Document qoKy81BmGmLor6JEm5E99wVj

x AR 226 - 08 &/ ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM VOLUTATOR) IESTSUBSTANGE Identity: ArefmeirxrteudretocaonstPaiFnOiSng,pFeCr-f9l5u,oroorocatsanaescuolmfponoanteen,twhoficFhC-m6a0y3EaFls.o (b1e- Octanesulfonic acid) (CAS # 2795-39-3). Remarks: FC-603EF. CuTrhreen3tMinpfroordmuacttiioonnilnodtincautmebseirtiissanomtixntoutreed.ofT1h.e30t%estPsFaOmSp,le10is% dpireotphaynleesnuelgtloynceolfobuatmyelr,et5he%r,A5lk4y.l1e5th%erwastueirf,at2e,2.05.%1%etNh-y(l3e-ne glycol, 2.6% Chioroallyhhexaminium chloride, 0.9% Xanthan gum, 0.9% starch, 1.0% triethanolamine, and 0.05% tolyl triazole. ~ cThhaerafcotlelorwiiznegd scounmcmenatrryataipopnlsioefsiampmuirxittuireesw.itDhatiancmoampylnetoetlayccurately reflect toxicity of the fluorochemical component of the test sample. MeTWoD: 000 Method: ASTM E1367-90, Standard guide for conducting 10 day static sediment toxicity tests with marine and estuarine sediments. TGyLpPe:: NAocute static Year completed: 2000 Species: Supplier: Corophium volutator Field collected from an unpolluted site near Trondheim, Norway. Analytical monitoring: pH and dissolved oxygen. Exposure period: 10 days Test organism age: Statistical method: Adults (4-8 LCs values mm size) calculated by PROBIT Analysis, National `NSOweEdCisbhyEsnivnigrloen-mfaecnttoarlAPNrOotVecAtifoonllBoowaerddb(yVBeornsfieornr2o.n3i,s 1990). Calculation procedure. of Test conditions: Dilution water: site in Byfjorden Natural outside seawater (34 of Stavanger, ppt salinity) from an Norway. Sediment unpolluted collected at afrnacutnipoonlolfut0e.d7s%itae.ndThaesislefdriamcteinotn is of a muddy 0.8%. sand and had an organic Dilution water chemistry: Not given. Lighting: Not given. -- Stock and test solution preparation: Each test concentration was prepared by adding the test substance to 600 g damp sediment and 150 mL of sseuabwsaatmeprl,est,hewnitshhaakneonvefrorla3yhoofur4s0.0 TmhLesseeadwiamteenrtawdadsedsptloiteianctho,tharnede aerated overnight before study initiation. 002407 Exposure vessels: 600 mL glass beakers containing 200 g of test sediment and ~400 mLof seawater with continuous aeration. Num ofrbepliecatres: 3 Number of organisms per replicate: 10 WNautmebrecrhoefmicsotnrcyendturraitnigontsh:e four plus study: a blank control pH range (0-10 days): 8.18.1 (control exposure) 8.08.1 (3060 mg/kg exposure) Temperature range: 15% 1C Dissolved oxygen range (0-10 days): 90 -- 97% (control exposure) 93 - 100% (3060 mg/kg exposure) gESOLYS Nominal concentrations: Blank control, 222, 457, 1060, and 3060 mg/kg (dry weight). Reference substance (fluoranthene) at 20.9 mg/kg dry weight. Element values: 10-day LCs) = >3060 mg/kg (sediment dry weight) 10-day NOEC = 3060 mg/kg (sediment dry weight) Element values based on nominal concentrations Remarks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. Conclusions dTrhyewteeisgthts)a.mpTlhee1100--ddaayyLNCosoOwbasserdveetderEmfifnecetdCtoonbceen>tr3a0t6i0onmg(/NkOgEC(s)ewdiamsent c3o0n6c0enmtgrlaktigon(steedsitmeednatnddrycwaeuisgehtd)~.1T7h%em3or0t6a0litcyo.ncentration was the highest Validity criteria fulfilled and reference substance obtained mortaliotfy 16.7%. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 pATAQUALTY tReesltiianbgi.litHyo:weKvleirmi,sschamrpalnekipnugri=ty2.wTahsisnosttupdroypmeerleytschtahreacctrietreirzieadfoarnqduatlhietystudy ~~~ lacks analytical confirmationof the amountoffluorochemical proportion in the solution. 002408 REFERENCES.0 eee eee Test was conducted by RF Rogaland Research, of Stavanger, Norway at the request of 3M Norge, Lab reference number 99312-4, 2000. Qe EEERm------------------ Last changed: 6/26/00 002409 Ul mF wim AESMRCR "FC-603 EF Light Water TM ATC TM 3%" Toxicity tests . Report RF-2000/004 i ; ii on -- "The following test results were obtained with "FC-603 EF Light Water TM ATC TM 3%": Ee om Acartia tonsa 48hLC, (mg): 280 Corophiumvolutator 10dLC,, (mg/kg dry weight) : >3060 ps The results relate to the product as supplied com by Novatech. 1 eopartof 4s Gormanmay 5a reproduced nanyformwihoutpermission inwingby RF -FogalandResearch. - Covir. M rellp fies 002410 ' Sousa - CONTENTS: 2. TEST FOR TOXWII THC SKEI LETT ONEY MA COSTATUM w.cvvsrressrsssssivsssssssssssssssssssssssins & 3. TEST FOR TOXI WIC THI ACATRTY IA TONSA ccvvssssssrssrssriimsmsmsssssssssssssssssssssssssssssssssses 10 4. TEST FOR TOXICITY WITH COROPHIUMVOLUTATOR c.vvvvsrrrssssssssssssssssssssssssssssssssssnssn 15 002411 L9a9b3r1e2fr4o. Page 3of31 PREFACE: NEcoovtaotxeiccho.loTghiecaslamtepsltes wiseraecpoencrefnotrrmaetde othnat"FnCo-r6m0a3lElFyLwiiglhltbWeautseedTMriAnTaC3TM%3A%FFiFn/a3gr%eAemRent with Solution. Tests were conducted in accordance with the "Harmonised Offshore Chemical Notification Format" (OSPARCOM 19/9SF5T 1998). pTehrefporromjeedctbwyaRsFca-rMriilejdgloaubt.atStRudFy-dRiroegcatloarnwdaRsSeesneiaorrchEnfogrin3eMerNoIrnggee.r LAilslatAhnedteersstsenw.ere The test results are presented in separate sections. The results relate to the product as supplied by Novatech. TThhiesatcecsrterdeiptoarttioins sitsastueesdtbhyatatlhaebloarbaotroartyoarcycmreeedittsetdhbeyNNAorrweqeugiiraenmeAnctcsrecdointcaetrinonin(gNAc)o.mpetence, 1etqaulispomestnatteasntdhawtortkheinlgabporroacteodruyrheassfoarsaatlistfhaectteosrtymqeutalhiotdysacsosnutraainnceedsiynsttehme,acwchriecdhitiantcilonu.des internal quality control schemes, certified reference materials and participation in interlaboratory secondary reference materials. comparisons, and the use of The tests performed are covered by the accreditation. This test report may not be reproduced in anyform other tha infull without the permission in writing by RF - Miljglab. 002412 L9a9b3r1e2fr4o. Page dof31 TEST FOR TOXICITY Marine alga: Skeletonema costatum 002413 Lawrepro 99312-4 rages a1 e534 Hii TEST REPORT `GROWTHINHIBITION TESTWITHTHEMARINE ALGA Skeletonema costatum flQ\ ma ROSALAND RESEARCH TEST SUBSTANCE: "FC-603 EF Light Water TM ATTMC 3%" TEST RESULT: `The72 hours ECso was calculatedto ~170 mg/l. - The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: = METHOD: NS-EN ISO 10253, 1998: Water quality - Marine algal growth inhibition test with Skeletonema costatum and Phaeodactylum tricornutum. "TEST ORGANISM: SokreglaentiosnmeimsakceopsttaattuRm,F-stRroaginalNaInVdAReBsAeaCrch1.. Astock cultureofthe test sux PREPARATIONS: Natural seawater (salinity: 34 %e) from an unpolluted site in Byfjord was used as basis for the growth medium. The water was filtered through a GF/C filter, and briefly heated to about 75C prior to use, `The seawater was. enriched with nutrients according to ISO 10253, and recommendations from the Paris... Commission. v Test solutions were prepared from a stock solution. A stock solution of 1020 mg/l was prepared by stirring 1.020 grams of the product in 1 litre of growth `medium. Other concentrations were prepared from this stock solution. INCUBATION: Test cultures of 50 ml were incubated in 100 ml flat-bottomed flasks on an olrabtietdaltoshaabkoeurt,230r0e0plcieclaltse/smlfofrreoamchancoenxcpeonnternattiiaolnl.y Tgersotwicunlgtuirneoscwuelruem icnuolcaur, The test was run under continuous light (> 50 pE/m? sek) from fluorescent--= tubes of universal natural white type, at a temperature of20 2C. Tthheetteessttfwlaassksreunacfhordaabyofuotr7g2rohwoturhsm,eaansdurseumbesnatmsp.leAslgoalf5grmolwwtehrweatsakmeenasfurroemd by fluorescence. pH measurements were performed as indicated on data sheet. 00241 L9a9b3.r1e2f4ro. Page6of31 DATA ANALYSIS: CALCULATIONS: Growth rates were calculated by log linear regression on biomass (fluorescence) versus time, as described in NS-EN ISO 10253. ECs: The inhibitory effect on the growth of Skeletonema costaturm is expressed as the concentration oaf product giving 50% reductionofgrowth rate (E,Cxo). This effect concentration was calculated by interpolation between 100mg/ and 320mg. NOEC: CalculationofNOEC (No Observed Effect Concentration) is done by singlefactor ANOVA followed by Bonferroni procedure for comparing each concentration mean with the control mean. TESTRESULTS: Table 1. EC and NOEC values obtainedwithSkeletonemacostatum. COMMENTS: VALIDATION: Testswbsance _ BCo W"FaC-r6r0 EaFTMLiase: - BCe 10 BO 100<EC320 NOEC: 100 VVaalluueesainrdeiccaatleccounlcaentbterydatiinotnerspoglaitniogn.10N%OE3C0%araencdal9c0u%latiehdibbyiwoinongfhgercoowmpataer. pUrroigsrianmmmalel. GraphPad Inet 3.0. The results are based on growth rates for the time span 0 - 72 b, the period during which the growth is considered to be exponentialinthe control cultures (see growth curves). The validity criteria given in the test protocol are fulfilled, in that the control cell density increasedby a factor of more than 16 in the test period (vacroyrrbeyspmoonrdeintghtaon a1g,0rouwnitths rdautreionfgmtoheretetsthaann0d,t9hed)7,2 hthoeurcsonttersotlrepsHultdsidwintoht 3,5-dichlorophenol was in the range normally found. Lab. ref. no.: Sample received.: Test period: Report date: 993124 20.09.99 07-10.12.99 10.01.2000 El Yor Elin Horve, Engineer Analytical technician Factloy SeniAorgeReseMaorlcvherSscmiyerntist Quality Assurance : Enclosed: Data sheets Tforomttshreeptohrant euld, wbityho+utsbhoeatpoerrymissesciorniiendwbyrNiobnryRwgEeg-iMAacenireadiaion (VA). Threport ayrnoebpe roduncaend 002415 LS9aabirziae rage 70131 PRIMARY DATA: Growth Inhibition test with Skeletonema costatum est substance: FC-603 EF LightWaterTM ATCTM 3% StLaabn.daotle: 9070.31122949 MosCsornacm.eunntit:: Tmhegbiomasswas measuredby fluorescence; values in furescence units I GSiagon| E0E95R0 |[E10E25[|OE11s55||| |dmaye-1||ctaotiroen||ofPtreHs|t||osipetHedst 00 0 0o1r2 || oi oozsss|| [om | 01s73|| 11 | e8z || 1r2s2s| 0r9o%w va| 088 82 00 o0o0os || ooo | oozss|| 026 | o1s1e|| 09 | e6a || 11446|8003985 7 151 | ogo 33a22z 0o0.00os9 ||0o042s3a || 1i71z5|| 4e1"73 | "1[1.416274||81010.09009008 0o0s8|| 0044 1t0ss|||| 81619| |oossees 01 | os 12 166| 1000 0011 || om | o3zs || os | 21095|| es | 9s32|| | 1|51757|oossms| ss || 1s2|oom ea| 62 11000 100 00010 || 1| oossts || os| 007775 || ozs | s51a || sa | | 113432||o09s8m8 130 |oser 2 007| oos | 00a | oo | [ooo 320 0.09 0.03 0.01 0.04 0.00 - 320 006 0.04 0.02 006 0.00 10l0w0o | 0o0s9s | 0o0o7 | 0o.e0s8 | 0o0o5s | | 0o.0o0 1000 01 003 003 002 0.00 RforTenecmeosunbsta|nce0(3059 |ichor0op1h5en|ol):018 sYommn || oooos || ooie|| ootrs Mean val0ves: a0z 1020 aw2o oo | o3s || 71 | | 77 ooens || o0sa || 32 || 8 o00w7 || 0030 || o1 | 5 foo | oo | o | [Refereesubst] 008 | 013 | 02|02 | 00738s| 0[9065%8 032| 0s21 a5 [058 -- 115722|| 0099090 115368|| 00998%8| mreoman 000000 i erie one Tamaya [0320869] mem 002416 L9a9b3r1ef2i4no. Pages oy 31 GROWTH CURVES: Growth inhibition test with Skeletonema costatum Testsubstance: FC-603EFLight WaterTM ATCTM3% Lab. ol: 993124 1 Control 55] 2 : 5!| g17 240 w on JY escnaton pou) w1ia]N 10 mon 31! n 32 mpt 3| ae i . | " Lae .= 37 tenasaonpour) kool8I 32 mon i' oY manatonpos) 2F sonpo) n. 100 mon IIat e =n 2 tesasatonteum 50n) 20 mg I I b ER EI Ba totdaion rosy ] 1000 mon ae | i' fag we on J SU = 002417 u La9b3r1e2f-n4o.: Page9of3I wIinthhi:bition of the growth of Skeletonema costatum mg/L ( FC-603 EF Light Water TM ATC TH 3%) Experimental data: CFCo-n6c0e3ntrEFatiLiognhtinWater TM ATC TH 3% Growth rate, ccoonnttrrooll 21 CCoonnttrrooll 34 CCoonnttrrooll Control mean : 331.2200 3.20 3 1100..0000 10.00 3322..0000 32.00 110000..0000 100.00 332200..0000 320.00 11000000..0000 1000.00 11.12529 - 11428 11s6 1.45 11.4687 1.42 11.689 1l66 11.5577 152 11.3032 139 0.020000 0.00 00..0000 0.00 Iinnhpiebricteinotn ---0 00.00 18 00.00 ol 00.00 ol 18.181 3s 110000..00 10020 110000.000 100.0 002418 LSaobs.rieafeno.: Page 100f 31 3 TEST FOR TOXICITY 1 Marine herbivore: Acartia tonsa LBe ot oR | == 002419 3 La9b9r3e1f2o4o.: Page 11of31 2 3 TEST REPORT ACUTE TOXICITY TEST WITH THE MARINE COPEPOD Acartia tonsa TEST SUBSTANCE: "FC-603 EF Light Water TM ATC TM3%" TEST RESULT: . i `The 48 hours LCso was calculated to 280 mg/l. `The test substance was supplied by Novatech, and the test results relate to this product. { TESTDETAILS: i | MemHoD: ItoSOm/aDriInSe1c4o6p6e9po-d1s99(7C:opWeaptoedra,qCruusta-acDeealt)e.rimintatiyon of acute lethal toxicity | TEST ORGANISM: AUcnairvterisaittoynosfaC(oDpaenan)h,agseunpp.lied by the Marine Biological Laboratory, . | CULTIVATION: wTihtehttehste o"rPagrainsisCmosmmwiesrseisounpp-lRiiedngasTeesggtsP,raotnodcwole"re(VcKuIl)t.ivaLtaerdgiencaocpceoproddaintcees and adults were used in the test. PREPARATIONS: aNsabtausrails sfeoarwtahteedril(suatliionnitwya:t3er4.%qT)hefrwoamtearnwuanpsoflilluttereeddstihteroiungBhyfajGoFrd/Cwafsiltuesred prior to use. T`megs/tlswoalsutpiroenspawreerdebpyrsetpiarrreindgf1r.o0m00a2sgtocrk asoolfmutthisoenp.rAoduscttoickns1olluittrieoonfodfil1u0t0i0on water. Other concentrations were prepared from this stock solution. INCUBATION: & T25hemlteosfttweasst rsuolnuitniognlaasnsdco5natainneirsm(42ra8epmlllicrsaotl,elsedfroirmeavicahlsc)onecaecnhtrcaotnitoani.niTnhge "==_ | vials were kept under a 16/8h light/dark photoperiod at a temperature of 5& 201C. data sheet. pH and oxygen measurements were performed as indicated on the | |i . 002420 La9b3r1ef2n4o.: Page 120f31 "fd DATA ANALYSIS: "3 CALCULATIONS: Tahperoedfufcecttloetnhatlhe10su5r0vi%voafltohfeActaesrttiaanitmoanlssa (iLsCesxcp)r.esTsheed casomtbheinceondcmeonrttraaltiitoyn of per test concentration were used for calculation. The 24 hours and 48 hours LCs values and the 95% confidence limit were calculated by using the standard procedure PROBIT Analysis, National Swedish Environmerital Protection Board (Version 2.3, 1990). This programme also calculate test concentrations lethal to 10% and 90%ofthe test animals. NOEC: Calculation of NOEC (No Observed Effect Concentration) is done by singlefactor ANOVA followed by Bonferronis procedure for comparing each concentration mean with the control mean. | TESTRESULTS: Table 1. LC and NOEC values obtained with "FC-603 EF Light WateTMr ATC TM 557. i Serine 24hous thous : Co 280 (130-380) 89 (54-120) 1 : Loo 610 (490-790) 1000 280 20-360) 830 620-1500) NoEC: 20 150 {chVaelcuaeosminldpbiceycaptePrRoi1Og0Br%Iat5Tma0mene%Gaarlnaddyp,h9aP0na%dden9h5%liiactoyn3af0.ifdeern2c4eiantderv4a5l horuersindUinciateidn, mNOgECVarieercaleeabty ' VALIDATION: The validity criteria given in the test protocol are fulfilled, in that the dissolved oxygen oncentration at the end of the test was greater than or equal to 4 mg/l, " tLhCespeorfce3n,t5a-gdeicmholrotraolpihteynionlt(hreefceornetnrcoel)swwaass ilnestshethraanng1e0%n,oramnadlltyhefo4u8ndh.ours `! LSaabm.plreef.rneoc.e:ived.: wl . |i `RTeepstorptedraiotde:: 9290.30192.949 1007-.1021..1210.9090 i Enclosed: Data sheets QEliLn HoYrover AnalyEtnicgailnteeecrhnician FE orm cher hn in ll, wou hepcmision in wring by RF - Mijlb. TAege MoHlvoerosmryrn, SeniQouralRietsyeaArscshurSacniceentist___ 002421 ;8 LEabrEeino: pase 130731 PRIMARY DATA: Acute toxicity test with Acartia tonsa Test substance: LaSba.nrata:: Measurement: "FC-603 EF Light WateTMr ATCTM 3%" s1m0n1r1z8a0 Numbofdeeard - Numberof| NUMBER OF DEAD ] i nTuomtbaelr|r`spevcoismseonl authors 48hours i: | concweonrnmainon||sopraccoinne,|n B oF os | A80CEF| Toma {i Gonrol 000000 000 01 0 | 0000 0000 000 0 s5 ss T| a | o000 Aotorancesubstance(5dchoraphonol: _ T t-- a. ms = 1 Theresult withthereferencesubstance iswithintherange normally found. 5 8k I i 002422 Labreino. } 993124 page 14of31 Test substance: "FC-603 EF Light Water TM ATC TM 3%" SLtaab.n rdeaft.:es 91903111249 ] [on [wnme] `Measuorfoexymgeenanndtps H. 3 I Concentration | Oxygen pH Oyen pH | Ongen pH CC=om[[ ww n [aw ] a] I (mg/) (mgf) - (mg/) - (mg) - C[oew [ eo[ wT Tw ww =[ o ve w [Twew] [Cow[ wew |[TTe e e [om [n J Tw wo] Referencesubstance (3,5-dichloropheno): _ 5 il | 002423 La9b9.5r1e2f:n4o.: kL Page 15of31 i TEST FOR TOXICITY Marine Amphipode: Corophium volutator Be . 0024 of wLab.erepro. i Page 16031 % TEST REPORT ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator i TEST SUBSTANCE: "FC-603 EF Light Water TM ATC TM 3%" TEST RESULT: - `The 10d LCso was calculated to >3060 mg kg! dry weight sediment. The test substance was supplied by Novatech, and the test results relate to this product. 5k{ TEST DETAILS: MeTHOD: ASTM E1367-90, Standard Guide For Conducting 10 day Static Sediment `Toxicity Tests with Marine and Estuarine Sediments. TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim. CULTIVATION: The test organisms were supplied as adults (4-8 mm in size) and were held in afeeredaitnegd.seawater at 15C. A small amountofnatural seaweedwasused for PREPARATION: | Natural seawater (salinity: 34 %) from an unpolluted site in Byfjorden outside Stavanger was used for dilution water. Sediment collected at an unpolluted site `was used for preparing test sediments. The sediment is a muddy sand and was. `analysed for organic content and proportion silt for each test. Each test concentration was prepared by adding the product in 600 grams of damp sediment in a plastic bucket. 150 mlof seawater was added and the `bucket was shaken fo3r hours. The sediment was dividedinto threebeakers, 400 ml ofseawater was added to each, and the beakers were aerated over night. 10 animals were then randomly selected for each beaker. A sample of . the damp sediment was analysed for water content, and all concentrations are calculated as mg kg! sediment dry weight. INCUBATION: Tsheeditmeesnttw,aasprpu.n40i0n mgllasosfscoenatawinaetrasen(rd60100maln)imeaalcsh,c3onrteapilinciantges20f0orgeoafchtest concentration. The beakers were kept under continuous aeration ata tinedmipceartaetduroenotfhe15da+ta1shCe.et,pH and oxygen measurements were performed as il 002425 LlA sbirzoe: Page 170f31 +4 DATA ANALYSIS: i CALCULATIONS: Tthraetieofnfeoctf2opnrotdheucsturlveitvhaall toof5C0or%oopfhithuemtvesotluatnaitmoarlsis(eLxCpsroe).sseTdheasctohmebcionnecden- v`maolruteaalnitdytpheer t9es5t%cocnocnefnitdreantcieolniwmeitraeruesecdalfcourlactaeldcublyatuiosni.ngTthhee s1t0anddaayrdLCso 2P.R3,OB19I9T0)A.naTlhyissisp,rNoagtriaonmamleSawlesdoicsahlcuElnavtiertoensmtecnotnaclenPtrroatteicotnisonleBtohaalrtdo(1Ve0r%siaonnd 90%ofthe test animals. NOEC: CfaacltcourlaAtNioOnVofANfOoEllCow(eNdobyObBsoenrfveerdroEnfifsecptroCcoendcuernetrfaotricoon)mpiasrdionngeebaychsingleconcentration mean with the control mean. TESTRESULe TS: Table e 1. LC andeNOeEC values obained with "EFSCS-6E0S3REPFLLiigoht WtahtayeTMrTATo C TM w 35" Coraphium voluator 10days Lo 9.( 760) Lon >3060 Lon >3060 BNr VoaOEluCes:nice 10% 30%ae nd 50% ehliyfer 10e dey. Unisi3m06g0Kg"ser dimeenrtdryweigh. VaclauelseriebyectdheacomlpubcytePurRpOlrBoIagTraatmlmeeyGd,reapnhdP9d5%nacotnf3i.d0e.ncenepal areindicted.NORCare VALIDATION: Tohxyegveanlicdointcyecnrtirteartiiaognaitvetnheinetnhdeoftetsht eprtoetsotcwolasagrreefautlefriltlheda,noinrtehqatuatlhetdoi6s0so%l,ved thepercentage mortality in the controls were less than 15%.Thepercentage. smoerdtiamleintty winasa r1e6f.e7r%e.nceThseubssetdainmceeonft2u0s.e9d imsgfoFulnudortaonbtehewniethkign!adcrcyepwteeidghlitmits for organic content but the silt fraction is recommended higher. We have soebdsiemrevnetd)absuitgntihfeicmaonrttamloirttyaliinttyhienhoingheecsotnccoenncternattriaotni(on10w6a0smngotkgsi!gndirfyicwaenti.ght Tabl2e. Characteristics of thesedimentusedfor testing Organic content (%) 01 - Siltfraction (%) 08 Lab. ref.no: TSeasmtppleeriroedc:eived.: . Reportdate: 993124 02-01.00.91.29999 07012000 & Enclosed: Data sheets Su Wow EEnligninHeorevre Analytical technician Felllirsny SeniAorgeReMsoelavrcehrsSmciyerntist Quality Assurance 002426 L9a9b3.r1e2f4no.: Page 18of 31 PRIMARY DATA: Acute toxicity test with Corophium volutator `Test substance: "FC-603 EF Light Water TM ATC TM 3%" : Lab. ref.: 993124. t StMaeratsudraetmee:nt: N17.u12m99obfdeeard {f Total |Nusmpebceirmeonf number | prvessel (Congccenrtyirwaetiigognht||pSrp.ecciomneen.. 100 1100 1100 |= El) 10 10 10 a7 10 10 10 NUMBEROF DEAD 1 says 10days Toil | lBaDceF | Toul 000000 3080 El 10 10 10 | Rterencesubstance (iuoranthene _ [ 2 T1010 10 LTo i _ 002427 | pu en oe Tse rTTow] CCo=mT[ eoTw wo w wlw eowe] (mg/kg dryweight) (%) # (%) - To Iw v w wlw wo] rT [eo Jewe Referencesubstance (fuoranthene): _ e_ w] [Rl 002428 Poirs. 4 pase 20051 |! . ; DATA SHEETS ; Bi| . 002429 La9b9r3e1f24no: Pagelof31 | ixs-oatasiap (felse-, Niljo- og Sikkeshetsdatablad) Sooskcuesesnctenrs. 072.07/20947/-907 vSheeagveis euse:: 0131//1111//9988 VSeizdesjon lav 03.0101 TieMlse-fdoant:abl6e3de8s4 7e5x u00tar/bTeeildeefsaxa:v k6i3lj8o4av1d7el8i8ngen ved 3M Norge A/S. 1 IDENTIZIXASION AV KJEMIXKALIZT OG ANSVARLIG FIRMA. 3 Importer: 3 Norse A/S ; HandelFsCn-a6v0n3:%F LIGHT WATER (TH) ATC 33 AR-ATEE :: Deklarasjonsaunmes, 2roduktregiszeset: i Telefon, Gifsinforasjonssentralent i 22's 13 00 2 OPPLYSNINGER OM KJEMISX SAMMENSETNING. . : Iaommasjon om enkeltkomponenter, faresymbol(er) og risikosstninge:r storaam cas-ne vaxz-pRosaNT v1a2-ErazoL 170773-22-11805 S2S5a6s 2-(2-FBaUzTeOsRySnYbEoTlOeKzS/Yr)is~iTkAoNsOeLsai/ngess Xa; Ri22 112-345 (DIZTYLENGLYROLHONOBUTYLETER) "10 ; SYNTFETaIzSeKsyOnVbEoRleFrL/ArTiEsAiXkToIsVeTtnSiTnOgFeEr: Xi FLUORALKYL OVERFLATEAKTIVE STOFFER RiTrade Trade Sseeccrreett ee i; l ios FLUORKIEMISK AKRYLAT Trade secre 1s i TTRRyEIRSvETzTERARENOALVAMOIRNGANISKE FLUORKEMIGALIER TTrraadd1ee02-SS7ee1cc-rr6ee:s Tike10K-j31ent 002430 SLaibrrseiro rage 220/31 FC-G03EF LIGHT WATER (TH) ATC 33 AR-APEF Homes mem To TT Vikeigste skadevizkninges ! EelsetKaarne:vaze faslig ved svelging. Ken irritere oynene. || sikkas:hec: || Miljotsapzees:ialaveall. PE------ i TilakSkoylyle:stzaks oynene med rikelige mengder vasn. Kontakt lege umiddelnare. TidtakSkhyuldl:streks huden med sige og rikelige menge: vana. Fern :i ttoiylseflotr tdeeyt.brEuvikses siygmjpetnomeorg oKpapssttitri,lseklotnteskkeotelye.ge. Vask tilselt | leakHviisnabsnydmipntgo:ms: ospstls, bring vedkommends bors fra |! keoknstsaoknsezilneggask.ilden. Sots for frisk Luft. Svis symptomene vedvarer, i| TileakKonstvaeklgtinlge:ge uaiddelbacs. Freskall breksinge: kun i sascdd med : Speecdsions.io lest. G1 416et nos sinncn meen 141 +n eviesiios | ; 5 TILIAK VED BRANNSLURNING. i Zgnet.Prboedaunkntseltukneixngestnibdrdaenlnsslukkingsmiddel. ! ; Sv pws ranmeitminpsnlitet | rm ws - | i cl 002431 LaFbrieitros Pa T FC-603EF LIGHT WATER (TM) ATC 3% AR-AFFF Forbremminsrerosuier ved brane Prosacycas ved slukking av beams rr ves orieren ween, FersonSieisVeervneartmieisiiatkeawkasder andre punkes 1 detsd-iS-dacanladet. eCGoernotetihleersmeanaddnecvhmeaecn.eriFSseoiviei:lenSaiovelstzeynseseenssteommnidaadnemnlbieasectti.eierbrseek,kn,ttSieLl nmmeed dat Esemmeiengpeav xje1n5stiaFteimonivainaiiosy Kjeatkatiesvrall. eee meena | 7 EANDTIRING OG OPPSIVARING. BetinSCWgaoietllis(taexirlksel:efroTTraagTgraseegieseksnkiedrv"ioeoesnpscp.ifbdoeemEvrmaagerrcnieaonstegsu:mveepscrodvsuoekntrmeeytceknanaasn rnooommenen 41123kToonrtoaokttemed beholderen tett lukke: nr produkzet ikke er i bruk. | Uforenelige materiales: | VentilOapssjboenv:ar emb-allasjen sh et godt ventilese sted. Sitkerhesstiteas for & fozhindre braze: Sikkarrhaerstmiiesakmfor & forhindse sksplostons I] stkacharstiteak for sozhindre stacisk eiokerisicess |b ForhoRPlordlosadzueskgeiaeemsratlvkeaedsniebTrneupkktsiensgs Lfourkhkeesea.ke.Rayfkoicnogrefnosrnbiuodde:avUntdoemrekrbernuoanvetter 002432 vofyl LSalren Page240/31 FC-60IEF LIGHT WATER (TH) ATC 34 AR-AFEE EXSPONERINGSKONTROLL 0G FERSONLIG VERNEUTSTYA. i vUnenzgndebz&ill4erdammpe,d vsepartaiyleerl.ler tke i oynene. Bruk tette BineveBrrau:k egnede vernehanskes av hensiktsmessig materiale ved hsinnbdettaelreisn:g aBvutyplrgoudmuskit.et. Vesnehansker av folgende materiale(r) Annet hudvern enn hindveza: | Uangd hudkontaks. AndedrUaenvsntglshuvfeiernfnno:drnudrienngsniavngelruftibiazrebseidmassaetsmiosslfea.ren3sve.erltgespheknonasvenftorlagsejnodneen otyrogaa(nri)skegoddkajmepaetr odfadevdarseksetfsovrearing:e hpaalzvemiakisekre:mAe/dZIfSiLl.ter mot | SvelgisDnergto:dumkbteitk.keVasspkiseust,sasdtrei-kkoenssheelrlergruronydkiessmeudndsehrpearobgeidvammne.d Vask Tii hendene etter hindering og fer spising. VSHveoindstkijleuantstsjuogAnnnidnesgdlirskavtetnest:vielcraanmspjkoboennrysizektxketesr.aesrjSoetnirelsnsetfroerhkokltedilelissgt,ruenmkddkeerleigsgnaebtefalte t administrative normer og/eiler kentrolier spray eller tdke. Ada. normer for forurensning i asseidsataostaze, Februar 1996: va A(n1m7a3r2i-n1i8n-g5e)s: Ingen adn. nor. 1,2-E9T-AcNiDnIeOrLs(v1e0r7d-s21p1p)m: - (s30v) 8-ciners verdt mg/ml: 10 (ssev) | Takvezal pou: 25 (dase) Takverdi mg/m3: - (damp) qr 2-(2-BU3-TtOiKnSeYrEsTOvKeSrYd)i-EpTpmA:NOL35/ (DISTYLENGLYKOLHONOBUTYLETER) (112-34-5) A(nImnegceknninnogresrk: aAdam.erinkoarnm)s.k grenseverdi anbefalt av produsenten. : SYNTE`TAInSmKesOkVnEiRnFgLerA:TEAIRnTgIeVnEsdSaT.OFFno(mT.rade Secret) will HASSE Ars aan sents i 0dz43a La99b3r1e3n4o Page250f1 FC-G03EF LIGHT WATER (TM) ATC 3% Amarrr Ameskainger: Ingen adm. norm, TRIZTANOLAMIN (102-71-6) 88--ttiinmeessss vveesrddii mppgm/:m:- 5 } ;: TYEAnme(ctkrnaidnegesre:creIsn)gen ada. norm. i| RESTERS-tAiVneOcRsGAvNeTzSdKsE mFgL/UmOlR:KI0I,N1IKAGLrIeEnRse(vTerraddie aSescbreefta)lt av in. 1. SE ee I e 9 FYSISK 0G XJEMISKE ZGENSXAPER. i Tilstandsform, farge, luke: Gul/brun vaske. 1 ou: 75-85 t Xokepunke/-iatesvall: <1s0c : Smeltepunks/-inservall: Tike relevant : Flammepunks: Ingen (Setaflash) : Selvantennelighet: Ikke kjent : =ksplosjonsgrenser, nedre: Ikke relevant | Eksplosjonsgrenser, ovze: * Ikke relevant i Demptrykk: Loselighet 1 vanne ca. 15.8 mag (Kelkulert v/20C) - | Fullstendiy Spesitikk vake: ca. 1.06 (vane) Danptetthat: vesi.2oc0).08 (luteal) (Ralsles a Flykeige organiske forbindslser (VOC): v=/230505) g/L SCAQMD (Kalkulert : fordanpningshastighes: Ike kiene Viskositat: <'5000 centigoise i i 002434 L5a9b3r1e2fr4o.: Page 26of 31 FC-GOJEF LIGHT WATER (TH) ATC 3% AR-ATFE 10 STABILITET 0G REAKTIVITET. - Forhole som skal uaaghs: MateriTaikleesjseonm.skal unaghs: | i FazligKeazsbpoanlmtnoinnogiksdsproogdukksaersb:ondioksid. Hydzogenfluorid. Giftige damper, i i gfaosrsveenrteeslleirkkepe&scirkelperse.seaDteekroemponnoeerninrgisiakvo.bruksferdig blanding SeebilSieceedtileo.g Freaarklsiiviptoelty:mesisasjon vil ixke forekomme. So | i e 11 OPPLYSNINGER OM EZLSZFe ARE. e | ztsekcHielsdoyonyee:irzitasion: thzes! symptoner ken vase rodnes, hevalse, smertes o || | : ffekcHeisldhhudu:dirsizesjon symptomer kan vare r(eoscthees, lhaenvgevlasreigogelkliesre.gjentate Kontak): i Langvazig eller gjentatt eksponesing kan fore til: AogllKeisssei.sk hudssakajon: symptoner kaa vase redhet, hevelse, blemmer |i EffektEenreniknenldsadionvge:rsissonesing nomez, kan fore til: som ovezstiser asbefalte adainistrative : | Pehcvhitr,knisonvgniagvhes:e,nsmraanlgnleecnvdeesysktoeomredti:nssjyomnpsteovmneer,kannedvsaartee hodepine, zbeeavkissjsotnlsoesvhneet,. slores tale, svimmelhe: og i ekstreme tilfeller i Isvrezligt,ashjoonsti(negveoglnuyfstivnegi.er): symptomer kan vase sirhet i nese og | EffektDeyrrefsovrelsgoikngu:tfert med organiske dette produktet, viser effekter sfloumorlkejveemrifkoarlsiteyrr,relssoemr,fivnenxesstaip, a Cbuaknsgplyecntd,e bsipnpyecziecso,g shelmoavthoelsogsia.ntDaettfefkotreerlissoenarphfvnimecnkertineenuernologhit |! oo43: | La5b3re1f3r4e. Page 270731 ' FC-GOIEF LIGHT WATER (TH) ATC 3% AR-AFPE velledning. PShvveilzgiianigsgkanavfonryezensei:l: symptomer urines og rygzsmertes kaa vare redusers urismengde, blod AoKsgoppniinzaeasrss.nj)eo:dnspsinyemLuupsntogonentne.es.(kLaEunnngvaealbraeeitnennhenolesiltisynegd,rssoapnkusstkfeyivlladnecssiklesartt,anfdgreienssomieenxdgl,eeses Hoste ope blod og Lungebetenneles son kan vare Livstrueads. Informasjon on ellesgt, ovesfelsomhec: Keefttzenkellende egenskapes: Arvestottaxadelige eseasiaser: Repzoduksjonsskedelise esenskaper: AndzeDslekuzaoedzeivcpijrceokadnkuiaknltgieeerss,,iashneoelmssoeml:udleirgeennselkleenssbfsloosrsberoersse0n3iskleagres i kropses | naveecshrTyeninnggesstiiod,fieernte(nmessaobmoluittgtaenrg)a,meloegkyKlaenraskiiiuemcclescoems ved nfdjossendmteeantbszreeuskkeeeksrspsofroname.zeifnkogsrepusot.nseartDitentgofgoorvieerlhfieegmrgheoorlrdgiatnnigielnskveekijlefenldtuneoirnkhgje.elnsieksaflfieekrter gFeonreszkeolnlsscenbeafvoloxzaginagneinskeosfulnudoerrkpjoepmuilkeasljioenreri sbiosmdeatchaiilderdee,n hat eVsanses paurbbleiisdeessss sviidseen: i19n7g0enArseknaed.eliIgMse eetpfiedxetmeiro.logiske studier av . 12 OPPLYSNINGER OM MiLJoFARE. PezsiDsettetnes/Bsisooltofgeitskexniekdkberyslbeatzthebti:ologisk nedbrythart, men brytes == deluis ned i tester for lett biologisk nedbrytoarhet. Dfeltutoerkjpernoidkuakltieter isnonmehmoulldiegrenesn ailjcet (persiscente)- eilklkeererflanreedborrygtabsairsskoeg forblir i J 7 Oxotokpseistkeolosgciastkteerdaecxa:minimal Rell Aavaeca tren omen siStIeLiTg oClvEefsftoorrtshkvvaassiisskkee osergman!tsaer 1100 00243 i L9a3b1r2-e4f: Page 280f31 + FC-0IEF LIGHT WATER (TH) ATC 3% AR-AFFF Andzebeszksadeovnirbkinoilnoggeiss,k mrieldjber:ytbashet: Cop 500 5(Cdhaegmeiscsal (O3xiyogcehnemDiecmaalndO)x:yge7n400D0e0manmgd/)k:g:216000 Ag/kg; 300 80D 10 20 dagess: dagess: 376000 446000 mg/kg; mg/kg; . 800 28 dagers: 602000 mg/kg. akvatisk gitvighes: 96 tines CSO for fisk (Fathead Minnow (Pimeghales promelas)): > 1000 mg/l; 48 timers ECS0 daphnia (Wate: Flea (Daphnia-magne)): 480 mg/l: 30 24 mtiirmuesrsce.sEsCS0ECSAOlgeMic(rSoetloexn:as1t2r4ummgc/alpiricornutea)): 170 mg/l. Behandling i renseanlegg: 3 timers 2c50, Activated Sludge Respiration Inaibition:'> 1000 g/L. Secs for aviailshindtering iht. gjeldende fozskziftes. 13 FIZRNING AV KJENTXKALTZAVFALL. MetodeSspesfioarlafvjeeamlnli.ngLaevverkjeamvifkaalllietaivlfaelnl:offentlig sodkjent innsamler, mottaks- eller behandlingsaalegg for spesialaviall. AHaObVeEfDaKlAtTeZGOaRvZfa0l7l:sgArVupFpAeLrL: FRA ORGAVISKE PROSESSER. UcNeDnEgRjKeArTiEnGgOsRmTidl0e7r,06:deAsvifnaflelksjfornasmPi3DdBleravogfektotssmteotfifkekr., sipe, EaX-kode 07 06 03: Halogemerte organiske lesesidler, vaskevaskes AogvfamoldlesrclouftZ.nummers 7151 Organisk avfall med halogen. Spesielle komponenter: inneholder fluorforbindelser. 14 OPPLYSNINGER ON TRANSPORT. ADR-klasse: - . sitter: - 002437 L9ab9.3r1e2f4no. Pageatt29e0l/31 FC-603EF LIGHT WATER (TH) ATC 3% AR-ATFF bokstav: mazgaunnes: csrrc-kors: -nuames: - . - - - IcA0-klasses - HOG-KLesse: - 1HDG-s ide: sens EaG: : -= - ovrigeIkokpealtyrsannisnpgoerss:taslig gods. 15 OPPLYSNINGER OX LOVER OG FORSKRIFTER. - Meskeesixest: SymbolES(LezS)I:SKADELIG (Xa) IonenoElydleesn:glykol 22,5 1, 2-(2-butoksyetoksy)-etancl 10 3, Trietanolamin 1% j ResetnFianrgleisg: ved svelging. S-sesninges: noynneane.inFndhndmianongg aksvtoondftafemekpte/silperegoeyy.nteenFtsAh;rkems.kaynlUlasntgsohftfrkaokpnshtaghkrutudenndm,eidgvhmauesddkeensstoogre eStnegaekessmveadnsstore mengder sipe og onghende og vis denne beholderen vana. Ved svelging, eller etiketten. kontakt lege =] YL-gruppe: 00 Kerr. yrkeshyg. lufcbehov: i evrigeGvoepnpnleyrsnntiengneerckoiangmeerrkebsatsiekretttpehn:tidligese merksforskrifter og vil : ew 002438 . La9b9r3e1f2n4o.: Pageala 300731 I FC-603EF LIGHT WATER (TH) ATC 3% AR-APIF reviderce meskeforsirifces av Januar 1998. Symbol: Ingen TZaenieehsoalrdoelsa:mia1,2-etandiol, 2-(2-busoksyetoksy)-etanol, iXavn dveamzpe/sfparrelyicgesvteed. svUenlnggidngk.ontKaakne imrerditehruecenoynoegneo.yneUnnen.ghFAiznnmfaanding YSotrottafkesr ilegeey.nenFei;r mseknyllstosftfzakpsh ghruudennd,igvmaeskdesstosrtezamksengmdeedrsvtaonrse og mdeenngnederbeshdopledeozgenvaeslal.erVeedtiksevsetlegnin.g, kontake lege omgiende og vis T0i0-grupse:: : Soesie1l.leTorlosvxecrifotgobmesutteamcmbeelisdeesl:se og distribusjon av Kelse-, Hilje- og S2.ixFkoerrshkerrisfdtatoamblaKdlasfsorififsaerrliigneg kojgemmiekrakliinegz.av 3. forsxcifc om Klassifisering, mesking m.v. efvarlsitgoeffkjseommikalier. k4.anFmoerdsfkozriefsmiolmjosfteozfef.kartosek. - 56. Tzeoer.skzifc om spesisleviall. 16 ANDRE OPPLYSNINGER AV SETYDNING FOR BRUKERNES SIKKERSST OG HELSZ. AavendTeillsaedsaonnnzeinddees:skumkenseatra: for slukking av bam. VikeigDsetteebikaidldef(rra) 3vedGenuessasrlbeiOfdfeilcseesn, avSt.HMSPa-udla,tabMliamdneets:otg, USA. AesekHe1l1e odpaptdaabtleardientg:ex reviders. Tilpasset nye merke- og MS-databladforskrifter, fastsatt i januaz 1998. Etc. Egne opplysninger: we IoSpnvpfiodyresntnatisenjgopenrreondoupgkhtbederesstutenedoeHrpMpSfna-otdrnamitanalgbelaafdnoegrthheolneddz.si Erhinekhntvhiegorldbbrruutikkl oavgvhzhpeirnodndtiuevkartzieencngdesenom Ipkrkoedukoecet1 siakmossvbairnmaesdjondetmteed EaSnd-rdeatparboldaudkette,r eelllleerr seonmhvmeerdfaenrneern bprruoksesasv | x brukerens ansvar. 00243] | La9b3r1e2f-r4o.: Page31of31 FC-GO3EF LIGHT WATER (TM) ATC 3% AR-AFFF FOLGENDE PRODUKTER DEXXSS AV DETTE HMS-DATABLADET: 3 10-nz. X-0008-0223-1 34 AFFZ/ATC FC-603EF Bramnslukn ingsskum Produksjon ; 3 1o-ne. + X7-0008-0209-0 34 Light Fighting WFoaatme,rd/FICS-A6F0F3FE/FA,T10C00FirLe 3 10-nz. + X7-0008-0208-2 - 3M Light Waterd/3WAFFE/ATC Fire Fighting Foam, FC-603EF, 200 L 3 oar. - : X7-0008-0207-4 3 Light Fighcing WFaoatme,sd/FICN-6A0F3FEEF/,ATC20FirLe | 002440