Document qmYyp7Z2D6ZvorqnNoK5B2jd5

Chemical Acenaphthene Acenaphthene Acenaphthylene Acenaphthylene Acetaldehyde Acetaldehyde Acetaldehyde Acetaldehyde Acetic acid Acetic anhydride Ac etoin Acetone Acetone Acetone Acetone Acetone cyanohydrin Acetonitrile Acetylene dichloride Acetylene tetrabromide Acetylene tetrachloride Acids, inorganic ACN Ac rolein Ac rolein Ac rylo nitrile Aerobic bacteria Alachlor Alachlor Alachlor Alachlor Aldehydes, screening Aldicarb Aldrin Alkaline dusts Allyl alcohol Allyl alcohol Allyl chloride 3/15/2003 METHOD FINDER (Key on page MF-34] Meth No. Method Name 5506 5515 5506 5515 201 8 2538 2539 3507 1603 3506 2558 1300 2549 3800 2555 2506 1606 1003 2003 1019 7903 1606 2501 2539 1604 0801 5603 5602 9200 9201 2539 5601 5502 7401 1402 1405 1000 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS PO LYN UC LEA R ARO MATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS ALIPHATIC ALDEHYDES ACETALDEHYDE ALDEHYDES, SCREENING ACETALDEHYDE ACETIC ACID ACETIC ANHYDRIDE AC ETOIN KETONES I VOLATILE ORGANIC CPDS (Screening) ORGANIC AND INORGANIC GASES BY EXTRACTIVE FTIR SPECTROMETRY KETONES I ACETONE CYANOHYDRIN ACETONITRILE HYDROCARBONS, HALOGENATED 1,1,2,2-TETRABROMOETHANE 1,1,2,2-TETRACHLOROETHANE ACIDS, INORGANIC ACETONITRILE ACROLEIN ALDEHYDES, SCREENING AC RYLONITRILE AEROBIC BACTERIA by GC-FAME ALACHLOR in AIR CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) ALDEHYDES, SCREENING ORGANONITROGEN PESTICIDES ALDRIN & LINDANE ALKALINE DUSTS ALCOHOLS III ALCOHOLS COMBINED ALLYL CHLORIDE Flow Rate (L/min) 2.0 Vol. (L) min max 200 - 1000 Extraction acetonitrile Analytical Technique HPLC-FL/UV 2.0 200 - 1000 varies GC-FID 2.0 200 - 1000 acetonitrile HPLC-FL/UV 2.0 200 - 1000 varies GC-FID 0.1 - 1.5 0.01 - 0.05 0.01 - 0.05 0.1 - 0.5 0.01 - 0.1 0.2 - 1.0 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 1 - 15 1 - 12 5-5 6 - 60 20 - 300 25 - 100 1 - 10 0.5 - 3 1 -6 ACN tol tol reag formic a reag Ac et-Meth CS2 thermal HPLC/UV GC-FID GC-FID/MS HPLC-UV GC-FID VIS GC-FID GC-FID TD/GC-MS 0.1 - 2.0 Instr. Dep. NA FTIR 0.01 - 0.2 0.2 0.01 - 0.2 0.01 - 0.2 0.2 - 1.0 0.01 - 0.2 0.2 - 0.5 0.01 - 0.2 0.01 - 0.1 0.01 - 0.05 0.01 - 0.2 28.3 1 0.2 - 1 0.5 - 3.0 0.3 - 12 1 - 25 0.2 - 5 50 - 100 3.0 - 30 3.0 - 100 1 - 25 1.5 - 48 5-5 3.5 - 20 50 - 300 70 - 1 750 12 - 480 CS2 Et Ac MeCl/MeOH CS2 THF CS2 HCO3-/CO32MeCl/MeOH tol tol acet/CS2 hex/MTBE methanol reagent GC-FID GC-NPD GC-FID GC-FID GC-FID GC-FID IC GC-FID GC-NPD GC-FID/MS GC-FID GC-FID ELISA GC/ECD NA NA NA GC-ECD NA NA I PA/di azomethane GC-ECD 0.01 - 0.05 0.1 - 1 0.2 - 1.0 1 -4 0.01 - 0.2 0.01 - 0.2 0.01 - 1.0 5-5 var-480 18 - 240 70 - 1000 1 - 10 2 - 10 16 - 100 tol reagent isooct HCl IPA/CS2 ipa-cs2 bz GC-FID/MS HPLC-UV GC-ECN Titration GC-FID GC-FID GC-FID Sampler PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 SG-DNPH XAD-2/HMP XAD-2/HMP BuB CCT BuB A-CMS CCT TD Dir. Read A-CMS Por QS CCT CCT SG PCT SG(washed) CCT lg XAD-2/HMP XAD-2/HMP CCT impactor SPE disk OVS-2 polyethylene bag PUF pad XAD-2 OVS-2 GFF & BuB PTFE CCT CCT CCT MF-1 NIOSH Manual of Analytical Methods Chemical Meth No. Method Name Allyl glycidyl ether 2545 ALLYL GLYCIDYL ETHER Allyl trichloride 1003 HYDROCARBONS, HALOGENATED Alumina 0500 PARTICULATES N.O.R. Aluminum 7300 ELEMENTS by ICP Aluminum 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) Aluminum 7301 ELEMENTS by ICP (AQUA REGIA ASHING) Aluminum 7013 ALUMINUM & CPDS, as Al Amines, aliphatic 2010 AMINES, ALIPHATIC Amines, aromatic 2002 AMINES, AROMATIC Aminobenzene 2002 AMINES, AROMATIC Aminobenzene 2017 ANILINE, o-TOLUIDINE, AND NITROBENZENE 2-Aminoethanol 2007 AMINOETHANOL COMPOUNDS I 2-Aminoethanol 3509 AMINOETHANOL COMPOUNDS II 2-aminotoluene 201 7 ANILINE, o-TOLUIDINE, AND NITROBENZENE p-Aminophenylarsonic acid 5022 ARSENIC, ORGANO- 2-Aminotoluene 2002 AMINES, AROMATIC Am monia 6015 AMMONIA by VIS Am monia 6016 AMMONIA by IC n- and sec-Amyl acetate 1450 ESTERS I n-Amyl acetate 1450 ESTERS I Amyl acetate 2549 VOLATILE ORGANIC CPDS (Screening) iso-Amylacetate 1450 ESTERS I Aniline 2002 AMINES, AROMATIC Aniline 201 7 ANILINE, O-TOLUIDINE, & NITROBENZENE Aniline 831 7 ANALINE and O-TOLUIDINE in urine Anisidine 2514 ANISIDINE Anthracene 5506 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC Anthracene 5515 POLYNUCLEAR AROMATIC HYDROCARBONS Antimony 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) Antimony 7301 ELEMENTS by ICP (AQUA REGIA ASHING) p-Arsanilic acid 5022 ARSENIC, organo- Arsenic 7900 ARSENIC & compounds, as As Arsenic 7300 ELEMENTS by ICP Arsenic 9102 ELEMENTS on WIPES Arsenic 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) Arsenic 7301 ELEMENTS by ICP (AQUA REGIA ASHING) Arsenic trioxide 7901 ARSENIC TRIOXIDE, as As Flow Rate (L/min) 0.01 - 0.2 0.01 - 0.2 1 -2 1 -4 1 -4 Vol. (L) min max 1.5 - 8 2 - 60 7 - 133 5 - 100 See Table Extraction diethyl ether CS2 HNO3/HClO4 HCl/HNO3 Analytical Technique GC-FID GC-FID Grav ICP-AES ICP-AES 1 -4 5 - 100 HCl/HNO3 ICP-AES 1 -3 0.01 - 1.0 0.2 - 1.0 0.2 - 1.0 0.2 10 - 400 3 - 30 30 - 150 30 - 150 5 - 50 HNO3 H2SO4/aq MeOH Ethanol Ethanol Ethanol FAAS GC-FID GC-FID GC-FID GC-FID 0.01 - 0.2 0.5 - 1.0 0.2 4 - 24 5 - 300 5 - 50 MeOH/H2O HSA ethanol GC-FID IC GC-FID 1 -3 0.02 - 1.0 0.1 - 0.2 0.1 - 0.5 0.01 - 0.2 0.01 - 2 0.01 - 0.05 50 - 1000 10 - 150 0.1 - 90 0.1 - 96 1 - 10 1 - 10 1 -6 buffer Ethanol HO HO CS2 CS2 thermal IC-HYAAS GC-FID VIS-Auto IC GC-FID GC-FID TD/GC-MS 0.01 - 2 0.02 - 0.2 0.2 1 - 10 5 - 30 5 - 50 CS2 Ethanol ethanol GC-FID GC-FID GC-FID NA 0.5 - 1.0 2.0 NA Alk 24 - 320 MeOH 200 - 1000 acetonitrile HPLC/ECD HPLC-UV HPLC-FL/UV 2.0 200 - 1000 varies GC-FID 1 -4 See Table HCl/HNO3 ICP-AES 1 -4 50 - 2000 HCl/HNO3 ICP-AES 1 -3 1 -3 1 -4 NA 1 -4 50 - 1000 30 - 1000 5 - 2000 NA See Table buffer IC-HYAAS HNO3/H2SO4/HClO4 HNO3/HClO4 HYAAS ICP-AES NA ICP-AES HCl/HNO3 ICP-AES 1 -4 1 -3 5 - 2000 HCl/HNO3 30 - 1000 HNO3/H2O2 ICP-AES GFAAS Sampler Tenax CCT PVC, tared MCEF MCEF MCEF MCEF SG SG SG GFF + SG SG IMP GFF + SG PTFE SG SG + H2SO4 SG + H2SO4 CCT CCT TD CCT SG GFF + SG NA XAD-2 PTFE & XAD-2 PTFE & XAD-2 MCEF MCEF PTFE MCEF MCEF Wipe MCEF MCEF MCEF 3/1 5/2003 MF-2 NIOSH Manual of Analytical Methods Chemical Arsine Asbestos Asbestos Asbestos Asbestos Aspartame Asphalt fume Atrazine Atrazine Atrazine Atrazine Azelaic acid Azinphos methyl Bacte ria B[a]P B[a]P Barium Barium Barium Barium Benomyl Benzaldehyde Benz[a] anthracene Benz(a) anthracene Benzene Benzene Benzene Benzene Benzene Benzene solubles 1,3-benzenediol Benzidine Dyes Benzidine Benzo[a]pyrene Benzo(a)pyrene 3/1 5/2003 Meth No. Method Name 6001 ARSINE 7400 ASBESTOS FIBERS by PCM 7402 ASBESTOS FIBERS by TEM 9000 ASBESTOS, CHRYSOTILE by XRD 9002 ASBESTOS (bulk) by PLM 5031 ASPARTAME 5042 BENZENE SOLUBLE FRACTION AND TOTAL PARTICULATE (ASPHALT FUME) 5602 CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) 8315 TRIAZINE HERBICIDES and their METABOLITES 9200 CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) 9201 CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) 5019 AZELAIC ACID 5600 ORGANOPHOSPHORUS PESTICIDES 0801 AEROBIC BACTERIA by GC-FAME 5506 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC 5515 POLYNUCLEAR AROMATIC HYDROCARBONS 7056 BARIUM, SOLUBLE COMPOUNDS 9102 ELEMENTS on WIPES 7303 ELEMENTS by 1CP (HOT BLOCK/HCl/HNO3 DIGESTION) 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 5601 ORGANONITROGEN PESTICIDES 2549 VOLATILE ORGANIC CPDS (Screening) 5506 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC 5515 POLYNUCLEAR AROMATIC HYDROCARBONS 2549 VOLATILE ORGANIC CPDS (Screening) 3700 BENZENE by portable GC 1501 HYDROCARBONS, AROMATIC 1500 HYDROCARBONS, BP 36-216C 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 5042 BENZENE SOLUBLE FRACTION AND TOTAL PARTICULATE (ASPHALT FUME) 5701 RESORCINOL 5013 DYES 5509 BENZIDINE and 3,3-DICHLORO-BENZIDINE 5506 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC 5515 POLYNUCLEAR AROMATIC HYDROCARBONS Flow Rate (L/min) 0.01 - 0.2 0.5 - 16 0.5 - 16 NA NA 1 -3 1 -4 Vol. (L) min max 0.1 - 10 400 -var 400 -var NA NA 70 - 1200 28 - 400 Extraction HNO3 NA NA NA NA eluent benzene 0.2 - 1 12 - 480 reagent NA NA NA NA NA NA NA 1 -3 0.2 - 1.0 28.3 2.0 NA 200 - 1000 12 - 240 50 - 300 200 - 1000 IPA/ diazomethane Ethanol tol/acet hex/MTBE acetonitrile 2.0 200 - 1000 varies 1 -4 NA 1 -4 50 - 2000 NA See Table HO NA HCl/HNO3 1 -4 50 - 2000 HCl/HNO3 0.1 - 1 0.01 - 0.05 var- 480 1 -6 reagent thermal 2.0 200 - 1000 acetonitrile 2.0 200 - 1000 varies 0.01 - 0.05 1 - 6 thermal > 0.02 0.01 - 0.2 0.01 - 0.2 0.1 - 2.0 80% vol 5 - 30 2 - 30 Instr. Dep. NA CS2 CS2 NA 1 -4 28 benzene 0.2 - 1 1 -3 0.2 2.0 5 - 160 methanol 150 - 500 HO 20 - 100 triethyl amine /MeOH 200 - 1000 acetonitrile 2.0 200 - 1000 varies Analytical Technique Sampler GFAAS PCM TEM XRD PLM HPLC-UV GRAVIMETRIC CCT MCEF open MCEF open bulk bulk PTFE Tared PTFE GC/ECD OVS-2 GC-MSD Urine GC-ECD GC-ECD polyethylene bag PUF pad GC-FID GC-FPD GC-FID HPLC-FL/UV PVC OVS-2 impactor PTFE & XAD-2 GC-FID PTFE & XAD-2 FAAS ICP-AES ICP-AES MCEF Wipe MCEF ICP-AES MCEF HPLC-UV TD/GC-MS OVS-2 TD HPLC-FL/UV PTFE & XAD-2 GC-FID PTFE & XAD-2 TD/GC-MS TD GC GC-FID GC-FID FTIR air bag CCT CCT Dir. Read Grav Tared PTFE GC-FID HPLC-UV HPLC-UV OVS-7 PTFE GFF HPLC-FL/UV PTFE & XAD-2 GC-FID PTFE & XAD-2 MF-3 NIOSH Manual of Analytical Methods Chemical Benzo[a]fluoranthene Benzo(b fluoranthene Benzo[e]pyrene Benzo(e)pyrene Benzo[k]fluoranthene Benzo(k)fluoranthene Benzo[ghi]perylene Benzo(ghi)perylene Benzo su lfon azole Benzo thiazole Benzoyl peroxide Benzyl chloride Beryll ium Beryllium Beryllium Beryll ium Beryllium & compounds Bioaerosol Biphenyl Bismuth Bitumen fume Boron Boron carbide Boron oxide Bromoform Bromine 1 -Bromopropane 2-Bromopropane Bromoform Bromotrlfluorom ethane Bromoxynil Bromoxynil octanoate 1,3-Butadiene 2-Butanone 2-Butanone 2-Butanone Meth No. Method Name Flow Rate (L/min) 5506 5515 5506 5515 5506 5515 5506 5515 2550 2550 5009 1003 7300 9102 7303 7301 7102 0800 2530 7303 5042 7303 7506 0500 1003 6011 1025 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS PO LYN UC LEA R ARO MATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS BENZOTHIAZOLE IN ASPHALT FUME BENZOTHIAZOLE IN ASPHALT FUME BENZOYL PEROXIDE HYDROCARBONS, HALOGENATED ELEMENTS by ICP ELEMENTS on WIPES ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) ELEMENTS by ICP (AQUA REGIA ASHING) BERYLLIUM and cpds, as Be BIOAEROSOL SAMPLING (Indoor Air) DIPHENYL ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) BENZENE SOLUBLE FRACTION AND TOTAL PARTICULATE (ASPHALT FUME) ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) BORON CARBIDE PARTICULATES N.O.R. HYDROCARBONS, HALOGENATED CHLORINE and BROMINE 1- and 2-BROMOPROPANE 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 1.0 - 2.0 1.0 - 2.0 1 -3 0.01 - 0.2 1- 4 NA 1 -4 1 -4 1 -4 28.3 0.01 - 0.5 1 -4 1 -4 1 -4 1.7 or 2.2 1.5 - 2.0 0.01 - 0.2 0.3 - 1.0 0.01 - 0.2 Vol. (L) min max 200 - 1000 Extraction acetonitrile 200 - 1000 varies 200 - 1000 acetonitrile 200 - 1000 varies 200 - 1000 acetonitrile 200 - 1000 varies 200 - 1000 acetonitrile 200 - 1000 varies 480 - 960 480 - 960 40 - 400 6 - 50 1250-2000 NA See Table hexane hexane diethyl ether CS2 HNO3/HClO4 NA HCl/HNO3 1250-2000 HCl/HNO3 25 - 2000 varies 15 - 30 See Table hno3/h2so4 NA CCl4 HCl/HNO3 28 - 400 benzene See Ta ble HCl/HNO3 100 - 1000 25 - 133 4 - 70 8 - 360 0.1 - 12 ash NA CS2 Na2S2O3 CS2 1003 1017 5010 5010 1024 2500 2549 3800 HYDROCARBONS, HALOGENATED TRIFLUOROBROMOM ETHANE BROMOXYNIL and B'OCTANOATE BROMOXYNIL and B'OCTANOATE 1,3-BUTADIENE METHYL ETHYL KETONE VOLATILE ORGANIC CPDS (Screening) ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 0.01 - 0.2 0.01 - 0.05 1 -3 1 -3 0.01 - 0.5 0.01 - 0.2 0.01 - 0.05 4 - 70 0.3 - 1.0 2 - 400 90 - 400 5 - 25 1 - 12 1 -6 0.1 - 2.0 Instr. Dep. CS2 CH2Cl2 CH3CN CH3CN CH2Cl2 CS2 thermal NA Analytical Technique HPLC-FL/UV GC-FID HPLC-FL/UV GC-ID HPLC-FL/UV GC-ID HPLC-FL/UV GC-ID GC-SCD GC-SCD HPLC-UV GC-FID ICP-AES ICP-AES ICP-AES ICP-AES GFAAS varies GC-FID ICP-AES Grav ICP-AES XRD Grav GC-FID IC GC-FID GC-FID GC-FID HPLC-UV HPLC-UV GC-FID GC-FID TD/GC-MS FTIR Sampler PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE + XD-2 PTFE + XD-2 MCEF CCT MCEF Wipe MCEF MCEF MCEF Impactor Tenax GC MCEF Tared PTFE MCEF CYC & PVC PVC CCT Ag F CCT CCT 2 CCT (lg + sm) PTFE PTFE CCT Carbon beads TD Dir. Read 3/1 5/2003 MF-4 NIOSH Manual of Analytical Methods Chemical Butoxyacetic acid 2-Butoxyethyanol 2-Butoxyethanol n-, sec-, & t-Butyl acetate Butyl acetate iso-Butyl acetate 1-Butyl acetate Butyl alcohol tert-Bu\y\ alcohol n- & sec-Butyl alcohol n-Butyl alcohol sec-Butyl alcohol n-Butylamine Butyl cellosolve Butyl cellosolve 1,3-Butylene glygol Butyl glycidyl ether n-Butyl mercaptan n-Butyl mercaptan p-ferf-Butyltoluene Butyraldehyde Cadmium Cadmium Cadmium Cadmium Cadmium & compounds Calcium Calcium Calcium Calcium & compounds Camphor Camphor Capsaicin Captan Captan Captan Carbaryl Carbaryl (Sevin) Meth No. Method Name Flow Rate (L/min) Vol. (L) min max 8316 BUTOXYACETIC ACID in urine NA NA 2549 VOLATILE ORGANIC CPDS (Screening) 0.01 - 0.05 1 - 6 1403 ALCOHOLS IV 0.01 - 0.05 2 - 10 1450 ESTERS I 0.01 - 0.2 1 - 10 2549 VOLATILE ORGANIC CPDS (Screening) 0.01 - 0.05 1 - 6 1450 ESTERS I 0.01 - 2 1 - 10 1450 ESTERS I 0.01 - 2 1 - 10 2549 VOLATILE ORGANIC CPDS (Screening) 0.01 - 0.05 1 -6 1400 ALCOHOLS I 0.01 - 0.2 1 - 10 1401 ALCOHOLS II 0.01 - 0.2 2 - 10 1405 ALCOHOLS COMBINED 0.01 - 0.2 2 - 10 1405 ALCOHOLS COMBINED 0.01 - 0.2 2 - 10 2012 n-BUTYLAMINE 0.01 - 1.0 2 - 100 2549 VOLATILE ORGANIC CPDS (Screening) 0.01 - 0.05 1 - 6 1403 ALCOHOLS IV 0.01 - 0.05 1 - 10 5523 GLYCOLS 0.5 - 2 5 - 60 1616 BUTYL GLYCIDYL ETHER 0.01 - 0.2 15 - 30 2525 n-BUTYL MERCAPTAN 0.01 - 0.05 1 - 4 2542 MERCAPTANS 0.1 - 0.2 10 - 150 1501 HYDROCARBONS, AROMATIC 0.01 - 0.2 1 - 29 2539 ALDEHYDES, SCREENING 0.05 5-5 7300 ELEMENTS by ICP 1 -4 13 - 2000 9102 ELEMENTS on WIPES NA NA 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 1 -4 See Table 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 1 -4 13 - 2000 7048 CADMIUM and cpds, as Cd 1 -3 25 - 1500 7300 ELEMENTS by ICP 1 -4 5 - 200 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 1 -4 See Table 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 1 -4 5 - 200 7020 CALCIUM and cpds as Ca 1 -3 20 - 400 1301 KETONES II 0.01 - 0.2 1 - 25 2553 KETONES II 0.01 - 0.2 1 - 25 5041 CAPSAICIN and DIHYDROCAPSAICIN 1 - 3 5 - 1000 5601 ORGANONITROGEN PESTICIDES 0.1 - 1 var-480 9205 CAPTAN and THIOPHENATE-METHYL on DERMAL PATCH NA NA 9202 CAPTAN and THIOPHENATE-METHYL in Handrinse NA NA 5601 ORGANONITROGEN PESTICIDES 0.1 - 1 var-480 5006 CARBARYL 1 -3 20 - 400 Extraction NA thermal CH2Cl2/MeOH CS2 thermal CS2 CS2 thermal CS2 CS2 ipa-cs2 ipa-cs2 MeOH thermal CH2Cl2/MeOH MeOH CS2 acet HCl/DCE CS2 tol HNO3/HClO4 NA HCl/HNO3 HCl/HNO3 HNO3/HCl HNO3/HClO4 HCl/HNO3 HCl/HNO3 HNO3/HClO4 MeOH/CS2 ipa-cs2 CH3CN reagent IPA/ACN NA reagent reagent Analytical Technique GC-ECD TD/GC-MS GC-FID GC-FID TD/GC-MS GC-FID GC-FID TD/GC-MS GC-FID GC-FID GC-FID GC-FID GC-FID TD/GC-MS GC-FID GC-FID GC-FID GC-FPD GC-FPD GC-FID GC-FID/MS ICP-AES ICP-AES ICP-AES ICP-AES FAAS ICP-AES ICP-AES ICP-AES FAAS GC-FID GC-FID HPLC-FL HPLC- UV HPLC-UV HPLC-UV HPLC- UV VIS Sampler NA TD CCT CCT TD CCT CCT TD CCT CCT CCT CCT SG + H2SO4 TD CCT OVS-7 CCT Chrom 104 GFF/HgAc CCT XAD-2/HMP MCEF Wipe MCEF MCEF MCEF MCEF MCEF MCEF MCEF CCT A-CMS GFF OVS-2 Patch Hand wash OVS-2 GFF 3/1 5/2003 MF-5 NIOSH Manual of Analytical Methods Chemical Carbendazim Carbitol Carbofuran Carbon black Carbon, elemental Carbon dioxide Carbon disulfide Carbon monoxide Carbon tetrachloride 6-3-Carene Cellulose Chlordane Meth No. Method Name 5601 2549 5601 5000 5040 6603 1600 6604 1003 1552 7404 5510 ORGANONITROGEN PESTICIDES VOLATILE ORGANIC CPDS (Screening) ORGANONITROGEN PESTICIDES CARBON BLACK ELEMENTAL CARBON (DIESEL PART.) CARBON DIOXIDE CARBON DISULFIDE CARBON MONOXIDE HYDROCARBONS, HALOGENATED TERPENES CELLULOSE INSULATION CHLORDANE Flow Rate (L/min) Vol. (L) min max 0.1 - 1 var- 480 0.01 - 0.05 1 -6 Extraction reagent thermal 0.1 - 1 1 -2 2-4 0.02 - 0.1 0.01 -0.2 NA 0.01 - 0.2 0.01 - 0.02 1 0.5 - 1.0 var-480 30 - 570 142-19000 80% vol 2 - 25 NA 3 - 150 2 - 30 NA 10 - 200 reagent NA thermal NA toluene NA CS2 CS2 NA tol Chlorinated camphene Chlorinated diphenyl oxide Chlorinated terphenyl Chlorine Chloroacetaldehyde Chloroacetic acid Chlorobenzene p-Ch loro benzotrifluo ride Ch lo rob ro mom ethane Ch lo rob ro mom ethane Chlo rod ifluorom ethane Chlorodiphenyl (42 & 54% CI) 2-Chloroethanol Chloroform 4-Chloronitrobenzene p-Chlorophenol Chloroprene Chlorpropham Chlorpyrlfos Chromic acid Chromic acid Chromium Chromium Chromium Chromium Chromium Chromium, hexavalent Chromium, hexavalent 5039 5025 5014 601 1 2015 2008 1003 1026 1003 1003 1018 5503 CHLORINATED CAMPHENE CHLORINATED DIPHENYL OXIDE CHLORINATED TERPHENYL CHLORINE and BROMINE CHLOROACETALDEHYDE CHLOROACETIC ACID HYDROCARBONS, HALOGENATED p-CH LO ROB ENZOTRI FLUOR IDE HYDROCARBONS, HALOGENATED HYDROCARBONS, HALOGENATED DICHLORODIFLUOROM ETHANE POLYCHLOROBIPHENYLS 2513 ETHYLENE CHLOROHYDRIN 1003 HYDROCARBONS, HALOGENATED 2005 NITROAROMATIC COMPOUNDS 2014 p-CHLOROPHENOL 1002 P-CHLOROPRENE 5601 ORGANONITROGEN PESTICIDES 5600 ORGANOPHOSPHORUS PESTICIDES 7600 CHROMIUM, HEXAVALENT 7604 CHROMIUM, HEXAVALENT 7024 CHROMIUM and cpds, as Cr 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 9102 ELEMENTS on WIPES 7600 CHROMIUM, HEXAVALENT 7604 CHROMIUM, HEXAVALENT 0.2 - 1 0.5 - 1.5 1 -3 0.3 - 1.0 0.05 - 0.2 0.05 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 0.05 - 0.2 2 - 30 8 - 200 100 - 1500 2 - 90 3 - 16 1 - 100 1.5 - 40 0.1 - 10 0.5 - 60 0.5 - 8 1 -4 1 - 50 pet ether isooctane isooctane Na2S2O3 MeOH HO CS2 CS2/MeOH CS2 CS2 CH2Cl2 hexane 0.01 - 0.2 0.01 - 0.2 0.01 - 1.0 0.05 - 0.2 0.01 - 0.1 0.1 - 1 0.2 - 1.0 1 -4 1 -4 1 -3 1 -4 1 -4 2 - 35 ipa/cs2 1 - 50 CS2 1 - 150 1.5 - 40 MeOH CH3CN 1.5 - 8 CS2 var-480 reagent 12 - 240 tol/acet 8 - 400 100 - 1000 reagent NaOH/Na2CO3 10 - 1000 5 - 1000 HCl/HNO3 HNO3/HClO4 5 - 1000 HCl/HNO3 1 -4 See Table HCl/HNO3 NA 1 -4 1 -4 NA 8 - 400 100 - 1000 NA reagent NaOH/Na2CO3 Analytical Technique HPLC-UV TD/GC-MS HPLC-UV Grav EGA/TOA GC-TCD GC-FPD Sensor GC-FID GC-FID SEM GC-ECD GC-ECD GC-ECN GC-ECD IC GC-ECD IC GC-FID GC-FID GC-FID GC-FID GC-FID GC-ECD GC-FID GC-FID GC-FID HPLC-UV GC-FID HPLC, UV GC-FPD VIS IC FAAS ICP-AES ICP-AES ICP-AES ICP-AES VIS IC Sampler OVS-2 TD OVS-2 PVC QFF air bag CCT & dry tube Port Instr CCT CCT ACF MCEF & Chrom 102 MCEF MCEF GFF Ag F SG SG CCT CCT CCT CCT 2CCT (lg+sm) GFF & Florisil PCT CCT SG SG CCT OVS-2 OVS-2 PVC PVC MCEF MCEF MCEF MCEF Wipe PVC PVC 3/1 5/2003 MF-6 NIOSH Manual of Analytical Methods Chemical Chromium, hexavalent Chromium, hexavalent Chromium, hexavalent Chrysene Chrysene Coal tar naphtha Coal tar pitch volatiles Cobalt Cob alt Cobalt Cobalt Cobalt & compounds Copper Copper Copper Copper Copper (dust & fume) Cresol Cresol, all isomers Crotonaldehyde Crotonaldehyde Cryofluorane Cumene Cyanides Cyanides Cyanuric acid Cyanazine Cyanazine Cyanazine Cyanazine Cyclohexane Cyclohexanol Cyclohexanol 3/1 5/2003 Meth No. Method Name 7605 CHROMIUM HEXAVALENT by ION CHROMATOGRAPHY 7703 CHROMIUM, HEXAVALENT by FieldPortable Spectrophotometry 9101 CHROMIUM, HEXAVALENT in settled dust 5506 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC 5515 POLYNUCLEAR AROMATIC HYDROCARBONS 1550 NAPHTHAS 5042 BENZENE SOLUBLE FRACTION AND TOTAL PARTICULATE (ASPHALT FUME) 7300 ELEMENTS by ICP 9102 ELEMENTS on WIPES 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 7027 COBALT and cpds, as Co 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 9102 ELEMENTS on WIPES 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 7029 COPPER (dust & fumes) 2549 VOLATILE ORGANIC CPDS (Screening) 2546 CRESOLS and PHENOL 2539 ALDEHYDES, SCREENING 3516 CROTONALDEHYDE 1018 DICHLORODIFLUOROMETHANE, 1,2-DICHLOROTETRAFLUOROETHANE, & CHLORODIFLUOROMETHANE 1501 HYDROCARBONS, AROMATIC 7904 CYANIDES, aerosol and gas 6010 HYDROGEN CYANIDE 5030 CYANURIC ACID 5602 CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) 8315 TRIAZINE HERBICIDES and their METABOLITES 9200 CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) 9201 CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) 1500 HYDROCARBONS, BP 36-216C 1402 ALCOHOLS III 1405 ALCOHOLS COMBINED Flow Rate (L/min) 0.1 - 4 Vol. (L) min max 1 - 400 Extraction NaOH-Na2CO3 Analytical Technique IC 1 -4 10 - 1200 (NH4)2SO4/NH4OH VIS NA NA NA Spot 2.0 200 - 1000 acetonitrile HPLC-FL/UV 2.0 200 - 1000 varies GC-FID 0.01 - 0.2 1 -4 1 -4 NA 1 -4 1.3 - 20 28 - 400 CS2 benzene 25 - 2000 NA 25 - 2000 HNO3/HClO4 NA HCl/HNO3 GC-FID Grav ICP-AES ICP-AES ICP-AES 1 -4 See Table HCl/HNO3 ICP-AES 1 -3 1 -4 1 -4 30 - 1500 5 - 1000 5 - 1000 aq reg/HNO3 HNO3/HClO4 HCl/HNO3 FAAS ICP-AES ICP-AES NA 1 -4 NA See Table NA HCl/HNO3 ICP-AES ICP-AES 1 -3 0.01 - 0.05 50 - 1500 1 -6 HNOj/HCl thermal FAAS TD/GC-MS 0.01 - 0.1 0.01 - 0.05 0.1 - 0.2 0.01 - 0.05 1 - 24 5-5 1 - 49 1 -4 MeOH tol buffer CH Cl GC-FID GC-FID/MS DPP GC-FID 0.01 - 0.2 0.5 - 1.0 0.05 - 0.2 1 -3 0.2 - 1 1 - 30 10 - 180 0.6 - 90 10 - 1000 12 - 480 CS2 KOH HO reagents reagent GC-FID ISE VIS HPLC-UV GC/ECD NA NA NA GS-MSD NA NA NA GC-ECD NA NA I PA/diazom ethane GC-ECD 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 2.5 - 5 1 - 10 2 - 10 CS2 ipa/cs2 ipa-cs2 GC-FID CG-FID GC-FID Sampler PVC PVC, MCE, PTFE Test strip PTFE & XAD-2 PTFE & XAD-2 CCT tared PTFE MCEF Wipe MCEF MCEF MCEF MCEF MCEF Wipe MCEF MCEF TD XAD-7 XAD-2/H M P BuB 2 CCT CCT MCEF & BuB soda lime PVC OVS-2 Urine polyethylene bag PUF pad CCT CCT CCT MF-7 NIOSH Manual of Analytical Methods Chemical Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexene 1,3-Cyclopentadiene Meth No. Method Name 2549 2555 1300 1500 2523 VOLATILE ORGANIC CPDS (Screening) KETONES I KETONES I HYDROCARBONS, BP 36-216C 1,3-CYCLOPENTADIENE Flow Rate (L/min) 0.01 - 0.05 Vol. (L) min max 1 -6 Extraction thermal 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 1 - 10 1 - 10 5-7 1 -5 CS2 CS2 CS2 Et Ac Analytical Technique TD/GC-MS GC-FID CG-FID CG-FID GC-FID 2,4-D 2.4-D acid; 2.4-D,2-ethylhexyl ester; 2.4-D,2-butoxyethyl ester 2.4-D acid; 2.4-D,2-ethylhexyl ester; 2.4-D,2-butoxyethyl ester 2.4-D acid; 2.4-D,2-ethylhexyl ester; 2.4-D,2-butoxyethyl ester Decabromodiphenyl Oxide n-Decane n-Decane Demeton Desethylatrazne Desisopropylatrazine Diacetone alcohol Diacetone alcohol Diacetyl o-Dianisidine Diatomaceous earth Diazinon Diazomethane Dibenz[a,h] anthracene Dibenz(a,h) anthracene Diborane 5001 5602 2,4-D and 2,4,5-T CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) 9200 CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) 9201 CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) 2559 DECABROMODIPHENYL OXIDE 2549 VOLATILE ORGANIC CPDS (Screening) 1500 HYDROCARBONS, BP 36o-216oC 5514 DEMETON 8315 TRIAZINE HERBICIDES and their METABOLITES 8315 TRIAZINE HERBICIDES and their METABOLITES 1402 ALCOHOLS III 1405 ALCOHOLS COMBINED 2557 DIACETYL 5013 DYES 7501 SILICA, AMORPHOUS 5600 ORGANOPHOSPHORUS PESTICIDES 2515 DIAZOMETHANE 5506 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC 5515 PO LYN UC LEA R ARO MATIC HYDROCARBONS 6006 DIBORANE 1 -3 0.2 - 1 15 - 200 12 - 480 MeOH reagent HPLC-UV GC-ECD NA NA NA GC-ECD NA NA I PA/diazom ethane GC-ECD 2.0 0.01 - 0.05 48 - 960 1 -6 Tol thermal GC/NCD TD/GC-MS NA 0.2 - 1.0 NA NA 30 - 500 NA CS2 toluene NA GC-FID GC-FPD GC-MSD NA NA NA GC-MSD 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 1 -3 1 -3 0.2 - 1 0.2 2.0 1 - 10 ipa/cs2 1 - 10 ipa-cs2 1 - 10 Acet-M eth 150 - 500 H2O 50 - 400 ash 12 - 240 toluene/acetone 6 - 30 CS2 200 - 1000 acetonitrile GC-FID GC-FID GC-FID HPLC-UV XRD GC-FPD GC-FID HPLC-FL/UV 2.0 200 - 1000 varies GC-FID 0.5 - 1.0 60 - 260 h2o2 PES Dibromodifluoromethane 2-Dibutylaminoethanol Dibutyl phosphate Dibutyl phthalate Dibutyltin bis(isooctyl mercaptoacetate) o-, p-Dichlorobenzene o-Dichlorobenzene 1012 2007 5017 5020 5504 DIFLUORODIBROMOM ETHANE AMINOETHANOL COMPOUNDS DIBUTYL PHOSPHATE DIBUTYL PHTHALATE & DI(2-ETHYLHEXYL) PHTHALATE ORGANOTIN COMPOUNDS 2549 1003 VOLATILE ORGANIC CPDS (Screening) HYDROCARBONS, HALOGENATED 0.01 - 0.2 0.01 - 0.2 1 -3 1 -3 2.5 - 10 4 - 24 50 - 250 6 - 200 IPA MeO H/H2O ch3cn CS2 GC-FID GC-FID GC-FPD GC-FID 1 - 1.5 50 - 500 Acetic a/CH3CN HPLC/GFAAS 0.01 - 0.05 1 - 6 varies TD/GC-MS 0.01 - 0.2 1 - 10 CS2 GC-FID Sampler TD A-CMS CCT CCT Chrom104/ maleic anhy GFF OVS-2 polyethylene bag PUF pad GFF TD CCT MCEF &XAD-2 Urine Urine CCT CCT A-CMS PTFE PVC/CYC OVS-2 XAD-2(coated) PTFE & XAD-2 PTFE & XAD-2 PTFE & CCT w/oxidizer 2 CCT SG PTFE MCEF GFF + XAD-2 TD CCT 3/1 5/2003 MF-8 NIOSH Manual of Analytical Methods Chemical Meth No. Method Name Flow Rate (L/min) Vol. (L) min max Extraction Analytical Technique p-Dichlorobenzene 1003 HYDROCARBONS, HALOGENATED 0.01 - 0.2 1 -8 CS2 GC-FID p-Di chlorobenzene 1003 HYDROCARBONS, HALOGENATED 0.01 - 0.2 1 - 10 CS2 GC-FID 3,3-Dichlorobenzidine 5509 BENZIDINE and 3,3-DICHLOROBENZIDINE 0.2 20 - 100 TEA/MeOH HPLC-UV Dichlorodifluorom ethane 1018 DICHLORODIFLUOROMETHANE, 1,2-DICHLOROTETRAFLUOROETHANE & CHLORODIFLUOROMETHANE 0.01 - 0.05 1 - 4 CH Cl GC-FID 1,1 -Dichloroethane 1003 HYDROCARBONS, HALOGENATED 0.01 - 0.2 0.5 - 15 CS2 GC-FID 1,2-Dichloroethane 1003 HYDROCARBONS, HALOGENATED 0.01 - 0.2 0.5 - 50 CS2 GC-FID Dichloroethyl ether 1004 DICHLOROETHYL ETHER 0.01 - 1.0 2 - 15 CS2 GC-FID 1,2-Dichloroethylene 1003 HYDROCARBONS, HALOGENATED 0.01 - 0.2 0.2 - 5 CS2 GC-FID Dichlorofluorom ethane 2516 DICHLOROFLUOROM ETHANE 0.01 - 0.05 0.25 - 3 CS2 GC-FID Dichloromethane 1005 METHYLENE CHLORIDE 0.01 - 0.2 0.5 - 2.5 CS2 GC-FID Dichloromethane 2549 VOLATILE ORGANIC CPDS (Screening) 0.01 - 0.05 1 - 6 thermal TD/GC-MS 1,1 -Dichloro-1 -nitroethane 1601 1,1 -DICHLORO-1 -NITROETHANE 0.01 - 1.0 1.5 - 15 CS2 GC-FID 1,2-Dichloropropane 1013 PROPYLENE DICHLORIDE 0.01 - 0.2 0.1 - 3.5 Acet/cyclohexane GC-ECN 1,2-Dichlorotetrafluoroethane 1018 DICHLORODIFLUOROMETHANE , 1,2-DICHLOROTETRAFLUOROETHANE & CHLORODIFLUOROMETHANE 0.01 - 0.05 1 - 4 CH Cl GC-FID Dicrotophos 5600 ORGANOPHOSPHORUS PESTICIDES 0.2 - 1 12 - 240 tol/acet GC-FPD Diesel exhaust 5040 ELEMENTAL CARBON (DIESEL PART.) 1 -4 142 -19000 thermal EGA/TOA Diethanolamine Diethylamine 3509 2010 AMINOETHANOL COMPOUNDS II AMINES, ALIPHATIC 0.5 - 1.0 0.01 - 1.0 5 - 300 3 - 30 HSA H2SO4/MeOH IC GC-FID 2-Diethylaminoethanol 2007 AMINOETHANOL COMPOUNDS I 0.01 - 0.2 4 - 24 MeOH/H2O GC-FID Diethylene glycol 5523 GLYCOLS 0.5 - 2 5 - 60 MeOH GC-FID Diethylene glycol ether 2549 VOLATILE ORGANIC CPDS (Screening) 0.01 - 0.05 1 -6 thermal TD/GC-MS Diethylenetriamine 2540 ETHYLENEDIAMINE, DIETHYLENETRIAMINE, & TRIETHYLENETETRAMINE 0.01 - 0.1 1 - 20 DMF HPLC-UV Di-(2-ethylhexyl) phthalate 5020 DIBUTYL PHTHALATE and DI(2-ETHYLHEXYL) PHTHALATE 1 -3 10 - 200 CS2 GC-FID Difluorodibromom ethane Difluorodichloromethane 1012 1018 DIFLUORODIBROMOMETHANE 0.01 - 0.2 DICHLORODIFLUOROMETHANE, 1,2-DICHLOROTETRAFLUORO-ETHAN E & CHLORODIFLUOROMETHANE 0.01 - 0.05 2.5 - 10 1 -4 IPA CH2Cl2 GC-FID GC-FID Dihyd rocapsaicin 5041 CAPSAICIN and DIHYDROCAPSAICIN 1 - 3 7 - 1000 CH3CN HPLC-FL Diisobutyl ketone 1300 KETONES I 0.01 - 0.2 1 - 10 CS2 GC-FID Diisobutyl ketone 2555 KETONES I 0.01 - 0.2 1 - 10 CS2 GC-FID Dimethylacetamide Dimethylamine 2004 2010 DIMETHYLACETAMIDE and DIMETHYLFORMAMIDE AMINES, ALIPHATIC 0.01 - 1.0 15 - 80 0.01 - 1.0 3 - 30 MeOH H2SO4/MeOH GC-FID GC-FID 2-(Dimethylamino)ethanol 2561 1 -Dimethylamino-2-propanol 2-(DIM ETHYLAM INO)ETHANOL 1 -DIM ETH YLAM IN O-2-PROPANOL 0.02 - 0.1 10 - 24 MeOH GC-FID N,N- Dim ethylani line 2002 AMINES, AROMATIC 0.02 - 1.0 3 - 30 Ethanol GC-FID Dimethylarsinic acid 5022 ARSENIC, ORGANO- 1 -3 50 - 1000 buffer IC-HYAAS Sampler CCT CCT GFF 2 CCT (lg + sm) CCT CCT CCT CCT 2 CCT (lg) 2 CCT TD PCT PCT 2 CCT (lg + sm) OVS-2 QFF IMP SG SG OVS-7 TD XAD-2 w/10% NITC MCEF 2 CCT 2 CCT GFF CCT A-CMS SG SG XAD SG PTFE 3/1 5/2003 MF-9 NIOSH Manual of Analytical Methods Chemical Meth No. Method Name Dimethylformamide 1,1 -Dimethylhydrazine N,N -Dimethyl-p- to lu id in e Dimethyl sulfate Dioxane Diphenyl Dipropylene glycol monomethyl ether Disulfoton Diuron n-Dodecane Dyes- benzidine-, o-tolidine-, o-dianisidineElemental carbon Elem ents Elements Elements Endrin 2004 3515 2002 2524 1602 2530 2554 DIMETHYLACETAMIDE & DIMETHYLFORMAMIDE 1,1 -DIMETHYLHYDRAZINE AMINES, AROMATIC DIMETHYL SULFATE DIOXANE DIPHENYL GLYCOL ETHERS 5600 5601 1500 5013 5040 7300 7301 7303 5519 ORGANOPHOSPHORUS PESTICIDES ORGANONITROGEN PESTICIDES HYDROCARBONS, BP 36o-216oC DYES, BENZIDINE-, o- TOLIDINE-, o- DIANISIDINE ELEMENTAL CARBON (DIESEL PART.) ELEMENTS by ICP ELEMENTS by ICP (Aqua Region Ashing) ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) ENDRIN Flow Rate (L/min) 0.01 - 1.0 Vol. (L) min max 15 - 80 Extraction MeOH 0.2 - 1.0 0.02 - 1.0 0.01 - 0.2 0.01 - 0.2 0.01 - 0.5 0.1 - 0.2 2 - 100 20 - 100 0.25 - 12 0.5 - 15 15 - 30 3 - 25 reagent Ethanol diEt ether CS2 CCl4 MeCl2/Meth 0.2 - 1 0.1 - 1 NA 1 -3 12 - 240 var-480 NA 150 - 500 tol/acet reagent CS2 HO 2-4 1 -4 1 -4 142 -19000 thermal Varies HNO3/HClO4 Varies Aq Reg 1 -4 See Table HCl/HNO3 0.5 - 1.0 12 - 400 tol Epichlorohyd rin EPN 1,2-Epoxypropane P-Estradiol Estrone P-Estrodiol-3-Ben zoate Ethanol Ethanol Ethanolamine Ethion Ethoprop 2-Ethoxyethanol 2-Ethoxyethyl acetate Ethyl acetate Ethyl acetate Ethyl acrylate Ethyl amyl ketone Ethylbenzene Ethyl bromide Ethyl butyl ketone Ethyl chloride Ethylene chlorohydrin 1010 5012 1612 5044 5044 5044 2549 1400 2007 5600 5600 1403 1450 2549 1457 1450 1301 1501 1011 1301 2519 2513 EPICHLOROHYDRIN EPN PROPYLENE OXIDE ESTROGENIC COMPOUNDS ESTROGENIC COMPOUNDS ESTROGENIC COMPOUNDS VOLATILE ORGANIC CPDS (Screening) ALCOHOLS I AMINOETHANOL COMPOUNDS I ORGANOPHOSPHORUS PESTICIDES ORGANOPHOSPHORUS PESTICIDES ALCOHOLS IV ESTERS I VOLATILE ORGANIC CPDS (Screening) ETHYL ACETATE ESTERS I KETONES II HYDROCARBONS, AROMATIC ETHYL BROMIDE KETONES II ETHYL CHLORIDE ETHYLENE CHLOROHYDRIN 0.01 - 0.2 1 -2 0.01 - 0.2 1 1 1 0.01 - 0.05 2 - 30 15 - 700 0.5 - 5 150 - 1000 150 - 1000 150 - 1000 1 -6 CS2 isooctane CS2 Meth Meth Meth thermal 0.01 - 0.05 0.01 - 0.2 0.2 - 1 0.2 - 1 0.01 - 0.05 0.01 - 0.2 0.01 - 0.05 0.1 - 1 4 - 24 12 - 240 12 - 240 1 -6 1 - 10 1 -6 2-butanol/CS2 5600 tol/acet tol/acet MeOH CS2 thermal 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.02 - 0.05 0.01 - 0.2 0.1 - 10 1 - 10 1 - 25 1 - 24 0.5 - 4 1 - 25 0.3 - 3 2 - 35 CS2 CS2 MeOH/CS2 CS2 IPA MeOH/CS2 CS2 ipa/cs2 Analytical Technique GC-FID VIS GC-FID GC-ECN GC-FID GC-FID GC-FID GC-FPD HPLC, UV GC-FID HPLC-UV EGA-TOA ICP-AES ICP-AES ICP-AES GC-ECD GC-FID GC-FPD GC-FID HPLC-UV HPLC-UV HPLC-UV TD/GC-MS GC-FID GC-FID GC-FPD GC-FPD GC-FID GC-FID TD/GC-MS GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID Sampler SG BuB (0.1 M HCl) SG Por P CCT Tenax GC A-747 OVS-2 OVS-2 CCT PTFE QFF MCEF MCEF PVCF MCEF MCEF & Chrom 102 CCT GFF CCT PTFE PTFE PTFE TD CCT SG OVS-2 OVS-2 CCT CCT TD CCT CCT CCT CCT CCT CCT 2 CCT (lg) PCT 3/1 5/2003 MF-10 NIOSH Manual of Analytical Methods Chemical Ethylenediamine Ethylene dibromide Ethylene dichloride Ethylene glycol Ethylene glycol dinitrate Ethylene oxide Ethylene oxide Ethylene oxide Ethylene thiourea Ethylenimine Ethyl ether Ethyl ether Ethyl formate Ethyl mercaptan Ethyl methacrytate Fenamiphos Fibrous glass Fluoranthene Fluoranthene Fluorene Fluorene Fluorides Fluorides Fluorotrichlorom ethane Fonofos Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formetanate.HCI Fo rm ic a cid Furfural Furfural Meth No. 2540 1008 1003 5523 2507 1614 3702 3800 501 1 3514 1610 1610 1452 2542 2537 5600 7400 5506 5515 5506 5515 7902 Method Name Flow Rate (L/min) ETHYLENEDIAMINE, DIETHYLENETRIAMINE, & TRIETHYLENETETRAMINE 0.01 - 0.1 ETHYLENE DIBROMIDE 0.02 - 0.2 HYDROCARBONS, HALOGENATED 0.01 - 0.2 GLYCOLS 0.5 - 2 NITROGLYCERIN & ETHYLENE GLYCOL 0.2 - 1.0 DINITRATE ETHYLENE OXIDE 0.05 - 0.15 ETHYLENE OXIDE by portable GC > 0.02 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 0.1 - 2.0 ETHYLENE THIOUREA 1 -3 ETHYLENIMINE 0.2 ETHYL ETHER 0.01 - 0.2 ETHYL ETHER 0.01 - 0.2 ETHYL FORMATE 0.01 - 0.2 MERCAPTANS 0.1 - 0.2 METHYL and ETHYL METHACRYLATE 0.01 - 0.05 ORGANOPHOSPHORUS PESTICIDES 0.2 - 1 ASBESTOS & other FIBERS by PCM 0.5 - 16 PO LYN UC LEA R ARO MATIC HYDROCARBONS by HPLC 2.0 POLYNUCLEAR AROMATIC HYDROCARBONS 2.0 POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC 2.0 POLYNUCLEAR AROMATIC HYDROCARBONS 2.0 FLUORIDES, aerosol & gas 1 -2 Vol. (L) min max 1 - 20 0.1 - 25 1 - 50 5 - 60 3 - 100 1 - 24 80% vol Instr. dep. 200 - 800 1 - 48 0.25 - 3 0.25 - 3 0.3 - 10 10 - 150 1 -8 12 - 240 400-varies 200 - 1000 200 - 1000 200 - 1000 200 - 1000 12 - 800 Extraction DMF bz/MeOH CS2 MeOH Ethanol DMF NA NA HO CHCl3 CS2 Et Ac CS2 HCl/DCE CS2 tol/acet acetonitrile varies acetonitrile varies NaOH Analytical Technique HPLC -UV GC-ECD GC-FID GC-FID GC-ECD GC-ECD GC-PID FTIR VIS HPLC-UV GC-FID GC-FID GC-FID GC-FPD GC-FID GC-FPD PCM HPLC-FL/UV GC-FID HPLC-FL/UV GC-FID ISE 7906 FLUORIDES by IC 1006 5600 2016 2541 3500 2539 3800 5700 5601 2011 FLUOROTRICHLOROM ETHANE ORGANOPHOSPHORUS PESTICIDES FORMALDEHYDE FORMALDEHYDE FORMALDEHYDE ALDEHYDES, SCREENING ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY FORMALDEHYDE on dust ORGANONITROGEN PESTICIDES FORMIC ACID 1 -2 s 1 - 800 i 120 - 800 0.01 - 0.05 0.3 - 7 0.2 - 1.0 12 - 240 0.1 - 1.5 1 - 15 0.01 - 0.1 1 - 36 0.2 - 1.0 1 - 100 0.01 - 0.05 5 - 5 0.1 - 2.0 Instr. dep. NaOH CS2 tol/acet acetonitrile tol NaHSO3 tol NA 2 0.1 - 1 0.05 - 0.2 240 - 1050 var-480 1 - 24 h2o/dnph/ch3cn reagent HO IC GC-FID GC-FPD HPLC-UV GC-FID VIS GC-FID/MS FTIR HPLC-UV HPLC, UV IC 2529 2539 FURFURAL ALDEHYDES, SCREENING 0.01 - 0.05 0.05 1 - 12 5-5 tol tol GC-FID GC-FID/MS Sampler XAD-2 w/10% NITC CCT CCT OVS-7 Tenax GC PCT w/HBr air bag Dir. Read PVC or MCEF BuB CCT CCT CCT GFF/HgAc XAD OVS-2 MCEF PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 PTFE & XAD-2 MCEF & pad w/ Na2CO3 MCEF & pad w/ Na2CO3 CCT (lg) OVS-2 SG/DNPH XAD-2/H M P PTFE & 2 IMP XAD-2/HMP Dir. Read IOM/PVC OVS-2 PTFE & SG (washed) XAD-2/H M P XAD-2/H M P 3/1 5/2003 MF-1 1 NIOSH Manual of Analytical Methods Chemical Furfuryl alcohol Gallium Glutaraldehyde Glycerin mist Glycidol Glycols Gold Heptanal n-Heptane n-Heptane 2-Heptanone 3-Heptanone Herbicides Herbicides Herbicides Hexachlorobutadiene Hexachloro-1,3-cyclo pentadiene Hexachloroethane Hexamethylenediisocyanate 1,6-Hexamethylenediisocyanate 1,6-Hexamethylene diisocyanate (HDI) Hexanal Hexanal n-Hexane n-Hexane n-Hexane 2-Hexanone 2-Hexanone Hippuric acid Hydrazine Hydrogen bromide Hydrogen chloride Hydrogen cyanide Hydrogen cyanide 3/1 5/2003 Meth No. Method Name 2505 7303 2532 0500 1608 5523 7303 2539 2549 1500 2553 2553 5602 9200 9201 2543 251 8 1003 5522 FURFURYL ALCOHOL ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) GLUTARALDEHYDE PARTICULATES N.O.R. GLYCIDOL GLYCOLS ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) ALDEHYDES, SCREENING VOLATILE ORGANIC CPDS (Screening) HYDROCARBONS, BP 36-216C KETONES II KETONES II CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) HEXACHLOROBUTADIENE HEXACHLORO-1,3-CYCLO PENTA DIENE HYDROCARBONS, HALOGENATED ISOCYANATES Flow Rate (L/min) 0.01 - 0.05 1 -4 Vol. (L) min max 3 - 25 See Ta ble Extraction acet HCl/HNO3 0.01 - 0.08 1 -2 0.01 - 1.0 0.5 - 2 1 -4 4 - 39 7 - 133 5 - 100 5 - 60 See Table CH3CN NA THF MeOH HCl/HNO3 Analytical Technique GC-FID ICP-AES HPLC-UV Grav GC-FID GC-FID ICP-AES 0.01 - 0.05 0.01 - 0.05 5-5 1 -6 tol thermal GC-FID/MS TD/GC-MS 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.2 - 1 NA 1 - 25 1 - 25 12 - 480 CS2 ipa-cs2 ipa-cs2 reagent GC-FID GC-FID GC-FID GC/ECD NA NA NA GC-ECD NA NA I PA/diazom ethane GC-ECD 0.05 - 0.2 0.01 - 0.2 1 - 100 0.25 - 90 hexane hexane GC-ECD GC-ECD 0.01 - 0.2 1 -2 3 - 70 15 - 360 CS2 tryptamine/DMSO GC-FID HPLC-FL 5521 ISOCYANATES, MONOMERIC 1.0 5 - 500 reagents HPLC - ECHD 5525 ISOCYANATES, TOTAL (MAP) 1 -2 1 - 500 MAP HPLC/UV 2539 2549 2549 1500 3800 1300 2555 8301 3503 7903 7903 6010 6017 ALDEHYDES, SCREENING VOLATILE ORGANIC CPDS (Screening) VOLATILE ORGANIC CPDS (Screening) HYDROCARBONS, BP 36-216C ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY KETONES I KETONES I HIPPURIC and METHYL HIPPURIC ACID in urine HYDRAZINE ACIDS, INORGANIC ACIDS, INORGANIC HYDROGEN CYANIDE HYDROGEN CYANIDE 0.01 - 0.05 0.01 - 0.05 5-5 1 -6 0.01 - 0.05 1 - 6 0.01 - 0.2 0.1 - 2.0 4-4 Instr. dep. 0.01 - 1.0 0.01 - 0.2 NA 1 - 10 1 - 10 NA 0.2 - 1.0 0.2 - 0.5 0.2 - 0.5 0.05 - 0.2 0.05 - 2 7 - 100 3 - 100 3 - 100 2 - 90 2 - 90 tol thermal thermal CS2 NA CS2 CS2 Etac reagents HCO3-/CO32HCO3-/CO32HO HO GC-FID/MS TD/GC-MS TD/GC-MS GC-FID FTIR GC-FID GC-FID HPLC-UV VIS IC IC VIS IC-DC Amp Sampler Por Q MCEF SG/DNPH PVC CCT OVS-7 MCEF XAD-2/HMP TD CCT A-CMS A-CMS OVS-2 polyethylene bag PUF pad XAD-2 2 Por T CCT IMP IMP GFF, IMP XAD-2/H M P TD TD CCT Dir. Read CCT A-CMS NA BuB SG SG soda lime SL MF-1 2 NIOSH Manual of Analytical Methods Chemical Hydrogen cyanide Hydrogen flouride Hydrogen flouride Meth No. Method Name 7904 7903 7902 CYANIDES, AEROSOL & GAS ACIDS, INORGANIC FLUORIDES, AEROSOL & GAS Hydrogen flouride 7906 FLUORIDES by IC Hydrogen sulfide Hydroquinone Indeno[1,2,3-cd]pyrene Indeno [1,2,3-cd] pyrene Iodine Indium Iron Iron Iron Iron Isoamyl acetate Isoamyl alcohol Isoamyl alcohol Isobutyl acetate Isobutyl alcohol Isobutyl alcohol Isobutyraldehyde Isocyanates Isocyanates Isophorone Isophorone Isophorone diisocyanate (IPD I) Isopropyl acetate Isopropyl acetate Isopropyl alcohol Isopropyl alcohol Isopropyl ether Isopropyl glycidyl ether Isovaleraldehyde Isovaleraldehyde Kepone Kerosene 6013 5004 5506 5515 6005 7303 9102 7301 7303 7300 1450 1402 1405 1450 1401 1405 2539 5521 5522 2508 2556 5525 HYDROGEN SULFIDE (withdrawn) HYDROQUINONE POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS IODINE ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) ELEMENTS on WIPES ELEMENTS by ICP (AQUA REGIA ASHING) ELEMENTS by ICP (HOT BLOCK/HCl/HNOj DIGESTION) ELEMENTS by ICP ESTERS I ALCOHOLS III ALCOHOLS COMBINED ESTERS I ALCOHOLS II ALCOHOLS COMBINED ALDEHYDES, SCREENING ISOCYANATES, MONOMERIC ISOCYANATES ISOPHORONE ISOPHORONE ISOCYANATES, TOTAL (MAP) 1454 1460 2549 1400 1618 1620 2018 2539 5508 1550 ISOPROPYL ACETATE ISOPROPYL ACETATE VOLATILE ORGANIC CPDS (Screening) ALCOHOLS I ISOPROPYL ETHER ISOPROPYL GLYCIDYL ETHER ALIPHATIC ALDEHYDES ALDEHYDES, SCREENING KEPONE NAPHTHAS Flow Rate (L/min) 0.5 - 1.0 0.2 - 0.5 1 -2 Vol. (L) min max 7 - 100 3 - 100 12 - 800 Extraction KOH HCO3-/CO32NaOH 1 -2 0.1 - 1.5 1 - 800 1.2 - 40 NaOH NH4OH/h2O2 1 -4 2.0 30 - 180 200 - 1000 acetic acid acetonitrile Analytical Technique ISE IC ISE IC IC HPLC-UV HPLC-FL/UV Sampler MCEF SG MCEF & pad w/Na2CO3 MCEF & pad w/Na2CO3 PTFE & CCT (lg) MCEF PTFE & XAD-2 2.0 0.5 - 1.0 1 -4 200 - 1000 varies 15 - 225 See Table Na2CO3 HCl/HNO3 GC-FID IC ICP-AES PTFE & XAD-2 CCT w/alkali MCEF NA 1 -4 NA 5 - 100 NA HCl/HNO3 ICP-AES ICP-AES Wipe MCEF 1 -4 See Table HCl/HNO3 ICP-AES MCEF 1 -4 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 1.0 1 -2 0.01 - 1.0 0.01 - 1 1 -2 5 - 100 1 - 10 1 - 10 1 - 10 1 - 10 2 - 10 2 - 10 5-5 5 - 500 15 - 360 2 - 25 2 - 25 1 - 500 HNO3/HClO4 CS2 ipa/cs2 ipa-cs2 CS2 ipa/cs2 ipa-cs2 tol reagents tryptamine/DMSO CS2 DEE MAP ICP-AES GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID/MS HPLC-ECHD HPLC-FL/ECHD GC-FID GC-FID HPLC/UV MCEF CCT CCT CCT CCT CCT CCT XAD-2/H M P IMP IMP PCT XAD GFF, IMP 0.02 - 0.2 0.02 - 0.2 0.01 - 0.05 0.1 - 9 0.1 - 9 1 -6 CS2 CS2-Meth thermal GC-FID GC-FID TD/GC-MS CCT CCT TD 0.01 - 0.2 0.01 - 0.05 0.01 - 0.2 0.1 - 1.5 0.01 - 0.05 0.5 - 1.0 0.01 - 0.2 0.2 - 3 0.1 - 3 1 - 30 1 - 15 5-5 50 - 600 1.3 - 20 2-butanone/CS2 CS2 CS2 ACN tol bz/MeOH CS2 GC-FID GC-FID GC-FID HPLC/UV GC-FID/MS GC-ECD GC-FID CCT CCT CCT SG-DNPH XAD-2/H M P MCEF & IMP CCT 3/1 5/2003 MF-13 NIOSH Manual of Analytical Methods Chemical Lanthanum Lanthanum Lead Lead Lead Lead Lead Lead Lead Lead Lead Lead Lead Lead sulfide Limonene Limonene Lindane Lithium Lithium Lithium hydroxide Magnesium Magnesium Magnesium Malathion Maleic Anhydride Maneb Maneb Manganese Manganese Manganese Manganese MBK MDI (4,4'-methylenebisphenyl isocyanate) MDI (4,4'-methylenebisphenyl isocyanate) Mercury 3/1 5/2003 Meth No. Method Name 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 9102 ELEMENTS on WIPES 7082 LEAD by FAAS 7702 LEAD BY FIELD PORTABLE XRF 7105 LEAD by GFAAS 7701 LEAD BY ULTRASOUND/ASV 7300 ELEMENTS by ICP 7700 LEAD in Air by Chemical Spot Test 9100 LEAD in Surface Wipe Samples 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 9102 ELEMENTS on WIPES 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 9105 LEAD in DUST WIPES by Chemical Spot Test 7505 LEAD SULFIDE 1552 TERPENES 2549 VOLATILE ORGANIC CPDS (Screening) 5502 ALDRIN and LINDANE 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 7401 ALKALINE DUSTS 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 5600 ORGANOPHOSPHORUS PESTICIDES 3512 MALEIC ANHYDRIDE 3601 MANEB 3600 MANEB 7300 ELEMENTS by ICP 9102 ELEMENTS on WIPES 7301 ELEMENTS by ICP (AQUA REGIA ASHING) 7303 ELEMENTS by ICP (HOT BLOCK/HCl/HNO3 DIGESTION) 1300 KETONES I 5521 ISOCYANATES, MONOMERIC Flow Rate (L/min) 1 -4 Vol. (L) min max 5 - 1000 Extraction HCl/HNO3 NA 1 -4 1 -4 1 -4 1 -4 1 -4 2 NA 1 -4 NA NA 200 - 1500 HNO3/H2O2 570 - 1900 NA 1 - 1500 HNO3/H2O2 20 - 1500 1250 -2000 HNO3 HNO3/HClO4 10 - 240 NA HNO3/HClO4 50 - 2000 HCl/HNO3 NA 1 -4 NA See Table NA HCl/HNO3 NA NA NA 1.7 or 2.2 0.01 - 0.2 0.01 - 0.05 600 - 1000 2 - 30 1 -6 THF CS2 thermal 0.2 - 1.0 1 -4 1 -4 18 - 240 100 - 2000 100 - 2000 isooctane HNO3/HClO4 HCl/HNO3 1 -4 1 -4 1 -4 70 - 1000 5 - 67 5 - 67 HCl HNO3/HClO4 HCl/HNO3 1 -4 See Table HCl/HNO3 0.2 - 1 0.2 - 1.5 NA NA 1 -4 NA 1 -4 12 - 60 40 - 500 NA NA 5 - 200 NA 5 - 200 tol/acet HO NA Cys/EDTA HNO3/HClO4 NA HCl/HNO3 1 -4 See Table HCl/HNO3 0.01 - 0.2 1.0 1 - 10 5 - 500 CS2 reagents 5522 ISOCYANATES 6009 MERCURY 1 -2 15 - 360 0.15 - 0.25 2 - 100 tryptamine HNO3/HCl Analytical Technique ICP-AES Sampler MCEF ICP-AES FAAS XRF (port) GFAAS Port ASV ICP-AES Spot AAS; ICP ICP-AES Wipe MCEF MCEF MCEF MCEF MCEF MCEF Wipes MCEF ICP-AES ICP-AES Wipe MCEF Spot Wipe XRD GC-FID TD/GC-MS CYC & PVC CCT TD GC-ECN ICP-AES ICP-AES GFF & BuB MCEF MCEF Titration ICP-AES ICP-AES PTFE MCEF MCEF ICP-AES MCEF GC-FPD HPLC-UV HPLC-UV HPLC-UV ICP-AES ICP-AES ICP-AES OVS-2 BuB Hand wash Patch MCEF Wipe MCEF ICP-AES MCEF GC-FID HPLC-ECHD CCT IMP HPLC-FL/ECHD IMP AAS-cold vap Hopcalite MF-1 4 NIOSH Manual of Analytical Methods Chemical Mercaptans Mesityl oxide Mesityl oxide Metals in air Metalworking Fluids Methanal Methamidophos Methanol Methanol Methanol Methiocarb Methomyl Metolachlor Metolachlor Metolachlor 2-Methoxyethyl acetate 2-Methoxyethanol Methyl acetate Methyl acrylate Methyl acrylate Methyl alcohol Methylal 4-M ethylbenzenesulfonic acid W-Methyl-y-butyrolactone Methyl-(n-amyl)-ketone Methylarsonic acid Methyl bromide Methyl cellosolve Methyl cellosolve acetate Methyl chloride Methyl chloroform Methyl chloroform Methyl cyanide Methyl cyclohexane Methylcyclohexanol Methyl cyclohexanone 4,4'-Methylene-bis (cyclo hexyl isocyanate) (HMDI) Meth No. Method Name 2542 1301 2553 7300 5524 2016 5600 2000 2549 3800 5601 5601 5602 9200 9201 1451 1403 1458 1459 2552 2000 1611 5043 MERCAPTANS KETONES II KETONES II ELEMENTS by ICP METALWORKING FLUIDS (MWF) ALL CATEGORIES FORMALDEHYDE ORGANOPHOSPHORUS PESTICIDES METHANOL VOLATILE ORGANIC CPDS (Screening) ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY ORGANONITROGEN PESTICIDES ORGANONITROGEN PESTICIDES CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) METHYL CELLOSOLVE ACETATE ALCOHOLS IV METHYL ACETATE METHYL ACRYLATE METHYL ACRYLATE METHANOL METHYLAL p-TOLUENESULFONIC ACID Flow Rate (L/min) 0.1 - 0.2 0.01 - 0.2 0.01 - 0.2 1 -4 1.6 - 2.0 Vol. (L) min max 10 - 150 1 - 25 1 - 25 var- 2000 1000 - ND 0.1 - 1.5 0.2 - 1 0.02 - 0.2 0.01 - 0.05 1 - 15 12 - 240 1 -5 1 -6 0.1 - 20 Instr. dep. 0.1 - 1 0.1 - 1 0.2 - 1 var- 480 var- 480 12 - 480 NA NA NA NA 0.01 - 0.2 0.01 - 0.05 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.02 - 0.2 0.01 - 0.2 1 -3 0.2 - 20 6 - 50 0.2 - 10 1 -5 1 -5 1 -5 1 -3 10 - 1000 Extraction HCl/DCE MeOH/CS2 ipa-cs2 HNO3/HClO4 DCM/MeOH/Tol MeOH acetonitrile tol/acet H2O/IPA thermal Analytical Technique GC-FPD GC-FID GC-FID ICP-AES Grav HPLC-UV GC-FPD GC-FID TD/GC-MS NA FTIR reagent reagent reagent HPLC-UV HPLC-UV GC/ECD NA GC-ECD I PA/diazom ethane GC-ECD CS2 MeOH/CH2Cl2 CS2 CS2 CS2 H2O/IPA hexane IPA/H20 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID HPLC-UV Sampler GFF/HgAc CCT A-CMS MCEF PTF E/CYC SG/DNPH OVS-2 SG TD Dir. Read OVS-2 OVS-2 OVS-2 polyethylene bag PUF pad CCT CCT CCT CCT A-CMS SG CCT GFF 1302 1301 5022 2520 1403 1451 1001 1003 2549 1606 1500 1404 2521 5525 W-M ETHYL-2-PYRROLIDI NONE KETONES II ARSENIC, ORGANOMETHYL BROMIDE ALCOHOLS IV METHYL CELLOSOLVE ACETATE METHYL CHLORIDE HYDROCARBONS, HALOGENATED VOLATILE ORGANIC CPDS (Screening) ACETONITRILE HYDROCARBONS, BP 36-216C METHYLCYCLOHEXANOL METHYLCYCLOHEXANONE ISOCYANATES, TOTAL (MAP) 0.05 - 0.2 0.01 - 0.2 1 -3 0.01 - 0.1 0.01 - 0.05 0.01 - 0.2 0.01 - 0.1 0.01 - 0.2 0.01 - 0.05 0.5 - 125 1 - 25 50 - 1000 1 -5 6 - 50 0.2 - 20 0.4 - 3 0.1 - 8 1 -6 CH2Cl2/MeOH MeOH/CS2 buffer CS2 MeOH/CH2Cl2 CS2 CH2Cl2 CS2 thermal 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 1 -2 3 - 25 4-4 1 - 15 1 -6 1 - 500 MECl/MEOH CS2 CH2Cl2 acet MAP GC-NPD or FID GC-FID IC-HYAAS GC-AED GC-FID GC-FID GC-FID GC-FID TD/GC-MS CCT CCT PTFE PCT(2) + drytube CCT CCT 2 CCT (lg + sm) CCT TD GC-FID GC-FID GC-FID GC-FID HPLC/UV CCT CCT CCT Por Q GFF, IMP 3/1 5/2003 MF-1 5 NIOSH Manual of Analytical Methods Chemical 4,4-Methylene-bis (phenyl isocyanate) (M DI) Methylene chloride Methylene chloride Methylene chloride 4,4'-M ethyl enediani line 4,4-Methylene diphenyl diisocyanate Methyl ethyl ketone Methyl ethyl ketone Methyl ethyl ketone Methyl ethyl ketone peroxide 5-Methyl-3-heptanone 5-Methyl-3-heptanone Methyl hippuric acid Methyl iodide Methyl isoamyl acetate Methyl isobutyl carbinol Methyl isobutyl carbinol Methyl isobutyl ketone Methyl isobutyl ketone Methyl isobutyl ketone Methyl mercaptan Methyl methacrylate Methyl parathion Methyl phenol N-m ethyl- 2-pyrroli din one a-Methyl styrene P-Methylstyrene Methyl tert-butyl ether Methyltin chloride Mevinphos Mineral spirits Molybdenum Molybdenum Molybdenum Molybdenum Monocrotophos Meth No. Method Name 5525 ISOCYANATES, TOTAL (MAP) Flow Rate (L/min) 1 -2 Vol. (L) min max 1 - 500 Extraction MAP 1005 METHYLENE CHLORIDE 2549 VOLATILE ORGANIC CPDS (Screening) 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 5029 4,4'-METHYLENEDIANILINE 5522 ISOCYANATES 0.01 - 0.2 0.01 - 0.05 0.5 - 2.5 1 -6 0.1 - 20 Instr. dep. 1 -2 1 -2 10 - 1000 15 - 360 CS2 thermal NA KOH/MeOH tryptamine 2549 VOLATILE ORGANIC CPDS (Screening) 2500 METHYL ETHYL KETONE 2555 KETONES I 3508 METHYL ETHYL KETONE PEROXIDE 0.01 - 0.05 1 - 6 thermal 0.01 - 0.2 0.01 - 0.2 0.5 - 0.2 0.25 - 12 1 - 10 52 - 520 CS2 CS2 reagent 1301 KETONES II 2553 KETONES II 8301 HIPPURIC and METHYL HIPPURIC ACID in urine 1014 METHYL IODIDE 1450 ESTERS I 1402 ALCOHOLS III 1405 ALCOHOLS COMBINED 2549 VOLATILE ORGANIC CPDS (Screening) 1300 KETONES I 2555 KETONES I 2542 MERCAPTANS 2537 METHYL and ETHYL METHACRYLATE 5600 ORGANOPHOSPHORUS PESTICIDES 2549 VOLATILE ORGANIC CPDS (Screening) 1302 N-M ETHYL-2-PYRROLIDI NONE 1501 HYDROCARBONS, AROMATIC 1501 HYDROCARBONS, AROMATIC 1615 METHYL tert-BUTYL ETHER 5526 METHYLTIN CHLORIDES 5600 ORGANOPHOSPHORUS PESTICIDES 1550 NAPHTHAS 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (Aqua Regia Ashing) 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 9102 ELEMENTS on WIPES 5600 ORGANOPHOSPHORUS PESTICIDES 0.01 - 0.2 0.01 - 0.2 NA 1 - 25 1 - 25 NA MeOH/CS2 ipa-cs2 Etac 0.01 - 1.0 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 15 - 50 1 - 10 1 - 10 1 - 10 1 -6 tol CS2 ipa/cs2 ipa-cs2 thermal 0.01 - 0.2 0.01 - 0.2 0.1 - 0.2 0.01 - 0.05 0.2 - 1 0.01 - 0.05 1 - 10 1 - 10 10 - 150 1 -8 12 - 240 1 -6 CS2 CS2 HCl/DCE CS2 tol/acet thermal 0.05 - 0.2 0.01 - 0.2 0.01 - 0.2 0.1 - 0.2 0.25 - 1 0.2 - 1.0 0.01 - 0.2 1 -4 1 -4 0.5 - 125 1 - 30 1 - 30 2 - 96 15 - 75 12 - 240 1.3 - 20 5 - 67 5 - 67 CH2Cl2/MeOH CS2 CS2 CS2 AAA tol/acet CS2 HNO3/HClO4 HCl/HNO3 1 -4 See Ta ble HCl/HNO3 NA 0.2 - 1 NA 12 - 240 NA tol/acet Analytical Technique HPLC/UV Sampler GFF, IMP GC-FID TD/GC-MS 2 CCT TD FTIR Dir. Read HPLC-UV HPLC-FL/ECHD gff/h2so4 IMP TD/GC-MS TD GC-FID GC-FID VIS Carbon beads A-CMS IMP GC-FID GC-FID HPLC-UV CCT A-CMS NA GC-FID GC-FID GC-FID GC-FID TD/GC-MS CCT CCT CCT CCT TD GC-FID GC-FID GC-FPD GC-FID GC-FPD TD/GC-MS CCT A-CMS GFF/HgAc XAD OVS-2 TD GC-NPD or FID GC-FID GC-FID GC-FID GC-FPD GC-FPD GC-FID ICP-AES ICP-AES CCT CCT CCT 2 CCT (lg) OVS OVS-2 CCT MCEF MCEF ICP-AES MCEF ICP-AES GC-FPD Wipe OVS-2 3/1 5/2003 MF-1 6 NIOSH Manual of Analytical Methods Chemical Monomethylaniline Monom ethylhydrazine Mycobacterium Naphtha (coal tar) Naphthalene Naphthalene Naphthalene 1,5-Naphthalene diisocyanate (NDI) Naphthylamines Neodymium Nickel Nickel Nickel Nickel Nickel carbonyl Nicotine Nicotine Nitric acid Nitric oxide p-Nitroaniline Nitrobenzene Nitrobenzene Nitrobenzol p-Nitrochlorobenzene Nitroethane Nitrogen dioxide Nitrogen dioxide Nitrogen peroxide Nitroglycerin Nitromethane 2-Nitropropane 1 -Nitropyrene Nitrosamines p-Nitrotoluene Nitrous oxide 3/1 5/2003 Meth No. Method Name 3511 3510 0900 1550 1501 5506 5515 5525 MONOMETHYLANILINE MONOM ETHYLHYDRAZINE MYCOBACTERIUM TUBERCULOSIS NAPHTHAS HYDROCARBONS, AROMATIC POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS ISOCYANATES, TOTAL (MAP) Flow Rate (L/min) 0.2 - 1.0 0.5 - 1.5 >4 0.01 - 0.2 0.01 - 1.0 2.0 Vol. (L) min max Extraction 11 - 100 NaOH 3 - 20 PMA/HCl varies PCR 1.3 - 20 CS2 100 - 200 CS2 200 - 1000 acetonitrile 2.0 200 - 1000 varies 1 -2 1 - 500 MAP 5518 7303 7300 7301 7303 9102 6007 2544 2551 7903 6014 NAPHTHYLAMINES ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) ELEMENTS by ICP ELEMENTS by ICP (Aqua Regia Ashing) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) ELEMENTS on WIPES NICKEL CARBONYL NICOTINE NICOTINE ACIDS, INORGANIC NITRIC OXIDE & NITROGEN DIOXIDE 0.2 - 0.8 1 -4 1 -4 1 -4 1 -4 NA 0.05 - 0.2 1.0 0.1 - 1.0 0.2 - 0.5 0.025 30 - 100 See Table acetic a /IPA HCl/HNO3 25 - 1000 5 - 1000 HNO3/HClO4 HCl/HNO3 See Table HCl/HNO3 NA 7 - 80 60 - 400 0.5 - 600 3 - 100 1.5 - 6 NA H NO3 EtAc ethyl acetate hco3-/co32reagent 5033 2005 2017 2017 2005 2526 6014 6700 6700 2507 2527 2528 2560 2522 2005 3800 p-NITROANILINE 1 -3 NITROAROMATIC COMPOUNDS 0.01 - 1 ANILINE, o-TOLUIDINE, AND NITROBENZENE 0.2 ANILINE, o-TOLUIDINE, AND NITROBENZENE 0.2 NITROAROMATIC COMPOUNDS 0.01 - 1 NITROETHANE 0.01 - 0.05 NITRIC OXIDE & NITROGEN DIOXIDE 0.025 - 0.2 NITROGEN DIOXIDE NA NITROGEN DIOXIDE NA NITROGLYCERIN & ETHYLENE GLYCOL 0.2 - 1.0 DINITRATE NITROMETHANE 0.01 - 0.05 2-NITROPROPANE 0.01 - 0.05 1 -NITROPYRENE in DIESEL PARTICULATES 1.0 - 2.0 NITROSAMINES 0.2 - 2.0 NITROAROMATIC COMPOUNDS 0.01 - 0.2 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 0.1 - 20 20 10 - 150 5 - 50 5 - 50 1 - 150 1.5 - 3 1.5 - 6 NA NA 3 - 100 1.2 - 3 0.1 - 2 480 - 960 15 - 1000 1 - 30 Instr. dep. IPA MeOH ethanol ethanol MeOH EtAc reagent reagent reagent ethanol EtAc EtAc Tol MeOH/CH2Cl2 MeOH NA Analytical Technique GC-FID VIS reagent GC-FID GC-FID HPLC-FL/UV GC-FID HPLC-UV GC-FID ICP-AES ICP-AES ICP-AES ICP-AES ICP-AES GFAAS GC-NPD GC-NPD IC VIS HPLC-UV GC-FID GC-FID GC-FID GC-FID GC-FID VIS VIS VIS GC-ECD GC-FPD GC-FID GC/NCD GC-TEA GC-FID FTIR Sampler BuB/H2SO4 BuB/HCl PTFE CCT CCT PTFE & XAD-2 PTFE & XAD-2 GFF, IMP GFF & SG MCEF MCEF MCEF MCEF Wipe CCT (low Ni) XAD-2 XAD-4 SG (washed) MS w/TEA & oxidizer MCEF SG GFF + SG GFF + SG SG 2XAD-2 MS w/TEA Diffusive Diffusive Tenax-GC Chrom 106 Chrom 106 GFF TD tube SG Dir. Read MF-1 7 NIOSH Manual of Analytical Methods Chemical Nitrous oxide n-Nonane NMP Nuisance dusts n-Octane n-Octane Octam ethylcy clotetra siloxane 1 -Octanethiol Oil mist (mineral) Organonitrogen pesticides Orga nophosphorus Pesticides Oxamyl Oxygen PAC Palladium Paraquat Parathion Particulates N.O.R. Particulates N.O.R. Pentachlorobenzene Pentachloroethane Pentachlorophenol Pentamidine n-Pentane n-Pentane 2-Pentanone 2-Pentanone Perchloroethylene Perchloroethylene Pesticides Pesticides Petroleum ether/naphtha Phenanthrene Phenanthrene Phenol Meth No. Method Name 6600 1500 1302 0500 2549 1500 2549 2510 5026 5601 5600 NITROUS OXIDE HYDROCARBONS, BP 36-216oC N-Methyl-2-Pyrrolidinone PARTICULATES N.O.R. VOLATILE ORGANIC CPDS (Screening) HYDROCARBONS, BP 36-216C VOLATILE ORGANIC CPDS (Screening) 1 -OCTAN ETHIOL OIL MIST, MINERAL ORGANONITROGEN PESTICIDES ORGANOPHOSPHORUS PESTICIDES 5601 6601 5800 7303 5003 5600 0500 0600 ORGANONITROGEN PESTICIDES OXYGEN POLY AROMATIC COMPOUNDS, TOTAL (PACs) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) PARAQUAT ORGANOPHOSPHORUS PESTICIDES PARTICULATES N.O.R., TOTAL PARTICULATES, N.O.R, RESPIRABLE 5517 251 7 5512 5032 2549 1500 1300 2555 3704 2549 5600 5601 1550 5506 5515 2549 POLYCHLOROBENZENES PENTACHLOROETHANE PENTACHLOROPHENOL PENTAMIDINE ISETH IONATE VOLATILE ORGANIC CPDS (Screening) HYDROCARBONS, BP 36-216C KETONES I KETONES I PERCHLOROETHYLENE (port GC) in exhaled breath and air VOLATILE ORGANIC CPDS (Screening) ORGANOPHOSPHORUS PESTICIDES ORGANONITROGEN PESTICIDES NAPHTHAS POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC POLYNUCLEAR AROMATIC HYDROCARBONS VOLATILE ORGANIC CPDS (Screening) Flow Rate (L/min) Vol. (L) min max NA 80% vol 0.01 - 0.2 4-4 0.05 - 0.2 0.5 - 125 1 -2 7 - 133 0.01 - 0.05 1 - 6 Extraction NA CS2 CH2Cl2/MeOH NA thermal 0.01 - 0.2 0.01 - 0.05 4-4 1 -6 CS2 thermal 0.01 - 0.2 1 -3 0.1 - 1 0.2 - 1 1 - 15 20 - 500 varies-480 12 - 240 acet CCl4 reagent tol/acet 0.1 - 1 NA 1 -2 var- 480 1 - NA 5 - 1000 reagent NA hexane 1 -4 See Table HCl/HNO3 1 -4 40 - 1000 0.2 - 1.0 12 - 240 1 -2 7 - 133 1.7, 2.2, 2.5 20 - 400 0.01 - 0.2 3 - 12 0.01 - 0.2 1 - 10 0.5 - 1.0 48 - 480 1 -2 50 - 1500 0.01 - 0.05 1 - 6 HO tol/acet NA NA hexane hexane MeOH reagents thermal 0.01 - 0.2 0.01 - 2.0 0.01 - 0.2 0.02 - 5 4-4 1 - 10 1 - 10 < 80% cap CS2 CS2 CS2 NA 0.01 - 0.05 1 - 6 thermal 0.2 - 1 0.1 - 1 0.01 - 0.2 2.0 12 - 240 tol/acet var- 480 reagent 1.3 - 20 CS2 200 - 1000 ac etonitrile 2.0 200 - 1000 varies 0.01 - 0.05 1 - 6 thermal Analytical Technique IR GC-FID GC-FID/NPD GRAV TD/GC-MS Sampler air bag CCT CCT PVC TD GC-FID TD/GC-MS CCT TD GC-FPD IR HPLC-UV GC-FPD Tenax GC PVC or MCE OVS-2 OVS-2 HPLC, UV Sensor FI-FL OVS-2 portable PTFE + XAD-2 ICP-AES MCEF HPLC-UV GC-FPD GRAV Grav. PTFE OVS-2 PVC CYC & PVC GC-ECD GC-ECD HPLC-UV HPLC/FL TD/GC-MS PTFE & XAD-2 Por R MCEF & BuB PVC/opaque TD GC-FID GC-FID GC-FID GC (port)-PID CCT CCT A-CMS air bag TD/GC-MS TD GC-FPD HPLC-UV GC-FID HPLC-FL/UV OVS-2 OVS-2 CCT PTFE & XAD-2 GC-FID PTFE & XAD-2 TD/GC-MS TD 3/1 5/2003 MF-18 NIOSH Manual of Analytical Methods Chemical Phenol Phenyl ether Phenyl ether-diphenyl mixture Phenyl glycidyl ether Phenylhydrazine Phorate Phosdrin (mevinphos) Phosphine Phosphoric acid Phosphorus Phosphorus Phosphorus Phosphorus Phosphorus Phosphorus trichloride Pinene Pinene Platinum PAH Poly acrylate PACs Platinum Polychloro biphenyl (42% & 54% Cl) Potassium Potassium Potassium hydroxide Progesterone Propazine Propham Propionaldehyde Propionaldehyde Propoxur n-Propyl acetate n-Propyl alcohol n-Propyl alcohol Propylene dichloride 3/1 5/2003 Meth No. Method Name 2546 1617 2013 CRESOLS and PHENOL PHENYL ETHER PHENYL ETHER-DIPHENYL MIXTURE Flow Rate (L/min) 0.01 - 0.1 0.01 - 0.2 0.01 - 0.2 Vol. (L) min max 1 - 24 1 - 50 1 - 40 Extraction MeOH CS2 bz Analytical Technique GC-FID GC-FID GC-FID Sampler XAD-7 CCT SG 1619 PHENYL GLYCIDYL ETHER 3518 PHENYLHYDRAZINE 5600 ORGANOPHOSPHORUS PESTICIDES 5600 ORGANOPHOSPHORUS PESTICIDES 6002 PHOSPHINE 7903 ACIDS, INORGANIC 7300 ELEMENTS by ICP 7905 PHOSPHORUS 7301 ELEMENTS by ICP (Aqua Regia Ashing) 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 9102 ELEMENTS on WIPES 6402 PHOSPHORUS TRICHLORIDE 1552 TERPENES 2549 VOLATILE ORGANIC CPDS (Screening) 7300 ELEMENTS by ICP 5506 POLYNUCLEAR AROMATIC HYDROCARBONS 5035 SUPER ABSORBENT POLYMER 5800 POLYCYCLIC AROMATIC COMPOUNDS, TOTAL 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 5503 POLYCHLOROBIPHENYLS 0.01 - 1 0.2 - 1.0 0.2 - 1 0.2 - 1 0.01 - 0.2 0.2 - 0.5 1 -4 0.01 - 0.2 1 -4 80 - 150 25 - 120 12 - 240 12 - 480 1 - 16 3 - 100 50 - 2000 5 - 100 25 - 2000 CS2 PMA tol/acet tol/acet reagent HCO3-/CO32HNO3/HClO4 xylene HCl/HNO3 1 -4 See Table HCl/HNO3 NA 0.05 - 0.2 0.01 - 0.2 0.01 - 0.05 NA 11 - 100 2 - 30 1 -6 NA reagents CS2 thermal 1 -4 2.0 13 - 2000 200 - 1000 HNO3/HClO4 varies 1 -2 1 -2 50 - 1500 5 - 1000 Cu(Ac)2 hexane 1 -4 See Table HCl/HNO3 0.05 - 0.2 1 - 50 hexane GC-FID VIS GC-FPD GC-FPD VIS IC ICP-AES GC-FPD ICP-AES ICP-AES ICP-AES VIS GC-FID TD/GC-MS ICP-AES HPLC-FL/UV ICP or AAS FI-FL ICP-AES GC-ECD CCT BuB/HCl OVS-2 OVS-2 SG/Hg(CN) SG (washed) MCEF Tenax GC MCEF MCEF Wipe BuB/H2O CCT TD MCEF PTFE & XAD-2 PVC MCEF GFF & Florisil 7301 7303 7401 5044 8315 5601 2539 201 8 5601 1450 1401 1405 1013 ELEMENTS by ICP (Aqua Regia Ashing) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) ALKALINE DUSTS ESTROGENIC COMPOUNDS TRIAZINE HERBICIDES and their METABOLITES ORGANONITROGEN PESTICIDES ALDEHYDES, SCREENING ALIPHATIC ALDEHYDES ORGANONITROGEN PESTICIDES ESTERS I ALCOHOLS II ALCOHOLS COMBINED PROPYLENE DICHLORIDE 1 -4 5 - 1000 HCl/HNO3 1 -4 See Ta ble HCl/HNO3 1 -4 1 NA 70 - 1000 150 - 1000 NA HCl Meth NA 0.1 - 1 0.01 - 0.05 0.1 - 1.5 0.1 - 1 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 var- 480 5-5 1 - 15 var- 480 1 - 10 1 - 10 1 - 10 0.1 - 3.5 reagent tol ACN reagent CS2 ipa/cs2 ipa-cs2 acet/cychex ICP-AES ICP-AES titration HPLC-UV GC-MSD HPLC, UV GC-FID/MS HPLC-UV HPLC, UV GC-FID GC-FID GC-FID GC-ECN MCEF MCEF PTFE PTFE Urine OVS-2 XAD-2/H M P SG-DNPH OVS-2 CCT CCT CCT PCT MF-1 9 NIOSH Manual of Analytical Methods Chemical Propylene glycol Propylene glycol monomethyl ether Propylene glycol monomethyl ether acetate Propylene oxide Pyrene Pyrene Pyrethrum Pyridine Resorcinol Ribavirin Ronnel Rotenone Rubber solvent Selenium Selenium Selenium Selenium Silica, amorphous Meth No. Method Name 5523 2554 GLYCOLS GLYCOL ETHERS 2554 GLYCOL ETHERS 1612 5506 5515 5008 1613 5701 5027 5600 5007 1550 7300 7301 7303 9102 7501 PROPYLENE OXIDE POLYNUCLEAR AROMATIC HYDROCARBONS by HPLC PO LYN UC LEA R ARO MATIC HYDROCARBONS PYRETHUM PYRIDINE RESORCINOL RIBAVIRIN ORGANOPHOSPHORUS PESTICIDES ROTENONE NAPHTHAS ELEMENTS by ICP ELEMENTS by ICP (Aqua Regia Ashing) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) ELEMENTS on WIPES SILICA, AMORPHOUS Flow Rate (L/min) 0.5 - 2 0.1 - 0.2 Vol. (L) min max 5 - 60 3 - 25 Extraction MeOH MeCl2/Meth 0.1 - 0.2 3 - 25 MeCl2/Meth 0.01 - 0.2 2.0 0.5 - 5 200 - 1000 CS2 acetonitrile 2.0 200 - 1000 varies 1 -4 0.01 - 1.0 0.2 - 1 1 -4 0.2 - 1 1 -4 0.01 - 0.2 1 -4 1 -4 20 - 400 18 - 150 5 - 160 5 - 1000 12 - 60 8 - 400 1.3 - 20 5 - 2000 13 - 2000 ch3cn CH2Cl2 MeOH H2SO4 tol/acet CH3CN CS2 HNO3/HClO4 HCl/HNO3 1 -4 See Table HCl/HNO3 NA 1.7 or 2.2 NA 50 - 400 NA ash Analytical Technique GC-FID GC-FID GC-FID GC-FID HPLC-FL/UV GC-FID HPLC-UV GC-FID GC-FID HPLC-UV GC-FPD HPLC-UV GC-FID ICP-AES ICP-AES ICP-AES ICP-AES XRD Silica, crystalline Silica, crystalline Silica, crystalline Silicon dioxide Silica in coal mine dust Silver Silver Silver Simazine Simazine Simazine Sodium Sodium hexa fluoro-alum inate 7500 SILICA, CRYSTALLINE, by XRD 7601 SILICA, CRYSTALLINE 7602 SILICA, CRYSTALLINE (IR) 7500 SILICA, CRYSTALLINE, by XRD. 7603 QUARTZ in coal mine dust 7300 7301 9102 5602 9200 9201 7303 7902 ELEMENTS by ICP ELEMENTS by ICP (Aqua Regia Ashing) ELEMENTS on WIPES CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) FLUORIDES, aerosol & gas 1.7, 2.2, 2.5 1.7, 2.2, 2.5 1.7, 2.2, 2.5 1.7, 2.2, 2.5 1.7, 2.2, 2.5 1 -4 1 -4 NA 0.2 - 1 NA NA 1 -4 1 -2 400 - 1000 ash or THF XRD 400 - 800 H3PO4/HF VIS 400 - 800 ash IR 400 - 1000 ash or THF XRD 300 - 1000 ash IR 250 - 2000 250 - 2000 hno3+ HCl/HNO3 ICP-AES ICP-AES NA 12 - 480 NA reagent ICP-AES GC/ECD NA NA GC-ECD NA IPA/diazomethane GC-ECD See Ta ble HCl/HNO3 ICP-AES 12 - 800 NaOH ISE Sampler OVS-7 A-747 A-74 7 CCT PTFE & XAD-2 PTFE & XAD-2 GFF CCT OVS-7 GFF OVS-2 PTFE CCT MCEF MCEF MCEF Wipe PVC (total) PVC&CYC CYC & PVC CYC & MCE or PVC CYC & MCE or PVC CYC & PVC CYC & PVC MCEF MCEF Wipe OVS-2 polyethylene bag PUF pad MCEF MCEF& pad w/Na2CO3 3/1 5/2003 MF-20 NIOSH Manual of Analytical Methods Chemical Sodium hexafluoro-alum inate Sodium hydroxide Stibine Stoddard solvent Strontium Strontium Strontium Strychnine Styrene Styrene Sulfur dioxide Meth No. Method Name 7906 FLUORIDES by IC Flow Rate (L/min) 1 -2 Vol. (L) min max 120 - 800 Extraction NaOH 7401 6008 1550 7301 7303 9102 5016 1501 3800 6004 ALKALINE DUSTS STIBINE NAPHTHAS ELEMENTS by ICP (Aqua Regia Ashing) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) ELEMENTS on WIPES STRYCHNINE HYDROCARBONS, AROMATIC ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY SULFUR DIOXIDE 1 -4 0.01 - 0.2 0.01 - 0.2 1 -4 1 -4 NA 1 -3 0.01 - 1.0 0.1 - 20 0.5 - 1.5 70 - 1000 4 - 50 1.3 - 20 10 - 1000 HCl HCl CS2 HCl/HNO3 See Table HCl/HNO3 NA 70 - 1000 1 - 14 Instr. Dep. NA reagents CS2 NA 4 - 200 HCO3-/CO32- Sulfur hexafluoride 6602 SULFUR HEXAFLUORIDE Sulfuric acid 7903 ACIDS, INORGANIC Sulfuryl fluoride 6012 SULFURYL FLUORIDE Sulprofos 5600 ORGANOPHOSPHORUS PESTICIDES Super absorbent polymer 5035 SUPER ABSORBENT POLYMER Simazine 8315 TRIAZINE HERBICIDES and their METABOLITES 2,4,5 -T 5001 2,4-D and 2,4,5-T TB 0900 MYCOBACTERIUM TUBERCULOSIS, AIRBORNE Tellurium 7300 ELEMENTS by ICP Tellurium 7301 ELEMENTS by ICP (Aqua Regia Ashing) Tellurium 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) Tellurium 9102 ELEMENTS on WIPES Terbufos 5600 ORGANOPHOSPHORUS PESTICIDES Terpenes 1552 TERPENES o-Terphenyl 5021 o-TERPHENYL 1,1,2,2-Tetrabromo ethane 2003 1,1,2,2-TETRABROMOETHANE Tetrabutyltin 5504 ORGANOTIN COMPOUNDS 1,2,4,5-Tetra chlorobenzene 5517 POLYCHLOROBENZENES 1.1.2.2-Tetrachloro2.2- difluoroethane 1016 1.1.2.2-TETRACHLORO-2,2DIFLUOROETHANE & 1.1.2.2-TETRACHLORO- 1,2DIFLUOROETHANE 1,1,1,2 -Tetrachloro-1,2-diflu oroethane 1016 1.1.2.2-TETRACHLORO-2,2DIFLUOROETHANE & 1.1.2.2-TETRACHLORO- 1,2DIFLUOROETHANE 1,1,2,2-Tetrachloroethane 1019 1,1,2,2-TETRACHLOROETHANE 1,1,2,2-Tetrachloroethane 2562 1 , 1,2,2-TE TRAC H LORO ETHAN E 0.01 - 0.05 0.2 - 0.5 0.05 - 0.1 0.2 - 1 1 -3 NA 80% vol 3 - 100 1.3 - 10 12 - 240 50 - 1500 NA NA HCO3-/CO32NaOH tol/acet Cu(Ac)2 NA 1 -3 >4 15 - 200 varies MeOH reagent 1 -4 1 -4 25 - 2000 25 - 2000 HNO3 HCl/HNO3 1 -4 See Ta ble HCl/HNO3 NA 0.2 - 1 0.01 - 2 1 -3 0.2 - 1.0 NA 12 - 240 2 - 30 2 - 30 50 - 100 NA tol/acet CS2 CS2 THF 1 - 1.5 50 - 500 0.01 - 0.2 3 - 12 0.01 -0.035 0.5 - 2 aaa hexane CS2 0.01 -0.035 0.5 - 2 CS2 0.01 - 0.2 0.01 - 0.2 3 - 30 3 - 30 CS2 CS2 Analytical Technique IC Titration VIS GC-FID ICP-AES Sampler MCEF& pad w/Na2CO3 PTFE SG w/HgCl2 CCT MCEF ICP-AES MCEF ICP-AES HPLC-UV GC-FID FTIR Wipe GFF CCT Dir. Read IC GC-ECD IC IC GC-FPD ICP or AAS GC-MSD MCEF& pad w/Na2CO3 air bag SG(washed) CCT (lg) OVS-2 PVC Urine HPLC-UV PCR GFF PTFE ICP-AES ICP-AES MCEF MCEF ICP-AES MCEF ICP-AES GC-FID GC-FID GC-FID GC-FID Wipe OVS-2 CCT PTFE SG HPLC/GFAAS GC-ECD GC-FID GFF & XAD-2 PTFE & XAD-2 CCT GC-FID CCT GC-FID GC-FID PCT A-CMS 3/1 5/2003 MF-21 NIOSH Manual of Analytical Methods Chemical Tetrachloroethylene Tetrachloroethylene Tetraethylene glycol Tetraethyl lead Tetraethyl pyrophosphate Tetrafluoroethylene Tetrahydrofuran Tetrahydrofuran Tetra kis (hy droxym eth yl) phosphonium chloride Tetramethyl lead Tetramethyl thiourea Tetra nitrom ethane Thall ium Thall ium Thallium Thiobencarb Thiophenate-methyl Thiophenate-methyl Thiophenate-methyl Thiram Tin Tin Tin, organic compds as Sn Titanium Titanium Titanium Toluene Toluene Toluene Toluene Toluene 2,4 & 2,6-Toluenediamine Toluene-2,4-diisocyanate Toluene-2,4-diisocyanate Meth No. Method Name 1003 HYDROCARBONS, HALOGENATED 3704 PERCHLOROETHYLENE (port GC) in exhaled breath and air 5523 GLYCOLS 2533 TETRAETHYL LEAD (as Pb) 2504 TETRAETHYL PYROPHOSPHATE 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 1609 TETRAHYDROFURAN 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 5046 TETRKIS(HYDROXYM ETHYL) PHOSPHONIUM CHLORIDE 2534 TETRAMETHYL LEAD (as Pb) 3505 TETRAMETHYL THIOUREA 3513 TETRANITROMETHANE 7300 ELEMENTS by ICP 7310 ELEMENTS by ICP (Aqua Regia Ashing) 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 5601 ORGANONITROGEN PESTICIDES 9205 CAPTAN and THIOPHENATE-METHYL on DERMAL PATCH 9202 CAPTAN and THIOPHENATE-METHYL in Hand Rinse 5606 THIOPHENATE-METHYL in AIR 5005 THIRAM 7301 ELEMENTS by ICP (Aqua Regia Ashing) 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 5504 ORGANOTIN CPDS. (as Sn) 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (Aqua Regia Ashing) 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 2549 VOLATILE ORGANIC CPDS (Screening) 4000 TOLUENE(Diffusive sampler) 1500 HYDROCARBONS, BP 36-216C 1501 HYDROCARBONS, AROMATIC 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 5516 2,4- & 2,6-TOLUENEDIAMINE 2535 TOLUE N E-2,4-DI ISOCYANATE 5521 ISOCYANATES, MONOMERIC Flow Rate (L/min) 0.01 - 0.2 0.1 - 1 Vol. (L) min max Extraction 1 - 40 CS2 <80% cap NA 0.5 - 2 0.01 - 1.0 0.01 - 0.2 0.1 - 20 5 - 60 30 - 200 20 - 48 Instr. dep. MeOH pentane toluene NA 0.01 - 0.2 0.1 - 20 1 -9 Instr. dep. CS2 NA 1 - 1.7 1 - 400 ACN 0.01 - 0.2 0.2 - 1.0 0.5 - 1.0 1 -4 1 -4 15 - 100 50 - 250 20 - 250 25 - 2000 25 - 2000 pentane reagents HNO3/HClO4 HCl/HNO3 1 -4 See Ta ble HCl/HNO3 0.1 - 1 NA var- 480 NA reagent IPA/ACN NA NA NA 0.1 - 1.0 1 -4 1 -4 20 - 480 10 - 400 5 - 1000 IPA/ACN CH3CN HCl/HNO3 1 -4 See Table HCl/HNO3 1 - 1.5 1 -4 1 -4 50 - 500 5 - 100 5 - 100 acetic a/CH3CN HNO3/HClO4 HCl/HNO3 1 -4 See Table HCl/HNO3 0.01 - 0.05 1 - 6 thermal NA 0.01 - 0.2 0.01 - 0.2 0.1 - 20 15 min-8h 2-8 1 -8 Instr. dep. CS2 CS2 CS2 NA 1.0 0.2 - 1.0 1.0 30 - 500 2 - 170 5 - 500 acetylate/MeOH MeOH acetylate/MeOH Analytical Technique GC-FID Port GC-PID GC-FID GC-PID GC-FPD FTIR GC-FID FTIR HPLC-UV GC-PID VIS GC-FID ICP-AES ICP-AES ICP-AES HPLC, UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV ICP-AES ICP-AES HPLC/GFAAS ICP-AES ICP-AES ICP-AES TD/GC-MS GC-FID GC-FID GC-FID FTIR HPLC-UV HPLC-UV HPLC-ECHD Sampler CCT air bag OVS-7 XAD-2 2 Chrom 102 Dir. Read CCT Dir. Read GFF XAD-2 IMP/HO IMP/EtAc MCEF MCEF MCEF OVS-2 Patch Hand wa sh QFF/SST PTFE MCEF MCEF GFF & XAD-2 MCEF MCEF MCEF TD Diffusive CCT CCT Dir. Read IMP GW coated IMP 3/1 5/2003 MF-22 NIOSH Manual of Analytical Methods Chemical Meth No. Method Name Toluene-2,4-diisocyanate Toluene 2,4-dissocyanate (2,4-TDI) Toluene-2,6-diisocyanate Toluene-2,6-diisocyanate Toluene-2,6-diisocyanate (2,6-TDI) p-Toluenesulfonic acid o-Toluidine o-Toluidine o-Toluidine o-Toluidine o-Toluidine Tribromomethane Tributyl phosphate Tributyltin chloride 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane 1,1,1 -Trichloroethane 1,1,1 -Trichloroethane Trichloroethylene Trichloroethylene Trichloroethylene Trichloroethylene Trichlorofluoromethane Trichloromethane 1,2,3-Trichloropropane Trichcylohexyltin hydroxide 1.1.2-Trichloro1.2.2-trifluoroethane 1.1.2-Trichloro1.2.2-trifluoroethane Triethanolamine Triethylene glycol Triethylenetetramine Trifluorobromomethane Trimellitic anhydride 2,4,7-Trin itroflu o re n -9-one Triorthocresyl phosphate Triphenyl phosphate Triphenyltin chloride 5522 5525 5522 5521 5525 5043 2002 201 7 5013 831 7 8313 1003 5034 5504 5517 1003 1003 2549 1003 1022 3701 3800 1006 1003 1003 5504 1020 2549 3509 5523 2540 1017 5036 5018 5037 5038 5527 ISOCYANATES ISOCYANATES, TOTAL (MAP) ISOCYANATES ISOCYANATES, MONOMERIC ISOCYANATES, TOTAL (MAP) P-TOLUENESULFONIC ACID AMINES, AROMATIC ANILINE, o-TOLUIDINE, AND NITROBENZENE DYES ANALINE and o-TOLUIDINE in urine ANALINE and o-TOLUIDINE in urine HYDROCARBONS, HALOGENATED TRIBUTYL PHOSPHATE ORGANOTIN COMPOUNDS POLYCHLOROBENZENES HYDROCARBONS, HALOGENATED HYDROCARBONS, HALOGENATED VOLATILE ORGANIC CPDS (Screening) HYDROCARBONS, HALOGENATED TRICHLOROETHYLENE TRICHLOROETHYLENE by port GC ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY FLUOROTRICHLOROMETHANE HYDROCARBONS, HALOGENATED HYDROCARBONS, HALOGENATED ORGANOTIN COMPOUNDS 1,1,2-TRICHLORO-1,2,2TRIFLUOROETHANE VOLATILE ORGANIC CPDS (Screening) AMINOETHANOL COMPOUNDS II GLYCOLS ETHYLENEDIAMINE, DIETHYLENETRIAMINE, & TRIETHYLENETETRAMINE TRIFLUOROBROMOMETHANE TRIMELLITIC ANHYDRIDE 2,4,7 -TRIN ITRO-FLUOREN -9-ON E TRIORTHOCRESYL PHOSPHATE TRIPHENYL PHOSPHATE TRIPHENYL TIN CHLORIDE Flow Rate (L/min) 1 -2 1 -2 Vol. (L) min max 15 - 360 1 - 500 Extraction tryptamine/DMSO MAP 1 -2 1.0 1 -2 15 - 360 5 - 500 1 - 500 tryptamine/DMSO acetylate/MeOH MAP 1 -3 0.02 - 1.0 0.2 10 - 1000 10 - 150 5 - 50 IPA/H2O Ethanol ethanol 1 -3 150 - 500 NA NA NA NA 0.01 - 0.2 4 - 70 1 -3 2 - 100 1 - 1.5 50 - 500 0.01 - 0.2 3 - 12 0.01 - 0.2 2 - 60 0.01 - 0.2 0.1 - 8 0.01 - 0.05 1 - 6 HO ALK ALK CS2 diethyl ether acetic a/CH3CN hexane CS2 CS2 thermal 0.01 - 0.2 0.01 - 0.2 > 0.02 0.1 - 20 0.2 - 30 1 - 30 80% vol Instr. dep. CS2 CS2 NA NA 0.01 - 0.05 0.01 - 0.2 0.01 - 0.2 1 - 1.5 0.01 - 0.05 0.3 - 7 1 - 50 0.6 - 60 50 - 500 0.1 - 3 CS2 CS2 CS2 acetic a/CH3CN CS2 0.01 - 0.05 1 - 6 thermal 0.5 - 1.0 0.5 - 2 0.01 - 0.1 5 - 300 5 - 60 1 - 20 HSA MeOH DMF 0.01 - 0.05 0.1 - 1 CH2Cl2 1.5 - 2 400 - 1000 MeOH 1 -3 100 - 500 toluene 1 -3 2 - 100 diethyl ether 1 -3 10 - 400 diethyl ether 1 -4 100 - 2000 TWM Analytical Technique HPLC-FL/ECHD HPLC-UV HPLC-FL/ECHD HPLC-ECHD HPLC-UV HPLC-UV GC-FID GC-FID HPLC-UV HPLC-ECD HPLC-ECD GC-FID GC-FPD HPLC/GFAAS GC-ECD GC-FID GC-FID TD/GC-MS GC-FID GC-FID GC-port FTIR GC-FID GC-FID GC-FID HPLC-GFAAS GC-FID TD/GC-MS IC GC-FID HPLC-UV GC-FID GC-FID HPLC-UV GC-FPD GC-FPD HPLC-ICP Sampler IMP GFF, IMP IMP IMP GFF, IMP GFF SG GFF + SG PTFE NA NA CCT MCEF GFF & XAD-2 PTFE & XAD-2 CCT CCT TD CCT CCT air bag Dir. Read CCT(lg) CCT CCT GFF & XAD-2 CCT TD IMP OVS-7 XAD-2 W/10% NITC 2 CCT(lg + sm) PVC PTFE MCEF MCEF PVC 3/1 5/2003 MF-23 NIOSH Manual of Analytical Methods Chemical Tubercle bacilli Tungsten Tungsten, soluble/insoluble Turpentine Turpentine n-Undecane Valeraldehyde Valeraldehyde Valeraldehyde Vanadium Vanadium Vanadium Vanadium Vanadium oxides Vinyl acetate Vinyl benzene Vinyl bromide Vinyl chloride Vinylidene chloride Vinylidene Fluoride Vinyl tolueneuene VM&P naphtha VOCs Warfarin Wood alcohol Xylene Xylene (o,m,p) p-Xylene m-Xylene o-Xylene 2,4-Xylidine Yttrium Yttrium Yttrium Yttrium Meth No. Method Name 0900 MYCOBACTERIUM TUBERCULOSIS 7301 ELEMENTS by ICP (Aqua Regia Ashing) 7074 TUNGSTEN (soluble/insoluble) 1551 TURPENTINE 2549 VOLATILE ORGANIC CPDS (Screening) 1500 HYDROCARBONS, BP 36-216oC 2018 ALIPHATIC ALDEHYDES 2536 VALERALDEHYDE 2539 ALDEHYDES, SCREENING 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (Aqua Regia Ashing) 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 9102 ELEMENTS on WIPES 7504 VANADIUM OXIDES 1453 VINYL ACETATE 1501 HYDROCARBONS, AROMATIC 1009 VINYL BROMIDE 1007 VINYL CHLORIDE 1015 VINYLIDENE CHLORIDE 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 1501 HYDROCARBONS, AROMATIC 1550 NAPHTHAS 2549 VOLATILE ORGANIC CPDS (Screening) 5002 WARFARIN 2000 METHANOL 2549 VOLATILE ORGANIC CPDS (Screening) 1501 HYDROCARBONS, AROMATIC 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 2002 AMINES, AROMATIC 7300 ELEMENTS by ICP 7301 ELEMENTS by ICP (Aqua Regia Ashing) 7303 ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) 9102 ELEMENTS on WIPES Flow Rate (L/min) >4 1 -4 Vol. (L) min max varies 50 - 1000 Extraction reagent HCl/HNO3 1 -4 0.01 - 0.2 0.01 - 0.05 200 - 1000 1 - 10 1 -6 hf/hno3 CS2 thermal 0.01 - 0.05 0.1 - 1.5 0.01 - 0.04 0.01 - 0.05 1 -4 1 -4 2-2 1 - 15 0.5 - 10 5-5 5 - 2000 5 - 2000 CS2 ACN toluene toluene HNO3/HClO4 HCl/HNO3 1 -4 See Table HCl/HNO3 NA 1.7 or 2.2 0.1 - 0.2 .01 - 1 0.01 - 0.2 0.05 0.01 - 0.2 0.1 - 20 NA 200 - 1000 0.75 - 24 1 - 14 2 - 10 0.7 - 5 2.5 - 7 Instr. dep. NA THF CH2Cl2/MeOH CS2 Ethanol CS2 CS2 NA 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 1 - 24 1.3 - 20 1 -6 CS2 CS2 thermal 1 -4 0.02 - 0.2 0.01 - 0.05 200 - 1000 1 -5 1 -6 MeOH h2o/ipa thermal 0.01 - 0.2 0.1 - 20 2 - 23 Instr. dep. CS2 NA 0.1 - 20 Instr. dep. NA 0.1 - 20 Instr. dep. NA 0.02 - 0.2 1 -4 1 -4 3 - 20 5 - 1000 5 - 1000 Ethanol HNO3/HClO4 HCl/HNO3 1 -4 See Table HCl/HNO3 NA NA NA Analytical Technique PCR ICP-AES FAAS GC-FID TD/GC-MS GC-FID HPLC-UV GC-FID GC-FID/MS ICP-AES ICP-AES ICP-AES ICP-AES XRD GC-FID GC-FID GC-FID GC-FID GC-FID FTIR GC-FID GC-FID TD/GC-MS HPLC-UV GC-FID TD/GC-MS GC-FID FTIR FTIR FTIR GC-FID ICP-AES ICP-AES ICP-AES ICP-AES Sampler PTFE MCEF MCEF CCT TD CCT SG-DNPH XAD-2/HMP XAD-2/H M P MCEF MCEF MCEF Wipe CYC & PVC MS(carbon) CCT CCT (lg) 2 CCT CCT Dir. Read CCT CCT TD PTFE SG TD CCT Dir. Read Dir. Read Dir. Read SG MCEF MCEF MCEF Wipe 3/1 5/2003 MF-24 NIOSH Manual of Analytical Methods Chemical Zinc and compounds Zinc Zinc Zinc Yttrium Zinc oxide Zirconium Zirconium Zirconium METHODS BY NUMBER 3/1 5/2003 Meth No. Method Name 7030 7300 7301 7303 9102 7502 7300 7301 9102 ZINC and compounds, as Zn ELEMENTS by ICP ELEMENTS by ICP (Aqua Regia Ashing) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) ELEMENTS on WIPES ZINC OXIDE ELEMENTS by ICP ELEMENTS by ICP (Aqua Regia Ashing) ELEMENTS on WIPES Flow Rate (L/min) 1 -3 1 -4 1 -4 Vol. (L) min max 2 - 400 5 - 200 5 - 200 Extraction HNO3 HNO3/HClO4 HCl/HNO3 1 -4 See Table HCl/HNO3 NA 1 -3 1 -4 1 -4 NA 10 - 400 5 - 200 5 - 200 NA HNO3/HClO4 HCl/HNO3 NA NA NA Analytical Technique FAAS ICP-AES ICP-AES ICP-AES ICP-AES XRD ICP-AES ICP-AES ICP-AES Sampler MCEF MCEF MCEF MCEF Wipe PVC MCEF MCEF Wipe 0500 PARTICULATES N.O.R. 0600 PARTICULATES, N.O.R, RESP. 0800 BIOAEROSOL SAMPLING 0801 AEROBIC BACTERIA - GC-FAME 0900 MYCOBACTERIUM TUBERCULOSIS 1000 ALLYL CHLORIDE 1001 METHYL CHLORIDE 1002 P-CHLOROPRENE 1003 HYDROCARBONS, HALOGENATED 1004 DICHLOROETHYL ETHER 1005 METHYLENE CHLORIDE 1006 FLUOROTRICHLOROMETHANE 1007 VINYL CHLORIDE 1008 ETHYLENE DIBROMIDE 1009 VINYL BROMIDE 1010 EPICHLOROHYDRIN 1011 ETHYL BROMIDE 1012 DIFLUORODIBROMOM ETHANE 1013 PROPYLENE DICHLORIDE 1014 METHYL IODIDE 1015 VINYLDENE CHLORIDE 1016 1.1.2.2-TETRACH LORO-2,2DIFLUOROETHANE & 1.1.2.2-TETRACHLORO-1,2DIFLUOROETHANE 1017 TRIFLUOROBROMOM ETHANE 1018 DICHLORODIFLUOROMETHANE, 1,2-DICHLOROTETRAFLUOROETHANE& CHLORODIFLUOROMETHANE 1019 1,1,2,2-TETRACHLOROETHANE 1020 1,1,2-TRICHLORO-1,2,2TRIFLUOROETHANE 1022 TRICHLOROETHYLENE 1 -2 7 - 133 1.7, 2.2,2.5 20 - 400 28.3 varies 28.3 50 - 300 4 varies 0.01 - 1.0 16 - 100 0.01 - 0.1 0.4 - 3 0.01 - 0.1 1.5 - 8 0.01 - 0.2 3 - 70 0.01 - 1.0 2 - 15 0.01 - 0.2 0.5 - 2.5 0.01 - 0.05 0.3 - 7 0.05 0.7 - 5 0.02 - 0.2 0.1 - 25 0.01 - 0.2 2 - 10 0.01 - 0.2 2 - 30 0.01 - 0.2 0.5 - 4 0.01 - 0.2 2.5 - 10 0.01 - 0.2 0.1 - 3.5 0.01 - 1.0 15 - 50 0.01 - 0.2 2.5 - 7 0.01 -0.035 0.5 - 2 0.01 - 0.05 0.01 - 0.05 0.1 - 1 1 -4 0.01 - 0.2 0.01 - 0.05 3 - 30 0.1 - 3 0.01 - 0.2 1 - 30 MF-25 NA GRAV NA Grav. NA varies hex/MTBE GC-FID reagent PCR bz GC-FID CH2Cl2 GC-FID CS2 GC-FID CS2 GC-FID CS2 GC-FID CS2 GC-FID CS2 GC-FID CS2 GC-FID bz/MeOH GC-ECD Ethanol GC-FID CS2 GC-FID IPA GC-FID IPA GC-FID acet/cyclohexane GC-ECN tol GC-FID CS2 GC-FID CS2 GC-FID PVC CYC & PVC impactor Impactor PTFE CCT 2 CCT (lg+sm) CCT CCT CCT 2 CCT CCT (lg) 2 CCT CCT CCT (lg) CCT CCT 2 CCT PCT CCT CCT CCT CH2Cl2 CH2Cl2 GC-FID GC-FID 2 CCT(lg+sm) 2 CCT (lg + sm) CS2 CS2 GC-FID GC-FID PCT CCT CS2 GC-FID CCT NIOSH Manual of Analytical Methods Chemical 3/1 5/2003 Meth No. Method Name 1024 1025 1026 1300 1301 1302 1400 1401 1402 1403 1404 1405 1450 1451 1452 1453 1454 1457 1458 1459 1460 1500 1501 1550 1551 1552 1600 1601 1602 1603 1604 1606 1608 1609 1610 1611 1612 1613 1614 1615 1616 1617 1,3-BUTADIENE 1- and 2-BROMOPROPANE P-C HLO ROB ENZOTRI FLUORIDE KETONES I KETONES II W-M ETHYL-2-PYRROLIDI NONE ALCOHOLS I ALCOHOLS II ALCOHOLS III ALCOHOLS IV M ETHYLCYC LO H EXAN O L ALCOHOLS COMBINED ESTERS I METHYL CELLOSOLVE ACETATE ETHYL FORMATE VINYL ACETATE ISOPROPYL ACETATE ETHYL ACETATE METHYL ACETATE METHYL ACRYLATE ISOPROPYL ACETATE HYDROCARBONS, BP 36-216C HYDROCARBONS, AROMATIC NAPHTHAS TURPENTINE TERPENES CARBON DISULFIDE 1,1 -DICHLORO-1 -NITROETHANE DIOXANE ACETIC ACID ACRYLONITRILE ACETONITRILE GLYCIDOL TETRAHYDROFURAN ETHYL ETHER METHYLAL PROPYLENE OXIDE PYRIDINE ETHYLENE OXIDE METHYL ferf-BUTYL ETHER BUTYL GLYCIDYL ETHER PHENYL ETHER Flow Rate (L/min) 0.01 - 0.5 0.01 - 0.2 0.01 - 0.2 0.01 - 2.0 0.01 - 0.2 0.05 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.05 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.1 - 0.2 0.02 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.02 - 0.2 0.01 - 0.2 0.01 - 1.0 0.01 - 0.2 0.01 - 0.2 0.01 - 2 0.01 - 0.2 0.01 - 1.0 0.01 - 0.2 0.01 - 0.1 0.01 - 0.2 0.01 - 0.2 0.01 - 1.0 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 0.2 0.01 - 1.0 0.05 - 0.15 0.1 - 0.2 0.01 - 0.2 0.01 - 0.2 Vol. (L) min max 5 - 25 0.1 - 12 0.1 - 10 1 - 10 1 - 25 0.5 - 125 1 - 10 2 - 10 1 - 10 6 - 50 1 - 15 2 - 10 1 - 10 0.2 - 20 0.3 - 10 0.75 - 24 0.1 - 9 0.1 - 10 0.2 - 10 1 -5 0.1 - 9 2-7 1 - 30 1.3 - 20 1 - 10 2 - 30 2 - 25 1.5 - 15 0.5 - 15 20 - 300 3.5 - 20 1 - 25 5 - 100 1 -9 0.25 - 3 1 -3 0.5 - 5 18 - 150 1 - 24 2 - 96 15 - 30 1 - 50 Extraction CH2Cl2 CS2 CS2/MeOH CS2 MeOH/CS2 CH2CL2/MeOH CS2 ipa/cs2 ipa/cs2 MeOH/CH2Cl2 CH2Cl2 ipa-cs2 CS2 CS2 CS2 CH2Cl2/MeOH CS2 CS2 CS2 CS2 CS2/Meth CS2 CS2 CS2 CS2 CS2 tol CS2 CS2 formic a acet/CS2 CH2Cl2/MeOH THF CS2 CS2 hexane CS2 CH2Cl2 DMF CS2 CS2 CS2 Analytical Technique GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID/NPD GC-FID GC-FID CG-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FPD GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-ECD GC-FID GC-FID GC-FID Sampler CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT MS(carbon) CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT & dry tube PCT CCT CCT CCT CCT CCT CCT CCT CCT CCT CCT PCT w/HBr 2 CCT (lg) CCT CCT MF-26 NIOSH Manual of Analytical Methods Chemical 3/1 5/2003 Meth No. Method Name 1618 1619 1620 2000 2002 2003 2004 2005 2007 2008 2010 201 1 ISOPROPYL ETHER PHENYL GLYCIDYL ETHER ISOPROPYL GLYCIDYL ETHER METHANOL AMINES, AROMATIC 1,1,2,2-TETRABROMOETHANE DIMETHYLACETAMIDE and DIMETHYLFORMAMIDE NITROAROMATIC COMPOUNDS AMINOETHANOL COMPOUNDS I CHLOROACETIC ACID AMINES, ALIPHATIC FORMIC ACID Flow Rate (L/min) 0.01 - 0.05 0.01 - 1 0.01 - 0.2 0.02 - 0.2 0.2 - 1.0 0.2 - 1.0 0.01 - 1.0 Vol. (L) min max 0.1 - 3 80 - 150 1 - 30 1 -5 30 - 150 50 - 100 15 - 80 Extraction CS2 CS2 CS2 h2o/ipa Ethanol THF MeOH Analytical Technique GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 0.01 - 1 0.01 - 0.2 0.05 - 0.2 0.01 - 1.0 0.05 - 0.2 1 - 150 4 - 24 1 - 100 3 - 30 1 - 24 MeOH MeOH/H2O HO H2SO4/aq MeOH HO GC-FID GC-FID IC GC-FID IC 2012 2013 2014 2015 2016 201 7 201 8 2500 2501 2504 2505 2506 2507 2508 2510 2513 2514 2515 2516 251 7 2518 2519 2520 n-BUTYLAMINE 0.01 - 1.0 PHENYL ETHER-DIPHENYL MIXTURE 0.01 - 0.2 p-CHLOROPHENOL 0.05 - 0.2 CHLOROACETALDEHYDE 0.05 - 0.2 FORMALDEHYDE 0.03 - 1.5 ANILINE, o-TOLUIDINE, AND NITROBENZENE 0.2 ALIPHATIC ALDEHYDES 0.1 - 1.5 METHYL ETHYL KETONE 0.01 - 0.2 ACROLEIN 0.01 - 0.1 TETRAETHYL PYROPHOSPHATE 0.01 - 0.2 FURFURYL ALCOHOL 0.01 - 0.05 ACETONE CYANOHYDRIN 0.2 NITROGLYCERIN & ETHYLENE GLYCOL 0.2 - 1.0 DINITRATE ISOPHORONE 0.01 - 1.0 1 -OCTAN ETHIOL 0.01 - 0.2 ETHYLENE CHLOROHYDRIN 0.01 - 0.2 ANISIDINE 0.5 - 1.0 DIAZOMETHANE 0.2 DICHLOROFLUOROMETHANE 0.01 - 0.05 PENTACHLOROETHANE 0.01 - 0.2 HEXACHLORO- 1,3-CYCLOP ENTADIENE 0.01 - 0.2 ETHYL CHLORIDE 0.02 - 0.05 METHYL BROMIDE 0.01 - 0.1 2 - 100 1 - 40 1.5 - 40 3 - 16 1 - 15 5 - 50 1 - 15 0.25 - 12 1.5 - 48 20 - 48 3 - 25 0.3 - 12 3 - 100 2 - 25 1 - 15 2 - 35 24 - 320 6 - 30 0.25 - 3 1 - 10 0.25 - 90 0.3 - 3 1 -5 MeOH bz ch3cn MeOH acetonitrile ethanol ACN CS2 tol toluene acet Et Ac Ethanol CS2 acet ipa/cs2 MeOH CS2 CS2 hexane hexane CS2 CS2 GC-FID GC-FID HPLC-UV GC-ECD HPLC-UV GC-FID HPLC-UV GC-FID GC-NPD GC-FPD GC-FID GC-NPD GC-ECD GC-FID GC-FPD GC-FID HPLC-UV GC-FID GC-FID GC-ECD GC-ECD GC-FID GC-AED 2521 2522 2523 METHYLCYCLOHEXANONE NITROSAMINES 1,3-CYCLOPENTADIENE 0.01 - 0.05 0.2 - 2.0 0.01 - 0.05 1 -6 15 - 1000 1 -5 acet MeOH/CH2Cl2 Et Ac GC-FID GC-TEA GC-FID Sampler CCT CCT CCT SG SG SG SG SG SG SG SG PTFE & SG (washed) SG + H2SO4 SG SG SG SG/DNPH GFF + SG w/H2SO4 SG-DNPH Carbon beads XAD-2/HMP 2 Chrom 102 Por Q Por QS Tenax-GC PCT Tenax GC PCT XAD-2 XAD-2 (coated) 2 CCT (lg) Por R 2 Por T 2 CCT (lg) PCT(2)+dry tube Por Q Thermalosorb/N Chrom1 04/ maleic anh. MF-27 NIOSH Manual of Analytical Methods Chemical 3/1 5/2003 Meth No. Method Name 2524 DIMETHYL SULFATE 2525 n-BUTYL MERCAPTAN 2526 NITROETHANE 2527 NITROMETHANE 2528 2-NITROPROPANE 2529 FURFURAL 2530 DIPHENYL 2532 GLUTARALDEHYDE 2533 TETRAETHYL LEAD (as Pb) 2534 TETRAMETHYL LEAD (as Pb) 2535 TOLUENE-2,4-DIISOCYANATE 2536 VALERALDEHYDE 2537 METHYL and ETHYL METHACRYLATE 2538 ACETALDEHYDE 2539 ALDEHYDES, SCREENING 2540 ETHYLENEDIAMINE , DIETHYLENETRIAMINE, & TRIETHYLENETETRAMINE 2541 FORMALDEHYDE 2542 MERCAPTANS 2543 H EXACH LOROBUTADIEN E 2544 NICOTINE 2545 ALLYL GLYCIDYL ETHER 2549 VOLATILE ORGANIC CPDS (Screening) 2550 BENZOTHIAZOLE IN ASPHALT FUME 2551 NICOTINE 2552 METHYL ACRYLATE 2553 KETONES II 2554 GLYCOL ETHERS 2555 KETONES I 2556 2557 2558 2559 2560 2561 2562 3500 3503 3505 3506 ISOPHORONE DIACETYL ACETOIN DECABROMODIPHENYL OXIDE 1-NITROPYRENE in DIESEL PARTICULATES 2-(DIM ETHYLAM INO)ETHANOL 1 -DIM ETH YLAM IN O-2-PROPANOL 1, 1,2,2-TETRACHLOROETHAN E FORMALDEHYDE HYDRAZINE TETRAMETHYL THIOUREA ACETIC ANHYDRIDE Flow Rate (L/min) Vol. (L) min max 0.01 - 0.2 0.25 - 12 0.01 - 0.05 1 - 4 0.01 - 0.05 1.5 - 3 0.01 - 0.05 1.2 - 3 0.01 - 0.05 0.1 - 2 0.01 - 0.05 1 - 12 0.01 - 0.5 15 - 30 0.01 - 0.08 4 - 39 0.01 - 1.0 30 - 200 0.01 - 0.2 15 - 100 0.2 - 1.0 2 - 170 0.01 - 0.04 0.5 - 10 0.01 - 0.05 1 - 8 0.01 - 0.05 1 - 12 0.01 - 0.05 5 - 5 0.01 - 0.1 1 - 20 Extraction diEt ether acet EtAc EtAc EtAc tol CCl4 ch3cn pentane pentane MeOH toluene CS2 tol tol DMF 0.01 - 0.1 0.1 - 0.2 0.05 - 0.2 1.0 0.01 - 0.2 0.01 - 0.05 1 - 36 10 - 150 1 - 100 60 - 400 1.5 - 8 1 -6 tol HCl/DCE hexane EtAc diethyl ether thermal 1.0 - 2.0 0.1 - 1.0 0.01 - 0.2 0.01 - 0.2 0.1 - 0.2 0.01 - 0.2 0.01 - 1 0.01 - 0.2 0.01 - 0.2 2.0 1.0 - 2.0 480 - 960 0.5 - 600 1 -5 1 - 25 3 - 25 0.5 - 3.0 1 - 10 2 - 25 1 - 10 1 - 10 48 - 960 480 - 960 hexane ethyl acetate CS2 ipa-cs2 MeCl2/Meth CS2 DEE Ac et-Meth Ac et-Meth DMSO Tol 0.02 - 1 10 - 24 MeOH 0.01 - 0.2 0.2 - 1.0 0.2 - 1.0 0.2 - 1.0 0.2 - 1.0 3 - 30 1 - 100 7 - 100 50 - 250 25 - 100 CS2 NaHSO3 reagents reagents reagent Analytical Technique GC-ECN GC-FPD GC-FID GC-FPD GC-FID GC-FID GC-FID HPLC-UV GC-PID GC-PID HPLC-UV GC-FID GC-FID GC-FID GC-FID/MS HPLC-UV GC-FID GC-FPD GC-ECD GC-NPD GC-FID TD/GC-MS GC-SCD GC-NPD GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID HPLC/UV GC-NCD GC-FID GC-FID VIS VIS VIS VIS Sampler Por P Chrom 104 2XAD-2 Chrom 106 Chrom 106 XAD-2/H M P Tenax GC SG/DNPH XAD-2 XAD-2 GW coated XAD-2/H M P XAD-2 XAD-2/HMP XAD-2 XAD-2 w/10% NITC XAD-2/H M P GFF/HgAc XAD-2 XAD-2 Tenax TD PTFE + XD-2 XAD-4 A-CMS A-CMS A-74 7 A-CMS XAD A-CMS A-CMS QFF GFF XAD A-CMS PTFE & 2 IMP BuB IMP/HO BuB MF-28 NIOSH Manual of Analytical Methods Chemical 3/1 5/2003 Meth No. Method Name Flow Rate (L/min) 3507 ACETALDEHYDE 0.1 - 0.5 3508 METHYL ETHYL KETONE PEROXIDE 0.5 - 0.2 3509 AMINOETHANOL COMPOUNDS II 0.5 - 1.0 3510 MONOM ETHYLHYDRAZINE 0.5 - 1.5 351 1 MONOMETHYLANILINE 0.2 - 1.0 3512 MALEIC ANHYDRIDE 0.2 - 1.5 3513 TETRANITROMETHANE 0.5 - 1.0 3514 ETHYLENIMINE 0.2 3515 1,1 - DIM ETHYLHYDRAZINE 0.2 - 1.0 3516 CROTONALDEHYDE 0.1 - 0.2 351 8 PHENYLHYDRAZINE 0.2 - 1.0 3600 MANEB NA 3601 MANEB NA 3700 BENZENE by portable GC > 0.02 3701 TRICHLOROETHYLENE by port GC > 0.02 3702 ETHYLENE OXIDE by portable GC > 0.02 3704 PERCHLOROETHYLENE (portable GC) in exhaled breath and air 0.1 - 1 3800 ORGANIC and INORGANIC GASES by EXTRACTIVE FTIR SPECTROMETRY 0.1 - 20 4000 TOLUENE (Diffusive sampler) NA 5000 CARBON BLACK 1 -2 5001 2,4-D and 2,4,5-T 1 -3 5002 WARFARIN 1 -4 5003 PARAQUAT 1 -4 5004 HYDROQUINONE 1 -4 5005 THIRAM 1 -4 5006 CARBARYL 1 -3 5007 ROTENONE 1 -4 5008 PYRETHUM 1 -4 5009 BENZOYL PEROXIDE 1 -3 5010 BROMOXYNIL and B'OCTANOATE 1 -3 5011 ETHYLENE THIOUREA 1 -3 5012 EPN 1 -2 5013 DYES 1 -3 5014 CHLORINATED TERPHENYL 1 -3 5016 STRYCHNINE 1 -3 5017 DIBUTYL PHOSPHATE 1 -3 5018 2,4,7 -TRINITRO-FLUOREN -9-ON E 1 -3 5019 AZELAIC ACID 1 -3 5020 DIBUTYL PHTHALATE & DI(2-ETHYLHEXYL) PHTHALATE 1 -3 5021 o-TERPHENYL 1 -3 5022 ARSENIC, organo- 1 -3 Vol. (L) min max 6 - 60 52 - 520 5 - 300 3 - 20 11 - 100 40 - 500 20 - 250 1 - 48 2 - 100 1 - 49 25 - 120 NA NA 80% vol 80% vol 80% vol 80% VOL Extraction reagent reagent HSA PMA/HCl NaOH CHCl3 reagent buffer PMA Cys/EDTA NA NA NA NA NA Instr. dep. NA 15 min-8h 30 - 570 15 - 200 200 - 1000 40 - 1000 30 - 180 10 - 400 20 - 400 8 - 400 20 - 400 40 - 400 2 - 400 200 - 800 15 - 700 150 - 500 100 - 1500 70 - 1000 50 - 250 100 - 500 200 - 1000 6 - 200 CS2 NA MeOH MeOH HO acetic acid ch3cn reagent ch3cn ch3cn diethyl ether ch3cn HO isooctane HO isooctane reagents chcn toluene Ethanol CS2 2 - 30 50 - 1000 CS2 buffer Analytical Technique HPLC-UV VIS IC VIS GC-FID HPLC-UV GC-FID HPLC-UV VIS DPP VIS HPLC-UV HPLC-UV GC GC-port GC-PID Port GC-PID FTIR GC-FID Grav HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV VIS HPLC-UV HPLC-UV HPLC-UV HPLC-UV VIS GC-FPD HPLC-UV GC-ECD HPLC-UV GC-FPD HPLC-UV GC-FID GC-FID GC-FID IC-HYAAS Sampler BuB IMP IMP BuB/HCl BuB/HSO4 BuB/HO IMP/EtAc BuB BuB (.1 M HCl) BuB BuB/HCl Patch Hand wash air bag air bag air bag air bag Dir. Read Diffusive PVC GFF PTFE PTFE MCEF PTFE GFF PTFE GFF MCEF PTFE PVC or MCEF GFF PTFE GFF GFF PTFE PTFE PVC MCEF PTFE PTFE MF-29 NIOSH Manual of Analytical Methods Chemical 3/1 5/2003 Meth No. Method Name Flow Rate (L/min) 5025 CHLORINATED DIPHENYL OXIDE 0.5 - 1.5 5026 OIL MIST, MINERAL 1 -3 5027 RIBAVIRIN 1 -4 5029 4,4-METHYLENEDI ANILINE 1 -2 5030 CYANURIC ACID 1 -3 5031 ASPARTAME 1 -3 5032 PENTAMIDINE ISETH IONATE 1 -2 5033 p-NITROANILINE 1 -3 5034 TRIBUTYL PHOSPHATE 1 -3 5035 SUPER ABSORBENT POLYMER 1 -3 5036 TRIMELLITIC ANHYDRIDE 1.5 - 2 5037 TRIORTHOCRESYL PHOSPHATE 1 -3 5038 TRIPHENYL PHOSPHATE 1 -3 5039 CHLORINATED CAMPHENE 0.2 - 1 5040 ELEMENTAL CARBON (DIESEL PARTICULATE) 2-4 5041 CAPSAICIN and DIHYDROCAPSAICIN 1 - 3 5042 BENZENE SOLUBLE FRACTION AND TOTAL PARTICULATE (ASPHALT FUME) 1 -4 5043 p-TOLUENESULFONIC ACID 1 -3 5044 ESTROGENIC COMPOUNDS 1 5046 TETRAKIS (HYDROXYMETHYL) PHOSPHONIUM CHLORIDE 1 - 1.7 5502 ALDRIN & LINDANE 0.2 - 1.0 5503 POLYCHLOROBIPHENYLS 0.05 - 0.2 5504 ORGANOTIN COMPOUNDS 1 - 1.5 5506 POLYNUCLEAR AROMATIC HYDROCARBONS 2.0 5508 KEPONE 0.5 - 1.0 5509 BENZIDINE and 3,3'-DICHLORO-BENZIDINE 0.2 5510 CHLORDANE 0.5 - 1.0 5512 5514 5515 5516 5517 5518 5519 PENTACHLOROPHENOL DEMETON POLYNUCLEAR AROMATIC HYDROCARBONS 2,4- & 2,6-TOLUENEDIAMINE POLYCHLOROBENZENES NAPHTHYLAMINES ENDRIN 0.5 - 1.0 0.2 - 1.0 2.0 1.0 0.01 - 0.2 0.2 - 0.8 0.5 - 1.0 5521 5522 5523 ISOCYANATES, MONOMERIC ISOCYANATES GLYCOLS 1.0 1 -2 0.5 - 2 Vol. (L) min max Extraction 8 - 200 isooctane 20 - 500 CCl4 5 - 1000 H2SO4 10 - 1000 KOH/MeOH 10 - 1000 reagents 70 - 1200 eluent 50 - 1500 reagents 20 IPA 2 - 100 dielhyl ether 50 - 1500 Cu(Ac)2 400 - 1000 MeOH 2 - 100 dielhyl ether 10 - 400 diethyl ether 2 - 30 pet ether 142 -19000 thermal 5 - 1000 28 - 400 ch3cn benzene Analytical Technique GC-ECN IR HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC/FL HPLC-UV GC-FPD ICP or AAS GC-FID GC-FPD GC-FPD GC-ECD EGA/TOA HPLC-FL Grav Sampler MCEF PVC or MCE GFF GFF/H2SO4 PVC PTFE PVC/opaque MCEF MCEF PVC PVC MCEF MCEF MCEF QFF GFF tared PTFE 10 - 1000 1PA/H20 150 - 1000 Meth 1 - 400 ACN HPLC-UV HPLC-UV HPLC-UV GFF PTFE GFF 18 - 240 1 - 50 50 - 500 200 - 1000 isooct hexane acetic a/CH3CN acetonitrile GC-ECN GC-ECD HPLC-GFAAS HPLC-FL/UV GFF & BuB GFF & Florisil GFF & XAD-2 PTFE & XAD-2 50 - 600 20 - 100 10 - 200 bz/MeOH triethyl amine /MeOH tol 48 - 480 30 - 500 200 - 1000 MeOH tol varies GC-ECD HPLC-UV GC-ECD HPLC-UV GC-FPD GC-FID MCEF & IMP GFF MCEF & Chrom 102 MCEF & BuB MCEF &XAD-2 PTFE & XAD-2 30 - 500 3 - 12 30 - 100 12 - 400 5 - 500 15 - 360 5 - 60 acetyla te/MeOH hexane acetic a /IPA tol reagents tryptamine/DMSO MeOH HPLC-UV GC-ECD GC-FID GC-ECD HPLC-ECHD HPLC-FL/ECHD GC-FID IMP PTFE & XAD-2 GFF & SG MCEF & Chrom 102 IMP IMP OVS-7 MF-30 NIOSH Manual of Analytical Methods Chemical 3/1 5/2003 Meth No. Method Name 5524 5525 5526 5527 5600 5601 5602 5603 5606 5700 5701 5800 6001 6002 6004 METALWORKING FLUIDS (MWF) ALL CATEGORIES ISOCYANATES, TOTAL (MAP) METHYLTIN CHLORIDES TRIPHENYL TIN CHLORIDE ORGANOPHOSPHORUS PESTICIDES ORGANONITROGEN PESTICIDES CHLORINATED ORGANONITROGEN HERBICIDES (AIR SAMPLING) ALACHLOR in AIR THIOPHENATE-METHYL in AIR FORMALDEHYDE on dust RESORCINOL POLY AROMATIC COMPOUNDS (PACs) ARSINE PHOSPHINE SULFUR DIOXIDE Flow Rate (L/min) 1.6 - 2.0 1 -2 0.25 - 1 1 -4 0.2 - 1 0.1 - 1 0.2 - 1 Vol. (L) min max Extraction 1 000 - ND DCM/MeOH/Tol MeOH 1 - 500 MAP 15 - 75 AAA 100 - 2000 TWM 12 - 240 tol/acet var- 480 reagent 12 - 480 reagent 1 0.1 - 1.0 2 0.2 - 1 1 -2 70 - 1 750 20 - 480 240 - 1050 5 - 160 5 - 1000 MeOH IPA/ACN h2o/dnph/ch3cn MeOH hexane 0.01 - 0.2 0.01 - 0.2 0.5 - 1.5 0.1 - 10 1 - 16 4 - 200 HNO3 reagent HCO3-/CO32- 6005 6006 IODINE DIBORANE 0.5 - 1.0 0.5 - 1.0 15 - 225 60 - 260 Na2CO3 h2o2 6007 6008 6009 6010 6011 6012 6013 6014 NICKEL CARBONYL STIBINE MERCURY HYDROGEN CYANIDE CHLORINE and BROMINE SULFURYL FLUORIDE HYDROGEN SULFIDE (withdrawn) NITRIC OXIDE & NITROGEN DIOXIDE 0.05 - 0.2 0.01 - 0.2 0.15 - 0.25 0.05 - 0.2 0.3 - 1.0 0.05 - 0.1 0.1 - 1.5 0.025 7 - 80 4 - 50 2 - 100 2 - 90 2 - 90 1.3 - 10 1.2 - 40 1.5 - 6 HNO3 HCl HNO3/HCl HO Na2S2O3 NaOH NH4OH/H2O2 reagent 6015 6016 601 7 6402 6600 6601 6602 6603 6604 6700 7013 7020 7024 AMMONIA by VIS AMMONIA by IC HYDROGEN CYANIDE PHOSPHORUS TRICHLORIDE NITROUS OXIDE OXYGEN SULFUR HEXAFLUORIDE CARBON DIOXIDE CARBON MONOXIDE NITROGEN DIOXIDE (Diffusive) ALUMINUM & CPDS, as Al CALCIUM and cpds as Ca CHROMIUM and cpds, as Cr 0.1 - 0.2 0.1 - 0.5 0.05 - 2 0.05 - 0.2 NA NA 0.01 - 0.05 0.02 - 0.1 NA NA 1 -3 1 -3 1 -3 0.1 - 90 0.1 - 96 2 - 90 11 - 100 80% vol 1 - NA 80% vol 80% vol NA NA 10 - 400 20 - 400 10 - 1000 HO HO HO reagents NA NA NA NA NA reagent HNO3 HNO3/HClO4 HCl/HNO3 Analytical Technique Grav HPLC-UV GC-FPD HPLC-CP GC-FPD HPLC-UV GC/ECD ELISA HPLC-UV HPLC-UV GC-FID FI-FL GFAAS VIS IC IC PES GFAAS VIS AAS-cold vap VIS IC IC IC VIS VIS-Auto IC IC-DC Amp VIS IR Sensor GC-ECD GC-TCD Sensor VIS FAAS FAAS FAAS Sampler PTF E/CYC GFF, IMP OVS PVC OVS-2 OVS-2 OVS-2 SPE disk QFF/SST IOM/PVC OVS-7 PTFE + XAD-2 CCT SG/Hg(CN) MCEF& pad w/Na2CO3 CCT w/alkali PTFE & CCT w/oxidizer CCT (low Ni) SG w/HgCl2 Hopcalite soda lime Ag F CCT (lg) PTFE & CCT (lg) MS w/TEA & oxidizer SG + H2SO4 SG + H2SO4 SL BuB/H2O air bag portable air bag air bag Port Instr Diffusive MCEF MCEF MCEF MF-31 NIOSH Manual of Analytical Methods Chemical 3/1 5/2003 Meth No. Method Name 7027 7029 7030 7048 7056 7074 7082 7102 7105 7300 7301 7301 7303 7400 7401 7402 7404 7500 7501 COBALT and cpds, as Co COPPER (dust & fumes) ZINC and compounds, as Zn CADMIUM and cpds, as Cd BARIUM, SOLUBLE COMPOUNDS TUNGSTEN (soluble/nsoluble) LEAD by FAAS BERYLLIUM and cpds, as Be LEAD by GFAAS ELEMENTS by ICP ELEMENTS by ICP (AQUA REGIA ASHING) ELEMENTS by ICP (AQUA REGIA ASHING) ELEMENTS by ICP (Hot Block/HCl/ HNO3 Digestion) ASBESTOS FIBERS by PCM ALKALINE DUSTS ASBESTOS FIBERS by TEM CELLULOSE INSULATION SILICA, CRYSTALLINE, by XRD. SILICA, AMORPHOUS Flow Rate (L/min) 1 -3 1 -3 1 -3 1 -3 1 -4 1 -4 1 -4 1 -4 1 -4 1 -4 1 -4 Vol. (L) min max 30 - 1500 50 - 1500 2 - 400 25 - 1500 50 - 2000 200 - 1000 200 - 1500 25 - 2000 1 - 1500 Varies Varies Extraction aq reg/HNO3 HNO3/HCl HNO3 HNO3/HCl HO hf/hno3 hno3/h2o2 hno3/h2so4 hno3/h2o2 HNO3/HClO4 Aq Reg 1 -4 Varies HCl/HNO3 1 -4 See Table HCl/HNO3 0.5 - 16 400 -var 1 -4 70 - 1000 0.5 - 16 400 -var 1 NA 1.7, 2.2,2.5 400 - 1000 1.7, 2.2,2.5 50 - 400 NA HCl NA NA ash or THF ash Analytical Technique FAAS FAAS FAAS FAAS FAAS FAAS FAAS GFAAS GFAAS ICP-AES ICP-AES ICP-AES ICP-AES PCM Titration TEM SEM XRD XRD 7502 7504 7505 7506 7600 7601 ZINC OXIDE VANADIUM OXIDES LEAD SULFIDE BORON CARBIDE CHROMIUM, HEXAVALENT SILICA, CRYSTALLINE 1 -3 1.7, 2.2,2.5 1.7, 2.2,2.5 1.7, 2.2,2.5 1 -4 1.7, 2.2,2.5 10 - 400 200 - 1000 600 - 1000 100 - 1000 8 - 400 400 - 800 NA THF THF ash reagent HPO4/HF XRD XRD XRD XRD VIS VIS 7602 SILICA, CRYSTALLINE (IR) 1.7, 2.2,2.5 400 - 800 ash IR 7603 7604 7605 7700 7701 7702 7703 7900 7901 7902 SILICA in coal mine dust CHROMIUM, HEXAVALENT CHROMIUM, HEXAVALENT by IONCHROMATOGRAPHY LEAD in Air by Chemical Spot Test LEAD BY ULTRASOUND/ASV LEAD by Field Portable XRF CHROMIUM, HEXAVALENT by FieldPortable Spectrophotometry ARSENIC & compounds, as As ARSENIC TRIOXIDE, as As FLUORIDES, aerosol & gas 1.7, 2.2,2.5 300 - 1000 1 -4 100 - 1000 0.1 - 4 1 - 400 ash NaOH/Na2CO3 NaOH-Na2CO3 IR IC IC 2 1 -4 1 -4 1 -4 1 -3 1 -3 1 -2 10 - 240 20 - 1500 570 - 1900 10 - 1200 NA HNO3 NA (NHJ2SO4/ NH4OH Spot Port ASV XRF (port) VIS 30 - 1000 30 - 1000 12 - 800 HNO3/H2SO4/HClO4 HYAAS HNO3/H2O2 GFAAS NaOH ISE 7903 ACIDS, INORGANIC 0.2 - 0.5 3.0 - 100 HCO3-/CO32- IC Sampler MCEF MCEF MCEF MCEF MCEF MCEF MCEF MCEF MCEF MCEF MCEF PVCF MCEF MCEF MCEF open PTFE MCEF open ACF CYC + PVC PVC (total) PVC&CYC PVC CYC & PVC CYC & PVC CYC & PVC PVC CYC & MCE or PVC CYC & MCE or PVC CYC & PVC PVC PVC MCEF MCEF MCEF PVC, MCE, PTFE MCEF MCEF MCEF & pad w/ Na2CO3 SG(washed) MF-32 NIOSH Manual of Analytical Methods Chemical Meth No. Method Name 7904 7905 7906 CYANIDES, aerosol and gas PHOSPHORUS FLUORIDES by IC Flow Rate (L/min) 0.5 - 1.0 0.01 - 0.2 1 -2 8301 8315 8316 8317 9000 9002 9100 9101 9102 9105 9200 9201 9202 9205 HIPPURIC and METHYL HIPPURIC ACID in URINE NA TRIAZINE HERBICIDES and their METABOLITES NA BUTOXYACETIC ACID in URINE NA ANALINE and o-TOLUIDINE in urine NA ASBESTOS, CHRYSOTILE by XRD NA ASBESTOS (bulk) by PLM NA LEAD in Surface Wipe Samples NA CHROMIUM, HEXAVALENT in settled dust NA ELEMENTS on WIPES NA LEAD in DUST WIPES by Chemical Spot Test NA CHLORINATED ORGANONITROGEN HERBICIDES (HAND WASH) NA CHLORINATED ORGANONITROGEN HERBICIDES (DERMAL PATCH)) NA CAPTAN and THIOPHENATEMETHYL in Handrinse NA CAPTAN and THIOPHENATEMETHYL on Dermal Patch NA Vol. (L) min max 10 - 180 5 - 100 s 1 - 800 i 120 - 800 NA Extraction KOH xylene NaOH Etac Analytical Technique ISE GC-FPD IC HPLC-UV NA NA SC-MSD NA NA GC-ECD NA ALK HPLC-ECD NA NA XRD NA NA PLM NA HNO3/H2O2 AAS; IC P NA NA Spot NA NA NA NA ICP-AES Spot NA NA GC-ECD NA I PA/di azomethane GC-ECD NA NA HPLC-UV NA IPA-ACN HPLC-UV Sampler MCEF & BuB Tenax GC MCEF & pad w/ Na2CO3 NA Urine NA NA bulk bulk Wipes Test strip Wipe Wipe polyethylene bag PUF pad Hand wash Patch 3/1 5/2003 MF-33 NIOSH Manual of Analytical Methods METHOD FINDER KEY TO ABBREVIATIONS Sampling Media/Devices A-747 Anasorb 747 A-CMS Anasorb CMS Ag F Silver membrane filter BuB CCT Bubbler Coconut shell charcoal tube Chrom CYC Chromosorb Cyclone DNPH Dinitrophenylhydrazine Hcl Dry GFF GW Drying tube Glass fiber filter Glass wool HMP 2- (Hydroxymethyl)piperidine IMP Impinger IOM MCEF Inspirable dust sampler Mixed cellulose ester filter MS Molecular sieve NITC 1 - naphthylisothiocyanate OVS-2 OSHA versatile sampler (quartz filter/XAD-2) OVS-7 OSHA versatile sampler ( glass fiber filter/XAD-7) Pad Cellulose backup pad PCT Petroleum charcoal tube Por Poropak PTFE Polytetrafluoroethylene (Teflon) filter PUF Polyurethane foam PVC Polyvinyl chloride filter QFF Quartz fiber filter SG Silica gel SL Soda lime TD Thermalalal desorption tube TEA Triethanolamine XAD Polymeric resin Extraction Media aaa acetic acid/acetonitrile a acid ac acetate ACN acetonitrile acet acetone al alcohol alk alkali aq aq reg aqueous / water aqua regia bz cychex benzene cyclohexane DCE dichloroethane DMF dimethylformamide DMSO dimethylsulfoxide DNPH dinitrophenyl hydrazine Et ethyl Etac ethyl acetate hex hexane HSA hexanesulfonic acid IPA isopropanol isooct isooctane MeCl /Meth methylene chloride/methanol Me methyl Meth methanol MTBE methyl-tert-butyl ether pet petroleum PMA phosphomolybdic acid pyr pyridine reag reagent THF tetrahydrofuran tol toluene TWM tropolone-water-methanol 3/15/2003 MF-34 Analytical Techniques AAS Atomic absorption spectrophotometry AMP Amperometric detector ASV Anodic stripping voltammetry CD Conductivity detector DPP Differential Pulse Polargraphy ECD Electron capture detector ECHD Electrochemical detector ECN Electrolytic conductivity detector EG Evolved gas analysis FAAS Flame AAS FI Flow injection FID Flame ionization detector FL Fluorescence detector FPD Flame photometric detector GC Gas chromatography Grav Gravimetric (filter weight) GFAAS HPLC Graphite furnace AAS High performance liquid chromatography HYAAS Hydride generation AAS IC Ion chromatography ICP-AES Inductively coupled plasma-atomic emission spectroscopy IR Infrared spoectrophotometry ISE Ion specific electrode MS Mass spectrometry NPD Nitrogen phosphorus detector PCM Phase contrast microscopy PES Plasma emission spectrometry PID Photoionization detector PLM Polarized light microscopy SCD Sulfur chemiluminescence detector SEM Scanning electron microscopy Spot Spot test TCD Thermalalal conductivity detector TEM Transmission electron microscopy TOA Thermal optical analyzer UV Ultraviolet VIS Visible absorption spectrophotometry XRD X-ray diffraction XRF X-ray fluorescence Other cap i NA port s var capacity insoluble not applicable portable soluble varies / variable NIOSH Manual of Analytical Methods