAL PROTECTIVE EQUIPMENT UNTIL 1Z/3T/92. STARTING 1/1/V5, THE FINAL KULt LIMITS MUST BE MET BY ADMINISTRATIVE OR ENGINEERING CONTROLS ONLY. SAL 000006835 2 SECTioK ,vi s C A 0 57 PftOXJCT NAME: CRITERION Tfltme* *47 CATALYST " 4165 " emergency amp TiMT aid procbdprbs ; EYE COKTACT FLUSH EYES WITH PLENTY OF WATER FOR T5 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION, SXIH CONTACT REMOVE contaminated clothinc/shoes and wipe excess FROM SKIN, SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. hush skin with water, follow BY washing uitn DO NOT REUSE CLOTHING UNTIL CLEANED. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION, INGESTION DO NOT INDUCE VOMITING. 00 NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS OR VERT DROWSY. OTHERWISE, GIVE LARGE QUANTITY OF WATER. IF VOMITTING OCCURS, REPEAT LIQUID ADMINISTRATION. GET MEDICAL ATTENTION IMMEDIATELY. ; SECT IOH VIX ^ flPPPLEHBKTAL HEALTH in^ORMATION :: -. IN ONE LIFETIME INHALATION STUDY, COBALT-EXPOSED HAMSTERS DEVELOPED PNEUMOCONIOSIS; ADDITIONALLY, THERE WERE NO INCREASES IN TUMORS. STUDIES CONDUCTED ON GUINEA PIGS HAVE DETERMINED THAT SIMILAR CRITERION CATALYSTS TO C*447 ARE NOT SKIN SENSU12ERS. HOWEVER, SOME INDIVIDUALS KAY BE SUSCEPTIBLE TO COSALT SENSITIZATION. ' SECTION VIII A PHYSICAL DATA .':V, ;V BOILING POINT: APPROX. 4000 (DEG F) SPECIFIC GRAVITY: NOT APPLICABLE (H0=1) MELTING POINT: APPROX. 3700 (DEC F> SOLUBILITY: APPROX. M (IN WATER) EVAPORATION RATE (K-BUTYL ACETATE * 1): NOT SIGNIFICANT APPEARANCE AND QOOR$ BLUISH-GREY, T* I LOSE*-SHAPED EXTRICATES. NO COON VAPOR PRESSURE: HOI SIGNIFICANT (MM HG) VAPOR DENSITY: NOT APPLICABLE (AIR*T) BULK DENSITY * 0.74 G/CC 8BCTioK IX - FIRS AND EXPLOSION HAZARDS FLASH POINT ICTtKfi: WIU NOT BURN. (SEE BELOW) FUWWBIC LIMITS ft VOLUME IN Alt LOWER: N/AP UPPER* N/AP EXTINOJ1SHJNG MEDIA AS PRODUCED, WILL NOT BURN. CHEMICAL OR C02. IF REDUCED (SPENT) CATALYST IS INVOLVED IN A FIRE, USE WATER FOG, FOAM, DRY SPECIAL | IRE FIGHTim PROCEDURES AK) PRECAUTIONS WILL NOT BURN. WEAR FULL PROTECTIVE CLOTHING AMD A HIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IF CATALYST IS IN FIRE AREA. UNUSUAL PULE A*> EXPLOSION HAZARDS AS PRODUCED, THE CATALYST WILL NOT BURN. HOWEVER, IN USE, THE CATALYST IS REDUCED AND SULFIDED. THE REDUCED FORM, ESPECIALLY WHEN WARM, REACTS WITH OXYGEN QN CONTACT WITH AIR. ENOUGH HEAT CAN BE PRODUCED TO BURN COKE OR RESIDUAL ORGANIC MATERIAL LEFT ON THE CATALYST, ANO COULD IGNITE FLAMMABLE MIXTURES WHICH IT MAY CONTACT. TO PROTECT AGAINST THIS POSSIBILITY, SPENT CATALYST SHOULD SE OXIDIZED ANO COOLED BEFORE REMOVING IT FROM THE REACTOR. OTHER MEASURES, SUCH AS COOLING AND BLANKETING WITH NITROGEN OR WATER WETTING THE CATALYST HAY ALSO BE USEO TO RETARD OXIDATION. SAL 000006836 3 SECTION ' t;:-:^1/ STABILITY: STABLE C A 0 57 PRODUCT IWt: CRITERIA** TKU-CSC* 7 CATALYST HSPS NO. 6165-OS " : > rv>- REACTIVITY BA2AKD0US PGLYMEJUZATION: WILL NOT OCCUR SECTION XI EMPLOYEE PROTECTION RESPIRATORY PROTECTION USE A NIOSH*APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134, USE EITHER AN ATMOSPHERE * SUPPLYING RESPIRATOR OR AN AlR-PURtPYIMG RESPIRATOR FOR PARTICULATES. PROTECTIVE CLOTHING AVOID PROLONGED OR REPEATED CONTACT WITH SUN. WEAR CLOVES AND OTHER CLOTHING AS REQUIRED TO MIMIMI2E CONTACT. ADOniCMAL PROTECTIVE MEASURES USE EXPLOSION*PROOF VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS. SECTION XII 'f f. ENVIRONMENTAL PROTECTION SPILL C L&AT PROCEDURES WEAR NJOSH APPROVED RESPIRATOR WHEN OUST LEVELS EXCEED OCCUPATIONAL EXPOSURE LIMITS. WEAR GLOVES, GOGGLES AND PROTECTIVE CLOTHING TO CONTROL EXPOSURE TO BOOT SURFACES, DO NOT DRY SWEEP OR USE METHCOS WHICH INCREASE OUSTING. USE VACUUMING OR SWEEPING COKPOUWO FOR CLEAN-UP. DO NOT WASH SPILLS INTO SEVERS OR OTHER PV8UC WATER SYSTEMS. WASTE DISPOSAL UNDER EPA RCRA <40 CFR 261.21), SPENT UNREGENERATED CATALYST IS A WASTE MATERIAL, IT COULD BE AN 1CNITABLE HAZARDOUS WASTE, HAZARDOUS WASTE NUMBER D001. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. ENVIRONMENTAL HAZARDS 00 HOT WASH SPILLS INTO SEWER5 OR OTHER PUBLIC WATER SYSTEMS. . ' sicTION XI11 * .___ SPECIAL ?ilECAUTIONfl;> DO NOT EAT, DRINK OR SMOKE IN AREAS WHERE CATALYST IS PRESENT. WASH HANDS THOROUGHLY AFTER HANDLING. KEEP CONTAINERS CLOSED WHEN NOT IN USE. NOTIFY AUTHORITIES IF MATERIAL THREATENS TO ENTER OR ENTERS INTO SEVER OR PUBLIC UA7ER SYSTEM. ALL PRECAUTIONS GIVEN FOR FRESH CATALYST SHOULD BE OBSERVED fOR SPENT CATALYST ANO WASHINGS. . SECTION XXV TRANSPORTATION REQCIREKEKTS_________ ___________ ; DEPARTMENT OF TRANSPORTATION CLASSIFICATION: FRESH CATALYST NOT HAZARDOUS BY DOT RES* OTHER REQUIREMENTS; * SPENT CATALYST ONLY - FLAMMABLE SOLID N.O.S. UNT325, SAL 000006837 C A 0 57P*eeucT names OtlTEKION TRIL08E* 447 CATALYST M5DS HO. 616505 8ECTION XV OTHER:REGULATORY COKTROL8 THE COMPONENTS OF THIS PRODUCT ATE LISTED OH THE EPVTSCA INVENTORY OF CHEMICAL SUBSTANCES. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US ANO IS BELIEVED TO BE CORRECT. HOWEVER, CRITERION HAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDINC THE ACCURACY OP THESE DATA OR THE RESULTS YO BE OBTAINED FROM THE USE THEREOF. CRITERION ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRCOUCT DESCRIBED HEREIN. SECTION ^ SClbti^ REVISIONS " '` MSDS NUMBER 6165-01 616502 6165*03 6165-04 6165-05 DATE NATURE OF REVISION'S) OECEMSER 26, 1986 ORIGINAL ISSUE MAY 14, 1989 ADO NEW OSKA TRANSITIONAL AND FINAL RULE EXPOSURE LIMITS. ADD SECTION XV! - SUMMARY OF REVISIONS. ADD REVIEW DATE TO TOP OF PAGE 1. CORRECT TTFO IN CAS NUMBER FOR COBALT OXIDE TO 1307-96-6. JUNE 23, 1989 ADD PROOUCT CODE 93552-05 TO HSOS, Novceber 14. 1989 ADO CERCIA INFORMATION TO SECTIONS 1IB AND XII WHERE APPROPRIATE. CORRECT PRCOUCT COOS 93552-05 TO 93554-55. CHANGE PRODUCT CODE NUMBERS (DROP 9V AND February 24, 1990 MOOIFT MSDS TO REFLECT OFFICIAL DELISTING CM FEBRUARY 14. 1990 OF NOtf-flBRCUS ALUMINUM OXIDE FROM SARA III SECTION 313 REPORTING LIST, review DATE: February 24, 1990 ^)owojleSl ^ DONALD C. MCCULLOCH TECHNICAL DIRECTOR CRITERION CATALYST COMPANY L.P. ^ 00006S38 CRITERION CATALYST COMPANY L.P, TWO GREENSP01NT PLAZA, SUITE 1000, 16825 NORTHCKASe d*., HOUSTON, tlxas 77060 5 RITERION CATALYSTS MATERIAL SAFETY DATA SHEET MSDS KtTMBBR t 6169-05 REVIEW DATE s rebinary 24, 1990 24 HOUR EMERGENCY ASSISTANCE . - -h:'GENERAL.'MOTS' ASSISTANGE ' dtlfsRicii:V800^777**-6076:<kMusa>chemirec: .oo-4^5W;xii:iJSArri: -plTERrORi 713-874-2606: CSI1ERICN: 713-86^59 42 (GLOBAL) :K':.:.CAiiuTi:: 613-996-^^ (CAW HEALTH Z FIRE 0 REACTIVITY 0 LEAST'S KA2ARD RATIKG : M00ERATE-2 EXTREME*4 C A 0 58 For jcute sod chronic hesUh effects refer to Section IV :: SECTION I"^v/- vV NAME PRODUCT CRITERION 544 CATALYST CHEMICAL NAME CHEMICAL FAMILY C-544 METAL OXIDE CRITERION PRCQUCT COTE CRITERION FILE NUMBER PRG0UCT USE SECTION II-A NO. COMPOSITION P CRITERION 544 CATALYST 352*0 40706170 35250 40706169 REFINERY PROCESSING PRODUCT/lNGREDIENT CAS NUMBER MIXTURE 1 ALUMINUM OXIDE (ALUMINA) - Al 23 Z MOLYBDENUM OXIDE - McO* 3 COBALT OXIDE COQ 1344*28-1 1313-27-3 1307-96-6 PERCENT 100 BALANCE 6 2.2 SECTION II-B T; SARA-TITlE III; AND CERCLA INTORMATION SARA 111 &ARA III SARA 111 SARA Hi HO. EHS fta (Iba) EH* TP <lbe) 311/312 CATEGORIES SECTION 313 <*1) <*2) <*3> () CE1CLA m ubs) c*s> 1 AU3 2 MoO, 3 coo H-1 H-1 H*1, H-2 TCS Tf$, COBALT COMPOUNDS SPENT C-544 H-1, *2. P*J .............................................................................................................................FOOTNOTES.............................................. -............*................................................ `1 RPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE IINOCR SECTION 302 *2 THRtSHHOLO PLANNING QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE UNDER SECTION 302 *3 HAZAM CATEGORY 10* SECTION 311/312 REPORTING; HEALTH -H-1 * IMMEDIATE (ACUTE) HEALTH HAZARD H'2 * DELATED (CHRONIC) HAZARD PHYSICAL P3 = FIRE HAZARD P~4 = SUDDEN RELEASE OF PRESSURE HAZARD P`5 REACTIVE HAZARD 4 TOXIC CHEMICAL UNDER SECTION 313, CATEGORY AS REQUIRED UNDER SECTION 313 (40 CfR 372.42). `5 REPORTABLE QUANT]7T OF HAZARDOUS SUBSTANCE UNDER CERCLA 0000b839 1 sM- ^SECTION II-C (as/kfl)HO. ACUTE ORAL LD50 p c-544 >5000 (RAT)* C A 0 58 PRODUCT NAMEi CRITERION 5*4 CATALYST MSOG HO. 6169-0$ ACUTE TOXICITY DATA ACUTE DERMAL U>?0 (AB/kfi) ACUTE INHALATION IC5Q (Q/M3) >1000 (RAT)* >748 (RAT - 4 HR)* BASED ON SIMILAR PRODUCT TESTING. SECTION ^ KwHMIS : INFORMATION -w :.'v: ACCORDING TO CRITERION'S UNDERSTANDING, THIS PRCOUCT (C*54) IS CLASSIFIED UNDER THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WMIS) AS: POISONOUS AND INFECTIOUS CLASS D DIVISION 2, SUBDIVISION B. FOR SPENT CRITERION 5*4 CATALYST, THE VHKiS CLASSIFICATION IS; POISONOUS AND INFECTIOUS CLASS D DIVISION l, SUBDIVISION 8. FLAMMABLE AwP COMBUSTIBLE CLASS B, DIVISION 6. SECTION IV 2 : ;: . HEALTH INPORkATION: J THE HEALTH EFFECTS NOTEO BELOW ARE CONSISTENT WITH REQU|RCHENT5 UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910,1200). EYE CONTACT PRODUCT MAY BE MILDLY IRRITATING TO THE EYES. SKIM CONTACT PRODUCT MAY BE MILDLY IRRITATING TO THE SKIN. INHALATION THIS PRODUCT HAY CAUSE IRRITATION TO THE NOSE, THROAT ANO RESPlAAtQRY TRACT. SENSITIZATION BASED ON COMPONENT 3 (COBALT OXIDE). MAY PRODUCE LUNG DAMAGE AND/OR INGESTION GENERALLY CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL TOXICITY. SIGNS ANO SYKPTCKS IRRITATION AS NOTED ABOVe. LUNG DAMAGE MAY BE EVIDENCED BY SHORTNESS OF BREATH, ESPECIALLY ON EXERTION, AKO MAY BE ACCOMPANIED Y CHRONIC COUGH. LUNG SENSITIZATION (E.G. ALLERGY, ASTHMA) MAY BE EVIDENCED BT WHEEZING WITH SHORTNESS OP BREATH AND COUGH. AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS HAY BE AGGRAVATED BT EXPOSURE TO THIS PROOUCf. IMPAIRED LUNG FUNCTION!5) FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PROOUCT. PREEXISTING SKIN OR LUNG ALLERGIES MAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FftCH EXPOSURE TO THIS PROOUCT. OTHER HEALTH EFFECTS NO REPORTS OF HEART TOXICITY NAVE BEEN ASSOCIATED WITH THIS PROOUCT, HOWEVER, COSALT IS KNOWN 10 CAUSE HEART TOXICITY (HYOCARDIOPAThY), WHICH HAY BE EVIDENCED BY EDEMA (SWELLING OF THE FEET) AND SHORTNESS OF BREATH ON EXERTION DR WHEN LYING SUPINE (ON THE BACK, WITH FACE UPWARD). SECTION V ' j OCCUPATIONAL EXPOSURE &IMIT8 OSHA ACGIH MO. TRANSITIONAL FINAL RUL^ TLV/TUA TLV/STEL LIMIT/PEL LIMIT/TUA <^/K3> C^X3> <^J/K3) OfllLR 1 Al23 2 MoOj 3 COO 15 $ 15 5 0.1 10 5 10 S 0.05 10 10 0.05 10TAL DUST RESPIRABLE FRACTION INSOLUBLE CCMPCXINOS, TOTAL DUST INSOLUBLE CCMPCUNDS, RESPIRABLE FRACTION AS Co COMPLIANCE WITH TRANSITIONAL LIMITS REQUIRED BY ADMINISTRATIVE OR ENGJNHERING CONTROLS ONLY, UNTIL 12/3I/9Z. COMPLIANCE WITH FINAL RULE LIMITS BT ANY COMBINATION OF ENGINEERING CONTROLS, WORK PRACTICES AND PERSONAL PROTECTIVE EQUIPMENT UNTIL 12/31/92. STARTING 1/1/93, THE FINAL RULE LIMITS MUSI BE MET BT ADMINISTRATIVE OR ENGINEERING CONTROLS ONLY. 2 sal 00006a4o ___________ W' v*V W A ** tfu W v* SECTION VI .. t AO 58 PRODUCT BANE; OUTERIC* 544 CATALYST **>* 61< EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH ETCS WITH PLENTY OF WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIM CONTACT REMOVE CONTAMINATED CLCTKING/SNOCS AND WIPE EXCESS FRCM SKIN. SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. FLUSH SKIN WITH WATER, FOLLOW ST WASHING WITH DO NOT REUSE CLOTHING UNTIL CLEANED. INHALATION REMOVE VICTIM TO FRESH AIR AMO PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET ME01CAL ATTENTION. INGESTION DO NOT lhDUCE VCMITING. DO NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE, GIVE LARGE QUANTITY OF WATER. IF VOMITTJNG OCCURS, REPEAT LIQUID ADMINISTRATION. GET MEDICAL ATTENTION IMMEDIATELY. SECTION VII / SUPPLEMENTAL HEALTH INFORMATION IN ONE LIFETIME INHALATION STUDY, C08AIT*EXPOSEO HAMSTERS DEVELOPED PNEUMOCONIOSIS; ADDITIONALLY, THERE WERE NO INCREASES IN TUMORS. STUDIES CONDUCTED ON GUINEA PIGS HAVE DETERMINED THAT SIMILAR CRITERION CATALYSTS TO C*544 ARE NOT SKIN SENSITIZERS. HOWEVER, SOME INDIVIDUALS MAY BE SUSCEPTIBLE TO COBALT SENSITIZATION. 1 SECTION VIII : / i PHYSICAL DATAyy.?~ J; v-''":v;.:. BOILING POINT: APPROX. 4000 (DEG f) MELTING POINT; APPROX. 3700 (05G F'j SPECIFIC GRAY1TY; NOT APPLICABLE (HZ0=1) S0LU81LI ITi APPROX. 5X (IN WATER) EVAPORATION RATE (N'BUTYL ACETATE 1); NOT SIGNIFICANT APPEARANCE AMO QDCR; BLUE SPHERES. NO GOOA. VAPOR PRESSURE: NOT SIGNIFICANT (MM MG) VAPOR DENSITY: NOT APPLICABLE <AIR1> BULK DENSITY = 0.82 G/CC SECTION IX: FI RE; AND EXPLOSION HAZARDS g/v: ~ Vi} : FLASH POINT METHOD: WILL NOT BURN. (SEE 8EL0W) HAHNASIE UNITS /X VOLUME IN AIR LOWER: N/AP UPPER: N/AP EXTINGUI SHING MEDIA AS PROOUCED, WILL NOT BURN. CHEMICAL OR COg. IP REDUCED (SPENT) CATALYST IS IWVOLVEO IN A FIRE, USE WATER FOG, FOAM, DRY SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS WILL HOT BURN. WEAR FULL PROTECTIVE CLOTHING AND A NIOSH APPROVEO SELF-CONTAINED BREATHING APPARATUS If CATALYST IS 1M FIRE AREA. UNUSUAL FIRE AW EXPLOSION HAZARDS AS PRCOU:ED, THE CATALYST WILL NOT BURN. HOWEVER, IN use, THE CATALYST IS REDUCED AND SULFIDED. THE SEDUCED MjRM, ESPECIALLY WHEN WARM, REACTS WITH OXYGEN ON CONTACT WITH AIR. ENOUGH HEAT CAN BE PROOUCEO TO BURN COKE OR RFSIDJAl ORGANIC MATERIAL LEFT ON THE CATALYST, AND COULD IGNITE FLAMMABLE MIXTURES WHICH IT MAY CONTACT. TO PROTECT AGAINST THIS POSSIBILITY. SPENT CATALYST SHOULD 86 0KIDI2E0 AND COOLED B6FORC NCMOVfNS IT FROM THC REACTOR. OTHER MEASURES, SUCH AS COOLING AND BLANKETING WITH NITROGEN OR WATER WETTING THE CATALYST MAY ALSO BE USED TO RETARD OXIDATION. SAL 000006841 3 SECTION X STABILITY: STABLE C A 058 REACTIVITY -: PRODUCT NAME: CRITERION 544 CATALYST USDS HO. 6169-05 HAZARDOUS POLYMERIZATION: UHL MOT OCCUR SECTION XX EMPLOYEE PROTECTION RESPlRATORr PROTECT1OH USE A NJOSH-APPRQVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR ATMOSPHERE-SUPPLYING RESPIRATOR OR AK AIR-PURIFYING RESPIRATOR FOR PARTICULATES. 1910.154, USE EITHER AN PROTECTIVE CLOTHING AVOID PROLONGED OR REPEATED CONTACT WITH S**1M. WEAR GLOVES AMD OTHER CLOTHING AS REQUIRED TO MINIMIZE CONTACT. ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOP VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS. SECTION XII : ENVIRONMENTAL PROTECTION SPILL Cft IIIAX PROCEDURES WEAR NIOSH APPROVED RESPIRATOR WHEN OUST LEVELS EXCEED OCCUPATIONAL EXPOSURE LIMITS. WEAR CLOVES, GOGGLES ANO PROTECTIVE CLOTHING TO CONTROL EXPOSURE TO BOOT SURFACES. DO NOT DRY SWEEP OR USE HETHCOS WHICH INCREASE OUSTING. LSE VACUUMING OR SWEEPING COMPOUND fOft CLEAN-UP. DO NOT WASH SPILLS INTO SEVERS OR OTHER PUBLIC WATER SYSTEMS. WASTE OISPOSAL UNDER fcPA ' RCXA (40 CFR 261.21), SPENT UNREGENERAT ED CATALYST IS A WASTE MATERIAL, IT COULD BE AN IGNI TABLE HAZARDOUS WASTE, HAZARDOUS WASTE NUMBER 0001. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. ENVIRONMENTAL HAZARDS DO NOT WASH SPILLS INTO 5CWCRS OR OTHER PUBLIC WATER SYSTEMS. SECTION XIII f ; ^IPECIAL PRECAUTIONS v/,,: 00 NOT EAT, 0R1NK OR SMOKE IN AREAS WHERE CATALYST IS PRESENT. WASH HANDS THOROUGHLY AFTER HANDLING. KEEP CONTAINERS CLOSED WHEN NOT IN USE. NOTIFY AUTHORITIES IF MATERIAL THREATENS 70 ENTER OR ENTERS INTO SEVER OR PUBLIC WATER SYSTEM. ALL PRECAUTIONS GIVEN FOR FRESH CATALYST SHOULD BE OBSERVED FOR SPENT CATALYST AND WASHINGS. SECTION XXV TRANSPORTATION REQUIREMENTS : DEPARTMENT OF TRANSPORTATION CLASSIFICATION: FRESH CATALYST NOT HAZARDOUS BY DOT REG* OTHER REQUIKEFCNTS: * SPENT CATALYST ONLY FLAMMABLE SOLID N.O.S. UN 1325. : SAL 0000068 4 C A 0 58 PIWMCT WflEs CRITERION 564 CATALYST USDS NO. 6169-05 SECTION XV OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRQOUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILADLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, CRITERION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARD INC THE ACCURACY OP THESE DATA OR THE RESULTS TO BE 06TAINE0 FRCM THE USE THEREOF. CRITERION ASSUMES NO RESPONSIBILITY FOR INJURY FRCK THE USE OF THE PRODUCT DESCRIBED HEREIN. SECTION XVI MSDS HUMBER 6159*01 6169-02 DATE NATURE OF REVISIONS) DECEMBER 20, I960 ORIGINAL ISSUE (TYPO - INCORRECT K$0$ NUMBER). FEBRUARY 14, 1989 CORRECT MSOS NUMBER TO 6169*02. 6169-03 MAY 14, 1969 ADD NEW OSHA TRANSITIONAL AND FINAL RULE EXPOSURE LIMITS. ADO SECTION XVI - SUMMARY OF REVISIONS. ADD REVIEW DATE TO TOP OF PACE 1. CORRECT TYPO IN CAS NUMBER FOR COBALT OXIDE TO 13or-?6-6 6169-04 NOVWTfcer 14, 1969 ADO CERCLA INFORMATION TO SECTIONS UB AND XII WHERE APPROPRIATE CHANGE PRODUCT COCE NUMBERS (DROP 93's AND -'s). 6169-05 February 24, 1990 HOOIFY MSOS TO REFLECT OFFICIAL DELISTING CM FEBRUARY 14, 1990 OF MGM-Fl&RCUS ALUMINUM CKIOE FROM SARA III SECTION 313 REPORTING LIST. Ktvjtw uatfc: February 24, 1990 oonald c. McCulloch TECHNICAL DIRECTOR CRITERION CATALYST COMPANY L.P. SA|_ 0000068 CR1 TER 1 Oil CATALT3T COTMir L.P. TWO OREEHSPOIMT PLA2A, PUITC tOOO, 16025 HORT HCMA3C DR, HOU3ION, TCXA9 77060 5 Petro Ware Inc. c a o 5 q P.O.Box 220 17 614-982-8420 713 Keystone Street Crooksville, Ohio 43731 614-982-4280 FAX #614-982-9875 MATERIAL SAFETY DATA SHEET SECTION I, MATERIAL IDENTIFICATION Petro Ware Ceramic Support Media contains 38% AljOj (Aluminum Oxide aka. Alumina) which is listed as a Sara Title III Section 313 chemical (CAS 1344-28-1). SECTION II, INGREDIENTS AND HAZARDS Inert ceramic support containing 38% A1205 and 51% SiO, (Silica). Current OS HA Permissable Exposure Limit for total dust is 10mg/mJ/% (TWA) and 20 mg/m3 (STEL); respirable dust averaged over an 8 hour shift 5 mg/mV%. (Also see Section VI). SECTION III, PHYSICAL PROPERTIES Color: off white to tannish brown Odor: none detectable Density: 92 Ibs/cubic foot Crushing Strength: 1,200 psi to 1,700 psi Size: one-half inch diameter, three-quarter inch diameter, one inch diameter Water Absorption: 0.02% Insoluble in water SECTION IV, COMBUSTIBILITY AND EXPLOSIVITY Non-combustible, non-explosive. Use extinguishing media appropriate to other area materials. SECTION V, REACTIVITY Stable and non-reactive under normal circumstances. SECTION VI, HEALTH HAZARDS Dust may cause irritation to respiratory tract if inhaled. Long term exposure (10-25 years) to dust may cause cough, chest pains, dyspnea, decreased vital capacity, and diminished chest expansion. Treat as nuisance dust. SECTION VII, SPILLS, LEAKS, DISPOSAL This product contains Alumina, which is currently listed as Toxic under Section 313 of Title III of the Superfund Amendments. Clean-up personnel need respiratory protection (in case of dust). Sweep spills and vacuum where necessary. Dispose of waste in an approved landfill in accordance with federal, state, and local laws. SECTION VIII, SPECIAL PROTECTION Provide workers with NIOSH approved, disposable dust respirators, when dust is apparent. Exposure levels over 100 times PEL (see Section II) require oxygen supplied respirators. Gloves and safety goggles should be worn when exposed to excessive dust. SECTION IX, SPECIAL PRECA UTIONS Dust in work area should be minimized and proper ventilation provided. SAL 0000 0<s8* 4 MANUFACTURERS NAME Norton Company ADORESS (STREET. CHY STATE AND OP COOO p7Q. Box 3S0, Akron, Ohio SECTION I NAME AND PRODUCT ... ' 44309 ' TRADE NAME. COMMON NAME OR SPECIFICATION. * " Denstone^ balls and pellets - all sizes CHEMCAL FANtU OR NIOOUCT TTPC - CONTACT K. Harrison CMCftGMCY.TELPHONE NO 216/673-5860 "WOVEDY L.._Walte 10/31/89 SECTION 0 COMPOSITION .... CH&UCAL NAME COMMON NAME REG.* (T/N) CAS . OSHA PCRM6SIVE cxposLttELiurr ACQIH TIV, _ SIT iron dioxide 60-70 Is Silica Y 14808-60-7 0. Img/m3 Aluminum oxide 72-78 Titanium dioxide 8-7 5 Iron oxide .6-7 5 * * '* Alumina Titania Iron oxide _JL 1344-28-1' ` VSnte/m3 Y -13463-67-7 .. "5me/nu Y 1309-37-1 - - lOmc/ml -- -- - Calcium oxide ?-7 0 * Calcia V 1305-78-3 _ 5rag/m3 * Magnesium oxide ."-.8 Magnesia Y l309'-48-4 " 5mg/ra3- * . Potassium oxide i.0-4:0 JL. "Potassia Sodium oxide * t.D-7.0 -s \ Soda il- 12136-45-7 1313-59-3 .lOrag/nu i'Jmg/ia3 These shaoed articles are not a regulated chem cal as they do nc t release; orotherwj result in exDosiire to haz ardDus chemical under nor lal conditions ..of use. * MiTwnamwabyOSHA20cfr wo-iaa.mx*roCommunonontewwmawwmhmoumiOanmimm&momiitF,ibKmnijmr BOiUNG POINT n/a VAPOR PRESSLRE n/'a EVAPORATION RATE n/a SOLUBMTY IN OTHER SOLENT SECTION U1 PHYSICAL AND CHEMICAL DATA MfiTMO POINT - n/a p0CENrvoucnLESYvou n/a solubility in mbi insoluble specific QMftrr 176-------- r VAPOR OENSITY n/a - SCLUBUTY IN ALCOHOL insoiub. APPEARANCE AND OOOR insoluble buff colored solid: odorless SECTION rv FIRE AND EXPLOSION HAZARD DATA .............. * FLASH POINT n/a EXTTNOUISHMG MEDIA nZa. SPECIAL FIRE FIGHTING PROCEDURES (%4THOO USED) n/a n/a. \ flammable umits LB. n/a EXPLOSION POTENTIAL n/a. SECTION V HEALTH FIRST AIO ANO MEDICAL DATA PRIMARY ROUTERS) OF ENTRY INHALATION INGESTION ACUTE AND CHRONIC"HEALTH EFFECTS AND EFFECTS OF OVEREXPOSURE - '* If dust is created; there.lV tRe possi- bility of breathing_in. irritant powders. Excessive (years long) f exposure to Silica tail leau to 3iiiLUSis.--UiiTca-mayalsu be a possible carcinogen. - * F^ST.AlO ANO MEDICAL INFORMATION For*acute exposure. 1 victim to fresh- air^ for medical assistanc GympLLuma continue. . n/a n/a SKIN CONTACT 4 ABSORPTION n/a SAL 000006845 h/a EYE OTHER POTENTIAL HEALTH RISKS Dust may cuase irritation Irrigate eyes with Wt Examine for physical .presence ofLaarticle; /lumina is listed under section 313 of Title III of SARA, but"EPA Is"'proposing Minimize creattion o: to de-list* it. Most of the Silica is ch<ekically u Lelies_______ SECTION VI COMtOStVITY AND REACTIVITY OATA ffWUTY INSTALLED STASLEOt POCTUSBunON MAY OCCUR WILL MOT OCCURS mcommtmjty(materialstoMtoGi Silicate products may react* although not violently, with hydrofluoric acid or active fluorides. ^_ C A 0 07 COMPOSTDON FROOUCTS none CONDITIONS TO BE WOD Active fluorides ____________________ SECTION VII STORAGE. HANOUNG AND USE PROCEDURES______________________________ normal storage and handung 5tore in dry areas. Do not- overstack to the point of deforming cartons Suppress dust when unloading cartons* or wear respirators^ wProtect against sharp, broken edges. * N0*UALU^E Avoid rough handling to avert abrading or crushing the articles. " ' ofsteps to retaken in case leaks or srlls . Minimize dust. ' Sweep, shovel, vacuum,-. Watch footing if articles fall onto walking surfaces^. . .... wstsdisposalmethoo j^dfill in accordance local*, state and federal regulations. Be guided by extraneous matter to which tehse articles-may have been exposed inteh users* process. ! SECTION VIII PERSONAL PROTECTION INFORMATION respiratory PROTECTION (SPesrrTrPE) NTOSH APPROVED DISPOSABLE. OR OTHER DUST MASK. ventilation local recommended MECHANICAL ---- - See OSHA CFR 1910.: - _ (G&^AU OTHER * -- -- - protective gloves recoimtended .-- ......... -- -- rr protection. reconinended " " * - - ........ .. OTHER EQUIPMENT as customer.1 s policies dictate * . - - - ... MEASURES TO BE TAKEN DURING RCPAM AND MAINTENANCE OP COWTALOMATED EQLMPMEMT THAT HAS BEEN IN CONTACT WITH THIS MATERIAL As sold, these articles are inert and non-hazardous. If customer's processing introduces. hazardous (toxic) materials to the articles,-be guided by their nature. Minimize dust whe: handling these articles....................... ________________________________ __________ SECTION IX SPECIAL PRECAUTIONS ~ ______________ ____________ precautions to re taken in handling ANO storage Minimize dust by careful handling. Use repirators and adequate ventilation if dust is crated. . ' *"' other precautions These articles are hard and abrasive. Minimize bodily contact with gloves * safety glasses, and adequate covering. r FOR COMPANY USE The information and recommendations set forth herein are taken from sources believed to be' accurate as of the date herepf;howeverNorton Company makes no warranty with respect to the accuracy of the information or the suitability of the recommendations, arid assumes no liability to any user thereof. **MAJPNO APPUCASU MPORMATION POUND T/v-.'..: ***N/A*NOT APPLICABLE SAL 000006846 . ~'. I~-`.T Porm.4961 A Rev. S/84 fJC/W/W MATERIAL SAFETY DATA SHEET C A 0 37 3502 RIVERVIEW - Mailing Address - P. O. BOX 977 - PORT ALLEN, LA. 70767-0977 - Phone (504) 389-9945 SECTION I. PRODUCT IDENTIFICATION: TRADE NAME: CHEMICAL NAME: CHEMICAL FORMULA: CAS NO.: MANUFACTURER: EMERGENCY PHONE NUMBER: Activated Alumina Aluminum Oxide A1203 1344-28-1 Discovery Chemicals, 504-389-9945 Inc. SECT ION II. A 1203 Na20 S102 H20 1ngredients: 90.00-95.00* 0.30- 2.ON 0.02- 0.04* 5.00- 7.00* Exposure Limits ACGI11-TLV 10 mg/m3 Total Dust 5 mg/m3 Respirable dust SECT ION III. Physical Data: APPEARANCE/ODOR: MELTING POINT: SOLUBILITY IN WATER: White crystalline powder, spheres or granules/no odor >3000F Insoluble SECTION IV. Fire and Explosion Hazards: FLASH POINT (METHOD): Nonflammable EXTINGUISHING MEDIA: None required HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE & EXPLOSION HAZARDS: None None SECTION V. Reactivity Data: STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID: HAZARDOUS POLYMERIZATION: Stable None None Will not occur 7-02-90 00000684-7 SAL SECTION VI INHALATION: EYE CONTACT: SKIN CONTACT: INGESTION: Health Hazards C A 0 37 If exposed to excessive amounts, remove to fresh air. Begin Immediate eye Irrigation with cool water for at least 15 minutes with the eyelids held open by gently separating them with the fingers. No hazard under normal circumstances. No hazard under normal circumstances. SECTION VII. Safe Handling & Use: SPILLS OR LEAKS: Shovel material Into container for disposal. DISPOSAL METHODS: This product Is not by EPA's definition a hazardous substance. It may be disposed of In a landfill In compliance with any applicable local, state and federal regulation. STORAGE REQUIREMENTS: Store In a dry place away from moisture. 7-02-90 SAL 00006848 MATERIAL SAFETY DATA SHEET An **plv>*tk*t td th* fmrmt uwd ftvtoi may to found #1 OSHA 29 CFR WQ 1200, ivtfabh from OSHA regional or arM oflfctt. (Similar to U.8. Department of Labor Form OMB 1218-0077 and ganamlty accaptad In Canada for information purpoaaa) Do Not DupUcata Tfcia Form. Raquaat an Original. I. PRODUCT IDENTIFICATION +C AO 54 PRODUCT Molecular Sieve Type MRG-E CHEMICAL NAME FORMULA Sodium Aluminosilicate Na20, AljOj. SiOj, MgO SYNONYMS CHEMICAL FAMILY MOLECULAR WEIGHT TRADE NAME UOP Molecular Sieve; formerly UNION CARBIDE* Molecular Sieve II. HAZARDOUS INGREDIENTS Zeolite Molecular Sieve Not Applicable A complex of elements and compounds composed of material shown below. NOTE: In the table below, the symbol "<" means "less than." MATERIAL (CAS/TSCA NO.) Sodium Oxide (1313-59-3) Aluminum Oxide (1344-28-1) Silicon Oxide (7631-86-9) Magnesium Oxide (1309-48-4) Wt(H) <20 <40 <60 '< 5 1989-1990 ACGIH TLV-TWA (OSHA-PEL) None established (None established) 10 mg/m3 as Al (10 mg/m3 Total dust) ( 5 mg/m3 Respirable fraction) 10 mg/m3 {6 mg/m3) 10 mg/m3 Fume (10 mg/m3 Total dust) (5 mg/m3 Respirable dust) M-4978 r III. PHYSICAL DATA * - .7 BOILING POINT, 760 mm. Hg Not Applicable FREEZING POINT Not Applicable SPECIFIC GRAVITY (H,0 = 1) 1.1 (piece) VAPOR PRESSURE AT 20C Not Applicable VAPOR DENSITY (air = 1) Not Applicable SOLUBILITY IN WATER, % by wl. PERCENT VOLATILES BY VOLUME Not Applicable EVAPORATION RATE (BUTYL ACETATE = 1) APPEARANCE AND ODOR: Product is a bead, pellet, or mesh (granules); odorless. Not Applicable Not Applicable EMERGENCY^PHONE NUMBER IN CASES OF EMERGENCIES involving this material, further infotmation is available at all times: Emergency Phone No.: In USA: UOP 708-391*2123 CHEMTREC 800-424-9300 In Canada: CANUTEC 613-996-6666 From other Countries: CHEMTREC 202-483-7616 For routine information contact your local supplier UOP urges each customer or recipient of this MSDS to study it carefully to become aware of and understand the potential hazards associated with the product. The reader should consider consorting reference works or individuals who are experts in ventilation, toxicology, and fire preven tion, as necessary or appropriate to use and understand the data contained in this MSDS. To promote safe handling, each customer or recipient should: (t) notify its employees, agents, contractors and others whom it knows or believes will use this material or the information in this MSDS and any other information regarding hazards or safety; (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees, customers, and crther users of the product of this information. Copyright 1990 UOP UOP MOLECULAR SIEVE AOSOR8ENTS UOP CANADA, INC. Page 1 of 4 SAL 000006849 021443 IV. HEALTH HAZARD DATA tRESHOLD LIMIT VALUE: See Section H. C A0 54 / iFECrS OF SINGLE (ACUTE) OVEREXPOSURE: ---- SWALLOWING -- The product gets hot as it adsorbs water. Burns to moist body tissues can result if contact is prolonged. No other evidence of adverse effects from available information. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- May cause irritation of the nose and throat, accompanied by cough and chest discomfort. SKIN CONTACT -- May cause irritation seen as local redness and/or burns. EYE CONTACT -- May cause discomfort and/or irritation seen as excess redness of the conjunctiva. FFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: Prolonged Inhalation may cause lung damage. THER EFFECTS OF OVEREXPOSURE: None currently known. IEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Breathing erf dust may aggravate asthma and inflammatory or fibrotic ulmonary disease. MERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- If ingested in large quantities, drink 2 glasses of water. Contact physician for permission to induce vomiting. SKIN CONTACT -- Wash contacted area with soap and water. INHALATION -- Remove the person to fresh air. EYE CONTACT -- Flush eyes with water for 15 minutes. VOTES TO PHYSICIAN: This product is a desiccant and generates heat as it adsorbs wafer: The used product can contain material )f a hazardous nature. Identify that material and treat symptomatically. ( Page 2 of 4 SAL 000006850 Marcft 1990 V. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (test method) Does not burn AUTOIGNITION TEMPERATURE Not Applicable FLAMMABLE LIMITS LOWER IN AIR, % by volume Not Applicable UPPER Not Applicable EXTINGUISHING MEDIA: Unused material will not burn. Use media appropriate (or surrounding fire. CA0 SPECIAL FIRE FIGHTING PROCEDURES: Depends on the use of the material. Used material may contain products of a hazardous nature. The user of this product must identify the hazards of the retained material and inform the lire fighters of these hazards. UNUSUAL FIRE AND EXPLOSION HAZARDS: In their fresh unused state, molecular sieves are not flammable. When exposed to water, however, they can get quite hot. When first wetted they can heat to the boiling point of water. Flooding will reduce the temperature to safe limits. m * - VI. REACTIVITY DATA STABILITY | CONDITIONS TO AVOIO: Moisture (water) can cause rise in temperature which might result in burn. UNSTABLE STABLE X INCOMPATIBILITY (Materials to Avoid): Sudden contact with high concentrations of chemicals having high heats of adsorption such as olefins, HCI, etc. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrocarbons and other materials that contact the molecular sieve during normal use can be retained on the sieve. It is reasonable to expect that decomposition products will come from these retained materials of use. The molecular sieve itself does not readily decompose unless subjected to extreme temperature or chemical conditions. If such decomposition did occur the products would include the mix of oxides listed in Section II. HAZARDOUS POLYMERIZATION May Occur Will not Occur X CONDITIONS TO AVOID: None currently known. VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Sweep the spill area. Collect and place the spilled material in a waste disposal container. Avoid raising dust. WASTE DISPOSAL METHOD: Discard any product (including any retained materials of use), disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, State and local regulations. SAL 000006851 Page 3 of 4 March 1990 FLASH POINT (test method) V. FIRE AND EXPLOSION HAZARD DATA Does not burn AUTOIGNITION TEMPERATURE Not Applicable FLAMMABLE LIMITS LOWER IN AIR, % by volume Not Applicable UPPER Not Applicable EXTINGUISHING MEDIA: Unused material will not burn. Use media appropriate tor surrounding fire. CAOf SPECIAL FIRE FIGHTING PROCEDURES: Depends on the use of the material. Used material may contain products of a hazardous nature. The user of this product must identify the hazards of the retained material and inform the fire fighters of these hazards. UNUSUAL FIRE AND EXPLOSION HAZARDS: In their fresh unused state, molecular sieves are not flammable. When exposed to water, however, they can get quite hot. When first wetted they can heat to the boiling point of water. Flooding will reduce the temperature to safe limits. VI. REACTIVITY DATA STABILITY | CONDITIONS TO AVOID: Moisture (water) can cause rise in temperature which might result in burn. UNSTABLE STABLE X INCOMPATIBILITY (Materials to Avoid): Sudden contact with high concentrations of chemicals having high heats of adsorption such as olefins, HCI, etc. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrocarbons and other materials that contact the molecular sieve during normal use can be retained on the sieve. It is reasonable to expect that decomposition products will come from these retained materials of use. The molecular sieve itself does net readily decompose unless subjected to extreme temperature or chemical conditions, if such decomposition did occur the products would include the mix of oxides listed in Section II. HAZARDOUS POLYMERIZATION May Occur Will not Occur X CONDITIONS TO AVOID: None currently known. STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Sweep the spill area. Collect and place the spilled material in a waste disposal container. Avoid raising dust. WASTE DISPOSAL METHOD: Discard any product (including any retained materials of use), disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, State and local regulations. SAL 000006852 Page 3 of 4 CENTURY PAPERS INC. 4902 GULF FREEWAY HOUSTON. TEXAS 77023 PHONE NO. 713-928-5171 MATERIAL SAFETY DATA SHEET SECTION 1- PRODUCT IDENTIFICATION PRODUCT NAME: AMIGO HAND SOAP ITEM NO. 414-2373, 414-2365 SECTION 2- HAZARDOUS INGREDIENTS MANUFACTURER: vw CARROLL COMPANY 2900 WEST KINGSLEY RO. GARLAND. TEXAS 75041 EMERGENCY PHONE NO. 214-278-1304 SHEET NO. 0328 PRODUCT CODE: 442 NONE SECTION 3- PHYSICAL DATA SOILING POINT: >212F. VAPOR PRESSURE: 23.8 a 250 C SOLUBILITY IN WATER: COMPLETE SPECIFIC GRAVITY: 1.016 PRODUCT PH: 8.6. MELTING POINT: UNDETERMINED APPEARANCE AND ODOR: LIGHT ORANGE COLOR, ORANGE FRAGRANCE. SECTION 4-- FIRE AND EXPLOSION HAZARD DATA FLASH POINT: > 212 F, EXTINGUISHING MEDIA: WATER, C02, FOAM OR DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES: NONE UNUSUAL FIRE AND EXPLOSION HAZAROS: NONE SECTION 5- HEALTH HAZARD OATA THRESHOLD LIMIT VALUE: UNDETERMINED CARCINOGEN: NO ACUTE AND CHRONIC HEALTH EFFECTS: NONE PRIMARY ROUTES OF ENTRY: NO PRIMARY ROUTES OF ENTRY EFFECTS OF OVEREXPOSURE: EYES-MAY CAUSE IRRITATION. INGESTION- MAY BE HARMFUL EMERGENCY ANO FIRST AID PROCEDURES: EYES - FLUSH WITH WATER. INGESTION - GIVE LARGE AMOUNT OF MILK OR WATER TO DRINK. MEDICAL ATTENTION. GET SECTION 6- REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID: NONE INCOMPATIBILITY: NONE SECTION 7- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: FLUSH WITH PLENTY OF WATER. WASTE DISPOSAL METHOD: FOLLOW FEOERAL ANO LOCAL REGULATIONS. SAL 000006853 MATERIAL SAFETY OATA SHEET PRODUCT NAME: AMIGO HAND SOAP ITEM NO. 414-2373, 414-2365 SECTION 8- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: ADEQUATE VENTILATION GLOVES: NONE EYE PROTECTION: OTHER PROTECTIVE EQUIPMENT: NONE PAGE 2 NONE GS696 SECTION 9- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: OTHER PRECAUTIONS: NONE NONE V. SAL 000006854 BETZ PROCESS CHEMICALS, INC (713) 367-2442 9669 GROGANS MILL ROAD THE WOODLANDS , TX 77380 MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 PRODUCT : PHILMPLUS 5K8 DISTRIBUTED: MAY-24-1990 S 6 97ft (page 1 OF 3) EFFECTIVE DATE 05-18-89 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: 3 PRODUCT APPLICATION : A BLEND OF FILMING AMINES IN HEAVY AROMATIC NAPHTHA. ........... SECTION 1............................HAZARDOUS INGREDIENTS....................................... INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9;COMBUSTIBLE LIQUID;IRRITANT(EYE); MANUFACTURERS SUGGESTED EXPOSURE LIMIT:!O0PPM;PEL:NONE;TLV:NONE. TRADE SECRET INGREDIENT(076);COMBUSTIBLE;CORROSIVE;PEL/TLV: 10 PPM. TSRN 125438 - 5199P TRADE SECRET INGREDIENT(E108);IRRITANT TO SKIN;CORROSIVE TO EYES;PEL:NONE; TLV:NONE.THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 ^ - 5081P TRADE SECRET INGREDIENT(E141);CORROSIVE;PEL:NONE;TLV:NONE .THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 - 5102P ........... SECTION 2............................TYPICAL PHYSICAL DATA................................................................. PH: 5% EXTRACT (APPROX.) FL.PT.(DEG.F): 142 P-M(CC) VAPOR PRESSURE(rmtHG): <10 VISC cps70F: 151 EVAP.RATE: ND WATER=1 PHYSICAL STATE: LIQUID 5.8 ODOR: HYDROCARBON SP.GR.(70F)OR DENSITY: 7.7LBS/GAL VAPOR DENSITY(AIR=1): >1 %S0LUBILITY(WATER): 0 APPEARANCE: DARK AMBER FREEZE POINT(DEG.F): <-30 SECTION 3...........................REACTIVITY DATA STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. S4L 006355 G S 6 97 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PROOUCT: PHILMPLUS 5K8 ........... SECTION 4............................ HEALTH HAZARD EFFECTS............................................................... ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN ACUTE EYE EFFECTS *** CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS AND/OR DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** INHALATION MAY CAUSE IRRITATION OF MUCOUS MEMBRANES AND RESPIRATORY TRACT SKIN CONTACT CAUSES SEVERE IRRITATION OR BURNS. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ABSORBED THROUGH SKIN. ........... SECTION 5------------------------- FIRST AID INSTRUCTIONS.......... ............................................... SKIN CONTACT*** REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT -INHALATION EXPOSURE*** ^ REMOVE VICTIM FROM CONTAMINATED AREA.APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR UATER ...........SECTION 6------------ ---------- SPILL,DISPOSAL AND FIRE INSTRUCTIONS....................... SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENTS PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS<FULL FACE-PIF.CE TYPE).PROPER FIRE EXTINGUISHING MEDIA; DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER SAL 000006856  697 6 S6 *7MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: PHILMPLUS 5K8 ........... SECTION 7............................SPECIAL PROTECTIVE EQUIPMENT............................................ USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** GAUNTLET-TYPE NEOPRENE GLOVES,CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES.FACE SHIELD ........... SECTION 8............................STORAGE AND HANDLING PRECAUTIONS.................................. STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. KEEP AWAY FROM FLAMES OR SPARKS. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT. HANDLING INSTRUCTIONS*** COMBUSTIBLE.CORROSIVE TO SKIN AND/OR EYES. ************************************************************************** THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) .************************************************************************** APPENDIX: REGULATORY INFORMATION iIHE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: TREAT AS OIL SPILL ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002=CORROSIVE(SKIN) ...DOT HAZARD/UN#/ER GUIDE# IS: CORROSIVE TO SKIN.COMBUSTIBLE UN1760/#60 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - CORR ; PE - D SAL 000006857 E**P* MATERIAL SAFETY DATA SHST CALLAWAY CHEMICAL COMPANY 10/20/iT A ' 1 IKXOM CMtMtCAL AMK1CA - -L . p.o. M iui. cst-em. iimi-mii aByn J FA* 1 NO. SECTION I PRODUCT MOOUCT NAMf CALLAWAY 1330 CJmWICAL NAMt Not Applicable; Bland CHSAMnlCiAoLnPicAMIsLYurf.actant PNOOUCT APTfAAAMCS Clear solution, alcoholic odor IDENTIFICATION A - EMERGENCY INFORMATION EMERGENCY TELEPHONE NUMBERS: CALLAWAY CHEMICAL COMPANY 404-676-2000 CHEMTREC 800-424-9300 SECTION II HAZARDOUS COMPONENTS OF MIXTURES rm mccisc cc.*nitjc*i c# -mis Hirrvna is moNtCTANY imp iTIQN. A . . . MUKSt IS ms I VINT ON * NODICAL M*6MCV. THS FOLLOWING lULM AW III AMS OM1 OSHA HAZARD COMPONENT -hxafiaaidHoym.y?iny*i-rYrmIUetHis_iw*OitYhIPsOcT*ONaistMo.ftviosetci iu c Flammable Eye tnd skin irritant PEL, TLV Isopropyl Alcohol Isopropyl Alcohol Isopropyl Alcohol For additional information s# Saction III. SECTION III HEALTH INFORMATION AND PROJECTION FIRST AID NATURE OF HAZARD EYE CONTACT: Immediately flush ayas with large amounts of watar for at laast is mlnutas. Cat prompt mad leal attention. Irritating, and will injura aya tissue if not ramovad promptly. INHALATION: Using propar rasplratory protaction, immadiataly ramova tha affactad victim from axposura. Admlnlstar artificial rasp1 ratIon If braathlng is stoppad. Kaap at raat. Call for prompt madleal attantlon. High vapor concentrations ara Irritating to tha ayaa and tha rasplratory tract, may causa haadachas and dizziness, ara anasthatlc and may hava othar cantral narvout ayatam affacts. SKIN CONTACT: Immadiataly flush with larga amounts of water; us# soap if avallabls. Ramova contaminated clothing, including ahoas. aftar flushing nas begun. Get prompt medical attantlon. Low order of toxicity. Irritating. INGESTION: First aid la normally not requ 1 red. Minimal toxicity. May causa vomiting. PERMISSIBLE EXPOSURE LIMIT; OSHA REQUIRES (29CFR1910.lOOO): a TWA of 400 ppm (840 mg/m3) for Isopropyl Alcohol. * SAL 000006&58 ! - ----- -- - -- ------------------- -------------------- - ....... ......................__________ ODTTuaHTsXAgSHaTaIJ4.i!nAUCsnISMNtOINNAdpiC'aTSoaMittLKA*emlIDTlAno*Jt.LtFO*OHHaivOcO*ANAScWiSMilnCtLINtCtAVWTtS*AlX.TAMi*aTMMTsTOirOMTirlO.AMiTatMSFXvAfttISTMnSIPSo,tMAFnTSCTUaAICFmMTHItIICNCNMlIMoWS.PsLOsFWTMAUMioMlnAMITUAJMMOTeDMTcICXcOJSa1NICMTOStOhAMUTaAINTtTADMAMmtSATaIMMtSLD*IToTNTcINcAlCTA*MNMMOA0iOMnCLTCnMA^NSLMtTmVTOrC*aNA*lMLCuIISDTDsS#eCSKSAoMCOsUNCOMtUhSAMMUAisCOLTtMIi,BmIAMfPNToF.BKOmJLMAmtIlCAAMaCLNAtUiTIoULAICmAIMTMTDTn1o9OCnMINMN0sCCMoaOOIStCMNnlC1IAoULM*ATtTImltOPtM*LMtAATt**aS. IneTUnIMTaLAhTAVt*ISMt* T n(P* MATERIAL SAFETY DATA SHEET G S694 10/30/27 PRODUCT MARC: CALLAWAY 9390 THRESHOLD EXPOSURE LIMITS ACOIH RECOMMENDS: TWA of 400 pQ* <9AOmg/m3), snd o STCL of SOO ppm (122S mg/m3) Isopropyl Alcohol. for RAM 2 NO. PERSO9NAL PROTECTION For' opon systems hr contact 1l likely, wear long sleeves, chemical raai latent gloves, and chemical goggle*, Vhairro contact may occur, wear long tleevvsaa and aafoty glaaaoa with aido ah i a 1 da. Wharo coneantrationo in air may exceed tho limits givan in thia Section and engineering. work practice or othor aaana of exposure reduction ara not adequate. NXOSH/MSHA approved raaplratora may be neceaaary to prevent overexposure by inhalation. VENTILATION The uao of mechanical dilution ventilation la recommended whenever tma product la uaod in a confined apace, is heated above ambient temperatures, or is agitated. Uao exp loo ion-proof ventilation equipment. SECTION IV FIRE 4 EXPLOSION FLASHPOINT DEO. F : 91 METHOOi Setaflash FLAMMABLE LIMITS-LEL: 2.0 UEL: 12.0 NOTE: Component AUT01GN1TI0N TEMPERATURE OEG. F : HAZARD GENERAL HAZARD Flammable Liquid, can release vapors- thet fona f 1, tempereturee at or abovo tho tlasf^oirff; 1e mixtures-at T-. - J Empty product containers may contain product residue. Do not pressures, cut, heat, weld or expose containers to flame or other sources of ignition. FIRE FIGHTING Use water spray to cool firs exposed eurfacee and to protect personnel . Shut off 'fuel to fire. If a leak or spill has not Ignited, use water spray to disperse the vapors. Use alcohol type foas or dry chemical to extinguish fire. HAZARDOUS COM8USTION PRODUCTS No Unusual SECTION V SPILL CONTROL PROCEDURE LAFD SPILL Eliminate source# of ignition. Prevent additional discharge of material, if possible to do so without ha2ard. For small spills implement cleanup procedures; for large spills Implement cleanup procedures and. if in public area, keep public away and advise authorities. Also, if this product is an EPA hazardous substance (See Section X. Page 4) notify the U.S. EPA if appropriate. Prevent liquid from entering severs, watercourses, or low arses. Contain spilled liquid with sand or earth. Do not use combustible materials such as sawdust. Recover by pumping (use an explosion proof or hand pump) or with a suitable absorbent. Consult an expert on disposal of recovered materiel ard ensure SAL 000006859 M MATERIAL SAFETY DATA SHEET 10/20/87 PftODUCT NAMEs CALLAWAY 8290 99694 conformity to local disposal regulations. WATEft SPILL Consult on export on disposal of recovered materia) and ensure conformity to loco) disposal regulations. SECTION VI NOTES No notes applicable. *$M 3 NO. SAL 000006860 fi 6 91 MATERIAL SAFETY DATA SHEET 10/20/17 P20OUCT NAMf: CALLAWAY 2290 PAP ML SECTION VII TYPICAL PHYSICAL A CHEMICAL PROPERTIES W SUU`iN03. ,0Hb somsiLirv in water. rr. % m F Soluble VISCOSITY OF HQUIO. *T F tO cps jp. OllAVlTY OF VAPOR. M 1 ATM AlR Not available IVAFORATION RATI. ft-*U ACETATE* 1 2.3 FREEZING M1LTIN0 POINTERARCS. F Not available BOILING POINT/RANGE. F 17S STASILITVT Stable CO*4iTiONS TO AVOIO INSTABILITY SECTION VIII REA CTIV1TY DATA Will not occur CONDITIONS TO AVOIO HAZARDOUS POLYMERIZATION Not Applicabie Not Applicable MATERIALS AJ CONDITIONS TO AVOID INCOMPATIBILITY Strong oxidizing agents and strong acids MAA*DOue DECOMPOSITION PAOOUCTS -------- _____---^r---- ------------------------------- / SECTION IX TRANSPORT ANO STORAGE gi ACCUMULATION haaP Unknown. use proper grounding procedure STORAGE TEMPERATIME. f Aablent STORAOCvTRANSPORT PRESSURE, mnHf LOAOtNGAJNLOAOING TEMPERATUNC. F Arablent VISCOSITY AT LOAOINORJNLOAOING TIMPCRATURt^ST AtmosDheMc Not available U.i. Kf CLASSIFICATION F i aiarmae 1 e SECTION X HAZARD CLASSIFICATION Not Applicable 9 AMOUNT LBS. ADDITIONAL INFORMATION Under the provisions of Title HI. Sections 311/312 of the Superfund Ai--ndwnts and Rsauthorlzatlon Act. this product is classified into ths following hazard categories: Immediate Health. Delayed Health. Fire. / iFERENHCDS KNAUM-PBE-R102^9 PATE r^EPARCD OCTOBER 20.1287 ] TFOONR AAODODIITTIIOOKNAA4L. PSHAOLOTUMCi'TSAINFEFTOYRMINAFTOIORNMACTOIONNTACCATLLTO?U1R9*T7tO0-*MMCSAL SALES REPRESENTATIVE SUPERCEDES ISSUE DATE KARCH 31.1987 SAL 000006861 ts MATERIAL SAFETY DATA SHEET Ashland ASHLAND CHEMICAL, INC Sb*tiitty 0) Wi OH, lac P.0. BOX 2219 COLUMBUS, OHIO 43216 (614) 889-3333 c2^rH0URr ErgjncV Telephone 1(800) 274-5263 or 1 (800) ASHLAND 001285 CAUSTIC SODA LIQUID 50% INDUST 0808 THIS USDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 Product Nam: CAUSTIC SOOA LIQUID 50* INDUST CAS NUMBER: 1310-73*2 Data Sheet No: 0000721-006 05 50 076 2000810- Prepared: 05/31/89 CONOCO/WESTLAKE Supersedes: 02/08/89 REFINERV WAREHOUSE P. 0. BOX 37 PROOUCT: 3150000 WESTLAKE LA 70669 INVOICE; 120116 INVOICE OATE: 05/27/90 TO: CONOCO/WESTLAKE REFINERV WAREHOUSE ATTN: PLANT MGR./SAFETY OIR. P. 0. BOX 37 I I 1 I SECTION I - PRODUCT I DENT! I C AT I ON General or Generic ID: ALKALI DOT Hazard Classification; CORROSIVE MATERIAL (173.240) SECTI ON I I - COMPONENTS IF PRESENT, I ARC. NTP AND 05HA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION INGREDIENT * (by WT) PEL TLV Note S001UM HYDROXIDE CAS *: 1310-73*2 50 2 MG/M3 - CEILING 2 MG/M3 - CEILING wmammm Boiling Point m CTION I I I * P HYSI CAL DATA for PROOUCT Vapor Pressure for PROOUCT Specific Vapor Density Specific Gravity Percent Volatiles Evaporation Rate Appearance State Form 288.00 Deo F 142.22 Deg C) 760.00 imt Hq 3.00 mm He 100.00 Deg 7 ( 37.77 Deg C) HEAVIER THAN AIR 9 60i00 Deg F ( 15.55 Deg C) 50.00* SLOWER THAN ETHER 14.0 CLEAR & COLORLESS LIQUID HCMOG SOLN FLASH POINT NOT APPLICABLE EXPLOSIVE LIMIT NOT APPLICABLE EXTINGUISHING MEDIA: HAZARDOUS DECOMPOSITION PRODUCTS: NOT APPLICABLE FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MOOE AND FULL BODV PROTECTION WHEN FIGHTING FIRES. SPECIAL FIRE & EXPLOSION HAZARDS: CAN REACT WITH CHEMICALLY REACTIVE METALS SUCH AS ALUMINUM, ZINC. MAGNESIUM. COPPER ETC. TO RELEASE HYDROGEN GAS M-UCH CAN FORM EXPLOSIVE MIXTURES WITH AIR. NFPA COOES: HEALTH- 3 FLAW4ABILITY- 0 REACTIVITY- 1 PERMISSIBLE EXPOSURE LEVEL 2 MG/M3 - CEILING THRESHOLD LIMIT VALUE 2 MG/M3 - CEILING EFFECTS OF ACUTE OVEREXPOSURE: FOR PROOUCT EYES - CAUSES SEVERE DAMAGE ANO EVEN BLINDNESS VERY RAPIDLY. SKIN - CAUSES BURNS, POSSIBLE OEEP ULCERATION. BREATHING - MIST CAN CAUSE DAMAGE TO NASAL AND RESPIRATORY PASSAGES. SWALLOWING - RESULTS IN SEVERE DAMAGE TO MJCOUS MLM3RANES AND DEEP TISSUES. SAL 000006862 FIRST AIO: IF ON SKIN: IMMEDIATELY FLUSH EXPOSED AREA WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. COPYRIGHT 198 CONTINUED ON PAGE: 2 <Sdyo\ 2 ( R 3 09 MATERIAL SAFETY DATA SHEET Ashland AittLA.> LI Itlt.VllLAL, l.NL. SsDti4iaiy 01 Asfcla< Oil. lac P.O. BOX 2219 COLUMBUS, OHIO 43216 _______ (614) 889-3333 EmZMe-rtglUeUnKcy Telephone 1(800) 274-5263 or 1(800) ASHLAND 001285 CAUSTIC SODA LIQUID 50% INDUST V- HEAL TH HAZARD Page REMOVE CONTAMINATED SHOES PROMPTLY. DISCARD SHOES SATURATED WITH THIS PRODUCT. IF IN EVES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET 1MMEOIATE MEDICAL ATTENTION. IF PHYSICIAN IS NOT IMMEDIATELY AVAILABLE, CONTINUE FLUSHING WITH WATER, DO NOT USE CHEMICAL ANTIDOTE. IF SWALLOWED: DO NOT INDUCE VOMITING. VOMITING WILL CAUSE FURTHER DAMAGE TO THE TVROAT. DILUTE 8Y GIVING WATER. GIVE MILK OF MA<^E$lA. KEEP WARM. QUIET. GET MEDICAL ATTENTION IMMEDIATELY. IF BREATHED: IF AFFECTED. REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM. 0U2ET AND GET MEDICAL ATTENTION. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT. INHALATION SECT I ON VI-R E AC TI VI TV OATA HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOIO CONTACT WITH:, STRONG MINERAL ACIDS., REACTIVE METALS SUCH AS ALUMINUM AND MAGNESIUM, ORGANIC MATERIALS. WATER. STRONG ORGANIC ACIDS. COPPER 2 STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: NEUTRALIZE AND MOP UP SOLUTION. LARGE SPILL: COLLECT AND ADD SLOWLY TO LARGE VOLUME OF WATER. PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP IS COMPLETED STOP SPILL AT SOURCE. DIKE TO PREVENT SPREADING. PUMP TO SALVAGE TANK. STE DISPOSAL METHOO: SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: POUR INTO A LARGE TANK OF WATER ANO NEUTRALIZE. FLUSH TO DRAIN WITH LARGE EXCESS OF WATER IN ACCORDANCE WITH APPLICABLE REGULATIONS. seen ON VI f I - PROTECT I VE* EQUI PMENT . TO BE. USE RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMIT(S) OF PROOOCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION II). A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR 1$ ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MS1A RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/CR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:. NEOPRENE, NITRILE RUBBER, POLYVINYL CHLORIDE. POLYETHYLENE EYE PROTECTION: CHEMICAL SPLASH GOGGLES AND FACE SHIELD (8" MIN.) IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED; HOWEVER. OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER) OTHER PROTECTIVE EQUIPMENT: TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING ANO BOOTS. EYEWASH STATION. EMERGENCY SHOWER. PRE CAUT OTHER COMMENTS CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS MHEN EMPTIED.SINCE EMPTIED CONTAINERS RETAIN PROOUCT RESIDUES (VAPOR. LIQUID, AND/OR S0L10). ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, ANO SUITABLE TO THEIR CIRCUMSTANCES. COPYRIGHT 1989 SAL OOOO06863 LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE MATERIAL SAFETY DATA SHEET SECTION I PRODUCT NAME OR NUMBER (AS IT APPEARS ON LABEL) GBR-7005 MULTI PURPOSE THINNER MANUFACTURER * S NAME EMERGENCY TELEPHONE NO . (3131-643-4600 M-P 8s00am-4s30p* GROW GROUP INC. CHEMTREC: (800)-424-9300 ALL OTHER TIMES ADDRESS (NUMBER, STREET, CITY, STATE AND ZIP CODE) 3155 W. BIG BEAVER ROAD. SUITE 200 P.O. BOX 7026 TROY. MICHIGAN 48007-7026 MANUFACTURER'S D-U-N-S NO. 00-532-0551 HAZARDOUS MATERIALS DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS ID NO. PAINT RELATED MATERIAL NA-126 3 _____ ____________________________________________ ADDITIONAL HAZARD CLASSES (AS APPLICABLE) FLAMMABLE LIQUID CHEMICAL FAMILY FORMULA SOLVENT BLEND SOLVENT BLEND CAS REGISTRY NO. IV 1 IM < SECTION II - INGREDIENTS CHEMICAL NAMES EXPOSURE LIMITS IN AIR | LISTED AS A ' CARCINOGEN i:: 1 KT? IARC OR \ 67-63-0 I I 2-12 1 6.6*1 ISOPROPYL ALCOHOL (ISOPROPYL 1 4QQ A00 400 f_______ NO | ALCOHOL)* ______________________ !________________________ j__________ I _______ 1________________________________________ I ' 67-56-1 l 1 1 1 1-3 2.9* METHANOL (METHYL ALCOHOL)* SKIN i 200 1 200 200 1 1 1 1 1 NO *VAKHINC: Hazardous according to SARA. Section 313 of Title III. Toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III and of 40 CFR 372. SAL 000006864 P CO 86 t SECTION III ~ PHYSICAL OATA BOXLING RANGE 138-229 XX*F JC SPECIFIC GRAVITY"(H?0*i) 0.8270 VAPOR PRESSURE 90.6 PERCENT VOLATILE BY VOLUME 100% 4 68*T *C XX MM HG PSI PERCENT SOLIO BY WEIGHT 0% VAPOR DENSITY (AIR*i) 2.39 EVAPORATION RATE SLOWER THAN ETHER SOLUBILITY IN WATER 46t pH NOT APPLICABLE APPEARANCE AND ODOR WATER WHITE LIQUID IS MATERIAL: LIQUID XX SOLID GAS PASTE POWDER SECTION IV - PIRE AND EXPLOSION HAZARD DATA METHOD USED LEL DEL FLASH POINT 14 *F *C T.C.C. FLAMMABLE LIMITS 1.0% 36.0% EXTINGUISHING MEDIA C02* DRY CHEMICAL, FOAM, OR OTHER NATIONAL FIRE PROTECTION ASSOCIATION (WFPA) APPROVED METHOD FOR TREATING A CLASS B FIRE. SPECIAL FIRE FIGHTING PROCEDURES SUMMON PROFESSIONAL FIREFIGHTERS. USE FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS. WATER SPRAY MAY BE INEFFECTIVE IF WATER IS USED# FOG NOZZLES ARE PREFERABLE. IF EXPOSED TO FIRE OR EXTREME BEAT# WATER SHOULD BE USED TO COOL CLOSED CONTAINERS AND PREVENT PRESSURE BUILD-UP OR POSSIBLE AUTO-IGNITION._________________________________________________________________________ UNUSUAL FIRE AMD EXPLOSION HAZARDS KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM" HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAME. VAPORS MAY CAUSE FLASH FIRE. VAPORS MAY IGNITE EXPLOSIVELY. VAPORS MAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. DUE TO PRESSURE BUILD-UP, CLOSED CONTAINERS EXPOSED TO EXTREME HEAT MAY EXPLODE. NEVER USE A WELDING OR CUTTING TORCH ON OR NEAR CONTAINER (EVEN EMPTY) AS PRODUCT OR ITS RESIDUE MAY IGNITE. DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION._____________________ SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE lOtTppm""(ACGIH1 OTHER LIMIT 100 ppm (OSHA) PERMISSABLE EXPOSURE LIMIT 100 ppm 1100 pom (VENDOR) EFFECT OF OVEREXPOSURE ACUTE - BREATHING - IRRITATION OF THE RESPIRATORY TRACT; HEADACHE, NAUSEA, DIZZINESS, WEAKNESS AND FATIGUE. EXTREME EXPOSURE CAN RESULT IN UNCONSCIOUSNESS AND EVEN RESPIRATORY ARREST. EYE CONTACT - SEVERE IRRITANT. SKIN CONTACT - PROLONGED AND REPEATED LIQUID CONTACT CAN CAUSE DEFATTING AND DRYING OF SKIN, WHICH MAY RESULT IN SKIN IRRITATION AND DERMATITIS. SWALLOWING - VOMITING MAY RESULT. PULMONARY ASPIRATION HAZARD IF VOMITING OCCURS. CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. PRIMARY ROUTES OP ENTRYINHALATION. SKIN CONTACT, SWALLOWING. EMERGENCY AND PIRST AID PROCEDURES IF BREATHED - IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, SUMMON MEDICAL ASSISTANCE IMMEDIATELY. IF BREATHING CEASES, RESTORE USING APPROVED CPR TECHNIQUES AND SUMMON MEDICAL ASSISTANCE IMMEDIATELY. IF IN EYES - FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ASSISTANCE. IF ON SKIN - WASH AFFECTED AREAS WITH SOAP AND WATER. REMOVE SOILED CLOTHING. GET MEDICAL ASSISTANCE IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. IF SWALLOWED - DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN IMMEDIATELY. ASPIRATION OF VOMITUS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY OVEf-EXPOSURB NONE WHEN USED IN ACCORDANCE WITH SPECIAL PROTECTION INFORMATION (SECTION VIII). WARNING: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING TH. CONTENTS MAY BE HARMFUL OR FATAL. SAL 000006865 ?C0 86 PC0S6 i SECTION VI - REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID HEAT, SPARKS, FLAME. STABLE XX INCOMPATIBILITY (MATERIALS TO AVOID) STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE AND CARBON DIOXIDE. HAZARDOOS MAY OCCUR CONDITIONS TO AVOID NOT APPLICABLE POLYMERIZATION WILL NOT OCCUR XX SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, AND ELECTRICAL* STATIC OR FRICTIONAL SPARKS). DO NOT SMOKE. PREVENT BREATHING VAPORS. VENTILATE AREA. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD CAUTION INFORMATION IN OTHER SECTIONS OF THIS MATERIAL SAFETY DATA FORM. DIKE AND CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. STORE IN CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF. WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.___________________________________________________________________ CERCLA < SUPERFPND) REPORTABLE QUANTITY (IN LBST ONE POUND OR REFER TO SECTION 311 CLEAN WATER ACT. RCRA HAZARDOUS WASTE NO. (40 CFR 261.33) D-001 Notes Numbers apply to F-003 solvent blend only. F-005 VOLATILE ORGANIC COMPOUND (VOC) (AS PACKAGED, MINUS WATER) 100% XX THEORETICAL 6.878 LB/GALXX ANALYTICAL6.886LB/GAL SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION WHEN USED IN RESTRICTED VENTILATION AREAS, WEAR NIOSH/MSHA APPROVED CHEMICAL/MECHANICAL FILTERS DESIGNED TO REMOVE A COMBINATION OF PARTICULATES AND VAPOR. WHEN USED IN CONFINED AREAS, WEAR NIOSH/MSHA APPROVED AIR SUPPLY RESPIRATORS OR HOODS. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE ESTABLISHED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. VENTILATION USE ONLY WITH ADEQUATE VENTILATION. USE EITHER LOCAL EXHAUST OR MECHANICAL TO MEET TLV REQUIREMENTS. VENTILATION MUST BE SUFFICIENT TO LIMIT EMPLOYEE EXPOSURE AT, OR BELOW, APPLICABLE HEALTH AND SAFETY STANDARDS. HEAVY SOLVENT VAPORS SHOULD BE REMOVED FROM LOWER LEVELS OF WORK AREA._____________________ ________________ _ PROTECTIVE GLOVES NEOPRENE OR EQUIVALENT EYE PROTECTION SOLVENT RESISTANT SAFETY EYEWEAR WITH SPLASH GUARDS. OTHER PROTECTIVE EQUIPMENT EYE BATH AND SAFETY SHOWER. SOLVENT IMPSRMEABLE CLOTHING TO PREVENT SKIN CONTACT. SAL 000006866 SECTION tX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE KEEP AWAY FROM HEAT,"" SFARKS AND FLAME. DO NOT SMOKE. EXTINGUISH ALL PILOT LIGHTS AND TURN OFF ALL SOURCES OF IGNITION INCLUDING BEATERS FANS AND OTHER NON-EXPLOSION-PROOF ELECTRICAL EQUIPMENT. DURING USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY IGNITE EXPLOSIVELY. VAPORS MAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. PREVENT BUILD-UP OP VAPORS 3Y MAINTAINING CONTINUOUS FLOW OF FRESH AIR. DO NOT STORE ABOVE 120*F OR NEAR FIRE OR OPEN FLAME. STORE LARGE QUANTITIES IN BUILDINGS TO COMPLY WITH OSHA 1910.106. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELED CONTAINERS. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. NAME;_________ WALTER STUECKEN SIGNATURE t- TITLE: LABORATORY MANAGER DATE:' Seotember 29, 1988 ., j THE INFORMATION CONTAINED HEREIN IS BASEO ON DATA BELIEVED BY GROW GROUP. INC.. TO BE ACCURATE. BUT WE DO NOT ASSUME ANY LIABILITY FOR THE ACCURACY OF THIS INFORMATION. WE NEITHER SUGGEST NOR GUARANTEE THAT ANY HAZARDS MENTIONED ARE THE ONLY ONES WHICH EXIST. ANYONE INTENDING TO RELY ON ANY RECOMMENDATION *. OR TO USE ANY EQUIPMENT, TECHNIQUE OR MATERIAL MENTIONED SHOULD ALSO SATISFY HIMSELF THAT HE CAN MEET ALL APPLICABLE SAFETY AND HEALTH STANDARDS. DETERMINATION OF THE SUITABILITY OF ANY INFORMATION OR PRODUCT FOR THE USE CONTEMPLATED BY ANY OSER, THE MANNER OF THAT USE AND WHETHER THERE IS ANY INFRINGEMENT OF PATENTS IS THE SOLE RESPONSIBILITY OF THE USER. r SUPERCEDES MATERIAL SAFETY DATA SHEET DATED 6-15-87 SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IH HANDLING AND STORAGE KEEP AWAY FROM HEA'" -- SPARKS AND FLAME. DO NOT SMOKE. EXTINGUISH ALL PILOT LIGHTS AND TURN OFF ALL SOURCES OF IGNITION INCLUDING HEATERS, FANS AND OTHER NON-EXPLOSION-PROOF ELECTRICAL EQUIPMENT, DURING USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY IGNITE EXPLOSIVELY. VAPORS KAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. PREVENT BUILD-UP OP VAPORS SY MAINTAINING CONTINUOUS PLOW OP FRESH AIR. DO NOT STORE ABOVE 120*F OR NEAR FIRE OR OPEN FLAME. STORE LARGE QUANTITIES IN BUILDINGS TO COMPLY WITH OS HA 1910.106. KEEP CONTAINER CLOSED WHEN NOT IN USE DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELED CONTAINERS DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. NAME: signature WALTER STUECKEN , TITLEi LABORATORY MANAGER DATE:' September 29, 1988 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA BELIEVED BY GROW GROUP, INC., TO BE ACCURATE, BUT WE DO NOT ASSUME ANY LIABILITY FOR THE ACCURACY OF THIS INFORMATION. WE NEITHER SUGGEST NOR GUARANTEE THAT ANY HAZARDS MENTIONED ARE THE ONLY ONES WHICH EXIST. ANYONE INTENDING TO RELY ON ANY RECOMMENDATION \ OR TO USE ANY EQUIPMENT, TECHNIQUE OR MATERIAL MENTIONED SHOULD ALSO SATISFY HIMSELF THAT HE CAN MEET ALL APPLICABLE SAFETY AND HEALTH STANDARDS. DETERMINATION OF THE SUITABILITY OF ANY INFORMATION OR PRODUCT FOR THE USE CONTEMPLATED BY ANY USER, THE MANNER OF THAT USE AND WHETHER THERE IS ANY INFRINGEMENT OF PATENTS IS THE SOLE RESPONSIBILITY OF THE USER. ( SUPERCEDES MATERIAL SAFETY DATA SHEET DATED________ 6-15-87 SAL 000006867 MATERIAL SAFETY DATA SHEET NATURALIZER AEROSOL PAGE : 01 (037927-0429 -E0016293-5049 )|OATE OF ISSUE | 07/06/89 APR w 2 <5Tt SECTION I - GENERAL INFORMATION | SUPERSEDES i 04/14/89 CHEMICAL NAME 8 SYNONYMS N/A CHEMICAL FAMILY ORANGE TERPENES SOLVENT TRADE NAME 8 SYNONYMS NATURALIZER AEROSOL FORMULA X< --MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH 01V. OF NCH CORP. ADDRESS (NUMBER. STREET. CITY. STATE & ZIP CODE) BOX 152170 IRVINS. TEXAS 75015 PREPARED BY: R1CHAR0 STOLLEY/T.S.CHEM. | PRODUCT CODE NUMBER | EMERGENCY TELEPHONE NUMBER 5049 214-438-1381 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) i HAZARD D-L1M0NENE C0M8/IRR nonylphenoxypolyethoxyethandl IRRITANT | tlv NOT EST. NOT EST. | PEL NOT EST. NOT EST. ! CAS* 5989-27-5 26027-83-3 SECTION III - PHYSICAL DATA BOILING PT.<FAHRENHEIT) [375 VAPOR PRESSURE <MM HG). jN/A | SPEC GRAVITY (H2C-1) ' COLOR [WATER WHITE :0.838-0.843 (CONTINUED) VAPOR DENSITY (AIR-1 > PH P 100K PERCENT. VOLATILE BY VClUME (%> SOLUS ILITY IN WATER VISCOSITY NATURALIZER AEROSOL SECTION III PHYSICAL DATA ! N/A ! ODOR J ORANGE | 8-9 1 ! as ! Il | SLIGHT CLARITY [TRANSPARENT EVAPORATION RATE (BU AC - 1 ) !< 1 1 j NON-VISCOUS PAGE 02 SECTION IV - FIRE ANO EXPLOSION HAZARD FLASH POINT (METHOD USED) 1 16 F. T.C.C. EXTINGUISHING MEDIA `ALCOHOL' X<--FCAM <-- FOAM | FLAMMABLE LIMITS i X<--C02 DRV X<-'CHEMICAL LEL |n/a WATER X<--SPRAY | UEL ! N/A <--OTHER SPECIAL FIRE FIGHTING PROCEDURES WEAR MOSH/MSHA APPROVED RESPIRATOR WHEN FIGHTING FIRES IN CONFINED AREAS TO PREVENT EXPOSURE TO ACRID SMOKE AND HAZAROOUS DECOMPOSITION PRODUCTS. UNUSUAL FIRE 8 EXPLOSION HAZARDS SPRAY EXPOSED AEROSOL CONTAINERS WITH WATER SPRAY TO AVOID RUPTURING. LEVEL AEROSOL (NFPA 306) NFPA HAZARD RATING (0-1NSIGNIFI CANT; 1-SLIGHT:2-MODERATE;3-HIGH:4-EXTREME ) : 1 <--HEALTH 2 <--FLAMMABILITY O <--REACT I VITY <--SPECIAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) MAY BE IRRITATING TO EYES AND SKIN. MAY CAUSE DEFATTING OF SKIN. INGESTION OF LARGE QUANTITIES CAN CAUSE NAUSEA. CRAMPS, VOMITING AND OIARRHEA. ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNUEMDNITI5 WHICH CAN BE FATAL. EXCESSIVE BREATHING OF VAPORS OR SPRAY MIST CAN LEAD TO NASAL oooooo^8 SPX- 186 95 (CONTINUED) NATURALIZES AEROSOL SECTION V - HEALTH HAZARD DATA PAGE : 03 AND RESPIRATORY IRRITATION. CHRONIC - (LONG TERM MARKEO IRRITATION TO EYES EXCESSIVE OVEREXPOSURE TO THE DERMATITIS AND CHAPPING. TARGET ORGANS: EYES. SKIN. RESPIRATORY SYSTEM EXPOSURE) SKIN CAN CAUSE PRIMARY ROUTE OF ENTRY: X<-- INHALATION <-- INGESTION X<-- ABSORPTION EMERGENCY A FIRST AID PROCEDURES INHALATION : GENERALLY NOT A HAZARO. REMOVE VICTIM TO FRESH AIR AND PROVIDE SUPPORTIVE_MEASURES EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER FOR 10 MINUTES, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. TREATMENT IS MOST EFFECTIVE WITHIN ONE MINUTE- SKIN CONTACT: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. APPLY EMOLLIENT RICH CREAM. IF IRRITATION DEVELOPS, SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET. AND GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TC VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. NOTE5 TO PHYSICIAN : GASTRIC LAVAGE IS INDICATED 00 NOT INDUCE VOMITING. SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: I ARC <--YES NTP <-- YES OSHA <--YES ACGIH <--YES OTHER <--YES X<--NO X<-NO X<--NO X<--NO X<--NO D-LIMDNENE (MAJOR COMPONENT OF OIL ORANGE TERPENES CAS* $8647-72-31 IPR-MUS TOLO: 4800MG/KG/BW 1. ORL-MUS TOLO: 67GM/KG/39W: ETA 1. NONYLPHENOX YPOLYETHOXYETHANOL CRL-RAT LD50: 2210MG/KG SKN-RBT LD50: >2G/KG 1. 1. EYE IRRITATION: SEVERE IRRITANT- BLOOD VESSELS GROWING ON CORNEA OF EYE SKIN IRRITATION PRIMARY IRRITATION SCORE: 2.1 2. SECTION VII - REACTIVITY DATA (CONTINUED) NATURALIZER AEROSOL SECTION VII - REACTIVITY DATA PAGE : 04 | X<-- STAB LE <--UNSTABL | CONDIDTIONS TO AVOID AVOID EXPOSURE TO HEAT TEMP >120 F.). SPARKS OR OPEN FLAME. INCOMPATIBILITY (MATERIALS TO AVOID) STRONG CXICIZERS SUCH AS LIOUID CHLORINE. LIOUID OXYGEN ANO SODIUM OR CALCIUM HYPOCHLORITES. HAZARDOUS DECOMPOSITION PRODUCTS OXIDES OF CARBCN AND ACRID SMOKE. HAZARDOUS ! WILL NOT I X <--OCCUR P0LVMERI2ATI0N]N/A i MAY j CONDITIONS TC AVOID <--OCCUR 1 SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED AEROSOL PACKAGING MAKES MAJOR SPILL UNLIKELY. ELIMINATE ALL IGNITION SOURCES. USE ABSDRBANT SUCH AS PAPER. VERMICULITE, ETC. TO CONTAIN SPILL. DO NOT FLUSH TO SEWER. PLACE INTO LABELED CONTAINERS. WASTE DISPOSAL METHOD DISPOSE CF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL. STATE AND LOCAL REGULATIONS. DISPOSE OF EMPTY AEROSOL CONTAINER BY WRAPPING SEVERAL LAYERS OF NEWS PAPER AROUND CAN AND DISCARDING IN TRASH. NEUTRALIZING AGENT NONE SECTION IX - SPECIAL PROTECTION INFORMATION REOUIRED VENTILATION LOCAL EXHAUST VENTILATION SUFFICIENT TO MAINTAIN WORKPLACE CONCENTRATION BELOW PERMISSIBLE EXPOSURE LIMITS. RESPIRATORY PROTECTION TYPICAL USE OF PROOUCT DOES NOT REOUIRE THE USE OF A RESPIRATOR. PRODUCT IS MISTED. USE NICSH APPROVED MASK FOR SPRAY MISTS. PROTECTIVE GLOVES NEOPRENE OR NITRILE RUBBER IF REPEATED OR PRO LONGED SKIN CONTACT OCCURS. IF SAL 000006869 (CONTINUED) NATURALIZES AEROSOL GS695SECTION IX - SPECIAL PROTECTION INFORMATIOPAtiE : 0 EYE PROTECTION , WEAR GOOGLES IF DIRECT EYE CONTACT IS LIKELY tO OCCUR. OTHER PROTECTION APRON SHOULD 8E WORN DEPENDING ON SEVERITY OF EXPOSURE. , SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE | INDOOR 120 F.C--MAX 30 F.C--M1N | X |HEATED ! PRECAUTIONS TO BE TAKEN IN HANDLING A STORING KEEP AWAY FROM IGNITION SOURCES. OTHER PRECAUTIONS KEEP AWAY FROM CHILDREN. READ ENTIRE LABEL BEFORE USING PRODUCT. !REFft I GERATED I OUTDOOR j[ SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S. NUMBER UPPER % LIMIT N/A THOSE INGREDIENTS L1STE0 ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT CF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOT IFICAT ION BECAUSE THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE ( SU6h AS FERTILIZERS AND HERBICIDES), OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES- SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--1 MOD SHIPPING NAME HAZARD CLASS <--TARIFF 6 C <--I6TA <--MILITRY Alft (APR ?t-4l j IC NUMBER j REPORT QTY (CONTINUED) NATURALIZER AEROSOL SECTION XII - TRANSPORTATION (FOR FUTURE USE) LABELS UNIT CONTAINER | LIMITED QTY DDT SPS CONTAINER ! NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) PAGE : 06 SECTION XIII - REFERENCES 1 DANGEROUS PROPERTIES OF INDUSTRIAL MATE IRALS. 6TH EDITION. N. IRVING SAX. 2. VENDOR'S MSDS. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FCRMULATION. HOWEVER, NO WARRANTY IS EXRES5ED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FCR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED CN THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. DR DISPOSAL OF THE PRODUCT. 00000687 SAL ROHM RND HRRS COMPANY CORPORATE PRODUCT INTEGRITY DEPARTMENT INDEPENDENCE MALL WEST PHILADELPHIA. PA 19105 EMERGENCY TELEPHONE 215-592-3000 IROHM AND HAAS) 800-424-9300 (CHEMTREC) ft A 05 1 HA2ARO RATING rmt 4'EXTRME 3*H1GH 2`MODERATE 1'SLIGHT y ,,< TOXICITY N 0* INS I GNIF 1C ANT "SEE SECTION IV 0 SPCCIAt 3S231 LIST 7 material AMBERLYST 15 WET Resin MATERIAL SAFETY DATA SHEET NOT OSHA HAZARDOUS NOT WHMIS CONTROLT.ra CODE KEY DOT HA2ARO CLASS 69286 906233-7 NONREGULATED DATE ISSUED 11/02/88 FORMULA Not applicable CHEMICAL NAME OR SYNONYMS Strong acid cation exchange resin (hydrogen form) |l~- COMPOSITIONAL INFORMATION! CAS REG. NO. APPROX WT % TWA/TLV R&H OSHA ACGIH Styrene/divinylbenzene cation exchange resin NONHAZ Water NONHAZ 40-50 50-60 NE NE NE NE NE NE NE = None established Ill - PHYSICAL PROPERTY INFORMATION] APPEARANCE ODOR pH. Beads; pH (aqueous slurry) 3.0 max. VISCOSITY NA MELTING OR FREEZING POINT 0C/32F (water) SOLUBILITY IN WATER Negligible [plash point 'ha EXTINGUISHING MEDIA n foam n BOILING POINT 100C/212F (water) PERCENT VOLATILE IBY WEICHTI VAPOR PRESSURE Imm Hgl 17 @ 20C/68F SPECIFIC GRAVITY {WATER* 11 VAPOR DENSITY <AIR*1) Less than 1 EVAPORATION RATE (BUTYL ACETATE11) 50-60 (water) 1.1-1.4 Less than 1 1 111 - FIRE AND EXPLO SION HAZARD INFORMATION! AUTO >GNITON TEMPERATURE 500C/932F (est.) LOWER EXPLOSION LIMIT (%) NA 1 UPPER EXPLOSION LIMIT {%) | NA ca => nn'gsM.r. ra s&y n ot>" SPECIAL FIRE FIGHTING PROCEDURES Wear self-contained breathing apparatus (pressure-demand, MSHA/NlOSH-approved or equivalent) and full protective gear. UNUSUAL FIRE AND EXPLOSION HA2ARDS Toxic combustion products include oxides of sulfur. | IV - HEALTH HAZARD INFORMATION! ROHM AND HAAS RECOMMENDED WORK PLACE EXPOSURE LIMITS STEL = None established______________________________________________________ EFFECTS OF OVEREXPOSURE Eye Contact: Product, as supplied, can cause eye irritation. EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Flush eyes with large amounts of water for at least 15 minutes. medical attention. Get prompt I 1s SAL 000006071 *ry(\iCL 004281 STABILITY 1 - htAUIIVIIT INhUHWIAIIUN CONDITIONS TO AVOID e~A 05 l aG3STA*- UNSTABLE Temperatures over 200C/392? HAZARDOUS DECOMPOSITION PRODUCTS dermal decomposition may yield styrene monomer, divinylbenzsnef and sulfur oxides. ZARDOUS POLYMERIZATION Omay OCCUR nr)w,LL N0T 1 * J OCCUR CONDITIONS TO AVOID None known incompatibility (materials tq AvoiDiftvoid contact with concentrated nitric acid or any other strong P^water nnTHB oxidizing agents at ail times. | VI - SPILL OR LEAK PROCEDURE INFORMATION j ! steps TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Floor may be slippery. Use care to avoid falls. recovery or disposal. Sweep up and transfer to containers for waste oisposal methods Unused resin_may be incinerated or land~filled in facilities meeting local'7 state and federal regulations. For contaminated resin, the user must determine the hazard and use an appropriate disposal method. --------------------------------------------------- IW - SPECIAL PROTECTION INFORMATION! VENTILATION TYPE Normal room ventilation. RESPIRATORY PROTECTION None required for normal operations. PROTECTIVE GLOVES None required OTHER PROTECTIVE EQUIPMENT Eyewash facility EYE PROTECTION Safety glasses (ANSI 2-87.1 or approved equivalent) ( VI11 -STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE MAX 60C/140F MIN 0C/32F INDOOR YES HEATED NO REFRIGERATED NO NOTE: Store at ambient temperatures. Avoid repeated freeze-thaw cycles. OUTDOOR YES NOTE: Ground ion exchange resins should be treated as potential eye irritants. A finely ground form of a structurally related strong acid cation exchange resin produced severe rabbit. eye irritation. NOTE: The maximum operating temperature for this product is 121C/250F. destruction and loss of capacity will occur above this temperature. 1IX -- TOXICITY INFORMATION! No toxicity data available for this product. Functional group X - MISCELLANEOUS INFORMATION) Caution: Do not pack column with dry ion exchange resins. Dry beads expand when wetted; this expansion can cause a glass column to shatter. Caution: Nitric acid and other strong oxidizing agents can cause explosive-type reactions when mixed with ion exchange resins. Proper design of equipment to prevent rapid build-up of pressure is necessary if use of an oxidizing agent such as nitric acid is contemplated. Before using strong oxidizing agents in contact with ion exchange beads, consult sources knowledgeable in handling these materials. AMBERLYST IS A NA . NOT APPLICABLE C CEILING VALUE TRADEMARK OF KEY ROHM AND HAAS 906233-7 COMPANY OR ONE OF ITS DATE OF ISSUE 11/02/88 SUBSIDIARIES OR AFFILIATES--. --- SUPERSEDES _______________Q7/I1/87 Il-it |H| 'jnMi I .UN L UN" A.NLU rlihtif. 'V L.-I- C DNSiCt RID ACCURATE HOWEVER. NO WARRANTY IS EXPRESS'D OR IMPllCD RtGAROING THE ACCURACY 0> T he SC DATA OR THE RESULTS TO BE OBTAINED f ROM THE USE THERE O' RC'IV AND HAAS COMPANv ASSUMES ftf C pni|( ipn. IT. IOB PfB^ONtl INJURY OR PROPERTY 0AM4GC TO v-fNOCES. USERS OR THIRD PARTIES CAUSED BY THE MATERIAI SUCH VENDEES OR USERS ASSUME All Rises ASSOCIATED WITH THE USE OF THE MATE RIAI SAL 000006872 uoo MATERIAL SAFETY DATA SHEET An oxptanmtian ot tfw terms uood htroirr may be found kt OSHA 20 CFR 1910.1200, tvatabto from OSHA ngtanal or mom office*. (Similar to U.S. Doportmont <A Labor Form OM8 1216-0072 and ganoralty accoptod In Canoda for information purpo--t) Do Not Ouplicata Thl* Form. Request an Original. M-4959-A May 1989 *05 2 PRODUCT Molecular Sieve Type MRG-C CHEMICAL NAME FORMULA Sodium/Aluminosilicate Na?0, MgO, AljOj. StOa SYNONYMS CHEMICAL FAMILY MOLECULAR WEIGHT Zeolite Molecular Sieve Not Applicable TRADE NAME UOP Molecular Sieve formerly UNION CARBIDE Molecular Sieve A complex of elements end compounds composed of material shown below. NOTE: In the table below, the symbol "<" means "less than". MATERIAL (CAS/TSCA NO.) Sodium Oxide (1313-59-3) Magnesium Oxide (1309-48-4) Aluminum Oxide (1344-28-1) Silicon Oxide (7631-86-9) Wt (%) <30 <5 <30 <50 1988-1969 ACGIH TLV-TWA (OSHA-PEL) None established 10 mg/m3 Fume (None established) (10 mg/m3 Fume Total) ( 5 mg/m3 Respirable fraction) 10 mg/m3 as Al 10 mg/m3 (10 mg/m3 Total dust) ( 5 mg/m3 Respirable fraction) ( 6 mg/m3) BOILING POINT, 760 mm. Hg Not Applicable FREEZING POINT SPECIFIC GRAVITY (HaO - 1) 2.1 VAPOR DENSITY {air = 1) Not Applicable PERCENT VOLATILES SY VOLUME Not Applicable APPEARANCE AND ODOR Product is a Ian pellet; odorless. VAPOR PRESSURE AT 20 C. SOLUBILITY IN WATER, % by wt. EVAPORATION RATE (Butyl Acetate = 1) Not Applicable Not Applicable Not Applicable Not Applicable IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA (1 -800-822-4357) In Canada 514 -- 640-6400 For routine information contact your local supplier UOP urges each customer or recipient of this MSDS to study it carefully to become aware of and understand the potential hazards associated with the product. The reader should consider consulting reference worfcs or individuals who are experts in ventilation, toxicology, and fire prevention, as necessary or appropriate to use and understand the data contained in this MSDS. To promote safe handling, each customer or recipient should: (1) notify its employees, agents, contractors and others whom it knows or believes will use this material or the information in this MSDS and any other information regarding hazards or safety; (2} furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees, customers, and other users of the product of this information. UOP MOLECULAR SIEVE DIVISION UOP CANADAQ MOLECULAR SIEVE DIVISION Copyright 1969 UOP SAL 000006873 Page 1 of 4 M-4959-A PRODUCT: Molecular Sieve Type MRG-C p A A C O -1 M-4959-A THRESHOLD LIMIT VALUE: See Section II. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING -- No evidence of adverse effects from available information. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- May cause irritation of the nose and throat, accompanied by cough and chest discomfort. SKIN CONTACT -- May cause irritation seen as local redness and/or burns. EYE CONTACT -- May cause irritation seen as excess redness of the conjunctiva and/or burns. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: Prolonged inhalation may cause lung damage. OTHER EFFECTS OF OVEREXPOSURE: None currently known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Breathing of dust may aggravate asthma and inflammatory or fibrotic pulmonary disease. iRGENCY AND FIRST AID PROCEDURES: SWALLOWING -- If ingested in large quantities, then drink 2 glasses Qf water. Induce vomiting if the patient is conscious. SKIN CONTACT -- Wash the contacted area with soap and water. INHALATION -- Remove the person to fresh air. EYE CONTACT -- Immediately flush eyes with water for at least 15 minutes. NO TBS TO PHYSICIAN: This product is a desiccant and generates heat as it adsorbs water. The used product can contain material of a hazardous nature, identify that material and treat accordingly. 000006874 SAL PRODUCT: Molecular Sieve Type MRG-C t C AO 5 2 M-4959-A * May 1989 FLASH POINT (test method) Does not bum AUTOIGNtTION TEMPERATURE Not Applicable FLAMMABLE LIMITS LOWER IN AIR, % by volume Nol Applicable UPPER Not Applicable EXTINGUISHING MEDIA: Unused material will not burn. Use media appropriate for surrounding fire SPECIAL FIRE FIGHTING PROCEDURES: Depends on the use of the material. Used material may contain products of a hazardous nature. The user of this product must identify the hazards of the retained material and inform the fire fighters of these hazards. UNUSUAL FIRE AND EXPLOSION HAZARDS: In their fresh unused state, molecular sieves are not flammable. When exposed to water, however, they can get quite hot. When first wetted they can heat to the boiling point of water. Flooding will reduce the temperature to safe limits. STABILITY UNSTABLE STABLE X CONDITIONS TO AVOID: The addition of moisture (water) without flooding can cause rise in temperature from heat of adsorption and contact with skin might result in bums. INCOMPATIBILITY (Materials to Avoid): Sudden contact with high concentrations of chemicals having high heats of adsorption such as olefins, HCI, etc. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrocarbons and other, materials that contact the molecular sieve during normal use can be retained on the sieve, ft is reasonable to expect that decomposition products will come from these retained materials of use. The molecular sieve itself does not readily decompose unless subjected to extreme temperature or chemical conditions, if such decomposition did occur the products would include the mix of oxides listed in Section II. HAZARDOUS POLYMERIZATION May Occur Will not Occur CONDITIONS TO AVOID: None currently known. X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Sweep the spill area. Collect and place the spilled material in a waste disposal container. Avoid raising dust. WASTE DISPOSAL METHOD: Discard any product (including any retained materials of use), disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, State and local regulations. SAL 000006875 pr ri irT* Mftincutar Sieve Type MRG-C C A05 2 M-4959-A May 1989 hi-aPIRATORY PROTECTION (specify type): A NK5SH/MSHA approved respirator for protection against dust, mist or vapor is recommended for operations when the permissible exposure limit might be exceeded. LOCAL EXHAUST -- Local exhaust ventilation is recommended for operations where the permissible exposure limit might be exceeded. VENTILATION MECHANICAL (general) -- Not applicable - See Local Exhaust. SPECIAL -- Not applicable See Local Exhaust. OTHER -- Not applicable - See Local Exhaust. PROTECTIVE GLOVES: Use gloves to avoid PROLONGED skin contact. EYE PROTECTION: Safety glasses or goggles selected as per OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Select in accordance with OSHA 1910.132 and 1910.133. LABEL: CAUTION OUST MAY IRRITATE EYES, NOSE. THROAT ANO SKIN. Avoid breathing dust. *oid contact with eyes and skin. * container slowly. * with adequate wtftetion. Do not put in mouth or pour liquid into product Bums can rasuM. ____ BEFORE HANDLING OR USING. READ AND UNDERSTAND CURRENT MATERIAL SAFETY DAZA SHEET FOR THIS MATERIAL. FIRST AIO -- EYE CONTACT: Immediately flush with water tor at least IS minutes. Call a physician If Irritation persist*. SWkLLOWlNQ: Give two or more glasses of water. iNHALEP: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT: Flush with plenty of water 24 HOUR EMERGENCY ASSISTANCE PHONES USA 800-822-4357 CANADA 514-640-6400 USA FROM OVERSEAS 304-744-3487 OTHER HANDLING ANO STORAGE CONDITIONS: pH range if in aqueous slurry 8-11. Designers of processes and fabricators of equipment should read UOP's free booklet. Precautions and Sate Practices for Handling Mofecuter Steves in Process Units, M-1001. Request a copy from your OOP representative. Under the TSCA rules tor chemical mixtures and naturally occurring substances tha EPA defines this product to be a stetuteory mix, therefore, only its component oxides or metals shown in Section II of this MSOS are in the inventory The human and tha erwcnmentel hanrda ere, howmtec not the atanmadoncf the hazards of the components because the components do not separate from the product (see Section VI of this MSOS). Tha hazards discussed In this MSDS are based on the product as a whole. Superfund Amendments and Reauthortzatlon Act of 1966 (SARA) Tttte Ifl requires emergency planning based on Threshold Ptarming Quantities (TPO's) and refeass reporting based on Reportable Quantities (RQ's) tn 40 CFR 355 (used lor SARA 302, 304, 311 end 312). Components present in this preduct at a level which could require reporting under the statute are: ****NONE*a** Superfund Amendments and Reaulhonzation Act of 1986 (SARA) Title ill requires submission of annual reports of release of toxic chemicals that appear >n 40 CFR 372 (for SARA 313). This information must be included m all MSDSa that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: aluminum odds. . D.O.T.: Hazard Class Not a corrosive, flammable, irritant, or explosive materiel. Not a Class B poison by skin contact or acute Inhalation. PROPOSITION 65: This product contains no levels of listed substances, which the Stale of Caftfomia has found to causa cancar, birth defects or other reproductive harm, which would require a warning under the statute. This product is not classified as a controlled product under Canada's Federal Hazardous Product Act (WHMIS). The opinions expressed herein are those of qualified experts within UOP. We believe that the information contained herein is current rs of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of ihe product are not within the control of UOP, it is the user's obligation to determine the conditions of safe use of the product GENERAL OFFICES IN THE USA: IN CANADA: UOP UOP Canada Molecular Sieve Division Molecular Sieve Division 25 East Algonquin Road 245 Eglington Ave. East Suite 310 ycf> Des Plaines. IL 60017-5017 Toronto. Ontario M4P 3B7 Other offices in principal cities all over the world. UNION CARBIDE MOLECULAR SIEVES M-4959-A 89-0946 5/B9 1M Paye 4 of 4 Lithographed in U S A. * PRODUCT OF UOP SAL 000006376 05/2 *0, 10:22 0014 79$ 2204 UNION CARBIDE UOP MATERIAL SAFETY DATA SHEET U0P Special 020A KAY, 1990 0002 C A 05 3 An explanation of the terras used herein may be found In OSHA 29 CFR 1910. 1200, available from OSHA regional or area offices. (Similar to U.S. Department of Labor For* OHfi 1213-0072 and generally accepted In Canada for Intonation purposes). Do not Duplicate This Form. Request an Original - I. PROOUCT IDENTIFICATION >ROCOCT: Molecular Sieve Type MRG-D LEXICAL NAME: Sodium Aluml nosilt cate SYNONYMS: Silicic Acfd/ATumlnosl11 cate Mix formula: n^o, AI2O3, SIO* CHEMICAL FAMILY: Amorphous Stllco/ Alumlnate TRADE NAHE: UOP* Adsorbent MRG-D, formerly Union Carbide* Adsorbent HRG-0 MOLECULAR HEIGHT: Not Applicable II. HAZARDOUS INGREDIENTS A complex of elements and compounds composed of material shown below. NOTE: In the table below, the symbol * < means "less than* y^RIAL CCAS/TSCA ,uni Oxide 0313-59-3) Aluminum Oxide (1344-28-1) Silicon Oxide (763I-S6-9) Ht.Cl) 1989-=_J 990 ACGIH TLV-THA (QSHA-PEL) None established 10 mg/3 as A1 (None established) <10 rag/n3 Total dust) < 5 mg/m3 Respirable fraction) 10 mg/m3 Total dust <6 mg/m3 III. PHYSICAL DATA N/A Not Applicable BOILING POINT, 760 mm. Hg: N/A FREEZING POINT: N/A SPECIFIC GRAVITY (H2Q-1): 2.1 (particle) VAPOR PRESSURE 20*C: N/A VAPOR DENSITY <a1r-1>: N/A SOLUBILITY IN H2O Cwt t): N/A PERCENT VOLATILES (volume): N/A EVAPORATION RATECButyl Acetate-1): N/A APPEARANCE AND ODOR: Product is In the form of pellets, odorless. Sal 000006877 For routine Information contact your local supplier. UOP urges each customer or recipient of this HSDS to study It carefully to become aware of 'd understand the hazards associated with the product. The reader should consider consulting .ference works or Individuals who are experts In ventilation, toxicology, and fire prev*^tion, as necessary or appropriate to use and understand the data contained In this MSDS. promote safe handling, each customer or recipient should: (!) notify Its employees, agents, contractors and others whom It knows or believes will use this material or the information in this MSDS and any other Information regarding hazards or safety; (2) furnish this same infor mation to each of its customers for the product; and (3) request such customers to notify -their employees, customers, and other users of the product of this Information. Copyright <c> 1990 UOP Page 1 of V2\A ^7 05/5 _/*0 10;57 0014 789 2204 UNION CARBIDE U 0? jqouCT: Molecular Steve Type MRG-D ; 4058 emergency phone number Special 02QA KAY, 1990 In USA: UOP 708-391-2123 CHEMTREC 800-424-9300 in Canada: CANUTEC 613-996-6666 From other Countries: CHEMTREC 202-483-7616 XV. HEALTH HAZARD DATA HRESHOLD LIMIT VALUE: See Section IIJTECTS OF SINGLE <ACUTE) OVEREXPOSURE: ^ua\ 1 owing - No evidence of adverse effects from available Information. yiK ABSORPTION - No evidence of adverse effects from available information. TNHAIJUTON - May cause Irritation of the nose and throat* accompanied by cough and chest discomfort. <fciN CONTACT - May cause Irritation and local reddening. eye CONTACT - May cause eye Irritation* retina diseases, and choroid atrophy. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: May cause upper respiratory tract Irritation 'h discomfort of nose and throat. If high concentrations are Inhaled over ^ iong period of time, lower respiratory tract Irritation may result In coughing and production of sputum. Submicron amorphous silica does not cause pneumonoconi os Is in roan Lung damage may result. OTHER EFFECTS OF OVER LIKE: Hone currently known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicology Information and of the physical and chemical properties of the material suggest that overexposure Is unlikely to aggravate existing medical conditions. EMERGENCY AND FIRST AID PROCEDURES: SHALLOWING - If Ingested In Urge quantities, then drink 2 glasses of water. Contact physician for permission to Induce vomlttlng. SKIN CONTACT - Hash the contacted area with soap and water. INHALATION - Remove the person to fresh air. If symptoms persist, see a physician. EYE CONTACT - Flush eyes with water for 15 minutes. See a physician, preferably an ophthalmologist; Immediately. NOTES TO PHYSICIAN: This product Is a desiccant and generates heat as It adsorbs water. The used product may be contaminated by material of a hazardous nature. Identify that material and treat symptomatically. V. FIRE AND EXPLOSION HAZARD DATA H/A - Hot Applicable FLASH POINT <Test Method): Does not burn FLAMMABLE LIMITS IN AIR (vol D LOWER: N/A i nnn i v**f> AUTOIGNITION TEMPERATURE: N/A UPPER: N/A 00000691 SAL Page 2 of 5 __MZ* /gO 10-37 QU 769 2204 UNION CARBIDE H4 u 0 P Q0< *RT XTT: Molecular Sieve Type MRG-0 EXTINGUISHING MEDIA: Unused material will not burn, surrounding fire. Special 02GA 'Pi OH53 Use media appropriate for SPECIAL FIRE FIGHTING PROCEDURES: Depends on the use of the material. Used material jay contain products of a hazardous nature. The user of this product must Identify the lazards of the retained material and Inform the fire fighters of these hazards. JNUSUAL FIRE AND EXPLOSION HAZARDS: In their fresh unused state, the adsorbent Is not flamnable. When exposed to water, however. It can get quite hot. Hhen first wetted It can heat to the boiling point of*water. Flooding will reduce the temperature to safe limits. VI. REACTIVITY DATA STABILITY Stable X Unstable CONDITIONS TO AVOID: Moisture Cwater) can cause rise in temperature which might result in burn. r COMPATIBILITY (Materials to Avoid): Sudden contact with high concentrations of c. .micals having high heats of adsorption such as olefins, HC1, etc. [ \RD0US DECOMPOSITION PRODUCTS; Hydrocarbons and other materials that contact the aosorbent during normal use can be retained on'the adsorbent. It is reasonable to expect that decomposition products will come from these retained materials of use. The adsorbent Itself does not readily decompose unless subjected to extreme temperature or chemical conditions. If such decomposition did occur the products would Include the mix of oxides listed in Section II. HAZARDOUS POLYMERIZATION May OccurHI 11 Not Occur X CONDITIONS TO AVOID: None currently known. VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Sweep the spill area. Collect and place the spilled material In a waste disposal container. Avoid raising dust. HASTE DISPOSAL MET7D: Discard any product (Including any retained materials of use), disposable container or liner In an environmentally acceptable manner. In full compliance with Federal, State and local regulations. RCRA HAZARDOUS WASTE NO.: Not Federally Regulated. VIII. SPECIAL PROTECTION INFORMATION k--iPIRATORY PROTECTION (specify type): A NIOSH/MSHA approved respirator for protection against dust Is recommended for operations where PEL might be exceeded. SAL 000006879 ----- *> *> r 03/30/90 789 2204 UNION CAKEIDE OCUCT:Holecular Sieve Type HRG-0 > 0 58 VENTILATION UOP Special 020A MAY, 1990 kfi 003 XAL EXHAUST -- Local exhaust ventilation Is recommended for operations where PEL Ight be exceeded. CHANICAL (general) -- Not applicable >ECIAL -- Not applicable THER -- Hot applicable flOTHTIVE GLOVES: Use gloves Impermeable to dust where prolonged hand contact Is osslble. re PROTECTION: Safety glasses or goggles selected as per 0SHA 29 CFR 1910.133. JTHER PROTECTIVE EQUIPMENT: Eyewash fountain. LABEL: IX. SPECIAL PRECAUTIONS CAUTION DUST MAY IRRITATE ETES, NOSE, THROAT AND SKIN. Avoid breathing dustvoid contact with eyes and skin, open container slowly. Use With.adequate ventilation. Do not put In mouth or pour liquid Into product: Burns can result. BEFORE HANDLING OR USING, READ AND UNDERSTAND CURRENT MATERIAL SAFETY DATA SHEET FOR THIS MATERIAL AND. WHEN APPROPRIATE, ALSO READ SAFETY BOOKLET H-1001. FIRST AID - EYE CONTACT: Immediately flush with water for at least 15 minutes. Call a physician If Irritation persists. SHALLOWING: Give two or more glasses of water. ].mAl_ED: Remove to fresh air. If not breathing, give artificial respiration. If breathing Is difficult, give oxygen. Call a physician. SKIN CONTACT: Flush with plenty of water. OTHER HANDLING AND STORAGE CONDITIONS: pH range If In aqueous slurry 3.5-B.O. Designers of processes and fabricators of equipment should read UOP's free booklet, "Precautions and Safe Practices for Handling Molecular Sieves In Process Units", H-1001. Request a copy from your UOP representative. Pouring dry material can cause static electricity build-up. Ground container where electric sparks must be prevented* Keep container sealed tightly to maintain product quality. X. REGULATORY INFORMATION Under the TSCA rules for mixtures and naturally occurring substances the EPA considers this product to be a statuatory mix, therefore, only Its component oxides or metals 'hovn In Section II of this MSDS are In the Inventory. The human and the environmental azards are, however, not the saturation of the hazards of the components because the components do not separate from the product (see Section VI of this HSDS). The hazards discussed In this MSDS are based on the product as a whole. Copyright (c) 1990 UOP SAL 000006880 Page 4 of 5 0S/30/90 10:38 --P914. 759 2204 ;ODUCT:HolecuUr Sieve Type MRG-D UNION CARBIDE 444 U 0 P Qiooe Special 020A HAY, 1990 ^ A C*058 il fund Amendments and Reauthorization Act of 1986 (SARA) Title III requires lergency planning based oh Threshold Planning Quantities (TPQ's) and release reporting .$ed ort Reportable Quantities (RQ's) in 40 CFR 355 (used for SARA 302, 304, 311 and ,2). Components present In this product at a level which could require reporting under ie statute are: ****N0NE**** jperfund Amendments and Re authorization Act of 1986 (SARA) Title III requires ubmfsslon of annual reports of release of toxic chemicals that appear In 40 CFR 372 for SARA 31.3). This Information must be Included In all HSOSs that are copied and istrlbuted for this material. ^nponents present In this product at a level which could require reporting under the Utute are: ****H0HZ****. -O.T.: Hazard Class - Not a corrosive, flananable, irritant, or explosive material, ot a Class B poison by sMn contact or acute Inhalation. ROPOSITION 65: This product contains no levels of listed substances, which the State f California has found to cause cancer, birth defects or other reproductive harm, which ould require a warning under the statute. his product Is not classified as a controlled product under Canada's Federal Hazardous r ict Act (KHMIS). A*ft Title III: Product is In none of the Health Hazard Categories. *he opinions expressed herein are those of qualified experts within UOP. He believe hat the information contained herein Is current as of the date of this Material Safety Jata Sheet. Since the use of this information and these opinions and the conditions of jse of the product are not within the control of UOP, It Is the user's obligation to ietennlne the conditions of safe use of the product. GENERAL OFFICES: IN THE USA: UOP Molecular Sieve Division 25 East Algonquin Road Des Plaines, IL 60017-5017 IN CANADA: UOP Canada Molecular Sieve Division 245 Egllngton Ave. East Suite 310 Toronto, Ontario H4P 3B7 Other offices In principal cities all over the world UOP a MOLECULAR SIEVE DIVISION UOP CANADA MOLECULAR SIEVE DIVISION rr-y iron nrip SAL 000006881 Page S of 5 2-vf/G+i b-.T^j. MATERIAL SAFETY DATA SHEET APPROVES BY U S LABOR SEPT, ESSENTIALLY SIMILAR TO FORM QSHA 174 PRODUCT IDENTITY; Four Star Lacquer Thinner FC085 I. SUPPLIER SOUTHNEST 50LV I CHEN P 0 BOI 41165 HOUSTON,Tl 77241 PHONE; 713-937-9300 CHENTREC PHONE: I-BI0-424-9JI# II. HAZARDOUS INGREDIENTS Section 313 Supplier Notification This product contains the indicated <l) toiic chemicals subject to the reporting requireaents ol Section 313 of the Emergency Planning L Community Right-lo-Knon Act of 1986 I of 4# CFR 372. This information lust be included in ill NSDSs that are copied and distributed for this eaterial. HATERIAL IToluene lAcetone Isopropsnol tNethanol HATERIAL Toluene Acetone Methanol HATERIAL Methanol Toluene Toluene CAS IBB 00-3 67-64-1 47-63-0 67-54-1 CAS 110-88-3 67-64-1 67-56-1 CAS 67-56-1 108-68-3 iia-BB-3 PEL (OSHAI TLV (ACGIH) SARA TITLE HI NT. Z (RE6. SECTION) 106 ppa 160 ppa 52 (311,312,313,RCRAI 756 ppe 750 ppa 38 (311,312.313,RCRAI 406 ppa 461 ppa Not Applicable 206 ppa(S) 20f ppafS) 3 (311,312,313,RCRAI CEILING STEL I0SHA t ACS1HI 306 ppa 151 ppa None known 1001 ppa None Known 250 ppi LOHEST KNOMN LETHAL DOSE INFORMATION Lowest Known ID56 (ORAL) 1601 eg/lcg (Han I Lowest Known LC56 (VAPORS) 5300 ppa (Nice! Lowest Known LD56 (SKIN) 4006 ig/kg (Rabbits) HEALTH IKfPAh 2 HAIARI RATIN6 HEALTH (UNIS): 1 FLAMMABILITY; 3 REACTIVITY: 6 SARA SECTION 313 HA7AR0S; Acute Health, Fire DOT SKIPPING NAME: Compound Cleaning, Liquid 1NA199J) DOT DRUM LABEL: Flanable Liquid III. PHYSICAL DATA BOILING RANGE l 6RAV1TY 6 6#'F : API l SPECIFIC GRAVITY INater=l) i POUNDS/GALLON : VAPOR PRESSURE (aa of Hg)l20 VAPOR DENSITY <aif*1> t NATER ABSORPTION : ACID ABSORPTION (05Z H2S041 i DRY TIME (Ether=1> ; l VOLATILE BY VOL ; APPEARANCE ; ODOR ; SOI VENCY FARAMETFRS: HKB (Hydrogen Bonding! : PKB (Polarity) : DKB (Disprrsionl : RURACIIVE IMDEI : MIXED ANILINE POINT (Acid InsoDl 56 87 lll'C / 133 189 232'F 38.B .831 6.919 B7.9 2.6 Appreciable Appreciable 3*7 101.1 Liquid^ater-Hhite Ketone 26.3 46.6 33.1 1.428 9'C / 4B*F SAL 000006882 C035 PRODUCT IDENTITY! Four Star Lacquer Thinner FA6 2 IV. FIRE * EXPLOSION HAZARDS LONER FLAMMABLE UNIT IN AIR (X by volli 2.1 FLASK POINT (TEST METHOD)! -tt*C / 2*F (ICC) (Lowest Component! FLAMMABILITY CLASSIFICATION! elm I I EXTINGUISHES \ NFPA Clast 8 extinguishers (C0t or foot) MEDIA i for class 1 8 liquid Tires. SPECIAL FIRE FI6HTING PROCEDURES i Mater spray eay be ineffective on fire but can protect fire fighters A cool closed containers. i use fog nozzles if eater ia used. Do not enter confined Ure-space without full i bunker gear. (Helaet with face shield, bunker coats, gloves l rubber boots). 2 Use N10SH approved positive-pressure self-contained breathing apparatus. UNUSUAL i EXPLOSION i AND FIRE i PROCEDURES! i EXTREMELY FLAMMABLE!! Vapors can cause flash fire. Keep container tightly dosed. oxidizers, heat, sparks, electric equipment I open flaee. Closed containers say explode if exposed to extreee heat. Applying to hot surfaces requires special precautions. Eepty container very hazardous! Continue all label precautions! Isolate froa V. HEALTH EFFECT DATA THRESHOLD UNIT VALUE! 191 ppe (Evaporated Blend) PREVENTION: Of OVER-t EXPOSURE: Use only with adequate ventilation. Avoid contact with skin l eyes. Avoid breathing of vapor or spray list. ORGANIC EFFECTS: INHALIN61 Anesthetic. Irritates respiratory tract. OF ACUTE: Can cause serious nervous systee depression. OVER- : Can cause daaage to kidneys, blood, nerves, liver b lungs. EXPOSURE: EYE V SKIN CQNTACJtPrieary irritation to skin, defatting. deriatitis. t Prieary irritation to eyes, redness, tearing, blurred vision. : Absorption thru skin increases exposure. : SNALLQN1N6: Harnfgl or fatal if swallowed. 1 Swallowing can cause abdoainal irritation, nausea, voaiting and diarrhea. ORGANIC EFFECTS! Vapor hareful. Breathing vapor can cause irritation. OF CHRONIC: Can cause daaage to kidneys, blood, nerves, liver t lungs. OVER- i EYE ( SKIN CONTACTtUquid can cause eye irritation. EXPOSURE: Nash thoroughly after handling. : Absorption thru skin say be haraful. : Studies with laboratory aniials indicate this product can cause daaage to fetus. CANCER HAZARD: This product has no carcinogens listed by IARt,NfP,NIOSH,OSHA or AC6IH, : as of this date, greater or equal to 0.XX. i This product aav contain less than Ilf ppe of Benzene. i Not considered hazardous in such low concentrations. CONDITIONS! Persons with severe skin, liver or kidney probleis should avoid use. AGGREVATED: ENER6ENCY I 1 In case of contact with skin, flush with plenty of water. For eyes, FIRST AID i flush with plenty of water for IS einutes t get eedicat attention. FROCEDURES: After high vapor exposure, reiovc to fresh air, If breMthing is difficult : give oxygen. If breathing has stepped give artificial respiration. : If swallowed, CAIL A PHYSICIAN IHN'.DlATtLY! : Never give anything by enuth to an unconscious person. SAL 000006383 PRODUCT IDENTITY] FouriDStar Lacquer Thinner PAGE 3 VI. REACTIVITY DATA STABILITY : Stable CONDITIONS TO AVDIDt Isolate froa oxidizers, heat, sparks, electric equipment I open flase. MATERIALS TO AVOID i Isolate Trot strong oxidizers such as permanganates, chroeates I peroxides. HAZARDOUS i Carbon Monoxide, Carbon Dioxide froa burning. DECOMPOSITION] PRODUCTS I VII. SAFE HANDLING Sc USE PRECAUTIONS SPILL OR LEAK PROCEDURES t Stop spill at source. Dike area t contain. Puap spilled liquid I put contaainated soil t in DOT approved containers for disposal. Label ieeediately. t Clean up reiainder with absorbent aaterials. HASTE DISPOSAL t Dispose of waste by legal aethods complying with local, state t Federal regulations. METHOD : If questions exist, contact the appropriate agencies. OTHER i Vapors aay ignite explosively I spread long distances. Prevent vapor buildup. PRECAUTIONS] Put out pilot lights I turn off I ignition sources during use I until all vapors are gone, s Do not store above 49*C/I2#*F. t Store large aaounts in structures aadt for OSHA Class ! B liquids, t Avoid free fall of liquid. t Ground containers when transferring. Do not flaae cut, saw, drill,braze or weld, i Eapty container very hazardous! Continue all label precautions! VIII. CONTROL MEASURES RESPIRATORY PROTECTION: Ventilate to keep air below 99 ppe. If over TLV, in accordance with 29 CFR 1911.134 (SPECIFY TYPE) : Use N10SH approved positive-pressure self-contained breathing apparatus. : Consult Safety Equipment Supplier, use explosion-proof equipment. VENTRATION : LOCAL EXHAUST i Necessary MECHANICAL(GENERAL) i Acceptable : SPECIAL i None OTHER t None PROTECTIVE : Hear OSHA Standard goggles or face shield. Consult Safety Equipient Supplier. CLOTHING] Hear gloves, apron 1 footwear iepervious to this eaterial. Nash clothing before reuse. NOTICE SOUTHWEST SOLV I CHER disclaims all expressed or ieplied warranties of aerchantability or fitness for a particular purpose, with respect to the product or intonation provided herein. All intonation appearing herein is based upon data obtained froe lanufacturers and/or recognized technical sources. Hhile the intonation is believed to be accurate, we take no representations as to its accuracy qr sufficiency. Conditions of use are beyond our control, and therefore users are responsible for verifying the data under their own operating conditions to delenine whether the product is suitable for their particular purposes and they assuee ail risks of their use, handling, and disposal of the product. Users also assuee al risks in regards to the publication or use of, or reliance upon, intonation contained herein. This intonation relates only to the protect designated herein, and dors not rel/te to its use in(udbin.ition with any oilier aiteriat or in any other process. OAfE : MAY I7t 1991 SAL 000006884 cass SOUTHWEST SOLV Si CHEH p O BOX 41065 HOUSTON,TX 77241 PHONEi 713-937-9300 Four Star Lacquer Thinner CONTAINS: TOLUENE,ACETONE,ISOPROPANOL,METHANOL DANGER!! EXTREMELY FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE INHALING: ANESTHETIC. IRRITATES RESPIRATORY TRACT ACUTE QVERE1P0SURE CAN CAUSE SERIOUS NERVOUS SYSTEM DEPRESSION VAPOR HARMFUL. BREATHING VAPOR CAN CAUSE IRRITATION ACUTE OVEREXPOSURE CAN CAUSE DAMAGE TO KIDNEYS. BLOOD. NERVES. LIVER I LUN6S EYE 1 SKIN CONTACT:PRIMARY IRRITATION TO SKIN, DEFATTING. DERMATITIS PRIMARY IRRITATION TO EYES, REDNESS. TEARING, BLURRED VISION ABSORPTION THRU SKIN INCREASES EXPOSURE HASH THOROUGH!Y AFTER HANDLING ABSORPTION THRU SKIN MAY BE HARMFUL STUDIES KITH LABORATORY ANIMALS INDICATE THIS PRODUCT CAN CAUSE DAMAGE TO FETUS SHALLOWING: HARMFUL OR FATAL IF SNAILOHED SHALLOWING CAN CAUSE ABDOMINAL IRRITATION, NAUSEA. VOHJT1N6 AN0 DIARRHEA PERSONS WITH SEVERE SKIN, LIVER OR KIDNEY PROBLEMS SHOULD AVOID USE Isolate fro* oxidizers, heat, sparks, electric equipment 1 open TIaee. Use only with adequate ventilation. Avoid breathing ol vapor or spray eist. Avoid contact with skin 1 eyes. Hear OSHA Standard goggles or lace shield. Consult Safety Equipeent Supplier. Hear gloves, apron ( footwear impervious to this material. Hash clothing before reuse. Vapors may ignite explosively l spread long distances. Prevent vapor buildup. Put out pilot lights I turn off electric equipeent t other ignition sources during use I until all vapors are gone. Keep container tightly closed l upright when not in use to prevent leakage. Eipty container very hazardous! Continue all label precautions! Ground containers when transferring. Do not Hate cut, saw. drill,braze or weld. DISPOSAL*. Recycle or dispose of observing local,state L Federal health, safety 1 pollution laws. If spilled, Hop up I dispose of. FIRST AID : In case of contact witn skin, flush with plenty of water. For eyes, flush with plenty of water for 15 einutes b get eedical attention. After high vapor exposure, reaove to fresh air. H breathing is difficult ive oxygen. If breathing has stopped give artificial respiration. rI swallowed, CALL A PHYSICIAN IMMEDIATELY! Never give anything by eouth to an unconscious person. Consult MSDS for further information. FOR INDUSTRY USE ONLY KEEP OUT OF THE REACH OF CHILDREN DOT SHIPPING NAME: Compound Cleaning, Liquid (NA1993) DOT DRUM LABEL: Flaaaabte Liquid DATE i MAY 22, 1991 /\ /\ /\ /\ /\ Legal responsibility is assumed only for the fact that all studies reported here V opinions art those of qualified experts. Buyer assumes all risk I liability. He accepts It uses this eaterial on these conditions. ATTENTION! THIS CONTAINER HAZARDOUS WHEN EMPTY OR PARTIALLY EMPTY. SINCE CONTAINERS RETAIN PRODUCT VAPOR OR LIQUID RESIDUES, ALL HAZARD PRECAUTIONS MUST BE OBSERVED. RESIDUAL VArORS MAY EXPLODE ON IGNITION. DO NOI CUT, DRILL, GRIND. OR HELD ON OR NEAR THIS CONTAINER. HAZARD RATING HEALTH INFPAIi 2 HEALTH IHHISI: 1 FLAHMABILIIY: 3 REACTIVITY: f /\ / / / \ RED FLAMMABLE LABEL \ \ \/ \/ \/ \/ \/ \' / \/ \/ SAL 000006885 MATERIAL SAFETY DATA SHEET M/M PIPE SEALANT PAGE : 01 <037927-0429 -E0016293-4913 ){0ATE OF ISSUE j 92/26/90 APR 0 2 HEC1 ................... SECTION I - GENERAL INFORMATION j SUPERSEDES ! 01/26/90 CHEMICAL NAME & SYNONYMS N/A TRADE NAME ft SYNONYMS M/M PIPE SEALANT CHEMICAL FAMILY DIMETHACRYLATES FORMULA X< --MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP. ADDRESS (NUMBER. STREET. CITY. STATE & ZIP CODE) BOX 152170 IRVING. TEXAS 75015 PREPARED B Y : KELLY SEALS/T.S.CHENIST ! PRODUCT CODE NUMBER | EMERGENCY TELEPHONE NUMBER 4913 214-438-1381 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) POLYTETRArLUOROETKYLENE POLYGLYCOL DIMETHACRYLATES 1-OCTANOL BIS-PHENOL A FUMARATO RESIN SILICA (MICA) CUMENE HYDRPEROXIDE j HAZARD IRRITANT SKIN IRR. TOXIC 5KIN IRR. IRRITANT SKIN IRR. | TLV- N/A N/A N/A N/A 20PPM 1. N/A j PELN/A N/A N/A N/A N/A N/A ! cas# 9002-84-0 25852-47-5 111-87-5 3938225-7 12001-26-2 80-15-9 M/M PIPE SEALANT SECTION IIA - NON-HAZARDOUS INGREDIENTS PAGE : 02 NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NO TRADE SECRET REGISTRY * 409363-5193P SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) VAPOR PRESSURE (MM HG>. |>300 F. ! < to i SPEC GRAVITY (H20-1) ! COLOR WHITE PASTE VAPOR DENSITY (AIR-1) !n/a ! ODOR ALCOHOLIC PH 100% |n/a | CLARITY OPAQUE PERCENT. VOLATILE BY VOLUME <%) SOLUBILITY IN WATER j <10 1 | EVAPORATION RATE 1 (BU AC - 1 ) | NEGLIGIBLE ]N/A j VISCOSITY ! VISCOUS : 1.21 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) >300 F. T.C.C. j FLAMMABLE LIMITS 1 EXTINGUISHING MEDIA ALCOHOL" X<--F DAM <--FOAM XC--C02 DRY X<--CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES N/A ! LEL !n/a WATER < -- SPRAY i , *JEL |n/a <--OTHER UNUSUAL FIRE & EXPLOSION HAZARDS N/A NFPA HAZARO RATING {O-I NS IGNIFI CANT; 1-$LIGHT;2-MODERATE;3-HIGH;4-EXTREME ) : 2 <--HEALTH 1 <--FLAMMA6ILITY O <--REACTIVITY <--SPECIAL 000006886 SAL G S6 90 > 'kf M/M PIPE SEALANT SECTION V - HEALTH HAZARD DATA PAGE : 03 THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE INTOXICATION. NAUSEA. HEADACHE PROLONGED CONTACT IN SENSITIVE INTOXICATION. NAUSEA, HEADACHE PROLONGED CONTACT IN SENSITIVE - ACUTE - (SHORT TERM EXPOSURE) DIZZINESS. MAY CAUSE DERMATITIS ON INDIVIDUALS. - CHRONIC - (LONG TERM EXPOSURE) DIZZINESS. MAY CAUSE DERMATITIS ON INDIVIDUALS. PRIMARY ROUTE OF ENTRY: <-* INHALATION INGESTION <-- ABSORPTION EMERGENCY A FIRST AID PROCEDURES INHALATION : REMOVE INDIVIDUAL TO FRESH AIR. IF SYMPTOMS PERSISTS. OBTAIN MEDCXAL ATTENTION. EYE CONTACT: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. OBTAIN MEDICAL ATTENTION. SKIN CONTACT: FLUSH WITH WATER. INGESTION : DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN MEDICAL ATTENTION. N/A NOTES TO PHYSICIAN : SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY 1 ARC <--YE5 NTP <--YES OSHA < -- YES ACG1H <--YES OTHER < * - YES X<--NO XC--NO X<~-NO X<--NO X<--NO PRODUCT TOXICITY ORL L050: >5000MG/KG 1. SKN L050: >2000MG/KG 1. THIS PROOUCT CONTAINS OTHER INGREDIENTS KNOWN AS NUISANCE OUST THEY ARE AS FOLLOWS: SILICON DIOXIDE DUST HAS BEEN SHOWN TO CAUSE PULMONARY EFFECTS ON INHALATION. TITANIUM DIOXIDE HAS BEEN SHOWN TO CAUSE TUMORS IN EXPERIMENTAL ANIMALS WHEN INJECTED INTO THE MUSCLES. IN LIGHT OF THE LOW CONCENTRATIONS OF THESE COMPONENTS IN THE PROOUCT. IT IS OUR BEST TECHNICAL JUDGEMENT THAT NORMAL USE OF THIS PRODUCT P0SE5 NO SUCH HAZARDS. THESE WARNINGS ARE PRESENT ONLY TO COMPLY WITH OSHA REGULATIONS. (CONTINUED) M/M PIPE SEALANT SECTION VI - TOXICITY INFORMATION PAGE : 04 SECTION VII - REACTIVITY DATA STABILITY jX<--STABLE <--UNSTABL | CONDIDTIONS TO AVOID N/A INCOMPATIBILITY (MATERIALS TO AVOID) MAY ATTACK SOME THERMOPLASTICS. HAZARDOUS DECOMPOSITION PRODUCTS TOXIC FLUORIDES. HAZARDOUS WILL NOT X O-0CCUR polymerization! ;n/a MAY <--OCCUR i CONDITIONS TO AVOID ( SECTION VIII - SPILL OP LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEA5ED OR SPILLED SOAK UP IN AN INERT ABSORBANT. STORE IN PARTLY FILLED CLOSED CONTAINER UNTIL DISPOSAL. WASTE DISPOSAL METHOD BURY OR INCINERATE IN ACCORDANCE WITH EA AND LOCAL REGULATIONS. NEUTRALIZING AGENT N/A SECTION IX - SPECIAL PROTECTION INFORMATION REOUIRED VENTILATION GENERAL EXHAUST IS USUALLY ADEQUATE UNDER NORMAL CONDITIONS. RESPIRATORY PROTECTION LOCAL VENTILATION RECOMMENDED FOR PROLONGED USE. PROTECTIVE GLOVES RUBBER OR PLASTIC GL0VE5 RECOMMENDED. SAL 000006887 (CONTINUED) SECTION IX ,,6690M/M PIPE SEALANT SPECIAL PROTECTION INFORMATIOPAGE EYE PROTECTION CHEMICAL GOGGLES SHOULD BE WORN DEPENDING UPON SEVERITY OF EXPOSURE- OTHER PROTECTION N/A SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE 110 F.<"MAX 32 F.< --MIN j INDOOR \X jHEATED | PRECAUTIONS TO BE TAKEN IN HANDLING 6> STORING STORE AT MODERATE TEMPERATURES. OTHER PRECAUTIONS KEEP OUT OF REACH DF CHILDREN. READ ENTIRE LABEL BEFORE USING PRODUCT. j REFRIGERATEDJ OUTDOOR j ,X SECTION XI - REGULATORY INFORMATION CHEMICAL NAME CUMENE HYDROPEROXIDE C.A.S. NUMBER BO-15-9 UPPER % LIMIT 5 THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHOR 12ATI ON ACT OF 1986 AND AO CFR PART 372. IF UE < USE EXEMPTION) APPEARS UNDER UPPER % LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SU6h AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--IMCO SHIPPING NAME HAZARD CLASS < --TARIFF 6 D <--IATA <--MILITARY AIR (AFR 71-4) 1| ID NUMBER ! REPORT QTY (CONTINUED) M/M PIPE SEALANT SECTION XII - TRANSPORTATION (FOR FUTURE USE) LABELS | LIMITED QTY UNIT CONTAINER DOT 5PS CONTAINER | NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) PAGE : 06 1 . VENDOR'S MSDS. SECTION XIII - REFERENCES THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION, HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PRODUCT. SAL 000006888 MATERIAL SAFETY DATA PACE SHEET OF ************************************** PREMIER INDUSTRIAL CORPORATION 4500 EUCLID AVENUE CLEVELAND, OHIO 44103 * EMERGENCY/INFORMATION TELEPHONE: * * 216/391-8300 * MAIL TO: CONOCO REFINERY WHSE OLD SPANISH TRAIL WESTLAKE LA 70669 * * * * * * ************** * FORMULA: 36517 DATE: 06/14/85 * MSDS EFFECTIVE: 01/27/90 BY: SSL * SUPERSEDES MSDS OF:11/09/88 * * COF: 742394 * INVOICE: 378685 * * SDS KEY: 0746998 ** ******* ****** * * * * * * * * * * * ************** DEAR CUSTOMER: IN COMPLIANCE WITH THE SUPERFUND AMENDMENTS AND REAUTHOR 12ATION ACT (SARA TITLE III, SECTION 313). FEDERAL HAZARD COMMUNICATIONS REGULATIONS (WHMIS AND OSHA 29 CFR 1910. 1200) AND IN THE INTEREST OF INFORMED USE OF OUR PRODUCT, WE ARE PROVIDING YOU WITH THIS MATERIAL SAFETY DATA SHEET <MSDS>. THIS MSDS WILL BE UPDATED REGULARLY TO REFLECT THE MOST RECENT INFORMATION IN OUR POSSESSION. PLEASE ENSURE THAT OBSOLETE MSDS SHEETS IN YOUR FILES FOR ""HIS PART NUMBER ARE DISCARDED . WE THANK YOU FOR YOUR CONTINUED PATRONAGE AND LOOK FORWARD TO PROVIDING 'OU WITH ADDITIONAL QUALITY PRODUCTS AND SERVICES. ****************** SECTION I ~ PRODUCT IDENTIFICATION ********************** PART NUMBER: 92435 PRODUCT NAME: CONTAX H P 16 OZ. AEROSOL TRADE NAME/SYNONYMS: CONTAX H P CHEMICAL FAMILY: AEROSOL CLEANER ******************** SECTION II - HAZARDOUS INGREDIENTS *********************** INGREDIENT CAS NO. WT 7. PEL TLV STEL UNITS LC50, PPM LD50. MG/KG ******************** ********** ***** **** **** **** ***** ******************** TRICHLOROTRIFLUORO ETHANE CARBON DIOXIDE #00076-13-1 00124-38-9 95 1-5 1000 1000 1250 PPM 100005000 30000PPM RAT >87000RAT 143000 M >90000N/A INGREDIENTS TOTAL WT 7. ARE BELOW 1007. ONLY IF ALL OTHERS UNLISTED ARE NOT CONSIDERED HAZARDOUS BY ANY FEDERAL (OSHA, WHMIS, SARA), ANY STATE OR PROVINCE, OR LOCAL RIGHT-TO-KNQW REGULATIONS SYMBOLS, ABBREVIATIONS AND NOTATIONS: N/A^NOT AVAILABLE OR APPLICABLE, C=CEILING LIMIT, S=SKIN DESIGNATION #=LISTED IN SARA TITLE III SECTION 313, **IF FOUND AS DUST, MIST OR FUME M=HUMAN, RAB=RABBITS, GPG-GUINEA PIGS, MIC^MICE I=INGESTION,A^SKIN ABSORPTION, LO=LITTLE OBSERVABLE EFFECT,NO^NO EFFECT PEL--OSHA PERMISSIBLE EXPOSURE LIMIT, TLV=ACGIH THRESHOLD LIMIT VALUE STEL=SHQRT TERM EXPOSURE LIMIT, @=AMONG 5 MOST PREDOMINANT SUBSTANCES SAL 000006889 68691 PART: 92435 PRODUCT NAME: CONTAX H P 16 OZ. AEROSOL PAGE 2 OF 3 ****************** SECTION III - PHYSICAL DATA **************************** BAILING PT DEG F/C: 114F / 45C SPECIFIC GRAVITY: 1.42 ^OR PRESSURE (MM HG ): 284 XVOLATILE VOLUME: 100 VrtPOR DENSITY(AIR^l) : 4 EVAPORATION RATE: (ETHER 1> <1 SOLUBILITY IN WATER: NIL WATER/OIL DIST COEFF:O APPEARANCE AND ODOR: CLEAR AEROSOL WITH A FLUOROCARBON ODOR. PHYSICAL STATE: AEROSOL FREEZE PT DEG F/C. 55F / 13. 2C THRESHOLD ODOR,PPM: N/A OTHER:N/A PH:N/A ******************* SECTION IV - FIRE AND EXPLOSION HAZARD DATA ************ CLASSIFICATION: N/A NFPA RATING: N, /, A COMBUSTION PRODUCTS: CO, C02, HCL, HF FLASH POINT DEG F/C: N/A LELX: N/A UELX:N/A EXTINGUISHING MEDIA: EXTINGUISH WITH WATER/FOG/FOAM/DRY CHEMICAL/CARBONDIOXIDE UN/NA/PIN#: UN1956 SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING EQUIPMENT. AUTO IGN. TEMP DEG F/C: N/A UNUSUAL FIRE AND EXPLOSION HAZARDS: EXPOSURE TO FIRE, HEAT OR PROLONGED SUNLIGHT MAY CAUSE BURSTING. CONTACT WITH FLAME OR HOT SURFACES MAY PRODUCE TOXIC GASES. EXPLOSIVE POWER: LOW IMPACT SENSITIVE: NO BURNING RATE: LOW STATIC SENSITIVE: NO ******************* SECTION V - HEALTH HAZARD DATA ************************** PRODUCT GUIDE:TLV (SEE SECTION II) STEL: (SEE SECTION II) ROUTES OF ENTRY: EYE, INHALATION EFFECTS OF OVEREXPOSURE: ACUTE: NO CHRONIC: NO ''AY CAUSE EYE IRRITATION. VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC AND xRRITATE UPPER RESPIRATORY SYSTEM. EXCESS INHALATION MAY CAUSE DIZZINESS. 'IDDINESS, AND NAUSEA. STED AS A SUSPECTED CARCINOGEN: NO EMERGENCY AND FIRST AID PROCEDURES: EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MIN. & CALL PHYSICIAN. SKIN: WASH THOROUGHLY WITH PLENTY OF WATER & SOAP. INHALATION: IF AFFECTED, REMOVE TO FRESH AIR. INGESTION: SEEK PHYSICIAN IMMEDIATELY, SHOW MSDS OR LABEL, INDUCE VOMITING. ******************* SECTION VI - REACTIVITY DATA **************************** STABLE: YES CONDITIONS TO AVOID: KEEP AWAY FROM HEAT AND FLAME. INCOMPATIBILITY(MATERIALS TO AVOID): YES AL, BA, LI, SM, NAK ALLOY, TI HAZARDOUS DECOMPOSITION PRODUCTS: YES CO, C02, HCL, HF HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: N/A ******************* SECTION VII - SPILL OR LEAK PROCEDURES ****************** LISTED IN: SARA TITLE III, #302: NO #304,CERCLA: NO #313: YES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: IN CASE OF SPILL: VENTILATE THE AREA. CLEAN UP WITH ABSORBENT MATERIAL. CONTAIN AND PICK-UP WASTE MATERIALS. PUT IN A SEALED APPROVED CONTAINER. REPORT QUANTITY, LB: N/A KG: N/A TPQ, LB: N/A REGULATIONS: SARA,PROV/STATE,WHMIS OTHER: N/A HAZARD WASTE: AEROSOL,HALOGENATED SOLVENT NO.: N/A DISPOSAL METHOD: DISPOSE OF WASTES IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. 30 NOT PUNCTURE, INCINERATE (OR BURN) CONTAINERS. 000006890 SAL QS 691 PART: 92435 PRODUCT NAME: CONTAX H P 16 OZ. AEROSOL PAGE 3 OF 3 ******** SECTION VIII - SAFE HANDLING AND PROTECTION INFORMATION *********** u--SPIRATORY PROTECTION: USE ONLY IN WELL VENTILATED AREAS. Vc.NT ILATI ON-LOCAL: RECOMMENDED MECHANICAL: RECOMMENDED SPECIAL: N/A OTHER: N/A PROTECTIVE CLOVES: SOLVENT RESISTANT GLOVES EYE PROTECTION: SAFETY GLASSES OTHER PROTECTIVE EQUIPMENT: N/A ESTIMATED LD50* MG/KG: YES ORAL RAT 43000 ESTIMATED LC50* PPM: YES INHALATION RAT >87000 SENSITIZATION: NO IRRITANT: NO SYNERGISTIC AGENTS: NO ******************* SECTION IX - SPECIAL PRECAUTIONS ************************ PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: CONTACT WITH FLAME OR HOT SURFACES MAY PRODUCE TOXIC GASES. KEEP AWAY FROM HEAT AND FLAME. USE ONLY WITH ADEQUATE VENTILATION. AVOID PROLONGED OR REPEATED BREATHING OF GAS* FUMES* VAPOR OR SPRAY MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. OTHER PR EC AUTIONS: KEEP OUT OF REACH OF CHILDREN. ALWAYS READ AND FOLLOW DIRECTIONS ON PRODUCT LABEL. ADDITIONAL TECHNICAL DATA SHEETS AND/OR MATERIAL SAFETY DATA SHEETS (MSDS) ARE AVAILABLE UPON REQUEST. FOR PROFESSIONAL AND INDUSTRIAL USE ONLY 'HE INFORMATION AND RECOMMENDATIONS PROVIDED HEREIN ARE BELIEVED TO BE ACCURATE j OF THE DATE HEREOF. HOWEVER* SUCH INFORMATION AND RECOMMENDATIONS ARE '"'OVIDED WITHOUT WARRANTY OF ANY KIND AND PREMIER INDUSTRIAL CORPORATION SCLAIMS ANY AND ALL LIABILITY OR LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON SAME. SAL 000006891 CENTURY PAPERS INC. 4902* GULF FREEWAY HOUSTON. TEXAS 77023 PHONE NO. 713-928-5171 MATERIAL SAFETY DATA SHEET MANUFACTURER: TECHNICAL CONCEPTS, INC. 4545 W. AUGUSTA BLVO. CHICAGO, IL 60609 EMERGENCY PHONE NO. 312-227-3233 SECTION 1- PRODUCT IDENTIFICATION SHEET NO 1379 PRODUCT NAME: DEOMATIC AEROSOLS (FEMALE, ORANGE, COUNTRY GARDEN, APPLE) PROOUCT NO. 417-4402, 417-4381, 417-4411, 417-4399 SECTION 2- HAZARDOUS INGREOIENTS DOES PRODUCT CONTAIN HAZARDOUS INGREDIENTS? {Y,N,N/A, N/I) : YES CHEMICAL/COMMON NAME: CAS NO. % PEL- OSHA: TLV - ACGIH: 2-PROPANOL 67-63-0 20-30 400 PPM 400 PPM C3-C9 ISOPARAFFIN 64742-48-9 10-20 N/A N/A PROPANE 74-98-6 10-20 1000 PPM N/A 1,1,1,--TRICHLOROETHANE 71-55-6 5-10 350 PPM 350 PPM 1,1,2-TAICHLORO- 1,2,2-TRIFLUOROETHANE 76-13-1 5-10 1000 PPM 1000 PPM DOES PRODUCT CONTAIN CARCINOGENS? (NTP IARC OSHA) (Y,N,N/A, N/I): NO SECTION 3- HEALTH HAZARD DATA HEALTH EFFECTS (ACUTE AND CHRONIC): EYES - MAY IRRITATE EYES. PRIMARY ROUTES OF ENTRY: NONE MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: UNKNOWN EMERGENCY AND FIRST AID PROCEDURES: QUICKLY FOLLOW DIRECTIONS BELOW AND CALL POISON CONTROL CENTER. GET QUICK MEDICAL ATTENTION IF ANY ILL EFFECTS CONTINUE OR OEVELOP LATER. EYES - FLUSH EYES WITH PLENTY OF WATER WHILE REMOVING ANY CONTACT LENSES, THEN HOLD EYELIDS OPEN AND CONTINUE FLIUSHING FOR 15 MINUTES. CHEMICAL DATA (ON CONCENTRATE) BOILING POINT: 117 SPFCIFIC GRAVITY: 0. 89 VAPOR PRESSURE: 49 MELTING POINT: N/A VAPOR DENSITY: >1 EVAPORATION RATE: >1 SOLUBILITY IN WATER: NEGLIGIBLE APPEARANCE AND ODOR: CLEAR, YELLOW LIQUID PLEASANTLY SCENTED. SECTION 4- PHYSICAL HAZARD DATA FLASH POINT: 50 F FLAMMABLE LIMITS: LEL: 3 UEL: 19 EXTINGUISHING MEDIA: WATER SPECIAL FIRE FIGHTING PROCEDURES: KEEP CONTAINERS COOL. USE SHIELDING TO PROTECT PERSONNEL AGAINST BURSTING, RUPTURING OR VENTING CONTAINERS. UNUSUAL FIRE AND EXPLOSION HAZARDS: AT ELEVATED TEMPERATURES (OVER 120 F ) CONTAINERS MAY VENT, RUPTURE OR BURST. SECTION 5- REACTIVITY DATA INCOMPATIBILITY - MATERIALS TO AVOID: NONE HAZARDOUS DECOMPOSITION PRODUCTS: HCL, HF, OXIDES OF CARBON AND TRACES OF PHOSGENE AND CHLORINE MAY BE FORMED UPON COMBUSTION. WILL HAZARDOUS POLYMERIZATION OCCUR? NO SAL 000006892 S69* :* MATERIAL SAFETY OATA SHEET " PRODUCT NAME: OEOMATIC AEROSOLS ( FEMALE, PRODUCT NO. 417-4402, 417-4381, 417-1411, PAGE ORANGE. COUNTRY 417-4399 2 GARDEN,APPLE) SECTION 5- REACTIVITY DATA CONTINUED................. CONDITIONS TO AVOID/POLYMERIZATION: NONE IS THE PRODUCT STABLE? YES CONDITIONS TO AVOI0/STABILITY: AVOID HEATING TO ABNORMAL SECTION 6- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: REMOVE SOURCES OF FLAME, SPARK OR HEAT. PROVIDE ADEQUATE VENTILATION DISPOSAL METHOD: REPLACE CAP AND DISCARD CONTAINER IN TRASH. INCINERATE. DO NOT PUNCTURE OR SECTION 7- EXPOSURE CONTROL INFORMATION VENTILATION: LOCAL EXHAUST : NONE REQUIRED MECHANICAL: ADEQUATE VENTILATION RESPIRATORY PROTECTION: NONE REQUIRED PROTECTIVE GLOVES: NONE REQUIRED OTHER PROTECTIVE EQUIPMENT: SAFETY GLASSES OTHER ENGINEERING CONTROLS: N/A WORK PRACTICES: ALWAYS FOLLOW SAFE WORK PRACTICES. HYGIENIC PRACTICES: N/A SECTION 8- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: CAUTION: CONTENTS UNDER PRESSURE. KEEP OUT OF REACH OF CHILDREN. 00 NOT STORE WHERE TEMPERATURES MAY EXCEED 120 F. AVOID CONTACT WITH EYES. MAINTENANCE PRECAUTIONS : N/A REAO ENTIRE LABEL BEFORE USING: OTHER COMMENTS READ ANO FOLLOW LABEL DIRECTIONS ANO OTHER PROOUCT SAFETY AND HEALTH INFORMATION WHICH YOU HAVE BEEN PROVIOED WITH WHEN HANDLING AND USING OUR PRODUCTS. SAL 000006393 CENTURY PAPERS INC. W02 GULF FREEWAY HOUSTON, TEXAS 77023 PHONE NO. 713-928-5171 MATERIAL SAFETY OATA SHEET MANUFACTURER: LEHN C FINK INDUSTRIAL PROD. DIVISION OF STEPLING DRUG INC MONTVALE. NEW JERSEY 07645 EMERGENCY PHONE NO. 201-573-5700 SECTION 1- PRODUCT IOENTIFICATION_ SHEET NO PRODUCT NAME: INSTITUTIONAL LYSOL * BRAND DISINFECTANT SPRAY 1368 PROOUCT NO. 406-1004 GENERIC DISCRETION: DISINFECTANT AND DEODORIZING SPRAY SECTION 2- INGREDIENTS ETHYL ALCOHOL O-PHENYLPHENOL N-ALKYL- (92% C185 8% C16)- MORPHOLINIUM ETHYL SULFATES CAS NO. 64-17-5 90-43-7 61791-34-2 PERCENT : 709..01%% 0.35% SECTION 3- PHYSICAL DATA BOILING POINT: SPECIFIC GRAVITY: VAPOR PRESSURE: 98 PERCENT VOLATILE BY VOLUME: VAPOR OENSITY: NO SPRAY PATTERN: CIRCULAR EVAPORATION RATE: PROPELLANT TYPE: CARBON DIOXIDE PH, WITHOUT PROPELLANT d 77F: ASTM E-70 8.2 SOLUBILITY IN WATER: CONTENTS, FL. OZ.: 19 VISCOSITY, WITHOUT PROPELLANT, CPS 377 F: BROOKFIELD SPINDLE #2 3 30 RPH <100 USOA CATEGORY: P SECTION 4- FIRE AND EXPLOSION HAZARD DATA FLASH POINT: BULK PRODUCT (PROPELLANT FREE) 70 TAG CLOSEO CUP FLAMMABLE LIMITS: LEL: UEL: ASTM 3065 FLAME EXTENSION TEST - FLAMMABLE F EXPLOSIVE: PRESSURIZED CONTAINER VOLATILE INGREDIENTS GIVEN OFF AT ROOM TEMPERATURE: ETHYL ALCOHOL - WHEN AEROSOL CONTAINER ACTUATED. VOLATILE INGREDIENTS GIVEN OFF WHEN HEATED DURING NORMAL USE: HEATING NOT NORMAL TO USE. FIRE EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE EXPLOSION HAZAROS: FLAMMABLE SECTION 5- REACTIVITY DATA STABILITY: INCOMPATIBILITY - MATERIALS TO AVOID: HAZARDOUS POLYMERIZATION: CONOITONS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: SECTION 6- SPILL, LEAK AND DISPOSAL PROCEDURES SPILL RESPONSE: PRODUCT DISPOSAL: REPLACE CAP AND DISCARO IN TRASH. INCINERATE. 00 NOT PUNCTURE OR SAL 000006894 S 6 9 MATERIAL SAFETY DATA SHEET PAGE 2 PRODUCT NAME: INSTITUTIONAL LYSOL * BRAND DISINFECTANT SPRAY PRODUCT NO* 406-1004 SECTION 7- HEALTH HAZARD DATA SYMPTOMS OF OVEREXPOSURE: SKIN CONTACT: PRACTICALLY NON-IRRI TAT ING. THE UNDILUTED PROOUCT MAY CAUSE MILO OR SLIGHT IRRITATION (ERYTHEMA SKIN REACTION VALUES OR 0 OR 1) OF THE INTACT OR ABRADEO SKIN OR RABBITS AT 72 HOURS* EPA CATEGORY 4. EYE CONTACT: MODERATELY IRRITATING. THE UNDILUTED PRODUCT. WHEN INSTILLED INTO THE EYES OF RABBITS- PRODUCES CORNEAL INVOLVEMENT OR IRRITATION, CLEARING IN 7 DAYS OR LESS. EPA CATEGORY III. SKIN ABS0R9TI0N: NON-TOXIC. THE PROBABLE LETHAL DOSE OF UNDILUTED PRODUCT TO 50 % OF THE TEST ANIMALS DETERMINED FROM DERMAL TOXICITY STUDIES (LD50) IS GREATER THAN 500 MILLIGRAMS PER KILOGRAM AND LESS THAN OR EQUAL TO 5 GRAMS PER KILOGRAM OF BODY HEIGHT. EPA CATEGORY III. INGESTION: SLIGHTLY TOXIC. THE PROBABLE LETHAL DOSE OF UNDILUTED PRODUCT TO 50 X OF THE TEST ANIMALS DETERMINED FROM INGESTION STUDIES (L050) IS GREATER THAN 500 MILLIGRAMS PER KILOGRAM AND LESS THAN OR EQUAL TO 5 GRAMS PER KILLOGRAM OF BOOY WEIGHT. EPA CATEGORY III. INHALATION: MILDLY TOXIC. THE PROBABLE LETHAL OOSE OF UNOILUTED PROOUCT TO 50 % OF THE TEST ANIMALS DETERMINED FROM INHALATION STUDIES (LC50) IS GREATER THAN 2 MILLIGRAMS ANO LEAS THAN OR OR EQUAL TO 20 MILLIGRAMS PER LITER BY VOLUME WHEN INHALED CONTINUOUSLY FOR ONE HOUR OR LESS. EPA CATEGORY III. SECTION 8- EMERGENCY ANO FIRST AID PROCEDURES EYE CONTACT: IF SPRAYED DIRECTLY INTO EYES IMMEDIATLEY FLUSH WITH~PLENTY~ OF WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN CONTACT: INHALATION: INGESTION: IF SWALLOWEO, DRINK PROMPTLY A LARGE QUANTITY OF MILK. EGG WHITES, GELATIN SOLUTION, OR IF THESE ARE NOT AVAILABLE. ORINK LARGE QUANTITIES OF WATER. CALL A PHYSICIAN IMMEDIATELY. NOTE TO PHYSICIAN: PROBALB MUCOSAL OAMAGE MAY CONTRAINOICATE THE USE OF GASTRIC LAVAGE. MEASURES AGAINST CIRCULATORY SHOCK. RESPIRATORY DEPRESSION ANO CONVULSION MAY BE NEEDED. SECTION 9- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: NOT APPLICABLE VENTILATION: NOT APPLICABLE OTHER PROTECTIVE CLOTHING/EQUIPMENT: NOT APPLICABLE SECTION 10- LABELING ANO ADDITIONAL PRECAUTIONS OTHER STORAGE ANNO HANDLING REQUIREMENTS: STORE IN ORIGINAL CONTAINER IN AREAS INACCESSIBLE TO SMALL CHILOREN. LABELING (PRECAUTIONARY STATEMENTS) CAUTION: WARNING: KEEP OUT OF REACH OF CHILDREN. AVOIO CONTACT WITH FOOD. AVOID DIRECT SPRAYING INTO SPARK, OR FLAME. DO NOT PUNCTURE OR INCINERATE CONTAINER. EXPOSURE TO TEMPERATURES ABOVE 130 F. MAY CAUSE BURSTING. THIS PROOUCT IS LA3ELE0 AND PACKAGED IN ACCORDANCE WITH THE REGULATIONS DEPARTMENT OF TRANSPORTATION UNDER THE FE06RAL HAZARDOUS MATERIALS TRANSPORATION ACT. ENVIRONMENTAL PROTECGION AGENCY UNDER THE FEDERAL INSFCTICID6. FUNGICIOE, AND RODENTICIDE ACT. SAL 000006895 **-"-*> 11/ta/M CALLAWAY CHEMICAL COMPANY * IMMW ml %nnm AA1t*4 aASSII n Ih MN. Ill...........*#* HMD-MM BT * 4*1 PAM 1 SECTION t PRODUCT IDENTIFICATION 4 ENEROENCY INFORMATION jFRQ<UCt HAIM ilAVPLOC 110 A CAt lAhic Potyaorylaalde in Netr in OH lAulelon IMItAl fAMRV CatlOniC iDWMPtfUill M^OVCt AFFIaRANCI Milky white liquid, light hydrocarbon Odor EMERGENCY TELEPHONE NUMBERS: CALLAWAY CHEMICAL COMPANY 404-671-3000 CHEMTRIC 600-434-6300 SECTION II HAZARDOUS INGREDIENT INFORMATION The composition of thlo mixture may Os proprietary information. Jn the event of e (eedicel emergency, compos 11ions! information win be provided to A physician or nurta. This product i hazardous At defined in 26 CFR1610.1300. bated on the following compos 11 ions) informat ion; gpMPOHiig Pttroiewn Distillate Petroleum Distillate BIHA HAZARD Combust ibis Irritant to eyes end akin CAtlonie Polyacrylamide Irritant to eyee end tkin for tdoit'On*i information Section 111. SECTION HI HEALTH INFORMATION AND PROTECTION NATURE or HAZARD EYE CONTACT: Irritating, and will injur* *y* tiitu# if not removed promptly. SKIN CONTACT: Irritating. low orddr of toxicity. INHALATION: Irritating te eyee end respiratory tract in nigh concentrations. INOCfTlONl Seen amountt Of the liquid aeplrated into me reepiratory eyetea during ingestion. or from vomiting, may cause proncmopneumonia or pulmonary edema. PlftST AID IT I CONTACT! Immediately flush ayee with large amounts of water for at least 16 minutes. Oat prompt modiCAl attention. SKIN CONTACT! riueh with large amounts of water; Vi# soap if available. Remove grossly oontamlneted clothing. Including shoes, and launder before reuse. 1# Irritation persists, seek medical attention. INHALATION! Using proper respiratory protection, immediately remove the effected, victim from exposure. Administer artificial respiration If breathing is stopped. Keep at rest. Cell for prompt medical attention. i -4_ TMIt HWfrtWAtlO* aiiAYal Afwst urtai*i* t* it Tf Y>* F*oer Uarte*tOFliR 104oTatRu!TA*i CMMH14OT**tTtVvm Mnrrbl** SAL 000006896 MlH9ruVntKfIa**J DmmIILaIttnfaj s4MCC.UmR4TV IinScoMasIUt maMt io*4it* a*r r*s ., t^iJH riili 1 i : 40 IT : i Zc. r (VIA I trtlAL bAhfe I Y DAI A SHEET n/tt/M uAmoc Eto 86 87 IMCtTtOM J If vnov0, oe mot induce voeiting. Keep at fast. Oat proept bedicel attention -,c MOt i K. to WORKPLACE EXPOSURE LIMITS EXXON RECOMMENDS THE fOLLOVlNS OCCUPATIONAL EXPOSURE LIMITS; 200 pp* total hydrocarbon baaed on composition. PRECAUTIONS PERSONAL PROTECTION far open ays tats vr>ara contact is likely, vaar long sleeves, chaaica! resistant gloves, and chemical pope lot. Where contact aay occur, wear long sleeves and safety glasses wth tide an toidt. wnere ooncantfationa in air nay exceed tn# Haiti pi van in true Section and engineering. work practice on other means of exposure reduction are net adequate. NIOSH/MSHA approved raapiratona *ay be nocaaaary to prevent overexposure py inhalation. VENTILATION Tne uaa of eecnsmcai dilution ventilation it r*cofirtended whenever thia product it uaad in a confined apace. it heated above ano i ant temperatures, or ia agitated. SECTION IV FIRE EXPLOSION HAZARD PLASHPOINT: i$4 Did F METHOD; TCC PLAMHAMLE LIMITS: Not available AUT0I6NITI0N TEMPERATURE: Not Available OCNERAL HAZARD Combustible nou'd. can fore ecOuttib)o *utur t toapa^sturss st or above t*e 4 laenpemt. Empty* containers retain product roaiduo (liquid and/or vspor j *r\d can be dangerous 00 NOT PRESSuRUE. CUT. WHO. 6RA2E. SOlOCR. 0<Hl. QRILO. OR expose such containers to hiat. flame, sparks, static electricity, or OTHER SOURCES Of IONJTION; THEY MAY EXPlOOE ANO CAUSE INJURY OR DEATH. Empty drw*a should b completely drained, property bunged and pro^tly re* turned to a drum reeonditioner. or properly disposed of. PXME PltHTlNS Uee water to cool fire-expoied cwrfscea and to protect personnel. Isolate fuel* supply from fire, Uaa foaa, dry chemical. or water spray to extinguish fire. Reeplratory and aye protaetion required for fira fighting personnel . Of COMPOSITION PROOUCTt UNDER EIRE CONDITIONS Mo unuaual SAL 000006897 _ SECTION^ SPILL CONTROL PROCEDURE LAND SPILL Eliminate aourcaa of ignition. .Pravant additional discharge of notarial, if possible to do ao without hatard. for email apiila implement ciaanup prpeeduree; for Targe apiila Implement ciaanup procadurea and, if in pvbtle area, keep public away and advice authorities, Also, If thia product la eubject to CERCLA raportlng (aaa Section vti) notify the Natlonel Response Center, Prevent liquid from entering severe, watercourse*. or 1 ov areas. Contain ; SA&tV GAYA SHEET n/n/M >wrHK in G S ^ 87 AOE 3 N0.M ia< l *Mh *nd er eart*. Da net uea eoaOuetlDte at ituit. fteeover by puapinp (uee an expleaion proof or hand poop) or with a tv Mao it absorbent. If Hqwi* ie too viooovo for pulping. aeropo ^e>. Consult an expert on diapoaal of reooverad actor ipi and eneure oonforaity to local diapoaal regulation#. euon VATti Mill tooovo fro* aurfaoa Oy a*laming or vitn twitable abaorbentt. Do not uaa dlapereanta. Coneult an export on diapoaal of raeovarod notarial, and anawra oonforaity to local diapoaal reguletlone. SECTION VI Protect froa freeting. NOTES SECTION VII REGULATORT INFORMATION TSCA: Caapanonte of thia product aro llatad on tna TICA Inventory. CCtCLA: Under tna Coftprahanaiva fteaponea. Coapentation, and liadiMy Act. (CIACLA). certain ralaaaaa to air. land, or water may be reportaDlt to tna National feeponee Cantar at a00'424~aa02. Circumttancet aumounding tna retaeaa and elaanup determine raportaOlity. Tn*e product ia not tuojact to CttCLA reporting repy i r*mnta. SAftA TITLI III; Unoar tna prev'iiona of Title !!]. Seetient 9*1/319 of tn# $uperfuno Amandmanta and In ytnoriaation act. tna product it ciaaeified into tna following naaare eategoriat: iMtadiata naaitn. fire. Tmi product doaa not contain Section )i) *apo*taeic !ngedienta. SECTION VIU TYPICAL PHYSICAL A CHEMICAL PROPERTIES Metric AAAVITV: O.M to 112 0 77 f OtUAlLITf IN VATIK VT. t AT "F: Soluble 2. A1AV. OF VAPOA, at 1 ATM AXM1: Met available IVAPOftATION tATI, n-AU ACITATC1: Weee than 1 VAPOA PAtSSUAC, OoHq at *F: < 10 At V 9 VISCOSITY OF LIOUIO, CST AT 400 - 2000 CP AT 77 $ Pttf2XNG/NKLT1NC POINT, *f: 10 to 33 f OILING POINT, *P; 213 te 370 *F: SAL 000006898 n/u/ii IVlAlfcrtlAL SAFETY DATA SHEET uayfloc iio GS68T SECTION U REACTIVITY DATA PAGE 4 po STABILITY: CONDITION# TO AVOIO INSTABILITY AvplR ttWpifAtUF#t 056VO MO 9 Av#1# t#Hp#rOtur#t 0#1Ow 93 t HAZAROOU# POLYNIRIZATION: W1U not occur CONO. TO AVOIO HAZARDOUS POLYMERIZATION Mot Appl100*1# NATBRIAL* AND CONDITIONS TO AVOID 1NC0NPAT1RXLITY: CofitMl witn valor foroo o p#i #t product ooi 10 eontont rootor thon IDS. HAZARDOUS DECOMPOSITION PROOUCTS: SECTION X TRANSPORT AND STORAGE U.S. OOT CLASSIFICATION: CooouttiOio fLtCTROSTATtC ACCUMULATION HAZAAO: Unknown, u# propor orounoing proeoowro OTORAOS TINPIRATURE. *F: Koop fro* fr*0*1*9 STORARE/TRANSPORT PRESSURE. OfliHg: AtJOO#pn#ric UN NUMBfBt Hot LOADJN9/UML0ADIN4 TEMPERATUREf *P: K##p from fr#0*1*9 VISC. AT LOADING/UNLOA0IN9 TEMP., e$T; 400 to 2000 fcp# 1 000006S90 S M- i | REFERENCE NUMBER; HDHA*P- 109RR DATE PREPARED: NOVfMBIR 22,1090 SUPERCEDES ISSUE DATE: JUNE 19.1990 1 FOR ADOXTJONAL PROOUCT INFORMATION. CONTACT YOUR TECWICAl SALES REPRESCNTATIVE FOR ADO IT IONA L HEALTH/SAFITY INFORMATION. CALL 713-970-499# tfAS BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 NFPA/HMIS : HEALTH - MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 86 89 DISTRIBUTED: APR-17-1990 PRODUCT : SPEC-AID 8Q302 (PAGE 1 OF 3) EFFECTIVE DATE 12-13-89 PRINTED: 10-Apr-19 90 REVISIONS TO SECTIONS: APPENDIX/9;EDIT:2 PRODUCT APPLICATION : OIL SOLUBLE DEHAZER. ---------- SECTION 1.............................HAZARDOUS INGREDIENTS--------------------------------- INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9iCOMBUSTIBLE LIQUID;IRRITANT(EYE); MANUFACTURERS SUGGESTED EXPOSURE LIMIT:100PPM;PEL: NONE;TLV:NONE. TRADE SECRET INGREDIENT(372);POTENTIAL EYE,SKIN AND INHALATION IRRITANT ; PEL:400 PPM;TLV:NONE. TSRN 125438 - 5252P TRADE SECRET INGREDIENT(078);FLAMMABLE ; POTENTIAL LIVER AND KIDNEY TOXIN; CNS DEPRESSANT;PEL/TLV:100 PPM(150PPM-STEL). TSRN 125438 - 5200P TRADE SECRET INGREDIENT(162);FLAMMABLE LIQUID;IRRITANT;CNS DEPRESSANT; PEL/TLV:50PPM-C(SKIN). TSRN 125438 - 5224P ---------- SECTION 2------------------------TYPICAL PHYSICAL DATA------------------------------------------------------- PH: 5% EMULSION (APPROX.) FL.PT.(DEG.F): 113 P-M(CC) VAPOR PRESSURE(mmHG): <10 VISC cps70F: 33 EVAP . RATE: ND WATER*1 PHYSICAL STATE: LIQUID 10.4 ODOR: HYDROCARBON SP.GR.(70F)0R DENSITY: 7.8 LBS/GAL VAPOR DENSITY(AIR=1): >1 %SOLUBILITY(WATER): 0 APPEARANCE: AMBER FREEZE PQINT(DEG.F): <-30 ---------- SECTION 3.............................REACTIVITY DATA---------------------------------------------------------------- STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000006900 &XS BETZ PROCESS MM CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: SPEC-AID 8Q302 ---------- SECTION 4------------------------ HEALTH HAZARD EFFECTS----------------------------------ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY,MAY CAUSE CNS DEPRESSION,OR MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS,HEADACHE AND NAUSEA. ---------- SECTION 5................................FIRST AID INSTRUCTIONS............................................................ SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ---------- SECTION 6--....................... SPILL,DISPOSAL AND FIRE INSTRUCTIONS............. ........... SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS>- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE.FOAM OR WATER SAL 000006901