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Genium Publishing Corporation Material Safety Data Sheets Collection: One Genium Plaza Schenectady. NY 12304-4690 USA Sheet No. 382 Vinyl Chloride (518) 377-8854 Issued: 7/78 Revision: C. 9/92 Section 1. Material Identification Vinyl Chloride (CjHjCI) Description: Derived from ethylene dichloride and alcoholic potassium, by reaction of acetylene and hydrogen chloride (as gas or liquids), or by oxychlorination where ethylene reacts with hydrochloric acid and oxygen. Inhibitors such as butyl catechol, hydroquinone, or phenol are added to prevent polymerization. Used in the plastics industry for the production ofpolyvinyl chloride resins, in organic synthesis and formerly as a refrigerant, extraction solvent, and propellant (banned in 1974 because of its carcinogenic activity). Other Designations: CAS No. 75-01-4, chloroethylene, chloroethene, ethylene monochloride, Trovidur, VC, VCM. Manufacturer: Contact your supplier at distributor. Consult latest Chemical Week Buyers' Guid^*** for a suppliers list. Cautions: Vinyl chloride is a confirmed human carcinogen. Vapor inhalation leads to central nervous system (CNS) depression. The liquid can cause frostbite. It is a flammable gas at room temperature and polymerizes on exposure to air or sunlight. Avoid exposure to VC through engineering controls and wearing PPE 39 NFPA HMIS H 3* F4 R2 PPE - Sec. 8 * Chronic effects Section!^ Vinyl Chloride, ca 98 to 99%. Impurities include water, acetaldehyde, hydrogen chloride, hydrogen peroxide, methyl chloride, butane. 1,3-butadiene, chkjrophene, diacetylene, vinyl acetylene, and propine. 1991OSHA PELS 8-hr TWA; 1 ppm Ceiling: 5 ppm; OSHA-X 1990 NIOSH REL NIOSH-X 1992-93 ACGIH TLV TWA: 5 ppm (13 mg/m3) TLV-A1 1990 DFG (Germany) TRK* Existing Installations: 3 ppm MAK-A1 1985-86 Taxidty Dataf Man, inhalation, TC^: Intermittent exposure to 200 ppm for 14 yr caused liver tumors. Man, inhalation, TQ^: 30 rag/m3/5 yr caused spermatogenesis. Human, inhalation. TC: Continuous exposure to 300 mg/m3 far an undetermined number of weeks caused blood tumors. Rat, oral, LD^ 500 mg/kg; toxic effects not yet reviewed * TRK (technical exposure limit) is used in place of MAK wben a material is a caronogen. Unlike an MAK below which no advene effecti arc expected, the TRK it a limit set below which advene effects may still occur. This is based on the dieoiy that 1 molecule at a carcinogenic substance may still produce a tumor. The TRK is set to allow for an acceptable risk (for example, 1 tumor in 1 million persons may bean acceptable risk), t See NIOSH, KTBCS (KU9625000). for additional mmaaoo. reproductive, ttanorigenic, and toxicity data. SeMTOPhracal PatT" Bolling Point: 7 *F (-13.9 *Q Freezing Point: -245 *F (-159.7 'Q Molecular Weight: 62-5 Specific Gravity: 0.9106 at 68 *F (20 *Q Ionization Potential: 9.99 eV Refraction Index: 1370 at 20 *C/D Surface Tension: 23.1 dyne/cm at -4 *F (-20 *Q Odor Threshold: 2000 to 5000 ppm* Vapor Density (Air = 1): 2.155 Water Solubility: Slightly soluble, 0.1% at 77 *F (25 *C) Other Solubilities: alcohol, benzene, carbon tetrachloride, ether, hydrocarbon and oils. Vapor Pressure: 2530 mm Hg at 68 *F (20 *Q, 400 mm Hg at -18.4 *F (-28 *C) Critical Temperature: 304.7 *F (1513 *Q Critical Pressure: 56.8 atm Viscosity: 0.01072 cP at 68 T (20 *C). gar, 028 cP at -4 *F (-20 *C), liquid Appearance and Odor: A gas at room temperature. Usually found as a compressed/ cooled liquid. The colorless liquid forms a vapor with a pleasant ethereal odor. *The actual vapor concentration that can be detected by humans has not been adequately determined and varies from one individual to another, from impurities, and probably from exposure duration. The odor threshold is not an accurate warning of exposure. Section 4.; fireand Explosion Data Flash Point:-108.4 *F (~78*C) PC | Autoignition Temperature: 882 *F (472 *C) |LEL:3.6%v/v UEL: 33% v/v Extinguishing Media: For small fires, use dry chemical or carbon dioxide. For large fires, use water spray, fog, or regular foam. Unusual Fire or Explosion Hazards: Large fires can be practically inextinguishable. Vapors may travel to an ignition source and flash back. VC may polymerize in cylinders or tank cars and explode in beat of fire. Vapors pose an explosion hazard indoors, outdoors, and in sewers. VC decom poses in fire to hydrogen chloride, carbon monoxide, carbon dioxide, and phosgene. Burning rate = 43 mtn/min. Special Fire-flghtlng Proce dures: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode. Stop gas leak if possible. Let tank, tank car, or tank truck burn unless leak can be stopped. For massive fire in cargo area, nse monitor nozzles or unmanned hose holders; if this is impossible, withdraw from area and let fire bum. Withdraw immediately if you hear a rising sound from venting safety device or notice any tank discoloration due to fire. Do not release runoff from fire control methods to sewers or waterways. Sections. ReactivityData Stability/Polymerization: Long term exposure to air may result in formation of peroxides which initines explosive polymerization of the chloride. VC can polymerize on exposure to light or in presence of a catalyst. Chemical Incompatibilities: VC can explode on contact with oxide of nitrogen, may liberate hydrogen chloride on exposure to strong alkalies, and is incompatible with copper, oxidizers, aluminum, and peroxides. In the presence of moisture, VC attacks iron and steeL Conditions to Avoid: Exposure to sunlight, air, heat, and incompatibles. Hazardous Products of Decomposition: Thermal oxidative decomposition of vinyl chloride can produce carbon oxides, and chloride gas. Section 6. Health Hazard Data Carcinogenicity: Vinyl chloride is listed as a carcinogen by the IARC (Class 1, sufficient human evidence)/164) NTP (Class 1, sufficient human evidence)/169* NIOSH (Class X, carcinogen defined withoutfurther calegorizalion)P&l ACGIH (TLV-A1, confirmed human carcinogen),iltJ) DFG (MAK-A1 .capable ofinducing malignant tumors in humans),and OSHA (Class X, carcinogen defined withoutfurther calegoriiat<on).(164* Liver tumors (angiosarcomas) are confirmed from VC exposure. Other tumors of the CNS, respiratory system, blood, and lymphatic system have occurred from exposure to the polyvinyl chloride manufacture process but VC itself may not be the causative agent. Summary of Risks: Vapor inhalation causes varying degrees of CNS depression with noticeable anesthetic effects at levels of 1% (10.000 ppm). Studies have shown loss of libido and sperm in men exposed to VC and in Russian studies, 77% of exposed women experienced ovarian dysfunction, benign uterine growths, and prolapsed genital organs. However, no teratogenic effects have been seen in offspring of exposed workers. Copyright C 1992 Genium Publishing Corporation. Any catunuciil mm or uptrisninw wnbout the publisher's pemiiwiini w piMiisil CTL031677 Continue on next poge ------------------------ No. 382 Vinyl Chloride 9/92 _____________ __ __________________________________________________ _______________ ____ _________ Section 6. Health Hazard Data, continued_____ ____________________________________ ________ ll appears that metabolism is necessary before many of VOs toxic effects occur. Some vinyl chloride is exhaled unchanged but most is metabolized to chloroacctaldehyde. Skin absorption may occur if liquid is confined on skin but absorbed amount would be small. It is possible that the phenol inhibitor may be absorbed as well. The compressed liquid can cause frostbite. Vapors are severely irritating to the eyes. Chronic exposure can cause cancer and a triad of syndromes known as vinyl chloride disease. Medical Conditions Aggravated by Long-Term Exposure: Liver, cardiac, pulmonary, and connective tissue disorders. Target Organs: Liver. CNS, respiratory and lymphatic systems, bone, and connective tissue of the skin. Primary Entry Routes: Inhalation, skin/eye contact. Acute Effects: CNS effects include fatigue, headache, vertigo, ataxia, euphoria, visual disturbances, dulling of auditory cues, numbness and tingling in the extremities, narcosis, unconsciousness, and death due to respiratory failure. Respiratory problems include dyspnea, asthma, and pneumonoconiosis. Chronic Effects: Repeated exposure has lead to liver cancer, confirmed because of the otherwise rarity of its type (angiosarcoma). Tumors in other organs have occurred in the polyvinyl chloride industry but agents other than VC may be responsible; authorities are still debating this issue. A triad of other effects are associated with VC exposure. Acro-osteolysis is associated with hand cleaning of polymerization vessels and characterized by dissolution of bone in the hands, especially when associated with resorption. Raynaud's Phenomenon is a vascular disorder marked by recurrent spasm of the capillaries and especially those of the fingers and toes on exposure to cold. This is usually accompanied by pain and in severe cases may progress to local gangrene. Sclerodermatous skin changes (affecting the dorsal hands and distal forearms) are seen and described as a slowly progressive disease marked by deposition of fibrous connective tissue in the skin. The sldn becomes thickened and raised nodules appear. Arthralgias (pain in one or more joints) and blood changes with decreased platelet number and capillary abnormalities may also occur. FIRST AID Eyes: Do nos allow victim to rub or keep eyes tightly shut. Gently lift eyelids and flush immediately and continuously with flooding amounts of water until transported to an emergency medical facility. Consult a physician immediately. Skin: Quickly remove contaminated clothing. Rinse with flooding amounts of water for at least 15 min. Wash exposed area with soap and water. For reddened or blistered skin, consult a physician. For frostbite, immerse affected area in 107.6 *F (42 *C) water until completely rewarmed. Do noS use dry heat Inhalation: Remove exposed person to fresh air and support breathing as needed. Ingestion: Unlikely! VC is a gas above 7 *F (-14*C). Note to Physicians: Endotracheal intubation may be required if significant CNS or respiratory depression occur. Diagnostic test thiodiglycolic acid in urine (normally < 2 mg/g creatinine). Section 7. Spill, Leak, and Disposal Procedures.-'"y. _____________________________ SpUI/Leak: Notify safety personnel, isolate and ventilate area, deny entry, and stay upwind. If possible without risk, stop gas flow. Shutoff ignition sources. Report any release > 1 lb. Follow applicable OSHA regulations (29 CFR 1910.120). Environmental Transport: VC reacts with hydroxyl radicals in the trophosphere with a half-life of 12 days. The half-life = a few hr in photochemical smog. Reaction products in the air include chloro- acetaldehyde, hydrogen chloride, chloroethylene, epoxide, formaldehyde, formyl chloride, formic acid, and carbon monoxide. In soil, VC rapidly volatil izes. What does not evaporate will be highly mobile and may leach into groundwater. In water. VC is not expected to hydrolyze, bioconcentrate, or absorb to sediment. It will rapidly volatilize with an estimated half-life of 0.805 hr for evaporation from a river 1 meter deep with a current of 3 meter/sec and a wind velocity of 3 meter/sec. In waters containing photosensitizers such as humic acid, photodegradation will be rapid. Soil Absorption/MobQlty: From an estimated solubility of 2,700 ppm, a Koc of 56 is established for VC which indicates high soil mobility and potential to leach into groundwater. Disposal: Dilute any waste compressed liquid to a 1% solution and remove phenol inhibitor as sodium. Pour onto vermiculite, sodium bicarbonate, or a sand & soda ash mixture (90/10). Add slaked lime if fluoride is present Mix in paper boxes, place in incinerator, cover with scrap wood and paper, and ignite with excelsior train. Another method is to dissolve waste in a flammable solvent and spray in incinerator firebox equipped with an afterburner and alkali scrubber. Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and local regulations. EPA Designations OSHA Designations Listed as aRCRA Hazardous Waste (40 CFR 26133): No. U043 Listed as an Air Contaminant (29 CFR 1910.1000, Table Z-I-A) SARA Extremely Hazardous Substance (40 CFR 355), TPQ: Not listed Listed as a SARA Toxic Chemical (40 CFR 372.65) Listed as a CERCLA Hazardous Substance* (40 CFR 302.4): Final Reportable Quantity (RQ), 1 lb (0.454 kg) [* per CWA, Sec. 307 (a); CAA, Sec. 112.&RCRA, Sec. 3001] Section 8. Special Protection Data Goggles: Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Because contact lens use in industry is controversial, establish your own policy. Respirator: Seek professional advice prior to respirator selection and use. Follow OSHA (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. According to NIOSH*14*', for any detectable concentration use a SCBA or supplied-air respirator with a full facepiece operated in pressure-demand or other positive pressure mode. See 29 CFR 1910.1017 for detailed OSHA respirator recommendations. For emergency or nonroutine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. Wanting! Airpurifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas. Other: Wear chemically protective gloves, boots, aprons, and gauntlets made of Viton or chlorinated polyethylene to prevent skin contact Ventilation: Provide general and local exhaust ventilation systems to maintain airborne concentrations below the OSHA PEL'S (Sec. 2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source/103) Safety Stations: Make available in the work area emergency eyewash stations, safety/quick-drench showers, and washing facilities. Contaminated Equipment: Separate work clothes from street clothes, launder before reuse and clean PPE Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics. Section 9. Special Precautions and Comments Storage Requirements: Store in a cool, dry, well-ventilated area in dearly labeled containers. Outside or detached storage is preferred. Large amounts should be stored in steel containers under pressure. Keep separate from incompatibles (Sec. 5). Venting, under pressure should be safety relief. At atm, venting should be pressure vacuum. Regularly monitor inhibitor levels. To avoid static sparks, electrically ground and bond all equipment used with VC. Avoid open flames, spark formation and electric discharges around VC. Engineering Controls: To reduce potential health hazards, use sufficient dilution or local exhaust ventilation to control airborne contaminants and to maintain concentrations at the lowest practical level. Install Class 1, Group D electrical equipment. Administrative Controls: Infoim VC exposed personnel of hazards associated with its use. Preplacement and periodic medical exams of workers exposed above the action level is mandatory under OSHA 29 CFR (1910.1017). Monitor for liver cancer, scleroderma, pneumonitis, clotting abnormalities, and acro-osteolysis. Transportation Data (49 CFR 172.101) DOT Shipping Name: Vinyl Chloride DOT Hazard Class: 2.1 ID No.: UN1086 DOT Packing Group: -- DOT Label: Flammable Gas Sp_e_c_i_a_l_P__ro__v_is__io_n__s_(_1_7__2_.102): B44 Packaging Authorizations a) Exceptions: 173.306 b) Non-bulk Packaging: 173304 c) Bulk Packaging: 173.314 & 173.315 Quantity Limitations a) Passenger Aircraft or Railcar: Forbidden b) Cargo Aircraft Only: 150 kg Vesse, Stowage Requlrements a) Vessel Stowage: B b) Other: 40 CTLO 3167 1D' MSDS Collection References: 26.73.100. 101,103.124. 126,127,132.133, 136,140, 148. 149,153. 159. 162.163, 164. 167,168, 171. 174 175 Prepared by: M Gannon. BA; Industrial Hygiene Review: PA Roy, MPH, C1H; Medical Review: AC Partington. MPH. MDI CtyrrtahfOtWZbyGcoiemPuMoheigCorpcoMKa,. AnycrnienoreiUicorie|Modwtionwrthowthc|oibfaWa|onintMionwprohbriod.Jo4nenMwlothcM*iiabaityofetfonmtronhcfeinforthcporchacr,ininoec tMKhtMef* leaporwibility. Althraigb teuonaUo ewe ha, been ufccn m the pepvalKnof ntch eiformauoa. Gaueat Ptibfuhrnc Ctryornnaroxaenda no -irrutet. mitn no leprcacnuijoin, and utionei no mpteutbility u to tie rccwrecy or Mutability o( web mfonnwjrei for application to the perefwcr'i mtcnrhx) pwrpmo or for cofne<|ucnaM of its uae. Genium Publishing Corporation 1145 Catalyn Street Schenectady, NY 12303-1836 USA (518)377-8854 Material Safety Data Sheets Collection: Sheet No. 701 Polyvinyl Chloride Issued: 4/90 Section 1 Material Identification________________________ - ______________ ____ 31 Polyvinyl Chloride (PVQ Description: Produced by polymerization of vinyl chloride in the presence of initiators such R 1 as 0.1 to 0.5% benzoyl peroxide. Used as a rubber substitute, floor covering, and imitation leather, in tubing, electric wire, I cable coverings, pliable thin sheeting, film finishes for textiles, nonflammable upholstery, synthetic turf, sealant liners for S 2 ponds and reservoirs, plastisols and organisols, adhesives and bonding agents, belting, shoe soles, gaskets, raincoats, and K Genium containers for cosmetics, toiletries, household chemicals. PVC tubing is used in items requiring clear, flexible tubing such as catheters and parts of dialysis devices. PVC may be molded into electric insulators, water pipes, handles, and various recreation items. Other Designations: CAS No. 9002-86-2; (Cj-H^-Cl)^ chloroethylene polymer, PVC; vinyl chloride bomopolymer, Rhovyl; Nip; Fibravyl; Envilon; Thermovyl; Crinovyl; Isovyl; RetractyL Manufacturer: Contact your supplier or distributor. Consult the latest Chemicahveek Buyer,s' Guided for a suppliers list HMIS H2 F0 R0 PPG* * Sec. 8 :OccMppLtiotttal Expostire li,iini^ Polyvinyl chloride, ca 100% OSHA PEL None established ACGIHTLV, 1989-90 None established NIOSH REL, 1987 None established Toxicity Data* Rat, oral, TDU: 210 g/kg ingested over a continuous 30-week exposure showed PVC is an equivocal tumorigenic agent, with tumors found on the lungs, thorax, skin, and appendages Rat, implant, TDU: 75 mg/kg implanted showed effects of an equivocal tumorigenic agent, with tumors developing at the application site * Monitor NIOSH, KTBCS (KV0350000), for future data. Sfediotf3|sPftyacatl)a^ ?: Molecular Weight: 60,000 to 150,000* Water Solubility: Insoluble Appearance and Odor: White powder; odorless. * Since PVC has polymers with molecular weights ranging from 60,000 to 150,000, its physical properties vaiy with molecular weight. Consult your manufacturer or supplier to ascertain the exact information applicable to your purchased PVC. Sedtioiif^Eire andImplosion Data Flash Point: None reported Autoignition Temperature: None reported LEL: None reported UEL: None reported Extinguishing Media: Use large quantities of water to fight polyvinyl chloride fires. Unusual Fire or Explosion Hazards: Finished foam resins burn readily. If freshly manufactured foam resins are not allowed to cool thoroughly before stacking in bulk, they may ignite spontaneously. While burning, most foam resins spread the fire with their drippings. An explosion hazard exists during vinyl chloride's polymerization. Special Flre-flghting Procedures: Since fire produces toxic fumes, wear a self-contained breathing apparatus (SCBA) with a full facepiece operated in die pressure-demand or positive-pressure mode. Be aware of runoff from fire control methods. Do not release to sewers or waterways. Seetioh 5; Reactivity Data : . -;v:^ .v?-:: ' i Stability/Polymerization: PVC is stable at room temperature in closed containers under normal storage and handling conditions. However, even at ordinary temperatures, polyvinyl chloride may undergo slow dehalogenation with evolution of hydrogen chloride. Hazardous polymerization can occur. Use stabilizers to prevent dicoloration from exposure to heat or light. Chemical Incompatibilities: Reacts violently with fluorine (F2). Conditions to Avoid: HeaL Hazardous Products of Decomposition: Thermal oxidative decomposition of polyvinyl chloride can produce toxic fumes of carbon monoxide (CO), hydrochloric acid (HC1), and phosgene (CCl^O). Phosgene is not irritating at first, but may cause fatal pulmonary edema or pneumonia. Inhalation of high concentrations causes choking, painful breathing, coughing, and bloody expectorant (MSDS Collection, No. 66). Copyright 01990 ftbikbsi Cocponboa Any coamcrctal me at reproduchoa without the publisher's pennroan ts prohibited CTL031679 No. 701 Polyvinyl Chloride 4/90 Section6. Health Hazard Data Carcinogenicity: Neither the NTP, IARC, nor OSHA lists polyvinyl chloride as a carcinogen. Summary oT Risks: Chronic inhalation of polyvinyl chloride causes pulmonary damage, abnormal liver functions, and blood effects. Prolonged or repeated skin contact causes irritation and allergic dermatitis. "Meat wrapper's asthma" (conjunctivitis, rhinitis, bronchoconstriction) has resulted from cutting PVC film with a hot knife. Applying heat to PVC initiates thermal degradation (pyrrolysis) and production of toxic gases such as hydrogen chloride, ethyl chloride, etc. PVCs toxicity may result from the other compounds associated with it. Fresh PVC can contain small amounts of toxic and carcinogenic vinyl chloride. Medical Conditions Aggravated by Long-Term Exposure: In plants that make PVC from monomeric vinyl chloride, several cases of angiosar coma (rare malignant tumor) of the liver among long-time workers ate reported. After 20+ years of PVC dust exposure, cases of dyspnea (short ness of breath) are also reported. Target Organs: Eyes, skin, respiratory tract, lungs, liver, blood. Primary Entry Routes: Inhalation. Acute Effects: Direct contact with the skin and eyes causes allergic dermatitis and conjunctivitis, respectively. Chronic Effects: Chronic inhalation causes fibrotic lung changes, alterations in the respiratory organs, and rhinitis. FIRST AID Eyes: Flush immediately, including under the eyelids, gently but thoroughly with flooding amounts of running water for at least 15 min. Skin: Quickly remove contaminated clothing. After rinsing affected akin with flooding amounts of water, wash it with soap and water. Inhalation: Remove exposed person to fresh air and support breathing as needed. Ingestion: Never give anything by mouth to an unconscious or convulsing person. If ingested, have a conscious person drink 1 to 2 glasses of water, then induce repeated vomiting until vomit is clear. After first aid, get appropriate In-plant, paramedic, or community medical support, Section 7. Spill, Leak, and Spill/Leak: Notify safety personnel, remove all heat and ignition sources, provide adequate ventilation, and evacuate all unnecessary personnel. Cleanup personnel should protect against dust inhalation and skin and eye contact With nonsparking tools, scoop spilled powder into appropriate disposal containers. Follow applicable OSHA regulations (29 CFR 1910.120). Disposal: Contact your supplier or a licensed contractor far detailed recommendations, follow applicable Federal, state, and local regulations. EPA Designations RCRA Hazardous Waste (40 CFR 261.33): Not listed CERCLA Hazardous Substance (40 CFR 302.4): Not listed SARA Extremely Hazardous Substance (40 CFR 355): Not listed SARA Toxic Chemical (40 CFR 372.65): Not listed OSHA Designations Air Contaminant (29 CFR 1910.1000, Subparl Z): Not listed Section 8. Special Protection Data Goggles: Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Respirator: follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a NIOSH-approved respirator, for emergency or nonroutine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. Warning: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Other: Wear impervious gloves, boots, aprons, and gauntlets to prevent skin contact. Ventilation: Provide general and local explosion-proof ventilation systems to maintain airborne concentrations that promote worker safety and productivity. Local exhaust ventilation is preferred since it prevents contaminant dispersion into the work area by controlling it at its source.''0* Safety Stations: Make available in the work area emergency eyewash stations, safety/quick-drench showers, and washing facilities. Contaminated Equipment: Never wear contact lenses in the work area: soft lenses may absorb, and all lenses concentrate, irritants. Remove this material from your shoes and equipment Launder contaminated clothing before wearing. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics. Section 9. Special Precautions and Comments Storage Requirements: Store in closed containers in a well-ventilated, cool area equipped with an above-average density of sprinkler heads. Maintain this material's temperature below its critical value. Keep storage area free of paper, textile, and other combustible materials. Engineering Controls: Adequate ventilation and appropriate personal protective gear is essential. Preclude from exposure those with respiratory disease. Since vinyl chloride is explosive during polymerization, tanks should be guarded by wire netting. All engineering systems should be of maximum explosion-proof design, electrically grounded, and bonded. In addition, remote controls and alarms should be installed to detect any leakage of vinyl chloride into the air. , Transportation Data (49 CFR 172.101, .102): Not listed CTL031680 MSDS Collection References: 1, 73, 89, 100, 101, 103, 123, 124, 126, 127, 136 Prepared by: MJ Allison, BS; Industrial Hygiene Review: DJ Wilson, CM; Medical Review: W Silverman, MD C"P'rt*hl ^ 6r Corporation. Any moamid Be or rcpntoncaoo oriltarr Be pnbluher-. pertrmaton a protobtoi. hidfment. u u> Be nrubilrty of mlonaetloo herein lor Ore anrchWa prana ere nml,r Be potrapomrbtlity. Although rcaottnblo core hoe been token to Be preporenon of meh toforrneooo. Gernrrta Fabiahtat Corporrtroa ciiendi nobuo, etontn rrrranuBoi. end-________ oorc^oostbflity ta to (he accuracy or notability of arch mfornMUon for opplKalian to fee purchaso** intended purpose or lot coaseqwcoccs of us use.