Document pm20w6GkdZQ067B5NdJRwak8d

conoco INTEROFFICE COMMUNICATION To Distribution From J. E. Cearley Date November 22, 1988 Subject SARA Title III Section 313 Toxic Chemical Inventory LAKE CHARLES REFINERY TABLE OF CONTENTS I. LIST OF CHEMICALS REPORTED II. RELEASE SUMMARY FOR REFINERY III. CALCULATIONS 1. Calculational Methods and Assumptions 2. Sample Calculations 3. Chemical Specific Calculations a) Release Inventory i) Amount Released Per Medium ii) Percentage of Total Release Breakdown b) Waste Treatment Methods and Efficiencies c) Calculations IV. APPENDICES a) Appendix A: Reportable Toxic Chemical List Development i) Technical Services List of Chemicals API Refinery List ii) Rationale for Eliminating Chemicals iii) Threshold Calculations for Reportable Chemicals b) Appendix B: Emission Factors i) SOCMI Emission Factors ii) AP-42 Hydrocarbon Emission Factors 1 iii) Wastewater Release Table From EPA Guidance Document iv) EPA Land Treatment Emission Data c) Appendix C: Blue Book Data (for Threshold Calculations) d) Appendix D: Maximum Quantity On-Site Calculations e) Appendix E: Chemical Composition Data I i) Liquid Stream Composition Data and Calculations ii) Gas Stream Composition Data and Calculations f) Appendix F: Solid Waste Data and Calculations i) Solid Waste Disposal Summary ii) Solid Waste Disposal Calculations and Composition Data iii) EPA Land Treatment Emission Data g) Appendix G: Wastewater, API Separator, and Cooling Tow=r Data i) Flowrate Calculations ii) Wastewater Release Calculations and Composition Dkta iii) API Separator Release Calculations iv) Cooling Tower Release Calculations v) Wastewater Release Table from EPA Guidance Document SAL 000005240 h) Appendix H: Storage Tank VOC Calculations and Data i) Storage Tank Release Summary ii) Equipment Inventory Survey (EIS) (Tank Capacitie s) iii) Storage Tank Release Calculations and Computer S preadsheets i) Appendix I: Fugitive Equipment VOC Calculations and I ata i) Fugitive Equipment Release Summary ii) Fugitive Equipment Calculations iii) Fugitive Emission Sources In Refinery Process Ur .its iv) Leaking and Non-Leaking Fugitive Emission Factor S (SOCMI) v) Fugitive Equipment Stream Data vi) Process Drains Fugitive Release Summary vii) Process Drains Fugitive Release Calculations viii)Fuel Gas Fugitive Release Calculations j) Appendix J: Loading Loss VOC Calculations i) Loading Loss Release Summary ii) Loading Loss Release Calculations and Spreadsheets /jk 11/9/88 JEC\152 SAL < >00005241 LAKE CHARLES REFINERY 1987 SARA 313 REPORT LIST QF REPORTABLE TOXIC CHEMICALS Aluminum Oxide Ammonia Benzene Biphenyl 1,3-Butadiene Chlorine Cobalt Cresol Cumene Cyclohexane Ethyl Benzene Ethylene Hydrochloric Acid Manganese Methanol Molybdenum Trioxide Naphthalene Nickel Phenol Phosphoric Acid Propylene Sodium Hydroxide Sodium Sulfate Styrene Sulfurid Acid Toluene 1,1, l-Tr|ichloroethane 1,2,4 -Tr|imethy lbenzene Xylenes SAL 000005 242 vi r.n m cn _ S--. , * P-P i. .*. ' 1 i; '.-- I ii o , , ! .-I>3 ; i r nr 1 i i ' :. ' ' h < ` : *! 03 E- v:r 1 `: : i ' Hi ". i ! !. - i \ -,i ...0: 1 O-'J -pn r i : - . V (O i-i . 'fc..V <- h. > :.! 1 :.r. ... r i ; a H-..: . -J. r. , i i- -1 i....- ' I i i ! i . I'! 1 i < ! i ' 1 - i !.i t:f il-i JU L r c , -vr-:- > - 1 i <. Acid i r ' -1 i , O' ichiorosthane J H < , ' ; r d ineth >' 1 bens ene i L. 1 Hr-ir'. Lr:P-' .i Hi- r v ; : -iN. ? HbP'O;. r'i < ' U I c i- :. '..ii U H' V; : '.'Ir.i..L AUb '._b'b V i i < Hi'--. i i'lUi-iT NA 1. U'.".M 1 U4 Mb 4:j( j L> rii-i 4 i i:(.. r-ii-i i+; ! i~i i. Hi i :'lA t'. r-i-4 J -1 4 44 ] bP: Hf"! : ; G4C rib: 410 r.:/ 3 i !. O'X-1 4 5 >...1 ; h .) : 4-.:H 4U i. H'J'-j 4' J- 4 U * :t :t 6 !. Hh i'j N f-. \4 44? 4 0- ".i *4 />'* 4 OH'. > i in 43uO r Jr Nn ior: .... ... hJA 47'-} : / 44 * .4 r;, 7 /rif'i : > NN 0 h;-v " 0 4':-4 .? / --'It -0... ;>. ...4 Mh .: LN < ' Ob NA NA 49 H j f 9400 ' OF 0 ( Oi l ' >, (u: i.' J UN.' >_> i Hi : ?H4 NA ? 479 HUM . 4- u:-"j . ` on.34'.' '.''i' iCf < :uri 1 i i .UN : . ur- f ji'i ' - Ml' - in C-ii \ j. / 000-.. u.iii:. r-h'? mjM UJlJy i. * ,14 ' '.44 0 !. L-. : i i- ' I . r. ..Ob'" -1 b . .i - V - IE 4 ,4 4 - .1 E r: 4-iE N44 -IE j L'- -5E iE6-1E7 : j 5E7 . i..- 4 - 1 A V E4- i ` ; i E4- i I'. !:: / - i /'? j. 44 1 i:.- I ' .!. i r. , j. -t , E4 1. i;: 1 ?: J 4 ;. L-: i. i I:-. i-;. H. i. iE 4 ... ^ i. L:/' 44" ,`i:: i r .9 IE -1- :. i..:: " 4:. ' - Hi- i P-.'.';: "i-i :1 !.. fPCi '.p 'i 1. v : , I- 4 !. r- -- 1- ; t-.- - ..1 v. .' p H 1 H --r, = rv 1. ...j 'i. i;..*-.' , ; ." i - j. X H '' * ' i 4 ; ! /] ! rv.-i; r .!. ' vv -..J.V j f, C i n . ;.! v. r i r.< : v j1 i Pi-Hivn:; 1 :i i 4. Ci er i. e/i i .; v t.i i: e : i e l'i !.l : i jri-- - i. r: ' 1 11 IV' .V 00'000 S^ i ?&"' -jAF\i-i ... j ..l ALKUL, 1 h;l I... ill ; i s E 11'- t V E N i' (J A L: ! K l i. i-l r'i R L... E L- i t: r ]. N E. r> CUMENE OiJR Ct A M iJ U N1 R E:: L. r:I H li> D ' j.!" / r ') i i LR POINT RELEASE r. \ a q a ! ;iir i r s I i. Dd > i nu R tKJt R;:Of 1 r. 1 h'oj ni Rei ecise 4/I r*\ r*%7 >\ A ir RUN I N ! RELE-Aoc o LoacLi. ng Loss !"' '.j 1 i.l i. V 'A i:r. dj U i p iTi0fi T I _ lj 3 No. LRU O HDb Keg u i -if" .ik er r-'r tiifii 3. uni Coi-: kt Mo., 2 Cukor '< aLi Recovery :J. A.Ij t. "CC No. 2 LRU 0 H.OS ' I 1 A r iTl 2 i (.II i- ' s-rl 1.1 !< Li? f" I ~a n f a r n > / B1 e n d i n g '-. 'ac si; a Or a l n a ".tijiar at or r- AP1 OA>- .<. Ah l nq Tower 'iaatewdter Kel ease to A M a a tie Re I ease to Ai_r. Total Non--point Release it'. 1 34. 1 0. 34. o2 ,, ''.Ho . I 44 . 1 240. i a. i. !. 102. 27 1. 1 . 1.2400) OF ' 01 At.. I LJ i" It:- U 1 Lj! 1 0 o 1 0 1 J4 1O i 40 L j (} 4 1O l O0 TU PAL AIR RELEASE 2/22 . l-'-i'-t \ hr, RbLEiABE 37. LI 499) i. AND RELEASE On i i- e? M. anc.it or no Q r t -Si t.o i. 1.1.2. ! i.M Ai... LAND I 'Ll. . L AC E O. N/A 'll. SAL 000052 44 1987 SARA 313 REPORT WASTE TREATMENT METHODS AND EFFICIENCY LAKE CHARLES REFINERY CUMENE GENERAL WASTESTREAM GASEOUS TREATMENT METHOD VAPOR RECOVERY UNIT TREATMENT EFFICIENCY 98%(a) RANGE OF INFLUENT CC JNCENTRATION C .01-1%(a) WASTEWATER BIOLOGICAL TREATMENT (AEROBIC) 95%(b) 1 l >pb-l ppm(c) SOLID WASTE BIOLOGICAL TREATMENT (AEROBIC) 100%(d) 1- 100 ppm(e) (a) Based on data provided by Brandt Butler. (b) See Table A-2 in Wastewater Appendix. n,4*,I A<-0 . / Ov'C -oLrfecfi'-' (J).L '-(OfpL > (tt) (Based on 1977 R&D Lake Charles Wastewater Ar alysis, N Tecnical Memorandum No. 603-79-350-2, (d) Assumption based on data for similar organic compounds (see "Estimating Land Treatment Air Emission s" in Solid Waste Data Appendix). () Based on Ponca City Solid Waste Composition Data. $AL Oo ^s Co^eve. Cof*\Pcs\TiGN5 GaSo lines, Unle^vAeAj S^per- LVi Ba-S&j FCC GaSoKo ^ Slop^ Cok'er- Crud.e. >r\iVv a. '^4tS-o\ ****.$ VP = .06>n Ps'fl O 7^#P LfrKE. C HAtfCt?5 V/f. % l.c /,0 < \.6 sep <4f>Pe/VZ>/x ao^^osiTio/v. oj/V xmfo. ads 3y necked 3 ate ace of Conoco Inc. Calculation Sheet Title Job No Field State SAL 000005246 Cumene Calculations (methyl. EnfYi. Seivzsiye') $TDRA&E TANKS r ^ ^ ^o.aiil^/ FLOATING RooE = 1.7 f 2.2.2. f 3-2., f] (o.I A_(>"~X2jsoa') ' /2 *%/? l*ClN(r- LESS = I/o.fo Z.+ ^7,-73 4- rt,sfJ(o.i)( -Q`i`1~)(^a') - IE ^Vy* Fus-mi/E &Qu,P/^e^r losses-- Sfe fiPP&Nt,IX JZ Process DRA/^S = o,i7 *) ao 7 3 , ey - , OOS) T PY - /O. I-? \/ a.OCi?!<,l >/ \ _ 4E$/ Ate SEAA/Wofc^ 3*t>HZ Ct&& /( 5TJ--A*2000) - 2,4 /y^ IS c% CC00L1/Y& 7^EA. : 2.4.4 TPY cS = JQ2 /:: vYArnr v>/Ath-/R : Efl=^ue/vr = 7.3i vio^ `/'y* v = 'S-j ^4* ^ W4STE AEiE/KE'S ' J -------------- - V . *2& - ^*7? v .05^ ------------------------- tto 04t4 4/4flAc on cu^st/sr ftsso#\E$ za*\s x* ft>TWTirtaY PABSB^/T AT c&tfcJ^/VrtfAT/otys .&04/n>Ty Tb u/WOFARM is OB~CRAhBD, losses tz A-tfi Assume^ tiEGLiGll*E 0*&/ PRoQfrgLy Cr>v~R5 TrftS), /vote see /We/VO ices (=* Details o/v cacco^at/oa/s. -lace 3y CnecKea By Date -age of Title Conoco Inc. Calculation Sheet Job No. SAL held State 00005247 1 VC/ bAiin 313 ptKJR I RELEASE .I NvLNfORV P.Hk.P LHliRLk:8 RLh i iCP.r! f C_Y LJ.3JH_E X Li hiL Li iUh-L-E a i. ' '! J N : i"1. Ll. _ i:L Pi on;. ( c..H ..-"`.it-' i anka P 3 Fiuof Pi/ed Roof lot. a.i Poi ril Rei ease h-(Ml U Jl'-11 REL.F:: A8L L (lb/ V !' 1 130. 0249,,. 2379. '(2400) - v P. i'iiiN-P'UINr RELEASES L'..oiri.i nq Loss '-nqi rive Lquipmenr. Lose No. 3 Cl ,.J No. 4 HOC No. 3 CPU N HOC ReyuJ. ar Coker I 'r oito i.siii Coker No. 2 baker C a s R e c o ec v P1 a n t. .Jo. 3 HuS i -J o . 2 C r u cl e J n i. k t-r L L i._f Li a so 6p J i.r No. 1. J IDS No. 2 CRU HD3 i a or ill ,a i. Cr ac k er i' Ll i ank Fanri/Gi end i ny Process Drains Separators API DAF IAF Coolinq Tower Wastewater Release to Air W .j r. e it e 1 ea se to A i r i c; t, h 1 N o r i - p) o i n t. R e 1 e a s e jf-O. 3 6 2. 3 8 3. 20. 1 04. 380. 194. 438. J. 4 4 ,, 64S. 116. 1d12. 1 1 6b . 480. 0. i 1330.' ( 11OOO) i OTAL hIR RELEA3E 139o9. Li.. In Adi:. ...Ari 5.) EELEAGE Uti6i i e ('Land-far- m> t ;;8-LL e ( La rid f j. i 1 . i' G i AL. I..AND R EC... EASE! 0 N/ A 0 l-F i J l AL L: o i Ui i i 1a 17 0 4 3 (i i i i 13 X - j r' I 1 SAl. 0) 00524q 1987 SARA 313 REPORT WASTE TREATMENT METHODS AND EFFICIENCY LAKE CHARLES REFINERY CYCLOHEXANE GENERAL WASTESTREAM TREATMENT METHOD TREATMENT EFFICIENCY RANGE OF INFLUENT CONCENTRATION GASEOUS VAPOR RECOVERY UNIT 98%{a) . 01-1%(a) WASTEWATER BIOLOGICAL TREATMENT (AEROBIC) 95%(b) 1 I pb-1 ppm(c) SOLID WASTE BIOLOGICAL TREATMENT (AEROBIC) 100%(d) 1- 100 ppm(e) (a) Based on data provided by Brandt Butler. (b) See Table A-2 in Wastewater Appendix. (c) Chemical was not detected, so one-half the a etection limit (D.L.= 10 ppb) was assumed (based on 1977 R&D Lake Charles wastewater analysis, Technical Memorandum No. 603-79-350-2 & EPA Guidance Document). (d) Assumption based on data for similar organic compounds (see "Estimating Land Treatment Air Emissiors" in Solid Waste Data Appendix), (e) Based on Ponca City Solid Waste Composition Data. SAL 00000524 9 C'iCJjOHF.X.ME Ca/tiPOSiTiOA/S GclSoIia^, -- L^nle-o-cAtfclj ^OC- I "" L i-S ^*s.5o(</*e CruJ- lA/et- <>=-5 ^ Al N*ipk~tkj\ Crocte. sp-4 Coker r=\s /k leaded. W+ Va <|.o I .o < 1.0 2*0 ^ I ,o 1.0 SEE /VppE/V'OIX f=b/Z ComPos\ riO'V AC*<rtfOO<Y) I^Ofl/"*T7or aae 3y Cnecrtea By Date page Of Conoco Inc. Calculation Sheet Title Job No. <AL 000005250 Field State 19L7 SARA 31.o ERROR RtLflhSt; INVENI'GP.'r i.. AKL Cri ARLES REP- i NEE 301. IR f; IP ,i [ i-: '"'HIM r KbLicAbRS l or' age 7 an k :~~ i 'l oat i nq Root i i.Rc].o_f i ci L j l'-'.i nt keifcirfSt- 1'.HYL Btlrt/ENR mMULIN T K't. L. EASE:. D lb/v^- . 1 7. 5 82. l 499 ) '. ;r till Al. 0 i' 'EH i L'M 1 4 i- t i R r.!Uf-i-R 0 [ t-J f RELISA 3173 i.. f.atJi nq Los* :toi a t- Equipment La No. oTL rio . 4 HUb MO. 3 LRU S, HDS Re qul a.r Laker i i' :Ti ). Lin: UokOI- i' lo . 3 Crud o Un t t A*==<.; Splt.r Uo. 1 HDS No., 2 LRU 3 HUb i -:ui k F arm / El end i ng ! r o i." e s '-2 U!" a i n s Sep a rat. ora Hr 1 7Q . 30 u 468 . I O. 34 . /Oa ] 74 . 40. 3 8. 382. 1 OO. 08. 12. 4. 1 0' 10 i 1 4 j. io 43 Looting lower Wastewater Release to Air Waste Release to Air. Total Non--poi nt Rel ease 174. 176. 3b 4520. >; 4300 i TUFAL AIR RELEASE 4702 WH I b K RELEASE 494) 4 4 I. AMD RELEASE :,.'ii- k::i te (Laiidlartii) Or f ;.;St Nje .LL.snd.r. i... 1.1 .L. jlj'i AL u. AMD RELEASE 0. N/ A 0. SAL 0 00005252 1987 SARA 313 REPORT WASTE TREATMENT METHODS AND EFFICIENCY LAKE CHARLES REFINERY ETHYL BENZENE GENERAL WASTESTREAM TREATMENT METHOD TREATMENT EFFICIENCY RANGE OF INFLUENT CC NCENTRATION GASEOUS VAPOR RECOVERY UNIT 98%(a) 0 .01-lX(a) WASTEWATER BIOLOGICAL TREATMENT (AEROBIC) 95%(b) 1 I pb-1 ppm(c) SOLID WASTE BIOLOGICAL TREATMENT (AEROBIC) 100%(d) 1- 100 ppm(e) (a) Based on data provided by Brandt Butler. (b) See Table A-2 in Wastewater Appendix. (c) Chemical was not detected, so one-half the detection limit (D.L.= 10 ppb) was assumed (based on 1977 R&D Lake Charles wastewater analysis, Technical Memorandum No. 603-79-350-2 & EPA Guidance Document). <d) See "Estimating Land Treatment Air Emissions" in Solid Waste Data Appendix. (e) See Waste Composition Data in Solid Waste Data Appendix. SAL 300005253 Errfy c. Benzene. ccv^Pos'TtctM^ G'Q-So I i'nPecj^t-o-r ^ On le-asJed^ Supe.r Cle<^eAeo/ FCC, Re to C rr.vA^ ^i.p n"FA5s. LS>P Gre^oli*^ (Zf-uJifL Wef ^Iky Icifi Cr^ete Jp-M ^Coktr- <?$ % /.7 1.2 ?S l.o < 10 See flfVm&K _E. Fo Q'^PosiTlO/V B+CKG-&eVMQ XVFa RA14T/0/1/. 5v r<eC 3'y 0 Conoco Inc. Calculation Sheet Title job No Field State SAL 0005254 Eth-yi Beni-e/Ve Calculations Sto&QGB. IANKS FLoimi#* Roof - t (32,1 TPY^TiS) - S"5" (Y~7 TPy)(^1^) + (2$ ^ ^X-rs'YKlTiy2 F.xefi (tooF '- (56.22. TPyX-r^X -. )^7 xr>! i-0Ai>lN6 - C(/a6.2.7FyXS) 7TPy)( + 6^ srTPrXrsz)J <7lS ^ ,/fy (e.n * ^OO - ^ 2 7 aSuiP^ErTT Rj&iTi/XS ~ (SEE APP-fJQlX x) Process DRAINS ^ (2.^.^ rey'{ ts')( ~ ?S a%Y<? PftD SEPMATofi. = (3TY2. Cooci/Vfr Towrp - (a'),, t^y)^ " IZ 2 11 ^ y '4* wastf wrt-T&rt ' EPPLue^n--. To a-iP, : 7.3 ( x 10^ -tV.^6Ar ' /' 36,6 X 0za .os ' H 37 Y^k /76 tX r<t waste RblSiHe ; -- --TarAt^- T&-.-(/`f,65DTPyv + IllZ * 7X2000) z ,06.6 L,/y /' Release is fbR - (\Le.C? - _ < / 3 6 /> R&vBAsE. T& cJWO = O Cioo% Z)ec,r^<Xe^. ) jVote: we: oet/4ic_ CA-LcoLfiTtcsvs t s&s ^ppe^/cFs ace By Checked - V Date Page of Conoco Inc. Calculation Sheet Title Job No Field S AL 000005255 State G G Li RL, E. Gt-ipR i 3. rEFOR'l PEL.EASE MVENTfjEY LAi<E. L.[ U-iRLJ:-.b RLF 1 NL.E r ETHYLErlE A MDUNT GELF ASED ( l b / / r ) AtP Pi": Li-1! PEl.EAGE A IE ! iG.ii-4 POINT RELEASE Pi.iqi. L i v Equipment Lose, Kequi ar Coker Pr envi uni Coker No. 3' Coker lii:? i'.'t?ccv'-2r. Plane: i CC i.:.-VO m i t?r n;=ii or ac: k er r - -.id PI a n t Fuel rJ a e Fuqi C i ves 4 e t e w I: e r F, e L as a s e t o A :L i Wi:< \r, l. t.: f & J, 6556 t D A_1 r Lot a I Mon..poi rrt Pel ease !' N f A L. A1 E E IE L.. E Pi 3 E N/A 1 0,, 4. 1 EP o SCO. 4CEO - 1 83. 760. 7r-;c-, . 70,U l`JA > EK I ".' EL L. Fi 3E N/A i...t't N 1j i\tL..EA3E N/ A UF '! A'! A! EE L. EASE 0 ilF.DNjh I'M ' i l l.) (j 1 30 34 0 1 00 1 00 hi M 000005256 SAL p-rayi^/yg aM-CUt_ATlQt/Z fb\NT &M\SS)oN = /V/fl ^iXrlTfVE &OotPfi\E./VT~ tbftE To WW ' LANO -- &AS (G-.A5E0uS C.otnPouN 0. f=oSL AS f=uGm/S (Se-E AfiPENO\X i - N/A ,aae 3v Ci'>.iCKed By Date ~age of Conoco Inc. Calculation Sheet Title Job No. c Field State 000005257 IAEA AhRA 3 i Ai" F'OFVi R.Ei-E;;:'i o E I. N'v'EM TORY i. AKE i.'-:MAR!. 3 Vi Ri..3:' l MITE "i HYiA- fjCrtL.yK.i 0 AC I D f : j.jiKL'L AMOUNT Kbi . 1: USED ( I b / y1- 1 i i. R A'i > j p.j r REL tHbf'. pru.9^ 1 an k i C> t cil Roin t 19 e l t= a e or- 4,, 4. : 499) UK i JOI-4..PC. f] i4 1 RE LEAR E i>e ui j. r i At a i 2 Z. 0 Rtsin RG-cien a t U. Non - pul n t. 19 eie a S &i 46Uj_ 4i3'-.`, ( 499) i i.j r A i K RE!.. h: m EE. 4E4 . waver release 0 i AND '(E-lEmoE. N/A OF' i i A1 RELEASE MEDIUM ?9 99 SAL 003005258 L 7`o / c:j hF '.t\ .:> i O i < F"`J T i ; video >E i'EEA ! ME'NT METHODS AMD EFFICIENCY i.Hi.t 0HARLE S REFINERV H Y .0!'-! U C i -j L. 0 f\ IU A U [Jj FKoj'l I RhATMENT METHOD TREA I'MEN i EFFICI EMC r' Mi-ji.-i!:.. OF influemr OL!Ni.;EH i Rh IV E U T R A l... I i A i" I M I. 0 0 % ( a) 1 /. . a) t;a = ed on d at a pr ov ided ij v Dr an dt But 1 er . SAL 0000 35259 HVDRouAtoPtc fl-ciC AAoe c.hAA_ A1/5 V(- |0 . (j r~~\ l/f^o Cvtr HCl') ~ @ *20 r_ AfJo J j ' 0.0.1 S'. tj[^v.'vfTs -OilO P$Z PjX" Q) PriR fbiifr Release - s-^rac-e Release - 0-2. ce^i- .3 * - ^_5- ^ AiA Ufav-fbiivr Release- [ Uji) + / Rje-iriv/e AEl.bAs\ K I P<""P W i^fe/es V. H & o ^/y/? ^zh * j gA^is = Er/fffrV'eeAifV'G- ^uE,<S-ef*\ENT / CAt-CouAT(orf (/J y/A-ref? fO y/ATg: Ael4s = o BASIS - pH fflorvtTo R lf/6- TREfiTmE/VT- Ne.utPAli 24Tl A/ ^ /oo % EEp/ci E/V' X/lIFLUSN T CchKE.fi/TRA TlO >/'- > / % UtfD uAr/C tfextAcr -.. /V/fl ft^Tes '. G-V --..................... - (*-) S/_ _ (?) Pe* HiWot/r . oTC-* ^6-x7-ygr c>/v \/CAS4?tO*/ Made By Chec*ec ByCate age of Conoco Inc. Calculation Sheet Title Job No. Field State JiAL 000005260 n /1 n p r n p p p p n p n r: p r r- r. n n p n. p p p p. g ?? p p _p; ; p p p n .p p n p p p .p p n p p n p p p p p p p p, r*;;-) -- r* ^ " ; vGC EMISSION CALCULATIONS FIXED ROOF L'H i <T. TIME PEP ICD ; MONTH,YR LOCATTON : MONTH,7R F: O I i 7 I 6 :J U R 0 E I . b.. # MA T ER i. hL STORED '! ' A r i K C :T P A C I T v (b b 1 ; T Ti R U P Li 7 >' b b i -5 / v r > START END BREATHING LOSS IP T -,y --3S ./,> n A 7 b-c Tv aHe CbsrleHCI LanF "'A'; HC1 2T0 .1 oooo 3 TANK DIAMETER (ft; D= 11 i-; TANK. HEIGHT -.ft) H= id 20 [AiTT A VAPOR SPACE HEIGHT +1) h ?' <; p p n p p p p p M p p p p j.j f`.j p p ;( ft p p p p p p p p p p pi p p p p p p p p p p p p pp p p p p p p pp p p p p p p p p p p p p p p p p p p j.9-Mav-3H T`2 16 AM pppp 3HEE I _ l 0 p p P D D D A D D DVD D C 0 D D D D P D D V D D DBD V D D D D D D V I' D PDDD D lJ DCDDD DDDDDV D D it) D D P 0 P D D D P P P P D P P P D BREATHING LOSS 17 1 Pi i. ? i! [ALT] A 2 1 I ALT I h - ^ '.ALT'] C J c al r I D ...4 L v-^L V "i E . ..J. L ALT J rr .7 o L ALT } G L ALT j H 20 - r-i TANK DIAMETER (-ft) TANK HEIGHT (-ft; VAPOR SPACE HEIGHT (ft) DAILY TEMP CHANGE (F) MOLECULAR WEIGHT VAPOR PRESSURE <psia> PRESSURE, ipsi a) PRODUCT FACTOR PAINT FACTOR SMALL TANK FACTOR BREATHING LOSS (lbs) D H n dT = Mv Pv Pa = Kc Fp = C Lb r= i1 15 2.5 20 Tn > TH 14.7 1 O'. 5 6 22 J 3 - ? - 7 7 "1 - v WORKING LOSS 7 T O I' i! ,0 ;1,0 ,0 ,0 .0 !! H P r: M r y: HT P p /? r: H yl ;1:'/ !1 H !1 p F/ /; /.' // H il il M M rl /'/ ,'THII r!il ;'7 T !'1P il M /v // !1 /'/ T T '? !`1 .'O' il ri ri/'/ r: 7/ /' ,0` 0 N /v .:0 P r: 1 v -- '*:-- S3 ti LI; 3.6 AM SAL 000005261 SH-T 7: 0 V D D 0 D P D A D D D U D D P ,0 D DDP .2 D DD V D DBDD D D D D D V V V ODD ODD D D CD DU V D D D D D D D .0 0 DD: ,r PP V PPP PP WORKING LOSS LlLEi4bifc. Er-ivb.M i OK r LAl.E:: CHAr\LL: E f\b.r I Nb. r\ rl^OANEOK b`_ i (RLE AMO .JNT RELEAPEi'j (iL/vr < i X f: JIN r PELL H oE y. t i...' links 1 '.J : * 1 P O 1 nt Rtf i Li ye t H I\1 J N r: 0 i NT R EL Eri 3 Erl i. r": c.| i... C E .-id Vd d aaoi i. o t5 & 1 encli i'T.3 i u.d.' <.it .1. Nor p o i n i. P Ed. o a e t? 0 f AL A.[ p b ELL i:i Lib 7 7. (,;49P) C) 4 J -3_._ 453.. ' 499 ) 4o0. -JAT Er\ REL EASE 499 . ,,Ah D 9FLE ALE Off -b 11 e 1... a I'm. f L-K f iT) 0 f f.. S i t E ( Lan c f i 1 1 ) \ ri * AL LAND PEL E AE E 499 . N/A ",499. OR i 9E LEA ! 0 LE:.: L .3 0 78 98 1 OO ccjco SAL OOOOC5262 Lake. Air PosNT RELEASE' STORAGE, tank Loss - 2S l& ^<nr Csee AttAaH^O 3-S* SH.1 u^-gfL<*_ 7 U Ann. 2n u mt>t_ '------- - Pfiifi/T ovT) tfoft-PoxNT RBLBAsE ' Fut?Tii/e ^,5S(oa/S .` / Pv*\p ' io VAi-vC* 2 3 PM/V'CffJ' L l (.11 ) + \>(,Qi(p^) + JO f.OOjS)}* 2.*/ ^ 265" at. 63 17^^ /*7*!T X cy, 2.i7 M L4 f^^rr *7 VS~2 /^A?r LS /% : BM^txHEG-AkNo Cj^cmlATlo^ MYQ - 0.31 PP O') 7. 11*10 i H. $ /y* = 23? "7 tfl **i %* SuT ficzoAtil/V- 76 ROSEA/OA/ IWP-UA k/Ar&A {to PL/'Wvr) Ce>/Y7*"V oP T* f P/W. TrtK if^aKe &EFtNe&y OP./?ATto*S A7*Y V^r tf f?Es^b/VS/g^ psR /9V'/' 0/=- "We /*W rvi/ T^fe EfFlu^T. tiweveR s.rfce me P^reuvr/^c e^isrs (?EPo^T^0 <^<7. Sfc'5 e^&(NpiN<y CAUCuUfnotfS /Tl>0<*-MzVfT - bid OfrTA- Otf Cd/VcertfTfti4-T70 VS "V ty/fc t^. Ho^Ei/eA S/^C_SbA--<s PftEci^/Ta-T^O //^ T?^ A/S /kicoW/A/t -p fi^Jr-D ,~AfiArU'i<>te? , (~.33 //y -v, 3 owr) > j*?Po>$re,/) < -fa . CfhVOFyV/?^ . PSiSl; EtiGiNESRltfG- cAL&jUVrtQWS/ ^TjC^B^k//-- Q) Seel wvv' frppEtfoix Report ^rom RSrb. .'ace By Checked By Date Page of Conoco Inc. Calculation Sheet Title Job No. Field S ftL 000005263 State Dl: PR [W20] READY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 [ALT] 16-Jun-88 B CD VOC EMISSION CALC JLATIONS FIXED ROOF DATE TIME PERIOD : MONTH,YR START : MONTH,YR END LOCATION POINT SOURCE I.D. # MATERIAL STORED TANK CAPACITY (bbls) THRUPUT (bbls/yr) 16-Jun-88 JAN,1987 DEC,1987 LAKE CHARLES STG TANK MMT 90 88500 BREATHING LOSS TANK DIAMETER (ft) TANK HEIGHT (ft) A VAPOR SPACE HEIGHT 01:23 PM (ft) D H h CAPS 8 10 5 D21: U [W20] 20 READY AB 21 [ALT] B DAILY TEMP CHANGE (F) 22 [ALT] C MOLECULAR WEIGHT 23 [ALT] D VAPOR PRESSURE (psia) 24 [ALT] E PRESSURE (psia) 25 [ALT] F 26 [ALT] G 27 [ALT] H PRODUCT FACTOR PAINT FACTOR SMALL TANK FACTOR 28 29 BREATHING LOSS (lbs) 30 31 32 33 34 35 MOLECULAR WEIGHT 36 VAPOR PRESSURE 37 # OF TURNOVERS PER YEAR 38 TANK CAPACITY (gal) 39 [ALT] I TURNOVER FACTOR 40 PRODUCT FACTOR 16- Jun-88 01 : 23 PM D41 : (FO) PR [W20] C dT = Mv = Pv = Pa = Kc = Fp = C= Lb = WORKING LOSS Mv Pv = NV= Kn = Kc = D 20 92 0.4 14.7 1 1 0.42 28 92 0.4 9! 13.33333333 3780 1 CAPS READY AB 41 42 WORKING LOSS (lbs) 43 44 A c, Tri'T* at r/*\e?e? / ii. C Lw = D 0 SAV. 000005264 X ::i cj ' .6 A a A 3 ih F' u A 1 (::l-l-EAGc LNvL-j-lVOR i i.. AK h AhARLEIS RF I HLKV ..'iI){..IKt..h. t-ii"IUUN i RE;l...ARibLU ; 1 b / yr.i PA R POINT RELEASeS o t rir <3 q t-v 1 <:-x f i Jk_ '> I O'LrHj. l-'n I. I'i L Pi.-? 1 S-SStif .Li-iy 1 iOU. P I R i'-jl jM-i-'U }. ! 4 | h'LL.E Lb ! ai.i 11 i ve i pinsri L L.o. Crvo Ret r i ci !'u.el ui i. B1. end i no I ota! Hon..point Fvei oa-1 j 400. 3 730. (3.G00> rOTAu A I R ftELEASE 30 iii i LB' R E L. E ABE:: '). i ..At iO RELEASE r in-Si. i.e i .and f ar m ) 0 L~ -S ij. s . Lc.in_c.l_f imThL LAND i-*;EEL_fez.ASE. O. N/Ji O, Ur lu'i" RELLAS E 1 U Hf: i.' i L.l 4i 41 11 j too ool t> SAL OOC005265 1 Vf.<i F l"vt: (-'Ur1.1 ! WASiE TREATMENT METHODS AND OFF t C I ONLY LAKE. CHARLES REFINERS METHANOL i:J ! i h r\ 1-1L was ms rftEArt 1 (\E ATrlCNT METHOD TREATMENT ERF ICIENCV 1 RANG.:: uf,: jINFLUENT COiNFEN' EA'iIJN LAS i LWA t EL, I:i I GLOG ; CAL TREATMENT ' AEF.aB.i: C) 1 00% ( a ) 1 p b L p p in <; b ' SGL IF WASTE rJ] OLOGICAL lREATMENT <AEROBIC) 1 COL ic; .1 - 1 AO ppm d ) See i ab L e A i r Wastewater Append i . Chw/T!iLJ was not. detected, so one-half the detection l in .it 'D.L.-= 10 ppb) was assuiTiisd (based on l F 7 7 RAO Lake Charles wastewater analysis. Technical Hemorandum No,. o03--79-"o5E>--2, and EF'A Guidance Document) .1 H:i. = U(iiption based on data for similar organic (see "Est i mat .L ng Land Treatment. Air Emission! Waste Data Append! .ompouncis i n Sol .!. -J d) Based on Ponca Li tv Solid Waste [Composition okta. 00005266 SM- ! P7ETjf#f/0 LflkE frlfi 6P-- L?H. i(p 'C j VP - ico.oo ^ PottfT 6os5 O. &'7r75T v "Z&qo I ^QQ, /Yd>/V- Poi^T RELEASE ~ *~UG-1 Ti v~ES a 'Jfl/jEC'TiorS SpoTS M/ aP/o rL P(RoP/We et-ENQlNG ZiNjEc.^:oN Si PrOTrl Tfil&EcrrioN fta 'NT ftCOiTt /. cV S'?~&r<$ ; 1 pufP (E&- ee^O l 0,11] > ?x3(,rcHet^ U *2 - i J Ib'j- lb Lg * / T j- 2^00 7 ,L iY? -. C&'ios -- ;/)94 ost ('sp em'^'PE:^ ~to SGisvE.fi, C&omA Og$A4*^-' ftfAT U$EO * IlOO LS ^ Cfiv\ ??j - TotA-l Els<?iT! i/c <- 0ffs = i%ac u$ EWG(p/eAiA/6 W4TEF LArW Maae 5> CFec*-?c 3v Da: Page ^ ^(Oca1^ Oe-^rcM^^ ^p? Oo- iS- S/JYFf {=?!/V& F/VT TRE^nhEffT: ...g.J0(-0<r(Ci<k- e 'CNj ; fOo I !Bp-p-/C /E//T^ TtMFLvZfl/T CzN^^NTfiaT(oa/* I PPS - ( P^ t/W/0 ^q T7=?fA^e/V-^)| gPsiS * EYV&i^/FF ^ 1 fl/fr ^6 f/^t f/t/p giot-oGic^^^t^^^) >00% cPFioe^t, =r^FCu<c,vr' Conoco Inc. Calculation Sheet Title Job No. Feld State p**- 000005267 ^ i. "'o/ OAR A JO A Al.d-'l.iR ! KELLo"i 1:3Ei INVEN I'uR'r LmKE CHAF-'L!;.'::? HrLT I Nrl.i "'i ;uUkoe A FH f-;,n [AT b.'. .EASE MOLPPQENUM L<5 I.QX I >jE AMOUNT F: EL.EASED : j. f N/ h A \ R i TUi' -r" AU 1 H t Kr.Lk.AUE. O lj z i. cj .i ncj l... o b r- riuS rid 1 q Ti' i a L 0 i' r i ]:.! t:> n h ft e 1 k? a e rn fal air release 1,0}. i5t: L Ra 499) kIA'I HR RELEASE:: ft. 499) i.. A NI "' Er_ l_ E H S F:: Ur, -S ;i h t:; 0... o.i' t d f r*r" m ) uf_ f ;;; 5i te \ Lai l j_ 1 L: 1 fTL i....aNj.j KEL..L. tiat. : 4990 '5000 . LorR. > SAL 00,0005260 i 'Vo - oAKh i -.! R t:iPuP'l RPLEAvlE I. NVEN !"Ur' V ..Hi :1- CHARLE:.E> Rtr J('.|rPY ALLlR Cf.'. ^AFirrHALENtL AtiUUN 1 KE..L E A6LD (Ib/vr) A i I FLliNi I PLEApEb' I C.'f f-v 1 l'i r. S ! ;.i uat. j r'tQ Root F i ; ed 11o<..j F i O L ::( 1 I- ' i'j j r i I. K i.i` J. &aS' i[R it ON puiNT releases i - o a d 3 n "l L c) *-- s r- u.q i l;. j. ve Equ.i prrien r: Loss 'id , 3 L 'i U Mo . 4 1H 0o No . 9 Nub ri.v. ' ee-j Prep No, 1 HD 6 Tan k Far i'h / G1 end l ng Pr o-fe-s s Drain a OQ 1 i 1": j Tower Wastewater Pel ease to Ai. r Waste 'iia 1 ease to Air i o t. a 1 11 on--point. Release i L) T At., i-i 1 ft Rh. L P A 3 E ij . i376. 1 376 . < i 400 > 10 416 1 76 224 66 .1. /6 2430 \) 6 ij 94 3638 5014. WA i tvF' REEL.EASE 4 9 S'* LAND RELEASE On-Site (Landfarm) Of f --Si te (Landf ill >_ TOTAL LAND RELEASE ' o. ft / H J HE (.) 70 vy O 4 49 ij 0 loo co t- SAL 0000 05270 WASTE ]9Q7 SAHA 31..:. HEP SR 1 ! REATMENT MET! IODS AND EPF L C I EMC y L AKfc:. uHaFm..LS REF 3 NEKy NiA p H J H y L.ENP. ; .'.-iUif.r f l NAS I H" j MILAM R PAT MEAT METHOD TREATMENT eff i: c j: ency TANGE MrINFLUENT SO ACS N'T F A T H_ N ij A f:i iIJS LAST Ei\i A I FP AFiJF H El. UV F R UN I T }. j. OL..OG i:cal THEATHEN T \ t-i [ F"\ O P I L- ' 93 V. (a 957(b) >2.01-13 < a Pj b 1 ppm(c) SAL J.D WAS i E TREATMENT . AERG3TC) 1 O 03 t d ) 1 -- 1 00 ppm() 3a Bed an ddU. provided by Dr and t Sutler. See TaL.-lE' A--2 in Wastewater Appendi . !.. i ier-iTii c al was not detected , so one--hair the cle . ec t i on 1 iirut ( D . L . = 10 ppb > was assumed ( h a sed on J ' RED Lake Char 1 es was tewater anal ys ,l s , for: h ri ical Humoranuum No. 603-79-350- 2, and ERA Gui dance Document \d ) See "Estimatinq Land Treatment Aar Diueaion a " rn bo I. i. d Waste Data Appendi;; . bee Waste Ccmposi ti/jn Data :t n Solid Waste D aid Apfjfi d I SL 000005211 Ter 5"o 0i<>^ Ke^ose^/e Co/voe/VSATC H^WY f=CC_ &A5oUtJB All Othea StREA/HS CcMfostTio/vs ,wr% 3.0 3.0 3.0 ;.o ].o 1.0 See ApRb.noix E Fb/? Co/npar/r/Grt/ x/v^o. aae 3y decked By ate age Title Conoco Inc. Calculation Sheet job No Field State iAL 00005, 272 C^i-CU4.AT~/Q/y/5 StoR*&e. TJw/cs P/xteC Roof r k-e-Ro 5 ItS. TpyY .O?) {'Qo<4f\ +(yy.ij){ .o?Y,oo^rN I37&, iJ/ye ,0*1 / oo kerosene z (*> + Ce)( C>z} ( l7STT ") '- 0,3 '*/>vr Oisi. r (4 37 ^ ZO^V'O^X^Erf V* Jbil Yy t" Positive EqPmt l_oss = See /4pRa/Pik it /O.Q nr ib 7vr (Zaoutfe To^er^- TP/ Y-OCC?/ : ^ ^*1 WVjSTS ivATEi? ' 5PF^o/Vrr 75> 4< "7. 3 i 36>-(p ,05- 10*^ /y* * r IO* <-* O - Q U/yr */rtsT/E, ftELE^sG- ^ tc-toc Rete^se 56. & HM '- 27 I (/n*-rpi)('-^)j (^) ~ Zflll `//y(? RSleAsE ts A\ = ("-2.6 il uS/'iR)( O.OH l) ~ !ci t'Vy^ Recede -*> <.<wc = Q (Xteg'^teJ ) fVbT^ : 5&e RPPELtfO)cE5 EbR cAl~<uj<_atioN &*<JrGRo\>f(C> ENF=oRfi\sEn<#Vl Conoco Inc. Calculation Sheet Job No. Title or Field State SAL 000005273 ' ji'-if-. A 1 t-<Kr.f Oi\ ! p!:;L.iZH3c f MvTM i -iV- i... AkI:: CMARLEA RRi-- i !'-.}b'K Y A^CKX;.!,:. AMGMNl REi.i.'AbER ; ib/vr [i-if R'.\\ b.HShS !iiR A r-'U l N i REt.. /...<;ad i nu i..oii.s 1...,.0.. al/5t - h.jj , >.j a 1 M i " 11 - d a l ; "i'Re i.,-a -,.s a ! ;...' I rn . m i K K'f:.EmAR M/A 0`.VG r_ ./A. 49 9 '> Mm i EK AELRALA.: 40/ , . 4`?V.) On 9i 1. > j...i! : fj T , i. T HG J;;X. Le nd.-f ,l_l j; i iJ I AL t.ANI) ElLEhoE- .1. 1 3 . 900 . 0 3. 1 . ; 499 ) OR 1 L.i ' Al . KL:J. .i.i:~i'..ii": 111 AO : SAL 000005274 fijfi H ic.kE/_ C-&KS. C/f^WcO Point Reme^sez - N/fiT^Zf*rJ Coif1 > ^ /hosi'tt Vtr NoN' PaiN* fiE leP$E = too c32 x ? tf/x fobs C+fAl'rs^ hMl$.) Dvr-f* 17- - \Ob-} LG *: .OR A{V/-'//u}* ^ 10 60 ,1^ W, c')> - 3P M StH f5 = r//GlfV^l/VG CJ+L-Qj l PfTto/V 5 r/ATF (2 laNO water Rel4<E -7,t w toJ < -l2v- * (SF-FLuE/vr) 10 ~L%0 Xt-7Y Ni - P-O 2srO L%a < i_<?//A rt/t' -- E/vQ-i/ve: EL#.(rt& CA<~cv c-AT(orY S LMO REl~A& - (crtf-s/re uwO PMrP) /5^> U3 /^x * , m7H ft*' - m as ^ (S^e^ /Vrrei Gfistb - i=Ms(fyEE#tt1/6- Sb>S-E/"*T` ___ C^WO^-fi-ECE/feC - j|(p To/VS x ,o<Y - ^'iOO c ////Go /,>/ . C^S^-. SITE Fl a ) .--.gfcL%L...&f6tNPttf& TvV^ ^ Oj Poa/c/i ary eSTr^^TEj1 / Ste/: jo a/~5 C'aJ OiivposTi^A/ 'h E/oypt H/.V\er Phet/E CL//s/< prt'nav .'Jaae By CnecKea 3y Date Page ot Conoco Inc. Calculation Sheet Title job No. Field State SAL 000005275 ! 'V 0 7 7: A E A 3 i 3 R h~. P G i 7 7 EElM-IASE I AREN r-)R v J...AK t: CHARLES h`: F 1 Y F{El)iOL oUUEll ij!!-: RELEASE Di" c.\ci tv r ank o i oL i" u n c. I 7 01 ea a 0 -liiUUkl ! RE I..L t i _: L L' l a vr ; . 499 . AIK i j Li! F" F-` i_j .1 A F RELEASE Load 3 nq Loss ij r nenolt c Raust.iFj ug 1 -;.L .i i Mon--pot fit Re lea ini AL AIR F-xELEmSE to 09 Al0 dll. 99) W A TL 17 Fr-: t- L. E A 03. (. 9?9> LAND RELEASE 0 p S i t e ' L a n d f a r ;n > 0 L:tj:.3i..Le (Land ri.il ) TO'! AL. LAND KLl...EASE N/A SA. 000005276 ; H;-f! 1 ""F o Lm-WF-. i. b Vfc: r'UR i i'E T F F AMEN i' Ml-THGDG AND Dr"' Hi LFhC LAi-.E CHARLLG KEf- i WE E. 'i PHENlJi, I K L Hi 'vit: ill MiG "HOD I EE.A i HE HI FFF I Ci FACE n<`.H L.j ' f i! '_ ,1:0 I !..-i j' it..,!:: Di i l"!i I i. -i V- i i Ji . uG 1 I'D;i"^L 'I REATMEN7 mEFuFIC ' O ,L ' i /. <, C.H } D I LOGICAL. TEFATl tHF !" ` AEROBIC> D ppm(c > Da s ci<~ u t a prov j. dd b v Br and t But 1 v~r . HOC? 1' t::.-!i> t 1 iTi <'ri t 1 H "| land ! r S5t. iVit?n t Air" tiiOj O S 1 O fi -- '' ;i. n Wuato f;a I:a. Appaidi :. O J. 1 d Ghh Waste CrmpuEj] tioi'i Data j n Solid Waste: Data Append i . 000005277 ! Ptfpr/o l AkE ^AfLtZ *?0% VP- .oo3*t ps*c\ J Ovtr C*css4''c- ` f-$~fhy {4 ^ - 0.2*? pSt'*^ fti/VT ftt/teE - STo^erE ^>si /"Cg*? A-H*.cm*~t}\ * -0o?* ^ .--2. -^ _^. Nbrr-Pbirvi <?EcE*vsr = Fugitive Los5 Pu^r:v 3s' Valves, iib FlA/vge ^7 --A xX-ovy) * 35-<f,ooor/)+^^ 0<J Q IS)) * ' s&s x, ? - 6(?9 d- 4PU- ^/4stE RelBdHE (.*) ** l,!'! lS - I lS WATER nAtecR RE CEASE - \,! <A ^ 3^,5- = 2 3 C8 (j3 7C Vocffrr?/ W-y UflsiS- /H ary, roAttfA DATA TREArrAEfTT- e\aca&\CAt- (AeAo&lc) ^ TPA EPEi a V~r. T.NFLISEHT CANCENTRA!1 orf - O, Q\ - I V. lmc CANQ fiECB^E (afi-STTrc tARD EARN) O 0e, raster; 0 Steis-- FA/^i/VAi/Vff ZVDC'EAS/VP TReRxrcENT - Uiousiohi Caeacsio') , 100% Eff:cicj/~} XtfPUi/VT CifVce/VT7?4-r|0fV - 1 -- ic>o p/3^ f^OTE-S : 0) From EPrt GoiOAflfcE ftcc 4/VO CtfC tfAHMoo* (z) 5fLE AW>eNO\X F- - S*U6 ^#sri? Mr# Conccc Inc Calculation Sheet Jot No. Title age Reid State SAL 000005278 f. : * i r* f\ r, ;:** r. vo -- a, f; fr\ /7 r, r*i ?* n r*. "p ; , * . -At" : ' T- y " ? ' n VCL LrLIT ' ON CAl.CL - : V f L-.FD FT LF ~ IT R i ART j.-a F / :.,T, = dec 3 7 :J7 i' GLi 1 = i-.e i.harl es I'LLMT hr: ;zk : :,-:e sranEii' F t-isoi " onenal ; caLiiit i i ALL ...iPA'I L r"'; 1 ?ol " - 21 00 \ot'- vr / t: 5714 A BREATHING LOGS ; !! ,V| 11 l,j , 14-N*-/ -RF "1 --NF DIAMETER 7h ! A r-.ir. '-re: 1 GH i ( f t ; '.'7; DFI tn ;<1 11 r il m :<n!.< n 1111 111 M 1111 i-t 11 >11,.r ,. i.. ,v: -if j.t . ,i ,'.T i,i ;.i ... , . 7H | r, D [\ T) P , n n - ;-(i P p- p p r1 ^ n n p p p. p p ;; r D r'V:"O' npr^onr-r. '':t ' J0 : AL T J D . ~r L :'!! i ?, ... ,, hL T F - '.7 L AL.T 'J G r.;..T : i ! l.j Hivi- C 1 hMETER (-ft; TANK HEIGHT (ft; VAPOR SPACE HEIGH1' t) DAILY TEMP CHANGE (F) MOLECULAR WEIGHT VAPOR PRESSURE p S 1 PRESSURE (psia > -RODUCT FACTOR PA m! FACTOR STALL :ANA FAC TOR ERRTA'HIMG LOSS J. b i: u H"t dT ~ Mv pv Pa = ! c --rp " Lb = 24 1 JiF M:'1 4.. " 1 'j .. " i *7 WORK. L i\\G L ,.OS MULEC: ;*..AR WEIGHT Mv ~ H'/J /v ? r: rf r1 My! r'ri-1 r !,l .! >1 ']/! r] <1 ii :? ir rtr? S":-': i'i i-'1 AM ::!! :1 1 I <. SAL 000005279 'L'DDr'D ErEc. A ~ i-- l hi'3 GCAC'C - ' T-- ;"5 r r\ T-; Q ' r ' hofa :ng loss MOLECULAR HEIGH' VAPOR PRESSURE # OF TURNOVERS PE ' TANK CAPACITY igal HJRHGYER - AC:'Or "hc::rAcroi-; OAR i ng --Css ; : H'/ Fv M -J i kc - -- C" -.L LUSH . 1 z:. : 7~ .7 ! H {'! ?! ?! ?! i: ?! ?! h ri ?! ?! r! ?!; ! ?! A ?! ;? ?! ?! ?! R ?! ?! ?! ?! ?! ?!'?! ?! ?! r! ?! ?! ?;?! y< ?j ?*;<!?!?: y ;!?! ;.!y*; 1 'I, .r `W SAL 0000 )5280  GAEA ,cLu;-:i,- : i : ! AkA ui-iAki-L S 'VAAAri A 1 i i!;: v f-o: lAjAAfi k;i' _r r h A I 0 Ai-iGAAl Ku v i./ v; ., . ; ui : "'k'...CAk A V' i 1 f" ! *-:`i J "4 ; f\LL GAEL: i ;*i. i-i ' rd:i!E A i'-J H MA i.-.': ' i : i: A EL A Adi: I. !.L> Etii...A.i-oi:. iJi : Ai to ' V a- id-?- v.r Hi) !J V- v i O L-j.l it. A". L ; ..i ! !**! i !.. ni'-i !/ H sM- 0001i052fll L: ; it; r 'Al. a ita:i r AA A* wj-ij i d !. iinf-h, .1 A u!r\ ]' *! ::::r; ArTHoOo and sakf rdiE;*: i i._. --!h u h Or<I. I:: r vL'r I Nfc"R Y r:! 'Jd-PHOR .1. L At. 10 i ! A I i;:0ri OA 71 i Jo 'i ObATMr;,; r tr'.FF .1 L I l::.NCY i "Ji-- i r NdA/i'RAi. 1A riGM 1 0::1 .* 1 --'i.. i. ! J. I'N OAKrr or If ;i::LoLli r iU i Of i' I. i. A \ a ' *V cH ? O'-. pro. i ;.!ed bv BrarvJL Butler. SAL 000005282 A\P P^Sf40p|C firCiL: fhR RE-le^zC = /'//A uW D 6^S)S -- pH ^ HtfAiWGr T/f'/r71/`T /VEcfr i*-L /?HH/0/V toe % TC/FLU & rTT CG/VcE/vT-ftAr rio 7~ = >1/^ lMO el^(off o-n? ; ,,/Wfi - O. g/hsu -- EWG,(Vf'/'1'Vc- T^C^c/'^'V-- TP.e^TT>nr/vr s NS.urGfl-L.ri-AT I ad > /oo^ EFFIClEAfT jrN^Luet/r c.ifiCFNip.fi-n -V ' > | P, '`fiQF C-ejK n:i^ P'HC*' Title Conoco `nr. Calculation Sheet uob No. Reid State SAL 000005283 i ' 't:-' ' bf-'ihn }. 3 I 'InRUR Kill. .LMoE INVEN I OR v- .hit: .CHARLES REFINER' `:J5L3v.xL^iE. A MO UN r R E Li-: A BED ; tb/yr 1 ii- ; i r-i i e> ,oi-:: M:- ! It. N I'Ll M PEL2AEE3 !-!; ci i En n j. p man Loso '.t-m u J. -A: i* Cl I: Of- !'' (Aill i. Cj ':. ?:>! Ou.. !...:01- ar A .a o Ri0i.: i..j i--r v p' i. --tnO ; l,l, l,, i**' Vo Oat Mm v i ! i uVi i. A r ac or i" . -!. i. h-;,i or: Ac. .1. '! 1 r! J !'t X `C I. .1. T.. I. V00, u- :l: f. crtAtSr M E-I !?#. Sr " tC Ml' Ac a to Ma i. 00.se Rn Mir ola.!. Non-pcant Pel ease 240 420 I. 40 40 1 2 400 <b 200 j 4 300 o 200 2 i 00 o 031 14 1 1. j 1 i:r release 631 14 63000) EAM-F-: RELEASE M/ A LAND RELEASE SAL fifoPVi-grVc CAu^uc^rnoN S f=bir/r rtecEftses -- tf/tf (f*s) R/friri^ EQoiP/*E/vr Losses -- Sec j4?1/M0iX X tfoNe To W& ; UWA " <SAs) acts 3y C-ec.ed 3y Date Page of Conoco Inc. Calculation Sheet Title Job No Field State SAL 000005285 j 987 EAR;A i 5 REF UK'f RELEASE !. NVEA . . jRV lake l` maki if: 3 refinery '.ipOIiJH HYpRU.XIDE i.l! AMUUN i FA-E, K A ED i b v't- } I-i .i i'\ RU 1 L i l"'.!:.:LL.-iRF j-. j r: l-iui I- Pfj I N 1 RELEASE AFAR.. AER RELEASE O. O,, Am ! i::.K RELEASE i .AIM'D RELEASE N/A 000005Z6 SM- vL.L ''L ]. / .:iFtF;i-:i 1 5 Kc-.PuF-; t i'REA mLNl" METHODS AMD EFF i . LEM : , L AKE CHARLES REF j NLP , LOOJ L:M <:j.a.i-'jlQX_I OJi 4L_. : ! i. . I'UiS i !-; : EHs'l 1 R Eh T M t-NT MET, tOD TREA1 MEN"'' EF-- ICIENOY hr.NCr' ; '.i f i Hi ELEN i >.L HELM EH ' ! UN MEN F EAL i. TA7 UJN L OG7. < l"(a > Sailed cn data provided by .Brandt Mu11 e-r. S*L 00 0005287 SsCis/^ tf yQ f\oyi D ^5oUfs^ bpt - vP - )~^QOa CL Nil. ( EPt *V^ calcj-**:&/v V0L*T (HT'f AiP REuPPSE (FuG'TiVE. lr -^\u:CR^>^ 4O BPS;< ^NGi(/EE&\NG- LPLC-UL#Tfa/v-' /jLoGB^c f^i WATER RLeEAsE - O Bfo' p H f'nN i to a> /vc- " L To l r^A'/v'f/zr -- aeutprue r^ioaj ,o^ /o E^/or/i/r T/vrcLje/i/r cf/vcL/sTfi p n ! 0 N - > \ 'A IfitiO uAr/Q REuEAiE- = lV/A Bit5iS ' tfo rP/w^s ; /?ecycc Speat caustic rtBuTR /V Vvtfsrn*47*v? ^S ' C/h/sUc_ WMstf Made "v CiecK^G . D^;e Page Title Conoco Inc. Calculation Sheet Jod No. Field 5AL 000005288 State j. '7 c` / b'Hfli' i J: 1 t^'bHLiK i RP^IASE INVPNTORr I r-lK CMAKLErE ht. i" i I'-iEl 30 0 I DM OULr-MlM. f iT'li .'ON ! r< L I. C, / y i--f V O' P i"i L r-i i" i i--! lf:'. i -- r'U J t'i i i-'f..: i...r.. Mp'f:'. ,V) .';iL . i LB I 'h::'i.(-V. ri N/0 M/ O 'it ;i i ,i'\ i"1'fi. Lm 1 .riMi.1 Ki.'-.L.f-.Obi-;. 1 .> V! - l;.:: ! te > : u;i 1 :<r"iTi> - - t~-p ` v0. .v'J.it'.t.A. Li_L O i Mi... L- iN!) H:;: .r-iOL 1 / f..'1 L 1 >.J '.J . M__ A 1 / 000m SAL 00000^269 OOOl us* -'*-t- -c: AiR Y/f~`C * fhR RE r t~ (Iff- (Z&OU < MS h^E-ft D#(ft~ Yh^io? -05$ So t*C ~i~o iS< 7S -^0 ( X PVUcS in t-AftO Qu\ckx^). H^r{z fir^xr SE -- /k<) t>5E - Ct Ofrpr r ' mi. /4c rO CAS^CS^ ' 7^yooo l @ Ci" * - l)aL/bJt>2 t-& ^H-"cv fWs.fice LOi/i^oj- ic,<j coo = S8Q o3 ,/j /K,. ;g 6*Hi% - IT/\/(SfMrH`AiN& ^uq<$e/*iE:a/t 7tn ^WPVb(z.^r ^Ra' v P^Aiv'r AcTn/(ry lA<tf) Ct DRiPt- *^4(.*i- (__V Title Conoco !rc Calculation Sheet f Z` ~> f' `:/~ JOO N( F.e a Sta:e SAL 000005290 CALCULATIONAL METHODS SARA 313 Storage Tanks 1. Calculated total VOC loss (breathing and working) using AP-42 correl ations. 2. Used Raoult's law and the liquid weight -fractions tc estimatevapor weight fractions of specific chemicals. Loading 1 Calculated total VOC loss using AP--42 correlations. Assumed 987. efficiency for vapor recovery or flarinc Used Raoult's law and the liquid weight fractions tc estimate vapor weight fractions of specific chemicals. API separators Calculated total VOC using AP-42 emission factors and refinery crude throughput. Assumed crude oil component composition for separatcr oils, Used Raoult's law and the liquid weight fractions tc estimaiG vapor weight fractions of specific chemicals. Fugitives 1 . Estimated number of sources per unit from published (Radian) study and/or VQC monitoring data. Used SOCMI emission factors to calculate total VOC r=. missions f or earh unit.. Used leak/no leak factors where VOC moni taring data were available. Divided the total VOC by the number of "major" stree ms for each an it. Multiplied the VOC per stream by the liquid weight f raction of the chemical present in each stream. All relief vaives servicing streams with loxic chemi cal compositions above deminimus were considered t_? be c 1 osed : i. . e. , tied into a flare system. Process Drains i Estimated the number of drains from the Radian stud\ or VOC monitoring data. . OAtvsf>(t SAL 0000052V1 Assumed 75 V. are covered based on Lake Charles VOC mon i tor mq data. Also assumed covered drains released 90': 1 es s VGC than' uncovered drains. Used AP--42 emission -factor to calculate total VOC emission from process drains. Assumed crude oil component composition. Used Raouit's law and the liquid weight fractions to estimate vapor weight compositions of specific chemicals. Cooling Tower 1. Used cooling tower circulation rate or crude throu ghput and AP--4! emission factors to calculate total VOC emissions. 2. Assumed crude oil composition to calculate release of each chemical. Wastewater Releases 1. Effluent a. Used monitoring data where possible, such as fc r phenol and ammonia. (Ammonia was corrected to free ammonie ) b- For other compounds, used snapshot analytical d ata, such as th 1979 R&D study of Ponca City and Lake Charles astewater effluents. If no analytical data were availabl e, but the chemical was suspected to be present, data for si mii ar compounds were used. 2. Volatilisation Vol at i 1 i r: at i on from wastewater treatment impour dments wai back-calculated from effluent release estimates and EPA Guidance Document values for treatment off icier cy and component volati1ization. Volati1ization from other impoundments was based on plant provided infor mat ion. Land Releases Landfarm a. Used land-farm disposal volumes and component a/ft alyses to estimate the amount of chemical present. b. Used ERA developed data on land treatment to e timate waste component volatilization. c. If data were not available, analytical and pub i shed data similar compounds were used. f os ff--site Disposal Disposal records and analytical component quantities. data were used to calculate SAL OOOOOS 292 Impoundments . Impoundments that receive periodic cleanouts, such as wastewater treatment lagoons, were not considered: in land release totals. . Releases to land were estimated based on plant provided ciat . Leakage to groundwater was not considered a release. Spills-*1. Used spill volume estimate provided by plant. 2. Calculated the amount volatilized using Raoult's lai* and the liquid weight fractions to estimate vapor weight fr= cticns of specific chemicals. 3. Assumed all contaminated soil was excavated and stor ed in a mannei that prevented contact with land; i.e., no land rei ase. SAL 000005293 uwe. Ct+APLBS STaRA^E -TflrNk-^ (SAMPL.E. CAlc') calculation MET-HoP> : AP- HX Voce x / Che/* (up) ylo f. cheat f.V ToTAC SAMPLE CALCULA-T/ON ' CVcloHEXANE - ((M-P'o. s heU, Ca.sts>l`ir'o') 2 * ^ Vc O^AifkeJ Oo.>e l>'* Wf % OfA'hi^eJ Cr-+>}o\i* ^\ O - CACAO To 0. OU TS r~%(r C a-s. iO*r 2 . C^ecK^o 3, 3a'." ~iqe Title Conocc Inc Calculation Sheet jod No. Field State SAL OOOOO5294 LAKE CtffiflLE 5 : (sfinPLE CAi-z_) La-401/VS- Loss C4tCui4T/oAT AneTAQO ' fi-P-^X Vac < % ctfEK (no) x \oa ^y C-f+E *1 'fv TbT-/f Ct* *-//? Tv SA/nPLE C4LC.ULA-T {0tV Be.f)&es\e. - 10.69. ^NS/\fH * ^f l/pC *v^cvvj Co*'Sv'r4 A jfi/ 3,7k ^ ^ ! T ) OO (c ' 2- o Y ? ToVjy ________ /*? Vgipor Prejs^^ 6- Mace By CnecKt-a 5 Date Page or Conoco inc. Calculation Sheet Title job No. Field State SAL 000005295 lAkr CHARLES (SAftPtE CAiLc) FUCr-lTtVE EQU (PftE# ( Loss ' CAcjjcAHoN WETH-eO : A/- Soorcg.^ * x S&clPii:* * (?uwnn -- NQs\ i $Ire* m*, _ - v'oc (_M < A i/oc CHS/h lOo ct+e/i^ 7^ /?-,* SAMPLE C#LUl4T70A/ ' /V- ^ ctu itoe.-)?/ C<*>*0- + & L ' * f Tcbitf 0-2 /Z?vAiuw *ZL /ion- f6Ak (.tf) ' 0-2 + NH(.qoo5() + Hl(mii) + Ml(xOOl%) fu 1A ff ssr* #**y r\6s\-(e*\k * rlo/) ^>'2. -M psV) * 2(.<=!(,) + l(,o%o) + -2(0.20)1 *2i * J61& -r2Oooji 1* lUk+U* id, SS* t A-* t f+ f ~Z *.,,* -f jfc/s " /^ ne*-/e*4 /**c nA^U+/' Srrg*** f * >r SfffcA^J. -ift" ^encp^n ^Oiycce. S/tst/y + L^k/Mo Le^k /or ctf LC- \/0C- Pffar,"r\.<i I/O CL /Ho^.'lW,'^, fv'iCi- 5-, Che'K-c 5. Date Pjtge ' Title Conoco Inc Calculation Sheet Job No. Fieid State SAL 000005296 LAKE CHARLES CsAMPLE cALjC.) PRocjEss ORA INS CalculationAL AiBTtfod ' ft' Dr:*s * AP-HX Fac.'iyr- * XRvlbTx % at* i* ceuQE lo<$ X^ =. "fi, IbTfrL C^A7 7o AlR Sample C-Aic^i/mo/V ('X'XZL**! xr ,Oo7 + 7/3 v .07 ST ^ * 2:V f /VProcess Drbm'^5 C*ppeA f !^ l e<rwy f j prec^-sr Pr^.Wj f ffp-iz x loo T n/f"* Fr^cfvW $****>* ,V\ _ JJT ?. ^ Y* vV<k^ Pressor*, V^po^ f'hsj.jvr't Cr*Ve x T6A/ Z.Ooo c vlrtCG S' - *r,Cl'-?\ Sate '-?ge Title Conocc inc Calculation Sheet Jod No. Field State SAL 000005297 LAxre: cm-MlBs PtPZ SPfrP,P,TbR / i C4LC.\ ( 5l4*i Pu J CAt-CL>L.fr~noM ftlBTTfoQ ' (Fco^f x / So<* of --v V Stij&CJ:*, J AhP-c/2_ SfA?Al 4p c ulAT(oM c = 7ro <^W >< --.<*0*^ f Tbr* Pl-Q'*' -- \z?.7 Cf^SAi j/Y 0O CttfA Te>jAL CffB/h , 7^, *4^/? Z*{ kr- Z(pyy' P*^ ^ v V yr loop &AC. |. r S3.,Yy r v^'4 ge^*< 4 tioec _Ky>f f*. &. ^yo^r O-c * 'ade Sv Cnee- rr2 Dc1 p~ae of Title Conccc Inc Calculation Sheet job n0 Field State SAL 000005298 LAKE C.HA-RL&5 (sample CAlcl.' CoquMCt TbwERS ' CAoCULA-TtQM rt^THcD ( No S~hr >'pf? * s\^ k&L Cr wJt '* 2 Aievfe'r . 1& A r C'Z-Hx3G$~ v to CAetn QiU l Oc> SAMPLE CAlculAT/cA/ .' H^pZlpac* 8ol y* ^ i.-z cs ^ loop SCi. f /4P-HZ. l -h> ~2-doo fCy >r P'^Je- -. tO> r f/Vc^ C>\o%T*p ' v C/Vet <1. Vace 3`. CnecK^c Dare Page Title Conoco Inc. Calculation Sheet job No Field State SAL 000005299 00SOOOOO TVs sieJS PiS'd on aor 70Q 03 2 'Itnfy ^ . '5<L 9^ U/V3^\r -r+v sags uoije|no|BtD DU| COOUOQ 9U!i 7o i /*?'? >< *VC, ~z Z_ / l % -? ) / so' -- %n ) -9 *b*99 S') ('rtJ x t 7 "Si ?"> ) ` (w? tWO * Ci^ -l - *V#7 <,0/'* - "^32U3,$ ; /WLLV^mTiO 3~'dwv$ "f 372 T*1^ 71 % (^ jr^'*135" <5j. j.i '7-c?; -3V(^ -J-.I (p ^ JO fi.-7 "^7-^30 * \-j0~) ^ '-^'D - fvAo*>y % -T * ^07d Sddx. : QOHJ3W NU.-ti~>convZ) (^70 3ldWj/s) ; *y3LW7W =us-pm 5j7pO JJMfl LAKE. C.HARl5 CififrPLE CAlil) LWO (ZE LASF CALCULATION/ METHod L<*/\ol~z\C/u> ppno >0 /o ^/olcx-fi&oeA * C-Ke**', A^r~ Qour\4:riif D<->*ypejk pp/n xr ^ \ ~ % lhUi'iesh " jr&Ae^ ~ dhe**, "^b S4WPLE CALCULATION Benzene r 6</ <r* izris 8*o SocfDS Ov/+feA. + /a* <tv ppf* fame*? iK Q,''e 2 &o0 <~ T* V lo^.G, 'C?..(fi L$ ^ .^0 3 - 1117 Tfe/vs SaL/^J HI tou PpA~t 6e*ie*te tW ftPE Soi'Jj <-S 6ev/vr XA/ W^STP ^2,6*5" L<k GV2Etf 7d /h/% 102.Cr> X { |-.^3 " .0*7*7^ ' O Tb o<?/vy) IF ov* * fO 2 ^ To L*/V .'.soe i: C^ecK- Datc- Title oanccc ;n.: Calculation Sheet Job No Field State SAU 000005301 j '`L- / AAKh j r\'Ri 'OR ! ' Ir. L L:. Hi S b. i N'v'ErJ I UK Y L.hK.~. OHAF'lLE r> Kr INt.Kr 5ljUki':c yuui'U.bjyti uaide. Ai--RE}.... h. b1 b/vr A J. R RO f i I'l'-Ltinbr:,; U tk fn i. srii o n lLLtLE:..:. r;,a.ini; 'Uie^iS h x E 1 Ju}'.( -f-'01 NT RELEASE iUlh!.. h IR KELEAUii: 4_5_6O0._ (M.'ooo^) 4.1 600 - N/ A 4 J. 600. Oh i F:..F\ EE-J....R A'-:>L ,4 / A (...Ak I ij R E L E A 8 E On--Rj i; s? (Lancif ar -ti !J_r f -Ui_6t5 KF J i [' i PiL LAND RELEASE N/A '? 1 4000 . 9i4000. \ 9 l OOuO ) sal 000005302 MAA'lE 3 9B'/ bAft A Si A REP DR ! I'REAmENr METHODS AND EFFICIENCY LAKE LrdAKL.Eb REFINERY ALUM I NLiM OXIDE MEND KmL WAS TES i' REAM 1 REA 1'MEN'i' flfclTHOD V REA MIEN I EFFIC lEiOC r .Ml YJL L ' IMRLUEM OML-LrM Er-M > MLCHAN i LAI . SEP'AF\A f i (Jf -I . 0- l .LL (a CASES' ELEC fROSTAT 10 H'OR A'-y . '?'/. <vb ) Darned on Ponca C i. L , c. a. i. an and the y ac 1 l: t -i a <_ L a Char 1 e-i La a.li. qh>:lv Larger (per Srandt Put l r . Eiatr-ea on iTic?,nu.tacturer data (per Brandt But! t '( t.retinen t wl thi rnechan i.cal epara1.1 on > , -quer t sal Oc 053o3 At# wArefi ) P,Lun<riun oXiOe;I lake: C-HARles ftoN-fbtNT RElEAsE = N/A Poitir Release - HoTPy 0) * iPcts SrAcjs) = ^600 ,b/yr ^OOO tb 7W X 0.52. -- Vtoco V g4biS - p\p&$ BAcA/Vcc ciAuCuuAT4'V3 sEQuewiAl. T^^TRn.E^T : Q M&LtfAtflCAt SeP4/?^T7fl^ .zyTFcu EAT^ <zo//CE:MTWTt(>M' - / -0,0 / Vo c?) @ ELZCTRa ST&T /c P fT#To K -n?4T/Yr Epfic/rfcy /* ^0 r/A-TBA. Release * tt/4 (5) la^/O (l) l4W0 RELEASE = /, 2T X 10 = /}75"^ O*o X. - *?/<?, Pop ^ ^ LAi/dFtU- 5 uke-Sfre') /34S/5= />10iV/TQ^/^S- VW? ^^A7~S tfJTES ' CO #- SfttftoT auTLe/^ 0) S CoMpa^iTio/v' MtW ^/WE/V^IX E PETE* fz) 8frsE$ cN PqNca c/77 CAuzulAtioR MO T 4-.C. XS SUl<kH-TL% LJfoGEA(pEfi BRAHtiT 8uTL#) ^SEE Ct LcutrfTw ?v ve<r ^ (4) tfPArtoT &/n.e* 4sE0 o/v MMuF%crfi&l OfiTA Qg) SUiQ3 T* W>V iVftL -SETTLE j /VeWE 73 EFFLL jz/vr Made 3v Checked B , Date P.nae Title Conoco Inc. Calculation Sheet Job No. Field State SAL 000005304 -------------------- i-------------- :-------1------- :------- 1------- :------ !--~~------- '--------------- 1------- i ! i! i 1..................................... ......... !------- 1------- !------- !' i: il1:i,i1 1 1; iii j ii :1 '' :1 11 atjt 1 ( or >0--~Tt>\ (Gf-f \.o AifT ( PoNC-A > _________ - i1 /An : -tt'jxXv___ _ ;! ; i itRi 1H ! '1 ! , ..................................... ......... ii . J. --!------i ri)___ ,i j > AA i !i1 1 i !,i: :i jj 1 ta=Flir_uhlk"Y^:!1 1 it, i1 i ____ i____ :1;! j \ : ' ; 1 i 1 i i ____ L_ 1 ' ___ :____ jfi 1 1 i i /A fl[ L i , 1 i ./ i 1 4?). i ! 1 : iBzl i| ! 1 !` 1 iI ! i::i 1t;,i | "y y kj4/Y ' /A \ ' 1 ___ L n i j 1 !: /r i i i i! 1!i 1j 1 \ |i L2L 34 1 v!.773 Irh |3 i' ! 1 - ii! ,1 11 1\ 1 i !jji! 1 |i i i ! ; i! ! 1 ! it ! i 1 ' i^I!' j ! :!(,'! i p--: ; |--! ! 1 i 1------- >--------' -----.-.-].------- 1---- 1 i ; i. I| !------- j j------- j ; 1i r ii ii *1 .! i !| ;1 Mi1-' li t , fj!11 it1'1 I i; 1 Mill'' ) 1j 1 i1 i1 i1 | i ii: jj i1 1 j! i 1i1 1!! 1! ! t i 1j \i |i ____ !____ i____ ri | j i j ^ i !!! ! -. ! i ii i 1! [ t 1i 1 i; 1 1i :! . J__ !__1 1 i : ; !1 i jfii!: M]1 i i< ii IM1 _ !i!!; Ma0e BY--------------------------------------- Checked 8y___________________ Conoco Inc. Calculation Sheet Job No. I T DateTitle____ ____________________________________________ Field____ 00000530s Pageof_____________ _____________________________________________________________ State 1 bu! iRCc. 'O'cp :: ARA ] - RrPOE'T RELEASE I f'-iVEN TORY !.. r-i!1 C r 1 m R L. El S A E F 1 i-4 E RY AHHGN I AMD UN T RE L.E A 3L.D i ib/vr ) A F. H !"`U !. Ki ! RELEASE N/'h AIR I Y I i'4 -- F' J I N I RE LLi-iEE: ti ve Equ i psnerrh Losss Crude Urn t Inhibitor w 3.ri-t. eba t er Hel i?_33e Ro A i r i <.j i. .1 ; .1 or i p ij 3. n v R e i. es *- e 34 0. Y 429 , 3269 . . 3200 ) ' i.j i ' A t.. A [ F R E L it! A 3E . 2 3 9 . WATER RELEASE 431S. (4300) L.AMD EEL EASE U! ! U t ml U MEDIUM N " A 36 z 1 00 I oo SAL 000005306 MriO i :i FA f 'A .!>.! o Kbf"UP ! I htn ! ML h I Ml.. i h-4 L ,3 fJ G l-.l-i- [ C. A: A..- i. ALL u i IrELEB r<E F1 MLPv rtHfii.M [A Gr- ('-ic. K- ML MAG i ! KLMM 1 LLA'i rib A J METHOD TREAT ME N'T EFFICl. EMC Y r.MHLR LiI Mi-' LLENT Cu Mf EN 1 PA i I Oil WAG ! EWM I'LL SIOLGA CAL !EF r T HEM 1 MEEUG i. Li) EOT (a) 1 - 100 ppin b .1 i EWmT EL RT RIF'r J MG , > TEAM) r'BY. (* J . %-lX (b) Et1 i V ;..1 i~! South r i;i 1 1 t L 'J. opond 1 J on e- '.Pori!':-3. Ci i: at. men L u at. a jr rjvi Av b .> D -I ied c>n F` :::> r t c: a C i t y d a t a provided by St. eve J :.'i i A fr . SAL 000005307 UftrtoMA1 MR 6P -- ~C C'^ &>\NT REt-eAsC - ^/A 44>T cHARl-S tiofi-Poirrr Rec.eA<. - Fua^tUve. ~ dr<_o(e 6/n ' 1"s y U&V 4 V^kts ^ . 01^ % * 2<1 x 3&T X 3. Te. m/C-TS SYo % V^S'k.itwHr" Tr^f^eM' Release. ~k> A^r a, N /r , Jbj*w oa 77 - (r^ - Oo^) -tZHIx-lO yr * --j - HiX'i li Csee- beicKv) - -Zi'X0! tb/s,r(3) A/#y J_ * l--I.-TU 7 % , A^fhJLti u "TaTiW- a/oa/'Po/|YT R(ZlA$ TV AiR. - 'S`2.(pcJ GAsfS erf^tneeRi^dr calculation wRtbR H^TBX 2^,5" PPM pW '7, , T = ^"F Z*/. S' W* /0,07. \ _ io, ?T / 0 s ^ 7*7 fa) ft*V /?E <.** - 7, X-/O^ JbjW <5, $"77 * /o* -y?/g* ^ 'finee /U pAr(u-*it~ LAdCi vl a G 6 3r C.'nec<.o = Oat* Page SAs/.S 1 _EiVfiK/ert i/V6" o*ccw c *4 Ho fl/ Tfie#rsi/YT'' (Xx.J-fr(oy'K*t C4es*hO Cb) '~>'h~,ppf'A^ -- ^^ A (s) f~ j J*rW Os/ic,' & G>flc, -0,01 - 17^ L/WO Title - 4/4 ;f*er cAe^i'o/J^y Volosrt.ieJ , or Conccc Inc Calculation Sheet Job No. Fieia State ^ 000005308 tfoTES ^i) Pe.ccy.5 M See T^t/e 0-1 3 PPPErtfOi* e Ce^tfswrv p|*c7T9/?$) Cl) CH^) S , $"<31 to 0*v n^A^s t_)i^1 i Ait 'S Vol %c_i k ^"ce /I'vxmomV CornLc'K'o T*blc C,'4y SooftA PU*r& BiaporiC^ C prvvi^ed by Sitv_ 3o**s) Or\ fiasco* d(-fy , f/a-e 2v Oec^o e . Date Page Title Conoco Inc. Calculation Sheet Job No. Field State sAl 0ooo53 09 Coacaotraeiooa U b/L * total tMoaia (M-t HI.> which contain* an uolooitad OMoaia (HHj) coocantratloa of 0.02 oi total ihoiU soot tha ataedarda for at Cba taaparatura and pH valuta above. ta _ V M0 3^ 2 36 4 3* 6 V3 fl ik 10 12 14 16 i? 57 6/ 18 20 22 24 26 24 30 32 a -MT Z7X -2 --_ 2______ _______ _______ vft____ o o o o rcso> 6,0 4.2 4.4 4.4 4.4 7.0 7.2 7.4 7.4 7.4 4.0 4.2 4.4 4.4 1.4 1.0 9.2 9.4 9.4 9.4 10.0 10.2 2S0 133 47.0 94.1 33.3 23.0 20.0 0.70 3.24 3.33 2.44 0.33 0.91 0.34 0.34 0.24 0.14 0.11 0.04 0.04 0.04 0.03 200 lit 74.1 43.9 24.2 20.0 11.1 7.41 4.33 2.46 2.06 1.12 0.77 0.41 0.31 Q.23 0.14 0.10 0.07 0.03 0.04 0.03 167 90.9 64.3 36.3 23.4 16.7 9.32 6.43 3.43 2.41 1.73 0.96 0.66 0.41 0.26 0.19 0.12 0.09 0.06 0.03 0.04 0.03 143 40.0 34.1 32.4 20.4 14.3 4.00 3.41 3.24 2.04 1.49 0.40 0.34 0.33 0.23 0.17 0.11 0.04 0.06 0.04 0.04 0.03 129 66.7 46.3 27.4 17.2 12.3 6.67 4.33 2.74 1.79 1.27 0.70 0.44 0.30 0.20 0.13 0.09 0.07 0.03 0.04 0.03 0.03 109 37.1 39.2 23.4 14.4 10.3 3.71 3.92 2.34 1.90 1.09 0.60 0.42 0.26 0.17 0.13 0.04 0.06 0.03 0.04 0.03 0.03 90.9 44.4 33.9 20.4 12.4 9.11 3.00 3.39 2.06 1.29 0.94 0.92 0.36 0.23 0.19 0.11 0.07 0.06 0.04 0.04 0.03 0.03 40.0 42.6 29.0 17.4 10.9 4.00 4.33 2.90 1.77 1.11 0.41 0.49 0.31 0.19 0.13 0.10 0.07 0.03 0.04 0.03 0.03 0.03 66.7 36.4 23.0 13.0 9.40 6.90 4.26 2.70 1.71 1.09 0.69 0.43 0.29 0.19 0.13 0.09 0.06 0.03 0.04 0.03 0.03 0.02 34.4 31.3 21.9 12.9 8.10 3.90 3.70 #2.33 * 1.44 0.94 0.60 0.39 0.29 0.17 0.11 0.08 0.06 0.04 0.04 0.03 0.03 0.02 30.0 27.0 14.5 U.5 6.90 5.00 3.14 2.02 1.26 0.82 0.52 0.34 0.22 0.13 0.10 0.07 0.05 0.04 0.03 0.03 0.03 0.02 43.5 23.3 16.0 9.70 6.00 4.40 2.74 1.73 1.12 0.71 0.44 0.30 0.19 0.13 0.09 0.06 0.03 0.04 0.03 0.03 0.02 0.02 37.7 20.2 13.9 4.40 3.20 3.90 2.44 1.54 0.91 0.62 0.40 0.26 0.17 0.12 0.06 0.06 0.04 0.06 0.03 0.03 0.02 0.02 32.6 17.3 12.0 7.30 4.50 3.30 2.11 1.33 0.83 0.54 0.33 0.23 0.15 0.10 0.07 0.03 0.04 0.03 0.03 0.03 0.02 0.02 24.6 15.3 10.5 6.30 4.00 2.90 1.82 1.16 0.74 0.47 0.31 0.20 0.13 0.09 0.07 0.03 0.04 0.03 0.03 0.03 0.02 0.02 24.7 13.3 9.10 5.50 3.40 2.30 1.51 1.00 0.64 0.41 0.27 0. IB 0.12 0.06 0.06 0.03 0.04 0.03 0.03 0.02 0.02 0.02 21.7 1J.7 7.90 4.40 3.00 2.10. 1.33 0.63 0.34 0.33 0.23 0.13 0.10 0.07 0.03 0 .04 0.03 0.03 0.03 0.02 0 .02 0.02 S 1 90 k OhRh 31 /' vtEpfjR "i" RELEASE '[ N v'Ei'-JT ORV LAKE LHhF'..L. ES r(EF INEh'Y BE.NZENE SOURCE. A[E POINT RELEASES Str:raqe 'rank;? R 3 oat i nci Root R blLLL'I Total Point Release AMOUNT RELEASED >; Lb/yr) 382 . 1 OS4_._ ] 636. \ 1600> OF rLN m it EL. EASE TO At:: I,' 1 iji'i 0j 14 a ;:e nom-ejin r releases l..(.jadi ng l. ass i Live Equipment Las:; No. 3 CTU No. 4 Hub No. 5 HDS No. 3 LRU & HDS Hei.iui ar Lc-ker HV in.i uiTi Laker No. 2 Laker 0<*a Recoverv' Rlarit No. c.- HDS No. V HDS Mo. 2 Crude Unit cc Lt 0aso Spltr Ho., i HDS No. 2 LRU 3 HDS !" hermal Cracker i-'BC Tank Fa^m/Blendinq Process Drains Separator s API DAF 1 AF CoO'l inq 1'ower Wastewater' Release to Air '.*)atje Eel.ease t_o Air I'cat. a i Non --poi nt. Release 1001 . 326. 210. 12. 6 .1 6. 6. 1 0. 190. 2 13. j61 . 3. 326. --i T `'"i 420. 33 . 1 960. jbtJ. 2520. 912. 1 25. 35 . 15. 216. 176. o3 10405. i 10000> 8 2 0 i. o 6 D 21 8 1 0 3 1 66 i U f Hi... A I It RELEASE L 204 L. 00 M A ! E P It L L. E A S E 499; i... hi N L1 R E. L E A b E Ur..b ite < Land-f ar rn > Off2-2-i.t..^ > card fill )m I 0 1 Al. LAND RELEASE 0 N /A ... . 0 SAL 0013005311 1987 SARA 313 REPORT WASTE TREATMENT METHODS AND EFFICIENCY LAKE CHARLES REFINERY GENERAL WASTESTREAM GASEOUS WASTEWATER SOLID WASTE TREATMENT METHOD VAPOR RECOVERY UNIT BIOLOGICAL TREATMENT (AEROBIC) BIOLOGICAL TREATMENT (AEROBIC) TREATMENT EFFICIENCY 9836(a) 95%(b) 10036(d) RANGE OF INFLUENT C( )NCENTRATION ( .01-1%(a) 1 1 >pb-l ppm(c) 1- 100 ppm(e) (a) Based on data provided by Brandt Butler. (b) See Table A-2 in Wastewater Appendix. (c) Chemical was not detected, so one-half the detection limit (D.L.= 10 ppb) was assumed (based on l|977 R&D Lake Charles wastewater analysis, Technical Memorandum No. 603-79-350-2 & EPA Guidance Document). (d) See "Estimating Land Treatment Air Emissions" in Solid Waste Data Appendix. (e) See Waste Composition Data in Solid Waste Data Appendix. SAL 000305312 >E!feEN eoMPoscTtoNS R.goiot.r G`isol'rt. On leaded l5o\ /rte, Super C/n/-Ap(ed FCC- (?c^q1 i-S^ Setsal<>. ffe,for/vic\+^ rudcL Vs/ff S^lS lky U'k- Crude. TP-4 I>ekj+^oiH.r- Qtf: O^e WAPK f h^J Coker- Cro^s VV* *%> 1.4 I >~7 2.4 `i 3.4 3. U *0,1 /.O O.z 0,3 3,3 0.3 0.3 SfEE frPp&rfOiX FoR COAiFo5i77CA/ BAc.KGRg'JA/Q T/YFo . ade 3y Checked By Cate Page of Title Conoco Inc. Calculation Sheet Job No. Field State SAL 000005313 CALCULATIONS 0) SloRn&e TA/VK75 | F^r/MS /%aoF ' (4.1 TPyX^A^) +(32.l TPy^^^fo^-X^Oj ^atV?yo_0/^ + (o.KtXo.owjJ * (ij renii^ Xtt)+ - 0.-2. =)| TPV -- Si% LVYft Fixeo fioop - (S(c,.zz-rry)(o.oi)({) - o.Wi 7?y ^ ioW C%R uof\o^Cr ussi^-^o.t,^ jp'i)[a.o\7C,) + * (t^)(30a)- IQOI rpy)fo.o3t 6?.S'5"TP'iX0, OI~7b), Fwg-iTivE eaPmx Losses : w ^ p 'C-rfwtufOcrEft on i^rv ffT/4'n'Mrr'ilAin 3 CTU = 3.M7 TPY 1^0,003 *- O.Oo^ -t- Ot OZt *-<3.0037 -Q,l(p3l Tpv -- 31L LV Process ORAi/VS - 2%.=? TP^ (o.,oo3Cfi) ) -OWfii TPf - ?a ^ ' rtPr ^ f?`?,`/2Tpy^(^r~Y^'X^'=o) = us- %? Cooli/YG to^S/K = (V?8X7.7 Meet) ( x C^7~) * Ojio? TPV = 31k yrf .'ace dv C necned By Data pace /Vores: 0)>e JfcPsA/DiX h- f=o# sroM&s ta** vbt oat/? )_5EE (3) AEe J^E/VD/X J Fb (-OA0/N&LoS-S |4?C (0^^ I ft*/? F^fr/nv 0*rV/r V^i. calculation MiO PEsT OP &ENZ.BME a^LCuiATlC^t? fjb^ E'qPaiT ^5. (H) see APP|V0/X r Fbtf PPoo=ss OffrxN Jc. (S) SE A^pEfVDiy & Fb* PJPr;/)AF;A^ X4F vbi >AM Af/O C/k.CuO/4T?OA/5. ((e) SEE Af'PEtfOlX <3- R*? C<ioOi/V6- I VO(T, Conoco Inc. Calculation Sheet job No 1 Title Field State SAL 000005314 . cCJs By CnecKid Date ?^ge aOUM.E RELEASE INVF.L-J T OR f LAKE CHARLEYS r vLF INERT B ip hen;Lk aNOIJN'T REi..E LASED (lb/vr;t air point release :/1 ui t? I an /. ; FI oatinq Root ioci Root i ut a i F"cji r11 Release AH': NGN'-'PL I N"f RELEASE Fugitive? Equipment Logs ,' CL Tank I" a r in , Blending Total Non-point Release I 0 1 AL hIR RELEASE i. O- i . `,<4991 144. 232. < -:499) 233. -i ; r~,|~Ar NA1ER RELEASE l . 49? ' .. A N D R E I... F A S E Ovv-Sitti (L.andf arfn > yfT;:A.Lii'.e IL-o-iO.d-L.tA.iJ.! DIAL LAND RELEASE " o. n_/.a 0. 1987 SARA 313 REPORT WASTE TREATMENT METHODS AND EFFICIENCY LAKE CHARLES REFINERY BIPHENYL GENERAL WASTESTREAM TREATMENT METHOD TREATMENT EFFICIENCY RANGE OF INFLUENT ca NCENTRATION GASEOUS VAPOR RECOVERY UNIT 9856(a) 0 .01-l%(a) WASTEWATER BIOLOGICAL TREATMENT (AEROBIC) 90%(b) 1 I pb-1 ppm(c) SOLID WASTE BIOLOGICAL TREATMENT (AEROBIC) 10056(d) 1- 100 ppm(e) (a) Based on data provided by Brandt Butler. (b) Assumption based on data for similar organia compounds (see Table A-2 in Wastewater Appendix). (c) Chemical was not detected, so one-half the d etection limit (D.L.= 10 ppb) was assumed (based on 1 977 R&D Lake Charles wastewater analysis, Technical Memorandum No. 603-79-350-2 &. EPA Guidance Document). (d) Assumption based on data for similar organic compounds (see "Estimating Land Treatment Air Emissions" in Solid Waste Data Appendix). (e) Assumption based on data for similar organic compounds (see Waste Composition Data in Solid Waste Data Appendix). SAL 0C 053I7 0lPWe/VYL CftoQutATtodS STbRAG-E TAM& ' itj HEAVY Ptc GA%cuNeT - z.%,2. xTPy * O.Ol X ,, x 2000 ~ %? (Ftocrf}^ fa*f) ( H-i/tr Eec FUG-tT] /E LOSSES SEE 4tfpE/VDl* X Losses : there is /vo 0At<1 clRooe 8i9HEN'i- <io^p. /Ksu/vie ^17* ? So PRoceh bMir/^ A Pr}CaoLiv& t*>*$ -c W4steWAteP Release : w ORTA D.L, - Ab giWerf*. S'PgfetPiC* ---- jj 72> wATetf " 7. 3/ x lO71 ^74 * S_^_ ury /<?' Lg ' 37 /w To - 37 ^4* tfi/ = 751 * * O - _0 .or rkk V,P, -asso^J v v^Asre* Releases ; r> DAT* fl-MMrfSUE: oN 6/tftfe/vw fcsvmeo sens: would ge IN W/HTES (s/MC J^ir), WfaTES TO LAt/OF'WM DE6&A&-. Losses To Aid rdoftr yv4s7E fiEOL. (vjv^J Wu^qejz P&0&A8L y ao V'EgS.. TOES ). Trts is Tf+E ONLY STREAM Asso/HE Q tz> CflWTfl/fl. Atfppeci/^ce giPl4E/VYL Csee APPEJi&X ). -ade By Checked By Date Dage cf Title Conoco Inc. Calculation Sheet Job No. **L 0OOOS3I8 Field State SOUROE i '"`o ' drRh ] U FLPGrUi RELEASE [N VEN i URV I.... Ai: L Ci-iakI...E 3 RE F ]. NER V J:-JL.J_:A&U A0_I fe Nt_ AMOUNT RELEASED (Ib/vr; A L Fv POL AI R 1 jOf-A F'i j 1 NT RELEASE Funi ti `vti t'quipment Lass i..-' a Kt'LO/PI' v Plant FPL Ci-vd iv BE hi kv 1 at 3. on Ac :i d F] ant L$D..k P d..C1 iF' .F 1 ..on d Losi. 1 ot; a I Non-po:i. nt Red. ease OjTAL a F; release N/A 1 J. 6. llo. 0. AG. 42. 0. 408.' aob. NA ! RR RP LEASE N/ A land kelehcT N/A ' Ur- T O | Al TO '-!c.;1 i UN !-;/ A 23 23 0 16 17 11 0 0 J. 00 I. (')Q N ' A N/ A SAL 00005319 1^3 guTlD\BNB CAi-OjufiTt GA5&00S 03(^1 Pou/tfi " PCU LOSS'S 4/? SE APP&MiK X fw/e F=CJ$iTi t/_ B.QUiPW&n-' Vc CALCVL* Tpr* iviaae By CnecKea By Date Page of Conoco Inc. Calculation Sheet Title Job No. Field 00000532 i 'VB7" oAEA 3 i.AERoR'i EE!...tii-i..-jc: IMvbN COR V L.AH.F:. L HAKER F'R.R .1. i 0:.! ' i CHLORIfiR. Ri'iURLi::. ARinur-j 7 be (1U^ M i.E EO.m 1 EELEabE M/A >-i i K oUl\l - r'LJ 1! -i 1 RR!L:. not .>o ij oq_ Tc'>w_ej- i <: t m.l Non -'poi :"i t. Re !. e-v=r:-' 2'> 1 &. 20 IE. ' ;j ! mL. A j K r!r: LtAbt: bo :l. B. wii i L.E RELEASE N/A i.... i- (<--! i) ER1.. b. h`iSb. N/A SAL OC 0005321 M `-AkE Pc<Nt REi-EAiC - |V/A Non-Point release : ^ Cosl.A^ "To^cri j 1 (?o,'/er JT-ij, . - WW e_pvc,k ' -- [ 2(,0/a) V s(.ool ?){$ 3US- - sL rTrp^r ^j- P+. - * (s'+t') ToTftL firifi RELSjASE = 2.0 1 ? L gfcib \ ENGr<NE-efl'rf<P CTWXj t' v/AteR KATE R AEi-EASE - N /A LfttfO ' lANQ Ri?t*fs- - /V/4 (*) SEE APPENO [X 6 - />i^5^v F^cro^s r\iaae By C-ecKea By Date Page o* Conoco Inc. Calculation Sheet Title Job No. Field State SAL 000005322 POUPEL >.'VA/ SARA 31-3 REPOK I RELEASE INVENTORY LAKE LMAKLEb REFINERY COBALT A M (.) L.J N "I RELEASED (Ih/vr> A [R F'0 I NT RELEASE NT iAIR NuN-t-'U 1 Re: ..BARE Hi) j C'j L a l v t ! Land 1 i ru] 1 ijiai i'Jon-poi nl i-;:e-'i ease:: ! i.j I r '< i.. A I!RELEASE i'-l / A 11. i 1 . < 499 ) t1. Wr E EF! f\E.LL: H'.:.'C. 499) LAND RELEASE fj 11 - i I. ta < i.. a n ci f a r hi) 1 jf f ;_-3 it e ; La;ruvf_i jl i ! i.J I AL LAND RLL.EmER 39. AiLL.T^.. 2452. v-:499) <3400) OF T 01 AL. RELEASE 0 MEDIUM 78 AO $4l Oc Oo s3'*3 coe qctj ^*7t io p Vi/A-te p PoitVT PE^et-A - zl/// <9 ftofrn ^a/- poiNi-- Release - 6) ii4smi*a <^*5 Ago f- >a S HOs fl-V6. r? u/vT *37 v -/^2- % i)Oo v y ,oh H& C*UH& Wig.) ^ - ^f3 ^ /W/Co x , 2p Co <o sr r / f LS C^3 &&Z15 - Ef^&fA/e/7/?](V<S- C4^CC/Z,^T/ 0^4 T7?e:4T^rfVr - A//4 A/A- 4 R^LFAS E - >r ,"0*75" y<^ ^'/Co 71 `*4* c. + OS*s* i^<5 * &M5-t A/rztf fA/o JR&A7^EVT /V/Vt cpti-uc ulatiqa/s / . T^C 3- /* sa/T' LWC IPrKO RBUjTA5 CctS-SiTE.') ~ /STZ? ^ /, /T > ,16? C > ( L^/yC1 TR E fffS* (T S/t \ ~- I*5? t-/%/?l rn .@$S> V._.. *_ EiVS i/VfA/<? cA^cs/L^io^J / O cf " A" /. /^T" .^^0- Rel-R<e C&^~ s/rs>) - )i(* toas x iO1/ ^ . xu <r* - ^13 z_g Co fe^'3 r Cfi/G(*V^EPf\iAfG CAz-CC'CyTitA/ 'CJ-f /V" /v Rzte'i : (1) ffc/vc* c/ry esri^rfs pe^ Mace = . CneCK ?c 3y f2-) Co/npssmoaJ P/?oai oiay^ Conoco Inc. Calculation Sheet Date Title Dage sre/r frt&vc <z&a/\/irA** 7io^y. Job No. Field State SAL 000005324 J2I I 'll I'A'.', OiiOO Rt.PuR i RRLEAGE INVt-.N ! GEN i.. ft K E G H A E L. tl S E E. F 1 |\f fc- K t' CEEJUL jKi... L... AMOUNT E t:. L... 1.:abed ( Lb [R r;lj i!'i r PELE.mSL: .;t or aao i on k o o t a. j. : ' o i rIEo .i. e a se 1 R NON -- FT N NT EEL .EASE: i. O'o. d i n 1.4 l... O' O :: Rii.o: ~i o i .i. i_ Gau-S i: :i o Fuq . O L 1 Non-"pGi ll t R E" i .' c`. O- O i* i - < 4??> o. 33 ,, BE 1 499 ) G !'ir-L AIR EELE A':> b. 3R i EE RELEASE 105. , <499 Nl- RELEASE n ;;> i te 1 1 . o n c.i r air n'i > f f -3 3. Le ( L.ai i d r 3. 1 I ) i AT L..ANL1 RE (....EASE. :h N/A 0. i l'1F;i. tJi't 1 0 99 99 .i. 00 SAL 000Q0S3 25 1987 SARA 313 REPORT WASTE TREATMENT METHODS AND EFFICIENCY LAKE CHARLES REFINERY CRESOL GENERAL WASTESTREAM TREATMENT METHOD TREATMENT EFFICIENCY RANGE OF INFLUENT CO NCENTRATION WASTEWATER BIOLOGICAL TREATMENT (AEROBIC) 95%(a) 0 .01%-l%(b) SOLID WASTE BIOLOGICAL TREATMENT (AEROBIC) 100%(c) 1- LOO ppm(d) (a) See Table A-2 in Wastewater Appendix. (b) Based on Ponca City data provided by Steve J ones to J See "Estimating Land Treatment Air Emissions in Solid Waste Data Appendix. (d) Based on Ponca City Solid Waste Composition Data. SAL 000005326 CRe So AlP eP = 2oi.i c , vR - o.oo^n <%/<? R) W*T CfMBCES - . OS' FurTi~;\/F n-itf fiec/H.e \etH *-, 3 X, rr - gg Z-6. BPs:Z- EffG-lNeEfirtG- Cft-CocAl/o/VS <i LB wAJeP WAreR PEcErtsE - yal uS >-r. ts~ ~ Volet,--o CPKEhoL-EPR GotbMcE BAsis = BtvcifveeRi/vg- cae.cueA~uopvs /o|- as. -rPS&rpnE/vr - B toc,os-\taAc. ~ AeRoSic^ >T*h F'Eprcie-'VT TNELutrfjT CotVCEN'PftTtorS' a.01 ~l % lAflO LfrtiO (REl,BAts, - iLMcrMkr*,') O. ~~ ^n^e.x) Bfrsts - ..EyV<f(/veAiA/,<f- 3tDG-B/'&Fr' iPBjQTffiEjVT* giQ<_Qsic^- FtEBoBlCj \oomf< E^p-tCl tZtf? EMFUJEfST CDfiCSf/Tfi PT(QfV - I (OC PPfr ^forrg;'. Fft0/n EPi4 SuilWrtfcE Osc. a-\M. CR.C. lAn^JBco Ij(j)SE AnTEcrt-S-0 APirj-r- n(S) PHE/VOUC <^QMtEtsrRA7Its/V p.p S>TFE\/& JcjVEj IG-&1E tbPktNz Vaae 5v Checked B.Date Page Title Conoco tnc. Calculation Sheet Job No. Field State 000005327 " | ".HER i PDDPDDPDDhDPDPDDPDVDPDDDDDDDDBDDDDDDDUDDPDDDDDPO 2rVDP0DPPPPPLhvP>PPPDPDPDJ'PPP"PP~" 2 vuu b.H 1 S3 i UN u!-- LC.|jbA7 UNU :> F i '/F;r ROUP 4 3 o DATE I 4--Ms?.y *-08 TIME PERIOD ; MONTH,YR START a : MONTH,YR END i ~i8 / dec. 07 LOCATION i o POINT SOURCE I.D. # 1 |-.ke uhar ,i <:?= t.- 1001 11 MATERIAL STORED one no ic. caustic TANK CAPACITY (bblh) Cl 00 i -3 THRUPUT (bbls/yr> 571 4 3. 4 1 5 BREATH.MG LOSS 1 .' A., TANK DIAMETER (ft) 19 TANK HEIGHT C*Ft > D H- 20 CALH A VAPOR SPACE HEIGHT (ft) h- TKilMMMttili'itttoiiiitfMHHMtltlMHHttMHHMHHttMMHHttHMMHHHttttHm-itisiHHMHtiWHfWM Hn<?MHHHj*tfi?'? r:!* 1 4~Mav~S8 1 0: 00 AM h,Ti: ! SHEE7 7 V P D D D D 0 BfiDDUDDDDDDr-D VDVDDDV 8B DDDVDVDVDBDDDPDDD DC DP .0 P VDV D DD D D c|d l> V V D V B D B DV V PP V P1? 7 17 13 19 CALI J A 21 I ALT I D 2 c hl r i C '~"T r. ALT J l) 24 CAL 731 E 25 calt: F 2 s C ALT `J G ''* HALT j H 28 TANK DIAMETER (ft> TANK HEIGHT (ft) VAPOR SPACE HEIGHT (ft) DAILY TEMP CHANGE <F> MOLECULAR WEIGHT VAPOR PRESSURE (psia) PRESSURE (psia) PRODUCT FACTOR PAINT FACTOR SMALL TANK FACTOR BREATHING LOSS (lbs) D H j7 07 - Hv C' v r.-~ -- Pa r.Kc ~T Fp K c Lb | * *" c. ; 24 12 20 1& r-. 29 14.7 1 1 0.93 I .117 ; ... 4 - WORKINF LOSS O0000532B SA 7 34 35 MOLECULAR WEIGHT riv IB TllHMiltIMMttlIttilMMMfIMMMMilMMMMNilMMMlIMMMMIIilMMIIIIIIMMMMMMHflilMMMilttiniiliINMifMM&MMNttHtoMfIttjIHHH .1 -"i'lav-33 1 0 : 00 A3*1 : *. r , r\ ;. 17' >?. ;*s v- r: . }: >; l,;; SHEATHING LOSS , - r L? : " r .-/; [_;;; r: ji r p / \ ! MOLECULAR WEIGH"- 19 v'AF'LjK i-'h!;:- SCURF. v '* # of 'turnovers p[::: la; M-- - '720952331 TANK CAPACITY : a ? 1 38'2 00 ? alt:: i TURNOVER PACT OR 40 -RODUCr FACTOR 41 42 WORKING i. OSS !3.rm) L.w 43 44 40 TOTAL LOSS (lD/vr; < H: L.b + Iw 46 = 117 47 43 7ili'iili'lni'lHHMMM!1 n!if1 HHHMMHH!::iHMflN ftMMf'i!)?1 rfft M(1Mfl/'/<,4 WHiliiMil!1 ttN11 !}h MNMMM!1 tt!1 Nilfl!1 !1 MK!.M 14--liav--88 10:OS AN SAL 000005329 |4er<L ck(~_ ~~S S'ol-fwle. c^fc-okrA^s for Cf\ldL. Cjs\c\r(z_i CoJtlsi&y Plee&z "fk* secAt^ bzbWcl ~fU^ s4'o^ S'o/A'7^. CWSr^ff r<2.(e^SC boc^ o-f -f^e L. C, 4o c c*4o (O^, -y^v^ S^ele^s^rcj ^ r t s*i- oo G?(coL*ciios)$ /Jo//v'/yK tr . Z> - ^i^oo yf-- Zi - * fr *fl> A-j^ /V!uv -I- ' ;/.2. - - ^.7 * uf" 2/ Lo ^ IS , 4 t o,t*/3 -= oi?/ v -- toisf- - i! 1 m **Aa C f v u-s. e. G*j L^e. {ZI'OOO */^ -r J/40) /W/ - 3 R- j)p~ *J? <?.CO, (JV,ooo Vr -T ?/<sa) *- .?r/.?ir x/.cW --'ii'f] rf>~^ ?--A is V t* * H^O r V/f o,j ^ <2L^ <% ?* ^ 9 ^ <S_ k ( >/2.^U * 3,is< ^ : V/4r ) (1/ >6>y 's. * (.<) Cc>6' 'V > .. f ' - < /t; 3.4# * U/ * 3 0 y -?. c. * / o*4 ' * 3 7 |>f nt^ 7o>taI <l\ Stf, 38 // ^ ^ 3o^ - 4 3 7' tT^ Co Co Co --:x:ng a; c5^ l* C> */i *s ri* * ^ ,r Un/ na.~ Jj* X . S"7 / (V/I (L (|L<. ^ /ZrJcA A CQx HjUZzHo *> x vr& // - &) Per- /^."Pe- 4Hc(e^) ZeAsu^ Serv/.tc.^ SAL 000|g05331 n. M 3Sr S' / y\\A \ ij</ i i / -> I >v nq t-.J* CyC <j C /7 i 3o 5c ^/o r \ i>f T f *V y//*7 ! \`jz c/ A/ g, ^ . - '* )-. K ' > 6Y Z -> | '5 i Its ; Y-' y ct7 ^5^ Vo2 UVT iJ4 > ;* 1 2 3.' -3 tov ; ( 3.r 2o /? 2 2.5 -- - 51 / ^<7 <T z< o It. 1 *41*'* Jot ^ > <V; 3 72 J Zoi i> '^ 7 3.0 1 3? -- 3<" Z.C - / y-- 7 Y e7 <4ui 5 7r *24. Zo / 1T3 17* *- *3 2 > 2 00 22.11 r z.^w 25 3. V -- 2Z 3-3 -- -- /'3 1m.* 'l y o u^i. </ir~ 2.2r >UQQ 2?V 23 r o 2oT !?'* 2.4 / S~ / * <r 5- 4 -- r5 E/V Z < 3 C. M&V - </o7 2HZ n>/ 24 l 20 ^ 2 1 -u -- n V J.~ ^4f VO Uf+Z> zcr <3 0 >^Z1 2 2-7 LW 7/1 Zl-L 7 77 7 j 11 ? s.7 J. > -- - *-- 3.(. -- .57 ,, to* 3*.? A 35-/ vt. tof m n nt* // tt? i.z nu 3 2-- 32 -- -- * 1 y<*? 3 70 37/ 2'4 fto 43/ > 3^0 /? /o yf- >?/ To 7 S 2 - ftf 22 ~ -- 3.f - 47 3^2 j LJZL <^2_ 2 WO X" /7C ?/- 2.i i?C* 27 ^ - 5 . ~L - /0 L // 7 /n(A / 112, ^/o r3 C^n >< it Z/u./V'? -''I !<J^ 0<i c / o Cl -Tt A(A. *' 0 jf <-r '- >, -i V/rxJt W 7 J-, c\ fj ' J " /^ ' <->0 ' j> * ' -* , /-i ff\+un ^zt 2V? /*f 2^4 /^ 2-s'? 3 7 /S39 ? 0J 7-7^ * ,J l v\ ^ *** , '. K y-^ r* - *7 'j> lilt. S7 <-/0 $" - ?*7 (ia^x 2 P >572. Ud_s" . 23<* -/A 2 b" 2X1 K4 2P ZdO 7 . U / V i-fi z1 / - 2 y-3 ft*/> i STo*" <Uf ^ P >P; 2,0/ 77.-7 2o/ VP Z f- 2*T7 3.7 J 9 3. 7 ,i 3. V r/ pcuo >33*1 2-60 n\ no lt3 7 Zoo Z .o ! (a 7 J. ' ?.or s~o Oil 377 ZOV Jo > ns VO ?7* 4 20_ 3 TO ^ ?o >3^8 < in /?/ I 9 /?* u ^M >?C. IW n*6 VP U m 3-0 it.' ^? t / 9 *f 2 A / o7 j i 3 .or ?& ^7 S'? 3 V<ffc ' t/jTD C Vo A73_ ,,,_233 n/ Z0\ Z*> 4.0 2'0 V> <f<a 47, 573 V7/ U-7 4*1 z?sr ? i s?7 >P1? XU s~ ^f X to Zol A ^ 2 s' 7 Z!% 1 2oP nu UjTi s 1 .1.7 ZoV z 1 2 3v Z-l /92 ? 7 7.V *3 7 SAL 000005303 /0; M / a/< /$>47 /7Z <- / J> t? <* J7 4* iT"6 3^ 5'?y qW yzsf 2y<? >4 8 277 zM 2^ L. ~L O */ 3& 2 7>" H-V 2./ 7, 3>$ 4.o ^ J7 ->/r7 Zc-T zol Z20 i jfei 3/ 2*<t i.tf 2o</ 2. c 3-7 saz. V&7 S~?2_ ^~>Y >'J^ 2.3S" 2*3 72 Z 20 /? zr^ j s y<+ >v 3 S' SAL 00005 334 S&'i (f*K. 1-^ A 1 LA. AAUfl >o / 22- ____ CJL *** * /3 <1 /c? nrt ' o ) 30 ! Q it V S' 6 17 r*. M /D t o io Z <. l o 10 Z /f 1/ < )o III ni :r> /O /. // ^ !0 / o 3 W /a. 10 ( // to 3 <L ' 0 ; )to if t/ Y r //3 C 1 D //t 7 nf 5" ni <- l 0 v .. ./Vk:. : --^ //t - -... -- S' / / 0 ' T7T) 3l*T7 '13 Ty aJ '(A L / * /U U rf u % Y 33 3 2* 0 2a. rj 7 *7 7 re 3 3 3 si -2 1 2_ r-f / 7 */ V.s" SAL 00000533 > rfw#''- cn^ciucnui manage, ni btwviutb \ 03146 CONOCO, INC. LAKE CHAS. REFY-WHSE RT. 130LD SPANISH TR WESTLAKELA7 A DATE SAMPLED 12/30/86 BETZ REPRESENTATIVE GOLLA, M. D. 22G MEDIAN LEGEND X) x.x } x>fx.x XX SAMPLING POINT 105 DEG MAKE UP 70107036H CT Yl BLOW DWN 70107039H CT Y2 BLOW DWN 70107041H PH 7.9 7.2 7.3 7.9 * > 7.2 2 7.3 ! SPECIFIC CONDUCTANCE, 25 DEG C, UMHOS 435. 435. ! > 1750. 1800. f 1710. 1760. ! ALKALINITY, "P" AS CAC03, PPM 0. 0. i 0. 0. i 0. 0. ! ALKALINITY, "Mm AS CAC03, PPM 135. 133. i 37. 34. i 42. 40. ! SULFATE AND SULFITE, AS S04, PPM L 10. 10. ` 450. 478. ' 426. 466. ! CHLORIDE, AS CL, PPM 59. 58. ! 273. 277. * 265. 269. 1 HARDNESS, TOTAL, 1 CAC03, PPM 9!* *! 365. 374. 2 344. 362. ! CALCIUM HARDNESS, TOTAL,AS CAC03,PPM 63. 64. 2 250. 259. 2 236. 249. 2 MAGNESIUM HARDNESS, TOTAL, AS CAC03, PPM 28.28. ! 114. 114. 5 107. 110. 2 COPPER, TOTAL, AS CU, PPM L .05 .05 ' .rr"1 IRON t vTOTAL, AS F&f PPM SODIUM, AS NA, PPM \ j 53. 53. 2 8.1 W ' 7. 2 221. 227. 2 7.1 7.1 2 210. 220. 2 PHOSPHATE, TOTAL, AS P04, PPM .8 .7 2 19.4 12. 3 18.9 13. < PHOSPHATE, TOTAL INORGANIC, AS P04, PPM .8 .6 ! 17.21 12. 3 1126.5.41i PHOSPHATE, ORTHOAS P04, PPM .8 .6 4 16.6 11.8 ^ 16.1 11.7 2 SILICA, TOTAL, AS SI02, PPM 54. 54. 2 210. 221. 2 208. 208. 5 SOLIDS, TOTAL SUSPENDEE 1 MG/L L 10. 13. 4 15. 15. 4 T Y3 LOW DWN 70 107038H 7.4 7.4 \ 1670. 1820. ! 0. 0. 1 47. 45. 2 415. 487. 2 257. 285. 2 339. 382. 2 234. 265. ! 104. 115. ! 5 7.6 i.** 7.3 { 205. 230. 2 18.1 16.3 2 15.6 15.5 2 15.5 13.6 2 198. 223. 2 L 10. 13. < - AO i NG 324 A 81 05 SAL 000005 336 dd* jCh^ClMChOI MANAGEN . |T SERVICES 03146 CONOCO, INC. LAKE CHAS. REFY-WHSE OLD SPANISH TR WESTLAKELA7 DATE SAMPLED 2/26/87 BETZ REPRESENTATIVE GOLLA, M. D. 22G T*T MULTI MEDIAN LEGEND X xx.x * XX.X XX SAMPLING POINT 105 DEG MAKE UP 707061 77* CT Yl BLOW DWt 70306173* CT Y2 BLOW DWt 7030617 4* CT Y3 BLOW DWt 707061 76* PH 8. 7.3 7.: 7.: 7.q 5 73 5 7.4 5 7.4 6 SPECIFIC CONDUCTANCE, 2 5 DEG C. UMHOS 438. 435. 5 1460. 1750. 5 1420. 1 71 0 . 5 1450. 1 670 . 6 ALKALINITY, "P" AS CAC03. PPM ALKALINITY, "M" AS CAC03. PPM a0. . s ' 140. 135. < ,,0- 5 -,?1- 5 0. 0. 6 50. 50. 5 0. 05 40. 45 . 5 SULFATE AND SULFITE, AS S04. PPM L 10. 10. 5 369. 460 5 368 . 476 6 378. 41 5 . 5 CHLORIDE, AS CL, PPM HARDNESS, TOTAL, AS PACO? . PPM 46- 5 q!I' 5 200. %{J 377 67 0 7*249. 0. l' 6 219. 'V0'^763 6 284. 744 6 211. 757 5 772081. s CtoALtCaIlUrMas HARDNESS, i'P;-." 6' 197. 776 5 . . 771494. V. ... v . MAGNESIUM HARDNESS, TOTAL. AS CAC07. PPM COPPER, TOTAL, AS CEJ. PPM AIRSOPNP, f TOPPTMAL, ^C|,v; r /. J.: 5 ,05 L .05 5 17 .8 S 89. llfl' 6 .05 13 5 AO4 . 6 1 10787. 6 1 0486. 6 .06 14 --5--__ .06 ,i_--_--_-_--_-_--_-_------ 6 4s .6 C i1l 6 4.c7 _____________ SODIUM, AS NA, PPM - - 60. * 53. 6 701790. ^ 6 189. 706 . 6.________70168_6_. 6 PASHOPSP0H4rATPEP,M TOTAL, 5 "TO A 6 1 Q 2Q0. 6 ' 21. 10 1 6 - PTMHOORSPGHANATTCE,, TASOTAPLQ4f PpN 5 ------ >17 20-. -7 C 16 2A0. 5 16 216 . .v. > * APSHOPSP0H4fATPEP, M ORTHO- ' r .'V - 7 > 6 1 16 76.7 6 16171.' 6 16is.6; - SILICA. TOTAL, AS STOP, PPM *. 54. S4 s 71i n68. tA 6 165. 704 6 i 1on69 5 ' ________ SOLIDS, TOTAL SUSPENDI D mo/r. L i 10. a 6 1712 s 1 10 i a 5_______________ ENG 324A8105 QOOOO! ;33 r Mi tK/tIMtHUT MANAGE' NT SERVICES .46 NOCO, INC. *KE CHAS. REFY-WHSE OLD SPANISH TR rfESTLAKELA7 DATE SAMPLED 4/20/87 BETZ REPRESENTATIVE GOLLA, M. D. 22G 4T HCtUbTi MEDIAN LEGEND X xx.x X XX.X XX SAMPLING point ?H SPECIFIC CONDUCTANCE, 25 DEG C, UMHOS ALKALINITY, "P" AS CAC03, PPM ALKALINITY, "M" AS CAC03, PPM 3ULFATE AND SULFITE, AS S04, PPM :hloride, as cl, ppm '\RDNESS, TOTAL, CAC03, PPM :alcium hardness, POTAL,AS CAC03,PPM 105 DEG MAKE UP 70430204H CT Y1 BLOW DWN 70430205H 8.3 8. 5 448. 438. S 0. 0. 5 133. 135. 5 10? * 5 7.6 7.3 5 1740. 1740. 5 0. 0. 5 83. 51. 5 425. 425. 5 ' 56?'5 243. 243.-5 :^.v 367,e 9 5. v5. 36.5. ;5 CT Y2 BLOW DWN 704 30206H 7.82 7.5 5 1700. 1700. 5 0. 0. 5 87. S0. 5 409. 409. 5 236. 236. 5 363. v , 344. s Cl' Y3 B ,0W DWN 70 130207H 7.7 7.4 5 1750. 1670. 5 0. 0. 5 84. - 47. 5 429. 415. .5 242. 242.-5 . J373. ;339. 5 1AGNESIUM HARDNESS, POTAL, AS CAC03, PPM :OPPER, TOTAL, iS CU, PPM [RON, TOTAL, S FE, PPM SODIUM, AS NA, PPM >HOSPHATE, TOTAL, AS P04, PPM 'HOSPHATE, TOTAL [NORGANIC, AS P04, PPM -V"- 'HOSPHATE, ORTHOP04, PPM > ILICA, TOTAL, AS SI02, PPM JOLIDS, TOTAL SUSPENDED 1G/L *28?'-5 113. - ii3. s :* . 05^*5 L . .13'5 1.2 ... ' 1.8 5 6.* 6. S ^ 224. 221. 5 31. $ ... ` 19.4 5 .77^ ~ 31. 17.2 5 .7 .7 5 25. 16.6 5 49. 54. 5 189. 189. 5 11. 10. 5 111. 107. 5 115. 104. 5 .. .05 L ... ... .05 .14 5 .15 6.1 " 6.1 5 6* ; 6. 5 221. 210. 5 227. - 205. .5 29. 18.9 5 30. 18.1 5 ..,29. 16.4 5 30. Vl5;6 5 24. 16.1 5 25. 15.5 5 186. 186. 5 192. 192. 5 13. L 12. 5 10. 10. 5 EL ! i i ENG 324A 8105 SAL 00000533a INC. -HAS. REFY-WHSE OLD SPANISH TR .'LAKELA7 DATE SAMPLED 7/01/87 BETZ REPRESENTATIVE GOLLA, M. D. 22 G eutftCNT Tt*T MEDIAN LEGEND G4 xx.x XX.X NUUC O' XX *CV(OU$ CMLTS SAMPLING POINT | IQ5 DEG MAKE UP 70707092H CT Yl BLOW DWN 70707094H CT Y2 BLOW DWN 70707095H PH 7.8 8. 5 7?665 7?33 7l485 SPECIFIC CONDUCTANCE, 25 DEG C, UMHOS ALKALINITY, "P" AS CACQ3, PPM &7.-' o?- il38?*s 0?`5 litasoS*s liS?-5 0?*5 ALKALINITY, "M" AS CACO3, PPM SULFATE AND SULFITE, AS S04, PPM L i 527-5 3157-5 s3?- 3^-5 4^-5 3^2?'5 CHLORIDE, AS CL, PPM Sit- 2i4!-5 2141-5 2389-5 HARDNESS, TOTAL, S CAC03, PPM -ALCIUM HARDNESS, TOTAL,AS CAC03,PPM MAGNESIUM HARDNESS, TOTAL, AS CAC03, P^M COPPER TOTAL, AS CU, PPM IRON, TOTAL, AS FE, PPM SODIUM, AS NA, "PPM L PHOSPHATE, TOTAL, AS P04, PPM PHOSPHATE, TOTAL INORGANIC, AS P04, PPM PHOSPHATE, ORTHOAS P04, PPM SILICA. TOTAL, AS S102, PPM SOLIDS, TOTAL SUSPENDEI 1 MG/L 98. 95. 66* * 2? ` 5 .05 L .05 f 1^5 5^*5 .?6J ,}65 .76" sff-s L 3247-5 lifts 9?'5 .05 L .05 5 l:5 s 190^ * 5 l4435 1^235 Aft' 1100. . 3a<??-5 3iiS-5 211S-5 989-5 .05 L .06 5 4?635 ill?*5 2111-5 92?`5 .05 .06 5 iiSS-5 li?935 i9a35 lih5: iJ!}-. 1210. . f 239*5 239*5 l4!225 lit?-- 1 10. , io. ; | . G 324A 8701 SAL 000005339 EIMEKIj Y manage ;nt services 3. REFY-WHSE uD SPANISH TR XELA7 DATE SAMPLED----- 8/213/87 BETZ REPRESENTATIVE GOLLA, M. D. 22G MEDIAN LEGEND TT xxx.x XXX .X XX Mtvioui niiucTi Make"uP ------ gl'OWDWFT BLOW DWN 70826033H 70826034H 70826035H 7l LOW DWN 826036H PH 8.2 7,8 7.8 o 5 ---------------- 7TTT 7.8 5 7.7 5 SPECIFTC CONDUCTANCE. 25 DEG C, UMHOS ALKALINITY. "P" aS Uaco3, pEM alkalinity, "Mm ASCAC037PPM SULFATE AND SULFITE. AS STJT7 PPM 444. 5 ' .. v............. 0J` 0. 5 130.' 133. $ L>P";:- 102$ JL0. b 1630. 1490. 5 0" 5 59. 5 383: 5 1 <?Q0_ 1450. 5 0. 0. 5 5R. 58. 5 .-a .443. 371. 5 1640. 1540. 5 0. 0. 5 s* . 55. 5 463. 392. 5 i CHLORIDE. AS CL, PPM b9T b : :243, * 7 * ??5- 219.5 220: b HARDNESS, TOTAL, |AS CACUJ",--PPM -------------- ya. s :-^V--380ie fr&j] >395. JU 7 b 316. b LCIUM HARDNESS, - OTAL f AS uAlu3 , t'PM 0^ 3 2ib b T 223. b MAGNESIUM HARDNESS, TOTAL , JtS CSCOT, PPM------- --*=----- `79. 5 *WttSWI 3. 0 --^--fin 2. b COPPER, TOTAL, AS Cu f P PH IRON, TOTAL, AS "E, PPM SODIUM, AS NA, PPM ZINC, TOTAL, ad 2W, frn PHOSPHATE, TOTAL, ffS P04 , PPM-------------------------- wo o L wo b ' ; : .05 ' .05 5 .0b b 5*1^ 1.8 5 '" f!P/- V'^S^ jZm*'-;" -v: 4.5 5 4 / b WVSii. bb 5 T90"' "5l *aWS^`25 - 2Uv* 189? V -.25^ ^Vir'--' < * lob 5 AC28' -. . .. . 'AtTvBr ./ lb . 3 0 ' 15/ lb 3 0 15.6 20. b . vf PHOSPHATE, TOTAL ifcUkGANTU, AS "P04-; PPM PHOSPHATE, ORTHOt'u*, PPM ' .1 b ->: ' <14 /2 16. J/b ------------ 16.3 ? '^/-/'Tl.8 - 14.2 b 13.b b . ; X5 .r 1 20: b ----- 17725 SILICA, TOTAL, \S Slu2, t't'n 50LIDS, TOTAL SUSPENDED 1G/L----- --------------- ------------------------ 04. ' * . **'>*'' 'i98\ 0 lab b <\v -fc~ - :i0. T0. b ,-V' / , . [4ib'*7?>.-. . 1 . 194. mi b 11. ii. b 198i 106. b ni lrlK:s - v - v'-' ifJG 324A 8105 SAL 003005340 deti OiMhmSirSsiS ^ Hrywii Oman el BU ueaaeunee e f 1ADATE SAMPLED 10/16/87_______________________________________1KiL. :ONOCO INC. .ARE CHAS. REFY-WHSE OLD SPANISH TR JESTLAKELA7 BETZ REPRESENTATIVE GOLLA, M. D./TERM, 22G TCT RCBULTB MEDIAN LI EGEND xxx,, X XXX. X XX .ftCVIOUl MESUIT* 105 DEG MAKE UP 71021072H SAMPLING POINT CT Y1 BLOW OWN 71021077H CT Y2 BLOW DWN 71021075H CT 'i 3 BLCf4 DWN 7102 .L074H 1 7.5 8. 5 ------ 6.1 7T3 -- 7. -7.2 'BUfii; CONDUCTANCE, i DEG C, UMHOS 434 . 444. 5 I4y w. 1490. T"tMi 1T4T8R00. T- L5T5TT 1.370. .rAl. 1N AT X , ' F" 5 CAC03, PPM ' 0. 0. f w 0. id. 0. ` 0. 0. .SALINITY', "M"------------------ ----------------- 13 4T~ ------------------^54. __ --=--7-^ l CAC03, PPM 133. 2 54 58. .40^ 41. ! ILF ATE AND SULfliL, 5 S04, PPM L 10. 10. 5 425. 425. 393. 393. . 435. 129. iLORIDl^ ri5 | PPM -- 6^^ " 63V f 234. 7 234. 226. 71--------- L * J 226. ?-' __ p3.4. ' CAC03, PPM 104 98. Ji 365. >'< 355. I366**5 n'AL, AS CAC03, PPM 69. 253. 250. TM ,fe57. ` 'TAL, AS CAC03, PPM 29. 103. 100. 103. CU, PPM FE, PPM niMM TlC M* T>pfA flSPHUTR . TOTir. P04, PPM OR PH ATP . TOTir. ORGANIC, AS P04, QSPHATF. ORTHOP04, PPM PPM LICA, TOTAL# 5Iu2, LIDS, TOTAL SUSPENDEr 7L ---------------------- .05 1.3 CA 55." o .7 fl .7 7 .7 !T57a .05 ^ 4.5 ,, nnA 204. l * IT * 16.3 IT R 16.3 17 1 14.2 182. W itiZ. 5 18. 10. 5 '. rts9: 7 fll 201. 1T X 16.3 IT A 16.3 V? . 7 13 * 5 I 178. 181. 19. 12. 1 .05 ___ 1_C____ T 5. 2 3fl7_ 207. 1A Q 20. 1i Q 20. 17 . fl 772! 185. 185. 5 14. 10. i \ \ ? <A 8701 , SAL 000005341 OL OCnVlLC^ 146 s-ONOCO, INC. LAKE CHAS. REFY-WHSE OLD SPANISH TRAIL WESTLAKE LA 70669 DATE SAMPLED 10/03/86 BETZ REPRESENTATIVE GOLLA, M. D. 22G MEDIAN Legend xxxjx xxxfx XX 'ECIFIC CONDUCTANCE, DEG C, UMHOS .KALINITY, "P" CAC03, PPM KALINITY, "M" CAC03, PPM LFATE AND SULFITE, S04, PPM LORIDE, AS CL, PPM RDNESS, TOTAL, CAC03, PPM IUM HARDNESS, iAL,AS CAC03,PPM 3NESIUM HARDNESS, TAL, AS CAC03, PPM ?PER, TOTAL, CU, PPM >N, TOTAL, FE, PPM >IUM, AS NA, PPM `SPHATE, TOTAL, P04, PPM SPHATE, TOTAL RGANIC, AS P04, PPM SPHATE, ORTHOP04, PPM TCA7 Total, SI02, PPM ids, TOTAL SUSPENDED L CT Y1 BLOW DWN 61106112H 7.3 7.2 5 1800. 1800. 5 0. 0. 5 34 . 31. 5 528. 478. 5 277. 313. 5 398 . 374. 5 275. 259. 5 122. 114. 5 .13 .13 5 7.9 7. 5 242. 230. 5 7.5 12. 5 6.9 12. 5 57T" 11.8 5 '212. 221. 5 "11.' 17. 4 CT Y2 BLOW DWN 61106114H SAMPLING POINT CT Y3 BLOW DWN 61106111H 7.5 6.8 5 7.4 7.3 5 1760. 1770. 5 0. 0. 5 1820. 1840. 5 0. 0. 5 40. 30. 5 35. 35. 5 494 . 466. 5 532. 487. 5 269. 285. 5 285. 288. 5 362. 363. 5 370. 412. 5 249. 249. 5 112. 112. 5 254 . 282. 5 115. 128. 5 .24 .14 5 .1 .1 5 74 . 7.2 5 .220 226. 5 7.4 7.3 5 230. 242. 5 7.2 13. 5 7.4 16.3 5 6.7 12.5 5 6.9 15.5 5 5.6 11.7 5 5.8 13.6 5 ' 204. 207. 5 214 . 227. 5 "nrr" 20. 4 10T20. 4 ff . v KR . ?4A 8105 SAL 00000534 T t int kniunw MANAijfcf N! stHvlLtti 33146 CONOCO, INC. LAKE CHAS. REFY-WHSE OLD SPANISH TRAIL WESTLAKE LA 70669 DATE SAMPLED 10/03/86 BETZ REPRESENTATIVE GOLLA, M. D. 22G Q\jnmm**r MEDIAN legend KX x|<x.x xkx.x XX Pm |vte<j i 105 DEG MAKE UP 61112056H PH 7 J'5 SPECIFIC CONDUCTANCE, 25 DEG C, UMHOS U7RM7FNITV, nP" \S CAC03, PPM VLKALINITY. "M" vS CAC03, PPM '<Tn7FATE--AT7D--SULTTT E\ .S S04, PPM :HL0RIDE7 AS"CL7 ppm L ARDNESS, TOTAL/ S CAC03' PPM -.nriM Hjpnup<;<: AL,AS CAC03,P>M AGNEST HM HARnNESS OTAL f AS CAC03, PPM DPPER. TOTAL. S CU, PPM *ON. TOTAL. 3 FE, PPM >nTTlMr AS N A ; PPM 10SPHATE, TOTAL. ; P04, PPM [OSPHATE. TOTAL ORGANIC, AS P04, PPM OSPHATE. ORTHOP04, PPM LTCA, TOTAL. SI02, PPM 4T8T442. 5 0. 0. 5 132. 132. 5 10. 10. 5 30 . 56. 5 gif`5 64. 5 28 . 5 .as .05 5 7. 1.6 5 si 53. 5 .7 .6 5 .6 .6 5 .6 .6 5 56 . 53. 5 SAMPLING POINT 1 j | 324A BIOS I 1 AL 000005343 ! MU ir r-. \ .!. r MU '...MUt. '....i > AEi ,,t;'. ' 'V' "i 'URr-: 'j 3 2UE .I.IF*'*"' A MfJ UN'] h\ l"_ I... E:. i-i.... t. !..i ; i u / v . 1 N :! :-ij.iNT RELEASEE ;aqe i anl--^ : ; .1 o j, v 1 n ") Wuii-'j i- J v. ( ' .'I aU. r nt E& I G-^'-e * i. ii-tuU "r-'L' x I'i f !- Li. .RMSES 1 ..4!... CJtV.Q fl O.Jii; if, : ,u:i i t i / Equipinent Loss Hequl <=r Cok re Freiiii 'j.iY! uoker iNcj . U LuE: er t-aSvK'J V''el'' Y -Idl'lt H- i';t liiei' -tiL i..ri?cE.or I -ririr:. r oriTiL3 t-?t'idj. nq . 4 - r rj. 0 Of' ::'i 3 '.3 6. 1 44. i.240. IhF i.Coq l i ".r] i owei" Wo. ei-iat&r h:oi es?e to Air (i -qj; o ! o i <a s e t a Aji_r T i.>t.ai i\ion-poi nt R&lea&e VOTAL AIR RELEASE i. &4 v 2043 i, 2000) WATER RELEASE 4'-"') I AND RELEASE Nn-Si tS' iLdridtarin > U r f -3i :e (Land-? i i. 1 j i '..1 l ri!. ....r-,i\D EL Lu. A Sir: 0 N/_A 1 o tj 17 I :'+ I ij`J sal 00 30534<. .-.L' .-t:! Hi. Wi-i b Wl-'i I S: F:, ;Ui l L; 'wl.i ! E. ;.] } Kbr-jiT'!' u A Hi- r.i ibfh'i. .1-F-'r:.r INtrOr : eni: Jr. rVPENf- r 'c . ! rll. A ' II:' 1'HOO TREA'i MEN i EPF 1CIEMCV i i-i iji'- i NFLUENT U. L'T <E. L_! - I r vb: "> j CM -Ei r;DVERV JNI7 Vd7. * . O l " i '/. a ; I; I OLun 1 Lel .. i Pb. H i piln r ' t-ic Hi it! 1 ' vn"; ;b > p p I.' - 1 ppmic) HI GLOGj J..Ai. TREATNENI" \ fib F-.'i j tI C '> i . ; c.i) ppmie) based on dt provided by Brand L Sutler bee Fable A--J' in Wastewater Ap p en cl ] ;; . ChsiriLcal was not detected, so one-half the c acecLion iiiTnt < D . L . i. O ppb ; was assumed i based on 197:' Ebb bake Char 1 es wastewater anal ys.l s , recnni ea I Mefrior a; i d urn Mo. 603--79--350--2, and EFA Guidance Document i d > Assumption based on data for similar organic c impounds (see "Estimating Land Treatrrient Air Emissions'' ] i i o J. i d Waste Data Append i) . | bee Waste Composition Data in bo[id Waste Dit? i i ": J SAL 030005345 SryflEft/s Cor*po$iTio(v$ &LEMOEL /Mse G-A-Solihe: FEc QA$oliV SLOP (yfr^OU^E CoKE* GMctUNL - i/i_> Rb.Oj Sul. WT% 1*0 1.0 1.0 1.0 1.0 SEE APPEtffltX E Ffctf Co^PosmaN 6AT4 Made 3y Checked By Date page 0* Conoco Inc. Calculation Sheet Title Job No. Field State SAL p00005346 STYAELfVE CAuZuuATlctf$ StoRAg-e. 17Wtc$ PloATIMG- j^OoF = [J2J Tpy 4 \r? tPV + Z?.* -- II l5/y* . . ,^ v y-z-<x?o) v Lo>M)\C(g- LosS - ClOt(e2 TPY + /^,5'S'T'Py^T^ XfX )'- ? "/y* ^liP/mg/vt - (see APpstfoix r) SePaawhk, (|1Z T?y)( -^f) C X ^ ~~ ^ ^ 2.600 Coo Li//G ToMeR -- TPV')( TSS")^2000) - _^ <V* yA vMsre &r=uo/vt * 731 * [0* Tfc 4a?/~^ r?, , , 4* 0.(0 tie MtA Q.L fmr on*ess )07 os v. x3 , 3 `Vy* **/ /y* WASfE ABLBAiSe top?-. Release 73 LMORtor-(1112. Tf\X ('z) ~ 27 RELEASE r2> 4*/? *(*27 ^/w)(.^7iV - J2 CVv* /y/? ^EEE/fsE- uMO = Q_ C-D^^o^lJ Co^lt-klf) fbvE ' see APPENOices For calculation bacx&Ro y/vo nVFcPfn^T/o/V Made By CrecKed By Cat? =,ig? of Conoco Inc. Calculation Sheet Title Job No Field State sAl OOo 005 34 ? L_Rl i.., !"i A EL F-.r' i.J f v "i b- 1 j'f HR': EL r I ;4tii ' 3Ut i C mU_I.Q AMU`JN1 '.b Li.... i; Ac i d , .+ ! N ! i iLLb. I'.iEb i ai it Dt-'jro j=t>.'r E;-= t~<a .:5<e 4.>0,. 42 -i i. F. i 51 NT EE:!LLRjES i. Qadinq L.obt- H 1 !:: >' i r? I". I. -'f! , b . ,, i-: L H t , Loci i. i nci I owpc Nau.'L. I o L .< 1 Moi; -poi r: t Rd :,4V';R i >.. i Rl. A I h", Eb L..E:.Ast>Erj A-.-:1.' . < "i Wft fi:- R R't-IL.EA'bE L.I ';ldL> L'EL.L" RfbE N.1 A SAL 000005348 NAD TE W8V 8AEA 3 i 3 Kt'POR ! I'REh 7'MEN T 88 i"H0D8 AND EFF CCiENC L..fVh E L'HAFLh:.,:.- h- j Nfc-~'r\ V iL ! KImi-iM 3ULr!-.4EI.Q acid IkEATMEN I METMOD 1 KL A 1 MEN i ErF l CIENCv '-'t-T-Juil Ur ;.N!"i.JJEM f L - iJi'Jt. T:.N ! E A i i !' i I-.-- :.j 1 f\ L- i i L \Jr t l 008 >; -a .) l ., 5 i* Eirtised uft oats prc:/ided u / Brandt liut.ler, SAL 000005349 -UL PuP c fiaC '-fiXE Lr-C.c AiK vP - 1.72 X o'fc '*j7 SA & ZCaC \ friNT RBLBASE * LoA&'.t*& - S^aA-G-e i-vAOitfo-- it^co esc y Product = ^700 ^ ' CP /lS" 5<y .-> c/ 2.,~7 ife/js E>ust. Q,C"L lC ^ q ( -%<$> ~!oa 'jTa/V > ^ 5^ Xpr-^i . ^\ - //?//- PoitJ^ (\^rts. ; Rj6*/T/i/5 - Soc/^r. &ksro&3 Qa/vr f^rr HE4|// ^A/eP&WlCS (EJ ^ Swii" 4-o<) PLfitfr^bufoivr :VS&, Cfrtcvc#?iGrf*/ jo&GEftWP Fr R><? &PaPTtNCr <./Vi (VTj ft E P tH'V'f"- j Wa S-oaii i/vt*r- wa-tpb Pei/^se -o gAfS - pf'- WafVfro{\[fi/G- - 6-^ ~J^,s~r~^ FrfT- (/ Zf/ PuM-r ,#0 *< efP'c ftrs/' / AT!or/5 > /y3 pAd G lAND - //// 70TE5 ; 60 P&ftfiY'S CH^!c4L 7/ </VE # > tt*M Mace =/ Checked Bv Date Page of Conoco me Calculation Sheet Title Joo No Field State S*L 00)005350 '!i/*nnr>nn;in"njn nr,pnn$jjp0r r. tr;..a ;. ;. " r " /- ~ : P npr,r. ppy'm' clI-I Gr-v c i--*_ ;ul.at r onf -'f.P: . CAI J MCI -.09? C: : 1 rill' r r'r. . ,.j. : NON .'h , . I" : , ' FL .j: r i :jn Ml I NT LCURCE I.!;. 4 LA 1 --.in . HANDLED .-ifrL'f- !.J 1" (c p ` p . -K-'i r.i-r' i.C 1ENCY L 5 TAP hFMD ZULF . .Ar F '7HA"L F i GAD.LC gulf., ft;i LOADING ,,OSS LALrl A J-ULECLjL.HR WEI&hi" Mv - 98 CAL:: 3 TEMPERATURE ^: T- 70 r r i-P-J P !! r' :-r r: rf rl i'! !!>>:* P :1 ri r! I%: H :1 il n n H !! !1 il H il r? yl `1 !'1i* !1 !1 i'1 H !1 !} ;1 M tf ii n ilil i1 H !1 i'l r! \! P r; r! P P PM P PPM P P P P PP r ..7?v--fld ` Zv .-A!"! Lsp G ^L = 1.7FLCDD3 AL G .7 GL'DL PDrDDPDrpPPP'BPPPnnOODUDUODVDFPP'iZrDDDDPPDDDDkWT.'UDPUPDPP:1 ' DPPLP .AD i NG LOSS zi halt: a do & CAL.Tj c j ;i4 MOLECULhR WEIGHT I I-Mi-'ERATURE1 (F) VAPOR PRESSURE ipsi a > S A7'URAT I ON FAC70R Mv T c- !,'C 3. . 45 UNCONTROLLED EM[38IONS 1b .1 - CONTROLLED EM I S3 i ONS <b > . 1 -= L J. ^ i ? f / 1 .''0 > 74 - La , , v ALT7 Z TO PRINT AND/OF SAVE /v 7 rlr:PPP PP :/p PP P P y: y>PpPpp ?//////:1 r r1 Pi'1 r!Py; rir*H | ;!| 'it ,} yi ^i.ry.: /r .y - Cap T` ? r) ' ` n 7 7' ** r\ 'T "; *. V, r,% i ; n n r: rz n n p p p J} p p D p ^ n r n ?p r, r; ^ n p n n n ,"[,1'! n r>v;,';non/}/;.; '/LJl I-'MISSLjN CAL liJL.AT I DNS FIXED ROC SAL 00000)351 : NGN LOCATION ron-;: gourde i.c.. # MATERIAL 57ORL0 TANK ChF'AC I T Y < c; b : 3 ; THRUPUT 'bbls/M- j END v "'H L NG iz. n r r IT =r"T;R:-'-'"E r; / , . '! THNr C i AML TER v -0 r A' !: . fit: .1. GH ! ; : t !i / riHHi.JrL HE i OF T !. i- h iv; P r*:1 r! r` r:r::!:!rf:;,,T:'?/) pri I'h^y: r: yp`i!: i'l /`w hi Jr} i). 7 am == = " :.r i-f ;-t i' t .< m . P PI:-! i`1r'r' .? A1 i? L V V 0L D D D 0 0 V R;' V V D D P ,f'DP D DVD /'A,.n'' } r. r nnr .T.H KO 0 H EA THI N Qj LOSE < / l c-:,.. "r o J. Ai.. V. 1A;. ' J 4.1 - L Ai... r 1 4 e: a:., r 2 .i '.j L Al... \ J : L rL i J ' 7 r al. , j !-i TANK DIAMETER v>F.; T AN1' AEEGI-r ( f V. ; OAF DR BF ACE HE I GH'1 ( T t ) On. JL.V i'RrT CHANGE i F / MCI..ECULAR WEIGHT VAPOR FfTEBBi.JRBL ( p a i ; ATvEBSUREL (psivi; PRODUCT FACTOR -AIN'T Fact OF BMAL:_ TANK FACTOR AREA TNI MG LOSS (lbs) L* H dT ;Tv C`V Ps / " G Lb -- 24 12 20 99 O 000178 1 4.. 7 1 i WORKING LOGS !!;!>: r: pp h i p pyp-1 >] y! /? r/ri p HrlPr; rlrl v-- OS 00: 4/ AM PPPH N tf HP HylilH tfy: H yl HNn p H !1 H y] HP <1H r'r< H H H :1 ;; !! :1 H Hi! H: ////'//: y: r: Cap h49 : SHEL" n r r- rsr;- ';ODP.DDCDDDDDDDDDDDDDDDDBD DD P D D V D D D PVDDD'O D 0C D V DD V V U D D D D l1D D I-P D P D P P PD D L7PDDDP 01 WORKING LOGS HI ,'G O." r=i 9 i AL T ; i 441 :K,l n 4 -5 MOLECULAR WRIGHT vAf-'UR HRE'B riURE # IK I URNCO'ERS r'feR '/EAR VANK CAPACITY > c * I > NJENGVEE ractcr :: - OLLCT ^ACTOR WORT The cUSH i !: ; OGTOL. i.O:L-: ; |-iV r'\ N" ;- Kn ~ b , H0 / 04 :/ !...r " Lb +- Lvi SAL 000005352 '-.JL'r'.L-b .'Vi.'. mKi-- 7!' j. i-'fc.r 'UfOi bSrl l NvEH FORy i.-nKL l. Vih-iF-'.L.. RLF 11 JcE^"v !`U LULNE rMCjUN i Kb L L?--(1-7iJ' . 1 b/ -t) bi. or -v. C; (' i <.: i S v 1 c. at. l n..i Koo-i" f- t;d i-'oo-f 1 otai omt feleaw ityJ* / l 2 S3 1 372 . t. i. 900) A i R Li. 'hr 2 I Vi' F A; L) _!:: A A L. 3 O d 2 na Loss i-iu] i 1: i. ve Hquipmert Loss 1 io. n r.yi.i No. 4 HDS No. LEU ;. HDS ** tr c. u L ar Coker f: remi urn i.';cjker No , L. Eoker 0 Ker QVHr F1 i ant i'io - :.> H,V3 i j'-j . 2 C.' r ijoe Un 11 EC.: Lt Lid5Q bp 1 t. r ! -j 12 . L HDS ! -Jo. .I:.' I.KU L HDS ; h-* r i >}a .i I., r a o k er ' 'i'C fan k F a r m / B l e n d i n a Hr ocs 5S Drains Separators API DAF IAF Cooling Tower Wastewater Release to Air v-i at e F.e.L eiiStt tr) A.i r I'ot :J J non-point Eelea6F i 1 34. * 240, 2oOO. C) J . 1 33. 42b. 1240. 1 2. 3 60. CD . fZr / 1 4. t 96. 5080. 1 26. 674. 1. 0 420 . 234. 7` "T 9. 4. 480 . 64 . i f"J i 26 1 2o- . 260uO> I'U !'AL A IR RELEASE 28020. W hi ! !:, K KLL EASE 37 . i : 499; L.ANL r !:. L.r A n t. e and tar no C'f-f -'i i. te (Land fill. ) T 'J i A i _ Lr'ii'JI.) h: L L E. A S FF 1 >. N/ A > ir : I ! -li I H7u L i JM ri 7 4 1 1 9 1 i 0 S^L 00COO5353 Wirvi'ih. ! i'HFN I" Hr" ' i t'jUb AND F.i-F I L J. LNoD i. FiKE CHPiRL EF> Kr F I lE Rr TOLUENE F.tDi.. i ATHE.N'l hfthll TREA!HEN1 EFF lC 1EMCY 1 ' f-,\ 4 i.t> i NR L UCii'lV OUNCEN KAi iAN LOUS VriPCR RECOVERY UNI ! 9 3 7. ( a) 01 i / ' cA W A TR.K a J L LUO.' 1 L.,HL i Rtwr me or ' hEF1 OF I L ' OV. (b PPb- 1 ppm(c) H-,Cl E CIULUbJ CAL TREA t'NEN i' 'AEROBIC) ( d ) ] 00 ppm(e) S.-5S ed on '.i s'Lj prov i dec! by Brand t Bt.it 1 c-r . See Table A~2 i. n Wastewater1 Fippend i . Cherni cal was not detected, so one--halt the id e'l' at: t i on limit (D.L.- 10 ppb > was dS^umed (based on j. v77 r cm) Lake Char 1 es wastewater anal ysi a , Techn .i csi r-ifittior and uifi No. 603-79-350-2, and ERA bin. dance Docnmerit See "Estimating Land Treatment Air Emissions'' in iu L 1 d Waste Data Appends . bee Waste Composition Data Eul l c:l Nas t.e Dae a rip per.d j. SAl. JOOOO5354 "7o4_C>fVr it~ioa/.s &A0E0 Fee (SV^SOCIA/E: f?EFo(< Al^TE -fi^UL SUL LS# G-feouNE. ALKitATS J CAuQe naphtha yP'H Cok^ (2t4S0Li/V wrVe -7.^ HM is:o 3.0 ^ /.o W.5~ /.S' S /We/VAi* Fbtf cs^Posirtf'V' D4-T/4 ^ao 3y C ~ec.-?d Sv U fl. _ o< Conoco Inc. Calculation Sheet Title jod No Field State SAL 0(i 0005355 T&lue-NE cAi-cxJLA-rioiVs STofiAG-E TPttflcS r ^ FloATxHs PaoP r [C32. I TP fX 7^) +C1'"? TP'fX'Tat; (2S-.2 t-PyXt^^ OlsS * zooo - (pO~7 L%K F'xeC fe= f=- -- fe&,22 reyX'^Y'TTijX200 2-G,T '%i U>*C\N<S loss - j(lo.k^ i^.rs-TFyY^Y-f^-) T (^.-73 TpVyX/r.rUYXzz} .73 TP/A^A *r Z^o ~ f f 3 <-( e^oiPaiewt PoG-/r?i/s - see rtPPE/YOix' X Process DP4//VS - (ZSQ,.*! r*Yjf 'T^'X'ttW =| _ sEP/iArfTd^ ^3at.iiz. cpouvg -ro^sA- C'Z^.'n TFy) (t^^C7-000) ' ^ 73 `Vy* VgZ> */? W^rE^Te/? i BS=FLUSNT - ~7.3l* to"1 US4<i * - ?4<i> 6%/< -37 c%* -ra (4tR, v/f5T Release = -?6.6> `'Vy* 0, 10 . 0,23 = ^ Jr >-G3/ /y< 'fo-ra^ Release to ^h-d ^/^ra tp^ ypni tpYJ^)j(- Z<3C AELBAiE ^^j4s - 3 os'.-4 %? -ra f--fi. ^ (W.4 `t/tA)(i>^`M')- T& C./VYO - O tfe<SA40) j|s~/ ^4r? JVorE: s eet Appe/voicrs ^ c^cu^rioy ^/f^r<?^4uUJ rwFatf Maae 6v Checked By 3ae Page o* Conoco Inc. Calcuiation Sheet Title Join No. Field State SAL 600005356 l J i.J! \ t j i... i r-iT.i f iHL ' j r.i.. i_jji L N'--;HN i LK Y th-sL- j ' JL i"; - 1,1,1 - i [Ci-ii-ORQi Fi-tAr-lt r-i i-1 r.i L` N7 F'l L L. c. n> L H L> . ,i. o / /r : i Li''. !-' O i Li i l"1. IrJ... H H -jaCiNr m L !. R Nl ,>i j !'( .J j t i 1 I \i. Lr-icsti -:> I cJ i:H d X f I l!ij i.. S -- r'..(!'! i r. .l , o i pcaon <; Ooa. !' PI1 H'; i.t t.L i Li.'i 1" - vl.i <. wWc* L 3?- Kh l ri t O M l I" 'l\n *1 Non-poi nt Re->] 3900. 54.3^. L46 / . , 2j0C ! 1J 1 M L S**i 1. 1"*! RLLLriHH 0467. NO! ! !-, FvH i,,. < :i n 1.: J'CJ I.OND HLLHN OH r '11 & 1t. ` i. 1 1 d t l!" Til ) U 7 T -- 31 (Land ; L 1 i 5 7 fJ 1 AL l AND RELEASE ..). N_'Yi 0. . i> L .' i r-r. N NLo ' un f J I-i o 78 1 00 1.00 000005 ?57 sM- WAGli" j. ','3 7 ShRA 3t 3 Kt^-'uh i TREA rriEhr METHuDb AND EFF i C IENCY L.mKE LriAKL.EB EEC IMcK ' i i_r-.ffcL. i AL. I' Mb i'PEHfi v:' ;'CMA rur- j', W m 3 T E ;'RL.A - n/ J'i'T method b j'. GI... Q t j 1 C A i_ TREATMENT *: AEROE l C > BIDLUBJXAL 3'REA THEM f *: AF.RQDIO "i REATMENT hr F J. C I EMC i vfj/l i, a) 1 007. 1 c ) Kef JiTE >]' IT'trLLEN T JNL. bN I' EMI j. ON j p b 1 p p iTi * b ) J >- 0 ppm < d ) Assumption based on data tor similar ore;am c ixiDJurd ; sew Table A--2 in Weis c ewa!.; er Appendix). Cheirii c a 1 was not detected. so one- h ai -f t ,e d t tec t j or. limit (O.L.= 10 ppb) was assumed ibasea on lj'rOV Rt.G Lake Charles wastewater analysis. Technical ifietiior andum Nc. 603-CT--35C "2, and EPA Guidance Document) t - > Assumption based on data for similar or dan i c: comp our id a (see "Estimating Land Trea trnen t A.i. r Eirussioni" 1.1: Guild Waste Data Appendix). d ) Based on Ponca CL tv Solid Waste Composition ) a t SAL 000005 358 f ^jc-r '. ('() Pf?0p6 PTt T- S/oloG/c^ Ro61c) OS V. EFPiCfCA/T L UEfifT etVCV7ftfi'..Dfy - HOo /T ^ y f^O'V' Goi/^A/Ct Aoco^f/vr Conccc inr Calculation Sheet joc No. Title ~ ieid State SAL OC 0005359 URLE .i 'r-iiA ..ID -L-.r OF C KL:._.EASE !' iT .'ENTER < i. AI--tii KHAELLS Eli" j y i. ........ ;j - i'i\.[ ME i H O .I 'EM Z Er.it- M f' i U i. 1 h I I F'I c... I . t:.i A 9 L i 1 1 I.j /VI" -"I on i. ' n C] KijGt R j. ed Kopt lotrtJ i r. t Re] east.- .i[R non- f- j im r r;..L:...Eares `:uqi i; < v8 tv^Li i pmen t IT.;. CPU FArrq<_; l jf i-l 1 > ;t> urn Coker No. ,i Coker L o?s <~<:c NO. 2 D r-v 0 a ML'G i rarmA 1 Cr -*c ker i ank r arm/Lit endi ug Pro reas Draini Sepai-iturs A rit. OAK ,i Ar j .i. i r ower WdS t &wat &r Release Vo Air Waste Rei. ease to hi r. Total Non-poi nt Rel ease TOTAL AIR RELEASE WATER RELEASE LAMP RELEASE ji i - - i. - e ; LancH arm Or ; -.21. tt; (l-_arid tii 1 1 T l 11 hl '.AND KE..S; A're J. i: . ' A 4. A (_} . 1 04. 1 64 . 1 1 58. 1 44 . 04. 2480. 8. L. 1. 46/5. 465 /'. .' j .- A O, 499 > 499) ] oo I'.'O SAL 00000536b (see "Estimating i.. ind Treat nent. a i r am l a i or Was !';.e Do t a Append i.) . i 'Do i i. J :.jas1 c-r aata + cur ?- \ i ar or gan t o. c mip 0-11. d -- s j !:i:.in a. t: a i.n 5 pi id Wa-.'.e ii. SAL 00(1005361 PSEu[)o - Compostr/ons Q} z <{- TRiW-rfj ,/LBEtt-Ne') GAsoli/VS - Ut-^RE-Cx, &Ase J 5i-oP Fee (SAsolmVjT CO/V0EA/.SATE ^OK-ER QfrSoLiNE W1^ 2^ j,b /.to i.p 3JD SEE /^FSEWOIX Ctf^PbsjT/o/v B/ie^Rod/VO JWFbRMATlo/V ,'e ov C-ec-.ed 3, Conoco Inc. Calculation Sheet T.tle JoD No. Field State SAL ^00053 62 jj2..H - -m frtern yu?g/i/gg-/V abLCULATtoh s ( PseuDo-Curlewa.') StoraGtE ~tiwk5 p Fort-png RooJ= = [^z.ItpyX^O ^ 0.7r?yX`0 x-$cw 2rp ^2^03 - <? */1K LobbiNG- Cess - ^((0,tsi-rpy)(.o;i)+ 6*2.7"* Tpy^.Ol) + '|A.5TtfyX / .03^3^ VC fr.J * 2o 0 -s i-i l% ECPUiP/^EA/T F^mveS ~(SE- Appemcix x ") Process DRAINS - C-Zg<e.lTP'fX 0.1-2100 \AX._x2^3-'Y1i.)^zooo^) = 5 %K. ARC SEp/'NHATt) R - (3nAZ Tf>Y)( cM2A/ tO/L .03^5 2(7*0^) 1 L%* C0061/V6- To^SA - ^2A.*1 Tf?y)(^s)Czeoa\ 72. L%? WfcTBMATER' E^LUE-NT - O RElEA%B To Ai(K O waste /Vo M-T.4 .MtlLfrGLE c>N pseuOo c.o/MEtf .AS..S u/MSO Sane tcs Bcrrstmiiu-i P#Sht fir imu. Goofoe^r5>9-r/o/v,s, Qot/i/riTy T& IS S>E&RAbEb, LOSSES lb PnR RfiE Assumed /YE&-{G/6ie N&rE see, ^P^e^/cEs f=o* j>etaycs <o/y at^/v's Made By Checked Sy Date ^aae of Conoco Inc. Calculation Sheet Title Job No. Field State SAL 0000053 S3 ','1 _! --i l i Jlv 't ! .HI- 'll C: IARI ES i VE- r I Mr ':'Y >-l.'Uf- i Hhi :u in i k-f:. i. fc / v IT.' RUIN i RRI ..ENGLE C L C.\ H i an 1:. a <- i. o p i. 1. !`iQ KCD f- Fj, Egg- "it. :.a.1 Point Re] ease 7L8 5:34. 842 (<lW ) i R r-iUM- i~ Pi l i i T RELEaGR;: oad .' n r.i L ess 31 4 5 'JO .1. t i. h Lgu. i. pineo t Loss No. T. L 1 U ilo'...' , 4 NOG J. 2 0 I in. CRU P HI'S 24 1 -j Rod- 1 Sr' Luli S:" i'i O-TA i'll i .,."> r. (T-f Pit J - CokL-ji" 46 k".- O 1U4 <..as R era , er R) m . a N6i:.- di3 , i.R-t i i. L 2/ d !" L '... i 288 ! L . H S'... GO i. O'" 120 1 Jo, :i ! IDS .. No. 2 LRU L HLG 4G28 flier iTial Crscker 80 I HiL R arm/ 81 end i. no i 0 c-. <= Drains 11>500 330 teparat or s hF 1 DAF 1AF 46 4 Coolin g T awer O1O Wastewater Release to sir J. 76. Waste Re.l ease to H.i r Total Non-Doi nt Rei ease 22F3V . ( P 4 OO* ' 1 i ;..j 1 hL h IR R E L LEh F t. 2 T /';v. WA TER EEL.2NSE 37 . >. < 499 v 1 ..AND RIEL !:ii3E U F Lr5L 3P. L I'M AL. i., / 4D R L i - i.. h t N /A SAL 000005364 i`iAS fi:_ ] .>r-1F'.r i i 1 nF:r <".'lF'-' ! rREA i'i'|!!--i f 'V!E fhODS ANL> C;-'FIC iLNi. L.i-ikL L-Hi iRL.tub ULf IMr.r.. * XYLENES rsuilA.i AA... .;Ro ' i'-.G l ELAM r.c i;;i r ALN ilfi Vi lijij TEL A"1 i''i! EFFIC1ENCt Uf-ii jlr-LJi.i: : ! v w t: i ; l- 'JLi-.i Ij WrtS'ib! RECOVERY' jr;.[ r :h j ulue i l"m`. i'R BATMEN ! 1 Ah ROrJ I C > ftiOLGC-j] CAL TREATMENT AERQBIC) '?/. , a) c?b7. (b > 3. OOV. ( d ) : LAE N " Cj: -i <_ : RA i' i Ai 1 - i.'/. { a / ppu 1 ppm(c) 1 0 V ppm <e > based on data provided by Brandt Butler. See T an 1 e r~ V: in Wastewater Mppendj.;: . Ahemi cal was not: detected, so one-half the <: et o> t j. on limit. (D.L.~ 30 ppb > was assumed (.based on 1 Lake Charles wastewater analysis, i'ethruc-a. Mem. :) am ji.uTi No. 603--79-350-2:, arid ERA Guidance Document 1 d) See "tstimatint Land 'eatment Air Em t. as ?, ton-; l'i iu L l d Waste Data Appei nil . See Waste Composition Data .in Solid Waste 1.;. Appendi;; . SAL 000005365 XVigfl/BS Ce^posiTioNs bLENd^b GAzU/YS - GE&^Ui-jSUL Fcx. <3-AS&Ultf PePoA^A'TP f/AAtfTw4 CPHSR WT % 8.3 *\7 14. 4. uf i.r Se Maae 3y Checked Bv ".-.te E- fo tCo^^Sino^ BACk&floo/VQ Data Conoco inc. Calculation Sheet fine Jod no Field State SAL 000005366 XYLEt/z. QAlcjjlA-t\cNS Storage. Tanks : r ?0\ FusfiTiNG Roof = [ (34.1 TPyX 7^ ) * (l. 1 TPY\7S ) -*- (zs.1 tpy)(v)](z x iooa * 'd>Q% ^S/hH Fixed Roof - (V^.2zTPyX^st^T^rX2000 ) = USPOlWG Ltfiss .JCiO.ht-re'^X'ioo) TPiXlo' 0 ')* 6^.5Tt/yX^)) oo * TTx * 2400 - Srt /vl Fu&mvE EauiFwEtfr Rle4-s$ ~ See: fiPPEtf&nc X Process ORfyNS = (ZSPf.l TPyX " cvyA Apr SEPfiMroF^-- (tTtMZ TPiXJf^')('J^iY'^c>0') ^ Hs ^ Cool.\ng -towers -' (^C7 C) TPi)( l')(zooo) = 6/6 ^/v* WA-sre ivATEtf EFFlu^I'/T'- v.'b\ xiO*,uUA'(-K x^ -- =37 T/y TB 4l/? _ 3(*.6 Cfi/Y* ,o r ,2f = 17S'. 7 `V * /76 t5/> WfrsTE- REL4SS To Ai- 6^653 * -2.?ir lo4* ///z K ^X-zpooXp, j Zo) t /(i/% TO * _0 CO^^ACCC) (Vote : sr 4FP/vi>jcE5 Ft*? cAlcu^at/qa/ 9Ac.kgago# xnForpvhiotv Conoco Inc. Catculation Sheet ritie Job No Field State SAL 000005!i67 89CSOOOOO 1V> aieis DOij -n cor )ddi|S uoi;e|nO|eo 3U| COOUC'O ' /a. D sscn 5^1 Qjcn tfVO wV3.Vdin&^ 3^u'5vy >7/VbLL - 5>V0/SS/u/= _ S- bfc7 w|yx- J*<?/ ^3^^. O/Vnoco <7//# 7*^3^ z) 3 --y//-S-jJTtyM 5V0/i`O/^?tO Qyvy yit/C 2^.S*M (?/7C?S {*ifc/Q /VO'l'S^wCTj 3-US-A/o Ax/iA^yOD ^Kyix^u/ ^V0 xoc$ jo-i3 *7/^3 _s.'? ">o! ^-xQi. A/oi9S{u/3 3d3d *W3^ T Xl<JA/=WdV s? WfJSddti =/ XIQM34dti 3 *3/./.-' Jd,y 9 X:.7/'3ddd XlOA/3dd^ 3 s..:'j/j7Jdfi X\QN3r)dv * d ^//' d3'd ' 3 7* -d<ys<y d-vys tn S3:>!<M/3ddtf FePoP Tf-C. -t Lftfri 7" h -y/,c^ c^r< c^ us' Ccy. *kr:f. T tie -.i'. .., t. ' 0 "' " h\ $4(. 00005369 Interoffice Communication To P. L. Youngblood From T. G. Waltrip <>* February 25, 1988 Subject SARA Title III - "Toxic Chemicals" List for Sec* 313 Reporting As you requested in your IOC of February 9, 1988, we have put together a survey of the "toxic chemicals" which are listed under SARA Title III for Section 313 reporting and which may be present in refineries at or above the concentration criteria and threshold quantities as defined in the final rule on reporting requirements (FR 53, February 16, 1988). The chemicals are divided between two tables. Table I contains a list of chemicals which may be present above specified de minimis concentrations and threshold quantities in crudes, intermediate; and products. Table II contains a list of'chemicals which may be present in additives incorporated into products, as well as chemicals, which may be used as process chemicals, catalysts, etc. This list is by no means to be considered as complete or totally comprehensive, but only represents our best effort to narrow th i scope of the reporting task and to present a guide to be used in the reporting process. Particularly, additives and process chemica|Ls will require a thorough search of the MSDS Information and any other descriptive material on hand relating to these. We have attemp :ed to err on the conservative side in estimating chemicals reportable both by concentration criteria and quantity thresholds. Pseudocumene (1,2,4 trlraethylbenzene) was not included in the Tibles, In anticipation of Its removal by EPA. On the other hand, hove rer several chemicals have been included on the list which may not lave been present in refineries in 1987, nor currently, but which mar be present in alternative processes, catalysts, etc., in future yeirs. Also as the threshold quantities decline to 25,000 pounds by 1959, some not reported for 1987 may then be reportable. We hope these lists will be a reasonable and fairly comprehensive starting point for Section 313 reporting. If you have any questions, please call Ollle Engle, who has coordinated our efforts. T. G. Waltrip * bl cc: JEC-TLT-MAC-OFE-F:Oil.4 SAL <>00005370 Phi1 2 '3'o4ungolood Feb ;y 26, 1986 Page 2 SARA Title III, Sec. 313 Reportings TABLE I Chemicals which may be present in crudes, intermediate streams, and finished products: Chemical De Minimis CAS Cone. Number Wt.% Crude Oil Benzene Ethylene Naphthalene Biphenyl Xylene o-Xylene m-Xylene p-Xylene (1-Methylethyl) Benzene Ethyl Benzene Styrene 1,3 Butadiene Toluene ^ Cyclohexane Propylene ... Anthracene ' * MTBE . Sulfuric Acid ^ * Ammonium Sulfate 71-32-2 74-85-1 91-20-3 92-52-4 1330-20-7 95-47-6 108-38-3 106-42-3 98-82-8 100-41-4 100-42-5 106-99-0 108-88-3 110-:82-7 115-07-1 120-12-7 1634-04-4 7664-93-9 7783-20-2 0.1 1 1 1 1 1 1 1 l 1 1 0.1 i 1 1 1 1 l 1 X X X X X X X X X X X Crude Fract. X X X X X X X X X X X Reformer Refinery Process Cat Cryo/ Thermal Poly VRU FCC Products (1) (2) Other Gaso. Dlst. Ocher XX X X XX XX XX XX X XX X X X X X X X X X X X X X XX X XX X XX X XXX XX XX X XX X XX X XX X X X X X X (1) 1,3 Butadiene and MTBE are produced in MTBE Units; Sulfuric Acid in Sulfuric Acid Unit; Ammonium Sulfate in NASH Units. (2) Includes; LPC| Sulfuric Acid Plant Product; Asphalt and ResiduaT Oils ffonTfilghly aromatic crude oil; NASH Product^ ~~ (3) May be present in quantities approaching one percent in aromatic crudes and their residuals. Paraffinic and naphthenic crudes are not believed to contain substantial anthracene. (4) Sulfuric Acid and Toluene also appear in Table II, Process Chemicals. t UAJ. 2/2f Pagt iUUl ' .ooa SARA Title III, Sec. 313 Reporting TABLE II Chemicals which may be used as process chemicals or as additives In finished products. Chemical^ ^ CAS Number De Minimis Cone. Wt.% Process Use'^ Blending Additive Area of Use Diethanolamine Bis (2-ethylhexyl) adipate Ethylene Dibromide Ethylene Dichloride Ethylene Glycol Phenol Hydrazine Sodium Hydroxide Cresol o-Cresol m-Cresol p-Cresol Asbestos (friable) Aluminum Oxide Aluminum Lead Dust Lead Compounds-Inorganlc Salts Lead Compounds-Organic Manganese & Compounds Mercury & Compounds Nickel & Compounds Antimony & Compounds Barium & Compounds Chromium-- ----- =-------Chromium Compounds (Hexavalent) Chromium Compounds (Other) Cobalt & Compounds Copper & Compounds Molybdenum Trioxide j > Continued 111-42-2 103-23-1 106-93-4 107-06-2 107-21-1 108-95-2 302-01-2 13 L0-73-2 1319-77-3 95-48-7 108-39-4 106-44-5 1332-21-4 1344-28-1 7429-90-5 7439-92-1 1313-27-5 1 1 0.1 0.1 1 1 0.1 1 1 1 1 1 0.1 l 1 1 0.1 1 1 l 1 1 1 l 0.1 1 1 1 1 X X X X X X X X X X X X X X X X X X X X X X X Amine Unit X Possible Lube Oil Additive X Leaded Gasoline X Leaded Gasoline X Refrigerant Systems; Closed Loop Cooling Systems FCC Caustic Wash; Sour Water Stripper. Boiler Feedwater Treatment X Caustic Wash Systems; Greasemaking Lube Solvent Treating; FCC Caustic Wash; Sour Water Stripper, etc. Same as above. Same as above. Same as above. X Insulation; Asbestos Filled Asphalt X Catalysts; H/T; FCC & Cat Poly Mechanical Greasemaking; Mechanical Bender Sweetening X Leaded Gasoline Blending (TEL) X Leaded Gasoline Blending (MMT); Mechanical Mechanical Catalyst X Greasemaking X Lub Rlenrilnp/flroaeamaWng --------------------------- ---- Mechanical Cooling Water System Treating (chromate) (?) Catalyst X Mechanical Catalyst Phil voui\ 2/2( Page 4 ~ood SARA Title III, Sec. 313 Reporting: TABLE II (Cont*d) Chemicals which may be used as process chemicals or as additives in finished products. Chemical^ ^ De Minimis CAS Number Cone. Wt.% Process Use*1 ; Blending Additive Area of Use Vanadium (fume or dust) 7440-62-2 1 X Catalyst, H/T; Mechanical Zinc & Compounds 1 X X Lube Blending/Greasemaking; H-S Absorbent; Water Treating Hydrochloric Acid 7647-01-0 1 X Mechanical Phosphoric Acid 7664-38-2 1 X Cat Poly Catalyst Hydrogen Fluoride 7664-39-3 1 X HF Alkylation Ammonia 7664-41-7 I X Refrigerant; Sour Water Stripper; NASH; Sulfuric Acid(3) 7664-93-9 1 X Overhead Corrosion Control Cooling Water System; etc. Nitric Acid 7697-37-2 l X Chlorine 7782-50-5 1 X Cooling Water System; Well Water System Effluent Water System Titanium Dioxide 13463-67-7 1 X Mechanical (Paint) Acetone 67-64-l 1 X X Butamer Guard Reactor Spent Adsorbent; Greasemaking; etc. n-Butyl Alcohol 71-36-3 1 X X Same as above. Sec-Butyl Alcohol 78-92-2 1 X X Same as above. tert-Butyl Alcohol 75-65-0 1 X X Same as above. Carbon Disulfide 75-15-0 1 X Sulfiding HDS Catalyst Methyl Chloride 74-87-3 1 X Mechanical Dlchloro Methane 75-09-2 L X Mechanical Formaldehyde 50-00-0 0.1 X Lube Blending (FR Hydraulic Fluid) Hydroquinone 123-31-9 1 X Boiler Feedwater Treatment Methanol Methyl Ethyl Ketone 67-56-1 .... 78-93-3 --1 1 ------- X ------ X MTBE Process; Mechanical , Lube Sotvenc Dewaxing------------------------------------- 1,1,1 Trichlorethane Toluene' ^ 71-55-6 108-88-63 1 1 X X Mechanical Lube Solvent Dewaxing; Mechanical (1) Listed metals in form of either fume or dust. Metals in the form of articles and which are not released to the environment are not reportable. (2) Process use category includes mechanical in this list. (3) Sulfuric Acid and Toluene also appear in Table I, crudes, intermediates and products. sal P. L. Youngblood 2/25/88 Page 5 SARA Tide III, Sec. 313 Reporting Addendum to Tables I & II Chemicals in Tables I & II which were listed carcinogens (de minimis concentration of 0.1 percent) were determined by W. D. Broddle, per 29 CFR 1910.1200 (d)(4), through a search of (1) IARC Monographs (2) NTP Reports (3) OSHA 29 CFR Parc 1910, Subpart Z, as: Asbestos Benzene 1,3 Butadiene Hexavalent Chromium Ethylene Dibromide Ethylene Dichloride Formaldehyde Hydrazine Lead Compounds (Inorganic salts only) 00i S3?4 (conoco) Interoffice Communication To From Oate Subject P. L. Youngblood T. G. Ualtrip March 7, 1988 SARA Tide III - "Toxic Chemicals" List for Sec. 31B Reporting REFERENCE: Subject letter of February 26, 1988 ADDITION TO TABLE 1 Although pseudocumene was removed from the Extremely Hazardous Substances List, you have pointed out that it is still classed as a long 1 term hazard and therefore is still Included In the Sec. 313 Release Reporting. A corrected copy of Table I, which includes pseudocumeme and the affected streams and products, is attached. Please attach this reviser copy to my February 25 letter and discard the original Table I. T. G. Waltrip cc: JEC-TLT-MAC-OFE-F: 011. A SAL OG 0005375 f. i ;oungDlood Sruary 26, 1988 (Revised 3/7/88) 2 SARA Tide III, Sec. 313 Reporting: TABLS I Chemicals which may be present in crudes, intermediate streams, and finished products: Chemical De Minimis CAS Cone. Number Wt.% Crude Oil _____Refinery Process___________________________________________ Products Crude Cat Cryo/ (1) (2) Fract. Reformer Thermal Poly VRU FCC Other Gaso . Dist. Other Benzene 71-32-2 0.1 X X XX XX Ethylene 74-85-L 1 X XX Naphthalene 91-20-3 1 X X X X X Biphenyl 92-52-4 1 X Xylene 1330-20-7 1 X X XX XX o-Xylene 95-47-6 1 X X XX XX m-Xylene 108-38-3 1 X X XX XX p-Xylene 106-42-3 i X X XX XX (1-Methylethyl) Benzene 98-82-8 1 X X X XX 1,2,4 Trimethylbenzene (Pseudocumene) 95-63-6 1 X X X XX Ethyl Benzene 100-41-4 I X X X XX Styrene 100-42-5 1 X XX 1,3 Butadiene Toluene ^ ' 106-99-0 108-88-3 0.1 1 ,X X X XX XXX X X Cyclohexane 110-82-7 1 X X X XX Propylene , . 115-07-1 1 X XXX X Anthracene 120-12-7 1 X X X MTBE 1634-04-4 Sulfuric Acid v*; 7664-93-9 Ammonium Sulfate 7783-20-2 1 1 1 XX X X X X >J (1) 173 Butadiene ano nxtsK are produced in MTBE Units; Sulfuric Acid in Sulfuric Acid Unit; Ammonium Sulfate in NASH Unit o o (2) Includes; LPG|, Sulfuric Acid Plant Product; Asphalt and Residual Oils from highly aromatic crude oil; NASH Product. o (3) May be present in quantities approaching one percent in aromatic crudes and their residuals. o Paraffinic and naphthenic crudea are not believed to contain substantial anthracene. U1 (4) Sulfuric Acid and Toluene also appear in Table II, Process Chemicals. o L-AsKt CtA^i POTENTIALLY REPORTABLE TOXIC CHEMICALS UNDER SARA 313 MOST LIKELY POSSIBLY (Most Have Been Eliminated) --Benzene* "Ethylene -Naphthalene ^Biphenyl `-Xylenes *-T^Methylethyl benzene ^E^hyl benzene `-Styrene Butadiene* ^Toluene ^Cyclohexane ^Ptopylene _ ^Sulfuric acid^ (phenol^ (Cumene) Ethylene dibeemide* ElUyleuc. dichloride* Csodium hydroxide^ ^Lresol j ''Aluminum oxide' ($laijnganese Compounds "wydgegeu iJUprleeT aonia" Metbano; mm 2 Mathoiiy ethanol lolybdenum trioxid^ iNicke! I Chlorine^ rwaj-t-.-- --I -- Bio (? othylhamyl) -ediyat Hydniine Affheofee* (linrif Mereegy Nitric Aeid Titanium dioxide Acetone Methyl Uilortde Dichlorocthane Hydgequinone Crfydrochloric acia^ Butyl gicohota _JJZ\ VtsmfrA' >" -CJ%^ i/ Formaldehyde*- ^ -- AmTTl^'r. ^ l.TT. fMT 1 fato -- -Stp. RgftiAf" Etltylcue glycol Antimony Barium Copper filch1 rtr->Tnf *~hane -- Carbon disulfide Freon 113 Vanadium leopropanel Aluminum Anthracene. JS&OlU/U.SUC. P& 0Jrvc'rt.i?t Ilonevnlemt ChrsnHum* Zinc (fume bb duo*) ^Phosphoric aci<Q v^T2,4 Trimethylbenzene (Psuedo Cumene) 7? /T,l,i Trichloro EthaneJ Tnt-ro^h I nrl/U head -(Organic) * Carcinogen subject to deminimus concentration of 0.1 wt%. chemicals have deminimus concentrations of 1.0 wt%. ill other h(jTt$ : ((^ OLUE EMG-LE LIST PU>3 pEF(#EY PfiofosED UST< -APr fOEET)tf& (4-/5 (~S) C.HErn\cAuS FooND ON Qfl/Ly ONE GmPMy`5 PREUfttA My list - wERE H6T bOOEC JO Ttf/S LISTING ooM"5'1 r CheTM ictfL eumiMAteo Sfrffi 3f3 fc.EPo&T LAKE CHPBl$ REFifiEK/ Rl&rrti<- -t-E>utvl EtHER - None f'Efof'^ec usEQ By &LuE8o& k; ETHjLErjE Di&Rot" tQg -- / 7 % Of= tEl (olliF Y/6 l_ - FP*^ .rp^ ^ WOjOao pc J7 - 2.3 3:0^ ^ < -75; 000 <_ - l^acc CHV" ET^y^/ZE QlCttiO^ E><~ /S% OF "TEL. ^OU.i ENGLE ~ FRe^ SPEC. \ HjOjCoO X ,/<? = 2TZoo t-<J. (< yTOaa cl- PtocEsSEO cm^icAl. PlETtfyt etAyi KEhpftC -- NeNS. ^ePo^THO 4^ usEA y Bujf&ooc 2.- ^CTHoxyETH^^oC -- /Ybtfr flEP<5i?TE AS uselO >Y Blub Book: None BERoATEjO As USBQ gy RLUEBooK CtfPofrtofry ----- ONUi U^oo US OF $\^ &5~ u$EO WEu. BFccvj THRFSHto^O, C< 10^0 ao USEQ Ctfe/ViC* Hir/C Du&T -- ^YojVE (fePoATSO /h USED SV RUjE&^K CARgcfl TE^Rtc-tfcoPtQR -- /vb/v'E usr) usfO 6Y # UE 0/^ L5A/}_" 31.^^ oF-.-TL (CLL\E BNGuE - FRom f^MuR, SPec ) IHOjOOO }< ,3**/ - S3~/&O 1$. (<-~?TOOa - RrogbssEO crfF^iCA B\S ( 2. ETrtyirtg*yC 1 AQ\PAT - AtWE PePoPTAO '`K o'SeA gy WiDfiagEA/ Flu6B>0E - /*W (SC/ gbo<) Q k.,r k Cate Pciqe Conoco inc Calculation Sheet Title Job No. Field State SAL 000005378 r- ^ H'fORA'ZftfZ ~ /V./?. CSLueavo*') fhg'FcroS. - f=oR structural myt/Tic/'/ " tier ftep^^R^cF ~ FPh 6-oiC^f: RFgCUA'/ -- frUL IN C-LAttC TrtSTfcO&EtVT SYST/T/hS /VlTfffC. zfc/fi - CgL0&50<) "TfT^^/fUyvi j3tX/0 -- OR&PP PQ ^RO/^ C/$7~ (R, -FF ) . Puc^ortE /- R) ETHYL lh-loGiQS/ QiCHCoRoE TtlArtC/ HYORoQ^jt/oY/t - ft. "" ~ CBlu<Eoq IjyflgacHfjagiC ^0 -- S.XZ, /VT) Lg. XQ 3 ~ 1,^7 -B CBLj 3oa}*^ BoT-fL Algols. --------- M /?. C6LoFg<uX) FcR^ALOEfiypt cartstoerf Q 72. PRo<^bs% D #/ jvptfotffTy ' uW D Mlttifllv'i 3 Sb A/or fiBRbRTFC (&-!? m^ofUt ft; TA Tc - TO &E ftBRcRTF-R 6/ KE&Rt-)f SYYQustR^s t BTH'/L^f/S &LHCoL --ff.fi* CgLofydlc)> (fcttr\frotfy $RfUufr\ /cgpp(?/CAR 0/Y DlS(jLf=/0 - M ft< C &L(ji=- 8c>k) ^FREeo/ - N'. ft . C SLU&1 ooR) vAfiAQiufa ~ Selo'*/ bewiNitftA asv 15 PRoPftfbE j Auur*Ufl/v/*\ " /Y. ft. CBLuE <sata)lys7~ Title Core"" re Calculation Sheet jOO No "ieia State SAL OOOOO5379 YWnHHHCErtE - No Streak canAosmart DATA HvAtcArtUS j lex rtHHV, OB flltfiMoS frCJ^iZClrtiS- TO OLL/E E-rtfrC ANO G\Ll QEV&EllE. f^SEf/iC ' PHosPrtoRi>c, -- //. R. t&LU. &o<) NoT ' THE PiNHL. CHE/HIeac UST As//B\vEC -3/ EHrtrtOT Sutler , I-r fV+s so&zestec tHAt- >AtA L/y -pHAOE /Y4a?c CtfFHUcACi fW> A00/TH/E1 &E HY/C*/AC rtiR OHi/SS/oH: S/HCE THE TN40B. H'4/HET <ZJfE.AAtc.AL //oT7 P^tCAVCA REGuiRE/VE/TTS A# /Tot YET E/VACTCO =otoE OfitTA Mpf EXPMf) THE c/sT oP REfofiTA6l cHSAVC/fLS, iVace 3v Checked Sy Date Fage of Conoco Inc. Calculation Sheet Title Job No. Field State ^AL 000005380 i r- - ITWftES.Hot-0 C-ALCuuQTIoNs] I^S"? SAAA 313 Rb.PoFT 1/tKB CHARlE S RSLFlNEfi'l Note. '. Sifkz& 7H ? RE.Fi/YFrfy Ms A `-arge.r tMo j^h Put THAN THE Po/Vcn cnry QF/\ Potfc-A FtTy TveesFatj) za/c.uLAT t a /vs ARs "rfOrcpo^TC FoR ES-TftgUZhHP/G- TVS P/PEsEMC >R Floir R/Rocey Crt*vci\LS zR LAKE CHRRlBS AdoVE THE TAAesAocC iSXElS, BeR^ehe - a.s* io4 bbl cruoe * v , % k <4=2.7 - /.33x/o^ 5 <[i2-?7 orViy P.C. ^ "W,/=//- - `tz 2oo * 10s ggL X x- .3.^5 X (s2M * ,OCo - (piH >-1ou te, (lli? t&tAl Pc. DPrA) ^Vi-e/Ar: - ISlBl.tJ X iOZ BBC * x.7(o X -- Rio x iok (?/Ho, ORtV J p-c- O/Wj) -<0,1 ewyo gEf/?EA/E = isyzi.H * 107 &bl x * ,76 * ^2.'/ * 0,0/7 - 70 X (06, ue ( OL. GABO, <4Z. i^-&UTAOl(V- 2.4.x /O4 set x oNul. P-C. Da-tf *62.7 X .003 A^b'v 7"!SL Nj3E/t>*r X'.S^V = I.& t-6 ( B-8 ONL P.C, data') MitioAu SoR.^^y 0(= THRou&tfporB Fgorf i<=igl g(jj Pa/Vc.* goaFB cvry fte.Fi/Ye#y m?, Title Co^-;o to Calculation Sheet JOD No. Field State IAL 0000053 61 p'^ -ToujEfVE. c/Z = /SS8/./ ,* io1 * * ~H> X Ga,H X ,07? 72 V X 10^ L& CuL GAS3. ONL'(y P'C. CIClOnexH-rtG - "7.2*1ofe X- x , -?6> X <b2</ x .o| PPo P/lPNE - I^XIO4, eg C'cc. SAiO, QNtP.c. OAt#\ 32, Sod K 10* X V2 X ^ X fc2,i/ X',01 3V7 V lo^ 6?8 7 ToT#_ J P.C, >r?-) tJfitPH'THtLEIVe- -. [r$<g0,<J * 2S6oJ * (.KERO + DlElBL) * ,oi = '27 < io' LS CPC. >Ar, SlPHcf-r/L J_ ~~7. H JQ1* K *^g ^ .~"7(fi ^ X*vc| ~ ^ * 10^ l& {Re. '- r' U^BN -- 3*4?,6> * (?4 x.o/ ~ 1G x to0, eg Co. 6 GASo. 0/V6/ p.c, >#^4J) PSU(X> CurtE/YE - (/2%) -- 72^/0^ 68 Cue S/fs. P-C. ST'YptpE Ov*)- "? X' /O fc 63 (J6 QA$G, P.C D/>T73) SutPuR ic P-^iO - ll YP.O CB USED PftStiOL. - 3, *7 Sodiopv, H'/OP^iOC 1 /<?. CREsoU 3,"7 y 0,30 l UzEC rVWLS X* 0>5" = 5". 35 f>]Sh L oseq u2 v 0, 3 XO./5" - />"7 L user. Conccc >nc Calculation Sheet Title Job No 0000053B2 S/L F.eia State Pruj<ntftuOi oKiOE Z16C, * ~?oo * i.'ZS * 1 , *22 /W7 lQ , WA/izANe-se 142,80 0 /i T x 0. U*X ~ ^8,5-1 / ^ frMrtcr/ifi METHbrtoL ' ^T2A "Sjo^ j Used (p &OCJ (aJo, X 1 CP yM% Gt C,Z.<f 7e - VY, # 0 [* Voi_1&0AuF TRloxioe - LI? An ^ Ot fb ' 20 ^ Ooo tilc%eL_ \.%<? y 1 0 6 X 0,0<( = SY,` 00 CHuof* >r/fr rOy$ao m ^ssc Pli&% pbio pi r ActjQ (eCoO^GoG X , 4 2f : Hf\ lj l I -T&tcH-Lorto B-rtfAtfC Sz > 5"^x .33 s 2-Y.3 jo cc CoafitT 3feOj oo x .oV - U'ifyfo^CCRfC- fruo SoDi ur* SotFA-lT 5:^^^ * 3 ILffoo t_g Sc>*` x ftfz. Ooo > L& n^oo ,_g Mfir* Move. 0$E> cjJ&aVcac. vA-tA FAp^ ! ft 7 EloE &oo*r Varji 2. C~&c.< :-o 5 - Di'r Page of Title Conoco !nc. Calculation Sheet job No. Field State SA<- 000005383 Append \y e E/W/SS/o/Y FACTORS 'ao-i r . Title Conoco Inc Calculation Sheet JoD No Field State SAL 000005384 TABLE 0-1. AVERAGE FUGITIVE EMISSION FACTORS FOR Tl_ SYNTHETIC ORGANIC CHEMICALS MANUFACTURING INDUSTRY (SOCMI)a Fugitive-emission source Emission factor (la/h) Pump seals Light liquids Heavy liquids 0.11 0.047 Valves (in-line) Gas Light liquid Heavy liquid 0.012 0.016 0.00051 Gas safety-relief valves 0.23 Open-ended lines 0.0037 Flanges 0.0018 Sampling connections 0.033 Compressor seals 0.50 a Emission Factors for Equipment Leaks of VOC and HAP, EPA-450/3-86-002, January 1986, Table 3-4. These factors take into account a leak frequency determined from field studies in the synthetic organic chemicals manufacturing industry. Light liquids have a vapor pressure great4r than 0.1 psia at 100F. GtK. Uclo^E PA, /2.-S7 l>-2- ? D-2 000005335 SAL TABLE D-2. LEAKING AND NONLEAKING AVERAGE FUGITIVE EMISSION 'ACTORS FOR THE SYNTHETIC ORGANIC CHEMICALS MANUFACTURING INDUSTRY {! jOCMI)a Fugitiveemission source Leaking (>10,000 ppm) emission factor (lb/h) Nonleakim (<10,000 ppm) emission factor (lb/h) Pump seals Light liquids Heavy liquids 0.96 0.85 0 026 0 030 Valves (in-line) - Gas Light liquid Heavy liquid 0.099 0.19 0.00051 0 0011 0 .0038 0 00051 Gas safety-relief valves 3.72 0 .098 Open-ended lines 0.0263 0 .0033 Flanges 0.083 0 .00013 Sampling connections _ Compressor seals 3.54 0 20 a Emission Factors for Equipment Leaks of VOC and HAP, EPA-45 1/3-86-002, January 1986, Table 3-3. These factors take into account a leak frequency determined from field studies in the synthetic organic chem cals manufac turing industry. Light liquids have a vapor pressure greater than 0.1 psia at 100F. R.ePt.AcT'ice - PA R^c^MeAJT- / p, D-3 SAL >00005386 Table 9.1-2. FUGITIVE EMISSION FACTORS FOR PETROLEUM REFINER :ESa Sure< StFaap A T?>* 11 III lr V 0>o r i *-ag aaala- III CamTHWi Hil/ it V Praceae drataa* I rraaawn waaaal n(glal. (-rale.)*-* Sealing tawara tl _ 011Amtar aagaratare - Seerage ......| Paccar Unite lb/hr-aaarca kg/dar-aawrea * - - " - ' . " ' " " - UlatlM ft Oftcoacrl)4 KaliilAiia 0.01* O.fti (0.030 - 0.110) (0.32 - l.II) 0.024 0.24 (0.017 - 0.034) <0.1* - 0.3*1 0.0003 <0.0002- 0.0013) 0.003 (0.002 - 0.014) 0.010 0.20 (0.007 - 0.043) (0.00 - 0.4*) 0.003 0.03 (0.0014- 0.014) (0.017 - 0.17) 0.00034 (0.0001- 0.0023) 0.0041 (0.002 - 0.027) 0.23 2.) (0.14 - 0.31) (1.7 - 4.0) 0.044 0.30 1.4 13 (0.01* - 0.11) (0.21 - 1.2) . ).44 - 2.*) <7.1 - 31) 0.11 " 1.2 0.010 0.24 0.34 3.0 (0.03 - 0.23) (0.3 - 2.5) (0.023 - 0.10) (0.23 - 2.2) (0.10 - 1.3) <1.1 - 14) C*ftcrU4 EiUlf4 HA to taglicabl* Caacra] lacliMlan IMttwU| aM Hltu KA HA HA MlltClM af ( ar glag HA Hniwui MUm.m pm to IMiuicil Mali. 4m1 Mill, I 4, HaitMlli u4 hUuLkm tan, CM<nlU4 | M to to kirtaaltll aaale, taai tuU. ^K|aP wU. Mtwrts 4 walat rmii oiinlM a|M*lk to to Negligible ____4liki *1 nil rt Him and/or tattlM W I Lata Factor lb/104 gal aaollag M11lUfkg/104 tara aaallag lfc/101 MljMlawy hg/101 11tara refinery [m/ 10lb/ 1 gal waatawatar kg/10* Hear wwaca 10 v*tr lh/ * hhl nUaaty toad kg/101 lltara raf lnr leaf Saa Sactlaa 4.3 Saa tactlaa 4.4 4 0.) 10 0.03 3 0.4 200 0.4 0.70 0.9*3 1.2 0.004 0.2 0.014 to 0.03 HHIalutH* af INwmiW la aha Into caaliac HUr eyataa, af caallaf HUT for kjfiau Caaanf aafaracara aa4/aa raraaaay B Seta !na lalaiaacaa 1, 4. u ^ LI ma W at matUkU. *Tha HliClUty and hggragea eaataal af th 1W acnaa ifaatllUadaa ananla aaf (( Set MaaMflcallaa JJI rtr Saa act af taacrlfUaaa ara - 11 hr Mda af tfea ratal IOC hIhI-- ara . m maf fact aa cl t~1~t*-- rata af aaaa fwglt I oatfaalaa aaarcaa. ftaagflrtlaa gyfracarbaa g--a( peeaaaa c llclaaa (eaaulalac la tlN a SOS hydragaa. kj light liraId Ml aa/Uaal4 arc haeay liraid act 10UfaU *r gaa/llawld arraan with a riper prappwri gtwatar chaa that at liman (> o.l gala C~T at Mtfa( tt'C). baaed aa tba emit *alatlla Uae pmai at MI hr eaUae 'I 11 raid ectaa with a wagar praaawra ggaal la ar laac than that i< karmaaa (< 0.1 gala * 100~F at Mt h f 30*Cl. haaod aa the Mat walatfla tlaa gcaaaat ac " Ml hg rwlwaa HyfHfM atraaaa Saa atraaaa ceaCalalag aara rhaa SOS hfdtagag hy walma 1Siahin la garoathaaaa ara cha aggat aad lawar haaft af the U tfldaaea fatarral for the aalaalaa factor. *Sata fzoa halaraaca If. Sa fanctna aide af thaoa ralraa la agaa to Cha ataaaghara. lalaalaaa ara thraagh the walwa aaat af tha alaaad aalrf. 'lalailaa factor far ratlaf aalewa la gaa aaralca la far leakage, mat far aalaalaai aaaaad hT aaaaal graaaara ralUf. Hcflaara rata la daflmd aa th erMa all faad rata ta tha ataaagharlc flat111atlaa calaa. 9.1-10 14 EMISSION FACTORS N^-42. j WnKS 10/60 ]> ^ ' 1' -/D , SAL] 000005387 TABLE A-2. FATE OF HAZARDOUS AND/OR TOXIC POLLUTANTS AT LOW CONCENTRATIONS IN SECONDARY, BIOLOGICAL WASTEWATER TREATMENT PLANTS DVERALt 'ERCENt REMOVAL iPERCENir VOLATILIZEO TO AIR PERCENT PARTITIONED TO SLUDGE l | PERCENT BIODEGRADED _______ 1_______ POLLUTANT ACCLIMATED JNACCl IMATED ACCLIMATED UNACCL MATED MEDIAN LOW MEDIAN LOW % %% % % % ACCLIMATED UNACCLIMATED MEDIAN LOW % %% ACCLIMATED JNACCLIMATED MEDIAN LCW % /o % 2.4-0 ACENAPHTHYLENE ACETALDEHYDE ACETONE ACROLEIN ACRYLAMIDE ACRYLIC ACID ACRYLONITRILE ALDRIN ANILINE ANTHRACENE ANTIMONY ARSENIC BARIUM BENZAL CHLORIDE BENZENE BE NZOTR CHLORIDE BENZYL CHLORIDE BIS-2-CHLOROETHYL ETHER BlS-2-ETHYLHEXYL PHTHALATE BROMOMETHANE BUTYL BENZYL PHTHALATE CADMIUM ____ CAP7AN CARBON DISULFIDE CARBON TETRACHLORIDE CHLORDANE CHLCRC6ENZENE CHLOROBENZILATE CHLOROETHANE CHLOROFORM CHLOROMETHANE (continued) 90 9S 95 95 95 90 90 90 90 95 95 60 50 90 90 95 90 90 90 90 95 95 27 90 95 90 90 90 90 95 90 95 60 50 90 90 95 95 SO 30 95 95 62 50 B5 80 75 70 90 90 65 60 90 90 60 60 50 50 90 90 55 50 90 90 45 40 90 90 60 30 90 90 95 95 90 90 27 27 50 30 65 80 65 80 90 90 90 90 60 50 90 90 60 60 90 90 0 00 7 19 54 54 9 0 55 10 0 32 10 0 55 10 0 00 '9 0 00 9 0 44 9 0 0 0 33 0 00 to 0 0 0 52 0 0 0 60 0 0 0 50 0 0 0 90 0 17 15 7 24 72 72 2 18 14 12 7 23 45 45 7 0 32 9 0 0 0 66 66 90 90 0 0 0 0 43 0 0 0 27 0 00 7 76 77 72 1 72 77 72 12 9 9 9 33 27 45 45 14 9 65 7 76 81 61 1 63 72 72 2 66 86 66 1 54 88 10 10 53 10 10 65 98 87 33 33 98 SO 50 60 60 50 50 90 90 44 22 43 77 53 66 66 00 41 41 27 27 42 11 96 33 33 14 14 54 11 22 11 83 55 46 67 28 20 85 81 81 85 43 26 85 81 81 81 56 45 81 77 72 81 64 60 57 57 57 86 77 72 43 41 41 0 00 0 00 0 00 83 34 31 69 16 16 65 28 25 60 38 38 81 43 26 24 24 24 10 5 5 52 50 50 0 00 83 46 28 18 6 7 6 00 48 48 48 50 32 32 74 49 41 18 a 8 25 6 6 9 44 TABLE A-2 (continued) POLLUTANT 3VERAL 3ERCEN IEMOVA . lPERCEN r VOLATILIZE D TO AIR ACCLIMATED JNACCU IMATED ACCLIMATED UNACCLl MATEO MEDIAN LON MEDIAN LOW % %% % %% PERCENT PARTITIONED TO SLUDGE 1 ACCLIMATED UNACCLIMAT60 MEDIAN LOW % %% >ERCENT BKj DEGRADED ACCL1MATE0 JNACCUMATED MEDIAN LCW % %% 2-CHLOROPHENOL CHROMIUM CRESOLS CUMENE CYANIDE CYCLOHEXANE OI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE OI8ROMOMETHANE 1.2-DICHLOROBENZENE 1.3-DICHLOROBENZENE 1.4-DICHLOROBENZENE 1.2-0 ICHLOROETHANE 1.1 -DICHLOROETHYLENE 2.4-DICHLOROPHENOL 1,2-DlCHLOROPROPANE DICHLORVOS DICOFCL DIETHYL PHTHALATE 3.3-DIMETHOXY BENZJDINE 2.4-DIMETHYL PHENOL OIMETHYL PHTHALATE 2.4-DINfTROPHENOL 1.4-DIOXANE EPICHLOROHYDRIN ETHYLBENZENE ETHYLENE OXIDE ETHYLENE THIOUREA FORMALDEHYDE HEXACHLORCM .3-BUTADIENE HEXACHLOROETHANE HYDRAZINE (continued) 95 70 9S 95 60 95 90 90 85 90 90 90 90 95 95 90 90 90 90 80 95 95 90 90 67 95 90 65 85 95 95 95 65 60 70 70 50 40 95 95 60 60 95 95 90 90 90 90 80 80 87 85 87 85 87 B5 so 30 90 90 55 50 70 70 50 30 90 90 75 70 30 20 85 80 65 60 75 70 50 40 59 25 90 90 50 40 67 60 85 80 90 90 90 90 85 80 0 00 8 55 0 00 70 70 70 0 00 8 43 38 57 57 4 4 4 0 33 57 57 57 10 86 66 4 4 4 0 0 0 20 20 20 0 0 0 '7 77 43 64 64 13 12 12 45 78 77 32 9 9 45 78 77 3 3 3 45 78 77 23 9 9 45 45 27 5 3 2 76 81 81 0 00 0 00 8 44 45 63 63 0 0 0 0 00 9 53 45 45 45 8 6 8 0 00 1 11 0 00 8 32 0 00 8 76 0 00 0 00 0 00 9 87 0 00 9 54 0 00 9 63 24 72 72 _ 6 .....-5. . 5 0 32 9 S4 0 00 9 76 0 44 9 98 0 55 9 88 0 55 9 88 0 44 10 9 8 87 60 55 0 00 87 46 37 53 34 34 3 00 82 6 6 70 70 70 63 63 83 30 4 4 14 0 0 42 6 6 23 0 0 41 3 2 19 9 9 67 51 46 45 7 7 61 45 27 37 37 37 89 74 69 72 27 18 87 78 74 95 65 60 61 68 63 ai 45 36 78 53 23 fifi ia ,, 13 81 43 34 77 60 54 76 72 68 86 77 77 86 77 77 85 72 68 SAL 000005^89 TABLE A-2 (continued) POLLUTANT DVERAL 'ERCENl 1EMOVA lPERCEN r VOLATILIZELo TO AIR ACCLIMATED JNACCl IMATEC ACCLIMATEC UNACCL MATED MEDIA!* UOW MEDIAN LOW % %% % % % PERCENT PARTITIONED TO SLUDGE I ACCLIMATED UNACCLIMATED MEDIAN LOW % %% 1 PERCENT BKDEGRADED 1.......... ACCLIMATED JNACCLIMATEO MEDIAN tew % %% sx-v LEAD MALEIC HYDRAZIDE MERCURY METHANOL METHOXYCHLOR METHYL ETHYL KETONE METHYL ISOBUTYL KETONE METHYLENE CHLOROE N-BUTYL ALCOHOL N-NITROSODIMETHYL AMINE NAPHTHALENE NICKEL NITROBENZENE 2NITROPROPANE P-BENZOQUINONE PARATHION PCB PENTACHLOROPHENOL PHENOL PHENYLENE DIAMINE PHOSGENE PHTHALIC ANHYDRIDE ---------------.PYRIDINE___________ SELENIUM SILVER STYRENE 1.1.2.2-TETRACHLOROETHANE TETRACHLOROETHYLENE THIOUREA TOLUENE TOLUENE DIAMINE TOXAPHENE (continued) 70 00 SO 100 00 05 00 05 05 00 95 35 90 05 05 0 92 05 95 00 100 90 IS 50 90 90 90 90 90 90 90 9S 70 70 75 70 50 50 95 95 90 90 50 30 50 30 87 85 90 90 75 70 75 70 35 35 25 20 95 9S 50 40 55 40 92 92 25 20 85 80 75 70 100 100 90 90 15 10 50 90 90 90 90 25 20 85 80 75 70 90 90 75 70 90 90 0 0 0 1 54 0 0 38 0 0 0 0 0 66 0 0 9 0 0 0 1 0 0 u 0 23 36 45 0 23 0 57 00 00 33 55 54 54 32 00 52 51 00 00 44 00 00 90 90 00 00 99 00 00 00 55 00 11 uo 00 72 72 15 12 68 64 00 72 72 00 72 72 70 70 70 9 67 48 48 48 10 10 10 B 86 10 5 3 9 53 13 12 12 10 9 9 9 87 27 21 20 35 35 35 9 32 11 8 43 0 43 22 22 22 17 5 4 14 13 12 6 67 10 10 10 9 99 2 21 90 90 90 14 14 14 41 3 32 9 87 25 16 18 9 87 4 44 0 00 61 68 63 2 00 90 81 81 28 26 28 85 43 26 81 45 27 44 23 22 86 81 81 81 66 63 66 50 47 0 00 81 23 18 9 44 87 46 37 0 61 37 61 61 61 78 21 16 81 72 68 81 68 63 90 85 85 81 81 81 13 13 9 .n Q. 0 00 54 5 5 50 9 7 42 14 14 81 68 63 42 0 0 81 68 63 34 14 { 14 TABLE A-2 (continued) POLLUTANT DVERAL ^ERCEN 1EMOVA tPERCEN r VOLATILE D TO AIR ACCLIMATED JNACCl IMATEC ACCLIMATEC UNACCL MATED MEDIAF' LOW MEDIAN LOW % %% % % % PERCENT PARTITIONED TO SLUDGE r ACCLIMATED UNACCLIMATED MEDIAN LOW % % /. 1 j>ERCENT BIC DEGRADED ACCLIMATED JNACCLIMATED MEDIAN LCW % %% TnANO-l .g-PICI 1L0R0ETHYLGNE -- 90 ao - 63 72 77 27 88 TRIBROMOMETHANE 65 35 30 36 21 18 5 3 2 1,2.4-TRICHLOROBENZENE as as 65 43 51 51 6 8 8 1.1.MRICHL0R0ETHANE 95 90 85 76 61 77 1 1 1.1,2-TRICHLOROETHANE 80 25 20 40 20 16 0 00 TRICHLOROETHYLENE 95 87 85 67 70 66 6 55 2.4.6-TRICHLOROPHENOL 95 55 50 0 00 6 44 1,1,2-TC 1.2.2-TF ETHANE 90 65 80 63 68 64 4 33 TRIFLURAUN 90 90 90 0 0 0 33 33 33 VINYL CHLORIDE 95 95 95 86 90 90 2 22 XYLENES 95 67 85 24 70 68 14 13 13 0 00 24 11 10 35 26 26 18 8 8 40 5 4 23 12 12 87 51 46 23 14 13 57 57 57 8 33 57 4 4 A-16 A* A3to/& O' fo in oo o o o < CO T'f< 3 \ LAND TREATMENT MODEL LATA ; 1 and cr eal.r: :r. L, Loading i g 01 l /cc "nil) Enter Ci >: 10'''6 VO ppmw 1.Depth (cm) Total porosity Air Per as i ty (de-f ?,lu L-O > MW oil VO diss. in water, renter Time of calc. !dav=i Biodegradation, enter ! Temperature (Dec- d Wind Speed (m/s? Area \m2) m r* 2*J . i 4.47 :*5000 COMPOUND NAME. METHYL-ETHYL'KETONE BENZENE TOLUENE CRESOLS NAPHTHALENE PHENOL CARBON TETRACHLORIDE TRICHLOROETHAVr ' 3 , i. , p METHANOL ETHYLBENZENE CUMENE ( i sopropy? r^ij XYLENE <~o) LAND TEE A'!' r-iEMT TRACT I CJhi LOST A1P r. V r IT INTERMEDIATE Ti IE 365. days IF: BI n . 7 : _ ru . 0. 474 . (>56 .. 1 7 C . 9 90 O. 999 0. 96^ i'; ,, 373 0.99^ (*> ~r 0. 236 '> 9 7 0. 506 0. 94 4 ,"1- 953 924 0 002 f> 002 034 O. ft67 ^ r~ O 6SO ~0.714 0.907 0.492 0.056 0.047 A.. 076 .. .. 7 73 O. 998 0. 966 0.362 O. 968 0. 320 286 097 j. buS 944 !l933 :j. 924 j. 000 ooo ). 07 4 >. 633 ;?. 000 >. 680 SAL 000005392 o r\ Estimating Land Treatment Air Emissions Based on EPA Land Treatment Mode Compound Benzene Toluene Xylene Phenol Ethylbenzene Cresol Naphthalene MEK MIK Acetone "^ere^e-Mce - Land Treatme nt Fraction Lost Air Bitideqradation 0.903 0.097 0.494 0.506 0.320 0.680 0.076 0.924 0.333 0.667 0.056 0.944 0.047 0.953 0.714 0.286 0.969 0.031 0.978 0.022 l]-<58/ CjW>\ M, CricHkiM/ TbAaek o/a A^e>av=-fc" Soh_ SAL 000005393 /?PpE/VDi* C BLUE Book: Ofirfi Tide Concc: t-: Calculation Sheet SAL 000005394 jcc No Fie'O State u REPORT NO. 08-0512 JOD NO 6658 PROGRAM HO. A7632 LAKE CHARLES REFINERY PROCESSING SUPPLIES - OTHER DETAIL - SCHEDULE C PAGE RUN DATE 01/29/, ITM -FTR- --------- DESCRIPTION ---------- DECEMBER 1987 QUANTITY DDLLARS PROC SUPP-NONCIASSIFIED 006 0001 ACID SULFURIC 006 0531 ACIDIC ACID * i LBS LBS 6.1 606 0103 ACTIVATED ALUMINA DE-4 LBS 006 0106 ACTIVATED ALUMINA-H-151LBS 006 0376 ACTIVATED CARBON 006 0H6 ALUM --LBS 006 0396 ALUMINA BALL T-162 1/2 LBS 006 0667 AMBERLITE 200 LBS 006 0012 AMMONIA LBS 006 0699 AN - 676 CHEVRON OLOA GAl* 506 0386 AHTHRAFILT LBS 006 0606 fi - SQUARE 10025 GAL 006 0508 BETZ ADJUNCT 7V LDS 006 0557 BETZ AF11 61.2 5.6 6.8 2.6 3.2 15.11.3 8.9 23.1 006 0169 BETZ C-30 SLIMICIDE LBS .3 1.3 006 0178 BETZ DEI 186 LBS 6.5- 006 0608 BETZ DM 1067 GAL 7.1 67.8 006 BETZ DM 276 006 0666 BETZ DM 795 LBS LBS 006 0177 BETZ DM1112 GALS. 006 0528 BETZ EB 911 006 0710 BETZ MS 150 LBS LBS 006 0711 BETZ MS 200P LBS 006 0612 BETZ OS-16 GALS 006 0209 BETZ OS-8 05-22 006 0680 BETZ SULFITE 3 GALS LBS 006 0163 BETZ 2W2 006 0166 BETZ 2W30 6 560 BETZ 20026 006 06?7 BETZ 2020 LBS GAL .1 1.2 13.2 1.0 13.0 16.1 006 0639 BETZ 2060 006 0626 BETZ 22K 006 0628 BETZ 262 LBS. LBS 9.2 9.5 006 0179 BETZ 30K 006 "8662" BETZ 35A LBS 3.1 LBS 1.7 006 0623 BETZ 607 LBS 1.1 1.0 006 0620 BETZ 65 LBS C7T oT3T CaLGON KID LbS -------- ------------ :l 6876 12.3 006 0266 CALGON KNL-1600 006 0251 CALGON WT 2660 GAL 35.5 11.7 006 0363 CALGON WT 2511 LBS inrr 0096 CATALYST FCC EPZ -55 f&S 006 1116 CATALYST FCC SP LBS PROFIT OBJ 1987 QUANTITY nm 1 ARS CUMULATIVE TO DATE ACTUAL 1987 OUANTTTY non ARS ACTUAL 1936 OUANTTTY DOLLARS -1987 CUMULATIVi ACT QVER(UHDER) QUANTITY DOLLAi 11.8 692.1 424.0 270.5 52.6 10 . 7 .2 18.0 9.5 2.3 3.2 11.8 15.3 32.0 31.3 24.5 28.5 562.8 74.1 458.2 35.7 .7 .9 2.6 3.5 .7 13.8- 8.1 12.7 52.2 13.0 36.3 9.6 62.8 54.2 15,7 23.5 13.2 1.7 23.2 202.1 22.0 164.6 .6 .2 2.4 54.5 2.0 8.3 1.7 6.9 20.7 24.5 76.8 775.2 65.9 652.3 1.5 18.0 .5 5.0 .6 .2 5.3 1.8- 1.2 1.2 .6 . 3 .1 1.1 1 .1 11.7 .3 3.7 .4 5.0 2.3 .8 5.0 53.0 5.8 61.2 8.2 88. 1 1.7 17.8 262.2 286.5 222.6 238.5 .5 .7 1.3 1.5 47.1 48.0 4.9 20.5 7 . 4 31.1 29.4 29.2 " ' 71 ..... .7 22.3 20.5 19.0 17.2 6.4 4.7 .3 . 3 .3 .3 --mrs------- 5570 .2 .6 355.3 116.4 347.8 127.1 268.8 43.8 361.1 64.4 ~1 ,'25075 mrn76--71771577^743179^ 23.8- 11.8 52.4 2.3 32.0 562.8 .7 .7 52.2 42.8 23.2 .4 2.0 20.7 76.8 692 10 3 31 74 13 13 54 202 8 24 775 1 .1 1 . .3 3 2.3 5.0 53 . 8.2 88 . 262.2 286 . .5 1.3 1 . 47.1 48 . 4.9 20 . 29.4 29 .7" 22.8 20 . ______ 6-4. -------4- .3 ~3I5.4 8D. 355.3 268.8 1728075 116 43 . 1,012 23 . SAL 000005395 :BPORT NO. 08-0512 OB NO.6658 ROGRAfl NO. A7632 LAKE CHARLES REFINERY PROCESSING SUPPLIES' - OTHER DETAIL - SCHEDULE C PAGE 11 RUN DATE 01/29/88 |, - V -'r, . I.: . I'L ` ' - i'DECEMBER 1987 PROFIT OBJ 1987 TM- FTR----------- DESCRIPTION 4--5----------i-- QUANTITY. DOLLARS .... QUANTITY DOLLARS fV'nl, i- .t |? PROC SUPP-NOHCLAfeSIFIEDJj f, t'*T )J ' 06 0128 CATALYST: HYDRO-REGENERATIO nr06 9998 CATALYST W/0 PREC METAL LB rur CATALYST-DESULF 'M,;c-L85 06 1113 CATALYST-FCC SPENT1 LBS 06i 0151 CATALYST-MEROX 1 LBS X :: * ' 06. 0015 CATALY5T-P0LY LBS 98,0 06 oils CATALYST-PLATINUMLBS 06 1115 CATALYST-PlATIUM SPENT LBS f .5 06 0133 CATALYSTrRHEHIFORMING LBS nr06 0028 CATALYST-SULPHUR f LBS 0217 CATALYST-VANaDIUM |-----------VST 2.5- 1 .. 80.2 27.8 9.0 * 06 9999 CATALYST,PREC METAL TR-02 06 0009 CAUSTIC SODA-MERC CELL LBS 06 0010 CAUSTIC SODA LIQ LBS 06 0021 CauStICsqda^CaReTbT 06 1010 CAUSTIC SODA-SPENT LBS 169.5 784.9 4. b- 16.1 90.0 .91.6- 06 0009 CAUSTIC UAL POTASH 06 0389 CERAMIC BALLS LBS 67.9 LBS 35.5 39.6 23.3 06 0393 CERAMIC PELLETS AGGREGATE 06 0190 CHEMLINK IPC 5120 LBS 3.6 9.1 1.3 5.3 06 0032 CHLORINE LBS 06 0007 CLAY-ATTAPULGUS 16/30 LBS 9.0 .8 06 w Coastal iooi-c p~h" cnTL "gal" 06 0098 CORTEC VCI-376 GAL 06 0117 DAVISON COMBUSTION PRO LBS 06 0038 DTETHYLENE GLYCOL LBS 06 0289 DIMETHYL SULFIDE 06 0299 DUPONT AO 23 06 0978 DUPONT DCI-6 t 06 0199 DUPONT FOA 11 c6 0058 "T>Y"- ' fiRONZE REG GAS LBS LBS LBS LBS LBS^ 25.9 9.2 19.2 98.6 3.3 23.2 06 0059 DYE - RED PREM GAS LBS 06 0559 ELCO 231 LBS 2.2 3.0 0_6 rt6rt1 4 =9^-------- 5 8----- - 06 0037 "ETHYL MERGAPTAH .............TBS" 06 0087 FCC CATALYST HEZ 55 LBS 184,3 195.9 06 0101 FCC CATALYST, CCZ-11 LBS 06 0139 FILTER MATERIALS (MISC) U~ 0397 FILTREtrSUffPORT MEDIA LBS 06 0003 FIRE FIGHTING CHEMICAL 06 0212 HYDRO,TREATING CATALYST LB 186.2 962.1 06 0211 HYDROCHLORIC ACID LBS 06 0138 "HYDROGEN, `ELECTRTJ-------- CU-FT 598.9 19.6 . 9- 06 0300 K602 LBS 5.2 8.1 CUMULATIVE: TO DATE ACTUAL 1987 ACTUAL 1986 QUANTITY DOLLARS QUANTITY DOLLARS -1937 CUMULATIVEACT OVERCUNDER) PC QUANTITY DOLLARS 28.0 54.6 28.0 54.6 76.5 12.6 2.1 12.6 2.1 16.9- 303.6- 106.4- 16.9- 1.2 1.2 660.0 1,102.9 612.0 1,023.5 660.0 1,102.9 2.0 3.0 50.3 2.0 28377 . 95.1 95.1 145.5 197.5 145.5 17.9 63.8 69.1 150.1 17.4 63.8 9.9 18.1 V . 9 18.1 18.9 1.3 31.5 18.9 1,775.9 149.8 1,477.8 118.9 1,775.9 149.8 8.620.9 ' 399.9 7,380.7 342.3 8,620.9 399.9 12871 2875 128. r- 287IT 1,659.5 266.9 2,005.2 232.1 1,654.5 266.9 135.9 69.3 135.9 69.3 225.9 160.1 53.4 30.0 225.9 160.1 191.9 ..... 6T72 210.0 5874 17174" 65.2 59.7 69.3 40.0 50.4 54.7 69.3 90.6 14.8 174.8 26.9 90.6 14.8 1,271.2 95.3 1,271.2 95.3 .1 .7 .1 1.1 2.9 67.1 4.0 88.6 2.9 67.1 106.0 28.6 140.3 44.6 106 . 0 28.6 71.9 61.3 52.9 38.0 71.9 61 . 3 168.1 321.9 81.9 156.4 168.1 321 . 9 92.9 33.6 29.3 23.3 42.4 33.6 119.3 189.1 108.2 176.9 114.3 189.1 4.3 T972 3.8 ' 1876 9.3 19.2 5.3 116.8 ------- 22.2-- "T374-- 21.7 156.5 17.6-- 11. T~ 7.7 116.3. 17.3 31.3 5.3 21.7 154.1____ _____\ 1 fi. ,& ---- 14.4 . . ..2. j2-.t2-. 17.6 11.2" 592.0 411.4 542.0 411.4 .1 187.1 9.2 26.1 2.6 187.1 9.2 2.0 .5 2.0 7T 1.3 1.3 932.9 2,485.1 708.9 2,015.7 932.4 2,485.1 5,229.3 139.3 4,157.9 117.5 5,224.3 139.3 8879 3.4 82.1 3.5 88.4 3.4 16.6 25.8 1.6 18.1 16.6 25.8 SAL 000005396 REPORT NO. 08-0512 JOB NO 6658 PROGRAM NO. A7632 LAKE CHARLES REFINERY PROCESSING SUPPLIES - OTHER DETAIL - SCHEDULE C __________ (IN THOUSANDS? ___________________ PAGE 1 RUN DATE 01/29/8 ---------- MONTH ---------DECEMBER 1987 ITM--FTR-'--------- DESCRIPTION -------- QUANTITY DOLLARS PROFIT OBJ 1987 QUANTITY DOLLARS CUMUlATIv S TO DATE - ACTUAL 1987 ACTUAL 1986 QUANTITY DOLLARS QUANTITY DOLLARS -1987 CUMULATIVE ACT OVER(UNDER) i QUANTITY DOLLAR! PROC `5UPP-N0MCLASSIFIED 006 0136 METHANOL GALS 006 0387 MOLECULAR SEIVES LBS F5T"5554 MORPHOLINE LBS 006 0120 N-477 CATALYST LBS 006 0520 NALCO D5163 LBS 006 0519 NALCO 1700 006 0524 HALCO 1701 GALS 006 0669 NALCO 19 LBS 006 0193 NALCO 2RB431 LBS Q06 0264 NALCO 264 LBS 0 6T 0 2W NALCO 356 LBS 006 0280 NALCO 5163 GALS. 006 0231 NALCO 5166 LBS 006 0597 NALCO 5180 LBS 006 0493 NALCO 5196 006 0516 NALCO 5178........................ LBS 006 200 NALCO 5265 LBS 006 0353 NALCO 5553 LBS 006 0599 NALCO 5742 LBS 006 0507 NALCO 7200 IBS 006 0486 NALCO 8184 LBS 6 490 NALCO 8252 LBS J06 0265 NALCO 8263 LBS C06 0354 HALCO 85RB253 006 0616 NALCO 85RP124 LBS 006 0351 MAI CO 87RE010 LBS 006 0137 NITROGEN CU FT 006 0327 NITROGEN CYLINDERS 006 0685 OXYGEN LBS 006 0705 OXYGEN P/L FEE LBS 006 0013 PLATINUM TR 02 006 0303 POTASSIUM PERMANGANATE LBS 006 0652 PROX :SVERS LBS 006 0703 SHELL CATALYST HPS 544LBS .1 4.3 3.5 4.1 1.9 1.6 3.9 21.5 .8 44.6 .8 .1 3.3 5.1 7.1 2.2 4.1 4.8 13.9 1.8 86.9 31.3 4.3 6.8 22.3 8.3 9.6 .5 40.4 36.6 46. i 5.2 16.4 4.7 6.8 26.8 54.9 213.3 5.4 4.0 4.5 592.6 .1 13.9 7.9 4.5 1.8 19.1 16.0 10.7 .8 28.1 54.5 74.7 6.0 40.4 11.2 ITT2 1.4 29.2 66.0 "13?:5" 12.8 5.2 4.7 532.5 .3 530.2 51.3 38.4 13.1 9.1 1.2 ..... 48.1 6.6 12.4 1.9 ' " ~V 10.6 60.8 2 STB 13.3 14.8 3.2 2.1 54.8 .5 1.3 107.7 " .3 819.6 .1 20.9 1.1 1.2 . 6.8 1.8 74,5 22.3 19.1 377-------- 873 ' "is; 0 5.1 14.8 9.6 10.7 3.6 1.6 .5 ---------- 75 8.4 40.4 28.1 87.4 36.6 54.5 .2 48.7 79.7 5.2 6.0 33.4 16.4 40.4 21.4 ----------- 45-.775----- 11.2 --15 .T 4.6 1.4 26.8 29.2 2.8 65.2 54.9 66.0 .7 1 1.5 ; 5575 -------5T373--- n7;$ 5.4 . 12.8 3.2 4.0 5.2 ' 4.5 1 4.7 945.1 592.6 532.5 .2 .1 .3 895.5 51.3 13.9 ! 530.2 1 51.3 34.2 38.4 1.6 7.9 13.1 1.0 1 4.5 ___ 9-t4 m 0459 ToblUM HrPffCHmilT-------- T55 006 0050 SODIUM SULFITE - HYDRO LBS 006 0018 SODIUM-MONOSODIUM PHOS LBS 306 1118 SPTHOUDRY H2-1 FCC CATLBS nmnrsr SULPHUR >06 0022 SULPHUR DIOXIDE SAL 000005397 777777 . ^til; 19 i i' K 1 i V 1 l>\: !' , .i . i ' i. > EPORT NO. 08-0512 i- " LAKE CHARLES REFINERY OB NO 6658 RO<RAM NO. A7632 ' PROCESSING SUPPLIES1 - OTHER DETAIL - SCHEDULE C ! ......... -p j,- ----- * .... _________ (IN THOUSANDS 1___ .........." r ............. ........ ( r rDECEMBER 1987 PROFIT OBJ 1987 ACTUAL 1987 TH-FTR ---------- DfiSCBIPTIQN " wuwmi.iT uuimna QUANTITY.DOLLARS QUANTITY DOLLARS - " - \ PROC SUPP-NQNCLASSlPlED . Ii ''*'if < -'*j 06 0602 TRET-OaLITE !K437 1 !* GALS ! 06 0612 TpLT-PrLItE D$ 415 'GAL 5.3 5.5 45.1 ____________________________________ 1.4 _ 44.2 1.8 06 0613 iRET-O-LITE K450 06 1186 TRET-O-LITE AF-61 06 0617 TRETOLITE K-456 LBS GAL , 1 7.4 1.3 11.1 1.8 44.2 37.9 13.3 58.0 56.5 17.4 6 702 TRETOLITE DS 4056 ______ GAL. -- 2.8 2.6 30.0 25.9 6 704 TRETOLITE DS504 06 0712 TRETOLITE PET4000C ` 2.6 4.6 38.3 < 66.2 06 0718 TRETOLITE 4010 06 0046 TRIETHYLENEGl YCO! 06 0468 TYSOL WW50i GAL ' - 7.5 LBS -- 40.2 35.2 15.0 70.7 9.8 8.0 06 0469 UCARSOL-MDEA ' LBS 620.2 783.0 06 0471 UCARSON HS - 101 06 0106 VAN DRI-O-LITE , LBS LBS 44.0 51.0 44.0 .1 51.0 06 0123 ZEOLITE AMBERLITE 120 LBS 11.2 18.3 11.2 ------ ~YS73 TOTAL PROC SUPP-NONCLASSIFIED 1, 337.1 14,024.0 ACTUAL 1986 QUANTITY DOLLARS 5.5 4.3 98.5 3.3 .9- 6.4 47.8 51.1 149.2 23.4 .9- 12.1 29.2 15.0 1,139.0 1,447.7 .1- 13,101.2 PROC SUPP-CORR 1HH_(PR0C) 36 0485 BETZ 562 LBS 36 0601 TRET-O-LITE K-430- U GALS TOTAL PROC SUPP-CORR INH (PROC) 1.8 2.4 2.4 27.3 33.7 33.7 2.3 .1 24.0 24.2 TOTAL CLASSIFIED 2.4 33.7 2472 TOTAL PROCESSING SUPPLIES PER BBL_ CRUDE CHARGE 1, 339.6 2930 14,057.7 13,125.4 ,2*21 _______________ ,2468 . PAGE 13 RUN DATE 01/29/88 - L'iCf <*UnULA liVf ACT OVER(UNDER) PC QUANTITY DOLLARS 45.1 1 .4 44.2 37.9 13.3 30.0 44.2 1.8 58.0 56.5 17.4 ?5.9 38.3 40.2 35.2 15. 0 6 20.2 44.0 .1 11.2 66.2 70.7 9.8 8.6 783.0 51.0 1873 14,024.0 27.3 33.7 33.7 33.7 14,057.7 .2821 4> .. 00 > r- :1 o o o o o Ut I ` ' UJ o CD - S?;- r b . f i^ti I- h 589 10:42 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME03 - NET REFINERY BALANCE PAGE 11 mix "CHARGES' TrSiXF --------------- YTD 1987 INVENTORY AND R/S------------------ ---------- YTD 1987 PRODUCTION------------ OPENING CLOSING CHANGE PURCHASE SALE VOLUME VOL X"WEIGHT WT X LOADED --BBLS _ BBLS BBLS MBBLS_____MB ELLS_____ MBBJJMMLBSBBLS- RUDE OIL SWEET CRUDE I --------CONOCO PIPECITOF" DOMESTIC BRGE-RF TEXACO PlPELH-RF *G0N0EN3*f-R ------- CABIHDA-SWEET^ITF^ SUBTOTAL SWEET CRUDE SOUR CRUDE ^BCFI3 VENE2UE-RF T J PE5A00-RF , -WAYA MEXICAN-RF ~MEREY"VERE2UrRF GULF OF SUEZ-RF ORIENTE E4UAD-RF MENEM0TA _VENZ-RF H/StaKh PILON VENEZU-RF E. TEXAS SDUR-RF WYOMING SOUR-RF TRAQ Lk-RF i GEISUM EGYPT-RF SUBTOTAL'SOUR CRUDE i TAL CKUUE DTC "* ^293T. *""55236. 124005. 118502. 259235. 90967. 1838. 44150. 0. 0. 448009. 308879. -7671. -5503. -168268. 42312. 0. -139130. 6959.1 2218.1 5474.9 235.8 1781.3 16669.2 0.0 6966.8 13.4 0.0 2223.6 4.3 0.0 5643.2 10.9 0.0 193.5 -- 0.4 0.0 1781.3 - 3.4 0.0 ^680573 32.4 1998.7 643.4 1674.3 54.2 537.2 4907.9 12.3 4.0 10.3 0.3 3.3 30.2 "9. 0. 41560. 76914. 489ZI. 0. 0. 0. 0. 97283. 19511. 0. 0. 0. 284189. 73Z198. 0. TT------ 43575------- 13179. 13179. 2512.1 0. -41560. 14.1-r 245587. 168673. 11278.l\ 127034. ?8n37" 5128.3 \ 0. 0. -OUOV 0. 0. 394.7 4433. 4433. 720.8 `842437" 842437"*^192:3 65208. -32075. 6764.1 17244. -2267. 2717.5 0. 0. 379.8- 0. 0 * 881.9"=" 0. 0. 384.4- 556928. 272739. 33292.1 86580 f. "1336097""4998173 6.0 465.0 0.9 152.4 0.0 2498.9 4.8 848.9 0.0 55.6 0.1 19.3 0.0 11109.4, 21.4 3579.7 0.0 5048.2 9.7 1686.2 0.0 41.0 0.1 12.5 0.0 394.7 0.8 121.6 0.0 716.3 1.4 233.4 6.0 2108.6 4.1 659.2 0.0 6796.2 13.1 2324.6 0.0 2719.8 5.2 841.4 0.0 379.8 0.7 117.0 0.0 30179" 0.6 9475 0.0 0.7 127.1 0.0 63.6 10822.9 0.0 "4982777" 96,0 "T5731)78 0.9 5.2 0.1 22.0 10.4 0.1 0.7 1.4 4.0 14.3 5.2 0.7 6.4 0.8 66.5 967? 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. Q. 0. 0. 0. RUN STOCK NAPHTHA C/S-RF : DI5T.C/S-RF 3*460B1i r7r. ~ 18209. -15808. ZI5Z7"" -3865. TAL RERUN STOCK TXT CrtAKUfcS ` |--4---0--0--3--4--.---------772232. 20361. 886168. -19673. 1T3936. MM PRODUCTS MMMM 1861.0 18115 2042.4 52083.7 0.0 1876.8 o:tr 185.3" 3.6 074" 492.3 55.2 3.0 0.3" " 0.0 2062.1 4.0 547.5 3.4 0.0 "5188978"TTflO. 0^62787 3 16870 . 0. 0. Q. tr. NET OUTPUT -MBBLS-. 0.0 0.0 0.0 0.A 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 "9.6 0.0 0.0 </) > O o o o 0 \J\ 01 I NO NET REFINERY 6 eINE.. NCE i- PAGE 12 YTD 1987 INVENTORY AND R/S OPENING CLOSING CHANGE PURCHASE ^ i *..> BBLS \ BBLS BfckS_____ ^BB.LS. SALE _HBBLS_ --------- YTD 1987 PRODUCTION VOLUME VOL X HEIGHT WT X LOADED .MBBLSMMLBS____ ___BBLS. NAT GAS LIQUIDS REF PROPAN REF BUTANE "REF`I50BUTANE BUTANE-BUTYLENE REF ISOPENtANE DEN CASINGHEAD 1235.8 _r.260.8. -698.1 0.5 -101.2 2.4 :0.5_ 1.3 0.0 0.2 lO_jL 217.5 __r51 8. -137.5 0.1 -22.1 -66 1.3 :0._3. 0.8 0.0 0.1 JL_4_ TOTAL NAT GAS LIQUIDS 4116. 4637. 521. 1357.6 1242.7 -114.4 -0.2 -60.5 -0.4 0. MOTOR FUELS- ' -------FNSHD-REGULAR" REG GASOLINE LOCAL REGULAR SUBTOTAL FNSHD REGULAR 117321. 122605. 12372. > 33204. 129693. 155809. 5284. 20832. 26116. 0.0 4624.6 4629.9 8.9 1195.4 7.3 0.0 814.0 834.9 -- 1.6 217.7 -- 1.3 0.0 5438.7 5464.8 10.5 1413.1 8.7 0. 0. <u - FNSHD UNLEADED ' UNLD GASOLINE 86169. LOCAL UNLEADED 14374. "SlIBTjDTJn^FRSH^URUEADEIJ-------- 1005437 130197. 31194. 1613917 44028. 16820. "60848. 0.0 8317.8 8361.9 ' 16.1 2145.1 13.2 0.0 1331.0 1347.8<_ 2.6 348.4- 2.1 0.0 9648.8 9709.7 18.7 2493.5 15.3 0. 0. 0. FNSHD SUPR UNLO SUPR UNLEADED 112419. --------- ruCAC--5UPR~UNLD-------------------- 224777 SUBTOTAL FNSHD SUPR UNLD 134896. "363067 115826. -32899. *13829. -19070. 0.0 0.0 0.0 GASO. BASE STOCK " PRTO~GASOUTHE` 0. 0. 12975 , RASE ST RUN GASO 2066g 25241. 4576. 0.0 . DSR GASOLINE 993. 993. 0.0 BASE FCC GASO 26273 63642. 37369. 0.0 TTO- TS-r_T_T__E_F__O_RilllIATE- 57594 -------49787" -178077* "D :r ALKYLATE 23033 10057. -12976. 0.0 SUBTOTAL GASO 1 BASE STOCK. .137565 JM49720.-> v MOLEX GASOLINE , , SHEET NAPHTHA , SOUR NAPHTHA ` ii' J!. I 0 .-lii'- 0'.' i 27387 .1: 11080. ! 152574 96506. I 12155. I * 129.4 j \ \i i < > `t i . J o .. V 0. >423.3 -16307. o i>. 0.0 -56068. ' 0.0 1-----DRAGRED-NAPHTHA------ j---- "28365 :------- 12327 -2/133. 0.0 SUBTOTAL! NAPHTHA STOCKS 208326 108818. -99508. 423.3 TOTAL MOTOR FUELS 4614.6 603:*" 5218.4 < 4581.7 617.65199.3 8.8 r:r~ 10.0 0.0 "^12974-----"072 0.0 4.6 0.0 0.0 1.0 0.0 0.0 o:o 37.4 0.1 -1778 " 0.0 0.0 -13.0 0.0 i 0.0 J -117.2 -0.2 0.0 0.0 235.5 0.0 235.5 y. -423.3 -16.3 179.4 -2771 -287.3 -0.8 0.0 0.3 _ -0.1 -0.6 1207.6 7.4 161.7- "1.6 1369.4 8.4 0. 0. 0. -357*0 1.5 0.3 9.6 -5.0 -3.2 -31.8 "^*72-------- or 0.0 0. 0.0 0. 0.1 0. 0.0 ....0. 0.0 0. -0.2 0. -114.5 -4.2 47.1 -7.1 -78.8 -0.7 0.0 0.3 0.0 -0.5 0. 0. 0. 0. 0. NET OUTPUT J1BBLS_. 1235.8 ____ 6.9.. 0.0 0.5 0.0 _____ QiO 1243.2 4629.9 834.9 5464.8 8361.9 1347.8 9709.7 4581.7 617.6 5199.3 0.0 4.6 1.0 37.4 -17.8 -13.0 12.2 0.0 -16.3 179.4 ~-27;r 136.0 569 10:42 01/14/66 CONOCO INC.-LAKE CHAKIES REFINERY ME03 - NET REFINERY BALANCE PAGE 13 ------------- YTD 1967 INVENTORY AND R/S -................ - --------- YTD 1987 PRODUCTION------------ NET OPENING CLOSING CHANGE PURCHASE SALE VOLUME VOL X WEIGHT UT X LOADED OUTPUT BBLSBBLSBBLS_____MB BIS_____ MBBLS_____ MBBLSMMLBSBBLS_____ MBBLS IGHT FUEL OILS JET SO/KEROSENE JET 50 FUEL ------- tOCALMET 50 CONOCO LVT OIL MOLEX RAFFINATE KEROSENE SUBTOTAL JET"~507KERdS'EHE 63985. ____90554. 3537. 3256. 1721. 18573. 6208. 5885. 0. 0. 75451. rune. . 2656 9,___ 0.0 -281. 0.0 16652. 0.0 -323. 2559.9 0. 60.0 42817. 2619.9 4025.4 71.1 96.2 65.5 0.0 4278.3 . 4051 .J 70.8 113.1 -2474.6 -60.0 1701.2 7.8 0.1 0.2 -4.8 -0.1 3.3 1159.1_ 20.2 32.4 -705.8 -17.0 468.9 2T 0.1 0.2 -4.3 -0 . 1 3.0 2045*. 0. 1245. 0. o4 3290. 4051.9 70.8 113.1 85.2 0.0 4321.1 DIESEL t *2 FUEL FUNGIBLE DIESEL LOCAr'ROTZ'OIL VIRGIN DIESEL DISTILLATE BASE SUBTOTAL DIESEL 4 *2 FUEL 135863. 21462. 0. 205204. 362529. 157009. *24494. 0. 183886. 365389. 21146. 3032. 0. -21318. 2860. 0.0 1189.1 1210.2__ _2.3 362^6 0.0 16707.0 18710.0 36.1 5651.0 0.0 349.3 349.3 0.7 104.2 O.Q 0.0 -21.3 0.0 -6.6 0.0 20245.4 20246.2 39.0 _6jai._2 2.2 34.7 0.6 0.0 37.5 0. 1210.2 0. 18710.0 0. 349.3 0. -21.3 0. 20248.2 MOLEX FEEDSTOCK MOLEX FEED 0. 0. 0. 0.0 2105.4 2105.4 4.1 594.3 3.7 0. 2105.4 --BTYDUTEEDSTOCK LSR GASOLINE LT BLEND F/S HVY BLEND F/S ------ 5YFrr~C0RDENSATE'~ SUBTOTAL BAYOU FEEDSTOCK 0. 0. 56310. 17764. 74074. 0. 0. 0. "36700. 36700. 0. 0. -56310. 16936. -37374, 0.0 398.8 396.6 0.8 94.2 0.6 0.0 615.6 615.8 1.2 147.8 0.9 0.0 611.9 555.5 1.1 169.1 1.0 0.0 0.6 18.9 0.0 4.3 0.0 0.0 1626.5 1589.1 3.1 415.5 2.6 0. 398.8 0. 615.8 0. 555.5 0. 18.9 0. 1589.1 TAL LIGHT FUEL OILS \KS IN PROCESS ' " LT GAS OILS CUTTER STOCK --Fcc~crcrE*oit-- CRACKED DIST CYC HEATING OIL SUBTOTAL LT GAS OILS 512054. 69250. --27424'.' 156790. 0. 253464. 520357. 0. *1754. 6958. 0. 10712. 8303. 5> I -' - -69250. -25670. -147832. < 0. -242752. 2619.9 28255.5 25643.9 216.5 o:o" 0.0 0.0 216.5 2107.6' 0.0 0.0 104T/2211?7y 1821.9 -25.7 -147.8 104.1 1752.5 49.4 3.5 o.o -0.3 0.2 3.4 7609.9 487.0 -8.3 -45.7 33.3 466.3 46.7 5.0 -0.1 -0.3 0.2 2.9 3290. 28263.8 0. 2038.4 0. -25.7 0. -147.8 0. 104.1 0. 1968.9 HVY GAS OILS UAS UIL ------IIV COK GAS OIL -- SWyFCC^CHG^STK THERMAL CHARGE DESUL. SLURRY SUBTOTAL' HVY GAS OILS Trent? "240330 5463. 25966. 391944. ___ __ 0-^ -8-.-- ---- 341352. 221167. 103495. -136835. 16267. 10804. 0. -25966. 461114. 69170. fr.tr0.0 0.0 0.0 0.0 8.0 O.D -8.0 0.0 0.0 221.2 0.4 0.0 -136.8 ' 0.0 10.6 0.0 0.0 -26.0 -0.1 0.0 61.2 0.1 -2.5 72.7 =*3ro 4.1 -9.2 22.0 0.0 0.4 -0.3" 0.0 -0.1 0.1 0. 0.0 0. 221.2 0. -136.8 0. 10.8 0. -26.0 0. 69.2 SAL 000005401 0 5S9 JO-'*2 14/55 CONOCO INC.-LAKE CHARLE' "FINERY ME03 - NET REFINERY oaLANCE PAGE 14 YTD 1987 INVENTORY AND R/S - OPENING CLOSING CHANGE PURCHASE SALE __ _BBLS_ BBLS BBLS MBBLS MBBLS ----------YTD VOLUME MBBLS 1987 PRODUCTION VOL * WEIGHT MMl ns UT X LOADED RBLS NET OUTPUT MJtm s RESIDUUMS SLURRY OIL PURCH SLURRY ------KOCH SLURRY SOHIO SLURRY CHEVRON SLURRY CHAMPLIN SLURRY ------ ANODE* VAC" RES I IT PYRO TAR THERMAL TAR L S THERMAL TAR ------ r 5~THERMAC"TH6* VACUUM RESIDUUM HOT RESID SUBTOTAL RESIDUUMS 76555 ______ 0 0 0 0 0 IDS 3 3 35637 6996 0 ---------- 0 0 196680 528701 1180102.. 0. 0. 00.. 210346. 103961. 42398. 31162. 16303.. 283717. 791429. 41457. . . o0 .. 0. 0. 0. "487. 68324. 35402. 31162. 1833. 0. 65037. 262728. 40.7 120.8 172.3 565.2 60.1 238.9 1067.2 413.4 0.0 0.0 0.0 0.0 0.0 2698.7 3.6 0.0 0.0 0.0 0.0 0.0 300.7 0.0 0.0 0.0 0.0 253.0 0.0 557.5 4.6 -.120.6 -172.3 -565.2 -80.1 -238.-9__ -767.0 -345.1 35.4 31.2 1.8 253.0 85.0 -1878.4 0.0 -0.2 -0.3 -1.1 -0.2 -0.5 -1.5 -0.7 0.1 0.1 0.0 0.5 0.2 -3.6 5.4 -45.1 -65.9 -214.8 -29.4 -67.4 -266.1 -131.6 13.6 11.9 0.6 92.3 29.5 -687.0 0.0 -0.3 -0.4 -1.3 -0.2 -0*5 -1.6 -0.8 0.1 0.1 0.0 0.6 0.2 -4.2 00.. 00.. 00.. 0. 527206.. 0. 0. 0. 0. 52726. 45fi..2fi 0.0 0.0 0.0 0.0 300.2 68.3 35.4 31.2 1.8 253.0 4-85.0 820.2 SLOP OILS ARO DISTILLATE 0 LCCP RETURNS 0 ------ RERUN------------------------------------------- 12189 SLOP 18877 SABINE HAD 0 SUBTOTAL SLOP OILS 31066 00.. mo: 12162. 13052. 26344. 0. 0. -71859. -6715. 13052. -4722. 81.2 327.3 0.0 9.4 16.6 434.5 0.0 0.0 0.0 " 0.0 0.0 0.0 -81.2 -327.3 -11.1 -16.1 -3.6 -439.2 -0.2 -0.6 0.0 0.0 0.0 -0.8 -23.5 -101.1 -3.2 -4.7 -l.l -133.7 -0.1 -0,6 0.0 0.0 0.0 -0.8 0. 0. f0i..f0t 00.. 0. 0. -11.1 -6.7 13.1 -4.7 TOTAL STKS IN PROCESS 1205175 . 1289599. 84424. 3357.6 2769.2 -504.0 -1.0 -332.4 -2.0 52726. 2853.6 HEAVY FUEL OILS ------utrrrucco--------------- 2508' <1192r 39I8V7 0.0 81174 850.6 "1.6 31873 2.0 -----------r. 8387* 201 LCCHT POOL 5 --------- GRH~HI~5 FUEL-------- TONS 121315. , I21310T 1217T "07 0 870" 0.0 678 8. 121.3------- 202 BT - 1 SILOS POOL 2 --------- NORffAr-pREPlIUri----- TONS o; 2535. 2535. " 2.5 o;<r o:o~ *o:o -- -- O.O" ~078------- 275--------------- POOL 3 NORMAL RECARB TONS 0. 75. 75. 0.1 0.0 0.0 o.o 0.0 0.0 0. 0.1 TOTAL 202 BT - 1 SILOS 0. 2610. 2610. 2.6 0.0 0.0 0.0Q.Q n a_____________ ^ `589 10*42 01/14/85 CONOCO INC.-LAKE CHARLES REFINERY ME03 - NET REFINERY BALANCE PAGE 15 03 PORT OF 1C POOL 1 LOU S RECARB YTD 1987 INVENTORY AND R/S - ^ ^ ^ ^ ^ OPENING CLOSING CHANGE PURCHASE SALE BBLS BBLS BBLS MBBLS MBBLS ............YTD VOLUME MBBLS 1987 PRODUCTION VOL X UEIGHT MMLBS UT X LOADED .BBLS NET OUTPUT MBBI S TONS 0. 620. 620. 0.6 0.0 0.0 0.0 0.0 0.0 0 . 0.6 POOL 2 SUPER REG COKE TONS INTR GRAPHITE TONS NORMAL PREMIUMTONS^ SUBTOTAL POOL 2 0. 2576. 2576. 2.6 0.0 0.0 0.0 0.0 0.0 0. 6223. 6223. 6.2 0.0 0.0 0.0 0.0 0.0 b: 321. 321. 0.3 0.0 0.0 0.0 0.0 0.0 0. 9120. 9120. 9.1 0.0 0.0 0.0 0.0 0.0 0 . 2.6 0 . 6.2 0 . 0.3 0. 9.1 POOL 3 NORMAL kECArBTONS^ 0. ~?2srr 92SVT 4.3 0.0 0.0 0.0 0.0 0.0 0. 9.3 POOL 5 COKE FINES TONS 0. 233. 233. 0.0 0.0 0.2 0.0 0.5 0.0 0. 0.2 OTAL 203 PORT OF LC 0. 19242. 19242. 19.0 0.0 0.2 0.0 0.5 0.0 0. 19.2 04 REFINERY ------POOL~l CAL PREM COKE TONS 3749. 710. -3039. 0.0 43.5& 40.5 0.1 80.9 0.5 LS RECARB CK TONS 0. 0. 0/ 0.0 16.6 h 16.6 0.0 33.1 0.2 SUBTOTAL POOL 1 3749. 710. -3039. 0.0 60.0 57.0 0.1 114.0 0.7 0. 40.5 0 . 16.6 0. 57.0 POOL 2 CAL NOR PRM COKE TONS INTR GRAPHITE < TONS ~SUBTTJTA r~P 00 C""2 0. 715. 715. 0.0 4.3 ft 5.0 0.0 10.1 0.1 0. 0. 0. 0.0 1.0 0 1.0 0.0 2.0 0.0 o. 715. 0.0 5.4 ' 6.1 tf.o 12.1 o.i 0 . 5.0 0. 1.0 0. 6.1 POOL 3 ! NnwORmMinAbL RncEuCnARnoB TI OuNnSj s27/J5f7. w0. `-"2t7u5i7..*: w0.w0 C21l..g6 V l1O8..9f U0..W0 ------ CCH"AN0DE----TONS --""71*;-------------- 0^--------- =71T7;--------- O.'fl---------- 54.5 7*-------53 ."8---------Oil CAL FUEL COKE TONS 0. 0. 0.:' 0.0 11.1f 11.1 0.0 SUBTOTAL POOL 3 L 3473. 0. -3473.0.0 *i 87.3 83.8 0.2 ootrv GREEN PREM COKE TONS 1. CRN NORM PREM CK TONS 0. GRN LS RECARB rY TONfr ------ GRtmORM-RECARB--TONS-- -----------oi-- GRN INTR GRAPH TONS 1. GREEN LCH ANODE TONS 4458. GRN PUR ANODE TONS 0. suoTor*irpooc"4------------------------ 4460. 3100. 822. t. ' 3190. 1. 14867. 0. 21981'. 3099. 822. 1. 3190. 0. 10409. 0. I752H------ 0.0 Q--Q -____ 0.0 0*4------ 0.0 0.0 o:o 0.0 0.0 0.0. 0.0 25.2 7.0 0.0 7.0 ' - 25.2 3.1 0.0 Ovfr------- 0.0 - 0.0 0.0 3:?~ 0.0 0.0 0.0 35.6 0.1 -7.0 0.0 35.8------- 0.1 J3/7.O.8 0.2 W0.. 107.6------- 0.7------------- 0T 22.2 0.1 0. 167.6 1.0 0. 108.79 53.8 11.1 83.8 6.2 0.0 6.4~ 0.0 71.2 -14.1 7113 0.0 (T.O 0.0 o:o_ 0.0 0.4 -0.1 0.4 ____ 0. 0.8 0. o: ' ' "30..02 0000.... ~ 0.0 305.. 60 42.7 SAL 0000054-03 0589 1 C 01/14/88 CONOCO INC.-LAKE CHARLE*. FINERY ME03 - NET REFINERY BALANCE PAGE 16 POOL 5 GRN HI S FUEL COKE FINES '5UBT0TALP00L 5 TONS TONS TOTAL 204 REFINERY 205~~HOODCHIP--PAD POOL 5 GRN HI S FUEL TONS 206 TRANSPORT POOL I X COKE poor-? NORMAL PREMIUM TONS TONS TOTAL 206 TRANSPORT 207 PORT ART TML POOL 5 GRN HI S FUEL TONS SULFUR PRODUCTS SULFUR SULFUR-TONS 5UCFUR-AS~H25 SUBTOTAL SULFUR TONS TONS FINISHED ACID o* ACID 100X ACID CONSUMED 100X SUBTOTAL FINISHED ACID SrtNT ACID AK SPT ACID 100X TOTAL SULFUR PRODUCTS -............- YTD 1987 INVENTORY AND R/S----------------- ---------- YTD 1987 PRODUCTION------------ NET OPENING CLOSING CHANGE PURCHASE SALE VOLUME VOL X WEIGHT UT X LOADED OUTPUT _BBLS_____ BBLSBBLS____ _MBBLS______MBBLSPIBBLSMBLBSBBLS_____ J1BBLS__ 4365. 0. 4365. 16047. 5323. 0. 5323. 26729. 958. 0. 958. 12682. 0.0 786.6 P 787.6 1.5 1575.2 9.7 0.0 0.4 Y 0.4 0*0 0.9 0.0 0.0 787.1 788.0 1.5 1576.1 9.7 7.0 964.9 970.5 1.9 1941.1 11.9 0. 767.6 0. 0.4 0. 788.0 0. 977.6 0. 13335. 13335. 0.0 0.0 13.3 0.0 26.7 0.2 0. 13.3 0. 3352. 3352. 0.0 0.0 3.4 0.0 6.7 0.0 0. 1324. 1324. 1.0 0.0 0.4 0.0 0.7 0.0 0. 4676. 4676. 1.0 0.0 3.7 0.0 7,4 0.0 0. 3.4 0. 1.3 0. 4.7 0. 12654. 12654. 919. &. 919. I/5/ . 0. 1767. 1378. 4064. 723. 0. 723. -196. 9. -196. > 3161 ~1374~: 0. 0. 3161. 1374. 1289. 5173. -89. 1089. 0.0 0.0 12.7 0.0 25.3 0.2 0. V 0.0 v7-9, 78.9 0.2 157.8 1.0 0.0 2572^ 2372 o:r~ 46747" 0.3 0.0 102.3' 102.1 0.2 204.2 1.3 173. O. 173. 3.7 3.6 1.4 0.0 0.0 0.4 0.4 0.0 3.7 4.0 /, 1.7 0.0 0.0 . --^, 0.0 0. 0.0 0. 0.0 13.1 13.0 0.0 26.1 0.2 3.7 119.4 116.9 0.2 233.7 1.4 0. 173. 12.7 78.9 23.2 102.1 5.0 0.4 5.4 13.0 --_____ XT > O o o --------- O------------------o \x> ** -------- o ---------- _ -- r 05 0589 10^42 01/14/00 CONOCO INC.-LAKE CLARIES REFINERY ME03 - NET REFINERY BALANCE PAGE 17 --------------- YTD 1987 INVENTORY AND R/S------------------- ---------- YTD 1907 PRODUCTION OPENING CLOSING CHANGE PURCHASE SALE VOLUME VOL X WEIGHT WT X LOADED BBL5 8BL5 _ _ BBLS_______ MBBLS_____MBBLS_____ HBB.ISMULES_____ ___ BBL5_ NET OUTPUT J1BBLS__ t HYDROGEN VISTA EXCHANGE 1 VISTA IMPORT H2 FOE FUEL TO VI5T/T" FOE SUBTOTAL VISTA EXCHANGE 0. 0. 0. 592.0 0.0 _ "592 J) -1.1 -97.5 -0.6 0. 0.0 0. 0. 0. 0.0 973.8 973.8 1.9 277.0 1.7 0. 973.8 0. 0. 0. 592.0 973.8 381.8 0.7 179.4 1.1 0. 973.8 ! HYDROGEN , _ --------- CITIES H2----------------- FOE-------- JUPITER HYDROGEN FOE SUBTOTAL HYDROGEN - TOTAr^HYDROGEN \ MISCELLANEOUS 1 CIT CON EXCHANGE "TOPPED CRUDE------------------------- I 1 CC GAS OIL } . CC FURFURAL EXT CC INTERNED EXT - ---------CDKETf"NAPHTHA----------------------- CC BR.STK. EXT CC RESIDUUM 1 SUBTOTAL CIT CON EXCHANGE 0. -------------ff. 0. 0. 0. 0. - 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0.0 567.1 567.1 1.1 0. 364.5 0.0 -364.5 -0.7 0. 364.5 567.1 202.7 0.4 0. '956:5" ~1540.9 58470"* 1.1 108.2 -38.6 69.7 249.1 0.7 -0.2 0.4 1.5 0. 0.0 199170"' 390170 7.7 1282.8 7.9 0. 781.6 0.0 -781.6 -1.5 -235.6 -1.4 0. 781.8 0.0 -781.8 -1.5 -261.0 -1.6 0. 190.5 0.0 -190.5 -0.4 -63.7 -0.4 0. 241: 7 236.2 -5.5 0.0 0.0 0.0 0. 262.1 0.0 -262.1 -0.5 -93.6 -0.6 0. 697.5 0.0 -697.5 -1.3 -238.1 -1.5 0. 2955.3 4227.2 1271.9 2.5 390.8 2.4 0. 567.1 0. 0.0 0. 567.1 0. 1540.9 0. 3991.0 0. 0.0 0. 0.0 0. 0.0 0. 236.2 0. 0.0 0. 0.0 0. 4227.2 ' FUEL PRODUCTION GULIS FUEL FOE ti FUEL CONSUMED FOE UHRES FUEmoSS FOE 5- SUBTOTAL FUEL PRODUCTION LOSSES * ' 5` ------------REF~PROCtOSS-- SULFUR PROC LOSS TONS COKE MOISTURE TONS COKE CONSUMED TONS TOTAC-FCARE" FOE UNRES CHG LOSS UNRES PROD LOSS ATMOSPHERE LOSS -ywnTQTor i imn 0. 0. 0. 0. 0. 0. 0. 0. u. ........ 0. 0. 0. 0. 0. 0. .. 00.: . 0. 0. 0. 0. 952.8 0.0 0.0 952.8 0.0 2785.7 0.0" 2785.7 -952.8 2785.7 2679 1859.9 -1.8 5.4 0.1 3.6 070 ` 0.0 0.0 o:o~"179179" 3.5 0.0 -10.3 0.0 0.0 -60.2 -0.1 -260.4 753.8 7.9 501.3 336:8 -20.6 -120.4 -1.6 4.6 0.0 3.1 2.r -0.1 -0.7 0. 0.0 0. 2785.7 0. 26.9 0. 2812.7 " 0. 0. 0. 1791.9 -10.3 -60.2 TOTAL MISCELLANEOUS 3908.1 7013.0 4342.5 8.4 1093.5 6.7 0. 8250.7 TGTTrtrTRODUCTS------------------------ "2455007"2755578 "1290679 6325873--5188977" 18070--1627872--10070 56189: 64796.6 ^coprocessing supplies#** SAL 0000054-05 03&9 lQUi. 1/14/88 CONOCO INC.-LAKE CHAR REFINERr ME03 - NET REFINERY BALANCE PAGE 18 YTD 1987 INVENTORY AND R/5---------------- OPENING CLOSING CHANCE PURCHASE SALE BBLS BBLS BBLS MBBLS MBBLS ----------YTD 1987 PRODUCTION------------ VOLUME VOL X WEIGHT UT % LOADED MBBLS MMLBS ___ BBLS NET OUTPUT MBBLS MISCELLANEOUS PROC. SUPPLIES TEL " MMT LBS LBS <(0000 . 16240. 68880. 36375. 28880. 20135. 168.9 163.0 0.0 140.0 0.3 0.0 142.8 0.3 0.1 ___ 0.0 0.1 0.0 0^_ 0. ILL 0.0 TOTAL MISCELLANEOUS 56240. 105255. 49015. 331.8 0.0 282.8 0.5 0.3 0.0 0. 0,0 VOLUME UNIT5~0F~MEA5UKEMENTT---------------------------- BARREL FUEL OIL EQUIVALENT(BFQE) FOE EQUIVALENT LIQUID BARRELS ELB SHORT TONS TONS ~7UNS'1003rsULFURIC"A;CIIJ----------------------- 1003c' GALLONS CALS POUNDS LBS THOUSANDS OF POUNDS________________ MLBS :? OO059O 10*td 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 ~ MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 30 **** UNIT 03 - no: 3 CTU`* VAC `HAS BEEN "ON STREAM 31]O DAYS IN DECEMBER AND 365.00 DAYS TO DATE THIS YEAR ** 22 STREAM----------kmk CHARGES **** ------------ DECEMBER -------------- ------------------ YEAR TO DATE------------------- . VOLUME ________ WEIGHTVOLUMEWEIGHT___ BBLS PCT MLBS PCT MBBLS PCT MMLBS PCT TEXACO PIPELINE CONDENSATE CABINDA-SWEET DOMESTIC BARGE ALASKAN N/SLPE F-10 E.TEXAS SOUR WYOMING SOUR IRAR LR GEISUMTEGYPTJ------BACHAQUERO 13 MEREY GULF OF SUEZ ----------- ORIENTE~EQUAD0R MENEMOTA VENEZ T J PESADO PILON FTATA NAPHTHA C/STOCK DIST. C/STOCK SLOP 5ABINE~HRD RECYCLE NAPHTHA NO. 2 NAPHTHA MOLEX GASOLINE SEAL-OICTLUSH 14/15 HDS GASO 5627. 0.2 0. 0.0 0. 0.0 0. 0.0 572136. 16.0 25804. 0.7 239969. 6.7 0. 0.0 263009. 7.4 37334. 1.6 168443. 4.7 431651. 0. 12.1 0.0 0. 0.0 269690. 7.5 0. 0.0 331450. 9.3 833139. "23.3 99994. 2.8 27156. 0.8 62149. 1.7 " 5196.' 0.1 30071. 0.8 48493. 1.4 0. 0.0 *5547'. ~ i:8 39593. 1.1 1626._ 0. 0. 0. 179055. 8492. 74238. 0. 87066. 18456. 58012. 144534. 0. 6. 87957. 0. 113261. 268125. 26225. 7973. 17035. 1633,. 8056. 12952. 0. 20991. 9205. 0.1 0.0 0.0 0.0 15*6 0.7 6.5 0.0 7.6 1.7 5.1 12.6 0.0 6.6 7.7 0.0 9.9 23.4 2.3 0.7 1.5 0.1 0.7 1.1 0.0 1.8 0.8 173.5 121.4 1775.0 39.1 2061.6 465.0 2719.4 379.8 301.9 384.4 2499.1 5047.4 41.0 394.7 716.2 55.6 6796.8 11110.3 1876.7 185.3 .393.9 .5 72 298.2 938.7 6.8 >68.4 400.0 0.4 0.3 4.4 0.1 5.2 1.2 6.8 1.0 0.8 1.0 6.3 12.6 0.1 1.0 1.8 0.1 17.0 27.8 4.7 0.5 1.0 0.0 0.7 2.3 0.0 1.9 1.0 50.0 33.3 537.3 11.4 642.8 152.9 842.7 122.5 100.0 126.9 1861.1 1695.0 12.5 123.3 233.9 19.3 2327.9 3582.5 487.4 54.5 107.5 1.6 79.4 251.2 1.8 246.8 93.4 0.4 0.3 4.2 0.1 -5.0 1.2 6.6 1.0 0.8 1.0 6.7 13.2 0.1 1.0 1.8 0.2 18.2 28.0 3.8 0.4 0.8 0.0 0.6 2.0 0.0 1.9 0.7 TOTAL 3576451. KKMM YIELDS MMMK 100.0 1145388. 100.0 39955.4 1QQ.Q 12799.0 100.0 STAB OH GAS "STAB'OH'LIQ-------STAB LSR NAPHTHA RECYCLE NAPHTHA KER05I iEl GAS OIL SEAL OIL FLUSH CVGO---------------------HVGO VACUUM RESID SLOP ELB 33940 38784 207382 190282 30071 397775. 82552. 164301. ' 414072. 441093. 1193920. 4577. 0.9 1.1 5.8 5.3 11.1 2.3 4.6 1i . 6 12.3 33.4 0.1 6870 8180 51433 50723 tt- 121033. 26016. 52596. 132646. 145761. 428878. 1240. 0.6 10.6 2.3 4.6 11.6 12.7 37.4 0.1 267.6 459.0 1993.7 3733_,& z$8.2 3255.3 4478.7 1479.9 1862.1 3860;i 4891.3 13626.0 37.7 11.2 3.7 4.7 977 12.2 34.1 0.1 1350.6 463.0 598.3 ----- 1239 75 1618.1 4955.2 10.3 10.6 3.6 4.7 9:7 12.6 38.7 0.1 SAL 000005407 LOSS -53861. TOTAL 3576451. -1.5 100.0 -11577. 1145388. -1.0 100.0 -287.9 39955.4 -0.7 100.0 -77.1 12799.0 -0.6 100.0 %; ,y?^yp j|if |r '** ].......".i L, `I'l -f-- 0590* X0 43 '' 01'/1 i/i8 ; i* ; CONOCO4INC L*AKE CHARLES REFINERY -r **** UNIT 10 - NO. ME05 - MONTH END AND YEAfJ TO DATE' FINAL UNIT YIELD REPORT 4 HDS 1 HAS BEEN ON STREAM 31^0 DAYS IN :',*/ i : DECEMBER AND 365.00 PAGE 31 DAYS TO DATE THIS YEAR *** ' STREAM XMMK CHARGES MKMX VOLUME BBLS PCT ' _ WEIGHT MLBS PCT ' '' _ VOLUME MBBLS PCT WEIGHT MMLBS PCT HPU HYDROGEN FOE 5 HDS STRIP `OH 15 HDS SEP H2-*- FOE H2 #1 2 t HPU FOE 3 CTU KEROSENE ~ 13 CTU DIESEL CYC OIL FM STGE-. SOUR NAPHTHA* CRACKED NAPHTHA , NO. 6"HD5GAStfCI MOLEX GASOLINE i 19342. '27524. 49015. / r 14001. 148485. 397?75. .M15X93Q7.. 223719. 94641. 0. 1.7 2.4 4.4 1.2 13.2 35.3 13.5 0.0 19.9 6.4 0.0 3153^ 4951. ' 9657. 2181. 42598 121033. 49066. f 0. 60677. 25406. 0. 1.0 2.2 3.0 0.7 13.3 37.7 15.3 0.0 18.9 7.9 0.0 160.4 . 318.0 578.2 132.8 15341_ 4478.7 2102.5 158.2 1522.5 654.8 10.1 __1,4_ 2.7 5.0 1.1 13*2_ 38.4 18.0 1.4 13,1 5.6 0.1 23.8 79.5 104.7 20.1 438.6 1350.6 679.6 42.3 408.6 176.9 * 2.7 0.7 2.4 3.1 0.6 13.2 40.6 20.4 1.3 12.3 5.3 0.1 MXMM YIELDS MXNK TOTAL 1125839. 100.0 32012^ 100.0 11650_*_1_ 10Q_i_0 3.327^5...I00.J) r STR REFLUX 85HDS 2752. ------ (""CRACKED GASOLINE^----------------- 39593. r fi2S RECOVERED FOE 2949. H2 TO 85 HDS FOE' 52946. STRP OH GAS ELB PURGE" 65"T0`GRP' FOE .. 16-8580 . DES DISTILLATE 840184. DES KEROSENE 0. DES NAPHTHA 160112. 0.2 ' 515 0.3 4.7 1.5 `0.6 74.6 0.0 14.2 626. 9205. 2610. 10424. 6033. ' 0. 255911. 0. 41905. 0.2 2.9 0.8 3.3 1.9 6.0 79.8 0.0 13.1 60.3 396.8 51.4 644.5 198.2 0.5 7296.0 1236.8 1649.1 0.5 3.4 0.4 5.5 1.7 0.0 62.6 10.6 14.2 13.7 92.6 45.5 120.0 70.1 0.1 2221.1 355.6 436.2 0.4 2.8 1.4 3.6 2.1 0.0 66.7 10.7 13.1 LOSS 10445. 0.9 -5993. -1.9 116.5 1.0 -27.4 -0.8 TOTAL 1125839. 100.0 320722. 100.0 11650.1 100.0 3327.5 100.0 CO > o o o o o US o CD in59Q 10:43 ul/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 32 xxktt UNIT' 14'"-_N0. 5 HDS HA$~BEEN ON TTREjufirTrDAYS~IN DECEMBER AND 394.08 DAYS TO DATE THIS YEAR nkmk ---------------- DECEMBER -------------- ------ -- YEAR TO DATE ------------------ STREAM **** CHARGES *** BBLS PCT MLBS PCT MB8LS PCT MMLBS PCT *3 CTU GAS OIL LT VAC GAS OIL HV VAC GAS OIL H2 FM 14 HDS FOE STR REFLUX FM #4 82552. 414072. 0. 52946. 2752. 14.9 75.0 0.0 9.6 0.5 26016_ 132646. 0. 10424. 6.26_1_ 15.3 78.2 0.0 6.1 0.4 1384.7 3599.3 166.0 644.5 60.3 .23.7 61.5 2.8 11.0 1.0 434.0_ 1157.4 52.9 120.0 13.7 24.4 65.1 3.0 6.6 0.8 XMXX YIELDS MXMK TOTAL 552322. 100.0 169713. 100.0 5854.8 100.0 J 1776.0 100.0 STP OVHD TO 4 HYDR SULFIDE SWEET SEP HYD DE5 GA5 On FOE FOE 27524. 3445. 49015. 489716. S.O 0.6 8.9 88.7 6951. 3050. 9657. 154473. 4.1 1.8 5,7 91.0 318.0 26.9 578.2 4931.0 5.4 0.5 9.9 84.2 79.5 23.9 104.7 1547.2 4.5 1.3 5.9 67.0 (Si 1 LOSS -17378. -3.1 -4418. 1 0.7 0.0 22.8 1.3 | 1 TOTAL 552322. ioo.o 169713. 100.0 5854.8 100.0 1778.0 100. Q x*x UNIT 82 - NO. 3 CRU A HDS HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 314.89 DAYS TO DATE THIS YEAR xxxx STREAM xxxx CHARGES **** DECEMBER VOLUME HEIGHT BBLS PCT MLBS PCT VOLUME MBBLS PCT i. TO DATE -- WEIGHT MML6S PCT NAPHTHA 2 NHDS NAPHTHA KKXX YIELDS XX*K IOTAL 346801. 100.0 0. 0.0 346801. unno > 91009. 0. 91009. 100.0 0.0 100.0 3603.9 99.9 4.6 0.1 % I* 3608.610070 * 947.4 1.2 9*8.6 99.9 0.1 100.0 "ABSORBER"NZ------------ FOE' HYD TO FUEL FOE 13 STRIP OH LIQ STRIP/STAB OFF G ELB 13 DEPRQP_71H~IIC~^= REFORMATE 31189.-------- 9.0 0. 0.0 27591. 8.0 1Q53S. 3.0 *o: = 284070. 81.9 LOSS -6594. -1.9 TOTAL 346801. 100.0 DECEMBER ENDING VALUES "REFORMATE-RDNC '99740 4657: ' 0. 5192. 2387. 5.3 0.0 5.7 2.6 79677. 87.5 -1107. -1.2 91009. 100.0 454.01276 ~------- 697ST' 0.6 0.0 0.1 125.3 3.5 23.6 78.1_ 2.-2 2.4 --on~ tr.y- 2888.1 80.0 813.1 9.4 0.0 2.5 o ;o 85.7 60.0 1.7^ 4.9 0.5 3608.6 100.0 948.6 100.0 SAL 0000054-09 0590 10:43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT #*** UNIT 38 "r REGULAR COKER HAS BEEN ON STREAM 0.0 DAYS IN DECEMBER AND PAGE 33 77.88 DAYS TO DATE THIS YEAR nnkn STREAM KXXX CHARGES K MX X DECEMBER VOLUME BBLS PCT MLBS PCT MBBLS YEAR TO DATE PCT MMLBS PCT CC BRIGHT STOCK CC INT.EXT. CC RESIDUUM CC FUR EXT THERMAL TAR 11HCG0 ANODE VAC RES FCC CYLCE OIL COKER NAPHTHA SUT'FCC* CHG 5TK PYRO TAR KKKK YIELDS KKKK TOTAL 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 0.0 .0 0.0 .0 0.0 .0 0.0 .0 0.0 0. 100.0 0. 0.0 0. 0.0 0. 0.0 0. 0.0 .0. 0.0 0 0.0 0. 0.0 0. 0.0 .0. 0.0 0 0.0 0. 0.0 .0 10Q.0 420.. 2_ 4.3 559.3 2.2 12.5 0.3 40.7 0.6 47.8 6.4 3.8 38.3 0.4 50.9 0.2 1.1 0-9 . 3.7 0.1 4.4 0.6 0.3 1098.3 100,0____ 148.5 1.4 189.8 0.7 4.5 0.1 14.6 0.3 14.9 2.0 1.4 378.2 39*3 0.4 50.2 0.2 1.2 0.0 3.9 0.1 3.9 0.5 0.4 100.0 COKER GAS ElB Khli CUKfcR UASU LTE C0K GAS OIL HVY C0K GAS OIL ANODE COKE TONS INIKHtUJA 1fc CUKb IONS LOSS -------TOTAL .0. 0.0 0 0.0 0. 0.0 0. 0.0 .0 0.0 .0 0.0 0. 0.0 0. ioir;ir-- .0. 0.0 0 0.0 0. 0.0 0. 0.0 0. 0.0 0. fc.ti 0. 0.0 0. "itfrnr- 161.9 142.6 440.4 223.1 45.5 0.2 64.7 109&.3 16.6 13.0 40.1 20.3 4.1 0.0 5.9 100.0 41.1, 37.1 135.4 75.9 91.9 0.5 10.9 9.8 35.8 20.1 24.3 0.1 -3.6 -1.0 575.2 "15675 cn > o o o _r < o n~ 590 13:43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 34 xxxx UNIT 39 - PREMIUM COKER HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 263.11 DAYS TO DATE THIS YEAR mmxk ............... . STREAM xxxx CHARGES xxxx DECEMBER VOLUME WEIGHT BBLS PCT MLBS PCT TL^K VOLUME MBBLS PCT WEIGHT MMLBS PCT ANODE VAC RESID FCC SLURRY CC RESIDUUM CC BRIGHT STOCK THERMAL TAR PYRO'TAR-- FCC LCO 44. 0. 1434 . 1561. 243873. 0, 25470. 0.0 0.0 0.5 0.6 *9.5 0.0 9.4 17*_ 0. 534. 608. 93322. 0. 8255. 0.0 0.0 0.5 0.6 90.8 0.0 8.0 0.5 2.5 16.5 13.9 .I*?** 5_ 133.7 145.8 0.4.0- 0.1 0.7 0.6 85.8 6.1 6.6 0.2 0.9 6.0 5.3 721.8 50.9 47.3 0.0 0.1 0.7 0.6 AA 7 6.1 5.7 xxxx YIELDS xxxx TOTAL 272382. 100.0 102736. 100.0 2206,4 100,0 832.5 100.0 COKER GAS ELB GASOLINE LCGO HCGO PREMIUM COKE TON5 NORMAL PREM CDKE"T0N5 INTRMEDIATE COKE TONS LS RECARB COKE TONS RECARB COKE TONS 34808. 1352. 75269. 99158. 10952. 5454. 0. 0, 1090. 12.8 0.5 27.6 36.4 4.0 2. ff 0.0 0.0 0.4 9046. 355. 25906. 38043. 21904. 10908. 0. 0. 2180. 8.8 0.3 25.2 37.0 21.3 10.6 0.0 0.0 2.1 333j.J_ 23.6 628.1 823.1 68.9 5.5 3.4 17.9 19.5 15.1 1.1 28.5 37.3 3.1 0.2 0.2 0.8 0.9 61.6 6.3 215.1 314.7 137.8 10.9 6.6 35.9 39.1 9.* 0.* 25.* 37.8 16.6 1.3 0.8 4.3 4.7 LOSS TOTAL 44319. 272382. 16.3 100.0 -5606. 102736. -5.5 100.0 282.4 2206.4 12.8 100.0 -15.6 *32.5 -1.9 100.0 t/> -- r* o o o-- o o * H- .f i. Mi L, > 'Ei- [ CmM CnM OiNn V nN>o HA^<0'<f rw< <r Nr#-tOI KO|M >esjr.a|*o cm r-* *-* oaia a jgfgrv-s- -- -.'.J U.-V4-4 >- --;;-~ .t of ' in cm iCnMPnvJ to <0 h m(e m > rJm oi*r m r n,o N en NO> r* on>o H I (CM UoJf Alfl(A fJrCNJ' boooo UJ AN <TM Of < UJ o UJ IOf Of U3JA uj ia **CM !* CM oeeee 0 CM lACM hr 1*0 AN a too Of -f o UJ UJ >- o UJ >UJ oa oo o za z UJ < oz uI t-- z OUJf I ZIf* u in t--i a r< UJ !o SI Ui i -<! 1 o' i >y> ( L_i ri a MI M F:CM i |1 nj-CMO oe am axe iflkriirt ui Ui A o ,Lo ITIC3 ore rAIT* CAMI ooeeo <A|ooeee mr>o. -mr* *tComM* o 0 r 1. fT WO p a a a a aa bI (A in o o zzzzzz h- zzzzzz oooooo oooooo -- l-l- w Mj X E X [ *f if X uiui o o a X MX Of ooxua -< C*c * UJ JJ UJ if UI UJif Lf ^ o Sf r Ui S:uj c o ouo.au u < O < LLl ESC KZU X x: o d o o Ui o o uuou Do Of Uj a UJUJ O X UI M E xiu<e ae*t oc. a of Uj rwLDua: t- x au Q-B-l--X ' xoa 3 M IUOCXOUJ< >- Of Q_bf Z Of o ZZut^-l z X UJ Q. P<C UJ X E~ E CM X ujzzzz z -JOfHXCM X CCMOCMOOfOOfOOfIOf X * o z o o a OZh-iX-< 5 SAL 000005412 0590 10 5 A 3 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 36 xxxx UNIT 56 - Nor 2 CALCINER HAS BEEN ON STREAM 0.0 DAYS IN DECEMBER AND 17*.27 DAYS TO DATE THIS YEAR xxxx ' "STREAM ' xxxx CHARGES **XX DECEMBER VOLUME BBLS PCT MLBS PCT MBBLS YEAR TO DATE PCT MMLBS PCT GREEN PREM COKE TONS GRN LS RECARB CK TONS GRN RECARB COKE TONS GRN INT GRAPH CK TONS GRN LCH ANODE TONS TOTAL XXXX YIELDS XXXX 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 100.0 0. 0,Q 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 100.0 30.,$u_ 16.* 15.0 6.7 47,3 .26.i 2___ 14.3 13.0 5.ft 40.ft 116.0 100.0 60.8 33.1 30.1 13.4 94.6 232.0 26.2 14.3 13.0 5.ft 40.ft 100.0 CAL PREM COKE TONS LS RECARB COKE TONS NORM RECARB COKE TONS INT' GRAPH"COKE "TONS LCH ANODE COKE TONS COKE BURNED TONS "TOSS TOTAL 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 0.0 0 . O.Q 0. 100.0 0. 0.0 0. 0.0 0. 0.0 b. 0.0 0. 0.0 0. 0.0 0. 0.0 0. 100.0 24.5 13.3 12.1 5.4 3ft. 4 22.3 b.O 116.0 21.1 11.5 10.4 4.7 33.1 19.2 0.0 100.0 49.0 26.7 24.1 10.8 76.ft 44.6 0.0 232.0 21.1 11.5 10.4 4.7 33.1 19.2 0.0 100.0 Tr*xjrUMrr27^ PT'ARTHUR"CAICIN~ HAS' BEEH"`0N~5TREAM 0DUAY5TN' DECEMBER AND 2973rTT/fi'3Ttf_MTiriHTS-YEAR~HNXr 5TREAM xxxx CHARGES xxxx DECEMBER -------------- ------------------ YEAR TO DATE------------ VOLUME ______ HEIGHT ________ VOLUME _________ HEIGHT BBLS PCT------- , mBs "PCT------- ----- MBBLS' PCT-------- MMLBS PCT---------------------------------------- GREEN PREM COKE TONS "GRN'RECARB COKE TONS GRN LCH ANODE TONS GRN HI S FUEL CK TONS xxx* YIELDS xxx* 1 U 1 AL 0. 0.0 0. ' 0.0 0. 0.0 0. 0.0 0." 100.0 0. 0.0 0. " 0.0" 0. 0.0 0. 0.0 0. 100.0 " 9.9 0.6 15.2 17.4 23.0 r.3 35.3 40.4 4371 10070 19.ft "" 30.4 34.6 23.0 1.3 35.3 40.4 *.r' 100.0" ---- u Al'IkbrrccK^ "TONS------- NORM RECARB COKE TONS LCH ANODE COKE TONS HI- S FUEL COKE TONS CUft.lL UUKHtU i uHs> LOSS "TOTAC S*L 000005413 o: --- 0". 0 -- 0. 0.0 0. 0.0 0. 0.0 0. - O.o 0 . 0.0 u. 10OTD 0. r.u 0. 0.0 0. 0.0 0. 0.0 0. 0.0 ' 0. 0.0 u. tooth 671------- T47T 1.0 2.2 10.4 . 24.2 12.5s' 29.0 1571"- jorr 0.07 0.0 J' i* - ;< 431 , lOOTTT 12.2 --1471-------1.9 2.2 20.9 24,2 25.0 29.0 26 rz . 30.4 0.0 0.0 ""867T~TOOTH-------- \[ v MK Ilf 0590 10:43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY < ! \ ME05 ~ MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT xxxx UNIT 79 - NO. "2 COKER' HAS' BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 365.00 DAYS TO DATE THIS YEAR **** -----------STREAM-~-- xxxx CHARGES xxxx ------------- DECEMBER -------------- -------------------YEAR TO DATE-------- ----------- VOLUMEWEIGHTYOLUMEWEUSRI_____ B8L5 PCT MLBS PCT MBBLS PCT MMLBS PCT 16 CRACKED GASO B7D SLOP OILRICH SPONGE OIL SEAL OIL FLUSH CHG FM STGE 0. 2576. 38629. 75178. 1216735. 0.0 0.2 2.9 5.6 91.3 0. 948. 11941. 24066. 448126. 0.0 0.2 2.5 5.0 92.4 515.4 51.6 343.1 673.5 14272.6 y*2 0.3 2.1 5.4 88.9 139.2 18.8 104.9 280.6 5201.2 2.4 0.3 1.6 4.9 90.5 xxxx YIELDS xxxx TOTAL 1333118. 100.0 485081. 100.0 16056.2 -100.0 5744.7 100.0 COKER GAS ELB COKER GASOLINE LT COKER GAS OIL ' HV C0KER~GA5 OIL LEAN SPG OIL ANODE COKE TONS FUEL GRADE COKE TONS 215341. 226936. 345139. 185816. ~ 28011. 0. 67406. 16.2 17.0 25.9 13.9 2.1 0.0 5.1 LOSS 264469. 19.8 TOTAL 1333118. 100.0 56297. 60004. 106684. ~6 3l4<r. 8658. 0. 134812. 55481. 485081. 11.6 12.4 22.0 15.0 1.8 0.0 27.8 11.4 100.0 2808.6 2161.5 4554.5 284472 245.9 67.0 747.7 2626.8 16056.2 17.5 13.5 28.4 17.7 1.5 0.4 4.7 16.4 100.0 690.6 565.5 1386.7 961.0 75.2 134.1 1497.7 434.0 5744.7 12.0 9.6 24.1 16.7 1.3 2.3 26.1 7.6 100.0 . </i >r " o o O' o * p* * 0590 10:43 01/14/88 CONOCO INC.-LAKE CHARLES 2EFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 3ft **** UNIT 75 - GAS REC PLANT HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 365.00 DAYS TO DATE THIS YEAR mxmm STREAM *### CHARGES MKXM DECEMBER VOLUME HEIGHT BBLS PCT MLBS PCT - YEAR TO DATE -- VOLUME HEIGHT MBBLS PCT MMLBS PCT MISC LT ENDS ELB COJCER-TCU GASES EtB~ HDS REC H2 PURGE FOE CRYO P/B TO GRP THERMAL GASOLINE COKER GASOLINE" 2 CK LN SPG OIL 112606 . ' 273392. 0. 39167. 35893. ""228268'." 28011. 15.7 38.1 0.0 5.5 5.0 3i:ft- 3.9 28590 71105. 0. 7630. 9148. 60359. B658. 15.4 38.3 0.0 4.1 4.9 32.5 4.7 1004.2 __ 12*6. 3592.3 45.2 0.5 0.0 419.6 . 5.3 .363*2 _ 4^6. 2327.7 29.3 245.9 3.1 258.6 874.6 0.1 83.6 92.9 609.0 75.2 13.0 43.9 0.0 4.2 4.7 30.5 3.8 MMXK YIELDS XNKM TOTAL 717337. 100.0 185490. 100.0 7953.5 .100.0 1993.9 100.0 ABS.TAIL GAS FOE PROPANETROPYLEN ------- BUTANE BUTYLENE GRP GASOLINE PP TO FUEL FOE 5P0NGE~0It H2S FOE 180039. 25.1 99335. " 1378' 72502. 10.1 351120. 48.9 0. 0.0 ----- 38629. " 574 9876. 1.4 ' 49543. "17687. 14810. 90875. 0. imi. 8742. 26.7 9.5 8.0 49.0 0.0 6.4 4.7 1995.7 1071.2 885.1 3813.2 3.1 343.1 127.5 25^1 13.5 11.1 47.9 0.0 4.3 1.6 547,7 190.8 180.3 975.2 0.9 104.9 112.9 27.5 9.6 9.0 48.9 0.0 5.3 5.7 LOSS -34164. -4.8 -8107. -4.4 -285.4 -3.6 -118.7 -6.0 TOTAL 717337. 100.0 185490. 100.0 7953.5 100.0 1993.9 100.0 ' *}!:*. `v: .j:j:i 'I.- '1 *1 'if f.f* 0590 10:43 01/14/8$ CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL. UrjJT YIELD REPORT PAGE 39 **** UNIT 74 - NO. 6 HDS HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 346.71 DAYS TO DATE THIS YEAR]!**** ' STREAM" MMMM CHARGES **** BBLS " DECEMBER PCT " MLBS PCT MBBLS YEAR TO DATE PCT MMLBS PCT | 8 HDS SEP LIQ 17 * 18 STROVHD SEAL OIL FLUSH RECYCLE H2 CRACKED DISTILLA FOE 0. 32639. 0. 66223. 614837. 0.0 4.6 0.0 9.3 86.1 0. 10242. 0. 10639. 193988. 0.0 4.8 0.0 5.0 90.3 12.8 469.2 6.6 602.3 67.26_i5__ .0.2 6.0 0.1 7.7 86.0 4.6 144.8 2.1 81.3 2085.4 0.2 6.2 0.1 3.5 90.0 KXKX YIELDS MXMX TOTAL 713699. 100.0 214869. 100.0 7817.4 100.0 231B.3 100.0 SEP H2 TO HPU HYDROGEN SULFIDE STRIPPER OH GAS STRIPPER REFLUX 86 HDS GASOLINE DES DISTILLATE FOE FOE ELB 75667. 1958. 10451. 5483.*" 94041. 579847. 10.6 0.3 1.5 o:* 13.2 81.2 11631. 1733. 3124. * 1482 . 25406. 177643. TOSS-53748. -775 -61497 5.4 0.8 1.5 0.7 11.8 82.7 -2.9 539.5 12.6 118.1 234.4 1173.3 6126.7 -287.2 6.9 0.2 1.5 2.7 15.0 78.4 -3.7 82.9 11.2 38.2 36.3 317.0 1872.6 -39.9 3.6 0.5 1.6 2.6 13.7 80.8 -1.7 TOTAL 713699. 100.0 214869. 100.0 7817.4 100.0 2318.3 100.0 TOrxir-UHIT_S4"="N0T 8'HD5" HA5'BEEN"ON-STREAH"3XTO~DAYnH----- DECEMBER *Rtri28727~t>m TO bATE_7fll5_7E/fR'Mfinf ----------- STREAM #*#* CHARGES KKK* DECEMBER ------ VOLUME WEIGHT BBtS* PCT MLDS* PCT------ YEAR TO DATE VOLUME WEIGHT MB8CS PCT ------MMLBS PCf SAL 00000(5416 PURCHASED SLURRY 9498 . KOCWSLURRY 29943. L CH SLURRY 124138. SOHIO SLURRY 118835. -------- -8.--= "CHAMPCTN_SLURRY ' 54. DESULF. SLURRY 0. PYRO. TAR 0. THERMAL TAR Tjunirrmw IT CYC OIL-T023 -- 0o.r 0. RECYCLE H2 FOE 76933. SEAL OIL FLUSH 0. "REG--COr-GAS~UTC------------------- V. PREM COK GAS OIL 0. 2.6 s;3" 34.5 33.1 8^8 0.0 .. 0.0 0.0 0.0 o;o - 0.0 21.4 0.0 0,0 0.0 3497. 3.0 122.8 11249. 9.5 154.9 46567. 39.4 1421.3 44641. 37.8 536.1 .... --JL. -___ 0.8 _ ' 0.0 A2 . A 218.6 0. 0.0 22.0 0. 0.0 163.6 0. 0.0 0.5 0. 0. U -------148."5" 0. 0.0 57.8 12187. 20.3 817.6 0. 0.0 11.0 0. 0.0' -------13572" 0. 0.0 13.3 3.1 4.0 36.4 13.7 2.1 "5.6 0.6 4.2 0.0 3.8 1.5 20.9 0.3 3.5 0.3 TOTAL 359401. 100.0 118159. 100.0 3905.7 100.0 45.1 57.6 528.8 202.1 30.0 79.6 7.6 62.1 0.2 49.4" 18.5 220.0 3.5 46.0 5.1 3.6 4.6 42.4 16.2 2.4 6.4 0.6 5.0 0.0 4.0 1.5 8.8 0.3 3.7 0.4 1245.8 100.0 0590 10:43 01/14/S8 CONOCO INC,-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE *0 XX UNIT 84 - NO. 8 HDS HAS BEEN ON STREAM 31,0 DAYS IN DECEMBER AND 328.27 DAYS TO DATE THIS YEAR **** STREAM DECEMBER VOLUME B8LS PCT -- WEIGHT- MLBS PCT VOLUME_____ MBBIS PCT DATE - -- WEIGHT MMLBS PCT XNXX YIELDS MXKX wonrsEi^fT^uiir HO. 8 SEP GAS FOE NO. 8 STRIP OVHD NO.8 DES. SLURRY ----------- NtmJES. GAS 01 HYDROGEN SULFIDE FOE LOSS TOTAL XKXK UNIT 90 - NO. 7 HDS STREAM jnmr-CHARGES-RSfRtf '5. 67191. 10900. 286861. 0. 2305. 0.0 18.7 3.0 79.8 0.0 0.6 0. 11183. 3368. 105206. 0. 2060. 0.0 9.5 2.9 89.0 0.0 1.7 12.* 729.9 113.1 2827.8 288.0 11.1 0.3 18.7 2.9 72.6 7.6 0.3 6.6 107.2 36.8 1019.7 96.1 9.8 0.4 8.6 2.8 81.8 7.6 0.8 -7836. -2.2 -3636, -3.1 -77.0 -2.0 -26.3 -2.0 359601. 100.0 118159. 100.0 3905.7 100.0 1245.8 100.0 HAS BEEN ON STREAM 19.2 DAYS IN DECEMBER. AND 326.52 DAYS TO DATE THIS YEAR ***X DECEMBER VOLUME WEIGHT B8LS PCT MLBS PCT VOLUME MBBLS PCT DATE -- WEIGHT MMLBS PCT SEAL OIL FLUSH H2 FM H2 SYSTEM FOE IS-HD5~~3TTr"REFLX LVGO HVG0 REG HCG0 1J C 1 U OAi> Ui L CHG FM STORAGE 23576. 112168. ' 56*3, 0. 270616. 82653. 0. 188813. 3.5 16.6 ' 0.8 0.0 39.6 12.1 O'. 0 27.6 7539. 18626. 1681. 0. 89626. 28103. 0. *2207. 3.6 8.9 0.7 0.0 63.2 13.6 0.0 30.0 202.6 1666.5 13676 95.1 3969.6 1699.3 irr 2219.0 2.1 17,0 1.6 1.0 60.6 15.3 o.r 22.7 65.2 36?3 30.9 1310.0 506.7 5.3 732.7 2.2 7.7 1.2 1.1 45.0 17,4 0.2 25.2 NKMX YIELDS XKXK TOTAL 683109. 100.0 207179. 100.0 9783.2 100.0 2910.9 100.0 SEP GAS TO HPl) FOE STRIP T1VHD GAS DES GAS OIL HYDROGEN SULPHID FOE 76709. 21760. 563950. 3206. -------------------- - ---------- IUSS~ "195867 TOTAL 683109. n o 10.9 3.2 82.6 0.5 279 100.0 13068. 68 / 3. 182187. 2836. 2235; 207179. 6.3 3.3 87.9 1.6 1.1 100.0 1137.6 " 356vr" 8020.8 15.9 11.6 3.6' 82.0 0.2 25278" 2.6 9783.2 100.0 172.2 5.9 110.0"' 3.8 2594.4 J9.1 14.0 Q.5-------- ----------------------------------------------------------- - -z<r:j --5T7------------------------------- 2910.9 100.0 o o \J\ !t l. m mm 0590 10:43 01/14/85 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT I PAGE 41 **** UNIT 89 - HYDROGEN SYSTEM HAS SEEN ON STREAM 31.0 DAYS IN DECEMBER AND 344.54 DAYS TO DATE THIS;YEAR *$**. STREAM KKNM CHARGES XMMM -------------- DECEMBER ----------- VOLUME ____ WEIGHT. BSlS PCT MLBS PCT ---------- YEAR TO DATE------------ VOLUMEWEIGHT. MBBLS PCT MMLBS PCT TOTAL VISTA IMPO FOE TOTAL' JUP IMPORT* FOE HDS SEP H2 FOE NO. 3 CRU HYDROG FOE H2 FRM 11 t 12 H FOE TOTAL xxxxFields mmmm 51300. 24741. 217566. 31189. 40798. 365594. 14.0 6.8 59.5 8.5 11.2 100.0 8175. 2588. 35662. 4657. 7326. 58608. 13,9 4.4 61.0 8.3 12.5 100.0 592.0 364.5 2407.0 454.0 454.6 4272.1 13.9 6.5 56.3 10.6 10.6 100.0 97.5 ___ 14 J*. 36.6 5.7 362.2 53.5 89.2 13.2 89.6 13.2 677.1 ,100.0 RECYCLE H2 FOE 255323. LP H2 TO EFS HDS FOE 14001. HP H2 TO 14 HDS FOE 19342. HP HZ to IZItr HF0E------------ 10602. REC PURGE TO FUE FOE 655. H2 TO CITIES FOE 21379. H2 TO VISTA FOE 0. JUPITER H2-FUEE FOE 7519. VISTA H2-FUEL FOE 14502. PSA TG TO FUEL FOE- 18775. LUSS 3496. TOTAL 365594. 69.8 3.6 5.3 2.9 0.2 5.6 0.0 2.1 4.0 5.1 1.0 100 . ot 41252. 2181. 3153. 1259. 111. 4206. 0. 786. 2302. 3871. -313. 58808. 70.1 3.7 5.4 2.1 0.2 7.2 0.0 1.3 3.9 6.6 -0.5 100.0 3086.5 132.0 197.1 59.1 19.8 567.1 0.0 36.6 104.8 225.4 72.2 3.1 4.6 1.4 0.5 13.3 0.0 0.9 2.5 5.3 -15677" -3.7 4272.1 100.0 415.2 19.9 29.2 6.6 3.0 108.2 0.0 3.8 17.5 46.8 24.8 677.1 61.3 2.9 4.3 1.0 0.4 16.0 0.0 0.6 2.6 7.2 3.7 100.0 ttai" i vI ? r> in > o o o o -o- CD x 590 10:43 01/14/88 CONOCO INC.-LAKE CHARLES RtFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 42 xxxx" UNIT 85 "FCC FEED PREP HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 331.83 DAYS TO DATE THIS YEAR xxxx ---------- STREAM XXXX CHARGES XXX* ------------- DECEMBER -- VOLUMEWEIGHT BBlS *'" PCT MLBS PCT --------- YEAR TO DATE ----------- VOLUMEWEIGHT. MBBLS PCT MMLBS PCT DESUL. GAS OIL 10 32 949. 10.0 .J)____________33 0 0 96_,____10Jg_Z,_B3_ WJ__ LDJLJL 3937.7 100.0 XXXX YIELDS XKNM TOTAL 1032949. 100.0 330096. 100.0 12309.3 100.0 3937.7 100.0 DIESEL DES GAS OIL SLOP 155446. 837099. 8034. 15.0 81.0 0.8 47967. 268410. 2276. LOSS 32370. 3.1 11443. TOTAL 1032949. 100.0 330096. xxxx UNIT 86 - CDR UNIT HAS BEEN ON STREAM 14.5 81.3 0.7 1561.2 10609.9 ____ 03_,_3_ 12.7 86.2 3.5 54.9 0.4 100.0 12309.3 100.0 7.0 DAYS IN DECEMBER 482.1 12.2 3414.3 86.7 __UL -JUS. 17.7 0.5 3937.7 100.0 AND 164.00 DAYS TO DATE THIS YEAR mmxk STREAM xxxx CHARGES xxxx DECEMBER ------ VOLUME" ------------- WEIGHT' BBLS PCT MLBS PCT ----------- YEAR TO DATE ------------- VoLUHE BeIgHY MBBLS PCT MMLBS PCT CDR"RAFFINATE DECENE DEAC DIBAC ---------- ETHER----------------TITANIUM CL3 VAN LUBE SL GALS GALS GALS GALS GALS LBS GALS "442065." 91.7 38972. S.l 0. 0.0 430. 0.1 547....... 0.0 647. 0.1 96. 0.0 " TOTAL" "482264. 10 0.0 xxxx YIELDS xxxx 3020T" 241. 0. 3. 0. * l. 1. 92.5 7.4 0.0 0.1 o. 0 0.0 0.0 3266. loo. r "352*77""9176 327.3 6.2 0.0 .o 6.5 0.2 076* 0.0 7.0 0.2 0.8 0.0 3971.0 10070 2471""9*72" 2.0 7.5 0.0 0.0 0.0 0.2 07 ft.O 0.0 0.0 0.0 0.0 '26.9 100.0 DRAG-REDUCR I02R "GALS 07 DRAG REDUCR 102M GALS 460550. DRAG REDUCR 1025 GALS 19818. DRAG REDUCER T/R GALS 0. CDR OFF'5PEC--------- JSKT5--------- '"T!7 V* > 1o o_ o o LOSS 1 U 1 AL 1696. 4822697 "0.0 95.5 4.1 0.0 0.0 0.4 100.0 0. 3132. 135. 0. 07 - 0,0 95.9 4.1 o; o 0. 0.0 326 6. 10070 0.0 3771.6 79.2 1.JL3--JL " ` 070 0.0 95.0 2.0 2.6 0.0 ` 16.6 0.4 I97ITB *10070 * 070 25.6 0.5 ------ * 0.0 0.0 95.4 2.0 070 0.0 0.0 26.9 TO 0. O' .H sj3 0590 10:43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE AS ***** UNIT'02 - NO ,"'2' CRUDE UNIT HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 363.46 DAYS TO DATE THIS YEAR *** ---------- 5TREAM-------------kkkm CHARGES **** DECEMBER -------------- VOLUME WEIGHT BBlS PCT MLBS PCT ------------------ YEAR TO DATE------------------ VOLUME _ _ WEIGHT MBBLS PCT MMLBS PCT _ CONOCO PIPELINE TEXACO PIPELINE ALASKAN N/SLPE CABINDA-SWEET CONDENSATE DOMESTIdSAJnJE SLOP 540378. 290771, 103. 0. 72096. 670902. 44466. 38.1 20.5 0.0 0.0 5.1 3372 3.1 152574. 61661. -11. 0. 19307. 13 3 6 5 57" 23003. 37 12 19.9 0.0 0.0 4.7 32.6 5.6 6966.65469.5 46.2 6.3 72,1 2184.5 383.5 46.0 36.2 0.3 0.0 0.5 14.4 2.5 1988.2____ 45.2 1562.6 35.6 14.2 0.3 1.9 0.0 ,19.3 0.4 424.6 14.2 183.7 4.2 MKKK YIELDS KMKX 1418716. 100.0 410188. 100.0 15128.8 100.0 4395.0 100.0 CRUDE/DEBUT GAS ELB T5R~GA50t INE-----------------NAPHTHA KEROSENE HEAVY HOD "DIE5EC------------------------------GAS OIL TOPPED CRUDE SLOP 51069. 205265 231202 38994 379079 93454, 311672 0. 3.6 12819. 16.5 56700. 16.3 66870. 2.7 11162. '2677------- 1115607 6.6 28567. 22.0 0.0 .99765. 0 3.1 13.3 15.8 2.7 `27 72 7.0 26.3 0.0 630.3 2111.7 2382.6 666.7 '351472 500.1 3990.0 21.0 412 UZut- hA__________________ L05S 50695 3.6 12394. 3.0 481.6 3.2 153.6 3.5 TOTAL 1418718 100.0 410188. 100.0 15128.8 100.0 4395.0 100.0 to > O -cr o o o rv> o 590 10:43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 4* **h* unit 35 - fcc Unit HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 360.49 DAYS TO DATE THIS YEAR mmkx STREAM **** CHARGES #nxx DECEMBER VOLUME WEIGHT BBlS PCT MLBS PCT TLnK _ yOUIME. MBBLS PCT I4EIGHT MMLBS PCT CHARGE FROM STGE HV CYCLE OIL ' LT SLOP FM STGE f2 CTU GAS OIL OES GAS OIL MI5C. TTRENDS ELB 457772. 0. 5358. 93454. 576333. 22549. TOTAL 1155466. **** YIELDS KMXM 39.6 0.0 0.5 8.1 49.9 270* 100.0 146306. 0. 1491. 28567. 185915. '5516. 367795. 39.6 0.0 0.4 7.8 50.5 1.5 100.0 5.7.99.1_. 40.6 9.7 0.1 72.9 0.5 453.6 3.2 7721.7 _5_4_JL 220.6 1.5 14277.6 100.0 1858.6 3.1 20.3 137.6 2460.8 46.8 4547.2 40.9 0.1 0.4 3.0 54.6 1.0 100.0 _. H25 FOE ABS TAIL GAS FOE PROPARE-PROPCFNE' P-P TO FUEL FOE BUTANE-BUTYLENE FCC GASOLINE IT CYCCE OIC H CYCLE OIL RECY SLURRY SLOP UUAb BUKNtU TOMS- 456. 54258. 01267. 0. 144133. 604285. 322950. 0. 84181. 0. 7548. 0.0 4.7 7.8 0.0 12.5 52.3 27.9 0.0 7.3 0.0 0. T 403. 17603. "14797. 0. 29200. 155018. 104479. 0. 31447. 0. T5096. 0.1 4.8 4.0 0.0 7.9 42.1 ' 28.4 0.0 6.6 0.0 4.1 4.1 697,2 T008.3 16.1 1660.4 7390.5 3906.4 9.7 1176.9 35.2 93.9 0.0 4.9 0.1 11.8 51.8 27.4 0.1 8.2 0.2 o.r LOSS "143612. -12.4 -248. -0.1 -1741.0 -12.2 T0T*rT1554F6~.--7D0T0----- 357795:--10 075------- T427775--10*75 3.6 184.0 4.8 342.2 1908.6 1263.3 3.1 437.7 9.7 187.6" 0.1 5.0 4.0 0.1 7.5 42.0 27.8 0.1 9.6 0.2 4.1 -26.5 -0.6 T54772--ronr 11 0590 10-43 01-/14/88 CONOCO INC."LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE *5 Xkkx UNIT S3 -"CRYO GAS 'PLANT HAS'BEEN ON STREAM 31.6 DAYS IN DECEMBER AND 36372TDAYTTOifi^iS^YEAOiNr ------ ""STREAM **** CHARGES **** ------------- DECEMBER ----------- VOLUME _______ WEIGHT BfiLS PCT MLBS PCf --------------- YEAR TO DATE ----------------- ........VOLUMEWEIGHT_____ MBBLS PCT MMLBS PCT CRY0 FEED GAS *KKX YIELDS XMK* TOTAL 216318. 216318. ioo,p_ _ .5.9 96 9.__ .lQo.e ___2469.JL. 100.0 100.0 59969. 100.0 2469.6 10Q.0 700.9 100.0 700.9 100.0 _ CRY0 GAS TO FUEL FOE CRYO GAS TO FLAR FOE CRYO P/B TO GRP 177056. 0. 39167. 81.8 0.0 18.1 48473. 0. 7630. 80.8 0.0 12.7 2064.1 0.0 419.6 85.6 0.0 17.0 586.6 0.0 83.6 83.7 0.0 11.9 LOSS 95. 0.0 3866. 6.4 -14.2 -0.6 30.7 4.4 TOTAL 216318. 100.0 59969. 100.0 2469.6 1UJ___ 700.9 100.0 **** UNIT 41 - CAT POLY UNIT HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 303.87 DAYS TO DATE THIS YEAR **** STREAM MKXK CHARGES MKMM ................ DECEMBER ----------- VOLUME--------------------- WEIGHT BBLS PCT MLBS PCT ---------i-- YEAR TO DATE------------------ --VOLUME Weight MBBLS PCT MMLBS PCT PROF-PROPYLENE 150858: rr 342.0 lETT#" YIELDS KKKK TOTAL 160858. 1899.7 100.0 342.0 100.0 PROPANE PP TO FUEL FOE "BUTANE :-------------------------- POLY GASO SLOP 77833. 0. 165127 44523. 0. T055------ 21990. i in: 144*7 ^878------ "2:5 TOTAL 160858. 100.0 28892. 100.0 1899.7 100.0 342.0 100.0 in > o o o o o IJt Pv 90 10*43 01/14/88 CONOCH INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 46 KNrtrt UNIT 68 - NP'SPLiTTER" HAS SEEN ON STREAh"3X.O DAYS IN DECEMBER AND 320.86 DAYS TO DATE THIS YEAR xxxx ---------------- DECEMBER -------------- ------------------ YEAR TO DATE--------------------- _______ ,VOLUME.WEIGHTVOLUMEWEIGHT 5TREAM B6LS PCT MLBS POT MBBLS PCT MMLBS PCT xxxx CHARGES xxxx NORMAL PARAFFINS114483. 100.030193., 10 ^ 01056.6 100.Q279.0 100.0 xxxx YIELDS TOTAL xxxx 114483. 100.0 30193. 100.0 1056.6 100.0 279.0 100.0 _____ ________ _________ __________ LT PARAFFINS HVY PARAFFINS 71642. 62.6 47097. ' 41.1 18844. 12569. 62.4 41.6 643.5 409.5 60.9 38.8 171.1 61.3 109.4 39.2 ------------------------- ---------------C055~ -"4Z5T.------ =TT77-------- =T22n-------=*7S-------------- STS-------- 073------------ ^175------ HITS' TOTAL 114483. 100.0 30193. 100.0 1056.6 100.0 279.0 100.0 IN DECEASES XfiiTStfrftO DAYS TO DATE "THIS* YEAR XXXX --------------- 5TR EAW--------------xxxx CHARGES xxxx ------ DECEMBER -------- VOLUME WEIGHT BBLS per MLBS PCT ---------------- YEAR TO DATE ------------------- VOLUME WEIGHT MBBLS PCT MMLBS PCT GRP GASOLINE --12713 CTITC5R 351120. '262836.' 57.2 42.8 90875. 65373. 58.2 41.8 3813.2 2906.8 56.7 43.3 975.2 719.6 57.5 42.5 TOTAL 613956. KXX' TIECDS XJTXJf 100.0 156248. 100.0 6720.0 100.0 1694.9 100.0 PRIMARY TUR GAS EL! PRI TWR GAS FUEL FO! ISR-GASOIINE" LIGHT CRACKED GA NAPHTHA CRACKED NAPHTHA stop --------- ------------- 4142. 0.7 904. 0.6 45.4 509. 0.1 143. 0.1 4.6 "56236. 9.2 13115. * ;4------ 804.6 95538. 15.6 25657. 16.4 1315.3 186237. 30.3 47271. 30.3 1928.4 225753. 36.8 61235. 39.2 2456.1 -- 0 . ------- o:o" ----------- o.- ....... o.o -- " 0.2 0.7 0.1 I2:0 19.6 28.7 36.5 0.0' 9.7 0.6 1.3 0.1 188.8 "11.1 337.2 19.9 486.9 28.7 658.9 38.9 0.0' 0.0 --------------- >ZA -------- n LOSS rOTAL 45541. 7.4 7924. 5.1 165.4 2.5 12.1 0.7 613956." --100.0 " ` 1562487"-10070------ *672070--10 070 ----- 16^9479" loonr 0590 10^43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY i ME05 i mmUM 'UNIT '`37~-=""M0r 1 HDS STREAM XMMM CHARGES NNMN MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 47 HAS BEEN ON STREAM"3l70 DAYS IN D..E...C..E...M. BER AND 264.94 DAYS TO DATE THIS YEAR hmnm --------------- DECEMBER -------------- -- -- YEAR TO DATE ------------------ BBLS PCT MLBS PCT MBBLS PCT MMLBS PCT H2 FRM HPU FOE RECYCLE PURGE R2~FOE CRACKED NAPHTHA 3 CTU KEROSENE ----------------------------------------- Tom MMMM YIELDS NMXK 10602. 0. 0. 173760. 5.8 0.0 0.0 94.2 184362. "UTffTff 1259^ 0. 0. 49734. 2.5 0.0 0.0 97.5 50993. 100.0 57.3 36.7 1037.9 503.3 1635.2 .3.5 2.2 63.5 30.8 100.0 6.4 5.4 278.3 144.1 434.1 1 .5 1.2 64.1 33.2 100.0 "Hsrwrupu-- SOH 6AS SOUR NAPHTHA DES. KEROSENE "GASLIT FEW SLOP For ELB ""5078". 676. 0. 168547. 0. 0. ~Z7S------- 50ZT 0.4 189. 0.0 0. 91.4 48359. o;o' 0. 0.0 0. 1.0 0.4 0.0 94.8 0.0 0.0 54. 12.2 1059.5 458.4 0.0 24.3 3.3 0.7' 64.8 28.0 0.0 1.5 5.9 3.6 279.9 131.5 0.0 6.9 1.4 0.8 64.5 30.3 0.0 1.6 LOSS 10063. 5.5 1943. 3.8 26.4 1.6 6.3 1.5 TOTAL 184362. 100.0 50993. 100.0 1635.2 100.0 434.1 100.0 UNIT 62 - NO. 2 CRU 1 HDS HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 330.01 DAYS YEAR xxx* STREAM HIITK-CHARGES-RRRR" DECEMBER ------ VOLUME WEIGHT BBLS PCT MLBS PCT --------- YEAR TO DATE ----------- VOLUME WEIGHT MBBLS PCT MMLBS PCT SAL 000005fr24- NAPHTHA MOLEX GASOLINE "HPtrmTJROGEN-- FOE-------- TOTAL *** YIELDS--****--------------- 347393. 34408. 0. 381801. 91.0 9.0 07 0" 100.0 91407. 9225. " 0. 100632. 90.8 9.2 " o:o" 100.0 4397.3 378.3 1.9 4777.4 92.0 7.9 o;o 100.0 1157.0 102.5 0.2 1259.7 91.8 8.1 0.0 100.0 SP H2 II 4 HPU FOE PESPL. NAPHTHA HTDROucNTu FUELFUE STAB GAS ELB GASES TO FLARE FOE 5TAB LIQ KbPUKDA1t LOSS "TOTAL --or----3---5--7--2- 2jj--. 9.4 ____ *82*. 0* 18190. 4.8 ~ 3379. 7484. 2.0 1779. 109. 0.0 31. 17715. 4.6 3156. 2997607 78.5 filbDi. 6.8 0.0 3.4 1.8 0.0 3.1 81.1 2821. 0.7 3858. 3.8 dOlAlli 1UU.U XUUbJZ. --18070 4ILl.iL 8.4 63.7 1.3 30.6" 0. b 256.2 5.4 0.1 0.0 134.0 2.8 376173"--78.7-- 130.5 2.7 --47777C~"10070 88.8 17.0 5.7 56.3 0.0 25.0 1031.?" 6.7 1.4 075 4.5 0.0 2.0 81.9 40.5 3.2 1259.7 IDO . 0 DECEMBER ENDING VALUES REFORMATE RONC 96 .23 590 10:43 14/ofl CONOCO INC.-LAKE CHARLES REF7 r f1E05 - MONTH END AND YEAR TO DATE FINAL UnIT YIELD REPORT PAGE 48 Xxx* UHlT~l5~-"THERMAL" CRACKER~HA5 BEEN ON StREAM_3lT0 DAYS IN DECEMBER AND~29410 DAYS TO DATE THIS~YEAO*K*' "STREAM xxxx CHARGES XXXx DECEMBER VOLUME bbls PCT MLBS PCT MBBLS YEAR TO DATE PCT MMLBS PCT GAS OIL FM STG FCC"CYClE~0Il7FH` TUnHrTIELDS--RSTiR TOTAL 266062. 10332. 276394. 96.3 3.7 100.0 97571. 3336. 100907. 96.7 3.3 100.0 2669.6 37.4 2707.0 98.6 1.4 100.0 964.2 12.2 976.4 98.8 1.2 100.0 FRACT GAS-GRP ELB VENT GAS TO FLAR FOE -----------THERMAL" GASOLINE" CYCLE OIL THERMAL TAR SLOP i LOSS TOTAL 23243. 423. "35893. 4B06. 228600. 0. 8.4 0.2 "1370 1.7 82.7 0.0 -16571. -6.0 276394. 100.0 5763. 120. 4l48. 1412. 87697. 0. -3233. 100907. 5.7 0,1 9.1 1.4 86.9 0,0 -3.2 100.0 267.9 5.1 363.2 122.0 2017.4 1.1 -69.5 2707.0 9.9 0.2 13.4 4.5 74.5 0.0 -2.6 100.0 61.3 1.4 92.9 38.0 771.2 0.3 11.2 976.4 6.3 0.1 9.5 3.9 79.0 0.0 1.1 100.0 xxhx UNIT 42 - CASINGHEAD UNIT HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 363.33 DAYS TO DATE THIS YEAR xxxx STREAM xxxx CHARGES xxxx DECEMBER ------- VOLUME ------------- UEIGHT BBLS PCT MLBS PCT YEAR TO DATE "VOLUME HEIGHT" MBBLS PCT MMLBS PCT FTEE1TPBC CONDENSATE REF PBC LIQ MISC IT ENDS CAT"POLY/AlKT~C3 POLY t ALKY C4 3 REF PP ELB 40436. 0. 106B41. 0. ' 89B10. ' 72068. 7. 13.1 0.0 34.6 0. D 29.0 23.3 0.0 ^ TOTAL "309162. ' 100.0" xxxx YIELDS xxxx 6725. 0. 15608. 0. 2/6/i. 10813. 1. 11.1 0.0 25.7 0.0 45.5 17.8 0.0 60823. ' 100.0 - 438.1 10.0 799.6 413.0 1128.6 712.9 2.3 "3504.6" 1275-----0.3 22.8 11.8 32.2 20.3 0.1 100:0 7871" 1.4 131.0 78.5 285.4 115.7 0.3 1175 0.2 19.0 11.4 41.3 16.8 0.0 690.4" 100.0 " PBC"VAPORS" ELB DEETH TAIL GAS FOE PROPANE -------- PROPANE TO FUEL FOE bU1ANfc ISOBUTANE CH -GASOLINE \ ...... 1428." 8983. 4380. 59223." 21844. 63263. TOST 20957 o o o TOTAL 309162. o o U) Sr\>' 0.5 2.9 1.4 ~1972 7.1 20.5 orr 100.0 411. 2604. 1265. --12X55. 4296. 15326. 0.7 4.3 43.4 2.1 20.0 7.1 25.2 "T297^------ =27T 60823. 100.0 2 0 75" 076 57T "0 79--------- 65.9 1.9 19.2 2.8 ----- 44-4----- ----- AWt J --44 9------------------------------- 22.7 0.6 6.7 1.0 --714T6"----- 20.4------ 14678"--2172 283.0 8.1 55.8 8.1 739.9 21.1 177.7 25.7 ^9179" "=7Tr -3m--------T75" 3504.6 100.0 690.4 100.0 1 0590 10*43 01/14/88 CONOCO INC.-LAKE CHARLES REFIHERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT *** UNIT 43 - ALKYLATION UNIT HAS BEEN ON STREAM 30.3 DAYS IN DECEMBER AND 360.42 DAYS STREAM **** CHARGES xmmm DECEMBER VOLUME ...... WEIGHT _ VOLUME BBLS PCT MLBS PC7 MBBLS PCT WEIGHT MMLBS PCT B-B FM STORAGE ' IC4"FM STORAGE FCC P-P PBC VAPORS ELB 218739. 147788. 19744. 142S. TOTAL357599. MttXK YIELDS *XNX 56.4 38.1 5.1 0.4 100.0 44436i 29060. 3592. 411. 77499. 57 t 3 37.5 4.6 0.5 100.0 2553.8. 1596.0 177.5 20.5 58,7 36.7 4.1 0.5 4347.9 100.0 520 . O 314.5 32.4 5.9 872.8 59.6 36.0 3,7 0.7 100.0 PROPANE BUTANE ISOBUTANE ALKYLATJE WEr^BL DflFFTOEE FOE WET BL DWN-FLARE FOE 11977." 54832. 84124. 213968. 8. 0. 3.1 14.1 16.5 55.2 0.0 0.0 21177" 11332. 12616. 52503. 0. 0. 2.7 14.6 16.3 67.7 0.0 0.0 - 135.4 642.9 699.2 2406*4 10.7 0.1 3.1 14.8 16.1 55.3 0.2 0.0 23.9 131.6 137.7 589.5 3.1 0.0 2.7 15.1 15.8 67.5 0.4 0.0 LOSS 42798. 11.0 -1069. -1.4 453.2 10.4 -13.1 -1.5 TOTAL 387699. 100.0 77499. 100.0 4347.9 100.0 872.8 100.0 *** UNIT 23 - ACID PLANT HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 313.97 DAYS STREAM JT*inrtfiSRGE5~RRRR DECEMBER ------ VOLUME WEIGHT BBLS PCT MLBS PCT YEAR TO DATE VOLUME WEIGHT MBBLS PCT MMLBS PCT AMINE ACID GAS FOE SMS GAS FOE --; SPENT ACID- 100JT" CALC. 02 I H20 TONS TOTAL XMKM YIELDS MMXX 1719. 985. 5259. 2241. 10204. 16 .8 9.7 51.5" 22.0 100.0 1521. 8.7 872. 5.0 10518. ' `60.5" 4482. 25.8 17393. 100.0 3.9 8.5 "52.5 16.6 81.5 4.7 10.4 '64.4 20.4 100.0 3.4 7.5 105.0 33.2 149.1 2.3 5.0 70.4 22.3 100.0 _______ 98X SUL ACID--------i-o--ox--------- ----- 8816. LOSS 1388. SA TOTAL 10204. 86.4 13.6 100.0 17632. -239. 17393. 101.4 -1.4 100.0 67.7 13.8 81.5 83.1 16.9 10Q.0 137.1 12.0 149.1 91.9 8.1 100.0 o o o Oo in f\; i PAGE 49 YEAR **KK YEAR **** )590 10*43 14/88 CONOCO INC.-LAKE CHARLES REF* .AY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 50 ***** UNlT~9i - SULFUR PLANT HAS-BEEN ON5TREAM3176^)4 Y5~IH DEcTlIBER AND 365.00 DAYS TO DATE THIS~YEAR-**** STREAM ***M CHARGES KKXX ---------------- DECEMBER -------------- VOLUME WEIGHT BBLS PCT MLBS PCT ------------------ YEAR TO DATE--------------------- _ VOLUME WEIGHT MBBLS PCT MMLBS PCT SWS ACID GAS FOE AMINE ACID GA5------ FOE TOTAL inonrYiELDS--*n?jr 0. 15472. 13672. 0.0 10O.O 100.0 . 0^ 0.0 11925. 100.0 11925. 100.0 0.9 180.5 181.5 0.5 99.5 100.0 0.8 159.8 160.6 0.5 99.5 100.0 FUEL MAKE FOE SULFUR-TOMS TONS "CAEC7_PR0C"Ctf55--TONS* 673. 7522. " 351. 3.5 55.8 2.6 98. 15065. 701. 0.8 126.2 5.9 5.1 78.6 4.8 2.8 43.2 2.6 1.1 156.7 9.6 0.7 97j_4 6.0 LOSS 5126. 38.0 -3919. -32.9 93.2 51.4 -6.7 -4.2 Turn--m72: 151)76------------ n J7"To 67T 161.5 100.0 160.6 100.0 K**x UNIT 22 - NASH PLANT HAS BEEN ON STREAM 31.0 DAYS IH DECEMBER AND 270.50 DAYS TO DATE THIS YEAR *** STREAM *MKK CHARGES **** - --------------- DEC EM 8ER VOLUME WEIGHT BBLS PCT MLBS PCT --------------- YEAR TO DATE ----------------- VOLUME WEIGHT MBBLS PCT MMLBS PCT AMINE ACID GAS FOE TOTAL XMNK YIELDS KKKM 4476. 4476. 100.0 100.0 3934. 3934. 100.0 100.0 58.3 58.3 100.0 100.0 51.2 51.2 100.0 100.0 SULFUR AS H2S I'KuLLSSlHi) TONS likHb 1324. 1 IB 29.6 2.6"' LOSS 3034. 67.6 TOTAI------- 6676. "100.0 " 2648. ~ 236. 1050. 3936. 67.3 6.0 26.7 100.0-- 23.2 *' 1.5 39.8 2.6 33.5 57.5 587J"10070 46.4 90.6 3.1 ` 6.0 1.8 3.4 $i:2~~ioo.o r o O-- o o - OU1 * po <4 0590 10*43: 01/14/58 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 51 k*k* UNIT~05 "REG "BLENDING HAS~ BEEN'bN "STREAM' 16 70 DAYS-IN DECEMBER AND"T72700~~DAYS~TOATE"THlV^AFx*^ STREAM *XKK CHARGES MKKK BUTANE ALKYLATE PYRO GASOLINE LSR GASOLINE LIGHT CRACKED GA uAblNUHLAD GASO POLY GASOLINE FCC GASOLINE NO. 2 REFORMATE NO7"3"REF0RMATE KMHH ritLus KXXN --.............. DECEMBER -------------- VOLUME UEIGHT B8LS PCT MLBS PCT 35122. 5.8 . .7201, 36551. 6.1 8975. 0. 0.0 0. 900. 0.1 236. 73071. 12.1 19729. 45027. 7.8 11992. 15580. 2.6 4026. 213773. 35.4 57200. 60031. 10.0 15962. '123023. ~20.4 32414. TOTAL 603078. 100.0 157734. 4.6 5.7 0.0 0.1 12.5 7.6 2.6 36.3 10.1 20.5 100.0 ------------------ YEAR TO DATE--------------------- VOLUME UEIGHT MBBLS PCT MMLBS PCT 204.9 3.8 411.3 . 7.6 2.1 0.0 60.3 1.1 600.5 ___Iltl 312.7 5.8 167.1 3.1 2326.3 42.9 403.4 7.4 938.1 17*3 5426.7 100.0 42.1^' 100.8 0.6 15.5 155.6 80.0 41.4 600.6 114.7 264.2 3.0 7.1 0.0 1.1 11. Q 5.6 2.9 42.4 B.l 18.7 1415.2 100.0 i REGULAR GASOLINE 603080. 100.0 157734. 100.0 5426.7 100.0 1416.8 100.1 LTJ55-" -2. 0.0 O. 0.0 0.0 0.0 -1.6 -0.1 TOTAL 603078. 100.0 157734. 100.0 5426.7 100.0 1415.2 100.0 ^Jrw-UNmr^-UNLEADEinCEND--HAS"BEEfr0N"BTREAM"I77O~DA?5~IN------ DECEMBER JRIT~2557'fl 6" DAYS^TOTJAtE"" THI'S' YEAR" *xkx_ STREAM MMMM CHARGES XXKM DECEMBER VOLUME WEIGHT -------------BSCS' --PCI-------- 7TCB5--------"PCT-------- --------- YEAR TO DATE VOLUME MBBLS" PCT --MMLBS" PCT " " SAL 0 0 0 0 0 5 4 2 8 BUTANE MLATLA1C PRYO GASOLINE LSR GASOLINE LIGHT CRACKED GA LAbiNuHkAU POLY GASOLINE NO. 2 REFORMATE narr reformate 42384. ' 88901. 0. 476. 29247. 17071. 27164. 355675. 74547. 221127 6.4 i3:r 0.0 0.1 4.4 " 2.6 __ 6 .-1 54.1 11.3 "3 74 8706. 21801. 0. 125. 7896. 4546. 93116 18966 5730 TOTAL 657577. 100.0 . 167734. TonruTIECUS--Jnonr 5.2 449.1 4.5 i3:r "1101V2 H.l 0.0 97.1 1.0 0.1 76.4 0.8 4.7 725.4 7.3 "2.7 34377 315 ------ 341T7 --T74----- 4634.6 46.6 12933667.24-----1r9r.5r 92.2 269.7 25.9 19.4 184.6 " 87.0 84.7 1196.9 542.6 ~l J7T 10.5 1.0 0.8 7.2 Y A" 3.3 46.6 21.1 "275" 100.0 9941.8 100.0 2566.5 100.0 ------- 1------------------- UNLEADED 657579. 100.0;. 167734. 100.0 9941.9 100.0 TOSS' -------- T:--------- 070----------------- 07 -----878--------------- 870---------imr TOTAL 657577. 100.0 167734. 100.0 9941.8 100.0 2568.6 100.1 --=27I------=87T 2566.5 100.0 1590 10*43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 52 #*K* UNir'0r~SUPER*UNr'l0LEND`"HAS"BEEN"dNrstRlAM~i8`o DAYSHEN DECEMBER AND 167.00 DAYS TO DATE THIS YEAR-***^ ---------- STREAM------------MKMM CHARGES NXNN -------------- DECEMBER ----------- VOLUME ______ _ WEIGHT "BBCS PCt MLBS PCT -------- YEAR TO DATE ---------- .V 0 LUMEWEIGHT, MBBLS PCT MMLBS PCT BUTANE ALKYLATE PYRO GASOLINE LSR GASOLINE LIGHT CRACKED GA CASINGHEAD GASO POLY GASOLINE FCC GASOLINE NO. 2 REFORMATE NOn'REFORMATE------ 46261. 84422. 0. 12. 10957. 7454. 2860. 37137. 176160. 154830'. 6.9 16.2 0.0 0.0 2.1 1.4 0.5 7.1 33.9 29.8' 9499. 20728. 0. 3. 2959. 1485'. 716. 9659. 48210. 42851. 7.0 15.2 0.0 0.0 2.2 1.5 0.5 7.1 35.3 31.4 383.3 942.8 20.3 3.7 30.8 18.8 52.0 694.0 1464.1 1740.7 . L2_ 17.6 0.4 0.1 0.6 0.4 1.0 13.0 27.4 32.5 78.6 231.2 5.2 0.9 8.2 4.9 11.8 166.7 411.0 494.6 5.6 16.4 0.4 0.1 0.6 0.3 0.8 11.8 29.J 35.0 TOTAL 520113. 100.0 136611. 100.0 5350.4 100.0 1413.0 100.0 ----------RRJOTTI ErDS--RRWJr* . SUPER UNLEADED 520114. 100.0 136611. 100.0 5350.4 100.0 1414.3 100.1 LOSS" -1. o;d 0. 0.0 0.6 0.0 -1.2 -0.1 TOTAL 520113. 100.0 136611. 100.0 5350.4 100.0 1413.0 100.0 ~"AREA"T"FUEL "HP--HA5~BEEH OinTREAfOrTO-D*Y5"IR DECEMBER~THD"3P?7BrD^YS"10'l)TtE"THiS_YEAR" **** ---------------------STR EAP1-----------NNXN CHARGES MXXX ----- DECEMBER -------------- -------------------YEAR TO DATE------------ VOLUME ______ WEIGHT ________ VOLUMEWEIGHT BHCS" -- "PCT Tins -----PCT-------- --MBBLS" PCT----------MMLBS PCT CRYO GAS TO FUEL FOE --------- FCCTAILTA 5-- TOE-- GRP TAIL GAS FOE PROPANE FOE PROPANE-PROPYLEN VT5TAHZ TO FUELFOE JUPITER HYDROGEN FOE H2 RICH FUEL FOE MISC FUEL GASES FOE ------- PURCriA5CD~rUgt------ THE 177056. 36.6 ' 54258. 11.2 180039. 37.2 4300. 0.9 0. 0.0 14502." 3:0 7519. 1.6 16845. 3.9 9965. ?.l "17760."' 3.7 TOTAL 484244. 100.0 T ft IF*fI ElDS xx 48473. 37.0 2064.1 36.2 566.6 17603. 13 697.2 12.9 229.0 49543. 37.6 1995.7 37.0 547.7 1265. 1.0 22.7 0.4 6.7 0. 0.0 1.6 0.0 0.3 2302. 1.8 104.8 1.9 17.5 766. 0.6 36 .8 0.7 3.8 3490. 2.7 50.9 0.9 8.8 .___ 2145. --------- -----106.4 --tttj-- 30.6 ----- 4845." " 3.7 ' 316 T9 "5.9 ------ 8676" 38.7 15.1 36.1 0.4 0.0 1.2 0.3 oA 20 5 rr 131152. 100.0 5397.2 100.0 1517.6 100.0 CRYO FEED GAS CRYO GAS TO LGS FOE EXrT FUEL Tu VI5T FOE FUEL CONSUMED FOE AREA II MAKE-UP FOE FLARE FOE SAL 000005429 216316. 0. B2095I " 101110. 67956. 0. 44.7 0.0 17.0 20.9 14.0 0.0 59969. 0. 22475. 26519. 17783. 0. 45.7 0.0 17.1----- 20.2 13.6 0.0 2469.6 0.0 973TB 1215.1 709.4 2.5 45.8 0.0 --1870------ 22.5 13.1 0.0 700.9 0.0 277.0 336.2 194.9 0.7 46.2 0.0 16.2 22.2 12.8 ft . ft I I I 1 I 1 \I 000005^ SAt 590 10*43 Ox/14/88 CONOCO INC.-LAKE CHARLES REFIN^r ME05 - MONTH END AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE S3 *K**"UNIT 98 - Area 2 FUEL HP HAS-BEEN ON~$TREAM'31.0 DAYS IN DECEMBER AND 365.00 DAYS TODATE THIS YEAR **** STREAM **** CHARGES NKMM DECEMBER -------------- ------------------ YEAR TO DATE------------ VOLUME __________ WEIGHTVOLUMEWEIGH.! BBIS PCt ' MLBS PCT MBBLS PCT MMLBS PCT PURCHASED FUEL D-37 MIX FOE FOE TOTAL --------RKtIELD5 RxJIR 61931. 47.7 67956. "52.3' 129887. 100.0 16889. 48.7 17783.' 51.3 34672. 100.0 635.9 709.4 1345.2 47.3 52.7 100.0 173.8 194.9 368.7 47. L. 52.9 100.0 FUEL CONSUMED LP DRUM MAKE-UP FOE FOE LOSS TOTAL 97348. 29739. 2800. 129887. 74.9 22.9 2.2 100.0 25925. 7934. 813. 34672. 74.8 22.9 2.3 100.0 1055.6 289.3 0.4 1345.2 78.5 21.5 0.0 100.0 289.5 79.2 0.0 368.7 78.5 21.5 0.0 100.0 *** UNIT 99 - AREA 3 FUEL LP HAS BEEN ON STREAM 31.0 DAYS IN DECEMBER AND 365.00 DAYS TO DATE THIS YEAR *xxx STREAM XKKK CHARGES MXKM VOLUME BBLS PCT WEIGHT MLBS PCT T L A K IIJ UA 1C VOLUME WEIGHT MBBLS PCT MMLBS PCT ---------- P5A TfllL GA5 FOE HP FUEL MAKE-UP FOE "18775." 3r:t '------ 3871. 29739. 61.3 7934. *32.8 67.2 2257443.8 289.3 56.2 4878" 36.1 79.2 61.9 XXX* YIELDS XXXK TOTAL 48514. 100.0 11805. 100.0 514.7 100.0 128.0 100.0 FUEL CONSUMED FOE 49027. 101.1 11941. 101.2 515.1 100.1 128.2 100.1 LOSS -513. -l.l -136. -1.2 -0.4 -0.1 -0.1 -0.1 TOTAL 48514. 100.0 11805. 100.0514^7__ 10IK 0128^^100.0 go > o o o o. o .p* IP K* 0590 10*43 ft - i : f- ;1 ' `t ' - - 01/14/33 * :: r 1 r-'. CONOCO INC.-IAKE CHARLES REFINERY >H ME05 - MONTH EMD AND YEAR TO DATE FINAL UNIT YIELD REPORT PAGE 54 WxxX UNIT"95"- FLARE SYSTEM HAS'BEEN ON' ST REAM *311 0 DAYS IN DECEMBER AND 365.00 DAYS TO DATE THIS YEAR * STREAM MX** CHARGES mmxx ---------------- DECEMBER .............. - VOLUME ----- feBLS PCT ML8S PCT -- -- YEAR TO DATE ------------------ MBBLS PCT MMLBS PCT PROCESS FLARE FOE TOTAL KXMM YIELDS **XKN 533. 533. 100.0 100.0 151. 151. 100.0 100.0 7.8 7.8 100.0 100.0 2.2 2.2 100.0 100.0 PROCESS FLARE FOE LOSS 15430. 2904.3 -14947. -2804.3 4957. 3286.1 -4806. -3186.1 224.7 2898.1 -217.0-2798.1 72.0 3320.5 -69.8-3220.5 TOTAL 533. 100.0 151. 100.0 7.8 100.0 2.2 100.0 0591 10^93 01/19/88 CONC :0 INC.-LAKE CHARLES REFiNERY J - MONTHLY FUEL BALANCE REPORT *xx" FUEL GAS M5CF FOE XXXXX HHV MX fuel" OIL xx BBLS FOE TOTAL FOE'S k**x PURCHASES/INPUTS *xxx :3" PROPANE TO FUEL' 10899. 9300. 2529. 0. 0 . 9300 . >G PURCHASED FUEL 501671. 79691. 1012. 0. 0. 79691. IJ JUPITER HYD 197686. 7519. 329. 0. 0. 7519. /H VISTA_ HYD219728_ 19502... 920. 0. 9,. L4 5 0 2_ TOTAL 879939. 106012. 767 . 0. 0. 106012. <xxx EXPORTS/OUTPUTS xxxx IF" EXPORT"FUEL ~GAS------ 533089^------820957 981. 0. 0. 82095. :L FUEL DRUM FLARE 0. 0. 0. 0. 0. 0. TOTAL 533089. 82095. 981. 0. 0. 82095. *** PRODUCED FUEL GAS xxxx 2 NO. 3 CRU A HDS 0. 0. 0. 0. 0. 0. 5 GAS REC PLANT 929999. 180039. 1239. 0. 0. 180039. 9" HYDROGEN SYSTEM 219383. 19930. ` 569. 0. 0. 19930. 5 FCC UNIT 289388. 59258. 1215. 0. 0. 59258. 3 CRYO GAS PLANT 1199218. 177056. 981. 0. 0. 177056. 1 O' CAT POLY UNIT "REFURM"FEED'PREF-------- 0. 22397 _---5fl09.:- 0. 1998. 0. 0. 0. 0. 0. 509. 2 NO. 2 CRU i HDS 228399. 18190. 507. 0. 0. 18190. 2 CASINGHEAD UNIT 26352. 8983. 2171. 0. 0. 8983. 3 ALKYLATION UNIT 0 . 0. 0. 0. 0. 0. I-----5ULFUR~PLART-------- ~ 9861."--------- *73'.'" 620. 0. 0. 973. 7 CRYO FEED GAS "1290239. -216318. 1068. 0. 0. -216318. TOTAL 1559000, 292620. 999. 0. 0. 292620. 3TAL REFINERY FUEL 1900895. 266537. 893. 0. 0. 266537. xxx CONSUMED FUEL GAS **** f----POWER'TLANT----------------- 938680:-----69 0937-- S NO. 3 CTU l VAC 280336. 91583. ) NO. 9 HDS 98568. 7198. NO. 5 HDS 23565. 3992. r~NO--3"CRU I"HDS--219798:------ 25508'.' " ) PREMIUM COKER 81899. 11656. NO. 2 COKER 198038. 23519. . No. 1 CALCINER 37289. 591A^ _ nr~ noi acc iiicit"*------ --~ " or > NO. 6 HD5 7013. 1032. NO. 7 HDS 8298. 1269. NQ. 8 HDS 5109. 755. ~""NO: 2J-CRUDE~UNIT-----T0I293:-------- 19339:- FCC UNIT 61130. 8755. NO. 1 HDS 19951. 2828. NO. 2 CRU I HDS 105225. 15160. THERrtAL~CR ACKER----------60351"-----"8562":------- 930. 0. "O'. 945. 0. 0. 944. 0 . 0. 944. 0. 0. 756 7' 0. - o; 906 . 0. 0. 756. 0. 0. 10 IP.--------- ------ Hr-----------in 0. 0. 0. 937 . 0. 0. 970. 0. 0. 942. 0 . 0 . 902. 0. 0 . 912. 0. 0. 903. 0. 0. 917. 0 . 0. "903. u. -1. 64043. 41583. 7198. 3492. 25508; 11656. 23519 5916. 0. 1032. 1264. 755. 19334. 8755. 2828. 15160. 8562. SAL 0000059-33 XXX FUEL GAS MMSCF MFOE PAGE 55 i_J u_r DAlfc_7~:irjvr XMKXX X** FUEL OIL MX HHV MBBLS MFOE TOTAL MFOE'S 57. 23. 2529. 0. 0. 23. 5983. 953. 1019. 0. 0. 953. 722. 37 . 329. 0. Q . 37. 1521. 105. __439.*. n 0 . 105 8283. 1117 . 859. 0. 0. 1117. 5575. 979. 1112. 0. 0. 979. 17. 2. 930. 0. 0. 2. 5592. 976. 1112. 0. 0. 976 . 6. 10589,. 2623. 3739. 11828. 3. 20. 381. 188. 21. 52. -13327. 16118. 18809. 1. 1999. 295. 719. 2069. 1, 5. 31. 66. 11. 5. -2970. 2671 . 2812. 581. 1202j_ 595. 1218. 1111. 2995. 1971. 511. 2229. 3299. 620. 1180. 1055. 952. 3993. 416. 983. 2855. 445. 992. 457. 71. 993. 215. 33. 989. 1816, ''227; 795: 898. 137. 974. ^^4lirar---- 2AA. 784?" 589. 93. 1008. 1069'. 182. ' "1085. 168. 27. 1006. 134. 21. 1006. 67. 11. 1004. 395"; 1 38 . 989. 506. 77. 966. 151. 23. 985. 1218. 190. 992, 56*:' " ' 87'.' " 9a r: 0. 0. 1 . 0. 0. 1999. 0. 0. 245. 0. 0. 714. 0. 0. 2064. 0. 0. 1 . 0. 0. 5. 0. 0. 31. 0. 0. 66. 0. 0. 11. 0. 0. 5. 0. 0. -2470. 0. 0. 2671. 0. 0. 2812. Tf. ~ * *0. --nr: 0. 0. 445. 0. 0. 71. 0. 0. 33. 0. 0. 227. -------- --9-!----- ----- 73Tt 0. 0. 288. 0. 0. 93. o: o: 182. 0. 0. 27. 0. 0. 21. 0. 0 . 11. o: --0. 138. 0. 0. 77. 0. 0. 23. 0. 0 . 190. 0. o; S7T h m iL. 1591 10`-43 01/14/88 CONOCO INC.-LAKE CHARLES REFINERY ME08 - MONTHLY FUEL BALANCE REPORT 3 ACID PLANT a SULFUR PLANT 3" HOB DISTRIBUTION MXM MSCF 20103. 20812. 41860 . FUEL GAS FOE 2793. 3077. 6011. TOTAL 1774208. 247486. *** NET FUEL BALANCE MXM* (PROD - CONS) 126637. 19051. ***** HHV 885. 941. 914. 888. MM FUEL BBLS 0. 0. 0. 0. OIL K* FOE 0. 0. 0. 0. TOTAL FOE'S 2793. 3077 . 6011. 247486 . 0. 0. 19051. MMK MM5CF 166. 216. 382. FUEL GAS MFOE 25. 34. 59. 18699. 2786. 111. 26. PAGE 56 MNMMM HHV 959. _1001 988. 949. NX FUEL MBBLS 0. 0. 0. 0. OIL KM MFOE 0. 0 0. 0. TOTAL MFOE* 5 25. 3569. 2786. I 1 1 1I I 0. 0. 26. (A > O o o o o VI p* OJ p* ftPPE-NDiy. D ft)A* I Mart) QUMTI Ty O/V-S/TH Title ^c^cc'; r.' Calculation Sheet Joe N H:6:C State SAL 000005435 ffriaxi/'iv quantity on-site.; ns 7 5/hK/t 3/3 fe-no/TT L$KS OO.S.&ltfEr 'f SoQlufr HYORfiXlOt (jSiJt-fu*" Recess* Orvi^-or) ^") " (r-\ ) 5*0 8hk - 310*-- C-iiif: (it, V a - V --------- x' OsO^Y &A >I / 7.^?tc6-f 1A fr-iO 5*0 x ^7- v 6=*.^ x <.S" = _7J 700 1^ lie yntor Cr-H*) Too xjii. X O.IZ: ,-z> ' ^-p-^O ?..H%^ \ xjfi_ x 6?2.Y *^-5" - 5& x 3JL~ v^2-^X >. X5" =. t/S S !h ?.Y?or SH.T'(-p- 5Tj T-5&) 2720 X M * ^,2f = S"7 ?o/ 7,^oS :T-2>^' H KQ X ^ 7. HVOT (V- ZO^ZJOS^ *2 X ^5^ ^k'Z.Y ^ 0. , x^|x<3 ^5T - ^'?.c53 *'6:^ZOJ- 7 7, CT-f^oi^ *2^(00 * Y Z ^ /r,o (4 x y.HW* O.^o , i t*i%JioQ & UQtKjHoo (k * <2. IS sp-c- A ~ I, 4 ^ xfo^ 7 es^-ic ^ uv*'4^ / - id> >c /o^ /fa Conoco me Calculation Sheet Title Jcb No F.eid State SAL 000005436 ( HYDROCHLORIC &<L\b - \ ~ lG x /O LQ ( ^ H~&i 4=. '-' c _ - - /YS7) ^-e;v ^ Olk'/j.'s^ fYo-'iii) oCJLP^.iC Ac'C - (-T-1202.) 2. too X Jj_7 *U>^H X O.Lj ~7.H%o<r 2 ^ ~ 1 c c _/? (r-\?oi) 2iooooe,i x ^.tL, x 7.^r /.*V 15"^?^ <* ('r-fS^Y.T-iSor) 2 < izkcoo * 62,^ _ 7 Wo? '* J.2Y = 3 ; ic 0>O -cf K JiML x ,<70* /.<?Y - I, - 7, YS^S- (T-^07) ^2 000 J A &?.'( x ,W * 7. H%o^- .*4 = 5^0 zoo u 3(0-74-0-71* Lp * <px> esis* j/ _ nM%o5 .40*1 si ) l^OfOo V (0-& O-zf) -i^seo k 57/Ss- * U~i. i * 7S * (i,3i ^00 ls pHEflo L CSol^v*' - i I Z X I?!.Jr- i * (o'7 - S"x/0 'X ^<V`"Sf1,E`-' prs+i/e ^ 2,'^JiL- X&?.7*0.0 7. yyas" * O.U*! 2,0 3^100 c x I0r - i *r (0* ccte&L 203^100 t& x o.is* I XT'IO ^ - I *rrO^~ Title ^ _ ______ V. Caicuistion Sneet 3p^HCe r ^a SAL 000005437 p- PrUJ^iNu^ 0)0 DS- Sta^oo (BEricer<) - '6,?ao * + (. Hti, -+ /^J^Voo (tBiLo&c'j /(p ij ^ zil^os>(uiP) + t %z,7C6 (rc~j - i f yj^J C*C~ fTLsr>) - 2.J x 10 c.i -- | O > (O (-8 g/HSC /V fhrtcA Cny'\ MAMg-anc ic Arwcf/tA KBthMol %u> BBL k h-z ^ * //,r HO v' j - lOKfO ^"T;/<? i iV3 X s, 62 - 2r. ?^o k &0oo Ser > H~l '"'/6K. 7-^ ^ /cr 6>2> ^ ^ x <3.77 = ^/5" x/ CJr ~\0 K (O^ L& WoU-i&OfL lU^' --fi.iOXiCB ' *&Oj.30O*\f5"- (2 030 X <40^ \tr/<T$ - ^7^ coc JJ J J--10 oV PortcA C.lT'i: ttiCKZL -- goooo x ^ ^ 32^0 ^1^^XT ,7V V/ X toStUsMS.Prcc ^ f ^ 10 x 10 * 4JL_.. CWLOP.Mt Pri^spH-ofiic Zi * l>0 0 ^Vt/w* * 5" C.T, - 2/ ooo cs I - 10 < (0 ^ Cfi C Po^r Pro-P/e_3 }(o ^OOO X .62 - l& t$flrSf>C 3/V poNC^ CT Esri#viAT(T U4/C6 CJM&lES t-lO*IOw $} ]i Title CC~CCD inc Calculation Sheet SAL 000005438 JcC No. -.eiG State Cog* ZOjOOO X .OH- M3-z^o N'fc+ x , lb Cc W ? WOS s bQTC? * 0/7 r^/VcA- C/TV ^ C=>*V< t$ T ' -'v' z1' Ti I- to * /Ow' L crt^^'?: zi-2 SoClJs> S^^F/47F (;-/S'o^') ItffoocTM x 6?.? _ ^ 005" * IMtO? *2- * ^ -- A 3^ Ik t~T~ (ZO~l ) <f t 030 -So. f v 6: z. x* O .o5~/' :5kr~ 7k ; => ^.7*-0-7-)4v5aa ,, x------------ NX iz, ^ < aorv'7Zr*ii /kifl^rS*"" c/7) fc $2c/' X IH Z nu> ~ IOr 'O^ c C,i : i S'OO !i> V; -- Tfc icH<lo^o BTtiM/E - S"2 x SIT x 8\ I 3 2- Y ; !>o& -- | o *" to 4 Calculation Sheet itle AL 000005439 JOE No r e <j State ON OV7900000 "IV$; laa^S uoiiejnDieQ -- :-cuco ~ ^O) -* Ql-l ,oO`o - S'1 9 0 \xSO 'L - ,0] x (^O0'C> x ZO + lo `O +-S oo'PxZ'b f ^o`C? xi^i S-*C> * : 9// - ^ oo'O xL'? - soo'0 *Z$.hJ suo\ x Ol - ,0\^(^-S00'0 x |Ol 4 300'O X\,h + >0`O * IS + SO'C? '/, + rSO*o >3r^/ r iO'o *^<9 ^ ^O'C X <9/j 0&0'0 x -f Z^^co ip X Z J?y ~3hO~7~)i y z -)N3Z// Loi*s- i = j?/* r - ,OI x-(300'Ox J o +i,oO'Oxtfc + I O'o x /3 - c.<q'qx z.'h f Lio'O x S)i + o'O x hV + t~\G>'o x o/f + LlO'O * L`7 + -SDO'O X ZLb ) - 3/J3?A>ag OA HJ_3 ^ : _C-: X Ol -3 Ol X {Sco'Oxlct+soo-oxLh ~ShO`0 xis + (gLO'O xZ'h -* O > 3s)! -* ti-O'O X ^<9 - tLO'O X 9)/ ^ tz.0'0 X 4? ^ ^ -- j.`,'JO-jc^ V7 LVI >< _$- ( XO'I loo'o* bh /O'O X / ., + gio1! hZO`Ox' h) + 4/D'O x <9// + /7IC 7jO) X / oo'O X I 0*2. + 'C'f, + G'CQ'O * S'?/ * x L*i + ^oq'<7 x = 3/^^/vsg ` I Q bh IS Z'h '$<01 ho < -Oil G^.b $7*01) -?9V3eiS 'WW 3AJ.-c>sy-9 {p3S310) 31&-77USI0 rff \` 3 zQ rj izJ)^ 0^33 33# doiS 3/vn<?<{if) Q3 HSl/yldN^ r ms ^ 3WISG'>^9 "?n 4 '-93^ "710 ~7if\ >f3J--VLj f ^ 2 X 0.00*7 + (c7 * 0,7 1 +- life x O.Oi ^ * O, 7: + IUSx o.o i *- ^,2 * 7 o , - V? x o.oos" - 3c x C.CC7 ') >* fO (+ : -5~ *ffl7 L-6 P$EODoCu/^eq - ( ^32.* 0.00 O < &7 vC.cz- T' r\U > 7,72 -t ,0.^(07 - I - S' * |07 L<S 6: / < 0.7 3o I X o.oosy- 5Ty /<~ 77 MPHTH/UENC (432* O.oo sr t fr-?* a.oi 4. >(Cr * 0.0 l + 6 T - c , c ; 0.0 I^ I G'~ * J cf,2 jr d .O I + 41 X" o, COS" * SO I *c .car) > ) --5" v- (O7 *r o.O3 -<- 5,0 l vo.oO * - /OK'O1^ i-3 - I -fO > ^O g|Pt4F/7yc (- 0/i(e<( r /,f * )0.0 1 X lo Co _ 3, 5^/0^ c/3 -/ <0 X I0r ^ E.TK YCE/VE. - Fro** P^. BboJoa^k e^^ol &icu o^S C2 1,000 L. S.-/f -------- ^---------- r------------------- *' '';------- --;-------- i.Cf/x'iO* ug -f^y, Prtdt/cjeJ/yeor _, . j -ci - l>76 '0 lb F-ik o* S -------------- ------------ '3 f-' /v,,. 1-- .O, fffo* Uaz>K ' I SeF P6. x / | /*> *( p`-6'\{lfs>.(eZ'2- lb. F.&. \ 371 ScP r.cT/l, 15 $ - - ).3>a. x 1(7 It f;s. x o. I 1 /, 3 2*(0* II, -i "f^e fi* /" _y *777 f&to &r UC, (J.ttx to lb 7V^ 7</yr -- 1-10* 10 f L& .SZ-^O8 lb r-/(. pr~e *(o'i lb -tUr a. ftoPycE/VE 1.1- gor/=D)t/V 1-10 x- 1 oft..*r& ) - !O x io1 (3<4?ec A/V5 coai,?4^i s^ t'/,hw r'^ii c <? CbfaP.LCi- Cor'7f\((^,'J of= Fvpl, g-fo srairc or] S'Tf Title Ccic-jiai'or Sheet SAL 000005^41 Sts:e 1 i^Mf i&'of t'f&n PRODUU NAME TIRN VAPOR VAPCfi iINS WORKING TOTAL TAW CAP. MAN, OVERS PRESS VAPOR SPACE PAINT SIZE TURNOVER LOSS LOSS LOSS NO. HBBLS FT PER YEAR PSIA NOL. NT, FT FACTOR FACTOR FACTOR tpy TPY TPY REFORMER FEED REFORfCR FEED 193 80.0 120.0 SO 55.0 100.4 1.5 1.3000 68.0 4.1 1.3004 68.4 REFORMER FEED CRACKED DIET KEROSEW KEROSENE 69 55.0 100.0 4.1 1.3000 68.0 21 25.0 67.0 5.0 0.0150 68.0 94 2.5 25.0 10.3 ,0.0150 130.0 95 2.5 25.0 10.3 0.0150 130.0 KEROSOC t 2 DISTILLATE t 2 DISTILLATE t 2 DISTILLAlE 1 2 DISTILLATE f 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE t I DISTILLATE 35 8182 201 202 343 351 370 74 75 76 378 22" 80.0 120.0 150.0 25.0 15.0 80.0 80.0 80.0 150.0 ISO. 0 150.0 80.0 25.0 120.0 134.0 150.0 67.0 60.0 120.0 120.0 120.0 150.0 150.0 150.0 120.0 67.0 10.3 28.6 10.3 467.8 467.8 3.8 3.8 3.8 29.8 29.8 29.8 3.8 108.3 0.0150 0.0(20 6.0120 0.4124 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 OP FPSTK OP FDSTK 344 80.0 120.0 345 150.0 150.0 19.9 0.0 0.0124 130.0 0.0120 130.0 LT. FEEDSTOCK 342 80.0 120.0 4.9 0.0120 130.0 LT. FEEDSTOCK 340 80.0 120.0 4.9 0.0170 130.0 HVY. FEEDSTOCK 297 80.0 117.0 4.? 0.0120 130.0 HVY. FEEDSTOCK 338 80.0 117.0 8.5 0.0120 130.0 MS OIL 6AS OIL 36 80.0 120.0 26.6 0.0001 190.Q 37 80.0 120.0 28.6 0.0001 190.0 SA$ OIL 93 120.0 134.0 8.5 0.0001 190.0 8AS OIL 100 150.0 150.0 28.6 0.0001 190.0 SAS OIL 101 150.0 150.0 28.6 0.0001 190.0 SURRY SLURRY 71 25.0 67.0 n 25.4 67.9 5.0 0.0401 190.0 5.4 0.4441 m.o SLURRY 73 25.0 67.0 4.7 0.0401 190.0 SLURRY 299 BO.O 117.0 5.0 0.0001 190.0 SLLRRY 308 80.0 117.0 5.0 0,0001 190.0 COKER FEED 67 55.0 (00.0 13.6 0.0001 190.0 COKER FEED 91 80.0 120.0 1.8 0.0401 190.0 COKER FEED 20 25.0 67.0 13.6 0.0001 190.0 COKER FEED 66 55.0 100.0 6.3 0.0001 190.0 COKER FEED 90 80.0 120.0 13.6 0.4001 190.0 COKER FEED 400 25.0 78.0 15.5 6.0001 190.0 > COKER FEED r~ COKER FEED 3801 3802 200.0 200.0 190.0 190.0 21.4 21.4 0.0001 0.0001 190.0 190.0 COKER FEED 3805 200.0 190.0 1.8 0.0001 194.0 o oo flffP" m-- 1 6 FUEL OIL 84 150.0 150.0 8.5 0.0001 190.0 o 1 6 FUEL OIL 89 150.0 150.0 1.8 0.0001 190.0 o 1 6 FLO. OIL 355 15.0 58.0 3.8 0.0001 194.0 1 6 FUEL OIL f* 1 6 FIB. OIL ro 1 6 Fia on. , 1 6 FUEL OIL 354 398 3803 3804 15.0 90.0 200.0 200.0 58.0 120.0 190.0 (90.0 3.8 8.5 21.4 21.4 0.0001 0.0001 o.ooot 4.0001 190.0 190.0 190.0 190.0 DOST OIL NT-1 0.6 15.0 0.0 0.0002 190.0 DOCK EDC DOCK ALCOHOL 415 50.0 100.0 416 55.0 110.0 0.0 1.8375 96.6 0.1 0.0140 145.0 DOCK ALCCHOL 672 10.0 43.0 0.2 4.6140 145.0 DOCK LAB 910 25.0 60.0 4.1 4.0002 190.0 OLEFIN 4300 0.3 11.0 0.0 0.1560 160.0 HEXANOL PAfFTWfF 4301 O.t 8.0 0.0 0.1000 100.0 1 ft"? *1 A ' ' ' 19.9 19.7 19.7 19.9 14.3 14.3 19.9 23.9 23.8 19.9 14.9 19.9 19.9 19.9 23.8 23.8 23.8 19.9 19.9 19.9 23.8 19.9 19.9 20.9 20.9 19.9 19.9 23.9 23.8 23.8 19.9 19.9 19.9 20.9 20.9 19.7 19.9 19.9 19.7 19.9 14.7 19.8 19.8 19.8 23.8 23.8 15.9 15.9 22.3 19.8 19.8 8,0 17.0 16.0 20.0 24.0 7.5 5.0 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.60 1.40 t.oo 1.00 1.60 1.00 1.00 1.00 1.04 1.04 1.46 1.46 1.46 1.46 1.46 1.46 1.00 1.00 1.46 1.46 1.00 1.00 1.44 1.46 t.46 1.44 1.46 1.46 1.06 1.30 1.30 1.30 1.46 1.46 1.46 1.46 1.46 1.30 1.30 1.46 1.06 1.00 1.06 1.00 1.00 1.00 1.00 1.00 1.00 1.00 0.97 0.97 1,00 1.00 1.66 1.00 1.00 1.00 1.06 1.00 1.00 1.04 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 t.oo 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 i.oe 0.75 1.00 1.00 1.60 1.00 0.59 0.53 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 (.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 0.95 0.95 0.60 0.60 0.85 0.85 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 12.55 9.11 9.11 4.21 0.06 0.06 1.09 1.24 1.50 4.34 0.24 0.93 0.93 0.93 1.50 1.50 1.50 0.93 0.34 0.93 1.50 0.93 1.36 1.34 1.34 0.08 0.08 O.il 0.08 0.08 0.83 0.03 0.02 0.05 0.05 0.46 0.08 1.02 0.06 0.08 0.02 0.15 0.15 0.15 5.35 10.05 10.05 0.06 0.03 0.03 0.81 2.70 1.21 9.20 5.52 0.24 0.24 0.24 3.51 3.51 3.51 0.24 2.13 1.19 0.00 0.18 0.18 0.26 0.45 0.12 0.02 0.01 0.14 4.44 1.04 0.00 0.00 0.00 0.00 0.01 0.00 0.00 4.00 0.41 0.00 0.04 0.04 0.00 17.90 19.16 . 19.16__ _ 0.27 0.08 0.06 1.89 --nr 2.72 9.54 5.76 1.17 1.17 1.17 5.12 5.02 5.02 1.17 Jdl "TIT 3.50 1.12 1.55 1.60 1.79 0.10 0.10 O.M 0.13 0.13 0.03 0.03 0.12 0.06 0.06 0.06 0.08 0.02 0.06 0.09 0.03 0.19 0.19 0.15 1.00 1.00 1.00 1,00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 0.12 0.12 0,02 0.02 0.08 0.15 0.15 0.00 15.62 0.89 0.20 0.03 0.02 (i.OI 0.01 0.00 0.00 0.00 0.01 0.04 0.04 0.00 0.00 Q.Ol 0.00 0.00 0.00 0.00 0.14 0.13 0.02 0.02 0.09 0.19 0.19 0.00 15.62 0,89 0.70 0.03 0.02 0.01 3.94 TOTAL CAPACITY fNBBLS)* 4709.2 TWOUMPUT (MBLS/'YR)* 35.4 TOTAL fit * 31W 01 SNOISSIB fi'Kfi `009 0'?2 CO! 2'0O 279 O'O 07 CO *! Cl 6*C 27 27 ri CO DO c CO n CO 07 CO it Vi Vi Vi ' Vi Vi CO rot 0*Ct 0# viz roi CM SSI r> c vu 0'62 O'CI O'Ct vu vu vu Z`U r>2 2 >72 eri 2*21 e*i2 8*12 r* 2-21 VU Vc 2'C Vi Z't :*> Vi CO O'O S'O ri ri 7 n 00 2 11 `0 Cl l`0 CO 97 2'0 Cl it C 2-S rr Vi Vi CO mi C'CI 9`0 VIC Ml >71 >71 c> ra 2'92 9'2 871 CM 8'0C COC rci 2*CI >72 >72 172 9'CI 9'EI 2`2 02 2`8 rei 2'C1 7 `> Vi ft ft rc O'O CO 0*0 27 Vi ri) CO CO Cl * O'O 2'l 07 0*0 CUD TT 2*1 1 CO 1 9*0 ] 97 - to Cl Cl CO Cl ft 9*0 C'e M 0*2 0'2 CO ox 0*C 97 0*1 Cl 7 97 Cl Cl 17 07 VI Cl >1 C'C VI Cl *l Cl TTH CO rt 97 97 CO CO 07 07 0900*0 07 07 07 0900*0 07 CO 0 0 0900 7 17 cr 27 0900 7 07 9'l 27 0900*0 07 CO 07 1007 07 87 CO 0900 7 CO 87 17 0900 7 00 2*11 n 1007 07 7 07 1007 --{*------- --m-- STTC^O 07 Cl 27 tm*Q O'O 17 00 100*0 07 17 07 1007 '97 Cl 1007 ' 27 07 1007 07 rr 27 1007 07 l' CO 0900*0 17 it fit 09007 17 IS 7 09017 17 CO 0 0 09017 CO CO C0 09007 CO CO 07 09007 97 07 Cl 09007 27 i*n Cl 09007 CO 971 r\ 09007 97 O'O 17 09007 17 2'2C 27 09007 27 2'Ii Cl 09007 27 271 2*1 0900 7 27 271 27 09007 17 C> SI 1900 7 7 8'82 C2 Q9007 >7 0'2 92 09007 7 2'2 27 09007 >7 >>l O'l 09007 17 O'M >*l 09007 7 cot 17 0900*0 97 CK 17 0900*0 27 Ctl >'l 0900*0 2*0 9'l >*l 090C9 CO 172 2*2 0900 7 CO 172 27 09107 07 172 27 0900 7 CO 9'CI 07 0900*1 17 9'EI >7 0909*0 07 CO2 0 7 0900*0 27 C02 0 7 09007 27 07 27 09007 17 9*CI 07 0900*0 17 9'EI C5----- ~~Tt 7 Z't 07 O9007 "IT'' ~Tisn" >7 1007 >7 fi 97 (1007 17 rt CO 1007 CO rt CO 1007 17 CE 7 1407 Adi Adi Adi 31M Oi "W33 AHwidj 1w$ ua 1UW3U $$01 HflGl * Adi 3901 'mw Adi $$oi 'aio AiftWWi Adi 5901 7l$ Ida aoid 39**1!) 8701 > lUA/siaawi nuonoaHi itec (ST83HJ AilttdtO TPJOi >7 OO'I >'8 00'! > *8 OO'I >7 OO'I >7 OO't >7 OO'I >'8 OO'I >7 OO'I re OO'I ____a____ ___ 00,71 re 00 71 re 0071 >'8 1071 >*8 0071 >'8 00*01 >*8 0971 >7 00*01 >7 OO'I re OC! >7 OO'I >7 OO'I >7 OO'I >7 OO'I >*8 OO'I >'8 00*1 re OO'I >*8 cr re OO'I >7 N'l >8 00*1 >7 OO'I >7 10*1 r OO'I >7 01*1 >7 00*1 >7 01*1 >7 00*1 >7 10*1 >7 00*1 >7 00*1 >7 00*1 >7 00*1 >7 OCI >*8 00*1 >7 00*1 >7 00*1 fi 00*1 >7 00'i 07 OO'I re OO'I >7 00*1 re on >7 oro >7 oro >7 on >7 oro >7 oro H* yoiWd 13.1 JN1N - 'inaJ C'2 C2 C2 C2 CL >'2 C2 VI C9 --CO------- 19 C9 2*9 2'9 9*9 2*9 1*9 l'2 CL 1*2 O'L 9' 9'S 9' 9*6 9'S 97 97 97 97 97 97 97 97 97 97 . 97 97 97 97 97 97 97 97 97 97 97 97 97 97 97 i*2 I'2 I '2 C2 rt rt 0*901 0*90! 0*901 0*901 '90i 0*18 0*901 0*901 0*88 '2M CtM 721 C02I 0'2C 721 C2H D*0 COS 9*0S '1 0*89 0*89 07CI 0*89 0*89 fi 'OCI C89 0 *89 0'89 C89 0'89 0*89 0*89 0*89 C89 0*89 0*>9 I'M 0*>9 079 979 I'M C>9 I'M 79 0*>9 079 0*>9 *>9 O'M 0*0 O'OS O'OS 0 7 O'OS 6'OS ' >7 07 DC >7 07 oc >7 07 c> 97 07 041 97 07 001 0*2 07 041 ro 07 2 >7 07 C2 0*9 07 29 --ri-------- 82 07 c> $2 07 87 80 0*0 0*> 2 07 0 *> 2 0*2 6*91 S 07 >7 Oil 07 7 Oil 97 0 7 2C 9 CO 1C 9*0 6*0 It. 07 *0I 021 9*8 Cl -> 9*8 SSI O CO 2 'OCI ' 9*8 CSC ?S 97 ClJI 29 07 270 2S 97 rt Otl 97 * 25 97 1 ' 06 97 CSC 08 97 S*2 12 97 '8C >0 97 2'9C 02! 97 1*12 0(1 97 272 29 97 Ct 29 97 2*62 OSI 97 2"9C 051 97 9*92 29 97 9*92 29 97 CC2 Cl 97 1*12 0 97 17 tl 97 C2I 29 97 C2I 29 97 CCS 021 97 CC2 021 97 CI2 021 97 C9I 29 97 C9I 29 ft <`6> 081 ft fit . 961 ft fit 0S2 ft VU 002 ft vu 802 ft vu OSI 100/61 'I* "BH Olid $$3Bd HP3a H3d 133d SNW Oil HOdwi BCUOA 3181 $B3Altau H3l3wM sr \1s \ 8-1H 01 2-LH ss 9 IN S-1H JtilAXWd 'j 3N31AXO!Wd ' 31WaOJ3a AAP3H i -* 3N31AHWd 3VM(W4- ' r ss >-2N iiU-Jiii aiowaoisj oc C-W 93N3UX 4KIH oc flT 2-iN , $31AX 03X2H 5* J-l" -_______------- ------------- 921 Niidoaod 'll c SCI NldJrtftM 'i! 0$ it (tidied c 26 NIJiPHPd AAP3H c 96 NlJJHaPd AA03H St 0> >3WH13H ss 20> HI ddPftd *AAH i1s 6 6SI Nidjaaoj 'n m > 02 XV, s Ct 4VH Zt dCS 08 tc O -3N3SOM34 l~5r~7* 29 03t$lNldMI 41 19 JII10SW 43HSINIJI1 fcJ >2 o -110 $W H3KD irtjn SI 6! 3NID8WI 03KSINrJii OC if 3A1T0$C< 03A$lNIdM! ~*SI a o -110 SW> H3AO) IH'JH 951 90 3NCB9W 03<SINIdNn SI 81 JflDSW oatSINIftl SC 66 3HI10SW 03H5INI741 SC 86 3NI105W 43HSIN1JH c C 3NITOSW 03HS1MI7*! 021 u mxm aiKsiNiHi 08 1C 3ai3Stf8 4$1N!M! OS! 6 3NI33SV9 03H3IHIW1 2 6 3UH9SW OKSINIill 2 dL 3NITOSP9 43K9INI3N1 OSI 88 3NM0SP9 43HSINI3 OSI 28 3NI10SW 43HSINli 52 C6 3NfSW 43H$Md S2 26 3W10SW 43H9INIJ 021 .06 3NfT0SW 43HSIN1J 021 62 jhiiosw liJfsiNU 021 82 3NI13SW J3HSIN1J S2 9 dNlXSOO 43HS1NIJ 2 >9 JillOSW JUSINIJ 08 ee JiCBSW 43H$lNId 06 IC 3NIT3SW 03H3IM1J 06 0 suiosyo '.msiNu S2 92 Jinosw <!3HSIWd Sc 2 3NCWSW 03HSINId 002 uc 110 >1(111 (k(2 zu no nm 44> 1 Li 0S2 m os: it>: SI 241 920 JOiWJ lio 3-iiia) no 3'JiiHi no 3<iiw) on '] ,#i 3WPN "ll.'OJ / <- -4~ t ,, 1 1 -- ' SAL 000005444 1. SULFUR PROCESSING DIVISION The Profile provides a general look at the Sulfur Processing Division. The process information given here will be expanded in depth in the individual manual sections. PURPOSE The Sulfur Processing Division Is responsible for: 1. The unloading and/or loading of sulfur, fresh or sfent acids and caustics, via the loading rack; spent acid, fresh jcld and spent caustic storage and transfers within the tank fare storage, mixing, and transfers throughout the refinery of various strength caustics. 2. The regeneration of spent acid from the A1ky1at1o4i Unit to an acceptable grade of sulfuric acid for reuse in the alky atlon process, and the processing of waste gas streams with high corcentratlons of amnonia (NH^), and hydrogen sulfide (N^S), Into a mark*table grade of sulfuric acid. 3. The removal of H^S and NH^ entrained In the sour water received from the various refinery divisions, so the water may be rtiised within the refinery or leave the refinery as an environmentally safo effluent, via the Reformer Division. 4. The removal of H^S, entrained In the propane butanes (PB's) from the No. 3 CTU Division, as well as the removal of H^S entrained In the tailgas from the various refinery divisions prior lo Its use as Cryogenic Unit feed and refinery fuel gas. 5. The regeneration of H^S laden rich amine received firom contactors throughout the refinery and Vista Chemicals, into a relatively H^S free lean amine, for reuse in the refinery and |/1sta Chemical SAL 000005445 P^ofi'e 2. GENERAL DESCRIPTION LOADING AND TRANSFER (SECTION 1) (See Figure 1) The loading and transfer section Is divided Into three parts: Loading Rack, Tank Farm, and Caustic Mixing and Transfer. Loading Rack I. Rail Car Loading Rack The loading rack is made up of ten rail car loading spots (or stations) and three truck loading spots. The following products mqy be loaded or unloaded at each spot: Spot I - Unload SOX caustic rail cars and trucks. Lod<d spent caustic (acid oil or sulfides) rail cars and trucks. Spot 2 - Unload 50% caustic rail cars, load spent caus tic (acid oil or sulfides) rail cars. Spot 3 - Load or unload 931, 96%, 98% sulfuric acid ral cars. Load or unload spent acid rail cars. Spot 4 - Load or unload 931, 96%, 98% sulfuric acid ral cars. Load or unload spent acid rail cars. Spot 5 -Load 93%, 96%, 961 sulfuric acid rail cars. Spot 6 -Load 93%, 96%, 98% sulfuric acid rail cars. Spot 7 -Load 93%. 96%. 98% sulfuric acid rail cars. Spot 8 -Load 93%. 96%. 98% sulfuric acid rail cars. Ideated at Spot 8 Is a truck loading station at which 93%, 96%, 98% sulfuirlc acid can be loaded. Spot 9 - Load product sulfur trucks or rail cars. Spot 10 - load product sulfur trucks or rail cars. SAL 00000544*> 4 Prof:'e to transfer sulfides or acid oils to the loading facilities. The SC/RC Division sends sulfides from the caustic wasp tower to T-204 and is gravitated with T-203 and T-205 to provide add tional storage. Sulfides from this unit are sent in batch amounts. Sulfides in T-203, T-204, T-205 can be pumped directH to the loading rack at spots 1 and 2 or to T-1802 with P-231 or P-82. If there would be any hydrocarbons in these tanks they could be pumped to the heavy slop line going to the Pumping and Transfer Division. Provisions for truck loading 1$ also present at these tanks. The 98X sulfuric acid, also referred to as fresh acid is sent to the Alky Unit, No. 2 Reformer and Power House Division, by ejither pressuring with nitrogen at about 35 pslg or by pumping (P-1805). Fres h acid Is stored in two horizontal drums, called bullet tank, D-80 and 0-81. Fresh acid can also be stored, in some instances in 0-78 and 0-79, but tpese bullets are usually used as spent acid storage. When empty, these bullets are filled from T-1803 with P-1807. P-1807 can also pump fresh acid directly to the Alky Unit. The fresh acid sent to the Alky Unit In the Thermal Clacking Division is vital to their operation, and It Is Important that the ^cld flow not be Interrupted. The "used" or spent acid is pumped back to the storage area from the alky unit to bullet tanks D-79, D-78, D-77, D-76, 0-75 and )-74. The spent acid is sent back at about 89-921 strength. As spent acid is pumped back to the storage area, liquid hydrocarbons are sometimes entrained with the spent acid. Since hydrocartbons are lighter than spent acid, they will separate and "float" on top of the spent acid and can be removed. 0-74 Is reserved for storage of hydrocarbons. SAL 000005447 6 Profile Cracking and Sulfur Processing. Caustic at 25X can also be routed to the SC/RC Division. T-50A and T-50B can also be used as 25X caustic storage. These drums are used as backup storage after dilution and mixing in T-54, T-55 or T-56 In the event of low 50X caustic Inventory. Caustic at 12X Is stored In T-45 to be used by the Alky Unit for their process. T-45 is filled from one of the mix tanks (T-54, T-55 or T-56) where 12X caustic has been prepared. T-l Is used as 4X caustic storage for the No. 3 CTU Division. This 4X caustic Is transferred with pump P-22X to that unit. 25X caustic from the mix tanks and well water, at specific amounts are used to mix 4X caustic. A recirculation line from the discharge of P-221 back to T-l continuously mixes the caustic. 0000054A8 SAL 8 Loading and Transfer SECTION PROCESS EQUIPMENT Drums D-74 D-75 D-76 D-77 D-78 D--79 D-80 D-81 Pumps Driver/Innerdrlver R-4 Recipr. steam driven R-102 Recipr. steam driven R-113 Recipr. steam driven P-1804 M-1804 P-1805 P-1806 M-1805 M-1806 P-1807 M-1807 P-1808 M-1808 P-1809 H-1809 P-1810 M-1810 P-1811 M-1811 P-1801A M-1801A P-1801B M-1801B P-1801C M-1801C P-221 M-267 P-82 M-265 Description Alky Spent Acid Alky Spent Acid Alky Spent Acid Alky Spent Acid Alky Spent Acid Alky Spent Acid 98* Acid to Alky 98* Acid to Alky Description Caustic Transfer Caustic Transfer Caustic Transfer Alky Spent Acid to Blend T^nk 98* Acid to Alky Alky Spent Acid to Blend T^nk 98* Acid Product loading Spare Acid Product Loading 93* Acid Product Loading Hydrocarbon Skim Pump on Tl-1806 Spent Acid to Blend Tank (Acid Oil Loading Pwnp- , Acid Oil or Sulfide Spare .oadlng Pump Sulfide Loading Pump 4* Caustic Transfer to No. 3 CTU Division Sulfide Loading Pump AL 0000054-49 7 Loadirjg and Transfer SECTION EQUIPMENT DESCRIPTION R-4, R-1Q2, R-113 Caustic Transfer Pump These are positive displacement reciprocating pumps driven from the steam piston end of the pump (steam chest) by ISO psi steam, The steam from these pumps exhaust to the atmosphere. The product side and the steam side have adjustable packing glands at the piston rods. P-1810 and P-1811 - Spent Acid and Product Acid Transfer Pumpjs These are motor driven centrifugal pumps with all wetted metal parts being made of alloy 20 to resist corrosion. These pumps are equipped with mechanical seals which are flushed with product recirculated from the discharge. The Impellers and driver horsepower ratings of these pumps may be slightly different to compensate for performance requirements of each pump. P-1801A. P-1801B. P-18Q1C\ Sulfide and Acid Oil Loading Pump These are motor driven centrifugal pumps made of 316 sta nless steel to prevent corrosion. These pumps are equipped with mechanical ;eals which are flushed with product recirculated from the discharge of the p^imp. P-221 - 4% Caustic Transfer to No. 3 CTU division This is a motor driven, centrifugal pump made of cast tron. The pump is equipped with a mechanical seal. P-82 - Sulfide Loading Pump (No longer in service) This is a motor-driven single stage turbine pump wlt^i a mechanical seal. P-231 - Sulfide Loading Pump P-231 is a motor-driven centrifugal pump equipped with a mechanical seal. SAL 0000015450 9 Loadi ng and Transfer T-50A and B - 25% Caustic Storage This is a 9 foot 0 inch by 44 foot 0 inch long horizontal drum with a partition separating the A and B side of the drum. The t^tal capacity of this drum is 500 barrels. T-54, T-55 T-56 - Caustic Hix Tanks These are open dome tanks each being 11 foot 0 inch bj 12 foot 0 inch high with a capacity of 220 barrels. T-203 - SC/RC Sulfide Storage This is a 12 foot diameter by 24 foot high, open vent Atmospheric flat roof tank with its capacity being 480 barrels. T-204 and T-205 - SC/RC Sulfide Storage These are 10 feet in diameter by 24 feet high, cone ^oof, open vent atmospheHc._tanJks._w.iJ:h a capacity of 350 barrels. T-1801 and T-1802 - Acid Oil and Sulfide Storage These are 25 foot diameter by 24 foot high dome roof tanks having a capacity of 2,100 barrels. Each Is equipped with vents to the atmosphere. T-1803, T-1804, T-1805 - Acid Product Storage Tanks T-1803 is a 33 foot 6 Inch diameter by 32 foot high dome roof tank. It has a capacity of 210,000 gallons of 98% sulfuric acid. The product enters the tank at the top and travels down an Internal line to this bottom of the tank. Regulated nitrogen is pressured into the tank to provide a "blanket" to prevent air from entering the tank and causing oxidation on the tank walls. Vents are also provided on these tanks that run to gjround level for added safety. T-1804 and T-1805 are 26 foot In diameter by 32 foot high dome roof tanks with a capacity of 126,000 gallons of 93-96% sulfui ric acid. The associated equipment is similar to T-1803. SAL 000005451 11 loading and Transfer Here the spilled materials can be neutralized and drained to the surface sewers or taken off with a vacuum truck. Water that accumuldites in the acid storage area is disposed of in one of three places. If withi n specification (less than .1 ppm phenols, less than 5 ppm sulfides, pH, 6-9) the water can be drained to the storm water sewers. Water that does not meet these specifications must be removed by vacuum truck and dumped either at the API traps or T-115. Since the No. 2 Reformer Division top operator is responsible for the waste Mater treating system, he must be notified anytime water is drained or haulejd off. Sulfur Product Line to Loading Rack Since sulfur will begin to solidify below 245F, it Is important to keep the entire product line hot at all times. This is accomplished by a double wall steam jacketed line. The six inch product line is surrounded by an eight inch line. 50 psi steam is injected into the eigh'; inch line and the condensate is trapped out at different points along the line. Hydrogen Peroxide Addition to Rail Cars and Trucks A tank, pump and associated piping are provided in the event hydrogen peroxide must be added to a rail car or truck. This equipment is located east of T-1805 by the retaining wall. Spots 3 through Spot 8 and the truck loading rack have the necessary connections for adding hydrogen peroxide. ocoO 13 Sulfuric Acid Plant 1. the process This section of the Sulfur Processing Division Manual covers the Sulfuric Acid Unit. Within this unit four (4) distil :tly different processed are combined to yield the finished product. These processes are: 1. Formation of sulfur dioxide. 2. Cooling and purification of the S02 gas stream, 3. Conversion of S02 to SOj. 4. Absorption of SO^ into sulfuric acid (HjSO^). Because of their close interrelation to one another however, "Conversion** and "Absorption" will be combined into one step* PURPOSE ANO IMPORTANCE The primary purpose of the Sulfuric Acid Unit is the regeneration of the Alkylation Process Unit spent acid to an acceptable gr^de of sulfuric acid for reuse in the Alkylation process. The secondary purpose Is to process waste gas streams with high concentrations of hydrogen sulfide and ammonia and using these environmentally objectionable components to produce a marketable grade of sulfuric acid. The grades of sulfuric acid to be produced are 93t, 96t, and 98V SECTION FUNCTION (See Figures 2.1, 2.2, 2.3, 2.4, 2.5 and 2.6) The process may be divided into the following three (3) steps: 1. The formation of sulfur dioxide (S02) gas in the combustion chamber by the burning of Sour Water Stripper (SWS) overhead gas (sour gas) and Primary Amine Unit regeneration overhead gas (amine gas) and the SAL 000005453 1 Sul 1uric Actd Plant The cooled gas stream leaves the waste heat boiler ard flows to the humidifying tower where it travels upward through a spray of circulated weak acid and is cooled by the evaporation of water from he weak acid. Sufficient acid is circulated over the tower to remove mos : of the solids (primarily ash from impurities such as iron in the spent acid feed to the combustion chamber) and most of the S03 formed in the combustion chamber. The gases then pass through the tube side of the primar> gas coolers in parallel with cooling tower water circulated through the \ hell side. In these coolers the gas is cooled and sufficient water is condensed Into the weak acid system and returned to the humidifying tower to ma ke up for water lost from purging to the combustion chamber and by evaporatic n. The process gas stream then flows in series through two electrostatic mist precipitators where the SO^ in the form of an acid mist and those solids not previously removed In the humidifying tower are collected and dralneo into the weak acid system. The process gas then flows through the tube side of this secondary gas coolers where the gas stream is further cooled by the cooling tower water circulated shell side and additional water condensed. The relatively acid free water is then pumped to the Effluent Stripper Tower to remove entrained SOg. Atmospheric air brought into the effluent stripper tower contacts the circulated weter, removing the entrained S(>2 and the water neutralization pit via the weak acid drain system. The S(^ enriched air leaves the effluent stripper tower via the overhead line and joins with the process gas stream before entering the secondary coolers. The process gas from the Secondary Coolers flows through an entrainment separator for further drying. At this point dilution air nay be added to SAL 0000054-54 3 SuHuric Acid Plant The partially converted first pass outlet gas then pas ses through the tube side of the hot heat exchanger where it is cooled by the first converter bed inlet gas before it enters the second converter bed. The second converter bed outlet gas then passes through the tube side of the hot interpass heat exchanger where it is cooled by the fourth converted bed inlet gas before entering the third converter ted. Partially converted third converted bed outlet gas g< es through the tube side of the cold heat exchanger where it Is cooled )y the SOg gas stream from the discharge of the main blower. The gas stream from the cold heat exchanger flows to the tube side of the combustion air preheater and Is further cooled before entering the Interpass absorbing tower. In the Interpass tower the $0^ ir the gas stream is absorbed Into the 981 acid circulated over the tower. The cool gas stream, leaving the Interpass tower and s till containing unreacted SO^ flows through the shell side of the cold interpass heat exchanger where It Is heated by the fourth converter bed ou tlet gas. From here, the gas stream enters the shell side of the hot interpass heat exchanger, where it 1$ further heated by the second converter bed outlet gas before entering the fourth converter bed where final convejSion of SOj to 503 Is accomplished. The gas stream upon leaving the fourth bed of the Converter flows through the tube side of the cold Interpass heat exchanger where It Is cooled by the process gas stream from the Interpass absorbing tower. The converted gas then flows to the final absorbing tow< r where the S0< in the gas stream is absorbed In the 981 acid circulated over the tower SAL 000 0054-55 5 rros oi sosj NaiSb3AN03 sos NOI133S lNVltJ OI3V noisiaio ssaaood onjins HVU9VI0 I9d I I Ii ... iVimit MirMw iirM '"eg... - iau^-j zwa^n i SAL 000005<h$9 hhwm iBiiga ttBS-i inmni) ujimu wifl-w cok-o TAM i HMUUIl'in wr *HH$ !? o i^SORPT i -/1I't \ n_ Oz 2; J 5= s U)g^ s ch n j- 3la Is i= >J !a Ot 000005461 Powerj House Profile Plant Cooling Towers and Potable Water System (Section 0 {See Figure 8A) The refinery's cooling water system consists of thirteen cooling cells in three separate but interconnected cooling towels (Y-l, Y-2 and Y-3). i ! Heated water enters each cell through distribution valves and flows out through the distribution boxes onto the de:ks. The water then gravity feeds through spray cups and falls down to a grid system located in the cell interior. A fan induced air flow,jcrosscurrent to the falling water, extracts heat and carries it to the atmosphere. The cooled water continues downward and is collected irt the tower basin. In the basin the water is treated with chlorine and th^n flows through two sets of screens and into the pump basin. j Except for chlorination, routine chemical treatment for the system i is accomplished at the Y-2 water basin. j i The cooling tower pumps take suction from the {pump basin and I discharge the cooled water to the cooling water supply Readers where it i is returned to the units. A combination of electrical ^nd steam driven pumps provides for flexibility in power consumption and aids in optimizing plant efficiency. All three cooling towers feed the low pressure (refinery) cooling water system while selected pumps on Y-2 and Y-3 feed the hi^h pressure (No. 3 CTU Division) cooling water system. I The potable water system (see Figure 8A) is supplied from the well water system. The well water is chlorine treated ajid routed to a degaslflcatlon/storage tank. The water is drawn from ttje tank and pumped through two backwashable sand filters before entering tije potable water distribution system. SAL 0000054-62 25 SAL 000005463 6 Power;House Profile 2. GENERAL DESCRIPTION j Demineralized Boiler Feedwater Make-up (Section l) j Raw water from the plant wells is pumped to a storage tank. From the storage tank the raw water is pumped through the prcfilter and then goes to the demineralizer trains for removal of dissolved metals. There are three trains. j A. Demineralized Boiler Feedwater Make-up (See Figure 1) j Raw well water is fed to the raw water storage tank (T-105) from the raw well water system. The raw well water pumps take suction off the raw water tank and well water is pumped through a pre-filter (F026). The pre-filter removes 90+X uf the oxidized i iron and suspended solids from the raw well water. 1i From the pre-filter the raw well water Is fe<^ to one or more of the three regenerative-type demineralizer trains for processing to insure boiler feedwater quality and supply to meet the steam generation demand. One train can be regenerating (on a regulated time sequence) while the other demln (demineralization) trains are in service. A demln train consists of a cation exchange vessel, decarbonator (clearwell) and an anion exchange vessel. The three separate demln trains are referred to as "A," "8," and "C" trains. The three trains are operated the same, so we will only go through the operation of one train. The filtered water first goes through a strong aci' cation resin bed vessel to remove calcium, magnesium, and sodium minerals from the water. SAL 000005*6* 4 Power! House Profile The effluent from the strong acid cation vessel is routed to a forced draft decarbonator unit. The water is distributed in a i countercurrent flow with respect to the forced |a 1 r flow. i decarbonator process removes bicarbonates in the f^rm of COg. The The effluent water from the forced draft (decarbonator is collected in the decarbonator clearwell section.(A booster pump takes suction on the clearwell and feeds the strong base anion resin bed vessel. The strong base anion bed removes chlorides, sulfates* and silica. More Information will be gl^en In Section 1 covering demineralized boiler feedwater make-up a^ to exactly how cation* anion and decarbonizers work. The effluent water from the strong base ajnlon vessel Is called demln water and Is routed to the demln waljer storage tank (T103). The demln water from the demln water storage tank is i pumped as make-up water along with condensate for final treatment. I This Is described In the Condensate and Make-Up (Water Treatment Section S. The In-service cycle of our demln vessel is (terminated when the resins becoaw exhausted. If a train Is allowed to stay in service beyond this point* breakthrough can occur |and the quality i of water being processed 1$ greatly decreased. In order to return the exhausted resin beds ^f a demln train i to a condition where It will again produce purified water. It has to be regenerated. SAL 000005465 5 FI6URE 1 N o .L C -3 7 -0 0 -e 6 -4 2 .iK - Tank Farm, Cooling '"ewer ajnd Flare System Y-4 Cooling Tower (See Figures 2.3, 2.4, 2.5) j The removal of heat from process streams and equipment's an integral function in the refining process. Heat removal from the SC/RC and Premium Coker Divisions (PCD) is accomplished through the proper functioning of the cooling water circulation system, the Y-4 cooling tower. i I Three cooling tower water pumps provide for circulation! of Y-4 cooling water. Centrifugal pumps P-1501, P-1502, and P-1503 draw watjer from the Y-4 pump basin through 24-inch suction lines. The cooling waterj is pumped into i the 20-inch discharge line of each pump before combining jinto a 24-inch cooling water supply (CW$) main. Water pumped into the mainj flows into the 14-inch CWS header for the SC/RC and the 14-inch CWS header for the PCD. The PCO CWS header splits into several flows before supplying water to i that unit. Cooling water flows through a li-inch line to t^e acid dilution trough in the Y-4 basin. The next tie-in provides waterj to the No. 2 Calciner via a 6-inch line. The PCO CWS line is also connected to a 14-inch i tie-in that may be used to supply cooling water to the No. 2 Reformer. From i this junction, water flows through exchangers and equipment!in the PCD via the 14-inch CWS header, then into the cooling water returi^ (CWR) header. ! The 14-inch CWR line from the PCD Is joined by several flows ibefore it joins the 24-inch CWR main at Y-4. The 14-Inch PCD CWR header is first joined by a 14-inch CWR line from the No. 2 Reformer. The combined flow in the PCD CWR header Is joined by a flow of make-up water from the 105* pit In the No. 3 CTU Division via a 6-inch tie-in. The last tie-in to the PCO CWR header befofe it joins the Y-4 CWR main is the 6-inch CWR from the No. 2 Calciner. These streams SAL 00000546} 21 Tank Farm, Cooling ''cwer a'rc 3/Ste-' constitute the sum of return water that enters the Y-4 cwj? main via the 14-inch CWR header from the PCD. \ i The 14-inch SC/RC CWS header supplies cooling water frcih the Y-4 basin I to exchangers and equipment in the various sections of the ^C/RC Division. This heat-laden water returns to Y-4 via a 24-inch CWR headef*. As it joins iI the CWR main, some return water flows through a sample line a|nd empties into the Y-4 basin. In addition to providing water for circulation through the SC/RC and the PCD, the CWS main supplies high pressure wa^er for several purposes at the Y-4 basin area. Each circulating watef pump has an associated priming eductor system. EJ-1502, EJ-1503, and E|-1504 are used to prime P-1501, P-1502, and P-1503 and are powered by wat^r from the CWS main via a U-inch line. Water flows through the eductoj* and into the i basin. This priming is necessary to start the circulating water pumps because the pumps are mounted in a suction lift installation at a distance ! above the level of water in the basin. High pressure wate|r from the CWS main also flows via l$-inch lines through a analyzer and'the chlorinator eductor EJ-1501. The water returns to the basin after use. i Water from the CWS main Is used for some cooling purposes at the pump i basin area, flowing to the CWR main after use. Turbine {bearing oil is cooled via 3/4-inch takeoffs from the CWS main. Cooling water for turbine/innerdrlve lube oil coolers X-1502 and X-1504 supplied via li-inch lines from the CWS main. i i The Y-4 cooling tower has four independently operated {cells, numbered from the north. Water from the CWR main flows to each cell| via an 18-inch line. The flow of water through each 18-Inch line is distributed equally to both halves of a cell via tee handle distribution valves. The distribution valves open into a distribution box to control the splash, l^ater flows from i SAL 00000546ai 22 Tank Farm, Cooling Tower arc "'are System the distribution box onto the cell deck and through the hol^s drilled into the deck. As water flows through the spray cap in each hol^, it is broken into small streams by the blades attached to the bottom of each cap. Water flows down through the cells, and the streams a|re broken into ! droplets by the rows of packing under the deck. This provides return water i with the maximum surface area for evaporative contact ^ith air. The crossflow of air enters the tower via side-mounted louvers ^nd is drawn up the tower by the cell fan located in the center and at the tip of the cell. The lateral air flow evaporates some of the falling water; the heated air and water vapor are exhausted to the atmosphere via t^e fan shroud. Evaporation is the heat-removing mechanism for Y-4. The droplets of cooled water fall into the solids settling basin where they collect and flow into the pump basin. Flowing through dual suction screens for each pump, the water becomes available to be pumped through the system again Water is lost from the system through evaporation, exchanger i backflushing, and the intentional removal of water (blowdowrj). To replace this water, make-up water from the 105 pit in the No. 3 CTU Division enters Y-4 via a tie-in downstream of the PCU CWR header block valve. The 105 make-up line also provides water for P-3601, P-3602 and P-3(j03 in the Coke Drum Processing and Closed Blowdown section of the SC/RC via a 2-inch line upstream of the make-up water control valve. These pumps may alternatively be supplied from the CWS main via a H-inch jumper line. IBlowdown water exits the system via a 6-inch line from the No. 2 Calclner CWR header. The use of chemical additives enhance cooling towe|r performance. Untreated cooling water causes problems with corrosion, scaling, fouling, pH, microbiological growth, and slime. Control of these conditions protects process equipment and maintains cooling tower efficiency. ! SAL 000005469 23 'ank Farm, Cooling Tower afid Flare System Chemical and electrochemical reaction between exchanjger alloy and heated water causes corrosion. For this reason a corrosioh inhibitor is injected. Inhibitor flows from storage tank T-1501 to ^he suction of metering pumps P-1504 or spare P-1505. These pumps discharge directly into the basin to mix with cooling water. Corrosion is monitore^ with a coupon corrosion rack. A 1-inch line from the CWR main provides a constant flow of water through the rack into the basin. The rack contains coupons of metal alloys found in exchangers, and the coupons are checked periodically for indications of corrosion. Scaling and fouling are related processes. Scaling occurs when dissolved salts are deposited on heat exchange surfaces. Fouling is the deposition of materials such as silt and suspended irons. |n either case, i heat transfer is impeded and cooling tower effectiveness deteriorates. To prevent scaling and fouling problems, a chemical dispersant is added. Stored in tank T-1502, dispersant is injected into the tj^wer basin via metering pump P-1506. i j Corrosion inhibitor and dispersant work together withiri an optimum pH range. pH may be better understood as the relative acidity fc)f a substance. The optimum pH range for Y-4 cooling water Is achieve d through the introduction of 982 H^SO^ (sulfuric acid) from the Sul fur Processing Division. Incoming acid is directed Into Y-4 via one of two line-ups. Acid can be sent to the elevated storage drum 0-1503 and be grav ity fed through the controller into the acid dilution trough in the settling basin. The acid flow can bypass 0-1503 and be fed through the contrjoiler into the trough using line pressure from Sulfur Processing. Either line-up can be used, but fluctuations In line pressure from Sulfur Processl ng make gravity feed from 0-1503 the more consistent mode of acid addition SAL 000005470 24 Tank Farm, Cooling Tower and Fid1- SysteT Microbiological growth and slime will hamper cooling tcjwer efficiency by obstructing water flow through exchangers and equipment. The i introduction of chlorine inhibits microbiological growth pnd slime. A lj-inch line from the CWS main flows through EJ-1501 and draw^ chlorine from one of two 2000 lb. chlorine containers. This solution flows into the basin via the chlorine solution diffuser. SC/RC Flare System (See Figures 2.1, 2.2) SC/RC flare drum D-1504 receives liquids and gases via liwo headers: a 30-inch warm flare line and a 12-inch cold flare line. The warm flare line | carries a mixture of fluids from the No. 3 CTU and the vaYidius sections of i the SC/RC Division to D-1504, while the cold flare line has |the metallurgy to handle low temperature light ends (30 or less) that may jbe flared from portions of the Gas Recovery Plant (GRP). A two-phase flpw of gas and i i liquid separates in D-1504 with liquid collecting in the ^oot and gases i drawn off the top of the drum via a 30-inch line to the flaire stack. The SC/RC Flare system can also handle some of the refinery flarie load via the flare header from the No. 3 CTU Oivision knockout drum. TM^ knockout drum can be lined up to accept flared material from the refinery when the south flare must be taken out of service. NOTE: The north flare! cannot accept the entire refinery flare load; some units must be shut down.| Tt is critical to prevent liquid accumulation from building to the point where liquid enters the flare line to the flare stack, j A high liquid level in D-1504 coupled with the opening of a relief va1v4 in the flare system could force liquid (usually hydrocarbons) into the fl^re line and to the atmosphere via the flare stack. This liquid would ignite and fall to the ground, posing a fire hazard. * K* , SAL 000005471 25 1S> > o oo -4 APPa/{)ix- b<Tr$ \ Cor-Ccz :n<* Cafcuiation Sheet Tii/e SAL 00000^475 j'ct No. S.E'S *; -"v uor I 9/.^S0000<> TVS 199MS uo|iB|nD|eo DUj ODOUOO 5>;;< rn/&3UiS 3finQS*2 /y^oyvM/yn Ufty SJOJ )jSl ~*0 i*> . 1^ i- 9*1 i -> i^> ; l> 0'/ O'l 0* O'l b 1 !~> O'l l> i> l> i> 1* J> -S'( l> l'<7> l> l> )> !'c?> !> l> !> 1 'i7> o'l l> 0*/? I'O i> )> i> i> O'J 1> O'l Q'l o*e O'? O'? H/=y |-> /> ;> /> /> o') /> O'f O'! O' 1 o'l nO^' n1 j It 1^ /> )> : b; i l> o-| O'l O'l O- 1 ! O'l : 9? m 3 ... )> h'\ /> l> 1? O't b l> b 1* )> 1 > l=> Co* io *3 O'l It- o'l 1-^ \> )> i> il>> XHD ("4 )> !> i> i> i> 0-1 o'z l> l> O'l l> !> l^> l> O'i o*z O'b l> l> 01S O'Z 0*2: i'l O'h L'l O' b /> t'l L'l lz iz L'\ O'h sr Vd xx-u> *X-Q V 0M^_'5ol'W* l> 31 1*0 /> l> 1*0 O'l 3*^7 O'l l> !> /0'D> !> I> S'Z 0'5/ ;> 0*1 r*i h'b n h'h r<? nmt yt ri 1*/ A'/ L'L h-'* z// L'L Z'l L*l b'L h' l 93 'ri L_Zh\ StwSttSOdwo-) U/V3VX3 /yaA/'^a^ s3-?ywo Q\n&[~l rgxt/'-j v35 ol;^ t- */V ^5> h~d_ 7>f^J 9 St *705 "7/7 ^Jwjo^jxcj LiquiD St6Aw Co^Pch tig/vo 2$ f'A L#k CPPP3E3 2/3 Ktr'^" fta^.'/V/r P v Pe^E'v' Pe`6^L/5'5 Ga'sh-iWC OA'LBAtjEo, (S-^ounS, I, A vt v Pep TSL. Pepo^T * JT- -32. - BS 1.7 W(% PEP T5^ Repair--- ifLcX-3f Rl.*/, CcAYToM XoCr ^ 5" C, ,- o| scPep uc GAf>cu/v_ - 2 M Wt`/ (PeFc TSE ReFoP'7 ^J'-ia-S'^ *--( fy\.vj.CL(\'(T&N Tocl Cc ) Fa: Sasoc<<V Ct 4- ^vy) - /. I WYo lsR GMettME. RefoP T fcTE ^CtC'/CpT'E N/}p^'p_p CoK'Ep /4s^~/a/E. = *?,cl lvt% - 3,G ^ Y - 0. o / ^ r % - /. 0 w P 4 -- 0,3 ^Y0 PER Tim AiyePS (\~-7-?$) ) X<c Cooe Wet Ga$> CftuOE - 0,7i wt% CteR n7/ fe/ic* Cj,'t- XPe^ ^ 0,1> wf% SoWFi -** ?os-o-o>-in ) (fetf T"n ^lye^s xoe (T-1-%?')) JP-H = 0,7 VF"/. ('estimate ASeo art P`Hca aty &4tJ) I /V0 ^ biSTau-ATEi KEROSENE - <o/\ 4 (pep 13c (focuijc ENGLEJ P/CC (SEcEEccE) jA<3TC oA7 @Pr. p4-/v^i- ) ! SAL 0(00005477 UdTE :Q)f!c2B2 To THE. CyBAtA QiApcTlY Ffe^ beR'iri-! IaSNE OP ^(QuiD SnR&j/n Co^fosfroNS. -hC RefiHEAy wfiS ^ser FfEL-EfiB'vn#lLY 7cnocc inc Calculation Sheet JoD No Field State ~b LuEN/E Regular unleaded Super ul gasoline - FCe GA-teuNECLtlrtivy') ^SF QASC^iNL P&ForYo^c CA$a~,w. - Nt% = 3.0 we% = is~. o i^tVo - /,r - %,0 Wt% 4! % (f^aeic. \ Gfoourtr &V6. w/o 'HtGHE'-T) { (p&. >7 7 / R_ ^.Di Psr. Ca, Cv --, StTe*./v" r! Jor^i^ ^lor-0-3.-7/ j ^>E '7 = #u*Y(.A7iE =C#u)E - <| % (oluE EMG-uEj B'fCL GE^BE-lF ~Ne.a bfS7lct4re - KERctBNE Jp ~ ^ " 1.5" vvF % (E$Tt*\*7C HiPER CRuBE ANALOG R-b STf-fA/' Sai? /) 0AsbL on fbNoA enty C>4lA ) etf ve 5 E tr/g Rf^ooPP e/VL40^ Super l/l. (M5oliA/F = I.-? wt% (Vw/c <$hoL>vE 5^y" Fee GvHoei/V fc- Pvy) = J.2. l/y % EJrse^) R C_ hCf r' ^ ^ e Nftti^n 4 2,r^r4 !, 0 Ia/4 Vo Bill GluBelle: - tf-t<i-p} pf-bste CofVVF ,*' AT/tr AlIc^cA 1~E-ER.u$E - Wa. 2 0isntc-*J7 ^CftyE ^T 6*i - kERosCNE -LSfi. GA<*ot~ifijr - asom^F ~ ^ I% &J) Sir^o. * X+rv^y ~rse _* r, ,- -4 N 2 firstb q/v <Se ';< ; C-XjLENE: Regular } umlEaoeD. SoPejk ul gasoline - ^3 vf % ffli/f. a^/<_ j - hi&nEST Fee asoua/e_ - (Lt Sr Hvy''; /. F ^76 (fl *f 7 / P ' 0 Pof\C-\ Ol'X -SVn?^ *! *3^- o- 2--? { Conoco Inc. Calculation Sheet JGD No SAL 600005478 Fiescs Stale r Rl=bf^4TE: ~ H-0% ((fuc Geu6(-c_ A-t** tifWHTHP OZKB& G-frsoLiN^ - r. (Bill GB'o&E Li_E t/-/^-5>N) LSP G-hZ^C< f/E - PL^'/EAtE - Cu0El ~ Oh _ - tCEP?zr>ver - A/o. Ol bisriu-P^c. =7?- / ^ */ ( P, lx D S+y~eo'- Survey Tsl -:g>P" /'l-Ky^.S/Vi Pe&u6*^ SuPEP Fee (?ASoe/A/ 6-^r &r Hvy) ~ &&SOUNE - O,-? (s-,7)- H ,C> w */< C&?G- Wogn - '?,UiQthE$r~ yRATtj) ia ^fd?^/frr --> i .*> /y ^ ^,0 Wt ?C (S/EL. GEu&E^t.rh' 4-/*)-r0 /V^PPTA/4 Co*F 3*P W - ~7,o w-e % (Sill Ge.u$elce - 2. t O Uy % ^ /.5" ^ Y-^-jgss) - /, H wt% (&5>Ttf*47E <7// PoA\k*t cfry ({LKHLATE ; Cf-v)Z - >TeP05eA/f = 0/6Se ~ 45^ = Cftv0E OH - l Wt 7 iglLL G-EuSEiEEj R&~S> SvRPEy GRu/jf: ^/fcys.o; P-XYeE/Ve Pe-<?ulM uNLBADEb Super ue ghsol^e - O^C^.i) - 1.1 Fee <Sas<3L/a/ /?5FiD(?4i4TE NAPHTHA C&vg W6il. - T-HiG-rfEST - El-Xy ^f4-no3 Ta Sr Hvy') RE.FGflM4"UE CamP ) " 5".O Uvf- *%, 9 ! - Wir% X 6i(X &EuBEL<- j ^ H ~ -% $ - | , o wf % ^ - Gitce^ <^As3L7rtS-, AUcYCA-TfL - CPoQE - KEROSENE - Di&Ste- /_SF oH - ~ ^ ! W6 r <^/EC GEvgeLUE^Rtri) SuRi/c^ CRuOt. ^eYSlS) Conoco Inc. Calculation Sheet SAL 00ojo05479 Job No. Field State r CYC-LOHEXArfE. . UClLEAfjEC^ 5uPEP, UL '9rtSour/t Fa: SM>c\-nE (& k H*y) /VAPt-TH-A CokfP G^io^nE = 1.0% -2,0/ - 1*0% fs `A/. Pw w> c) /^ GEuPElcC : p-n-i%') OSF GAsoLifl/tr ~ *5<ZL *% ^&=oP^.~C - Alk-(lATE ~- CfrubE - SuaP T PeP I ^7! Ko/V^/r C-iT* :kaO Si/^t S_*(- / = C?^)c o//| - F\Cr^) ScJ^i/Ey IMPtE^ ACtrtt GP-i = 0."7>/ 2oV, -- !,</ % C$T(*AT a/v NAPrtT$L/Z (all Pep ou^tE E/Ygcb &- c/Ty MTA) \ 577FE/KE Cufr^NF PPEuQC 0^7g/P (ftU- PeP &/CL GEugELL j <T-2~&Z n) s. t- *^A/ Cc^A/ i4~' t< </-' aC/V 's, Tin*? Conoco tnc. Calculation Sheet 0000^ 0 joo N; FieiC State (conoco) Interoffice Communication To G. N. Constien - Denver From S. D. Graybill, MT&E - Houston Date July 11, 1986 Subject EPA LIMITS ON BENZENE IN REFORMATE - NOT A PROBLEM As we discussed, the benzene concentration in reformate from Denvet's new reformer should be much lower than EPA's 10 WT% maximum limitation, as required by NESHAP (National Emissions Standard for Hazardous Air Pollutants). Test run data from Ponca City's reformers indicates the benzene content in reformate ranges from 2-4 WT%. However, the actual benzene content of the Denver reformate will depend upon the feed quality, operating pressure, and octane severity of the operation. Shown below are reformate benzene contents from the Ponca City Nori 2 and No. 3 CRU's presented with respective RONC's and feed quality data. Increasing the light ends in the feed will generally increase the benzene content in the reformate, For example, cyclohexane converts mos tly to benzene, boiling at 177F. Ponca City No. 2 CRU Dec/85 Aug/83 Dec/85 No. 3 CRU Dec/85 Feb/84 Feb/84 Dec/85 Feb/84 REFORMATE BENZENE vrr% RONC API GRAV FEED FRONT-END D-86 FEED <? PC ELEVATION, F BENZENE IBP 5LV% 10LV% 20LVfc VT% 2.1 90.9 51.9 128 159 197 216: 0.2 2.2 93.9 47.4 130 186 208 2281 0.1 2.8 95.1 49.4 128 159 197 216 i 0.2 ; 2.3 91.5 52.5 117 195 205 2181 0.2 2.8 91.5 53.1 106 169 195 215 0.2 3.9 97.3 47.3 102 170 191 212! 0.3 2.9 97.8 48.5 117 195 205 228 i 0.2 4.0 98.7 45.4 105 173 197 216! 0.2 In addition to the above data. all of NAR's streams were well below! NESHAP limitations at the time the standard was introduced , according tlo Phil Youngblood with Environmental Conservation. Moreover , Humber ' s helrt-cut reforming operation at low pressure and high severity still maintains less than 10 WT% benzene in the C5+ reformate If you have any questions or comments, please contact me (ETN 3868) 6r Phil Youngblood (ETN 3677). SDG:ci MT9/sdg6 cc: LTW, PLY, OA/File 2.52 - Houston DJP -- Denver TGW, PCP, OFE - Ponca City SAL 000005481 conocoJ TV-.' Interoffice Communication To Mike Johnston From M. W. Clayton Date June 19, 1986 Subject Benzene Analysis of Gasoline Tanks Lake Charles Refinery The benzene content of Refinery base gasoline tanks and finish ptoduct gasoline tanks was determined. All of the tanks were below the five pkrcent maximum allowable concentration*. The tanks showing the highes't levels of benzene were the reformate tanks and the super unleaded tanks which contain a high percentage of reformate. Tank Sample Cate Gasoline Type Benzene fMet< 38 6-11-86 Light St. Run 0.93 77 6-13-86 No. 2 Reformate .. 3.47 85 6-13-86 FCC Gasoline 0.94 98 6-13-86 Alkylate 0.10 99 6-12-86 Alkylate 0.10 if--? 33 6-11-86 No. 3 Reformate 4.14 ~ 78 6-13-86 Super Unleaded 1.79 ' 64 5-27-86 Super Unleaded 65 6-09-86 Super Unleaded 3.18 1.49 ! 80 6-13-86 Regular Leaded 1.86 25 6-01-86 Regular Leaded 1.65 32 5-29-86 Regular Leaded 2.36 92 6-08-86 Unleaded 93 6-13-86 Unleaded 1.87 0.29 1 31 6-05-86 Unleaded 2.12 * Maximum allowable concentration for gasolines sales m. tv. esurpzr M. W. Clayton Analytical Chemist r cc: PFM/DLW RJH/PAN/H1M RHC KWC/JJM/JI/FILE T. <^L Waltrip - Ponca City SAL 000005482 CONOCO INC. PONCA CITY, OKLAHOMA TECHNICAL SERVICES LABORATORY Pit. : File: ;lc '662.1 ! 924 Date: 9-11-85 LABORATORY NO.: 1-32-85 CHARGE: TSL SUBJECT: Summary of Benzene. Content of Finished Gasoline and In-flant Streams - X977 to 1985 - Lake Charles Refinery CONCLUSION: None of the Lake Charles Refinery finished gasolines or in-plant stream^ analyzed by this laboratory contain as much as 10.0 wt. Z benzene. Therefore, the Control provisions of EPA regulation 40 CFR 61, Subpart J, do not apply. DISCUSSION: j A June 6, 1984, promulgated regulation from EPA mandates controls on benzene fugitive emissions at petroleum refineries. A key definition in Che regulation is: "In benzene service means that a piece of equipment either contains or contacts a fluid that is at least 10 percent benzene by weight as determined according tb the provisions of 61.245(d)." Unless fluids produced or used in the refinery contain at least 10 wt.Z benzene, the controls in the regulation do not apply. At P. L. Youngblood*s request of 9-6--85, the results of previous laboratory studies of benzene In Lake Charles Refinery streams are summarized in this repojct. Five major studies on this topic were made from 1977 through 1985. Benzene jcontent of all the streams measured in them was lower than 10 wt.Z. Additional analyses have been done by-the Lake Charles Refinery Laboratory. Attachment II is a laboratory crosscheck comparing benzene concentrations determined using gas chromatography and infra-red analytical methods. The benzenej results included in this report were obtained using both methods at different t[Lmes. The method described in the regulation at 561.245(d) is gas chromatography.i I ANALYTICAL DATA: Attachment I. REFERENCE: 1. Verbal request from P. L. Youngblood to R. S. Jones, dated 9-6-85. 2. Several laboratory reports dated in 1977, 1983, and 1985. SAL 000005483 ASORATORY NO.: 1-32-85 September XI, X985 Page 2 ATTACHMENT I BENZENE CONTENT OF TiAKE&GHARLES? REFINERY FINISHED GASOLINES AND IN-PLANT STREAMS ! Stream Description Finished Gasolines Sample Date Benzene Wt.Z Regular Gasoline Unleaded Gasoline Super Unleaded Gasoline Regular Gasoline Premium Gasoline Unleaded Gasoline Unleaded Gasoline Regular Gasoline Premium Gasoline 8/83 8/83 8/83 5/77 5/77 5/77 3/77 3/77 3/77 1.8 2.6 2.8 1.3 1.2 1.3 1.8 1.2 1.3 In-Plant Streams Naphtha Cutterstock Naphtha Cutterstock Naphtha Cutterstock Naphtha Cutterstock pFieid PBC D enuded~ CasingheadSuSi** o^^cru XSR No fl.v'3 ~iCTU-XSR,~ 5/85 4/85 4/85 4/85 -^S^r>4/85gi 0.7 0.7 W--10 ^ FCC Gasoline t^Rim? Gasoline Denude4Casinghead -ag* Cat Poly Gasoline Alkylate Coker Gasoline WoV*2 W!S3ftfoxaate^^ NqMBbAefornateg ^NovT^CXIT No. 2 CTU Naphtha thermar GasSllSr^^^^^ \ Coker Gasoline Coker Gasoline \Thermal Gasoline ttcJir" - - -- SAL 000005484 K\crt 6 t \o o l T^VT'A \C f'i V f-\k \Ai n u {'ma\)C -to OcnvO Oi oC t-oC- TWl. '|VhAt Cb^vo ~ic VM V'a-fO pA lcnc , >cF^ lcms: [ 5 l^cTK^cMt MCA C \ c UnK.C C-VAS >f>CTA iF" \^ilA6h3) 'GrReA/A H-TTH') trMc OMCeAfT^rnoAj , Kcc c/0 Fft-CPv/ LtrMC TvJO_ &\5 Fee iAl^. G F*B (FccA ( T>-P 6-6 ^PccbO^o^ CkCj CTft>io VR.o \ al a CpjAs G^estfc* (Gv-> C(fAjo') (p iO ^1 /O -o I Lo Tteo`c> CCft-yo) CAkeR VAct GAs. Cc^B' mcT> TRy pee> "pRcpAMe CXiCRHe^b \jfb\>j V^U\nts^_ PPK <! 6 ^I <1 Au^j(OftNo) Veeb &hB AokW OvfoAtasB. ^3>^erfA 'Btv\s (bvbW ) Ko^^Tavl GA> < \ -O ^1 <1 T 'SvciS Ov/c^B0Vb> 3 3 3c> 35 7 fl 0-1 60 3 Ms t ~i 5o 2_o /o 5 V io 2-0 2_ ^7 71,7 >775 LA/C 26! 6 | ^l i203 6-] -H 1 A/ ^3 0.2- A/ ^1 /VlpTgr ~. 1>g 7avvc A^ Momco6 edPrFoCrt-nsicS. AMjao aj0 \Jco OXAv^S <C>M5 rfS-CAA -fV^TCTeS . ABoorr ?8 7o Fo\iOo iFFFuueMoJ ( &rr FoA^eb GA? B2M &alAUcA) . OOP A^A. *# vAlMOS Po^K\0h3 FROK C^XivieR. l>rrA, Ki 3i? FV-OS FovOO GAs VA^v)t3 MOTCz> /M LC (Is) t=t 2. Cr^o pi) 7?" Fftc^v l-OvOoiC Oc/^CS T"hAsv\ SborA A^nST omTT7 Fee ><_os Oft-HD ^GLOifc> SAL 00ooo5^85 ! VStOTX; 0 CMC ^ v v :M L"f\T*\ 'SrReftJA M r^w-Uw^c am\3 LVfMeX^ L. >rm CoM^smoM^ wrr%| A4ivpvm^L04tr 3cr V3uo- - ^Ter- 5c> m a CVot>F CoMbeM VvTe- KeRes^e ^VeA^ YRlc (jrASXfWc 3 3 I 3 : ^ f ; x. i ; 3/ ; [ CteOPC CLm'V'dS rpoAi Au loTC '. ~TTH^ CsCv-oHCSAAMe \otoeWtr LTrt'|urbe>RcMC n^/lcwc D- VfV Lewe r > * CuKOlF ^'vps<su>'fro-Co mexi e /slKP^m \d-cc-aj e Sr^fteue" 3i 'p,rt3\jVL ^Aoees^ ^t>A.fs^AlS VATT^f, C.3Cp C). -7t 6.3^ 0,21 O.77 0.2.7 0. O. l:7 o./^ o. o i * 0.05 A^or Rsitl> #* McG'UOiGte SAL 0010005486 ^~n-toL" FadAX A Co2>e A^vyrroRc Bcrr SHoui_b f&F ClcOO, jXJo vvm OMk ^ATwi^Lcmc 4 Bi'mtwvL. ^OMC Soa^ct^a\6-IKto3 A^vu's-r ctfen ~m^e ioith isc, + Fac.\ "Pc_ vU^svrc: "t*=>i\)t7X P\?X Sio> OfU. ; j X- ,s {,isV if?p <Qjzd< Mobiil Oil CCoorDrpooraatfiioonn^/; ""'. v/.y v ^ APPENDIX B EnvihJenTai a**airs ANO TOlldsLOCT 0E*aAtuCS7 S0 EAST JjNO STREET new TC*^. NEW TO*< >C0* 1 August 17, 1983 American Petroleum Institute 2101 L Street, N.W. Washington, D.C. 20037 Attached are data which may be useful in the API package of information being prepared on gasoline as a potential source of human exposure to ethyftoluenes 1 (EX) and trimethylbenzenes (TMB) . The information comes Ifrom earlier Mobil investigations of the chemical components of gasoline both in the liquid and vapor states. c Table 1. Chemical Composition of Commercial Unleaded [Gasolines, shows "the percent composition of 48 components in 12 j commercial gasolines. The content of ET range from ^.50 to 5.29 (average 3.74) and individual TMB isomers range |from 0.61 to 4.56 (average 1.80). Table 2, API-PS6 Gasoline and Vapor Sample Comoositidns, eimraftrizes mp.a8urPTnpnf.fi or 75 components in an equilibrium air/gasoline mixture headspace when the liquid level j approximated 20Z of the total container volume (simulating refueling a car at the one fifth tank capacity level! . Appendix A describes the procedure. No quantities o:: ET and TMB could be measured in the headspace at a detection limit of 30 ppm, even* though calculated values might have j indicated the presence of up to 96 ppm. The headspace conditions represent the maximum potential for exposure to gasoline vapors. In actual practice, people would hi exposed to considerably lower concentrations as the | headspace vapors mix with outside air. Substantiating the conclusion from the Table 2 data are Results of air monitorings conducted at various gasoline handling locations. Ambient air samples were taken at-an eastern Pennsylvania Mobil service station and analyzed for their gasoline vapor content. Additionally, numerous studies were made ac refineries add terminals for the hydrocarbon content of air. These studies indicate the following: 1 SAL 000CjO5487 2- - Mobil . No detectable quantities of ethyl-toluenes or trixnethylbenzenes were found in the eastern Pennsylvania service station airosamples. The detection limit for these I compounds is 0.2 mg/mJ or 0.04 ppm (40 ppb). # No measureable quantities of ethyltoluenes or trimeihylbenzenes have been found in the hydrocarbon studies j conducted at various Mobil facilities. The results of these studies indicate a very low potential for human inhalation exposure to ET or TMB as a consequence|of their presence as minor components of gasoline. One interesting observation when reviewing the overall 4*ta on Table 1 is close agreement between the calculated valued and the measured values. The calculated values are slightly hiiher than the measured values (482,490 vs. 460,000) because the i calculation procedure recognizes all theoretical valuesiin the vapor space.i t i SAL 00000548 c c .. '. r i '"' COMPOSITION' S Or TWELVE COMMERCIAL UNLEADED GASOLINES* \ ^C>iugmef (v3uur> Butane Butenes n-Pentane pentanes Penienea Cyodbentane Metnyieydopentane rwHexane Hanes Hexenes Cydonexane". Metftytcydbhexane jvHeotane Heptanes Heptenes diWetnytcydopentanes n-Oetane Octanes Octenes C^Napranenes (N, iK*) >Noaw Nonanes Nonenes C*Nasmnenes (N* & N9) n-Decane C-,o- *-Pvatttns. Olefins. Naantnenes Benzene Toluene Emyioemene m-.>Xvienes - --o-Xyien " 12.3-Tnmemyt- benzene 12.4-mmeiny* benzene 1 J.5*7nmetny* benzene Metnyteuwj* benzenes) Prppyioenzenes Butytbenzenes Metnytpropytbenzenes dhfftytr>enzenes 12.42-Teira* metftylbenzene 12.3.5*78ire* metnyioenzsne 12-3.4-Tetra* metnyibenzene Otner Ci Alkyiben2enes C,, Alkyipenzenes Napmnaiene Metnyt- napntrteienes A B 0.13 0-17 227 1.M 12 0.80 2.65 0.45 3.10 i.n 625 20.80 5.01 123 0.15 0.09 c 0.04 420 0.70 0.75 225 928 5.65 020 0 123 425 0.07 029 1.65 823 323 0.12 -T- G 0.09 3.02 2.10 1.00 3.16 624 2.70 023 0.03 3.11 0.73 1.01 1.60 9.70 3.72 0.17 0.03 X71 028 0.65 3.17 723 3.69 023 M 0.63 5.12 021 0.70 226 5.18 3.00 027 1 0.00 3X2 0.96 1.69 3.05 7.63 523 0J1 JK 0.02 0.02 325 3.11 0.92 0.43 1.13 020 1.12 4.72 724 10X8 420 XS1 X14 026 LI 0.05 i 4.01 i 0.64 ! 025 ! X45 ; 826 1 223 1 026 : 1 29 2.45 7.18 326 X12 0.41 1-20 4.73 2-26 CL57 0.46 3.84 2-55 0-51 123 323 026 0-04 026 020 322 0.73 1.11 0.88 620 4.46 0-09 0.44 0.44 428 223 024 0.47 4.46 227 0.05 0.17 0.40 S-C2 027 023 022 0-48 025 0.42 0.48 8.05 18.99 23.04 028 224 127 1.70 223 624 227 029 024 120 5.02 321 1.10 120 320 128 1.12 020 4.83 X43 0.09 028 025 2.64 128 0.62 X16 128 128 1.40 126 623 429 023 028 0.76 524 221 028 0.45 927 128 027 025 4.16 6.60 0.14 0.43 0.62 326 122 127 1.64 6.42 424 0.15 X49 022 428 221 129 X85 7.04 X77 0.09 024 024 421 124 1.05 121 5.67 325 0.19 X40 023 321 128 1.61 223 626 X79 X41 0.61 1.17 5X8 128 j , < j X\ *L ! \ : i 028 025 826 124 1.00 1.14 0.68 028 021 028 827 14X4 10.80 X67 XOS X96 i.oi 023 723 XOS ; ' ; 027 0.2S 0.84 020 029 022 0.79 0.72 0.46 027 0.00 0.00 XS2 1.17 X24 129 720 14.86 2.11 224 025 025 324 026 026 0.00 321 0.63 221 024 422 1.84 022 024 229 023 120 021 123 123 1.19 0.17 228 026 0.71 023 121 128 0.74 028 128 1.10 0.60 0.75 027 X76 0.45 0.00 0.00 020 0.00 o.oo 2.97 324 2-16 '32c*---i34 0.45 122 221 1.78 122 6.10 10.78 T7.7 6.13 1321 1.70 1.72 1.63 1.71 xn W< 6.40 S.71 5.19 722 226 220 229 226 X63 029 020 2.48 028 1.16 022 XOS 1.13 0.54 0.19 120 029 X89 320 1.67 021 1 ^ ; ; . 0.75 0.72 025 0.76 0.00 0.00 0.00 0X0 (it/C-TT -7^ ~ 2.87 1X6 4.76 xos 627 X64 422 ' X68 1XS 1.94 4X5 7.43 120 1X7 5.73 XS5 X16 120 i xoo 126 9.77^, 1.95 J .3 6.67 bl ?*.7l 225 S /'' ^ 5.7 122 1.00 0.61 0.73 025 020 1X0 028 025 0.79 126 025 3.67 127 C53 X64 0X8 329 124 427 0.71 0X8 222 0.82 220 020 OXS 3X7 1.10 227 0.44 0X5 X4S 127 3.61 0.63 0.09 325 1.07 3.62 0.74 0X8 XI6 1X2 325 0.70 X44 X37 1.02 4.01 021 028 324 1.17 427 X76 Xll 223 1.10 3X2 0.44 xio 426 X10,_4=Stol>o 1 124 1.04 1 S29 325 + t I s 021 T3T ( 027 023 -- Vy V *7- 123 1.02 025 0.63 0.41 0-94 X96 1.58 .1X2 029 1.10 1.13 Xll 0.94 0.53 025 0.91 1X6 029 020 120 0.6$ 1.17 023 025 028 027 025 029 026 024 024 023 021 025 021 027 0-43 022 029 0.63 029 023 0.40 025 020 029 021 0.17 0.12 0.11 0.09 022 0.12 X19 024 xoa 0.15 X13 X17 | SAL 000005489 1.74 X71 020 0.12 125 1.43 026 021 0.98 221 027 024 1.00 123 024 022 1.80 3.61 0.64 0.69 122 126 023 0.10 121 3.42 0.45 0.49 1.96 X68 0.40 028 126 123 X17 0.00 1.48 X77 X47 0.87 Xll X68 027 0.47 123 X86 0.00 028 4^ : Sampled in southern New Jersey in summer, 1980. Tjje analyses were carried out by gas chromatography and (are shown in weight percent. ; x Table 2. $^ API-PS6 GASOLINE AND VAPOR SAMPLE CQMP05It|i0NS COMPONENT HYDROCARBONS. 100 WT1 BASIS LIQUID VAPOR VAPOR MEAS. MEAS. CALC. 1 UNKNOWNS (HC AROMATICS) 2 PROFENE 3 PROFANE 4 I-BUTANE 5 1--BUTENE+2-HETHYLPROPENE 6 N-BUTANE 7 TRANS-2-BUTENE *8 CIS-2-BUTENE 9 3-METHYL-1-BUTENE 10 I-PENTANE 11 1-PENTENE 12 2 -METHYL-1-BUTENE 13 N-FENTANE 14 TRANS-2-PENTENE 15 CIS-2-PENTENE 16 2-METHYL-2-BUTENE 17 C5-DI0LEFINS (DIENES) 18 2,2-DIKETHYLBUTANE 19 CYCLOPENTANE 20 2,3-DIMETHYLBUTANE 21 2--KETHYLPENTANE 22 3-METHYLPENTANE 23 HEXENES 24 N-HEXANE 25 2,4-DI KETHYLPENTANE 26 METHYLCYCLOPENTANE 27 3,3-DIMETHYLPENTANE 28 CYCLOHEXANE 29 2-HETHYLKEXANE 30 2,3-DIMETHYLPENTANE 31 3-KETHYLHEXANE 32 1-CIS-3-DIMETHYL--N5 33 1-TRANS-3-DIMETHYL-N5 34 1-TRANS-2-D1METHYL-N5 35 3-ETHYL-PENTANE 36 N-HEPTANE 37 C7-OLEFINS 3B KETHYLCYCLOHEXANE 39 MONOMETHYL-IS0-C8-P 40 OTHER ISO-C8-? 41 C8-OLEFINS ; C8-NAPHTHENES (N5+N6) N-OCTANE 0.04 0.01 0.05 0.90 0.13 3.97 0.27 0.23 0.07 8.69 0.23 0.49 3.60 0.54 0.36 1.01 0.00 0.22 0.29 1.82 3.91 2.49 2.26 1.69 0.97 1.24 0.11 0.12 1-47 0.86 1.50 0.32 0.31 0.31 0.09 0.57 0.78 1.38 5.24 10.06 0.05 2.61 0.23 0.00 0.20 1.44 10.50 1.25 30.40 1.96 1.56 0.27 25.10 0.58 1.18 7.10 1.27 0.63 1.77 0.00 0.31 0.22 1.49 2.88 1.57 1.21 0.79 0.27 0.51 0.03 0.03 0.24 0.15 0.23 0.05 0.04 0.04 0.01 0.06 0.10 0.10 0.48 0.76 0.48 0.12 0.00 0.00 0.18 1.25 8.97 1.13 28.23 1.81 1.45 0.25 24.65 0.60 1.25 7.68 1.36 0.74 2.00 0.00 0.29 0.39 1.80 3.49 2.00 1.82 1.11 0.41 0.73 0.04 0.04 0.43 0.36 0.40 0.09 0.09 0.08 0.01 0.12 0.33 0.26 0.48 1.35 0.01 0.14 0.02 SAL 000005490 1C In HC+AIR SAMPT-E PPM VOL PPM"VOL CALC. 0 1408 9136 49937 6524 157117 10441 8362 1190 110512 2777 5757 34421 6274 3083 9201 23 1073 1810 6729 13085 7513 6988 4153 1320 2805 125 166 1377 1165 1299 289 292 281 30 382 1076 871 13 69 3828 17 395 43 APPENDIX A i API-PS6 GASOLINE AND VAPOR SAMPLE COMPOSITIONS! To help define Che composition of gasoline vapors to which people might be exposed, auto gas tank refueling conditions wen simulated in the laboratory. An apparatus was construct sd which allowed controlled filling/emptying (with agitation) and subsequent sampling of the equilibrium air/hydrocarbon mixture headspace when the liquid level closely approximated 20Z of the total container volume (simulating a refueling at the on`-fifth tank capacity level). Temperature for the test was 79F and the gasoline used was API PS-6. The resulting data are attached in Table 2 for both measured and calculated values. The first data column is a chromatographic analysis of the API PS-6 gasoline charged to the simulated gas tank. The second column shows a chromatographic analysis of the headspace vapors on a 100 wt. Z hydrocarbon basis. As wbuld be expected, the predominate hydrocarbons are those of lowetc molecular weights. The third column is a calculated hydrocarbon composition (100 wt. Z basis) for the headspace, using methods, slightly modified, described in SAE Paper 690506, "Mathematical Models for Prediction of Fuel Tank and Carburetor Evaporation Losses" by W. J. Xoehl, Jr. As indicated, agreement is Ivery close between the measured and the calculated vapor spacb hydrocarbon compositions. Both the measured and calculated vapor space hydrocarbon compositions were then converted to parts-per-million volume of the hydrocarbon plus air mixture without round-off of val1u' es. The measured values shown in the fourth column axe based on the 46 mole Z hydrocarbons/54 mole Z air mixture in the vapor space as determined by the chromatograph or (and confirmed by bass spectrometer analysis). The calculated ppm volume values for hydrocarbons in the mixture are listed in the fifth colurn. These are slightly higher than the measured ppm volume values (482,490 vs. 460,000) because the calculation procedure recognizes all theoretical hydrocarbons in the vapor space, and includes several not detected by the actual chromatograph analysis. Overall, however, the calculated and measured values are in very reasonable agreement. SAL 000005491 Appendix C ET & TMB Charcoal Tube Readings for Service Station Emp loyees Station A ET <0 .05 TMB <0.05 <0 .05 <0.05 <0 .05 <0 .05 <0.05 <0.05 <0 .04 <0.04 <0 .05 <0.05 <0 .04 <0.04 <0 .05 <0 .05 <0.05 <0.05 ro O o V ; Station B ET 0.14 TMB 0.11 <0.04 <0.04 0.03 0.04 0.03 0.04 0.03 0.03 <0.05 <0.05 <0.04 <0.04 0.03 0.03 <0,03 <0.03 0.03 A .oO Stat ion C1 ET <0.04 Tt' B <0. 04 <0.04 <0.05 <0. 04 <0. 04 <0. 05 <0.04 <0, 04 <0.05 <0.05 <0 i 05 <ot 05 <0.04 <0.04 <0, 04 <0 04 <0.04 <0 04 Source: This study was conducted under contract for API by UBTL Div., University of Utah Research Institute. SAL 0000054^2 Tabic LI. Individual Hydrocarbons in. a Typical liasoltnel^TTi. C Cjx |*Oik ii( Aromaiies"'} ^Sengeoe^ - -- Toluene -- Ethyl benzene Xylene 1 -Methyl-3 -ethyl benzene 1 -methyl -4 -ethyl benzene 1.5 13 3.1) ' ity, ^ 0.8845 0.H719 0.8717 0.8730 0.8073 -- Cir;..'i:| OUJUiV 1 t ! 1' i 1.000 1 0 057 1 0.750 0.750 0.666 /cj'/'Butvt benzene 1,2.4-trt methyl benzene 1 7 , / / 0.875G Weighted average density =* 0.8732 c, nl. Weighted rai n> . r arbotis riMitlli'i inrhons present -- 0.7S35 ! 0.503 i Paraffins tt-Butane Isopentane n-Pcntanc 2.3 -Dimothvlbutanc 2-Methyl pentane 3-Methyl pentane -Hexane 7.0 0.5844 1.000 93 Q.G248 1 1.000 4.0 0.6312 : 1.000 1.4 0.G664 ! 1.000 . 3.H 0.657`J 1.000 2.4 0.CG90 1.000 1 3.3 0.6040 1.000 Methyl cyclopontane * 2.2-dimelhyl pentane l.H 0.7159 j 0.928 * 2,4-Dimethyl pentane 2.2.3 -trinicthyl butane 0.6858 0.928 2.3 -Dimethyl peniane -* 2-methyl hexane 3.9 0.6912 . 1.000 3-Methyl hexane - unknown 3-Ethyl pentane 2,2.4 -trimcthvl pentane 2.4 4.9 . 0.6915 0.6994 1.000 : 0.937 f ir-Hcptnnc Methyl cyclohexane 2.2-dimeihyl hexane 2.0 0.6882 1.000 0.7308 < 0.937 2,2,3 -Trmiethyl pentane ' 2.5-dimctlni hexane * 2,4-dimethyl hexane 19 0.7070 0.958 3,3 -Dlmeihvl hexane ; 2.3.4 *lrmvthyl pentane 2.3,3-inmethyl pentane 1 2,3-dimethyl hexane 3 -Methyl heptane 1.1 Weighted average den-it v 0.4512 g 'ml. Weighted rut i<> . enrlhn- <'mnuOlefins 2 -Methyl -1 -butene 0.H trans -2-Pcntcne 0X 2-Mcthvl-2 buier.c 1.7 2 -Methvl -1 -pentene 1 -hexene 03 0.7211 0.7101 4 ar*Kn< P*e-t m = n 0 6357 3 *'533 0.6676 0.6614 i \ 0.937 1.000 i 0 400 0.400 0.200 0.416 \ t r [ ' : t 2 -Methyl -2 -pentene 4,4-Dimothvl-l -pentene 2-Mclhvl-l-h.xene 1.0 0.6913 , 0.166 o.i; 0. G871 0.428 1 -hcpiene 2-ethyl-1-pentene n *< fi 70'ir ! 0.333 i 3 -Methyl -tutus -2 -hexene 2-methyl-2 "hexane -3-hcpiene n.s -3 -h pienc i.o V 0.7053 0.214 < ; i Weighted average <l-nit v * H.iihiiS g ml Weighted ral i<< . 1 irlNlfl- 4 lljllllc M ill furs uheri tu<< or mure i uppi nr unn-i .U* <1 >, <li. nmoiinlH. anti the aviTMi'e <li-n--ilie> not I jivifni,i- rati., \ nine* -in' <. 1 2012 ANALYTCAL CHEMISTRY. VOL. 47. NO 1?. OCTOBER 1975 inriM.it', ir--in - o i*fi;T i t 3 ` rhr< n.ii*'i*r:im, il.. v me a**umed t< In- present in equal 9' . \' V ^ j SAL 00d005493 i 1 , i ^NlPEg NATIONAL INSTITUTE FOR PETROLEUM AND ENERGY RESEARCH Post Office Box 2128 Bartlesville. Oklahoma 74005 (918) 336-2400 April 25, 1988 l SINCE 193 Ms. Dana Burke CONOCO P. 0. Box 1267 Ponca City, OK 74603 Reference: Your phone call of April 22, 1988 Dear Dana: I have enclosed two PIANO analyses from our Siemens gas chromatogr jph. One is the analysis of a blend of sweet crude oils, and the other is t i e analysis of a 250-375F boiling range distillate of the same crude, W ; have this file set up to eliminate the olefin category from the printout be :ause the samples are crude oil. Olefins would also be printed for analysis of petroleum products such as gasolines. We can provide this type analyses on your samp! I trust this information will be useful to you. Call me at (918) 3374256, if I may be of further assistance. Si nee rely, Enclosures Paul W. Woodward Senior Chemist Fuel Chemistry Research COMMITMENT TO EXCELLENCE SM- OOOO C.5A-9* Cau1jj_ s. p. R. P. N. rt. Sample ID: '08-1SCR run on: 3 Nov 1 987 11:13 83 Peaks from File: Jo037H2a Spl.Wt.: S . 5036 / $ t d . U* t . : 355 Normalized Ut . % Vo i . 7. i n Samp J e Wt .7. Vo 1 . % Total Total Total Total Total Paraffins = Iso-paraffins Naphthenes = Aromatics Unknowns = Paraffins: Cl C2 C3 C4 C5 CE C7 C8 C9 C10 CM C12 Iso-paraffins: C4 C5 C6 C7 C8 C9 C10 Cl 1 Naphthenes: C5 C6 C7 C8 C9 CI0 C1 1 C12 Aromatics: C6 C7 CS C9 C10 C1I C12 34.289 25.098 29.289 11.323 -0.000 0.000 .038 2.070 5.104 6.528 S.S29 5.281 5.197 4.443 0.000 0.000 0.000 1.748 4.002 4.909 4.668 4.635 5.136 0.000 0.000 .862 6.828 10.291 9.435 1.874 0.000 0.000 0.000 1.658 3.613 6.047 0.000 0.000 0.000 0.000 37.496 26.457 28.864 9.183 -0.000 0.000 .075 2.891 6.190 7.328 6.007 5.436 5.208 4.362 0.000 0.000 0.000 2.200 4.541 5.254 4.799 4.636 5.026 0.000 0.000 .814 6.294 9.451 8.628 1 .678 0.000 0.000 0.000 1.328 2.941 4.913 0.000 0.000 0.000 0.000 7.436 .443 6.352 2.458 0.000 0.000 .033 . 449 1.107 1.416 1 .22! 1.145 1.127 . 963 0.000 0.000 0.000 .379 868 1 .065 1 012 1 .005 1 t !4 0 . 000 0 000 187 1 4 SI .2d. 046 .406 0 000 0 .000 0 000 .360 7S5 1 31 I 0 000 e 000 0 000 e .000 8.132 5.738 5.SZ6 1 .991 0.000 0 000 01b 627 1 342 1 589 1 303 1 179 129 946 0 000 0 .000 0 000 477 985 1 . 139 1 041 005 1 090 0 .000 0 000 176 1 365 .050 T 87! .364 0 000 0 . 000^ 0 000 .238 638 065 0 000 0 000 0 000 0 . 000 Wii. TV-C_^ U**b *>~iL K ix. SAL 00000^495 ] S. P. R. P. N. A. The Detailed Analysis of^Petroleum Hydrocarbon Samples by Capillary Gas Chromatography Components Listed in Chromatographic Order Sample ID_- <03-1 SCR ran on: j> Nov 1987 @ 11:13 83 Peaks from Fiie: J3087H2a ! Spl.Wt.: 6.5036 / Std.Wt.: . !355j COMPONENT Ethane Propane i-Butane n-Butane 1-Pentane n-Pentane Cyclopentane 2-Methylpentane 3-Methyipentane n-Haxane 2 ,2-0lmethylpentane Methylcyclopentane 2,4-0imethylpentane Benzene 3,3-Dimethyipentane Cyclohexane 2-Methylhe>.ar,e 2 ,3-Dimethylpentane l-Di me thylcy cl opentane 3-Methyihexane It ,3-Dimethylcycicpentane ]^c ,3-0 ime* hyl c yc lopentane 3-Ethyl pentane 1 t ,2-Dimetbylcyclopentane n-Heptane Methylcyclohexane 1 ,1 ,3-Trimethy1cyc1opentane Ethy lcyclopentane 2 ,5-Dimethylhexane 2 ,2 ,3-Trimethylpentane !c ,2t ,4c-Trimethvlcyclopentan 1 c ,2t ,3c-Trimethy Icyclopentan 2 ,3 ,4-TrimethyIpentane Toluene 2 ,3-Dimethylhexane 2-Methylheptane 4-Methyiheptane 1c ,2c ,4t-Trimethylcyclopentan 3-Methylheptane 1c , 21 ,3-Trimet hyIcyc1opentane 1 ,4-Dimethyl eye 1ohexane 1.1-DimethyIcyclohexane 3c-Ethylmethylcyclopentane 3t-EthyimethyIcyciopentane 2t-EthyIroet hy 1 cyclopentane 1.1-Ethyimethylcyclopentane !t ,2-Dimethyl eyelohexane n-Octane i-PropyIcyc1opentane 2 3 ,4-Trimethylhexane N2 2 ,2-Dlmethy1 heptane NORMALIZED Wt. % Uol. X .038 2.070 1.748 5.104 4.002 5.528 .862 3.045 1.864 5.629 .075 2.89! 2.200 6.190 4.541 7.328 .S? 4 3.279 1.975 6.007 .079 3.3C7 .207 1 . 58 .057 3.521 1 .587 .634 .356 1 .959 .082 3.109 .216 1.328 .058 3.185 1.647 .642 . j32 2.007 .774 . 683 . 145 1 .216 5.28! E.676 .414 .5BS .222 .732 .642 . 147 1.108 5.436 6.098 .404 .538 . 222 .299 .386 .517 .085 3.619 .528 1.93! .462 .060 1 . 108 .293 .364 .483 .063 2.941 .522 1.948 .462 .055 1 .106 i.769 .641 .215 .230 .208 .632 .074 .847 5.197 .085 1.618 .592 . 1 94 .203 .199 .574 .068 .769 5.208 .077 .037 .075 .352 .036 .063 .051 i n Samp 1e Wt X Uol X .008 . 449 .379 1.107 .858 1 .416 . 1 87 .660 . 404 1 .221 .016 . b 17 .4 77 1 .312 .935 1 .539 .176 .711 I .428 1 .333 .017 .717 .045 .360 .012 .764 .344 . 137 .077 .425 .0 8 .6 ?4 .0 17 .2; 38 .0 3 .6' 31 .3! 57 . i; 19 '2 .4$5 . 168 . 1 48 .032 .264 1.145 1 .448 .090 . 127 .048 . IS 19 . i: ;g ..M40*:A 12 0 i. r '9 1.3; 2 .af . 1 17 . 0i 8 .065 .084 .112 .018 .785 .115 .419 . 100 .013 .240 .06 4 .0' '9 . 1C 15 .018 .s: Is . 1113 .4:j3 . 1C .0 -0> ,2i10 .384 .139 .047 .050 .045 . 137 .016 . 184 1.127 .018 .351 .12 .04 .04 | .04! . 12 5 .0 1|5 . 16 7 1 .12 9 .017 SAL 000005496 .008 .016 .01 1 .009 .01b .01 2,5-0lmethyiheptane n-Prcpylcyciopentane 2 ,4-0imethylheptane Et hyicyclohexane 2 ,6-Oi.nethylheptane 2 ,3-Oinethylheptane N5 NB N? E t hy i benrene 2 ,5-Dinethylheptane P3 rn-Xy 1 ene p - X y i ene P4 P5 4-Methyloctane 2-Methyloctane t c ,21 ,4t-Trifnethylcyclohexane 3-Ethylheptane 3-Methyloctane o-Xy 1 ene N1 1 N! 2 N1 3 P7 l-Butylcyciopentane N1 4 N1 5 n-Nonane .432 2. 145 .794 .844 .400 .051 . 1 35 .076 .083 1 .34! .350 .034 2.147 1 .232 .295 .073 .588 .796 .097 .244 . 933 1 .327 .417 .728 .459 .057 .096 .048 .029 4.443 .417 1 . 947 . 782 .755 .397 .049 .121 .058 .074 1 .090 .340 .033 1 .754 1 .007 .285 .070 .578 .783 .087 .236 .913 1 .063 .373 .652 .41 1 .055 .086 .043 .026 4.362 .094 .465 .172 .183 .087 .01 1 .029 .016 .018 .291 .076 .007 .466 .267 .064 .016 . 128 . 173 .021 .053 .202 .288 .090 .158 .099 .012 .021 .010 .006 .963 1 .090 i .422 i . 1 70 . 164 .086 .01 1 .026 .015 .016 .236 .074 .007 .380 .218 .062 .015 .125 .170 .019 .051 .198 .230 .081 , 141 .089 ,012 .01 9 .009 r006 .946 SAL 000005497 iZ. 3 wlL ^ CajulI*. AP = xeo-37S*A c. F. R. p. N. A. Sample 10: 0B-I5CUTJ run on: 4 Nov 198 @ 02:3 Total Total Total Total Total Paraffins * Iso-paraffins Naphthenes * Aromatics * Unknowns * * Paraffins: C! C2 C3 C4 C5 C6 C7 ce eg C1 0 Cl 1 C12 Iso-paraffins: C4 C5 CS C7 C8 C9 CI0 Cl 1 Naphthenes: C5 CS C7 C8 CS CI0 Cl 1 C12 Aromatics: CS C7 C8 C9 CIS Cl 1 C12 209 Peaks from File: J3087H8b i Spl.Wt.: 7.2S34 / Std.Ult.: .13$2 Norma 1 i zed Ut.% Uol.X in Sample Wt.% Upl.% 23.831 20.092 23.S8G 28.3S3 4.029 0.000 0.000 0.000 0.000 .009 .022 .398 5.42S 8.118 6.858 2.838 . b3 0.000 .007 .015 .137 2.385 8.554 7.803 1.110 0.000 .092 1 .514 9.883 S.523 5.585 .046 .042 .026 1.195 10.111 9.155 5.362 1 .480 . 034 25.809 21.475 23.501 25.396 3.819 0.000 0.000 0.000 0.000 .01 1 .027 . 455 6.017 8.819 7.323 2.990 . 169 0.000 .009 .018 . 156 2.642 9.253 6.227 1.170 0.000 .093 1 .533 9.934 5.403 5.452 .045 .042 .023 ! .075 9.086 8.218 5.55 J 1 .302 . 030 21.937 18.496 21.804 26.110 3.658 0.000 0.000 0.000 0.000 .008 .021 .366 4.995 7.473 6.313 2.612 .150 0.000 .006 .014 .127 2 . 1 96 7.875 7.256 1 .022 0.000 .084 1.394 9.098 6.005 5.142 .042 .039 .024 1.100 9.507 8.427 5.857 1 .362 .032 n 5.756 n1 3.769 .634 >.379 5.467 ?.000 5. 000 5. 000 3.000 .010 .024 .417 5.539 I 18 5.741 2.753 .156 5.000 .000 .017 . 1 44 2.432 >.517 f. 573 .077 5.000 .085 .411 3. 145 3.895 >.019 .041 .038 .02) .989 5.364 7.565 .21 * B . 1 98 .029 SAL 000005498 S. P. R. P. N. A. The Detailed Analysis of Petroleum Hydrocarbon Samples by Capillary 6as Chromatography Sample ID: 06-15CUT3 run on: 4 Nov I 98 @ 02:3 ted in Chroma t ographic Order i *7 09 Peaks from File: J3087H8b Spl . Ult, : 7.2B34 / Std.Wt.: .12 52 COMPONENT 1- Pentane n-Fentane 2- Methyipentane 3"Methylpentane n-Hexane Methylcyclopentane Benzene Cyclohexane 2- Methy1 hexane 2 ,3-0imethylpentane 1 , I-Dimethy1cyc1opentane 3- Met hylhexane It ,3-Dimet byicyc1opentane 1c ,3-Dimethyicyclopentane It ,2-Dimethylcyclopentane n-Heptane Methyicyc1ohexane 1 ,1 , 5-Trimethylcyc1opentane Ethylcyciopentane 2 , S-Dimet hy1 hexane 2 ,2 , j-Tnmethylpentane 1c ,2t ,4c-Trimethylcyclopentan 1c,2t ,3c-Tnmet by i cyc 1 cpentan 2,3,4-Trimethylpentane Toluene 2 .3-0imethylhexane 2-Methylheptane 4- Methylheptane Ic ,2c ,4t-Trimethylcyclopentan 3- Methylheptane I c ,4t , 5-Trimethylcyc1opentane 1 ,4-0imethyicyclohexane 1.1- Dimethy1cyc1ohexane 2 ,2 ,S-Tnmet hyl hexane 3c-Ethylmethylcyclopentane 3t-Ethylmet hylcyclopentane 2t-Ethylmethyicyclopentane 1 ,1-Ethylmethylcyclopentane It ,2-Dimethylcyclohexane n-Octane i-Pr-opylcyc 1 opent ane 2 ,3 ,5-Trimethy1 hexane 2,3,4-Trimethylhexane N2 2.2- Dimethylheptane 2fS-Oimethylheptane n-Propyicyc1opentane 2 ,4-Dimethylheptane N4 NORMALIZED Lit. % Vol . % .007 .009 .009 .006 .022 .024 .026 .068 .044 . 022 .009 .01! .01 1 .007 .027 .025 .023 .068 .051 .024 .013 .071 .039 .033 .072 .398 1.237 .089 . 120 .013 .081 .041 .035 .072 .453 1 .250 .096 . 122 .051 .072 . 121 . 184 .036 1.195 .259 1 .032 .256 .039 .057 .078 .126 . 190 .039 1 .075 .284 1.153 .284 .040 .677 1.402 .525 .189 .012 . 1 95 .182 .534 .065 .899 .747 1 .418 .537 .189 .013 . 196 . 182 .537 .065 .904 5.426 .108 .060 .054 .095 .081 .650 3.207 1 .271 .050 6.017 . 108 . 065 .059 .095 .089 .695 3.221 1 .395 .050 in Samp] e Ut . % k oi % .006 .008 .008 .006 .021 .022 .024 .062 .041 .020 .008 .010 .010 .007 .024 .023 .021 .062 .047 .022 .012 .066 .036 .031 .066 .366 1.139 .082 .Ml .012 .075 .037 .032 .066 .417 1 . 151 .088 .113 .047 .067 .111 . 169 .033 1.100 .239 .950 .236 .036 .052 .072 .116 . 175 .036 . 989 .261 1 .061 .261 .037 .623 1.290 .483 . 174 .01 1 . 179 .167 .492 .059 .827 .688 1 .305 .494 . 174 .012 . 180 .168 .494 .060 .832 4.995 .099 .056 .050 .087 .075 .599 2.953 1.170 .048 S .539 .099 .060 .055 .087 .082 .'640 2 .965 1 .275 .045 SAL 000005499 hi NE N7 Ethylbenzene 2 ,5"Dinethyiheptane P3 N9 n-X y1ene p-X y1ene 3,4-Dinethylheptane P4 P5 4-Methyloc t ane 2-Methyloctane 1 c ,21 .At-Trjnethylcyclohexane 5-E t hy1 hep t ane 3-Methy1oc t ane ? ? o-Xyiene P6 N1 1 N12 N1 3 P? i-Butylcycl opentane N1 4 7 N1 5 n-Nonane 1 ,1-Ethyinethy1 eyeiohexane N17 ? i-Propylbenzene Ml 3 i-Propy1 eye 1ohexane PI0 3-Et hy1 octane 2 ,4-Dirnethyioctane 2 , 6-Dimethyloctane 2 ,2-Ethylmethylheptane n-Eutyleye 1 opentane PI 3 P!5 N25 ' n-Propylbenzene 2-Methy1 nonane 2 .o-Dinethyioctane 2 ,4-Diet hy1 hexane N27 '-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene NZ'S 1 ,0 ,5-Trimethylbenzene 7 P22 5-Me t hy1 nonane \-Met nyl-2-ethylbenzene 3-Et hyloctane N30 lt-Methyi-2-n-propy1 eye 1ohexa N3 f P23 1 ,2 ,4-Trlnethylbenzene t-But yleyeiohexane i-Butylcyclchexane P24 ? N34 ? N35 i -But ylbenzene sec-But ylbenzene n-Oecane P26 .274 . 1 40 . 1 45 2.063 .526 .092 .035 3.5)7 2.020 .062 .413 . 128 1.068 1 . 430 .225 . 443 1 .691 .041 .033 2.506 .051 .74 9 1 .295 .807 . 127 .215 .105 .024 .056 8.118 .886 .040 .015 .584 1 .001 .491 .067 .399 .066 .270 2.193 .608 .229 1 . 943 .133 .065 1 .035 .577 .040 .111 .038 1.712 .640 .567 1.112 . 104 .404 1 .058 2.035 .325 . 108 1 .307 .306 .055 1 . 1 96 .339 .583 . 146 .038 .213 .034 .169 .144 .032 6.858 .093 ?^ ] !)39 . 1 43 I .950 .673 .098 . 035 3. 190 1 .826 .067 .440 . 137 1.161 l .556 .223 .475 1.830 .044 .036 2.220 .055 .742 1.284 .800 .136 .213 .104 .024 .066 8.819 .857 .039 .014 .528 .969 .478 .065 .420 .071 .290 2.349 .594 .245 1.895 . 130 .064 .939 .614 .042 .118 .037 I .544 .577 .554 1 .002 .094 .428 1 . 125 1.802 .349 .105 1.276 .299 .059 1 .065 .331 .569 .157 .041 .208 .033 . 164 .130 .028 7.323 .098 . 2 --' \ T2 . ' JO 1 . 903 . 577 . 084 .032 3.237 1 . 860 .057 .380 .118 .983 ! .317 .207 . 406 1 .557 .038 .031 2.307 .047 .689 1.192 .743 .117 . 1 98 .097 .022 .061 7.473 .815 .037 .013 .537 . 921 .452 .062 .367 .061 .249 2.019 .560 .21 1 ) .788 . 122 .060 .952 .532 .036 . 102 .035 1.576 .589 .522 1 .024 .096 .372 . 974 1.873 .299 .099 1.203 .282 .051 1.101 .312 .536 .135 .035 . 196 .031 .155 .132 .029 6.313 .086 2=0 T:s i. i 32 1.712 1 cic ! 090 033 2L 927 ! '.68 1 i 06 1 r 405 . ) 26 1.069 1 .f4~317^ !r 20PJ ^437 1 ;665 .041 ,03- 2,044 i 05 1 \ 683 1*182 j 756 * 1 26 . 1 96 .096 .02 2 i 06 i 8jj i8 *789 '036 J^ 0*1* 3** .:48S j892 .440 .060 J387 .j065 .267 2.163 .547 2226 1 2745 2)20 .1059 .864 .65 .039 ,^09 .035 1.422 53 j !pS6 .394 1 1 .659 . p2 1 .097 1.174 .275 . 054 .980 .304 .523 . 144 .039 ! 91 .030 . |5! .[20 .026 6.T41 .090 SAl 000005500 *? 9 9 N5? ? sec-Butylcyclohexane 9 ? 9 PZ7 N38 ? 1 ,3-0ie.thylbenzene ? l-Methyl-3-n-propylbenzene ? 1- Methyl-4-n-propylbenzene n-Butyl benzene !,3-Dimethy1-5-ethylbenzene 1 ,4-0iethylbenzene 7 1 ,2-Diethy1 benzene 1 -fie thyJ-2-n-propyl benzene 2- EtHyl-t ,4-dimethylbenzene P28 1,4-Dimethy1-2-ethylbenzene 1,3-Dimethy1-4-ethyibenzene P 29 1 ,2-Dimet hyl-4-ethylbenzene Af4 1 ,3-0lmethy1-2-ethyIbenzene 9 9 7 ? 7 9 7 (2-MethyibutyiIbenzene A15 n-Undecane 9 1 ,2 ,4 ,5-Tetramethylbenzene 1 ,2-0imethyI-3-ethyIbenzene 1 ,2 ,3,5-Tetranethy1 ben:ene 7 9 ? P31 7 1-t-Butyl-2-methylbenzene 7 *1 A2 A3 A4 A5 7 n-Pentylbenzene 1t --M--2 -- <4-MP )cyclopentane A6 A? A8 P32 7 A9 9 9 7 A17 9 A10 n-Dodecane 9 Ioe: . 1 09 .016 . 145 .210 . 1 34 1 .273 .072 . 1 45 .672 .017 .335 . 167 . 1 33 . 034 .930 .061 .207 .452 .288 .046 .039 .489 .460 .407 .429 .931 .384 .457 .335 .041 .067 .023 .032 .100 . 154 .134 .046 . 1 77 .332 .119 2.e36 .067 . 100 . 1 IS .137 .073 .022 .077 .115 .031 .016 .033 .112 .027 .253 .107 .158 .025 .058 .042 .057 .054 .068 .055 .047 . 101 .128 .01 1 .007 .017 .009 . 034 .183 .018 . 0r5 . 096 .0 14 . 127 .206 .131 1 .247 . 07 i . 1 23 .656 .018 .327 .163 . 1 20 .031 . 842 .055 . 1 97 . 401 .255 . 04 ! .035 . 443 . 403 .362 .452 . S3] .337 .481 .254 .036 .076 .020 . 028 .088 . 135 .113 .040 . 1 55 .293 . 104 2.990 .071 .089 . 102 . 121 .065 .019 .068 . 121 .032 .014 . 029 .098 .024 .223 .094 . 139 .022 .051 .042 .051 .048 .060 .058 .049 .089 .113 .010 .008 .014 .007 .030 .169 .0)8 . 26 . .101 .014 -7*7 ! 94 , 1 23 1.176 . 067 .116 .613 .015 .308 . 54 . 122 .031 .856 .056 . 1 90 .416 .255 .042 .036 . 450 . 424 . 37S . 395 .957 .354 .490 .308 .036 .080 .021 .029 .052 . 42 . 123 .042 . 163 .306 .110 2.612 .062 . 092 . 107 . 126 .068 .020 .071 . 106 .028 .015 .031 .103 .0?275A .098 .146 .023 .053 .039 .053 .050 .063 .051 .043 .093 .118 .010 .007 .016 .008 .032 .150 .016 .250 , .035 .013 .117 . 1 39 .120 1. 148 . 065 '.113 .604 .016 i. 301 . ! 50 '..110 1.028 ,.775 .0G1 i. 172 i. 369 1 236 1. 0p7 032 .407 .371 ,.333 .415 L 765 1310 'r,443w f 270 ,033 . 070 .018 + 026 |081 ; 125 1 108 .037 . M3 .269 j 096 9 l 7C7 ^065 J 08 1 1094 .jin 059 01S 062 1 12 030 .1013 027 091 022 205 086 128 020 047 038 047 044 055 054 045 052 104 009 006 013 006 &2S 1 55 017 H 0 in m 0 0 0 0 0 < tn Aa v;* N*'-1 MO b'V trtT rCC C'Nm\^vr" C?t. Z^>j Uu. j #-A&- }'3(* toki >CM\/eX Laicc CH^ pcyuCA nN iM>7 'l S3 (.31 T-.H-lo 7 AmC^ ^8% 52-X 5/ 7. 5-5 7,, SAL 000005502 aiejs ' Pl!d *' on qof eossooooo ivs jeeqs uouB|no|eQ 3UJ OOOUOQ A0 pivr-:4j .-0 | XS3V*pTj<=<J^ '^TNV<5?'ng ptOuA/^^voj-^ 3Vd3T3^ V<!3 (^) * ii1' i1 | i , . 1 !M : l1 j : 1` j ! ! i!' 1i;i 1! : 1i j 7 bOO'Q IIOV h' Tf? ; rb lo'O 9b7o`0 b^O'O U^bO-O SkoQ'0 a?7 LrO gl "0 bv 9\ ! ; 3<PL O x>ch?/\ to ps* ia cn^US>90J^7j cn -opr^ ;? uu *n-j ('o3Uv,x3MOp(p ^3>MrtH5q 0) ^wpnjCJj^ to p-^.UJpL^ t5e/u v^Aje; 0,3 G^CLoHeyAAir ] OCAJEAJ^t-TTrV^t_ 3t/Vt7UT }A Y>- xyucMC. . o-xyuam__ G-OMOVfc : J 'P's eu/^i) Cl/ (yicAye 0.1 U ; 0.1 O..*) 6.^7 .. O. J&7 o-z% Q. 1 7 j_ AJAl>/!77i*LE7Ue:_______Q'C>/ ' _..... I 'Sry^4e:j.._ j_._[___L__!.Q|q15..-LJ ij -*- . A\o OAJL Kt^"' Ii IIi Ser Aliped <5-0 ~Au*v>|&is )w ?vT^cufc/jc ^ ~i Made By Cocked By Oate Page of Conoco inc. Calculation Sheet Title SAL 0000|0550A Job No F:i*:d Slate CONOCO ACHIEVING * *** ** * ** * ** SAFETY ** * # ** * EXCELLENCE INTEROFFICE COMMUNICATION To: All Supervisors From: Tim Ityera Date: Januarv {<'7, 1938 Sub ; ec t: Lab Results Of The Refinery's Streams That Have Been Tested For Bsn:enp Content rn Attai_hed you will find a list of the rsMnery's streams t have been tested for Benzene content. The samples dated 1 14-87, were tal'.en after the HAD from Tanf.- Z7 had baon injected into the 4 Z CTU* s crude charge for over a w4er. The total Benzene content of # " CTU * t crude snar^e wan & J.7.V. . We are monitoring a represented number cf the job t**sts wherr an employee is exposed to a stream wj th j Benzene concentration of 0.1V. . A list should be develop by the Operating Department of all equipment that is in service of these streams, or any l.ie streams that would contain 0.1 v. Benz ene. Please contact the Safety Department, in advance, as equipment m service of these streams is brought down;for repair. This will help us in setting up the personnel monitoring required by the new Benzene Standard. Many of the employees have already rct?i /ed th results o the monitoring that they tool part in. Additional results will be made available as we receive it. Please contact your area Safety Super/i*or or the Safiet / Department with any questions concerning Benzene Exposure. Safety Supervisor 04/'c:6/SS 21:29 005 BENZENE RESULTS OF REF INERT'S STREAMS UNIT SAMPLE FIRST RESULT SECOND RESULT 1 HDS UNIT l* 2 CUKfcN It 1 HDS EFFt. IJENT # 2 COKER GASOLOINC 0. 1B7. (01-31-06) 0. 43V. * 01--23--86 5 I?. 197. <12-14 # 2 CRU ^ HDS * 2 CRUDE UNIT # 2 HDS CHARGE # 2 REF. REFORMATE # 2 LSR GASOLINE ff 2 NAPHTHA 1 . 167. (01-71-06) 2.717. (01-31-36) 1.957. (01-31-86) 0, I 87, (01-31- 36) 0.707. ( 12-14-8" J. 767 <12-14-F7 5.497 f12-14-2? i. 2 1 7 (12-14-27 # 7 CRU s HDS * 7 CT(J # 7 HDS CHARGE It 7 REF STB OH L TO It 7 REFORMER CHARGE ft 3 REFORMER REf-ORMAT 1 . 167. < 0.17 1 . 177. 2-717 (01-31-86 > (12-14-87) <12-14-37) (01-31-86) # 3 HUD CHARGE (W/ 500 BPD HAD) Desalted Water <0.01% <02-ii4-B6> 0.37. (12-14-37) <0,017. (12-14-07) 1-01 7 <12-14 -3" 1 207 (12-14-e- 0. 037. < ) 2 -14-27 # 7 CTU 3, VAC It 3 LSR GASOLINE It 3 NAPHTHA 2.797. (02-04-06) 0, 417. (01-32-86) 5. 287. <12-14-8^ >.417. <12--14-97 # 4 HDS # 4 HDS Strip* OH L2 0.197. (12-14-87) # 4 Mod It 4 Fr jc. &tm*. It 4 Fr ac. HOD *t 4 Frac. Naphtha It 4 Frac. UH Liquid <0.017 C12-14-87) <0.01% (12-14 87) 0. 077. <12-14-07) 2. 767. (12-14-87) * 6 HCS n 6 HDS Strip. OH LQ 0. 1 27 (12-14-07) ALKYLATION UNIT CASINGHEAD TOTAL ALKVALTE PBC DENUDED CASINGHEAD . 0.01 7 (02-02-06.' 1.297. <02-03 *06) ^^ 4 QOg**tM/ <i2-14-S7 CAT POLY UNIT CAT POLY GA3QLINE < 0.01 7 (01-20-06) FCC PRODUCT FRACT GRP FCC GASOLINE LV7. FCC GASOLINE GRP GASOLINE 1.217. <01-28--06 > 1.217 (01-28-86) 0. 397 <01-28-86: 0.937 <12-14 5" 0.457 (12-14 7 LITE GASO. SPLITTER PRIM TwR BTMS PRIM TWR CH GASOLINE '0.017 <01 31--S6 J 0. 527. (01-31-36) 1.41 7. . ic-14 ~ l FARM TK. 73 LSR tt . as fcc. cp 1.707. (12-14 87 0.877. (12-14-07) SftL 000005505 THCRMAL CRACK CP THERMAL GASOLINE W- 10 GASOLINE W*i0 NAPHTHA 0.237 (02-04-86) 3. 157 (02-04-36) 2.297 <02-04-86 ;i . 667 (12-14-2. !3. 737 (12-14-3 4.6 27 (12- 1 4 *S' '^t~!~'*' J %*. r. * 'm.% ^^n*pf- ^4r, k;-/r. .g y __^i,, H ' * ~2f &pr. V<r(% Y O . gg Ptrr^ty O-U' /Uf Zttc^ir\ ?-/** P)PZ @ 60*F ~^2&ditJi jj'di-tfA^'&.i' rJfiJg.Le>'. cS'. tyOtj&O-dLat* yc'l4r*r / '.'/. '' ' y * 5Z7 &!*$ pf /<* /p--t 7-f.^ V " Vp&o*ry pjCr .i.cxZ-Z^ /&.4 - -} V <* v^;. ' Gt A z(?5 m) -Or P-oa-^ t-,> o<? (^7 Roth Y y J p', / -0 - 63. 3 33.2. 13.7 ~i2.6 H $_ f~.? 6o,7 7/?, & .^t.7~ Q &*Cg ?/rrJ VoS-te- 0.7i$ 0.7?? 7?/ 0,726 3.35? 0,726 0.V6Z. _f-7*7 V, 7J5 D,6 5? 2.776 3.^ 7- / LI.. / 0 0.7'... /. 0 *?_ 3.0 .3 >.2 <o./ o,2 to z,r z.3 1.2. c-7 J,Z 0,1 z.t t-.e t.3 Y/ A7 SAL 000005606 SAL 00000550$ ftPPENOlK F SouD Wrt-STE DATA calculations Ar/o Title Conoco Inc. Calculation Sheet SM. 00^05510 Job Nt>. Field i State LAND Release: son/m fifty LAKE. CtfrtrtLES CHEAiicAL g B-tiiENP Tolue/VE ETffYL &E-NZBCIE STY/?(VE XYi-e/VES PWtfO (YAPrf-nMUSAe LAVO RELEASE to lAyVfl X ^/vV, IO. i so. 71. 12, 3 40. ir, H<jo . fi|=-EfKE To j*.'* ^/v*) ^3. ISo. =1, I to, I. -laoe S / :-ge Corccs 'nc Calculation Sheet Title SAL 0^)0005511 ! Job No. i Field State | ; -- /-- /A K o V/^-re, 'ii/S5Jor/^ CD IB 1 0L 04/Cv>c ^oc/Os - CTc? jy T/ff ^ Pc* '07'-r'<?rsOs>' r ~7s>%tc S- 3 193? \socut~*c = / 7, 390 vos. Cpvsi 17.330 vo^ x 3 3 ^T"7 CYO <;?,4 cq * , 1- ^ 14,6 50 TMWI 5 C *= 5 e>c>e> u a "To "V-c 6x ^7/vSCC .T-S^ ^ TS (s/ i aC 204>0 L.0 - .3-* , T<? v = i 52? 7 ooo -= *7, O L- di/ViS-^-ra. ,0*' ` i iouuiz^o - JA-CSO < , 066 >o` < Jooo -- j?0, 7 t fi */Ycj* * 1 t_7"Xyyc *j 2. c*j c; ~ ( A C O y . ??y a 5jy - / o* / , O c <$-r/ yew j 'XYLC'VCt " IA&SO y 5.3/r x /o* ! = C2> u$f/Ye** \ N>15/c _p/->0^Oc - lACmSO y . 9r /O * y 2oov r ?9.& t-&j/'r*ii i - lACSo y tt> , i = 7, & <- 6^/yca.* ` /\J/i. pMTA/ACC'Wtf =* IACSq y rx y r 2i"3 cs^/yca/ *oc i Z-<J^O s' Ijljf. Cn \'f<ec / 0.:te - t QS 0 * V.r f0 ( x 3<>V<x ~ 13 5, i- ft/j/Vc-*- * *i Conoco Inc. Calculation Sheet jooNo SAL 000005512 Title Field State ; /4 PJZ -- 0 or^&cs.t-rtq m pe* /?y'-rs?e*+r*> ir~. y-\ t S-y <g) ^S1? \/oc-ut--ic. ~ I -Sq yoj5 (Pen. 0/?4w5 7j i?ncaj 13 P O vor m ?%T7 . 2 4- *-7 * - 1 i T 1 l f\ 2. -T1 O \J $ c vc> w r .*0001/ i ] o *tv\ *y $ . c TVy rj ce r- vj) , "7T? * "n/w 9 <- f3s i CMiT7tf<? *= / y y 2. ,< j?g>go /O6 1 -- ^_r?*r/V/? 1~C <- VI c AJ C T Ill 2. y n& * ?_o to& / - v* t:7vyt 8e*->2-c~>c - ///z * V7 y 2000 />* f ^ Tyy? Co ~ in z * / 2.2 * 2 ooo /o< / y.YCc<u<.s r mx * * ^ 00 toc / - 1 - ! * Y3. ?<-#//* - ///z -ill * 2ooo / 0* t - V/ ?! oA-/ v/? OC. ~ ///z < JJL X * r to* / f\jApL/7A/ACC*J6 ,4iL Vaco 2 ,C ^ec ^ ec By Lars pAce of - tt/Z * ?9J x lava /o / J//2 > /0. * 2 000 to ( / Conoco Inc. Calculation Sheet Title - /?s~$ t-es/Yn - i?y 4*s-r// ** SjAL 000005513 Job No Field State 3.fWj -i r n iy^zif3~A,r R-r-v.-v r i t) C N\ '< v'n h' 0 ( Kio.Pr A 3 ' C l f- v: luX *v> j) x -rs ' r 'L^/re J Cs^ic rt'r-rsTC '~, f- ~*~J OX : ^ - / .l; -\ r: x o' / ~. u* -, - /o.*T o;l - /.`liv;- is. = .32^ " /^./, ( ;1. * *2. -U ( 1.* J 2--'>(.C>1^) - /,X> '' 2=0- 4 H=-tY ,64'/''' ' "99,5 ' 'S'- -+ Zi ' ^ d04<i-tXT / :-j ' V U1 _r 4- _.f Vaae 3/ CnecK^o 5v Date page Title Conoco ;nc. Calculation Sheet 000005514 i job No I Field State ChcjaDv^t* U -R LAND TREA7M2N i" MODEL DATA (]. an d t!" eu L ment 1 L,Leading \q cdi/c::c: soil) Enter Ci 2; 10 "` d VO ppmw 1 . Depth (citi! Total porosity Air Porosity (do-? am i.--"0 ) MW ail OO rii SB. in water, enter l Time ci calc, (days) Biodegradation, enter 1 Temperature:' (Deg. 0 -1 ;.'J i n d E; p e -: d (m / 2 ) Area (m2) 0. 006 2000 20 0 . i 1 .0 292 360 ' ct; i nc4 1 . 47 ^l._J 000 1 COMPOUND NAME METHYL ETHYL KETONE BENZENE TOLUENE CRES0LS NAPHTHALENE PHENOL CARBON TETRACHl.OR I DE TRICHLORQETHANr 3. , 1. , 1 ) METHANOL ETHYLBENZENE CUMENE (isopropv1 .r: a nr XYLENE<-0? LANDTREAT FRACTION LG 8 7 A i F: V* V 1 s* ! INTERMEDIATE T ME : . R `365. 25 day:PIfj: . . 7i* .. 90": 0. 49'! 0. OS6 o, 04 7 f '.076 0. 998 0.998 0. 966 O - 33T 0.990 0.. 320 0. 306 497 0. 506 0.944 953 0. 924 7 0.002 0.03 4 .1.: L/ w / `0. '2'02 O. 680 0/714_' 0.903 0.492 0.056 0.047 0. 076 **, * ;* 0. 993 0. 966 0. 362 0.968 O 3 mo "to. 286 0.097 ;0. 503 ;o. 944 0.9 |0.924 O'. oo0 j'J m 1J 'j 10. 0- -1 : 0.630 !-0 . OOO \0. 680 SAC 000005515 Estimating Land Treatment Air Emissions Based on EPA Land Treatment Modi Compound Benzene Toluene Xylene Phenol Ethylbenzene Cresol Naphthalene MEK MIK Acetone Land Treatment Fraction Lost Air B|iodeqradation 0.903 0.097 0.494 0.506 0.320 0.680 0.076 0.924 0.333 0.667 0.056 0.944 0.047 0.953 0.714 0.286 0.969 0.031 0.978 0.022 SALi 00005S16 SUMMARY OF t*6lE 5-3 CONTENT WASTE CHARACTERISTICS Panaattr Oil and Great*, ng/icg Chioroe, ag/kg Mttala, mg/kg Arsenic Bariua Beryllium COM It Nul IT Of SMpi.es Above D.u Mean Range Lower Upper S.O. , c.v. 6 53100 5 1502 1900 170000 63720 1 .20 580 *000 1443 j 0.96 i 0.3? <0.23 <4.3 *** 1 6 66 32 12* 35 : 0.53 Z 0.16 <0.096 0.22 0.06 | 0.36 6 1.1 0.6 2.1 0.6 j 0.51 jttaszzz Selemua vanadium Mercury Volatile Organics, mg/leg Carbon disulfide Chloroform 4 2.? 0.7 <13 2.5 0.93 6 2.0 1.1 3.8 1.0 0.51 4 0.4 <0.10 o.aa 0.3 0.91 1 0.0027 <0.005 0.0027 ___ 2 0.012 0.012 <1,2 m m ST pnenanrnrene Anthracene Fluoranthene Pyrane Bia<2-etnyylnexy Ophthalata* 8enfo. a /rtnracer.e Chryaerp Benzov6)fluoranthene1TM 3en*o(k)f iitorartnane Benzela^pyrene Dioenio(arri;antnracene 2-Methy. naphtha^ant 6 30 3.2 5 8.6 1.2 6 40 3.0 6 140 9.5 2 0.39 0.26 6 4? 3.3 6 52 4.2 5 56 <0.67 5 58 <0.67 4 24 <0.67 5 5.20 0.20 6 22 3.0 0-L- Detection Lia\t * aApoond detected in blank ** * coeluting laaeera *-*- n 'ievietiin not possible tar one sample. 81 31 180 640 <26 220 390 260 260 80 11 66 3? 13 i 70 i 248 0 *8 52 3 : : : 13 28 4 r.r , ; ! G7 1.48 1.74 1.77 0.47 1.82 1 . SS 1.97 1.97 ' .56 1.41 1 .10 SAl| 000005517 4^ Parameter on and Grease, eg/tcg Chloride, ag/fcg Natela, eg/kg Araenic Benue TABU 5-4 CONTENT WASTE CHARACTERISTICS Nuaber of saepiea Mean Range LOwer Upper S.O c.v. 143950 J1?0 2700 310000 105859 1200 9600 3743 0.74 ' ?0 0.42 83.3 <0.23 34.0 <4 3 145 0 0.07 40.1 0.17 0.48 volatile Organic*, eg/kg Ban tarnm ScewoUtile Organics, eg/kg 1,2-61chlorobenzene mam BSI n 3.4 <3,3 Phenenthrene Anthracene &i(n)butyi phthelete* ftuoranthan* Ryreoe eta<2-ethyi,ne*yOpntriai,at 0*iiJQ()antnracen$ Chrysene 6#nio{b)f Luorantii*ne Bn2o(Jf Luoranthene 8en2o(a)pyrfrne o i ben *o( a, n / an n racene 2-nethyl nopnthaiene 1930 131 310 109 519 5.8 70 143 39 39 33 3.2 2384 <33 26 <3 3 27 <33 <3.3 15 25 13 13 <3.3 1.4 500 0 c Detection na^t " coapewno Ute*teg .n elan* ** " coeluting 1aa#ri - 5taAa.u Jev*ai(ij: .Ajajlbie fji jtaapie. <120 7900 250 iin 220 1200 <120 140 280 90 90 72 <120 4800 2V5J 73 2> 2.5 1914 a.w -*> C.8G 05^lS 000 SsaA- 0M *2 *1$ 1 C*a.X & c - ispD C X 2Ar N\ P V^*-w^a t. c J- " O^uJ SOLt ^ O AST?" <\e cLxvfxo*^' f / ta 'hi-y^aS - i f( / "7 /&- ^ ^ <**- r - . ZS \ Wvw A 13 W* W v , Vvsr 0 0 ^ jv VuaJ&a\< ^ I --ov.-'.\%\p.vwO^ ^OO^t) -4. SAL 000005519 U <X \ Zb zj n\ TAftlE 5-4 SUftMAKY Of NIGH OIL CONTENT WASTE CHARACTERISTICS Nuabef Range et P*rMtr Saaplea Neon Lower Upper S.O. i C.V. ***- -- OU and Grease, ag/kg Chloride, ag/kg 6 143950 S 3120 2700 310000 109659 1200 9000 3743 0.74 1.20 Hatala, ag/kg Arsenic Bariua ierylliue 2 0.42 <0.23 <4.3 0.07 0.17 7 S3.3 34.0 14S.0 40.1 0.46 A 0.14 45.10 0.18 0.03 0.23 Cobalt 7 2.1 0.6 4.7 1.7 o.ai Chroeiua 7 7.7 4.6 13.0 2.7 0.36 Load 6 10.6 2.3 20.0 7.2 0.66 Nickel 4 S.3 <2.1 12.0 3.7 0.45 Seleniue 4 4.5 0.4 <13 4.1 0.90 Vanediua 7 6.6 1.0 20.0 6.7 0.9B Hereury 3 0-43 <0.074 0.50 0.13 0.30 VoLatil# Organics, ag/kg Bansant Toluene Ethylbenzene 7 43 7 121 7 43 10 100 32 0.75 36 310 99 0.77 17 66 24 0.56 Styrene Total Xylenes Nethyl ethyl ketone 4 12.2 4.5 7 196 17 1 2.10 2.10 33 13.9 520 171 <24 ** 1.15 r 17 Seai-velatile Organics, ag/kg Phenol 1,2-M chlorobenzene 1 3.6 3.8 <67 *** 1 3.6 <3.3 <120 Hi Naphthalene Phenonthrcne 7 791 6 1930 140 1600 477 0.60 <33 7900 2953 1. S3 Anthracene OiCrObutyl phthelete* 6 131 28 250 73 0.S6 1 310 <3.3 310 *** fluorantnene 6 109 27 220 71 0.65 Pyrene 81(2-ethylhexyl)phthalate 6 519 <33 1200 415 0.60 1 5.8 0.3 <120 Mr* 8eme(e)entnrecene Chrysene aenio(b)fluoranthene** 6enzo(k)fluoranthene 6 70 6 143 6 39 a 39 15 140 43 0.41 25 260 92 0.64 13 90 27 0.49 13 90 27 0.69 ben2P(a)pyren 3 33 <3.3 72 25 0.75 Oibenro<a,h)nthrecene 2 3.2 1.4 <120 2.5 o.ao 2-Neihyt nephthaltne 7 2364 300 4600 1914 j o.eo ____ L________ O.L. Detection Liait * " eeepeund detected in blenk ** w eoeluting isoaers *** * Standard deviation not possible tor one seaple. SAL 000005520 49 f A /1 TABLE 5-3 SUMMIT QP LOU OIL CONTENT WASTE CMAJtACTMlSTXCS Muabar af Renge Parsaatar $apU ----- ------------- Above D.L Naan lower Uppar 5.6. C.V. _______ oil and grease, ag/kg chloride, ag/kg Natal*, mg/kg Arsenic a 33100 5 1502 1900 170000 63720 580 4000 1443 0.37 <0.23 <4.3 *e* 1.20 0.96 Benue Berylliuo cobalt chpooiua Laad Nickel Salem ua vanediua Narcury volatile Organics,, eg/kg Carbon disulfide Chlorofora Benzene Toluene Chlorobenzene Ethylbenzene Total Xylene* Methyl ethyl ketone Seei-votetile Organic*, ag/kg Phenol Naphthalene Phenanthrene Anthracene Fluoranthene Pyrene Bis(2-ethyyIhexyl)phthalate* Ben*o<e)anthrane Chrysene Banco(b)tluoranthena** 6en*o<k)fluoranthene 6enzo<a)pyrene Bibenzo(e,h)anthracena 2-Nethyl naphthalene 6 6b 32 124 35 0.53 2 0.1S 0.096 0.22 0.06 0.36 6 1.1 0.6 2.1 0.6 0.51 5 9.5 <3.9 23.0 7.6 0.79 4 4.5 1.9 11.0 4.3 0.97 3 4.2 ^.0 5.7 1.3 0.31 4 2.7 0.7 <13 2.5 0.93 6 2.0 1.1 3.8 1.0 0.51 4 0.4 4).10 0.88 0.3 0.91 1 0.0027 <0.005 0.0027 *e* 2 0.012 0.012 <1.2 *** 4 0.239 0.016 0.660 0.300 6 0.706 0.068 2.400 0.889 1.25 'A i 0.007 <0.005 <1.2 *** 6 0.374 0.052 1.000 0.354 ; 6 2.315 0.290 5.600 2.016 | 0.87 2 0.950 <0.010 1.600 0.919 | 0.97 2 Q.26 0.11 <26 0.21 ! 0.80 4 a.b 0.76 34.0 12.7 , 1.48 d 30 3.2 81 32 ! 1.07 5 8.6 1.2 31 13 I 1.48 6 40 3.0 180 70 S 1.74 6 140 9.5 640 248 , 1.77 2 0.39 0.26 <26 o.ie ; 0.47 6 47 3.9 220 86 1 1.82 6 62 4.8 390 152 i 1.85 5 58 <33.67 260 ns ; 1.97 5 58 <0.67 260 113 1,97 4 24 <0.67 5 3.20 0.20 90 38 i 1.56 11 4.50 1 1.41 6 22 3.0 66 24 J 1.10 ----------- _______ -- --_______L -- D.L. - Detection Lioit * co^ound detected In blenk ** coeluting iloairi *n Standard deviation not poeelble for one-----r1 SAL <>00005521 48 'Zr-tf.* o.rrr -Co Ia** C\ * An % ul&I Zen?, Se-e ZM^rr-at/ySfl crfo^rcl r+- h<z&t, th EoFA LonoL Ff-uarmert Senz^H-e- "Tolutre X^cnee ^>jl benzene lAaphth^Unis Cmuktjc/.^' Model j i -&)OAid cm -6^ u^a<ct ihaF'rfaphtkaAznz. u -fnack.. %tp '-&k ~ttAXO J^nuryLs-^LfeZs Jitneys s* iftof tt h^&djt<^QdU^ -{b%lAi4^ , -t$uF td^U'mMc&n ^u>c^d`Xn&Xle- -iAat * CLjdc-Wjiyane-. r ': gt \xrrji ne iplrunyl gXE JbAzQ Jb^dilM^ Conoco Inc. Calculation Sheet SAL oj)0005522 ` 'Ju' APpErtDlX G- \ wastewater ) APS SEPPP.PTCP / OfitF -TAR \ ftNO -'NO- To/Efi OAlA J\ Title Ccr'OCC ire Calculation Sheet SAL 00d|005523 I I .00 No. j WAs-r e ga EFPLoivr AT -- 2 .A wr\GA<^/^~ s 3f,, <T y CF 7'HHT G*t- ^2A\lS -_ V.-5lx 10^ te/, / y-C - v^c : Ffr'JTOfc (coVBP&O) - O.X LS VoC/iooo S4c \f/ tV /?^r = 7? %lriy "" 3Mz r^ OAF SysrgvK - Voc. ftp-^7 PAcToP. .Ol ,-,. , X AATE -' /jOO ^/w < kO Voc. /1ooo GA_ . oi <.8oc * jj_+= x JfcS"* |OOC, sat 'OO i-6 XIA F Svg-g^- '/o A A- ^ FAeTo (2 A 471= -- SO ,035 ^ V^ Aaao s*C 7A? * <^2.q 3&S- x 2^00 ^ ^ r, C?ot-|fr/6- "TSWB- -- i/oc AP-/ 7. FfccroQ R*TE - W27.7 i.i. ug%V/C. /fV\&&L rfir.pr?r^&'/.VwO.t^X -6,\'.( ?. / "JL ,J 'V ^Ac^c cAwJF X 1.2- i_ ' ^.=70 rPy Wx + a-iiei?Mr ft`TE * (^at5 pf af>mr g<jtl<i o &LUr (Igok: SAL 0(j(000552A Title Calculation Sheet jot No ieic : t3 REVISED VOC EMISSION FACTORS FOR REFINERY WASTE WATER SY|STEHS Based on more recent information, we suggest the following emission factor. Source: "VOC Emissions From Petroleum Refinery Wastewater Systems - Background Information For Proposed Standards" Preliminary Draft July 1984. I. API Separator AP-42 emission factors: Uncontrolled Controlled 5.0 ; ib/ioJ Gal. 0.2 : ib/103 Gal. Revised Factors: Uncontrolled Covered Covered w/Vent to Vapor Collection System (420kg/M Gals.) (852 Control) 0.93 0.14 ib/103 Gal. ib/103 Gal. (972 Control) 0.03 ib/103 Gal. II. Air Flotation Systems AP-42 Emission Factor Dissolved Air Flotation (DAF) 0.01 'lb/103 Gal. Revised Factors:* Dissolved Air Flotation (DAF) Uncontrolled (15.2 kg/M Gal.) Cover v/Atmo8pheric Vent (772 Control) Cover w/Vent to Vapor Collection System (972 Control) 0.033 11j lb/103 Gal. 0.008 lb/103 Gal. 0.001 lb/103 Gal. Induced Air Flotation (IAF) Completely Uncontrolled (15.2 kg/M Gal.) Covered w/Doors Open ( 8.7 kg/M Gal.) * Covered w/Doors Closed ( 3.0 kg/M Gal.) Covered (Tight Seals) ( 2.3 kg/M Gal.) 0.033 :lb/103 Gal. 0.02 lb/103 Gal. 0.0066 lb/103 Gal. 0.005 lb/103 Gal. Covered w/Vent To Vapor Collection System ( Q.45kg/M Gal.) 0.001 !ib/103 Gal. SAL 0000oj5525 * Typical IAF Operation .! Qh o O 'O' L~ Qs/'v & -- Vy& 5 ~r< \</y% -r&sz CMC'^'CAt, /^4/\ * /Ay/'tOfvr <Tvctj //ef ^V//rt &CsZc*->* /><XYt-C*-te s' _/*> 4^ ' G ^ AXrf/%/ r//*?t e<sc l/l 3t~tys>Die*-*& (0/?/?/?G*s /e~r/&* C/s< af'Oe /j I D/C//C 0*0 T T/SYt e*S9 Ccoc) Y~T-r'f?C^c5 73 2 9?2 9 32 3^ 7 72 932 9 72 -- 012 932 9 7-2 ^3 /?< 4r / 2$ & 4- ;? y Is V C /-//?o M s )/Ot-S?7/2Co -- J O 23 ~O 37 3"7 37 3? 37 37 77 --- 77 17 SAL OOOOOp5Z6 T yv/J. Jt -Ti y j\SAAo/?*07'sq*J CstSVCc ^ j?. A MM^Ab/oAy &'?&iOOOiOQO GsX. r ^ r vr ?,4tk> fBcA/ZCwC 7 3 f aio'lq ^ S' -8 = y/l to\* K*<r/=\ t^ "&o/*/ - & 8> ~\po Z ~7Z-<Zce A j ,, $2>4**n c. c a! *= 7.3i * 10 uts/vi SCm.Cm us/ve inje.FFicutSNj-r 3<.<, U S/vR -- ,0 C^S*4 ffih4Q>s9) lq/vc i^i^x do ruu c mt 7 3 X l. rj/v ft * .2^* - \OS.7 cq/v* volat/2c^ I 7 37- ue/ v/t X . | O - 73J c ff/^ ~7tJ'rC 3c**z c~se C**`0.) 9`2`X c*/v* .2y 5 /?r*9 VOt-^THc# '~7oCiSC*se C*^,0.) 9, 3/ * /<? V/* - LO/y< = J /O {90*7* fir*-****) MAj 3 66 <-a/ysi. _ % t. ?3 = <8 4, <2 i-ff/T* l/^T/zrfo XYcc</ 5 (*s.o ) 73 7 ut/** x, av " /?$",? c, fj /y/7 1/CK-sy-r/Z eo .'ade By Checked By Cate Page of Title Conoco Inc. Calculation Sheet .. . SAL ^00005527 Job No Field State ! T ^&V4P. CCcCvt+~*rr^} C?f-//}r# p-S ) ) 3 C3 ut*>Q lt+s<2 -- /^<- (~ P&ors/itjc v V^<-/^ ~n z cr-o P&t&x. to Y^PoPVC C*->G/(5'r+/YiC`*+ - AS0-T A/V/>t V-jcc^ <3> Peso ci* -- C <5 o/v -oj- ; Aj oc/Ga^ot ty yt^T/j TtO B I PC ^ '''"d ~ c&*/f /0/?O/?S\) C S''~tfc' 0*4 V t P } CD \y oosy~r /z<s J^e PUt'-Au -" (T /0C7 T 7^ /S7- JSi^T O''TCC~r&`0 4*0 C. *36. * .18 .or - 2?8.Z L,f?/'+* {/OCS-r>Zee> AjAPfiTtWlC^e Cas.O^ ~irCr ' ^2 - c; CD \S oo/y CA-niQ*J Tc ~r/?A Ca/C C? /? C<s*O.D 9,3! *. to it X .9? - *?6V<-ff/y|< l/06^'>vn? lJf?Q^4 iu t^4 ~7o 7c - ./</** <v/t-- D/Wtftu^ : .09 8 M&/L- . /V- ,G?fl ?_ .GVfc_ M <- /OO0*** f cc? 4SXC*&9 C e.^^c c'jx-u-O I 06> <3 ! ,, j?.4 < ioc&*o -7<SV-2 />* 0/>^ x 3cro/> v* " uo/^t 30 = tfj/v* O 15 ^0C^T/tCO :ade 3y Chacked By Date Page of Conoco Inc Calculation Sheet Title SAL 000005528 Job No. Field State V/,V/. ~TGC*-n^ C-- -r Ccp^t.) /-A^cr C'/jsyrtcrs It / DiC/-J<,o#a"r//rcc!-~<r (".a,) c 3C ,<* # . .oT - 5 54. 3 t-ff/Y*. U <-sy -r / * <?<* jTtr/?c-sc (.".o!) 3C.c to a .53 - Q4-. 2 t-r?/** C> jf~ C^. 0.3 -- ajo~t O C y CO , /0 PPQ A 5^va^ * a * Dc-rcc -tso^ \ Lvimr-r. U /><~r or DcT&c.~rto** C//->/ t w<h ^ ^ ^ t* /~t co flc/i <?PA /?<rccf/Ue Cacc, *Doc.. ade By Checked By Date Page of Conoco Inc. Calculation Sheet Title SAL 000005529 Job No { Field State The data for Table A-2 were extracted from ''Report to Congress on the i Discharge of Hazardous Waste to Publicly Owned Treatment Works",, U.S. Envi ronmental Protection Agency, EPA/530-SW-86-004, 1986. The following notes apply to this table: o The data from this table apply only to secondary biological waste- water treatment plants receiving low concentrations (si 500 ppb) of the compounds listed. A number of design and operational factors will affect the fate of these compounds in any given treatment plant. These numbers are useful only as rough approximations of pollutant fate. All percentages are based on influent loading. The or' ginal reference provided removals for volatilization and sludge partitioning as a percentage of overall removal. This data was translated to removals based on influent loading by assuming that alii material not volatilized, transferred to sludge, or passed through untreated was biodegraded. e (Percent volatilized to air) + (percent partitioned to isludge) + (percent biodegraded) + (100 - overall percent removal)! = 100. Percent biodegraded was determined by difference in thej preceding equation. The percentage which is discharged to receiving waters equals 100 minus the "overall percent removal" (percent discharged! to receiving wastes 100 - overall percent removal). 1 o (Percent volatilized to air) + (percent partitioned to (sludge) + (percent biodegrded) + (percent discharged to receiving waters) * 100. "Acclimated" represents those processes which receive a;relatively steady amount of the pollutant in question, such that bjodegradtion rates stabilize. "Unacclimated, Median and Low" refer to processes which receive unsteady or "slug" loadings of the pollutant in question. A-12 SAL 00t>|005530 TABLE a-2. PATE OF HAZARDOUS A. R TOXIC POLLUTANTS AT LOW CONCENTRATIONS IN SECONDARY, BIOLOGICAL WASTEWATER TREATMENT PLANTS POLLUTANT DVERAL1 >ERCEN 1EMOVA Ipercen IT VOLATILIZI D TO AIR PERCENT PARTITIONED TO SLUDGE ACCLIMATED JNACCt 1MATEC ACCLIMATEd UNACCL MATED ACCLIMATED UNACCLIMATED MEDIAtv LOW MEDIAN LOW MEDIAN LOW % %% % %% % %% Percent BidbEGRADED l ACCLIMATED JNACCLIMATED MEDIAN LOW % %% 2.4-D 90 60 50 0 0 0 7 5 4 ACENAPHTHYLENE 95 90 90 19 54 54 9 86 ACETALDEHYDE 95 95 95 0 5 S 10 10 10 ACETONE 95 50 30 0 3 2 10 5 3 ACROLEIN 95 95 95 0 5 S 10 10 10 ACRYLAMIDE 90 62 50 0 0 0 9 65 ACRYLIC ACID 90 85 80 0 0 0 9 9 8 ACRYLONITRILE 90 75 70 0 4 4 9 8 7 ALDRIN 90 90 90 0 0 0 33 33 33 ANILINE 95 85 80 0 0 0 10 9 8 ANTHRACENE 95 90 90 0 0 0 52 50 SO ANTIMONY 60 60 60 0 0 0 60 60 60 A -13 ARSENIC 50 50 50 0 00 50 50 50 BARIUM 90 90 90 0 0 0 90 90 90 BENZAL CHLORIDE 90 u)" >v'$5 50 0 17 15 7 44 BENZENE rsT)' 90 90 24 72 72 2 22 BE NZOTR (CHLORIDE 90 45 40 18 14 12 7 4 3 BENZYL CHLORIDE 90 90 90 23 45 45 7 77 BIS-2-CHLOROETHYL ETHER 90 SO 30 0 3 2 9 5 3 BIS-2-ETHYLHEXYL PHTHALATE 90 90 90 0 00 66 66 66 BROMOMETHANE 95 95 95 66 90 90 0 00 BUTYL BENZYL PHTHALATE 95 90 90 0 0 0 43 41 41 (A CADMIUM 27 27 27 0 0 0 27 27 27 > CAPTAN 90 SO 30 0 0 0 7 4 2 CARBON DISULFIDE 95 85 60 76 77 72 1 11 o o CARBON TETRACHLORIDE 90 85 60 72 77 72 12 98 o CHI ORDAM? 90 90 90 9 0 33 3.1 . 33 '~o o CHLOROBENZENE 90 90 90 27 45 45 14 14 14 ut i*n CHLOROBENZILATE 90 60 50 9 6 5 7 5 4 uj CHLOROETHANE 95 90 90 76 81 81 1 11 CHLOROFORM 90 60 80 63 72 72 2 22 CHLOROMETHANE 95 90 90 86 66 86 1 11 (continued) 83 55 46 67 28 29 85 81 81 85 43 26 85 St 81 B1 56 45 81 77 72 81 64 60 57 57 57 86 77 72 43 41 41 0 00 0 00 0 00 83 34 31 69 1 6 16 65 28 25 60 30 36 81 43 26 24 24 24 10 5 5 52 50 50 0 00 83 46 28 16 a 7 6 00 48 . .40-- ....AB.-- 50 32 32 74 49 41 18 8 8 25 6 6 9 44 TABLE A-2 (continued) POLLUTANT DVERALl 3ERCENf REMOVAL IPERCEN r VOLATH IZ D TO AIR ACCLIMATED JNACCl IMATEC ACCLIMATED UNACCt MATED MEDM LOW MEDIAN LOW % %% % % % PERCENT PARTITIONED TOSLUOGE ------------ 1 ACCLIMATED UNACCUMATED MEDIAN LOW % %% I) Percent BKlOEGRAOED 1 ACCLIMATED JNACCLIMATED MEDIAA LCW % %% 2-CHLOROPHENOL CHROMIUM CRESOLS CUMENE CYANIDE CYCLOHEXANE DI-NBUTYL PHTHALATE DI-N-OCTYL PHTHALATE OlBROMOMETHANE 1 ,2-DICHLOROBENZENE 1.3-DICHLOROBENZENE 1.4-DICHLOROBEN2ENE t ,2-OlCHLOROETHANE 1.1-OICHLOROETHYLENE 2.4-DICHLOROPHENOL 1.2-DICHLOROPROPANE DICHLORVOS DCOFCL DIETHYL PHTHALATE 3.3-DIMETHOXY BENZIDINE 2.4-DlMETHYL PHENOL DIMETHYL PHTHALATE 2.4-DINITROPHENOL 1.4-DIOXANE EPICHIOROHYORIN ETHYLBENZENE ETHYLENE OXIDE ETHYLENE THIOUREA FORMALDEHYDE HEXACHLORO-1.3-BUTADIENE HEXACHLOROETHANE HYDRAZINE (continued) 95 70 95 95 60 95 90 90 85 90 90 90 90 95 95 90 90 90 90 60 95 95 90 90 07 95 90 85 85 95 95 95 65 60 0 0 0 8 55 87 60 55 70 70 0 0 0 70 70 70 0 00 50 40 0 0 0 0 43 . 87 46 37 95 95 36 57 57 4 44 53 34 34 60 60 0 33 57 57 57 3 00 95 95 10 86 86 4 44 82 6 6 90 90 0 0 0 20 20 20 70 70 70 90 90 0 0 0 7 7 7 83 63 63 80 80 43 64 64 13 12 12 30 4 4 87 65 45 78 77 32 99 14 0 0 87 85 45 78 77 3 33 42 6 6 87 85 45 78 77 23 99 23 0 0 SO 30 45 45 27 5 32 41 3 2 90 90 76 81 81 0 00 \19j1 99 55 so 0 0 0 8 4 4 8 7 51 46 70 70 45 63 63 0 00 45 7 7 50 30 0 0 0 9 5 3 81 45 27 90 90 45 45 45 8 88 37 37 37 75 70 0 0 0 1 1 B9 74 69 30 20 0 0 0 8 32 72 27 18 85 80 0 0 0 8 76 67 78 74 65 60 0 0 0 0 0 0 95 65 60 75 70 0 0 0 9 6 7 81 66 63 50 40 0 0 0 9 5 4 81 45 36 59 25 0 0 0 9 63 78 53 23 90 90 24 72 72 6 55 66 13 13 ____ -0_ --3- - -2- .......... 9--------- - -5 - _----- - - 81...... 43 "34 " 67 60 0 0 0 9 7 6 77 60 54 86 80 0 4 4 9 98 76 72 68 90 90 0 5 5 9 8g 86 77 77 90 90 0 5 5 9 8 8 06 77 77 85 60 0 4 4 10 9 8 85 72 68 SAL 000005532 00000553 i t-- cn tn r v>i TABLE A-2 (continued) POLLUTANT 3VERAL 'ERCEN' 1EMOVA iPERCENlT VOLATILIZ tD TO AIR ACCLIMATED JNACC1 IMATEC ACCLIMATED UNACCL MATED MEDIAN LCW MEDIAN LOW % %% % % % PERCENT PARTITIONED TO SLUDGE 1 ACCLIMATED UNACCLIMATED MEDIAN LOW % %% -------------------- 1-----------5----------- fERCENT BIOOEGRADEO 1 ACCLIMATED JNACCLIMATED MEDIAN LCW % %% LEAD MALEIC HYDRA2IDE MERCURY METHANOL METHOXYCHLOR METHYL ETHYL KETONE METHYL ISOBUTYL KETONE METHYLENE CHLORIDE N BUTYL ALCOHOL N-NITROSODIMETHYL AMINE NAPHTHALENE NICKEL NITROBENZENE 2-NITROPROPANE P-fiENZOOUINONE PARATH ION PCS PENTACHLOROPHENOL PHENOL PHENYLENE DIAMINE PHOSGENE PHTHAL1C ANHYDRIDE PYRIDINE SELENIUM SILVER STYRENE 1.1? 2-TFTRACHl OROETHANE TETRACHLOROETHYLENE THIOUREA TOLUENE TOLUENE DIAMINE TOXAPHENE (continued) 70 90 SO 100 90 95 90 95 95 90 95 35 90 95 95 0 92 95 95 90 100 90 15 50 90 90 90 ... 90 90 90 90 95 70 75 50 95 90 50 50 87 90 75 75 35 25 95 50 55 92 25 85 75 100 90 15 SO 90 90 25 85 75 90 75 90 70 70 50 95 90 30 30 85 90 70 70 35 20 95 40 40 92 20 80 70 100 90 10 so 90 90 20 SO 70 90 70 90 00 0 0 1 54 0 0* 38 0 3 5 54 3 0 52 00 00 04 00 00 86 90 00 00 99 00 00 00 15 00 0 00 00 23 72 ____ as.......... --15-- 45 68 00 23 72 00 57 72 0 0 3 5 54 2 0 51 0 0 4 0 0 90 0 0 9 0 0 0 s 0 1 0 0 72 42-- 64 0 72 0 72 70 9 48 10 6 10 9 (3 10 9 27 35 9 1 8 0 22 17 14 9` 10 9 2 50 90 14 --4-- 3 9 25 9 4 70 70 87 48 48 10 10 88 53 53 12 12 99 87 21 20 35 35 32 11 43 43 22 22 54 13 12 87 10 10 99 21 50 50 90 90 14 14 -4--- -----4-----32 67 18 18 87 44 - 00 81 68 20 90 81 28 28 65 43 81 45 44 23 86 81 61 68 68 50 00 81 23 g4 87 46 0 51 61 61 70 21 81 72 81 68 90 85 61 81 13 13 00 00 54 5 59-------- ___9-- 42 14 81 68 42 0 81 68 34 14 0 63 0 81 28 26 27 22 81 63 47 0 10 4 37 37 61 16 66 63 85 81 9 0 0 5 - -7- -- 14 63 0 63 14 'i'AlJUi V .Samp 1` KKF-87 Blank KLE-S8 Pump Blank WATER ANALYSIS LAKE CHARLES REFINERY ____________ , ________ ..A*. A1 __As__ <.0i <.03 <.15 <.15 <.002 <.002 Ba <-005 < .005 ssol veil Metal Concentratl oi\ (mg/1.) Be Ca Cd Or Cu <-01 <-01 <-050 <.050 <-015 <015 <.030 <.030 <.015 <.015 Fe <.030 v.0 30 <.013; <.10 <.0I 1 ; 10 REF-89 Composite REF-90 Effluent (3/4/79) kkf-i 01 Effluent (3/5/79) < - 01 _ <.03 <.03 1.3 1.1 1.3 _ <.002. <.002 <.002 -*23 . 22 .23 <,oi <.01 <01 49- <.015 49 <.015 49 <.03 5 . ttys .087 .16 < .015 <.015 <.015 - <.on.... .48 <.013 . 77 <.013 16 16 15 REF-92 Influent (3/5/79) REF-93 Influent (3/5/79) <.03 <.15 <.002 . 17 <.01 <.03 <.15 <. 002 .17 <.01 24 <.015 <.030 < .015 5.1 24 <.015 <.030 <. 0J 5 5.4 <.013 6.3 '<.013, 6.3 REF-87 Blank KEF-88 Pump Blank Mn <.010 <.010 Mo <.050 <.050 Na <.10 <.10 Ni <.075 <.075 Pb <-25 <.25 Sb <.2 <.2 KEF-89 Compos!te REF-90 Effluent (3/4/79) REF-10J Effluent (3/5/79) .30 <.050 .29 <.050 . 30 <050 350 <.075 <.25 340 <-075 <25 340 <.075 <.25 <.2 <.2 .2 REF-92 Influent (3/5/79) REF-93 Influent (3/5/79) .30 <.050 . 31 <.050 1) Hg, As, Se (HHS-1 Analyses) 2) Ag, Be, Sb (Atomic Absorption Analyses) 3) All Others (ICAP Analyses) 38 <.075 <.25 39 <.075 <.25 <.2 <.2 Se <.002 <.002 Sn <.10 <.10 Tl <.50 <.50 V <.025 < .025 Zn <.025 <.025 .002 <.002 <.002 <.10 <.10 <.10 <.50 <.50 <.50 <.025 < .025 <. 02 5 <.025 <.025 <.025 <.002 <.002 <10 <.10 <.50 <.50 < .02 5 <.025 <.02 5 <.025 <4m m m o o o o o < to .V:"'7 co ro ro '-o >> ro 00 Cfi H-* * * o w KM it ft ft Cnsr* * on w CT " cn rov 1 ro > ro p rr >O > 73 3 3 b "> o ro 3 Cu cn ro v> cconr ro cn NTO ft> t Cfl u 72 E Xro t; r so S3 CO ro rH l-- 3ro 3ro ro (-- CC ro ro 33 rr rr y--s CO Co Ln Ln *o >o SO O w' V o1 3 1 co CO > 3 11 CO 3* b ro 1 f L- 1 cn 1 A A ro cn 'w' 11 oo Ln Ln 11 O o | 11 1 1 LO LO 11 *0 LO i i 1 AA i oC 11 ~o -o Ln LA ) 1 1 AA 11 ro hO Ln Ln 1 11 1 1 AA 1 K3 ro r7o2 rXo PC ro i` f i' r- S3 co Oo3 H~ ro ro ro ro ro ro c= "ri ro ro ro C c c ro cn ro k_. 3 rr rr rr ft ^N Co LO , JA Ln Vj -o SO v>_3^ w' CO LO co ro c O A A A ooo Ln LA LA OOo LO LO CO 3- r-- ro Owo AAA o -o O -o o-0 Ln LA LA AA , NJ ro ro Ln Ln Ln AAA < AO ro ro AA 3C OC ro ro AA l--- H3o AA LA Ln OO A/ 3o ro ro Ln AA o ro rvo O" g 33O 3OO S3 ro so AAA I--* H- --i oo3 A / A Ln Ln LA 3 3O AA c o Q. ro ro \_n Ln Ln -- o rp Co w 5C rr Xrroo i CD Cc CO o -- -- X t-- 3 7T u-t 0; sO SO ^ ro ro 5 h-* 3rroo C c cro "3 t; " " II I H O CO O sC w *-n rrrroooo roc o J uu Cro o cn o3 0Ic CO "0 s C*--r a 3 7T C5 V. Ln Ln "J --j so sO "J ^ SO sw AA > Oo i--* Ho3 AA oO Ln Cn CO . ro SO 'vj A ,A 3o -o Ln LA AA ro ho Ln Ln AA CO Uu A On Ln AA * 3O O3 ro ro 1--' cc oo A oU-l o 1-- A /. A COO LO lo lo AA A ooo 3o3 ro ro ro ro ro to C-* ro CO AAA U-l oro o AA oo lo lo "1 AA ro L !> Ln Ln . 33 3 Ln O' AA o 3o S/i A A, OC -- I AA .. ro ro V A A CO 3O ro ro Ito*o*c I AA 3 .1 0 km 3 AA '-A 'on 3O AA 33 ro ro il< sA SOI . 3C O- LO 3 : co ro ro O' JN AA oro O cn CA AA 33 LO LO OO rion .eO' O' AA A oro U ro oro Ln Ln soi ro ro ro ro ro ro ro 3 , fp 1^ i 1?r>. :p AA ,c , r* 3ro O i-- i c LA Ln ro lro>. AA 13 X 1* 3O LO CO * "T 3o AA 33 -- cn LA AA O 3 oro ro S-n Ln co 3O CO ro ro s/l ^ '" O' .O' LA Ln CA CO j , ro LA O' o' ro 3 O' cs O' Ln SAL 000005535 CC i i i i i a m m m ' ui s'.'i'iH vnr) i i w TABLE B' Ref: TSR 242-79-350-2 WATER ANALYSIS LAKE CHARLES REFINERY (REF) SUMMARY GC/MS DATA " --__SA1IPLE NO. REF- 82-92 COMPONENT ----- -------------Influent Butyl-capped nonionic di-2-Ethvlhexylphthalate 1 opb Possible amino acid Tridecane Tetradecane Branched paraffin Pentadecane Diethvlphthalate Hexadecane Heptadecane Pristane Biphenylcarbaldehyde Octadecane Dibutylphthalate Nonodecane Eicosane Fluoranthene Heneicosane Trimethylphenanthrene Docosane Methyloyrene Terphenyl Tricosane Tetracosane Chrysene Pentacosane Dioctylphthalate Methylbenzanthracene Hexacosane Heptacosane Benzopyrene Benzo fluoranthrene Carbon dioxide Branched Co olefin Hexane Phenol 82-89-1 Effluent 1306 PPb 25 pob 10 ppb 21 PPb 41 opb 24 ppb 7 ppb 25 ppb 24 ppb 25 opb 10 ppb 21 ppb 4 ppb 23 ppb 19 opb 1 ppb 14 ppb 12 ppb 14 ppb 10 ppb 26 ppb 12 ppb 11 ppb 16 ppb 14 ppb 4 ppb 18 ppb 10 ppb 8 ppb 7 ppb 12 ppb 200 ppb 10 ppb 210 ppb 10 -P-E-b SAL 000005536 WATER ANALYSIS LAKE CHARLES REFINERY (REF) CC/HS OATA - II___ J TADI KIT ------------ SAMPLE NO. REF- 82-88-BN ' --------_ Blank Water COMPONENT---------------- -----------Base Neutrals Butyl-capped nonlonlc 300 ppb Isooccanol Isodecanol di-2-Echy lheicy Lphthalate 30 ppb 10 ppb Possible amino acid Trldecane Tetradecane Branched paraffin Pencadecane Olethylphthalate Hexadecane Heptadecaae Prlstaae Biphenylcarbaldehyde Tctadecane Jlbutylphthalate Nonodecane Eicosane F' Athene E -sane Ti_ whylphenaathrae Docosane Hethylpyrene Terphenyl Trlcosane Tetracosane Chrysene Peacacosane Oioctylphthalate Hathylbenxanthracene Hexacosane Heptacosane Bensopyrene Beneofluoranthrene Carbon dioxide Breached C$ olefin Hexane Phaol 82-B8-AC Blank Water Acid Fraction Nothing Significant 4- 82-92-BN Influent Base Neutrals Nothing Significant 82-92-AC Influent Acid Fraction 82-69-l-BN Effluent Base Neutrals 1506 ppb 82-t89-l-AC Effluent Acid Fraction l{)0 ppb 82-9S-VOA Volatile Organic Analysis l ppb 25 ppb 10 ppb 21 ppb 41 ppb 24 ppb 7 ppb 25 ppb 24 ppb 25 ppb 10 ppb 21 ppb 4 ppb 23 ppb 19 ppb 1 ppb 14 ppb 12 ppb 14 ppb 10 ppb 26 ppb 12 ppb 11 ppb 16 ppb 14 ppb 4 ppb 18 ppb 10 ppb 8 ppb 7 ppb 12 ppb 200 ppb 10 ppb 210 ppb 10 ppb SM_ 000005537 i-.lit <ilbilii>ii O T>>c- i-- /3> /v rz Msx&r -- /PX. 5efr***i*r-^4 /DA f= - X /\ tz- 0 <.<jZcZ<sg CZ^CCO //c Y / Oc csc*s c _ 77/TC &J2 C+SC /)} yrcc^s n O X^tr^e* > y Yc C*-* (Ct^t c --' d Ccs^tc<~<S '"TY/?C*J C AsstSt/rf/rf CC*scr -; - 3J <i Ia 52 H Z 2 ' 0.2 SAL 0000(55539 /X PX 5 cf P/* tZ A rz I--Akg C /-/A- 7^0 t^PM - Pc?. f3 /*a INI O' f3w/ ( AS JVMC O ffuofi GO /M f^O Sf~r* 0a/ V^f^or* Covc-sTiro ~ & $ ur/0c(Ut us.tS} 7SO i j. f-4l kJ Hin ^ ^ >-> . Jtfrojv ^ we o?y Y* Q, g t-g ,, --JLjda:; * vop <. 2000 <-& " 39.42tPY 'VOt Voc y Wt, % * VaPon Co0ACr~rro--> As9c ~ro4 * Soooo4 * (-Q/vn - S9. V2 * ,jc /e>0 v AC 3V X JOoU - 12S-.2 l.b/'tkl /*C YCt QX/FX/x /V ^ 39,V2 < _.9_4 * ay -* 2000 232 t.O/'fn ~Tocve*'C * 59.V2 * ,7_9 x 0.V /4>0 av < AOOO - ?3 L.o/'r*. T*/rc g&vtc^e = 3 9. yz * ,j?5 * U /oO j.v X Xooo - 1 P l 1? /r* /T?- Yce<> p- X VC c<sc * 39. vi * . V7 < /oo *19 J.Y x Zovo t - 39 / _t_22 X , /* v a Xoov r *^/ 4 ff/V* I t? eff/y^ O'XYtCsscT - 3?.y2 X ,29 /0 0 < X<t<!0 j.v 1 i3 <-Q/YX- CtssntStV' aae 8y Checked By Date Page of ' 5?.V? x ^7 * .ecu f O0 jy x 2.000 = J?.v2 x -ii?/ 00 , A . e?w ~y^? Conoco Inc. Calculation Sheet X XfOO Title ~ $\d/co/Y* /, 1 L. Q/y* Job No Field State SAL 000005540 1-- A>!< < CJ/-/XX rz<\ cr * l'-)A'Z/moov V/a$T 3aS'Kt -- J^MOR P<T/2 OR&ShMi C C W^--5 Ti='5 y3, tfc^-rce^^' W^srcs ^^'jv-9/rA/?Hcr<? c? l t'-J f* & o'^/C /i/cfw y* T/V / i asQ Rcces>*c -TO 3tf R<S/^ ot/co ~r*sas?a 0 .lade By Chacned By Date Page of Title Conoco Inc. Calculation Sheet sM_ 000009541 Job No Field State \jMewe Oo^e^c ^ LcM>. 444^*3 Mfvt>f rn-lAueMC A43> bI^ta} <S~Tftft>A QcM'rfrsmcAl, \\jr% A4Kv>V\Tf^ej4tr 3cr v-ujcl- " (xerr5c>) M a 3>cs*r^ CVot> CoMbC^VCTHT KtRe&ew^ Vcc (rASbuMe 3 3 I 3 4y 4I 4/ 4/ (_ Qfojpe CLkYoS rpoAJ Ac, 1^ta| Mo~nr ' Osc ~rrHs Fcs-. "^Access w7ft 3^ewe Ci C [cojeM^T c>. 1(= 0.3^ O>..Jf-- -fcr Cry o.ss ^'A/LCMC T>- 4V UfHe > 44LjEM^: ^ CoKvoaer ^ jA.eo 4o- CoMexie 0.^7 (b.2-1 0,2.^ - ** O. /^ Vxcctm t St^ new e 3j T^rtevYc 0.0 1 * 0.05 + K\cjt 3csre> MuG-u6-i(ite c/ $5^ 000 S^' ^-~THesc 4*a.^ FR>aK. a C&obe Mv^to&c 3ot tSc CtoSF, XJo )3\TA OM. ^AFHtACcmc 4 3(>r+ewvL, ^omc SgMcta<a.i6- LfVrro JAo'S-r C-H&n TH^c vO iTf\ TSL , +- Ffio/^x ~p-- vUfsvte: t>>i'0t5A /^?X ^oT> O/L. V/> Po IZ O52c5 $ 5u (2.<S 5 A B ajzeZMtL I GU(-><5*/G ELt/s/y*- SeA/ze-^# D vc d-o /~/e~x ss aj <5 5"7"V/3ca/<s D t-J h~*A G PsSCJ/^C CiS/^JtZASG Ay/AP/vrA'/Ac l3j_EA'.e_*> Y- <s- .02 i2uD6 i<^ tS /^O D/e j"c?.c /. 5 o. 4 o. / s I . <2* o. I 3 O. 0.36 7 0 -04 j 3 O. 0333 O, coo 4 5 0-_0.L33 3.: 4* <3- CO. CLJ J O. O O S I . > . jde By ___ Checked By Date............. Page a* Conoco Inc. Calculation Sheet Title SAL 00<t0055 Job No. . . j j | __ ''late fD A Osi r -- A/*/"-# , O I <-*r t O 3 t***- 7c es Geo x ^.-4g < ** /6> 200 0 \/OC~ > V/r. 7* d(Zuoti x \/. P` ca&e* c-r/9+s * 2oao (?/^ 0t/Cx4* G 13,2 x .003 c 1, S xOvvO 3,,4* - 3H9 3J-/r* 13. Cl x ,oo? * _LJ> X 2 tftfc? 3<* - J?,J cms/** 7*/rC 6c*jZ,c+'* /J.2_ X x it OovG = Y.O, i-fir/w 7o<- tsc*j c? XYCC^cS II 2- * ,<^7 x --l1 ZV * 2Oo0 - 0sAit il.2^ x ,40 J x f/ ^ 7.V X ^>6 0 - V, V t-ff/r* 17.1. < *0tf7 x .0947 x afl'O 7.*/ = 2,3 t-asjvt AJs4f//7/S*<i <r~- ^ C t^/>? C*s&6* 'g<*Co C<ss*&*fC iaae By Checked By Date Page of I 3^2<__ je^-,.047 x ,009r A %O00 ?. y ~ 0> i t-t/fy*. /_?.*, < ^*7 i - /.v ^er/y^ 17. z * .coJ > ,07*rJ x 2 #0t> 7^ Conoco Inc. Calculation Sheet Title * SAL 000005544 Job No Field State JZA f= - S.O 3,Pt+* Bo x___l__ ^ OS.y 3 2 v# (2yC<-OA/cx^e &74/YC 6Cut c^ /S Co*&J (* y.^fcc^a s ^-rv&c-jc l~/yxL tZ a* i 0 3 0 4L So 7* v r* ay ,, jir *` .07? ,, 3 . 7c? Towc / Q* 2ooo V-0 eoxscc t/ o-j x 2000 = avV* t * J>r~ K 2 ooo -- i S* 3 i <- os/yn. IV * JJ_ X 2-000 z 1 &' 3 A0f / 'nt I. y *. , f<$~ X 2.000 S. v i, 3 jt-az/y/i ' / ,V s. y X Xooo X ,) 9 X 2 vo 2* x ,09i? X a ooo ?. Y -- H1 if 9 t-Cf/rx 1,0 t-4s/y/L v e? lade 8y Cneckea By Date Page of * /oovr X 2 000 /. V Q. 1 <,,$//**. * ,o6' f X 2*0 0 tV T Q.U ^Or/y*. - , D39? X 2-009 lY Conoco Inc. Calculation Sheet Title - o.v SA|L 000005545 Job No. Field State Goqu Lf\* oAl-l Q^><r= 9 637.-7 f-Atb&L. -4983 7.7 x. I,2,l>_ g^.^O -jo^f KfiiiL 'Vie, a *9'*} `108 -fry --'U/ cjoinc. *6 *. = 41. T * . ' cl le ^ -43-rp/ "7b f j ^ - -- 4*7. ? > . rcn* = -4^ f '-j 1 v. = 7 -* .6017 - . 027 7 y ~V- tf ; ^ . -- ^.<7 x .H - ?9. 9 / Ool^ - A 21 r-- u v-'t ^ .? 1, r. ' ,, ,bcv\. ' 08.7 ^ '7 r* c r j-; ' 4??.? * ,05| F-:: ,. . *""*1 r ' i ' > 1. ? 1 %, ' ^ ^ ^ ' -' n 4.'_ ^ 453 / ,0O^f = -&3U .bob - ' * ' 1_ NT. I -- 4nr: ' ,00^5 'yA <*' :f;;L r a*. 1 - - .0/5 AIP DATA / t-as/**. *fto\ **fo\ /?Y 2 ?o K.Z mi\ 1 fox ?z \ c. 30 SAL;000005546 Jade By Checked By Date Page of Conoco Inc. Calculation Sheet Title Job No. Field State PtPPENOlX f/ nfyv&VToK'y ST&/?* T*V>C /oc. Made By Checkea By Date Page of Title - Conoco Inc. Calculation Sheet SAL 000005547 Job No. | Field State > &>oF tf&J PftOWJCT NAK TAW MO. CAP. ABBLS HAN. FT TIRN OLCRS PER TEAR VAPOR PRESS VAPOR PSIA MX. NT. VAPOR SPACE FT PAIN! FACTOR BREATHING M0RKING SIZE TURNOVER LOSS LOSS FACTOR FACTOR TPY TPY TOTAL LOSS TPY REFOBCA FEED REFORWI FEED REFORNER FEED CRACKED DI5T WBt visMt* J6-2 DISTILLATE >- l 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE t 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE I 2 DISTILLATE 1 2 DISTILLATE 1 2 DISTILLATE J 2 DISTILLATE OP FDSTK OP FDSTK LT. FEEDSTOCK IT. FEEDSTOCK WY. FEEDSTOCK HVY. FEEDSTOCK GAS OIL GAS OIL GAS OIL GAS OIL GAS OIL SLURRY SLIPPY SLURRY SLURRY SURRY COKER FEED COKER FEED COKER FEED COKER FEED COKER FEED COKER FEED COKER FEED COKER FEED -eeuRFEtfr COKER GAS OIL 6 FUEL OIL 1 6 FUEL OIL 1 6 FUEL OIL 1 6 FUEL OIL 1 6 FUEL OIL 1 6 FUEL OIL 1 6 FUEL OIL DUST OIL DOCK EDC DOCK FICtHX DOCK ALCOHOL DOCK LAB OLEFIN ICXAMX 193 80.0 69 55.9 69 55.0 21 25.4 94 2.5 95 2.5 35 90.9 81- 120.0 82 150.4 291 23.9 202 15.4 343 80.4 351 80.0 378 80.0 74 151.0 75 158.0 76 150.9 378 80.0 22 * 25.0 344 88.0 345 150.0 342 80.0 340 80.0 297 80.0 338 80.0 36 80.0 37 88.0 S3 128.0 100 150.0 191 150.0 71 25.0 72 25.0 73 25.0 299 80.0 398 80.0 67 55.0 91 80.0 20 25.0 66 55.0 90 80.0 400 25.0 380] 200.0 3802 200.0 -200.0 60 30.0 84 >50.8 89 150.0 355 15.0 354 15.0 398 90.0 3803 200.0 3894 NT-1 200.0 8.6 415 50.0 416 55.0 672 IQ.O 919 25.4 4300 0.3 4301 0.1 120.0 100.0 100.0 67.0 25.0 25.0 124.0 134.9 158,9 67.8 69.0 129.9 121.9 120.0 158.9 158.0 150.0 120.0 67.0 120.9 150.9 I20J 120.0 117.0 117.0 120.9 128.4 134.9 158.0 150.0 67.0 67.0 67.9 117.0 117.0 100.0 120.0 67.0 100.0 120.0 78.0 190.0 190.9 mr 67.9 150.9 150.0 58.0 58.0 120.0 190.0 190.0 (5.4 100.0 110.0 43.0 60.0 11.0 9.9 1,5 4.1 4.1 5.0 10.3 10.3 14.3 28.6 19.3 467.8 467.8 3.8 3.8 3.8 29.8 29.8 29.8 3.8 108.3 19.9 0.9 4.9 4.9 4.9 8.5 26.6 28.6 8.5 28.6 28.6 5.0 5.0 4.7 5.4 5.0 13.6 1.9 13.6 6.3 13.6 15.5 21.4 21,4 T.8 15.5 8.5 1.8 3.8 3.8 8.5 21.4 21.4 0.0 0.0 0.1 0.2 0.1 0.0 0.0 1.3900 68.0 1.3000 68.0 1.3000 68.0 0.9150 68.4 J-0150 130.0 0.0158 130.0 0.9150 130.0 0.0128 130.0 0.1120 136.0 0.9120 130.0 0.0120 130.0 0.0126 130.0 0.0120 130.0 0.9120 139.9 1.1129 139.9 0.1120 139.9 9.9120 139.0 9.8129 130.9 9.9129 139.0 9.1129 139.9 0.0120 130.0 9.0120 130.0 0.0124 130.0 0.0120 130.0 0.0120 130.0 0.0091 190.0 0.1801 199.0 0.0091 190.9 0.0991 190.8 0.0091 199.0 0.0001 190.0 0.0091 190.0 0.9001 190.9 0.0901 199.0 0.0901 190.9 9.0991 190.0 0.0101 190.0 9.9891 190.8 o.mi 190.9 9.0081 196.0 9.9001 190.0 9.9091 190.0 0.9001 190.0 9.HTT "lW.ff 9.9991 190.0 0.4001 190.0 0.0001 190.0 0.0001 190.0 9.0091 190.0 0.0091 190.0 8.9001 190.0 0.9001 190.0 0.0002 190.0 1.8375 96.6 0.0140 145.0 0.0149 145.0 0.0402 190.9 0.1500 100.0 0.1000 109.9 19.9 19.7 19.7 19.9 14.3 14.3 19.9 23.9 23.8 19.9 14.9 19.9 19.9 19.9 23.8 23.8 23.8 19.9 19.9 19.9 23.8 19.9 19.9 20.9 20.9 19.9 19.9 23.9 23.8 23.8 19.9 19.9 19.9 29.9 29.9 19.7 19.9 19.9 19.7 19.9 14.7 19.8 19.8 TO 23.9 23.8 23.0 15.9 15.9 22.3 19.8 19.8 8.0 17.0 16.0 20.0 24.0 7.5 5.0 1.00 1.09 1.90 1.99 1.90 1.8* 1.00 1.91 1.09 1.99 1.09 1.99 1.08 1.10 1.91 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.46 1.46 1.46 1.46 1.46 1.46 1.00 1.00 1.46 1.46 1.01 1.00 1.00 1.46 1.46 1.09 1.46 1.46 1.99 1.39 1.39 1.30 1.99 1.46 1.46 1.46 1.46 1.46 1.30 1.30 1.46 i.00 1.00 1.00 1.00 1.00 t.oo 1.00 1.00 1.00 1.00 0.97 0.97 1.00 1.10 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.09 1.00 t.oo 1.00 1.90 1.88 1.09 1.00 1.00 1.00 1.01 1.00 1.00 1.00 1.00 1.00 1.00 1.90 1.00 1.00 1.09 1.00 1.80 1.09 1.09 1.00 1.00 1.00 1.90 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.90 8.75 1.90 1.00 1.00 1.00 0.59 0.53 1.00 l.M 1.00 1.00 1.00 1.00 t.oo MO MO MO 1.00 1.09 1.09 1.01 1.99 1.96 1.99 t.OQ 1.00 0.95 0.95 0.60 0.60 9.85 0.85 1.99 1.90 1.99 1.09 1.99 1.99 1.99 1.99 1.99 1.90 1.90 1.00 1.10 1.89 1.99 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.90 1.00 1.90 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.09 1.00 12.55 9.11 9.11 0.21 0.96 9.96 1.99 1.24 1.59 9.34 9.24 9.93 0.93 1.93 1.59 1.50 1.50 1.93 0.34 9.93 1.59 9.93 1.36 1.34 1.34 9.98 9.98 9.19 0.98 8.98 0.93 8.13 9.92 8.95 1.15 0.06 0.08 1.02 0.96 9.08 0.92 0.15 9.15 0.15 9.92 0.12 9.12 0.02 0.02 0.08 0.15 0.15 Q.QO 15.62 0.89 0.20 0.03 0.92 0.01 5.35 10.05 10.05 9.96 0.03 0.43 6.81 2.79 1.21 9.29 5.52 0.24 9.24 0.24 3.51 3.51 3.51 0.24 2.13 1.19 0.90 9.18 0.18 9.26 9.45 9.92 9.92 8.91 1.14 >8.84 8.91 9.99 9.80 9.90 9.00 0.01 0.00 9.09 0.09 0.01 0.00 0.04 0.94 0.00 0.00 O.DI 0.00 8.10 0.90 0.01 9.94 8.94 0.00 9.00 0.01 0.00 9.00 0.00 MO 17.90 19.16 . 19.16.__ 0.27 0.18 0.08 1.89 2.72 9.54 5.76 1.17 1.17 1.17 5.12 5.02 5.02 1.17 2.47. '2J2 1.50 1.12 1.55 1.60 1.79 1.11 9.10 8.11 9.13 9.13 8.13 9.03 0.12 1.96 0.06 0.96 0.18 1.92 9.96 0.99 0.13 0.19 0.19 0.15 0.03 9.14 0.13 0.02 0.92 0.09 0.19 0.19 0.10 15.62 0.89 0.20 0.03 0.92 nm SAL 000005548 TOTAL 71.12 ss ^ ^^ ^ a tt jH% ^ ^ ^ jjj ^ ^K ^ QD O 9^ 9 ft Pi 9 9 9 ^ ^ ^^ ******** r- o> <ft. p-. 9 ft O* O' 40 QD 4D ft ^D O 222RS3S ns S22 r". r p ^S2 *** 55 ID O -- -- ft* n *-S n ft CD 00 iX* CD OC Q> CO 00 ft> ft O ft O' ft ft o 4IP440OfteesO<D4n4V>OtO tf) U*> CdOOODlftV^oe**^ CO TWDUOfUT (B 8LS /ffll = 05.4 TOTAL CAPACITY 11*8151- 4 8.2' ft ft R RBR r-^ r" -- & ^ jp r* r^-i rft ir*> R<^*i H3<->*4><*5>? j? S R N r-. S ~ <-J Irt R s*- V >x> *3 nO*. R ^ kriJ H< 4 4 u,^ a ^ a^ ^ i^i m >^ O - ^ dCddEtiieEdSgdggggg 85 & ffi ffi 5----VM---I+4- ^4> sd S ^ ^^ ' '^S iSaasioiSdoiS^SSSSSSS^S RR SAL 000005(549 fe erf SAL 0 0 0 0 0 5 5 5 0 fcpf 'TAwRE,- li'd'l PRODUCT NWC TAW NO. CAF. MMETER TUMDVEFS TRlf VAPOR veer* MPEL FEET PER YEAR PRESS PSIA MCI. NT. ,/ * CJUC OIL OBjK OIL due OIL CMC OIL out OH due OH FMMMttfUIC rteao basoluc FM90 MSaiNE rmvQ MSOLK FINIS* Meant F1NI90 M90DE nOMO M0GLHE Funwp groom FDTOB MSB.K FOOII0 MNLDC fsoso Meant FINIS* MSCLOt Fmto Meant FINISO tfaOtK urmsHD Meant JTINI9ED SASai* ItriNISFCD 6ASail UtHHD SASaiNE UFINISHED MSailt UfNlKD GASOLIC lAFJNISHED GASOLIC UFINI9CP GASaiC U01NI9D GASaiC uflNito Meant LIGHT COKER MS OIL- 0 unuto Meant UtMtf> M90L1C LIGHT CCKEF GAS OIL- O infibiscp Meant UFiNitB Meant KERMEC- O 10P SLOP OOP boo. LT. PARAFFIN ' 101346 347 371 373 371 25 : 30 32 33 64 65 7a 79 SO 92 93 s? 88 ~Tf- 59 85 31 77 3 98 99 18 86 23 it? 19 24 i 62 34 42 43 TO 159 v too: HW. PARAFFIN ' ^BOCK TMML 442 444 fCAVT PARAFFIN HAW PARAFFIN PARAFFIN ' TTTTSWFiH J.T. PARAFFIN / NTBE l NDSD XYLOtS ' ^NJXED MOfS ' 98 97 194 195 __ 196 NT-1 NT-2 NT-3 It REFOMtie ene-OH PARAWlfK PMAmElt CANY CTWRATE PARAKYlfNE PARAXYLE* NT-4 NT-5 NT-6 NT-7 NT-8 NT -9 150 150 254 200 250 200 400 251 700 180 ` 200 180 25 67 25 67 80 120 so 120 81 120 25 67 25 67 120 134 120 134 120 134 25 67 25 67 150 , 150 154 f<7 *>' 150 25 67 25 67 ISO 150 80 120 120 134 2 21 35 80 35 80 15 52 150 ISO *- 52 30 67 15 52 f5- 52 10 L-1L| 43 43 - 80 120 5 732 5 32 4 32 85 110 55 110 IS 58 3 23 3 25 80 120 .. 3 28 Ht> 3 28 25 (,0 30 67 73 30 73 l 55 \ 55 \U \5 100 100 too 43 30 35 30 23.3 23.3 23.3 49.9 49,9 49.9 16.3 16.3 21.1 23.1 83.1 12.1 12.1 0.8 21.1 23.1 26.6 26.6 36.2 29.2 15.5 74.2 21.1 36.2 38.5 2.5 35.1 35.1 35.5 4.1 130.2 127.5 35,5 130.2 15.5 15.5 10.3 43.9 43.9 0.0 0.3 0.4 16.9 4.0 4.9 0.0 4.3 4.3 M 0.0 0.0 0.0 0.0 0.0 1.0 0.0 0.0 4.0 50.0 4.0 51.0 4.0 50.0 4.1 50.0 4.0 50.0 4.0 51.0 8.6 64.9 8.6 64.0 8.6 64.0 8.6 64.0 0.6 64.0 8.6 64.0 8.6 64.1 8.6 64.0 8.6 64.0 8.6 64.0 8.6 64.0 8.6 64.0 8.6 64.0 8.6 64.0 8.6 68.0 8.6 68.0 8.6 66.0 8.6 66.0 8.6 68.0 8.6 68.0 8.6 68.0 8.6 68.1 8.6 68.0 8.6 68.0 M 130.0 8.6 68.0 8.6 68.1 0.0 138.0 0.6 68.0 8.6 68.8 0.0 138.8 8.6 51.8 8.6 58.8 8.6 58.8 8.0 142.3 0.0 170.3 2.0 32.0 0.0 170.3 0.0 171.3 0.0 142.3 0.0 142.3 0.0 142.3 6.0 88.0 0.4 106.1 0.4 106.0 2.0 81.0 0.6 106.0 0.6 106.0 0.4 106.0 0.4 106.0 0.4 106.0 LIB TENS CRUDE OH LB/GAL FACTOR 7.1 0.40 7.1 0.40 7.1 0.40 7.1 0.40 7.1 0.40 7.1 0.40 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.19 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.00 5.6 1.00 5.1 1.19 5.6 1.00 5.6 1.19 5.6 1.19 5.6 1.00 5.6 1.19 5.6 1.00 5.6 i.M 5.6 1.00 5.6 1.00 5.6 l.M 5.6 1.00 5.6 1.08 5.6 l.M 5.6 1.01 5.6 1.00 7.8 l.M 7.1 1.00 7.1 l.M 7.1 1.00 6.1 11.00 6.2 11.00 6.6 10.00 6.2 10.00 6.2 10.00 6.1 19.00 6.1 10.00 6.1 10.00 6.3 l.M 7.3 1.00 7.3 1.00 7.4 1.00 7.3 1.00 7.3 1.90 7.3 1.00 7.3 1.00 . 7.3 1.00 MW VEL *>H 8.4 8.4 8.4 8.4 8.4 fi.4 8.4 0.4 4.1 8.4 B.4 8.4 8.4 8.4 8.4 8.4 8.4 0.4 8.4 8.4 8.4 8.4 8.4 0.4 0.4 0.4 0.4 0.4 1.4 0.4 0.4 0.4 0.4 8.4 8.4 8.4 8.4 8.4 8.4 8.4 8.4 0.4 8.4 8.4 0.4 8.4 8.4 0.4 8.4 8.4 8.4 8.4 8.4 8.4 8.4 8.4 8.4 TOTAL CAPACITY (WBL5) 3841 DftaSfVT imas/YRM 109.8 ClINGAGE FACTOR RFI STS. LOSS TPY PRIMARY STG. LOSS TPY itft Lob'i WITH. LOSS TPY \ TOTAL LOSS REDUCTIONS RFI SEAL ffllNARY SEAL TO DATE TPY TPY TPY 0.0015 0.0015 0.0015 0.0015 0.0015 0,5515. 0.0061 0.1164 0.1164 0.0068 0.0060 0.0061 0.0060 0.0060 9.H6I 0.0060 0.0060 0.0060 0.0060 9.1161 0.0060 0.1060 0.0060 0.0061 0.0060 0.1060 1.0060 0.0061 0.1060 0.0060 M960 0.0060 0.0060 0.0060 0.0060 I.M60 0.0060 1.0061 0.0464 0.0069 0.MI5 0.MI5 0.M1S 0.MI5 0.0015 0.0015 0.MI5 0.0015 0.0015 0.1060 0.0060 0.0015 0.0064 0.1060 0.0060 0.0060 0.0060 0.3 3.5 0.5 4.6 1.5 4.6 0.6 5.0 0.4 ......... LI. 1.4 4.2 - A.i 13.6 1.4 13.6 1.2 8.0 2-4 24.3 2.4 24.3 1.4 13.6 1.4 13.6 2.7 27.1 2.7 27.1 2.7 27.1 1.4 13.6 1.4 13.6 3.1 30.3 3.1 30.3 1.4 14.4 1.4 14.4 3.2 32.2 2.6 25.0 2.4 20.0 0.5 4.5 1.7 17.2 1.7 17.2 l.l 11.2 3.2 32.2 0.0 0.1 1.4 14.4 1.1 11.2 M 0.0 0.9 9.1 0.9 9.1 0.0 _____ 1.5 5.1 1.5 5.1 I.S 5.1 0.2 1.8 M 0.2 M 0.6. 0.0 0.1 0.0 0.1 0.2 _ L.J 0.1 I.S 0.0 1.5 1.1 11.2 0.1 0.0 0.1 1.8 0.4 4.3 0.2 1.6 0.2 1.6 1.0 1.5 0.0 0.0 M 0.0 0.1 0.1 0.1 0.4 0.3 . .. .0,3 0.1 0.1 0.2 0.2 0.9 0.1 l.l 0.0 0.3 0.3 0.2 0.2 0.6 0.5 0.1 0.4 0.3 0.4 0.5 0.1 0.2 1.2 0.2 0.1 0.6 0.9 0.2 0.6 0.1 0.1 M 0.1 0.1 0.0 M 0.0 o.i 1.0 0.0 .. fl.0 0.0 0.0 M 0.0 0.0 0.0 1.0 0.0 1.0 0.0 0.0 9.5 0.6 9.6 1.0 0.7 0.7 1.5 1.5 1.9 2.7 3.3 1.4 1.4 2.7 3.1 3.1 1.5 1.5 3.6 3.5 1.3 1.9 3.6 3.9 3.4 0.5 2.0 2.0 1.3 3.1 1.6 2.4 1.30.6 1.0 l.ll.l 0.6 0.6 0.5 1.2 0.0 an 0.0 M 1*2. l.l 9.0 j l.l 0.1 0.1 (* 0.2 9.2 M 0.0 0.0 3.6 4.8 4.8 6.2 4.4 4.4 13.7 13.7 8.2 24.5 25.2 13.6 13.6 27.1 27.4 27.4 13.7 13.7 31.9 30.8 14.5 14.8 32.6 26.2 29.4 4.5 17.4 17.4 11.3 32.3 0.6 15.3 11.3 0.6 9.2 9.2 .1,2. . 5.2 5.2 3.1 i.e 0.2 o.6 0.1 0.1 1*9 0.5 0.5 11.2 i.e 0.0 4.3 1.6 1.6 1.5 0.0 0.0 3.1 4.2 4.2 5.2 3.7 3.7 12.2 12.2 6.8 21.8 21.8 12.2 12.2 24.4 24.4 24.4 12.2 12.2 27.3 27.3 13.0 13.0 29.0 23.2 25.9 4.1 15.5 15.5 10.1 29.0 1.0 13.0 10.1 M 8.2 0.2 0.1 4.5 4.5 4.5 0.0 1.0 0.0 1.0 0.0 u 0.0 9.0 10.1 0.7 0.7 3.9 1.5 1.5 0.4 0.0 0.0 60.7 590.2 10.3 71.0 600.5 525.5 EMISSIONS TO DATE - 75.0 /oi i O 7VW_ u.G6/yc. 'S y 13 C ""Tot.utS'Utz TMY(- S&.C/ ^<T*->c (9 X VCe-^C /?7 x x S 7 Y/? CT-o<S 0Cstr? aj ycco //Cx*9*Jg 3/ C*j v C_ C*S6 -- ICsZC, -- IS? 2. -- I Si -- 2/ 7 - Ho d - PI 9 - J9 - 13 -- ia -- P3?9 -- 102. -- i 3? G> i ! I T Conoco inc. Calculation Sheet SAL 0000d5551 v- f&AT/tk. TfaUC- S*J*B 4oSJ = T^TAC \bc K /Kl*55 Cyc .. K (-^L.\ (S*f~*i V-^. j 7o4 CftJDt OiL TJl^ Lasi - Boo^Me ; /I ><*' T?` *rr Se/i_TPV /iboe: (^t('3.*4 ^ -jo.ooW Tfy 1*^4^. M-L o4(u gjL. J. *JL . I ^i. ,.i..i- :on Sheet SAL 000005552 TApC- l-tci I sx u-- = Tjnaoc. x r\Fc % H&A Kfr ' F\k)\S&P &*>,% A~TctTftC t 3z, \ -rry V-11 / ft c|^*^ioL TffL W?. y/ - O7^000)*** r 21\ % VI77, % lyu. (*-l '"SaJseVe: ,. , , c v (' IrteX^) {rr)= *^2?v ^ rt6 -> 0. -? (3Z.I .oleZi TT1 V ^z-( - Mtf I 0**A T?^. nIL B y ov pn~ * ^ 0->-i p(y^) (~7^ - -jr) ' /Toirs 6z.7^(^(^ - ' f3Z.' (4s) ( `7) '- 11 -roc. .StY - 32. ( (, o / ( ".u; '. &c CuM * 3z. \ (.&('i'ir?:)- oc -*- 7 - 32-'1 (,ziYi~?x (V1r'"') (^(ttl) ~- p aikn ~tf^ ?.*y 'I SAL 000005553 ,- O-.v AW -kJ1- `n'V S'. ( /^a^ "i- ("terO^* A)fl * ^o? - ^ASaU^/C ^7 7n Uoe_ SVS /. 7 6^-pj>w : A* Cr~C. - + (. CwU.o^') - - 4M - (n ^) (X-&) -- . ocn^ iwy^* 1 "mL : <3 ; (u^mx^v-1 <0087 TT^ T*- ; 67W))(^Xnr) = i :QQP gt/ t>| gTj "Y *`T f-v ov>((t=y ^ - .**/ *0i>/2 Try o-*4) | (COZ.CSFf^ A*-*y X ainU^Vi^-- ' .coosi i*y. 7-^ | Sty cr^ -4 1 (c.o^o-r^7)^ -0OOZ1 *S lt;.ix;0/v- .,<,,7 (mV .o/Yfift = .0O0(, <J/izr 'V' JsH J>7 SAL b00005554 Swsc Uff tZl >5iwifc Tfc^lL Lrrs r (ysaJL Ibc) )c((V\F^ Yx (&SdU*t" TnAC UX - 3-2. ~T?V >- e-^A. w^ 5Wt--> m*o n OlB*+* T&*- ts> &=9 A&LjGtA, Vr^ L-5^4 CamJXj**j fjL^L^ rct O^u aI*,z Xd~x< aJ 3 y/X-- & 7i7*L? 5^ Aij fjAy^u C|w<. ]__^ ] 3ft HZ b*io on L< 2.Z. Zf si;,</ ft 6 /xt C? Lo *1 zj o? iJ Z.C Z*G -- -- 4o 3.0 3.s i.o o 4</ /o /s'O -- -- c> o o o 0 /.* ?.< Zf -- -- t<o o o c? /ft .o fro -- :-- -- '-- U? o o ,o O' o o O -0 5Io 1.0 ? "?.6 I 16 X 'V __c4- i * ^ ^ y f ^ 6-J 7 \ rram - p.o3 -- -- /.O 52 f.z. r= o /o <2 A*- W c^-Jr c*--- e* ^0-4. ^ 0-^ O--io 6 W ^ o-- 6 f- yUi ~Q+i+ *_ + 3 +*4 j C-'W -- "7.i,% to + / > O + 1 ^ ^ /+-^>3 o>ia 04 UiH * 7" - j. 34 - DZ 3.^-6 = zAZ -- o.* 2 SAL 000005555 'v-.cliia'jon Sheet **JLji T*U? uc ' 2S.2. 77 '=* ^ * (^,'&) - ' 11% ' "T<^ TaCt B : "T>' m`Y 6?*.cXt=) (tt) - 6^)6^ (4) ^ <^^K4) - friX^V#) u)^)(-&v X^ ^ T^-P ^ozl 1+j ^ ^ I J OC^ /^ws^ 2-S. 'a- t1>\) xAA ^^22.. / *^. ,)0j - | u/y* ** ^ * .____L^_ -- t; i -NH Fee kcs4 Lrr K*>t^ !- Lm?f.kxt -i- ?) = 7T* ' 41 />oy tsy / / Cr-J5 1 Uf y .1 - "Yr &i. t 00 3 -rfy /00 V "Vp SAL 000005556 >neet ZSSSO^OOO ivs :-'- -- i^j r* Jp/7! ; u -_ i "*' r 'I A --- - (*r) (SfK^tf) ~ (^ 1^?^} t/t S'l.t!' j '- i&i ^^9*1 - (t&? (r?(^7^ .t - ("sF* ^ (rr)^7?'^'5^ ' >7/ *> ^~<L ' b-LAl , t#-C? : 43 r 'rJ~L ;^)U5' ` (^UfA1**-*) ^ (57) \ * *r^r^*^) "<m- 'tvjS' * ~>n -f&- -- <12$J ("4) \ T'A'dw)'^''' *?22eZi) = ~*7 SjN* 3aQ ^j_39nos vS-to^s ^.g- T-H ____ _________________ _________ ^/f^Tz, OSl.. 6SY .Qg^5> ^ ^5 -r-^v r-^5 .>// <o? A_I ,2.^ Mappf-J ' .- 17 ^ =\-L>Lb-l>r ' ( , 00=? >------------------------- - T SAL 000005558 Made By Checked By Date Page of _ .____ .. Conoco Inc. Calculation Shaat Title ___ ______ . _______ ___ _______ _____________ ______ ________ ________ __ Job No. Field State . L~afe Charles Refinery Sbr<eam Co i^c^Hr<j4xorts &OSckrt. Lit- (y'OSc(>n* SllL (Laeol^e^ PCC &'GSl"m(u-') PV &ae$\L e (fbg) LSR ^asoi're. P\d(or^"^e Cride^A rOi; Maph.4KcL. Crude 'Jebuh^f'- tt< OR cJMAPH-^hS tffluevr (Lcl<e< &as 7S/ | B. -----y rrt-yu h-?u i> Td" 7. 7 "= 1,9 ^7.? ;. 2.V L, ` :. 1 (7^ "t.W 1 ;j "' w. 3,1TM 3.0 3.'^- 15.0 ' 4| - 4.1 W *1 \ 1,0th R.5' 0.3U' - a-C /5 " 5 .3* -- as A3* -i.a. /. 7 r. /, 7 (. 7 i.z' i,t " c?-5 to M -- =? 3 r c?-3 L 5.3 =' /,<? P A? */ 4,0 ^1 1,0 <-1 LO V.o 1,7 ' * V,o" /7 P 4/ * y.o s' M " *1 ~~ =? 5,0 1,0 J-0 j<,> * / c/ f.o S.Z. 7,o $.0 M *1 K i LI */_. K/ *1 .0 iAO _ L'.Cl.. 4/ !4 i < 1 A*/ _ 1,1 /.5 LO j&tTGir \cti*) tofel nm-mp led- C&rv,cf^ Lab kSp^ts fi) fer Jlll^fbtic^ Sir^'irt SurveLj (4) Eat.. Lci^s.4. Or\ o^er M^ph4W<x (or Ga^o^n^yija^ fe ' A'/tK QqsoI*>t Sdvdj (b.. Ol I iC `ducbdl (7) Per T?^ M'ycV-s r^leyno (y*,, 7; |?T8r) Made By Checked By Oate Page of Conoco Inc. Calculation Sheet Title ; Job No. Field _ <?tata ,5*9 0 00 0* H.l IC2 1 Ose Foft, Vit_ <~^jr^-Cf\f^\\ SAL 000005560 Va Pc i 13 /. 5 1 auus/s/ o>. 4 H.TVsTr'C ___ ______O. 1 8 CL VC C-O SVCrX A we 1 . > XVLfi/Vtf.S- ' ox i ___ 5"Tv /Sew'd o. o e>& 7 O' /*v1.<2 A/fi o. 0> | 3 Pscwo Cu/vewe 0.0.3 93 . cx oo4 5 .S/PMfi^yc ............. ... 0,0193 <2 nbon__ 3.4- <3/* ___ . .4 _ 6 - -2 k'cS ...... . . O.QM AIASmtu-# -^P-4* i i , l o. o o S Made By Checked By Date Page of Conoco Inc. Calculation Sheet Title SAL 000005561 Job No. Field State ... PPpsNOlX X FUO~iT\ E&UiPnn^rST WO 04t4 voc. i.^TfO/V5 Title Co">ccc Inc Calculation Sheet SAL Q00005562 jot No ; Field State 95500000 1VS szoy oat ic/tn/b^p / g^O_[ 2^ ? 9^A /> M 'e 9 A Ub? %tsZ OiSh ' hbve . *> Ok l Q1 ^ ? 'o; 'zss'o i 9 9 8 JT "?Z b , bbTzi T:ZG6 - _ _ -- -- -- _ - -- -- -- -- -- f( *r2? + rf0ttr{ J>r*J ?A/?AJ? 3> r2 7Ss/^l . fi/i/Sf /.>9j ,{ <} r- z> p ~{ f~> s tX ''*-' '/ / ,,'/ <9 3 r^z>z^yc/ /y^. jt r>0<0 p<7/ osyjizrsor-; c~> >* A -/ 4 / ^ A/.r/-7 ''v^ r?/ atejs Pl!d on qor *96500000 1VS laaqS uoijeinoieo Otij OOOUOO H!1 *0 a6ed 9iec Ag pe>iaBMO Ag ope/ ^ef-^OZl'O = ' -+ (? O ]"$) ?A7 I oxrrovo ) ' 'pn HO / awf) '*3',ow/s <) H- '4,wop-?ST7 , 6otr ^ -4- ?o- '2^3" <3 (Y 1> o TV ~ ^Ti-Tlvv-U-Wa^y^ <?e s', 0 = fN-do'ti^ o , ^rGiwo^) o = K\Ua o_ ; "" -- . __.. ----- <?S* " - <^70 - '-crrO' ,-Y/yg 52 0' - (/<? ?0* = (-ZO-)tfi'l O-OIQ - A>-U/ 52 0" r (IO-)U` = A>-C 5ZO' =. (jG'jiA'Z oar - j-2-^O ' -+ Sc 1 4/>' " 1 Z^}* _ f2o- + Uc? -+ -ZOO- -+ 00- i ^'- ; 20 ' IQ t "1-i^w-; 'crjO>) ' ^4UH<JvrV `-3<ny y ------------------ ...-- pjo 't b rv Poprprs'<5 M 9 << S> --Cco cri\ ^ u3 r /W_6 ,o?} r *0/ <S-*y ^'9f7o/l ~ ,Q/C Mr M-x-V - ' -0-0 - -0 2 9 = /.oi) = . ^/r^ (L'fctty ' /,v^os4 + .o4= e>./27. iT LN^e les. <5t^R./ Oo/at "P. Oum. = o Ctt-pj =a r''FViof*^ =o ^ lt Si&fepa ^aPM-t-HAlcm*. - f . O 3-t.Oi^ ~. <2.Of-? - M 5 M>S^ . M -4 +\>s Ort uQ. _. . . ~fi>eNtc.TAC- LhC _.Oe>2#r Q<OQSr. Ai 3 C'fiO l lb. . M APHTHA. t^eFDftPlAft OJ Ht> ; _____ ' "Bew - [b,U % o ^s) - - *.3og f Jtij OJi Q~< i - (s> .^^0*4 + .0 Is) r - 3>2i5. M-VV r k n(,oit .07S = .,60^ SAL 000005565 viade By - Checked By = Date Page ..... of ........... -- Conoco Inc. Calculation Sheet Job No. Title ___________ ___________________________ _ Field . ____________________________________ State Al 3 CR.Q-- ~P- *w * fc^ *^>8' dtH ~ . o-O r Qc/3*/' /UA>n * o ^ Sr^a ^ o Ouaadue: ~ U^iVl,0/s) = Q.OLJ TCoMmac' "C-TH vj- LlU e = 7 -M47U^ k-i^f <07^ ^^Or^V-Lcrvrc ~ L*<i>"/cdQ_2^J -\ ./^y- O ) i, 3 "?0TA>/e7Mt ^o ~h?UGr-^L/Vr3. (To/^EJ^ Cc 3o4ZCM' QsACS^S*^ * Ma^HTHA. ! ^/ *E*W(lr C6- - -3 . St l . .003} -=:_. 0_Ofc/ "Toc_ - .,,!(( -1- ,02^ r #Q2>?7.. 3a^^EME>ruS<| ;QO(J ~ - * DOS | O ^y: V LtTA1 s- - AV siyccwc * -sy(j(.0.1 ^,0?) * .d/^z-' a tsar. -2U r ` i5 + .0/^ " 0,/3 ~P - LCM. ^ ^ A^rr- /4 -O .. lade By Checked By Date Page of Conoco Inc. Calculation Sheet Title SAL 000005566 job No Field State CoK.e?^-. CrVy * ..5/.L(~ At>V - -0/0 Kt^r>-rt -Of' St^RccsVC " *5//(f^/_3 ~ -005/1 CoMEwe= - .005.//. ~P- = *5// Pos) * *<P/_5 THVLtnue= .51 J(. oi^ ~ . 65| >oP^UEW^ .| I C. 07^ - ,03L 1^ =o ~~PrqaiUN\ (ZotaaZ. u< ajiTj ^err (Sav lie?uz.'cw^: ^ L723." .co55 .005/ 7 tol^ I -7^3C r -0^ 1,011kCoTs - .D/7 1 = f.mpLon =_.o n r hlZ3i.oi$) "" P' ^o iade By Checked By Date Page of Conoco Inc. Calculation Sheet Title U\^e C*A(k SAL 0C(0005567 Job No. Field State Ci\^. = /(It&Coz. + ,0h T e>. Oez- -o J 3 'St- Sry/3-iU - 6c/) /,723^ .017 CoKtut* Co'^i.-rQ - -c>/7 K. LuMCU L = 7z3 C .0^ : 0.652- = Mi3(\o*V .6/7. rcf>y = /,7 23/ o<fo z 0.1'L S\ 2. Cs .- Ck/^Ktr^Cr^ViCJ/ Oo/coi Gaso. Btxmau^ 3, 05g (,oz^t ,oo'3'^= Q.O^g -Ib<-- 3. <5Sg( .o-, + = n-2-lV E3S =0 ( = Q . ^ ^ fe-o . o-^y - ^.aay/^i-- .031 /'i-y y QlSfr OHS? Ct+y = 3 OS? ( 652. +- *Of\ - 0.1^0 St^Rj^h^ ~~ 3,05g(,bl ^ = ,03 SAL 000005568 iade By Checked By Oate Page of Conoco Inc. Calculation Sheet Title Job No. Field State Ki - - G^c^it7j>J) Oorvodt:^ . -3l052Boi3 ' 0'31 LfsKC -\ TM?CoMO,'C` 3.OS? OoSB CTnN^eiuE: - 3.052? oi'} *6.3/ B^y : < , =3 05^6073 <o,2j . (Sv=> pt^TT". OoKt^. G*.% CpyoBj&C " .. '-PB "a-6 3a> 5,0 l^o^ou-e - ^0^3-(j^.ot 4- tQO^j-h foe, " 7h 9 (0 OA) s') * o.irL as - L.A3 ( S to")") - 0 Cr*V = (o, H.3 % 3 x , 0 l ~ 0.193 M-yy * 14? < S.y. .Ct/S " 0. 2j\ p-kY - 0 / MiKPrt ^0 ,-- ^ J": 1-- _ C-HY = L,Aa cA3 `Bj CXLcT jZTjoM CM C ~ ../J7 a' &&o.: Gr-+Gr\%ci.^ QJO ^ __________ - - oy"jD r^- C--:>-'VA/A.:>f. Bo^oiC * B47.\c 3 sc . o3 ~ 0.^7^ t-'THVcciClC ^ (c.V?.(\Oi^ ; 0- Oi^JS SAL 000005569 /ade By Checked By Date Page of .. _ Conoco Inc. Calculation Sheet Title ____ _ ____ ____________________________ _____ _____ . ._. _________________________ __ Job No. Field State G-P-.r' Chills 4,S3.{ >d7+- .33+- to% -+ ,&s) * 7-<37'irf7' 5 'Sota'T^.icwil- .4? ( ,ct3 -i- .00 i.- ,oaz.i> 001') , OS^ M6 U --------------------------------------- D^tilcatT' Hi>S ___________ ------------------- G^ . ( t>iS,Ti u/ste^ Sr. i<OH iS^T 0^0 TBcAI^CME = i. % 1 {(. 00 zjz+- .0 39^^ .<DZO^ '"Tat-' l.%7 [ ,03) ' ->S(o G6 - o-yv ~ M - y:v - "r'-yry =0 - St^)Ooh) C% t /. f .Ooi* ^ o.Q^ni^ AJk?W ^ I , "7 ( , 0 3 *2.\ = O - f / -2--' M" S " ScAo/es At 0 7 ~H-t>S f+/>S OH- UGl ~GcXi^eWfcr--U'lS ( QO zG - .<00-2-5 <_________ __ i. ____ I ^asbl _ Jpfej> ;... b/e'SC^ /Jf\F-HT%H^E = G-94(,0^5 = ,0^fi lade 9y Checked By Date Page of Conoco Inc. Calculation Sheet Title SAl. a00005570 Job No. Field State M --LVxtl \\ Cake CrtfAitu/s* Qfiu>er/ ^/ AIM**, A.o'o, ""-TM 2-'exit, " (.Oq.3 ^ . GCZ- -+- .037 + .05^j i */ k 3 ^ ' '3- 'i * -fo^ = 3,77f ,o^ -*- .oz_e> - jo 4 tlb = S^lCot')-'-- o~*i = F*~ X y - * 4 *>3 M v x V -- MlC. o-z.^ - ,047 ^>54 ; , ^ _. Xn most- *2t-5.5 ^ -rc^rJ-z. 0^ CXor^^ jljz. -VHk- charge '-s Se- QHv ' 3i7 ( ,o /H 7- . OSiO =\asi. . ''7^) AJ APvf - - Cjm = r"CoH .-. cm('l>/2o?>'^ > T^cc Fee. >-Py. 6-6; hcc&ao.; Su>fr ^Bew^cuc T 7.i3. C-o i w-z^.003^ = O.///(.. ~Ti u = 1 Z3 [ . Q>w') - 3,3/s eS> = 7Z3. .0/2^ = .0*7 / 7 5 ~P~<i - T L3 f .os') = ^ 3k 3 / ^ ~7 2-3 C ,o/') ^ 072- /laae By - Checked By Page of Conoco Inc. Calculation Sheet Title SAL p00005571 Job No. ._ State \^ ^ ... ' 7-23T .01s- " .P72- " Com - T^com, tfrHVuTMt' 7- 7-5( ,iu}- ~ i- lL 'F'&d^VLcr?we = 7,Z-3C.ll + i^ + .os.) ' 3 ~ 7.U3 ( . co^ + .ao3-+~'0O3) ' -^5lt Hy L " 7 2.31. 0-/3 = aO'I.Z*' _L>So ~T/Vlu Ga^ . ^-THv| OCM t_ " 7.57. (" 7. 57 f . 33+ > ~ -vlO /, 3 3>.or-3y ^ O) cT^rr ~~~fe<-H ... >-> .F-? / . 7 ..f^-oPy = .g^g&C 4 (TTtog^ = 7,/ , 3 B)"b = $.20.(2-0*003 ^ - ..032_ <ade By Checked By Dale Page of Title Conoco Inc. Calculation Sheet 0000055^2 SAL Job No. Field .. State . \> 1,71 C.o) 4o aa^.o*/5)= O-S/? Ctty = 7-7 /. 6^05^i--<.o 2$) - .Hi H.. K\h>t\ -= St%|-- Co/= ~>c- 07f.^'?/toP= it 3> fV- M 0 I +te>S .MAP* PeF; k&>.fev\ ''Sewe.- /, v< C003 + .0/ .) = . .C>/? "Too ~ //Vd^.Qia.i-.o^5)= _6^^ Ofe ' -*3>=^' ~ o-yy = 7*-xv /Vi 7.aM) - ,<02f r\~i~ -es^s, = Cf^- f.vCf Q^) - ,09 9 <ade By Checked By Date Page of Conoco Inc. Calculation Shaat Title SAL 000005573 Job No. Field State VP tt, 2- QjVo AJ /VFt7 V^\Q-t y<3^h^ rx~M7_eMe - l*2 ^ ( 003 *- .039 + 6 3L^)- ,98 "Tb c, - J,--=vx ^r<? z' y , oxa + . 1 s - .05^ ~ 3.5V u6 = *<A. 1 .o/ -#- *O ^5*>. = . <^.Vf >'* f ' /a;1? ( ,0-S 4- .o/^ -. .. .bjtf. - - M-yy = a.r( ,07s) - M3, = 12,. si. c .03.+ 0/^) = \sa*/ C tv r '3 1? C ,)2 + .0 52.^ e /Ji^MTPn- - O ~ Sty &. ... C-ON\ = fA.** C.o^ - >C: o>\ a -J cthvucne T^f^Vtcu1^ ^J /,>} /i J ?5 Al7T-/7i' 1*! >1 ^ t ** "T r- r&exi /Stf ,, !Sfc -rrte^K < , / Ccfceio- Gv-s. lou ** /,5^0^: .,<2fc>3 ade By Checked By Date Page of Title Conoco Inc. Calculation Sheet SAL 000005574 Job No. Field State K (/$ & = c> a 'p-'V't- ______ " LfeSLC.OjV* J 0/k ^ -v:^ = I,s?(.0,.y .o^V J C'rW r l.'SCcn)- 'S-r^fZ. - C'o^ - ..OIL, Mrvv>Hi_=0 - l%6t>* ? Gom l,5f,oiV' 2^7.............................. cm'i - | .`Sg'f ,o(^ = .O/C - l.5S(.cn\ = -III. ~?&Q_ ... . . ..._.. ___________ '__ __[__ ^1 '"Pt^ GW>, ?-?, &-ie> Cf\ Gfi&a. ~rbew. *= S\b-I .oi3+.DOi +- .0 33^ .= .51S ic>t_ = 5.bJ (_ 2-C*o3Vi.- ,337_._ -o ot( ^ M--r^f- - --'Srj -- Coaa - y*Qqm - CtVv -- 3j *1 . OS3- " *5 23 erm/LF-Kirf s. |n/J ( =-0 >eo^iEM^ ."SjoJ..{. .Is81- ,CS) - (6 IP 1/ I ' ^ 3<^vt>'- 5.UJ { ,00^^003^- . 03t/.TP*f SAL OOOOO5575 :ade By Checked By Date Page of .... Conoco Inc. Calculation Sheet Title Job No. Field . . State AurCVLAnrcvg---------- tTTVS '-CMC ' B.^jh CcT) ~ ^ ^iPiu-Mt- fc^-f- .cs-) -- v?.s\r I, 3 = 3, V^-C 003-^03) =L .oai /\<^i b> "^cjvajct- s (5^ ems ^ i.cnC - .OS4/ r I'O-HCos^' au l,i cl> - /f^)VO^oi)- t.6Qio*f Ta^k ~biex(>/u6- '>ewte74E:r J> ^ Grvijo ;/Soi_ <3^5*0 G-^NSOfCS. .& <L_. +?.e*=o (jsoi^r ^P-f (~, Q i'] i-.o/7+ 0 2-*f + ,oo3i +- .OO ^ /. 26 Tf*y To*-' .acM^^C^4? vc3 r ,oj5^ " v5:*/ c> ^ - 20C .O. i ilK 3> - /!. 0 5 G-^M " 2o.6'C gY- /Y3 M-W ~ 245, ((, -v , o-'-fyc 2 -t-.o/H) - 5 17.7 lade By Checked By Date Page of Title Conoco Inc. Calculation Sheet Job No. Field State SAL 000005576 ll = 2C.&C. (.0/7 * * ; '' 5 Cf4y - Ac.</..d*3 +- .O'M) . ? / KifVPc= 3o.k(>L ,0Z%2^)- /. 5V OT1^ A - 2-C ' (j (2- (" < o / t 5> ^ r ->?$ >_ /"\ KL OA r 3^.02..= . ; , "*" U# i_ c^Q/ ' X3 C.O(') - * = a DM ^* }(_7Ufc> Stocks. lade By Checked By Date Page of Title Conoco Inc. Calculation Sheet SAL 000005577 Job No. Field State /-* o</r/t/dCT " /?cc (J*j/-rs A<<V At cv CP F?crc^ffvffc - /rac<* X h-'ic/Mi-ron/Kj c; css /s>f3<6 .0*2 * /P ~r'r'<C*'c>e '~rps>f^ voc. ~ KJui^iGc* V/> ^o/? f* ^/VC/ZO l/Witxffs ; v CT 0/*nP^ s?*sO /rc.*+j& CS 'T'/rvtSS 6 <?*7/*r*^4 /J+jO /VO*.j-CC'f'S'+'i &+7fS/o+^/r'*c-nt*s &'*"<?r';&>- T T/sv^-rc** 7&~k*c /*?<?<.Tost -T -ryr(**-~~s- < /V/ ~ y /Af ~ /'/*Q5 tiffis 2 c l/Q \J4CistJf - VrtP 1/deist's - 4- Co/rtPst ?S-fo*s ' Pt+s^Sr ~ //r 6 cr 73& /fZO % ^/c Ve>/ ?rJ> VC'C = \o(t0o7fr)t VfCoOOsi) -+ 3?\(.Oo?i}-h ^(,099)^ /5~$-o(,0G/$) + h(,qic) ^6,(.o?o) -f x(.z) X ?v 7 = jfg^S' - 2 4^"^ = 39/*^-f 2*w 5 V^c - r/^r * Ay- ^ MOl- lPOC. - /, 4t -rpy ade 6y Checked By Date Page ot Conoco Inc. Calculation Sheet Title SA*- 000005578 Job No. Field State FL/ c / -r/tsc f A-/C 6 hJ- 2 C-ru <7 5 7/9^5 At/ ^ V*/ ' F- PA -- * ^77V/w) /V?" /6V7 <T J2/?) 2 \JO<L - 71 (,do3$t C(.iq ) f /wC'Oocr?) + /v^.oo/P) -+ * I (*?0 + %-*&)+ 7(.0jo)^ 2 (.2&) s ?</ X 70 * ~^z0 +.9 = J, V7 V4C = 3,4 7 T^Y Qd N* 3 Ctl> 9 S~?&?<**** j Ss?f~7 c yO- ^ 1/0 C - ?,V7 -rygjr /V^7 Cs0tct*->&t\/OCL - CD l\l~ 2 CsftC/^C^ \/oc * o aac* By Checked By Date Page of Conoco Inc. Calculation Sheet Title SAL 00000&579 Job No Field State h user Pt, GftCM&C. \/oc, - o 50 / O - tag#TMr IV - vv . f CL - P- ^\W/u nt'* /*?y 2 /?/v vac 2(oojs) -+ 3^(tiP) * CiC.oooft) + tto(,oo/t') + tf(>a+9) + t St'ii ,oon)-t jCi ) -* /i(oii) r I (,?(')-t- y^.ow) x ,;y < J0175; r'o - l/6>, - VJ ~rPY N-- 6, UOS S /-- Q*)t.C.. /l V--(S /V- 7 LV c VV /= -Z3 _T nS/iz ?9 i <7^7 .._/* -rPcy-r y. '/fi'O r / / 9(,oo7t) t ?(,iei') + & z(. Oaor/) * TlC.OO//)-*- 4 (,c#f) * 9 f ?(,ao/i) * t,(.ou) + z(.a?ti) - */. s-g9 -r- 2 - f.sr ,27. ?v? x yiz, -r - //? VOC = h?7 -TPT --------- ---- ade By Checked Bv Date Page of Title Conoco Inc. Calculation Sheet SAL 000005580 Job No Field State FLI* . / TV l/CS Nk 9 NOS first*o f fi f'7#<F*'*f 2S 4.6/*#*. & AJ As -- *S0S j.zr (iXChXCSttS - ? = ur \/oc = A:?r tp <3 N- ? /Wf 9 .''7/?r^/ V \/ r /r ` 2 r P v^c * O5r(tc,oft) 7* \( ,o* 0 -7 ,2// C^oaj) * 2 K' * Ji* - V<2 C r . 95" 7/v ^ *7 . VT~ /A .fT/T A/ 6? t- < t* -r s9+, tv* ^ Q/2 _ _. _ _ . Poc^i+y^rs 1 a; - / Nor Prs ts r--> C~ Jrs4~f *f Aji V //Or 1/06 " /, -/ TV*/ aae Bv Checkea 3y cute paae of Title Conoco Inc. Calculation Sheet SAL 000005581 JoO No. Field State F <-*>/ T/tSCJ F'C C Ffir-0 cr (t> V Srr#o4~if IV T 13*/o X/S z 20 ' F - n <=> ]/0(L - ) t>( .col Sr}-* ?(",/*)''' rtC-OV") + /(.a**) + //?(, co/s) 'IV * m v itnr - v - 9v V OC - 0.9 9 -rfiv /FCC 7 r-r U IX F P c Ja*/793 a 229 P /r/j o we- 309 (. oo;ij + ?9j (,ooor i) -+ 2j->(,uoii)-f 2 * itC.cau; + /sC.oii)-* it/Ct-ru)-* /(.*> (j.r'') ' 2 * x ?^o * ~ 6>* t> 7 * 2 27 !/<?- ?,PJ T/^r lade By Checked By Cate Page of Conoco Inc. Calculation Sheet Title 0000 55 SM- Job No Field State C & -TO T Zl/ VV/ /= P C r , - " /?, / 6? /o 21L * /?tz ?Vo 6*/o yoc - J$t (, 00??) + oC.li) + 2 OiC + 'r(,0+?) -t t C 0 (,0 2 c ) + (*( i) / JV y >,,> * [_ Ju, - * h.r; \J DC ' ?/ i"? ~rp V Cld-T Pot V V C-rfiCAftS i-V ^ 777'/0 MV 6 9t* /= - uer /O * Joe, ' ??j(,007f)-+ 9rCtc///) + /CSr(,00/i)* /vCtton} x 2 V js, '2 V S.2i VOC^ -- S~,2 6 T/>y sdG 3y Checked By Dale Page of Conoco Inc. Calculation Sheet Title 9oooo55a3 $*A- Job No Field State t-- Ls&/-r/t/S L T (Sr SFt / rrcsst 4^r-'/6o t r / fo Tc - 6vP fi* y VOC - /foC^O??) + ^VS-Cco/f) -* r A 7/ t^v ' 2V * rT ` / ? y N- 2 CPcf < MQs ^ PtP/`r/?s~~> C'n S~ ?"*&&*<. s L V - (?2l`/?C ) W r Tj-c j F , 1o?y p -- /& 7/i c ' 2 voc - 296 ( oo?fr ')> a (,1^) + ?i(. Jo?v(, oo/r) + /?(,o2c) + ?(,ic) +*( ,o?o) ^ *(,*) * ?y *?Jo J.WQ ~r r 12.T9 yoc T /J?,r? T-^.y ado By Cnecked By Date age of Title Conoco Inc. Calculation Sheet 000^ s&v Job No Field State LA.^t & i Ca^O' t>-~ ------------------------------- ------ L>i*}m& fo^/iL C~ StA^.^% V'/* Ai> f - e-4*- f5* " ' ,, \JoC ' /C3 c" .0035^ ->- Z-C./q^-*- 9/ 6 00/A 2-C493) -- *iZA.. 001? , + iijr.ooci^zLAZ6> A OjX] 2.^ V *_ -5^ - 6 = / 52. Jp) -<1^Qa,i i-t- CV^/i.V tJit -^i> v)>-in~ L\) ~"9 79>*^ >J ^ - tS1 F - I9<3^ \ioC-i|^5^(,ooz3N)-(-/qC. I^A +- 77 Coo/A r /f.o?q W i9S^ Cc/ ~ +- i - t ^ ^ \ + ,^ 6?~i1 -2-M X 3 k 3 x --^ofo--o - S n- ' r^'j C^. Don--4 3 A^kv/ i m'ttC/I S' "Steams* oJ - 3>U>c>,e~ ^ = A5 F r /*##<. Frsv C-2 -aae ay C-necked By Cate Page o1 ^5?zA _ 3A?rr7 6.5/ stA JLA:V 30W- 'tzaoo 7 SAL 000005585 Conoco Inc. Calculation Sheet Title Job No Field State + 3Pe-for r. <- ,V1 J 3 CjLo 4 1+9? /''tPOOft. ^rnC.eA^S LA* f-* - Vn/~ C t_\l = 3<4 o 7'ri/n T - 3oj P ^ /p`/i C. ' \(oc = . c^\l^)+2sz(.003g) * 3l{oao5i}i ^ 3 U. 2-M V 3/5 >c ^ Lp .ul ,00/3'} 1 / ',%'u + 'U N f O^cr^ V^l ' 24a | S CO - St ' ri7l/e,yl F = /x3 l P ~ </v e -x Voc - ; ,00'^"* Ke>f. 0033") -+- l(.i+) *f /23! f.oc/a A^Li(.a^ \!,074^)^ Lcib) * A(. ZjS} ~j - 3.2 2- =^_r "3 . f * 7 = .V ^*+ X 7S * 2000 " O 5 It "1^7 /.3o?^/ ) = 3-^2- *34 - 7 = \'7Z3 ;U^; ll 2. Qs^ct^ _ ____ _____ \)J= 238* <_>/ " (?^/iJa) - -- --.- f' - /k ^"7" ^ -- - P " 3 7// Voc' ^2 3 5f com'} -t 3f- 09^ t 30Coq2-S^ "1 C-I9\ ^ /fczTtPW) /fV.ooosi) t- 3r.0ZC.V7 2.4* 31^5x2^5 ~ ~7 ~ 3.0 52-tH ^u(.dso) J --- -; :ade By CoacKea By Ddte Page of Title Conoco Inc. Calculation Sheet Job No. Field State SAL 000005586 /jdO Po*-tr VV ' r- 7 00 I/0C ' ?,(,0*4') -t ]/oc - A oy -Tv*y (j9 {,Co/j) *, Z V ,, 7/~ -- --7 < PPCcS?*-' -r *U 0*-i & *zf S'7/?C/9'^ S -- Pcr4 GrsffO J c*c G*fSVj ftyt G<*fO t OfCfPCj f<*ot Ovtfr; *JP-y <i/ -1/1/ r r <2 = f1 z / <??7 /007 /oo'/t? f &6r Voc = / 9 *`k(^0O?fzLf y*{./9) 7*" TTo(^ooS'A) + *?*( j(.09f) + 9 fC?26) t j(\%) * /.?(*,a/t>) + (,io)-t- ^GCrCoo/^) x J2V x/^r ^ ^2^ aO -r ^ "2.0 > CG ^ ^ sJ / l/ 0 C '- 20,LC -rPy ade By Checked By r Date ^age of Conoco Inc. Calculation Sheet Titte SAL OOOOO550T Job No cield State \//>. Po /z Pte cS -SR_<s I OLU^(S EtaA'c (S^/v^e^tf C YC, <- o >VOr x /5v AJ Xrc^5 - S' Tv/scvd d <_> ^ o*/fc P^arc^^o Cc^A^A/e ^4/^PHTN/\C. *s < fclPH&Wl^ (2. j2 u p e So c/-%/. /? .5* <5^ DtSfet /. 5 o. 4- O. I S I . G. O. J.9. 0,0 e>o 7 p- 0 J 3 O. 0.3 33 O. oo45 o. 0153 3.4- jes^.,2 0, 0 7 I O. O O 3 J- ,, . ..ade 8y Checked By Date ________ Page ol Title Conoco Inc. Calculation Sheet SAL 000005588 Job No. Field___ State Jo /VL ( C~t;/vs <s L- Si/vc O* li GKSZCASe sEU^/'/'TL QC*j2 C** O x yz-c*** /> J x yc<r--'c; x yc <Tc / -?C *~*Oo c c*>v^7 r/c 2? ^c:<rt' t/cxJ>^cj- 9/2 -TJV 93 2? i?0 /S 3 fosz T" CCcrZs D/P/Jk f l^i i SAL 000005589 o P Qyxi tu 5 L. A-htC C3 CstPPco - *>0 t c */*/*&& -- *? / 3 O 7c 1/<5C - C;?25^X .<^07 c-ff ) y- C?/;? X ,07^) /V>? /'* GS- <~c * '"'* * jt&T o*}'~ p ' bw *> y* j<c/o 1/0 c - ^3^.9 ^/=y - t: tp y GP Voc x coy % * V, A rs?c tv*, s TOc/ /V72 ~* *$r'9o '!3c5'*j2 C-t o' - 76, 7 x * lr = , vr6 ypy JOQ 3**f 9/3 < /&C u G<-> fc' - A$c,<r < .79 * /o 0 3.Y - .-?6 7 ypr Tt/YCr*jZer*ser - 9A ft. * / K J_ 3, y . . <>vv ~r/r SY?-X7'c<r^ r ......... . .... 7 --. . / P~ X X<L T-> <r _. - Aifc.7. -- X.97 it 9_ to# t. y .2? ,t)G X ti? f. Y = .07 r T/?y 'r/r J"3y ?? /ra ^7 'ade By Checked By Date page of JM.? > ill / v& /4PPt n Q\x - J -- ,ov&r y/*r IY e f=oa. CO /vi Pos ' T-fOA/ OAT# 9J Conoco Inc. Calculation Sheet Job No. SAL 000005590 Title Field State w O' **7 c? Pr- dy c c cj /sc> c (P/^/ec^r C- ' 2g6. ? x *19 .OC/f - ,00 $? ~r/aY' /oO 7. s' i?C. 9 * * ,079? tod ~l7*r - . OOYo -rSr * Xic. 9 * y /, i /uo zy /, 02C, -rfy I rctf/y $ 2o$z .lado By Checked By Cate Page of Title Conoco Inc. Calculation Sheet SAL 000005591 Job No Field State C'O^eMc * L cMT*. J^vth XVla^a/ Kif\p>fr^(ALauc r"^~-------- ------------ ~^-------------v d^cn^l. 1; <St^caa C!oM>&smofM/ wJn~!f A4^vrrrtf^ewtr ^5^3313: 3cr PCap^. - ^fer- 5c!) M? 3. "t>csr^Cft.ut>^ CoMbeRVcre: KeRcsewe ^CC GrASbuMe 3 3 I 3 -c f ai -i '^) pc CKmYoS rpoAi Ac, ^Dk~tA MoTC ', Osc "TTKS FtsR ^AdcjESS "l>Lf\>M^ vAn~7r, CsCuoHc/AMe jctueW^T fTrVr-jJ^OJ'ZcMO V/LCMC "P" UMC (> yWoEU-e ^ CvjKewe ^T^^scobo'Cowewe N^TwnVfSi-CAie SriRGWG" 3< ?*rt=NYc. C>.-7t. 0.7<? 0,2$ 0.^7 C>.2.1 0.2-=) - 7? O./sj 0.0/ 4- -+ 0-05 Men ~ ^^nnrt6592 "THcsc Fiao^v A Cobe Mu%-roe~ Bcrr SHou-Lb f2>~ CtoSF, Xio )>ATA CM ^iA'FwfV-CMr 4 a^omc ScMcrfjtx.\$-~ Lpcnr^ . FVo^-r CHn "m^c VOITH TSC. +- Ftej^A Tc vUfnvte FbtfL. 1>>i\JcR P\r^T Ro>oit. ~7o UBS/v* Cx ^-4 ('-i x*> r% - 1"1>CC (5-0-5 Pu<J T/l/C. //cr-o 5 J) /- 7V/V<: C*~> /'s?oJP'y' c-^c 2>lo 1 Si5<l SAL 000005593 f-- i-- /v rs e. L^K<S ^cc' ^ /~"t>ec C<??S t-o --J> 3. J T P Y tfV*1 ^ T>v? pco^VLe^t: - ET~t " 2 3-/? V / Li 0 r 1 t 1 ^ -rot~i$/'riz 2*3.7 *-n3.rL0 -- 0.& 5 TrOAvs /v e ^ l U 1*0 Pso Pc/?H|*T APPCiC/V-p^C/w t/r^/O Oz l2cv/ Cw ' ~7W 3c. -1- ^ f3sG,< }3 dde By Checked By Page of Title Conoco Inc. Calculation Sheet SAL 000005594 job No Field State I--Iea-tC/2 3 C? ~TO -TA <-- PRop Cc^O r^~--T// y 4, 4T-*-' Cc/ ^ *7 Wr 7* - .5 r 3. 6 l--Al<c CP W /a T2. \_ (T J Fqom T2m_>_ P^-- 5w HAtCi35 X /4v$ ^ VMvti/H<L/X-rt* fjC<J\JC4 VOC PlO^froA'^ \/4CISC -- "To V/>C &-* l/stC-tSC* -+" Ti? ^ i/^4.scs {?o/* <?* <t &/4f &S stTX&CASrj ye- t,C. mco/To/is**4 30 * 3> -i- IOZ ~t~ 165 -- 14 32. vu* 36 (W* &*o*+s ~r^9^tr) -- es - / VJ 2 ,3.<: - SSS F"C--*- <J fi tf ./ VACU'C ' * l^rrt/ffso^j f"#C 'T'o/t (T/Mftt ~f J -f f~^*->4Cf X (*~t/Xfso y /sfC-Te^ -- -r/*"* Cr OSJ Sfr-***"^ /4 3;?<f,/;0 ^ x 3(o (.oot&) * IIS.S tpy Etm^cmu " =.'<t'. *7 Y=-r v '37^? 0 itsl 25/^ PoPYtrez<* a r x .osC w-r %) -5. 8o -r/=>r x jjjj Q-S: U iR=1 laao 3y CnecKea By : Date Page of Title Conoco Inc. Calculation Sheet 000005^5 sM- job No. Field State TABLE D-l, AVERAGE FUGITIVE EMISSION FACTORS FOR THE SYNTHETIC ORGANIC CHEMICALS MANUFACTURING INOUSTRY (SOCMl)a Fugitive-emission source Emission factor (Ib/fi) Pump seals Light liquids Heavy liquids 0.11 0.047 Valves (in-line) Gas tight liquid Heavy liquid 0.012 0.016 0.00051 Gas safety-relief valves 0.23 Open-ended lines 0.0037 Flanges 0.0018 Sampling connections 0.033 Compressor seals 0.50 3 Emission Factors for Equipment Leaks of VOC and HAP, EPA-450/3-86-002, January 1986, Table 3-4. These factors take into account a leak frequency determined ffom field studies in the synthetic organic chemicals manufacturing industry. Light liquids have a vapor pressure greater than 0.1 psia at 100F. 00QS596 0-2 TABLE 0-2, LEAKING AND NONLEAKING AVERAGE FUGITIVE EMISSION FACTORS' FOR THE SYNTHETIC ORGANIC CHEMICALS MANUFACTURING INDUSTRY (SOCKI)3 Fugitiveemission source Leaking (>10,000 ppm) emission factor (lb/h) Nonleaking (<10,000 ppm) emission factor (lb/h) Pump* seals Light liquids Heavy liquids 0.96 0.85 0.026 0.030 Valves (in-line) Gas Light liquid Heavy liquid 0.099 0.19 0.00051 0.0011 C.0038 0.00051 Gas safety-relief valves 3.72 0.098 Open-ended 1ines Sampling connections 0.0263 0.083 - 0.0033 L00'^ _ Compressor seals 3.54 0.20 a Emission Factors for Equipment Leaks of VOC and HAP, EPA-450/3-86-0P2, January 1986, Table 3-3. These factors take into account a leak frequency determined from field studies in the synthetic organic chemicals manufac turing industry. Light liquids have a vapor pressure greater than 0.1 psia at 100eF. SAL 000005597 D-3 SUMMARY Between March 3 and May 28, 1987, PEI conducted the fifth annual Volatile Organic Compound (VOC) fugitive emission survey at the Conoco refinery in Westlake, Louisiana. This Is the fifth consecutive year that PEI ;has conduct ed this type of VOC screening program in this plant. The survey Covered all the required VOC sources including vapor valves, relief valves, compressors, liquid valves, pumps, and process drains. Tables I through 6 summarize the screening results. Each table presents data for a specific source type (vapor valves, relief valves, compressors, liquid valves, pumps, and process drains). Each table shows the yarious plant units, the number of leaking sources, and the total number of sources for the fourth and fifth year annual screenings. Because of continuous changes in the refinery and the ability to locate all the sources, the total number of sources in a particular unit will change slightly from year to yeqr. The data show: Q For vapor valves, 105 leaked out of a total of 4,119 (2.155 percent). 8 for relief valves, 4 leaked out of a total of 136 (2.94 percent). 0 For compressors, 0 leaked out of a total of 18. 8 For liquid valves, 196 leaked out of a total of 7,270 (2.70 per cent ). 8 For pumps, 9 leaked out of a total of 245 (3.67 percent),. FoV' process drains, 11 leaked out of a total of 2,971 (0.37 per cent) . The above data indicate that there were a total of 325 leaklnjg sources out of a total of 14,730 sources. Thus, the plant leak rate Is 2J21 percent (325 * 14,730 x 100). SAL OOOOQ5598 V TABLE 1. VAPOR VALVES. Unit A1kylation Tank Farm Crude Unit No. 2 EFS PBC Boi1ers No. 2 Reformer Cat Poly FCC Unit Amine Units Fuel Gas Acid Plant No. 1 Coker No. 3 Reformer No. 3 Amine Sulfur Plant HDS - Nos. 6 & 7 Hydrogen Gas Recovery No. 2 Coker Therma1 Feed Prep No. 8 HDS CRYO No. 3 Vacuum Calciner TOTAL Fourth Annual screening leakers Total 6 35 1 83 0 153 14 312 3 80 5 157 0 342 16 88 nk 197 0 39 3 54 0 70 1 261 9 401 1 40 1 80 6 97 13 424 2 114 0 290 0 93 0 20 0 70 9 247 * ** 92 3,747 * Unit not operating **New NSPS Unit. VI Fifth Annual screening Leakers Total 0 45 3 100 0 147 7 385 1 78 6 186 3 350 0 95 0 227 2 40 1 54 3 70 5 261 0 409 0 40 5 80 6 89 14 415 18 128 3 288 2 93 1 20 2 BO 8 216 4 125 11 98 305 4,119 0000*3 1 TABLE 2. RELIEF VALVES Unit Alkylation Tank Farm Crude Unit No. 2 EFS P8C No. 2 Reformer Cat Poly FCC Unit Amine Units Fuel Gas No. 1 Coker No. 3 Reformer HDS - Nos. 6 & 7 Hydrogen Gas Recovery Thermal Feed Prep COR No. 8 HDS CRYO TOTAL Fourth Annual screening Leakers Total 02 0 12 01 02 0 10 08 09 04 02 03 02 04 05 0 32 05 05 01 02 02 0 19 0 130 Fifth Annual screening Leakers Total 02 1 13 00 02 2 11 19 0 10 06 03 03 02 04 05 0 31 05 05 01 03 02 0 19 4 136 ooooo^0 sM- vi i LU. 1 TABLE 3, COMPRESSORS V Fourth Annual Fifth Annual screening screening I Unit Leakers Total Leakers Total Alkylation 01 0 1 I Tank Farm 22 0 3 Crude Unit No. 2 1 1 0 1 I EFS 01 0 1 No. 2 Reformer 01 0 1 I No. 3Reformer 03 0 3 FCC Unit 01 0 1 I No. 1 Coker Hydrogen 01 0 1 02 0 2 4 Gas Recovery 01 0 1 CRVO J, _3 0 _3 TOTAL * 4 17 0 18 Unit not operating. 4 4 m 000005601 SAL TABLE 4. LIQUID VALVES Unit Fourth Annual screening Leakers Total Fifth Annual screening Leakers Total Alkylation Tank Farm Crude Unit No. 2 EFS PBC No. 2 Reformer Cat Poly FCC Unit Amine Units Fuel Gas No. 1 Coker No. 3 Reformer No. 3 Amine HDS - Nos. 6 & 7 Hydrogen Gas Recovery No. 2 Coker Thermal Unit Feed Prep CDR No. 8 HDS CRYO Calciner No. 3 Vacuum 22 142 11 16 34 15 50 27 1 1 1 29 0 10 11 10 0 6 7 0 9 5 * ** 360 2,239 228 367 473 368 374 675 101 49 80 306 2 192 285 393 164 141 131 120 206 235 ** 12 48 6 5 19 26 0 0 2 1 1 0 0 7 5 34 4 2 3 0 4 17 0 0 360 2,307 221 336 473 358 373 702 91 49 81 314 2 188 293 387 164 141 13 119 0 168 39 91 TOTAL 407 7,489 196 7,270 Unit not operating. * ix SAL 000005602 TABLE 5. PUMPS Uni t Fourth Annual screening Leaker? Total Fifth Annual screening leakers Total Alkyl ation Tank Farm Crude Unit No. 2 EFS PBC No. 2 Reformer Cat Poly FCC Unit No. 1 Coker No. 3 Reformer HOS - Nos. 6 & 7 Hydrogen Gas Recovery No. 2 Coker Thermal Unit Feed Prep CDR No. 8 HOS CRYO Calciner 7 15 3 3 2 3 2 10 2 4 0 0 i 0 2 0 0 0 0 * 17 0 79 1 72 14 1 11 1 11 3 70 24 0 40 14 0 60 40 15 1 10 0 20 30 70 20 70 *0 17 SI 7 14 n 13 7 25 3 14 6 4 15 10 2 0 7 0 5 4 TOTAL 54 244 9 245 Unit not operating. X oopo^60' $tf- TABLE 6. PROCESS DRAINS Unit Fourth Annual screening LK/I.K No Cap/Cap A1kylation Tank Farm Crude Unit No. EFS PBC Boilers No. 2 Reformer Cat Poly FCC Unit Amine Units Fuel Gas Acid Plant No. 1 Coker No. 3 Reformer No. 3 Amine Sulfur Plant HDS - Nos. 6 & 7 Hydrogen Gas Recovery No. 2 Coker Thermal Unit Feed Prep COR No. a hos CRYO Calciner No. 3 Vacuum TOTAL 2/11 7/12 2/2 2/3 0/0 0/1 0/0 0/3 1/2 0/1 0/0 0/0 0/0 0/9 0/0 0/0 0/7 1/3 0/0 0/0 0/1 0/0 0/0 0/3 1/0 */* */* 16/35 34/102 281/368 31/87 62/121 22/115 5/49 17/124 32/75 50/165 5/28 2/20 5/9 13/54 14/181 3/7 1/6 13/55 56/150 34/89 21/158 10/51 15/21 10/19 0/74 7/110 V* */* 743/2238 Fifth Annual screening LK/LK No cap/cap 0/0 31/105 2/0 275/346 0/0 31/88 0/0 64/121 0/0 22/109 0/0 5/50 0/0 5/128 0/0 30/76 0/0 49/168 0/0 1/6 0/0 2/20 0/0 5/9 0/0 13/54 0/0 17/183 0/0 3/7 0/0 1/6 0/1 !2/5< 1/2 52/153 0/0 35/88 0/0 21/159 0/0 9/52 o/o 15/21 0/0 10/19 0/0 0/70 0/3 5/106 0/0 Q/7 0/2 q/26 3/8 713/2229 Unit not operating. xi SAL 00000560A t /44(o Si^7 /(047 Unit Alkylation Tank Farm Crude Unit No. EFS -? /93H b70 PBC Boilers No. 2 Reformer =0 7 29 75 Cat Poly FCC Unit Amine Units 37, Fuel Gas Acid Plant 1 | No. 1 Coker ' No. 3 Reformer No. 3 Amine Sulfur Plant <. r1 .r1 'i1 -t^DS - Nos. 6 & Hydrogen -Gas Recovery ; / r No. 2 Coker -) Thermal "/ Feed Prep- \ Total 5FT 3,125 495 923 704 241 864 591 1,178 141 128 84 415 944 52 87 TABLE I CONOCO, INC. LAKE CHARLES REFINERY ANNUAL MONITORING ESTIMATE C OUWT - TO Vapor Liquid Process Relief Valves Valves Pumps Compressors Drains Valves T7 r ( ('2H) T3T T 10O'-- 27307^' 81* Qco/ti) 3 621 13 147 ----- 221 * 7 r L-r?/*H) C3/t) 385 336' 14' itlZ/liS) (7//3) 1 v 119 0 185 2" 78' ( -47^ C fijo') 0 131 11 186 ^ 00 55 0 350* 358J> 13 \ <*S 133 9 95" 227" 40^ 54 70' 261 r 409 40 80' (3? 3/s) C Jo) _702 hA. " .ar0 00 811 (>7/yi) 314 (-23^1, (^0) 0 3 ('M l4 0 0 l1 C*') 0 0 0 (*) d) 0 0 106 10 217 73 22 3 14 0 67 2 200 4 10 0 70 352 89^ 188' 6, 0 (>2h/ki) OM 950 415 293/. 4, , 2j (&3/=) Uh) 659 128 >9 387^ 151 '(?*)'<) Qtff) 642 288' (34/50') 0 302 931 141\ 2\ 0 C/O^b) 70 20 13 0 0 (!5/o) 64 5 205 31 123 5 180 61 36 SAL 000005605 TABLE I (CONTINUED) CONOCO, INC. LAKE CHARLES REFINERY ANNUAL MONITORING ESTIMATE Unit CDR . ,, Total 158 No. 8 HDS 152 CRYO 522 Calciner 148 No. 3 Vacuum 242 Vista Returns(l) HAD System 99 TOTAL '-----^14, 829+ Vapor Valves 0 80'' 216s 98' 125r 0 0 4,119 Liquid Process Valves Pumps \VP~ r Compressors 0 Drains 1 29 0" 0 0 70 ,{1l&68o';) Osh\) 39 4" Lb3)J 0 111 7 Relief Valves 3 2 19 0 91J 0 0 26 0 ?Q 0 00 C 99 0 0 __ 0 0 7,369+ 245 18 2,942 136 Note: - - * i_ 1. Unknown quantity of sources; however, number of sources expected to be less than 20. r- - y. EPA6: RDT-01-19-88 00 Appendix j- lo^OiNG- uoss vcc. cauzulat/oNS Conoco Inc. Calculation Sheet Title SAL 000005607 Job No. Field State 809900000 1VS Oi Zf S( b Q It 6sr h A/ />< / t 1 OO ( " - - - OO^^SfJ P US /"Vp J r1>A x d >/ * / /J ?r*r>~p^ y (J ?s*P2r3& 7A/ts. Tp 3> nno j .9r>'J7'Zryr?ij "7 A (9 / l_0AO/*>6 Lost* /-/}*? (Pr^/sccj- CO Cst/isot,/*** Co+Ji. * Pc* OOt J2V7.P /vt wc {L->} C/7,C~t rw/ P, 7^0 Jco 2 ^ /* 7*# C ' = . v/7 -/?/* -^f3? = /,?;; Tor/>c VOC - tO.&2 tPy VVC. x W7 7* x V Pt cc**er * looo ~ t-~f3s/ynr TL<tV'2cr*>e- = /(J>.6p x !,0C X JiT y J?0<5? = /(JO 6, Z w ^/?j"/V>e OotVCog - iO-6l 9? X y <4 2. " lofr'ic ^ej/'rx. ilTz/yc gc^-z r^c ~ i 0.6*7 * /? < '* x Ze'OU / - -&r/f/L_ _ 0-YYcc-*jc = /O.C? . P.7 * xil X Xueo /oo C.x. = /*/ 77 e-Os/y* /7'7* /^- x r C <7^ f C~"r#c^ a . - /0.6Z. K ^a K _d 61 x JLOOO ' f0.6 l X. 1,7 < js x ic^<? /Ott C. 2. - Z6-./2. , --1_ H .6^7 X X(J9(J 2 - P&o*/ <~<zr/y# - f/.Of (--fj^'r/2 - 3.3/ <-ef/y* C^> ' to./tz. .1X x XO4G> I vd 6. t fsc^t^o CcSs*-r 1~*JC ' fO.$L -* 2_ > ,0??/ X 7 0 0O /(JO 6 * 2- iaae Bv Checked By Date Page of Conoco Inc. Calculation Sheet Title ' -?. /A t-4f/y*. - P7, ^7 t-gr/y* Job No Field State SAL 000005609 ems Pieid on qor 0T9S00000 1VS *aaqS uotjB|no|eo 0U| ODOUQQ u*i jo a6sd ejRG Ag peo3M0 Ag opei- v</r*7 Zh'3 IS % ' - cp *. >*/fi-> is'io = X7 &To y PI*' /tf' " JSAJf ^ /o' *--jsAj# -- x j?4/i4y-r *'7 ' <?' * JSAJS ; `"'V >*/#-> l's/ - >///>-? ~5C%Of - *' ' IT. x 0' * - * A 7' * ~JJA_S - ^ -* ~U/ ^ x-o zozi - -*a/s#~? -6 &'?C3 - ?4,/j-O? bZ'bblj - * 4t<7' * JSA*3% - S/37 .* j r * rsAss - ?J2~ x ^'/ ?G>' > TShSJZ, - .s> Zrj>J 9A-ytt//t5_y ?, > / Ca 9*^*0 tsOy 3 5></c/y! 4 ^' ? = saoo 1 * (yo` ~^X./? -- y+/s&-> -5At (fJSHO 2 //^ * SAOQ ' X C^' 2^ - JSO-? O <z> `Vyys?p? 3^7 7 7/ -fr-jc ^y<? 7> "'Ot/O A UDDDDDDDDDVDDDDDDVUBD D:' 0 P L' 0 1 P,~ 0 V1 ' P P. Pi'DPPDDDp COO ;00 LN I S3 i UN ChLOULh i'TONE TRUCK RACE! LOADING v053 r DA ' L : ME. F E ;-c i. :.j L1 ' NUN f H , r R : MONTH,VR i... O L, A i - UN - "J : N ! SOURCE L.D.. 4 MA I Eh . f-iL hiANL'L.b.L' i HR...PUT ibhhi) ''KU EFFICIENCY A.) STAR ! EMC Ov -Apr-v:! : EEC. 1937 lake: Charles LOAD i No ! AL.K GASOLINE LOADING LOSS MOLECUl-AR WEIGHT Mv - >? EMPIERh LURE -F > HH!'i . ! .7 H ri;: S '> \> p r!P !) p p p Priri '/p pp A' P v Kr A' ,'v //HPP ri p p ririP P Pp MP P P P PPP P 10;: OS E:'M Cap a2 70 pprrp 1 i r: ?*' y. ~ ! > p a Vi p p p p p r. / r; n p 'DDDDDDDD/)DPPp!' PPp f:PP LOADING LOOS MOLECULAR WEIGH!" i lMPBRAT ORE ( F ; VAPOR PRESSURE ;P5ia) H m T U R A T 1.1j N F A C 7 O E Mv - F == S UNCONTROLLED EMISSIONS (ID CONTROLLED EMISSIONS ilb; *** LI == 10a78*3 LI - LI * ( 1 -s+ f I _>N > - 21257 "ALT] :: TO PRINT AND/OR SAKE p p p/' /.; :*pp p ..t p p/.f /.r p yi p p p p p p p // p p ppp p,.ip pppp rt pp p ppp pp p pppp pp p pp u, p p ppp p p SAU 0000056H VuC EMISSION LhLl ULh T I DIMS TRUCK. RAoK LOADING LOSS Oh 1 F T' I ME PER I DO : MON TH , YR : MUNTH,VR LGCA I I Oi l POINT SOURCE l.D. # MA i'ERiriL I-imNOLED 7HRUPUT (bbliO VRU EFF I C l ENC r (*/. START END C1.1- M<s v'~&8 >j AN ,, X 987 DEL., i ;/o / L.AKE uHARLEb LOADING RACK kerosene 708000 98 LOADING LOSS MOLECULAR WEIGHT TEMPERATURE kF > VAPOR PRESSURE ipeiaJ SATURATION FACTOR Mv = T= P= S= 1 30 70 o .oil l UNCONTROLLED EMISSIONS : 1 b i CONTROLLED EMISSIONS (lb) LI = 1000 LI = LI * L -eft /' 10 ''j ) = 20 VUC EHI SSI ON CALCULATIONS TRUCK RACK. LOADING LOSS DA I E TIME PER CUD : MONTH,rR : MONTH,YR LOLA TION POINT SOURCE I.D. # M A f E E IA L H A N D L E D THRUPUT ibbls) VRiJ EFFICIENCY (V.) b 1 AR r END - = - = = 20--May-88 JAN, 1987 DEC, 1967LAKE CHARLES LOADING RACK tOIESEL 1S710000 90 M Ci L E L l .11.... hE WEIGHT IEMPERA TUBE (Fj VAPOR PRESSURE idsia) GhTUKAI ION F-AC TOR LOADING loss Mv * P= 3 30 70 0.009 1 UNCQN TROLLED EMISSIONS (lb) CONTROLLED EMISSIONS (lb) LI = 21<bl5 Li LI * U-ef f / X 00) = *32. 70C EMISSION CALCULATIONS TftUuk RACK LOADING LOSS liA i E TIME PERIOD : MONTH,YR : MONTH,YR LULAIUN POINT SOURCE I.D. # MATERLAL HANDLED THRUPUT (bb'Js) v RU EFFICIENCY START END U O -- M crt V - O O JAN, i907 DEC, 1987 LAKE CHARLES BARGE LOADING 1 REFORMATE 423000 LOADING LOSS MOLE.CULmR WEIGH T "I EMPERATURE (F> VAPOR PRESSURE (psia) SATURATION FACTOR Mv -- T = P= S- 66 70 .2 0.5 11MClJN I'PLjLL..ED bli I SS 1 ONS (lb) CONTROLLED EM I 551 DIMS (lb) LI 85450 LI - LI * ( 1-e-f-f / IOC) - ^S4S3 SAL 00000561* P j cl*--'' r* -2% A* `Jooo <. 3 49 a* c -W>-3 1A3 ^'. 'N Nko _^ocLo-<^ - ^IR-J S^S7* ^codL ^Cr<l Q/^ooo J 0,000 >>C Mlgh /XT, _^|2xr-a_ f Gu^o ^ S / 2 tT /^oor* Ty J>" 'NT F*L *" \jf\\t CuF~ Ou.xjSl*o^_ - ^ForbdL 1 sal 000005615 ^ocxdLcnn^ (Kj c.: ) i)xpHrr.Uvj_ l.i lef.Ci')- . *1% Ihstur *cj * Cc'tfr . >' ~f |0,,#--r -' H - . ' o3)x xaiis - 3.0-3 lbs/ur .oo*? ' 3a. -,-V : ; :<Ai J - ^ <j_r' ) 01 7wl( > 5~)- u z. - lbsjs) /fek..'.55 " , 0t2>Z.TPY -Tibu.-i.'- 370^/ Lon^)(.4^ L.z~ ~ /9?,55 = .CVJ^TFf ifbcjl fescue -'f ('.CH'X, - lc, z. r H.25? * ^0% Tpj' = 3*10*14 (.VLb'y.M') 1*. z, - =?7. 55 r 0/35>T#'r \o~ ruU; ^ - 3~to^if (- .ooV-rpy - <:'...; 1. = ` ^O'Sb - .bicTpf ._/ ^ : * 3-^0- > : f.oi)( i./0 - i<?3 :r/ - 'V.c^i /) - ir,:^ ~ 3,^ ~ .001*15 s' * ^ - -+ - 3iO-'H i. 3','-"X .'i'l i / ~; .0 625 ivi'i Sh*t SAL oooog5616 7 p f p n n n n p a n p n r> p r> p np r>p n p r> p n p> p n BOPDDP P D D 0 D DD D V D D p p CP PDD D 0 D D D D pp D D V D 0 D V 0 P 0 D D D D n D DP'' 13 VOCEMISSION CALCULATIONS 3 TRUCKRACK LOADING LOSS 3 4- . DATE = 2 7--l"1av-B8 3 TIME PERIOD : MONTH,vR START i-= JAN, IS'S/ 3 c? : MONTH,YR END - DEC, 198/ V LOCATION - LAKE. CHARLES 5 i 0 POINT SOURCE I.D. # = DARSE LOADING 3 ). 1 MATERIAL HANDLED - KUafcWi 3 ) 2 THRUPUT <: b bis) i VRU EFT- ICIENCY (';> = V<.K..'0 A, =A IP: LOADING LOSS 18 l? CALIJ a .,7:0 LALT3 B molecular weight TEMPERATURE (F> Mv = T= 130 70 A 3 3 3 TMMMmiiMMNMttllftHttMMttMNIIMMmMMMHMMMMMMMilttMttNHMMtlMMtlMMMMMIIMHMttMNlINHmUINtttlMHHttHMAlU. 27-May-88 OVs32 AM LiapNuffi U1 ;>j D1 *: SHEET 31 > V P P D D D D A V DD D D D DD V D P D PD DD V DD B D V D D D D P DD DDDD D DPDDCPPDDD DDV DD P D DtiDDDDDDDD DV ODD DVD'? LOADING LOSS 3 3 iH LAL721 A CALT3 B MOLECULAR WEIGHT TEMPERATURE <F > Mv = r- 1 30 0 3 3 3 2) CALTJ c, VAPOR PRESSURE (psia) p= 0.0 1 1 3 22 l AL. T i D SATURA\ ION FAC TOR s= 0. s 3 24 UNCON TROLLED EMISSIONS (lb) LI * CONTROLLED EM ISSIONS (lb) LI :: Ll \ 1 -- + f / 1 UU ) A A '31 A a [ALTO Z TO PRINT AND/OR SAVE -7 34 3 A 27-Mav~88 09:32 AM LapNum At: SAL 0000056X7 SHEET 'r>A'lnjOP'DrA^PPtiD'DL>r,DDVDUPllDDOVDhlKn)VDDUPVDTd'ipDVDVDC.PDtrUVDuDDPDDD^DDODDDDVDUDP'PliJjL> 7? vbc'KTTTSSIQN CALCLlLATTOte- 3 TRUCK RACK LOADING LOSS 3 C? DATE - - __ 27-M&V-B8 3 *7 T I ME PERIOD : MONTH,YR START JAN, 1937 I ci 2 MONTH.YR END DEC, 19S7 3 9 LGCAT' 1 ON =s LAKE CHARuLS T D P V P 3 0 0 0 A D D 9 D D VD DD D D D D D 0 D DDDBDD D D P D D D P p V D 9 P D P D D C D P D D D D D P P D P P' PD D :1 p p p p 1 2 VOC EMISSION CALCULATIONS .3 TRUCK RACK LOADING LOSS 4 DP P^DPPPP 3 3 3 DATE TIME PERIOD : MONTH,yR START 8 : MONTH,YR END LOCATION PO I NT SOURCE I . D. # l I MAiERIAL HANDLED 5.2 THRUPUT t bbIs) 1 3 VRU EFFICIENCY C/.) 7 / -- f'lst y ~dB JAN, IPS/ DEC, J937 LaKE CHARLES BARGE' LOAD I N6 *iaSOL. 349000 I4 15 1. 6 LOADING LOSS i/ 18 1. ? CALT 1 A MOLECULAR WEIGHT Mv = I3v C ALT1 B TEMPERATURE <F> T= 70 ItlMMl'IHNMMMNMNilMNMMMNNMNMMttMMHMHMMmiNttMHMttMNMHMMMMHMMHHttHHHHMMHMMHMHNHMMMlMAXM. -Mav-88 '.'9:35 AM CapNiim SHEET ' .0 D P P D D L'> D A D D l' D !J D D V 0 DD U D D D D P> D P> BD D P> D DD DP>DD V D D P D D l> D C D D D D P* D V D D D L> P> D DDl>DDVDD DEPDDDDDDD? 1c LOADING LOSS i7 lA [ALT! A MOLECULAR WEIGHT Mv = l 30 CaLTJ B TEMPERATURE (F> 7O [ALT :i C VAPOR PRESSURE CpsiaJ P= 0.009 [ALTJ d SATURATION FACTOR 24 UNCONTROLLED EMIS3 IONS (I b LI 73 CONTROLLED EM ISSIONS (lb) LI = Ll^d-eff/lO1:.') L ALT I 2 TO PRINT AND/OR SAVE 34 35 ***************##***** 2?-Mav-8B 09:36 AM CapNudi SAL 000005618 Do: <U1) NOW SHEET l> D D D D DAD DDDDDDDDDDD DDDD DDDBDD 0 D D V D D DDDDDDDDDDCDDPDDODDD0DDDD DDDDDDDDDDD iPDDDD? 1. 3 2 VOC EMISSION CALCULATIONS 3 TRUCK RACK LOADING LOSS 3 43 .J 3 o DATE -- 27--Mav-8S 3 7 TIME PERIOD : MONTH,YR START = JAN, 1987 3 0 : MONTH,YR END = DEC, 19S7 3 9 LOCATION LAKE CHARLES 3 1 O POINT SOURCE I.D. # = BARGE LOADING 3 1 1 MATERIAL HANDLED iftfttOttIMli* 3 3.2 THRUPUT (bbls) = 20600o 3 3 3. VRU EFFICIENCY ( 7.) = 03 14 3 15 3 16 LOADING LOSS 3 1/ 38 3 19 lALT J A MOLECULAR WEIGHT Mv - b2 3 20 [ALT'.] L-s TEMPERATURE (F) T= 70- - 3 " '7 --Me^y "88 09 : 2 8 AM Num T SHEET DDPDDDV ADDDDDDDDDDDDPDDDDDDBDPDPDDDDDDDDDDDDDDCDVDDDDDDPDDDDDDDDDPDDDDPDDDDDD. lb LOADING LOSS 3 17 3 IS 3 1 9 r. ALT 3 A 20 t.alt: 8 21 lalt: C MOLECULAR WEIGHT TEMPERATURE (F) VAPOR PRESSURE (psia) Mv = T= P= t2 70 6>. 2 3 3 3 4- *2 calt: D SATURATION FACTOR b= 0. 5 3 24 UNCONTROLLED EMISSIONS (lb LI = 39094 2 b' CONTROLLED- EMISSIONS (lb) L. 1 = LI * ( 1 --ef f / 1 00 > fo ro ********************************************************* [ALT: Z TO PRINT AND/OR SAVE 3.4 33. ********************************************************* 2 7-Mty--B8 09:29 AM 000005619 SAL Num \Apo m. & l5u. jaijs 5 E^SlA_._ f2> eAJZ<C5A/< 1 E~~r^ryc. (C Tcco A/CfxAJ<S XVLve.55" TV/2CV6 Pscuno Ccs/*.J1A/G ^i/xPH~r e*s s 31 Ph e- ^>rc^ d &U DtS, (ztSX So C/A./<L C?kJ..__ O/^r^fc ............ : , .. . /. 5 o. 4- O. 18 1 - <2> 0>. 1 3 .. O. 0 96 7 O.O^j3 0.03 93 O. oo4 5 O- O; 1 SL3l_. 5.4 j <s. .2 .. O. QJ .I O. O. O 3 /-> ____L -- ade By - Checked By 2 Date Page of Conoco Inc. Calculation Sheet Title SAL 000005620 Job No. Field State