Document ppXdXM8DKGXd6OGERGRydgvba

INDUSTRIES PPG INDUSTRIES, INC./ONE GATEWAY CENTER/PITTSBURGH, PENNSYLVANIA 15222/AREA 412/434-2841 June 7, 1983 CERTIFIED MAIL RETURN RECEIPT REQUESTED RICHARD J. SAMELSON, Manager Environmental Program* Industrial Chemical Division Administrator U.S. Environmental Region VI 1201 Elm Street Dallas, TX 75270 Protection Agency Attention: Mr. Ed McHam Re: NPDES Renewa. ,,_!.53 Gentlemen: Enclosed is a revised permit application Form 2C (non-analytical data portion) to replace that originally submitted March 27, 1981. This revision incorporates the changes brought-about by the modernization of Plant A diaphgram cell facilities (scheduled for start-up in June 1983) which were discussed under IV-B in the 1981 application. Item IV-B has been updated to reflect current planned projects. Three surface runoff discharge points not previously recognized have been added to the application. Also, a generarV updating of the water balance and associated sketches have been made, and an enlarged, improved Outfall map (Figure 1) is included. Please note that certain pages concerning our wate** balance have been labeled confidential. These have been enclosed in a separate envelope. These pagescontain information about our processes that is proprietary, not disciosedvto parties outside the company, and would be detrimental to our competitive position if disclosed. We therefore request confidential treatment of this information. SL 049351 INDUSTRIES PPG INDUSTRIES, INC./ONE GATEWAY CENTER/PITTSBURGH, PENNSYLVANIA 15222/AREA 412/434-2841 June 7, 1983 CERTIFIED MAIL RETURN RECEIPT REQUESTED RICHARD J. SAMELSON, Manager Environmental Program* Industrial Chemical Division Administrator U.S. Environmental Protection Agency Region VI 1201 Elm Street Dallas, TX 75270 Attention: Mr. Ed McHam Re: NPDES Permit No.( LAD008086506 Renewal Appl icationT--fl^-6-rr.^ 0 122.53 Gentlemen: Enclosed is a revised permit application Form 2C (non-analytical data portion) to replace that originally submitted March 27, 1981. This revision incorporates the changes brought about by the modernization of Plant A diaphgram cell facilities (scheduled for start-up in June 1983) which were discussed under IV-B in the 1981 application. Item IV-B has been updated to reflect current planned proj'ects. Three surface runoff discharge points not previously recognized have been added to the application. Also, a general updating of the water balance and associated sketches have been made, and an enlarged, improved Outfall map (Figure 1) is included. Please note that certain pages concerning our wate** balance have been labeled confidential. These have been enclosed in a separate envelope. These pages contain information about our processes that is proprietary, not disclosed to parties outside the company, and would be detrimental to our competitive position if disclosed. We therefore request confidential treatment of this information. SL 049352 Administrator June 7, 1983 Page Two If you have questions concerning this document, please call Mr. James E. tyyche III, Coordinator of Environmental Systems, at Lake Charles. His telephone number is (318) 491-4830. Very truly yours, "20.j&j&Ls R. J. Samel son RJS:sdh Enclosure cc: J. Dale Givens, Administrator LA Department of Natural Resources SL 049353 SL 049354 Please print or type in the unshaded areas only Iepa I.D. Numbe (copy from item J of Form i) 1 /r& LAD008086506 1 Revised s/dBJ Farm Approved OMB No. 158-R0173 ?Srm U.S. [NVIRONHENTAU PRO , AGENCY 2C EPA NPDES I. OUTFALL LOCATION APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program TOR?* `A -- sn- 'i-w ii i?<t i'h --mu. -U.1L.jf^^ijri~^ For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. aTOTYTXCC^ number (lutl B. LATITUDE i. o. L MIR. >. tc. C. LONGITUDE t. ota. 1. MIR, 1. *c. d. receiving water (name) 001 30 12 34 93 17 36 Bayou D'lnde (see Figure 1) - A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing waitewim to the effiuer and treatment unit* labeled to correspond to the more detailed description* in Item B. Construct a water balance on the line drawing by showing avers flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined fog, for efftain miningaetfvttmJ, provide pictorial description of the nature and amount of any sources of water and any collection or treatment measures, (see Figures Z through 0 B. For each outfall, provide a description qf: j1) All operations contributing wastewater to the effluent, including PrqCTff TfrytytfftRfWlltMy wwesttwst cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment receivaed bI y the wenasweer. Contin on additional sheets if ne FfA. LOLUNTO* fli*V z. operation!*) contributing plow e. OPERATION nut) b. AVERAGE PLOW (include unite) r^-------------------------3-*-T--R-E_A-T--M--E-N--T-----S* DCtCItIPTlON b. UITTABCLOEDE2SC*1FF 001 Plants "A", "B", "C", Silicas, and Powerhouses A, B, and C (see Table 1). This outfall is the combined discharge of effiuer ts from the facility to Bayou D'lnde "hr By category: 1) once-through cooling water 2) process wastewater 178,191 9Pm - fi',989 9*Pm 1) once-through cooling water' No treatment. 2) process wastewater 4-A 2-K Treatment of individual process 4-A streams entering Outfall 001 are described in detail under their respective outfalls. r",/,"'---- 1 Treatment of the combined f '' - process wastewater discharge . ; into Outfall 001 consists of pH adjustment in the PPG ,* 3) cooling tower blowdown 354 gpm Canal (see Figure 91. 3) cooling tower blowdown AHk Treatment of these streams is described under their respective outfalls. *,' ,* r.'-M - .*.', ;^t~t~\:V .:-*,-^^^5ft'^5?5ATr-i1'2? --/-"'.v''---V.Y.. . 2C i npdes M' Rev isedtg/U.S. CNVIROMMflifX'L PKO . TION AStNCY 2/83 APPLICATION FOR PERMIT TO 0ISCHAF,- WASTEWA&TTCERD w W uw EXISTINcf;'^NUFACTURING, COMMERCIAL, MINING /'. D SILVICULTURAL OPERATIONS - Consolidated Permits Program i. OUTFALL LOCATION Vi.~. -,. - For each put(all. lut the latitude and longnuae of it location to the nearest IS seconds and the name o( the receiving water. a."SuTTXUu number nut) 9. LATITUDE 1* DBA. a, min, a. icc. C. L. NCITUDE 1. OKA, a. win. a. icc, O. RECEIVING WATER (name) - II. FLOWS, SOURCES OF POLLUTION, ANO TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operation* contributing wattawater to the effluen and treatment units labeled to correspond to the more detailed descriptions in Item 8. Construct a water balance on the line drawing b showing event flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined <.$., for certain mining activities), provide pictorial description of the nature and amount of any sources of water and any collection or treatment measures. S. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary svastewatc cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the waitewtar. Contim on additional sheets if necessary. t. OUT- FALLNO (lift) l. OPERATION IS) CONTRIBUTING FLOW 1. OPERATION (list) b. AVERAGE FLOW fmeiudt units) "~'T '' 3. TREATMENT a. description b. LIST COOES Fft TAIL! ac*1 001 4) sanitary wastewater 36 gpm 1) sanitary wastewater 3-C (see Figure 8) Treatment of the portion ( 15 1-U gpm) coming from Outfall 007 4-A is described under that outfall. > The portion (21 apm) discharaec ' directlv to the PPG Canal is treated by the Imhoff method of anaerobic digestion (see 5) other non-process effluents 230 gpm Fiaure 10). 5) other non-process effluents 5-L (blowdown from incoming water purification systenrs, and powerhouse, bo i 1 er b 1 ow- downs ) Except for the Sabine River 1-U ... water clarification svstem 4-A which is described in Figure 1 lf all other non-process streams Total discharge from PPG_______ >85,800 apm + storm runoff discharge to in-plant outfalls and treatment is described 6) effluent from neighboring industries (Certain-Teed 600 gpm + storm runoff under those outfalls. 6) off-site effluent No treatment by PPG. 4-A Products Corp., Jupiter Chemical Inc., and Liquid Air > Corp.) plus storm runoff from off-site property. Total to Outfall 001 186,400 gpm + st >rm runoff (see Figure 2) r-T m EPA Form 3510-2G 16-801 oflrr i /"% c a epa i.o, number (copy from Hum 1 of Form it Revised 5/2/83 Please print Of type in the unshaded areal only. LAD008086506 ________________ L Form Approved OUB No. 159-ft0173 U.a. ENVIRONMENTAL. PROTECTION AGENCY , ,, APPLICATION FOB PERMIT TO DISCHARGE WASTEWATER ' EXISTING MANUFACTURING; COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program I. OUTFALL LOCATION For MCh outfill, llt the latitude and longitude of 111 location to tho nearest 15 seconds and tho name of tho rocolvinfl water. A, GUTfALL NUMBER cun B. LATITUDE 1. ON*. 1. MIN, 3. IBC, C. UONOITUOE 1. Dg, x. NMf D. RECEIVING WATER (mmt) 005 30 13 32 93 16 43 Bayou Verdine (01 In Ditch) [See Figurel] II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES ,, A. Attach * lino drawing allowing tho wator flow through tho facility* Indicate oourcot of intaka water, operation! contributing waotowotar go tho affluent, .and treatment unit* labeled to corratpond to tho more detailed dracrlptions in Item B. Construct a water belance on the line di owing by drawing average flow* botvwon Intakes, operations, treatment units, and outfalls. If a water balance cannot be determined (e.g., tor certain mining attMfmi, provide a ^.pictorial description of the nature and amount of any sources of water and any collection or treatment measures.. - B; For each outfall, provide a description oft jl) All operations contributing wastewater to the effluent. Including process wastewater, sewSXry iter. -V&goollng wator, and storm water runoff; (2) The average flow contributed by each operation; and (3)' "TThhoe treatment racebtrad by the waasewesan Continue j'S'bn additional sheets If i 3 .A*. 'irouTPAUi.NO nut) V;b. AVERAGE PLOW .... /Include unit*) v l DEacRiPTiors^lO^lSl^r^ be UT COM! wm r TABUS 2C-1 ft 005 1) once-through cooling wat.et 48 gpm and steam condensate + stnrm runnff 11 Nn treatment a_ a from -Diaphragm Dell i'hlny'y Alkali prnriurtinn (PlanM ... "A" ) _2) once-through coolino water from Powerhouse A and dock 350 q,pm 21 Nn treatment storaqe areas 3) treated sanitary waste ' ' I- 2 arm 5\ Sent,ic-tank' Mt . 3-C yatpr frnm plant "A11______ (see fiatire 8. 1 garage_________________ 4) ctOm pmnFf frnm Panstir and chlorinated storm runoff 4) No treatment 4-A hydrocarbon dock storaqe areas * Total to Outfall 005 400 qnm + storm runoff (see Figures 3, 4) 3Kfcv- * .*>*-..** - i.i EPA Form 3510.7C (- * * . r~ * ,r. r" , * 7 pleste ormt or tyoe in the unshaded arsis only I A0008086506 1Sa-RO!73 r,>FORM U.S. INVISONMINTAL AGENCY s. APPLICATION FOR PERMIT TO DU ;e WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS 2C' &epampdes Consolidated Permits Program j.u--..1) .. .j i .. OUTFALL For eeeh outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. a.NgUuMrBfEARLir (list/ a. latituds f. B|, 9. MIM. >. IKC. C. UONCITUOS 1. Pl. |. MIN. V. KffC. o. receiving water (name) 006 30 13 38 93 17 32 This is an internal effluent which discharaes into Outfall 018, thence to Outfall 001 and into Bayou D'lnde (see Fiaure 11. i1 i riies nwit A. Attach a line drawing showing the water flow through the facility, indicate sources of intake water, operations contributing wastewater to the efflu and treatment unin labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing eve flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined (t.g., for certain mining actMtietl, provii pictorial description of the nature and amount of any sources of water and any collection or treatment measures.(see Figures 2 through 8 B. For each outfall, provide a description of; (1) All operations contributing wastewater to the effluent, including pToQftCw^QPa<kr} Unitary wastew, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the westswater. Cont on additional sheets if necessary. 1. OUT- fALfiuLNi) O Z. OPERATION)*) CONTRIBUTING FLOW e. OPERATION (list) b. AVERAGE FLOW ' (includ* unitt) -- 3. TRCATMKNT ---------------- b. LIST COOES f 1. DESCRIPTION TAtLC 2C-1 006 11 process wastewater from Si lice 2,000 com 11 sand filters remove the solids 1_-_R manufacturing process * from this effluent and return them to the process. Sire; 4 filters in parallel. 5.2 MM gpd* capacity 1. * Flow rate: 4.3 MM gpd* Retention: 30 minutes 2) wastewater from wet scrubbers used to control particulate emissions from Silicas plant 115 gpm 2) Solids are separated from the effluent in a 15,000 gallon settling basin. Flow rate is 1-U 0.16 MM gpd* and retention is 6 hours. These non-hazardou: solids are periodically removed 3) process wastewater from milling, drying, and packing of Silica products Total to Outfall 006 and disposed of off-site. recycle to proceS ; 3) solids are separated from this 1-U water in a 15,000 gallon 4-C settling basin. Flowrate is 0.29 MM gpd* and retention is 2 hours. These non-hazardot s settled solids are periodically 2,115 gpm removed and disposed of off- site. Th water is returned to th process. (se Figure 7) *MMgpd = million gallons per da f FPA tnm ssio-pr m-nm SL 049358 ie orint.or tvoe in the unshaded mil only. ('_ LA0008086506{ )C. Farm /^pproye^8)tiSj6tiwi.5/^2/83 ORM ZC EPA JES UTFALL LOCATION U.S. CNVieONMCNYAL PROTECTttstfS AGCNCV APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program -r~ A',.','J. "T""T -fJPWU*^ -or each outfall, list the latitude and longitude of its location to the nearest 15 seconds end tne name of the receiving water. " 6u'YT all" number /lot) a. tATiTuoe 1* SH. L UM- 1. ICC. C. LONGITUDE t. Oo. i, ue. O. receiving watch (name) II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT' A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the affluent, end treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined la.g., for certain mining activities/, provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, providt a description of: (if All operations contributing wastewater to the effluent, including process wastewater, sanitary westtweterT cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary. .t OUT* FALLNO nut) 2. OPERATION**) CONTRIBUTING FLOW a. OPERATION <liat) b. AVERAGE ALOW (include unitt> * --7F s, TREATMENT S. DESCRIPTION 3. CIST COOES PROS taki ac-i 006 Note: All streams discharged through Outfall 006 receive pH > adjustment downstream in the chemical neutralization system .. - described in Outfall 001. official use onlt (^/fluent guideline* #u6>cdrfon*#) 1i ! 1 !; . - V* ' CT n /. n o r- ,, v 1. - "a,* 1 Iepa i.D' NUMBER (copy from Jltm l of Form PieM^rintortyoeJnjhie^jrnhaded^rnton\y^^j^.'''-r LAD008086506 Revised 5-2-83 Form Approved OMB No. 158-ft0173 U.S. ENVIRONMENTAL PROTEO.r; N AOENCY &EFA APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER' EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program ^L IL-UWJJRL[.i I. OUTFALL LOCATION iu-if "7! For each outfall, liit the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A.N6UuMtPBSA*LL (list) B. LATITUDE f. PIT*. 1, MIN, i. ice. C. LONGITUDE 1* AlS. 1* MIN, i. ice. O. RECEIVING water (name) 007 30 13 34 93 17 32 This is an internal effluent discharging into Outfall 018. thence to Outfall 001 and Into Bayou D'lnde (see Figure 1). II. FLOWS, SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility* Indicate sources of intake water, operations contributing wastewater to the effiue and treatment units labeled to correspond to the more detailed descriptions in Item 8. Construct a water balance on the line drawing by showing avert flows between intakes, operations, treatment units, pictorial description of the nature and amount of any and outfalls. If sources of water a water and any balance cannot be determined le.^., collection or treatment measures. *oriwy.g1 rovidi 6. For each outfall, provide e description of: (1) All operations contributing wastewater to the effluent, including procleesss wastewater, sanitary wwaeetewat cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Contir on additional sheets if necessary. - t. OUT* fAnLLuNt) O Z. OPERATION'S) CONTRIBUTING FLOW a. OPERATION nt*t) b. AVERAGE FLOW (include units) 1. TREATMENT a. DESCRIPTION b. WIST CODES Ft table: zc-1 007 1) Plant "C" process wastewater 954 gpm 1) Process streams are treated including: + storm runoff individually as follows: (a) stripped chlorinated condensate (b) waste sulfuric acid (c) waste caustic (a) -(q) No treatment (except pH adjustment) (h) Brine treatment solids are used to neutralize waste hydro- 2-K (d) hvdroqen condensate (e) chlorine header seal water (f) emeraency chlorine neutralize r (q) brine purges 1 (h) brine treatment solids | (i) cell renewal wastewater chloric acid before discharge. Capacity of the system is 0.14 MM gpd*, flovv rate is 0.03 MM qpd*, and retention time is 3 hours. (i) Cell renewal wastewater is 1-U allowed to settle and pass throujth 1-R - a rapid sand bed to remove asbestos prior to discharge. The collected asbestos solids are periodically processed throuah the asbestos filter system in Plant "A" diaphragm cell area | *MM gpd = million gollons p r dc y official USE ONLY (effluent fmdshne* *vb-caitgon*t) (see Figure 14) and disposed of offsite in an authorized hazardou* . waste facility. Settling pond volume is 60.000 ft^. Flow rate ... is 0.02 MM gpd* and ret^'*^^ 24 hr*. w't:?Ot)U Pleaie print or tvo* in the unshaded areas only. LA D00dUb66U6 1S8-R0173 FORM 2C &EPA 'NPDES ________ /' U.S. tNVmONMtNTSL PROTECTKyU AGENCY APPLICATION FOR PERMIT TO DISCH/fc^SS WASTEWATER EXISTING MANUFACTURING, COMMERCIAL. MINING AhlD SILVICULTURAL OPERATIONS Consolidated Permits Program ......... "we. "!vine;; , ------------ 1 ....-------------- For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. XTbutrAiin" number (list) B. LATITUDE 1 . Dlt. 1. UIR. >. **c. C. LONGITUDE 1. DIG. 1. MIN. V ICC. o. receiving water (name) * II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility, Indicate sources of intake water, operations contributing vwitlwRy to the effluent and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing averagt flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined le.g,, for certain mining aetMdaa), provide i pictorial description of the nature end amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of: (1) AH operations contributing wastewater to the effluent, including process wastewater, sanitary wastewatei cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continu on additional sheets if necessary. 1. OUT- FALL NO (lilt) i. OPERATION)*) CONTRIBUTING FLOW a. OPERATION flirt; b. AVERAGE FLOW /include unite) j}. TREATMENT S. DESCRIPTION be LIST CODES FR( table ac-i 007 2) sanitary wastewater from 15 aom 2) sanitary wastewater is treated l-M Plant "C"/ Silica Products, (see Figure 8) in an extended aeration systen 5-A Tri-Ethane II, and VCM II described in Figure 12 2-F 1 3) other non-process wastewater 46 gpm 3) non-process wastewater is 2-K from Plant MC" including: see Figure 6) discharged to Outfall 007 (a) deionization unit regeneration discharge without treatment except for neutralization of the deion- (b) powerhouse boiler blowdown ization regeneration chemicals Total to Outfall 007 1Q15 gpm + storm runoff Note; All streams discharqed throuqh Outfall 007 receive pH ' adjustment downstream in the chemical neutralization system ! 1 described in Outfall 001. ! r----------------------------------------------------------------------------! i official ust only (tfflutnt guidtlint* ub*e*tBont$> r""T FI/. Q yH 1TM plea** print ortypa in tha urwhadad areat only. itrA t.u nwmflbR t1 VM ** A V# * *+* "* *f | C.- LA D008086506 Revised 5-2-83 Form Approved QMS No. 158~ft0l73 U.S, cnviaqnmental . *agency FORM, 2C ERA APPLICATION FOR PERMIT TO DISCHAnUE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS NPDES Consolidated rPeemrmititss rPrrooggrraam outfall"l'5cat.on For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. k. 6uTFaLi_ NUMBER nor; a. latitude i. Ott. 1, HIM. . SIC. c. longitude 1. M|*. *. e. D. RECEIVING WATER (Heme) 010 30 13 25 93 17 09 This is an internal monitoring station which discharges into the PPG Canal, thence to Outfall 001 and into Bayou D'lnd (sec Figure | II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES^ A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wanaweHr to the effluer and treatment unit* labeled to correspond to the more detailed descriptions in item B. Construct a water balance on the line drawing by showing avsra flows between intakes, operations, treatment units, and outfalls. If a water Balance cannot be determined (*.g., tor certain mining activities), provide pictorial description of the nature and amount of any sources of water and any collection or treatment measures, (see FiOlireS 2 Through 8 B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including p*3Em wCttkUkliGjaanitarywastewan cooling water, and norm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wtWatoter. Contin on additional sheets if necessary. 1. OUTFALL NO i. ORE RAT ION ($| CONTRIBUTING FLOW S. OPERATION (list) b, AVERAGE FLOW (inelud9 unit*) TREATMENT *. description b* LIST COOES F* TABLE 2C-1 010 Plant "B" wastewater as follows 1) cooling tower blowdown 289 gpm 1) Metals discharge is minimized by the use of non-heavy metal 1 treatment systems and by purification of incoming water which allows the water to be recycled a greater number of times, thereby decreasing the volume of the blowdown. 2) once-through cooling water 340 qpm 2) no treatment - 3) furnace decoking water from two vinyl chloride monomer production un?tj(intermittent -- 42 gpm 3) no treatment . ,: 400 apm for 38 days/vearl Total at Outfall 010 > 671 gpm + storm runoff (see Figure 5) OrnciAL USE ONLY (ttflutnt seidslmtt tuo-catrsonss) 2-K Note: All streams discharged through Outfall 010 ore adjusted for pH downstream in the chemic si n utilization system described in Outfall 001 . i Q^g362 ' Please print or type in the unshaded areas only rJ- LADOObUtfiOUb 1S8-R0173 FORM EPA2C <3? npdes APPLICUA.ST.IO(NNVFIROORNPMEERNMTITSLTOPRDOISChHLt Z:NE UStNCt WASTEWATER EXISTING MANUFACTURING. COMMERCIAL. MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program I. OUTFALL LOCATION ^:.... _____________________________________________________________ For each outfall, list the latitude and longitude of its location to the nearest IS seconds and the name of the receiving water. A. OUTFALL " ft. LATITUDE C, LONGITUDE (list) 1. o<*. a. **m. i. *e. i. oeo. a, Mia*. ). lac. on 30 13 25 93 17 01 This is on internal monitoring station which combines with Outfall 111 prior to discharging into Outfall 014, thence to Outfall 001 and in Bayou D'lnde (see Figure 1). e II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing rrmrrraifrti the efflut and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing aver flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined It.g., for egrnin minita aptlWtiefi, nrnvid pictorial description of the nature and amount of any sources of water and any collection or treatment measures, {see FI gurei Z through 8 B. For each outfall, provide a description of; (1) AH operations contributing wastewater to the effluent, including pi cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment r' on additional sheets if necessary. wastewa iter. Conti 1. OUT* FALLNO <U*t) Z. OPERATION(S) CONTRIBUTING flow t. OPERATION (Urt) fa. AtiVnEelRuAd*GuEnFit!L)OW J. TREATMENT a. DESCRIPTION by LIST CODES F TABLE 2C-1 on Mercury-bearinq process waste- 240 apm waters from the Mercury Cell (see Figure 4) Treatment of the Mercurv-beorinc 2-C wastewater is described in 5-R Chlor/Alkali production facilitie: Figure 13 2-A including; (a) Cell Room water (b) caustic filter washdown - (c) brine treatment solids (d) brine purges dIus limited storm runoff from the brine treatment area Note: This stream receives tw stage pH adjustment downstream in the chemical neutralization - systems described in Outfalls 01' and 001. i . - - , ... L 0*93^,,- Jepa i.o. number (copy tram item i of /arm > ( Revised 5/2/83 r-;r.Please print or type in the unshaded areas only .FORM' ' LAP00O8.0S.8C6N5V0I6M_O_N_M_C__N_T_A_L_P_aOTEAC--iii-Wlt'v''<-i1AN, . Form Approved OMB No. ASCNCY 158-R01T3 APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS 2C EPANPDES Consolidated Permits Program L outf'all locatToTO^^^ 'fl "err" For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name ol the receiving water. A. OUTF ALL. number (list) a. LATITUDE 1 o. a. vin. la SEC* c. longitude 1. DIG, t. HIR. la tie. D. RECEIVING WATER (name) 111 30 13 25 93 17 01 This is on internal monitorina station which combines with Outfall Oil prior to diseharoina Into Outfall 014, thence to Outfall 001 and irt< Bayou D'lnde (see Figure 1). A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the efflue: and treatment units labeled to correspond to the more detailed descriptions Ir, Item B. Construct a water belance on the line drawing by showing avers flows between intekes, operations, treatment units, and outfalls. If a water balance cannot be determined (e.g., for certain mining activities), provide pictorial description of the nature and amount of eny sources of water and any collection or treatment measures. (see Figures 2 through 8 B. For each outfall, provide a description ofHI) All operations contributing wastewater to the effluent, including proceQft#tT$^eMff)*ry vwwastewai cooling water, end storm water runoff; (2) The average flow contributed by each operation; and (3) Thre t1 reatment received by tne wrt/water. Contir on additional sheets if necessary. 1. OUTFALLHO Out) Z. OPE R ATI ON (51 CONTRIBUTING FLOW a. FERATION (lUt) b. AVERAGE FLOW (include unite) . "1- TREATMENT *, DESCRIPTION t>. LIST COOES Ff table ic-i 111 other process wastewaters from 362 gpm No treatment feasible since Mercury Cell Chlor/Alkoli + storm runoff Mercury pollutant waste load is facilities including: (see Figure 4) below treatability levels. (a) chlorinated condensate (b) chlorine neutralizer efflue nt Mercury content is monitored. (cl spent sulfuric acid Note: This stream receives two stage pH adjustment downstream in the chemical neutralization systems described in Outfalls 014 and 001. - SL 0493 64 Please print or type in the unshaded areas only. Jepa i.D. number {copy from U*m 1 of Form Revised 5/2/83' Gfea LAD008086506 | /*!-: form Appro*'* OMB No. 1S8-R0173 FORM 2C ' A EPA NPDES II.. OWU,,T..FALL .L--O---C---A--TION U.S. CNVIRONMtHTAL fROTECt. ,N AGENCY APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL. MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program -.v.t-- - :- - vrrv-; 'Jfca * ^T WT.TTt ..............,-- mi ijewp. un..'> *' - < *>t * -V* - - A 'I. For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. aT--.-6rL u. . TIU f.P a. .lTL"" I _ ______ ___ B. LATITUDE i` C. LONGITU___D_E_ _l (list) t. D. I, UtN, a. ice. i. sea. 2. MIN. 3. ice. D. receiving WATse (name) 012 30 13 24 93 16 54 This is an internal monitoring station dischargin into the Powerhouse Ditch, thence toOutfal! 0( and into Bayou D'lnde (see Figure 1). 013 30 13 34 93 17 00 This is an internal monitoring station di'sehargir into the PPG Canal, thence to Outfall 001 ane into Bayou D'lnde (see Figure 1). II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES StSuB nttiL A. Attach a line drawing -showing the water flow through the facility. Indicate sources of intake water, operations contributing waiTawaiai to the efflu and treatment unit* labeled to correspond to the more detailed descriptions in Item B, Construct a water balance on the line drawing by showing aver flows between intakes, operations, traatment units, and outfalls. If a water balance cannot be determined for certain mining activities), provic pictorial description of tha natura and amount of any sources of water and any collection or treatment measures, (see Figures 2 tnfOUflh 8 B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process cooling water, and storm water runoff; (2) The avenge flow contributed by each operation; and (3) The treatment racer on additional sheets if necessary. rater. Conti 1, OUT* FALLNO (list) 2. OPERATION!*) CONTRIBUTING PLOW e. OPERATION (lUt) b. AVERAGE FLOW finetud* tinitt) 1. TREATMENT a. DESCRIPTION b* WIST COOES F TABLE 2C*1 012 cooling tower blowdown from the 5 gpm Metals discharge is minimized Mercury Cell Chlor/Alkali facility - (see Figure 4) by the use of a non-heavy metal* treatment system and by the purification of the incoming - water to be recycled a greater number of times, thereby decreas ng the volume of blowdown water. 013 onee-through cooling water from 411.045 gpm No treatment; however, this Diaphragm Cell Chlor/Alkali + storm runoff stream receives pH adjustment facility (Plant "A") (see Figure 3) downstream in the chemical V neutralization system described - in Outfall 001 . 0-Y 1) CrriCiAL us Onlv ((//Iwal|yiSclinwS^aiissriM; SL o<.65 -- FORM 2C &EPA NPOES ___________________ LAQQnanflfiSflfi___________________ ____,A, U.S. tHVIHOMHENTAL PRO1'' "T)OH A(tlNCY KeV 1 S 6Q / APPLICATION FOR PERMIT TO 01: y*~ WASTEWATER K/7/HI ' ' EXISTING MANUFACTURING, COMMERCIAL, MINiwG. \,D SILVICULTURAL OPERATIONS Consolidated PermitsProgram i* outfall location For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A? OUTFALL.-' NUMBER oiit) B. LATITUDE 1. D, 1. MIN. 3. tee. C. LONGITUDE i, ei. 2. MIN. ), nt. D. RECEIVING WATER flume/ 014 30 13 20 93 17 04 This is an internal monitoring station discharging into the PPG Canal, thence to Outfall 001 and into Bayou D'lnde (see Figure 1). It. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate KHitces -f intake water, operations contributing naitsisetsr to the elfluen end treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing averat flows between intakes, operations, treatment units, and outfalls. If e water balance cannot be determined (a.g., lor certain mining acSrithti, provide' pictorial description of the nature and amount of any sources of water end any collection or treatment measures.Figure* 2 through 8 B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including sanitary wastewate cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment recaiWtrtytmrwesfwsui. Contim. on additional sheets if necessary. r. our- PALLNO 0`tt) a. operation)*) contributing flow a. OPERATION (lilt) b. AVERAGE FLOW /include unitt) a. treatment a. description . list cooes fr TABLE 1C-1 014 Outfoll 014 is subjected to pH adjustment as described on the following page. In addition, some 1) process wastewater from Diophrogm Cell portion of Plant "A" including: 370 gpm components of Outfall 014 ard individually treated os described below; 1) 'No treatment (o) chlorinated condensate (b) waste sulfuric ocid (cl hydrogen condensate (d) chlorine header seal water (e) caustic evaporator condensafto (f) brine purges 2) once-through cooling water 100 gpm from Diaphragm Cells 2) No treatment Total contribution of Diaphragm Cells to Outfall 014 470 gpm OrnciAW U5 ONLY itffhient juidllinc* iub-cotfMQFt**) EPA Form 3510-2C (6-801 PAGE 1 OF 4 $1 049366 continu d on next page [PA i.d. humpkn(copy from lum 1 of FormT Revised 5/2/83 PtMM print Of tvpa in tht unthoded area* only. LAD008086506_______________ _ Form Approved 0MB No. 158-R0173 FORM 26 NPOES U.I. (NVIKONMtNTAL FNOTICT1 N AOKNCY ` - APPLICATION TOR PERMIT TO DISCHARGE WASTEWATER ^ ^ EXISTING MANUFACTURING,COMMERCAL, MINING AND SILVICULTURAL OPERATIONS Jr Consolidated Permits Program ; - t >''?& -fl/-.- L OUTFALL LOCATION J For **eh Obtfall, llat tha latitude and longitude of It* location to the naaraatlB taconds and the name of the receiving witor. A.'OUTFALL" ,NUMCR , aiiti Is LATITUDE M4, L HIM. Is INC, C, LONOITUDKvs. I. on. t. MIN. I* tie. , O. WKCKIVINO WATS. iUji'. . . "L ' II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES, A. Attach a Una drawing thowing the water flow through the facility. Indicate tourcst of intake water, operation* contributing waatowattr t the effluent, and treatment unit* labeled to corretpond to the more detailed description* In Itpm B. Construct a water balanca on tha line drawing by Ihowing average flows between Intaka*, operations, treatment unit*, and outfall*. If a water balance cannot be determined h-g., for certain mining actMtfm), provide a pictorial description of the nature and amount of any source* of water and any collection or treatment measures. .... . B. For each outfall, provida a description of: (1| All operations contributing wastewater to the affluent, including process cooling water, and storm water runoff; (2) The average flow contributed by each operation; and <31 TIM treatment received by the on additional sheet* If necessary. V' Continue 1. OUT* FALLNO () 2. OPERATION(5) CONTRIPUTINO FLOW ft. OftRATION flfst) b. A(IVnCciRudA*QuIniFt*L)OW 1. TltKATMKMT 1. DESCRIPTION b. LIST CODE* FROM A*LE 2C*I 014 3) process wastewater from 607 apm 3) Mercury Cell processwwaste Mercury Cell portion of water treatment is discrib d in Plant "A". Outfalls 011+ Outfalls 011 and 111. No 111 + HC1 storage tank treatment of vent scrubber vent scrubber effluent effluent. (5gpm)_______________________ * - Total tD Outfall 014 EPA Form 3510-2C 16-80) 1077 apm + storm runoff (see_Fiaures 3 and 4) Note: Outfall 014 is equipped ?-K with an aut.nmatir nH rnn+nnl cvetan ntiliyinn arid and caustic reagents and a static mixer plus feed forward contr ol instrumentation to maintain this discharge within pH liml ts of approximately 5-10. This stream is further adjusted fc r pH downstream in the chemical neutralization system in Outfall 001. PAGE 1 OF 4 1 SL f)AQ -livii ;awiT ^ - y Hteaie oont or tyO <n ire ufltnaoea area* omy. umomteob- _ Revi-s*d~5/l/3.---------------- FORM 2C &EPA U.S. ENVIRONMENTAL PRO" T'-jjACENCV ' ' y APPLICATION FOR PERMIT TO DIS .V '<'2 WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS NPDES Consolidated Permits Program I, OUTFALL LOCATION For etch outfall, list the latitude and longitude of iti location to the nearest IS seconds and the name of the receiving water. A, OUTFALL NUMBER (Hit) B. LATITUDE i. on, HlN. 3. ICC. C. LONCITUDE t. 0*0. 7, MIN, , cc* O. RECEIVING WATER (tUntt) 015 30 13 16 93 16 52 This is an internal monitoring station dischargir into the Powerhouse Ditch, thence to Outfall ( and into Bayou DMnde (see Figure 1). 016 30 13 16 93 16 52 This is an internal monitoring station dischargir into the Powerhouse Ditch, thence to Outfall C and into Bayou D'lnde (see Figur 1). A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing weiteweui to the efflue and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the lino drawing by showing aver flows between intakas, operations, treatment units, and outfalls. If a water balance cannot be determined (e.g.. for certain mining ectMties), proviri pictorial description of the nature and amount of any sources of water and any collection or treatment measures. (see Figures 2 through 8 B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including proceQfjdjtTciijI0 silvery wastews cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Contii on additional sheets if necessary. OUTfacl.no fiur) 2. OPERATION(S) CONTRIBUTING FLOW S. OPERATION flUt) b. average flow (include unit*} 3. TREATMENT . DESCRIPTION b, LIST CODES F TABLE 2C-I 015 Powerhouse "A" 11 once-throuqh coolinq water 41,703 gpm 1) No treatment - 21 non-process water includino: (a) boiler blowdown (bl deionization unit regen eration 26 apm r * 21 Deionization regeneration chemicals are neutralized .prior to discharge. 2-K Total to Outfall 015 41,729 gpm (see Figure 4) 016 Powerhouse "B" 1) once-through cooling water 2) non-process water including: (al boiler blowdown (b) deionization unit regeneration Total to Outfall 016 86,025 gpm 26 gpm 1) No treatment 2) Deionization regeneration chemicals are neutralized prior to discharge. * ... - 86,051 gpm (see Figure 4) 2-K ! 1 \ l 1 1 --- EPA Form 3510-2C <6-801 PAGE 1 OF 4 SL 049368 LAD008086506 Revised c;/2/83 2CFORM O r-ma APPLICATION^OR PERMlf TO oTs'ch .GE WASTEWATER EXISTING : >NUFACTURING. COMMERCIAL. MININQ&3 SILVICULTURAL OPERATIONS NPD6S I ^ wi.-TM--1 Consolidated Permits Proy.Tm I p-iyy**1 * win i \ 1 9 """fy+wnf I. OUTFALL LOCATION *%- ^ -i.V,^--. .For each outlall, list the latitude and longitude o< n location to the nearest 15 seconds ond the name ol the receiving water. LF.NOU(UM'iTnBF)EkR.UL B. UATItUDE l. ed*. J. MIH, i, ice. C. LONGITUDE l. DCO, t, MIH, ). ice. O. NCCCIVING WATCH 017 30 13 93 17 0? This is an internal monitoring station which dis- charges into the PPG Canal, thence to Outfall 001 and into Bayou D'lnde (see Figure 1). o V| ro cn uiftL A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wntsneur to the affluent, and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined ft.ff., tor cerre/rj miningjfpMtitt). provide pictorial description of the nature and amount of any sources of water and any collection or treatment measures. (see Figures 2 thtroougr B. For each outfall, provide a description of: (1) All operations contributing wastawater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (21 The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary. 1. OUTFALLNO (list) OPCNATION($| CONTRIBUTING FLOW a. OPERATION (tUt) b. A(VinEeRiuAdGf uEnitFML)OW 3* TREATMENT A. OCftCftfNTIQX b. I.1StTaCilOsD; EicS *Pi *ON A^sbestos-bearina Drocess in ` gpm Treatment of both streams (a) and 5-R wastewater from Diaphragm Cell (see Figure 3) (b) Is described in Figure 14. 2-C Plants "A" A VC" -including: 1-U (a) cel! room wastewater. r (b) cell renewal wastewater 1 t ` s~ EPA Form 3510-2C 16-80) - Ofi (1 c AC A 1i '1 - 1 ti j P\e*e Dfint or tvbe in tn* unjhaded wtM only. epAToTNOMoeRTcooTTromTwinToTTonrrTTlRevi S0d5/2/83 LA D0Q8086506 * Form Approved QMS No. 158-ft0173 FORM 2C &EPA NPDES u,f. [NVWOHMtNTAU rHOTtc.'ji"-) AGENCY APPLICATION FOR PERMIT TO DISCHA- WASTEWATER EXISTING MANUFACTURING, COMMERCIAL. MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program outfall location For *ach outfall, list the latitude and longitude of in location to the nearest 15 tecondt and the name of the receiving water. a.N6U(jMYBfEaRl.u' (IVtJ____ B. LATITUDI 1a Dlf . 1, MIN, >a ice. Ca longitude 1. bC4. X. MIN, i. tie, o, RECEIVING water (name) O 0*0 30 13 22 93 17 08 This is an internal monitoring station discharging into the PPG Canal, thence to Outfall 001 and into Bayou D'lnde (see Figure 1). * *See O jtfall TIE A. Attach a line drawing thowing the water flow through the facility. Indicate source* of intake water, operations contributing wastewater to tha affluent and treatment units labeled to correspond to the more detailed descriptions in Item 8. Construct a water balance on the line drawing by shewing averag flows between intakes, operations, treatment units, and outfalls. If e water balance cannot be determined (e,g.t for certaw mining acdrftrerf, provide pictorial description of the'nature and amount of any sources of water and any collection or treatment measures, (see Figures 2 through 81 8. For each outfall, provide a description of: (1) Ail operations contributing wastewater to the effluent, including processes cocling water, and storm water runoff; (3) The average flow contributed by each operation; and (3) The treatment rscenr on additional sheets if necessary. ~ 1. OUTfALLNO (hit) 2. OPERATION'S) CONTRIBUTING FLOW S. OPERATION (IUt) b. AVERAGE FLOW (Include unite) . TREATMENT 1. DESCRIPTION b, LIST COOES PRi TAVLK 2C-1 018 1) process wastewater from all 750- 9pm 1) Process wastewater is steam 1-U Plant "B" products units except + storm runoff VDCM from process pads stripped as described in Figure 15. 2) process wastewater from VDCN 38 aom 2) This process water.has been 1-D production unit * treated within the production ** process in which chlorinated organics were stripped from the aqueous bottoms stream prior.to discharge. 31 primary scrubbina water from 1530 ppm process waste incinerator units (four) 3) No treatment. Total contribution to Outfall 018 from Plant "B" 4) Plant 'C\ Outfall 007 (see Flaure 6) 2r338- 9pm + storm runoff (see Figure 5) Ml 5 gpm 4) Plant "C" treatment is described in Outfall 007 Please'print or type in the unshaded areas only X LA0008086506 Revised '5/2/83 Form Approved OMB No. 1S3-B0773 FORM ERA2C in V 2* U.S. INVIRONMCflTAL PRO -7- . AGENCY APPLICATION FOR PERMIT TO DISCHA^-'e WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING ANO SILVICULTURAL OPERATIONS NFOES I. OUTFALL LOCATION Consolidated Permits Program . i . I. IT-nf. iKIi'i *L'' .is&i. For each outfall, hit the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. OUTFALL NUMBER (list) O- latitude 1, . t. MIN. 1. IKC. C. LONGITUDE i. oce. t, MIN. 1. see. (name)d. receiving water - A. Attach a line drawing showing the water flow through the facility. Indicate source* of intake water, operations contributing trinsvneur Til the cffluen and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing awerai flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined (e.g., for certain mining ecdritiet), provide pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wsttswater, tannery wastewati cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wneWettr. Contini on additional sheets if necessary. 1. OUT* FALLNC (liMt) 2. OPERATIONS) CONTRIBUTING FLOW a. OPERATION (lUt) b. AVERAGE FLOW (include units; 3. TREATMENT *. DESCRIPTION b. LIST COOES PR TABLEiC-l 018 5) Silica Products, Outfall 006 2,115 qpm 5) Silica Products treatment is (see Figure 7) described in Outfall 006 Total to Outfall 018 5,468 gpm + storm runoff - 2-K Note: All streams discharged through Outfall 018 receive pH adjustment downstream in the chemical neutralization system described in Outfall 001. i 1 j A 1 . * -! j '- i i ` OFPICI* r~ _\ ... , ' *' ' SL 049371 - ^ FORM ZC &EPA lypoES i AnananR^nfi U.S. (NVINONMENTAL TROT APPLICATION FOR PERMIT TO D1S> - AWGAESNTCEYWA^yised 5/2/83 EXISTING MANUFACTURING, COMMERCIAL, MINING'AND SILVICULTURAL OPERATIONS Consolidated Permits Program ; OUTFALL LOCATION For each outlall, liit the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. ra.nauimrrirkxrix" f (tut) B. LATITUDE I. OCA. 1. HfH. I. c* , C. LONGITUDE 1, DIO. 1. HIM. \. o. receiving water (name) 118* 30 13 22 93 17 OS This is an internal monitoring ttnlinn w-Ii-U charges into the PPG Canal, thence to Outfall 001 and into Bayou D'lnde (see Figure 1). H. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES . A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wettewatex to the effluen and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing averse flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined flop., for certain mining activities), provide - pictorial description of the nature and amount of any sources of water and any collection or treatment measures, (see Figures 2 through 8 B. For each utfall, provide a description of: (1) Ail operations contributing wastewater to the effluent, including prraffMwnxM'tafelltonitsrY wastewatt cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment raccivetniy ma!westawatar. Contirn on additional sheets if necessary. f. OUT* FALLNO (tut) Z. OPERATION(| CONTRISUtlNC PLOW . OPERATION (U*t) b, AVERAGE PLOW (include unite) 3. THCATMINT . DESCRIPTION bp WIST cooes r* TABUS 1C-1 118 1) Process wastewater from the 220 gpm 1) Treatment of the process waste- 2-K CHC-EDC production units (3' water is described in Figure 1-D in Plant "B" 16. 2-B 2) Process wastewater from the incinerator secondary scrubber: 50 gpm 2) No treatment. (three) Total to Outfall 118 270 gpm (see Fiqure 5) Note: All streams discharged through Outfall 118 receive pH adjustment downstream in the chemical neutralization system described In Outfall 001. 2-K * *Cutfall 018 in the current NPOI S permit consists c if two separate sewers which are fl jw-mea: urea and analyzed separately, and th : results are report sd as a combined total for purposei of m a iuring compliance with the permit limit i. The use of two sewers to convey Plant B organic process v 'aste- waters is necessary to avoid cont act of basic chlori ne-bearing components with highly acidic components; contact would result in the evolution c f chlorine gas into plant work areis. By separately conveying these two s ream? to the plant pH neutral*izati*on system at the h^1 od of th e PPC Canal where the flow is much larc er and pH extremt s do not exist, the chlorine releasp proble n Is 1 minimized. To clarify t >e physical arrang ;ment, these two sewers hove b erj identif ed wi sepatate Outfall numbers (018 an d 118) in this app ication; however, PPG suggests thy t these two sewers continue to be treated as c single outfall poi nt for the purpose of establishing ; OPFICIA l use only (t/fluent guidelines tub-cott/onn) |{ nits. EPA Form 3510-2C 16-aO) c> r> r- c , or n Pieaie print or type m the unsnapea areaj omv. t LAuuuouoojucRevised 0/ L>V"5 bom Aoorovea umh no. ioh-hoi/J lFORM U.s. [HVIAOHMINTAL PRO' rr APPLICATION FOR PERMIT TO OISv ActHCv WASTEWATER 2G &EPA EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS NPDES Consolidated Permits Program 1. OUTFALL LOCATION For each outfall, lift th* latitude and longitude of its location to the nearest IS leeondi and the name of the receiving water. A,NuUwTfcr OUt) a. LATITUDE 1. 01A k. Mm, 1. *c. C. LON ITUOC . Olfti 1, U|R, i. ice* d, receiving water fname) ' 019 30 13 34 93 17 00 This is an internal rr.onitorina station d'isenaraina into the PPG Canal, thence to Outfall 001 and into Bayou D'lnde (see Figure 1). .. _i A. Attach a line drawing showing the water flow through the facility- Indicate sources of intake water, operations contributing wastewater to the effluen and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing averse flows between Intakes, operations, treatment units, and outfalls. If a watar balance cannot be determined (e.g,, for certain mining aCtMtiet), provide pictorial description of the nature end amount of any sources of water end any collection or treatment measures. (see F> Qures 2 through 5 B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including proces^yy^taMu^aMitaiywwai stewate cooling water, and storm water runoff; (2) Hie average flow contributed by each operation; and (3) Tha treatment received by The wastewater, Contini on additional sheets if necessary. Out)I.OUf* FALLNO 2. OPERATION (SI CONTRIBUTING PLOW S. OPERATION diet) b. AVERAGE FLOW finehid* unit*) ,,-n 3, TREATMENT a. DESCRIPTION - be LIST COOCf FR taile zc-i 019 Process wastewater from the 140 gpm Brine solids from the brine treat- 2-K Plant "A" Diaphragm Cell brine (see Figure 3) ment system are used to neutralize 'S. treatment system waste hydrochloric acid before i discharge. Capacity of the syster 1 is 0.18 MM apd*. flowrate is 0.14 MM gpd* and the retention time is 15 minutes. Note: This stream receives pH adjustment downstream in the 2-K chemical neutralization system described in Outfall 001. * i y*MM gpd = million gallons per d< SL 04937:i PImm print or typa in tha unihaded great only. ep* i.o. NUMBERfeojty from Item i iTh'orm-- LAD008086506 Revised 5/2/83 ___ form Appro**/OMB No. 1S8-R0173 U.E. nttfmONMCriTAL protection aoency APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER L EXISTING MANUFACTURING;COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program ' I. OUTFALL LOCATION For mch Olitfsll, lift tha latitude and longitude of lt> location to the i : 16 taeondi and the name of tha receiving water. A.N8UUMTBFCARLC.," Olit) . LATITUDE 1, o. L MIN, 3, SC C. LONGITUDE 1* BE. t. NIK. s. ite, d, nacaiviNo water (mmo) 0?1 30 13 40 93 15 46 Bavou Verdine f01 in Ditch) [see Figure 1] A. Attach inline drawing shewing the water-flow through the facility. Indicate source* of intake water, operationa contributing to Sw affluent. j-^y ind treatment unit* labeled to correspond to tha more detailad deecriptiont In Item B. Conatruct a water balance on the lino drawing by damning overage flows betvwen Intake*/ operationa, treatment units, and outfalla. If a water balance cannot be determined feft, for cara/n mkMag tctMt/n), provide a pictorial description of the nature and amount of any toutoaa of wetar.and any collection or treatment maaaurai.-^lf-WTWi^yV. "V Bc For each outfall, provide a daacrlption of; (1) All operationa contributlng.witewatar to tha effluent. Including prooeaa waabtwetar, lanfeary weetawater. ^pooling water; and atorm water runoff; (2) The average flow contributed by each operation; and (3) The treatment raeceived by th x. Continue l.tTon additional aheeta If necetaary. ;> tv-mv 't. OUT FALL NO <- filar; -'W............ . OPERATION'S) CONTNIOUTINO PLOW nhhffe- * ' ' . OPERATION (lUt) .0. AVCRAQI FLOW (include unto) --3 - *. TREATMENT A DESCRIPTION - i b, LIST COOCt FRO TABLE 1C*1 021 1) Once-through cooling 24,370 gpm 1) No treatment. 4-A water from Plant "A" Diaphragm Cell facility ' 2) Barometric condenser discharge 2,200 qDm 2) No treatment 4-A 31 Cooling Tower Blowdown 30 pom 31 Metals discharge is 4-A minimized bv the use of non-heavy metal treatment systems and bv Durificatio n . of incoming water which allows the water to be re- cycled a greater number of 4) Storm runoff from Caustic storm runoff times, thereby decreasing !i the volume of the hlnwdowr 4) No treatment 4-A storage, chlorine liquefaction, and brine treatment areas Total to Outfall 021 26,600 qom + storm runoff (see Fiaure 31 onifiii 4 EPA Form 3510-2C <6-80) PAGF 1 OF a 9374_ ` ' >'Af continue AiTA^OI Mf Please prim or type in the unshaded areas only. Revised 5/2/83 (ERA I.D. number (copy from Item l of farm i) LAD008086506 Form Approved OMB No, 158-R0173 c/EPA U.S. ENVIRONMENTAL PROTECTION aoencv APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program I. OUTFALL LOCATION For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. JCOUTFALET" NUMBER flirt) B. LATITUDE Is o. t. HIM. 3. IKC. C. LONGITUDE 1. DEO. t. Mlf*. t. tic. D. etcuviHS WATIPI (name) 024 30 13 26 93 16 41 Bayou Verdine (01 in ditch) [see fiqure 11 H. FLOWS, SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES^ A. Attach a line drawing showing the water llow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions In Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment units, end outfalls. If a wwter balance cannot be determined ie.g., for certain mining acthrltfmt, provide a pictorial description of the nature Bnd amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional iheets If necessary. ' ... 1. OUT* FALL NO (tat) a. OPERArtON(S) CONTRIBUTING? FLOW m. OPERATION (tUt) b. AMVIuNdA*OuBnFit*L)OW ' 3* TREATMENT a. DESCRIPTION b, LIST CODES FRO* TABLE IC-t 024 storm runoff from Power- (see Figure 4) Runoff from the caustic dock 4-A house "A: and Caustic/ storage area is collected chlorinated hydrocarbon (430,000 qal. holdinq capac- dock storage areas ) ity), and, if contaminated. * i pumped to Outfall 014 for * neutralization. Otherwise. it is released directiv to , to Outfall 024. Runoff from other areas is not treated. - i* -- > OFFICIA EPA Form 3510-20 (5401 PAGE 1 OF 4 Continue o^i Reverse Pirate print or type in the unshaded areas only. I L AUUUfcUbODUQRpvi cpH 5/2^3 Form Approved OMB No, 158'RQ173 Uw,,S*., ENV.I.R.....O....N.....M.....ENT. AL PR^OT, Ew .WAGCNCY EPA vi;- APPLICATION FOR PERMIT TO DISCH*A'^rtASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS 1 Consolidated Permits Program iFor each outfall, list the latitude and longitude of its location to the nearest IS seconds and the name of the receiving water. NUMaC (list) B. LATITUDE 1. 01*1 1. HIM, s. see. C. LONGITUDE 1. DIG, t, MIR. 1. HC. o. receiving watis (name) 30 13 28 93 17 26 This is an internal monitoring station discharging into the PPG Canal, then to Outfall 001 and into Bayou D'lnde (see Figure 1). II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing tif showing averag flows between Intakes, operations, treatment units, and outfalls. If a water balance cannot be determined (a.g., for certain mini g activities), provide pictorial description of the nature and amount of any sources of water and any collection or treatment measures. (see p;oures 2 through S B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process waHesMwr.iaanitary westewatei cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment rettnVedlDy^nn wwtawater, Continu on additional sheets if necessary. t. OUTFALLsNO 2. OPERATION (3) CONTRIBUTING PLOW . OPERATION (list) b. AVERAGE FLOW, ^include unitM) ' 2. TREATMENT a. DESCSIPTIDN ' b. LIST CODES FRt TABLE 2C*1 025 1) cooling tower blowdown from 50 gpm Metals discharge is minimized by Plant "C" Diaphragm Cell plus stprm runoff from Plant "C" the use of a non-heavy metal treatment system and by purificat ion fc_____ w and Silicas .. of the incomina water, which allows the water to be recycled a greater number of times, thereby - 2) additional flow from neighbori n9 industrial dischargers plus storm runoff 100 gpm decreasing the volume of blowdov m water. Off-site effluent No treatment by PPG Total to Outfall 025 150 gpm + storm runoff (see Figures 6 and 7) * *I EPA i.o. NUMKH (cony from Item l of Form Revised 5/2/83 Please print or type in the unshaded areas only. LAD008086506 -L Form Approved 0MB No. 158-R0173 : FORM 2C v>EPA NPDES O.l. environmental, protection agency .. APPLICATION FOB PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL. MINING AND SILVICULTURAL OPERATIONS Consolidated Permits Program I. OUTFALL LOCATION f For each outfall, litt the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. J.LNOUCMJBTEFRTIX" (litt) ft. LATITUDE . DC*. t. M|N, . **C, C. LONQITUOC I. DM, a. m<m. D. receiving water (nmmt) 026 30 13 20 93 17 24 This is an internal morn*torina station ciischargino into the Silica Pigments Ditch, thence to Outfall 001 and into Bavou D'Inde (see Fiourell. II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES ,, A. Attach a Una drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wuuwiisr to the effiue . and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct e water balance on the line drawing by showing even ? flows between intakes, operations, treatment units, and outfalls. If a water belance cannot be determined fag., far certain mining actfvftfes), providt ", pictorial description of the nature and amount of any sources of water and any collection or treatment measure*. B, For asch outfall, provida a description of: <1) All operations contributing wastewater to the effluent, Including process wastewater, sanitary wastewet cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wwiewetai, Contir on additional sheets If necessary. fAt.LoLuNtOflirt; X. OPERATION(S) CONTRIBUTING PLOW . OPERATION (litt) b. AVERAGE FLOW (ineludt unlit) 3. TREATMENT a. DESCRIPTION b. LIST CODES PI TAILS XC-I 026 Miscellaneous wastewater from VCM-II (Plant "B"): 1) furnace decoking water 23 gpm 1) Furnace decoking waste 1-U water from periodic furnaqe operadons are removed fron 2) cooling tower blowdown 10 gpm the wastewater by settling in a 20,000 gal, settling basin. The average flowrate is 0.03 MM qpd**with a re tention time of 24 hours. Solids accumulated Tn the basin are removed and dis posed of off-site in an authorized disposal facili 21 Metals discharge is min imi zpH hv the usp of a nnnL heavy metal treatment, system and by purification of the incoming water, which -allots the water to be recycled a * OFFICIAL USE ONL.You(dt/flu?tnml mtuiidilhle-lMimnetnit wtufgrsaillflfoonrltstl bpr riav greater number of times thereby decreasing the volume of blowdown water. SL 049377 A. Aiuch a lina drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to tne efflue end treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing ever; flows between intakes, operations, treatment units, end outfalls. If a water balance cannot be determined (e.g., for etrtain mining actMtiot), provid pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewa cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Contir on additional sheets if necessary. 1. OUT* 'ALL, NO nut). a. orteATioNisl contributing now a. OPERATION Hitt) 6. AVERAGE FLOW (ineludc unit*) '-1 3a treatment ---------------------------------------------------------"------------------------------ 5. LIST C DES F 8. DESCRIPTION TABLE IC*t 026 3} once-throuah cooling water and steam, condensate 28 apm No treatment Total to Outfall 026 61 gpm + storm runoff _..!i - (see Figure 5) - i l | i \------------ i i---------------------- 1-- ; ii l 1 T Revised 5/2/83 era i.d. NUHitafenar from lim # nf yon Please print or typt In the unshaded area only. _____ LADQQSQSfiSflS. Form Approved OMB No. 1S8-R0173 U.S. INVIRONMCNTAU PROTECTION AGENCY >ERA APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS ' Consolidated Permits Program ___ I, UTFALL LOCATION For each outfall, lilt tha latitude and longitude of iti location to the neerait IS seconds and the name of tha receiving water. x. outfxix" number (list) a. LATITUOE I. DH. 3. MIN. 3. UC. C. LONGITUDE %, OB0, 1. HINi 1, *KC. o. receiving water (namei 097 30 13 45 . 93 17 Iflff-ci to rirainaijo Hi+rh loarl-inrj +iv 028 30 13 45 93 16 57 1 ^Bayou Verdine (01 in Ditch) [see Figure 1] 029 30 13 45 93 16 53 1 1 -I II. FLOWS, SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES. A. Attach a line drawing ihowing tha water flow through tha facility. Indicate tourcei of intake water, operation* contributing wastewater to the effluent and treatment unit* labeled to corretpond to the more detailed description* in Item B. Construct a water balance on the line drawing by showing average ' flows between Intake*, operations, treatment units, and outfall*. If a water balance cannot be determined (e.g., tor certain mining ectMUet), provide i pictorial description of the nature and amount of any source* of water and any collection or treatment measure*. B; For each outfall, provide a description of: (1) All operation* contributing wastewater to the affluent. Including proce*e wastewater, sanHUfty wastewater (. cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by tha wessHmSar. Continui : " on additional sheet* if necessary. i.our PAnLuLtN) Cl *. OPCRATIONISI CONTRISUTINO PLOW a. OPERATION (lUt) b. AVIRASS FLOW (Include unlit) 027 Storm runoff from rail car storm runoff S. TRSATMINT a. DESCRIPTION No treatment b. LIET CODES PRC TAILS 1C-1 4-A storage area1 028 Storm runoff from rail car storage area* storm runoff No treatment 4-A 029 Storm runoff from rail car storage area* storm runoff No treatment 4z&. * No loading, unloading, wasMng or other ac ;i vi ties occur in this area. orriciAi. USE only (tffluent euidtlinet sub-caMforlM) uridMN/'iiaib , j*> iV .* EPA Form 3S10-2C (S-801 4. . - . * - v `F' . PAGE I OF 4 ----------------- SL 049379* --P'lip">i - .v -- CONTINUED FROM THE FRONT C, Except for storm runoff, leaks, or spills, are ai QvtS (complete the following tablet he discharges described in Items 11-A or B interm, jr seasonal? MO (go lo Section lilt 0/ I J/ OI 1. OUTFALL NUMBER His ll 2. OPERATIONfs) CONTRIBUTING FLOW (list) 3. FREQUENCY I. DAYS PER WEEK (gpecify overapt) b. MONTHS PER YEAR frp#c<7y average} . PLOW RATE (in mpd} I. kON TCBM t. mahimum DAIlf 4. FLOW b. TOTAL VOLUME fipec/fy u*ith bAitt) (. TIMM X, HuXtMtfh AV(HAt DAILY A. Does an effluent guideline limitation promulgated by EPA under Section 304 Of the Clean Water Act apply to your facility? jv~l Vej (complete Item tfl-BI I Imp (lo to Section IV) B. Are the limitations in the applicable effluent guideline expressed in terms of production (or other measure of operation)? [x)vcs (complete Item IIJ-C) -T~|HO (go to Section IVl C. If you answered "Yes" to Item lll-B, list the quantity which represents an actual measurement of your maximum level of production, expressed in the terrr and units usad in the applicable effluent guideline, and Indicate the affected outfalls. i, *UAHT|TY Pm* BAY I. MAXIMUM QUANTITY C. PCft4TIOM| PDOBUCT. HAUKIlkL ETC. (specify) a. AFFECTED OUTFALLS (list outfall numbers) 1420 (1506)" 1,000 pounds Chlorine/caustic production by mercury cell process 011 and 111 chlorine product 1956 (2046)* 1,000 pounds Chlorine/caustic production by diaphragm cell process 014,017,019 chlorine product (Plant A) (carbon anodes) 3070 (3120)* 1,000 pounds Chlorine/caustic production by diaphragm cell chlorine product process (Plant C) (DSA) 007 (018) * These figures in parenthesis indicate the highest single doy of production. IV. IMPROVEMENTS^ A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operation of wa;:i water treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This include: but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and gran or loan conditions. O YES (complete the (allowing tablet 0no (go to Item IV-Bl t. IDENTIFICATION OF CONDITION, 2, AFFECTED OUTFALLS AGREEMENT. ETC. a. m. b. .ounce or one*.*,**. a. BRIEF DESCRIPTION OF PROJECT 4g.faFiXINwAccj. c M* PATE JblMYfIr B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs for other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate your actual 01 Planned schedules for construction. -x- IF DESCRIPTION OF ADDITIONAU CONTROL fROGRAMS ,S * ^ EPA Form 3510-2C IG-80) PAGE 2 OF 4 WWW . INUE ON PAGE Revised 5/2/83 Page 1 of 1 Item IV 8 Planned Projects Affecting Discharges 1. Modernization of the Plant A Diaphragm Cell facilities has been approved by PPG's Board of Directors and is scheduled to be completed in late 1983. This project consists of converting the existing anode diaphragm cells to more efficient bipolar dimensionally stable anode electrolyzers, as well as significant improvements in the ancillary facilities. Production capacity will be unchanged. No new pollutants will be discharged to the waterways. In fact, when completed, this modernization project will have a substantial positive environmental impact including the following in the water area: (a) The new chlorine cells installed as part of this project employ metal anodes and do not use lead, thus eliminating this source of a toxic pollutant. (b) The quantity of hypochlorite discharge (Outfall 111) will be sharply reduced by the installation of a sulfur chloride unit to recover chlorine from the tail gases, in place of the existing caustic scrubbing tower. (c) The quantity of dissolved chlorine discharged (Outfall 014) will be reduced by the installation of an improved chlorinated condensate stripping system. (d) The chlorinated hydrocarbon stream associated with the chlorine gas scrubbing system (Outfall 014) will be eliminated by the conversion to dimensionally stable anodes. A more detailed description of the project scope may be found in the August 28, 1980 letter from R. J. Samelson to Oscar Cabra (Region VI, EPA) The revisions to effluent volume and routing occurring as a result of this project are reflected in the Outfall descriptions, water balance, and sketches of this application since initial start-up of the first chlorine circuit is scheduled for next month (June, 1983). 2. Several projects are now in the design phase. These include additional hypochlorite control for Outfall 007 and a change in process effecting about 25% of total silica products production. Since neither of these changes has been approved by the Board of Directors, they are not in cluded in this package of information. Depending upon approval status, these changes may be requested for incorporation at the time of permit negotiation. Both projects would qualify as minor modifications. No new pollutants would be added; in fact, total pollutant loads would be expected to decrease slightly. SL 049381 epa I. . NUMecRfcopy tram Item J at Form l) CONTINUED FROM PAGE 2 LAD008086506 V, INTAKE AND EFFLUENT CHARACTER 1ST/t Revised 5/2/83 form Approved OMB No. 158'ROt73 flgy;iiiSfc^V;^.iV .^W. A, B, & C. See instructions before proceeding -- Complete one set of tablet for each outfall -- Annotate the outfall number in the ipace provided. NOTE: Table* V-A. v-B, and V C are included on Mparata theett numbered V-1 through V-9. 0. Uie the space below to lilt any of the pollutant) listed in Table 2e-3 of the instructions, which you know or have reason to believe it discharged or may discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical data in yi possession. 1 , POLLUTANT 2. SOURCE t. POLLUTANT X. SOURCE Asbestos Used in chlorine cells in Plants "A" and "C" * V|, POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS A. It any pollutant listed in Item V-C a substance or a component of a substance which you do or expect that you will over the next 5 years use or manufacu. as an intermediate or final product or byproduct? I Chromium, total Copper, total 0 YM ftitt all tuch potlutantt btlow) Chloroform 1,1 - Dich I oroethane I~1 NO (go to Item VI-B) Toluene 1,2-Transdichloroethylene 1.2-Dichloroethane 1.1.1-Trichloroethane Mercury, total 1,1-Dichloroethylene 1.1.2-Trichloroethane Phenols, total Methylene chloride Trichloroethylene Carbon tetrachloride 1.1.2.2-Tetrachloroethane Vinyl chloride Chloroethone_______ _____ Tetrochloroethylene________ B. Are your operations such that your raw materials, processes, or products can reasonably be expected to very so that your discharges of pollutants may durir the next 5 years exceed two times the maximum values reported in Item V? Qvts icnmplcte lltm Vl-C below) (29 NO (to to Section VII) C. If you answered "Yes" to Item Vl-B, explain below and describe in detail the sources and expected levels of such pollutants which you anticipate will be discharged from each outfall over the next 5 years, to the best of your ability at this time. Continue on additional sheets if you need more space. EPA Form 3510-2C (6-80) PACE 3 OP 4 SL 049382 JUE ON REVERS CONTINUED FROM THE FRONT Kevisea d/^/oj VII. BIOLOGICAL TOXICITY TESTING DATA Do you hay* any knawMga or reason to baitava that any biological tart tor acuta or chronic toxicity har baan mad* on any I your discharger or i rtcaWing watar in relation to your discharge within tha last 3 years? (Identify the terl(i) and describe their purpowaa below) 25 no (to to Station Vtll) VIII.CONTRACT ANALYSIS INFORMATION , Wert any of lha analyse* reported in Item V performed by a contract laboratory or consulting firm? * oddrtAi and telephone number of, end pollutant* each Much laboratory or firm below) - ** ' i-t a'*' L' Q NO (to to Section IX) B, ADDIttfS ----------C. TELEPHONE------------ U. POLLUTANT! ANaLVS*b (area cOde 6 no. 1 nun Core Laboratories, Inc. P. 0. Box 3303 Lake Charles, LA 70602 Radian Laboratories, Inc. Kemron Environmental Services 8501 Mopak Boulevard Austin, TX 78766 16550 Highland Road Baton Rouge, LA 70808 (318) 882-0334 Phenols COD Nitrogen.total org Nitrate-Nitrite Ammonia (512) 454-4797 Heavy metals (504) 293-8650 Heavy metals -*L V -v' 'ty;' * \ 'fa - IX* CERTIFICATION, / certify under peaetty of lew thet I have personally examined and am familiar with the information submitted in this application and all attachments end that, based on my inquiry of those individuals Immediately responsible for obtaining the information, t belfevathat the in~ formation is true, .accurate and complete, i am aware that there are significant penalties fer submitting false information, including the possibility of fine end imprisonment. A. NAME a OFFICIAh^lTI. R. D. Duncan VP/GM ICD V; a. phonc no. (area codr & no.? (412 ) 434-2515 EPA Form 3510-2C (6-80) PAGE 4 OF 4 D---------SL 049383 p /O "^Sised 5/2/83 FORM 2-C SCHEDULE OF ATTACHMENTS To assist the Agency in understanding the information requested in items I and IIA, the following attachments are provided: 1) listing of production facilities by area, identified as Table 1 2) water balance summary/ identified as Table 2 3) outfall schematic and characterization/PPG Dwg 35A-10005,'identified as Figure 4) overall schematic of water flow, identified as Figure 2 5) detailed schematic of water flow by areas, 6 pages, identified as Figure 3-8 To support the information requested in item I IB, the following attachments are included: 1) schematic of Outfall 001 neutralization system, identified as Figure 9 2) schematic of lmhoff sanitary treatment system, identified as Figure 10 3) schematic of Sabine River water clarification system, identified as Figure 11 4) schematic of aerobic sanitary treatment system, identified as Figure 12 5) schematic of mercury treatment system, identified as Figure 13 schematic of asbestos treatment system, identified as Figure 14 - 7) schematic of Plant "B" wastewater collection and treatment system, identified as Figure 15 m 4 8) schematic of OHC-EDC wastewater treatment system, identified as Figure 16 / SL 049384 Table 1 PPG Industries, Inc. Lake Charles, La. CHEMICAL PLANT PRODUCTION FACILITIES Plant "A" Diaphragm Cell Chlor/Alkali facility producing; chlorine gas and liquid sodium hydroxide (caustic) Mercury Gell Chlor/Alkali facility producing: chlorine gas sodium hydroxide (caustic) hydrogen gas Plant "B" Chlorinated Hydrocarbon facilities producing: Perchloroethylene Trichloroethylene Vinyl chloride monomer (VCM) Ethyl chloride (EC) Me thy I chloroform (MC) Vinylidene chloride monomer (VDCM) Ethylene dichloride (EDC) by direct chlorination by oxychlorination Muriatic acid Plant "C" Diaphragm Cell Chlor/Alkali facility by producing: chlorine gas sodium hydroxide (caustic) hydrogen gas Silica Products Silicas facility producing amorphous silica products SL 049385 Power Facilities Pbwerhous A producing electric power and steam Powerhouse B producting electric power Powerhouse C producing electric power and steam 0493*6 Revised 5/2/83 TABLE 2 PPG Industries, Inc. Lake Charles, La. WATER BALANCE SUMMARY CONFIDENTIAL ENCLOSED IN SEPARATE ENVELOPE SL 049387 Kev/isea ou/66 TABLE 2 PPG Industries, Inc. Lake Charles, La. WATER BALANCE SUMMARY Incoming Water Sources Gallons Per Minute Calcasieu River Sabine River Well Water Kaw Brine Generated in process Neighboring industries 201,655 6,907 5,331 3,267 -87 _________________ m. Total 217,547 Effluent Water Discharges Gallons Per Minute flayou u'Inde * 186,400 Bayou Verdine (01 in Ditch) . 27,000 Atmosphere 3*695 Product *740 Field Lines (i.e., septic tank systems)_____________ Total 217,847 Sufcjuc r* of f . i*, v r\ ** ' C'e - J .1 %*: *- 1 \) .i.S _ ,**, l Orr.^r :t Court 049388 si> eo &-&M 3fw&7'Zm/^Arl ^?36 <S*=?W C^-^iLCZ-OIS'^47 ZOf,G5S SW <TO G?s=>a. f TcO SX^j-'Vc<Sw Q7&^.\1 TE>ATTM<Oi, -. e- CO o js VO Co 00 VO (ZOO <3*sV ULAT&Fl tO/StO/A S ct^s)vr /U&/cS/AXUr3 / VJ^S~7~ftJ'fcS~______ --Tnrmr^TT- T ^7~bx=t\ 1 UJTKg. 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T/O* V ~7&F9A'f 7^> c^utt^A LL <&o/ SL 049404 / r&^ATMs-A./t &-&-r /=L4AJT // // :,w C--=L-Lr&as&mal. -~ / CJ /^L^sr^/7- S4 " TtdL P/**S7S~<P. L FCTf/OfiJ *;* CZ&fiST74Mt/^4 TEO f &?./OS HROHf PLA^'T "CD " OBFIOBBTIftl; r OUT/=~Al.U 0/7 Subjec tt t)o-vj ^ri'rfoO,.' iaici'~ ^ Wo. 2i c. ^.rict Court ^fe&^gSTCJS' SfeX/OS 70 HAZAB&OUS PUH<&rr P*`Srje=*<S>S5s4L. 049405 m=p^A7DW&A/7' CHARADDT&P/&77CDS S/Z'ts- :aor (TAAX/PfUM 7%JZ0<~/<STUSfiDlS T^> 7~~: 0.04- /R^TS-fUT'/OH 71AAS : ^ HOURS * \* 4fT i*^. FIGURE "15 CHLORINATED HYDROCARBON WASTEWATER COLLECTION AND TREATMENT SYSTEM PLANT "B" ENCLOSED IN SEPARATE ENVELOPE cX SL 049406 ' 7~rC? 7~S=/g <^^^/-^CT57~/cr7A/ ^A/P ~T~?Z?Er^\ 7~7WF/V 7~~ ^V^r7^/W * f==:t^A /V 7~ ''fc* 7/ SL 049407 FIGURE 16 OHC-EDC WASTEWATER TREATMENT SYSTEM PLANT "8" uU NFIDENTIAL ENCLOSED IN SEPARATE ENVELOPE s\v Cr c<^VSVv; ^ v \6> 0, ^ *0 r' V ' , rtO A^> ^0\V .'V*O-. V SL 049408 SL 0494Q9 -j^/DCZ yj2g./g JO^4~/SS7~ tt O'- - v;. ,.A ' * V C . ' '' " sK* ,Ov c . rcv .,o>C> ^ 'S- <^p * 6 SL 049410 ,:o ,, o.- .^VT" '/ ' * -;' CP--V'---v 'V'*- O-, ' ' r. ,, ,. -\-- \ ..V \CU -'"AS ' 6^',^ l-` V-' : vh*`* -V SL 049411