Document ppd1XONRY1LJ8X3vm41gQEJxB
BUSINESS CONFIDENTIAL
Preliminary Information Sub|oct to Iator verification
or revision
JNFORMAL REPORT Project No.: 347K10
Data: August 21, 1967
Autfioi(>): Jt
Fields
VINYL RESINS GENERAL, METAL CONTENT OF SELECTED RESINS
Samples of suspension poly(vinyl chloride) resins from Pechiney-St. Gobain (Lucovyl GB-1210) and of the Leavyn fiber ^reportedly made from crystalline poly(vinyl chloride)} both contain an unexpectedly high percentage of iron, aluminum, silicon and magnesium compared to the QYTQ-7 resin. The Pechiney-St. Gobain resin was found to be unsuitable in an earlier critical wire evaluation at Bound Brook. The samples evaluated include the following:
(a) QYTQ-1, Blend 193, a UCC PVC homopolymer produced in production autoclaves at Texas City by the suspension process.
(b) Lucovyl GB-1210, a PVC homopolymer produced by PechineySt. Gobain of France by a new bulk process.
(c) Leavyn fiber, produced in Italy reportedly from PVC homopolymer; sample was obtained from American Viscose.
Mr. H. J. Pazinski of the Bound Brook Laboratory has reported the Pechiney-St. Gobain resin to be unsuitable for critical electrical applications due to the low volume resistivity (letter dated April 7, 1966). The unfavorable electrical proper ties may be due in part to the high content of iron, aluminum, silicon and magnesium present in the resin. The metals analyses were obtained using emission spectroscopy at the South Charleston Plant Laboratory.
The high tin content of the Leavyn fiber may be due to the presence of a stabilizer used in fiber manufacture.
s Attachment: Table I
- l(J. FltlcL;'/
Distribution
Supervisor: Dr. J. J. Brezinski
Assistant Director: Dr. F. E. Bailey, Director: Mr. J. J. Smith Mr. W. H. Bauer, TNY Dr. G. M. Bryant, 511 Mr. A. J. Costantin, 312 Mr. N. A. Gimber, 515 Mr. G. G. Himmler, 312 Mr. J. L. Hockersmith, 515
Jr.
Mr. H. J. Pazinski, 312 Mr. D. E. Richardson, 515 Mr. T. R. Smith, 515 Mr. A. T. Walter, Mr. R. N. Wheeler
Librarian, TNY Information Retrieval Author (2)
Research and D velopmoat Department
Chemicals and Plastics
Union Carbide Corporation
UCC 070163
BUSINESS CONFIDENTIAL 347K10
TABLE I
METAL ANALYSIS, PPM
QYTQ-7 Blend-193
Pechiney-St. Gobain GB-1210
Leavyn Fiber
Iron
2 30
10
Chromium
2 <1
<1
Nickle
<1 3
<1
Aluminum
2 27
Too strong *
to r ad
Copper
<1 <1
5
Tin
<1 <1
20
Lead
<1 <1
<1
Silicon
1
Too strong *
Too strong *
to read
to read
Magnesium
<1
Too strong *
Too strong *
to read
to read
Samples were analyzed for metals content using emission spectroscopy at the South Charleston Plant Laboratory.
* Estimated at >100 ppm.
ucc
070164