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DuPont C orporate Center for Analytical Sciences
Experim ental Station W ilm ington, D e 19880
C ertificate o f A nalysis
C haracterized W ithin a GLP Com pliant F acility
Name: Molecular Formula: Formula Weight: Date o f Synthesis: Date o f Analysis: Expiration Date: Storage Conditions: Solvent (crystallization): Physical Appearance: Stnicture: PurityImpurities:
Perfluorooctanoic acid, [l,2-d i-13C]
CgHFisOa
416
January 2,2003
May 2005
May 2007 controlled normal room temperature
Vertrel-XF
Solid, Colorless flakes
C6Fi3l3CF2I3C 0 2 H
96.6% 1.4%
1.9%
n.d.
C7F,513C 0 2 H C6Fl313CF2C 02 H C7Fl5C 0 2 H
Printed Name
Signature
Date:
/ ' 5 l `S b S
Fipura 1:
L-PFOS; (TIC and Mass Spectrum)
20jan2006_LPFOS_0Q4 12.5 ug/mL
10O-,
20-Jan-2006
13:33:07
p.8
Scan ESTIC
1.07efl
J L0 i TTTiTT7yTnr| n 1i ff) rT|YT,fr-|Tr rrpnTr|/H-ri,)-T
0.50 1.00 1.50 2.00 2.50
3.00
3.50
4.00
4.50
5.00
5.50
Conditions for figure 1:
LG: Waters Acqulty Ultra Performance LC MS: Micromass Quattro micro API
Chromatoaraohlc Conditions
Column:
Acqulty UPLC BEH Shield RP,,
1.7 pm, 2.1 x 100 mm
Mobile phase: Isocratlc Start: 35% H ,0 with 10 mM NH,OAc
65% (80:20 MeOH;ACN) with 10 mM NH,OAc Ramp: none Time: 10 mins
Flow:
300 pUmin
lyiS Parameters
Experiment Full Scan (215- 900 amu)
Source: Electrospcay (negative) Capillary Voltage (kV) 2.60 Cone voltage (V) *=80.00 Cone Gas Flow (UHr) 50 Desolvation Gas Flow (UHr) = 650
Fotmlk2T RevO, 2003-03
Wellington Laboratories Inc., 345 Southgate Dr. Guelph ON N1G 3M5 CANADA LPFOS0405 (2 of 3)
Figure 2:
L-PFOS; Selected MRM Transitions
P-9
' Conditions tor Flaure 2:
Injection:
Direct loop injection 10 pi (500 ppb L-PFOS)
IVI?Pacametere
! Collision Gas (mbar)a 3.46e-3
I
Mobile phase: Isocratic 65% (80:20 MeOH/ACN}/35% H,0
Collision Voltage (V) = 40
(10 mM ammonium acetate buffer)
Flow
300 pi/min
F<X(t\&27 RevO. 2003-02
Wellington Laboratories Inc., 345 Southgate Dr. Guelph ON N1G 3M5 CANADA LPFOS0405 {3 of 3)
p. 10
WELLINGTON
L A B O R A T O R IE S
CERTIFICATE OF ANALYSIS/DOCUMENTATION
PRODUCT CODE:
someoumbi STRUCTURE:
L-PFOS Sodium perfluoro-1-odanesulfonate
LOT NUMBER: LPFOS0405
F. F F. F F. \/ \/
F F. F \/
. SOj -Na*
/\ / \ / \ A
Fp F FF FF F
CAS#:
LUPAC ft
Not available Not applicable
MOLECULAR-FORMULA;
CONCENTRATION; CHEMICAL EUPITY; LAST-TESTED: h-- * * RECOMMENDED STORAGE: EXPIRYDATE:
C,F,,SOj'Na 50 2.5 pg/ml >98% 01/20/2006 (LC/MS/MS) Store at 4*C protected from light Stability studies ongoing
MOLECULAR WEIGHT: 522.11
SOLVENTS:
Methanol
B ETA ILS;
One-product unambiguous synthesis Structure confirmed by NMR ("F) Uncertainty Is the maximum combined relative uncertainty of weights and volumes All weights and volumes are traceable to NIST LC/MS (TIC and mass spectrum) data attached, see Figure 1 MRM transitions showing L-PFOS at greater than 98% purity and the absence of common impurities
are shown in Figure 2
ADDITIONAL INFORMATION:
if additional information is required please contact Wellington Laboratories (www.well-labs.comT
NOT FOR HUMAN/DRUG USE POTENTIALLY TOXIC TO HUMANS
FOfttiMT
RbyO. 2003-03
C ertified By:
Date: 01/23/2006
Wellington Laboratories lnc,, 345 Southgate Dr. Guelph ON N1G 3M5 CANADA LPFOS0405 (1 of 3)
4 'Y i '%J%
g t 0 -**
125 Mafket Street New Haven, CT 08513 USA
AccuStandard, Inc. * * * *
Tel (203)788-5290 Fax (203)786-5287
Web AccuSfandard.com
CERTIFICATE OF ANALYSIS
CATALOGNO. PFOA-001S
DESCRIPTION: Perlluorooctanoic acid
LOT: B6010049
SOLVENT:
MeOH See reverse fo r additional certification inform ation.
EXPIRATION: Jan 10, 2016
This produel U guuvueed accurato lo 05% oflfoe Certified Aflfllyto concentraiIon Ihrwjft the Expiration Dal on the Label.
Component Pertluoroctanofc acid
CAS #
Purity % MFG
Prepared C o n c e n tra tio n 1
(/jg/m L)
94 107.0* 4.28
C ertified Analyte C o n c e n tra tio n 1 Ot/g/mL)
100.6
J-v;..!"- Vv"3- o 'j V5^*4 2 :. ,,,. `ivi,-!.. r '.*' * SV*>X.
: * . **/ v'
`;V-
Weight compensated to 100% purity
Please note: AccuStandard follows the U.S. conventions in reporting numerical values, on both certificates and labels.
A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as a decimal place marker.
1. AH weights are traceable through National Institute of Standards & Technology
Test No.
822/270236-04
2. Certified Analyte Concentration Purity x Prepared Concentration
3. A product with a suffix (-1A, -2B, etc.) on its lot# has had its expiration date
extended and is identical to the same lot# without the suffix.
Candied by? This product was manufactured to meet the quality system requirements of ISO 9001:2000 and IS0 17025
OR-ORGANO-
Rsv.&OS
p. 12 c/ ki v /' -- r y
125 Market Street New Haven, CT 06513 USA
AccuStandard, Inc.
Tet (203)786-5290 Fax (203)766-5267
Web AccuSlandard.com
CERTIFICATE OF ANALYSIS
m9at d MS'1
uife. (ris
CSS
io n
Cerasa*KvtenCilfMfvrfllM*w
CATALOG NO. PFOS-001S
DESCRIPTION: Perfiuorooctane sulfonic acid
LOT: B6010180
SOLVENT:
MeOH See reverse for additional certification inform ation.
EXPIRATION: Jan 17, 2016
This predite* Is gomraeed scansie to 0.5$ ofihe Certified Anriyte cwKCQtraifon ihreujh lite Expiration One on tbo Label.
Component Perfiuorooctane sulfonic acid
CAS#
Purity % MFG
Prepared C o n c e n tra tio n 1
Cug/mL)
1763-23-1
98 100.4 4.016
Certified Analyte C o n c e n tra tio n 1 0/g/mL)
98.4
\ '>
. S. 'A- f..v*%,*..'.#. *V; `
* .ft
3-- '
Please note: AccuStandard M ow s the U.S. conventions in reporting numerical values, on both certificates and labels.
A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as a decimal place marker.
1. All weights are traceable through National Institute of Standards & Technology
Test No.
822/27023(5-04
2. Certified Analyte Concentration = Purity x Prepared Concentration
3. A product with a suffix (-IA, -2B, etc.) on its tot# has had its expiration date
extended and is identical to the same lot# without the suffix.
CflrtiNtdfcya:
C 'jrrry z fL
This product was manufactured to meet the quality system requirements of ISO 9001:2000 and IS 0 17025
O-Ofl<3/fWO-C01 RftV-BOS
I n l e t Method R e p o rt
Method File: Last Modified:
Printed:
Mas3Lynx 4 .1
Pape
C:\MassLynx\PFOA.PRO\ACQODB\PFOA2Tes t Wednesday, November 29, 2006 10:23:03 Mountain Standard Time
Wednesday, November 29, 2006 10:58:53 Mountain Standard Time
Waters Acquity SOS Method
Comment: Solvent Selection A: A2 Solvent Selection B: Bl Low Pressure Limit: 0 psi High Pressure Limit: 15000 psi Solvent Name A: Methanol Solvent Name B: 0.1% aq Formic Acid Switch 1: No Change Switch 2: No Change Switch 3: No Change Seal Wash: 5.0 min Chart Out 1: System Pressure Chart Out 2: %B System Pressure Data Channel: Yes Flow Rate Data Channel: Yes %A Data Channel: Yes %B Data Channel: Yes Primary A Pressure Data Channel: No Accumulator A Pressure Data Channel: No Primary B Pressure Data channel: No Accumulator B Pressure Data Channel: No Degasser Pressure Data Channel: No [Gradient Table]
Time (min) Flow Rate(mL/min) %A %B Curve 1. Initial 0.300 80.0 20.0 Initial 2. 10.00 0.300 100.0 0.0 6 3. 10.01 0.300 80.0 20.0 6 Run Events: yes
Waters Acquity Autosampler Method
Comment: Load Ahead: Disabled Loop Option: Full Loop LoopOffline: Disable Weak Wash Solvent Name: Water Weak Wash Volume: 1000 uL Strong Wash Solvent Name: Water Strong Wash Volume: 1000 uL Target Column Temperature: Off C Column Temperature Alarm Band: Disabled Target Sample Temperature: 15.0 C Sample Temperature Alarm Band: Disabled Full Loop Overfill Factor: 1.0 Syringe Draw Rate: 50 Needle Placement: 2.0 Pre-Aspirate Air Gap: 2.0 Post-Aspirate Air Gap: 2.0 Column Temperature Data Channel: No Ambient Temperature Data Channel: Yes Sample Temperature Data Channel: No Sample Organizer Temperature Data Channel: No Sample Pressure Data Channel: Yes Switch 1: No Change Switch 2: No Change Swi tch 3: No Change Switch 4: No Change Chart Out: Sample Pressure Sample Temp Alarm: Disabled Column Temp Alarm: Disabled Run Events: yes End of Report
Quattro Premier Tune Param eters
MassLynx 4.1
File: C:\MassLynx\PFOA.PRO\ACQUDB\PFOA.IPR
Printed:
Wednesday, November 29, 2006 11:00:15 Mountain Standard Time
Page 1 of 1
Type Daughter Scan
Source (ES-) Capillary (kV) Cone (V) Extractor (V) RF Lens (V) Source Temperature (C) Desolvation Temperature (C ) Cone Gas Flow (L/Hr) Desolvation Gas Flow (L/Hr)
Analyser LM 1 Resolution H M 1 Resolution Ion Energy 1 Entrance Collision Exit LM 2 Resolution HM 2 Resolution Ion Energy 2 Multiplier (V) Syringe Pump Flow (uL/min)
Pressure Gauges Gas Cell Pirani Pressure(mbar)
MUX Configuration Probe
Source T-WAVE Parameters Automated
Collision Cell T-WAVE Parameters Automated
Start Mass 368
Settings 1.50 20.00 5.00 0.2 120 300 19 699
Settings 12.5 12.5 0.8 0 10 1 12.5 12.5 0.8 650 50.0
5.30e-3
Standard
End Mass 370 Readbacks 1.46 -26.25 -5.74 119 294
Readbacks
10 10 11
-649
p. 15
Experiment Report
MassLynx 4.1
File: c:\massiynx\pfoa.pro\acqudb\pfoslong.exp
Printed:
Wednesday, November 29,2006 10:59:00 Mountain Standard Time
Page 1 of 1
Name Creation Time Instrument Identifier Version Number Duration (min) Calibration Filename Solvent Delay Divert Valve Enabled Number Of Functions
Default Experiment Wed 29 Nov 2006 07:02:14
1.0 12.0
C:\MassLynx\Hexachlorophene.PRO\ACQUDB\PEG100306.cal 0
1
Function 1 : MRM of 5 mass pairs, Tim e 0.00 to 12.00, ES>
Type
MRM
Ion Mode
ES-
Inter Channel Delay (sec)
0.010
InterScan Time (sec).
0.010
Span (Da)
0.0
Start Time (min)
0.0
End Time (min)
12.0
Ch Prnt(Da) Dau(Da) Dwell($) Cone(V) Co!l(eV) Deiay(s)
412.70 218.90 0.300 20.00 16.00 0.010
412.70 368.90 0.300 20.00 10.00 0.010
414.70 369.90 0.200 20.00 10.00 0.010
498.60 79.90 0.200 60.00 40.00 0.010
498.60 98.80 0.400 60.00 40.00 0.010
Quantify Calibration Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Method: C:\MassLynx\PFOA-PRO\MethDB\pa36k29s.mdb 30 Nov 2006 06:57:57 Calibration: 30 Nov 2006 07:08:01
Compound name: PFOA Coefficient of Determination: RA2 = 0.999251 Calibration curve: -0.000247718 * xA2 + 0.926432 * x + 0.0773411 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
Page 1 of 4
p. 16
Quantify Calibration Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Compound name: APFO Coefficient of Determination: RA2 = 0.999249 Calibration curve: -0.000226201 * xA2 + 0.889835 * x + 0.0776092 Response type: internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
Page 2 of 4
p. 17
Analyst: Steve Cowling
Quantify Calibration R eport M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday. November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Compound name: PFOA 13C2 Response Factor: 3387.75 RRF SD: 95.0757, % Relative SD: 2.80646 Response type: External Std, Area Curve type: RF
Page 3 of 4
Analyst: Steve Cowling
Quantify Calibration Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Compound name: PFOS Coefficient of Determination: RA2 = 0.999658 Calibration curve: -0.000346812 * xA2 + 0.751564 * x + 0.0129081 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area )
Curve tpf2n*0`rder, origin: txciuae, Wighiihg: l/x, AxtsnarrerNune
Page 4 of 4
p. 19
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
-
Method: C:\MassLynx\PFOA-PROtMethDB\pa36k29s.mdb 30 Nov 2006 06:57:57 Calibration: 30 Nov 2006 07:08:01
Name: pf36k2954, Date: 29-Nov-2006, Tim e: 18:52:04, ID: 930.86.1, Description: Blank
PFOA pf36k2954 Smooth(Mn,2xl) Blank 930.86.1
PFOA 7.98
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2954 Smooth(Mn,2x1) Blank 930.86.1
Page 1 of 148 '
PFOA 8.06
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
min
p. 20
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Tune
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2954, Date: 29-Nov-2006, Tim e: 18:52:04, ID: 930.86.1, Description: Blank
APFO
pf36K2954 Smootf)(Mn,2xi) Blank 930.86.1
APFO 7.98
MRMof5channels.ES412.7 > 368.9
APFO
pf36k2954 Smooth(Mn.2xl) Blank 930.86.1
Page 2 of 148
APFO 8.06
MRMof5xhannets.ES412.7 >218.9
p. 21
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2954, Date: 29-Nov-2006, Tim e: 18:52:04, ID: 930.86.1, Description: Blank
PFOA13C2
pf36k2954 Smooth(Mn,2x1) Blank 930.85.1
PFOA13C2 8.03
MRMof5channels.ES414.7 > 369.9
PFOS
pf36k2954 Smooth(Mn.2x3) Blank 930.86.1
Page 3 of 148
MRM of 5 channels.ES498.6 > 79.9
p. 22
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4. ,
PFOA Analysis
Dataset:
C:VMassLynx\PFOA.PRO\pf36k292s.t(!d
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2954, Date: 29-Nov-2006, Tim e: 18:52:04, ID: 930.86.1, Description: Blank
PFOS pf36k2954 Smooth(Mn,2x3) Blank 930.86.1
MRM of 5 channels,ES498.6>98.8
Page 4 of 148
0 " i r r r p r i i i-p i i i | i 11 i i p i 'I1v 1 r-i-r i | r m | i i i i | i i' i"'i")' t t~n ~| i ' i 'i 'l 'n i i min
2.0 4.0 6.0
8.0 10.0
is," < '5-, te l
1 PFOA 2APF0 3PFOA13C2 4 PFOS
7.98 230.467 bbl 7.98 230.467 bbl 8.03 35044.391 bb
-.ja 35044.391 35044.391
35044.391
3 3 0 3
0.066 0.066 35044.391
10.344 103.4
Analyst: Steve Cowling
p. 23
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C :\M assLynx\P FO A P R O \pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2955, Date: 29-Nov-2006, Tim e: 19:05:01, ID: 930.86.2, D escription; 0.2 /ra /L
PFOA
pf36k2955 Smooth(Mn.2xl) 0.2 pg/L 930.86.2
PFOA 8.03
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36X2955 Smooth(Mn,2x1) 02.PQ/1930.86J2
:
Page S of 14S
PFOA 8.06
MRM of 5 channels.ES412.7 >218.9
p. 24
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2955, Date: 29-Nov-2006, Tim e: 19:05:01, ID: 930.86.2, Description: 0.2 //g /L
APFO
pf36k2955 Snrcootti(Mn.2xl) 0.2 //g/L 930.86.2
APFO 8.03
MRM of 5 channels.ES412.7 > 368.9
APPO
pf36k2955 Smooth(Mn,2x1) 0.2 pg/L 930.86.2
'
Page 6 of 148
APFO 6.06
MRM of 5 channels.ES412.7 >218.9
p. 25
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qlcl
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2955, Date: 29-Nov-2006, Tim e: 19:05:01, ID: 930.86.2, Description: 0.2 jjgIL
PFOA13C2
pf36k2955 Smooth(Mn.2x1) 0.2 /g/L 930.86.2
PFOA 13C2 8.03
MRM of 5 channels.ES414.7 > 369.9
PFOS
pf36k2955 Smooth(Mn,2x3) 0.2 jjq/L. 930.86.2
Page 7 of 148
PFOS MRM of 5 channels,ES8.86 498.6 >79.9
p. 26
Analyst: Steve Cowling
Quantify Sample Report
MassL> x 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s .qId
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2955, Date: 29-Nov-2006, Tim e: 19:05:01, ID: 930.86J2, Description: 0.2/sg/L
PFOS pf36k2955 Smooth(Mn,2x3) 0.2 pg/L 930.86.2
PFOS MRM of 5 channels.ES6.86 498.6>98.8
Page 8 of 148
p. 27
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C :\M assLynx\P FO A P R O \pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2956, Date: 29-Nov-2006, Tim e: 19:17:58, ID: 930.86.3, Description: 0.5 jjg/L
PFOA pf36K2956 Smooth(Mn,2x1) 0.5 ^g/L 930.86.3
PFOA 8.03
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2956 Smooth(Mn,2x1) 0.5 p g lt 930.86.3
Page 9 of 14E
,
PFOA
MRM of 5 channels,ES-
8.01 412.7 > 218.9
p. 28
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.uid
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2956, Date: 29-Nov-2006, Tim e: 19:17:58, ID: 930.86.3, Description: 0.5 //g /L
APFO pf36K2956 Smoom(Mn,2x1) CI.5 //g/L 930.86.3
APFO 8.03
MRM of 5 channels,ES412.7 >368.9
APFO
pf36k2956 Smooth(Wn,2x1) 0.5 ^g/L 930.86.3
.
Page 10 of 148
APFO 8.01
MRM of S channels,ES 412.7 >218.9
p. 29
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2956, Date: 29-Nov-2006, Tim e: 19:17:58, ID: 930.86.3, D escription: 0.5 //g /L
PFOA13C2
pf36K2956 Smooth(Mn.2x1) 0.5 pg/t 930.86.3
PFOA13C2 6.03
PFOS
MRM of 5 channels,ES- pf36k2956 Smooth<Mn.2x3) 414.7 > 369.9 0.5 pg/L 930.86.3
-
Page 11 of 148
PFOS MRM of 5 channels,ES8.89 498.6 >79.9
p. 30
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2956, Date: 29-Nov-2006, Tim e: 19:17:58, ID: 930.86,3, Description: 0.5 pgIL
PFOS pf36k2956 Smooth(Mn,2x3) 0.5 //g/L 930.66.3
PFOS MRM of 5 channete.ES8.89 498.6>98.8
Page 12 of 14i
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.03 8.03 8.03 8.89
1919.961 1919.961 33937.699 1284.654
bb bb bb bb
33937.699 33937.699
33937.699
3 0.566 3 0.566 0 33937.699 3 0.379
0.527 0.549 10.018 0.487
105.4 105.5 100.2
97.3
Analyst: Steve Cowling
p. 31
Quantify Sample Report
MassLynx**
PFOA Analysis
Dataset:
C :\M assL yn x\P F O A P R O \p f36k292s.q ld
Last Altered: Thursday, November 3 0,200 6 07:08:01 Mountain Standard Time
B-inted:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2957, Date: 29-Nov-2006, Tim e: 19:30:55, ID: S30.86.4, Description: 1 //g /L
PFOA
PFOA
Page 13 of 148
Analyst: Steve Cowling
Q uantify Sample Report
MassLynx 4.1
Page 14 of 148
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
(Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
________ __________ -- ..... -- -- -- ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Q.
Name: pf36k2957, Date: 29-Nov-2006, Tim e: 19:30:55, ID: 930.86.4, Description: 1 //g /L
APPO
pf36k2957 Smooth(Mn,2x1) 1 jug/L 930.86.4
APPO 8.03
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2957 Smooth(Mn,2x1) 1 //g/L 930.86.4
APFO 8.03
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Q uantify Sam ple Report
M assLynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
^Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2957, Date: 29-Nov-2006, Tim e: 19:30:55, ID: 930.86.4, Description: 1 //g /L
PFOA13C2
pf36k2957 Smooth(Mn,2x1) 1//g/L 930.36.4
PFOA 13C2 8.03
MRM of 5 channels,ES414.7 > 369.9
PFOS
pf36k2957 Smooth(Mn,2x3) 1//g/L 930.86.4
Page 15 of 148
PFOS MRM of 5 channels,ES-
8.89
498.6 >79.9
Analyst: Steve Cowling
\
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
p rin ted :
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
co-------- -- ------------------------------------ - ----------- - ......
Name: pf36k2957, Date: 29-Nov-2006, Tim e: 19:30:55, ID: 930.86.4, Description: 1 /ug/L
PFOS
pf36k2957 Smooth(Mn.2x3) 1 pg/L 930.86.4
100-
PFOS MRM of 5 channels,ES-
6.89 498.6>98.8
186A8.93
6.632e+003
%
U-^T-T> i ''i' ..... ' i |_i '*i i'*'i | rr i i |- m i i"r-rn r f1.- ." r1p 'i11 !"[' rn"i"["i i i i min
2.0 4.0 6.0 8.0 10.0
.."l VS;?
m u -. $ ||
Mm 1 1 1
4 Z*
1PFOA 2APF0 3 PFOA 13C2 4 PFOS
8.03 8.03 8.03 8.89
3234.157 3234.157 35119.074 2724.531
db db bb bb
35119.074 35119.074
35119.074
3 3 0 3
0.921 " 0.921 35119.074 0.776
0.911 0.948 10.367 1.016
91.1 91.1 103.7 101.6
Analyst: Steve Cowling
Page 16 of 14i
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
tin te d :
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2958, Date: 29-Nov-2006, Tim e: 19:43:53, ID: 930.86.5, Description: 2 //g /L
PFOA
pf36k2958 Smooth(Mn,2x1) 2 //g/L 930.86.5
PFOA 8.06
MRMof5channels.ES412.7 > 368.9
PFOA
pf36k2958 Smaoth(Mn.2x1) 2 //g/L 930.86.5
Page 17 of 148
PFOA 8.08
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Quantify Sam ple Report
MassLynx 4.1
PFOA Analysis
Dataset;
C :\M assLynx\P FO A P R O \pf36k292s.qld
Last Altered; Thursday, November 30,200 6 07:08:01 Mountain Standard Time
iRrinted:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2958, Date: 29-Nov-2006, Tim e: 19:43:53, ID: 930.86.5, Description: 2 //g /L
APFO
pf36k2958 Smooth(Mn,2x1) 2 /g/L 930.86.5
APFO 8.06
MRM of 5 channels.ES412.7 > 368.9
APFO
pf36k2958 Sinooth(Mn,2x1) 2 //g/L 930.86.5
Page 18 of 148
APFO 8.08
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Q uantify Sam ple Report
M assLynx 4.1
Page 19 of 148
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
printed:
Thursday, November 3 0,200 6 07:09:11 Mountain Standard Time
co~----------------- ------------- ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
d
Name: pf36k29S8, Date: 29-Nov-2006, Tim e: 19:43:53, ID: 930.86.5, Description: 2 pg/L
PFOA 13C2
pf36k2958 Smootti(Mn,2x1 ) 2 ^g/L 930.86.5
PFOA 13C2 8.06
MRM of 5 channels.ES414.7 > 369.9
PFOS
pf36k2958 Smooth(Mn,2x3) 2 //g/L 930.86.5
PFOS MRM of 5 channels,ES8.6S 498.6 >79.9
*
Analyst: Steve Cowling
rp. I39Ni
Quantify Sam ple Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30. 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2958, Date: 29-Nov-2006, Tim e: 19:43:53, ID: 930.86.5, D escription: 2/jgfL
PFOS pf36k2958 Smooth(Mn,2x3) 2 //g/L 930.86.5
PFOS MRM of 5 channefe.ES8.89 498.6>98.8
Page 20 of 14
sgi **;: & C kl- M
1 PFOA * 2 apfo 3 PFOA 13C2 4 PFOS
Toe 8.06 8.06 8.89
6788.372 6788.372 32835.023 5227.391
bb bb bb bb
32835.023 32835.023
H
3 2.067 3 2.067 0 32835.023 3 1.592
i
2.149
2.237
9.692
2.103
107.5 107.5 96.9 105.2
Analyst: Steve Cowling
Quantify Sam ple Report
M assLynx4.1
PFOA Analysis
Dataset:
C :\M assL yn x\P F O A P R O \p f36k292s.q ld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
firinted:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2959, Date: 29-Nov-2006, Tim e: 19:56:49, ID: 930.86.6, D escription: 5p g /L
PFOA
pf36k2959 Smooth(Mn,2x1) 5 pg/L 930.86.6
PFOA 8.06
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2959 Smooth(Mn,2x1) 5 //g/L 930.86.6
Page 21 of 146
PFOA 8.08
MRM of 5 channels.ES412.7 > 218.9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k^92s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
p rinted:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2959, Date: 29-Nov-2006, Tim e: 19:56:49, ID: 930.86.6, D escription: 5 //g /L
APFO
pf36k2959 Smooth(Mn,2xl) 5 jt/g/L 930.86.6
APPO 8.06
MRM of 5 channels,ES412.7 >368.9
AFFO
pf36k29S9 Smooth(Mn,2x1) 5 /g/L 930.86.6
Page 22 of 142
APFO 8.08
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
p. 42
Quantify Sam ple Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0,200 6 07:08:01 Mountain Standard Time
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2959, Date: 29-Nov-2006, Tim e: 19:56:49, ID: 930.86.6, Description: 5 fjglL
PFOA13C2
pf36k2959 Smooth(Mn,2x1) 5 //g/L 930.86.6
PFOA 13C2 8.06
MRM of 5 channels.ES414.7 >369.9
PFOS
pf36k2959 Smooth(Mn,2x3) 5 ^g/L 930.86.6
Page 23 of 148
MRM of 5 channels,ES498.6 >79.9
Analyst: Steve Cowling
Q uantify Sample Report
MassLy. x 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
f'dO-
Name: pf36k2959, Date: 29-Nov-2Q06, Time: 19:56:49, ID: 930.86.6, Description: 5/jgiL
PFOS
pf36k2959 Smooth(Mn,2x3)
5 pg/L 930.86.6
100
PFOS MRM of 5 channels,ES-
8.89 498.6>98.8
9640.07
3.339e+004
%-
"r 'p " i"i i"| "i r r 'r p r i u | i"'i t i |"i "i i r p 1
2.0 4.0 6.0
"i i i ry v'll i1] 11|| ii111II11 8.0 10.0
min
i 1 PFOA i. ' ' 2APFO
| | | 3 PFOA 13C2 4 PFOS
8.06 16036.770 bb 8.06 16036.770 bb 8.06 35034.536 bb 8.91 12765.787 bb
35034.535 35034.535
35034.535
3 4.577 3 4.577 0 35034.535 3 3.644
4.864 5.063 10.342 4.842
97.3 97.3 103.4 96.8
Page 24 of 148 mm
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qla
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2960, Date: 29-Nov-2006, Tim e: 20:09:46, ID: 930.86.7, D escription: 10jc/g/L
PFOA pf36k2960 Smooth(Mn,2x1) 10//g/L 930.86.7
PFOA 8.06
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2960 Smooth(Mn,2xl) 10 ^g/L 930.86.7
Page 25 of 148
PFOA 8.06
MRM of 5 channels,ES412.7 > 218.9
p. 44
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.Mld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2960, Date: 29-Nov-2006, Tim e: 20:09:46, ID: 930.86.7, Description: 10/sg/L
APFO
APFO
Page 26 of 148
p. 45
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2960, Date: 29-Nov-2006, Time: 20:09:46, ID: 930.86.7, D escription: 10 figlL
PFOA13C2
pf36k2960 Smooth(Mn,2x1) 10 pgA- 930.86.7
PFOA13C2 8.06
MRM of 5 channels,ES414.7 >369.9
PFOS
pf36k2960 Smooth(Mn,2x3) 10 //g/L 930.86.7
;
Page 27 of 148
MRM of 5 channels.ES498.6 >79.9
p. 46
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.i
PFOA Analysis
Dataset
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday. November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2960, Date: 29-Nov-2006, Tim e: 20:09:46, ID: 930.86.7, Description: 1 0 //g /L
PFOS pf36k2960 Smooth(Mn,2x3) 10//gA. 930.86.7
100-,
PFOS 8.89 18390.65
MRM of 5 channeis.ES498.6>98.8 6.297e+004
1
0 * \ v t i | i i i i p 'T n r j 'i t i i"| "i i i i j 2.0 4.0
i > \ rrT*i [
6.0
I I 'I '! I I I" min 10.0
ilT j
1PFOA 2APFO 3 PFOA13C2 4 PFOS
e.oe"
8.06 8.06 8.89
30703.297 30703.297
32762.703 24682.434
bd
bd
bb bb
32762.703 32762.703
32762.703
aakM H M M aH aaa
3
9.371
10.059 100.6
3
9.371
10.472 100.6
0 32762.703
9.671 96.7
3
7.534
10.053 100.5
Analyst: Steve Cowling
Page 28 of 148
p. 47
Quantify Sample Report
MassLynx 1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed;
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2961, Date: 29-Nov-2006, Tim e: 20:22:44, ID: 930.86.8, Description: 20 //g /L
PFOA
pf36k2961 Smooth(Mn,2x1) 20 pg/L 930.86.8
PFOA 8.06
MRM of 5 channels,ES4-12.7 > 368.9
PFOA
pf36k2961 Smooth(Mn.2x1) 20 jjg/i. 930.86.8
'
Page 2 9 of 14
PFOA 8.06
MRM of 5 channels,ES412.7 >218.9
p. 48
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2961, Date: 29-Nov-20Q6, Tim e: 20:22:44, ID: 930.86.8, D escription: 2 0 //g /L
APFO
pf36k2961 Smooth(Mn.2x1) 20 pg/L 930.86.8
APFO 8.06
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2961 Smooth(Mn,2x1) 20 //g/L 930,86.8
'
Page 30 of 14S
APFO 8.06
MRM of 5 channels ES412.7 >218.9
p. 49
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k232s.qld
Last Altered: Thursday, November 3 0,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday. November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2961, Date: 29-Nov-2006, Tim e: 20:22:44, ID: 930.86.8, Description: 20 pg/L
PFOA 13C2
pf36k2961 Smooth(Mn,2x1) 20 ^g/L 930.86.8
PFOA 13C2 8.06
MRM of 5 channels.ES414.7 > 369.9
PFOS
pf36k2961 Smooth(Mn,2x3) 20//g/L 930.86.8
'
Page 31 of 148
MRM of 5 channels,ES498.6 >79.9
p. 50
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.1
PFOA Analysis
D a ta s e t
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2961, Date: 29-Nov-2006, Tim e: 20:22:44, ID: 930.86.8, D escription: 2 0 /ig /L
PFOS
pf36k296l Smooth{Mn,2x3) 20/vg/L 930.86.8
100 t
PFOS 8.89 37467.13
MHM of 5 channels,ES498.6>98.8 1.273e+00S
%-
0*Wtttjt
y'p'TTI JI M l"|T'HT[" 'I
2.0 4.0 6,0
I'
mi 8.0
T-J-pn
10.0
min
4&.4-** rifts. ffr
62927.840 62927.840 34013.551 50704.246
bb bb bb bb
34013.551 34013.551
34013.551
3 18.501 3 18.501 0 34013.551 3 14.907
19.993 20.814 10.040 20.002
100.0 100.0 100.4 100.0
Analyst: Steve Cowling
Page 32 of 148
p. 51
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2962, Date: 29-Nov-2006, Tim e: 20:35:43, ID: 930.86.1, D escription: Blank
PFOA pf36k2962 Smooth(Mn,2x1) Blank 930.86.1
PFOA 8.08
MRM of 5 diannels.ES412.7 > 368.9
PFOA
pf36k2962 Smooth(Mn,2x1) Blank 930.86.1
;
Page 33 of 146
PFOA 8.06
MRM of 5 channels,ES412.7 >218.9
p. 52
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4..
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2962, Date: 29-Nov-2006, Tim e: 20:35:43, ID: 930.86.1, Description: Blank
APFO pf36k2962 Smooth(Mn,2x1) Blank 930.86.1
APFO 8.08
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2962 Smooth(Mn,2x1) Blank 930.86.1
Page 34 of 146
APFO 8.06
MRM of 5 Channels,ES412.7 >218.9
p. 53
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C :\M assLynx\P FO A P R O \pf36k292s.qid
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2962, Date: 29-Nov2006, Tim e: 20:35:43, ID: 930.86.1, D escription: Blank
PFOA13C2
P 3 6 K 2 9 6 2 Smootti(Mn,2x1 ) Biank 930.86.1
PFOA 13C2 MRM of 5 channels,ES-
6.06
414.7 >369.9
PFOS
pf36k2962 Smooth{Mn,2x3) Blank 930.86.1
Page 35 of 148
MRM of 5 channels.ES498.6 > 79.9
p. 54
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.'1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA PRO\pf36k292s .qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2962, Date: 29-Nov-2006, Tim e: 20:35:43, ID: 930.86.1, D escription: Blank
PFOS
pf36k2962 Smooth(Mn,2x3) Blank 930.86.1
MRM of 5 channets.E S 498.6>98.8
Page 36 of 148
1 PFOA 2APFO 3PFOA13C2 4 PFOS
8.08 8.08 8.06 9.35
236.178 236.178 36359.434
8.244
bbl bbl bb bbl
36359.434 36359.434
36359.434
3 0.065 3 0.065 0 36359.434 3 0.002
10.733 107.3
Analyst: Steve Cowling
p. 55
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2963, Date: 29-Nov-2006, Tim e: 20:48:37, ID: 930.86.9, Description: 2 //g /L ICV
PFOA
pf36k2963 Smooth(Mn.2x1) 2 pQ /L ICV 930.86.9
PFOA 8.06
MRM of 5 channels,ES412.7 > 368.9
PFOA
p(36k2963 Smooth(Mn,2x1) 2pglL ICV 930.86.9
Page 37 of 148
PFOA 8.08
MRM of 5 channels,ES412.7 >218.9
p. 56
Analyst: Steve Cowling
Quantify Sample Report
M as sL y n x 4 .1
PFOA Analysis
Dataset;
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2963, Date: 29-Nov-2006, Tim e: 20:48:37, ID: 930.86.9, D escription: 2 /#g/L ICV
APFO
pf36k2963 Smooth(Mn,2x1)
APFO
MRM of 5 channels.ES-
APFO
pf36k2963 Smooth{Mn,2x1)
;
Page 38 of 148
APFO
MRM of 5 channels.ES-
p. 57
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C :\M assLynx\P FO A P R O \pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2963, Date: 29-Nov-2006, Tim e: 20:48:37, ID: 930.86.9, Description: 2 //g /L 1CV
PFOA13C2
pf36k2963 Smooth(Mn,2x1) 2 yt/g/L ICV 930.86.9
PFOA13C2 8.06
MRM of 5 channels.ES414.7 > 369.9
PFOS
pf36k2963 Smooth(Mn,2x3) 2pgJL ICV 930.86.9
Page 39 of 148
MRM of 5 channels,ES498.6 >79.9
p. 58
Analyst: Steve Cowling
Quantify Sample Report
NlassLynx 4.1
PFOA Analysis
D a ta s e t
C:VMassLynx\PFOA.PRO\pf36k292s.md
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2963, Date: 29-Nov-2006, Tim e: 20:48:37, ID: 930.86.9, D escription: 2 //g /L ICV PFOS
Page 40 of 146
,;r .
1 pPFfOoAa ' " 2 APFO 3 PFOA 13C2 4 PFOS
8.06 8.06 8.06 8.91
6110.953 6110.953 33411.656 4104.304
db db bb bb
33411.656 33411.656
33411.656
3 1.829 3 1.629 0 33411.656 3 1228
1.892 1.969 9.863 1.618
94.6 94.6 98.6 80.9
m
Analyst: Steve Cowling
p. 59
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:06:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2964, Date: 29-Nov-2006, Tim e: 21:01:35, ID: 930.86.3, D escription: 0.5 pg/L RLV
PFOA pf36k2964 Smooth(Mn,2x1) 0.5 ^g/L RLV 930.86.3
PFOA 8.08
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2964 Smocrth(Mn,2x1) 0.5 ^g/L RLV 930.86.3
;
Page 41 of 14
PFOA 8.08
MRM of 5 channels.ES412.7 >218.9
p. 60
Analyst: Steve Cowiing
Quantify Sample Report
M assLynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2964, Date: 29-Nov-2006, Tim e: 21:01:35, ID: 930.86.3, Description: 0.5 /vg/L RLV
APFO
pf36k2964 Smooth{Mn,2x1) 0.5 p g /L RLV 930.86.3
APFO 8.08
MRM of 5 Channels,ES412.7 > 368.9
APFO
pf36k2964 Smooth(Mn,2xl) 0.5 //g/L RLV 930.86.3
Page 42 of 146
APFO 8.08
MRM of 5 Channels,ES412.7 >218.9
p. 61
Analyst: Steve Cowling
Quantify Sample Report
Nlassl_ynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qid
Last Altered: Thursday, November 30,200 6 07:08:01 Mountein Standard Time
Printed:
Thursday, November 3 0,200 6 07:09:11 Mountain Standard Tim e
Name: pf36k2964, Date: 29-Nov-2006, Tim e: 21:01:35, ID: 930.86.3, D escription: 0.5 //g /L RLV
PFOA13C2
pf36k2964 Smooth(Mn,2xl) 0.5/yg/L RLV 930.86.3
PFOA13C2 8.06
MRM of 5 Channels,ES414.7 >369.9
PFOS
pf36k2964 Smooth(Mn.2x3) 0.5//g/L RLV 930.86.3
Page 43 of 146
MRM of 5 channels,ES498.6 >79.9
p. 62
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2964, Date: 29-Nov-2006, Tim e: 21:01:35, ID: 930.86.3, Description: 0.5 pg/L RLV
PFOS
pt36k2964 Smooth(Mn.2x3) 0.5 pg/L RLV 930.86.3 ,,AA
PFOS MRM of 5 channels.ES-
8.91 498.6>96.8
966.38
3.456e+003
Page 44 of 14S
& .$ # &
1 PFOA 2APFO 3 PFOA 13C2 4 PFOS
8.08 1864.180 bb 8.08 1864.180 bb 8.06 34345.410 bb 8.91 1292.502 bb
34345.410 34345.410
34345.410
3 0.543 3 0.543 0 34345.410 3 0.376
m
0.502 100.5
0.523 100.5 10.138 101.4
0.484 96.7
Analyst: Steve Cowling
p. 63
Quantify Sample Report
MassLynx ' 1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2974, Date: 29-Nov-2006, Tim e: 23:11:05, ID: 930.86.6, Description: 5 //g /L CCV
PFOA
pf36k2974 Smootti(Mn,2x1 ) 5 ^g/L CCV 930.86.8
PFOA 8.10
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2974 Smooth(Mn,2x1) 5 fjgll. CCV 930.86.6
:
Page 81 of 148
PFOA 8.10
MRM of 5 channels,ES412.7 >218.9
p. 64
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
D a ta s e t
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30.2006 07:09:11 Mountain Standard Time
Name: pf36k2974, Date: 29-Nov-2006, Tim e: 23:11:05, ID: 930.86.6, Description: 5 //g /L CCV
APFO pf36k2974 Smooth(Mn,2x1) 5 /ug/L CCV 930.86.6
APFO 8.10
MRM of 5 channels,ES~ 412.7 > 368.9
APFO
pf36k2974 Smooth(Mn,2x1) 5 //g/L CCV 930.86.6
Page 82 of 148
APFO 8.10
MRM of 5 channels ES4 1 2 .7 > 2 1 8 .9
p. 65
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA. PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2974, Date: 29-Nov-2006, Tim e: 23:11:05, ID: 930.86.6, Description: 5 //g /L CCV
PFOA13C2 pf36k2974 Smooth(Mn,2x1)
PFOS PFOA13C2 MRM of 5 channels,ES- pf36k2974 Smooth(Mn,2x3)
Page 83 of 146 MRM of 5 channels,ES-
p. 66
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C :\M assLynx\PFOA.PRO\pf36k292s.qlu
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2974, Date: 29-Nov-2006, Tim e: 23:11:05, ID: 930.86.6, D escription: 5jug/L CCV
PFOS pf36k2974 Smooth(Mn,2x3) 5 pg/L CCV 930.86.6
MRM of 5 channels,ES498.6>98.8
Page 84 of 148
2 APFO 3 PFOA13C2 4 PFOS
8.10 15930^1*81 bb 8.10 15930.181 bb 8.10 36178.738 bb 8.96 13354.931 bb
36178.738 36178.738
36178.738
3 4.403 3 4.403 0 36178.738 3 3.691
PM 4.675 4.867
10.679
4.906
93.5 93.5 106.8 98.1
Analyst: Steve Cowling
p. 67
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2975, Date: 29-Nov-2006, Tim e: 23:24:02, ID: JJV7E1AA, D escription: D6K160299-5
PFOA
pf36k2975 Smooth(Mn.2x1) D6K160299-5 JJV7E1AA
PFOA 8.18
MRM of 5 channels,E S412.7 > 368.9
PFOA
pf36k2975 Smooth(Mn,2x1 ) D6K160299-5 JJV7E1AA
Page 85 of 148
PFOA 8.18
M R M o f5d ian n els.E S 412.7 >218.9
p. 68
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2973, Date: 29-Nov-2006, Tim e: 22:58:09, ID: JJV7C1AA, D escription: D6K160299-4
PFOS
pf36k2973 Smooth(Mn.2x3) 06K160299-4 JJV7C1AA
MRM of 5 channels,ES498.6>98.8
Page 80 of 14E
0 I I I r r i'T iTp'-i i i i'Ti I'l'T'i (' 2.0 4.0 6.0
[~t i
8.0
1 1 [ I i"r> ; I I I I min 10.0
39118.750 39116.750
39116.750
3 0.107 3 0.107 0 39116.750 3
0.001 0.001 11.547
115.5
Analyst: Steve Cowling
p. 69
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qid
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2973, Date: 29-Nov~2006, Tim e: 22:58:09, ID: JJV7C1AA, Description: D6K160299-4
PFOA13C2
pf36k2973 Smooth(Mn,2x1) D6K160299-4 JJV7C1AA
PF0A13C2 8.15
MRM of 5 channels,ES414.7 > 369.9
PFOS
pf36k2973 Smooth(Mn,2x3) D6K160299-4 JJV7C1AA
Page 79 o f 148
MRM of 5 channels.ES498.6 > 79.9
p. 70
Analyst: Steve Cowling
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.q!d
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2973, Date: 29-Nov-2006, Tim e: 22:58:09, ID: JJV7C1AA, Description: D6K160299-4
APFO
pf36K2973 Smootfi(Mn.2x1) D6K160299-4 JJV7C1AA
APFO 8.08
MRM of 5 channels.ES412.7 > 368.9
APFO
p age yg 0f 1 4 5
p. 71
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:VMassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2973, Date: 29-Nov-2006, Tim e: 22:58:09, ID: JJV7C1AA, Description: D6K160299-4
PFOA pf36k2973 Smooth(Mn,2x1) D6K160299-4 JJV7C1AA
PFOA 8.08
MRM of 5 channels,ES412.7 > 368.9
PFOA
Page 77 of 14?
p. 72
Analyst: Steve Cowling
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Tim e
Name: pf36k2972, Date: 29-Nov-2006, Tim e: 22:45:11, ID: JJV691AA, Description: D6K160299-3
PFOS pf36k2972 Smooth(Mn,2x3) D6K160299-3 JJV691AA
MRM of 5 channels,ES498.6>98.8
Page 76 of 148
llll
1 PFOA 2 APFO 3 PFOA 13C2 4 PFOS
8.15 6841.614 bb 8.15 6841.614 bb 8.13 38915.801 bb 8.93 17074.643 bb
38915.801 38915.801
38915.801
3 1.756 3 1.758 0 38915.801 3 4.388
0.036 0.037 11.487 0.115
114.9
Analyst: Steve Cowling
p W
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2972, Date: 29-Nov-2006, Tim e: 22:45:11, ID: JJV691AA, Description: D6K160299-3
PFOA13C2
pf36K2972 Smoom(Mn,2xl) D6K160299-3 JJV691AA
PFOA13C2 MRM of 5 channels,ES8.13 414.7 > 369.9
PFOS
pf36k2972 Smooth(Mn,2x3) D6K160299-3 JJV691AA
P age 75 o f 14
MRM of 5 channels,ES498.6 > 79.9
p. 74
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2972, Date: 29-Nov-2006, Tim e: 22:45:11, ID: JJV691AA, Description: D6K160299-3
APFO
pf36k2972 Smooth(Mn,2x1) 06K160299-3 JJV691AA
AFFO 8.15
MRM of 5 channels.ES412.7 > 368.9
APFO
pf36k2972 Smooth(Mn,2x1) D6K160299-3 JJV691AA
;
Page 74 of 146
APFO 8.13
MRM of 5 channels ES412.7 >218.9
p. 75
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2972, Date: 29-Nov-2006, Tim e: 22:45:11, ID: JJV691AA, D escription: D6K160299-3
PFOA
Pf36k2972 Smooth(Mn.2x1) D6K160299-3 JJV691AA
PFOA 8.15
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf36k2972 Smooth(Mn,2x1 ) D6K160299-3 JJV691AA
Page 73 of 148
PFOA 8.13
MRM o f 5 channels,ES412.7 >218.9
p. 76
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynxVPFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2971, Date: 29-Nov-2006, Tim e: 22:32:13, ID: JJV671AA, D escription: D6K160299-2
PFOS pf36k2971 Smooth(Mn,2x3) D6K160299-2 JJV671AA
100-i
PFr Ov oS
a-93 1
451166..13
MRM of5 channels,ES49a6>98.8 1.188e+004
-T j i
2.0
t"| "r'i"n~[*T r
4.0
1 PFOA 2APFO 3 PFOA 13C2 4 PFOS
r-r-rrT-rt-j-t t h "y-r"ft n r " *t~t--|**i tt i-p r r r r nun 6.0 8.0 10.0
8.13 4044.266 bb 8.13 4044.266 bb 8.13 39473.387 bb 8.93 7436.145 bb
39473.387 39473.387
39473.387
3 1.025 3 1.025 0 39473.387 3 1.884
tikh.i.livj-i'.-1-r
0.020 0.021
11.652 116.5 0.049
Analyst: Steve Cowling
Page 72 of 14S
P- 77
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2971, Date: 29-Nov-2006, Tim e: 22:32:13, ID: JJV671AA, Description: D6K160299-2
PFOA13C2
pf36k2971 Smooth(Mn.2x1) D6K160299-2 JJV671AA
PFOA13C2 8.13
MRM of 5 channels,ES414.7 > 369.9
PFOS
pf36k2971 Smooth(Mn.2x3) D6K160299-2 JJV671AA
Page 71 of 14
MRM of 5 channels.ES498.6 >79.9
p. 78
Analyst: Steve Cowling
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2971, Date: 29-Nov-2006, Tim e: 22:32:13, iD: JJV671AA, D escription: D6K160299-2
APFO pf36k2971 Smoom(Mn,2x1)
APFO
APFO MRM of 5 charinels.ES- pf36k2971 Smooth(Mn.2x1)
;
Page 70 of 148
APFO
MRM of 5 channels.ES-
p. 79
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2971, Date: 29-Nov-2006, Tim e: 22:32:13, ID: JJV671AA, Description: D6K160299-2
PFOA
pf36k2S71 Sm ooth(M n^xl) D6K160299-2 JJV671AA
PFOA 8.13
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf3Sk2971 Smooth(Mn^xl) D6K160299-2 JJV671AA
Page 69 of 14E
PFOA 8.10
MRM of 5 channels,ES412.7 >218.9
p. 80
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2970, Date: 29-Nov-2006, Tim e: 22:19:17, ID: JJV631AD, Description: D6K160299-1 DUP
PFOS
pf36k2970 Smooth(Mn,2x3) D6K160299-1 DUPJJV631AD
MRM of 5 channels.ES498.6>98.8
Page 68 of 148
lS^ : ,
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.13 8.13 8.10 8.93
3577.006 3577.006 38088.262 7856.674
bb bb bb bb
38088.262 380B8262
38088.262
3 0.939 3 0.939 0 38088.262 3 2.063
0.019 0.019 11243 0.055
112.4
Analyst: Steve Cowling
p. 81
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2970, Date: 29-Nov-2006, Tim e: 22:19:17, ID: JJV631AD, Description: D6K160299-1 DUP
PFOA13C2 pf36k2970 Smooth(Mn,2x1)
MRM of 5 channels,ES-
PFOS p!36k2970 Smooth(Mn,2x3)
Page 67 of 148 . MRM of 5 channels,ES-
p. 82
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\Massl_ynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Tim e
Name: pf36k2970, Date: 29-Nov-2006, Tim e: 22:19:17, ID: JJV631AD, Description: D6K160299-1 DUP
APFO pf36k2970 Smooth(Mn,2x1)
APFO MRM of 5 channels,ES- pf36k2970 Smooth(Mn,2x1)
Page 66 of 148 . MRM of 5 channels,ES-
p. 83
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2970, Date: 29-Nov-2006, Tim e: 22:19:17, ID: JJV631AD, D escription: D6K160299-1 DUP
PFOA
pf36k2970 Smooth(Mn,2x1) D6K160299-1 DUP JJV631AD
MRM of 5 channels.ES412.7 > 368.9
PFOA
p#36k2970 Smooth<Mn,2x1) D6K160299-1 DUP JJV631AD
Page 65 of 148
MRM of 5 channels,ES412.7 > 218.9
p. 84
Analyst: Steve Cowling
Q u antify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2969, Date: 29-Nov-2006, Tim e: 22:06:21, ID: JJV631AC, Description: D6K160299-1 MS
PFOS
pf36k2969 Smooth(Mn.2x3) D6K160299-1 MS JJV631AC
MRM of 5 channels,ES498.6>98.8
Page 6 4 o f 14
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.13 43661.070 bb 8.13 43661.070 bb 8.13 38649.508 bb 8.93 27872.289 bb
38649.508 38649.508
38649.508
3 11.297 3 11297 0 38649.508 3 7.212
mmm 0.243 121.5 0253 121.5 11.409 114.1 0.192 962
Analyst: Steve Cowling
p. 85
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
D a ta s e t
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2969, Date: 29-Nov-2006, Tim e: 22:06:21, ID: JJV631AC, Description: D6K160299-1 MS
PFOA13C2
pf36k2969 Smooth(Mn,2x1) D6K160299-1 MS JJVS31AC
MRM of 5 channels,ES414.7 > 369.9
PFOS
pf36k2969 Smooth(Mn,2x3) D6K160299-1 MS JJV631AC
'
Page 63 of 14
MRM of 5 channels ES498.6 >79.9
p. 86
Analyst: Steve Cowling
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed: .
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2969, Date: 29-Nov-2006, Tim e: 22:06:21, ID: JJV631AC, D escription: D6K160299-1 MS
APFO
pf36k2969 Smooth(Mn.2x1) D6K160299-1 MS JJV631AC
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2969 Smooth(Mn,2x1 ) D6K160299-1 MS JJV631AC
Page 62 of 148
MRM of 5 channels,ES412.7 >21B.9
p. 87
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0,200 6 07:09:11 Mountain Standard Time
Name: pf36k2969, Date: 29-Nov-2006, Tim e: 22:06:21, ID: JJV631AC, Description: D6K160299-1 MS
PFOA
pf36k2969 Smoottn(Mn.2x1) D6K160299-1 MS JJV631AC
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf36k2969 Smooth{Mn,2x1) D6K160299-1 MS JJV631AC
P ag e61o f14i
MRM of 5 channels.ES412.7 >218.9
p. 88
Analyst: Steve Cowling
Quantify Sample Report
M assLynx4.1
PFOA Analysis
D ataset
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2968, Date: 29-Nov-2006, Tim e: 21:53:23, ID: JJV631AA, Description: D6K160299-1
PFOS
pf36k2968 Smooth(Mn,2x3) D6K160299-1 JJV631AA
MRM of 5 Channels,ES498.6>96.8
Page 60 of 148
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.13 3878.344 bb 8.13 3878.344 bb 8.13 38538.133 bb 8.93 7477.024 bb
38538.133 38538.133
38538.133
13
3
3
0
3
1.006 1.006 38538.133 1.940
0.020 0.021 11.376 0.051
113.8
Analyst: Steve Cowling
p. 89
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qId
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2968, Date: 29-Nov-2006, Time: 21:53:23, ID: JJV631AA, Description: D6K160299-1
PFOA13C2
pf36K296S Smooth(Mn.2x1) D6K160299-1 JJV631AA
PFOA13C2 8.13
MRM of 5 channels.ES414.7 >369.9
PFOS
pf36k2968 Smooth(Mn.2x3) D6K160299-1JJV631AA
Page 59 of 148
MRMofSchannds.ES498.6 >79.9
p. 90
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\Massl_ynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2968, Date: 29-Nov-2006, Tim e: 21:53:23, ID: JJV631AA, Description: D6K160299-1
APFO
pf36K2968 Smooth(Mn.2x1) D6K160299-1 JJV631AA
APFO 8.13
MRM of 5 channels,ES412.7 > 368.9
APFO
pf35k2368 Smooth(Mn,2x1) D6K160299-1JJV631AA
Page 58 of 14
APFO 8.13
MRMof 5 channels,ES412.7 >218.9
p. 91
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2968, Date: 29-Nov-2006, Tim e: 21:53:23, ID: JJV631AA, D escription: D6K160299-1
PFOA pf36fc2968 Smooth(Mn,2x1) D6K160299-1 JJV631AA
PFOA 8.13
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2968 Smooth(Mn.2x1) D6K160299-1 JJV631AA
Page 57 of 148
PFOA 8.13
MRM of 5 channels.ES412.7 >218.9
p. 92
Analyst: Steve Cowling
Quantify Sampie Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2967, Date: 29-Nov-2006, Tim e: 21:40:26, ID: JJ7QR1AD, Description: R6K210000-618 LCS
PFOS pf36k2967 Smooth(Mn.2x3) R6K210000-616 LCS JJ7QR1AD
100
PFOS 8.93 1327.01
MRM of 5 charmels.ES498.6>98.8 4.865e+003
%-
, ! 1 |I-1' I 1 I I
2.0
j L L d 1PF0A"1
4 PFOS
I i' iT -rt j 1 1 `t r \ 1 i i i [ i 1 i"i 1 1r r ) rr t r \ 1 r
10.0
r rn"" min
H W i
'
8.08 3245.832 bb
34760.438
3
0.934
0.018 92.5
8.08 3245.832 bb
34760.438
3
0.934
0.019 92.4
8.08 34760.438 bb
0 34760.438
10261 102.6
8.93 1762.663 bb
34760.438
3
0.507
0.013 65.8
Page 56 0f 148 a
p. 93
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2967, Date: 29-Nov-2006, Tim e: 21:40:26, ID: JJ7QR1AD, Description: R6K210000-618 LCS
PFOA13C2
pf36k2967 Smooth(Mn,2x1) R6K210000-618LCS JJ7QR1AD
M RM of5channels.ES414.7 > 369.9
PFOS
pf36k2967 Sfnooth{Mn,2x3) R6K210000-618 LCS JJ7QR1AD
Page 55 of 148
MRM of 5 channels,ES498.6 > 7 9 .9
p. 94
Analyst: Steve Cowling
Q uantify Sam ple R eport
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s .qId
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2967, Date: 29-Nov-2006, Tim e: 21:40:26, ID: JJ7QR1AD, Description: R6K210000-618 LCS
APFO
pf36k2967 Smooth(Mn,2x1) R6K210000-618 LCS JJ7QR1AD
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2967 Smooth(Mn.2x1) R6K210000-618 LCS JJ7QR1AD
Page 54 of14
MRM of 5 channels,ES412.7 >218.9
p. 95
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynxVPFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2967, Date: 29-Nov-2006, Tim e: 21:40:26, ID: JJ7QR1AD, D escription: R6K210000-618 LCS
PFOA
pf36k2967 Smooth{Mn,2x1) R6K210000-618 LCS JJ7QR1AD
MRM of 5 channete.ES412.7 > 368.9
PFOA
pf36k2967 Smooth(Mn,2x1) R6K210000-618 LOS JJ7QR1AD
Page 53 of 148
MRM of 5 channels.ES412.7 > 218 .9
p. 96
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynxVPFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2966, Date: 29-Nov-2006, Tim e: 21:27:30, ID: JJ7QR1AC, D escription: R6K210000-618 LCS
PFOS pf36k2966 Smooth(Mn,2x3) R6K210000-618 LCS JJ7QR1AC
100-,
PFOS 8.93
"I
17038.85
MRM of 5 channels.ES498.6>98.8 5.968e+004
%-
Page 52 of 14E
0 IT T | I I 1 1 | 'I'T'I T'p 'I I I | I I I I | H 'l T J I TT' 2.0 4.0 6.0
Tl'l min
^ 2 APFO 3PFOA13C2 4 PFOS
8Qa 8.08 8.08 8.93
38589.758 38589.758 34415273 22184.063
bb bb dd bb
34415273 34415273
34415273
3 ' 11213 3 11213 0 34415273 3 6.446
IS E lP iiE iilE liS
0241 120.6 0251 120.6 10.159 101.6 0.172 85.9
p. 97
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2966, Date: 29-Nov-2006, Tim e: 21:27:30, ID: JJ7QR1AC, Description: R6K210000-618 LCS
PFOA13C2
pf36k2966 Smootfl(Mn,2x1) R6K210000-618 LCS JJ7QR1AC
MRM of 5 channels,ES414.7 > 369.9
PFOS
pt36k2966 Smooth(Mn,2x3) R6K210000-618 LCS JJ7QR1AC
'
Page 51 of 148
MRM of 5 channels.ES498.6 > 79.9
p. 98
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s-qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2966, Date: 29-Nov-2006, Tim e: 21:27:30, ID: JJ7QR1AC, Description: R6K210000-618 LCS
APFO pf36k2966 Smootfl(Mn,2x1) R6K210000-618 LCS JJ7QR1AC
MRM of 5 channels,ES412.7 > 368.9
APFO pf36k2966 Smooth(Mn,2x1) R6K210000-618 LCS JJ7QR1AC
100-1
Page 50 of 148
APFO 8.08 5119.70
MRM of 5 channels.ES412.7 > 218.9 2.020e+004
%-
r v .nn w n [ r m i r n 1p ! in j
2.0 4.0 6.0
J i,
8.0
10.0
min
p. 99
Analyst. Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2966, Date: 29-Nov-2006, Tim e: 21:27:30, ID: JJ7QR1AC, Description: R6K210000-618 LCS
PFOA
p06k2966 Smooth(Mn,2x1) R6K210000-618 LCS JJ7QR1AC
MRM of 5 channete.ES412.7 > 368.9
PFOA
pf36k2966 Smooth(Mn.2x1) R6K210000-618 LCS JJ7QR1AC
Page 49 of 148
MRM of 5 channels,ES412.7 >218.9
p. 100
Analyst: Steve Cowling
Quantify Sample Report
M as s L y n x 4 .1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qId
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30.2006 07:09:11 Mountain Standard Time
Name: pf36k2965, Date: 29-Nov-2006, Tim e: 21:14:31, ID: JJ7QR1AA, Description: R6K210000-618 MB
PFOS pf36k2S65 Smooth(Mn,2x3) R6K210000-618 MB JJ7QR1AA
MRM of 5 channels,ES-
498.6>98.8 1.443e+002
P a g e 4 8 o f1 4 E
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.13 186.311 bbt 8.13 186.311 bbl 8.08 34470.504 bb
34470.504 34470.504
34470.504
3 0.054 3 0.054 0 34470.504 3
10.175 101.8
Analyst: Steve Cowling
p. 101
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2965, Date: 29-Nov-2006, Tim e: 21:14:31, ID: JJ7QR1AA, D escription: R6K210000-618 MB
PFOA13C2 pf36k2965 Smooth(Mn,2x1) R6K210000-618 MB JJ7QR1AA
100-1
PFOA 13C2 8.08 1
34470.50
MRM of 5 channels.ES414.7 > 369.9
1.378e+005
PFOS
pf36k2965 Smooth(Mn.2x3) R6K210000-618 MB JJ7QR1AA
.
%-
0 * 1 1 * I I'
T - ) T ' | - | | "| " I" T '| T
2.0 4.0
p ) I I I 1 I n ] I ; I I I I ; I I I I I I I I I min 6.0 8.0 10.0
Page 47 of 14
MRM of 5 channels,ES498.6 > 79.9
p. 102
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:09:11 Mountain Standard Time
Name: pf36k2965, Date: 29-Nov-2006, Tim e: 21:14:31, ID: JJ7QR1AA, Description: R6K210000-618 MB
APFO
pf36k2965 Smooth(Mn,2x1) R6K210000-618 MB JJ7QR1AA
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2965 Smooth(Mn.2x1 ) R6K210000-618 MB JJ7QR1AA
:
Page 46 of 148
MRM of 5 channels ES412.7 >218.9
p. 103
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:09:11 Mountain Standard Time
Name: pf36k2965, Date: 29-Nov-2006, Tim e: 21:14:31, ID: JJ7QR1AA, Description: R6K210000-618 MB
PFOA
pf36k2965 Smooth(Mn,2x1) R6K210000-618 MB JJ7QR1AA
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf36k2965 Smooth(Mn,2x1) R6K210000-618 MB JJ7QR1AA
Page 45 of 148
MRM of 5 channels.ES412.7 >218.9
p. 104
Analyst: Steve Cowling
Quantify Compound Sum m ary Report M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Compound name: PFOS
Analyst: Steve Cowling
Page 16 of 16
p. 105
Quantify Compound Summary Report M assLynx 4.1
PFOA Analysis
Dataset:
C:VMassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Compound name: PFOS
$3CVNov/06
I I 3O/N0V/O6
3O/N0V/O6
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
' 30/NOV/06
30/NOV/06
:'30/N ov/06
' 30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
iw s
30/NOV/06 30/NOV/06
30/NOV/06
30/NOV/06
sa?30/N0V/06
^t.30/N ov/06
\30/NOV/06
130/Nov/06
|30/Nov/06
I30/NOV/06
130/Nov/06
|30/Nov/06
; 30/NOV/06
|30/N ov/06
s3Q/Nov/06
bo/N ov/06
"
Analyst: Steve Cowling
Page 15 of 16
p. 106
Quantify Compound Sum m ary Report M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Page 14 of 16
Compound name: PFOS
32 P*36* 2985 33 Pf36k2S8634 pf36k2987
3 5 ? ; ' * 3 5 pf36k2988 36 pf36k2989 37 pf36k2990
930.86.3 930.86.4 930.86.5 930.86.6 930.86.7 930.86.8
0.5 pgrt.
1^/g/L
2//g/L Sj/gA.
10//g/L 20pgA
QC
0.500
9.03
1370.478 bb
1.351 NO 33514.785
0.409
QC
1.000
9.03
2753.079 bb
1.355 NO 35184.527
3
0.782
1.0244 102.4
QC
2.000
9.03
5475.385 bb
1.397 NO 32952.016
3
1.662
2.1959 109.8
QC
5.000
9.03 12969.129 bb
1.338 NO 34709.254 3
3.737
4.9658
99.3
QC
10.000
9.06 25785.563 bb
1.363 NO 33222.512 3
7.761
10.3594 103.6
QC
20.000
9.03 51030.070 bb
1.357 NO 32866.145 3 15.527
20.8424 104.2
p. 107
Analyst: Steve Cowling
Quantify Com pound Sum m ary R ep o rt M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Page 13 of 16
Compound name: PFOS Coefficient of Determination: RA2 = 0.999658 Calibration curve: -0.000346812 * XA2 + 0.751564 * X + 0.0129081 Response type: internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area )
Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
1, 1 pf36k2954 930.86.1 2 pf36k2955 930.86.2
3 pf3Bk2956 930.86.3
4 pf36k2957 930.86.4
5 pf36k2958 930.86.5
6 pf36k2959 930.86.6
7 pf36k2960 930.86.7
8 pf36K2961 930.86.8
9 pf36k2962 930.86.1
10 pf36k2963 930.86.9
11 pf36K2964 930.86.3 -
12 pf36k2965 JJ7QR1AA
SwsS
13 pf36k2966 14 pf36k2967
JJ7QR1AC JJ7QR1AD
15 pf36k2968 JJV631AA , 16pf36l<2g69 JJV631AC
17 M B S *' 17 pf36k2970 JJV631AO
18 pf36k2971 JJV671AA
19 pf36k2972 JJV691AA
20 pf36k2973 JJV7C1AA
,, . ...
21 pf36k2974 930.86.6
I I I 22 pf6k2975. JJV7E1AA 23pf36k2976 JJV7F1AA
24 pf36k2977 JJV7G1AA
25 pf36k2978 JJV7H1AA
26 pf36k2979 JJV7X1AA
27 pf36k2980 JJV751AA
28 pf36k2981 JJV791AA
29 pf36k2982 JJV8E1AA
30 pf36k2983 930.86.1
31 pf36k2984 930.86.2
Analyst: Steve Cowling
Blank
02 pg/L
Blank Standard
0.5 pg/L
Standard
1 pg/L
Standard
2 pg/L
Standard
5 pg/L
Standard
10 pg/L
Standard
20 pg/L
Standard
Blank
Blank
2 pg/L ICV
QC
0.5 pg/L RLV
QC
R6K210000-618 MB Blank
R6K210000-618 LCS QC
R6K210000-618 LCS QC
D6K160299-1
Analyte
D6K160299-1 MS QC
D6K160299-1 DUP Analyte
D6K160299-2
Analyte
D6K160299-3
Analyte
D6K160299-4
Analyte
5jug/LCCV
QC
D6K160299-5
Analyte
D6K160299-6
Analyte
D6K160299-7
Analyte
D6K160299-8
Analyte
D6K160304-1
Analyte
06K160304-2
Analyte
D6K160304-3
Analyte
D6K160304-4
Analyte
Blank
Blank
0.2 pg/L
QC
0.200 0.500 1.000 2.000 5.000 10.000 20.000
2.000 0.500
8.86 8.89 8.89 8.89 8.91 8.89 8.89 9.35 8.91 8.91
538.654 1284.654 2724.531 5227.391 12765.787 24682.434 50704.246
8.244 4104.304 1292.502
bb bb bb bb bb bb bb bbl bb bb
10.000 1.000
10.000
8.93 8.93 8.93 8.93 8.93 8.93 8.93
22184.063 1762.663 7477.024
27872.289 7856.674 7436.145 17074.643
bb bb bb bb bb bb bb
5.000
8.96 13354.931 bb 8.96 7375.658 bb 8.96 8043.850 bb 8.96 10357.889 bb 8.96 4351.452 bb 8.84 632.523 bb 9.01 207.217 bb
8.98 703.425 bb
0.200 9.03
553.135 bb
1.211 1.301 1.458 1.367 1.324 1.342 1.353
NO NO NO NO NO NO NO
1.430 NO 1.337 NO
1.302 1.328 1.647 1.377 1.648 1.647 1.595
NO NO YES NO YES YES NO
1.366 NO 1.522 NO 1.610 NO 1.587 NO 1.518 NO 1.672 YES 1.429 NO
1.469 NO
1.343 NO
35044.391 33439.629 33937.699 35119.074 32835.023 35034.535 32762.703 34013.551 36359.434 33411.656 34345.410 34470.504 34415.273 34760.438 38538.133 38649.508 38088.262 39473.387 38915.801 39116.750 36178.738 39494.617 40320.957 40399.027 40178.684 27003.035 37522.980 34410.773 33609.238 37380.000 33395.363
'3 '
iiK
3 0.161
0.1972
3 0.379
0.4866
3 0.776
1.0155
3 1.592
2.1031
3 3.644
4.8419
3 7.534
10.0535
3 14.907
20.0022
3 0.002
3 1.228
1.6185
3 0.376
0.4837
3
3 6.446
0.1719
3 0.507
0.0132
3 1.%J0
0.0511
3 7.212
0.1924
3 2.063
0.0546
3 1.884
0.0489
3 4.388
0.1153
3
3 3.691
4.9055
3 1.868
0.0479
3 1.995
0.0512
3 2.564
0.0675
3 1.083
0.0284
3 0.234
0.0058
3 0.055
0.0011
3
3 0.209
0.0051
3
3 0.166
0.2032
98.6 97.3 101.6 105.2 96.8 100.5 100.0
80.9 96.7
85.9 65.8
96.2
98.1
o
00
Quantify Compound Summary Report M assLynx 4.1
PFQA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qid
Last Altered: Thursday, November 30,2006 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,2006 08:04:08 Mountain Standard Time
Compound name: PFOA13C2
Analyst: Steve Cowling
Page 12 of 16
p. 109
Quantify Compound Summary Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36l<292s.qld
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Compound name: PFOA13C2
f 30/NOV/06
'.^;;:i;30/NoW06 '30/NOV/06
30/N 0V/O6
30/NOV/06
30/N0V/O6
30/NOV/06
30/NOV/06
3 0 /N 0 V/O6
30/NOV/06
30/NOV/06
30/NOV/06
a 30/NOV/06
30/NOV/06
30/NOV/06
m 3Q/NOV/06 ES? 30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
31 30/NOV/06
30/NOV/06
30/NOV/06
3Q/NOV/06
30/NOV/06
1 30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/Q6
30/NOV/06
30/NOV/06
30/NOV/06
30/NOV/06
3 5 fS |
30/NOV/06
Analyst: Steve Cowling
Page 11 of 16
O
Quantify Com pound Sum m ary R eport M assLynx ' 1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Compound name: PFOA 13C2
^ 32 pf36k2985 "i** 33 pf36k2986
34 pf36k2987 35 pf36k2988 35 pf36k2989 [37 -M M , 37 pf36k2990
930.86.3 930.86.4 930.86.5 930.86.6 930.86.7 930.86.8
0.5 //g/L 1 //g/L 2 //g/L 5 //g/L 1 0 //g/L 2 0 //g/L
QC 10.000 8.15 33514.785 bb
QC 10.000 8.15 35184.527 bd
QC 10.000 8.18 32952.016 bb
QC
10.000
8.18 34709.254 bb
QC 10.000 8.18 33222.512 bb
QC 10.000 8.18 32866.145 bb
Page 10 of 16
0 33514.785 0 35184.527 0 32952.016 0 34709.254 0 33222.512 0 32866.145
9.8929 10.3858
9.7268 10.2455 9.8067 9.7015
98.9 103.9
97.3 102.5
98.1 97.0
p. 111
Analyst: Steve Cowling
Quantify Compound Summary Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qId
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Compound name: PFOA 13C2 Response Factor: 3387.75 RRF SD: 95.0757, Relative SD: 2.80646 Response type: External Std, Area Curve type: RF
rpf36k2954 2 pf36k2955 3pf36k2956 4 pf36k2957 5pf36k2958 6 pf36k2959 7 pf36k2960 8 pf36k2961 9 pf36k2962 10 pf36k2963 11 pf36k2964 12 pf36k2965 13 pf36R2966 14 pf36k2967 S i - 15 pf36k2968 16 pf36k2969 17 pf36k2970 18 pf36k2971 19 pf36k2972 20 pf36k2973 I 21 pf36k2974 22 pf36k2975 23 pf36k2976 24 pf36k2977 25 pf36k2978 I 26 pf36k2979 27 pf36k2980 I 28 pf36k2981 I 29 pf36k2982 i 30 pf36k2983 31 pt36k2984
m m *m
930.86.1
Blank
Blank
930.86.2
0.2 jt/g/L
Standard
930.86.3
0.5/yg/L
Standard
930.86.4
1/^g/L
Standard
930.86.5
2fjgfl
Standard
930.86.6
5pg/L
Standard
930.86.7
10/^g/L
Standard
930.86.8
20pg/L
Standard
930.86.1
Blank
Blank
930.86.9
2pg/LlC V
QC
930.86.3
0.5 jjglL RLV
QC
JJ7QR1AA
R6K210000-618 MB Blank
JJ7QR1AC
R6K210000-618 IC S QC
JJ7QR1AD
R6K210000-618 LCS QC
JJV631AA
D6K160299-1
Analyte
JJV631AC
D6K160299-1 MS QC
JJV631AD
D6K160299-1 DUP Analyte
JJV671AA
D6K160299-2
Analyte
JJV691AA
D6K160299-3
Analyte
JJV7C1AA
D6K160299-4
Analyte
930.86.6
5//g/LC C V
QC
JJV7E1AA
D6K160299-5
Analyte
JJV7F1AA
D6K160299-6
Analyte
JJV7G1AA
D6K160299-7
Analyte
JJV7H1AA
D6K160299-8
Analyte
JJV7X1AA
D6K160304-1
Analyte
JJV751AA
D6K160304-2
Analyte
JJV791AA
D6K160304-3
Analyte
JJV8E1AA
D6K160304-4
Analyte
930.86.1
Blank
Blank
930.86.2
0.2 pg/L
QC
Analyst; Steve Cowling
10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000
8.03 8.03 8.03 8.03 8.06 8.06 8.06 8.06 8.06 8.06 8.06 8.08 8.08 8.08 8.13 8.13 8.10 8.13 8.13 8.15 8.10 8.15 8.15 8.13 8.15 7.93 8.15 8.15 8.13 8.15 8.18
35044.391 33439.629 33937.699 35119.074 32835.023 35034.535 32762.703 34013.551 36359.434 33411.656 34345.410 34470.504 34415.273 34760.438 38538.133 38649.508 38088.262 39473.387 38915.801 39116.750 36178.738 39494.617 40320.957 40399.027 40178.684 27003.035 37522.980 34410.773 33609.238 37380.000 33395.363
bb bb bb bb bb bb bb bb bb bb bb bb dd bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bd bb
Page 9 of 16
0 35044.391 0 33439.629 0 33937.699 0 35119.074 0 32835.023 0 35034.535 0 32762.703 0 34013.551 0 36359.434 0 33411.656 0 34345.410 0 34470-504 0 34415.273 0 34760.438 0 38538.133 0 38649.508 0 38088.262 0 39473.387 0 38915.801 0 39116.750 0 36178.738 0 39494.617 0 40320.957 0 40399.027 0 40178.684 0 27003.035 0 37522.980 0 34410.773 0 33609.238 0 37380.000 0 33395.363
10.3445 9.8708 10.0178 10.3665 9.6923 10.3415 9.6709 10.0402 10.7326 9.8625 10.1381 10.1751 10.1588 10.2606 11.3757 11.4086 11.2430 11.6518 11.4872 11.5465 10.6793 11.6581 11.9020 11.9250 11.8600 7.9708 11.0761 10.1574 9.9208 11.0339 9.8577
103.4 98.7 100.2 103.7 96.9 103.4 96.7 100.4 107.3 98.6 101.4 101.8 101.6 102.6 113.8 114.1 112.4 116.5 114.9 115.5 106.8 116.6 119.0 119.3 118.6 79.7 110.8 101.6 99.2 110.3 98.6
fO
Quantify Compound Summary Report M assLynx 4.1
PFOA Analysis
D a ta s e t
C:\MassLynx\PFOA-PRO\pf36k292s.qId
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30, 2006 08:04:08 Mountain Standard Time
Compound name: APFO
Analyst: Steve Cowling
Page 8 of 16
p. 113
Quantify Com pound Sum m ary R ep o rt M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PROVpf36k292s.qld
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30, 2006 08:04:08 Mountain Standard Time
Compound name: APFO
m
3!:'T'kiL 4
j30/NOV/06 130/NOV/06 j30/Nov/06 30/NOV/06 ps|30/Nov/Q6 ^'^3(Wiovy06 1 30/NOV/06 30/NOV/06 |30/Nov/06 30/NOV/06 30/NOV/06
;30/Nov/06 {3 O/N0 WO6 ;30/Nov/Q6 jj:30/Nov/06 I30/NOV/06 3tVNov/06 % (30/Nov/06 3O/N0V/O6 ;30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06
!30/N0WO6 I 30/N0V/06
jj3 0 /N0 V/ 0 6 (30/N0 V/06 J30/Nov/06 S'30/NOV/06 j30/Nov/06 j'30/Nov/06 |30/Nov/06 30/N0 V/O6 S?30/NOV/06 30/NOV/Q6
Analyst: Steve Cowling
starts late
Page 7 of 1e
Quantify Compound Sum m ary Report M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30,2006 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30,2006 08:04:08 Mountain Standard Time
Page 6 of 16
Compound name: APFO
32 pf36k2985
y 33 pf36k2986
! 34 pf36k2987 35 pf36k2988 36 pf36k2989
'" a 37 Pf36k2990
930.86.3 930.86.4 930.86.5 930.86.6 930.86.7 930.86.8
" SamplTexr. 0.5 pg/L 1 fjg/L 2/tglL Spg/L 10//g/L 20 pg/L
QC QC QC QC QC QC
0.520 1.041 2.082 5.205 10.411 20.821
8.15 8.18 8.18 8.18 8.18 8.18
1726.087 3403.384 6791.868 15540.666 30274.820 60245.313
bb bb bb bb bb bb
8.064 8.872 7.949 7.440 7.569 7.562
NO NO NO NO NO NO
33514.785 35184.527 32952.016 34709.254 33222.512 32866.145
3 0.515 3 0.967 3 2.061 3 4.477 3 9.113 3 18.331
^ .C g h c y r 0.4916 1.0001 2.2304 4.9507
10.1801 20.6208
94.5 96.1 107.1 95.1 97.8 99.0
p. 115
Analyst: Steve Cowling
Quantify C om pound Sum m ary R ep o rt M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30.200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30.200 6 08:04:08 Mountain Standard Time
Page 5 of 16
Compound name: APFO Coefficient of Determination: RA2 = 0.999249 Calibration curve: -0.000226201 * xA2 + 0.889835 * x + 0.0776092 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
1 pf36k2954 2 pf36k2955 3 pf36k2956 4 pf36k2957 5 pf36k2958 6 pf36k2959 7 pf36k2960 S pf36k2961 9 pf36k2962 10 pf36k2963 11 pf36k2964 12 pf36k2965 13 pf36k2966 14 pf36k2967 15 pf36K2968 16 pf36k2969 17 pf36k2970 18 pf36k2971 19 pf36k2972 20 pf36k2973 21 pf36k2974 22 pf36k2975 23 p(36k2976 24 pf36k2977 25 pf36k2978 26 pf36k2979 27 pf36k2980 28 pf36k2981 29 pf36k2982 30 pf36k2983 31 pf36k2984
930.86.1 930.86.2 930.86.3 930.86.4 930.86.5 930.86.6 930.86.7 930.86.8 930.86.1 930.86.9 930.86.3 JJ7QR1AA JJ7QR1AC JJ7QR1AD JJV631AA JJV631AC JJV631AD JJV671AA JJV691AA JJV7C1AA 930.86.6 JJV7E1AA JJV7F1AA JJV7G1AA JJV7H1AA JJV7X1AA JJV751AA JJV791AA JJV8E1AA 930.86.1 930.86.2
Analyst: Steve Cowling
Blank
Blank
0 .2 //g/L
Standard
0 .5 //g/L
Standard
1 /^ L
Standard
2pg/L
Standard
5 //g/L
Standard
10//g/L
Standard
2 0 //g/L
Standard
Blank
Blank
2 //g/L ICV
QC
0.5 //g/L RLV
QC
R6K210000-618 MB Blank
R6K210000-618 LCS QC
R6K210000-618 LCS QC
06K160299-1
Analyte
D6K160299-1 MS QC
D6K160299-1 DUP Analyte
D6K160299-2
Analyte
D6K160299-3
Analyte
D6K160299-4
Analyte
5//g/LC C V
QC
D6K160299-5
Analyte
D6K160299-6
Analyte
D6K160299-7
Analyte
D6K160299-8
Analyte
D6K160304-1
Analyte
D6K160304-2
Analyte
D6K160304-3
Analyte
D6K160304-4
Analyte
Blank
Blank
0.2 //g/L
QC
0.208 0.520 1.041 2.082 5.205 10.411 20.821 2.082 0.520 10.411 1.041 10.411
5.205
0.208
7.98 8.03 8.03 8.03 8.06 8.06 8.06 8.06 8.08 8.06 8.08 8.13 B.08 8.08 8.13 8.13 8.13 8.13 8.15 8.08 8.10 8.18 8.15 8.15 8.15 7.93 8.13 8.16 8.13 6.15 8.18
230.467 866.860 1919.961 3234.157 6788.372 16036.770 30703.297 62927.840 236.178 6110.953 1864.180 186.311 38589.758 3245.832 3878.344 43661.070 3577.006 4044.266 6841.614 420.132 15930.181 3618.455 3425.200 5688.496 3029.045 7858.163 4967.577 943.854 9273.520 258.814 873.683
bbl bb bb db bb bb bd bb bbl db bb bbl bb bb bb bb bb bb bb bb bb bd bb bb bb bb bb bb bb bbl bb
8.664 NO 35044.391 3
0.066
6.612 NO 33439.629 3
0.259
8.197 NO 33937.699 3
0.566
6.059 YES 35119.074 3
0.921
8.466 NO 32835.023 3 2.067
7.675 NO 35034.535 3
4.577
7.704 NO 32762.703 3
9.371
7.849 NO 34013.551 3 18.501
7.952 NO 36359.434 3
0.065
7.823 NO 33411.656 3
1.829
7.831 NO 34345.410 3
0.543
3.386 YES 34470.504 3
0.054
7.537 NO 34415.273 3 11.213
7.691 NO 34760.438 3
0.934
8.516 NO 38538.133 3
1.006
7.649 NO 38649.508 3 11.297
7.191 NO 38086.262 3
0.939
8.776 NO 39473.387 3
1.025
7.895 NO 38915.801 3 1.758
6.123 YES 39116.750 3
0.107
7.770 NO 36178.738 3
4.403
6.932 NO 39494.617 3
0.916
9.105 NO 40320.957 3
0.849
7.642 NO 40399.027 3
1.408
8.721 NO 40178.684 3
0.754
8.659 NO 27003.035 3
2.910
8.142 NO 37522.9B0 3
1.324
8.412 NO 34410.773 3
0.274
8.850 NO 33609.238 3
2.759
17.957 YES 37380.000 3
0.069
7.024 NO 33395.363 3
0.262
0.2041 0.5486 0.9479 2.2374 5.0634 10.4723 20.8142
98.1 105.5 91.1 107.5 97.3 100.6 100.0
1.9692 0.5228
94.6 100.5
0.2511 0.0192 0.0208 0.2530 0.0194 0.0209 0.0373 0.0007 4.8671 0.0183 0.0168 0.0297 0.0151 0.0627 0.0276 0.0044 0.0589
120.6 92.4
12 t.5
93.5
a>
0.2068 99.4
Quantify Com pound Sum m ary R eport M assL ynx 4.1
PFOA Analysis
Dataset:
C :\M assLynx\P FO A P R O \pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 08:04:08 Mountain Standard Time
Compound name: PFOA
Analyst: Steve Cowling
Page 4 of 1C
Quantify Compound Summary Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0,200 6 06:00:46 Mountain Standard Time
Printed:
Thursday, November 30,200 6 08:04:08 Mountain Standard Time
Compound name: PFOA
ir
i 30/Nov/06
jtao/Nov/06 J3Q/NOV/06 30/Nov/OS %0/Nov/0B j30/Nov/06 iHSS 130/Nov/06 l3(VNov/06 130/NOV/06 I30/NOV/06 |30/Nov/0S 53Q/NOV/06 |30/Nov/06 J3 O/N0 V/O6 J3Q/NOV/06 j30/Nov/06 30/NOV/06 **3<V N ov/i 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30TNOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06 30/NOV/06
re30/NOV/06
30/NOV/08
Analyst: Steve Cowling
startslate
Page 3 of 16 00
Quantify Com pound Summ ary Report M assLynx 4.1
PFOA Analysis
D a ta s e t
CAMassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 08:00:46 Mountain Standard Time
Printed:
Thursday, November 30, 2006 08:04:08 Mountain Standard Time
Page 2 of 16
Compound name: PFOA
_. ^
29 pf36k2982 30 pf36k2983 31 pf36k2984 32 pf36k2985 33 pf36k2986
34 Pf36k2987 3 * * 1 35 pt36k2988
36 pf36k2989
3?" 37 pf36k2990
JJV8E1AA 930.86.1 930.862 . 930.86.3 930.86.4 930.86.5 930.86.6 930.86.7 930.86.8
D6K160304-4 Blank 0 .2 //g/L 0.5 //g/L
1 mqA2pg/l 5 pg/L 10 //g/L 2 0 //g/L
!o-5uJ!i$iusm Analyte Blank QC QC QC QC QC QC QC
0.200 0.500 1.000 2-000 5.000 10.000 20.000
m m m 8.13 9273.520 8.15 258.814 8.18 873.683 8.15 1726.087 8.18 3403.384 8.18 6791.868 8.18 15540.666 8.18 30274.820 8.18 60245.313
S fli bb bbl bb bb bb bb bb bb bb
gag^t i 8.850 NO 33609.238 17.957 YES 37380.000
7.024 NO 33395.363 8.064 NO 33514.785 8.872 NO 35184.527 7.949 NO 32952.016 7.440 NO 34709.254 7.569 NO 33222.512 7.562 NO 32866.145
tigggS
3 2.759 3 0.069 3 0.262 3 0.515 3 0.967 3 2.061 3 4.477 3 9.113 3 18.331
0.0566
0.1989 0.4725 0.9609 2.1426 4.7555 9.7785 19.8076
99.5 94.5 96.1 107.1 95.1 97.8 99.0
p. 119
Analyst: Steve Cowling
Quantify Com pound Sum m ary R eport M assLynx ^.1
PFOA Analysis
D a taset
C:VMassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30,200 6 08:00:46 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 08:04:08 Mountain Standard Time
Page 1 of 16
Method: C:\MassLynxVPFOA.PRO\MethDB\pa36K29s.mdb 30.Nov 2006 06:57:57 Calibration: 30 Nov 2006 07:08:01
Compound name: PFOA Coefficient of Determination: RA2 = 0.999251 Calibration curve: -0.000247718 * xA2 + 0.926432 * x + 0.0773411 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
1 pf36k2954 2 pf36k2955 3 pf36k2956 4 p!36k2957 : 5pt36k2958 I 6 pf36k2959 7 pf36k2960 i 8 pf36k2961 9pf36k2962 10 pf36k2963 ! 11 pf36k2964 I 12 pf36k2965 13 pf36k2966 P 14 pf36k2967 J g 15 pf36k2968 ; 16 pf36k2969 17 pf36k2970 18 pf36k2971 19 pf36K2972 20 pf36k2973 21 pf36k2974 22 pf36k2975 [ 23 pf36k2976 I 24 pf36k2977 : 25 pf36k2978 S26 pf36k2979 ; 27 pf36k2980 : 28 pf36k29S1
Analyst: Steve Cowling
930.86.1 930.86.2 930.86.3 930.86.4 930.86.5 930.86.6 930.86.7 930.86.8 930.86.1 930.86.9 930.86.3 JJ7QR1AA JJ7QR1AC JJ7QR1AD JJV631AA JJV631AC JJV631AD JJV671AA JJV691AA JJV7C1AA 930.86.6 JJV7E1AA JJV7F1AA JJV7G1AA JJV7H1AA JJV7X1AA JJV751AA JJV791AA
Blank
Blank
0.2 fjQlL
Standard
0.5jug/L
Standard
1pg/L
Standard
2 pgtL
Standard
5 /glL
Standard
10/rg/L
Standard
2 0 //g /L
Standard
Blank
Blank
2//g/L ICV
QC
0.5 pqIL RLV
QC
R6K210000-618 MB Blank
R6K210000-618 LCS QC
R6K210000-618 LCS QC
D6K160299-1
Analyte
D6K160299-1 MS QC
D6K160299-1 DUP Analyte
D6K160299-2
Analyte
D6K160299-3
Analyte
D6K160299-4
Analyte
5 //g/L CCV
QC
D6K160299-5
Analyte
D6K160299-6
Analyte
D6K160299-7
Analyte
D6K160299-8
Analyte
D6K160304-1
Analyte
D6K160304-2
Analyte
D6K160304-3
Analyte
0.200 0.500 1.000 2.000 5.000 10.000 20.000
2.000 0.500
10.000 1.000
10.000
5.000
7.98 8.03 8.03 8.03 8.06 8.06 8.06 8.06 8.08 8.06 8.08 8.13 8.08 8.08 8.13 8.13 8.13 8.13 8.15 8.08 8.10 8.18 8.15 8.15 8.15 7.93 8.13 8.18
230.467 866.660 1919.961 3234.157 6788.372 16036.770 30703.297 62927.840 236.178 6110.953 1864.180 186.311 38589.758 3245.832 3878.344 43661.070 3577.006 4044.266 6841.614 420.132 15930.181 3618.455 3425.200 5688.496 3029.045 7858.163 4967.577 943.854
bbl bb bb db bb bb bd bb bbl db bb bbl bb bb bb bb bb bb bb bb bb bd bb bb bb bb bb bb
8.664 NO 6.612 NO 8.197 NO 6.059 YES 8.466 NO 7.675 NO 7.704 NO 7.849 NO 7.952 NO 7.823 NO 7.831 NO 3.386 YES 7.537 NO 7.691 NO 8.516 NO 7.649 NO 7.191 NO 8.776 NO 7.895 NO 6.123 YES 7.770 NO 6.932 NO 9.105 NO 7.440 NO 8.721 NO 8.659 NO 8.142 NO 8.412 NO
35044.391 33439.629 33937.699 35119.074 32835.023 35034.535 32762.703 34013.551 36359.434 33411.656 34345.410 34470.504 34415.273 34760.438 38538.133 38649.508 38088.262 39473.387 38915.801 39116.750 36178.738 39494.617 40320.957 40399.027 40178.684 27003.035 37522.980 34410.773
3 0.066 3 0.259 3 0.566 3 0.921 3 2.067 3 4.577 3 9.371 3 18.501 3 0.065 3 1.829 3 0.543 3 0.054 3 11.213 3 0.934 3 1.006 3 11.297 3 . 0.939 3 1.025 3 ' 1.758 * 3 0.107 3 4.403 3 0.916 3 0.849 3 1.408 3 0.754 3 2.910 3 1.324 3 0.274
0.1963 0.5272 0.9108 2.1493 4.8638 10.0592 19.9934
1.8917 0.5025
0.2412 0.0185 0.0200 0.2430 0.0186 0.0201 0.0359 0.0006 4.6752 0.0176 0.0162 0.0285 0.0146 0.0602 0.0265 0.0043
98.2 105.4 91.1 107.5
97.3 100.6 100.0
94.6 100.5
120.6 92.5
121.5
93.5
roo
p. 121
LC/MSAS MSEPMLEIVDOALTAATILE
Quantify Calibration Report M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292sec.qld
Last Altered: Thursday, November 30,2006 07:12:17 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:12:58 Mountain Standard Time
Compound name: PFOS Coefficient of Determination: RA2 = 0.999527 Calibration curve: 0.000310008 * xA2 + 0.768662 * x + 0.018805 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
Page 4 of A
p. 122
Analyst: Steve Cowling
Quantify Calibration Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292sec.qld
Last Altered: Thursday, November 30,2006 07:12:17 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:12:58 Mountain Standard Time
Compound name: PFOA 13C2 Response Factor: 3369.21 RRF SD: 89.7392, % Relative SD: 2.66351 Response type: External Std, Area Curve type: RF
Page 3 of 4
p. 123
Analyst: Steve Cowling
Quantify Calibration Report M assLynx 4.1
PFOA Analysis
D a taset
C :\M assLynx\P FO A P R O \pf36k292sec.qld
Last Altered: Thursday, November 30,200 6 07:12:17 Mountain Standard Time
Printed:
Thursday, November 30,200 6 07:12:58 Mountain Standard Time
Compound name: APFO Coefficient of Determination: RA2 = 0.999298 Calibration curve: 0.000320363 * xA2 + 0.868009 * x + 0.0816079 Response type: Internai Std ( R ef 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
Page 2 of 4
p. 124
Analyst: Steve Cowling
Quantify Calibration Report MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292sec.qld
Last Altered: Thursday, November 30,2006 07:12:17 Mountain Standard Time
Printed:
Thursday, November 30,2006 07:12:58 Mountain Standard Time
Method: C:\MassLynx\PFOAPROVMethDB\pa36k29s.mdb 30 Nov 2006 06:57:57 Calibration: 30 Nov 2006 07:12:17
Compound name: PFOA Coefficient of Determination: RA2 = 0.999297 Calibration curve: 0.000345073 * xA2 + 0.903701 * x + 0.081358 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None
p age Df 4
p. 125
