Document qa6k80OpgQR37mLMw4nDzqmoE

FILE NAME: US Government Contractor Regulations Including Shipyard Regulations (GCR) DATE: 1969 June 20 DOC#: GCR025 DOCUMENT DESCRIPTION: Military Standard - Symbols for Packages and Containers for Hazardous Industrial Chemicals and Materials tlIL-STD-1341 W W l 03^250^ 2^5 MIL-STD-13!il(SA) 20 June 19o9 MILITARY STANDARD SYMBOLS FOR PACKAGES AND CONTAINERS FOR HAZARDOUS INDUSTRIAL CHEMICALS AND MATERIALS > JHtS DOCUMENT COMTAINSA^PAGES /rec p a c k / I Provided by IHS No reproduction o r networking permitted w ithout license from IHS 1413 Sold to PATTEN, WQRNOM. HATTEN & DtAMO, 01844492 Not fo r R esale^O 11/2/4 14 31'3 0 GMT _____ ______ MIL-STD-1341 4444411 0342510 T07 MIL-STD-1341(SA) 20 June I969 DEPARTMENT OF DEFENSE NAVAL SUPPLY SYSTEMS COMMAND WASHINGTON, D. C. 20390 Symbols for Packages and Containers for Hazardous Industrial Chemical and Materials M H j-STD-13^1(SA) 1. This standard has been approved by the Naval Supply Systems Command. 2. Recommended corrections, additions, or deletions should be addressed to the Naval Supply Systems Command (SUP 0442), Washington, D. C. 20390. 4 1414 Provided by IHS No reproduction o r networking permitted without license from IHS ii Sold to PATTEN, W ORNOM, HATTEN & DIAMO, 01S4442 Not fo r Resale,2011/2/4 14 31.30 GMT MIL-STD-1341 T'm'lll QS^Sll <M3 FOREWORD MIL-STD-134l(SA) 20 June 1969 Bie purpose of this standard is to establish a uniform symbol to warn users of the potential dangers involved with the use of the mate rial in containers. The materials to be marked are those having one or more hazardous characteristics defined herein. This standard prescribes marking of unit, intermediate and shipping containers, unit loads and containers that are components of kits or sets. It also provides criteria for application of symbols and for submission of data. Exceptions. The symbols of this standard are not intended to cover or conflict with the following conditions, regulations or categories of material: 1. macies. Chemicals or drugs used or dispensed by medical department phar 2. Chemicals used by clinical or chemical laboratories. exempted laboratories will be those designated by the departments, bureaus, offices and the Marine Corps.) (The 3. Explosives, fuels and compressed gases adequately covered by statute, regulation or current instructions. 4. Magnetic materiels requiring shielding or marking or both for air shipment. 5. Items and containers which require marking to conform to Depart ment of Transportation or Shipping Regulations. 1415 [Provided by IHS Mo reproduction o r networldng p e rm itte d w ithout license from IHS iii Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844482 Not fo r Resale,2011/2/4 14 31.30 GMT HIL-STB-13H1 R W l l DB^ESIE T CONTENTS MIL-STD-lS^liSA) 20 June 1969 Paragraph Page 1. 2. REFERENCED DOCUMENTS........................................ 1 I 3- DEFINITIONS.................................................. 2 I k. GENERAL REQUIREMENTS........................................ 2 I 5. DETAILED REQUIREMENTS....................................... 2 1 5.1 Size of Symbols................. ........................... 2 1 5.2 5*3 Marking and Design........................................... 2 1 5.^ Posters and Signs........................................... 3 1 5.5 Criteria for Application of Symbols..................... 3 1 5.5.I Application........ ...... ................................... 3 5-6 Data Submission............................................. 3 I FIGURES Figure 1. Hazard Identification System........................... . k I 2. Color Format........................ ................. ...... 5 1 3. Alternate Color Format...................................... 6 I 4. Dimensions.................................................. 1 1 5. Small Size Marking.......................................... 8 1 6. Posters...................................................... 9 1 7. Form LSB OOS-I+ ..................................... iB 1 1 ` 16 provided by IHS No reproduction or networking permitted without license from IHS tr Sold to PATTEN, W ORNOM, HATTEN & DIAMO. 01844492 Not for Resale,2011/2/4 14.31.30 GMT 1 MIL-STD-1341 "H T m i D B i e s i a 71b MIL-STD-13^l(SA) 20 June 1969 > Appendix APPENDICES Page A. HAZARDOUS MATERIAL SYMBOL APPLICATION CRITERIA.............. 10 B. INSTRUCTIONS FOR PREPARING DEPARTMENT OF LABOR MATERIAL SAFETY DATA SHEET FORM LSB OOS-4............. ......... ... 12 > 1417 iProvided by IHS Mo reproduction or ne tw o rkin g p e rm itte d w ith o u t ic e nee from IHS y Sold to PATTEN, W ORNOM, HATTEN & DIAMO, 01644492 Not fo r Resale,2011/2/4 14 31 30 GMT HIL-STD-1341 W W l 03^514 bSE 1. SCOPE MIL-STD-134l(SA) 20 June 1969 1.1 Scope. This standard covers design, colors, sizes and require ments for warning symbols to be affixed to packages and containers con taining hazardous industrial chemicals and materials. 2. REFERENCED DOCUMENTS 2.1 The issues of the following documents in effect on the date of invitations for bids form a part of this standard to the extent specified herein. SPECIFICATIONS Military MIL-M-I959O Marking of Commodities and Containers to indicate Radioactive Material STANDARDS Federal i FED-STD-595 Colors (Requirements for individual color chips) ( 3 X 5 supplements) should be submitted to the Naval Supply Depot, Philadelphia, Citing FED-STD-595 to gether with appropriate chip number as shown therein (Copies of specifications, standards, drawings and publications required by contractors in connection with specific procurement functions should be obtained from the procuring agency or as directed by the contracting officer.) OTHER PUBLICATIONS Recommended System for the Identification of Fire Hazards of Mate rials, NFPA No. 70*01: Fire Protection Guide on Hazardous Materials (contains NFPA 325A, 325M, kS, 491M and 704m ) (Copies may be purchased from the National Fire Protection Association, 60 Battery March Street, Boston, Massachusetts 02110.) 1 Al 8 [Provided bv IHS No reproduction or ne tw o rkin g p e rm itte d w itho ut license from IHS 1 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01644492 Not fo r Resale,2011/2/4 14 31 30 GMT riiL-sTD-iBm oa^Esis s'n MIL-STD-134l(SA) 20 June 1969 3. DEFINITIONS 3-1 Fire Hazard. The definition of Fire Hazard, which includes Flam mability Hazard, Reactivity and Health Hazard, of the National Fire Pro tection Association, NFPA No. 70hM, shall apply. 3*2 Radiation Hazard. Any commodity that must be labeled in accordance1 with requirements and criteria of MIL-M-19590 3.3 Reactivity. The definition of reactivity of NFPA No. 704m shall apply. 3-4 Health Hazard. The definition of health hazard of NFPA No. 704M shall apply. 35 Oxidizing Material. A substance such as chlorate, permanganate, peroxide, nitro carbo nitrate, or a nitrate that yields oxygen to stimu late the combustion of organic material. 3.6 Corrosive Material. Acids, alkali or other material that will cause severe damage to living tissue or to other material it contacts. 4. GENERAL REQUIREMENTS 4.1 Symbols covered by this standard shall be applied to each unit, intermediate, and shipping container, unit loads and individual compo nents within kits and sets. Symbols shall be in accordance with Figures 1 through 5, and may be applied by stencilling, painting, printing, lithographing or labelling with water resistant materials. Marking of commodities containing radioactive material shall be in accordance with MIL-M-19590. 5. DETAILED REQUIREMENTS 5.1 Size of Symbols. Symbols shall be the sizes designated in NFPA No. 704m summarized in Figures 1 through 4 of this standard. Smaller size symbols commensurate with surface available may be used on containers having two or more dimensions less than 6 inches, such as small cans, bottles, tubes, or individual components of kits or sets. (See Figure 5-) 1419 PTOVKted by IHS No mproduction o f n o tw o fta g p w m tts d w ithout Icons from IHS 2 Sold to PATTEN, WORNOM, HATTEN &. CHAMO 01S44492 Not fo r Roeala.2011/2/4 14 3 1 3 0 GMT MIL-STD-1341 l u m i G31SSlb 425 MIL-STD-13^l(SA) 20 June 1969 5-2 Color, The colors indicated for the symbols in Figures 1 through 6 shall acceptably match in shade the applicable color of FED-STD-595, as follows: Color Class Black Red White Yellow Blue I7O38 III05 17875 13538 I5IO2 5-3 Marking and Design. Each symbol shall conform to the applicable markings and design, as indicated in Figures 1 through 5 5A Posters and Signs. Posters and signs illustrating the hazard shall be prepared in accordance with Figure 6. Activities requiring posters should state the size required, weight and quality of paper or other material required, and surface finish required. Posters and signs are intended for display in work and storage areas. 5.5 Criteria for Application of Symbols. Symbols shall be applied to containers whenever the contents has hazardous characteristics defined in this standard. Specifically, any material listed as hazardous in National Fire Protection Association publications, or having similar characteris tics shall be so labeled. Application criteria for Federal Supply Groups and Classes are given in Appendix A. 5.5*1 Application. These requirements shall apply to all material sup plied to the Navy directly or indirectly through the Defense Supply Agency, General Services Administration, jobbers, dealers and contrac tors, sub-contractors and other channels. 5.6 Data Submission. Contractors shall provide data described in the U. S. Department of Labor Material Safety Data Sheet (Form LSB OOS-k) as required in the contract or order. Once data has been submitted for a particular commodity, no change in formulation affecting its hazardous characteristics is permitted without prior approval by the contracting officer. Instructions are provided in Appendix B. Suppliers are encour aged to submit the same information to the National Fire Protection Asso ciation, 60 Batterymarch Street, Boston, Massachusetts 02110. 1420 [Provided by IHS No reproduction or ne tw o rkin g pe rm itte d without license from IHS Preparing Activity Navy - SA Project No. PACK N0l6 3 S o tt to PATTEN. W ORNOM. HATTEN 1 DIAMO 01044492 Not ter Resale,2011/2/4 1431 30 GMT niL-sT-iam mil-std-13^i (s a ) 20 June 1969 w m i 03=12517 3bi HEALTH HAZARD 4 * Deadly 3 Extrem danger 2 * Hazardous 1 Slightly hazardous 0 - Normal material FIRE HAZARD Flash Points O x id iz e r Acid A llto ll Corrosive Use NO WATER REACTIVITY May detonate Shock and heat may detonote Violent chemical change 1 Unstobie if heated 0 Stable Symbol arrangement and text shall be as above. Color formats are provided in Figures 2 and 3* Dimensions are shown in Figure L. The following specific hazard symbols shall be used: TERM SYMBOL REFERENCE Oxidizer Acid Alkali Corrosive Fire Fighting Use No Water Hazard OXY ACID ALK COR -W- 3.5 3.6 3-6 3-6 NFPA No. 70 Combinations of specific hazard symbols shall be as follows: OXY OXY OXY OXY ACID ACID ACID ALK COR COR -W- ALK ALK COR COR -W- -W- Figure 1. Hazard Identification System 4 1421 f>r0VKied W IH8 No reproduction o r networking permitted without icense from IBS Sold to PATTEN, WORNOM, HATTEN & DIAMO. 01B44492 Not fo r Resale,2011/2/4 14 31 30 GMT MIL-STD-1341 'H 111 03S2S1 2Tfl MIL-STD-13^1(S A ) 20 June 1969 Numerals shall he white and may have a black border. Letters G L 3 or combinations thereof may be used in the center circle to snow that the contents are a gas liquid or solid at the proper condition of storage. The letters may be white with black border or all black. The letter V m the "Use Mo Water" symbol -W-- shall be white with a black border. All other printing shall be black on a wnite background (see Figure l). Figure 2. Color Format 1422 Provided by 1H$ No reproduction o r networking permitted w ithout license from IMS 5 Sold to PATTEN. WORNOM. HATTEN & DIAMO, 01044492 Not fo r Resale 2011/2/4 14 31 30 GMT MIL-STD-13^1(SA) 20 June 1969 MIL-STD-1341 `Hi il11 DB'esn 134 Backgrounds shall be white. Borders shall be black. Numerals shall be the color Indicated and may have a black border. The letter W in the "Use No Water" symbol border. shall be black with a black All other printing shall be black on white (see Figure l). Figure 3 . Alternate Color Format 1^23 Provided by 1HS No reproduction o r networking permitted w ithout license from IHS 6 Sold to PATTEN, WORNOM, KATTEN & DIAMO, 01844492 Not fo r Resale,2011/2/4 14 31 30 GMT niL-STD-iam tW cm i 03^2520 5b MIL-STD-13^1(SA) 20 June 1969 B c D w T BORDER k 2-1/2 3 A 3/8 4 2-1/2 1 1/2 6 3-3 A 1 -1/2 3,/i. 8 5 2 1 Dimensions are in. inches. 5/8 5/32 3/4 ' 5/32 1 7/32 1-1/2 5/16 Tolerance 1/32 in unless otherwise note. All "borders shall he 1/64" TTPE SIZE POINTS HI!! MAX 7 8 7 8 10 12 14 16 Figure U. Dimensions 1424 IProvided by IHS Mo reproduction or ne tw o rkin g pe rm itte d w itho ut license from IH3 7 Sold to PATTEN, W ORNOM, HATTEN & DIAMO. 01 M 4492 Not fo r Resale ,2Q1lf2/4 14 31 30 GMT HIL-STD-1341 TOTOl OBTSSBl 'iE m-STD-^liSA) 20 June 1969 This illustration shows acceptable application for containers too small for symbols having dimensions specified in Figure h. Further reduction is permissible, providing printed information is legible. Figure 5. Small Size Marking 1425 Provided by IHS No reproduction o r networking permitted w ithout license from IHS 8 Sold to PATTEN, WORNOM, HATTEN & D1AMQ, 01344492 N ot fo r Resate .2011/7/4 H S 1 30 GMT niL-STD-i3m `m ' m i 03*12522 72*1 HAZARD IDENTIFICATION SYSTEM MIL-STD-l34l(SA) 20 June 1969 Identification of H ealth H azard C olor C o d e: B L U E Iden tification of F lam m ability Color C ode: R E D Identification of R e a ctiv ity (S tab ility) C olor C ode: Y E L L O W T y p e of Possible In ju ry Su scep tibility o f M aterials to Burning Su sceptibility to R elease o f E n ergy S ig n a l S ig n a l S ig n a l 41 M aterials w hich on v e ry short exposure could cause death or m ajor residual in ju ry even though prom pt m edical treatm en t w ere g iv e n . 41 M aterials w hich w ill rapid ly or com pletely vaporize at atm ospheric pressure and norm al am bient tem pera tu re, or w hich are read ily dispersed in air an d w hich w ill burn read ily. 41 M aterials w hich are read ily cap able of detonation or of explosive decom position or reaction a t norm al tem peratures and pressures. g M a te r ia ls w h ic h o n s h o r t e x posure cou ld cau se serious tem p orary or residual in ju ry even though p rom p t m edical treatm en t were given . Liqu id s an d solids th a t can be ignited under alm ost all am bient tem p eratu re condi tions M aterials w hich are cap able o f det onation or exp losive reaction b u t re quire a stro n g in itiatin g source or w hich m u st b e h eated under confine m ent before initiation or w hich react explosively w ith w ater. M ateria ls w hich on intense or continued exposure could cause tem porary in cap acita tion or possible resid u al in ju ry unless p rom p t m ed ical treatm en t is given . & M aterials th a t m ust be m od erately heated or exposed to relatively h igh am bient tem peratures before ignition can occur. & M aterials w hich are n orm ally unstable and read ily undergo violen t chem ical ch an ge b u t do n o t d eto n ate. Also m aterials w hich m ay react v iolen tly w ith w ater or w hich m ay form poten tia lly explosive m ixtures w ith w ater. a a a M a te r ia ls w h ic h o n e x p o su re w ould cause irritation b u t on ly m inor residual in ju ry even if no treatm en t is g iv en . M aterials th a t m ust be pre heated before ignition can occur M aterials w hich are n orm ally stable, b u t w hich can becom e u n stab le a t ele vated tem peratures and pressures or w hich m ay rea ct w ith w a ter w ith som e release of en ergy b u t n ot vio len tly M aterials w hich on exposure under fire conditions w ould offer no h azard b eyo n d th a t o f ordinary com bustible m a terial. M aterials th a t w ill not burn. M aterials w hich are n orm ally stable, even un d er fire exp osu re con d ition s, and w hich are not-reactive w ith w ater. Copyright 1966 by the National Fire Protection Association and pub lished in the "Recommended System for the Identification of the Fire Hazards of Materials (NFPA No. 70i(-M)." Reproduced with permission. Posters in color (l6" X 4") may be purchased from the National Fire Pro tection Association, 60 Batterymarch Street, Boston, Massachusetts 02110. Decals in color (6" X V") are also available. Figure 6. Poster for use with Hazardous Material Symbols 1426 Provided by IHS Ko reproduction o r netwoifcng permitted w ithout bcenee from IHS Sold to PATTEN. WORNOM, HATTEN & DIAMO, 01844492 Not for R eM ie,2011/2/4 14 31 30 GMT niL-sTD-iam m w m i 03*12523 bt,s MIL-STD-134l(SA) 20 June 1969 APPENDIX A HAZARDOUS MATERIAL SYMBOL APPLICATION CRITERIA The Application Criteria of this Appendix are mandatory for all material supplied to the Navy. 10. HAZARDOUS MATERIAL IDENTIFICATION APPLICATION GUIDE 10.1 Hazardous Identification Symbols shall be applied to containers of material in the following Federal Supply Groups and Classes: FEDERAL SUPPLY GROUP 3* 68 79 80 85 87 91 (Packaged Products Only) FEDERAL SUPPLY CLASS 3^39 Welding and Brazing Supplies 6810 Chemicals 6820 Dyes 6830 Gases; Compressed and Liquified 68*40 Pest Control Agents and Disinfec tants 6850 Miscellaneous Chemical Specialties 4 7930 Cleaning and Polishing Compounds I and Preparations 8010 Paints, Dopes, Varnishes, and Related Products 8030 Preservative and Sealing Compounds 80*40 Adhesives 8510 Perfumes, Toilet Preparations, and Powders 8520 Toilet Soap, Shaving Preparations, and Dentifrices 8720 Fertilizers 9110 Fuels, Solid 9I30 Liquid Propellants and Fuels, Petroleum Base 9135 Liquid Propellant Fuels and Oxidi zers, Chemical Base 91*40 Fuel Oils 915O Oils and Greases: Cutting, Lubri cating, and Hydraulic 9160 Miscellaneous Waxes, Oils, and Fats 99 9920 Smokers' Articles and Matches Lighter Fuel Only 1427 10 i Provided by IHS No reproduction o r networking permitted without Icense from IHS Sold to PATTEN. WORNOM. HATTEN & DIAMO. 01844492 Not fo r Resale,2011/2/4 14 31 30 GMT I HIL-STD-1341 m l I T m i 0312524 5T1 I M1L-STD-13^1(SA) I 20 June 1969 m 10.2 Symbols shall be required for items that vould ordinarily be cata- V loged under one of the above classes, but are stocked numbered in another class because of their specific use. 10.3 Symbols shall be required for all items listed in National Fire Protection Association NFPA No. 325A, 325M and t-9 and for items having similar characteristics. i Provided by IHS No reproduction o r networking permitted w ithout license from IKS 11 Sold to PATTEN. W ORNOM. HATTEN & DIAMO, 01W 4492 N ot to r Resale,2011/2/4 14 31 30 GMT flIL-STD-1341 l l l ' n i l 03^5525 43fl APPHDIX B M IL-STD-i34l{SA) 20 June 1969 4 DfSTRUCTIOHS FOR PREPARING DEPARTMENT OP LABOR MATERIAL 8AFETT BATA SHEET FORM LSB OOS-4 Instructions in this appendix are Mandatory to the extent specified elsewhere la this standard, or as specified in contracts or orders. 20. INSTRUCTIONS 20.1 Material Safety Data Explanation of Tense and Instructions. Font LSB 003-4, or one essentially similar, approved by the Bureau. 0# Labor Standards, is required to be filled out only on Materials which, when not provided with special attention or controls, will constitute a hazard. If infonsetion is inapplicable to the Material under consideration, the initials "n.a." (not applicable) shall be Inserted. 20.1.1 Definition of an Essentially Slnilar Form. An essentially simi lar fora is interpreted as being one in which Section II is modified to indicate only the produet or group of products which it is intended to cover. The remaining sections of the form will list the Items of infor mation in the sequence shown on Form 008-4, but the space given to those i entire sections which are inapplicable may be reduced to that necessary to enter the Initials "n.a." (not applicable). 20.1.2 Definition of a Hazardous Material. A hazardous material has one or more of the following characteristics: (a) has a flashpoint, or is subject to spontaneous heating; (b) has a threshold limit value below 500 ppm for gasea and vapors, and below 25 mppcf for dusts; (c) a single dose oral ID^q below 500 mg/kg; (d) is subject to polymerization with the release of large amounts of energy; (e) is a strong oxidizing or reducing agent; (f) causes first degree burns to skin in short time exposure, or is system!cally toxic by skin contact; or (g) in the course of normal operations, may produce dnsts, gases, fumes, vapors, mists, or smokes which have one or more of the above characteristics. 20.2 Instructions for Section I. *42 9 Provided by IHS No reproduction o r networking permitted Without license from IH8 12 Sold to PATTEN. WORNOM, HATTEN & DIAMO. 01844492 Not for ResaleJ 0 1 1/2/4 14 31 30 GMT i MIL-STD-1341 m m i n i oaisssb 374 W L-STO-134l(SA) 2D June 1969 w 20*2*1 Manufacturer1 Haae and Address. Nailing address, including zip code, the federal Supply Code for Manufacturers (PSCN), and tune of certi fying company official. 20.2.2 Baergency telephone Humber. Show area code, telephone number(a) and extension's), and boors of operation at which further information nay be obtained in the event of an emergency involving the material. 20.2.3 Chemical game and Synonym. Applies only to produets consisting of a single element or compound, such as oxygen, or methyl-ethyl Ketone. 20.2.V grade Marne and Synonyms. Include formula number or other defi nite designation of the producer 20.2.5 Chemical family. State generic name of single elements and com pounds, sucK as acid orketone. 20.2.6 formula. Refers only to the chemical formula for single ele ments or compounds, not to the formulation of a mixture. Example: Og and C2H5 COCH3. 20.3 Instructions for 8ection II-Hazardous Ingredients. 20*3*1 Ingredients. A hazardous ingredient is a hazardous material in W A a mixture in sufficient concentration to produce enough flammable vapor or gas to ignite, or to produce acute or chronic adverse effects in doses which could result from normal use or predictable misuse of the mixture containing it. Ingredients of a hazardous nature shall be noted by chemi cal name in one of the three divisions of Section II, viz., Paints, Pre servatives, and Solvents) Alloys and Metallic Coatings) and Hazardous Mix tures of other liquids, solids, or gases. The listing of ingredients in the first division is self-explanatory. Metallic coatings listed In the second division refer to coatings such as plating, cladding, and metal lizing) and filler metal is any metal added in making a brazed, soldered, or welded joint. Filler metals shall be considered with the ingredients of rod coatings and core fluxes as single mixtures. The third division refers to other hazardous mixtures, such as abrasive blasting materials. 20.3.2 Composition. Ike approximate percentage of each hazardous in gredient by weight or volume shall be shown to the nearest 5 percent. The percentages of any substance constituting less than 5 percent may be indicated as such, for mixtures, such as filler metals and their coat ings and core fluxes, in which the hazardous ingredients constitute very Mail proportions of the mixture, the hazardous Ingredients shall be stated to the nearest 0.5 percent, and ingredients constituting less than 0.5 percent nay be indicated as such. 143C Provided by IUS No reproduction o r networking permitted without license from IHS Sold to PATTEN, W ORNOM, HATTEN & DIAMO, 01644492 Not fo r Resale,2011/2/4 14 31 30 GMT HIL-STJ-1341 'ITi'mi 0332.527 200 MIL-STD-134l(SA) 20 June 1969 20*3-3 threshold Limit Valve. The threshold limit value ( W f ) for OMk ku> ardous ingredient in a mixture will be entered in the column provided, in accordance with instructions given in Section V. 20.3.4 Additional Information. If more space is needed in the first or secorid division, use the lines provided in the third division. Normally this space will be used for mixtures not falling in the other two divi sions. In addition, addenda sheets may be added to the form. 20.4 Instructions for Section Ill-Physical Data. 20.4.1 Boiling Point. State the temperature at which the liquid boils, in degrees F., at a pressure of 76O mm Hg. For mixtures, a boiling range is acceptable. 20.4.2 Vapor Pressure. State the pressure of saturated vapor above the liquid in mm of Hg, at 20C. 20.4.3 Vapor Density. State the relative density or weight of a vapor or gas (with no air present) compared with an equal volume of air. Val ues should be given in the ambient temperature range of 60 - 90F. to facilitate field usage. 20.4.4 Solubility in Water. Use the following terms to describe the solubility of the product by weight in distilled water at 50F: Negligible........................less than 0.1 percent Slight........................ ...0.1 - 1 percent Moderate.......... ......... .1 - 10 percent Appreciable.......... ............ more than 10 percent Complete.......................... in all proportions 20.4.5 Specific Gravity. State the ratio of the weight of a volume of material to the weight of an equal volume of water at 39*2F. This deter mines whether the material floats or sinks in water. 20.4.6 Percentage Volatile by Volume. State the percentage of the liquid or solid by volume that evaporates at the ambient temperature of 70F. O^is applies to solids such as Napthalene. 20.4.7 Evaporation Rate. State the ratio of the evaporation rate to that of either Butyl Acetate or Diethyl Ether. Insert the name of which ever is used. 20.4.8 Appearance and Odor. Give a brief description, e.g., viscous, colorless liquid with aromatic odor. 14 1 i Provided by IMS No reproduction o r networking permitted w ithout license from IHS Sold to PATTEN. W OKNOM . HATTEN 4 DIAMO. 01B44492 Not for Reeale.2011/2/4 14.31 30 GMT MIL --STD--1341 T W l l l OBIBSEfl 147 MIL- STD-13 ^-1(SA ) 20 June 1969 I 9 20.5 Instructions for Section IV-Fire and Explosion Hazard Data. 20.5.1 Flash Point. State the temperature in degrees F., at which a liquid will give off enough flammable vapor to ignite when tested by the open cup method. When multi-component paint systems are used and mixed in the field, the flash point of the individual components shall be noted. 20.5.2 Flammable or Explosive Limits. State the range of gas or vapor concentrations (percent by volume in air) which will burn or explode if an ignition source is present. LEL means the lower explosive limit, and UEL means the upper explosive limit. Knowledge of the LEL will aid in determining the volume of ventilation needed for an enclosed space to prevent fires and explosions. 20.53 Extinguishing Media. List the firefighting media suitable for use on the burning material. For certain specific chemicals, special formulations, in addition to the standard agents, are available for extin guishing fires. These should be indicated by generic name. The standard firefighting agents are water fog, foam, alcohol foam, CO2, and dry chemi cal. 20.5^ Special Firefighting Procedures. If water is unsuitable, specify the firefighting media to be used. Also list any necessary per sonal protective equipment. V 20.5.5 Unusual Fire and Explosion Hazards. Specify such hazards and/or any special conditions that govern them. 20;6 Instructions for Section V-Health Hazard Data. 20.6.1 Threshold Limit Value. Threshold limit value (TLV) refers to current figures of the American Conference of Governmental Industrial Hygienists. The TLV for single elements and compounds shall be entered here. For mixtures, the threshold limit value for each significant ingre dient shall be noted in the column provided in Section II of the form. (See Section II above for explanation.) Express these value in millions of particles per cubic foot of air (mppcf), or in milligrams of particu late per cubic meter of air (Mg/M^) for dust; and in milligrams of par ticulate per cubic meter of air (Mg/M^), or in parts per million parts of air by volume (ppm) for gases, vapors, mists, fumes, and all other con taminants except dusts. State the units in which the TLV is expressed. 20.6.2 Effects of Overexposure. Describe most common sensations that exposed person will feel, and his appearance. 15 1432 Provided by IHS No reproduction o r networking permitted without license from IHS Sold to PATTEN. W ORNOM, HATTEN & DIAMO, 018444S2 Not fo r Resale,2 0 11/2/414 31 30 GMT MIL-STD-1341 mTUl 03`ESe,:i 063 MIL-STD-13kl(SA) 20 June 1969 20.6.3 B r g e n c y and First-Aid Procedures. State emergency procedure! to be usec Only inhalation and skin or eye contact should be considered in recommending first-air measures. Hie victim should be examined by a doctor as soon as possible after exposure. 20.7 Instructions for Section VI-Reactivity Data. 20.7*1 Stability. Indicate, by cross or check, whether stable or un stable under reasonably foreseeable conditions of storage, use, or misuse. If unstable, list those conditions which may cause a dangerous reaction. Examples: Shock from dropping; temperature above 150F. 20.7*2 Incompatability. Provide information on such common materials and contaminants with which the product may reasonably come into contact, producing a reaction which would release large amounts of energy. If none, so state. State whether oxidizing material, acid, caustic alkali or corrosive. 20.7.3 Hazardous Decosposition Products. List hazardous materials pro duced in dangerous amounts by burning, oxidation, or by heating In weld ing or burning. Thermal decomposition products, such as CO, CO2, and hydrochloric acid from vinyl chloride plastics are examples. 20.7.^ Hazardous Polymerization. Hazardous polymerization is that which takes place at a rate which releases large amounts of energy. Indi cate by check or cross whether or not hazardous polymerization can occur. If so, list those reasonably foreseeable storage conditions which would start polymerization. Include the expected time period in which the inhibitors may be used up. 20.8 Instructions for Section V l l - a p i U or Leak Procedures. Indicate any applicable precautions as: avoiding breathing gases and vapors; con tact with liquids and solids; removing sources of Ignition; any special equipment used for cleaning up, such as glass or plastic scoops; and dis posal of spilled solids or liquids, such as flushing with water, returning material to container, burning, etc. 20.9 Instructions for Section YIII-apecial Protection Information. Indicate the type of personal protective equipment, ventilation, and such precautions to be taken when using the product for its Intended purpose, as elimination of ignition sources. 20.10 Instructions for Section IX-Speclal Precautions. Indicate any special precautions to be taken',* such as in handling or storing, to avoid reaction hazards. When applicable, indicate safe storage life of product in relation to reactivity. Also Indicate any other general precautions to be taken. 16 1433 < Provided by IHS No reproduction or networking permitted w ithout license from IHS Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01644492 Not fo r Resale,2011/2/4 14 31 30 GMT MIL-STD-134l(SA) 20 June 1969 NIL-STD-1341 I'i'n'ill OBIESaO flT5 m 20.11 Federal Stock Number, and Package Dimensions and Weight, Indicate the Federal Stock Number (FSN) at the bottom of page 1. Also indicate the outside dimensions of the unit package in inches and tenths thereof. Example: For a container 4-|" in diameter and 6-3/8" high, enter: Package Dimensions 4. 5 X 4.5 X 6.4-. The gross weight of the unit package shall he indicated in pounds and tenths. Example: For a container weighing 44 pounds 12 ounces, enter: 44.8 lbs. gross. 20.12 Submission of Data. Mail completed form as directed in the con tract or order. In the absence of specific mailing instructions, mark the contract or order number under the FSN and mail to the Commanding Officer, Navy Fleet Material Support Office, Mechanicsburg, Pennsylvania 17055. > 1434 Provided by IKS No reproduction o r networking permitted without license from IHS 17 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01844492 Not fo r Resale,2011/2/4 14 31 30 GMT niL-sTD-iam n i n i l 0312531 731 m Form A pproved Budget Bureau No. 4 4 -fit 387 A pp ro val E xpires A p r il 30. 1971 U.S. DEPARTMENT 0F LABOR > W AG E AND LABOR STANDARD S ADM INISTRATION Bureau of Labor Standards MATERIAL SAFETY DATA SHEET F orm N o . LS 8-O O S -4 May 1969 KHf-STD-I3^\ SA) Figure 7 M A N U F A C T U R E R 'S N A M E ADDRESS [Number, Street, City, State, and ZIP Code) CHE M ICA L NAME AND SYNONYMS C H E M IC A L F A M IL Y SECTION I EMERGENCY TELEPHONE NO. TRADE NAME AND SYNONYMS P IGMgNTS i METALLIC COATINGS FILLER METAL PLUS CO ATING OR CORE FLUX HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES TLV (U nit,) BOILING POINT (F.I VAPOR PRESSURE (mm H 8.) VAPOR DENSITY < A lR = l) SOLUBILITY IN WATER APPEARANCE A N D ODOR SPECIFIC GRAVITY (H2O s 1l PERCENT VOLATILE BY VOLUME (%} EVAPORATION RATE I ------------------------ =11 Fkg. Dim 1435 tProvided by IHS No reproduction or netw orking pe rm itte d w itho ut license from IHS I Orse Vgt. Sold to PATTEN. W ORNOM, HATTEN 4 DIAMO, 01444492 Not fo r Resale,2011/2/4 14 31.30 GMT MIL - S T D - 1 3 M 1 R T W l l 03*12532 b? KEL-Sn>-134l(sa) 20 JQM 1969 EFFECTS OF OVEREXPOSURE EMERGENCY AND FIRST A IO PROCEDURES 1 unstable STABLE 1 INCOMPATABILITY (M aterials to o v o id ) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION MAY OCCUR W i ll NOT OCCUR C O N D ITIO N S TO A VO ID I CO N D ITIO N S TO A V O ID STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED < WASTE DISPOSAL METHOD RESPIRATORY PROTECTION ( S p e c if y t y p e ) V E N T IL A T IO N lo ca l exhaust MECHANICAL (C en erai) PROTECTIVE GLOVES OTHER PROTECTIVE EQUIPMENT >lixmi,!-n PRECAUTIONSTTOO BE TAKEN IN H A N D L IN G A N D STORING OTHER PRECAUTIONS EVE PROTECTION SPECIAL OTHER Figur 7 (Continued) 1436 Provided by IBS No reproduction or networking permitted without license from IHS 19 * U S GOVERNMENT PRINTING OFFICE 1969-383-087/837 Sold to PATTEN, WORNOM, HATTEN & DIAMO, 01W 4492 Not fo r Resale ,2011/2/4 14 31 -30 GMT