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o ! AR&26 1185 rornaTmySemn apres comaonSRT ene SHE, - TAFT, STETTINIUS & HOLLISTER LLP 425 WALNUT STREET, SUITE 1800 CINCINNATI, OHIO 45202-3957 T samE a etm nTeeocwmsarece [soppy wdFe f SSuEmd as Rsoiisaet2Ai5n.7o.no36c30orm - August 19, 2002 B TELECOPY Perry D. McDaniel, Esq. West Virginia Department of Environmental Protection Office of Legal Services 1356 Hansford Street Charleston, WV 25301 a oi = Ef = Ee z = . Re: Dear Perry: WVDEP Document Production Issues `This letter responds to your letter of August 12, 2002. requesting that we identify "any particular documents or categoryof documents that have not been produced to date" in response to "outstanding document requests and the issues raised in the order by Judge Hill." As the party requesting the documents from WVDEP. we obviously are not in a position to know whether WVDEP has. in fact. produced all of the documents it is required to produce and must rely upon WVDEP's representations in that regard. As the party possessing the documents at issue, WVDEP has the burden to demonstrate compliance with its document production obligations and cannot shift that burden to the party requesting the documents. We, therefore, request that 'WVDEP confirm, in writing, that it has produced all ofthe documents at issue or identify, in writing, what has not yet been produced. Upon reviewofdocuments that have been produced to date by WVDEP, it appears that there may be certain recently-generated documents that have not yet been produced. As explained below, it appears that there must have been recent modifications to the Consent Order between DuPont and WVDEP that allows WVDEP to prepare the final CAT Team reports, as. opposed to allowing WVDEP's contractor - TERA- to do that work. If such modifications to the CAT Team procedures have occurred, we have not yet received those documents. CONTAIN NEY CRI 000143 Perry D. McDaniel, Esq. August 19, 2002 Page 2 prepareUdpaondrarfetvdieowcoufmtehnet adlolceugmeedlnytssupmrmoadruiczeidntgotdhaeterebsyultWsoVfDtEhPe,meweetiunngdoefrstthaendCtAhaTt TTeEaRmAin CCiAncTinTneataimomneMmabeyr6s afnord r7e, v2i0e0w2,anadndcotmhamtenTtE.RAWemaudnedetrhsattadnodctuhmatenTtEaRvaAilaalbsloeptroetphaerevdaraidoruasft TdoEcRuAmeanltsoremfaledcetitnhgatthdeoCcuAmTenTteaamv'aislasbelleecttoiotnheoCafA"TscTreeeanminmgelmebveelr"sffoorrCr-e8viinewaiar,ndancdotmhmatent AlemveolnrganogtehefrorthCi-n8gs.asthlaotwpaarst0i.c3uluagr/dmr.a'ftWdoecufumretnhetrfurnodmerTsEtaRnAd tsheatt,forratthhaerptrhoapnofsoerdwaairrdstcoreening 5T0EtRhaAt eTaEcRhoAfctohueldCAinTcoTrpeoarmatmeetmhbeecrosm'mceonmtmseinnttso iotns fTiEnaRlAr'espodrtr,afWt VscDrEeePn'isngelmepvleloydeoec,umDre.nts Sitnacaotrsp,oruantiel,ataenradllhyoawssthuomseedctohmemteansktosfwdoeucliddibneg iwnhciocrhpoorfattheed iCnAtoTthTeefaimnalmeTmEbRerAs'repcoortmsm.enMtosrteo sTpeeacimfimcaelmlbye,rwse, uanndderpsrteapnadretdhaatcDor.loSrt-acaotdserderveiveiwseedd veearcshioofnotfheTEcoRmAm'esntdrsafsturbempiotrttesdebttyintghefoCrtAhT hceormmveienwtssaisnttoo twhheicfihnoalftvehresicoonmomfenthtesTsEhoRuAldrebpeorit.ncoArtpotrhaitsepdoainntdahnodwtibmees,t ittoiisnncootrpcolreaatrettohuosse swehtyupTtEhReACAwTasTneoatmp.eromriwttheyd TtoEpReArf-ortmhetchiosnttraasck.toarsrceotnaitneemdplbayteWdVuDnEdePr tthoepCroepnasreentthOerCdeArTthat Team reportsor whether the was not permitted to decide which comments were, in fact, consistent comments with what to incorporate into the was actually discussed final or report dCeotnesremnitneDdecdruereinbgettwheeeanctDuaulPConAtTanTdeaWmVmDeeEtPingw.asTmhoidsirfaiiesdesstohmeeqhuoewsttoiaaolsnlotwo wWhVeDtEhePr'tshe employee to unilaterally take over these tasks. being In addition, it permitted wide is not clear why a latitude to suggest non-CAT numerous Team member, John Butenhofo3fMf, is now substantive revisions to the conclusions in TfrEoRmA'wshidcrhafCt AreTpoTrteoarmwmheymbWerVsD/oEbPsenrvoewrshawsiltlhebepoiwnceorrptooruantieldatienrtaolltyhedefciinadleCwhAiTchTecaommmreenptorst, and which will not. level" range for C-8 In in particular, we note that air as lowas 0.3 ug/m'. TERA's In fact, original drafts suggested a Joan Dollarhide of TERA, "screening specifically rstaantgeed fionrrCe-s8poinnaseirtoshToEuRlAd'bsedsrealfecrteepdoarst tthhaetftihneal0s.3cruege/nmin'glloewveeslt"lbeevcealuosfetthheis"siscrteheenmionrge.level" paunbdlircevhieeawltehdpTrEotReAc'tisverecchooimcmee.n"da(tSieeonAtitnatchhismernegtarAd.,) itAalptpheoaurgshfWroVmDtEhePdaopcpuamreennttlsyrreececnetilvyed tphreod"usccreedenbiyngWVleDveEl"PfotrhaairD,r.asSotpapatosseisdstuoggtehestlionwgetro0r.e3viusge/Tm'ER"As'crseerneipnorgtlteovesle"lercetc1omugm/emn'deasd ahnasdtrheecoauntfhiorrmietdy atso trheejeacptptrhoeprCiAatTe sTceraemencionngtrlaevcetlorb'ys TreEcRoAm.menItdiastniootncilneatrhitsoruesgahrodwanWdVDEP OunridleartebraeltlwyecehnanDguePotnhte aainrdscWrVeeDnEinPg.lePvaerltuicnudlearrltyhetrporuobcleidnugrienstsheitsurpeguanrddeir tthhee ofraictgitnhaaltConsent WVDEP and Dr. Staats are well-aware that DuPont's own air modeling data confirms that 000147 Perry D. McDaniel, Esq. August 19,2002. Page 3 + DuPont's air community. emissions would Again, it seems exceed that the a 0.3 "screening level" for C-8 Consent Order must have been in thesurrounding modified somehow to give WVDEP new power to unilaterally alter the CAT Team's recommended "screening levels.". the Based on documents it the foregoing, it is not i required to produce clear at relating this time whether to the CAT Team WVDEP has produced all activities. Recent actions of by WVDEP to change the final CAT Team reports seems to suggest that there must have been some recent modification of some sort to the Consent Order between DuPont and WVDEP that set up rtehqeuCesAt.TtTheeraefmorper,otcheadturWesV.DEIfPthcatonifsitrhme.ciansew.riwteingh,avwehentohteyretthreerceeairveedantyhoasdedidtoicounmaelntrse.sponWsei.ve. documents to be produced and when WVDEP plans to produce them. Thank you. hd 8 } LGerb t &' :Bio(if ' RAB/mdm Anachment ce: LR.amEydiAs.onWiHniltle,r,EsEqs.q. 000148 rom: Tor *Jozn "Andy KDaoilelra'rhicdmea"ier<adtoelrlaa.rohrigd>e,dte"rMai.cohragesl Dourson <doursenatera.org> Dates 7/12/02 3:410M subject: 8 rec Ri, Juse read for a UFs this, of 10 nfoircebowtohrkpoAntdeyn!tialMycrointliycaclomemfefnetct-s.I was the only Sven though holdout I scill believe a total UP of use of 1,000. I like t3h,e000wayisyoauppprroepsreinatteed ftohre threangReED,of I tcheanRElCi.ve with che Bue I would level recommend che lower making value itnhethefinraalngep,RECracchhoericethaannda resulting air median value, screening because this uinscetrhteaimnotrieespuabnlidc thheeaulptrhoaprrotatecttihivse choice. site, it Given makes the existing sense to be as conservative as is reasonable. Joan ----- Original Message ----- From: "DEE ANN STAATS To: <whysnersaol coms; cdstaacsdmail.dep.state.ww.uss <jzwlacdc.govs; <cicmanec.john@epa.govs: . <<jriomt.esnfbeerrrga.dseapmau.esltzaecpea..goohv.su;s>;<s<ejeldb.ujteennnhioffefradmempma..cgoomvss;: <:maieratera.orgs; <<d:oglelraarhlidd.els.tekrean.noergd>y;su<sdao.udruscponodnmtt>era.org; SSeunbtj:ect:WednFueds:dayF,w: July 03, C8 PREC 2002 8:46 AM Hello again everyone, pI osamc-mfeoertwianrgdinagctitoon yoiutemasn email from Andy Maier that he has completed that explains - essencially the development of the PREC attached and as air well. screening level. The supporting calculations etc are Please reveiw these it's directions for to the make post sure they accurately meeting actions to reflect be taken, the meeting and just as you are doing (or a on no the meeting notes. comment statement) byPlcelaosese soefndbumesinaensds MiokneJuDloyurs17o.n you comments Thank das you again for your time and assistance. Dee Ann Staats, Ph.D. Science Advisor WVDER Executive Office 1356 Hansford Street Charleston, WV 25301-1401 phone: 304-558-2508 ext 309 fax: 304-558-3998 000143 Page lof 1 -- DAVE WATKINS - DAQ_ /DuPont Meeting on -- 4/24/02 m TFroom: ""MJ.ohAnnBnenBeraddilcety('E<maabrialci<eJ,B@EsNpEiDmIanCiTa@wMaclomd>ep state wy.us> SDuabtjee:ct: 4D/A1Q9//D0u2P3o:n1t0MPeeMting or: 4/24/02 Gi R(oEbmaaritlL BeRirtncaheryd(.JERmehial)ye@<ueRsoabdedrutp.oeLnRtiteccohmeys 1@USA dupont cam, `Bernard J. Rely Escurs EAbLesGsceiTocanwuwiSastoeessasbAeyArssshAooCeB.eeanofemr3seais4n.5sSou0gemgtefhstmeeeWdarsHso ghaapnggrteeforrvhweeermteenaifnygetbBbry e We cok omar o magrmin you 14 other DAQ restates ne ween Frases Ages for esing Setneen OAQ 30d Dupont, 4/24/02 11$031000211031000 GGnoiicruotctMoosnoesicnnsgsResemascntsassorpeyvend out data 3223300033R30a00aSDiug wlasutiIng sokornocneand ss <r ace Seper 417 02 docs Sle/CAWINDOWS\TEMPIGW)00002.HTM WVDEP 11678 42302 000150 ' ror IC Modeling Methodology and Results Emission Source Information TatheesfIoSrC3yemaord2e0l0w0aasctuusaeldCo8 cemailscsuiloansamfbrioemntthegrWoausnhd-ilnegvteolnvWaoporrkscosntcee.ntTraabtlieon1ssahnodwdseptohseition ausstneaddc.karTpeahiredaemsnetttaiecckralsptauorsaetmdheotisneertsshueabmmnidotdetemelidsfpsuoiroesnuaacanhtteestmoiusCesodinaosnreenptotinhOtor.sdeeTrtahbGaltWeRw-2e2rs0eh0oa1wv-asi0lt1ah9be.leemSaiisnsocifeo1nt2hr/ea1Ct7e/8s01, bewyemrimeosbdsaeisleioadnnrgoesnepatachrheiptiohotaansleeedsmebipesatsriwatoeenelsny).th(eMvoadpeolrinagndrupnasrttiocldeepthearsmeisn,edgerpoousnidt-iloenvreulncsonwceernetrcaotmipolnested `Dfmoeropdoeesalicithnigopnhfaomsroetodhefelpieanmnigiscrsleieqounpishrae(ssveappawonariscalonebdisaipziaenneiddcilsfet)rr.iobmTuhttieeosnstiiizneg ndatisftthreiobWurataisomhnnidnaisgncfttaoovrnimeanWtogoiironnnkgsucssoetedf.fiiTnchiteeh.nets scDIaSuvCPeSoUnnsgteiwrnh'gisccGoehufifwdieecr.ieenTstshubemuvisatetpdeodrfopurhntadhseereptsahcneaicvCleoenngspiehnnagtsecOorwedefefrri.ecioTebhntisasiudnsaeetddafswreormehbFaitgshuoeerdceao1lwn-a1l1caastolfceudtlhavetaiEpoonPsrAby ctshcaeanvmbeoendgeeinlntgeprrceeoddeificfntiticooinetnshtewbIeaSrsCee3dcomononsedrreav,iantitivhneet.elnasTriagtbye.slteSs3icnascvheeonowgnsliyntghoecnogeeafvsfaialcnuideeonptfawtrathiseclsecchdaoavsteeannugsi0endgecniosnuetrfheec.itheantt model and. additionally. shows the basis forthe vapor scavenging coefficient used in the model. . Modeling Methodology DMiosdpeelrs(iIoSnC3a)n,dvdeerpsoisointi0o0n10m1o.deplrionvgidweadsbpyeLrafkoersmeEdnvuisrionngmetnhteaIln.dusAtlrliamlodSeoluirncge Cwaosmpdloenxe 3in atAhcpecpomerondddaeinlx,ceW)w.itThhteheEpPrAocreedguurleastoirnyEdPeAf'ausltGuoipdteiloinnseanodn rAuirraQludailsipteyrsMioondecloesff(i4c0ieCntFsRwPearret u3s1e,d in `LTahkeeCs8EnevmiirsosnimoennstoaulrcBePsIwPerVeieewvamlouadteeld wfaors duoswednwtao sphroevfifdeectwsifnrdomdisreucrtrioounnsdpiencgifbiucilbduiinglsd.inTg he pthaerasmteatcekrsb.y Aclalusbiunigldbiuniglsdoinngtdheowsintweawsehreefefvecatlsu.atAedpltootdpeltaenrmsihnoewiifntghetyheclooucladtipoontoefntbiuailllydiinmgpsact ithnecllusdtesduibnmitthetemdodunedlerisCsohnoswenntinOrFdiegrurGeWRI. -(2T0h0e1-b0ui1l9d)i.ngs included in the model are identical to rAec1e0p0to-rmsetweirthgr1i0d0e-xmteetnedrinsgpaocuitng4.w0e0r0empeltaecresdfornomthteheplsaonutrpcreopwearstyusleidn.e. ITneardrdaiitnioenl,evdaitsicornestewere imported from electronic files obtained from the U.S. Geological Survey. AHoncakdidnigtiWoanatlerreAcsespotcoiragtriiodnwwaesllusfieedldt.oAdeUtSerGmSinteodpoegproasphiitciaoltonmathpe wwasterussheeddtofoirdetnhtiLfiytttlhee WVDEP 11679 000151 ' ro sieinrnalthairsswaotferhesyhaedte(Frisguhrde (3igur)e, anda recepor 5rd ith 100 mete sping was laced sspOcieonteenedsMyesletaafenroeosrofs.losougsnhiicaniagnlW|imPlenrtmoseigonrrwgaotemloroneGg,uiricOadahtlaiendodcecfcoofrn(otsr1hi9esR9te6ueg)npltpwsewstriotilhttdyMhietoaeredMc.ionsmTsmhieenngddadattiswoanassudprramotceesssedSPbtyA.Troin.n meters was used fr the modeling. ry deg An ammo repro 1 Modeling Results pAn3apndnoiacrselaecrnoaasngncaiednndgtveratappitomioreosnhosaifsinsteesehsssoecwoanvrsehirwnoatwFshnieugeisunendrFt4eis.ogusCdroeenestteSooraumnridgpni6ltd.hoTeoAahfncnmhuoealmoaotveirdaoegpeoofsvtiahtpieoornacsnoanc)csernptrsieioan:s bythe model were si oat sas ered Maximum Annual Average Ground-Level Concentration = 2.806 nym' Panicle Phase: MMMaaaxxxiiimmmuuummm TWDreoytlDDDeeepppoooissiiitooinnonRRRaaaette===00.0.1.03144375394mgmmyyyere - Vapor Phase: Maximum Wet Deposition Rate = 0.0085 ymilyr Tpferhneecdeimlcitanexedin1mourotmchcogufrrotuahtnedt-phileaensstea.lmTechorneeccemenapttxroairtmi(uo4nm2a1ann3dn5usaAllTEog.rto4hue3n4dm6.a8es9vi9emNlu)Sr,mwohdiencpohesiiriooanepraescecstowimenree polae in areas where people may reside in the community is. approximately 0.8 ug/m'. epLApdoidtosiesttiiiHooonoacnnlkliraynt.tgeesswwafmesolaclawaaclltcherurelrscaehetcepedetd.poforonTg,hraeihdlimwcooahdtsehruiwsesadcsewtpueoornderes1th0earcnnmodilinepmeuplltotheriecavedanpuioabrolyndsdheepapoussbsiiiceoinnrpatsaonthseneage (c2a.l5c7ulkatme'd)wteorege:t a total deposition pet year over the entire d watershed. The ep dn deposition amounts Panicle Phase: TTTooottaaalll DDWerepytosDDieetppiooossnii=ttii1oo9nn.==4561092.6g46s8r4ggeye Vapor Phase: Total Wet Depositio=n 1642 g/yr WVDEP 11680 000152 Tablet Stack Parameters e Pemic e Pemit Reg29| TZonTe 1T7 amber Veuld_ VemID| UME eHeeight UMN| @ sDiaameterS Flow e Velocityk Temper @) (min) (A) (ged. [1E3n8 ns TTIIMCEE TCE eGeh | aaomss aaeess|| 0Sis15 9 | sues | san w9w wow iwezs ionm 22m PreHExsiisaing 61a I16B6S2E6 66s2 | fMaIn Mosee|| 60 ME 31 aio oem| 5 116% 2ommm 2se4l 06 sw me 2a0 1 pTMs 1953 EWHNE 22 2226 aaso noaimee| @S10013 20 fas oe| es 0s 2as0 120 mwes 1061 iins 200 Scmiwerk2s6A5p0plicaton KOCZSLLEF6 ScmiworksApplicaton ROZ2LEFS6 am aanms aawwed|| 000 2s0 0 wer| 9 20 wLosw m0 0de0 wo a0ss 0 SSecmmiiwowrokkssAApppplliiccaattiioonn KROO2222LL4F887) awoos ooue0ss| 2200 samms w 00 w ow np TVhenetveIlDocTiGtIyZiCsEecd ohmesveolofc1itoy cfulteueddfaotnevedsi.viTdheedlvoewt.tegiven istesfo af18ves, 3 5 % 000153 KaanTannferrmtion Fmt Rao| PNaaicse VMoaosr|| CooAsmcummlT on OCbEAmV ciodnlins||FEnaikoAiPbuee TVoopArPTrTe Emsnfe | Vel VID Scion Enea| oo ay ) enn | weieeewn || o0s ow ww eo| o> ol [noom o eaon | ouovs eoons o . waas a | o[oooo wea | on ow [as swoowns vow || {omwomr ome aFrotso obs WwEiNn ae owme|| oom am | oes om | doe or [ase owvn | owoas eves | ems on oes woansteits wont momLovolom | sais moiuens || ionoes ame | ome sours o RRoommie I I 03 ioerse || osoense o. 2 000154 H ror Gas &TPaarbtlic3ele Data Particle Phase: Scavenging Cosficients DPaartimcles| vas | DPareicsle||prLeiiqpuiiadti+n PrcFrpoizneinon (mic0OrFons[)[|ooFrsaxctio[ n[|s(grem)3 [| |si(sza"7 /amom0-bT"|) hwo (s"/mm-h") Teno OE T 008 A |r ToT EE 30 3350" Vapor Phase: Liquid Scavenging Coefficient (s"/mm-h") = 6.4x10* . Frozen Scavenging Coefficient (s"/mm-h") = 6.4x10* CvaalpcuolratsiconasvoenfgiVnagpcoorSecfafviecnigeinantgesCopefrfeicsieennti the consent order submial as alsofvalues for . differen snl menses - tnihhieetsvseaaopronerd ttshcheaevsedcniagvviiendngegdicnobgeyfcftoihceeifeiinctnitanhtalts ismsheeonwtnenrseind tihnetoctohneseInStCormdoedreluics inbeunaidtjsuostfeds/mmh-eh"p.roper 0menhsuraeihnatnmiosdeil pweadsiUcsieodn.s25whiiobsescuohneslerrgevdset,vtahleescoarvennguitngnceoefhceiemnosdeblased ona | 23100100 Le B 56005 mm I SHoEm gg ge7 WYDEP 11683 000155 i | oa - : -" EnRp eAdY oan Tn \ . Vm \ | - 0) } ha we 1m, fen 0 V1 i! a Lawot = vi ep Wo amt Im w Hal +| sob Ce | | -" MN Figure | Buikling Plot Plan 000158 RTE : ak a Ao AnElB E oE e 8 Tr lB Bg es EEA st a rR Col BSEERT TT Sl i . [2 Ftdreeoe n ES ft] oss? wo i ISSIR RRRRTRRTARIE ISRA FI aso Penn oo PEE Cee| . oe 3 w [A Lot oad! Choe wim wm wm wm we wie wie en Lite Hocking Wel WFaiegrusrh3eed Rector Modeled ; 000158 At i ove 3 ! ( Ne /0 [5 so aR lo \ Soey, A lle (EE [\ v0) o 7 \ Ce $7 - > i = | wei wm we we whe we ae ale we | ; Si B | |R1[7 Ii . ||| ) X | Figure. Prick Phase Tol Deposion Roc I| r z: ". -- I i [me | || | |KEr p n| | o| 3 ||) 3 rey | om || LT | ag ey LI | i py rm Figure 6- Vapor Phase Wet Deposition Rates