Document rBN7GD9vgaEKM9wxm2kRqp8Ea

Jan-06-04 05:39pm From-RIKER, DANZIG, SCHERER T-3Z8 P.094/114 F-57T CANCELLED PVC EMULSION RESIN fiece/vecj 2003 PVC EMULSION RESIN is a generic MSDS for the following products: EH-71 EE-7XL EH-71AH EN-73 EH-210 EH-218 EH-219 EH-219LF EH-219LFHY EH--232 EH-233 EX-240 EX-241 EH-242 EH-25G EH-250HY EH--255 GGC00052S6 Jan-06-04 05:40pm From-RIKER, DANZIG, SCHERER T-3Z8 P.095/114 F-577 PVC EMULSION RESIN SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME AND SYNONYMS; Polyvinyl chloride resin, PVC resin, Chloroethylene polymer, Chloroethylene homopolymer, EB-xxz CIS NAME AND NO.: CHLOROETHYLENE POLYMER [9QQ2-86-2] rHPMTriT. ptMTT.v Vinyl resin CHEMICAL FORMULA.: (C2H3Cl)x MANUFACTURER'S NAME AND ADDRESS Georgia Gulf Corporation PVC Division P.O. Box 629 Plaqueroine, Louisiana 70765-0629 EMERGENCY TELEPHONE NO.: (302) 836-2100 or CHEMTREC (BOO) 424-9300 SECTION--II - HAZARDOUS INGREDIENTS COMPONENT X (WT OR VOL) ACGIH TWA (UNITS) Vinyl chloride < 0.0002 CAS # [75-01-4 J 5 ppm PVC Dust should be limited to 10 mg/3 ACGIH STEL (UNITS) N/A OSHA PEL (UNITS) 5 ppm/15M Cl 1 ppm/8H TWA SECTION III - PHYSICAL PROPERTIES APPEARANCE AMD ODOR; White powder, odorless MOLECULAR WRIGHT; ca xxx,xxx weight average BOILING POINT (DEGREES FAHRENHEIT): N/A MELTING POINT (DEGREES FAHRENHEIT)i N/A VAPOR PRESSURE (MM. OF MERCURY); 0.1 SPECIFIC GRAVITY (WATER = 1)i 1.39 Page 1 of 7 Jan-06-04 05:40pm From-RIKER, DANZIG, SCHERER T-328 P.096/114 F-577 VAPOR DENSITY (AIR = 1): N/A PERCENT VOLATILE (BY WEIGHT); 0 H: N/A SOLUBILITY IN WATER: None EVAPORATION RATE (BUTYL ACETATE a 1): PVC EMULSION RESIN None SECTION IV - FIRE AND EXPLOSION DATA FLASH POINT: 500"F (COC) FIRE EXTINGUISHING MEDIA: Carbon dioxide or water FLAMMABLE LIMITS fPERCENT BY VOLUME); LOWER UPPER N/A N/A SPECIAL FIRE FIGHTING PROCEDURES & EQUIPMENT; Wear gas mask approved for acid vapors. UNUSUAL FIRE AND EXPLOSION HAZARDS: pvc will not continue to burn after ignition without an external fire source. Burning liberates HCI gae. SECTION V - REACTIVITY DATA STABILITY: UNSTABLE ______ STABLE __ X CONDITIONS TO AVOID: Temperature above 300* F - will decompose raw resin and liberate HCI. INCOMPATIBILITY (MATERIALS TO AVOID): Polyvinyl chloride compounds should not come into contact with Acetal or Acetal copolymers in elevated temperature processing equipment. The two materials are not compatible and will react in a violent decomposition when mixed under conditions of heat and pressure. HAZARDOUS DECOMPOSITION PRODUCTS: Slow release of Bel when heated above 300*F. HAZARDOUS POLYMERIZATION; WILL OCCUR ______ WILL NOT OCCUR X CONDITIONS TO AVOID! N/A Page 2 of 7 firtmnfwisn Jan-06-04 05:40pm From-RIKER, DANZIG, SCHERER T-328 P.097/114 F-577 PVC EMULSION RESIN SECTION VI - HEALTH HAZARD INFORMATION EFFECTS OF OVEREXPOSURE: Polyvinyl chloride as a resin is more or less inert. Its main hazards, if any, would be associated with unreacted vinyl chloride monomer (generally extremely small amounts) and other additives in the plastic. Pneumoconiosis has been described from inhalation of the dust which should be avoided. Combustion products of Polyvinyl Chloride may result in an asthma syndrome. Check OSHA VCM Regulation 29 CFR, Title 29, Chapter XVII, Fart 1910. PROBABLE ROUTES OP EXPOSURE; Inhalation (of duBt) EMERGENCY AND FIRST AID PROCEDURES INGESTION: Practically inert. INHALATION: Remove victim to fresh air. Get medical attention if necessary. EYE CONTACT: Flush with water. Do not rub. see physician if residual foreign body is suspected. SKIN CONTACT:N/A SECTION VII - TOXICITY DATA ORAL; N/A DERMAL: N/A TMWATJLTTQN: N/A CARCINOGEN!CITY: This material may contain trace amounts of vinyl chloride which is a cancer suspect agent. Polyvinyl chloride is not listed as a carcinogen by IARC. Monograph 7, 1988. There is no polyvinyl chloride listing in NTF Fourth Annual Report on Carcinogens. 1985. OSHA. as of 1/30/86, does not list polyvinyl chloride per se but requires labeling that it may contain vinyl chloride monomer which is listed as a cancer suspect agent. OTHER PERTINENT DATA: N/A Page 3 of 7 firtrtnnn ra an Jan-06-04 05:40pm From-RIKER, DANZIG, SCHERER T-328 P.098/114 F-577 PVC EMULSION RESIN SECTION VIII - SPECIAL PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPMENT PROTECTIVE GLOVES; N/A EYE PROTECTION: Safety Classes (for dust) RESPIRATORY PROTECTION (SPECIFY TYPE): Any MSHA-approved dust respirator OTHER; N/A VENTILATION LOCAL EXHAUST; As required for general wort areas. MECHANICAL (GENERAL); N/A SPECIAL; N/A OTHER; N/A SECTION XI - SPILL. LEAK. AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OH SPILLED: Vacuum, sweep, or shovel up. WASTE DISPOSAL METHODS; Landfill, high temperature incineration under controlled conditions due to formation of HC1 SECTION X - REGULATORY INFORMATION FDA; Approved for use in film wrap under prior sanction provided that FDA-specified quality assurance tests are met, (See JLSTM standards 1243-66 and 3030-72.) Also approved for use iu cellophane (177.1200). Regulated under 21 CFR 176-180 for safe use as component of the uncoated or coated food-contact surface of paper and paperboard intended for use in producing, manufacturing, packing, processing, preparing, treating, packaging, transporting, or holding any food of the type identified in 176.170(c), table 1, under type VTII. Also listed under 175.105 as a substance for use as component of adhesives. Regulated under 175.300(3) - (xv) and 175.320(b)(3) - Resinous and polymeric coatings for food-contact surfaces, and for polyolefin films, respectively. Page 4 of 7 Jan-06-04 05:41pm From-RIKER, DANZIG, SCHERER T-328 P.099/114 F-577 FVC EMULSION RESIN EPAi CLEAN WATER ACT REQUIREMENTS: Not listed. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) REQUIREMENTS: Unknown. SUPERFUND AMENDMENTS and REAUTHORIZATION ACT of 1986 (SARA). TITLE III: Not specifically listed. COMPREHENSIVE ENVIRONMENTAL RESPONSE. COMPENSATION and LIABILITY ACT <CERCLA): $101 (14) - Hazardous substance, not listed. STATE; Check state and local requirements. USDA; CPSC; TSCAi DOT USDA self-certification (9 CFR 317.20); is FDA approved. Not listed in Hazardous Substances Labeling Guides. CAS #9002-86-2 PROPER SHIPPING NAME; Polyvinyl chloride HAZARD CLASS: N/A LABEL REQUIRED: N/A IDENTIFICATION NO.; N/A OTHER PERTINENT INFORMATION; N/A OSHA; PVC nay contain a very low level of VCM. Therefore, under normal working conditions with adequate ventilation, OSHA'S PEL (1 ppm) should not be exceeded. The workplace should be monitored, and if the level exceeds the PEL, refer to 29 CFR 1910.1017. In addition, containers of PVC shall be- legibly labeled: POLYVINYL CHLORIDE CONTAINS VINYL CHLORIDE VINYL CHLORIDE IS A CANCER-SUSPECT AGENT SECTION U - SPECIAL PRECAUTIONS AND COMMENTS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in dry area below 100"F. Page 5 of 7 Jan-06-04 05:41pra From-RIKER, DANZIG, SCHERER T-3Z8 P.100/114 F-577 PVC EMULSION RESIN OTHER PRECAUTIONS; When opening truck or railcar for unloading, ventilate before entering. REGISTRATIONS/CERTIFICATIONS; N/A EFFECTIVE DATE: USDS CONTACT; 12/8/88 F. E. Sorrelli SUPERSEDES: 7/14/86 PHONE NUMBER} (404) 395-4582 IMPORTANT: The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable. It is offered for ' your consideration, investigation and verification. Buyer assumes all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. Georgia GULF MAKES NO WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, CONCERNING THE ACCURACY OR COMPLETENESS OF THE INFORMATION AND DATA HEREIN. Georgia Gulf will not be liable for claims relating to any party's use of or reliance on information and data contained herein regardless of whether it is claimed that the information and data are inaccurate, incomplete or otherwise misleading. This information' relates to the material designated and may not be valid for such material used in combination with any other materials nor in any process. MAJOR SOURCES USED FOR MSDS PREPARATION 1) "The Condensed Chemical Dictionary", Tenth Edition, 1981. 2) "Threshold Limit Values for Chemical Substances In the Work Environment Adopted by ACGIH for 1988-89", American Conference of Governmental Industrial Hygienists. 3) "OSHA Safety and Health Standards (29 CFE 1910) OSHA 2206", Revised March 11, 1983, U.5. Department of Labor, Occupational Safety and Health Administration. 4) "Occupational Health Guidelines for Chemical Hazards", Prepared for National Institute for Occupational Safety and Health, January 1981, U.S. Department of Commerce National Technical Information service. 5) "NIOSH Pocket Guide to Chemical Hazards", September 1985, U.S. Department of Health & Human Services. Page 6 of 7 Jan-06-04 05:42pm From-RIKER, DANZIG, SCHERER T-328 P.101/114 F-577 PVC EMULSION RESIN 6} ''Registry of Toxic Effects of Chemical Substances", 1983 Supplement to the 1981-82 Edition, U.S. Department of Health & Human Services, Public Health Service, NIOSH. 7) "Fourth Annual Report on Carcinogens", 1985, National Toxicology Program (NTP), U.S, Public Health Service. 8) International Agency For Research On Cancer Monographs, Supplement 7, 1988. (0050S) Page 7 of 7 fifiOKIOftfft