Document pp38RGQyQjaaRDV7LrmNNXzyE
BFG TECHNICAL DOCUMENT
MINUTES
VINYL CHLORIDE SAFETY ASSOCIATION MEETING Atlanta, Georgia
February 27, 1976
Distribution List*
E. L. Beeler W. E. Brodlne H. R. Calsing F. R. Carvell
A. W. Clements C. B. Cooper L. B. Crider D. L. Cross F. C. Dilley R. L. Ehnle A, M. Fairlie C. R. Flynn D. E. Giffin L. V. Goode W. T. Gunning B. W. Holdman M. N. Johnson E. B. Katzenmeyer, J. A. Klupar F. E. Krause R. M. Kreager R. A. Krueger P. H. Lawrence T. R. Linak M. Lukity
Jr
J. F. Malone /
jR. L. Martin
R, S. Mather M. D. McClusky G. H. Metzger H. G. Miller R. M. Montgomery J. L. Nelson D. P. O'Keefe G. Pow R. N. Rylands R. D. Savage M. D. Schrader E. G. Schwaegerle R. D, Scott W. A. Spillman R. A. Spurlock R. W. Strassburg G E. Thompson P. A. Wagner H. Waltemate N. C. wearsch A. R. Webber C. L. Woods B. M. G. Zwicker
NGC35457
VINYL CHLORIDE SAFETY ASSOCIATION MEETING Atlanta, Georgia February 27, 1976
Representatives of 24 VCM and PVC producers met In a one-day meeting for discussion of the preparations made to meet the April 1, 1976 effective date for OSHA vinyl chloride regulations. Representatives commented on these items:
Average VCM Plant Readings VCM Sampling Method and Number of Points Types of Masks Medical Surveillance--Effect of Solicitors Decision Position on Outside Contractors Residual VCM in PVC The attached chart shows the position of each company in these areas. General Discussion Items 3M has a new type of mask for 10 ppm VCM, which has been submitted for NIOSH approval. General Tire & Rubber has had three employee complaints to OSHA on breathing air. They also have a pregnant female who has worked in the regulated area for six months; she is expecting in May. Personal monitoring is being conducted 100% of her time in the regulated area. Firestone has submitted a variance to extend the optional use of respiratory equipment for 25 ppm VCM for an additional six months. Later it was learned this variance was denied by OSHA. Because of the URW, Firestone's medical examinations are on an optional basis. Twelve employees have refused examination and are continuing to work in regulated areas. The Department of Labor's solicitor, Mr. B. Mintz, ruled December 4, 1975, that employees are not required to submit to medical examination, which the employer is required to make available under the vinyl chloride standard. This ruling pertained to the Pottstown, Pennsylvania Firestone plant where twelve employees refused examination. Except for Firestone, the other company repre sentatives were fairly unaminous in reporting no problems. Tenneco has had some employees experience nosebleeds from breathing bottled air. They plan to humidify the air and heat with chromolax heat tape.
NGC35458
2- -
Atlantic Tubing has had a new plant on stream for about one month. Except during upsets, they have found no VCM In monitoring the area. Their ventilation enters through the roof, passes through the floor, and exits at the lower sides. They have not regulated this operation.
Tenneco was recently inspected by OSHA. The compliance officer collected five 1-1/2 hour samples with Sipin pumps. He also used MSA color tube detectors. He had a cartridge mask but did not wear it. Several employees were questioned on the adequacy of training. Union representatives were asked to select the areas for collecting air samples.
Several companies have canisters available, but very few are used.
All producers reported varying degrees of difficulty in reducing RVCM levels without degradation of the PVC. Levels in general were slightly above those we experience. The most significant response was "RVCM is a function of silo residence time.".
John Barr of Air Products presented a short review of the EPA standard. However, until the final version is published at mid-year, little action will take place. Several representatives expressed the thought that their company would not rush in to comply, and in general, expressed fear of a moving target-- equal the best known technology.
Robert Dostal of Dow presented an outline of their plans for EPA monitoring to satisfy the leak detection and control procedure requirement:
1. Use OSHA fixed monitoring devices for leak detection. 2. Locate source with portable hydrocarbon detector. 3. Have a program for detector calibration. 4. Establish points to be monitored routinely by hand meter:
a. Moving shafts, vent stacks, frequently used valves, etc. (develop statistical frequency for monitoring).
b. But, do not test after press check of equipment. 5. Publish a plan of action. 6. Definition of leak:
25 ppm is a leak, also two subsequent excursions above 5 ppm at 1 sample point.
A fall meeting is planned at Denver, Colorado.
/k attachment
T. R. Linak H. Waltemate
NGC35459
VfM Producer* Allied Cbealcal Dow Chemical Ethyl Corporation PPG Indostrls* Shell Closed PolT Mode Central Tire StAUffS* Oms Air Plant.* Conoco
Dinned
Gao rgls~fselfic Goodyear Air Products Other Firestone Tenoaco Union Carbide Pantssole Bordea Csrtsin-Tmsd Great American Hooker
Keysor Century
Aablant tv*r* .S-.7 ppe
< 1 PP .S-l ppe
<5-1 PP
.*-.7 ppe
Pr*onaX a
.05
<1 ppa
68Z Cl ppa
ppa
7IX Cl 89X C5 MX <1
Stapling
2-10 point flnns io&iucioo--|oio| to C.C.
12, 50, 54 poiat flaee Ionia*tIon
10 pelat Hiraa 1.1. tola* to C.C.
9 pelat Arcus GC system
Oss hags for perooual aonlterlng
Haalra
ttedlcsl fturvelllanr*
Canister Air Pal Air Una
Canister Air Una
Caolstax 1, + FP Air Line
FT Air Una
h* rr Air Lina
Condition of Eoploysftt
Ho Problems
He Refusals
Do Dot permit voaaa of child baarlns a*. Condition of Employment
Politic* on Contracture
Ms outsido coDtrsctoro
Contractor's Responsibility Contractor'. taepoatlblllty Mo ovtsido cootractors
Evacuate at 5 PPe
1 PP" 0-.5 ppe
.5-1 ppe
.2-2 ppe 70X <1 ppa 50Z 1-5.5 ppe
5 ppm
16 pelat flame ionicstied ead Hiraa 1.1.
16 poiat Arcus GC 90 point tystsm
50-40 points Honeywell
68 poiat Arcus CC
< 1 PP .5-1.6 ppe 1-2 ppe
.25 ppe C.5 ppe
2-5 ppe Dryer Axes 5-10 ppe Reactor Area
1-5 ppe
.5 ppm &T7r Area 2 ppm Eaactor Area 2.5 ppa lacovary Area .
2.3 ppe
Being Axes ftonitoring
1-1 ppe
500 reading* over 5 ppm la a aooch
60S <1 ppe 3 ppe
5-4 ppe
12 point Bundle C.C.
10-20 poiat basd^x
20-30 polato flmee loelsatloa
12 poiat Hiraa 1.1.
70 .point c.C.
30 pointVPA
IS point Hiraa and 68 point Bocoa
Coavarted free THA to CC
12 Hires 1.1. Colas to 30 Point CC 30 point Area. CC
60 point GC
tseeatly installed 16 point Eavlettrackard g.c.
Gaaiatar Air Liaa
canister % + PP Air Lina
He Problems Coddleloo of
Contractor'* lospoosiblllty
Prwlda --<--- --and Equipment
Coablnatloa ead
Air Una, Air Pah
Canister H * FT Air Line
Bo Problsas
Condition of Bvteyeanc
Canister Air Fek rr Air Lins
V Air Lias
Canister h Air Una
Coaditioe of BBpkoyvsot
CeodltioB of bslej*M&
CooditiM of BaplsyrnsnS
Contractor's
tsepomalhlllty. Offer medical exaelnatIona.
Shore-care Gosersccsrfc Beapenslhlllcy. Lon*ttrn saae a* employes# ,
lotify if 1 ppe it ixcMdad
i
Evacuate at 5 ppa
HelUral Examination* Provided
Canister Air Lina (Sea Hot.)
Canister Air I..., fm Bottles
Cealstey Air 9eV Air Llae Bottles
H tit Line
(Bee Hot.)
Condition of bpioyonC
Caedltloe of Employment (6 refusals) Caadltlom of EU> loyaent
Canister Air Lin.
1, + IT Air Lin*
Ho Problems 3 Posies la Bssulsted Arasa
Condition of Eaployaent
Contractor1! Beapeaaiblllty. Svecuate at 25 ppa.
Contractor's kaapenslhlllty. ' Evacuate at $ ppa
Coatraetor's Responsibility. Show thee allde/tape.
Contractor' koepenalhllley. Bnciut. -1 5 ppa
Contractor's BeopMslblltty
l Air Line
Canister Air Line
Dual flow Canister with AAx Lina
Ho Problem
lafstm Contractor
Onion questioning their aedlcal prograai goin, to
srbltratlcnr
Inform Contractor
CoedlCloB of Employment
Ho contractor la Eegulatad
Area.
Beeiduml vai In PVC
; *
10 ppa axtrusioD 50 ppa eaindar 50 ppa eopolymsr <5-10 ppe boaopolyear <50-100 ppa copolyear
2.9] <1 ppa 4S.7X 1-10 ppe 37.IX 10-25 ppe 14.31 >25 ppe 10-50 ppe
90X <10 GP
5 ppe Averega Usually 30-60 ppa Plaquamlna <5-50 ppa boaopclyecr 100 ppe Acetate
50-200 ppa copolymer 5-50 ppa suspension <1-5 ppa peats <10 ppa usually
<1 ppa solvent <10 ppa Seenpolymer 300 ppa copolyear 10-50 ppa beaopelyasr
<25 ppa pipe grade
<10 ppm for shipment 10 ppa
100-200 ppa copolymer
NGC35460