Document qmZDXj6aZDVnKxyGZqRbNgB1G

STLS E V E R N TRENI STL Chicago 2417 Bond Street University Park, It 60466 Tel: 70B 5 3 4 5 2 0 0 Fax: 7 0 8 5 3 4 5 2 1 1 www.$tl-in.c.om Citie: Projeel Manager E-Mail : rwri ght.@s1_l-inc .com Th.i s R e p o r L C o n t a i n s Leaders in E n v iro n m e n tal T esting ___ 2 . / / / / ^ Date ___ STL Chicago 2417 Bond Street University Park, IL 80466 PHONE: (708) 53 4-52 00 FA.X ,, . : (708) 5 3 4 - 5 2 1 1 ) Pages Severn [rent Laboratories, Inc. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION JOB# 233856 D ata S u m m ary............................................................................... 1 C hain o f C u stod y .................................................................. *...28 C ase N a rra tiv e.............................................................................34 R aw D a ta ................................................................ 36 STL, Chicago is part of Severn Trent Laboratories, Inc. SAMPLE- I N F O R M A T I O N ... -..-....../..bate.: 02/11/2.005 Job Number.: 233856 Customer...: Weston Solutions, Inc. A t t n . : Jai Kesari Project Number.,__ r...: 20004891 Customer Project ID,.,.: CONFIDENTIAL DECATUR Project Description___ : Confidential Decatur - FC Investigation \ Laboratory Sample ID' 233856-1 233856-2 233856-3 233856-4 233056-5 233856-6 233856-7 233856-8 233056-9 233856-10 233856-11 233856-12 233856-13 233856-14 233856-15 233856-16 233856-17 233856-18 233856-19 233856-20 Customer sample ID DF09-55-0001-0-0000 DF09-55-01-0-0003 DF09-SS-0002-0-QO DF09-SS-0002-0-0003 DF09-SS-0003-Q-0000 DF09-SS-0003-0-0003 DF09-SS-0004-0-00 DF09-SS-0004-0-0003 DF09-SS-0005-0-0000 DF09-SS-0005-0-0003 DF06-SS-0001-0-0000 DF06-5S-0001-0-0003 D F06-SS-00020- 0000 DFO6-SS-02-0-00D3 DF06-SS-0003-0-0000 DF06-SS-0003-0-0003 DF06-SS-0004-0-0000 DF06-SS-0004-0-0003 DF06-55-0005-0-0000 DF06-SE-05-0-00O3 Semple . Matrix Sui l Soil Soi L Soi l Soi 1 Soil Soi L Soi L Soi 1 Soit Soil Soil Soi L Sei L Soil Soi L Soi l Soi l Soi l Soi l Date Sampled . 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 01/27/2005 Time.; . Date .Sampled. .Received Time Received ! 08:30 01/29/2005 09:00 08:40 01/29/2005 09:00 08:25 01/29/2005 09:00 08:30 01/29/2005 09:00 08:55 01/29/2005 09:00 09:00 01/29/2005 09:00 08:00 01/29/2005 09:00 8;05 01/29/2005 09:00 08:30 01/29/2005 09:00 08:35 01/29/2005 09:00 09:35 01/29/2005 09:00 09:45 01/29/2005 09:00 09:45 01/29/2005 09:00 09:55 01/29/2005 09:00 09:45 01/29/2005 09:00 09:50 01/29/2005 09; 10:10 01/29/2005 09:00 10:15 01/29/2005 09:00 10:25 01/29/2005 09:00 10:35 01/29/2005 09:00 Page 1 1 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233056 CUSTOMER: Weston Solutions r Inc. Customer Sample ID: DFG9-SS-00Q1-0-0000 Date Sampled..... : 01/27/2005 Time Sampled..... : 08:30 Sample Matrix.... : Soi L TEST METHCO :: PARAMETER/TEST DESCRIPTION Lloyd Kahn Total Organic Carbon tSoiIs) TOC Average Duplicates, Solid CM LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233B56-1 Date Received...... : 01/29/20Q5 Time Received...... : 09:00 Date:02/t1/2005 ATTN: Jai Kesari SAMPLE RESULT Q FLAGS 11000 HDL 270 RL 1100 DILUTION UNITS BATCH DT ; DATE/TIME ; TECH - 1 mg/Kg 140945 02/02/05 1213 els * En Description = Dry Wgt. Page 2 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233856 CUSTOMER:Weston Solutions , Inc. Customer Sample ED: DFQ9-SS-0001-D-0003 Date Sampled...... :01/27/2005 Time Sampled...... :08:40 Sample Matrix..... :Soil TEST- METHOD Lloyd Kahn PARAHETER/TEST DESCREPT0N Total Organic Carbon {Soils} TOC Average Duplicates, Solid co LABORATORI TEST RESULTS ' PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 233B56-2 Date Received...... 01/29/205 Tiine Received...... 09:00 Date:O2/11/2B05 ATTN: Jai Itesari ` SAMPLE RESULT QjFLAGS. 7000 MDL 230 Rl DILUTION UNITS BATCH DT ' 0ATE/TIME TECH 900 mg/Kg 140945 :02/02/05 1232 :c Is In Description = Dry LJgt. Page 3 STL Chicago is part oi Severo Treni Laboratories, Ine. Job Humber: 233356 r CUSTOMER: Weston Sa tt ins:p Jnc. Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... O F 0 9 -SS-0002-0-0000 01/27/2005 03:25 Soi L TEST;METHCO Lloyd Kahn PARAMETER/TEST DESCR3FT]ON Total Organic Carbon [Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233856-3 Date Received....... : 01/29/2D05 Time Received....... : 09:00 Date:02/11/2005 ATTN: Jai Kesari SAMPLE RESULT 7200 FLAGS MDL 250 RL 1000 D ELUT 1-QN UNITS BATCH DT DATE/TIME TECH mg/Kg 140945 02/02/05 1327 els * [n Description = Dry Ugt. Page 4 STL Chicago is part of Severn Trent Laboratories,, Inc. Job Number: 23356 CUSTOMER: Wes tor. Solutions, Inc. Customer Sample ID: D F09-55-0002-Q-0003 Date Sampled...... :01/27/2005 Time Sairpled...... :08:30 Sample Matrix..... :Soil TEST HETROD Lloyd Kahn :PARAMETER/TE ST !DESCRI P H O W Total Organic Carbon <5oils} TOC Average Duplicates, Solid 1/3 LABORATORY TEST RESULTS PROJECT : CONFIDENTIAL DECATUR Laboratory Sample ID: 233856-4 Date Received....... : 01/29/2005 Time Received....... : 09:00 Date:02/11/2005 ATTN: Jai Kesari SAMPLE- RESULT 8000 FLAGS: :mdl 250 RL 0]LUT TOM UNITS :BATCH: OT DATE/TIME TECH 960 mg/Kg 141632 02/01/05 0915 e l s In Description = Dry Ugt. Page 5 STL Chicago is part of Severn Trent Laboratories, [nc. Job Number: 33356 CUSTOMER: Weston Solutions, Inc. Customer Sample ID: D F09-S S-0003-0-0 000 Date Sampled..... : 01/27/2005 Time Sampled..... : 08:55 Sample Matrix.... : Soi l I TEST METHOD Lloyd Kahn PAAHETER/T.ST DESCRIPTION TotaL Organic Carbon (Soils) TOC Average DupLicates. Solid & LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUP Laboratory Sample ID: 233656-5 Date Received...... : 01/29/2005 Time Received...... : 09:00 Date:Q2/11/2005 ATTN: Jai Kesari SAMPLE RESULT 14000 FLAGS :M)L 300 :Rl : 1200 DILUTION UNITS BATCH QT: PATE/TIME TECK rr>g/Kg 141632 02/01/05 1019 c Is [n Description = Dry Ugt. Page 6 STL Chicago is part of Severn Trent Laboratories, Inc. !> In Description - Cry Wgt. Page 7 STL Chicago is part of Severn Trent Laboratories, Ine. Job Number: 233356 CUSTOMER: Weston Solutions, 1nc. ::: Customer Sarr^ale 3D: D F09 -SS -LI004 -0 -000 D Date Sampled..... .: D1/27/2005 Time Sampled...... :03:00 Sample Matrix..... :Soi l fEST:METHOD Lloyd Kahn PARAMETER/TEST D ESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid CO LABORATORY TEST RESULTS PROJECT: CONH DENTIAL DECATUR Laboratory Sample ID 233856-7 Date Received...... 01/29/2005 Time Received...... 09:00 Date:02/11/2005 ATTN: J-ai Kesari . SAMPLE RESULT 2DD00 FLAGS: 350 RL 1400 10]LUTTO! UNITS BATCH DT DATE/TIME TECH mg/Kg 141632 02/01/05 1053 els * In Description = Dry Wgt. Page 8 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number : 233856 ^CUSTOMER : Wes ton ;SoLut ions , Inc. Customer Sample ID: DF09-SS-0004-0-0003 Date Sampled.......:01/27/2005 Time Sampled.......:08:05 Sample Matrix......:Soi l TEST METHOD Llayd Kahn : PARAMETER/TEST DESCRIPTION Total Organic Carbon fSoiIsl TOC Average Duplicates, Solid Ci LABORATORY TEST RESULTS . PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233856-8 Date Received........ :01/29/2005 Time Received........ :09:00 Date:02/11/2005 ATTN: Jai -Kesarj SAMPLE1RESULT : Q FLAGS j 10000 j ij MDL 350 RL 1400 DILUTION UNITS BATCH' 0T DATE/TIME TECH 1 n>g/Kg 141632 02/01/05 1140 cLs j ]________ .. .____ .---------------------------------* In Description = Dry IJgt. i! Page 9 STL Chicago is part ot Severn Trent Laboratories, Ine. OH * In Description = Dry Wgt. Page 10 STL Chicago is part of Severn Trent Laboratories, Inc. Job Nimber: 23385 CUSTOME R i: Weston :So luti Mis , Inc. : Custodier SairpLe ID: 0 F09-SS-0005-0-0003 Date Sairpled...... :01/27/2005 Time Sairpled...... :03:35 SairpLe Matrix..... :Soil TEST METHOD : PARAMETER/TEST DESCRIPTION- :L Lloyd Kahn Total Organic Carbon tSoiLs) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ED: 233856-10 Date Received........ :01/29/2005 Time Received........ :09:00 Date:02/11/2005 ATTN: Jai Kesar.i SAMPLE:RESULT ; .FLAGS ' 11000 MDL ' 360 RL 1500 DILUTION UNITS . : :BATCH1: D T DATE/f[HE TECH 1 mg/Kg 141632 02/01/05 1225 els * En Description = Dry Wgt. Page 11 i STL Chicago is part oi Severn Trent Laboratories, Inc. Job Nurrber: 233E56 CUSTOMER :!Weston So Eut ipris;I:Inc ;I Custocner Sarrple ED Date Sampled..... Time Sampled..... Sample Matrix.... DF6-55-0001--0000 01/27/2005 09:35 Soi L TEST METHOU Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS ^PROJECT: COWFEDEMTIAL' PECATUR Laboratory Sample ID 233856-11 Date Received...... 01/29/2005 T ime Recei ved...... 09:00 Date:02/11/2005 fiTW:: Jai K e s a n - SAMPLE RESULT 4200 FLAGS: -MOL 370 :RL 1400 DILUTION UK ITS BATCH DT :d a t e m m . TECH mg/Kg 141632 02/01/05 1242 els * In Description = Dry Ugt. Page 12 _L STL Chicago is part of Severn Trent Laboratories, ]nc. Job Nimber: 23385 ; CUSTOMER: Weston Solutions, Inc. Customer Sample ID: D F06-S S-0001-0- 0Q03 ate Sampled..... : Qt/27/2005 Time Sairpl ed..... : 09:45 i Sample Matrix.... : Soi l TEST METHOD PARAMETER/TEST DESCRIPTION -- Lloyd Kahn Total Organic Carbon [Soils) TOC Average Duplicates, Solid nH LABORATORY TEST RESULT S :;:PROJECT: CONFIDENTIAL- DECATUR ;! Laboratory Sample ID 233856-12 Date Received.... . 01/29/2005 Time Received...... 09: DO Date:02/11/2005 ATTN: Jai Kesari SAMPLE- RESULT '3 P U G S 4100 MDL 270 .RL : 1100 DILUTION UNITS BATCH DT DATE/TIME TECH 1 mg/Kg 141632 jD2/0f/05 1336 els * [n Description - Dry Ugt. Page 13 I; STL Chicago is part of Severn Trent Laboratories, Inc. tH In Description = Dry Ugt. Page 14 S U Chicago is pari of Se-vern Treni Laboratories, Irte. Job Number: 233356 LABORATORY TEST RESULTS Date:02/11/205 LO * [n Description = Dry Ugt. Page 15 STL Chicago is part of Severn Trent Laboratories, Inc. & * In Description = Dry Wgt. Page 16 STL Chicago is part of Severn Trent Laboratori e s r [nc. Job Number: 233856 CUSTODE R : Weston :Solutionsr [nc. C ustom er Sam ple !.D Date Sampled..... Time Sampled..... Sanple Matrix.... DF06-SS-0003-0-0003 01/27/2005 09:50 Soi I TEST METHOD Lloyd Kahn :PARAMETER/TEST 0 ESCRIPTIOW Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT:' CONFIDENTIAL DECATUR Laboratory Sample ID: 233356-16 Date Received....... : 01/29/2005 Time Received....... : 09:00 Date:02/11/2005 ATTW: Jai Kesari LvH SAMPLE RESULT 'FLAGS 9100 :MDL: 370 RL . :;i D 3LUT TOM UNITS b a t c h ; DT d a t e m m tech: 1500 mg/Kg T41632 02/01/05 1448 els * In Description = Dry Ugt. Page 17 STL Chicago is part of Severn Trent Laboratories, Enc. GO t * (n Description = Dry Wgt. Page IB STL Chicago as part of Severn Trent Laboratories, Inc. erHn * ]n Description = Dry Wgt. Page 19 STL Chicago is part of Severn Treni Laboratories, Ine. Ow * In Description = Dry Ugt. Page 20 STL Chicago is part of Severn Tr&nt Laboratories, Enc. 1 Job Number: 233856 CUSTOMER: Weston Solutions, Inc. Custodier Sample ED Date Sampled..... Time Sampled..... Sample Matrix.... D F06-SS-000 5-Cl-0003 01/27/2005 S10o:i 3I5 TEST. METHOD: Lloyd Kahn PARAMETER/TEST ;DESCRtPfTON Total Organic Carbon [Soils) TOC Average Duplicates, Soil'd HN LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL 0ECATUR . Laboratory Sample ID: 233356-20 Date Received...... : 01/29/2005 Time Received....... : 09:00 Date:02/11/2005 ATTN: Jai Kesari SAMPLE RESULT 14000 FLAGS MDL 390 RL 150D DILUTION UNITS : I-- -------- -- -- BATCH :D T . DATE/TIME TECH mg/Kg ;141632 02/01/05 1543 Cl 5 In Description = Dry Ugt- Page 21 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number-. 233B56 LABORATORY CHRONICLE D ate : 02/11/2005 CUSTOMER: Weston Solutions, Inc. Lab ID: 233856-1 METHOD EDD PKG INO <WC) Lloyd Kahn Client ID: DF09-SS-0001-0-0000 DESCRIPTION Electronic Data Deliverable PKG INO (WET CHEMISTRY) Total Organic Carbon (SoiLs) Lab ID: 233856-2 Client ID: DF09-S5-0001-0-3 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-3 METHOD Lloyd Kahn Client ID: DF09-SS-0002-0-0000 DESCRIPTION Total Organic Carbon (Soils) Lab ID: 233856-4 Client ID: DF9-SS-0002-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-5 METHOD Lloyd Kahn Client ID: DFQ9-SS-0003-0-0000 DESCRIPTION Total Organic Carbon (Soils) Lab ID: 233856-6 Client ID: DF09-SS-0003-0-QQ03 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-7 Client ID: DF09-SS-0004-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-8 Client ID; DF09-5S-0004--O3 METHOD DESCRIPTION H o y d Kahn Total Organic Carbon (Soils) Lab ID: 233856-9 Client ID: DF9-SS-0Q05-0-00 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-10 client ID: DF09-SS-005-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-11 Client ID: DF6-SS-0001-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-12 Client ID: DF06-SS-001-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) Lab ID: 233856-13 client ID: DF06-SS-0002-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-14 Client ID: DF6-SS-0002-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT: CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 01/29/2005 sample Date: 01/27/2005 RUN# BATCH# PREP BT #<$) DATE/TIME ANALYSED 1 1 1 140945 140945 02/02/2005 1213 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140945 140945 02/D2/2005 1232 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140945 140945 02/02/2005 1327 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 0915 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1019 DILUTION Date Recvd: 01/29/2005 sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1034 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1053 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1140 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1212 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1225 DILUTION Date Recvd: 01/29/2005 sample Date: 01/27/2005 RUN# BATCH# PREP BT #{S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1242 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1338 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1400 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1420 DILUTION Page 22 22 STL Chicago is part of Severn Trent Laboratories, Inc. Job Nunber: 233856 LABORATORY CHRONICLE Date: 02/11/2005 CUSTOMER: Weston Solutions, Inc. Lab ID: 233856-15 Client ID: DF06"SS-0003-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-16 Client ID: DF06-SS-0003-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-17 Client ID: DF06-55*0004-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-13 Client ID: DF06-SS-4--3 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-19 Client ID: DF06-SS-OO5--00 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233856-20 CLient ID: DF06-SS'0005-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT: CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1433 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1448 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1503 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1520 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1532 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141632 141632 02/01/2005 1548 DILUTION Page 25 23 Job Numb&r.: 233356 CUSTOMER: Weston Solutions, Inc. QUALITY CONTROL RESULTS .. PROJECT: CONFIDENTIAL DECATUR Report bate.: 02/11/2005 ATTN: Jai Kesari ..'Test Method....... : Lloyd Kahn " :Method Dcscrlption.:,Tbtal Organic Carbon(SoiIs) Parameter......'___ : Organic Carbon, Tot. (TOC) . Batch........ ___ : 140945 Equipment Code T0C4 Analyst els .. Test Code. I.'.TC" :::: QC Lab IP Reagent Uni ts QC Result QC Result True Value Orig. Value QC Calc. F it- Limits Date T ime ICV 140945-002 I05ASTTC2 MB 140945-003 LCS 140945-004 IO0FSTLK3 LCD 140945-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg CCV 140945-017 I05ASTTC2 mg/Kg CCB 140945-013 mg/Kg 1833.30 32.00 U 4523.44 3899.55 4523.44 1826.30 32.00 U 2000.00 4780.00 4780.00 2000.00 92 186.18 U 95 164.10 U 82 15 91 7, 85-115 % 53-140 % 53-140 R 30 % 85-115 02/02/2005 0809 02/02/2005 0822 02/02/2005 0844 02/02/2005 0852 02/02/2005 1347 02/02/2005 1405 Test Method. ..: Lloyd Kahn Method Descr ption.: Total Organic Carbon (Spits) Parameter... . f Organi c :Carbo \ Tot. (TOC) ..Batch, .'v t41632 Equipment-.. Code ___ : TOC4 Analyst.. : els Test Code : TOC . QC Lab ID Reagent Units ICV 141632-002 I05ASTTC1 MB 141632-003 LCS 141632-004 IFSTLK3 LCD 141632-005 IO0FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg CCV 141632-016 I05ASTTC1 CCB 141632-017 CCV 141632-016 I05ASTTC1 CCB 141632-017 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 1988.72 32.00 U 4488.08 4757.13 4480.08 1986.26 32.00 2135.00 32.00 U U True Value 2000.00 4780.00 4780.00 2000.00 2000.00 orig. Value QC Calc. F * Ll (lilts Date Time 99 199.22 178.40 U 94 U 100 6 99 107 % 85-115 % 53-140 % 53-140 R 30 % 85-115 % 85-115 02/01/2005 0811 02/01/2005 0815 02/01/2005 0848 02/01/2005 0856 02/01/2005 1258 02/01/2005 1302 02/01/2005 1608 02/01/2005 1626 Test Method.. .: LLoyd. Kahn Method Destri ption.: Total Organic Carbon (Soils) Parameter... ;!,____ : TOC Average duplicates QC Lab ID MS 233856-2 MSD 233856-2 Reagent Units I05ASTTC2 mg/Kg I05A5TTC2 mg/Kg QC Result 12991.40 10659.17 QC Result 12991.40 Batch : 140945 Equipment Code ___ ; T0C4 Analyst.. -"cits. Test code : TOCAV2 True Value 2000.00 2000.00 Orig. Value 6964.10 6964.10 QC Calc. F * Limi ts Date Time 101 % 53-140 02/02/2005 1246 72 % 53-140 02/02/2005 1252 48 R 30 Test Method. ______ : Llbyd Kahn Method Description.: Total Organic Carbon (Soi l.s) Parameter ^4'. .-- ., : TOC Average Pupiicates " Batch........ ___ : 141632 Equipment Code TOC4 ' Analyst,. els Test Code : T0CAV2 QC Lab ID MS 233856-4 MSD 233856-4 Reagent Uni ts I05ASTTC1 mg/Kg I05ASTTC1 mg/Kg QC Result 14952.66 12635.86 QC Result 14952-66 True Value 2000,00 2000.00 Orig. Value 8038.07 8038.07 QC Calc. F it Limi ts Date Time 85 % 53-140 02/01/2005 0948 127 % 53-140 02/01/2005 0957 40 * R 30 Page 24 * %=% REC, R=RPD, A=ABS D 1ff.F 0=% Diff. 24 Q UAL I T Y A S S U R A N C E M ETHDD E R E N C E S AND NOTES .."..Report Date: 02/11/2005 REPORT COMMENTS 1) ALL pages of this report are integral parts of the analytical data. Therefore, this report should he reproduced only in its entirety. 2) Soil, sediment and sludge sample rcsuLts are reported on a "dry weight" basis except when analyzed for landfilL disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis uhless noted differently. 3!) Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. A) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to A0CFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on laboratory receipt. Glossary of flags, qualifiers and abbreviations Cany number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the statedlimit. < Not detected at or above the reporting Limit. J Result is Less than the RL, but greater than or equal to the methoddetection Limit. B Result is less than the CRDL/RL, but greater than or equal to the IDL/MDL. $ Result was determined by the Method of standard Additions. F AFCEE: Result is Less than the RL, but greater than or equal to the methoddetection Limit. Inorganic Flags (Flag Column) ICV,CCV,ICR,CCB,ISA,ISB,CR1,CRA,MRL; Instrument related QC exceed the upper or lower control limits. * Lcs, LCD, MD: Batch QC exceeds the upper or lower control Limits. + MSA correlation coefficient is less than 0.995. A MS, MSD: The analyte present in the original sample is A times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD: Serial dilution exceeds the control Limits. H MB, EB1, EB2, EE3: Batch QC is greater than reporting limit or had a negative instrument reading Lower thah the absolute value of the reporting Limit. N MS, MSD: Spike recovery exceeds the upper or lower control limits. W AS(GFAA) Post-digestion spike was outside B5-115% control limits. Organic Qualifiers (Q - column) U Analyte was not detected at or above the stated Limit. ND Compound not detected. 4 Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typicaL fuel pattern. 1 The chromatographic response does not resemble a typical fuel pattern. E Result exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting Limit or a tentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting Limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or Lower control limits. EB1, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) R Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The Lower of the two values is reported when the % difference between the results of two GC columns is Page 25 25 Q U A L M Y A S S U R A N C E ' M E I N D D S R E N C -;E::'S:/ A N D '' N;0 T :E..$ . Report Date: 02/11/2005 ...... greater than 25%. Abbreviations AS Post Digestion Spike (GFAA Samples - See Note 1 below) Batch Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP Capillary Column CCB Continuing Calibration Blank CCV Continuing Calibration Verification CF Confirmation analysis of original Cl Confirmation analysis of A1 or D1 CZ Confirmation analysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level Standard Check ' GFAA; Mercury CR[ Low Level Standard Check - ICP CV Calibration Verification Standard Dil Fee Dilution Factor - Secondary d i lution analysis Dl Dilution 1 D Dilution 2 D3 Di Lution 3 DLFac Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled Standard - Low Level DsM Distilled Standard - Medium Level EB1 Extraction Blank 1 EB2 Extraction Blank Z EB3 DI Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial calibration ICB Initial Calibration Blank 1CV initial Calibration Verification IDL Instrument Detection Limit ISA Interference Check Sample A - ICAP ISB Interference Check Sample B - ICAP Job No. The first six digits of the sample ID which refers to a specific dient, project and sample group Lab ID An S number unique laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory Control standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation Blank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System <LI MS ) PDS Post Digestion Spike ClCAP) RA Re-analysis of original A1 Re-analysis of Di A2 Re-analysis of D2 A3 Re-analysis of D3 RD Re-extraction of dilution RE Re-extraction of original Rc Re-extraction Confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor R1 Retention Time Page Z6 26 Q U A L I T Y A S S U R A NX E M E T HOD S . R E F E R 'E W C E S ' A N D 1 0 T . E S ; Report Date: 02/11/2005 RTW Retention Time Window Sample ID A 9 digit number unique for each sample* the first six digits are referred as the job number SCB Seeded control Blank SD Serial Dilution (Calculated when sample concentration exceeds 50 times the MDL) UCB Unseeded Control Blank SSV Second source Verification standard SLCS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control Sample Duplicate MDPH pH Sample Duplicate MDFP Flashpoint Sample Duplicate LCFP Flashpoint LCS G1 Gelex Check standard Range C M G2 Gelex Check Standard Range 1-10 G3 Gelex Check Standard Range 10-100 G4 Gelex Check Standard Range 100-1000 Note 1: The Post Spike Designation on Batch be for GFAA is designated with an "S" added to the current abbreviation used. EX. LCS S=XCS Post Spike (GFAA); MSS=MS Post Spike (GFAA) Note 2: The MD calculates an absolute difference (A) when the sample concentration is less than 5 times the reporting limit. The control limit is represented as +/- the RL. Page 27 CHAIN OF CUSTODY 28 CHAIN OF CUSTODY / ANALYSIS REQUEST FORM Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, fL 60466 PAG E / of 6 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: i.kesarifo)westo nso Iution s.com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: T Frinak, A Murphy 256-552-6189 P O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # 1 & 10 Client Sample Identification DF09 SS 0001 0 0000 DF09 SS DF09 SS 0001 0002 00000030 DF09 SS DF09 SS 0002 0003 00000030 DF09 SS 0003 0003 DFQ9 SS 0004 0000 DF09 SS DF09 SS 0004 0005 00000003 DF09 SS 0005 0003 Collection Data 1/27/2005 1/27/2005 1/27/2005 1/27/2005 1/27/2005 1/27/2005 1/27/2005 1/27/2005 1/27/2005 1/27/2005 Collection Time 8:30 8:40 8:25 8:30 8:55 98::0000 8:05 6:30 8:35 X X a C 'S o. Eo 2O Sample Matrix SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL CHAIN OF CUSTODY RelinqyiBire^'By^ jf - rJ Cooler ID No.: Time l/ycfC Received By: ,,Fed Ex W' Cooler Temp. (C): Date Time / V S & oz cR o o Comments 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES X X I PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: CHAIN OF CUSTODY / ANALYSIS REQUEST FORM Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE oi PROJECT INFORMATION Client: W eston S olutions, Inc. 1400 W eston Way, Bldg. 5-2 W est Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: i.kesa rifwesto nso Iuti o ns. com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: T FrinakrA Murphy 256-552-6189 P.O. #: Quotation #: Oo SAMPLE ANALYSIS ExyLIMS # u & nu > 16 Collection Client Sample Identification ate DFQ6 SS 0001 0 0 0 0 0 H 27-Jan-05 DF06 SS 0001 0 0003 27-Jan-05 DF06 SS 0002 0 0000 27-Jan-0 5 DF06 SS 0002 0 0003 2 7-Jan-05 DF06 SS 0003 0 0000 27-Jan-05 DF06 SS 0003 0 0003 27-Jan-05 DF06 SS 0004 0 0 0 0 0 27-Jan-05 DF06 SS 0004 0 0003 27-Jan-Q5 DF06 SS 0005 0 0000 27-Jan-05 DF06 SS 0005 0 0003 2 7-Jan-05 C o lle c tio n Time 9:35 9:45 9:45 9:55 9:45 9:50 10:10 10:15 10:25 10:35 X X X X X X X X X X 4E> Zo <oJ 1 1 1 1 1 1 1 1 1 :1 Sample Matrix SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL CHAIN OF CUSTODY Rei inqu isJiper:^ Pate, is * ~ jF ^ V/ Cooler ID No.: Time Received By: Fed Ex TH i - t Cooler Temp. (C): Date Time cfioo Grab Sample Composite TOC Comments 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 iNCHES X X X X X X X X X X PROJECT REQUIREMENTS Results Deadline: Laboratory Report O ptions: Sample Results OnJy Add Case Narrative Add Quality Control Summary Add Cafibration Summary Add Raw Data Other: I S a m p le L o t#: S a m p ie N o. A n a ly s is c h e /L _ STL Chicago Internal Sample Custody Transfer Record ____ Client: R e lin q u is h e d b y: _____________. p t - R e c e iv e d by: D a te T im e C o m m e n ts s u ffe r ' J j- : (k y )U V - ________________ __ / / & / < * ' / n rr" H fO C H 1-22-11-001/C-1/99 rpj'sckL Job Sample Receipt checklist Report Job Nunber.: 233856 Location.: 57222 Check List Number.: 1 Description.: Customer Job lb.... : Job Check List Date.: 01/29/2005 Project Number.: 20004891 Project Description.: Confidential Decatur - FC Investigation Customer...... : Ueston Solutions, Inc. Contact.: Jai Kesari Questiohs ? (V/N) Contnents V2 Date of the Report.. 02/11/2005 Project Manager.... rcW Chain-of-CUstody Present?........................ . V Were samples dropped off at or picked up by STL?. . N Custody seal on shipping container?......... .... . Y ...If "yes", custody seal intact?................ . Y Custody seals on sample containers?........ . .N ...If "yes", custody seal intact?............ . Samples iced?......................... . Y Temperature of cooler acceptable? (4 deg C +/- 2) . Y 3.2 Samples received intact (good condition)?r,...... . Y Volatile samples acceptable? (no headspace)..... Correct containers used?..,.,.................... . Y Adequate sample yoLume provided?.......... . .Y Samples preserved correctly?..................... . Y Samples received within holding-time?........... . Y Agreement between CQC and sample Labels?........ . Y Radioactivity at or below background Levels?.... . Y A Sample Discrepancy Report (SDR) was needed?___ . N If samples were shipped was there an air bill #?. . Y Sample Custodian Signaturc/Date....... .......... . Y Page 1 32 Express U S A i r b i l l -'- g - f i 4 3 4 ' i b ` i a f i l b 1 fro m Cate / ^/ Sender's Hante 7/V? ; `t--v-x-^n- -1 f~ / ^ /; / ?.V"4:.-itr,.^,-CE5' Phone -'j?*' < "z u v Company 4a ExpressPackageService OS--tIFHietod!BfattfelrsiaemriTMty*OPwmiglt I1-- 1I HFuetdfBattSestia(rrfieatrod*O*wBntrt flKfevHfptowafc 'B m rtlwriwt PI-- iI FEMiEetiadetvE;evxtnaonFitoaaaebsauatfflCaaMuitfaoalmiuiirningar?taitt TFTheirtddIEtuixiiiiaixjui.mlri|ewtTe1sSam F E w ttrB in tfn *^ Irtwiii tin Ifamfriidi Express Freight Service I W a ir-- r a J k nLj FfeadBttt1tDenay*F*ragha* II--- !ISFaemddEfxa2tDeaBfyaFfiB^*t I>---! =KFeidEtxi30^awaR^rcisht Privad fa* SO FedEx Pefc* H FedEx -- hFstdefeUFflrit&FW4.andl PFri*faSut*P* Box FedEx Tl*e j? | Dttwr Recipiente Address ~i i1 t/ WeMMX(frill toP.Vani ITPJ).JlPttft, fttMtonutiXfan hcfcfaiFw&itWa fabcfa!, SATW AYM m er A ^ m to jM b h rt, r~ i HOLOW riW oy |_| st FedEx Locatici the*till*d^atitc h W dwftnea*wti*T Pna baciuMtaefaekm i--i W tOSttuday l_ l aM0tawu"areaF-rfaieaHiidjutfbrBeriitrfielfxaMleiFtrf;i3oc)&nfpainto RNa P I Yas I-- I I I Vas 1--J Srtiat*->?9ttd.xljut M DdtdUintlMiiilinyl^iainteCfat*l I I Dry ice I-- I fr in it i I I CarfloAirnreft Or^r J P^a m m l jM-- =b----Bm FatasiH*.er*ttC*ilt.M m .--- -- -- | AOictiNnjlRace1.--I 1I ItaLjuSi Q R e lia n t - QH Thnl Psrty Q Credit Card Q CestyChack Address TonqiMta padceQ*ba hM rti frepft-f*4Eta l n prtf*4Elatomi pn. Cltv L/ S i/A s ; -' .-=' .. v. ' j! State t ! ZIP i f o J ? P i -( IttelR adap* T*W Weight Total D e d m d V W j S .DO 1Qj bufarla fated m$HI Litui youdu fax nifaSir-nbfr.SafrbacXinteij. Total Ctw^M Grafi:CardAidt Mfi4 flfliib L n CASE NARRATIVE 34 STL Chicago W et Chemistry Case Narrative Client: Weston Solutions, Inc. Job #; 233856 Date Rec'c; 01/29/05 1. This narrative covers the analysis of the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, alter afocridmifoicisattuiorenctoonrteenmt.ovTehienoavrgearangice ocafrtbhoens,amanpdledbryuimngs.isNreopocrotrerde.ction was made, therefore, 2. The method-recommended holding time of 2 weeks was met. Refer to the Laboratory Chronicle Page for dates of sampling, receipt, and analysis. 3. Tmheet aTcOceCptcaanlicberactriiotenricau, rve and the initial and continuing verification standards and blanks 4. The method blanks were less than the reporting limit. 5. The LCSs were within acceptance limits. 6. The matrix QC done on samples 233856-2 and -4. The recoveries were all within acceptance limits, but the RPDs between the MSs and the MSDs were both high. Diane L. Harper Wet Chemistry Section Manager -_ 1 Date 35 RAW DATA *** RUN LOG AAA <V2 .) 2/2/05 15:00 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140945 status.......: RPT Botch Date...: 02/02/05 Batch Time...: 1432 User Name.......: els QC Code......... : TOCS Calc Code.......: TOCS Location Code..: 57222 Equipment Code.: T0C4 Import Code____: TEST CODE Tr TTT TTT TTTTT O000O00CCC III Cc C ccccS ssCCC 234AAA 2ASss VVV V 2A 234 2 2 SAMPLE: Grp Pos Sample ID 11 ___ ICAI_I05ASTTC1_ D i lution TEST POS Date / Time 1234567111222 789 0 12 0 12 ___ I C V J 0 5 A S T T C 2 _ 2/2/05 1 0B09 D 13 ___ MB__ 2/2/05 1 0822 0 14 ___L C S J 0 0 F S T L K 3 3 2/2/05 1 0844 0 15 16 17 1S 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 ___ L C D J 0 0 F S T L K 3 _ 3 2 3 3 8 6 4 ^ 1 ___ 233763_1_S___ 2 3 3 7 6 3 _ 2 J j__ 233763 3 S___ 233763j4_S___ 2 3 3 8 6 3 J S ___ 2 3 3 B 5 J S ___ 233856_2_S___ 233856_2_S_MS_I05ASTTC2_13 233856^2_S_MSD_I05ASTTC2_13 233856_3_S___ ___CCV_IQ5ASTTC2_ ___CCB__ 2/2/05 1 0852 0 2/2/05 1 1001 2/2/05 1 1018 2/2/05 1 1036 2/2/05 1 1055 2/2/05 1 1112 2/2/05 1 1142 2/2/05 1 1213 2/2/05 1 1232 2/2/05 1 1246 2/2/05 1 1252 2/2/05 1 1327 2/2/05 1 1347 0 2/2/05 1 1405 0 0 0 0 0 0 0 0 0 0 * 0 Page 1 37 *** QC Summary *** <V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140945 Status...... : RPT Grp Smp Sample ID Batch Date.. : 02/02/05 Batch Time.. : 1432 User Name... : els DC Code........ Calc Code..... Location code. TOCS TOCS 57222 Pos Test Result Known Original 12 13 ___ICV_I05ASTTC2_ ___ME__ 1 TOC 1 TOC 1833.30 -2.01 2000 14 LCS I00FSTLK3 5 1 TOC 4523.44 4780 -2.01 1 5 ___LCD_IQ0FSTLK3_3 1 14 233856_2_S_MS_I05A5TTC2_13 1 TOC 3899.B5 4780 5 TQCAV2 12991.40 2000 -2.01 6964.10 1 15 2 3 3 8 5 6 ^ 5 JI SD J 5A ST TC 2J 3 1 17 ___CCV_I05ASTTC2_ 1 18 ___CCB__ 5 TQCAV2 10659.17 2000 1 TOC 1826.30 2000 1 TDC -2.04 6964.10 Report Date: 2/2/05 15:01 Equipment code.; TC4 Import Code___ : Alternate QC Rea 92 F QC Res F 95 4523.44 82 101.0 12991.40 72.0 91 15 48 * Page 1 38 *** RAW TEST DATA *** <V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140945 Status....... : RPT Batch Date...: 02/02/05 Batch Time...: 1432 User Name...*: els SAMPLE: Grp Po b Sample id 11 ICAL I05ASTTC1 12 ICV I05ASTTC2 13 MB 14 LCS I0FSLK3 3 15 LCD I0FSTLK3 3 1 6 233864 1 S 1 7 233763 1 S 1 B 233763 2 S 1 9 233763 3 S 1 10 233763 4 S 1 11 233863 1 S 1 12 233S56 1 S 1 13 233856 2 S 1 14 233856 2 S MS I05ASTTC2 13 1 15 233356 2 S MSt> I05ASTTC2 13 1 16 233356 3 S 1 17 CCV I5STTC2 1 1B ___CCB__ QC Code........ : TOCS Calc Code...rT.: TOCS Location Codew ; 57222 Dilution TOC mg/Kg T0C2 mg/Kg Report Date: 2/2/05 15:00 Equipment Code.: TOC4 Import Code----: T0C3 mg/Kg T0C4 mg/Kg TOCAV2 mg/Kg 1333.30 -2.01 4523.44 3399.B5 764291.25 24298,71 30433.90 60356.90 23391.39 3112.42 10371,14 6546.30 12991.40 10659.17 B1.28 1326.30 -2.04 613491.60 34871.78 33284.38 35106.62 31986.34 3884.14 12343.51 7381.40 6755.87 688891.43 29585.24 31859.14 72731.76 30439.11 3498,28 11357.33 6964.10 12991.40 10659.17 6718.57 Page 1 39 *** RAW TEST DATA #*# tn > Total organic Carbon (Soils) Method Code.. rocs Batch Code... 140945 Status KPT Batch Date__ : 02/02/05 Batch Time...: 1432 User Marne___ : els SAMPLE : Grp Pos Sample ID 11 ICAL 1Q5ASTTC1 11 2 3 ICV I05ASTTC2 MB 14 LCS I00FSTLK3 3 15 LCD IQQFSTLK3 3 1 6 233864 1 S 1 7 233763 1 S 1 8 233763 2 S 1 9 233763 3 S 1 10 233763 4 S 1 11 233863 1 S IS1 12 233856 1 S 1 233B56 2 S 1 14 233B56 2 S MS ID5ASTTCZ 13 1 15 233856 2 S MSD I05ASTTC2 13 1 16 233856 3 S 1 17 CSV I05ASTTC2 1 18 CCB__ QC Code... ___ : TODS Calc Code. TOCS Location Code..: 57222 Di lut ion TOC mg/Kg T0C2 mg/Kg Report Date: 2/2/05 17:02 Equipment Code.: 0C4 Import Code..,,,,: TOC3 mg/Kg TQC4 mg/Kg T0CAV2 mg/Kg 1833.30 -2.01 4523.44 3899.85 764291.25 24298.71 30433.90 60356.90 28891.89 3112.42 10371.14 6546.80 12991.40 10659.17 6681.28 1826.30 -2.04 613491.60 34871.78 33284.38 85106.62 31986.34 3884.14 12343.51 7381.40 7771,10 688891.43 29585.24 31859.14 72731.76 30439.11 3498.28 11357.33 6964.10 12991.40 10659.17 7226.19 Page 1 40 *** RAW TEST DATA *** <V2 ) Total Organic carbon (Soils) Method Code..: TOCS Batch Code...: 140945 Status...... : RPT Batch Date...: 02/02/05 Batch Time...: 1432 User Name---- : els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV I05ASTTC2 13 MB 14 LCS I00FSTLK3 3 15 LCD J0QFSTLK3 3 1 6 233B4 1 S 1 7 233763 1 S 1 a 233763 2 S 1 9 233763 3 S 1 10 233763 4 S 1 11 233863 1 S 1 12 233856 1 S 1 13 233856 2 S 1 14 233856 2 S MS 105ASTTC2 13 1 15 233856 2 S MSD I5ASTTC2 13 1 16 233856 3 S 1 17 CCV I05ASTTC2 1 ie CCS QC Code..... , TOCS Calc Code...... : TOCS Location Code..: 57222 Dilution TCAV3 mg/Kg TOCAV4 mg/ICg Report Date: 2/2/05 17:02 Equipment Code.: TUC4 Import Code____ : TOCR1 ug TOCR2 ug TOCR3 ug 91.6652 -0.3218 124.3945 121.6752 305.7165 102.0546 146,0827 295.7488 132.9027 70.6520 189.7919 138.1375 218.2556 207.8538 136.9663 91.3149 -0.3265 306.7458 170.8717 186,3925 382.9798 179.1235 92.0541 235.7611 173.4628 153.0906 Page 2 41 *** RAU TEST DATA *#* (V2 ) Total Organic Carbon (Soils) Method Code.. : TOCS Batch Code,.. : 14 0 9 Status.,.,,r.. : RPT Batch Date.. : 02/02/05 Batch Time.. : 1432 User Name... : cls SAMPLE: Grp Pos Sample ID 11 ICAL IQ5ASTTC1 12 ICV I05ASTTC2 13 MB 14 LCS I0DFSLK3 3 15 LCD I0QFSTLK3 3 1 6 233864 1 S 1 7 233763 1 S 1 8 233763 2 S 1 9 233763 3 S 1 10 233763 4 S 1 11 233863 1 S 1 12 233856 1 S 1 13 233856 2 S 1 14 233856 2 S MS 105ASTTC2 13 1 15 233856 2 S MSD I05ASTTC2 13 1 16 233856 3 S 1 17 CCV ID5ASTC2 1 18 CCB QC Code....... : TOCS CaLc Code,,,,,., ! TOCS Location Code.,: 57222 Dilution TOCR4 g WT1 9 Report Date: 2/2/05 17:02 Equipment Code.: T0C4 Import Code....: WT2 UT3 WT4 g g9 0.05 0.16 0.0275 0.0312 0.0004 0.0042 0.0048 0.0049 0.0046 0.0227 0.0183 0.0211 0.0168 0.0195 0.0205 0.05 0,16 0.0005 0.0049 0.0056 0.0045 0.0056 0,0237 0.0191 0.0235 0.0197 Page 3 42 *** RAW TEST DATA *** CV2 ) Total Organic Carbon (Soils) Method Code..: tnrs Status___ RPT Batch Date__ : D?/fl?/05 finteh Timo__; 13? User Name___ : els SAMPLE: Grp PoS SampLe ID 11 1CAL I05ASTTC1 12 ]CV I05ASTTC2 13 MB 14 LCS I00FSLK3 3 15 LCD J0FSTLK3 3 1 6 233364 1 $ 1 7 233763 1 S 1 8 233763 2 S 1 9 233763 3 S 1 10 233763 4 S 1 11 233863 1 S 1 12 233856 1 S 1 13 233856 2 S 1 14 233856 2 S MS I5ASTTCZ 13 1 15 233856 2 S MSD I05ASTTC2 13 1 16 233856 3 S 1 17 CCV I05STTC2 1 IS CCB QC Cade.... ___ : TOCS On lo rode ___ : TnCR Location Code..: 57222 Di lut ion DLFAC N/A TCS mg/Kg 3.2000 1.0000 5.8182 5.1282 355.5556 35.1648 30.7692 34.0426 31.3725 6.8966 8.5561 7.1749 9.5238 8.2051 7.9602 3.2000 1.0000 Report Date; 2/2/05 17:02 Equipment Cade.; TQC4 Import Code.... : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg Page 4 43 Calibration Report Print Date/Time: 2005/02/02 7:13:17 Cal. Curve ID: SOILCURVE Created: 01/17/2005 11:33 Calibration Factor (m): 8,538e+G4 Y Intercept (b): 436425 r-squared: 0.99800 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -4530 0.000 -5,165 No Sample Det 01/17/2005 09:53 10ugramC 1085240 10.000 7.599 01/17/2005 10:15 20 ugram C 1870210 20.000 16.794 01/17/2005 10:26 40 ugram C 3806480 40.000 39,473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/2005 10:45 120 ugram C 11114689 120.000 125.072 01/17/200510:58 200 ugram C 18428840 200.000 210.740 01/17/200511:07 300 ugram C 26478564 300,000 305.025 01/17/200511:15 400 ugram C 33682344 400.000 389.401 01/17/2005 11:32 Multiple Analysis Report Print Date/Time: 2005/02/02 14:17:00 Sample ID Result Std Dev. RSD t Mode ALT ICV 91.6652 TC ICB-MB -0.3218 TC LCS 124.3945 TC LCD........................ ......... 121.6752.............. ...TC ., 223864-1 1242.9965 TC 223864-1 529.5431 TC 223864-1................ ............ 8.4862............. . ...TC . 223864-1 12.5518 TC 223864-1 575.9740 TC 223864-1................ ............ 305.7164... ........... TC 223864-1 306.7458 TC 223763-1 36.5269 TC 223763-1................ ............ 102.0546... ........... TC 223763-1 170.8717 TC 223763-2 146,0827 TC 223763-2................ ............ 186,3925... ........... TC 223763-3 295.7488 TC 223763-3 382.9798 TC 223763-4................ ............ 132.9027... ........... TC 223763-4 179.1235 TC 223863-1 28.0338 TC 223863-1................ ............ 70.6520... ...........TC , 223863-1 92.0541 TC 223856-1 451.9823 TC 223856-1................ ............ 189.7919... ........... TC 223856-1 235.7611 TC 223856-2 138.1375 TC 223856-2................ ............ 173.4628.,, ........... TO 223856-2ms 218.2556 TC 223856-2msd 207.8538 TC 223856-3................ ............ 136.9663... ........... TC 223856-3 153.0906 TC CCV 91.3149 TC CCB......................... ......... -0,3265............... ...TC .. Detailed Analysis Report Print Date/Time: 2005/02/02 14:17:07 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02020803 Timestamp. 02/02/2005 08:09 Sample Type: Cal. Verification-- - Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 91.6652 91.6652 8262540 0.236 1.236 286 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02020819 / Timestamp: 02/02/2005 08:22 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3218 -0.3218 -1712 0.498 0.489 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02020839 Timestamp: 0 2 /0 2 /2 I Sample Type: Sample 6 08:44 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 124.3945 124.3945 10646220 0.958 1.957 269 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02020848 Timestamp: 02/02/ Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 121,6752 121.6752 10414052 2.708 3.708 234 Sample ID: 223864-^ Method: boat Cal. Curve: SOILCUR Operator ID: CAROL Mode: TC Filename: 02020901 Timestamp: 02/02/2005 09:12 Sample Type: Sample Rep # ppm C R^w Data Beginning Ending Integration Baseline Baseline Time .6. / 1 179.1235 179.1235 15318827 1.535 2.535 281 Sample ID: 22\ Mode: TC Method: boat Cal. Curve: SOIL&URVJy y- r Operator ID: CARO(- TM A Filename: 02021132 , Timestamp: 02/02/2005 11:36 Sample Type: Sample if R e p # ppm C u ^ C Raw Data Beginning Ending Integration BaselinX Baseline Time 1 28.0338 28.033$ 2 4 1 9 2 1 4 \ 1.528 2.528 211 Sample ID: 223863-1 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021138 Timestamp: 02/02/200^ 11:42 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline \ i m e 1 70.6520 70.6620 6057833 1,963 2 $ 6 2 245 Sample ID: 223863-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021148 Timestamp: 02/02X^005 11:53 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 92,0541 92.0541 7885083 1.576 2.574 301 Sample ID: 223856-1 Method: boat Cal. Curve: SOILCURV Operator ID: CAROL Mode: TC q Filename: 02021159 Timestamp: 02/02/2005 12:06 Sample Type: Sample R e p # ppm C ug C Data Beginning Ending Integration ^line Baseline Time 1 451.9823 451.9823 38614740 1.653 2.650 358 Sample ID; 223856-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021207 Timestamp: 02/02/2005/12:13 Sample Type: Sample ( R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 189.7919 189.7919 16229663 2.240 3.237 271 Sample ID: 223856^1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021219 Timestamp: 02/02/2005 12:24 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 235.7611 235.7611 20154384 1.853 2.853 287 Sample ID: 223856-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021227 X Timestamp: 02/02/200512:32 Sample Type: Sample } Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 138.1375 138.1375 11819558 2.477 3.475 250 Sample ID: 223856-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021233 Timestamp: 02/02/2005 12:38 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 173.4628 173.4628 14835529 2.171 3.167 269 Sample ID: 223856-2ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021240 Timestamp: 02/02/200 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 218.2556 218.2556 18659808 3.094 4.091 310 Sample ID: 223856-2msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021247 Timestamp: 02/02/2' Sample Type: Sample \ is 12:52 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 207.8538 207.8538 17771736 2.886 3.884 289 Sample ID; 223856-3 Method; boat Cal. Curve: SOILCURVE Operator ID; CAROL Mode: TO Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 136.9663 136.9663 11719563 1.853 2.852 268 Sample ID: 223856-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02021328 Timestamp; 02/02/2005 13:34 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 153.0906 153.0906 13096208 2.315 3,314 262 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 91.3149 91.3149 8232637 1,575 2.574 319 Sample ID; CCB Mode: TC Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL -- Filename; 02021359 f Timestamp: 02/02/2005 14:05 VSample Type: Sample y Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3265 -0.3265 -2108 1.656 1.635 120 Last Message: No Sample Detected irk* RUN LOG *** <V2 ) 2/11/05 11IS Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...; 141632 Status..... RVWD Batch Date...: 02/10/05 Batch Time...: 929 User Name....... : els QC Code......... : TOCS Calc Code______: TOCS Location Code..: 57222 Equipment Code.: T O W Import Code____: TEST CODE TTTTTTTTTTTTT 0OOOO00CCC III CCCCCccSssCCC 234AAA 2ASss VVV V 2A 234 2 2 SAMPLE: Grp Pds Sample ID D i lutioh TEST POS Date / Time 1234567 111222 7890 12 11 ___ ICAL_I05AS7TC2_ 0 12 ___ I C V J 0 5 A S T T C 1 _ 2/1/05 1 0811 0 13 ____MB__ 2/1/05 1 0B15 0 14 ___ LCS_I00FSTLK3_3 2/1/05 1 0848 0 15 LCD I0QFSTLK5 3 2/1/05 1 0856 0 16 233856_4_S___ 2/1/05 1 0915 0 17 13 233S56_4i_S_MS_I05ASTTC1_6 233856_4_S_MD_I05ASTTC1_6 2/1/05 1 0948 2/1/05 1 0957 0 * 19 233S56_5_S__ _ 2/1/05 1 1019 0 1 10 1 11 233856_6^S___ 23385 6_7_S___ 2/1/05 1 1034 2/1/05 1 1053 0 0 1 12 233856_8_S___ 2/1/05 1 1140 0 1 13 233856 9 S 2/1/05 1 1212 0 1 14 233856_10_S__ 2/1/05 1 1225 0 1 15 2 3 3 3 5 6 1 1 S ___ 2/1/05 1 1242 0 1 16 ___CCV_l05ASTTCl_ 2/1/05 1 1258 0 1 17 ___CCB__ 2/1/05 1 1302 0 1 IB 233856_12_S___ 2/1/05 1 1338 0 1 19 23385fi_13_S___ 2/1/05 1 1400 0 1 20 233856_14_S___ 2/1/05 1 1420 0 1 21 233856^15_S___ 2/1/05 1 1433 0 1 22 1 23 233856 16 S 233B56_17_S___ 2/1/05 1 1448 2/1/05 1 1503 0 0 1 24 1 25 1 26 1 27 1 2B 233856_l8r_Si__ 2 3 3 8 5 6 J 9 _ S ___ 233856 20 S ___ C C V J 0 5 A S T T C 1 _ ___ CCB__ 2/1/05 1 1520 2/1/05 1 1532 2/1/05 1 1548 2/1/05 1 1608 0 2/1/05 1 1626 0 0 0 0 Page 1 -- 43 *** QC summary ft** <V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 141632 Status..... RVWD Batch Date...: 02/10/05 Batch Time...: 929 User Maine....: d s QC Code........ : TOCS Calc Code......: TOCS Locati oh Code..: 57222 Grp Snip Sample ID 12 ICV I5ASTTC1 Pos Test Result 1 TOC 1988.72 Known 2000 Original 1 3 ___MB__ 1 TOC "3.94 1 4 ___LCS_IQFSTLK3_3 1 TOC 4488.08 4780 -3.94 1 5 ___LCDJ00FSTLl3_3 1 TOC 4757.13 4780 -3.94 1 7 233856_4_SJ1SJ05ASTCl_6 5 TOCAV2 14952.66 2000 8038.07 1 a 233856^S_MSD_l05ASTTClm6 5 T0CAV2 12635.86 2000 8038.07 1 16 ___CCV_I05ASTTCl_ 1 TOC 1986.26 2000 1 17 .__ CCB__ 1 27 ___CCVm I05ASTTCl_ 1 28 __ CCB__ 1 TOC 1 TOC 1 TOC "3.49 2135.00 "2.06 2000 Report Date; 2/11/05 11:18 Equipment Code.: OC4 Import Code____: Alternate QC Res 99 F QC Res F 94 44B8.08 100 85 14952.66 , 127 99 6 40 ft 107 Page 1 SO *** RAW TEST DATA *** <V2 ) Total organic Carbon (Soi'Lk ) Method Code..; TOCS Batch Code...: 141632 Status...... : RVWD Batch Date...: 02/10/05 Botch Time...: 929 User Name :els SAMPIE: Grp Pos Sample ID 11 12 13 14 15 16 17 18 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 ICAL I5ASTTC2 ICV I05ASTTC1 MB ICS IQFSTL13 3 LCD I00FSTLK3 3 233856 4 S 233856 4 S MS I05ASTTC1 6 233356 4 S MSD I05ASTTC1 6 233856 5 S 233856 6 S 233656 7 S 233856 8 S 233856 9 S 233856 10 S 233856 11 S CCV I05ASTTC1 CCB 233B56 12 S 233B56 13 S 233856 14 S 233856 15 S 233356 16 S 233856 17 S 233856 18 S 233856 19 S 233856 20 S CCV I05ASTTC1 CCB QC Code*.......: TOCS Calc Code..... i TOCS location Code..: 57222 Dilution TOC mg/Kg TC2 mg/Kg Report Date: 2/11/05 11:18 Equipment Code.: T0C4 Import Code____: T0C3 mg/Kg T0C4 mg/Kg TOCAV2 mS/Kg 1988.72 -3.94 4488.08 4757.13 8767.45 14952.66 12635.86 16232.89 9203.98 22449.42 11835.58 13373.94 10569.15 3817.46 1986.26 -3.49 4114.02 21617.58 14111.12 9680.75 9891.16 8684.49 10290.76 10533.99 1269B.43 2135.00 -2.06 7308.69 11978.36 8384.47 16555.99 8793.94 19803.87 11666.94 4572.06 4166.05 17732.92 858B.57 10456.57 8355.07 8560.38 11949.39 8372.23 15814.57 3038.07 14952.66 12635.66 14105.62 6794.22 19502.71 10314.76 16563.90 11113.05 4194.76 4140.03 19675.25 11349.85 10068.66 9123.11 8622.43 11120.0B 9453.11 14256.50 Page 1 51 *** RAU TEST DATA *** <V2 ) Total Organic Carbon (Soils) Method Code TOCS Batch Coda.. r: 141632 Status..... RVWD Batch Date,. 02/10/05 Batch Time.. 929 User Name... : cls SAMPLE: Grp Pos Sample ID 11 ICAL 105ASTTC2 12 ICV I05ASTC1 13 MB 14 LCS IQ0FSTLK3 3 15 LCD OOFSTLK3 3 1 6 233856 4 S 1 7 233856 4 S MS I05ASTTC1 6 1 8 233856 4 S MSD I05ASTTC1 6 1 9 233856 5 S 1 10 233656 6 S 1 11 233856 7 S 1 12 233856 8 S 1 13 233856 9 S 1 14 233856 10 S 1 15 233856 11 S 1 16 CCV I05ASTTC1 1 17 CCB 1 IS 233856 12 S 1 19 233856 13 S 1 20 233856 14 S 1 21 233656 15 s 1 22 233856 16 S 1 23 233856 17 S 1 24 233856 18 S 1 25 233856 19 S 1 26 233856 20 S 1 27 CCV I05ASTTC1 1 28 CCB QC Code....... : TOCS CaLe Code.r.+T TOCS Location Code.,; 57222 Dilution T0CAV3 mg/Kg T0CAV4 mg/Kg Report Date: 2/11/05 11:18 Equipment Code,; TOC4 Import Code___ : TQCR1 ug TOCR2 ug OCR3 ug 99.4359 "0.6307 115.3437 136.5296 191.1304 275.1290 257.7715 342.5139 181.3185 361.4356 162.1475 112.3411 130.0005 47.7183 99.3128 -0.5585 70.7612 244,2786 114.3001 145.2113 144.4110 148.5048 166.7103 141.1555 171.4288 106.7498 -0.3302 144.7120 158.1143 180.2660 216.8835 135.4266 239.6268 168.0040 70.8669 85.4040 198.60B7 102.2040 174.6247 106.9449 162.6473 187.6055 107.1645 204.0079 Page 2 52 #** RAW TEST DATA *** <V2 ) Total Organic Carbon (Soils) Method Code .: TOCS Batch Code, 141632 Status.... Batch Date. ,; 02/10/05 Batch Time. .: 929 User Name.. SAMPLE: Grp Pos Sample ID 11 ICAL IQ5ASTTC2 12 ICV 105ASTTC1 13 MB 14 CCS I00FSTLK3 3 15 LCD IDDF5TLK3 3 1 6 233856 4 S 1 7 233856 4 S MS I05ASTTC1 6 1 8 233856 4 S MSD I05ASTTC1 6 1 9 233856 5 S 1 10 233856 6 S 1 11 233856 7 S 1 12 233856 8 S 1 13 233856 9 S 1 14 233856 10 S 1 15 233856 11 S 1 16 CCV 105ASTTC1 1 17 CCB 1 18 233856 12 S 1 19 233856 13 S 1 20 233856 14 S 1 21 233856 15 S 1 22 233856 16 S 1 23 233856 17 S 1 24 233856 18 S 1 25 233856 19 S 1 26 233856 20 S 1 27 CCV I05ASTTC1 1 23 CCB QC Code....... : TOCS Calc Code___ _ ; TOCS Location Code.. ; 57222 Dilution TQCR4 ug UT1 g Report Date: 2/11/05 Equipment Code.: TOC4 import Code.,,.: WT2 WT3 tfT4 g 39 0.05 0,16 0.0257 0.0287 0.0218 0.0184 0.0204 0.0211 0.0197 0.0161 0.0137 0.0084 0.0123 0.0125 0.05 0.16 0.0172 0.0113 0.0081 0.0150 0,0146 0.0171 0.0162 0.0134 0.0135 0.05 0.16 0.0198 0.0132 0.0215 0.0131 0.0154 0.0121 0.0144 0.0155 0.0205 0,0112 0,0119 0.0167 0.0128 0.0190 0.0157 0.0128 0.0129 Page 3 53 *** RAW TEST DATA *** Total Organic Carbon (Sai la) Method Code . TOCS Batch code. r,: 141632 Status.... Batch Date.. .: 02/10/05 Batch Time.. 929 User Marne... SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC2 12 ICV I05ASTTC1 13 MB 14 LCS I00FSTLK3 3 15 LCD IQ0FSTLK3 3 1 6 233856 4 S 1 7 233656 4 S MS 05ASTTC1 6 1 a 233856 4 s MSD I05A5TTC1 6 1 9 233856 5 S 1 10 233856 6 S 1 n 233856 7 S 1 12 233856 8 S 1 13 233356 9 S 1 14 233856 10 S 1 15 233856 11 S 1 16 CCV I05ASTTC1 1 17 CCS 1 IS 233856 12 S 1 19 233856 13 S 1 20 233856 14 S 1 21 233856 15 S 1 22 233856 16 S 1 23 233856 17 S 1 24 233856 18 S 1 25 233856 19 S 1 26 233856 20 S 1 27 CCV I05AstTCl 1 28 CCB OC Code....... ; TOCS Calc Code..... : TOCS Location Code..: 57222 Dilution DLFAC N/A TCS mg/Kg 3.2000 1.0000 6.2257 5.5749 7.6923 S.6957 7.8431 9.3294 7.7670 10.9589 10.9966 15.6098 11.9850 11.4286 3.2000 1.0000 8.4881 14.2222 16.0000 10.0946 11.6788 8.8643 10.0313 12.2137 12.1212 3.2000 1.0000 (V2 ) Report Date: 2/11/05 11:18 Equipment Code,: TQC4 Import Code--- : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg Page 4 54 Calibration Report Print Date/Time: 2005/02/03 7:28:12 Cal. Curve ID: SOILCURVE Created: 01/17/2005 11:33 Calibration Factor <m): 8.538e+04 Y Intercept (b): 436425 r-squarad: 0,99800 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -4530 0,000 5.165 No Sample Det 01/17/2005 09:53 10ugramC 1085240 10.000 7.599 01/17/2005 10:15 20 ugram C 1870210 20.000 16.794 01/17/2005 10:26 40 ugram C 3806480 40.000 39.473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/2005 10:45 120 ugram C 11114689 120.000 125.072 01/17/2005 10:58 200 ugram C 18428840 200.000 210 J 4 0 01/17/2005 11:07 300 ugram C 26478564 300.000 305.025 01/17/2005 11:15 400 ugram C 33682344 400.000 389.401 01/17/2005 11:32 Multiple Analysis Report Print Date/TIme: 2005/02/07 7:14:44 Sample ID Result Std. Dev. RSD Mode ALT ICV 99.4359 TC ICB-MB -0.6307 TC LCS 115.3437 TC LCD......................... .........136.5296.............. .,,TC .. 233856-4 191.1304 TC 233856-4 144.7120 TC 2 3 3 8 5 6 -4 m s ........... ................275.1290... ........... TC 233856-4msd 257.7715 TC 233856-5 342.5139 TO 233856-5................ ............ 158.1143... ........... TC 233856-6 181.3185 TC 233856-6 180.2660 TC 233856-7................ ............ 361 4356.,. ........... TC 233856-7 216.8835 TC 233856-8 162.1475 TC 233856-8................ ............ 135.4266... ........... TC 233856-9 688.3476 TC 233856-9 112.3411 TC 233856 9 ................ ............ 239.6268... ........... TC 233856-10 130.0005 TC 233856-10 168.0040 TC 233856-11.......... ............. 47.7183.,, ........... TC 233856-11 70.8669 TC CCV 99.3128 TC CCB........................ ......... -0.5585............... ...TC .. 233856-12 70.7612 TC 233856-12 85.4040 TC 233856-13.............. ............. 414.1832... ........... TC 233856-13 244.2786 TC 233856-13 198.6087 TC 233856-14.............. ............. 114.3001... ........... TC 233856-14 102.2040 TC 233856-15 145.2114 TC 233856-15.............. ............. 174.6247... ........... TC 233856-16 144.4110 TC 233856-16 106.9449 TC 233856-17.............. ............. 148.5048... ........... TC 233856-17 162.6473 TC 233856-18 166.7103 TC 233856-18.............. ............. 187,6055... ........... TC 233856-19 141.1555 TC 233856-19 107.1645 TC 233856-20.............. ............. 171.4288... ........... TC 233856-20 204.0079 TC CCV 106.7498 TC CCB........................ .........-0.3302............... ...TC .. Detailed Analysis Report Print Date/Time: 2005/02/07 7:15:00 Sample ID: ICV Method: boat Cal. Curve: SOiLCURVE Operator ID: CAROL Mode: TC Filename: 02030804 Timestamp: 02/03/2095 08:11 Sample Type: Cal. Verification^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 99.4359 99.4359 8925977 1.690 2.688 332 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02030812 f Timestamp: 02/03/2005 08:15 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.6307 -0.6307 -28078 2.178 1.864 120 :L=:a^s^t _M_e_s;;s_a=g!=eE:=_N=o==S=am==p=le==D=e=te=c=t=ed_===_:^^_=^^__;====_==_===========_^_;;_^^^;;==, Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02030843 Timestamp: 02/03/2005 08:48 Sample Type: Sample / y Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 116.3437 115.3437 9873485 2.077 3.073 268 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC y --\ Filename: 02030850 Timestamp: 02/03/200fe 08:5^ Sample Type: Sample R e p # ppm C ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 136.5296 136.5296 11682278 2.041 3.038 324 Sample ID: 233856-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02030909 X^ Timestamp: 02/03/2005 09:15 Sample Type: Sample y R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time I 57 1 191.1304 191.1304 16343937 1741 2.737 323 Sample ID: 233856-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02030925 Timestamp: 02/03/2005 09:31 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 144.7120 1447120 12380864 1.846 2.844 289 ======" -- TM^;=;=;~~================ = = = = = = = = =~==== Sample ID: 233856-4ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02030941 f Timestamp: 02/03/20009:48 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 275.1290 275,1290 23515504 3.744 4 741 299 Sample ID: 233856-4msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02030951 Timestamp: 02/03/2' Sample Type: Sample / 5 09:57 R e p # ppm C u g C Raw Data Beginning Ending integration Baseline Baseline Time 1 257,7715 2577715 22033568 4.892 5.885 257 Sample ID: 233856-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031012 Timestamp: 02/03/; Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 342,5139 342.5139 29268632 2.018 3.016 361 Sample ID: 233856-5 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031022 Timestamp: 02/03/2005 10:27 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 158.1143 158.1143 13525114 2.597 3.597 272 Sample ID: 233856-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TO Filename: 02031028 Timestamp: 02/03/; Sample Type: Sample >05 10:34 R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 181.3185 181,3185 15506226 2,470 3,467 304 Sample ID: 233856-6 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031037 Timestamp: 02/03/20 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integratio Baseline Baseline Time 1 180.2660 180.2660 15416367 2.194 3.192 291 Sample ID: 233856-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031046 Timestamp: 02/03/20 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 361.4356 361.4356 30884120 2,200 3.199 367 Sample ID: 233856-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031054 Timestamp: 02/03/2 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 216.8835 216.8835 18542666 2.717 3.716 284 Sample ID: 233856-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC .-- ^ Filename: 02031134 / Timestamp: 02/03/2005 11:4G Sample Type: Sample ( f Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 162.1475 162.1475 13869463 2.061 3,060 314 Sample ID: 233856-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031141 Timestamp: 02/03/2005 11:46 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 135.4266 135.4266 11588102 2.527 3.526 267 Sample ID: 23385 Method: boat (>\ V Mode: TC \jv\ Filename: 02031157 Cal. Curve: SOILCURVE Timestamp: 02/03/2005 12:06 Operator ID: CAROL Rep # Sample ppm ug C : Sample V R&w Data Beginning Ending Integration Baseline Baseline Time 1 688.3476 688.3476 944 2.181 3.179 472 Sample ID: 233856-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031207 Timestamp: 02/03/2005 12:12 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 112.3411 112.3411 9617131 2.959 3.954 263 Sample ID: 233856^9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031213 Timestamp: 02/03/2005 12:17 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Baseline Baseline Time 1 239.6268 239.6268 20484424 15.834 16.816 Integration 207 Sample ID: 233856-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031220 Timestamp: 02/03/20lJ512:2Sy/ Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 130.0005 130.0005 11124842 4.735 5.733 230 is; Sample ID: 233856-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031226 Timestamp: 02/03/2005 12:31 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 168.0040 168,0040 14369471 4,564 5.558 241 Sample ID: 233856-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ Filename: 02031238 // Timestamp: 02/03/2005 12:42 Sample Type: Sample ( j Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 47.7183 47.7183 4099821 2.423 3.423 228 Sample ID: 233856-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031246 Timestamp: 02/03/2005 12:51 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 70.8669 70.8669 6076178 2.638 3.635 265 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode; TC Filename: 02031252 // Timestamp: G2/03/206 12:50 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 99.3128 99.3128 8915472 2.365 3.363 314 Sample ID: CCB Method: boat C a l Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031259 Timestamp: 02/03/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integi Baseline Baseline Time 1 -0.5585 -0.5585 -21922 2.806 2,519 120 Last Message: No Sample Detected 61 Sample ID: 233856-12 Method: boat CaL Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031331 Timestamp: 02/03/200j Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 707612 707612 6067160 2.150 3.148 260 Sample ID: 233856-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031340 Timestamp: 02/03/2005 13:45 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 85.4040 85.4040 7317319 2,449 3.449 261 Sample ID: 2338564 3 Method: boat CaL Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031347 Timestamp: 02/03/2005 13:54 Sample Type: Sample Rep # ppm C Data Beginning Ending Integration iseline Baseline Time 1 414,1832 414.1832 3^387556 2,421 3.418 346 Sample ID: 233856-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename. 02031354 f Timestamp: 02/03/2005 14:01 Sample Type: Sample j R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 244.2786 244.2786 20881578 2.958 3.958 284 Sample ID: 233856-13 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031405 Timestamp: 02/03/2005 14:12 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 198.6087 198.6087 16982416 2.358 3.358 322 H" 25 5 TM 3 r ^ ^ 2 5 62 Sample ID: 233856-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031415 Timestamp: 02/03/200 Sample Type: Sample a 1 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 114.3001 114.3001 9784381 3.363 4.362 239 Sample ID: 233856-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031421 Timestamp: 02/03/2005 14:26 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 102.2040 102.2040 8751652 2.691 3.688 258 Sample ID: 233856-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031428 / Timestamp: 02/03/200914:33 Sample Type: Sample \ / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 145.2114 145.2114 12423500 2.621 3.618 267 Sample ID: 233856-15 Mode: TC Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Filename: 02031435 Timestamp: 02/03/200514:40 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 174.6247 174.6247 14934727 2.418 3.416 290 Sample ID: 233856-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031442 yi f Timestamp: 02/03/2005 14:48 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 144.4110 144.4110 12355171 2.466 3.465 275 Sample ID: 233856-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031451 Timestamp: 02/03/2005 14:56 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 106.9449 106.9449 9156422 2.314 3.312 264 Sample ID: 233856-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031457 ) Timestamp: 02/03/2005 15:03 Sample Type: Sample / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 148.5048 148.5048 12704685 2.653 3.653 278 Sample ID: 233856-17 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031507 Timestamp: 02/03/2005 15:13 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 162.6473 162.6473 13912134 2.304 3.303 288 Sample ID: 233856-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031515 Timestamp: 02/03/2Q Sample Type: Sample 15:20 R ep # p p m C u g C Raw Data Beginning Ending Baseline Baseline Time 1 166.7103 166.7103 14259021 2.615 3.614 270 ation Sample ID: 233856-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031521 Timestamp: 02/03/2005 15:27 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 187,6055 187.6055 16042990 2.764 3.761 279 Sample ID: 233856-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TO Filename: 02031527 Timestamp: 02/03/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 141.1555 141.1555 12077222 2.871 3.868 259 Sample ID: 233856-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031537 Timestamp: 02/03/2005 15:42 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 107.1645 107.1645 9175169 2.327 3.325 272 Sample ID; 233856-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031543 Timestamp: 02/03/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 171.4288 171.4288 14661871 2.765 3.762 271 Sample ID: 233856-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031554 Timestamp: 02/03/2005 16:00 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 204.0079 204.0079 17443384 2.271 3.270 292 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02031602 Timestamp: 02/03/200 Sample Type: Cal. Verifk 16:08 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 106.7498 106.7498 9550424 2.290 3.289 281 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename; 02031623 Timestamp: 02/03/200 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3302 -0.3302 -2423 2.118 2.092 120 Last Message: No Sample Detected ^?^:================^x^^?=^=:=. STL Chicago 134 Page No.:-- ^ J TOC in Soils Book No.: __3 3 ^ 7 _ Method: Lloyd Kahn Instrument: Phoenix 8000 (TQC4) Calculations: TOC (mg/kg) = ug C / grams sample LabNet Batch: / V / Date of Standard Curve; /n Book # r3 7 V ' 7 Page# / I f ______ MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS. MSD Rec. = robserved mo/kq - avo. sample result fma/kg^l x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) l & T T / K r TCI / Stock II (ICV/CCV) f~'OlH 'A<rT7T!. LCS Source ID f f O P w d LCS True Value V 7 / Acceptance Range S 3 - Sample ID: Sample Weight (g) ug C .oV 9f;f>2f Commenta: L ?5 w ?~ Q2b S? < A Y I -y O, /0 O .o ifl OMOl ' .02 /< a ot7 A . fi. C2oy n . o a it n ~C. C3o7 //r. ?VT7 /J A /?/. of V So7 N i.7/ 2T7 / 7 7 C i a a . a f 'i m n ) <&% 9 C7 7 7 / r - l'd fa .tf if,%! /2?% ^7-2 C/% / I --T /3 1 / r y / / / ?i -C , , / ? y . <? ^ / r - /? /. ^ i-r , "2.0Co -7 "7 ... 9 - , Of i f o T^H] n - / "3 7 <^. y / r Y y /. Y W oa . ro n / 2 , /Y ? 2 /? 7 Yatf -A - . / 7=3- - 5... CP , <V >. -4 o o /y / ...j - ( 6 r ; . iJ /O <7. <5/ y y ri f r , > 7 7 / / y 7 v // w .c r f3&. #7^' //f _ \ / /- / / -Q '7 /a A ty7, Prep Anaiyst^ Analyst: ^-^--- 7 r / Reviewed by:_ V*- --f- Date: -- -/ ?]'Q0 Date: rP - / 3 / o ~ Date: `v /i l/A CHI-22-12-006/8-05/01 STL Chicago TOC in Soils Page No.:. 13S Book No.: ~*%7tn Method; Lloyd Kahn Instrument: Phoenix 8000 (TOC4) LabNet Batch: U. / C?3 Calculation*: TOC (mg/kg) - ug C / grams sample Date of Standard Curve: / / Book # _ ^ 7 ^ ^Paoe# ^( MS, MSD Known Cone, (m g/kg) = 100 ug C / g ram s sam ple MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rea = fobserved ma/ka - avo, sample result (mo/koil x 100 known concentration in mg/kg ^ Standard Traceability: (Note: Working S tandardise re^d-daH^rfrornthe noted Stock Solutions,) Stock I (Curve)___________________ _ S t T " (ic v /C C V )____________________ LCS Source ID LCS True Value Acceptance Range Sample ID: Sample Weight (g) ug C Comments; a .rm -/l o , <- " / fU f o 9b 1 0(Pi/ 0 -/2 _ . O. OK . i f , O /7Z. O' O p s - 9 9 7/%- vo ? < r/z 9(9Ort ! ; = ^ -- - o . fi- I n Li ------- - cfi9 Lrt 3 .9 '-_______ i -V 3 n o //7 TNw 2-7 r /____ ~ n ! 1! ~ :/ H i I - /r 1 --/& O, Y / ' t O' O O p -/ O' o / (f t.CJ / r t # o, o / c y O . OlU 6 / ^ ir, < ^ 7 /'/ Ys 3<JCs/ /T2. /Y : 2 // 5 / / Y Y , <rrf<? 1 - ~L ! -/ n - !7 n , / '/ ? i v . O(9 f Cb , O /C ffr /rt. fr y f Y9<7 / G l' - f(n 9 Y (P'OtVt- /C C, i f ay _____ a , / k 'I - / ? 'rs.o-f'b V O . Of /fZrt'r 19(, / < iv i, rtK / - 20 Crtn i % " ^ - M b r? ' g / 3 - 9 C F ,^/y / Prep Analyst^ f i t . 92F? 2J0KO7 7 Date: / Analyst: Date:. Reviewed by:. n . 4 -U IT Date: J / u /i CHf*22-l2-O9S/B-05/I^JQ STL Chicago TOC in Soils Page No.:. Book No.: 7 13_376 ^, Method: Lioyd Kahn Instrument Phoenix 80QQ (TOC4) LabNet Batch: / * / / < ? _ Calculation: Date of Standard Curve:______________ ; TOC (mg/kg) * ug C / grama sample Book # _________ Page #__________ _ MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Ree. = Observed mo/ka ava, sample result fmg/koil x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standjantare prepared daily from the noted Stock Solutions.) Stock I (Curve) -^ Stoek II (ICV/CCV) LCS Source ID CSTrue Value Acceptance Range, Sample IDT ecu Sample Weight (g) , u g c .<?r /X /X "' . X 5 y r i \ X X X X N - X X. X z \ ............... \ x X X Comments: Prep Analyst:__ Analyst: Reviewed by: -- S L x Z _-c-- . Z chk*. . 1 \ \ IZ x z Date: <u Iff) Date: - X ? / X 7 r~ Date: 3 IIIIti CHI-22-12-095/B-S/01