Document qdYkwo9ng85L9733nn1OZKOvk

> 32JM l/>9 ' ^ MONSANTO CHEMICAL COMPArNrYaf Plastics Division Limited Procedure for Process Modification RlV^ested by . .v J^1P"b*o Tp-15 o t0 e e e Number .B &-.4o e c o o O O Technical Supervision Plant 0 0 ano Product Group . .XAttyA. Jle.^A .... e000*ao __P .T,,S . Sunv ,, Enff, Date 8/31 Plant Dept. No . 8.8,.... ocooooooetoo Research GrD,, Lead, 8/28 Approva1 F. Dust on R. Pollard ... "" :0oer. SuDt. 9/2 R* Perrv "" Gen. Mfe. Suet. or Expiration Date ....... 0 6 9*0 P.T.S- Manager Modification of SDP h^XWon o.f, Laurie . Standards Dent, Acid and Maleic Anhydride <5/S A . Erl clrsherg .. Reason for Requested Variation Approval required wheq segregation of expense is specified. To determine the effect of lauric acid and maleic anhydride on suspension, homopolymer resin quality (particularly particle size and heat stability). This information should permit us to redefine "Raw material Specifications for Lauroyl Peroxide, Hethyl Glucoside Dilaurate, and PDR-1. s of Modified Procedure The Opalon 300 FM - X-58 process will be used except for the addition of Lauric Acid or Maleic Anhydride to the batch formulation. In the first series of runs, Lauric Acid will be used in increasing amounts (100 grams, 200 grams, 300 grams, ets.) up to 1000 grams, which represents 10 percent of the weight of L202or MGD normally used in a batch formulation. In the second series. Maleic Anhydride will be used in Increasing amounts up to 750 grams, which represents 10 percent of the weight of PDR-1 used in the batch formulation. O $ 'Un vi)ARr.!3 :so` 'r.. ,, r Reference to Previous Work 1. A.P.T. To F.A.D. Progress Report on PDR-1 Study, -July 21, 1959 2. L.D.H. To F.A.D. Progress Reports on L2O2 Study, G Dec. 1958 3. Recent MGD stpdy using material with acid number of 10-15 (approx. 10$ Lauric Acid). ' RSV0024064 Safety Hazards and Predictions ..(Including Toxic' and Steam Pollut^jbn). Maleic Anhydride will he handled with protective equipment by a supervisor only. Product Testing Required and by Whom Slurry samples, will be tested by control lab for (1) particle size, (2) bulk density (3) dry time (4) cfolor and heat stability (5) V.R., (6) BSabender tests (7) extrusion. Identification and Disposition of Material Segregation of Product All material will be segregated from^jnormal .production Labeling of Product Approval for Shipment Opalon 368 X * To be used captively with approval of Research and Tech Service Costs A. Estimated effect on manufacturing costs, If successful 1 None B. Estimated extra manufacturing cost of this experiment None C. Segregation of Costs (by Operating Superintendent) BNo segregation of Costs required Special Accounting number will be required D. If costs are segregated, accounting number assigned (by P.T.S. Manager) ........ ...........1. Informational Copies tos (To be filled out by Standards Department) Plant Laboratory Supervisor Planning and Control Supt. Marketing Technical Service Mgr. General Mfg. Supt. P. T. S. Manager Accounting Dept. Product Administrator Research Section Leader Overseas Mfg) Dept. Other Domestic Plantn 1,1, Lorraine .T Hinchen.. .. ... . . ..... . HL. .Has el ton w, WilliS....... ........ . .....R . -Dunlan ......1... Crabtree - P. Fastuszak Erdman _. Q. Cohen . . _.... . 1..................... ___ EL Armstrong___ __ _ .... % Foreign Plants Other 3 3274 (back) 1/59 CL H-. Mills__ _ RSV00241 5 3274 1/59 MONSANTO CHEMICAL COMPAt1lJP Plastics Division Limited Procedure for Process Modification nested by , X .. 7^4 Vs VP... Technical Supervision , and Reporting By .......... r, -- ,, .. 000000600000 Number Plant . P . A00**00 0*0606000 060 oofOooOOoobccooCi PT'OdllC'fc GrO\lp * * 6 0 0 ^(6*00000*000*0 Plant Dept. No .,. A?* 0*006000*000000** Limited to: Amt. of Material 'P,W$^ or Expiration Date Modification of SDP .K...c..k..'....k..c.v..-.i.j. &F Vavj&\C Ha,Vs\c iXwVj^.'de, Reason for Requested Variation ~"To 4-Uc. c t?-*' <? Acct> StjfpP.T,,S. Sudv. Ene,, _ $$() Research Orb* Lead. Oner. Sunt. 'Mr #Gen. Mfc,, Suot,, fTdAf^r /r A/ x-Qc-,,..-^------ / P.T.S- Manager. Standards Dent,,... f A7 / fn Approval required when segregation expense is specified. t,KiVy dftkt cjv, &U Ss^us.tt!.y\ f e>U/^fcf-WW S'V^. f.ut4 k_\ ^skfc'l-kk. "kk:i wi i v-\&,kcv\ 7 ?btc. Uc.nu>-A- pap&yide % DDeettails of Modified Procedure os "W we. ?: ^ h-cAUI ^locos.'^ dvUwsAW ( Pknu, \Ve iOO 7 \1( - |Qoc.tiS CoAV AC.' e\ Ok or pcVI 5, ; L.vU*' t V-\A.W' - AA V\'} ck'ck, ,\\ t*. 3 co U'- <s^t ^ S ^ 1 09 k SCioo C^ftAvv^a >\T ^>0 (5^ i SCce^7 &> U \ f if > k 7^0 7 } uoii.' c k \o 47s. V>A`"> v.\A, ,t Ku V'j d i oc u> Al V ^ d<? itors 1 Reference to Previous Work nJ ioc.{, e^S'v1 Oj OOlJ '. u ; ,)ri utD C.: ^t^&OAPrrc' \, IX Pt 4-o V. h. , 4 . L.l>v\ Xo \ k ! ?W<i< 7a pAA g^y. \ Oc ^i osj , To\.j L>C a. 7'-' tv C, Vo. \t\t ' ' '"* A7 -y .. ,c 'rf 3. C \ ri; HG7 . .\ OS"1^ (\ uv 1 47 AC' d> vOu'\7='v \O.Atr C M^*W RSV0024066 ASafety Hazards and Pr<MTutjons (including Toxlcit * Air, and Steam Pollution) 9 Product Testing Required and by Whom Identification and Disposition of Material Segregation of Product ku_ h^V ^,\\ be Labeling of Product sl* v Costs A., Estimated effect on manufacturing costs. If successful B. Estimated extra manufacturing cost of this experiment C. Segregation of Costs (by Operating Superintendent) HJ' No segregation of Costs required Special Accounting number will be required D. If costs are segregated, accounting number assigned (by P.T.S. Manager) Informational Copies to; (To be filled out by Standards Department) Plant Laboratory Supervisor Planning and Control Supt, Marketing Technical Service Mgr. Oeneral Mfg. Supt. P. T. S. Manager Accounting Dipt. Product Administrator Research Section Leader Overseas Mfg. Dept. Other Domestic Plante Foreign Plants Other <TS 39.74 /haetN i /so RSV0024I IS 3274 I/59v MONSANTO CHEMICAL COMPANY Plastics Division Limited Procedure for Process Modification guested by Archie Pe Torrensano Number /0%r A/ Mriy[(j\J> * $EP 9 , \- CF- mrnom ,/y TaneaShR5sipoih*tifn"gSeBSyI1S*,l*pn*A.*r*e.hcioea?o.ocTt.oPrfpl*ooneeno Plant , 3pr iftrmrov.ai --------------------------- Kf c u> r i33 Product Group . p * * ......OOP... P.T.R. Sudv,, Ena: P- Duaton______ Plant Dept . No ..88............e...... Research Oro- Lead. 8/68 R. Pollard____ Limited to: Amt. of Material 2P. t ODer. SuDt. e Gen. Mfa,, Sunt,, or Expiration Date ........... *P.T*S- Manager 9/2 R. Perrv Modification . Standards Dent,, 9/3 A. Erioksberg. Reason for Requested Variation Approval required when segregation of expense is specified. To determine the effect of lauric acid and maleic anhydride on suspension, homopolymer resin quality (particularly particle sis and heat stability}. This* information Should permit us to redefine "Raw material Specifications" for Lauroyl Peroxide, Hethyl Glueoside Dilaurafee, and FZE-1. Details of Modified Procedure The Qpalon 300 PM - Xf>8 process will be used except for the addition of Laurie Acid or Maleic Anhydride to the batch formulation. In the first aerie of runs, Laurie Acid will be used In increasing amounts (100 grams, 200 grams 300 grams, ets.) up to 1000 grams, which represents 10 percent of the weight " of LgOjgor WD normally used in a batch formulation. In the -second series. Maleic Anhydride will be used in Increasing amounts up to 750 grams, which represents 10 percent of the weight of PDR-1 used in the batch formulation. 4 % 1QCQ hiTMENT to Previous Work A.P.V. To ,,A.D. Progress Report on FBR-1 Study, July 21, 1959 L.jD.H. To F.A.D. Progress Reports on LgOg Study, C Dec. 195-8 Recent MOD study using material with acid number of 10-15 (approx. 3.0$ Laurie Acid). RSV0024068 Safety Hazards and PreMutions (Including Toxlcltj^Air, and Steam Pollution) Maleic Anhydride will be handled with protective equipment by a supervisor only.. Product Testing Required and by Whom Slurry samples will be tested by control lab for (l) particle site* (2) bulk density (3) dry time (4) cfclor end heat stability (5) V.R., (6) Bvttbender teste (?) extrusion. Iaentiflcatlon and Disposition of Material Segregation of Product All material will be segregated from normal production Labeling of Product Opalon 368 X Approval for Shipment To be used oaptively with approval of Research and Tech Service Costs A.Estimated effect on manufacturing costs, if successful None B. Estimated extra manufacturing cost of this experiment None C. Segregation of Costs (by Operating Superintendent) BNo segregation of Costs required Special Accounting number will be required D. If costs are segregated, accounting number assigned (by P.T.S. Manager) ...................... .. Informational Copies to: (To be filled out by Standards Department) Plant Laboratory Supervisor Planning and Control Supt. Marketing Technical Service Mgr. General Mfg. Supt. P. T. S. Manager Accounting D<spt. Product Administrator Research Section Leader Overseas Mfg. Dept, Other Domestic Plant* L. Louralne J.,, Etnehen T. Haael.fcpn w. wniis R. Dunlap -^-Crabfcrcfl. A,, Erdman CL Cohen T Easfeusaak Foreign Plants Other rs 3274 (back* 1/59 0,. H.-Mills RvSV0024