Document ppvknjgXxZ3o90rB0ZrbMjk0a

Mm CASE NARRATIVE itiV; Analysis of Samples for the Presence of Volatile Analytes by High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry METHOD 8260 Rev. 1 (7/92) Date : September 30,1997 Client ID : Radian International TLI Project Number: 43396 This report should only be reproduced in full. Any partial reproduction of this report requires permission from Triangle Laboratories, Inc. Triangle Laboratories, Inc. 801 Capitola Drive P.O. Box 13485 Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485 919-544-5729 Fax # 919-544-5491 T 00 A 048700 GONF T DFNT T Al Triangle Laboratories, Inc. Case Narrative September 30,1997 43396 Objective: Analysis of six VOST tubes for the volatile compounds 1,1,2-trichloroethane and chlorobenzene using Method 8260. Method: Four VOST tube pairs were received at Triangle Laboratories, Inc. on September 26,1997 at 11C in good condition. The samples were stored in a refrigerator at 4C prior to analysis. The "FB" sample tubes will be processed and reported under Project 43397. The remaining VOST samples were analyzed according to die guidelines of Methods 8260 and 5040. The internal standards and surrogate standards were added in the amount of 0.25 micrograms (ug) to the VOST tubes immediately prior to analysis by GC/MS, The"internal standards are pentafluorobenzene, 1,4-difluorobenzene, chlorobenzene-dj, and 1,4dichlorobenzene-d*, and the surrogate standards reported are dibromofluoromethane, toluene-dg, and 4bromofluorobenzene. The results reported relate only to the items tested. The GC/MS analysis conditions are listed below: Purge and trap: Purge: Desorb Temperature: Desorb Time: Tekmar LSC-2000 11 min. 250 C 3 min. GC Conditions: Column: 30 m x .53 mm x 0.3u J&W DB624 0 C hold .5 min, 10 C/min to 45C, 6 C/min to 90C, hold 1.5 min, 50 C/min to 200C. MS Conditions: Instrument: Scan: Interface: VG-TRIO-1 Lab Base data systems 35-350 amu at .6s/scan Jet Separator, 200 C Report: Enclosed with the case narrative are copies of the sample identification index, the project summary sheets, client paperwork, sample log-in sheets, and log book pages. A sample identification index summarizes the client sample name, TLI sample number, and analytical file name for each sample and blank. The project summary lists the amounts for detected analytes in gray. The estimated detection limits will be listed in parentheses when the target analytes are not detected. The data are reported as quantitation reports, chromatograms, interim reports, and spectra of detected target analytes. The quantitation report header lists the TLI project number, analysis method, instrument sample file name, client sample name, client project number, TLI sample number, calibration file, date received, and analysis date. The response factors used for all calculations are from the calibration file listed in the header. All initial and continuing calibration data are located in the back of the data package. The amount is reported in total ug for the VOST tubes. The retention time (RT) will be listed for all ln. Triangle Laboratories, Inc. Case Narrative September 30,1997 43396 internal standards and analytes which are detected. If a target analyte is not detected, it will be flagged with a "U" and a detection limit will be listed. Estimated detection limits are calculated for all analytes which were not found in the samples by using an area of 2000. The estimated detection limits reported are the average detection limits achievable over time on an instrument type. The actual detection limit for a given compound on a given day may vary from the estimate reported. The quantitation limit for all analytes is half of the low point of the initial calibration adjusted for dilution or sample volume when appropriate. Below this point the calibration cannot be considered to be linear. Any amount reported at a level below the quantitation limit will be flagged with a **J" and should be considered estimated. If any compounds are found at a level above the upper calibration range, the analyte will be flagged with an "E" and the amounts reported should be considered estimated. If any target analytes found in the laboratory blanks are detected in the associated samples, they will be flagged with a "B" on each sample topsheet All analytes"are quantitated against the internal standard preceding them on the target analyte list. Surrogate standards are quantitated against the internal standard with the matching internal standard reference number. For example, toluene-d has 2 in the IS Ref column and would be quantitated against the internal standard which has IS2 listed in the flag column. If an internal standard area is above or below the quality control limits as defined by the continuing calibration, it will be flagged with "High" or "Low" in the flag column. Results: The VOST tubes were analyzed separately per client request. All samples were analyzed within the fourteen day sampling to analysis holding time. The analyst noted moisture in the Tenax tubes. All internal standard areas and surrogate percent recoveries met QC criteria. Data was included for an LCS/LCS DUP pair. The results were reasonable and consistent with historical data. There were no target analytes detected in the laboratory blank. The target analytes were manually searched f when not detected in the samples by the instrument. Sample Calculations: Response Factor (RF) = Amount (ug) = (area analvtel x famt IS-) (area IS) x (amt analyte) (area analyte in sample) x (amt IS1 (area IS) x (avg ical RF) Where: amt IS = amount of internal standard 0.25 ug ical - initial calibration .1?/ 04870? CONPrDFNTrA! oo Triangle Laboratories, Inc. Case Narrative September 30,1997 43396 The rfara in this package has been judged to be valid according to the guidelines of Methods 8260 and 5040 except as noted above. Should you have any questions, please feel free to contact our Project Scientist, Mary McDonald, at (919) 544-5729, ext. 269. For Triangle Laboratories, Inc., Report Preparation: Quality Control: Tracy Wardell Report Preparation Chemist s> A H Report Preparation Chemist The total number of pages in this data package is DO A 048703 CONFIDENTIAL -/t TRIANGLE LABORATORIES, INC. UST OF CERTIFICATIONS AND ACCREDITATIONS ENVIRONMENTAL American Association for Laboratory Accreditation. Certification pending. Certificate Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, Volatiles, Pesticides, PCB's. BNA's, and Dioxin/Furan. Method 1613 for Drinking Water. State of Alabama, Department of Environmental Management Expires December 31,1997. Laboratory I.D. # 40950. Dioxin in drinking water. State of Alaska, Department of Environmental Conservation. Expires December 21, 1997. Certificate number OS-00397. Dioxin in drinking water. State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate #AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste. State of Arkansas, Department of Pollution Control and Ecology. Expires February 18, 1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX. State of California, Department of Health Services. Expires August 31, 1999. Certificate #1922. Selected Metals in Waste Water Volatiles, Semi-volatiles, and Dioxin/furan in WW and Sol/Haz Waste. Dioxin in drinking water. State of Connecticut, Department of Health Services. Expires September 30, 1997. Registration # PH-0117. Dioxin in drinking water. Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140. Dioxin in drinking water. Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin in DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pestirides/PCB's (GO) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS# E87411. Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted" status for regulatory puiposes. Revised 9/18/S7 RM Prtrted 9/18/97 DO COMp lO Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking water. State of Kansas, Department of Health and Environment Expires January 31, 1998. Environmental Anaiyses/Non potable Water and Solid and Hazardous Waste. Method 1613 for drinking water. ID #*s - Drinking water and/or pollution control - E-215. Solid or Hazardous Waste -E-1209. . Commonwealth of Kentucky, Department for Environmental Protection. Expires December 31,1997. ID#90060. Dioxin in drinking water. Maryland Department of Health and Mental Hygiene. Expires September 30, 1997. Certification #235. Drinking water by Method 1613A. State of Michigan, Department of Public Health. Expires March 31, 1998. Drinking water by Method 1613. Mississippi State Department of Health. No expiration date.. Dioxin in drinking water. Montana Department of Health and Environmental Services. Expires December 31, 1997. Dioxin in drinking water. State of New Jersey, Department of Environmental Protection and Energy. Extended by state. Temporary certificate until December 31,1997. ID #67851. BNAs and Volatiles. Dioxin in drinking water. State of New Mexico, Environment Department Certification pending. Dioxin in drinking water. New York State Department of Health. Expires June 30, 1997. ID H11026. Environmental Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW. State of North Carolina, Department of Environment Health and Natural Resources Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water. State of North Carolina, Department of Environment, Health, and Natural Resources, Division of Environmental Management Expires December 31, 1997. Certificate # 485. Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP. North Dakota State Department of Health and Consolidated Laboratories. Expires December 31,1997. Certificate jTR-076. Effective October 4,1993. Dioxin in drinking water. Revtsad 9/18/97 RM PnnMd 9M8/97 00 A 048705 OONFTDFNTTAl, 5 Oklahoma Department of Environmental Quality. Expires October 31, 1997. Laboratory #9612. Dioxin by 1613A, 8290 and 8280. State of South Carolina, Department of Health and Environmental Control. Expires June 30, 1997. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCSs/pestiddes under Clean Water Act 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid and Hazardous Waste. State of Tennessee. Department of Environment and Conservation. Expires February 5, 1999. ID #02992. Method 1613 Drinking water only. U.S. Department of Agriculture Soil Permit. Expires September 30, 2001. Permit No. S3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive foreign soil samples for use in laboratory analysis. U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods 8280 & 8290 for Loekboume Landfill Site Investigation, Defense Distribution Depot Projects, and assorted projects for the USACE North Pacific Division Laboratory. U.S. EPA Region V. Expires November 14,1999. Dioxin in drinking water. U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in drinking water. State of Utah, Department of Health. Expires December 31,1997. Certificate Number E-166. Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method 1613; Metals including Mercury and Microwave Digestion. Commonwealth of Virginia, Department of General Services, Division of Consolidated Laboratory Services. Expires June 30,1998. ID # 00341. Dioxin in drinking water. State of Washington, Department of Ecology. Expires September 1998. Lab Accreditation Number C067. Scope of Accreditation applies to water analyses for Polychlorinated Dibenzop-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile) Organics and Puryeable (Volatile) Organics. State of Washington, Department of Health. Expires April 30,1998. Dioxin in drinking water. Lab I.D. 129 State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No. 9923(C). Dioxin in drinking water. 9n8ft7 RM Prinud9n&97 00 A O48706 chftdfnttal State of Wisconsin, Department of Natural Resources. Expires August 31, 1998. Laboratory ID Number 999869530. Certification for the following categories of Organics: Purgeable, Base/Neutral, Acid, PCBs. and Dioxin. Expires November 14, 1999. Laboratory ID 999869530. Dioxin in drinking water. PHARMACEUTICAL Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5. N.C. Department of Human Resources. Expires October 31,1997. Registration number NCPT 0000 0031. North Carolina controlled substances registration. Application submitted for renewal. Food & Drug Administration (FDA) Registration. Expires June 1998. ID tfs 001500 1053481. Annual registration of drug establishment Annual registration of drug establishment OTHER Clinical Laboratory improvement Amendments (CUA) Registration. Expires May 30, 1999. ID # 34DQ7Q5123. Department of Heaith & Human Services, Health Care Financing Administration. U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID #NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste. North Carolina Radioactive Materials License. Expires April 30 1998. License No. 0320954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and use such radioactive materials as designated. North Carolina General License for Radiation Protection. No. expiration date. License No. 032-875-OG. The general license applies only to radioactive material contained in devices which have been manufactured and labeled in accordance with specific requirements. RemM 9/18/97 RM Prmtad 9/18/37 A 048707 OONFTDFNT T Al,, o J Client Id: " ' Triangle Laboratories of RTF Sample Identification Index for Project 433% giiiigmii* iBil DOW-VP-VST-41-T02 T DOW-VP-VST-41-TC02 TC DOW-VP-VST-41-T04 T DOW-VP-VST-41-TC04 TC DOW-VP-VST-41-T06 T DOW-VP-VST-41-TC06 TC VOSTBLK 092797 T/TC * 184-69-1A 184-69-1B 184-69-2A 184-69-2B 184-69-3A 184-69-3B VOSTBLK 0927^"? HIS37 HT534 HT538 HT535 HTS39 HT336 HI532 Triangle Laboratories of RTP, Inc 801 CapitoU Drive Durham, North Carolina 27713 Phone (919) 544-5729 Fax: (919) 544-5491 , OAS70S Proj_Stnn v4.Q 9 Client ID: Filename: TUId : Matrix : Units : 1,1,2-Trichloroethane Chlorobenzene Triangle Laboratories of RTF Project Summary for Project 43396 DOW-VP-V5T -41-T02T HTS37 184-69-lA VOST US DOW-VP-VST DOW-VP-VST -41-TCQ2T - -41-T04T C HT534 184-69-1B HT538 184-69-2A VOST VOST ug ug (0.001) * (0.001) (0.001) (0.001) (0.001) (0.001) DOW-VP-VST -41-TC04 T C HT535 184-69-2B VOST ug (0.001) (0.001) DOW-VP-VST " -41-T06 T HT539 ( v 184-69-3A VOST ug (0.001) (0.001) ( ^Estimated Detection Limit Triangle Laboratories of RTF, Inc. 801 Capitols Drive * Durham. North Carolina 27713 Phone: (919) 544-5729 Fax: (9191544-5491 Page 1 L Savar v3-5 Printed: 1153:22 09/30/97 DO A 048709 CONFTOFNTTAl. to .J Client ID: rilename: Hi Id : Matrix : Units : l,l>Trichloroethane Chlorobenzene . i.r.. ' . .1 -:iv} Triangle Laboratories of RTP Project Sttmmary for Project 43396 DOW-VP-VST -41-TC06 T C HT536 184-69-3B VOST ug VOSTBLK09 2797 T/TC HT532 VOSTBLK0927 VOST ug (0.001) - (0.001) (0.001) (0.001) ( ^Estimated Detection Limit Triangle Laboratories of RTP, Inc 801 Capitals Drive Durham. North Carolina 27713 Phone (919) 544-5729 Fax: (919) 544-5491 Page 2 Savarv35 Printed: 113122 09/30/97 00 A 048710 CONFIDENTIAL 11 Dow, Plaquemine Trial Bum Vinyl nTT3jftt^=-Boiler F410/420' t/w U Stream Chain of Custody Record */ Condition Run Signature * Sample ID Date Analyses Sample ID Date Analyses /^ LDOW-VP- /5T- <//- T?2 a l DOW-VP- _ 7^0.1 DOW-VPDOW-VP- rev TCCV DOW-VP00W-VP- rt(a TCCL DOW-VP- TpSf TZmi^DOW-VP- \ dow-vp- ^5T- 7212 DOW-VP- TCc.1 vest . k^-VP-Ssr-^i-ldl ( reez _ L T<</ _______ _______ _ . _T<PV _. _ T<&> TFQJ sC_____ TtFBi f OOW-VPOOW-VPOOW-VPDOW-VP- DOW-VP- S 72>y Tart TL TC0& TFQi vf ; kr ANALYZE PER. HEIDI KRALL'S INSTRUCTIONS --12-41^-6030 (Analytical task leader) \JOst \/ . f\ Received by; DateTTune Relinquished by; Date/Ttme Received by; DatetTone Relinquished by; Doie/Tinte Received for laboratory by; Temp*C DatetTime Opened by: ffa/f7 *f/5 Comments: Dete/Tane Remar*k"s ------ a '7w f;--FuT "T1 ^k-stt CckcP,' h --*>-/-------------------------------------------------------------------Y* -V7-- ,_5Zg <^3^2.j g*t/y__________ * ^ DO A 048711 CONFTDFNTTAl. 12 CONFTDFtsir \J" u f / / '"f .1- --TRI AMPLE LABORATORIES, Custody Seal t Absent Sample Seals: Absent Chain of Custody t Present Container...i Intact Sample Tags t Absent Sample Ttjg Dumber si Dot Listed on Chain ol Custody SMO Forms i D/A INC. -- LOO 1H RECORD/CHAIN OF CUSTODYI TL1 Project Humber 43396 1 Client: RAC01 Radian International j Date Received j 09/16/97 j By C'5 Ice Chest TLI Humber. sA/HtCPH. (1M-69-1A |1I4-C9-1B |1I4-C9-1A |1(4-(I-1B 1--------f---- |lf4-69-JA jjlM-(9-)B |ll4-<*-4A 1* ..tlient Sample ID. ....Client COC ID.. DOW-VP-VST-41 -TQ2 DOW-VP-VST-41-T01 DOW-VP-VST-41-TC02 DOW-VP-V8T-41-TC02 OOH-VP-VST-41-T04 DOW-VP-VST-41-T04 j DOW-VP-VST-41-TC04 DOH-VP-VST-4X-TC04 DOW-VP-V6T-41-T0S DOW-VP-VST-41-TOC DOW-VP-VST-41-TCOS DOH-VP-VST-41-TC06 DOW-yP-VST-41-TFB1 DOW-VP-VST-4I-TFS1 ICE/ICE PACKS Temp II.0 C ~ZZLj Carrier and Humber | FedEx/1)1653)310 *r Matrixj To LAB To STORAGE j To LAB To STORAGE | To 1AB j To STORAGE( To LAB ) To STORAGE DISPOSED Location.............. j Date/Inlt Date/tnit | Date/Inlt Date/Inlt j Date/Inlt j Date/Inlt j Date/Inlt j Date/Inlt j Date/Inlt ------------------- 1----------------------1---------------------- ----------------------1---------------------- 1--------------------- --------------------- 1--------------------- ----------------------1--------------------- 1 TENAX] | 1I 1 11 ROIC 1 1J THX/CUAft| 1 l1 11---------------------- 1 --------------------- 1---------------------- 1 11 1 _ 1 1 __________ ___ ______________ 1 11 ll 11 A01C TENAX 1 1 1 1 11 ______________ 1______________ I hois 1 1 ROIC ROW TDK/CHAR TENAX 1 1 1 1 1 1 1 1 1 I R026 TDK/CHAR -- 1 ! ROIC TEHAX 1 t |ll4-(f-4B DOW-VP-VST-41:TCFB1 DOW-VP-VST-41-TCFB1 BO 3 6 TDK/CHAR 1 1 1 1 H J 1( 1 11 1 11 j1 ______________ _______________ 1 1 11 _1 ) ______________ _______________ 11 1 11 1___________________ 11 1 f k1 .I 1 1 L1 1 1 1 | 11 11 Receiving Remarks : jj FAST TAT V0ST( OTHER VOST'S ARB ID PROJ. 43397. |] .Archive Remarks: II it. r - I ............- -Form Revised 05/17/1997 -- Page 1 OF 1- Column Typo -Urn- Column ff T riangle Laborelb***, Inc. Run Log Analysis* 'JM Acquisition Method 'Js/l OC Method* Find DDs* Ollier* ** DO A 0 4 8 7 1 4 CONFTDFNTTAI Triangle Laboralori s, Inc. Run Log Column Type Column # Analysis* Acquisition Melliod OC Method* Find DBs* Other* HoSlo .. Al^EL^________ __32kSL_... Standards Interna) / Surrogate / Recovery _In__te_r_n_a__l _/_S_uirrofgliate / Recovery Vsf->*7-x ir'- A' /* v ,. Analyte Extract / Sample volume ^VtvQ.Sz? CkcttunN pL mL Jate** Time" Prolecl Sample# Client ID $h. 7 tb\% 4m lb M-nm DoutW-i/ir-i'i-WL ItHP '/in r Di*>4f"U7'lVT&H / Itizi T IIT3-13-30/1 JWV4-tfr^J~foC Filename pll* HKiJk ? Operalor/Dale Blgnilw* D*l Backup* Proc Comments*** U lime u // rsn JU llufi) u ii \rl lori mi [Tft 112} M "rjtlA, p hpk nrs-2 8 ^VoSTTW)-t JT Tire, ii [forfait r(r<- `link) X/link 4^ fhih) / ------'^ Jj \f iirku -- fkihi i-\xsbi- U ihh u u 1 LA LA LA r isvl NIU ' nc cb-0-w---/6- rr/1,---l-5- -F--2- --l---R---o---/ IIrb 33. Hfivl ihfo bAiluki. U. tu * Volatile Data Only RvmwvwonMSAnnuNLoo doc nrin Transcribed Data Dated Slgiiatiire/lnUlflls Required Pag___ y I ----0 c 1U DO A 0 4 8 7 1 R OONFTDFNTTAl Column Type Column # bin ^fo^L Analysis* ^60 Acqiilslllon Method <V&* GC Method* Find DBs* lore. Other* Standards Internal f Surrogate / Recovery V*7fr'/</7'L A ^ / j Inte7JrnWal / S7uZrroTga?te f Recovery n _i b } ( li> V jdJxsfc > c Analyte Extract / SampHlee voluuime <2 ilwa Tale** Time** Prolecl 1 Sample# Client ID Filename pii* Operalor/Dale mmism Comments*** Ur mi /c td1/ mi s" .4*/ f//j u Chela writ pL mL lU r/c /W-t# -viT' yf'Ttoi t-frsiL im-h-ia [W-tf /-*//?/& %' tnsi 4/ 4/ 1fnh\_ M u j*i*t*#< -6**** fay* wifyi ho ___ L r l')Ovt/Vl#'V^iT'VI-T^V fir&k' M llv/il /in 1 V1 w r 'To6 T imm (Pl-teSA IW-^/W-2/-rb> Iff S31 /i r sVo iJl/n/l) lA u i_____________________ i____________________ sim^**-* ___1 w# --w/. itvrf/W-- Hp itfik-y A-CS ini'll U- ihith ms-/ M'tO't -/1, White*) Lds /irsir 1/ ihiin u 1w 1 t Volatile Date Only " TianeOflbed Oala 8RvniwvonM94.nmM.(xi.Doo (town " baled SlgnaliaellnlllBls Requited Papa dientilcb? .'X-. Triangle Laboratories of RTF Sample Identification Index for Project 43397&A . if 'Aik: ' DOW-VP-VST-41-TPB1 t DOW-VP-VST-41-TCFB1 T/C DOW-VP-VST-42-TC02 T/C DOW-VP-VST-42-T03 T DOW-VP-VST-42-TC03 T/C DOW-VP-VST-42-T04 T DOW-VP-VST-42-TC04 T/C DOW-VP-VST-42-TD5 T DOW-VP-VST-42-TC05 T/C DOW-VP-VST-42-T06 T DOW-VP-VST-42-TC06 T/C DOW-VP-VST-42-TFB1T DOW-VP-VST-42-TCFB1 T/C DOW-VP-VST-43-TOl T DOW-VP-VST-43-TCOl T/C DOW-VP-VST-43-T03 T DOW-VP-VST-43-TC03 T/C DOW-VP-VST-43-TD4 T "X3W-VP-VST-43-TC04 T/C _XDW-VP-VST-43-TD5 T DOW-VP-VST-43-TC05 T/C DOW-VF-VST-43-T06 T DOW-VP-VST-43-TC06 T/C DOW-VP-VST-43-TFB1T DOW-VP-VST-43-TCFB1 T/C VOSTBLK100297 T/TC VOSTBLK100497 T/TC 184-69-4A 184-69-4B 184-70-1B 184-70-14A 184-70-14B eff'. 184-70-2A 184-70-2B 184-70-15A o^n 184-70-15B 184-70-3A 184-70-3B 184-70-4A 184-70-4B 184-70-17A 184-70-17B 184-70-5A 184-70-5B 184-70-fiA 184-70-6B 184-70-18A 184-70-18B 184-70-7A 184-70-7B 184-70-8A 184-70-8B VOSTBLK100297 VOSTBLK100497 /tjtalH : i File Name*. HT618 HT615 HT620 HT656 HT652 HT627 HT621 HT657 HT653 HT628 HT622 HT616 HT613 HT658 HT654 HT629 HT623 HT630 HT624 HT659 HT655 HT631 HT625 HT617 HT614 HT612 HT651 Triangle Laboratories of RTP, Inc. SOI Capitola Drive * Durham, North Carolina 27713 Phone: (919) 544-5729 * Fax: (919) 544-5491 DO A 048716 CONFTDFNTIAt Proj_Som v4.0 Q Client ID: Filename: TUId : Matrix : Units 1,1,2-Trichloroethane Chlorobenzene Triangle Laboratories of RTF Project Summary for Project 43397&A DOW-VP-VST -41-TFB1T HT618 184-69-4A VOST ug DOW-VP-VST -41-TCFB1 T/C HT615 184-69-4B VOST ug (0.001) (0.001) (0.001) (0.001) DOW-VP-VST -42-TC02T /C HT620 184-70-1B VOST ug A (0.001) ; (0.001) DOW-VP-VST -42-T03T HT656 184-7Q-14A VOST ug ________ (0.001) (0.001) DOW-VP-VST -42-TC03 T /C HT652 184-70-14B VOST ug____________ (0.001) (0.001) / / \ 9 ( )-Erimat*d Detection Limit Triangle Laboratories of RTF, Inc SOI Capitola Drive * Durham. North Carolina 27713 Phone; (919) 544-3729 Fax (919) 544-5491 Page 1_____________________________________ Savar v3-5 Printed: 11:08:49 10/31/97 bO A 048717 ^onftdfnttal 10 Client ID: Filename: TU Id : Matrix : Units 1,1,2-Trichloroethane Chlorobenzene Ib* WdfT.vV Triangle Laboratories of RTP Project Summary for Project 43397&A DOW-VP-VST -42-T04T HT627 184-70-2A VOST g DOW-VP-VST -42-TC04T /c HT621 184-70-2B VOST DOW-VP-VST -42-TQ5T HT657 184-70-15A VOST g (0.001) (0.001) (0.001) (0.001) (0.001) (0.001) DOW-VP-VST -42-TC05 T /c HT653 184-70-15B VOST ug (0.001) (0.001) DOW-VP-VST -12-T06T HT628 184-70-3A VOST g (0.002) (0001) A r~'C . -,\ ( )-E*tinuteti Detection Limit Triangle Laboratories of RTP, Inc 801 Capitols Drive Durham, North Carolina 27713 Phone: (919) 544-5729 Fax: (919) 544-5491 Page 2 Savarv3.5 Printed: 11:08:49 10/31/97 D A 048718 CONFIDENT TAt 11 Client ID: Filename: TUId : Matrix : Units 1,1,2-Trichloroethane Chlorobenzene Triangle Laboratories of RTP Project Summary for Project 43397&A DOW-VP-VST -42-TC06T /C HT622 184-70-3B VOST _________ (0-001) (0.001) DOW-VP-VST -42-TFB1T HT616 184-70-4A VOST JJg_________ (0.001) (0.001) DOW-VP-VST -42-TCFB1 T/C HT613 184-70-4B VOST JJg_________ (0.001) (0.001) DOW-VP-VST -43-T01T HT658 184-70-17A VOST Jfg__________ (0.001) (0.001) DOW-VP-VST -43-TC01T /C HT654 c 184-70-17B VOST ug CO.CO l) J5C- -e*4 /pWT? (0.001) ' ( ( )-E*tinut*d Detection Limit Triangle Laboratories of RTP, Inc SOI Capitals Drive Durham. North Carolina 27713 Phone; (919) 544-5729 Fax: (919) 544-5491 Page 3 \ Savar v3-5 Printed: 1^49 10/31/97 DO A 048719 OONFTDFNTT Al. Client ID: Filename: TLIId : Matrix : Units 1,1,2-Trichloroethane Chlorobenzene Triangle Laboratories of RTP Project Summary for Project 43397&A DOW-VHrVST ''-43-T03 Ty HT629 184-70-5A VOST ug DOW-VP-VST DOW-V^-VST -43-TC03T ^43-TOiT^^ /c HT623 HT630 184-70-5B 184-70-6A VOST VOST ug ug (0.015) (0.002) (0.001) (0.001). (0-010) (0.005) A DOW-VP-VST -43-TC04T /c HT624 184-70-6B VOST g (0.001) (0.001) DOW-VP-VST -43-T05T HT659 184-70-18A VOST "g (0.001) (0.001) e.<^ C ( ^Estimated Detection Limit Triangle Laboratories of RTP, Inc. 801 Capitola Drive Durham, North Carolina 27713 Phone: (919) 544-5729 Fax: (919) 544-5491 Page 4 Printed: 1 DO A 048770 CONFIDENTIAL Savar v3-5 10/31/97 Client ID: Filename: TLIId : Matrix : Units 1,1,2-TrichIoroethane Chlorobenzene Triangle Laboratories of RTP Project Summary for Project 43397&A DOW-VP-VST -43-TC05 T /c HT655 184-70-18B VOST DOWrYJM/ST "-43-T06T ) HT631 184*70-7A VOST DOW-VP-VST -43-TC06T /C HT625 184-7G-7B VOST ug g (0.001) (0.001) (0.002) (0.001) t 1 (0.001) (0.001) DOW-VP-VST -43-TFB1T HT617 184-70-8A VOST ug (0.001) (0.001) DOW-VP-VST -43-TCFB1 T/C HT614 184-70-8B VOST ug (0.001) (0.001) i ( ^Estimated Detection Limit Triangle Laboratories of RTP, Inc SOI Capitola Drive Durham, North Carolina 27713 Phone; (919) 544-5729 * Fare (919) 544-5491 Page 5 L Savar.v3j Printed: 11:08:49 10/31/97 14 DO A 048721 G0NFTDFNTTA1 Client ID: Filename: TU Id : Matrix : Units : 1,1,2-Trichloroethane Chlorobenzene Triangle Laboratories of RTP Project Summary for Project 43397&A VOSTBLKIOO 297T/TC VOSTBLKIOO 497T/TC HT612 HT651 VOSTBLK100297 VOSTBLK10049 7 VOST VOST ug (0.001) (0.001) (0.001) (0.001) ( ^Estimated Detection Limit Triangle Laboratories of RTP, Inc. SOI Capitola Drive Durham, North Carolina 27713 Phone: (919) 544-5729 Fax: (919) 544-5491 Page 6 SavarvSj Printed: 11:08:49 10/31/97 15 DO A 0487?? CONFIDENTIAL Triangle Laboratories f RTF LCS Summary of Results LCS File : HT606 Date : 10/28/97 LCS DUP File: HT607 1,1,2-Trichloroethane Chlorobenzene m 89 101 84 102 6 1 Triangle Libenmias ofKIT, !n& 801 CapitoLa Dove * Ouriim, North Carolina 27713 Phone (919) 544-5729 F*c (919) 544-5491 Savar v33 Printed; 17:4920 10/28/97 D0 A 0487P3 conftofmttai Chain of Custody Record Dow, Plaquemine Trial Bum Vinyl II Plant-- Boiler F410/420 Condition I t 7. **3 Stream Signature Remarks t* I n *tgs4 7t - W- DO A 048724 CONFIDENTIAL 17 Dow, Plaquemine Trial Bum Vinyl n Plant-- Boiler F410/420 r "-!!!! Stream Chain of Custody Record Condition 4/ / / Signature Sample ID Date Analyses Sample ID Date Analyses F 1i oow-vp- ysf. v/l fa/ c?/>y hi oow-vpoow-vp- TCc/ yc ? l_____ oow-vp- /^o? oow-vp- TcT OOW-VP- TCof oow-vp- 77t?2 oow-vp- rzfg: i. vto^T i i i i fruj-t/p-irtT-V3~ 7Z>; 1 TCC/ ToS" / * l i TCC.5 - \c X TABtfete: : \ _ tffi-v )\ _J . DOW-VP-|^-^-T7/ oow-vp- rd0/ oow-vp- 7T13 (... ... oow-vpoow-vpOOW-VPDOW-VP- 7t?3 -jpg I V > .\ X \ ANALYZE PER HEIDI KRALL'S INSTRUCTIONS-- <12--119-6030 (Analytical task leader) Received bv: Date/Time Relinquished by: Daie/Time Received by: Due/Time Relinquished by. DaioTime ^jj^ceived fur laboratorvjjy: Opuedby 'to Ml iff/S' Ctwucmi: Daie/Titne Remarrtkcss LHaW -fkesc "SGmpUs pe#dft'rt\ fti/i'&J &f itA/fi ^ / Ce5u ^' 2/ v- 00 A 048775 conftofnttai 13 DO A 0 4 8 7 2 6 O O N F T D F N T T A l. 00 A 04A777 C0NFTDENTTA1 DO A 0 4 8 7 ? 8 CONFTDFNTT At. -TRIANGLE LABORATORIES, Custody Seal i Absent Sample Sealsi Absent Chain of Custody i Present Container...* Intact Sample Tags i Absent ^ Sample Tag Numbersi Not Listed on Chain of Custody SMO Forms t H/A INC- -- LOG IK RECORD/CHAIN OF CUSTODY | TLI Project Number 41397 , j Client* RAC01 - Radian Internetlonal j Date Received V 1 19 l Book CM |TLI Humber............... Client Sample ID..................................Matrix l-H/Hirm. .............Client COC ID............. * Location............... |lt4-70-15A | DOH-VP-VST-4I-T05 DOH-VP-VST-4a-TOS R016 TENAX |l4-7Q-15B | DQH-VP-VST-43-TC05 DOH-VP-VST-43-TC05 R036 THX/CHAR |lB4-70-16A | DON-VP-VST-43-TFB3 DOH-VP-VST-42-TFB2 R036 TENAX |lB4-70-16B 1 DOH-VP-VST-42-TCFB2 DOW-VP-VST-4a-TCJFB3 R026 THX/CHAR To LAB Date/lnlt To 8TORAOE| To LAB Date/lnlt | Date/lnlt | To STORAGE| To LAB | To STORAGE To LAB | To STtbAOB j Date/Intt j Date/lnlt | Date/lnlt Date/lnlt j Date/Ifilt ll i i ili l '. t 11 t _______________ _______________il i 1 i i i _______________ ________________1 1 1 DISPOSED jj Date/lnlt f 11 (IM-70-17A DOH-VP-VST-43-TOl TEHAX I DOH-VP-VST-43-TO1 R0] a_________________________________________________ !________________ |lM-70-L7B DOW-VP-VST-43-TC01 THX/CHARj l 1 DOH-VP-VST-43-TC01 R02S j 1 |lS4>70-lA j DOH-VP-VST-43-T05 DOH-VP-VST-43-T09 R036 TENAXJ j a ...________________________________________________________ ______ __ 1_______________ ! jlM-TO LBB DON-VP-V8T-4 J-TC05 THX/CHAR | DOH-VP-VST-43-TC05 R036 i1 ! _______________ ________________ i . t i |lS4-70-19A | n |184-70-19B jj t* DOH-VP-VST-43-TFB1 DOH-VP-VST-43-TFB1 DOH-VP-VST-43-TCFBI DOH-VP-VST-4 3-TCFB1 R03S TENAX R036 THX/CHAR i uH J Receiving Remarks* Archive Remarks* i * Form Revised 05/37/1997 - Page 3 OF 3* !i i1 i0 11 1I * ------------------------ 1------------------------ * TRIAHGLE LABORATORIES, Custody Seal : Absent Sample Seals: Absent Chain of Custody r Present Container,..: Intact Sample Tags : Absent Sample Tag Numbers: Not Listed on Chain of Custody SMO Forms t N/A INC. -- LOO IN RBCORD/CHAIN OF CUSTODY* | TL1 Project Number 43396 } Client: RAC01 - Radian International i I------------------ f Date Received j 09/18/97 j By/ Jv. i Book 184 Page CJ (M |TIjI Humber.........Client Sample 10........................ , . .Matrix| To LAB ni-- " -- To STORAGE To LAB i TTO STORAGE) o LAB To STORAGE) To LAB ---- 1------ 9 | To STORAGE DISPOSED | |amR./H.:.C.PM..................Clien_ t _C_O_C__ID_._.._._.._..______L_o_c_a_t_io_n_.._._.._.._.._j1 Date/Intt |l84-69-lA DOW-VP-VST-41-T02 TEHAxjOPV | DOH-VP-VST-41-T02 R02S j X-Date/lnit " Date/lnit Date/lnit j Date/lnit | _D__a_te/lnit i|__D_a_t_e_/l_n_it_ | i Date/lnit V*-V> ? 1 Date/lnit | I |l84-69-lB DOH-VP-VST-41-TC92 1 THX/C1IAR| i | 1 |lB4-69-3A D0W-VP-VST-4I-TCC2 DOW-VP-VST-41-TQ4 R036 j 11 TEHAX| \____ ____ ______ L i i | 00H-VP-VST-41-T04 R026 | aft 1i i |lM -69-2B | DOH-VP-VST-41-TC04 DOW-VP-VST-41-TC04 R036 THX/C11AR| | i a1 t1 1i |lM-69-3A DOW-VP-VST-41-T06 TENAX| t | a V |184-69-3B | V1 (194-69-4A | DOW-VP-VST-41-T06 DOW-VP-VST-41-TC06 DOH-VP-VST-41-TC06 DOW-VP-VST-41-TFB1 DOW-VP-VST-41-TPB1 R026 R026 R026 *1j TNX/CHAR| j - 1 1|TENAX j 11____ .! / i i i _________ i_________ i / i*--, i (.* l_-_-_-_-__-_-_-_-------l------------------------------------------------- 1-------- v |184-69-4B DOH-VP-VST-41-TCFB1 TNX/CKAR| {i----- rM | DOW-VP-VST-41-TCFB1 R026 j j v1 1! 1 i-----------------------------------------------------------------1---------- i 1r i i i1 it i I I i i iNft i11 i11 1it i11 i11 1 1 1111 I 1 111I ;l H 11111 ------------------------1------------ i i i i ii )1 i 1a 1ii ii1 1ii ii1 tt1 t1 ti ai 1 1 11 11 iI 1fftt 1 1i 1 t 1ti I 1i f1i i i------------------------1------------------------- ,------------ --------- I f . .tiiil i i i 1------------------------ iiii Ii i ii 1i--------------i -------- 1i O<N' -<z1 IN ^ < C Cc - :ONFTDFNT 8 Receiving Remarks: FAST TAT VOST. OTHER VOST'K ARE IH PROJ. 41197. | Archive Remarks: Form Revised 05/27/1997 - Page 1 OF 1= < '< ' Triangle Laboratories, Inc. Run Log DO A 0 4 8 7 3 0 OONFTDFNTTAt Column Type wl- ...... Column # Analysis* MW Acquisition Metliod OC Melltod* Find DDs* farO Ollier* Standards Interna^l /DBurrogale / Recovery Internal / Surrogate / Recovery \f5(T r 3ale" Time** Project m Sample# 4, ID.6** Cllenl ID y&fA <6F& lI8M0-& r/rc Analyte __/ Clrcl* uni----_ ict / Samgje volume al--i*- <d"L} Filename tfr-^n kvhi /Tte Blontluit pir Operator/Dale [iHMilinSHi Commems*** (1(4 Hk XuU ok m m p .ha*__ ______________ m >'A\ ft-.it. i;-li b'4 III vosTh/iz- nk fi-mx 0ttp $ ~jovJ 7 fcxA. dOt-4 i M/cr-irfUn yQS'fbO./o t/tc M5Tbo.it) ihc 'losiba.zoiffc. H-rfM tvto.. tfffio joJ, / E ! ''{ostN.od r/n Hli3f flic itftei di fifa ($3 Wii ! f(U iHt? Ma#- V * Volatile Dala Only BRvnnvawronM9innuNioo.DOC (tnwi) Transcribed Dala Deled Blgimlme/lnlllals Requited L. rrouM llh (jlti XCMSt. Ml Xml ft- ........ OH fOtA-________________ - tt xauT.________________ A _Page, f A DO A 0 4 8 7 3 1 C0NFTDFNTTA1 Triangle La-^-iloiles, Inc. Run Log O' Column Type Column # Analysis* Standards Internal f Surroaale t Recovery internal / Surrogate / Recovery Acquisition Method VJ Analyte OC Method* _____ Find DBs* Extract / Sample volume IfynwAy Ollter* CbctaunN pL mL DBle** Tlme" Project M* /ill VV?8(> |7</7 Sample# Client ID ~r IMSVM XpsJ'V^X^-Jsx r TW*W-l6F-2> 7cJ v= T Ki-fi-m b#w-v/' V(iT'TT Filename /fr6d3 nn*i nTOo^ pH* Opetalor/Dale Backup* Proll Communis*** AZ t*(<i i <U **Ot**, " **>&C .Li iA 4-A- /el,fa }A IZlfe i/ssr-/** -J Wf- ? Z<^ rrrC iffboU !l/ M/f, u. / U'50 v/ J, cs i)4D r/rc i i 3-<iJ j-jf? -rst-q r>o /oh pW*t CSTss VniotfL -A/ c nr /Qt Un U CPJ orsy `OVIMVH o-io I'ot^Vn oVb trxp/s Itftlvi V'itjfcAyo.2*=i'\ Six. VYe^9S\\C V\t_ In Vl\<cAQ> U (4 aWt s & (oS'iSm C.P> OJ?:* 7 /O-.lO * Volallle Dale Only 9nvnrvKWVonM94.nflUHioa.ooc (tavtri Vtot \ ~T s i X/ 1 1 Transcribed Data VrrUv tft < ouln -Vn bsi_ eft uwAn Dated Blgnalui e/lnltlals Required L(^ Page. ^ l*r -V,?r^ DO A 0 4 8 7 3 ? CO NFIDENTIAL Triangle Laboratories, Inc. Run Log Column Typo Column # Analysis* Acqtilslllon Method OC Melliod* Find DBs* Other* ^Q"t Ho*t(o 0<i 0 ^vrtc_________ internal / 8utrooBle / Recovery 161-> t,Xvo -J&y. jtei........ Standards Internal / Surrogate / Recovery Jale** Time** Project Vt ia-^> H'Wtn 1 T \Y15 4Wn Sample# Client ID ^\L W*v TO 4fo 'bw-uP-tfaft ''"U-TtFfcl VW'lf-OWTVS- t't-Hfo tiooi- TIC. \T\n HWVT ttv'Ks-Hft ~ \T-MH tfi'W MTfcVt 4t>W\ ' ttr-To^n l>0j'viP IfVM-Mft H IVL*'T t b\ *T UT "T 1fcl T -T T fo t Analyte Filename Pll* Vn bil? \V\ b\n Ynfavs V\Tt\V. vn bn vn b\*a Extract / Sample volume CbdtunN |iL mL vAi tofy, /o\ 1 Vsi Signature Data Operalor/Date mm Proo Comments*** (0 Malm U /oIlHt Um t\<n ffc MiVt ( o /okWf to Cl} H'Wl'o CG CB la. W onaiM ,_____________________ ___________ to c&_ Hr?'VJn tftM- 'T''2ifc VfcVTp-US i-v P- v - tl 'TCoi He VM (ol`\ \Wb2o l b KiUtal to foUWl PVHT 1 !_ Y^O 'Ub IfrV ^O 'Tft Lj - \iP' v.-vi - `U-Hfe'-T VO HA T Ic. \vitav 1 -------- r--J Uh-|o W fatim-ue-xr'pV MTTt0Vi \A T Wi tft /oVlVsT (0 lohU') * Volatile Dale Only snvnn\aA\FonMs\LnnuHLoa.Doc (inq Transcribed Data Deled SlgnBlme/lnilinls neriiilred Xa_ ] w 1 Oi 1 CB Poe___ $ . m or ij w Triangle Laboratories, Inc. Run Log DO A 0 4 8 7 3 3 C O N F ID E N T IA L . Column Type Column # Analysts* Acquisition Method OC Method* Find DBs* Other* 'bSn 4oAa VSVi ft bt)TC Standards <In?tenrn-ailt/ivSu'irrogate l Recovery Internal 1 Surrogate / Recovery 07f Analyte Extract / Sample volume GrywOi^w Ckcft imft pL mL Tate** Time** Project Sample# ft} Ak) 4'b`2>n iV-*H us'b'6n 1-*^- Client ID Filename pH* Operator/Dale Backup* Proo Comments*" ItU -VPV'aH- ^'TC-0 T) WTki3 C.fc IoItWi Cpi Me tvva-AlP-0*rr\' "TCOH VN'V b^ { n loUWl JJ ft.SO /k>7 mr w-n (W'7f>OA -^P-Vir-WJ fer{ocA. r IM -1-llh Daix/'VP'^f-U ')j irl-io-x* P*u/i/p r (<4*fh ll rfeio Xl trftfa -- XA folifi') U U u nino. & Iff Mi XX uhrlj) T~ -VT' HMt-rci nripV\ AJ~ /<tf* ? r Hii 4m 7 ift-lo-OA ptfw-t'P'^r-'fiTpy tt a 30 U' f*hh} \ 1*141; V5jci7 r Hrt,}1 . 4/ /*AYf> to l*n u u gff/t u CC. fuoA -/Ji> tM `lAV flCC^ l***tA- 4ttAti4. / ' * Volatile DbIb Only 8nvninoxvonM94.nRUHLOo.tioc ftnq Transcribed Data Dated Slgnaliire/lnltlals Required Page CONFTDFNTTAL Triangle Laboratories, Iiic. Run Log Column Type Column # Analysis* Acquisition Method QC Method* Find DBS* Other* r- CM b3~\ M 2 tCi VtiO'b 'b\T\0 Standards internal t Surrogate / Recovery Internal f Surroflale / Recovery _ Analyte Extract / Sample volume ^rfl C^> Clrcteunft lL mL $/.$/} ,~2 Me" Time" Prolect lo/ %k OHlt \2tn Sample# i u'*, sttrtlSt-H iw-r rd , I'W't nt y l E3S-------------- Client ID foT^. VicscAtto r=$ V "iV'st- Filename Skmatura Data ptl* Operator/Date Backup1 Proo Comments*** ta^l. ^ 'o'b?) Vn hit-shT a*. fcrct*A^r*> to 'tf-nyoi to^V CA t^Zl *S/>**&> va C v. ta*\->lci 1 O p|C 1, t/MrbilZ r/TC ffT63G fsU Hih jU Jffi8 * t (_J if-rOM f\?t njfa 7 mi vswi*-* *TCf f_A Vri-in-3 Ayif *rJn K) b A fb $8 U- i&h -- ya^rbo io rtrcs U-rG^ r 9Qo2 * JO'V l .h si \bty<iO Jffi h{i&2 xIumoo^o rIR iih^i itst fy/,/n \J~ /4/b Volatile Oala Only SRVnH\GMOnMS\LflRUHlOO.DOC (UlinO Transcribed Data Dated Signal! ite/lnlllnls Re(|(ilred 1,/ u u M fotn- t3o*.l fa t- *>_______________________ oo rs cc c <E ac .W V..;` Triangle Laboratories, Inc. Run Log 00 A 04873B C O N F ID E N T IA L . Column Type Column # Analysis* Acquisition Method 1/6(4 OC Method* l/drf-3 Find DBs* 3 6ns Other* Standards internal / Surrogate f Recovery Internal / Surrogate f Recovery Analyte Extract / Sample volume ChctaunN fiL mL 3ate** Time** Projecl loW^, pi;ot tea. Sample# Client ID -,*zv -- Filename --W+T' t-firc*ufnf<k'ri \Zo$tboisr Hrc iItU 2- nalur* 'VaA"? pH* OperalodDale Brfckup* Proc Comments*** XI i4k) A< . ft/*) JfrJ ^__________________ "tin. ?.*o7 -7- >2 f/t.fU-IW. -* * jr--f Tl 9 r-- fti\ 1/ p loJJ, ^ , UViJyt-iis-T jUJ- M, JA'\ 1`ar/-r.pfil/l4flUfti1'l SfKfr, A r(#M3 1fasTbott Tire P. i/o)ro/.j6 T/rc Urmu vWfcikLrn]: tVrfaMT ioui r |0o3 r ll'.tl L> ll<i Nf >/ l \i tf 1~ w ivr^"o Has f JJ- f<>hh\ JU. Jj. withy L/ wiikr XI ^Iifn 4c/ /tf/vA't 1/ Mn 1/ /ofa hi V .A FC*t( /T 4*A*iW7 4dL K tCkl P-t-________________ AJ0d Ia* *tO 4 TUvc. P*4 Wifi') Ll V fad fat*. * Volatile Data Only 9RvnnKtFonM\LnnuM.ooDoc (i/ivsn Transcribed Data Dated Slgnalnre/lnltlals Required Page. i i I 1 Column Type Column # ^2.7 Triangle Laboratories, Inc. Run Log Analysis* Acquisition Melhod (/<3* GC Method* i/bn> Find DBs* IfT&d A Standards Internal / Surrogate / Recovery Internal / Surrogate t Recovery t m JT~ ^1 *** /$/jtf- <? ^ Analyte Extract / Sample volume Ollier* Chela unN l*L mL Hale'* Time** Protect Sample# Client ID \%$e> I'A-'h-Hb mvnh- . vo &)**> (r~irirWi. -rco i tic n.0> Filename H rU& Kill Operator/Dale Backup' Proc Comments*** Awi rt*oA** /kt/,*- -*u<te X/, U XX /chin XX * wA IMQ'llA DwJ'ie-frT-t/3-rloi ut&r/ lohM) iJ ftp ivift lif-foM , fa bHMsrXvratf Hr /'$/> /S-, % Hr$(p / (jU ///; $ -r/i &,& -f+--4 iWw-vsr-^-yar Y-- PkA 'M, i1 ^9 |5'31 lii-tifi bi^T-tWel jfn?5X rjU W/ a ' / fif 7 s' 7 X %?>W T1 z_ ' XX KlttSl X r/ifo 0k sX /N \ f / V......... X l_____ \ Volatile Dale Only snvmwwvonM94.nnuHLoa.Doo (wwt| Transcribed Data Dated 8lgnature/lnlllnl9 Required -- - ,(i , / rpd }V Project Number 43396 Sample File: HT537 Method 8260 VOST Sample ID: DOW-VP-VST-41-T02^~ Pencafluorobenzene 1,4-Difluorobenzene 1,1 ,2-Trichioroethane Chlorobenzenc-d^ Chlorobenzene 1,4- Dichlorobenzene-d^ Dibromofluoromethane Toluene-d IS 1 5-14 IS 2 5.89 U IS 3 10.15 U IS 4 15.52 0.258 0.254 5.01 7.80 0.001 0.001 1 2 0.05 0.05 103 102. i Reviewed by__ -TK) PreJLcfe/17 NA- Not Applicable; Del Limit; Detection Limit; Quan. Limit Quantitation Limit L IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitatioa Limit Estimated* Above Calibration Range Triangle Laboratories of RTF, Inc 801 Capitola Drive Durham. North Cardins 27713 Phone: (919) S44-5729 Fax: (919) 544-5491 Sitvar v3-5 Printed; 1152 /X/1997 DO A 048737 OONFTDFNTT AL un A 048738 00NFT0FNTTA1 09-27-97 15:56 Triangle Laboratories of RTP, Inc. ID CJ (919) 544-5729 r c> r jo (0 6> O' 0 Q) aa QUAN DB : HT537 lo. MAT FOR REV Delta 1 100 81 99 2 100 94 96 3 100 95 97 4 100 62 99 5 100 96 99 6 100 93 99 T 100 89 93 8000 9000 10 0 0 0 2 0 1 2 0 0 0 0 0 0 LAB-BASE QUAN Area P.Flags RT 2060408 bb 2399700 bv 2186564 bv 1227060 bv 1018100 bb 3192408 bv 1463696 bv 0 0 0 - 5.14 5.89 10.15 15.52 5.01 7.80 12.48 0.00 0.00 0.00 09-27-97 16:34 QM f168 Pentaf1uorobenzene 114 1.4- 0if1uorobenzene 117 Chlorobenzene-d5 \ 152 1.4- Dichlorobenzene~d4 113 Dibromof1uoromethane 98 Toluene-dS 95 4-Bromof1uorobenzene 63 1.2- Dichloropropane 97 1.1.2- Trichloroethane 112 Chlorobenzene i Data Review: Date: ^ - 3 0 ,, c^-7 DO A 048739 CONFTDFNTT Al 23 Project Number 43396 "ample File: HT534 Method 8260 VOST Sample ID: DOW-VP-VST-41-TC02 TC Chlorobenzene-d^ Chlorobenzene 1,4-Dichlorobenzene-d Sttrrogate-Stti^^ t -ii1 *':v.-!K':'ri"i;.-?? 'if. Dibrotnofiuoromechane Toluene-d IS 3 U IS 4 0-266 0-2.5 5 10.14 15.49 0.001 Spp3|^S^3ip v..""55' .*^'*^.. . s **' ...... i* - h': ,vv > 5-01 7.79 0.05 106 102 Reviewed by__ "T?jQ Dve_3j3Qj!X2 NA- Not Applicable; Dot Limit Detection Limit; Quart. Limit; Quantitation Limit IS: Internal Standard; U; Undetected; B: Present fc Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range Triangle Laboratories of KIT, Inc 801 Capitnla Drive Durham. North Carolina 27713 Phone: (919) 5443729 * Fax: (919) 544-5491 Savarv33 Printed: 1132 09/30/1997 27 DO A 0 4 0 7 4 1 CONFTDFNTTAL I^ O') Cvl 09-27-97 14:16 Triangle laboratories of KTP, Inc Sample: DOU-VP-UST-41-TC02 T/C 104-69-IB TL11143396 HT534 100 7.80 5.89 5.?4 b 10>14 f9 12,47 XFS 5. H. 15,v50 (919) 544-5729 Instrument H 1148987 TIC #1 q Or1 ro a> i D 5 BB DD 0 Mi n 4.0 6.0 8.0 12.0 14.0 J 16.0 18.0 T'>" i 1 " ri t 20.0 -r,v QUAN OB r HT534 o. MAT FOR REV Delta 1 100 83 99 100 94 96 100 95 97 4 100 74 99 5 100 97 99 6 100 93 99 7 100 38 93 s000 9000 10 0 0 0 2 0 0 0 0 -1 -1 0 0 0 LAB-BASE QUAN Area P.Flags RT 1955744 bb 2303812 bb 2106340 bv 1225264 bv 993228 bv 3075132 bv 1404064 bv 0 0 0 . 5.14 5.89 10.14 15.49 5.01 7.79 12.47 0.00 0.00 0.00 09-27-97 14:5. QM Name 168 Pentaf1uorobenzene 114 1,4-Difluorobenzene 117 Chlorobenzene-d5 152 l,4-0ichlorobenzene-d4 113 Dibromof1uoromethane 98 Toluene-d8 95 4-Bromofluorobenzene 63 1,2-Dichloropropane 97 1.1.2-Trichloroethane 112 Chlorobenzene Data Review: TLO Date: ^-3a-^ DO A 04874? CONFTDFNTIAl Project Number 43396 Sample File: HT538 Method 8260 VOST Sample ID: DOW-VF-VST-41-T04 S- Pentafluorobenzene 1,4-Difluorobenzene 1,1,2-Tridlloroethane Chlorobenzene-d} Chlorobenzene 1,4-Dichlorobenzene-d^ Toluene-d IS 1 5.13 IS 2 5.88 U IS 3 10.15 U IS 4 15.53 0.001 0.001 0.05 0.05 Reviewed by___ "TLO Date 1301^1 NA- Not Applicable; D*t Limit Detection Limit Quin. Limit Quantitation Limit ( IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E; Estimated' Above Calibration Range ^ Triangle Laboratories of RTP, Inc SOI Capitola Drive Durham, North Cantina 27713 Phone: <919) 544-5729 Fax: (919) 544-5491 Savarv33 Printed: 1152 09/30/1997 00 A 048740 OONFIDFNTTAl. I 09-27-97 16:32 Triangle laboratories of PTP, Inc, Sample: DOW-UF-UST-41-T04 T 104-69 2ft TL1IH3396 ____ f*' 05 (919) 544-5729 Instrument H 1309995 TIC ft! ^_ <i fS I-! CC I^Z C ti. c <1 M Ll C2 CC 15 '53 12.79 14.99 13 188 16.50 iA, f\ . lU Aft -i A 11 ' w w\j V - v,< UF.-/. ,-T 14.0 16.0 18.0 ,iit i * vr 20.0 GUAM DB : HT53S 0. MAT FOR REV Delta 1 100 SO 99 2 100 94 96 3 100 95 97 4 98 61 97 5 100 98 99 6 100 93 99 7 100 89 93 8000 9000 10 0 0 0 1 0 .2 3 0 2 2 0 0 0 LAB-BASE QUAN Area P.Flags RT 2259648 bb 2591768 bv 2309392 bv 1226488 bv 1058428 bb 3424612 bv 1513548 bv 0 0 0 5.13 5.83 10.15 15.53 5.00 7.80 12.48 0.00 0.00 0.00 09-27-97 17:16 QM Name 168 Pe ntaf1uo robenzene 114 1,4-Oif luorobenzene 117 Chlorobenzene-d5 152 1,4-Dichlorobenzene-d4 113 Dibromof1uoromethane 98 Toluene-d8 95 4-Bromof1uorobenzene 63 1,2-Dichloropropane 97 1,1,2-Trichloroethane 112 Chlorobenzene Data RsviewffkO Date: ^ - 30 _ DO A 048745 CONFTDFNTIAI. 31 Project Number 43396 cample File: HT535 Methpd 8260 VOST Sample ID: DOW-VP-VST-41-TC04 TC Reviewed by'TIjl'S /Date l3O CT7 NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated* Below Quantitation Limit; E: Estimated- Above Calibration Range Triangle Laboratories of RTP, Inc 801 Capitoia Drive Durham, North Carolina 27713 Phone:(919)544-5729 Fax:(919)5*4-5491 Savar v3i Printed: 1152 09/30/1997 32 DO A 04R746 CONFIDENTIAL I^ % , , CO CO 00 A 048747 OONFTOFNTT Al 09-27-97 14^47 Triangle laboratories of RTP, Inc, Sanpl : DOU-MP-UST-41 TC04 T/C 104 69-2B Tl, 11143396 (919) 544-5729 Instrument H 1120680 TIC #1 15,49 jkMk.14.96 16.44 A7*27 14.0 16.0 18.0 20.0 F=? .. o !? S> O'* o; P aj 88 QUAN DB : HTS35 3 . MAT FOR REV Delta 1 100 83 99 9 100 94 96 100 95 97 4 99 61 97 5 100 98 99 6 100 93 98 7 100 89 93 3000 9000 10 0 0 0 1 0 1 0 1 1 1 0 0 0 LAB-BASE QUAN Area P.Flags RT 1983580 bb 2260S20 bb 2051300 bv 1200016 bv 972964 bb 3012400 bv 1376664 bv 0 0 0 . 5.13 5.88 10.14 15.49 5.01 7.79 12.47 0.00 0.00 0.00 09-27-97 QM Name 15:22 168 Pentaf1uorobenzene 114 1,4-Dif1uorobenzene 117 Ohiorobenzene-d5 152 1,4-Oichlorobenzene~d4 113 Dibromof1uoromethane 98 Toluene-d8 95 4-Bromof1uorobenzene 63 1.2-0ichloropropane 97 1,1,2-T richloroethane 112 Chlorobenzene Data ReviewniO Date: ^-30^-7 DO A 048748 CONFTDFNTT Al Project Number: 43396 Sample FUe: HT539 Method 8260 VOST Sample ID: DOW-VP-VST-41-T06 T. Pentafluorobenzene 1.4-Difluorobenzene 1,1,2-Trichloroechane Chlorobenzene-d^ Chlorobenzene 1.4-Dichlorobenzene-d4 Dibromofluoromedianee Toluene-d 10.14 IS 4 15-50 0.05 0.05 0-255 0.257. 5.00 7.79 1 2 102 103 i Reviewed by. 72a) .._ Date *? /30/?7. NA- Not Applicable; Dct Limit Detection Limit; Qoan. Limit Quantitation Limit IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated* Below Quantitation Limit Estimated* Above Calibration Range Triangle Laboratories of RTP, Inc. 301 Capitola Drive * Durham, North Carolina 27713 Phone: (919) 544-5729 Fax: (919) 544-5491 Savar v3-5 Printed: 11:52 09/30/1997 DO A 048749 OONFTDFNTTA1 35 CO CO 09-27-97 17:13 Triangle Laboratories of RTF, Inc. (919) B44-5729 DO A 0 4 8 7 5 0 CONFTDFNTTAl cr* o a> OQ QUAN DB : HT539 No. MAT FOR REV Delta 1 100 80 99 2 100 94 96 3 100 95 97 4 98 61 97 5 100 97 99 6 100 93 99 7 100 89 94 s000 9000 10 0 0 0 1 0 1 1 0 1 1 0 0 0 LAB-BASE OUAN Area P.Flags RT 2051192 bb 2377828 bv 2133808 bv 1204036 bv 1000476 bv 3200244 bv 1450780 bv 0 0 0 5.13 5.88 10.14 15.50 5.00 7.79 12.47 0.00 0.00 0.00 09-27-97 17:47 QM Name 163 Pentaf1uorobenzene 114 1,4-Oifluorobenzene 117 Chlorobenzene-dS 152 1,4-Dichlorobenzene-o4 113 Dibromofluoromethane 98 Toluene-dS 95 4-Bromof1uorobenzene 63 1,2-Dichloropropane 97 1,1,2-Trichloroethane 112 Chlorobenzene { Data Review: Date: ?-3o DO A 04S7S1 CONFTDrNT T Al 3 Project Number 43396 unple File: HT536 Pencafluorobenzene 1.4- Difluorobenzene 1,1 ,2-Trichlotoethane Chlorobenzene-d Chlorobenzene 1.4- Dichlorobenzene-d ^oluene-d Method 8260 VOST Sample ID: DOW-VP-VST-41-TC06 TC 1 104 2 102 Reviewed by"V L<0___________________ Dace ^ l30 / NA- Not Applicable; Det Limit: Detection Limit; Qua. Limit Quantitation Limit IS: Internal Standard; U; Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range Triangle Laboratories of RTP, Inc 801 Capitola Drive * Durham, North Carolina 27713 Phone: <919) 544-5729 * Fax: (91?) 544-5491 Saw v3-5 Printed; 11=52 09/30/1997 DO A 04B7S? CONFTOFNTTAL 33 09-27-97 15^21 CO CO Triangle Laboratories of RTP, Inc. (919) 544-S729 i i 00 A 048753 OONFTDFNTTAl QUAN OB : HT536 lo. MAT FOR REV Delta 1 100 83 99 100 94 96 > 100 95 97 4 98 60 98 5 100 98 99 6 100 93 98 7 100 88 93 8000 9000 10 0 0 0 1 1 1 1 1 0 -1 0 0 0 LAB-BASE QUAN Area P-Flags RT 2024004 bb 2349120 bv 2118512 bv 1228132 bv 1009084 bb 3131484 bv 1433208 bv 0 0 0 5.13 5.89 10.15 15.51 5.01 7.80 12-47 0.00 0.00 0.00 09-27-97 IS: 5 QM Name 163 Pentaf1uorobenzene 114 1,4-Dif1uorobenzene 117 Chlorobenzene-05 152 1,4-0ichlorobenzene-d4 113 Dibromofluoromethane 98 Toluene-d8 95 4-Bromof1uorobenzene 63 1.2-Dichloropropane 97 1,1,2-Trichloroethane 112 Chlorobenzene DotaRsviewr^ Date: l- 3o _ A 048754 CONFrDFNTTAL