Document pmYmBG1gBeNG9DRQVaYZmjJbw

--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------+ Date Printed: 08-15-1996 Page 1 LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC 1 -PRODUCT IDENTIFICATION PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO.: PRODUCT USE: HYDROCHLORIC ACID, 0.005N TO 1.5N, MURIATIC ACID; CHLOROHYDRIC ACID; AQUEOUS INORGANIC ACIDS HCL 36.46 7647-01-0 MW4025000 LABORATORY REAGENT METHANOLIC HYDROGEN CHLORIDE, CHEMTREC # (800) 424-9300 LA-MAR-KA, INC. 10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814 EFFECTIVE: 05/01/89 REVISION #03 ISSUED: 04/14/90 REVIEWED 1-1-95 PRECAUTIONARY LABELING \-MAR-KA LABELING SYSTEM HEALTH - 3 SEVERE (POISON) FLAMMABILITY - 3 NONE REACTIVITY - 2 MODERATE CONTACT - 3 SEVERE (CORROSIVE) LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES U.S. PRECAUTIONARY LABELING HYDROCHLORIC ACID: POISON DANGER CAUSES SEVERE BURNS. MAY BE FATAL IF SWALLOWED OR INHALED. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. CAUSES DAMAGE TO RESPIRATORY SYSTEM (LUNGS), EYES AND SKIN. KEEP IN TIGHTLY CLOSED CONTAINER. LOOSEN CLOSURE CAUTIOUSLY. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL NEUTRALIZE WITH SODA ASH OR LIME AND PLACE IN DRY CONTAINER. METHANOL: POISON DANGER FLAMMABLE. HARMFUL IF INHALED. CANNOT BE MADE NON-POISONOUS. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE. FLUSH SPILL DO A 060733 CONFIDENTIAL --------------------------------------------------- ------------------------------------------------------------------------------------------------------------------- h Date Printed: 08-15-1996 Page 2 LA-MAR-KA (LM-0636 ,M!D) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC 1 -PRODUCT IDENTIFICATION (continued) AREA WITH WATER SPRAY. PRECAUTIONARY LABELING (CONTINUED) HYDROCHLORIC ACID: INTERNATIONAL LABELING IRRITATING TO EYES AND SKIN. KEEP OUT OF REACH OF CHILDREN. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. METHANOL: INTERNATIONAL LABELING HIGHLY FLAMMABLE. TOXIC BY INHALATION AND IF SWALLOWED. KEEP OUT OF REACH OF CHILDREN. KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. AVOID CONTACT WITH SKIN. LA-MAR-KA STORAGE COLOR CODE: WHITE (CORROSIVE) 2 -COMPONENTS MPONENT HYDROCHLORIC ACID .METHANOL CAS NO. 7647-01-0 67-56-1 WEIGHT % <1-6 >99-94 OSHA/PEL 5 PPM 200 PPM ACGIH/TLV 5 PPM 200 PPM 3 -PHYSICAL DATA BOILING POINT: 65 C (149 F) (AT 760 MM HG) MELTING POINT: -98 C (-144 F) (AT 760 MM HG) SPECIFIC GRAVITY: 0.79 (H20=l) SOLUBILITY(H20): COMPLETE (100%) PH: N/A ODOR THRESHOLD (P.P.M.): N/A COEFFICIENT WATER/OIL DISTRIBUTION: N/A VAPOR PRESSURE (MMHG): 96 (20 C) VAPOR DENSITY (AIR=1): 1.11 EVAPORATION RATE: 4.6 (BUTYL ACETATE = 1) % VOLATILES BY VOLUME: 100 (21 C) PHYSICAL STATE: LIQUID DO A 060734 CONFTDFNTTAL -f -------- - - - ----- ------------- -- ------ ------ -- -- -------- _ -- _ -- ----- -- -- -- -- -- -- " -- ---" ~ -- -- -- -- "*"" + Date Printed: 08-15-1996 Page 3 LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC ----------------------------------------------------------------------------------------------------------------------------------------------------------------+ 3 -PHYSICAL DATA (continued) APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID. PUNGENT ODOR. 4 -FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP): 12 C (54 F) NFPA 704M RATING: 1-3-0 AUTOIGNITION TEMPERATURE: 463 C (867 F) FLAMMABLE LIMITS: UPPER - 36.0 % LOWER - 6.0 % FIRE EXTINGUISHING MEDIA USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.) SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. .USUAL FIRE Sc EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. BURNS WITH A CLEAR, ALMOST INVISIBLE FLAME. TOXIC GASES PRODUCED CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED. UNUSUAL FIRE & EXPLOSION HAZARDS MAY EMIT HYDROGEN GAS,HYDROGEN CHLORIDE, UPON CONTACT WITH METAL. 5 -HEALTH HAZARD DATA METHANOL: THRESHOLD LIMIT VALUE (TLV/TWA): 260 MG/M3 THE TLV LISTED DENOTES TLV (SKIN). (200 PPM) Do A 060735 CONFIDENTIAL H-----------------------------------------------------------------------------------------------------------------------------------------------------------------------H Date Printed: 08-15-1996 Page 4 LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC ----------------------------------------------------------------------------------------------------------------------------------------------------------------+ 5 -HEALTH HAZARD DATA (continued) SHORT-TERM EXPOSURE LIMIT (STEL): 310 MG/M3 (250 PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 260 MG/M3 (200 PPM) TOXICITY OF COMPONENTS ORAL RAT LD50 FOR METHANOL INTRAPERITONEAL RAT LD50 FOR METHANOL SUBCUTANEOUS MOUSE LD50 FOR METHANOL SKIN RABBIT LD50 FOR METHANOL CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: 5628 9540 9800 20 NO MG/KG MG/KG MG/KG G/KG CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFFECTS NONE IDENTIFIED. EFFECTS OF OVEREXPOSURE INHALATION: IS HARMFUL AND MAY BE FATAL, HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, RESPIRATORY FAILURE, LOW BLOOD PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION SKIN CONTACT: IRRITATION, PROLONGED CONTACT MAY CAUSE DERMATITIS EYE CONTACT: IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE SKIN ABSORPTION: NONE IDENTIFIED INGESTION: IS HARMFUL AND MAY BE FATAL, BLINDNESS, HEADACHE, NAUSEA, VOMITING, DIZZINESS, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION, HEARING LOSS CHRONIC EFFECTS: KIDNEY DAMAGE, LIVER DAMAGE TARGET ORGANS EYES, SKIN, CENTRAL NERVOUS SYSTEM, GI TRACT, RESPIRATORY SYSTEM, LUNGS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE EYE DISORDERS, SKIN DISORDERS, LIVER OR KIDNEY DISORDERS PRIMARY ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT, ABSORPTION EMERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING. DO A 060736, CONFIDENTIAL Date Printed: 08-15-1996 Page 5 LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC ------------------------------------------------------------------------------------------------------------------------------------------------------------------ 5 -HEALTH HAZARD DATA (continued) INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: YES PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: CERCLA HAZARDOUS SUBSTANCE: SARA 313 TOXIC CHEMICALS: GENERIC CLASS: TSCA INVENTORY: NO YES YES YES CONTAINS METHANOL (RQ = 5000 LBS) CONTAINS METHANOL C05 DROCHLORIC ACID: ^iRESHOLD LIMIT VALUE (TLV/TWA): 7 MG/M3 (5 PPM) TLV (CEILING) IS FOR HYDROGEN CHLORIDE. SHORT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT (PEL): 7 MG/M3 (5 PPM) PEL (CEILING) IS FOR HYDROGEN CHLORIDE. TOXICITY OF COMPONENTS INTRAPERITONEAL MOUSE LD50 FOR HYDROCHLORIC ACID ORAL RABBIT LD50 FOR HYDROCHLORIC ACID INHALATION-1HR RAT LC50 FOR HYDROCHLORIC ACID INTRAPERITONEAL MOUSE LD50 FOR WATER INTRAVENOUS MOUSE LD50 FOR WATER CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: 40 900 3124 190 25 NO MG/KG MG/KG PPM G/KG G/KG CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFFECTS NONE IDENTIFIED. DO A 060737 CONFIDENTIAL ------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Date Printed: 08-15-1996 Page 6 LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC -------------------------------------------------------------------------------------------------------------------------------------------------------------------h 5 -HEALTH HAZARD DATA (continued) EFFECTS OF OVEREXPOSURE INHALATION: PULMONARY EDEMA, CIRCULATORY FAILURE, RESPIRATORY SYSTEM DAMAGE, COLLAPSE, COUGHING, DIFFICULT BREATHING SKIN CONTACT:: SEVERE BURNS EYE CONTACT: SEVERE BURNS SKIN ABSORPTION: NONE IDENTIFIED INGESTION: IS HARMFUL AND MAY BE FATAL, SEVERE BURNS TO MOUTH, THROAT, AND STOMACH, NAUSEA, VOMITING CHRONIC EFFECTS: NONE IDENTIFIED TARGET ORGANS RESPIRATORY SYSTEM, EYES, SKIN MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED IMARY ROUTES OF ENTRY INGESTION, INHALATION, SKIN CONTACT, EYE CONTACT EMERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN CONTACT:: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: YES CONTAINS HYDROGEN CHLORIDE (RQ = 1 LB, TPQ = 500 LBS) CERCLA HAZARDOUS SUBSTANCE: YES CONTAINS HYDROCHLORIC ACID (RQ = 5000 LBS) OO A 0607 CONFIDENTIAL ------------------------------------------------------------------------------------------------------------- ---------------------------------------------------------------------- + Date Printed: 08-15-1996 Page 7 LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC 5 -HEALTH HAZARD DATA (continued) SARA 313 TOXIC CHEMICALS: GENERIC CLASS: TSCA INVENTORY: YES CONTAINS HYDROCHLORIC ACID C16 YES 6 -REACTIVITY DATA METHANOL: STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG ACIDS, ZINC, ALUMINUM, MAGNESIUM DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE HYDROCHLORIC ACID: STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL .NOT OCCUR INDITIONS TO AVOID: HEAT, MOISTURE .COMPATIBLES: MOST COMMON METALS, WATER, AMINES, METAL OXIDES, ACETIC ANHYDRIDE, PROPIOLACTONE, VINYL ACETATE, MERCURIC SULFATE, CALCIUM PHOSPHIDE, FORMALDEHYDE, ALKALIES, CARBONATES, STRONG BASES, SULFURIC ACID, CHLOROSULFONIC ACID DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, HYDROGEN, CHLORINE 7 -SPILL & DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. VENTILATE AREA. NEUTRALIZE SPILL WITH SODA ASH OR LIME. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D002 (CORROSIVE WASTE) 00 A 060739 confidential 4*------------------------------------------------------------------ -- --------------------------------------------------------------------------------------------------------------- -- Date Printed: 08-15-1996 Page LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC 4- 8 8 -INDUSTRIAL PROTECTIVE EQUIPMENT VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 200 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ACID CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, NEOPRENE GLOVES ARE RECOMMENDED. 9 -STORAGE AND HANDLING PRECAUTIONS LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE) WHITE (CORROSIVE) STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. ISOLATE FROM INCOMPATIBLE MATERIALS. DO NOT STORE NEAR OXIDIZING MATERIALS. -TRANSPORTATION DATA AND ADDITIONAL INFORMATION THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. THIS DOCUMENT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS- CHEMICAL FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES. EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS. LA-MAR-KA WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL. LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE. DO COAyp ^607,4q ropNrjA( +------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- + Date Printed: 08-15-1996 Page 9 LA-MAR-KA (LM-0636.MSD) MSDS for HYDROCHLORIC ACID, 0.001N TO 1.5N, METHANOLIC 10 -TRANSPORTATION DATA. AND ADDITIONAL INFORMATION (continued) THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT HEEDED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DOCUMENTED GENERAL SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE THIS MATERIAL SAFETY DATA SHEET. APPROVED BY LA-MAR-KA, INC. DO A 060741 CONFIDENTIAL