Document ppRZM3ypzK2yzbk577ZMq1Yk7
Precise Research. Proven Results.
Attachment 2
^Bzz^r/77-^
Analytical Report
Air Sampling Fluorochemical Report
DuPont Washington Works - Air Sampling Program Round 11 Exygen Research Report No. L0001668
Testing Laboratory Exygen Research
3058 Research Drive State College, PA 16801
Requester Michael D Aucoin URS Corporation Barley Mill Plaza Building 27 Room 1260 Lancaster Pike and Rt 141 Wilmington, DE 19805
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 1 of 7
Summary
Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen Research) (Exygen) from DuPont Corporation. The media represent samples of air collected on OVS tubes. Please see Table 1 for a completed listing of samples received and field air volumes collected.
The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography / mass spectrometry (LCMS). The method employed is entitled "Method of Analysis for the Determination of Perfluorooctanoic Acid (PFOA) in OVS Airtubes by LCMS" (James Miller, Exygen Research, February 17, 2003).
The OVS tubes were separated into three fractions for specific fhiorochemical analysis. Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the first bed of XAD resin and the PUF backing. Fraction C contained the second bed of XAD resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (CIO Acid) was added as a surrogate spike to each fraction prior to extraction.
Instrument operating conditions can be found at the beginning of each analytical ran. Raw instrument data is given in Appendix A. Chain-of-custody information can be found in Appendix B.
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 2 of 7
C00516
Results Summary
Request #
WWK-A-AMS1-E11 A WWK-A-AMS1-E-11 B WWK-A-AMS1-E11 C WWK-A-AMS1-E11 (Total)
WWK-A-AMS2-E11 A WWK-A-AMS2-E11 B WWK-A-AMS2-E11 C WWK-A-AMS2-E11 (Total)
WWK-A-AMS3-E11A WWK-A-AMS3-E11 B WWK-A-EMS3-E11 C WWK-A-EMS3-E11 (Total)
WWK-A-AMS4-E11 A WWK-A-AMS4-E11B WWK-A-AMS4-E11 C WWK-A-AMS4-E11 (Total)
WWK-A-AMS5-E11 A WWK-A-AMS5-E11 B WWK-A-AMS5-E11C WWK-A AMS5-E11 (Total)
WWK-A-AMS6-E11 A WWK-A-AMS6-E11 B WWK-A-AMS6-E11 C WWK-A AMS6-E11 (Total)
Air Volume Sampled (L)
1398 1398 1398
1448 1448 1448
931 931 931
1424 1424 1424
1402 1402 1402
1434 1434 1434
C8 Acid (mg/m3)
< 0.00007 < 0.00007
NA <0.00014
< 0.00007 < 0.00007
NA <0.00014
< 0.0001 < 0.0001
NA < 0.0002
< 0.00007 < 0.00007
NA <0.00014
0.0003 < 0.00007
NA 0.0003
< 0.00007 < 0.00007
NA <0.00014
NA - Not Analyzed. B fraction was below the quantitation limit, therefore the backup fraction does not require analysis.
1. "<" is defined as not detected at or above the reported level.
2. Sample results have not been corrected for blank results or control spike recoveries.
3. Please note the following descriptions of the OVS sample tube fractions:
Fraction A B C
Fraction Description Frit Extract 1st set beads extract 2nd set beads extract (not analyzed)
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 3 of 7
G0 0 5 1 7
OC Data
LCS Please note: One control sample was spiked with each perfluorooctanoic acid to give a final concentration of 500 ppb. Air was pulled through the tube at a rate of 1-liter per minute for one hour (60 liters of air). The fractions were separated and analyzed. The acceptable range for control recovery is 75-125%.
Request # Control 1
C8 Acid (amount spiked - ppb)
500
C8 Acid (amount recovered - ppb)
509
C8 Acid (percent recovery
102
Blanks
Request # WWK-A-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B
Voi. Of Air (L) 0 0
C8 Acid (uq/fraction)
<0.10 <0.10
O o o rS l ATT. DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
C0
Page 4 of 7
Surrogates
A surrogate spike (CIO Acid) was added to all OVS tubes to give a final concentration of 500 ppb in the extract. Surrogate spike recoveries are given in the following table. There are no set criteria for surrogate spike recoveries. Advisory ranges are 75-125%.
Sample #
WWK-A-AMSFBLK-E11 A WWK-A-AMSFBLK-E11 B
W WK-A-AMS1-E11 A WWK-A-AMS1-E11 B W WK-A-AMS2-E11 A W WK-A-AMS2-E11 B W WK-A-AMS3-E11 A W WK-A-AMS3-E11 B W W K -A -A M S 4-E11 A W WK-A-AMS4-E11 B W WK-A-AMS5-E11 A WWK-A-AMS5-E11 B W WK-A-AMS6-E11 A WWK-A-AMS6-E11 B
Control Spike A Control Spike B
Amount Spiked
(Ppb) 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500
Amount Recovered
(PPb) 479 360 498 564 497 583 517 580 519 569 520 592 524 584 532 347
Percent Recovery
(% )
96 72* 100 113 99 117 103 116 104 114 104 118 105 117 106 69*
* Surrogate recovery outside of advisory range.
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 5 of 7
C C 05.9
Calculations
Request #
WWK-A-AMSFBLK-E11 A WWK-A-AMSFBLK-E11 B
WWK-A-AMS1 -E11 A WWK-A-AMS1 -E11 B WWK-A-AMS2-E11 A WWK-A-AMS2-E11 B WWK-A-AMS3-E11 A WWK-A-AMS3-E11 B WWK-A-AMS4-E11 A WWK-A-AMS4-E11 B WWK-A-AMS5-E11 A WWK-A-AMS5-E11 B WWK-A-AMS6-E11 A WWK-A-AMS6-E11 B
Control Spike A Control Spike B
Voi. Of Air (L) 0 0 1398 1398 1448 1448 931 931 1424 1424 1402 1402 1434 1434 0 0
C8 Acid (raw-ppb)
< 10 < 10 < 10 <10 <10 < 10
10 <10 <10 <10 434 <10 <10 <10 509 < 10
C8 Acid (ug/fraction)
<0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.43 <0.10 <0.10 <0.10
0.51 <0.10
C8 Acid (mg/m3)
< 0.00007 < 0.00007 < 0.00007 < 0.00007 < 0.0001 < 0.0001 < 0.00007 < 0.00007
0.0003 < 0.00007 < 0.00007 < 0.00007
a
& ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH 01
o?0
Page 6 of 7
Example Calculation For sample WWK-A-AMS5-E11 A C8 Acid,
[434 ng/ml of C8 Acid x (1ml) x (1 ug /1000 ng) x (1 mg /1000 ug) ] / [(1402 L) x (1 m3 / 1000 L)] 0.0003 mg / m3 Signatures
ohn M. Flaherty, Vice President Other Lab Members Contributing to Data James Miller
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 7 of 7
ANALYTICAL DATA REVIEW SHEET
LC/MS
fc. Hch
Analyst
J7 /y} ff) f/g j x & i y Reviewed by
S ta tu re /D a te
q/ W /Signature/Date '
U0Q8
Cn o
LC/MS SYSTEM AND OPERATING CONDITIONS
Client: Dupont
EXYGEN STUDY: L0001668
Instrument:
Hewlett-Packard 1100 LC/MSD (LC/MS 3) API-ES Interface - Negative SIM mode Nitrogen: 10 L/min at 300C Fragmentor: Variable; Vcap: 3500V
Computer:
Hewlett-Packard Kayak workstation
Software:
Microsoft Windows NT 4.0 Agilent ChemStation Version A.08.03
HPLC Equipment:
HP G1379A Solvent Degasser HP G1311A Quaternary Pump HP G1313A Autosampler HP G1316A Column Thermostat HP G1946A MSD
HPLC Column: Column Temp.: Mobile Phase (A): Mobile Phase (B):
Thermo Hypersil-Keystone Betasil C18, 30 x 2.0 mm x 3pm 35 C 2mM Ammonium acetate in OmniSolv Water HPLC grade Methanol
Time
%A
0.0 70
6.0 10
10.0
10
10.0
STOP
Post Time = 4 min.
Total run time = 14 min.
Flow Rate:
0.3 mL/min
Injected Volume: 5 pL
%B
30 90 90 STOP
Page 1 of 2
j Uu9
G0 0 5 2 3
Instrument : LCMS3 Wed Jan 07 09:11:11 2004
G1946: API_ES Negative mode Page 1 of 3
C :\HPCHEM\1\194 6TUNE\ATUNES.TUN
Scan: 50.00 - 3000.00 Samples: 8 Thresh: 0 Step: 0.10 29501 peaks Base: 2233.85 Abundance: 1132032 F Raw,Gauss 0.3 100 -,
80 -
60 -
20 -
1 '-- r--,-- >-- -i---- 1-- ' r 1 1.r.
500
1000
1500
11 2Q00
`11 2500
m/z gf Abund 112.99 80352 602.00 21400 1034.05 197568 1633.95 610624 2233.85 1132032
Rei Abund 100.00 26.63 245.88 759.94
1408.84
Iso m/z 113.98 602.99
1034.95 1634.95 2234.85
Iso Abund Iso Ratio
1768
2.20
3222
15.06
43112
21.82
217216
35.57
550720
48.65
0 ! 1
C005?5
Instrument : LCMS3 Wed Jan 07 09:11:11 2004
G1946: API_ES Negative mode Page 2 of 3
C:\HPCHEM\1\1946TUNE\ATUNES.TUN
Mode: API -ES Polarity: NEG
Fragment Skim2 Lensl Lens2 Iris
Gain
VAR WidthGain -128
6.0 WidthOffs VAR
-4.0 MassGain-36.30
18 MassOffs VAR
272
Energy
5.0
OpolPeak 300
OpolKnee 316
3.0 QuadDC
0.00
EMV VCap
Status: CapCur ChamCur
2358 Samples
8
4000 Averages
1
StepSize 0.10
55 DryingGas 6.0 0.82 Gas Temp 300
Quad Temp 99 Neb Pres
20
t y
uG ! 2
CCO526
Instrument : LCMS3 Wed Jan 07 09:11:11 2004
G1946: API_ES Negative mode Page 3 of 3
C:\HPCHEM\1\1946TUNE\ATUNES.TUN
Vl:' Mass Offset
Dynamic Parameter Ramp
Mass 112.99 1633.95
Setting 0.56 0.61
Mass 601.98 2233.91
Setting 0.62 0.56
Mass 1033.99
Setting 0.63
00 I3
C005^7
Sequence: C:\HPCHEM\1\SEQUENCE\012204 .S
Sequence Table:
Method and Injection Info Part:
Line Location SampleName
Method
Inj SampleType InjVolume DataFile
1 Vial 1 STD 50 ppb
FC8-10
__ 2_ Vial J.__ STD _5.Q ppb_______ FC8-10
3 Vial 2 STD 100 ppb
FC8-10
4 Vial 3 STD 250 ppb
FC8-10
5 Vial 4 STD 500 ppb
FC8-10
6 Vial 5 STD 750 ppb
FC8-10
7 Vial 6 STD 1000 ppb
FC8-10
8 Vial 7 STD 1500 ppb
FC8-10
9 Vial 92 solvent blank
FC8-10
10 Vial 11 L1668-22
FC8-10
11 Vial 12 L1668-23
FC8-10
12 Vial 13 L1668-1
FC8-10
13 Vial 14 L1668-2
FC8-10
14 Vial 15 L1668-4
FC8-10
15 Vial 16 L1668-5
FC8-10
16 Vial 17 L1668-7
FC8-10
17 Vial 18 LI 668-8
FC8-10
18 Vial 19 L1668-10
FC8-10
19 Vial 20 LI 668-11
FC8-10
20 Vial 4 STD 500 ppb
FC8-10
21 Vial 92 solvent blank
FC8-10
22 Vial 21 L1668-13
FC8-10
23 Vial 22 L1668-14
FC8-10
24 Vial 23 L1668-16
FC8-10
25 Vial 24 L1668-17
FC8-10
26 Vial 25 L1668-19
FC8-10
27 Vial 26 L1668-20
FC8-10
28 Vial 4 STD 500 ppb
FC8-10
29 Vial 92 solvent blank
FC8-10
30 Vial 1 STD 50 ppb
FC8-10
31 Vial 2 STD 100 ppb
FC8-10
32 Vial 3 STD 250 ppb
FC8-10
33 Vial 4 STD 500 ppb
FC8-10
34 Vial 5 STD 750 ppb
FC8-10
35 Vial 6 STD 1000 ppb
FC8-10
36 Vial 7 STD 1500 ppb
FC8-10
1 Sample 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 ' Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib
Calibration Part: Line Location SampleName
Method CalLev Update RF Update RT Interval
2 Vial 1 3 Vial 2 4 Vial 3 5 Vial 4 6 Vial 5 7 Vial 6 8 Vial 7 30 Vial 1 31 Vial 2 32 Vial 3 33 Vial 4 34 Vial 5 35 Vial 6 36 Vial 7
STD 50 ppb STD 100 ppb STD 250 ppb STD 500 ppb STD 750 ppb STD 1000 ppb STD 1500 ppb STD 50 ppb STD 100 ppb STD 250 ppb STD 500 ppb STD 750 ppb STD 1000 ppb STD 1500 ppb
FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10
1/22/04 4: 28: 51 PMi jmiller 7
1 Replace Average 2 Replace Average 3 Replace Average 4 Replace Average 5 Replace Average 6 Replace Average 7 Replace Average 1 Average Average 2 Average Average 3 Average Average 4 Average Average 5 Average Average 6 Average Average 7 Average Average
!4
-3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3
P, vv
r
Sequence : C:\HPCHEM\1\SEQUENCE\012204 .S
iCMS3 1/22/04 4:28:51 PM jmiller
?
uO 0
Page 2 of 2 ccor.na
Method C:\HPCHEM\1\METHODS\012204.M Calibration Table
Calib. Data Modified
Thursday, February 26, 2004 10:08:53 AM
1 Calculate Based on
External Standard Peak Area
I Rel. Reference Window ' Abs. Reference Window
Rel. Non-ref. Window Abs _ Non-ref. Window Uncalibrated Peaks Partial Calibration Correct All Ret. Times
5.000 % 0.000 min 5.000 % 0.000 min not reported Yes, identified peaks are recalibrated No, only for identified peaks
Curve Type Origin Weight
Linear Ignored Equal
Recalibration Settings Average Response Average Retention Time
Average all calibrations Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1 : MSD1 369, EIC= 368.7:369.7 Signal 2 : MSD1 469, EIC= 468.7:469.7
RetTime Lvl Amount
Area
[min] Sig
[ppb]
-------I - I - I
7.238 1 1 50.00000 ^2.54854e4
2 100.00000 5.21298e4
3 250.00000 1.38928e5
4 500.00000 2.68105e5
5 750.00000 3.95712e5
6 1000.00000 5.07448e5
7 1500.00000 7.25598e5
8.109 2 1 50.00000 7.14014e4
2 100.00000 1.43567e5
3 250.00000 3.67689e5
4 500.00000 6.92756e5
5 750.00000 1.00164e6
6 1000.00000 1.26065e6
7 1500.00000 1.75606e6
Amt/Area
^1.96191e-3 1.91829e-3 1.79949e-3 1.86494e-3 1.89532e-3 1.97064e-3 2.06726e-3 7.00266e-4 6.96541e-4 6.79922e-4 7.21754e-4 7.48773e-4 7.93240e-4 8.54185e-4
Ref Grp Name 1 C8 Acid
1 CIO Surrogate
More compound-specific settings:
Compound: C8 Acid Time Window
: From 7.066 min To 8.067 min
Compound: CIO Surrogate Time Window
: From 7.913 min To 8.718 min
Peak Sum Table
***No Entries in table*** C00414 2/26/04 10:10:50 AM jmiller
0 016
Method C:\HPCHEM\1\METHODS\012204.M
Calibration Curves
C8 Acid at exp. RT: 7.238
MSD1 369, EIC=3 68.7:369.7
Correlation:
0.99866
Residual Std. Dev.: 14581.78795
Formula: y = mx + b
m: 485.91764
b: 13835.67745
x: Amount[ppbl____________
y: Area
CIO Surrogate at exp. RT: 8.109
MSD1 469, EIC=468.7 :469.7
Correlation:
0.99690
Residual Std. Dev.: 53527.29878
i Formula: y = mx + b m: 1170.89142
b: 62080.82414
x: Amount[ppb]
y: Area
300414 2/26/04 10:10:50 AM jmiller
U0 : /
Page 2 of 2
ooosn i
Sample Name:STD 50 ppb Sample Info:Warm Up Injection
Data file :C :\HPCHEM\l\DATA\Chemstor\12087705\A521536\FC000001.D
1
C8 Acid -- CIO Surrogate
26327.43 76333.71
25.71 12.17
7.261 8.134
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:12:17 am
U0 18
Page 1 of 1
c corroo
Sample Name:STD 50 ppb Sample Info :
Data file :C :\HPCHEMU\DATA\Chemstor\12080405\A589376\FC000002.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
4:53:38 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : :
Acq. Method
FC8-10 .M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
... Last Changed
: 2/26/04_____________ 10:08:53 am
2 1 1 5 pi
1
Compound Name
C8 Acid -CIO Surrogate
Area
26027.72 74031.62
Amount
25.09 10.21
Meas. Ret. T
Signal Desc.
7.246 8.116
MSD1 369, EIC=3 68.7:369.7 MSD1 469, EIC=468.7:469.7
*** End of Report ***
PC00414
Thu, 26. Feb. 2004
10:09:41 am
Q !9
Page 1 of 1
C0 0 5 3 3
Sample Name:STD 100 ppb Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12080464\A591808\FC000003.D
1
C8 Acid ,,CIO Surrogate
53601.73 148148.97
81.84 73.51
7.246 8.116
*** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
1 PC00414
Thu, 26. Feb. 2004
10:13:00 am
Q02Q
Page 1 of 1
C- 0 0 5 3 4
Sample Name:STD 250 ppb Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12080548\A593984\FC000004.D
1
C8 Acid ,,CIO Surrogate
142444.72 376511.78
264.67 268.54
7.237 8.105
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:13:41 am
0 0 21
Page 1 of 1
0 705.75
Sample Name:STD 500 ppb Sample Info :
Data file :C:\HPCHEM\l\DATA\Chemstor\12080667\A596224\FC000005.D
1
C8 Acid CIO Surrogate
270860.69 703836.19
528.95 548.09
7.232 8.104
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
Q22
10:14:18 am
Page 1 of 1
009536
Sample Name:STD 750 ppb Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12088166\A532672\FC000006.D
Injection Date Acq Operator Instrument Dilution
Acq. Method Analysis Method Last Changed
1/22/04 jmi H e r PC00414 1
5:55:53 PM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
FC8-10.M
C :\HPCHEMN1\METHODS\012204.M
2/26/04
10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
6 5 1 5 pi
1
C8 Acid ,,.CIO Surrogate
397814.34 1009547.12
790.21 809.18
7.226 8.102
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
02 3
10:15:15 am
Page 1 of 1
CO0 5 3 7
Sample Name:STD 1000 ppb Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12088281\A534720\FC000007.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
6:11:29 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
Acq. Method
FC8-10.M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
Last Changed
: 2/26/04______________10:08:53 am
7 6 1 5 pi
1
Compound Name
C8 Acid CIO Surrogate
Area
514972.75 1274229.88
Amount
1031.32 1035.24
Meas. Ret. T
Signal Desc.
7.235 8.108
MSD1 369, EIC =368.7 :369.7 MSD1 469, EIC=468.7 :469.7
*** End of Report ***
PC00414
Thu, 26. Feb. 2004
0024
10:15:59 am
Page 1 of 1
CC0538
Sample Name:STD 1500 ppb Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12080979\A602816\FC000008.D
Injection Date | Acq Operator
Instrument Dilution
Acq. Method Analysis Method Last Changed
1/22/04 jmiller PC00414 1
6:27:05 PM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
FC8-10 .M
C :\HPCHEM\1\METHODS\012204 .M
2/26/04
10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
8
7
1
5 ul
1
C8 Acid ,C10 Surrogate
737835.69 1784410.75
1489.96 1470.96
7.237 8.105
*** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
?C00414
Thu, 26. Feb. 2004
10:16:50 am
U 'o
Page 1 of 1
c00539
Sample Name:solvent blank Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12088595\A539136\FC000009.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
6:42:34 PM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
Acq. Method Analysis Method Last Changed
FC8-10 .M
C :\HPCHEM\l\METHODS\012204.M
2/26/04
10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
9 92
1 5 pi
1
C8 Acid ,,,,CIO Surrogate
0.00 2059.66
0.00 0.00
0.000 8.108
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7 :469.7
>C00414
Thu, 26. Feb. 2004
026
10:18:53 am
Page 1 of 1
C0 0 5 4 0
Sample Name:L1668-22 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12088763\A541184\FC000010.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
6:58:07 PM
Seq Line Vial No. Inj.No. Inj. Voi.
: : : :
Acq. Method
FC8-10 .M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
Last Changed
: 2/26/04______________10:08:53 am
10 11
1 5 pi
1
Compound Name
C8 Acid CIO Surrogate
Area
261058.59 684950.62
Amount
508.78 531.96
Meas. Ret. T
Signal Desc.
7.232 8.104
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
*** End of Report ***
PC00414
Thu, 26. Feb. 2004
UU27
10:20:04 am
Page 1 of 1
C00543.
Sample Name :L1668-23 Sample Info :
Data file :C:\HPCHEM\l\DATA\Chemstor\12088932\A543360\FC000011.D
1
C8 Acid -CIO Surrogate
16576.66 468416.38
5.64 347.03
7.239 8.111
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
28
10:21:21 am
Page 1 of 1
000542
Sample Name:Ll668-1 Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12089100\A545408\FC000012.D
1
C8 Acid ,,CIO Surrogate
3786.80 623131.69
0.00 479.17
7.234 8.110
*** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
[ PC00414
Thu, 26. Feb. 2004
10:21:58 am
029
Page 1 of 1
000543
Sample Name:L1668-2 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12089269\A547456\FC000013.D
1
C8 Acid ..10 Surrogate
3055.95 483225.03
0.00 359.68
7.234 8.108
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
,I ,, ?C00414
Thu, 26. Feb. 2004
10:22:41 am
Page 1 of 1
C^05A4
Sample Name:L1668-4 Sample Info :
Data file :C :\HPCHEM\l\DATA\Chemstor\12089437\A549632\FC000014.D
Injection Date Acq Operator Instrument _ Dilution
1/22/04 jmiller PC00414 1
8:00:24 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
Acq. Method Analysis Method r-- Last Changed
FC8-10.M
C :\HPCHEM\1\METHODS\012204.M
2/26/04
10:08:53 am
14 15
1 5 pi
1
Compound Name
C8 Acid CIO Surrogate
Area
4345.78 645270.00
Amount
0.00 498.07
Meas. Ret. T
Signal Desc.
7.231 8.106
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
*** End of Report ***
?C00414
Thu, 26. Feb. 2004
UQ3 !
10:24:18 am
Page 1 of 1
C O O r;/! K
Sample Name :L1668-5 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12089605\A551680\FC000015.D
1
C8 Acid -CIO Surrogate
4645.49 722482.75
0.00 564.02
7.237 8.116
*** End of Report ***
MSD1 369, EIC =368.7:369.7 MSD1 469, EIC=468.7:4 6 9 . 7
! PC00414
Thu, 26. Feb. 2004
10:24:53 am
uUoZ Page 1 of 1
0 0 0 5 4 .6
Sample Name:L1668-7 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\1208980 0\A554112\FC000016.D
"" Injection Date Acq Operator
Instrument , . Dilution f
: 1/22/04 : jmiller : PC00414 :1
8:31:39 PM
Seq Line Vial No. Inj . No. Inj . Voi.
: : : :
16 17
1 5 pi
1
C8 Acid .,,CIO Surrogate
18158.58 643424.06
8.90 496.50
7.242 8.112
*** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC =468.7:469.7
I, PC00414
Thu, 26. Feb. 2004
10:25:47 am
0033
Page 1 of 1
C0 0 5 4 .7
Sample Name:LI668-8 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12089968\A556032\FC000017.D
1
C8 Acid CIO Surrogate
4804.49 744889.56
0.00 583.15
7.240 8.110
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
i" I
I-
[ PC00414
Thu, 26. Feb. 2004
u 3 4
10:26:36 am
Page 1 of 1
Sample Name :L1668-10 Sample Info :
Data file :C :\HPCHEM\l\DATA\Chemstor\12090137\A558272\FC000018.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
9:02:55 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
18 19
1 5 pi
Acq. Method Analysis Method L ast C h a n g e d __
FC8-10.M C :\HPCHEM\1\METHODS\012204.M 2/26/04______________10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM2090137\A558272\FC000018.D) 2500
API-ES, Neg, SIM . Frag: Var 7 .2 3 5 - C8 Acid
2000-
1500-
1000
500-
X-
MSD1 469, EIC=468.7:469.7 (CHEM STO RM 2090137\A558272\FC000018.D ) API-ES, Neg, SIM, Frag: Var 8 .1 1 2 - C10 Surrogate
80000
60000
40000 -
20000
1
.' Compound Name
C8 Acid -CIO Surrogate
---- !---- ,---- -- -,---- 1---- ,--- ' 24
'1 6
Area
Amount Meas. Ret. T
1j
i1
8
Signal D e s c .
i
min
18462.77 667939.62
9.52 517.43
7.235 8.112
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7 :469.7
** End of Report **
I PC00414
Thu, 26. Feb. 2004
U35
10:27:58 am
Page 1 of 1
CO0 5 1 9
Sample Name :L1668-11 (*" Sample Info :
1 Data file :C:\HPCHEM\l\DATA\Chemstor\12090306\A560448\FC000019.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
9:18:34 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
Acq. Method
FC8-10.M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
Last Changed____ : 2/26/04_____________ 10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
19 20
1 5 pi
1
C8 Acid ,,,,CIO Surrogate
4648.05 741114.31
0.00 579.93
7.240 8.111
I ===================================================== *** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
9C00414
Thu, 26. Feb. 2004
10:29:12 am
U036
Page 1 of 1
C00550
Sample Name:STD 500 ppb Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12090474\A562368\FC000020.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
9:34:09 PM
Seq Line Vial No. Inj . No . Inj. Voi.
: : : :
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\012204.M
2/26/04
10:08:53 am
20 4 1
5 pi
1
Compound Name
C8 Acid *C10 Surrogate
Area
266118.88 688464.50
Amount
519.19 534.96
Meas. Ret. T
Signal Desc.
7.239 8.110
MSDl 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
*** End of Report ***
PC00414
Thu, 26. Feb. 2004
10:29:46 am
U037
Page 1 of 1
CO0 5 5 1
Sample Name:solvent blank Sample Info :
Data file :C :\HPCHEM\l\DATA\Chemstor\12090696\A564608\FC000021.D
Injection Date : 1/22/04
Acq Operator
: jmiller
Instrument
: PC00414
, Dilution
:1
9:49:37 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
21 92
1 5 pi
1
C8 Acid ,,4310 Surrogate
0.00 1266.68
0.00 0.00
0.000 8.117
*** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC =468.7 :469.7
!" [ PC00414
Thu, 26. Feb. 2004
UU38
10:30:23 am
Page 1 of 1
Co g r r o
Sample N a m e :L1668-13 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12090837\A566720\FC000022.D
Injection Date Acq Operator Instrument ^ Dilution
1/22/04 jmiller PC00414 1
10:05:14 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
Acq. Method Analysis Method Last Changed
FC8-10.M C :\HPCHEM\1\METHODS\012204 .M 2/26/04_____________ 10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
22 21
1 5 ul
1
C8 Acid ,,,,CIO Surrogate
5714.06 669559.87
0.00 518.82
7.241 8.113
*** End of Report ***
MSD1 369, EIC =368.7 :369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:31:13 am
U39 Page 1 of 1
C00553
Sample Name :LI668-14 Sample Info :
Data file :C:\HPCHEM\l\DATA\Chemstor\12091032\A568704\FC000023.D
1
C8 Acid -- CIO Surrogate
4615.60 728402.94
0.00 569.07
7.227 8.103
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:31:46 am
U4
Page 1 of 1
C0 0 5 5 4
Sample Name :L1668-16 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12091175\A571008\FC000024.D
Injection Date Acq Operator Instrument , Dilution
1/22/04 jmiller PC00414 1
10:36:21 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
24 23
1 5 pi
Acq. Method Analysis Method Last C h a n g e d _
FC8-10.M C:\HPCHEM\1\METHODS\012204 .M 2/26/04 _________ 10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORVI2091175\A571008\FC000024.D) 30000
API-ES, Neg, SIM, Frag: Var 7.233 - C8 Acid
25000 -
20000 -
15000
10000
5000
MSD1 469, EIC=468.7:469.7 (CHEMSTORYI2091175\A571008\FC000024.D)
API-ES, Neg, SIM, Frag: Var
8
8 .1 0 8 - C10 Surrogate
80000
60000
40000 -
20000 -
1
Compound Name
C8 Acid ,,C10 Surrogate
Area
224633.11 670680.00
Amount
433.81 519.77
Meas. Ret. T
Signal Desc.
7.233 8.108
MSD1 369, EIC=3 68.7:369.7 MSD1 469, EIC=468.7:469.7
*** End of Report ***
PC00414
Thu, 26. Feb. 2004
10:32:33 am
U 04
Page 1 of 1
C00555
Sample Name:L1668-17 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12091264\A573120\FC000025.D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmi H e r PC00414 1
10:51:57 PM
Seq Line Vial No. Inj. No. Inj. Voi.
25 24
1 5 pi
1
C8 Acid CIO Surrogate
6979.76 755673.00
0.00 592.36
7.242 8.116
'* End of Report
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:36:14 am
0042
Page 1 of 1
C0 0 5 5 6
Sample Name :L1668-19 Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12091353\A575168\FC000026.D
"" Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
11:07:32 PM
Seq Line Vial No. Inj . N o . Inj. Vol.
: : : :
Acq. Method
FC8-10.M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
Last Changed____ : 2/26/04______________ 10 :08 :53 am
LC/MS analysis of perfluorooctanoic acid.
26 25
1 5 pi
1
C8 Acid .CIO Surrogate
4094.76 675171.81
0.00 523.61
7.245 8.116
*** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7 :469.7
S PC00414
Thu, 26. Feb. 2004
0043
10:36:59 am
Page 1 of 1
C0 0 5 5 7
Sample Name:L1668-20 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12091442\A577280\FC000027.D
1
C8 Acid CIO Surrogate
4583.95 746394.00
0.00 584.44
7.241 8.114
*** End of Report ***
MSDl 369, EIC =368.7:369.7 MSDl 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:37:50 am
U44
Page 1 of 1
C00558
Sample Name:STD 500 ppb Sample Info:
1
Data file :C :\HPCHEM\l\DATA\Chemstor\12091531\A579328\FC000028 .D
Injection Date Acq Operator Instrument Dilution
1/22/04 jmiller PC00414 1
11:38:43 PM
Seq Line Vial N o . Inj. No. Inj. Voi.
: : : :
28 4 1
5 pi
Acq. Method
FC8-10.M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
Last Changed____ : 2/26/04______________10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEM STO R\12091531\A 579328\FC000028.D) API-ES, Neg, SIM , Frag: t/ar
35000 -j
7.236- C8 Add
30000
25000 j
20000 j
15000 -j
10000 j
5000-
o-
-, .1 T1T J*
J`
1
1 1 1 1 i-----------r
2 4 6 8 min
*MSD1 469, EIC=468.7:469.7 (C H E M S T O R U 2091531 \A579328\FC000028.D) API-ES, Neg, SIM , Frag: Var
8 .1 1 2 - C 10 Surrogate
80000-
60000-
40000-
20000-
11 Compound Name
1
2
11 Area
r
1 11 1T
^
46
Amount Meas. Ret. T
Ji l ` 1I 8
Signal Desc.
min
C8 Acid CIO Surrogate
262699.81 676727.56
512.15 524.94
7.236 8.112
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7 :469.7
*** End of Report ***
[ PC00414
Thu, 26. Feb. 2004
10:39:50 am
U45 Page 1 of 1
CO0559
Sample Name :solvent blank Sample Info: I Data file :C:\HPCHEM\l\DATA\Chemstor\12091618\A581376\FC000029.D
1
C8 Acid -CIO Surrogate
0.00 1524.46
0.00 0.00
0.000 8.114
*** End of Report ***
MSDl 369, EIC =368.7 :369.7 MSDl 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
U4 6
10:40:22 am
Page 1 of 1
C0 0 5 6 0
Sample Name:STD 50 ppb Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12082179\A650816\FC000030.D
Injection Date Acq Operator Instrument Dilution
1/23/04 jmiller PC00414 1
12:09:44 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
Acq. Method
FC8-10.M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
r>,, Last Changed
: 2/26/04______________10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
30 1 1
5 pi
1
C8 Acid CIO Surrogate
24847.55 70223.10
22.66 6.95
7.237 8.111
*** End of Report ***
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
i.TM,. PC00414
Thu, 26. Feb. 2004
10:41:01 am
uU47
Page 1 of 1
C0 0 5 6 1
Sample Name:STD 100 ppb Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12082231\A652800\FC000031.D
1
C8 Acid -,C10 Surrogate
50641.38 140791.94
75.74 67.22
7.237 8.114
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:42:43 am
U0 48
Page 1 of 1
C005G2
Sample Name:STD 250 ppb Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12082266\A654848\FC000032.D
1
C8 Acid .CIO Surrogate
135673.20 362435.00
250.74 256.52
7.238 8.111
*** End of Report ***
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC =468.7:469.7
PC00414
Thu, 26. Feb. 2004 10:44:26 am
0 0 49
Page 1 of 1
C00563
Sample Name:STD 500 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\12092002\A590208\FC000033.D
Injection Date Acq Operator Instrument Dilution
Acq. Method Analysis Method Last Changed
1/23/04 jmiller PC00414 1
12:56:24 AM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
FC8-10 .M
C:\HPCHEM\1\METHODS\012204.M
2/26/04
10:08:53 am
33 4 1
5 pi
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEM STO R\12092002\A590208\FC000033.D) API-ES, Neg, SIM , Frag: Zar 7 .2 4 5 - C8 Acid
35000 -
30000 j
25000 -j
20000 ^
V-,, 15000
10000^
5000
!-<mTM
01
, , - 1 1 ' 1 T 1^ I
1 1 1 1 1---- r
2 4 6 8 min
*MSD1 469, El0=468.7:469.7 (CHEM STO R\12092002\A 590208\FC000033.D) API-ES, Neg, SIM , Frag: Var
8 .1 1 3 - C10 Surrogate
80000 -
60000-
40000 -
20000 -
,
Compound Name
C8 Acid -- CIO Surrogate
,,.i
2
Area
265541.34 682697.50
,iri1
46
Amount Meas. Ret. T
l1 i i f- 1 1
8
Signal Desc.
1I
min
518.00 530.04
7.245 8.113
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
*** End of Report ***
PC00414
Thu, 26. Feb. 2004
10:45:11 am
Q5
Page 1 of 1
CC05fi4
Sample Name:STD 750 ppb Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12092091\A592256\FC000034 .D
Injection Date Acq Operator Instrument Dilution
Acq. Method Analysis Method Last Changed
1/23/04 jmi H e r PC00414 1
1:12:01 AM
Seq Line Vial N o . Inj. No. Inj. Vol.
: : : :
FC8-10.M
C:\HPCHEM\1\METHODS\012204.M
2/26/04
10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
34 5 1
5 pi
1
C8 Acid ,,CIO Surrogate
393610.00 993731.13
781.56 795.68
7.236 8.103
*** End of Report ***
MSD1 369, EIC =368.7 :369.7 MSD1 469, EIC=468.7:469.7
PC00414
Thu, 26. Feb. 2004
10:45:45 am
U5 1
Page 1 of 1
0-^0565
Sample Name:STD 1000 ppb Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\12092180\A594368\FC000035.D
Injection Date Acg Operator Instrument Dilution
1/23/04 jmiller PC00414 1
1:27:37 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
Acq. Method
FC8-10.M
Analysis Method : C:\HPCHEM\1\METHODS\012204.M
:-i, Last Changed____ : 2/26/04______________10:08:53 am
LC/MS analysis of perfluorooctanoic acid.
35 6 1
5 pi
1
C8 Acid ,,.CIO Surrogate
499924.22 1247075.87
1000.35 1012.05
7.238 8.115
*** End of Report ***
MSD1 359, EIC =368.7:369.7 MSD1 469, EIC =468.7:469.7
! PC00414
Thu, 26. Feb. 2004
10:46:12 am
u 0 5.
Page 1 of 1
COQSfiG
Sample Name:STD 1500 ppb Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\12087617\A519552\FC000036.D
Injection Date Acq Operator Instrument Dilution
Acq. Method Analysis Method Last Changed
1/23/04 jmiller PC00414 1
1:43:15 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: :
:
FC8-10 .M
C:\HPCHEM\1\METHODS\012204.M
2/26/04
10:08:53 am
36 7 1
5 pi
1
Compound Name
C8 Acid CIO Surrogate
Area
713993.87 1732682.13
Amount
1440.90 1426.78
Meas. Ret. T
Signal Desc.
7.239 8.108
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7 :469.7
*** End of Report ***
PC00414
Thu, 26. Feb. 2004
10:46:54 am
U053
Page 1 of 1
G00567
(.
3058 Research Drive
Phone: 814-272-1039
State College, PA 16801 H
Fax: 814-231-1580
r
#:
Project:
P0000419
Conform COC:
True
f Project Storage: ----------------------------------------------------------------------------------- Conform Sample :----------- True
Company Name: DuPont de Nemours & Co, Inc.
Conform Request:
True
Submitted By:
Michael D. Aucoin
Login Type:
Immediate Receipt of Samples
Started:
T
Date Start:
01/19/2004
Due Date:
02/02/2004
Received Date: 01/17/2004
Received By:
AMMERMAN, MARK
Spread Sample:
Label:
Project Title/Type: Analysis of PFOA in OVS Tubes / ROUTINE
Exygen SD/PI: MILLER, JAMES
Login Notes:
Conform Notes:
Package PK0002257
Carton
Packages / Containers
Mail Date / Condition
S h ip p e r/ ID
1/17/2004 12:00:56PM Package & Contents Uncompromised
FEDEX 8363912984560200
Temp. Control/Temp.
None 23.3
Direction / Handled By
R E C E IV E D AMMERMAN, MARK
Container #
C0026159 , C0026160 C0026161 C0026162 C0026163 C0026164 C0026165 C0026166 C0026167 C0026168 C0026169 C0026170 C0026171 C0026172 C0026173 CD026174 C0026175 C0026176 C0026177 C0026178 C0026179 C0026180 C0026181 C0026182
Gross W eight
6.3 g 6.3 g 6.3 g 6.1 g 6.1 g 6.1 g 6.3 g 6.3 g 6.3 g 6.1 g 6.1 g 6.1 g 6.2 g 6.2 g 6.2 g 6.2 g 6.2 g 6.2 g 6.1 g 6.1 g 6.1 g 6.3 g 6.3 g 6.3 g
pH
M iscellaneous Item Key None
1/19/2004 Login.rpt
Container Type Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other
Description
Preservative NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE
ICOC
U 0 54
R e p o rt V ersio n : D e c 22 2003 10:44AM
Page 1 of 4
M fg. Lot
Instance:
Mfg. ID
R0080976 R0080976
Login
Sample ID L0001668-0001 L0001668-0002 . L0001668-0003 L0001668-0004 L0001668-0005 L0001668-0006
L0001668-0008 L0001668-0009 L0001668-0010 L0001668-0011 L0001668-0012 L0001668-0013 .... L0001668-0014 L0001668-0015 L0001668-0016 L0001668-0017 L0001668-0018 L0001668-0019 L0001668-0020 L0001668-0021 L0001668-0022 L0001668-0023 L0001668-0024
Matrix GAS GAS GAS GAS GAS GAS
GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS
Fraction OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes
OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes
Samples
Sample WWK-A-AMSFBLK-E11 A WWK-A-AMSFBLK-E11 B WWK-A-AMSFBLK-E11 C WWK-A-AMS1 -E11 A WWK-A-AMS1-E11 B W W K-A-AM S 1-E 11 C
WWK-A-AMS2-E11 B WWK-A-AMS2-E11 C WWK-A-AMS3-E11 A WWK-A-AMS3-E11 B WWK-A-AMS3-E11 C WWK-A-AMS4-E11 A WWK-A-AMS4-E11 B WWK-A-AMS4-E11 C WWK-A-AMS5-E11 A WWK-A-AMS5-E11 B WWK-A-AMS5-E11 C WWK-A-AMS6-E11 A WWK-A-AMS6-E11 B WWK-A-AMS6-E11 C Control 1 A Control 1 B Control 1 C
Date Sampled Date Received
01/16/2004 01/17/2004
01/16/2004 01/17/2004
01/16/2004 01/17/2004
01/16/2004 01/17/2004
01/16/2004 01/17/2004
01/16/2004 m /ie/onn/1
01/17/2004 rH /1 7 /o n n x
01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004 01/16/2004
01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004 01/17/2004
Date Due 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 m inom n*
02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004 02/02/2004
1/19/2004 Login.rpt
U 0 55
Report Version: Dec 22 2003 10:44AM Page 2 of 4
Instance: 009569
R0080976 R0080976
L0001668-0001
Container
C 0026159/ Other /N O N E
L0001668-0002
Container
C0026160 / Other / NONE
L0001668-0003
Container
C 0026161 / O th e r/N O N E
"L0001668-0004
Container
C 0026162/O ther/N O N E
L0001668-0005
r,,>. Container
C 0026163/ Other /N O N E
L0001668-0006
Container
C0026164 / Other / NONE
L0001668-0007
Container
... C 0026165/O ther/N O N E
L0001668-0008
Container
C 0026166/ Other /N O N E
,,L0001668-0009
Container
C 0026167/O ther/N O N E
L0001668-0010
Container
- C 0026168 / Other / NO NE
L0001668-0011
Container
C 0026169/ Other /N O N E
- L 0 0 0 1 668-0012
Container
C002617 0 /O th er/N O N E
_ 1/19/2004
Bottles
Method
Method
Method
Method
Method
Method
Method
Method
Method
Method
Method
Method
u 0 b6
Report Version: Dec 22 2003 10:44AM
Instance:
R0080976 R0080976
L0001668-0013
Container
C0026171 / O ther/N O N E
Login
Method
L0001668-0014
Container
C 0026172/ Other / NONE
Method
L0001668-0015----------------------------------------------------------------
Container
C 0026173/O ther/N O N E
Method
L0001668-0016
Container
C 0026174/O ther/N O N E
Method
L0001668-0017
Container
C 0026175/O ther/N O N E
Method
L0001668-0018
Container
C0026176 / Other / NONE
Method
L0001668-0019
Container
C 0026177/O ther/N O N E
Method
L0001668-0020
Container
C0026178/ Other/ NONE
Method
L0001668-0021
Container
-- 0 0 0 2 6 1 7 9 /O ther/N O N E
Method
L0001668-0022
Container
C 0026180/ Other /N O N E
Method
--L0001668-0023
Container
C0026181 / Other / NONE
Method
L0001668-0024
Container
-- C 0026182/O ther/ NONE
Method
1/19/2004 Login.rpt
JU57
Report Version: Dec 22 2003 10:44AM
Page 4 of 4
Instance:
c
R0080976 R0080976
CHAIN OF CUSTODY/ANALYSIS REQUEST FORM
Exygen Research Sample Receiving * 3 1 1 7 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com
II P a g e __ _ o f _ J ___
Sam plers): SO, RK, LK
DuPont Washington Works Air Sampling Program
FedEx Airbill #: 836391298456
Event Number
669842 669908 669901 669890 669796 669865 Hours
0 1 2 3 4
AMS-1 AMS-2 AMS-3 AMS-4 AMS-5 AMS-6 Minutes
0 60 120 180 240
WW K-A-AM S1-E11 WWK-A-AMS2-E11 WWK-A-AMS3-E11 WW K-A-AM S4-E11 WWK-A-AMS5-E11 WWK-A-AMS6-E11
Hours 5 6 7 8 9
0.9970 1.0160 1.0200 1.0180 1.0210 1.0150 Minutes
300 360 420 480 540
Field Blank: yes WWK-K-AMSFBLK-E11 yes or no
Weather: 1/15 Cold, aljout 27 F, snow flurries, windy
1/16 Cold, bout 18 F, clear, breezy
15-Jan 15-Jan 15-Jan 15-Jan 15-Jan 15-Jan Hours
10 11 12 13 14
0700 0625 0627 0632 0638 0647 Minutes 600 660 720 780 840
16-Jan 16-Jan 16-Jan 16-Jan 16-Jan 16-Jan Hours
15 16 17 18 19
0620 0635 0637 0658 0645 0722 Minutes 900 960 1020 1080 1140
0.9794 0.9739 1.0130 1.0140 0.9687 1.0330 Hours
20 21 22 23 24
Event 11
1398 1448 ` 931 1424 1402 1434 Minutes 1200 1260 1320 1380 1440
SAFER operational:
yes yes or no
Comments: Total minute s column is the reading from the monitor counter.
* AMS-3 was still running when we collected the sample after about 1410 minutes, but the counter only read 931 minutes.
CO r LC O c o
Os
L-O *111J ---\
f
1/16/2004
Page 1 of 2
airdataeventl 1
C ^0574
DuPont Washington Works Air Sampling Program
Sampler(s): SO, RK, LK
FedEx Airbill #: 836391298456
Event Number
669842 669908 669901 669890 669796 669865 Hours
0 1 2 3 4
AMS-1 AMS-2 AMS-3 AMS-4 AMS-5 AMS-6 Minutes
0 60 120 180 240
WWK-A-AMS1 -E1 1 WWK-A-AMS2-E11 WWK-A-AMS3-E11 WWK-A-AMS4-E11 WWK-A-AMS5-E11 WWK-A-AMS6-E11
Hours 5 6 7 8 9
0.9970 1.0160 1.0200 1.0180 1.0210 1.0150 Minutes
300 360 420 480 540
Field Blank: yes WWK-K-AMSFBLK-E11 yes or no
WB m m m m m w m m 15-Jan 0700 16-Jan 15-Jan 0625 16-Jan 15-Jan 0627 16-Jan 15-Jan 0632 16-Jan 15-Jan 0638 16-Jan 15-Jan 0647 16-Jan Hours Minutes Hours
10 600 15 11 660 16 12 720 17 13 780 18 14 840 19
0620 0635 0637 0658 0645 0722 Minutes 900 960 1020 1080 1140
0.9794 0.9739 1.0130 1.0140 0.9687 1.0330 Hours
20 21 22 23 24
Weather: 1/15 Cold, about 27 F, snow flurries, windy
1/16 Cold, cbout 18 F, clear, breezy
Event 11
1398 1448 *931 1424 1402 1434 Minutes 1200 1260 1320 1380 1440
Total Volume
1383 liters 1443 liters *946 liters 1489 liters 1440 liters 1510 liters
O vO
CD CD
SAFER operational
yes yes or no
Comments: Total minute;s column is the reading from the monitor counter,
AMS-3 was still running when we collected the sample after about 1410 minutes, but the counter only read 931 minutes.
1/28/2004
Page 1 of 2
airdataeventl 1
RESEARCH ' Precise Research.
Proven Results.
Sample "Condition Upon Receipt" Form
Protocol#
Oac^a^/f?
Exygen Study #
oo /6-Cif
Date & Time Received
O/J *1/0*4 /Ic o
Condition of Samples
Temporary Storage Location
Pciv
Initials & Date
/id(4 cs/r?/ff
Waybill #
r?6 i 9 /^
____________________
Comments:
A /C r /-/- cJy
a`'Z /'7 /i*
M ay 24, 2002/3
Q:'W ORD proeess-logm\SampleConditiononReceipt.doc
6 1
3053 Research Drive State College, PA 16801, USA
T: 8 0 0 .2 8 1 .3 2 1 9
F: 814.272.1019
cyj5Bn.com
UQ62
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