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Loss Prevention Bulletin No. 36.10 PROPERTIES OF FLAMMABLE LIQUIDS, GASES AND SOLIDS FACTORY MUTUAL ENGINEERING DIVISION Main Office: 184 High St., Boston 10, Mass. Copyright 1950 by The Factory Mutual Engineering Division DSW 587850 STLCOPCB4093186 Page 2 No. 36.10 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS This bulletin gives pertinent data concerning the fire and explosion hazards of flammable liquids, gases, and solids found in industrial plants. The table in this edition includes more than 200 materials not previously listed as well as additional data on previous listings. Values pre sented are for information and general guidance only and are not to be regarded as official standards. The data on flash points, auto-ignition temperatures and susceptibility to spontaneous heating has been assembled mostly from the results of tests made by the Factory Mutual Laboratories. Most of the data on explosive ranges was obtained from publications of the Bureau of Mines, but some material was obtained from other sources. Data on boiling points, melting points, and specific gravities were obtained from publications of Carbide & Carbon Chemicals Corp., E. I. du Pont de Nemours & Co., Commercial Solvents Corp., U. S. Industrial Chemicals, Inc., Dow Chemical Co., Sharpies Solvents Corp., the International Critical Tables, the Condensed Chemical Dictionary, 1942 edition, and tests made in the Factory Mutual Laboratories. Samples for test purposes were furnished by the listed companies, by plants insured in the Factory Mutuals, and others. Grateful acknowledgment is made to all contributors for adding to the completeness and reliability of the table. Minor variations in flash point, auto-ignition and explosive range figures are to be expected even among most competent observers. Purity of samples tested may be responsible for considerable differences in reported results. In most cases such minor variations have little practical significance. In case of difference of opinion as to fire hazard characteristics of any specific com pound, tests should be made from a sample of the particular compound in question. The facilities of the Factory Mutual Laboratories are available to Factory Mutual insured plants for such purposes. Characteristics of Flammable Liquids . The use of flammable liquids in industrial plants introduces a serious life and fire hazard. It is important to segregate processes involving such liquids and to pro vide reasonable safeguards. Machinery and piping should be properly installed, adequately maintained, and intelligently operated. When new installations or changes involving flam mable liquids are planned, consult your Insurance Com pany in advance, and submit detailed plans for comment and approval. This procedure will not only avoid the possibility of expensive changes to reduce life and fire hazards after completing the work but may forestall the costly installatioApf some safeguards which happen to be unnecessary. State and municipal regulations and ordinances should be observed. A flammable liquid itself does not burn; it is the vapors from the liquid which burn. The rate at which different liquids vaporize varies greatly, depending on their vapor pressure. Vaporization increases with the temperature, and a flammable liquid at elevated tem perature is therefore more hazardous than the same liquid at normal temperature. Flash Point The flash point of a flammable liquid is the lowest temperature at which it gives off enough vapors to form a flammable or ignitible mixture with air near the sur face of the liquid or within the container used. Many hazardous liquids have flash points at or below ordinary room temperatures, and they normally are covered by a layer of flammable vapors which will ignite immediately if a source of ignition is brought near. Both closed and open cup test results are reported. The open cup flash point is usually somewhat higher than the closed cup flash point for the same substance. DSW 587851 - . -I STLCOPCB4093187 No. 36.10 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) Page 3 Fire Point The lowest temperature at which a liquid in an open container will give off enough vapors to continue to bum when once ignited is the fire point. It is generally slightly above the open cup flash point. Explosive Range (Flammability Limits) The explosive range includes all concentrations of a mixture of flammable vapor or gas in air (usually ex pressed in per cent by volume) in which a flash will occur or a flame will travel if the mixture is ignited. The lowest percentage at which thisoccurs is the lower explo sive limit, and the highest percentage, the upper explo sive limit. If such a mixture is confined and ignited, an explosion results. Many common flammable liquids and gases have very wide explosive ranges. That of carbon disulfide is 1% to 50% and hydrogen 4.1% to 74.2%, which shows that only very lean or unusually rich mixtures of these materials in air are free from an explo sion hazard. The explosive ranges in the table are based upon normal atmospheric temperatures and pressures. There may be considerable variations in explosive ranges at pressures or temperatures above or below normal. Auto-Ignition Temperature The auto-ignition temperature of a substance whether solid, liquid, or gaseous, is the lowest temperature re quired to initiate or cause self-sustained combustion in the absence of a spark or flame. This temperature varies considerably, depending upon the nature, size, and shape of the igniting surface or container and other factors. The auto-ignition temperature of a solid is in fluenced by its physical condition and the rate of heating. Vapors of several common flammable liquids can be ignited under favorable conditions by metals heated to temperatures as low as 500F. The vapor of carbon disulfide can be so ignited at a temperature of about 257F. Susceptibility to Spontaneous Heating Many flammable liquids combine readily with the oxygen in the air at ordinary temperatures and give off heat. When these liquids are present on waste, rubbish, or other material under conditions in which heat is pro duced faster than it is dissipated, the temperature rises and ignition may occur. Specific Gravity Most flammable liquids will float on water where they can burn freely and flow over a large area. A few are heavier than water, and water will float on them and extinguish a fire. The specific gravity of a flammable liquid is important, as it indicates the proper type of fire extinguisher, the need of overflow drains on open tanks of flammable liquids, and the necessity of other special precautions. Vapor Density Vapor density is the relative density of the vapor as compared with air. The vapors of all flammable liquids are heavier than air. This explains why flash fires in flammable vapors often cover large areas and travel long distances along the floor or ground, and shows that ventilating outlets should be located near the floor level. Many combustible gases by contrast are lighter than air and require ventilation taken from near the ceiling. Melting Point The melting point is important in those materials which ari solid at ordinary temperature but assume the characteristics of flammable liquids when in the melted state, such as naphthalene, tallow, and similar substances. Boiling Point The lower the boiling point, the more volatile and therefore the more hazardous a flammable liquid. Miscibility with Water A flammable liquid's miscibility, or ability to mix with water, is important since the flash and fire points of a flammable liquid are appreciably raised as the amount of water in the mixture is increased. It is possible to make flammable liquids such as alcohol and acetone, which are miscible with water, entirely non-flammable by sufficient dilution. These water mixtures are conductors of elec tricity, and charges of static electricity cannot accumu late in flammable liquids miscible with water. Viscosity Viscosity is definitely related to the fire hazard of flammable liquids because viscous liquids spread slowly when liberated, and fires in them generally burn in a much smaller area than in equal volumes of free-flowing, less viscous liquids. DSW 587852 STLCOPCB4093188 Page 4 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) No. 36.10 EXPLANATION OF TABLE The following test procedures have been used by the Factory Mutual Laboratories: Flash Point, Tagliabue Closed Cup................................ A.S.T.M. Designation D56-36 Flash Point, Pensky-Martens Closed Cup..................................A.S.T.M. Designation D93-46 Flash Point, Cleveland Open Cup.................... ...............A.S.T.M. Designation D92-46 Auto-Ignition Temperature..... .A.S.T.M. Designation D286-36 Susceptibility to Spontaneous Heating. .Factory Mutual Modified Mackey Method (I. & E. Chem., Vol. 19, No. 3, p. 394, March 1927) ABBREVIATIONS AND SYMBOLS The following abbreviations are not used in the alphabetical listing but are shown with some names to identify the compound exactly. . o -- ortho p -- para m -- meta prim -- primary sym -- symmetrical n -- normal sec -- secondary ter -- tertiary The numerical prefixes mono-, di-, tri-, and tetra- will be found in regular alphabetical order. d. -- decomposes > -- greater than sub. -- sublimes < -- less than *An asterisk following the name of a metal indicates that hydrogen will be liberated when the metal is in contact with water. With the exception of potassium and sodium, hydrogen will be liberated in hazardous quantities only if the metal is in a finely divided form. The properties of asphalts, naphthas, oils, fats, and waxes vary over a large range as indicated. When it is necessary to know the exact hazard of a material, a sample should be sent to the Factory Mutual Laboratories at 184 High St., Boston 10, Mass., for test. Flash Point. The approximate closed-cup flash points of hydrocarbons (organic compounds composed of only carbon and. hydrogen) may be determined by the use of the following formula: Closed cupflash point F. =0.73 x [initial] boiling point F. -- 122 For petroleum and coal-tar distillates, the formula is applicable in practice between initial boiling points of 100F.-550F. Explosive Limits. The data given for the lower and upper explosive limits are, with few exceptions, the values for upward flame propagation throiigh a cylindrical tube at normal atmo spheric pressures and temperatures. Vapor Concentrations and Explosive Mixtures. The follow ing calculations can be used to determine the volume of vapor pro duced by the evaporation of a known solvent and the amount of air required to maintain mixtures below the explosive limit. The computations are based on a temperature of 70F. and normal atmospheric pressure. In calculating safety ventilation, a large factor of safety should be used because of the difficulty in main taining close control over the conditions affecting the hazard. Recommended safe practice requires the operation of equipment at not over 25% of the lower explosive limit concentration. __ , . . 8.33 x Sp. Gr. Cu. ft. vapor from evaporation of 1 gal. solvent = 0^75"^ VD 8.33 is the weight of 1 gal. of water in lbs. 0.075 is the weight of 1 cu. ft. of air in lbs. Sp. Gr. is the specific gravity of the solvent (water = 1) V.D. is the vapor density of the solvent vapor (air = 1) .. cu. ft. vaporx 100 Volume of the leanest explosive mixture ---------- T p .--------- L.E.L. is the lower explosive limit of the solvent vapor in air expressed in percent by volume. Example: Calculate the safety ventilation required for a drier in which 1 gal. of toluene is evaporated per hour. Toluene has a vapor density of 3.14, a specific gravity of 0.866, and a lower explosive limit of 1.27%. 8.33 x 0.866 0.075 x 3.14 30.5 cu. ft. vapor 30.5 x 100 1.27 =2402 cu. ft. volume of leanest explosive mixture 2402 x 4 = 9608 cu. ft. ventilation needed per gallon of solvent evaporated For ah approximation for the amount of air needed to dilute the vapors from 1 gallon of common solvent to the lower explosive limit, 2500 cu. ft. may be used. Vapor Densities for the most part, have been calculated using the formula: . Vapor density of a compound molecular weight of compound 29 (composite molecular weight of air) Suitable Extinguishing Agents. The code numbers in the last column indicate the following extinguishing agents. 1. Water (See Note A below) 2. Foam ' 3. Carbon dioxide or dry chemical 4. See Note B below. (Gas fires.) 5. Approved dry compound for metal fires. Note A: Water discharged from spray nozzles bdhaves differently from water discharged from hose streams or from sprinklers dis charging relatively large drops. The finely divided drops from a spray nozzle absorb much more heat than an equal weight of water from a hose stream or an equal weight oflarge drops from a sprinkler. In geneftl, water spray nozzles are suitable for use on fires in flammablesquids having a flash point over 150 F., but before purchasingnow equipment, consult your Insurance Company or the Factory Mutual Engineering Division. In many cases, water from automatic sprinklers will control fire in flammable liquids. If water is applied to a tank of material such as tempering oil or asphalt, the body of which is at a temperature above 250 F., the steam formed under the surface will cause foaming resulting in a rapid increase in the volume of the liquid. Under fire conditions, the tank may be overflowed and the fire spread by this means. Foaming-over may also result from the application of foam since foam is largely water. To avoid foaming-over, specially arranged fixed-piping foam extinguishers are available for use on open tanks containing materials heated above 250 F. Dry chemical extinguishers may also be used and will not cause foaming-over. Note B: While carbon dioxide, dry chemical, and in some in stances, water spray may be used to extinguish small gas fires, the extinguishment of gas fires by these extinguishing agents is not generally recommended since the discharge of gas or volatile liquid will continue unless shut off promptly and may well create a more serious explosion hazard. Generally, the best procedure is to use water to keep the surroundings cool until the leak can be shut off or until the volatile liquid has completely vaporized. I.C.C. SHIPPING LABELS Red --Flammable liquids with flash points at or below 80 F. and flammable compressed gases. - Yellow -- Flammable solids (except explosives) and oxidizing materials (chlorates, permanganates, peroxides, nitrates).- White -- Corrosive liquids (mineral acids). Green -- Non-flammable compressed gases. Labels are required only for interstate shipments or for intra state shipments by common carrier engaged in interstate or foreign commerce. Absence of a label does not necessarily mean that tine material is non-hazardous. DSW 587853 E STLCOPCB4093189 No. 36.10 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) Page 5 NAME SYNONYMS FORMULA Flash Point F. Closed Open Cup Cup Explosive Limits % by Vol. In Air ignition Temp. Lower Upper F. Suscepti bility to Sponta neous Beating Specific Gravity (Water* 1.00) Vapor Density (Air ** 1.00) Melting Point F. Boiling Extin Point guishing F. Agents Aoetic Acid (Glacial). . . Acetic Anhydride . . . Ethanal Acetyl Aldehyde . Antifebrin........................ EthanoicAcid .... Acetyl Oxide .... CHsCHfOCjHs)! .... CH3CHO.................................... CILCONHCsHs........................ CILCOOH........................ ...... (CHjCOJiO.............................. -5 -36 104 121 1.65 446 4.0 57.0 865 345 1015 110 4.0 1050 130 2.67 10.13 752 No No No No No 0.821 0.783 3.21 1.05 1.08 4.08 1.52 4.65 2.07 382 -191 237 62 -100 215 3 70 1.3,4 681 1.3 245 1.3 264 1.3 Acetone.............................. Aeetonyl Acetone .... Aoetophenone........................ p-Acetotoluide .... Aoetyl&cetone........................ 2-Propanone Dimethylketone . . 2,6 Hexanedione . . Phenylmcthyl Ketone . n-Acetyl-p-Toluidine . . , . . CH3COCH1.............................. CH3COCH2CH2COCH3. . . CJLCOCHj.............................. UH3O&II4WH.UOUW3 . . . CILCOCHiCOCHa . . . . 0 174 221 335 83 15 2.15 13.0 180 355 . . . 105 . ... 1000 920 No No No 0.792 0.973 1.03 1.212 0.975 2.00 3.94 4.14 5.14 8.45 -137 16 68 307 134 3 378 1.3 396 1. 2,3 584 1.2.3 285 1.3 Aoetyl Chloride .... Aoetylene.............................. Acetyl Peroxide . . . .' Acrolein.............................. Acrylic Acid........................ Ethanoyl Chloride . . . Ethyne; Ethine ... . Propenal Acrylio Aldehyde PropenicAcid .... chsgoci ............................... CjHs.......................................... (CHiC0)20! . ... . . CH.CHCHO.............................. CtHsCOOH.............................. 40 gas 113 InfUmmi ble gas 2.5 . .. 80 635 Unstable No No No 1.105 1.18 084 1.062 2.70 0.91 1.94 -170 -66 54 124 -119 125 285 1.3 4 1.3 4 Acrylonitrile . . . . . Adipic Acid ..... Aldol.................................... Allyl Alcohol........................ Ailyl Chloride........................ Propenenitrile .... Hexanedioic Acid . . . 3-Bydroxybutanal . . . 2-Propen-l-ol .... 3-Chloropropene . . . CHjCHCN ...... COOH(CH2),COOH ... . OH3CHOHCH1CHO . . . OHjCHCHjOH........................ CH2=CHCH!C1..... 385 181 70 -25 32 3.05 17.0 898 530 75 3.0 18 713 -20 8.28 11.15 737 No No o.soo 1.11 0.854 0.937 1.83 5.04 3.04 2.00 2.64 -119 803 -200 171 3 700 1, 2.3 380 1.3 206 3 113 3,4 Allylene.............................. Aluminum (Powder) . . 2-Amino-l-Butanol . . . 2-Aminoethylethanolamlne . Ammonia (Anhydrous) . . Propyne ............................... Hydroxyethyl- , Ethylcnediamine . . CH3CCH.................................... Al .... ........................ CH3CILCHNH1CH2OH . . NH2CH2CH2NHCH2CH20H . NHi............................................. gas 285 gas 1.74 165 275 16.0 25.0 695 1204 No No No 0.944 1.030 188 3.59 0,687 -156 28 -107 -18 352 469.4 -37 4 5 1,3 1.3 4 Amyl Acet&te-n .... 1-Pentanoi acetate Banana Oil ... . CHsCOOCeHn........................ 76 80 1.1 Amyl'Aoetate-iso .... 8-Methyl-1 -butanol 1.0 @ acetate ..... CHaCOOCH2CH2CH(CH3)2 . 77 100 212F. Amyl Aoetate-eec. . . . CH3C00CH(CH3)C3H7 . . 89 111 Amyl Alcobol-n .... 1-Pentanol; Fusel Oil . . CH3CH2CH2CH2CH20H . . 91 120 u 714 No 716 No 621 No 0.879 4.49 300 3 0.876 4.49 290 3 0.862 4.48 249 3 0.817 3.04 -108 280 3 Amyl Alcohol-p. Uo . . . Amyl Alcohol-eecm . . . Amyl Alcohol-eeo. iso . . Amyl Aloohol-Ter . . . Amylamlne, Mono . . . 3-Methyl-l-Butanol . . 3-Pentanol........................ 8-Methyl-2-Butanol . . 2-Methyl-2-Butanol . . 1-Aminopentane . . . (CH3M3HCH2CH50H . . . (CHjCH.)2CHOH .... (CMjCHCHOHCHi . . . (CH3)2C2H5COH .... CsHnNHz.............................. 109 94 103 67 .... 115 1.2 102 75 45 667 650-725 No No No 0.813 0810 0819 081 0.776 3.04 4.04 04 8.03 8.01 -178 ... 270 245 235 215 215-221 3 3 3 3 3 Amyl Benxene-mono . . Amvl Chloride .... Amyl Chlorides, Mixed . . Amylene-n ..... Amyl Ether........................ 1-Chloropentane . . . Propylethylene .... Diamyl Ether .... CcHsCbHii.............................. CfisfCiLl.iCHjCl .... CsHnCl.................................... CH3(CH2)2CH:CH2 .... CeHnOCtHu........................ . 150 0.78-0.85 6.11 365 1, 2,3 55 1.4 550 No 0878 3.67 ... 223 2.3 38 :r(jj| 0.88 185-228 2.3 0 1.6 No 0.666 2.42 -191 08 2.-3 135 0.78-0.80 5.46 329-338 1.2,3 Amyl Mercaptans (mixed) . Amyl Naphthalene . . . Amyl Phenol-o .... Amyl Propionate .... Amyl Salicylate .... Pentyl Propanoate. . . C5H11SH ....... C10H7C&H11.............................. CsHnCtfLOH........................ CHjCHjCOOCjHi, .... HOCtH.COOCsHu .... 270 65 225 219 106 0.83-0.84 0.973 0.96-0.97 0869-0873 1.065 3.59 6.86 5.66 6.0 7.17 <-21 220-257 550 649 275-347 512 1.3 2,3 1. 2,3 1.3 1.2.3 Amyl Stearate .... Amyl Sulfides (mixed) . . Amyl Toluene........................ Amyl Xylol Ether . . . Aniline.............................. Aminobenzene .... CHj(CHi)iiCOOCsHu .. CiHuCelLCHa........................ CsHnOCsHafCHA .... OHeNlh.................................... 168 865 185 1 . 180 . . . 205 1418 No 0.860 0.85-0.91 No 0.87 No 0.907 No 1.022 322 1.2,3 338-356 2,3 400-416 480-500 1,2,3 21 363 2.3 Aniline Hydroohloride . . Anthracene........................ AnthrsQuinone .... Asphalt (typical) .... Benialdehyde........................ Aniline Chloride . . . Para-Napthalene; Green Oil Petroleum Pitch ... Artificial Almond Oil . . CtHsNHjHCI........................ CeHdCHbCJL........................ CsHdCOLCtH,........................ CeHsCHO.............................. 250 365 400+ 148 880 885 485 535+ 165 0.63 No 1.22 4.46 388 473 1.3 881 No 185 6.15 424 644 1. 2,3 No 1.438 7.16 544 716 1. 2,3 905 No 0.65-1.1 180-220 >700 1.2,3 877 No 1.05 3.66 -15 355 1,2,3 Bensedrine........................ Amphetamine .... CsH.jN.................................... >80 Benjene .............................. Benxol............................... CeHc ........ 12 1.4 8 1076 Bensine.............................. Petroleum Ether . . . Cn Htn+r.................................... <0 1.1 48 476 Bensoio Aoid........................ FhenyUormio Aoid . . . CHsCOOH.............................. 250 1065 Benioyl Chloride .... Benzene Carbonyl Chloride CeHsCOCl.............................. 215 d No No No 0.931 088 0.64 1866 1812 392 1.3 2.77 41 176 2,3 48 >-100 100-160 2.3 421 262 482 1.3 4.88 31 387 1.2,3 Benioyl Peroxide .... Luoidol (White Granular) . (CsHsCOljOa.............................. d.205 BeniylAcetate .... CHeCOOCHiCeH, .... 2i6 862 Bensyl Alcohol .... Phenyl Carbinol . . . CbHsCHjOH.............................. 213 220 817 Beniyl Bensoste .... UftilcUOUUHjUfihs .... 298 ,. Bensyl Cellosolve.... Ethylene Glycol Monobenxyl Ether . . CeHtCHiOCHiCHjOH . . . 266 ... ... 665 No No No No 1 1.06 5.17 46 '7 1, 2,3 1.04 8.72 5 403 1.2,3 1.114 781 65 614 1, 2,3 1.07 493 1.3 Beniyl Chloride .... Omega Chlorotoluol . . Beniyl Diethylamine . . Borneol.............................. Borneo Camphor . . . Bromobemene .... Phenyl Bromide . . . Bronie Dust (Aluminum Free) CJLCH2C1 ...... CdiCHjNfCiHs)! .... CioHnOH.............................. CaHsBr..................................... 153 165 170 160 148 NoH aiard 1.1 . ... No 1.103 46 -41 849 1,2,8 No 0.89 405-420 1.2,8 No 1.01 581 407 Bub. 413 1.3 . No 1.497 5.41 -2$ 813 1.2.3 No Brouiiis Liquid .... Butadiene 1.8 .... Butadiene Monoxide . . . Butano-m ..... Butane-iso.............................. Butene-1.............................. Butyl Acetata-n. .... Butyl AoeUte-uo. . . . Butyl Aeetate-eeo. . . , Butyl Aoetyl lUoinoleate . Butyl Aloohol-n. .... Butyl Akohol-iw. . . . Butyl Alcohol-eeo. . . . Butyl AloohoLter .... Dnf^ininA . ... Erythrene........................ Yinyietbylene Oxide , . Methylethylmethane . . 2-Methylpropane . . . Ethyletbylene . . . . Butyl Ethanoate . . . 2-Butanol Acetate . . . 1-Butanol.................................. 2-Methylpropanol-l . . 2-Butanol; Methylethyfoarbinol . 2-Methyl-2-fropanol . , 1-AminobuUne.... CHjCHCHCHj........................ H*C=CHCHOCHs .... C<H,o.................................... ...... (CHj)jCHCHi.................................. <30 (May Be >"" c&s <-58 -76 gas -117 CHjCHjCHCH,........................ CHaCOOC.H#.................................. CHaCOOCHiCHCCHaJi . . CHiCOOCHtCHaKCiHa) . . Cj7H(OCOCHj)(COOC.H) . CHiCHjCHiCHiOH . . . fCHijiCHCHtOH .... -112 72 64 84 82 gas 90 88 230 no 105 CHiCHjCHOHCHi .... (CHahCOHCHj................................. CHj(CH.)iNHj.................................. 75 52 <40 |f ... 2.0 1.6 1.6 1.7 1.7 1.7 ' 1.68 ttf ... ... 118 6.5 88 16 1 1 ... ... 8.0 .... 842 806 . 1010 790 725 693 825 wi -- No 0.621 1.87 -164 No 0869 2.41 No 0.599 2.046 -211 No 088 2.01 0.601 1.939 No 088 4.00 -io7 No 0871 4.00 -148 0858 0.940 -25 No 0806 285 -120 No 0805 285 -162 0808-8812 285 No 0.786 - 285 0.74-0.70 242 '77 ... 24 150.8 33 14 20.7 260 244 221 428 243 225 201 181 172 2,3 4 3,4 4 4 4 2 3 8 1, 2, 3 1.3 1.3 1.8 ITS 8 DSW 587854 STLCOPCB4093190 Page 6 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) No. 36.10 NAME SYNONYMS FORMULA Butylamine-lso........................ Butylamine Oleate, Mono . Butyl Benzene-sec. . . . Butyl Benzene-ter. . . . Butyl Bromide-n..... l-Amino-2-Methyl-propane ........................ ...... 1-Bromobutane . . . (CH3)2CHCH2NtH2 .... CuHsiCOONaCiH, . . . 0,HgCrHs.............................. Cf.H&C(CH2)3.............................. CH3(GH2^OH2Br .... Flash Point eF. Closed Cup 15 126 Open Cup 150 55 Explosive Limits % by Vol. in Air ignition Temp. Lower Upper F. Susoepti- Sponta neous Heating No No 600 Gravity (Water* 1.00) 0.733 0.891 0.86 0.871 1.272 Vapor Density (Air* 1.00) Melting Point F. 4.62 4.72 -170 Boiling Point F. 150 345 336.6 215 Buitable Extin guishing Agents 3 3 2,3 3 Butyl Butyrate .... Butyl Carbind-ter ... Butyl Carbitol .... Butyl Carbitol Aoetate . . Butyl Butanoate . . . Diethylene glyool. monobutyl ether . . Diethylene glycol, monobutyl ether acetate . CH3(CH2)2COOC<H9 . . . (CH^CCHaOH........................ C<H9O(CH2)20(CH2)20H . . C.H.OlCHjLOtCIWjOOCCHj 98 172 128 200 240 442 No 670 No 0.874 0.955 0.987 3.03 6.58 <-4G 305 1. 2,3 3 448 1.3 474 1.2,3 Butyl Celloedve . . . . Butyl Celloeolve Acetate . Butyl Chloride-n.. . . . Butyl Decalin........................ Butyl Decalin-ter . . . 2-Butoiyethanol . . . - 1-Chlorobutane . . . .......................................... ..... C.H0(0{M,0H . . . . C.H,0(CH2)200CCH3 . . . CH3CH2CH2CH2CI .... C.H.C.oH.v.............................. O.HsOloH,; ..... Butyl Diethanolamine . . Butylene-n............................... Butylene Chloride! . . . Butylene Glyool .... Butyl Ethanolamlne-n. . . 1-Butene........................ 1, 3-Butanediol.... 2-Butylaminoethanol . . CiHsNfCHjCHjOHJj . . . , CH,CHjCH:CH! .... 1 C.&C1.................................... |CH,OHCH.CH(OH)CH, . . CH,(CH!)1NHCH1CH!OH . . 141 600 640 gas 228 165 180 20 1.85 10.1 472 800 245 1.7 9.0 2.25 9.26 250 710 170 No No No No 0.902 0.943 0.S87 0.97 0.926 1.006 0.89 4.07 3.20 <-40 -190 5.55 1.93 3.13 3.10 4.03 -202 74 340 370 170 503 23 162 404.7 377 1.3 1, 2,3 2.3 1.3 1.3 1. 2, 3 4 2,3 1.3 1. 2, 3 Butyl Ether........................ 1-Butoxybutane . . . OftKCJW.irHCHjLOH.i . . . 100 Butyl Fonnate-n .... Butyl Methanoate . . . HCOOC1H9.............................. 64 Butyl Hydroperoxide-ter . (OHiOaOOOH........................ 65 65 Butyl Lactate........................ ICO Butyl Monoethanolamine-n . C4H9NHC2H^OH .... 170 No No No 720 No 0.769 0.911 0.860 0.968 0.89 4.48 3.52 2.07 5.04 4.03 -130 -43 266 2,3 225 2,3 3 320 2.3 378 1. 2, 3 Butyl Naphthalene . . . Butyl Oleate........................ Butyl Oxalate........................ Butyl Perbenzoate-ter . . Butyl Phthallyl Butyl Glycollate........................ Dibutyl Ethanedloate . . "Santidzer" B-16 . . . ChHgCwHj'.............................. C^H^COOC^Hg........................ (COOC^H9)2.............................. CeHsCOOOCfOHs).-! .... C6H4(COO)2(C4HS)CH2COOC^H9 680 66 385 350 265 75 390 0.873 0.989-0.993 No 1.035 6.69 No >1 343 d.235 1.3 1. 2, 3 1.2,3 3 1. 2,3 Butyl Proplonate-n . . . Butyl Ricinoleate .... Butyl Btearate-n..................... Butyl Tetralin-ter. . . . Butyr&ldehyde .... Butyl Propano&te . . . Butyl-12-hydroxy-9- octadecanoate . . . . . .'. CHaCHsCOO^Ht, .... CkHmOoC.Hj........................ C.HSC,H,,.............................. CH3(CH2)2CHO........................ eo 230 320 680 20 no 385 800 No No 0.875 0.906 0.855 0.817 4.49 ei 2.48 -148 295 2,3 790 1, 2,3 650 1. 2,3 1.3 i69 3 Butyraldehyde-iso . . . Butyraldoxime .... Butyrlo Anhydride-n. . . Butyrone.............................. 2-Methyl Propanal . . Butanal Oxime .... Butanoic Add .... Butanolo Anhydride . . 4-Heptanone .... (OHaHCHCHO '........................ C4H6NOH ........................ CHi(CH2i5COOH .... [CH3(CH2i2C0120 .... (C3H;)2CO -40 136 170 190 120 490 K----- No No 0.813 0.923 0.960 0.978 0.815 2.49 3.01 3.04 18 5.38 -102 3.93 142 3 306 2,3 327 1.3 388 1.3 290 3 Camphor.............................. Camphor Oil (light) . . . Caprolo Add........................ Carbitol.............................. Gum Camphor .... Liquid Camphor . . . Hexanolo Add .... Diethylene glycol monoethyl ether . . . C9H,bCO.................................... CHafCH^OO'OH .... CH20HCH20CH2CH20C2H6 . 150 117 201 200 125 215 215 871 No No No 0.699 5.24 354 408 1,2,3 0.88 347-392 2,3 0.629 4.01 23 400 1, 2,3 0.99 4.62 396 1.3 Carbitol Acetate .... Carbitol Pbthalate . . . Carbon Disulfide .... Carbon Monoxide . . . Diethylene glycol monoethyl ether acetate Dicarbitol Phthalate . . Carbon Bisulfide . . . C2HS0(CH2)20(CH!)!C020H3 . C6H<rcOOC2H1OC2HiOC2Hs)I . CS2.......................................... CO.......................................... 225 405 -22 gas 230 475 1.0 60 12.5 74.2 257 1204 No No No No 1.013 1.121 1.256 6.07 2.64 0.967 -167 -339 424 >500 114 -314 1.3 1.3 4 Carbonyl Sulfide .... Carbon Oxyeulfide . . . COS.......................................... gas 11.9 28.6 No Caraauba Wax .... Brazil Wax........................ 640 595 Castor Cdl.............................. Kidnus Oil........................ Cationio Amlne-220 . . . 1-Hydroxyethyl 1-2- 445 645 840 Yea hept&decenyl glyoxalldlne C,,H33CN(CH2)2NCH2CH20H . 465 1.24 0.995 0.96 2.10 -216 185 10 122 4 1, 3 595 1. 2,3 1, 2,3 Celloeolve.............................. Ethylene glycol monoethyl ether .............................. C^OtCH^OH .... 101 120 2.6 15.7 460 No Celloeolve Acetate ... Ethylene glycol monoethyl ether aoetate .... CHsCOOCIfeCHsOCgH,, ' . . Charcoal.............................. Carbon.............................. c................................................ 124 135 1.71 716 No Yes 0.931 0.975 3.51 3.10 4.72 >6300 275 313 7600 3 3 1 Chlorobenzene .... Chloroethyl Aoetate . . . Chloroform........................ Chloronitroethane-1,1 . . Chloronitropropane-1,1 . . Phenyl Chloride . . . Ethyl Chloroethanoate . Trichloromethane . . . CfiHsCl...................... cat.ciooccHj........................ CHCL . ........................ CkHiNO^l.............................. CHNOs-CICzH* . . . . . 60 129 nnn-flAmmfthlp. 133 114 1.8 9.6 @ >1245 212F. 302F. upon No No 1.11 1.178 1.489 1.268 1.209 3.88 4.21 4.13 3.77 4.26 49 -82 270 2, 3 293 1,2,3 142 257 1.3 285 1.3 Chloronltropropene-2,2 . . CoalTsrOil Coal Tar Pitch Coooanut Oil .... .... CHaCNWlCHs........................ 135 <80 405 420 490 . . . 510 rapid heating Yea 1.193 <1 0.91 4.26 273 1.3 2.3 . 1. 2,3 72 1. 2,3 Collodion........................ - . Com OH.............................. Cotton seed oil (refined) . . Creosote Oil........................ Soln of nitrated Cellulose in ether/aloobol . . . Ci2H,e06(Nft).Ci3HiI0I(N03)3. <0 490 486 165 610 . 740 650 650 185 ... ... ' 637 No Yea Yea No 0.92 0.925 >1 U 15-30 . 382-752 3 1. 2,3 1. 2.3 1, 2,3 o-Cresol ...... p-Creeol.............................. Crotonaldehyde .... Crotonylene........................ 0-Methyl Phenol: O-Creeylio Ada . . . p-Methyl Phenol: p-Creeyllo Ada . . . 2-Butenal......................... 2-Butyne ..... CILCiH.OH .............................. CHsCsILOH . ................... CH3(CH)2CHO........................ CHjCCCHa.............................. 178 187 65 63 1.35 300F. 2.95 15JS 1.87 1038 1038 No No No 1.05 1.04 0.853 8.72 3.72 2.41 1.91 88 95 -92 376 1,2.3 395 1,3 216 3 83 2,3 Cyanamlde ..... Cydobutane........................ Cyclohexane........................ Cydohexanol........................ Cyclohexanone .... Carbamonitrile .... Tetraethylene .... Hexamethylene . . . HeTMlln . . . . . , Ketoheimmethliene . . CNNH2.................................... C<H8.......................................... CbHuOH.................................... CtHioO.................................... 285 <60 1 164 147 405 gas . . . 1J)1 8.35 1-1 ... 212F. 6M 847 No No No No 1.073 0.779 0.962 0.947 1.46 2.90 3.45 3.38 113 dA00 1,3 -68 55 4 43 176 2, 3 75 322 1,2,3 -60 313 3 DSW 587855 STLCOPCB4093191 No. 36.10 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) Page 7 NAME SYNONYMS FORMT'LA Flash Point F. Closed Open Cup Cup Explosive Limits % by Vol. in Air Auto Ignition Temp. Lower Upper F. Suscepti bility to Sponta neous Heating Specific Gravity (Water= 1.00) Vapor Density (Air= 1.00) Melting Point CF. Bolling Point F. Suitable Extin guishing Agents Cyclohexanone della . . Cyclohexylamine . . . Cyclcpentane .... Cyclopropane .... Hexatin Acetate . . . Aminocyclohexane . . . Pentamethylene . . . Trimethylene .... CeHfiO ........ OH:iCOOCnH,, ..... CtHnNH, ...... 0-.H,o.................................... ...... CsHg ........ 93 136 gas No No 90 660 2.41 10.3 No 0.865 0.751 3.31 4.90 3.42 1.45 -105 350 274 120.7 -29 3 2,3 3 4 4-lsopropyl-l- 0.7 @ methylbenzene . . . OHaCr,H,CH(OHJ)! .... 117 145 1 12F. 921 No 0.86 4.62 '101 334 2,3 Decabydronaphthalene . Decalm.............................. 136 504 No 0.895 4.76 -194 379 2,3 Decyl Hydride .... CHj(CH7)8CH.1........................ 115 I Denatured Alcohol--95% Denatured ethanol... . 60 0.67 2.6 >500 750 No No 0.730 0.82 4.90 1.60 -26 -60 344 2,3 175 3 l Diacetone (acetone free). Diacetone>(comm*2.) . . 4-Hydroxy-4-methylpentanone-2 . ... Diacetone Alcohol . . . ch;coch,o(cho,oh .. 136 48 145 55 . . . Diamylamine .... Di-n-amylamine . . . (C5H102NH ...... 124 >158 G10H20..................................... 118 1190 1118 . No 0.93-0.94 0.931 0.777 0.77-0.78 4.00 5.42 <-58 328 -1,3 328 1.3 356 2.3 302 2,3 Diamyl Naphthalene . . Diamyl Phenol-2,4 . . Di-ter-Amylphenoxy Ethanol Diamyl Phthalate . . Diamyl Phthalate-n. . . Amyl Phthalate .. . CjoHr.(OfiHu)2 . . . . (CsH.OjCtHjOH........................ (AiSU'O.JinWOftC'HjOH . . ('..H.CCOOCiHn), .... 'Cf,H4(OOOCoHi,)2 .. .. 245 245 315 260 300 340 0.83-0.94 0.93-0.94 0.959 1.023 9.26 8.08 0.6 624 2,3 627 2,3 -31 615 3 648 1, 2, 3 475-490 1. 2, 3 Diamyl Sulfide . . . Dianisidine .... Dibenzyl Ether . . . Dibutoxymethane . . to,h,,)s.............................. Di-para-aminodi- methoxydiphenyl . . |NH2(OCH3'CcH:,b .... (CfiHsCHzlOfC'fiHsCH-.) . . . CH2(OC,H,)2 ..... 403 275 140 185 0.88-0.89 6.02 338-356 1.2.3 269 1.3 No 1.036 6.82 41 568 1. 2,3 No 0.838 140 330-370 Dibutylamine .... Dibutylaminoethanol . Dibutyl Ether-n. . . . Dibutyl Phthalate-n . . Di-n-butylamine . . . Di-n-butylaraine ethanol . 1-Butoxybutane . . . Dibutyl 1, 2-benzenedicarboxylate . . . (C,H.j)2NH ...... (C^HiOaNOzHiOH .... ........................ OoH^COOOJT9)2 .... 77 220 315 135 200 335 382 No No 757 No 0.76 0.86 0.769 1.01 1.045 4.46 5.97 4.48 9.58 322 2,3 432 1.3 286 3 1. 2,3 690 1. 2, 3 Dibutyl Phthalate-iso -- Dibutyl Sebacate . . Dibutyl Tartrate-n. . .- . . . Diisobutyl 1, 2benzene dicarboxylate . Dibutyl-d-2, 3dihydroxybutanedioate . CfiH4(COO('H2OHCRiOH3)2 . l(CH,).COOC,H,]2 .... (COOC,H>MCHOH),, . . . 322 195 353 230 No 544 No 0.963 1.09 9.68 9.03 1, 2, 3 650 1, 3 72 650 1, 2,3 n-Dichlorobenzene . . 1,2-Dichlorobenzene . . ceH.cla..................................... 151 165 No p-Dichlorobenzcne . . 1,4-Dichlorobenzene . . C6H4C12 ............................... 150 165 No 1.3-Dichlorobutene-2 . CH2C1CHCC1CH3 . . . 80 65 No Dichlorodiflucromethane PDichloroethylene 1, 1 . Freon, F-12........................ CCl2F2.................................... Dichloroethene 1,1 . . CH2CCI2 ............................... non-flammable 57 6.6 No 856 No Dichloroethylene 1, 2 . Acetylene Dichloride . . G1CHCHC1 ...... 43 9.7 12.8 No Dichloroethyl Ether-sym l-chloro-2-(beta chloroethoxy)-etbane . (CIC2IM20.............................. 131 180 696 No Dichloroethyl Formal . Di-[2-Chloroethyl] Formal 1, 3 Dichloro-2, 4-Hexadiene CIWOCHaCHjCl)! .... CH2C1HOOCJHCCHCHj . . ies 230 180 1.325 1.458 1.250 1.282 1.22 1.23 5.07 6.07 4.31 3.35 3.35 4.03 5.9 5.20 2 127 -113 -58 354 345 258 -21.6 08.6 141 352 424 1, 2,3 1. 2, 3 2.3 1, 2, 3 1, 2, 3 1, 2, 3 1. 2,3 1/2, 3 Dlohloroisopropyl Ether . 1,1 Dichloro, 1 Nitro Ethane 1.1 Dichloro, 1 Nitro Propane Dichloropentanes, mixed l-chloro-2-(betachlorolsopropoxy) propane C]CH2CH(CH3)OCH(CHs) ch2gi.................................... OH3CC12N02.............................. CjHsCChNCk........................ CiHioCl,.................................... 185 168 151 106 No 1.11 1.405 4.87 1.314 5.45 1.08-1.08 362 1. 2, 3 255 1. 3 289 1.3 266 1.2,3 Dichlorotetrafluoroethane Dicyclbhexylamme . . Dioyclopentadiene . . Diethanolamine . . . Diethylamine .... Freon-114 ........................ Di(2-hydroxyethyl)amine . ClCkF,.................................... (CsHhJjNH............................... (HOCH2CH2)2NH .... (C2H02NH.............................. non-fla tunable >210 280 <6 <0 1224 No No No 0.910 0.9440 1.097 0.710 6.27 3.65 2.53 38.5 496 3 316 82 614 1. 3 134 3 Dlethylaminoethanol. . (CaHshNCHjCHjOH . . . 140 Diethyl Carbitol . . . Diethylene glycol diethyl ether.............................. CftifCHjOCIMsCHj . . . 180 Diethyl Carbonate . . Ethyl Carbonate . . . siyi.ya.,.............................. it Diethyl Celloeolve . . Ethylene glycol diethyl ether.............................. CsHiOCHsGH^OCsHs . . . 95 No No No 406 No 0.885 0.008 0.977 4.07 ^45 0.842 322 3 367 1.3 269 2,3 251 3 Diethyl Diphenyl Urea . 1 (O2H3) (CsH.-,) N ]200 . . . 302 No Diethylene Glycol . . Di-hydroxy-di-ethyl ether . CHaOHOHrflOH.CIMlH . . 255 290 444 No Diethylene Oxide . . . 1:4 Dioxane .... CH20CH2CH20CH2 . . . 54 65 1.97 22.2 356 Diethylene Triamine . . 2, 2-Diaminodiethyl-amine NH2CH2CH2N HCH2CH2NH2 . 210 215 750 Diethyl Ether .... Ether; Ethyl Ether . . COLOCtH,............................... -20 1.7 48.P 366 No 1.12 1.119 1.035 0.954 0.71 160 3.66 21 3.03 60 3.48 2.55 -177 620 1, 2, 3 472 1. 3 214 3 404 1 95 3 Diethyl Glycol Phthalate Diethylhexylamlne . . Diethyl Oxalate . . . Diethyl Malonate . . o-Piethyl Phthalate . . Diethoxyethyl phthalate . Diootylamine ... Ethyl Ethanedioate . . Ethyl Malonate . . . Ethyl-o-Phthalate . . . C6H)|C00(CH2)20C2H..,]2 . . [CiHsCHtCjftACHdiNH . . (COOC2H.s)2............................... CIMCOOClH* .... CsH.tCOOCyi* .... 343 270 168 200 325 1.11 1,3 0.806 833 ... 638 1.2,3 1.07 5.03 356 1,2,3 No 1.055 <-4 385-302 1.3 1.11-1.12 665 1, 2,3 n-Diethyl Phthalate . . Ethyl-p-Phthalate . . . CbH<(C0002H5)2 .... Difluoromono Chloromethane Freon-22 Dlglycol Chloroformate . ........................ (OHF2CD.............................. 243 305 220 praotically non-flammable 295 2.5 817 1170 No No 1.11 1.23 1.184 7.66 4.73 6.31 112 -12 ... 576 1. 2,3 226 1,2,3 406 1,2,3 i, 2,3 Dlglycol Chlorohydrln . Diilyool Dilevulinate. . Dihydropyran . . . Di-isobutyl Ketone . . DRsopropanolamine . Diethylene Glycol DUerulinate .... H0CH,CH20CH2CH2C1 . . ICH2CH200C(CH2)2COCH3]20 (CH3)2CHCH2COCH2CFi(CH3)2 [CH3CH(OH)CH!]2NH . . . 340 4 140 225 385 260 No 1.172 1.145 0.923 No 0.809 0.989 4.50 387 i86 107.6 1,3 1,3 Di-isopropylamine . . Dl-isopropyl Benzene . Dimethoxy Tetraglycol . Dimethyl Anflinw , . . 2,8-DimethylbuUuie . . Tetraethylene glycol dimethyl ether . . . Diisopropyl........................ [(CH3)!CH]2NH........................ [(CH3).CH]2C6Hi .... CHsOCHifCIIzOOH-ljCHiOCHs CeHiNtCKOi, . . . . . (CH3)!CHCH(CH3)2 . . . ft) 170 285 145 170 <-20 840 . No ... 700 No No 0.726 1.013 0.056 .0.872 M9 4.17 3.00 ... ... 86 180 1.2,3 528 1.3 370 1,2,8 255 3 b DSW 587856 STLCOPCB4093192 Page 8 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) No. 36.10 NAME SYNONYMS FORMULA Flash Point F. Closed Open Cup Cup Explosive limits % by VoL in Air Auto ignition Temp. Lower Upper F. Suscepti bility to Sponta neous Heating Bpedfio Gravity (Water- 1.00) Vapor Density (Air** 1.00) Melting Point F. Boiling Point F. Suitable Extin- guishlng Agents p-Dimethyl Cyclohexane Dimethyldichlorosilane . Dimethylethanolamine . Dimethyl Ether* . . . Dimethyl Formamlde . Hexahydroxylol . . . DDS ....... Dimethyiamlnoethanol . Methyl Ether .... (CHalsCsHio.............................. (CHshNtCIfcLOH .... CH30CH3 ...... (CKO2NCHO......................... 52 -42 136 3.4 >9.5 88 gas 3.4 26.7 155 2.2 @ 212F. 450 662 833 No No No 0.77 0.887 0.661 0.945 3.86 3.67 1.617 -m -216 -78 248 2.3 272 3 -11 3 307 1.2,3 Dimethyl Glycol Fhthalate Dlmethylpentane . o-Dimethyl Phth&late 2.2-Dimcthylpropane Dimethyl Sulfate . . . . , . Methyl "Celloeolve" Phth&late .... Diethyldimethylmethane . . Methyl Sulfate .... CsH,(COO(CH,),OCH,l2 . . OjHu ........ UeH4(UUUUH3)2 . . . . . (CHaliSO,............................... 369 295 .182 325 240 io32 No No No 1.17 9.72 446 1.3 0.677 1765 1.189 6.69 ... 540 1.2,3 0.695 49.1 1.332 435 -16 370 j.2,3 Dinitro Aniline-2,4 . Dinitro Benzene-1, 2 . Dinitro Chlorobenzene Dinitro Toluene-2,4 . . . . . 2, 4-Dinitrophenylamine . O-Duutrobenzol . . . Dinitrochlorobenzol , . l-Methyl-2, 4-dinitro- benzene ........................ (NCWjCsHjNHj ..... CeH.tNOj),.............................. CsHaCKNOd!........................ (NCD^tttjCH:,........................ 435 302 382 510 405 1.67 22 1.615 6.31 370 U9 5.79 243 1.68 6.98 109 1,3 605 1,3 1,3 No 1.52 6.27 158 572 1.3 Dioctyl Phthalate . . Dioxolane ..... Diphenyl........................ Diphenylamine . . . Diphenyl Methane . . Di-2-Ethylhexyl Phthalate Phenylbenzene .... Anilinobenzene .... Benzylbenzene .... ClH(|COOCH!CH(CdL)CiHsl! OCH2CH2OCH2 . ' . ... (V-Hf.Cf.Uf.................................... OCtHsLNH.............................. (IVILW'H:.............................. 235 307 266 360 35 255 0.686 13.45 726 1.2,3 1.065 2.65 165.2 3 No 0.685 5.31 158 491 1.3 No 1.16 5.82 127 675 1.3 No 1.006 5.79 70 508 1. 2,3 Diphenyl Oxide . . . Diphenyl Ether . . . UMI.HO ............................... 236 No 1.073 6.86 81 Dipropylene Glycol . , 1, l-Oxydipropanol-2 . . ICH3CHOHCH2I2O .... 280 No Divinyl Ether .... Vinyl Ether........................ CH2CHOCHCH2 .... <-22 1.85 36.6 680 No 1.040 0.774 2.41 Dodecane ..... Dihexyl . . . . . . CH3(CH21]oCH3........................ 165 0.6 No 0.750 5.86 10 375 655 No 285 600 1. 2,3 872 1.3 102 3 421 1. 2,3 465 1. 3 Ethane.............................. Methylmethane . . . C2Hf.......................................... gas 3.3 10.6 650 No Ethanolamlne .... 2-Aminoethanol . . . NHiCftCHjOH........................ 200 No Ethylacetanilide . . . Ethyl phenylacetamide . CH3CON(G2H5)(C6Hi) . . . 126 Ethyl Acetate .... Ethyl Ethanoate . . , CHaCOOCjHs........................ 24 30 2.18 11.5 607 No Ethyl Aoetoacetate . . Ethyl 3-oxobutanoate . . CfifCOOCHjCOCHj . . . 184 No 1.02 0.642 0.899 1.03 1.035 2.10 5.62 3.G4 4.48 -278 61 -iie -48 -128 342 400 171 356 4 1.3 2,3 3 1,3 Ethyl Aloohol .... Ethylamlne--70% aqueous solution........................ Ethyl Aniline-mono . . Ethyl Benzene . . . Ethyl Benzoyl Aoetate . Ethyl Borate .... 2-Ethyl Butyl Aoetate . 2-Ethyl Butyl Carbonate Ethanol.............................. Aminoethane .... Phenylethane .... Bromoethane .... CiHsOH.................................... C2H5NH2.................................... CsHsNHCdfL........................ CzHsCsHs.................................... C6H2COCH2COOC2H5 . . . (C2Hs)3B03.............................. C2H5Br.................................... CH3COOCH2OH(&HS)3 . . (CjHiXC.HOCOj .... 55 59 52 122 3.28 16 799 <0 185 75 870 285 6.0 11.0 s 652 i30 ...4 No 0.79 1.59 -178 "v. 0.778-0.802 0.95-0.97 4.17 No 0.868 3.66 -134 173 4005 277 3 3 1, 2,3 2.3 1.11 -___ 291-288 1.3 No 0.863 233 3 No 1.430 8.76 -182 100 1.3 0.880 324 2,3 No 0.82 6.03 276 2,3 2-Ethylbutyl Celloeolve . Ethylene glycol ethylbutyl ether . . . (C2HO2CHCH2OCH2CH2OH . 180 2-Ethylbutyraldehyde . 2-Ethylbutyrio Aldehyde . (C2HO2CHCHO........................ 70 Ethyl Butyrate-n. . . Ethyl Butanoate . . . CH3CH2CH2C00C2Hs . . . 78 85 2-Ethylbutyrio Acid . . 2-Ethylbutanoio Acid . . (C2H02CHOOOH .... 210 865 No 0.896 0.816 0.879 0.922 3.45 4.00 -135 4.01 886 1, 2,3 242 3 248 3 380 1.3 Ethyl Chloride . . . Ethyl Chloroformate . . Ethyl Crotonate . . . Ethyl Diethanolamine . Ethylene........................ Chloroethane .... Ethylchlorocarbonate . . Ethene ............................... C2HsC1 ....... CzHsOOCCl.............................. CHjCHCHCOOCiHs . . . C2HsN(C2ILOH)2 .... CjH............................................ -68 61 36 gas -45 3.6 12.0 82 966 255 3.02 34 1006 No No No 0.610 1.13 0.820 1.01 2.22 3.74 459 0.975 -220 -272 54 201 282 464 -165 3 3 2,3 1,3 4 Ethylene Chlorohydrin . 2-Chloroethanol . . . CH2C1CH20H........................ 140 No Ethylene Diamine . . 1,2-Ethanediamine . . H2NCH2CH2NH2 .... 69% 160 176 715 No 100% 93 110 Ethylene Dichloride . . 1,2-Dichloroethane . . CH2C1CH2C1............................... 56 65 6.2 15.6 775 No Ethylene Glycol . . . Glycol............................... CHjOHCHjOH........................ 232 240 3.2 775 No 1.213 2.78 -64 0.890 2.07 47 1,268 3.42 -33 1.113 2.14 3 264 1.3 24i 3 183 1.2.3 387 3 Ethylene Glycol Monoacetate CH20HCH200CCH3 . . . 216 No Ethylene Oxide . . . CHIOCH2............................... <0 3 80 804 No Ethylethanolamine-1 . . C2Hi,NHC2HOH ..... 160 Ethyl Formate . . . Ethyl Methanoate . . . HCOOCjHs . . . . . . -4 10 2.75 16.5 No Ethyl Hexaldehyde . . CiH9CH(C2Hs)CHO . . . 125 1.109 0.887 0.62 0.622 0.8205 1.62 80 2.55 4.42 -168 -112 367 61 822 130 325.4 1,3 3 1.3 2,3 2,3 2-EthylhexanedioM, 8 . 2-Ethylhexanolo Acid . Ethyl Hexanol . . , Ethyl Lactate.... Ethylhexylene Glycol . . Ootoio Aoid........................ Ethyl 2-hydroxy propanoate .... CHj(CH2l2CHOHCH(C2Hf.) CH2OH............................... CHXCHjHCHfCjHOCOOH . C<H,CH(C2HS)CH20H . . . CILCHOHCOOCjH, . . . 115 260 260 185 1.55 @ 212F. 752 No 0.942 0.907 0.8340 1.03 6.03 4.97 4.49 4.07 .. ... ... 472 1. 2,8 440 1.2.3 859 1.2,3 809 3 Ethyl Mercaptan . . . Ethyl Morpholine . . Ethyl Nitrate .... Ethyl Nitrite .... Ethyl Oxalate .... Etbanethiol..... Nitric Ether .... Nitrous Ether .... Ethyl Ethanedioate . . CjHtSH.................................................. CHfCHiOCjH.NCHffCHa . . CjHsONOi.......................................... CjHsONO.............................. (COOC2HO2.......................................... <80 BO -31 168 89.6 60 2.8 18.2 . 570 3.8 3.01 >60 194 No No No 0.839 0.916 1.105 0.900 1.080 2.11 4.00 8.14 2.59 6.04 -185 -162 +0 98 230.4 180 63 867 8 2,3 2,3 2,3 1.3 Ethyl Phthallyl Ethyl Glyoollate .... Ethyl Propionate . . . 2-Etbyl-3- Propylacroleln Ethyl Silicate .... Ethyl p-Toluene Sulfonamide Propionio Ether . . . 2-Ethylhexenal .... Ethyl orthoeilicate . . . C2H5COOC2H6........................ CaH2CH:C(C2H5) CHO . . . (CjILXSiO........................................... C7H7SO3NHC2H5 .... 865 54 260 885 155 125 380 890 No ... >1 0.891 0.851 0.836 352 4.36 7.22 ... -99 __ ... 1.2.3 2io 2,3 3(7 1, 2,3 334 3 1,3 Ethyl p-Toluene Sulfonate Mahffil................................. Formaldehyde (gas) . . (Sol'll, 37% gas in water) Eormio Add .... CjHlSCLCjHs........................ Methanal.................................. ..... Methanoio Add . . . HCOH.................................................. HCOOH.................................................. 316 420 , 130 166 7 73 800 200 a a 817 1114 Fuel (Ml No. 1 Fuel Oil No. 2 Fuel Oil No. 3 Fuel (Ml No. 4 Fuel Oil No. 6 ... ... ... ... ... Range Oil.................................. 110-165 110-190 a,, 125-200 150+ 260 ... 150+ aaa 150+ 320 ... ... 490 494 498 505 765 Yes No No No No No No No .... 1.218 <1 <<11 <<11 <1 1.075 1.03 1.58 aa .... .... .... .a. a.a ... ..a 47 a*. a. ... ... ... -6 .... .... .... .... .... .... 1,2.3 1.2.3 4 13.8 3,3 2,8 2,8 1,2,3 If 2,8 1.2,8 DSW 587857 STLCOPCB4093193 No. S6.t0 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) Page 9 NAME SYNONYMS FORMULA Flash Point F. Closed Open Cup Cup Explosive limits % by Vol. in Air Auto ignition Temp. Lower Upper F. Suscepti bility to Sponta neous Heating Specific Gravity (Water- 1.00) Vapor Density (Air* 1.00) Melting Point F. Bolling Point F. Suitable Extin* guishing Agents Furol........................ ..... . CrfLOCHO ...... 140 155 2.1 739 No 1.159 3.31 -31 322 1. 2,3 Furfuryl Carbinol . . . C.HeOCH*OH........................ 167 015 1.129 3.37 -1 810 3 Gas, Blast Furnace . . . 35 74 5.3 31 i2oi No No 4 4 i 6.3 31 1091 No 4 \ 1.8 13.5 No 4 6.0 13.5 637 No 4 20.7 73.7 No 4 Gas Oil............................. 150+ 9.0 65.0 No 6.0 13.6 610 No <1 4 1.2.3 Glyool Difonnate .... Glycerol............................... Triacetin . ... . Ethylene Acetate . . . Ethylene Formate . . . HOCHjCHOHCHjOH . . . (CeHiKOOCCHeL .... (CHeCOOJeCeH......................... HCOOCHiCHjOOCH . . . -50 320 . 280 0 350 295 220 200 0 495 No 739 No 812 No No 0.76 1.26 1.161 1.100 1.227 3-4 3.17 7.52 6.03 4.07 <-50 64 -108 -21 100-400 554 466 370 360 2,3 1.3 1,2,3 1, 2, 3 1.3 Heptadecyl Alcohol . . CnHasOH . ............................... 310 CH3(CH2)5CH3 ..... 25 i 6 452 No <0 1 6 No Beptanol-2........................ Amylmethyl Carbinol . . CH3(CH2)tCHOHCH3 . . . 160 Hexane-n.............................. CIWCHihCHs........................ -7 1.25 6.0 177 No 0.817 0.683 0.725 0.818 0.661 8.84 3.45 3.45 1.01 2.67 130 -130 -i37 586 208 176-195 320 166 1, 2,3 2,3 2,3 1. 2,3 3 CsHm........................................... <-20 1 Methyl Amyl Aoetate . . CsH.jCOOOHj ..... 113 1-Hexanol......................... CHafCHeiiCHjOH .... 145 Hexyl Alcohol........................ Elbylbutyl Alcohol . . (C!Hs)!CHCHjOH .... 137 Hexylene Glyool .... Hexandiol........................ CH2OHCHOH(CH2)3CH3 . . 205 Hexyl Ether........................ Dihexyl Ether . ... C6H13OC6H13.............................. 170 7 0.669 3.0 130 2,3 No 0.855 4.97 285 3 No 0.82 3.52 -62 311 3 No 0.818 3.52 275 3 No 0.922 4.07 385 1.2,3 0.791 6.43 440 1, 2, 3 Hydrocyanic) Aoid . . . Hydrogen............................. Hydrogen Sulfide .... Hydroquinone .... HvHrnTvInmin* Prussic Acid .... p-Hydroxybenxene, . . fWarnmnnimn HCN.......................................... H2................................................ H2S.......................................... CeIL(0H)2.............................. NHiOH.................................... 0 gas gas 329 Explodes at 265 gas 5.6 40 4.1 71.2 1.3 45.5 1000 1076 600 960 No No No 0.697 1.332 1.227 0.632 0.069 1.18 3.61 10 -435 -117 338 92 79 -422 -76 545 158 4 4 4 1,2 Indooene.............................. Indonex .............................. Isobutane.............................. Isobutylene........................ Isobutyraldehyde .... Xsoprene.............................. 2-Methylpropane . . . 2-Methylpropaual . . . (CHaJaCHCHa........................ (CH3)2Chch6............... CHj=C(CH3)CH=CH2 . . 170 450 gas -40 -65.2 1.8 8.1 490 428 1.064 0.9958 0.600 0.813 0.676 2.35 310 10 19.6 146 63 4 3 3 Isopropylamine .... Kerosene............................. Lactol Spirits .... Lanolin ...... Lard Uil (commercial) . . Monoisopropylaminp , . No. 1 Fuel Oil ... . Wool Grease .... (CIW2CHNH2 ..... 110-165 7 or less 460 395 -35 560 1.16 6.0 490 ....fIt 4' 590 833 833 No Yes Yes 0.68 <1 <1 <1 4 100 28 89 3 2,3 3 1, 2, 8 1. 2.3 Lard Oil (pure) . . . . Lead Tetrnmefhvl . . . Linseed Oil ..... Lubricating Oil, Mineral . Paraffin Oil, Includes motor oil........................ Pb(CH,)<.................................... 500 435 635 300-150 1.8 820 500-700 Yes Yes No 1.995 9.20 -is 0.93 -2 <1 230 600+ 1,2,3 1. 2.3 1.2,8 1.2,8 Magnesium (Powder or Chips)*.............................. Maleic Anhydride . . Manganese (Powder)* . . Menhaden Oil. . . cls-Butenedioio Anhydride Pogy Oil......................... Mg................................................. (CHCOHO............................... Mn.......................................... 218 435 240 No 890 No 828 Yes U05 0.927 3.38 1200 127 2300 2018 366 3450 5 1.3 6 1. 2,3 2-MeroaDtoet.hn.Ti nl 2-Hydroxyethyl-mercaptan HSCHtCHjOH ..... 165 Mesityl Oxide . . . 4-Methyl-3 penten-2-one . (CHaJjCCHCOCHs .... 87 652 Metaldehvde . . . m-Acetaldehyde . . . (Cs&O)..................................... 97 135 No Methane .Methoxy Ethyl Phthalate Methox................... gas 6.3 13.9 699 No 275 370 No .Methoxytrlglyool Aoetate Trictbylene Glyool Methyl Ether Aoetate . . . CHiO(CH2)20(CH2bO(CH;)2 OCOCHl............................... 260 Methyl Acetate .... Methyl Acetoacetate . . . .Methyl Acetone (Mixture) CH3COOGH3........................ CH3COCH2COOCH3 . . . 15 180 0 20 4.1 13.9 935 No No 15 Methyl Alcohol .... Meihylamine, mono . . . Methylaminc--30% eol'n. .Methyl Amyl Ketone .. Methyl Bromide .... Methanol............... Arrrinnefh&nA Heptanone-2 .... Bromomethane. , . . CH3OH....................... CH3NH2....................... CHj(CH2).COCH3 .... CHsBr ....................... 54 60 0 gas 32 120 practically 6.0 36.5 ( 878 No non-flaiamiable 13.5 11.5 998 No 2-Methyl Butadiene-1.3 . .2-Methylbutene-2 .Methyl n-Butyl Ketone Methyl iso-Butvl Ketone . . . Methyl Butyrate .... 2-Hcxanone............... 4-Methyl-2-Pentanone . CHjCdfCHiijCHa . . . . CH3COCH2CH(CH3)2 . . . CH3COOC3H,........................ 73 57 65 1.22 8.0 No No No 1.116 0.858 2.70 3.40 6.06 0.554 475 -300 316 266 -258 3~ 3 1.3 4 1. 2,3 1.094 0.925 1.077 7.11 2.56 -146 4.00 82 0.792 0.699 0.816 1.732 0.686 0.6631 0.830 0.803 0.898 1.11 3.91 3.27 -144 -134 -135 3.15 r70 3.45 -121 3.45 <-142 266 140 338 117 19 303 40 63.2 101.0 262 244 215 3 3 1.2,3 3 3 3 8 2,3 2,3 2,3 2,3 Methyl Carbitol .... .Methyl Carbitol Aoetate Methyl Celloeolve . . . Diethylene Glycol Mono- methyl Ether. . . . .Diethylene Glyool Mono- methyl Ether Aoetate Ethylene Glyool Mono- methyl Ether. . . . CH3(OCH2CH2)!OH . . . .CH3COOCjH.OC1B.OCHs . CH3OCH2CH2OH .... 107 200 r 180 115 ... ... 1 551 No No No 1.035 1.039 0.966 i.u 2.62. Methyl Celloeolve Aoetate . Ethylene Glyool Monomethyl Ether Aoetate . CH3COOCH2CH2OCH3. . . 132 no No 1.005 1.07 Methyl Chlnrirtn CH3CI.................................... gas 8.1 17.2 1170 No *0.92 1.78 -142 Methyl Cyclohexane . . . Hexahydrotoluene _ . CtHu........................................... 25 1.15 . No 0.770 3.38 -195 Methyl Cyclohexanol . . Hexahydromethyl Phenol. CjftsOH.................................................. 151 ... No 0.993 3.93 379 1,3 409 2,3 255 3 289 3 -11 4 214 2,3 829 1, 2, 3 Methyl Cyclohexanone . . Methyl Cyclohexyl Aoetate . MethyldlfthanrtlomfnA Methylene Chloride . , . Methyl Anon .... Dlebloromettuuu . . . CHjCsH.CO ...... CsHieOj.................................................. CHaNtCHjCHjOH), . . . CH2C12......................................... 118 117 200 t . DIM 16.5 65.0 1185 inO> InO, No No No 0.925 1.013 1-836 3.86 537 ___ 1.11 9*05 . . -143 825 2,3 2,3 ioi 8 ..... ioi 1..23 I- DSW 587858 STLCOPCB4093194 Page 10 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) No. 36.10 NAME Methyl Ethyl Ether . Methyl Ethyl Ketone Methyl Formate . Methyl Glycol Acetate Methyl lactate . . . . . . * . . . . . Methyl Monochlor Acetate . Methyl Fbthallyl Ethyl Glyoollate........................ Methyl Propionate . . . Methyl-iso Propyl Carbinol . BYNONYMS FORMULA Methoxyethane . . . 2-Butanone........................ Methyl Methanoate . . CHiOCiHs , . . . . . CH3COC2H5.............................. CHsOOCH.............................. (CHaJsCHCHjCOOCHs -` .. . CH3COOC2H&........................ CsHbO ....... Flash Point F. Closed Cup -35 30 -2 111 121 Open Cup Explosive Limits % by VoL In Air Auto Ignition Temp. Lower Upper F. Suscepti bility to Sponta neous Heating 2 1.81 4.5 2.2 @ 212F. 10.1 11.5 20.00 ... ... 374 660 853 726 No No* No No Spedfio Gravity (Water * 1.00) Vapor Density (Alr= 1.00) Melting Point F. 0.697 0.805 0.975 1.08 2.07 2.48 . -123 2.07 -148 4.07 Bolling Point F. Suitable Extin guishing Agents p0 3 176 3 90 3 3 2.2 3 lie 125 1.227 3.74 269 3 375 380 28 103 No >1 1. 2,3 No 0.915 3.03 -120 176 2,3 3.03 3. Methyl n-Propyl Ketone . Methyl S&lioylate . . . Methyl Vinyl Ketone . . Mineral Oil........................ Mineral Seel Oil (typical) . 2-Pentanone .... Oil of Wlntergreen . . . See Lubricating Oil . . Signal Oil........................ OHsCOCJIt . . . . . . HOC6H4COOCH3 .... CH3COCHCH2........................ Mineral Bpirits .... Turpentine Substitute. . Monocresyl Diphenyl Moaofluorodiohloromethane Freon-21 ........................ (CHFCb) . ........................ 45 60 214 225 20 42 380 170 255 85 110 450 450 Practically non-fl&mmable 1.65 0.77 @ 212F. 8.15 850 475 1026 No No No No 0.812 1.182 2.96 6.24 -108 18 0.80 >1 3.9 216 3 432 1.2,3 177 2,3 1, 2,3 1. 2,3 300 2,3 1,2,3 Monofluorotrichloromethane. Morpholine........................ Naphtha, Coal Tar . . . Naphtha, Safety Solvent . Freon-11 ..... Hl-Flash Naphtha . . . Stoddard Solvent . . . CGlsF.......................................... 0(CH2CH2)2NH........................ non-flammable 100 666 100-110 100-110 i.f 900-950 6.0 450- 600 No Yes No No f.ooi 1.02 <1 6.8 76 3.00 262 3 300 1. 2,3 <-50 300-400 2.3 300- <-50 400 2,3 Naphtha, V.M. A P. . . . Naphthol, beta .... Napthylainine, alpha . . Petroleum Naphtha . . White tar........................ E-Hydroxy Naphthalene . CioHg.......................................... C10H7OH.................................... CioH7NH2................................. 20 174 307 315 0.92 6.0 450- 500 190 0.9 6.9 1053 340 No No No No 0.75 1.145 1.22 1.171 3.75 4.42 4.97 4.93 <-50 176 252 122 212320 424 647 672 2,3 1.3 1.3 1.3 p-Nltroaniline........................ Nitroanlline, alpha . . . Nitrobenzene........................ Paranltranlline .... Nitrobenxol........................ CioHhNz.................................... (NCLXN&XML .... CsH5n62........................ 470 390 190 828 Yea 0.75 4.0 471 1.8J@ 200F 864 624 0.92 1.009 1.437 1.2 84-106 1. 2,3 6.61 <175 476 3 295 >645 1.3 4i2S 42 412 1,2.3 Nitrocellulose (Wet with Solvent) . . p-Nitroohlorobenxene . . NHroethane........................ Nitroglyoerin........................ p-Nitroohlorobemol . . Trlnltroglycerol . . . Coii.eiNO?.............................. C3H6N02.............................. C3H6(NO,)3 ...... 40 261 82 Explodes Nttronaphthalene, alpha. . 1-Nitropropane .... 2-Nttropropane .... Nitropyridlne ..... ClloNO; ..................................... CioSiNO, .............................. CH3CH2CH2N02 .... ClLCHNOiCHs........................ 95 327 p-Nitrotoluene .... m-Nltro-p-Toluldlne . . . Nonane-n.............................. Non Ethylene Glyool Hexarielnoleate . . . Methylnitrobenxene . . Nonyl Hydride .... CHaCi&NO,........................ C7HeNH2N03 . . . CBH20.................................... 223 315 88 106 112 120 103 345 630 ..... [ 778 |y Bis i ' 785 789 802 726 0.74 2.9 No No No 1.52 1.052 1.601 1.139 1.331 1.003 0.692 1.286 1.312 0.718 6.43 2.68 7.84 2.11 6.96 3.06 3.06 4.72 6.80 4.41 isi -130 -19 140 -164 -135 413 126 241 -80 ... 488 1.3 237 3 214 3 679 1.3 268 3 248 3 1,4 460 1,3 1.3 302 3 1.2.8 Non Ethylene Glyool Ootane-n.............................. Oolanes-iso (Commercial trade).............................. Octyl Hydride .... CgHie.......................................... CaHlg.......................................... 05 66 0.84 3.2 450 No 10 No 0.706 0.751 3.80 8.93 -69 1,2,3 257 2,8 210 2,3 Ootyl Acetate-n .... p-Octyl Aloohol-n. ... Ootyl Aldehyde . ... Ootylene Glyool .... OlebAcld ...... 2-Ethylhexyl Acetate . . 1-Ootanol........................ 2-Ethylhexanal .... 4,6 Octane Diol . . . Red Oil.............................. C.aCHCiHsCHjCOOCHj . . CHilCHgltCHiOH .... C7H15CHO . . . [CHstCHiLCHOHh .... CigHsaCOOH ...... 180 178 125 230 372 190 265 No 0.885 6.93 -37 No 0.827 4.48 3 No 0.821 4.41 635 0.939-0.943 6.05 685 Yes 0.891 i3 410 1,2,3 881 2.3 350 2, 3 476 1,2,3 432 1. 2,3 Oleo Oil.............................. Olive OU.............................. Sweet Oil........................ Palm Oil.............................. Palm Butter .... 450 437 236 0-80 421 315 Yes 0.915 826 Yes 0.910 No 0.85-0.95 Yes 650 Yes 0.92 2 21 136-230 80-110 464 ... 1.2,3 1. 2,3 1.3 2,3 1.2,3 Palm Kernel Oil , Paraffin Chi........................ Paraformaldehyde . . . Paraldehyde........................ Palm Nut (HI ... . See Lubricating (HI . . Paraform........................ 2,4, 6-Trimethyl- 1,3,5-trioxane . . . HO(CHjO)nH ..... (CHaCHO), ............................... 328 360 158 63 430 200 1.3 Yes 0.85 78-86 .... 1.2.3 473 No 0.88-0.82 572 No 110-140 >700 sub. >100 i. 3 1.3 460 4.55 ... 255 1.8 Eatohung (HI ... . 640 833 Yes 0.82 87 1.2,8 Amvl Acetates (Mixture) . 98 106 0.86-0.87 260 2.3 Amyl Hydride .... CHaCHaCHiCHaCHa . . . <-40 1.4 8.0 688 No 0.631 2.48 -206 97 2,3 Pentane-iso (Comm, grade) . Iso-amyl Hydride . . . CsH,2............................................... <-60 0.625 . 2.48 ... 80-86 2.8 Pentanedlone........................ CH3COCH2COCH3 .... i05 0.976 8.45 ... 284 3 p-ter-Amylphenol . . . C5H11C6H40H ..... 232 0.61-0.94 PeriUaOU.............................. 622 ... Yw 0.83-0.84 Petrohol 91%........................... 66 ... ... 895 .. .... Petrohol 68%........................... 62 ... 845 Petroleum, Crude . . . 20-90 ... No <1 195 23 ... - ... 482 1.2,3 1,2.8 3 8 2,3 Petroleum Sulfonate . . . Phenanthrene........................... Phenol . . ........................... Phenyl Celloeolve . . . Petroleum Naphtha, Benzine........................ Petronste........................ Fhnwnthrin .... Carbolio Add .... Ethylene Glycol Monophenyl Ether . . CmHio............................................... Cs&OH ..................................... CtHsOCa&OH........................ -60 176 1.4 6.0 400 * . 475 .... 1S6 . 1818 260 ... .... No 0.63-0.66 2.60 <-100 100-160 2,3 .. .... 1,2,8 No 1.063 o!u 212 644 1.2.3 No 1.07 8.24 108 158 1.8 No 1.108 -- -** ' 473 L a DSW 587859 STLCOPCB4093195 * > I I I No. 36.10 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) Page 11 NAME SYNONYMS FORMULA Flash Point F. Closed Open Cup Cup Explosive Limits % by Yol. in Air ignition Temp. Lower Upper F. PhenyldiethanolATnine . . p-Phenylene Diamine . . Di&minnhflnj.pnft Phffnylflt.hftTmlnminpi . . . Phenyl Ethyl Alcohol . . Phorone............................... Benzyl Carbinol . . . 2. 6, Dimethyl-2-5 Heptadien-4-One . . CeHsN (CHrCHiOH)! . . . CH<(NHt)i . . . . . . CeKUNHCaCHjOH . . . CtHaCIfeCHiOH .... (CHs)aCCHCOCHC(CHa)2 . 312 216 375 305 185 .... Phorone-iao ..... Phosphorus (Red) . . Phosphorus (Yellow) . . Phosphorus Sesquisulfide Phthalic Anhydride . . . ^ . . 3. 6, 6-Trimethyloyclohexene-2-one-l . . Tetraphoephorus Trisulfide COCHCCHaCHaCfCttOiClfc . P. . . . . . . . . P................................................. P<Sa ....... . CeHi(CO)jO ............................... 305 205 330 a 500 86 212 1083 Picdine, alpha . . . . Picrio Acid........................ Pine Oil ...... Pine Pitch........................ Pinene, alpha........................ Alpha-methyl-pyridine Tnnitrophenol . . . . CjBLNCft.............................. .' (NO,)sCHi(OH) .... Explodes 172 285 CioHie.......................................... 61 85 175 ... 1000 <572 Pine Resin........................ Pine Tar.............................. Pine Tar Oil........................ Polyamyl Naphthalene . . Polychloropentanes . . . Colophony........................ Wood Tar Oil ... . 370 430 130 255 144 360 175 671 Polyethylene Glycol 200 Mixture of Polymers . Polyethylene Glycol 300 Mixture of Polymers . Polyethylene Glycol 400 Mixture of Polymers . . . . 350 385 ... 435 Polyethylene Glycol 600 . . Polyvinyl Alcohol Mixture of Polymers . . Potassium*........................ Potassium Xanthate . . . Propanalamine-iso . . . Potassium Ethylxanthate . K................................................ KCaHiOSj.............................. CH8CH(OH)CHaNHj . . . 205 475 176 160 6.5 Propane ...... Propionic Anhydride . . . Propyl Acet&te-n .... Propyl Acetate-iso. . . . Propyl Alcohol-n .... nimpthylTTiP.f.hnTift . . , Prop&noio Anhydride . . Propanol-1........................ CaHs.......................................... (CHaCHiCOM)........................ C3H7OOCCH3 ..... CHaCOOCHCCROa .... CILCHfCHlOH........................ gas 68 43 56 23 73 105 70 1.77 8.0 60 1.78 7.8 85 2.16 13.6 874 860 812 Propyl Alcohol-Iso. . . . Propyl Amine-iso. . . . Propyl Benzene-n. . . . Propyl Benzene-iso. . . . Propyl Chloride-n. . . . Propyl Chloride-iso . . . Propylene.............................. Propylene Chlorohydrin . Propylenediamine . . . Propylene Dichloride . . Propanol-2........................ 1-Phenylpropane . . . Cumene.............................. 1-Chloropropane . . . 2-Chloropropane . . . Propene .............................. l-Chloro-2-Propanol . . 1, 2-Diaminopropane (anhydrous) .... Dichloropropane-1,2 . . CH3CHOHCH3........................ (CHaWJHNH,........................ CjHtCbHs ...... CtHsCHfCHs)!........................ C3H7CI.................................... CHaCHClCHa........................ CaHfi.......................................... CHsCHOHCHsCl .... CHjCH(NHs)CHiNH! . . . CHaCHClCHiCl........................ 53 86 102 <0 -26 gru? 125 66 60 2.6 -15 852 ;W 2Sl 10.5 2.87 10.7 2.0 11.1 t 1100 627-652 120 65 3.4 14.6 1035 Propylene Glycol .... Propylene Oxide . . . . Propyl Ether-iso. . . . Propyl Formate-n. . . . Propyl Formate-iso. . . . 1-2 Dihydroxypropane 1-2 Epoxypropane . . 2-isopropoxypropane . Propyl Methanoate . Isopropyl Methanoate . . . . . CHaCHOHCHiOH .... CH3CHOCH2........................ (CHa)iCHOCH(CHa)i . . . C2H7OOCH.............................. (CHa)jCHOOCH .... 210 >36 -18 27 22 225 2.62 12.55 790 2.1 21.6 -15 830 Pyridine ...... Ptopyl Fropionate-n. . . . Pyroeatechol........................ Quenching Oil........................ Rape Seed Oil........................ 1,2-Benzenediol . . . Colza Oil ..... CH(CHCH)*N........................ CHaCHsCOOCHsCHiCHa . . C5H.(OH)j.............................. 68 261 365 325 1.8 12.4 1065 176 405 650 836 Resorcinol.............................. Rosin Chi.............................. Rubber Cement .... Rum................................... Signal Oil.............................. Retinol.............................. Mineral'Seal Oil . . . CtH.(OH)2.............................. 261 266 77 200 648 Sodium*.............................. Na . ..................................... Soya Bean (hi .... 540 Sperm Oil No. 1 . . . . 428 No. 2 .... 460 ... Bteario Acid........................ Octadecanoic Aoid . . . CHa(CHj)igCOOH .... 385 '425 833 586 '743 Straw Oil........................ Styrene.............................. Sulfur . . Sulfur 1 .hliwMa Tallow .... See Lubricating Oil . . Yinylbenxene .... CetUCUCH*........................ S................................................. SaCla.......................................... 315-361 60 405 246 506 440 None 1.1 6...1. 914 450 453 Tallow Oil . Tannic Acid . Tartaric Add . Terphenyta........................ Terphenvl-m. . Tannin . Racemic Add .... 1,2-Dipbenylbeniene . . HOOC(CHOH)jCOOH.HaO . CJWCJL),........................ 492 300 410 325 376 >8 Terphenyl-p.................... Tetrachloroethyle&e . . . -Tetradecane . . Tetradecanol .... Tetraethylene Glyool ! ' 1.4-Diphenylbensene . . Perohlorethylene . . , Tetradeoyl Aloohol . . 0^.(0,),........................ CCliCCl,............................ HOfCiELOIaCtlLOH . . . 405 nniuflaTTifnAhta 212 285 345 05 Tetraethylenenentamine ...Tetrahydrcfurfuryl Alcohol . l5F*hrdrenaphthalene . , TaUdme TetraUn........................ NHi(CHiGHiNH)iCaCH.NH! C.H70.CHiOH................... 165-176 CioHu................................. 171 325 'ij a --- . . TrimethyH, 8.6- DitUanse .... SCH{CHi)SCH(CHi)NHCHCHi 200 a ... 980 802 Spontaneous Heating No No No No No No No Yes Yes Yes Yee Yee No No No No No No No No No No No No No No No No No No No No No No Yee No Yee No Yee Yea No No Yee Yee No No No No No No No Gravity (Water* 1.00) Vapor Density (Air* 1.00) Melting Point F. Boiling Point F. Suitable Extinguishing Agents 1.1203 1.067 1.024 3.72 4.21 136 284 -16 1,3 512 1,3 546 1* 2,3 430 1;2|3 0.879 32 338 1,2.3 0.623 2.30 1.82 2.03 1527 4.77 s.io 1337 112 342 262 419 1.3 1 549 1 76$ 1 543 1.3 0.952 1.763 0.86 0.86 7.90 250 148 262 3 1 1,2,3 460 1.8 312 2,3 1.08 0.862 0.92-0.93 133 212-300 1.3 208 2,3 3 1,2,3 345 1,2,3 1.12 1.13 1.13 1.13 0.862 1.558 0.6619 1.012 0.860^ 0.877 0.804 0.789 0.586" 0.862 0.864 0.860 0.869 1.113 0.873 1.15 1.040 0.856 0.73 0.906 0.873 0.682 0.885 1.344 0.9 0.615 1372 0.98-1.1 258 1.56 4.49 352 3.52 2.07 2.07 2.00 4.14 4.14 2.71 2.71 1.49 8.26 256 3.89 2.62 2.00 352 8.03 3.03 2.73 3.79 8.79 144 d.>392 -310 -134 -09 -197 -122 -152 -162 -188 -170 -301 <-112 <-76 -135 ... -44 -104 221 63 230 ... 1366 318 -45 836 215 164 207 181 138.2 316 311 115 95 -58 261 246 205 370 95 156 178 153 239 245 474 626 >680 0.97 0.925 0.847 0.907 2.046 1.687 0.895 0.914 1.667 1.14 1.164 1336 1.623 0.765 0.835 1.126 0.998 6.973 208 1612 72 950 7 '726 3.60 4.66 ...J 7.95 7.65 7.95 6.72 6.85 739 653 852 455 -24 234 -112 88-100 109 d592 284 .. 188 415 -8 41 ... -24 296 832 280 630 685 769 248 486 607 621 631 403 1.3 1,8 1.3 1.3 1,3 5 1.3 1.3 4 1,3 2,3 2,3 3 3 1,3 2,3 2,3 8 3 4 3 3 2,3 1.3 3 2,3 2,3 2,8 8 1,2,3 1,3 1,2,3 1,2,8 1,3 1.2,8 1.2,3 8 1,2,3 5 1.2.3 1,2,3 1.3 1,2,8 2,3 1 1.3 1,3 1.8 1 1 1.3 1.8 L3 1,2,3 1,2,8 1.3 1.8 156 5.63 1X3 A Lll DSW 587860 STLCOPCB4093196 Page 12 PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND SOLIDS--(Continued) No. 36.10 NAUR SYNONYMS FORMULA Flub Point *F. Closed Open Cup Cup Exnloehre Limit* % by VoL in Air Auto> Ignition Temp. Lower Upper F. oToiuldine c-ToIoldine................... o-Tolyl p-Toluene Sulfonate Trlainyl Beneene .... Tiibutybunine .... Metbylbeuene .... o-MethylanBhie . . . p-MettudaniUne . . . Tianifonner Oil . . . SntCHj). ... . . . . CACHi ............................. CHiCaH.NHt ..... CHiCtILNHj................... CuHmOiS............................ (CeHu)iN . . . . . (U&uJaUftU*.......................... B(CeHiiO),........................ (CiH.).N . . . . . . . "io "45 185 188 205 883 .... 295 ___ 215 __ 270 __ 180 .... 185 1.0 127 72 ttT ... -T- aaa ... ... __ ... __ ... ... ... ... ... ioio 900 900 .... .... .... .... .... .... Trtbqtyi Citrate .... (C&COO&H.bCOHCOO 1 ' CiHf............................ 815 865 nee a* 005 Tribatrl Phosphite . . . (C.H.).PO........................... a... 295 a tu .... Trichlarobeniene .... Triehlorotnaeol . . . CeHjCU . . . ... . 210 ... Trichloroethylene. . . . CHC1CC1, ........................ nrmtr.afl&dmctnawllyKU a a a i - - - o-Tricceeyl Fhoephate . . o-Tolrl Phoephate . . . (CHiCeHU.PO.................... 460 504 ... .... Triethanolamine .... TVyhyltmlns . . TViethylene Glywl . . . Triethrlene Tetremine . . Triflucrotrichlcromethane . Dieaproate ...... Freoo-113 ................... (CHaCHtOHjjN ..... (CiHt).N............................ (CHjOCHsCHiOH)i . . . HiNCHi(CH,NHCHi)jCHjNHi (CtF.CU)............................ 865 885 20 '850 885 275 290 praet cally noo-fla unable . . . .... oio 920 '700 a.. ... 640 ... ... 1250 Trirlyool Dlohlcrlde . . . Trileopnwinltmbe . . . Trimethyicyolnhsiannl . . Triaxane........................ 8,8,5-Trlmethyt Teloberanol-l . . . ClCHefCHeOCHjhCHiCl . . [(CHj)^OH1,N................... CHiCH(CHj)CHiC(CH,)i CHjCHOH................... (CHK))i............................ 250 ... ... .... . 806 ... ... . 165 . r 118 857 88.70 777 Triphenyl Phoaphatc. . . (CJLJjPO,................... . . 428 ... Tuna Oil........................ China Wood OQ . . . 562 .... ... ... *855 476 - l ... 833 95 02 ... 488 Ultraeene........................ Eeraeoe (deodorised) . 175 180 ... ... .... Undeeanol......................... LlbliftiMiuuiU . . . . Ca.CH(CdW(^H, CH(OH)CHi................... 285 ... .... <80 .... ... ... Yambh Shellan .... 40-70 ... . ,, .... VamoUne........................ Safety Sotrent .... 109 180 a*. .... Veaetable OH, Hydrocenated 510 ... ... .... Vinyl AoeUte................... CHjCOOCHCHj .... 18 80 800 Vinyl Chloride .... Chlomethene .... CHjCHCI........................ CM Vinyl CydoheuM . . , 4-Vhud Crdoheienfrl . . CsHu................................. 01 <0 4 83-jj .... 74 ... ... 1 617 VbjiJdene Chloride . . L l-Dichkroethylene . . 14 .... 7 io| d. Vlad Ethyl Ether . . . <-50 ... 895 Vinyl S-Ethylbexyi Ether . Vinyl Iaoprond Ether . . While Oil........................ Whlakay . . . . . . Whm 8berryAPort .... fiUk....... 116 140 ... ... 895 *28 446 .... ___ ... ... ... ... 522 800 82 .... ... ... .... 139 .... 00-80 ... o-Xylene........................ oXyiol........................ CaH4(CHs)i........................ 68 75 12 02 921 o-XyUdine. . . . . . o-Dnnethyi Aniline . (GHihCeHiNHj................... 206 Shu (dost or powder)* . . One Stearate................... Zn...................................... .... .... ... ... .... Zn(CuHitOi)t................... .... 580 ... ... 790 firoonhnn (Powder) . . . ...................................... Zr . .............................. ... 600 bility to Bpontaneons Heating No No No No No No No ,. No No No No No No No No No ,, No Tee No Yea No No .. a. * .. Ya * * No No No No Specific Vapor Gravity Density (Water- (Air* 120) 120) 1214 0260 0.099 0.978 .... 814 8.09 8.09 .... 02 0.79-020 027 0245 0.78-0.70 728 .... 028 Meltlni Point F. -iii 8 111 ... ... ... <4i Rrflinf Point F. 172 232 292 192 .... 453 676 430 417 Suitable Eitia- pwhtin Agent* 2,8 2,3 1.2.8 1.2,8 1,8 .1 2.8 .1 2.8 1.2.8 .1 2,8 1.2,8 .... 0278 145 12.41 *4 920 <-112 .... 45 .450 1.8 800 1 2.8 416 >8.8 1.47 423 -09 189 .... .... ... d.770 1,2.3 US 8.14 08 680 1.8 0.78 8.48 185 2,8 1.125 6.17 *28 550 1.8 0282 54 582 1.8 .... .... ... .... 1.197 1220 .... ... ... 405 1.8 670 1,8 0278 431 . ,, 388 1.18 147 Sub. 230 18 .... 122 750 1.8 034 .... 88 1.8 .... ... 1,18 <1 424 ... *800 18 ... .... 1,18 0280 .... .... <1 037* 0280 L25 .... 0325 .... 028 039 .... .... ... ... .... ... .... ... .... ... <-76 115 050 .... ... .... ... .... ... .... ... .... .... *82 .... ... ... >26 117 .... - -17 <5 787 2002 487 .... .... .... .... 101 7 Me 99 .... .... .... .... .... SOI 435 1700 >5350 1.1S V V IS 8 i S1* May 1950 (Sopereedca Jan. 1945) Flitted In U. & A. 1 - ' DSW 587861 i, i \ STLCOPCB4093197