Document pzMyYZR0kjzpvXm8xEwaKw4a

m ij MATERIAL SAFETY DATA SHEET Consumer Products Division, Division of Borden, Inc. 180 EAST BROAD STREET, COLUMBUS, OHIO 43215 For ordering Information, additional copies of MSDS, etc., 800-848-9400 For technical Information only, 614-431-8680 (614) 431-6600 PCOls THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 REQUIRES THAT THE INFORMATION CONTAINED ON THIS SHEET BE MADE AVAILABLE TO YOUR WORKERS. INSTRUCT YOUR WORKERS TO HANDLE THIS PRODUCT PROPERLY DESCRIPTION: PRODUCT TYPE: APPLICATION: KRYLON SPRAY PRIMER "AEROSOL" SPRAY PAINT ITEMS NOS.: 1314,1354. 1364; PLATINUM: 1315, 1355, 1365; WHITE; 1316.1356,1366; BLACK; 1317. 1357.1367, 9204; RUODY BROWN; 1318,1358,1368, 9205; GRAY; 900. 902.903; CAR COLOR PRIMER 0S-APR-90 SIGNAL WORD DANGER! THIS MATERIAL IS A "HEALTH HAZARD" AND/OR A "PHYSICAL HAZARD" AS DETERMINED WHEN REVIEWED ACCORDING TO THE REQUIREMENTS OF THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION 29 CFR PART 1910.1200 "HAZARD COMMUNICATION" STANDARD. CHEMICAL HAZARD MATINS HEALTH "^{MODERATE) f!RE"=4{EXTREME) REACTIVITY=0(LEAST) CHRONICTM* 2KFIIS10J2W HAZARDOUS INBREIIENTS/REPORTED HEALTH EFFECTS CAS/1EB1STAV MIL MATERIAL DESCHIFTIOH% AAK8E THE INGREDIENTS LISTED BELOW HAVE BEEN ASSOCIATED WITH ONE OR MORE OF THE LISTED IMMEDIATE AND/OR DELAYED (*) HEALTH HAZARDS. RISK OF DAMAGE AND EFFECTS DEPENDS UPON DURATION AND LEVEL OF EXPOSURE. BEFORE USING OR HANDLING, READ AND UNDERSTAND THE MSDS. 67-64-1 *ACETQNE NOTE REVISES OSHA PEI 30-66 INGESTION MAY CAUSE LIVER DAMAGE. INGESTION MAY CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUOE HEADACHE, DIZZINESS, NAUSEA, VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. -- SEE FOOTNOTE C. ACGIH TIV 750 PPM(1780 MG/M3)TWA;1000 PPM(23?5 MG/M3) STEL OSKA PEL 750 PPM(1800 MG/M3I THAI MO PPM(2400 MG/M3] STEL NIOSH DOCUMENT NUMBER: 78-173 74-98-6 PROPANE 10-30 THIS MATERIAL IS A SIMPLE ASPHYXIANT SIGNS AND SYMPTOMS OF OVEREXPOSURE INCLUDE CYANOSIS, RESPIRATORY DISTRESS HEADACHE DIZZINESS. DROWSINESS. UNCONSCIOUSNESS AND ASPHYXIATION CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. -- SEE FOOTNOTE C. ACGIH TLV SIMPLE ASPHYXIANT- SEE ACGIH TLVS, INTRODUCTION OSHA PEL 1000 PPM [1800 86/831 TWA 78-63-1 ISOBUTANOL 1-5 NOTE REVISED OSHA PEI CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS. NAUSEA. VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. -- SEE FOOTNOTED. ACGIH TLV; 50 PPM (150 MG/M3) TWA OSHA PEL 50 PPM (150 M6/M3) TWA 108-88-3 -TOLUENE 10-30 NOTE REVISED OSHA PEL CAN CAUSE LIVER DAMAGE. CAN CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS. NAUSEA, VOMITING, UNCONSCIOUSNESS AND ASPHYXIATION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY LEAD TO ADDICTION AND MAY BE HARMFUL OR FATAL -- SEE FOOTNOTE C. ACGIH TLV 100 PPM (375 MG/M3)1WA; 150 PPM (560 MG/M3) STEL OSHA PEL 100 PPM (375 M6/M3) TWA 150 PPM (560 N&/M3) STEL NIOSH DXUMENT NUMBER 73-11023 4032-32-4 V.M.&P. KAPHTHA 5-10 NOTE REVISED OSHA PEL CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA. VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. -SEE FOOTNOTE C. ACGIH TLV 300 PPM (1350 MG/M3) TWA OSKA PEL 300 PPM (1350 M6/M3JTWA; 400 PPM (1800 ME/M3) STEL NIOSH DOCUMENT NUMBER 77-192 FOOTNOTE C: AS OF THE DATE OF ISSUANCE OF THIS DOCUMENT, THIS MATERIAL HAS NOT BEEN LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN. PHYSICAL DATA APPEARANCE AND PHYSICAL STATE BOILING POINT, OEG F 760 MM HG ODOR VAPOR PRESSURE - SEE CAN PRESSURE VAPOR DENSITY HEAVIER THAN AIR SOLUBILITY IN WATER SPECIFIC GRAVITY LIGHTER THAN WATER EVAP RATE FASTER THAN BUTYL ACETATE BOILING P0INT;APPEARANCE;0D0R PERCENT VOLATILE BY WEIGHT PERCENT NON-VOLATILE BY WEIGHT PRESSURE IN CONTAINER PSIG a 70 F. LIQUID AND LIQUIFIED GAS >-49 (PROPELLANT) HYDROCARBON SOLVENT SLIGHT NOT AVAILABLE 80 TO 83 17 TO 20 ADPR0X 60 IMMEDIATE HEALTH HAZARD BATA SKIN ABSORPTION; NO HAZARDS KNOWN TO BORDEN. INGESTION: NOT EXPECTED TO BE HARMFUL UNDER NORMAL CONDITIONS Of USE. IF ACClDENTLYSWAlLOWED. BURNS OR IRRITATION TG MUCOUS MEMBRANES. ESOPHAGUS OR Gt TRACT CAN RESULT INHALATION: MAY BE HARMFUL IF INHALED. LIQUID OR VAPOR MAV CAUSE IRRITATION OF NOSE. THROAT AND LUNGS. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SKIN: CAUSES IRRITATION. EYES; CAUSES IRRITATION. KANOUNG PRECAUTIONS INHALATION. USE WITH ADEQUATE VENTILATION, TO AVOID BREATHING VAPORS OR SPRAY MIST. OPEN WINDOWS AND OOCRS OR USE OTHER MEANS, SUCH AS AN EXHAUST FAN TO ENSURE FRESH AIR ENTRY DURING APPLICATION AND DRYING. IF YOU EXPERIENCE EYE WATERING HEADACHE OR DIZZINESS, INCREASE FRESH AIR, WEAR RESPIRATORY PROTECTION (NIOSH/MSHA TC23C OR EQUIVALENT). OR LEAVE THE AREA. SKIN; AVOID CONTACT WITH SKIN. EYES; AVOID CONTACT WITH EYES. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING UNNECESSARY EXPOSURE AND REMOVAL OF THE MATERIAL FROM EYES. SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. EMERGENCY AND FIRST AID PROCEDURES INGESTION: IF ACCIDENTLY SWALLOWED. DILUTE BY DRINKING LARGE QUANTITIES OF WATER. IMMEDIATELY CONTACT POISON CONTROL CENTER OR HOSPITAL EMERGENCY ROOM FOR ANY OTHER ADDITIONAL TREATMENT DIRECTIONS. 000009354 SEE REVERSE SiOE DISCLAIMER--SEE REVERSE SIDE PREVIOUS ISSUE:03-APR-90 CURRENT ISSUE:05-APR-90 KD-1317C P C 015 - INHALATION: IF INHALED. REMOVE TO FRESH AIR. IF NOT BREATHING. GIVE ARTIFICIAL RESPIRATION. PREFERABLY MOUTH-TO-MOUTH. CALL A PHYSICIAN. SKIN CONTACT: FLUSH SKIN WITH PIENTYOF WATER. REMOVE CONTAMINATED CLOTHING. CALL A PHYSICIAN IF IRRITATION PERSISTS EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. EYELIDS SHOULD BE HELD APART DURING IRRIGATION TO INSURE WATER CONTACT WITH ENTIRE SURFACE OF EYES AND LIDS. CALL A PHYSICIAN._____________________________________________ FIRE AND EXPIDSIOR HAZARD DATA EXTREMELY FUMMAILE DO NOT INCINERATE (BURN) CONTAINER. AVOID HEAT. KEEP CONTAINER BELOW 120 F. {SB Cj HIGH TEMPERATURES MAY CAUSE BURSTING. DO NOT PLACE CONTAINER ON RADIATOR. STOVE. IN DIRECT SUNLIGHT OR NEAR OTHER HEAT SOURCES DO NOT PONCTOIE CONTAINER. CONTENTS UNDER PRESSURE WILL DISCHARGE. AVOID OPEN FLAMER. SPARKS. PILOT LIGHT! DO NOT SMOKE VAPOR MAY IGNITE EXPLOSIVELY. SPRAY MIST OR VAPOR EVAPORATING FROM A DEPOSITED FILM IS HEAVIER THAN AIR AND MAY SETTLE IN LOW PLACES OR TRAVEL OUTWARD TO A SOURCE OF IGNITION AND FLASHBACK. IN CASE OF FIRE. USE DRY CHEMICAL FOAM OR C02. WATER MAY BE INEFFECTIVE, BUT SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL REACTIVITY BATA NORMALLY STABLE AS DEFINED IN NFPA 704-12(4-3.1). HAZARDOUS POLYMERIZATION'. WILL NOT OCCUR. INCOMPATIBILITIES: NONE KNOWN TO BORDEN. OTHER HAZARDS: NONE KNOWN TO BORDEN. DECOMPOSITION PRODUCTS MAY INCLUOE. QXiQES OF CARBON CONTROL MEASURES IF AIRBORNE CONTAMINANTS ARE GENERATED WHEN THE MATERIAL IS HEATED OR HANDLED. SUFFICIENT VENTILATION IN VOLUME AND AIR FLOW PATTERNS SHOULD BE PROVIDED TO KEEP AIR CONTAMINANT CONCENTRATION LEVELS BELOW ACCEPTABLE CRITERIA ENGINEERING CONTROLS: THE FOLLOWING EXPOSURE CONTROL TECHNIQUES MAY BE USED TO EFFECTIVELY MINIMIZE EMPLOYEE EXPOSURE: LOCAL EXHAUST VENTILATION. ENCLOSEO SYSTEM DESIGN. PROCESS ISOLATION AND REMOTE CONTROL IN COMBINATION WITH APPROPRIATE USE OF PERSONAL PROTECTIVE EQUIPMENTANOPRUDENTWORKPRACTICES.THESE TECHNIQUES MAY NOT NECESSARILY AOORESS ALL ISSUES PERTAINING TO YOUR OPERATIONS. WE. THEREFORE. RECOMMENDTHAT YOU CONSULT WITH EXPERTS OF YOUR CHOICE TO DETERMINE WHETHER OR NOT YOUR PROGRAMS ARE AOEQUATE. PERSONAL PROTECTION IRFOIMAT1QB WHERE AIR CONTAMINANTS CAN EXCEED ACCEPTABLE CRITERIA USE NIOSH/ MSHA APPROVEO RESPIRATORY PROTECTION EQUIPMENT. RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION OF CONTAMINANTS IN AIR IN ACCORDANCE WITH OSHA 29 CFR 1910.134 OR OTHER APPLICABLE STANDARDS OR GUIDELINES. USE GOGGLES IF CONTACT IS LIKELY. WEAR IMPERVIOUS GLOVES A$ REQUIRED TO PREVENT SKIN CONTACT. SPIU 01 LEAK PIOCEMRES ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BODIES OF WATER. WASTE DISPOSAL DISPOSE OF ACCORDING TO LOCAL STATE/PROVINCIAL ANO FEDERAL REQUIREMENTS. EMPTY CONTAINER: MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT. PUNCTURE OR WELD ON OR NEARBY. INCINERATION WILL CAUSE CONTAINER TO BURST VIOLENTLY. STORAGE PRECAimORS DO NOT STORE AT TEMPERATURES ABOVE 120 F. DOT CLASSIFICATION ORM-D CONSUMER COMMODITY. SARA TITLE Ml SECTION 31# ANO 40 CF1 PART 372 TOJOC CHEMICAL NOTIFICATION SHEET KRY10N SPRAY PRIMER THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986. AND SUBPART C-SUPPUER NOTIFICATION REQUIREMENT OF 40 CFR PART 372. CAS REGISTRY PCT. BY NUMBER CHEIICRL NAME WEIGHT 67-64-1 ACETONE 33.0M 108-88-3 TOLUENE 27.00 V_ THIS TOXIC CHEMICAL NOTIFICATION SHEET MUST NOT BE DETACHED FROM THE MATERIAL SAFETY DATA SHEET (MSDS). ANY COPYING ANO REDISTRIBUTION OF THE MSDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF THIS NOTIFICATION SHEET ATTACHED TO COPIES OF THE MSDS SUBSEQUENTLY REDISTRIBUTED. PREVIOUS ISSUE.-03-APR-90 CURRENT ISSUE:05-APR-90 KD-1317C SAL 000009355 DISCLAIMER SELLER MAKES NO WARRANTY. EXPRESS OR IMPLIED. CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY BORDEN, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States patent. The information provided herein was believed by Borden to be accurate at the lime of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for non-delivery of product, and whether based on contract, breach of warranty, negligence or otherwise shall be greater in amount than the purchase price of Ihe quantity of product in respect of which damages are claimed. In no event shall Seller be liable lor incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or oiherwise. material safety data sheet CONQUEST (060935*0239 -E0016293-421? )!DATE OF ISSUE ! 06/11/90 PACE : Q1 SUPERSEDES P C 0 34 01/15/90 SECTION GENERAL INFORMATION CHEMICAL NAME 5 SYNONYMS N/A TRADE NAME & SYNONYMS CONQUEST CHEMICAL FAMILY TANMC-L ATEX MIXTURE FORMULA X< - -MIXTURE MANUFiCT URERS NAME NATIONAL chemsearch djv. of nch ccrp ADOBES' (NUMBER. STREET. CITY. STATE & ZIP CODE) BOX 1 = 2 70 IRVING. TEXAS 75015 PREBABEC BV-. j PRODUCT CODE NUMBER ! EMERGENCY TELEPHONE NUMBER KELLY *. RAHN/T.S-CHEMIST 4217 214-436-1381 935 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A V-OLE. CHEMICAL NAME (INGREDIENTS) tannic ACID OXALIC ACID | HAZARD IRRITANT TOX/IRR. | TLVNOT EST. 1MG/M3 | PEL* NOT EST. 1MG/M3 ; cask 1401-55-4 144-62-7 SECTION 2IA - NON'-HAZARDOUS INGREDIENTS NON-HA 2ARD0US INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NJ TRADE SECRET REGISTRY * 409363-5027P CONQUEST SECTION III - PHYSICAL DATA PAGE : 02 BOILING PT.(FAHRENHEIT) |215 j SPEC GRAVITY (H20-1) : 1 . 1BO VAPOR PRESSURE (MM HG . i '8 VAPOR DENSITY (AIR1> jO.6 j COLOR j ODOR TAN LATEX PH + 100% j 1-2 j CLARITY OPAQUE PERCENT. VOLATILE BY VOLUME {%) SOLUSILJTY IN WATER J EVAPORATION RATE jO.IO 1 ] IBU AC > 1 ) j j COMPLETE VISCOSITY j SLIGHT -viscous SECTION IV * FIRE ANO EXPLOSION HAZARD FLASH POINT (METHOD USED) NON-FLAMT.C.C. EXTINGUISHING MEDIA ALCOHOL* X < - -FOAM <--FOAM j FLAMMABLE LIMITS 1 X<--C02 DRY X<--CHEMICAL ! LCL !n/a WATER <--SPRAY j UEL |n/a <--CTHER SPECIAL FIRE FIGHTING PROCEDURES ALTHOUGH PRODUCT IS NCN-fLAMM.ABLE, TREAT AS ANY CHEMICAL FIRE. WEAR A SELFCONTAINED BREATHING AND FULL PROTECTIVE GEAR TO AVOID EXPOSURE TO P0SSI8LE HAZARDOUS COMBUSTION PRODUCTS. UNUSUAL FJRE & EXPLOSION HAZARDS SPRAY EXPOSED CONTAINERS WITH WATER SSRAY TO AVOID STEAM PRODUCTION. NF P A r-AZARD RATING ( C* INS I GNIF I CANT ; 1 * SLIGHT ; 2 "MODERATE ; 3H IGH ;4 ^EXTREME): 1 <--HEALTH O <--FLAMMABIUITY O < --REACT IVITY <--SsECIAL SECTION V - HEALTH HAZARD DATA SAL 000009856 THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) INHALATION - MIST SITUATION MAY CAUSE IRRITATION TC RESPIRATORY TRACT. p c 0 34 (CONTINUED) CONQUEST SECTION V - HEALTH HAZARD DATA PAGE : 03 MAY-CAUSE COUGHING AND SNEEZING. SKIN CONTACT- MAY CAUSE MILO IRRITATION. CONTACT WITH OPEN WOUNDS CAN PROMOTE ABSORBTION AND SYSTEMIC EFFECTS. IN AUTOPSIEO BURNED VICTIMS. DBSERVEO LIVER DAMAGE NAS ATTRIBUTED TO ABSORBTION OF TANNIC ACIO THROUGH BURNED SKIN. _ EVE CONTACT- MAY CAUSE REDDENING AND TEARING WITH POSSIBLE PAIN ANO INGESTION-5TOxic. MAY CAUSE GASTROINTESTINAL DISORDERS INCLUDING NAUSEA AND VOMITING. MASSIVE INGESTION CAN CAUSE SHOCK ANC COLLAPSE. - CHRONIC - (LONG TERM EXPOSURE) MARKED IRRITATION TO SKIN ANO EYES- PATHOLOGICAL FINDINGS IN EXPERIMENTAL ANIMALS SHOW EVIDENCE OF GASTRITIS AND LIVER DAMAGE. . .... PERSONS WITH PRE-EXISTING SKIN OR EYE DISORDERS. DR IMPAIRED KIONEY LIVER. AND RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLfc TO THE EFFECTS OF tHE 5UBSTANCE. SEE SECTION VI FOR MORE INFORMATION. or JMARY ROUTE OF ENTRY: INHALATION <-- INGESTION X<-* ABSORPTION EMERGENCY & FIRST AID PROCEDURES INHALATION : GET TO FRESH AIR AND TREAT SYMPTOMATICALLY. IF BREATHING IS LABORED. GIVE OXYGEN OR ARTIFICIAL RESPIRATION. SEE A PHYSICIAN IN SYMPTOMS OCCUR. ................. .............. ............................................. ........ .............. ............................................................... EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER FOR 10 MINUTES LIFTING UPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY. TREATMENT IS MOST EFFECTIVE WITHIN ONE MINUTE. SKIN CONTACT: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. APPLY EMOLLIENT RICH CREAM. INGESTION : GIVE TWO GLASSES OF WATER TO DILUTE CONTENTS OF STOMACH. DO NOT INDUCE VOMITING . SEE A PHYSICIAN AT ONCE. NOTES TO PHYSICIAN : ADDITION OF BASIC NEUTRALIZER IS NOT RECOMMENDED DUE TO ALKALI SALTS OF OXALIC ACID ARE JUST AS TOXIC AS ACIDIC FORM. SECTION VI - TOXICITY INFORMATION PROOUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: J Aft C <--YES NTP <-* YES OSHA <--YES ACGIH <--VES OTHER < -- YES X< -NO X<--NC X < -- NO X<--NC X<--NC TANNIC ACID ORL-RAT LDLC: JOOMG/KG 1. ORL'RBT 1050: SOOOMG/KG 1. ORL-RAT LD50: 2300MG/K6 ORL-RBT L05O: 500QMG/KG 2. 2. (CONTINUED) CONQUEST SECTION VI - TOXICITY INFORMATION SCU-RAT TDLO: 44SOMG/KG/17 W-I 1. TUMEROGENIC DATA CITED 2. OXALIC ACIO ORL-HMN LOLO: 71 MG/KG 1. ORL-RAT LD50: 375MG/KG 1. SKN-RBT: SOOM6/24H MOD. 1. TANNIC ACID PROOUCEO LIVER TUMORS IN RATS FOLLOWING SUBCUTANEOUS INJECT IONS OF HYDROL YZABLE TANNINS PRODUCED LIVER TUMORS. NO ADEOUATE PUBLISHED STUDIES INVOLVING ORAL STUDIES OR CASE REPORTS ON EPIDEMIOLOGICAL STUDIES WERE AVAILABLE. IARC 10.253.7. IARC 010 NOT INCLUDE TANNIC ACID IN THE LISTING OF SUBSTANCES<MONOGRAPHS 1-29)*FOR WHICH IT IS CURRENTLY CONSIDERED THAT THERE WAS SUFFICIENT EVIDENCE OF CARCINOGENICITY IN EXPERIMENTAL ANI MALS (SUPPLEMENT 4. 1982. APENC1X 2) SEE SECTION XII. SECTION VII * REACTIVITY DATA STABILITY |X<--STABLE C--UNSTABL ! CONDITIONS TO AVOID |............. ..........................................------------------ --------------------------- ----------- --------- KEEP CONTAINER TIGHTLY CLOSED. INCOMPATIBILITY (MATERIALS TO AVOID) STRONG OXIDIZERS(BLEACH).SILVER AND ALKALIS. HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE. ACRID SMOKE AND FUMES. HAZARDOUS ! WILL NOT i X <*-OCCUR MAY <--QCCUR polymerization! JN/A ! CONDITIONS TC AVOID SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED CONTAIN LEAK AND PICK UP S^ILL ANO PLACE IN A LABELED CONTAINER. CLEAN UP RESIDUE WITH DETERGENT AND WATER. SAL WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH FEDERAL. STATE AND LOCAL REGULATIONS. NEUTRALIZING AGENT ADO CAUTIOUSLY A SOLUTION CF SLAKED LIME 08 SODA ASH WHILE STIRRING UNTIL PH IS AT 7. 000009857 c UUNOUfcb1 SECTION IX - SPECIAL PROTECTION INFORMATIOPAGE : 05 KEOtHKEV VENTILATION GENERAL EXHAUST IS MORE THAN ADEOUATE TO PROTECT WORKER PROM EXPOSURE TO LEVEL ABOVE PERMISSIBLE EXPOSURE LIMITS- RESPIRATORY PROTECTION A RESPIRATOR IS NOT RE0U1REC IN THE NORMAL USE OF THE PRODUCT. APPROVED MASK FOR SPRAY MISTS. USE A NXOSH PROTECTIVE GLOVES RUBBER GLOVES SHOULD BE WORN TC PREVENT STAINING. EYE PROTECTION CHEMICAL GOGGLES IF METHOD CF APPLICATION OF PRE SENTS THE LIKELIHOOD OF EYE CONTACT. CTHER PROTECT ION APRON SHOULD BE WORN DEPENDING ON SEVERITY CF EXPOSURE. SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE INDOOR 120 F.<--MAX 35 F.< *-MIN ' X JHEATED [ PRECAUTIONS TO BE TAKEN IN HANDLING & STORING KEEP DRUM TIGHTLY CLOSED. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE USING PRODUCT. ! REFRIGERATED ! OUTDOOR || SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C- A.S NUMBER UPPER % LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TC THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND RAUTHOR 12AT1 ON ACT OF 198 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER N LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK. DR THE PRODUCT IS USED AND LABELEO FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MCTOR VEHICLES- PC0 34 CONQUEST SECTION XJI * TRANSPORTATION * (FOR FUTURE USE) PAGE : 06 APPLICABLE REGULATIONS <--45 CFR <--IMCO SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DOT SPS CONTAINER AEROSOL PROPELLANT(S) <--TARIFf 6 D <--lATA <""MILIT ARY AIR (AFR 71*4) ! 10 NUMBER | REPORT QTY i LIMITED OTV j NET EXPLOSIVE WT. SECTION XIII - REFERENCES 1. DANGEROUS PROPERTIES CF INDUSTRIAL MATERIALS. 6TH EDITION. N. IRVING SAX. 2. THRESHOLD LIMIT VALUES AND BILDGICAL EXPOSURE INDICES. 1986-1987. 3. VENDOR'S MSDS. CONTINUED FROM SECTION VI. GALLIC ACID, THE MAJOR HYDROLYTIC PRODUCT OF TANNIC ACID. DID NOT INDUCE TUMORS WHEN GIVEN SUBCUTANEOUSLY. SUGGESTING INTACT TANNIC ACID IS NEC" ESSARY FOR ANY TUMOR-1NDUCIN6 EFFECT. DATA INDICATING THAT TANNIC ACID IS NOT ABSORBED AFTER ORAL ADMINISTRATION. BUT IS FIRST HYDROLYZED TC GALLIC ACID. THIS MAY EXPLAIN THE NEGATIVE CARC 1NOGENCITY FINDINGS FOL LOWING ORAL OR DERMAL EXPOSURE. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT DF CURRENT FORMULATION. HOWEVER. NC WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FRDM THE USE THEREOF. SAL NATIONAL CHEMSEARCH DIV. CF NCH CCRP. ASSUMES NC RESPONSIBILITY FOR PERSONAL INJURY DR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR CXSPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PRODUCT. 000009858