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P.c.b.s--as safe as salt?
Polyrhlor.nated biphenyls, widely used as liquid dielectrics in transformers, have been blamed for causing cancer and their use is now tightly controlled in Britain and the US. Many of the fears about these chemicals are unjustified, however, according to Monsanto, a former manufacturer.
Though reputed to be carcinogenic, poly
chlorinated biphenyls (p.c.b.s) are actually
no more dangerous than table salt, accord
ing to Monsanto, a former manufacturer of
the controversial chemicals.
This opinion, if substantiated, will be
welcome news to hard-pressed US utilities
who are now faced with the task of dis
posing of thousands of tons of the material
each year (see Electrical Review,
1 October).
.
"Standard toxicity tests demonstrate that
p.c.b.s are less harmful than table salt,"
says the company. In addition a review of
recent international health studies on the
chemical "do not provide the exposure-
related results that would justify concluding
that p.c.b.s are carcinogenic in human
beings," says Dr William Gaffey, manager
of epidemiology with Monsanto.
First produced in 1929, p.c.b.s are com
pounds of carbon, hydrogen and chlorine
which are chemically inert and fire resis
tant. They also display good arc resistance
and high electric strength which soon
brought them to the attention of designers
of heavy electrical equipment, particularly
capacitors and transformers, and since the
1940s they have been widely used in askarel
liquid dielectrics. These fluids, perhaps
better known under one of their trade
names--Pyrochlor, Aroclor, Inerteen or
Pyranol, for example--comprise a mixture
of p.c.b. and trichlorobenzene which
reduces the viscosity of the p.c.b.
For more than 30 years, askarel-filled
electrical equipment was chosen, in the US,
in most high-rise buildings, schools,
hospitals, and industries where fires or
explosions were of particular concern.
A wide range of other applications for
p.c.b.s has also been found including
hydraulic and heat transfer fluids,
lubricants, surface coatings, printing inks
and adhesives.
Since the late 1960s, however, use of the
substances has been severely curtailed
because of fears about their toxicity and
their persistence in the environment.
One of the most widely publicised scares
about the health threat from p.c.b.s
occured in 1968 in Yusho, Japan. Some
1.000 people became ill after eating cooking
oil, which was contaminated with up to
3.000 p.p.m. of p.c.b. Symptoms included
skin discolouration, acne-like conditions,
eye discharges and central nervous system
irregularities. Though p.c.b.s were initially
! blamed for these problems, they are now
: generally thought to have been caused by
j impurities in the oil.
> Since then the compounds have acquired
a reputation for being highly toxic to fishes
' and birds and have even been blamed for
inducing cancers in humans. These fears were exacerbated by the belief that the com pounds are extremely resistant to biological breakdown and have half lives of hundreds of years.
In response to these worries, Monsanto phased out sales of p.c.b.s for applications which could lead to environmental releases between 1970 and 1972. Sales were then restricted to selected customers solely for use in totally enclosed electrical equipment. The US Government approved continued production of these uses, until effective substitutes could be developed, to prevent disruption of the country's power transmission systems.
In 1976, however, the Toxic Substances Control Act was enacted which included provisions for the total regulation of p.c.b.s. Monsanto ceased production of p.c:b.s in the following year and, in 1979, the US Environmental Protection Agency banned future manufacture of p.c.bis.
As reported in this week's news, the EPA has recently followed this up with further restrictions on the use of askarel-filled equipment.
All this legislation is a gross over-reaction to a relatively innocuous chemical, accord ing to Monsanto. The company has "no intention or desire to re-enter the p.c.b. business", it says, but is concerned that the substance should be more accurately under stood. Because this has not been the case, there has been "needless public panic and over zealous, costly regulation", Monsanto says.
To support its claims, the company cites
some 24 studies on human exposure to
p.c.b.s which, it says, "show no relation
ship between any specific type of cancer
and p.c.b.s, nor any increase in overall
cancer mortality as a result of p.c.b.
exposure. Neither do they show a
connection between p.c.b.s and other
serious illnesses or death."
The studies include data on large
numbers of industrial workers who, over
many years, were occupationally exposed to
p.c.b.s at significantly higher levels than are
usually found in the environment. One
study, for example, involved more than
2,500 electrical equipment manufacturing
workers, more than half of whom were
exposed to p.c.b.s at work for more than 20
years.
A November 1981 review of toxicity
studies concluded "there is no evidence of
an excess in total mortality or in mortality
due to cancer, cardiovascular disease, or
nervous system disease associated with
occupational exposure to p.c.b.s. "P.c.b.s
have not been linked to any human cancer
and studies to date indicate it is highly
unlikely future studies will establish such a
link."
This evidence, however, seems unlikely
to persuade the EPA to withdraw its ban on
p.c.b. manufacture, and substitute 'fluids
such as silicone and complex estens are
gaining in popularity.
The UK situation is similar, with the
CEGB having installed no new askarel-
filled transformers since the late 1970s (see
Electrical Review, 1
May, 1981). In the
rest of Europe, how
ever, the superior fire
resistance of askarels
is more highly valued
and p.c.b.s. are still
being manufactured
in Germany, France,
Spain, Italy and some
Eastern European
countries.
Q
Removing askarel
dielectricfrom a transformer--are such precautions unnecessary?
Electrical Review Vol. 211 No. 11
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