Document rB9Qze2jyK1L20xNR9pYkNrme
(conoco)
Int roffice Communication
Distribution
sc-'*
dm* July 30, 1980 Subject MATERIAL SAFETY DATA SHEETS
Enclosed are the final drafts of revised Material Safety Data Sheets for cresols. As described in our letter of March 17, outlining the development process, we need your final review and comments before printing and dlstribution-of..the sbeets,...;.* ^j~
Wease refufn corndnU^to mef1fiy' August 117
"oFcfianges" are
noted, no response Is necessary. Your prompt action on this matter is appreciated, as there are many more sheets to be reviewed.
Thomas G. Grumbles TGG:dem Enclosures
Distribution: R. J. Andersen Jt-H Wrlsew Harry Garrison Hank Pi tera E. -Fr~ftdams
~W. Dv Broddle-' W. H. Chamberlain iL-J. Doyte N. C. Tresfe
L. G. Hubbard F. Kennedy 0. C. Kerfoot J. J. Langford ' R. E. Lehmkuhl V. A. Moore C. L. Whetstone, M.D. J. V. Withey
-\ " --,, .i` ^
.
-W*r -
'-iE^-274536
MATERIAL SAFETY DATA SHEET
Conoco Chwnicats
5 Graanway Plaza East P.O.Box 2197 Houston, Taxas 77001
1
MANUFACTURER'S NAME
PRODUCT IDENTIFICATION
Conoco Chemicals
REGULAR TELEPHONE NO. 201/344-3800 BAER60ICY TELEPHONE NO. 318/491-5070
ADDRESS
191 Doremus Avenue - Newark, NJ 07105
TRADENAME cresol 110, 120, 121, 130
SYNONYMS Ortho-Cresol, o-cresol, o-methyl phenol
II HAZARDOUS INGREDIENTS
MATERIALORCOMPONBft
; ' HKBaasuaR
Ortho-Cresol
98 DOT: Corrosive liquid
III
BQUINCEPOINTfF.) VAPOR PRESURE(mnrHg.) VAPOR DENSITY (AIR=-1) SOLUBILTTr IN WATER APPEARANCE ANDOOOR
PHYSICAL DATA
375 0.25 @ 250C 3.72 2.5q/100 ml
SPBOTCUlRAVnr(Hyt-rt)
PBTcacrvounrtE.
BnfOCUME(%)
`r
EVAPORATION^ RATE
( -IT - ^ :
MELJ1NG POINT V
v'v'.V ;
1.05 30C (86F)
Molten Solid - White to tan color; Phenolic odor
FIRE AND EXPLOSION DATA
flashpoint
(TEST METHOD)
178F PM
AUTDUDtfTTON TBHPERATURE
1038F
FLAMMABLEUMTTS:iNAHt%.Br-VOL
LOWER
1.3 ____ UPPBI
EXTINGUISHING MEOUL
Water (fog or spray), foam, dry chemical or C02.
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARD
Wear self-contained breathing apparatus and full protective clothing. Cool tanks with water, if exposed to fire.
Emits toxic fumes when heated.
*'EV-274537
HEAL: H:UA
FIRST AID
Immediately begin flushing with large amounts of water and continue
EYES:
at least for 15 minutes while transporting immediately for medical
attention.
____________
Remove contaminated clothing. Immediately f1ush with large amounts
SUN: of water, then wash affected areas with soap and water. Isopropanol
can be used to further remove phenols. Seek medical attention as sooh -as pns&ihlp.______________________________
Remove from exposure. Administer 0? by nasal cannulae if available.
MHAunoN: Administer artificial respiration If breathing has stopped. Seek
immediate medical attention.
Drink large amounts of water or weak sod-turn bicarbonate solution. DO
INGESTION: not INDUCE VOMITTING. If spontaneous vomittlnq occurs, precautions
chrt.ilHha Valrftn rn--urtIH acp-ifafr^n Coolf -immoHiata maHlrail
BYES:
SION:
SB
Corrosive
Corrosive to skin tissue. Prolonged contact will cause severe burns. Cresols are absorbed through the skin, resulting in systemic poisoning.
INHALATION: Corrosive. Vapors can be absorbed by mucous membranes causing systemic effects.
Corrosive. Causes burning of mouth and throat, abdominal pain,
ingestion: nausea and vomitting. Cresols are absorbed and can adversely affect
the central nervous system, heart, reproductive and urinary tissues,
- ------- 4-iver and kidnoyo.--------------- ------------
------------ ,,
. -
EFFECTS OF OVEREXPOSURE:
Local sk-in tottww
CHRONIC OVEREXPOSURE:
nervous system, liver and kidney, reproductive and.
urinary tissues. THRESHOLD LIMIT VALUE (TLV)
5 ppm (22 mg/m3)
skin hazard
ACGIH 1979
TOXICITY DATA
SKIN CONTACT:
Severe Irritant. Rabbit Dermal LD50 2gm/kg Primary skin irritation index: 5.6/8.0
Corrosive by DOT definition (49 CER 173.240)
EYE CONTACT:
Rabbit eye irritation score (maximum score 110) @ 24 hours wash:
84 (corrosive). Wash at 4 seconds: 43 (moderate)
INHALATION:
Rat LCso^ 20 mg/L No deaths occurred when rats, 5 per sex were exposed for 6 hours
to atmospheric concentrations of 0.2, 2, and 20 ng/L.
INGESTION:
Rat oral LD50 =0.36 qm/kg Deaths occurred at 1-3 days after treatment.
QDcrtAf DOcrarmnu^ ALL SKIN CONTACT Qfc INHALATION SHOULD BE AV01DEDL , SPEW. INarcuiALrntUAUIlun^. ofmovinR CRESOLS IS OF PRIMARY IMPORTANCE, ,-f v -
lvlEivl-2745'?S
Not Dangerously Reactive
INCOMPATIBILITY
I_
Not Applicable___________
HAZARDOUS DECOMPOSITION PRODUCTS
Not Applicable
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION
Not Applicable
VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKBIIF MATERIAL IS RELEASH) OR SPILLED
Ventilate area. Sawdust, vemiculite or sand may be used as sorbant. up mechanically. Use personal protective equipment as appropriate.
Pick
NEUTRALIZING CHEMICALS
Two to five percent solution of sodium hydroxide.
WASTE DISPOSAL METHOD
i
Biological oxidation or incineration according to established Federal
procedures. -
VIII SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS
Ensure that ventilation is adequate to maintain concentration in air less than 5 ppm.
SPECIFIC PERSONAL PROTHTTIVEEQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL):
Full face organic vapor cartridge or supplied air for high concentrations.
EYE:
Chemical safety goggles or face shield with goggles.
GLOVES:
Use rubber gloves to prevent skin contact.
OTHER CLOTHING AND EQU1PM0IT:
Aprons, boots, etc. should be used where needed to prevent skin contact.
274539
IX
IMCO HAZARD CLASS AND NUMBER
SPECIAL PRECAUTIONS
HAZARD CLASSIRCAnONINFQRMATlQN
US -DOTCLASSlHCATIpN
Corros 1
|
2076
ADR CLASS NUMBER
SC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER
95-48-7
MM*MMM
Tank cars, tank trucks, drums
Yes
... .
STORAGE/TRANSPORT PRESSURE
STORAGE TRANSPORT TEMPERATURE
LOADINGAINLOADING TEMPERATURE
Mav reauire aentle heatinawlth low pressure steam or hot water.
VISCOSITY AT LOADINGAINLOADING TBNPSMIURE
|
HANDLING AND STORAGE MATERIALSAIUJ K)^
1i /l ;
*: BUBBIfr'
Stainless Steel Grassiines Heresite-1 ined Carbon Steel - for short periods
if kept dry
. mmm*'-
.. i&em -
Brass and copper - cause rapid discoloration
------------------_ -til1yt-'1- -J
The above data is baaed on testa and experience which Conoco believes reliable and are supplied (or informational purposes only. Conoco disclaims any liability for damage or injury which results from the use of the above data and nothing contained therein shall constitute a guar antee, WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liability) by Conoco with respect to the data, the product described, or their use for any specific purpose, even if that purpose is known to Conoco. Conoco assumes nb responsibility for injury to Buyer or third persons proximatety caused by the product if reasonable safety measures are not adhered to as tipt--* in the data sheet.
VEV-274540
MATERIAL SAFETY DATA SHEET
Conoco Chemicals 5 Graanway Plaza East
root
1 PRODUCT IDENTIFICATION
MAMiPAmiHFR-s tune
HwaumciuHEH s NMie Conoco Chemicals
REGULAR TELEPHONE NO. 201/344-3800 EMERGENCY TELEPHONE NO. 318/491-5070
ADDRESS
191 Doremus Avenue - Newark. NJ 07105
TRADENAME Cresol 140"-
SYNONYMS Ortho-cresol, o-cresol. o-methyl Dhenol
.... ......... ..
II _____
HAZARDOUS INGREDIENTS
MATERtAtQR COMPOKOir
: %
Ortho-Cresol -Phenol
88 DOT: Corrosive Liquid 12
111 B0UJN& POINT (*F:)
VAPOR PRESURE (mnr Hg.)
VAPOR DENSITY (AIR * T) SOLUBWTYINWATER APPEARANCE AND ODOR
PHYSICAL DATA
381-392 F
3.4 4.0 g/100 ml
SPEOFfCGRAVny (Hitt* 1)
PERCENT VOLATILE: BY VOLUME (%) EVAPORATION'RATE
C -t)
MELJ1NGPOWT .
White solid - Sweet Tarry Odor
1.05 72-77 F
IV
FLASHPOINT (TEST METHOD)
178 F PM
FLAMMABLE UMTTSINAIR. % BYVOL
FIRE AND EXPLOSION DATA
AUrOfGMTIO*
temperature
i110o p
LOWER
UPPER
EXTINGUISHING MEDIA
Water (fog or spray), foam, dry chemical or
SPECIAL ORE FIGHTING PROCEDURES
UNUSUAL HRE AND EXPLOSION: HAZARD
Wear self-contained breathing apparatus and full protective cloth ing. Cool tanks with water if exposed to fire.
Emits toxic fumes when heated.
VEy-27454!
FIRST AID
EVES:
Immediately begin flushing with large amounts of water and continue at least for 15 minutes while transporting immediately for medical attention._____
SKIN:
Remove contaminated clothing. Immediately flush with large amounts of water, then wash affected areas with soap and water. Isopropanol can be used to further remove phenols. Seek medical attention as soon
a<i ___________________________ _
Remove from exposure. Administer 0? by nasal cannulae If available. inhalation: Administer artificial respiration if breathing has stopped. Seek
Immediate medical attention.
Drink large amounts of water or weak sodium bicarbonate solution. DO
ingestion: NOT INDUCE VOMITTING. If spontaneous vomlttlng occurs, precautions -------------- should be, tar.an toTvoid aspiration.--Seek Immediate medical attention.
NATURE OF HAZARD
Corrosive to skin tissue. Prolonged contact will cause severe burns. Cresols are absorbed through the skin, resulting In systemic poisoning.
inhalation: Corrosive. Vapors can be absorbed by mucous membranes causing
systemic effects.
INGESTION: Corrosive. Causes burning of mouth and throat, abdominal pain, nausea and vomiting.
EFFECTS OF OVEREXPOSURE:
LOCftt
bUW^-~
central nervous system, liver
THRESHOLD LIMIT VALUE (TLV) 5 ppm (22mg/m^) - skin
5 ppm (19mg/m3) - skin
1979 ACGIH for cresol 1979 ACGIH for phenol
Iney.
TOXICITY DATA
SUN CONTACT:
EYE CONTACT:
INHALATION:
INGESTION:
SPECIAL PRECAUTIONS^
ALL SKIN CONTACT SHOULD BE AVOIDED.. r.RFsm s ts op pp-tmapv TnPrtoTflnrr___
SPEED II? REMQYIR& :
yEkJ-274F4.'
CONDITIONS
NorTOft#
loiwswmpf ftei
...
-- -V1
fa .V* *.***.
INCOMPATIBILITY
Not Applicable
HAZARDOUS DECOMPOSITION PRODUCTS
Not Applicable- -- ------------
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION
Not Applicable
VI! SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IP MATERIAL IS RELEASED OR SPILLED
Ventilate area, Sawdust7~vermiculite or sand may be used as sorbant. up mechanically. Use personal protective equipment a? appropriate.
Pick
NEUTRALIZING CHEMICALS
Two to five percent solution of sodium hydroxide.
WASTE DISPOSAL METHOD
~
'
Biological oxidation or incineration according to established Federal
procedures.
"
VIII SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS
Ensure that ventilation is adequate to maintain concentration in air less than 5 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL):
Full face organic vapor cartridge or supplied air for high concentrations. EYE: Chemical safety goggles or face shield with goggles.
GLOVES: Use rubber gloves to prevent skin contact.
OTHER CLOTHING AND EQUIPMENT:
Aprons, boots, etc. should be used where needed to prevent skin contact. Full slicker suit may be required where exposure is 1ikely.
VEU-
IX SPECIAL PRECAUTIONS
IMCO HAZARD CLASS AND NUMBER
Class 6.1
HAZARD CLASSIFICATION INFORMATION
US DOT CLASSIFICATION
Corrosive liquid (primary)
Cresol 2076
ADR CLASS NUMBER ...
___________
SC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER
95-48-7 (o-cresol) 108-95-2 (phenol)
USUAL;
Tank cars, tank trucks, drums
STORAGE TRANSPORT TEMPERATURE
STORAGE/TRANSPORT PRESSURE
LOADING/UNLOADING TEMPERATURE
May require gentle heating with low
pressure steam or hot water.
VISCOSITY AT LOADMG/UNLOADINQ TEMPERATURE
HANDLING AND STORAGEMATERIALS AND COATINGS' ' ' -UI1. m;nn ,|||| 1.
Stainless steel Glasslined Heresite-lined Carbon steel - for short periods
if kept dry
Brass and copper - cause rapid discoloration
The above data la baaed on teats and experience which Conoco believes reliable and are supplied lor Informational purposes only. Conoco disclaims any liability for damage or injury which results from the use of the above data and nothing contained therein shad constitute a guar antee, WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liability) by Conoco with respect to the data, the product described, or their uae for any specific purpose, even if that purpose is known to Conoco. Conoco assumes no responsibility for injury to Buyer or third persons proximately caused by the product If reasonable safety measures are not adhered to as stipulated in the data
UEy-274544
MATERIAL SAFETY DATA SHEET
Conoco Chemicals
5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001
PRODUCT IDENTIFICATION
manufacturer's NAME Conoco Chemi cal s
REGULAR TELEPHONE NO. 201/344-3800 BAERBENCV TELEPHONE NO. 318/491-5070
ADDRESS
191 Doremus Avenue - Newark, NJ 07105
TRADE NAME Creso1 174
SYNONYMS Qrtho-cresol, o-cresol, o-methyl phenol
II HAZARDOUS INGREDIENTS
: MATERIALORCOMPON0tr_ -
_%*
Phenol o-cresol m,p-cresol 2,6-xylenol
_
27-32 50-55 13-18 5 max i
DOT: Corrosive liquid i
III
BOlUmrPOMTtT.} VAPOR PRESURE (irmvHg.) VAPOR DENSITY (AIR'*T) SQLUBIUTYIN WATER APPEARANCEANDODOR r
PHYSICAL DATA
378-408 F
3.4 4.0 (9/100ml)
SPH2RCBRAVTTT
PERCENT VOLATILE BTV0UJME(%)
*
EVAPORATIONRATE
(--------------------- -TK '"' '
mmmm t>our point
1,05 40 F
Light colored liquid with sweet tarry odor
IV
FLASff POINT (TEST METHOD)
180 F PM
FIRE AND EXPLOSION DATA
AUToiewnaN TEMPERATURE
FLAMMABLE UMnS INAflt%,BY VOL
LOWER
UPPER
EXTINGUISHING7 MEDIA,
Water (fog or spray), foam, dry chemical or COg.
SPECIAL FIRE HQHTTN0 PROCEDURES'
UNUSUAL FIRE AND EXPLOSION HAZARD
Wear self-contained breathing apparatus and full protective clothing Cool tanks with water if exposed to fire.
Emits toxic fumes when heated.
MEU-274545
TZi
HAZAUPNFORM^ffBIF
FIRST AID
EYES:
Immediately begin flushing with large amounts of water and continue at least for 15 minutes while transporting immediately for medical attention.
Remove contaminated clothing. Inmedlately flush with large amounts SKM: of water, then wash affected areas with soap and water. Isopropanol
can be used to further remove phenols. Seek medical attention as soon as possible.
mu,.-rum- Remove from exposure. Administer 02 by nasal cannulae if available. ,0,, Administer artificial respiration If breathing has stopped. Seek
immediate medical attention.
---------------Urink large amouWdt wAt6r~<rrW6aK S6diurPTCaTO0nat6 solution. TO
INGESTION: NOT INDUCE VOMITTING. If spontaneous vomitting occurs, precautions -------------- should, hp taken tn avnirl aspiration,___sppV imrwdiate medical attantioi
.
EYES: ~ 'Corrosive ' TM
Corrosive to skin tissue. Prolonged contact will cause severe burns. Cresols are absorbed through the skin, resulting In systemic poisoning.
INHALATION: Corrosive. Vapors can be absorbed by mucous membranes causing systemic effects.
INGESTION: Corrosive. Causes burning of mouth and throat, abdominal pain, nausea and vomiting.
EFFECTS OF OVEREXPOSURE:
AGUftOVIBKiPQRMfc Local skin burns. chronic overexposure: Dermatitis aria chronic poisoning affecting the central
nervous svstem. liver and kidnev.
THRESHOLD LIMIT VALUE (TLV) Cresol 5 ppm (22 mg/m?) - skin hazard Phenol 5 ppm (19 mg/nr) - skin hazard
ACGIH 1979 ACGIH 1979
TOXICITY DATA
SKIN CONTACT:
EYE CONTACT:
INHALATION:
INGESTION:
SWPtEbCUIUALLPTMRtELCAAUUTl'IUOPNIS5^t ACLRLESSOLKSIffISCOONFTAPCRTIMSAHROYULIDMPBOERATAVNOCIDEE. D.
SPEHkTK: REMOVING ^
V
Not Dangerously Reactive
INCOMPATIBILITY
Not Applicable
HAZARDOUS DECOMPOSITION PRODUCTS
Not Applicable - --- --
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION
Not Abblicable
VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN If MATERIAL IS RELEASED OR SPILLED
Ventilate area. Sawdust, vermiculite or sand may be used as sorbant. Pick up mechanically. Use personal protective equipment ft's appropriate.
NEUTRALIZING CHEMICALS
Two to five percent solution of sodium hydroxide.
WASTE DISPOSAL METHOD
Biological oxidation or inceneration according to- established Federal procedures. _ ............
VIII
VENTILATION REQUIREMENTS
SPECIAL PROTECTION INFORMATION
Ensure that ventilation is adequate to maintain concentration in air less than 5 ppm.
SPECIFIC PERSONAL PR0TECT1VEEQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL):
Full face organic vapor cartridge or supplied air for high concentrations.
EYE; Chemical safety goggles or face shield with goggles.
GLOVES; Use rubber gloves to prevent skin contact.
OTHER CLOTHING AND EQUIPMENT:
Aprons, boots, etc. should be used where needed to prevent skin contact. Full slicker suit may be required where exposure is 1ikely.
IX
^
SPECIAL PRECAUTIONS
HAZARD CLASSIRCATIOtt.INFORMAnQN> :
/ . -: , '
IMCO HAZARD CLASS AND NUMBER
US DOT CLASSIFICATION
Class 6.1
UN NUMBER
Cresols Phenol
2076 1671
ADR .CLASS NUMBER
______
_____ ___
DOT: Corrosive
SC DANGEROUS SUBSTANCE CLASSIFICATION
SC SPECIAL RISKS ANO SAFETY AOVNX
|
CAS NUMBER
Mixed Cresols 1319-77-3
- ::V-'imismmmmismKSBv ^
- ''
' - % : --
USUAL SHIPPING CONTAINERS
ELECTROSTATIC ACCUMULATION HAZARD
Tank cars, tank trucks, drums
STORAGE/TRANSPORT PRESSURE
STORAGE TRANSPORT TEMPERATURE
LOADING/UNLOADING TEMPERATURE
V-`T *.
d -i
VISCOSITY AT LOADING/UNLOADING TEMPERATURE
HANOUNCTAND'ST0RAGEMA1B)IALS;AND^CIKIU,HIGS ; '' ;"J; ' ?* |
SUITABLE
UNSUITABLE
Stainless steel Glasslined Heresite-lined Carbon steel - for short periods
if kept dry
Brass and copper - cause rapid discoloration
The above date it bated on tests and experience which Conoco beiievet reliable and are supplied tor totormettonal purposes only. Conoco disclaims any liability tor damage or injury which results from me use of the above data and nothing contained thereto shall constitute a guar* antes, WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liability) by Conoco with respect to the data, the product described, or their use for any specific purpose, even if that purpose is known to Conoco. Conoco assumes no responsibility for injury to Buyer or third persons proximatety caused by the product if reasonable safety measures are not adhered to as adputotad in the data sheet
UEV-274548
MATERIAL SAFETY DATA SHEET
Conoco Chemicals 5 Greanway Plaza East P.O. Box 2197
Houston, Texas 77001
ManufacTURHI'Sname
PRODUCT IDENTIFICATION
Conoco Chemical-
REGULAR mB'HONENO. 20'Y1!/K; BcT:7i!i emergency telephoneno. 318/491 -5070
ADDRESS 191 Doremus Avenue. Newark. NJ 07105
TRADENAME Cresal 180
SYNONYMS Phenol, Carbolic Add
II HAZARDOUS INGREDIENTS MAIBBAL0RCQMP0NB1T
Phenol 0-cresol
78-82 18-22
DOT: Poison B
III
BORJNffPOMT (*E)VAPOR PRESURE(nnn-Hb,)
VAPOR D0tSrTY (AIR - 1)
SOLUBIUTYIN.WATER APPEARANCEAND ODOR ,
PHYSICAL DATA
393-398 F 3.2
SPEaHCOTtfOTTrC^tt*^. ^
PERcarnraumtE
BYVOLUME(%) ^ `
EVAPOHATIORRAIF --
i -------- -ty
MBHNffPowr
1.068 72 F
Light colored liquid with sweet tarry odor
IV
FLASH pomr
(TESTMETHOD)
178 F PM
FIRE AND EXPLOSION DATA
Auioiaimo* > TEMPERATURE
1
FLAMMABLE LIM1TSIN A1R.VBY VOlL
LOWER
UPPER
EXTINGUISHING MB)IA
Water (fog or spray), foam, dry chemical or CO2.
SPECIAL FIRE FIGHTING
PROCEDURES
Wear self-contained breathing apparatus and full protective clothing. Cool tank with water if exposed to fire.
UNUSUAL FIRE AND EXPLOSIONHAZARD
Emits toxic fumes when heated.
VEV-274549
FIRST AID
EYES:
HEAflinfAZARD INFORMATia?^
Immediately begin flushing with large amounts of water and continue at least for 15 minutes while transporting immediately for medical
skin-
of water, then wash affected areas with soaD and water. Isopropanol
can be used to further remove phenols. Seek medical attention as
soon as oossible. Remove from exposure. Administer Op by nasal cannulae ir available. INHALATION: Administer artificial respiration if breathing has stopped. Seek
imnedlate medical attention.
urinK large amounts of water or weax sodium bicarbonate solution, uu IN6ESTI0N: NOT INDUCE VOMITTING. If spontaneous vomlttlnq occurs, orecautlons
NATURE OF HAZARD
gygj.
Causes severe burns
skin-
Causes severe bums. Readily absorbed through the skin resulting in systemic toxicity. Skin exposures can be fatal.
INHALATION: Corrosive to mucous membranes. May be absorbed through the mucous membranes causing systemic toxicity.
INGESTION: Corrosive. Causes burning of mouth and throat, abdominal pain, nausea and vomittlng.
EFFECTS OF OVEREXPOSURE:
ACUTE OVEREXPOSURE: Local skin burns
..........
Dermatitis and chronic poisoning affecting the
chronic overexposure: central nervous system, liver and kidney.
THRESHOLD LIMIT VALUE (TLV)
Cresol 5 ppm (22 mg/m^) - skin hazard Phenol 5 ppm (19 mg/m3) - skin hazard
ACGIH 1979 ACGIH 1979
TOXICITY DA1A
SKIN CONTACT:
EVE CONTACT:
INHALATION:
INGESTION:
1 cpcffir PRmtfmnNCi ^LL SKIN CONTACT SHOULD .BE. AVOIDED*. SPEEDS"IN?* REJIQVINC'
am.lAtl'HtbAUIIUNSL CRESOtS is OF PRIMARY TMPflRTANOF.
>7
UEV-27455G
"REACTIVITY DM
CONDITIONS CONTRIBUTING TO INSTABILITY
Not Applicable
INCOMPATIBILITY
Not Applicable
HAZARDOUS DECOMPOSITION PRODUCTS
.Not Applicable
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION
Will not occur
VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPR1ED
Ventilate area. Sawdust, vermiculite or sand may be used as sorbant. Pick up mechanically. Use personal protective equipment as appropriate.
NEUTRALIZING CHEMICALS
................
Two to five percent solution of sodium hydroxide.
WASTE DISPOSAL METHOD
Biological oxidation or inceneration according to established Federal procedures.
VIII
VENTILATION REQUIREMENTS
SPECIAL PROTECTION INFORMATION
Ensure that ventilation is adequate to maintain concentration in air less than 5 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
' RESPIRATORY (SPECIFY IN DETAIL):
Full face organic vapor cartridge or supplied air for high concentrations. EYE: Chemical safety goggles or face shield with goggles.
GLOVES: Use rubber gloves to prevent skin contact.
OTHER CLOTHING AND EQUIPMENT:
Aprons, boots, etc. should be used where needed to prevent skin contact. Full slicker suit may be required where exposure is likely.
MEV-274551
IX SPECIAL PRECAUTIONS
~ ^ HAZARD CLASSIFICATION INFORMATION
IMCO HAZARD CUSS AND NUMBER
..... Class 6.-1 -- --------------
UN NUMBER
Phenol 1671 Cresol 2076
US DOT CLASSIFICATION
Poison B Corrosive Liquid
SC DANGEROUS SUBSTANCE CLASSIFICATION
ADR CLASS NUMBER
SC SPECIAL RISKS AND SAFETY ADVICE
,,
CAS NUMBER
Phenol 108-95-2 Cresol 95-48-7
' /' r" r
Y - TRANSPORTOIOItANDSOTAGE^'
USUAL SHIPPING CONTAMBIS
Tank cars, tank trucks, drums
ELECTROSTATIC ACCUMULATION HAZARD
Yes
STORAGE/TRANSPORT PRESSURE
STORAGE TRANSPORT TEMPERATURE
LOADING/UNLOADING TEMPERATURE
Mav reouire aentle heatina. with low oressure steam or hot water.
VISCOSITY AT LOAOMG/UNLOADtNG TEMPSUHJRE
HANDLING AND STORAGE MACBtlALS'AND COATINGS^ K'
SUITABLE
UNSUI1ABLE
Stainless Steel Glasslined Heresite-lined Carbon Steel - for short periods
if kept dry
Iron or copper cause discoloration
?^
The above data is bassd on tacts and experience which Conoco believes reliable and ara supplied for informational purposes ortfy. Conoco
disclaims any liability for damage or injury which results from the use of the above ate and nothing contained therein shall constitute a guar
antee, WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent KabiMy) by Conoco with reaped to the data,
the product described, or their use for any specific purpose, even if that purpose is known to Conoco. Conooo assumes no responsibility for
injury to Buyer or third persons proximately caused by the product if reasonable safety measures are not adhered to as
* In the data
sheet
yE'J-274'552