Document peBmwoZx6DRv0V218GVnG214k

pt A1 cqzursimsooin0Da1t8e% 23 27m2001011980502 54 2a7m2m00o1919105s 7 a2m7a0nio1199320 &5 227722000011995338 1110 z277a010002200001s 112 2aavn0a20i7 w1w5 2270200120200398 1167 2270270010022004584 119 22007020201210018 221 aanmmmnotzozitaie 22 aammazoinn 2250 a2n7m0ao0i2oz1t4s 27 nanmmoa0v2ozz0e2s 22 apna0oi02zz17 30 mRo0z2e 32 amnoozzes 3354 2a0m0m2o3010 37% m amz on 330 a 270m 102t 340 w moze VialPosiioniSample Name 2SPPFECCOO1S0Nh 4SPPFECCISOOMLS P7PFRCC2oh P7 PECC20S000 CCV 259PKEIGCOI200T0190.0C01V 2827 KKIIO000I1001111..000023 2829KKIIOO0O100T111..000054 3310KKIIOOOOTIOOT1I1..000087 3523KKIIOOO0TTO0TT11..000089 3345KKIIOODIIO0TNI.O01N0 373KKIIO0OOIIO0H111..001123 3S08KKIIOOOOII0OII11..00T145 4S10KKIIOOOOOTTOTT.L0O1T6 342KIKCIOIIO01N11.001168 4454 KKQIIOOI0O01S1G.400210 448 KKQQ1I0O00006S6644..0032 4468 KKQQ1I0O0O006B6644..0054 2500KKQQI1000000682604..0018 222KKQQ1I00O006G2Z00.0052 21 KQIO0062006 APcraCukinonetMeexthtoocdnagm PPRrCOkKnnastteedronLgcodanamgm PPRECCknkentaextoonogddnaamgm PPrRCCkunneatetdeodnlgdodanamgm PPrFCCkinientsetdoxntgdodanamgm PPEFCCikiinneatteexxiLcdooaannmmgg PPFFCCkKnneettoexxLtddooaannmggm PPFCCkknneatteerxLoddoananmmgg PPEECCKKknneetteoxxddooaannmmgg PPFFCCkknieetteexxLtddooaannmmgg PPFFCCkKnnateetxeLodoaannmmgg PPFEGCkKnenteotxeoxngCdodnaagmm PPFFCCKknneettooxxtdodoananmmgg PPFFCCKknneatteexxtLddooaannmmgg PPFFCCkinneetteeuxLdodoaannmmgg PPFFCCKknieetteexxLdodoannamggm PPFFCCkKnnaetteexxLdLdoaaonmmng PPFFCCkKnneatteexxcLddooannamggm PPFFCCkKnnaetteexxLLdcooaannmmgg PPFFCCkKnnaetteexxLLdoodananmmgg PFCKetexLdoanmg GF2i1e7N1a0mCe.alongwit 0G221i771I0C0aCkaalngluownntagtt 002211771100CCAaLLoanngguuitt C021177I100CCaaLLoanngguultt C0a21T1I7OC1a0LaaCnngaguLt C022171170110SCaamlpalentsgtLownig 00221177110011SSaammooppnneeggvssiLLt 0G2211771100SaImSpaemsplsaLnowgnifg 002211771100SSaommpplloonneeggssLL GC2211771100SSaamrlleessLLoowwnniggtt 0G2211771100ISSaammppllesslLoaannnigtgt 00221177110011SSaommppeessLLoowvnniigglt 00221177101S0s1mSpeosmLpoolnngewwsiLft G02211771100SSaammlpelsLeosLgooonrgt 002211771100SSaommpllselsoLnogwnogtt 00221711701S0aSmalmepselLnegoanttgt G02211771100S1aSmapmlpslLeosnLgouinttg 0G2211771100IS1aSmapmlpelsLeosnLgownntfgt 0G2211771100IiSSaammppliessLLooanntiggtf 0G2211771100SSaammppllseLLooinntggtt 021710Sampionegosr.t 15PeAveaa (cok"nss)e 225r0s0327000 2257072050000 r29s78s00 2296057100000 2s8a0v4i0c00 S3a0a8e3s2t0o0 a33s2e2z0z000 f28r90e60e0 33058200130000 2so0g1re8m0o 026910500000 33104050000 327u3a600000 22590506i30000 2Z6a334e6i0000 220061760000 22505041080000 a20710200 22713650000 2508200 A0 EAS 2 figlte 402 2 |] iE |; | ill] ES ttl] :| : LER p2 i : I i iE 5 3s 5 % i 451 Si ENNNNNF3S3R8RARRRNARABE RNIRRREARRERAENR 3i 5H$l 23 : :TR HEEEiREEREREE REE EE ErekeE Bl EER EEEEE RENN zg Z le adI s LL Eii]lE: LElle Ez_lleEEEE ] p; EEEER EEE RE Fee Li j i SEL) ell EERE EEE EEEEERER 3 EoEeEEE EEE EE REERa FREER EEE : i EB flu | 5 |3fE0 3 a5 Z a Elan | 2 1551 || Hi Io . I2E341EEAE 825 liailia l3)ags fi Fez HE $i HEHEHE So [eH fs] it [3 HEH HElEeeHaEs H|EB]: iB.d% lf)eeiie g fsfzt EBf i, ' L ;; i i 3 qe ; g |68)14 2 PEI i HBO [T) | 3 <2 Eg 3J 3 J 1 TOHEO H T of [4 HETIL TLL y G i| RATE 3SE Ee Lh ibe bbee etbtmy, 3 g EEE EEE EEE EEE EER ERE LE EEE EEE EEE EEE EEE RE EEEEE FIL SDENENSSESSEESNSAERSNRRMMRN EA EEEE EE EE NN lbIz 3 EHE A IA LAEBA EL ALLL ill lilalelelelseo = colelose ellaessallees) EE 3 of; & 32 . yy PAS Columbia Analytical Services~ roa wn was Ps -- February 22, 2010 Analytical Report for Service Request No: K1001011 David Anderson Camp Dresser & McKee, Incorporated 325 John Knox Road Building M, Suite 100 Tallahassee, FL 32303 RE: Baron & Budd, P.C./95779-75319 Dear David: Enclosed are the resultsofthe samples submitted to our laboratory on February 04, 2010. For your reference, these analyses have been assigned our service request number K1001011. Analyses were performed according to our laboratory's NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.caslab.com. All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. PPlDeiavsveelcaal@lciafsyloaub hcaovme any questions. Respectfully submitted, Columbia Analytical Services, Inc. My extension is 3281. You may also contact me via Email at WH Project Chemist PD/afs Page 1 of 34% ASTM ALA CARB CAS Number crc CFU DEC DEQ DHS DOE DOH EPA ELAP cc Gems LUFT M MeL MDL MPN MRL NA NC NASI ND NIOSH PQL RCRA SM TPH w Acronyms he American Society for Testing and Materials American Association for Laboratory Accreditation California Air Resources Board Chemical Abstract Service registry Number Chlorofluorocarbon Colony-Forming Unit Department of Environmental Conservation Department of Environmental Quality Department of Health Services Department of Ecology Department of Health U.S. Environmental Protection Agency Environmental Laboratory Accreditation Program `Gas Chromatography `Gas Chromatography/Mass Spectrometry Leaking Underground Fuel Tank Modified Maximum Contaminant Level is the highest permissible concentration of a substance allowed in drinking water as established by the USEPA. Method Detection Limit Most Probable Number Method Reporting Limit Not Applicable Not Calculated National Council of the Paper Industry for Air and Stream Improvement Not Detected National Institute for Occupational Safety and Health Practical Quantitation Limit Resource Conservation and Recovery Act Selected lon Monitoring Total Petroleum Hydrocarbons "Trace level is the concentration of an analyte that is less than the PQL but greater than or equal to the MDL. 2 + Theron See wemmineInorganic Data Qualifiers 7 4 DTTohoecNooELwlACaokterssebetiplniadble.eSdcahsekmev.l ts pe ive be pple osdecd by {3 hTThayerreeeasssonvomndedeootwtesaseted he dion ucieedemhdbeesarnattettsomveebroMsELsAe. TGDeh0ic0n 8MoRs37 doLhraLMiOdGnDLOLoerDowlncotdb os. mdar ietoes LD ot fa epic Te QX SSeeeeccoommamrmiiv.e Oeormr ality telcos us wide hei MetalsDats Qualiers 3 E. TThehpoemcmitsimssoewierhe eselowo entwadgutlr he1so5ninrsiosen miorc ele J ShTeeapsore Svkeewnpel-- eeetverreebsyth iconofee Sunodsar, SAesbd xn 45i0)n 0 DTe0m0i0efsooen feo oyowoe tbid(oNedeetraoreothBe4MLEOLNDL.cy prt The AW | TTJhheeopMioreRipiLoonrMLiOkOeQLLoOrfDsrcalAeAindles ot fom ln, we spl mi trac. haunt h S0% ope X Q TSSoeeecccooneesmnumirrnmniieve,eOfnieonrrbenMSabAy'cofonsult0s35v. o deen + Trois SeememeOrgans Dts Quatfiers A4 TNTichheeceiosmnselvweeueroddiisnpebometnepdiinlpe.tcShsdBchotskoaottnevlnttpof d e ive t he ple idef bye hfeeyves biel confirmedi CMS einen cen rby empath NDJE hTTThroehprreeendv1rpeeaossneptsisevoeedsTlohinoetintbtetsoseveeheediotucieaddehdelaslnivb io ntgael.tf osmagyssa mtstpn ermet, 1 Toone eyHPLCeldimebstlwtsdot setl.tThetoepstrth)vSMcRAs.nd en 80 D000 fo: ay wotGi co ep et LOD edyepret The X ToSeNeRAeMmDoLr LOL clemetd chrgepic rcs. PT F TTohecciumusomgtsic ggeeAdndipttoenrxalwePapellteertimolabetufismsdHeydcprhooiclnaorpsbtodnsoSopfeccbie,fticctQeubaliifnisernpsedte cisbe peo. . Hh Cc Trreeesvrseeve mooerspiletciae fe eet le ct laccoie A lSrfR Ac,dhectic be re of fTTehciehcutkmmgtgompephhiric p oapiiniof p fbueesrplse t e eisniebylpe,ilde pebceicnbepcrbst dorrs ies 2 Thc Sos dos st se pels rt. 3 bs Columbia AnKaellystoi,caWlAServices, Inc. State Certifications, Accreditations, and Licenses [ColoradoDPHE |. 1 Hawaii DOH - Idaho DHW - Louisiana DEQ LA0S0010 WAQ035 | 053-999-368 [NewMexicoBD I. ~~ 1 OOkrleaghoon-maDDHESQ Wisconsin DNR 1998386840 `Wyoming (EPA Region 8) - 1 Asu t ~~oS Em 4 bs Case Narrative 5 p10 COLUMBIA ANALYTICAL SERVICES, INC. SGrlaeejmenpcslte:Mars WBCaaomtnpdDrebsasedrd&PMCeee. DSeavrieneecReenqeusesst Nos SKIoodo1ioo11 CASE NARRATIVE mAEllrAaylyoarwteraepndpecfoofmmheaed aacoysnscsisateelndt rrwoiwslGthoeftquaalpcitihysaosfdsuosreapnmacencapdersoo.grraTWnhtoefnICsovpmlrbaieenAvoadyihecvalmaetSsheordi,nehsm,teiiInoo.g lk sh av bean poe wih sch natal ct. Sample Recent AeTceocgcaeadawioatrserosdamcCpolnepdsiotwoeneracnrdetcciovonetdnhefnoarbwnoilrlhthy,e aamCpoalnuymnbsAncalyhtiocaflcSoesrvoidcyefsoorn,0T2h0e41r.pTsheVsearmeplseosrewdes Peau Slane Acds and Peruana Carbosslie Acids b PLCS hJ CSooenmteeartheyso-- ntoefmdPadeCa1rmh tv1ee.2s.1a S3Cu2mluydeccTohnneoolliAHsctk.einBdLskbedCoonnvrhelesSeasmpdelep(aKdtQIi01o00nu6:e64wd-ae0tlsvas1s usreincoevdeatrthsae Seed woe mah ge expected for hs proce No fhe ores was ake SrTuhomeamadrreyc.orveeTryeeo,fiPmpseasmodT-re{lf1o2K-ea1w3"uC2aoideenScppaornaaaleyTAcmrseiln Vaiirll "svRauaswn"a,stiMduGeltdtoheopncoo"nstRoala,6ieAtinpoerstcrdNoi1rnthhcREla5ve"1, Tomsepocroneto.l iW.o rBeasredcaonnehseomsetahaodnaand torbeen da. Faves OPER WS RES GAPE dTThhaeemhreecdov"vaeaoryeoRvfomppPaeerrSafutotyerr 1o{rw1.ec2a-an3diClawJredeefcaianutodicdohtAaecipcdoosnsndvaPiresgaerntsrde{d121h-ce3or2leas.sdeasaumnmaaryAccTdhoinmITtelssma,a1 eTosodr ocnoehcetimncehsocdioanndwahsobreenGon he recovers sored we n he ngs Exped or tos GETS No eTheermsnloansvylaiofotPvedirsfaotprhic{o2ns-ee1e3iCn2sedroedoeds1a0nCuiclhuAceSidusahnadtSPeorllmoacroo.nn(tT1oh.e2T.itm3s,.s4-a1e3CdHd]oebltaheaomuesaschcd iaonndMruolydroocinn re savas hed wee ent pected fo procedure. No ahr comeet ahi wi AER -- oTMFhaevmipsSpoiskceheR-- eaecovvrereyeEoxfPceeprtiAoonmsctepShulefodnteuolr sawmapsleaMeAATstedr Raowk"OvaGsRoEsSe ctontAol r.eiNoeBsEe No ter name suited with he aalyss ofdhe samples wee wr LP Approved. 2 pad . p11 Chain of Custody Documentation 7 2 | <i e = i ll | LT :iit: = ih ) : EEmEAN HG J(== al F1l EEEREEEN Hk di wo R Og'R 08iyPLisog4 LH =e 3 REmERmmEEE 3: 3 a mEREES 8 BBS)y % 0 i S ; -- n fl : = HHH : <ff 5 A HHH 3B, 4 <0 Li Es H ] n safe :3 Ea Lal my Q =s SEs[1] g 5 1 = Tn EHHR ra TT Piriils H HLL 5 4 HeEB+i 2ERm Ins e FEa AE e CCr TTe 18: 2 ok5 fod (HTT CLE = |||hohbil| z fitie i n 2 i a aE Ts TM eTEs: gl 1% |- | 2 E2f; B d: 4ria43 dd3313 BAHT AAE EEEE Tak Hah 235 47I954s]&4871 43 8A Ik HE 3 2 R3a5e45dd 4R 2e E I J i giisf n :fjii5s:i 8 | LlBe 3 oo L! ! 4 A PEE | | --I[ | 8 RL I[SIs[1] 3S.s sal ENNAW ] Hl $I 7 2HE Lo i rt H le voy SEE is E | J : & i Hs] ik hg a ] 1 iif NS So ii IF 0 g4 Hi 1 ot. -- SH $i B TitFier a = S [EH RR H = be l R sel ss &oas| HH l, 3 d 83:: aE H RRE[R1E1S] i So H iH h &ElH HH H fog 3! = a 28 oe 2S 5ph aS H Sal 5i. j :5 3 2H 33 i 26 HH <23: Treeb HEE f Nclos F 5 ; j pia [223 d n 3| 33 3J3[3[3fz r E gi i z, t { Ndsi g Enes b Hl s | I "Hl 5 81] i E l 1E gai 1 a] ek t e e IS Feli1pe AC 31 3d m == Feeafiill | I !PlElEL 3 7, gE, iB LAEn Hl shi 3 |g 4 2 EE HA R | n | 1 3 45 ME i A : -- 3% i i A] 8 : rE 3 HEN i:1geg | | :H Sg Beri e BT 22i4) 2 T;e a ES amET A mEEH TETERTH EN i, oA) 2 5Hl5 I 3 E= TT] s: a5 l|g Hy EE ge ag SinEnHERHRH ENENR of Ra 5 =a Sh : mt Pi| ie Eg Toes oT EEEEEEE il| : o: =) ie5= = 5 5 olf 4i.3 r- 8 8e i wd mame TtTmI anunnife bfdH8 ii4sHe $ziireeE s 5 H RLr ET TT PR1iEhe: L:3li0 EE LEE 51 < 2 Es 12 |A = Be SL Emme i dG 8 EL 39 FE Ra g:1i4 =k1 Ld 39 ol 5 of of 2| Blo 7] EL, lfadl shi 2%, 32g isd HEHE 85 Ele 1 2 3H Ege S9ilLl | feElLiEs|] pailiaise i B00 AR CoolerReceipt and Preservation Form * TTT a Clien/t Project; - Received: Opened: Zam Z Servic quest K10_ iD 1 3. Samwerpe clsveedvsiet bal CFE) URS Sumwerpe rleceeivesdin:ccl) Ter, Box bHL PB {/ Cowie Ewelope Other HandDetvered ma 3. Werecusseat ls oo n codoley rs? NA N Ifyes,howmanyandwhere?_ 7% Ifpresent,werecustodyseals intact? N Ifpresent,weretheysignedanddated? &@ ~ FEETe TTT i ly L217 [ay Fore gpg| bpd THFTgp {| F457 Tz -- LegTrTyg 1 |] 7. 8 PWaecrkeincugsmtaotdeyrpiaapluesresdp.ropeInrsyerftisleIdoEutE(iEk,siBgunbeb,le Wrap GelPacks CWT Sleeves Other, NA ~ 5. Didllbotesamvingoodcondition (wnbroken)? nciin hecablaebeelo. 10. Werealsample bescomplet i. analysis preservation,etc)? NA N Na ~ HL. 12. DWiedraellapsparmopprlieatleboatasbctoanegsaanrleesswanidtvhocluusmtoedsyrpeacpeeirvesd? fnorithce sesmtsajionrddictieds? creinpteatanlecanipaeges2 NA NA x ~ 13. 14. WWeerreVhOeApvigerseaervieddSowlietsho(ustehSeHadOspGaEcNe?SOn P) sivii netheahlee esbeploo, t 10 datetallow. (Sh YN Yon 15. WasClaesnegative? Yon we emer eeTToT Tr L r rr r rr r TT | |rrr Notes, Discrepancies, & ResolutiL ons: mT T T1T 717 RE -- _-- -_-- _-- -_-- n Pa 1ogf e p16 Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPCL/MS 12 PCrlioejnetc:t: Sample Matrix: SLaambpCloedNe:ame: Avia Report BCaarmonp&DBruded,&sPMs.eCKeeSsrT,1I5nc3or1po9rated (CDM) Water KHIag0l0e1r01W1e.l0l0"1Raw" p17 DSaertveicCeolRleeqcuteesdt:: 2K/130/01100101802 DateReceived: 21 4/10 BUnaistiss:: gNAl Perfluorinated Sulfonic Acids and Perfluorinated Carbonylic Acids by HPLC/MS PrAneaplytMiectahloMde:thod: MPeFtOhAod Analyte Name PPeerlflouoonrot-enitrmiddeeccaannoiociacciadcd Perluorobuancsulfonate PePrelruuoorrsodbeucaannceicSuAlcfiodnate PeruorodecansicAcid PPeerrffluuoorroohdeopdteacnaonicciAccAicdid Perfluorohexanesulfonate PPeerrffluaoorroohneoxnaannooiicc AAcciidd Perflorooctanesufonate PePrelrfuuoorroopoecnatnaniocicAAcciidd Perfloroundecanoic Acid Rewlt Q MRL MDL DFialucttioorn NNDDUU050 009%5 11 " 50 0m9 1 01=9 1 55000 000195 11 113 50 048 1 ND4 U 5500 000858 11 m0 50 00% 1 2703 5500001o2n 11 E21) 50 00d 1 93% 5500 00066111 NDU 50 13 1 ExtDraatceted AnaDlaytzeed ExtrLaocttion 2Z99M00 F217I102O008 110055702 ono 2imi00209 10572 2299100 221178110020020089 l10o5s7t2 2910 21702008 1072 2299000 2217801200020089 11005577822 290 2100209 10572 22/990100 22w7I0020020089 1l0o57s8t2 25N0 217102008 10742 2299000 221178110020020089 1100557722 ono 21702008 10572 AnaLloytsisNote 1T500553T2 190532 119900553322 190532 119900553322 19032 119900553322 190532 119900553322 isos Surrogate Name %Rec ConLitmriotls AmDlayteed Q Note PePefrlfuluoorroo-nn-({11,223,344-51-31C34C]sbutmaonwoaicnoacciaded 19054 S0001800 U21m8m1o00m2o0s9 PPeerrfflluuoorroo--nn[{11,,22,-31,43-C123]Cd4e)caocntoaincoaicciadcid 1i0e0 SS001100 2211777711002200::0088 PePrefrlfuluoorroor-nn|-1{,12,-2-1133CC22]]hdoedxecaannoeiaccAicdid 1o0l5 550011500 22117877110020020089 PeSrofdliuuomrpo-ne-{o1,r2-1131C.22J4u.n1de3c0a4n]coiccAtncsiudlonste 92 00115500 22117710022000088 Sodium perfluoro--18h0e2Jxsalfnoent{e 1s S150 218100209 Comments: Piisnsaatmoeaman fom soesaRtee 0mm 18 PClrioejnetc:t: Sumple Matrix: LSaambpCloedeN:ame: Ansel Report CBaarmopnD&rBuedd,s&PMs.eC/ee9eSr,TI9I-n1c5or3p1o9rated (COM) Water HKaIg0l0e1r01W1-0e0*2Trleatled" pte SeDravtieceCoRlelqeucetsetd:: 2K/I30/01100018113 Date Received: 2/4/10 Units: ng Basis: NA Perfluorinated Sulfonic Acids and Peefluorinated Carboxylic Acids by HPLCIMS. PArnaelpytMiectahloMde:thod: MPeFtOhAod Aniyte Name Remit @ MRL MDL DFialcttioorn ExtDraatceted AnDaaityeed ExtrLaacttion AnaLloytsisNote PPeerrffhlauoorroo--nne-irrdaedceacnaoncoiacci3d50 NNOOUU 5500 00885% 11 2Z9o00 0 217102n 016 io10si su2 1m5o0e 5n32 Perflsorsbuanesulfonate 50 0029 1 250 218100218 1052 190532 PePrefrlfuloorroodbuetcaannoeicSuAlfcoindate 01341 5500 0o0n95 11 2299000 221178110020021168 110055722 119900553322 Peuorodecanoic Acid 079) 50 0481290217102016 10572 190532 PPeerrfflloorroodhoedpeacnaoniociAccAicdid sNtOU 5500 00088L 11 2299000 221I7S1N0020021I6S 110055722 119900553322 Perflorohesanesulfonae 50 000 1 910 2800218 102 190532 PPeerrflfuloorroonhoensaannooiiccAAcciidd 17360 5500 oolm 11 229900 221178110020021168 1100551722 119900553322 Perfluorooctanesulfonate 240 50 0046 1 2900 217102016 105742 190532 PPeerrfflluuoorrooopcetnatnaoniiccAAcciidd 100 5500 000616 111 22/9900 2281N7010022I0S6 110055722 119900553322 PerfiuoroundecanoicAcid NOU 50 13 1 250 217102016 losm2 150532 Surrogate Name PPeerrfflliuoorroo-nn--[{11..22,.33,,44,-51-31C34C]5b]utraonmoianaaciadcid PPeerrfflluuoorroo--nn--{{11..22-.1334C-21]3Cd4ecaoncotiacnaocciadcid PPeerrffulouroor-ornn-[{11,22--1133CC22]}hdeoxdaencaaincicacAicdid PSeordfiluumporeor-fn-o{r12-{131C21Ju3n4de-ca0nocicanAecsildfonte Sodium perfluoro-1-hexane{1802]sulfonate %Rec CoLnitmritosl AmDlatyeed Q SiTi aS05 15 220182100012168 1100 5S0011550 22117710022001166 51809 55001155 22118710020021168 &87 05011550 2211770022001166 11s 50150 218100218 Note -- Commens: FnVei2i231t0130e0 fomin Soho 100 14 PClrioejnetc:t: SampleMatriz: SLaambpCloedeN:ame: Analytica Report B(aCraomnpD&reBsuedrd,&P.MCe/K9e5s7,79I-n7co5r3p1o9rated (CDM) Water KIS0p0an1i0s1h1Tr-a0i0l3Raw" pds DSaertveicCeolRleeqcuteesdt::2/K3IO/01I000I8133 DateReceived: 21 4/10 BUansiitss:: NngA. Perfluorinated Sulfonic PrAnealpyMteictahloMde:thod: MPeFtOhAod Analyte Name PPerefrlfuoorro-nricdiercdaencoainccaicciadcd Perfluorobutancsulfonte PPeerrfflluuoorraobduetcaannoeiScuAlcfoindate Perfluorodecanoic Acid PPeerrfflluuoorroohdeopdteacnaoniociAccAicdid Perfuorohexanesulforate PPeerrfflluuoorroonhoenxaannooiiccAAcciidd Perfuorooctancsulfonate PePrefrlluuoorroopoecnttaannaoiiccAAcciidd Perfloroundecanoic Acid RestQ NNDUU 84 0a113)) NU 9N4DU 6 2u ou 1= NOU Acids and Perfluorinated Carbosyic Acids by HPLC/MS MRL MDL DFialucttioorn ExtDraatceted AnDaaltyezed ExtrLaocttion 5500 009%5 1 1 2299000 221700 02020 3 105 05572 50 0m9 1 29M0 wmiooxas losm2 55000000915 11 2299100 22117110002203283 1100557722 50 08 1 2910 21710202 05:2 5500 000858 11 22990100 l21071002202283 1100557122 50 0030 1 29n0 mi00228 10572 55000 o0l 11 229000 227i0n2i0o2a3s 110057722 50 00% 1 2M 2102023 10572 55000 00066111 229500 22118711000220238 1100557722 50 13 1 2910 217102023 lose AnaLloytsisNote 1H 90832E 190532 11990055322 13052 119900553322 190832 11990055322 190532 119900553322 190532 Surrogate Name PePrefrlfuloorroonn11.,22,,33,44,-51-31C34C]5b]utnaonnoaincoarceiadid PePrefrlfluuoorroon-n(111.2,231,342-1)3dCe4c)aoncoitcaancoiidacid PPeerrlfulouroor-onn{{11,,22--1133CC22}]dhoedxeacnaoniocicacAicdid SPoedriuuomrpone-r{1i.2o-1131C.22j,u4n-d1e3c0a4n]ooicctAnceimdlonste `Sodium perfuoro-1-hexane{1802]sulfonate %Rec CoLnitmritosl awo5n 0150 9100 5500115500 459+ 550010500 &74 5500115500 106 50150 AmDaaltyeed Q Note 2I 18100n 228 n 22117710022002233 22118711000220228 2211770022002233 218100228 -- Comments: VPsid22t31015t:40er Fomin Sodom, a0 1s Client: Project: Sample Matrix: Sample Name: Lab Code: Asaytca Report `CampDres&MscKeeer, Incorporated (CDM) Baron & Budd,P.C/9ST79-75319 Water Spanish Trail "Treated" KI001011-004 p28 Service Request: DateCollected: K1001011 2/3/100843 DateReceived: 2/4/10 Units: nglL Basis: NA Perflorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: Prep Method: MPeFtOhoAd. Analyte Name Perflooro-neiradecaaniodc Perfluoro-n-trdecanoicacid Perfluorobutancsulfonate. PerfluorobutanoicAcid PPeerrfflluuoorrooddeeccaannceiSculAfcoinadte PPeerrfflluuoorroohdeopdteacnaoniocicAAcciidd Perfluorohexanesulfonate PPeerrfflluuoorroohneoxnaannaciicc AAcciidd Perfliorooctanesulfonate PPeerfflluuoorroopoecnttaannociiccAcAicdid PerfluoroundecanoicAcid Result @ ND U ND U 87 437 oa J ND U ND U 93 [2 23 2 11 2% 1 ND U Dilution Date Date Extraction Analysis MRL MDL Factor Extracted Anlyzed Lot Lot Note So 046 1 50 09s 1 J9M0 M0031 105m 1058 2/910 2177102031 10572 190532 50 0m9 1 2910 218100237 105742 190532 50 oln 50 0095 T2910 1 2910 218100237 217102031 105742 105742 190532 10532 50 048 1 2/900 217102031 10572 190532 50 08s 50 0081 1 1 2/910 2910 217102031 218100237 10572 105742 190532 190532 50 0030 1 2910 218100237 105742 10532 50 oil 50 on T2910 I 910 218100237 217102031 105742 105742 190532 19032 50 008 1 2910 217102031 105742 190532 50 006s 50 onl 1 I 2/9/00 2/910 217102031 218100237 105742 10572 190532 190532 50 13 | 2/900 217102031 10572 190532 Control Date Surrogate Name %Rec Limits Analysed Q Note PPeerrfllvuoorroo--nn{-1{.12,,233.,44,-51-31C34C]3]buntoamnaonicoraeciadcid. 8 8s 0050 ZI7M02031 50150 218100237 --- PPeerrffllvuoorroo--nn--{{11,.22131,34C-21]3Cd4e)caoncotiacnoaicciadcid 102 100 5015 217102031 5005 217102031 PPeerrffllvuoorroo--nn--[[11,,22--1133CC22]JdhoedxeacnaoniccicacAicdid 0 50050 44 + 50150 218100237 217102031 SPoedriluumorpoe-fnl-u[1o2r-o1-31C-2J.u2n.d3e34c0a-4n1]cicccanAecsiudlfonate 768. 55000055 221177110022003311 Sodium perfluoro-1-hexane{1802}sulfonate: 100 5045 218100237 Comment Pred22310 1341 a] Fomia 16 -- Ansyical Report PCrloijeenctt:: BCaatmopn D&rBeusdsde,&rP.MCc/K9eSeT,9I.n7c5or3p1o9rated (CDM) Sample Matriz: ~~ Water SLaambpCloedeN:ame: KA1ir0p0o1r0t1N1o-r0t0h5"Raw" b.2t SeDravtieceCoRlelqeucetsetd:: K2/130/01100101912 Date Received: 2/4/10 BUansiitss:: NngAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCMS PrAneaplytMiectahloMde:thod: MPeFtOhAod AnalyteName Rewlt Q MRL MDL PePrfelfuolrou-on-rtori-denc-antoeicraacidadecdcancic NNDD UUU 30 50090546 Perfluorobutanesulfonate 507 50 0029 PPeerrffllvuoorroodbuetcaannoeiScuAlcfoindate 0428971 5500000095 Perflvorodecanoic Acid 101 50 048 PPeerrfflluuoorroohdcopdieacnaoniociAccAciidd 6s11] 5500 00088L Perflvorohexancsulfonate EY 50 0030 PePrefrlfulouroorohneoxnaanncoiiccAAcciidd 518 5500 00112 Perfluoroctancsulfonate: 2 50 0046 PPeerrfflluuoorroocpcetnatnaoniocicAcAicdid 718" 55000 0O0l6 Perfluoroundecanoic Acid 223 50 13 DFialcuttioorn ExtDraatceted AnaDlaytzeed ExtrLaocttion AnaLloytsisNote 1 1 2D99100 FM0020033 110055T7920019505372 1 250 M0047 105792 190532 11 2299000 2218701002204378 1100551122 11990055322 1 2910 21702038 105742 190532 11 2299000 M2M7I000022043T 11005577822 11990055322 1 250 MmI00247 10572 190532 11 22990000 22m7I00200x3487 110s5i22 11990055322 1 2910 217102038 10572 100532 11 22/99000 M21E7I10002204378 1100557722 119900553322 1 290 217102038 10572 190532 Surrogate Name %Rec CoLnitmirtosl AmDlaytzeed Q Note PPeerrfflluuoorroo--nn-{{11..22,.334,45-1-3TC34C]S]bntoannaoniociacciadcd 350 s5a 0050w 2w1m8m10w0s247 PPeerrfflluuoorroo--nn--{{11,,22,-31,34C-21]3Cd4e]caoncotiacnoaiccidcid 110007 550011500 2211770022003388 PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]]dhoedxeacnaoniccicacAicdid 83+ SS000100 221187/11000220:3487 SPeordfiluumpoerrof-ino-r{1o,-21-{1132C23]4u-n1d3e0c4an]ooiccnAecsildforste 7551 5500005500 2217177110022003388 Sodium perfluoro-1-hexane(1802Jsulfonate 110 50050 218100247 Comment: Peea tait be Fema SaseRenoce Toca " Client: PSraomjpeclte:Matrix: Sample Name: Lab Code: Analytical Repert CampDres&MscKeeer, Incorporated (CDM) Baron & Budd,P.C/95779-75319 Water Airport North "Treated" K1001011-006 p-2 Service Request: DateCollected: K1001011 2/3/100923 DateReceived: 2/4/10 Units: nglL Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS Analytical Method: PFOA PrepMethod: ~~ Method Analyte Name PePreflrufolrwo-onr-otrndeercaandooiccaacniaodiccd Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannoeiScuAlcfoindate PPeorcftluucoruonddoadceacsaentcsiAccAhcid Perfluoroheptanoic Acid PPereftluuoonrdoehnesxmanpauitctAociindty PPeerrfflluuoorroooncotnaanneosuilcfAocniatde PPeerrfflluuoorrooopcetnatnaoniocicAcAicdid Perfluoroundecanoic Acid Dilution Date Date Extraction Analysis RewltQ MRL MDL Factor Extracted Analyzed Lot Lot Note NDU0 ND U 50 0% 09 1 I 2910 2/910 17103046 2177102046 105742 105742 190532 19032 483 50 0020 1 2/90 28100257 105742 190532 291 034 50 oln 50 0095 T2900 1 2910 218100257 17102046 105742 10572 190532 190532 S15037 5500 o0a8s 11 M2u91h0 J17V 1020s46 11005s742 M1090532 60 50 008L 1 2910 ISN002ST 105742 190532 S 14 I 50 oomlle 1T29I1e0 w28s100257 M10e5742 i1n90532 oost 5500 0001426 11 22991100 21770022004466 110055774122 190532 19052 is 80 50 0066 50 on 1 I 290 910 27102046 218100257 105742 105742 190532 190532 ND U 50 13 1 2910 217102046 105742 190532 Control Date Surrogate Name %Rec Limits Analyzed Q Note PPeerlfulouroor-on-n{-1{,12,,23,,34,,4-51-31C34C]3b]utnaonnoaincoaicciadcid 107 107 0150 2777102046 50150 218100257 PPeerrfflluuoorroo--nn--{[11,,22-31,34C-21)3Cd4e)caoncotiacnoaiccidacid 116 100 50050 50150 217102046 217102046 PPeerrfflluuoorroo--nn-{11,,22--1133CC22]JdhoedxeacnaoniocicacAidc.id 109 6 50050 50150 218100257 2177102046 SPoedrifulmuopreor-lnio-s{o1-,12.-(113.C223J,u4n-d1e3c0a4n)coicctaAnceisdiforate 698 5500105500 2211777110022004466 Sodium perfluoro-11-8h02esxulafonneat[e 129 50050 2/181002:57 -- Comments: Proan22e31s0 1i3:e81sArie 6 Ramin Spree: 001m) 18 Client: Project: Sample Matrix: LSuambpCloedeN:ame: Ansyica Report B`aCraomnp &DBruded,&sPM.scCK/ee9e5r7,79I-n7co5r3p1o9rated (CDM) Water KM1cA0l0l1i0s1te1r-0"0R7aw" p33 Service Request: K1001011 Date Collected: 2/ 3100949 Date Received: 2/4/10 UBnasiitss:: NnAg Perfluorinated Sulfonic Analytical Method: PFOA Prep Method: ~~ Method Analyte Name Result Q PePrfeluforlo-un-otrriodencatnoeicuacaiaddcedcanoicNNDD U U Perfluorobutanesulfonate 58 PPeerrfflluuoorrdobduetcaannceicSuAlcfiodnate 501031 PerfluorodecanoicAcid 083 1 PerfluorododecanoicAcid Perfluoroheptanoic Acid 1N6D U Perfluorohexanesulfonate ss PPeerrlfulourooronhoenxaannooiiccAAcciidd 1920 Perfluorooctanesulfonate 150 Perfluorooctancic Acid Perfluoropentanic Acid E) 13 Perfluoroundecanoic Acid 31 Acids and Perfluorinated Carboxylic Acids by HPLCMS. MRL MDL Dilution Date Factor Extracted Date Extraction Analyzed Lot 50 50 08%1 290 095 1 290 Iii020510i5 702054 10542 50 0029 1 290 800306 1052 5500 0o0a9n5 T1 29219100 121T8I10020035046 11005577322 50 048 1 2910 217102054 105742 5500 0o0s8s1 I1 22/991000 22118710020035046 11005577422 50 000 1 21910 218100306 105742 5500 o0u1l2 1T29209100 218100306 702054 105742 105M 50 0086 1 2910 17102054 10572 5500 0o0ll6 11 22/991100 221178110020035046 11005577422 50 13 1 2910 217102054 105742 Analysis Lot Note 1 190532 190832 11990053322 190832 119900553322 190532 190532 190532 190532 119900553322 190532 Surrogate Name Control Date %Rec Limits Analyzed Q Note PPeerlfulouroor-on-{n-1{,12,,23,,34.-41,53-C143]C5b]untoamnaoincoiacciadcid 93%% 5o04050 27z1m8m1o00n3s0s6 -- Perfluoro-n{1,2,34-13C4] octanoic acid ng 50450 2/171020:54 Perfluoro-n{1,2-13C2]decancicacid 100 50450 2/171020:54 Perfluoro-n-{1,2-13C2)hexanoicacid 103 50450 218100306 Perfluoro-n{1,2-13C2]dodecancicAcid & 50050 2171020:54 SPeordfiluumopreor-fni-o{r1o,-21-{113.C22,J3u4n-d1e3cCa4n]ooiccanAecsiuldfonste 7101 5500405500 22117711002200::5544 Sodium perfluoro-1-hexane(1802sulfonate 1 50050 2/181003:06 Comments: Peod2n231a0 1n01 Fama Sopatee 1000Sert 19 ClPrioejnetc:t: SampleMatix: SLaambpCloedeN:ame: Aasyica Report CBaamropnDr&esBsuedrd&,PM.eCeSeT,I9I7nc5o3rp1o9rated (COM) Water KIMOcA0lIl0is1t1e.r0T0r8eated" b2e SerDvaitceCeRolelqeucetsetd:: K2I10301100110102 DateReceived: 2/4/10 UBansiiss:: nNgA. Perfluorinated Sulfonic Acids and Perfuarinated Carborslic Acids by PLCS PrAneapiMyiectahloMde:thod: PMeFtOhAod Analyte Name PFerfelorwo-nredercamnooiceaciedd Perlorsbutnesulfonaie PPeerrflluuoorroodbeucaannceiScuAlcfiadte PerfluorodecancicAcid PPeerroorroodhoedpeacnaaniocicAAcciidd Perluorohesancsulonate PePrfelruofruoonornhaneaaicnAocGiicdd Perluoroocancslfonste PPeerrluuoorrooopcenainacniociAcAccdi_d PerluoroundecanoicAcid RemiQt MRL MDL DFiautcioorn ExtDraatceted AmDiavtieed ExtrLaocttion AnaLlaytsisNote NNDDUU 3500 00%98 1 1 29/90000 J2I7100I2100r1 01055742 11090s532 029) so 0m 1 ui 2isio0xis i057 isos 07571 5s0o 0001s 11 2/90M00 22108120003116 1005574722 11990055322 Ge) 50 048 1 900 202101 10572 19052 0133271 5S0o 0008M 11 2299MM 22M800z0i3o1l6 110057702 115900552 0301 so 000 1 90 2800516 10572 i052 009s5)1 5s0o Oo1il |1 22/990100 2217801200030106 l10o5s7a422 119900553322 077) So 0G 1 90 2702101 105742 19052 To3a31ss 5S0 0001066 11 2299100 u21m8o1z00i3o1l6 llooss i19s0o53s2 19050 131 2900 21702100 Losi 190532 Surrogate Name %Ree CoLnitmirtosl AmDiatyeed Q Note PePPreelrrfullouuroororoo--nnn-[[[111..,222.3,33,,444--,151-331C434C]]S5bo]uctnaaonnnocaincoaiaccciiaddcid 9W7o 5ss0-aa15ss0 2g2/11o77/01o022s110:e001 PePrelrulouroor-on-n[{11..22--1133CC22]]dheecxaannooiiccaaciidd 01S SS4a5s0 2218710020130106 PePrelruuoorroo--nn{{11..22--1133CC22]]duonddeoccaannooiicAAcciidd 36 S50011500 2201177110022110010 Samperfor {.24-50H] ones 93 soas0 1702100 `Sodium perfluoro-1-hexane[1802]sulfonate us 50-150 2/18/10 03:16 Comment: raesmziaotnta A remin Sosa, os 2 Client: Project: Sample Matrix: Sample Name: LabCode: AnsyticalReport B`aCraomnpD& rBuded,&PsM.Cce/K9e5re7,7I9n-c7o5r3p1o9rated (CDV) Water Humphrey "Rav" KI1001011-009 Ib. 28 Service Request: DateCollected: K1001011 2/3/10 1055 Date Received: 2/410 Units; nglL Basis: NA Perfluorinated Sulfonic Acids and Perflurinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method AnalyteName Ret Q PePrfeluforlo-un-orirdeoca-noniccatcairdcaddecanNNoDDicUUU Perfluorobutanesulfonatc 161 PPeerrffliuuoorroodbuetcaannoeiScuAlcfoindate 0419371 PerfluorodecanaicAcid ND U PPeerfflluuoorroohdeopdteacnacniociAccAciidd 0871 313 Perflvorohexancsulfonate 7s PPeerrffllvvoorroonhoenxaannociicc AAcciidd 487 061) Perfluorooctanesulforate 59 PPeerrfflluuoorroopocetnatnaoniccicAAccidid 79 373 PerfluoroundecancicAcid ND U MRL MDL 3500090546 50 09 55000 0o0n95 50 048 50 085 50 0081 50 0030 500 0 55000 0001426 50 006 5500 O1l3 Dilution Date Factor Extracted Date Analyzed Extraction Analysis Lot Lot Note 1 1 Z9I0 250 F009 2702009 105 105782 T05T 190532 1 Jono 8M0032s 10572 190532 T1U 22/99100 218100325 217102109 105702 10572 190532 190532 1 2/9M0 217102109 105742 19032 1 1 2910 2910 217102109 8100325 10572 1052 190532 190532 1 2910 218100325 10572 190532 1 1 2900 290 1800325 21710209 lose 105742 190532 190532 1 2/910 217102109 10572 190532 1 1 2/900 290 217102109 MEI00%S 10572 105742 190532 190532 1 290 02109 1052 190532 `SurrogateName PPeerrffllouoorroon-{n1-{,12,,23,.344,-51-31C34C]5b]tnaonmoaincoaicciadcd PPeerrfflluuoorroo--nn--{[11,,22-,1334C-21]3Cd4e]caocntoainoaiccidacid PPeerrfflluuoorroo--nn--{{11,,22--1133CC22)]hdeoxdaecnaoniociaccAicdid PSeordfiluumopreor-lni-o{r1o,-2--{113,C223J4un-d1e0c4a]nooicctmAecuildfonste Sodiumperluoro-1-hexanc] 1802]sulfonate Control Date %Rec Limits Analyzed Q Note 90 kd s01% Zmmoazies 50450 218100325 110008 550000550 22117777110022110099 101 54 S010 218100325 50150 21771021:09 89 5015 5005 217102109 2177102109 120 5005 218100325 Comments: PNieneost22e010l130R1e AR Ronin SseRecs. Tomo 21 Client: Project: Sample Matrix: LaSabmpCloedeN:ame: Analytica Report Camp Dresse&r McKee, Incorporated (CDM) Ba&rBoudnd, P.C/95779-75319 Water KIH0u0m1p0hr1e1y:0"1Tr0eated" p28 Service Request: K1001011 Date Collected: Date Received: 2/3/10 2/4/10 1107 Units: nglL Basis: NA Perflworinated Sulfonic Acids and Perfluorinated Carboxylic Acidsby HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Ferfluoro nieiradecanoieaad Perfluoro-n-tridecanoicacid Perfluorobutanesalfoate Perfluorobutanoic Acid Perfluorodecane Sulfonate PPeerrfflluuoorrooddeocdaencoaincciAccAicd id Perfluoroheptancic Acid Perfluorohexanesulfonate PerfluorohexanoicAcid Perfluorononanoic Acid Perfluorooctancsulfonate PerfluorooctancicAcid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q Dilton Date Date Extraction MRL MDL Factor Extracted Analyzed Lot NUD _ 50 ND U 50 046 09s T2790 I 2910 I0aII6 10570 217102116 105742 ND U 50 009 1 2910 18100335 105742 0217 013 J 50 on 50 0095 1 1 2/910 218100335 105742 29/10 217102116 105742 NWDYU M 50 08s e I 2/900 MO 2I1V77I1A0T2L1I1S6 10105574422 ND U 012 50 008 50 000 1 1 2910 ILN00335 105742 2910 18100335 105742 0117 ND U 50 oll 50 on I 2910 12910 219100335 702L16 105742 105742 020 J 50 0046 1 2910 17102016 105742 0227 020 J 50 0066 50 on 1 1 2910 217102016 105742 910 218100335 105742 ND U 50 13 | 900 2177102116 105742 Analysis Lot Note 10052 190532 190532 190532 190532 1S905I22 190532 190532 190532 190532 190532 190532 190532 190532 Cantrol Date Surrogate Name %Rec Limits Analyzed Q Note PPeefrlfulouroor-on--n{{11,,22,33,,44-,153-1C34C]3b]untoannaonicoiacciadcid. % 9 0150 277102116 50150 218100335 Perfluoro-n-{1,23,4-13C4] octanoic acid 16 50050 217102116 Perfluoro-n{1,2-13C2) decanoic acid Perfluoro-n-{1,2-13C2] hexanoic acid. 100 101 5500115500 2211787110002313156 PePrefrlfulouroor-on-{n{11,,22--133CC22JJudnoddeeccaanncciicc AAcciidd 58 8 50050 217102116 50150 217102116 Sodium perflioro-11,2,34-13C4] ocanesilfonste 92 50050 217102106 Sodium perfuoro-1-hexane{1802)sulfonate: 1s 50150 218100335 Comments: Pred22310 1341 outs ren 6 Femin Super Releme 0301830000 22 PCrloijeenctt:: Sample Matric SLaambpCloedeNsame: Ansys Report BCaarmopnD&rBuedd,s&PsM.Cee/e9srS,779I-nc7o5r3p1o9rated (CDM) Water B1ro0a0d10"1R1aw0"11 td SerDvaitceeCoRlelqeucetsetds: 2K1130/01100111146 DateReceived: 21 4/10 UBnaistiss:: nNAg Perfluorinated Sulfonic Acids and Perfluorinated Carbosylic Acids by HPLC/MS APnraelpytMiectahloMde:thod: PMeFtOhAod Analyte Name PPeerrflfuioiroor-onm-rreiidreacdaencoaincciacaicdd. Perflorobutancsulfonae PPeerrfflluoorroobduetcaannoeicSuAlcfiondate Perluorodecancic Acid PePrefrlfolruoorhoedpotdaenccaniocicAcAicdid Perflorohoanesulfonate PePrefrlfulouroornoohneasnaoniiccAAcciidd Perfluorooctanesulfonate PPeerrfflluoorrooopcetnatnaoniccicAAcciidd Perfluoroundecanoic Acid Remit @ NNDUU 035 1 00715971 101 01329)] 0591 006530 1 173 0148417 16 MRL MDL DFialcattioorn 5500 008%5 11 50009 1 5500000O9I5 11 50 048 1 550 00080BL 11 50 0050 1 550000 001111 50 004 1 5500 0O0I66 11 S013 1 ExtDraatceted AnmDsaltyeaed ExtrLaocttion AnaLloytsisNote 929010 Z70O 2121 4 10572 190532 290 218100344 1052 190832 2u99M00 221I7m1I00201n2s4 11005778422 119900583322 290 n70aizs 1072 190532 22991100 wI1MmIi000231eass 11005577822 119900853322 2910 Miwlooses iose2 190532 225900 221178012010246 1100557722 119900589322 290 n7i02ias 1072 10532 22/991100 aJ1ImMiI0020i3a4s8 11005577822 11990055332 ono 207102126 10572 190832 Surrogate Name %Rec CoLnimtirtosl AmDiayteed Q PePrefrflliuoorroo-n{-1{1.22.33,44-51-31C34] bumtanooic macaidndoic8103 550011500 T218I10O0344 PePrefrlfulouorroo--nn-[[1122,-31,34-21]3Cd4e)cactnaonioiaciadcid 121000 5500115500 22117710022112244 PPeerrfflluuoorroo-nn1[.1,22--1133CC22]}dhoedxeacnaoniccicacAicdid 57 5S0015500 221087110002318244 SoPdiuem rperfflil1or,o2u11-3o1C.22]r,u4n-do1e3c-0a4n]cnioccuAncciadfonste 9117 5500115500 220770022112244 Sodiumperfuoro-1-hexane{1802lsulfonate mn 50150 21810054 Note -- Comments: Fntet2t231e01340 fomin Sopa m0 2 ClPireojnetc:t; Sample Matrix: SLaambplCoedNea:me: Analytical Report B`aCraomnpD& Brudde,&PM.scCK/9es5e7,79I-n7co5r3p1or9ated (CDM) Water KIB0r0o1ad01"1Tr-e0at1e2d" p.28 SDearvtiecCeolRleeqcuteesdt:: K1001011 2/3/10 1200 Date Received: 2/410 UBnaistiss:: NgAL Perfluorinated Sulfonic Acids and Perfluorinated Carbosylic Acids by HPLC/MS APnraelpytMiectahloMde:thod: PFOA Method Analyte Name Rewlt@ PePrfleuofro-ontrridoecnanicicmacdaidced anocNNDD U U PPeerrflluuoorroobbuutiaanncosiuclAfcoinadte 0337 PPeerfflluuoorrooddeeccaannceicSuAlcfoindate 002459)3 PPeerrflluuoorroodhoedpetcaanonicciAccAicdid 0N3D71U Perflvorohexanesulfonate 065 1 PPeerfllluuoorroonhoenxaannociiccAAcciidd 003411 Perfluorooctanesulfonate 12] PPeerrfflluuoorroopoecnttaanncoiiccAcAicdid 217 056 1 Perfluoroundecanoic Acid ND U Dilution Date MRL MDL Factor Extracted 30 50 046 09s 1 1 J299I100 ET5O0 oanTc T29. 00 50 50 0055 048 1 1 2910 2910 50 50 08s 008L T1 29219/010 50 0030 1 2910 50 oil 50 on TL2299000 50 004 1 2/910 50 0066 so on 1 1 2/900 290 5013 1 290 AnaDlatyezed ExtrLaocttion AnaLloytsisNote 72107120231311 11005s72 10905s32 1810035T 105742s 190532 221177110022103311 10572 10572 119900553322 221178710002013341 110055774422 190532 190532 218100354 105742 190532 2217801200133514 105742 10542 190532 190532 217102131 105742 190532 22117B1N0020133S1H 105742 105742 190532 190532 2702131 10572 190532 Control Date Surrogate Name %Rec Limits Analyzed Q Note PPeerlfulouroor-on-n(-1{,12,,23,.34,,4-51-31C34C]3]buntoanwoaincoiacciadcid 81 7 Sas 50450 w2o18m1a00n35s4 PPeerrfflluuoorroo--nn-{{11,,22,-31,34C-21]3Cd4e]coacntoaincoaicciadcid 9 100 50450 50050 2211777110022113311 PPeerrfflluuoorroo--nn{{11,,22--1133CC22]JdhoedxeacnaoniccicacAicdid 846 + s50d05s0 221178110020133516 PSoedrifulmuopreor-f{u1oo,-21--1(31C,22J3u,n4-d1e3cCa4n]coiccaAnecsiidfonate 7558 5500405500 221177110022113311 `Sodium perfluoro-1-hexane(1802slfonate. 109 50150 2187100354 Comment: PJ ied22310 1341 Famin SosaRte 10S0 2 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report CampDresser & McKee, Incorporated (CDM) Baron &Budd, P.C/95779-75319 Water Tennant "Raw" K1001011-013 p29 Service Request: 1001011 DateCollected: 2/3/10 1305. DateReceived: 2/4/10 Units: nglL Basis: NA Perfluorinated SulfonicAcidsand Perfluorinated CarboxylicAcidsby HPLC/MS Analytical Method: PFOA PrepMethod: Method Analyte Name Peooncindecaacndoic Perfluoro-n-tridecanoicacid Perfluorobutanesulfonate Perfluorobutanoic Acid PerfluorodecaneSulfonate PerfluorodecanoicAcid PerfluorododecandicAcid PerfluoroheptanoicAcid PS erfluorO ohexaneE sulfono ate n PerfluorohexanoicAcid. PerfluorononanoicAcid Perfluorooctancsulfonate PerfluorooctanoicAcid PerfluoropentanoicAcid Perfluoroundecanoic Acid. Resul@t WNDU ND U 061 J 080 1 017 J ND U ND U 161 2327 7 237 0.66 J 59 327 21] ND U MRL MDL 30 0% 50 09s S000 50 om 50 0095 50 048 50 oss 50 0081 3500 0000300 50 on 50 on 50 0046 50 0066 50 oll 50 13 Dilution Date Factor Extracted Date Extraction Analysis Analyzed Lot Lot Note 1 ZII0 JI703T3 ToS TOS 1 2910 217102139 105742 190532 1 29/10 218100403 105742 190532 I 29/10 218100403 105742 190532 1 290 217102139 10572 190532 1 2910 2171021:39 105742 190532 129/10 20177102139 105742 190532 1 29/10 218100403 105762 19032 11 9290 10 2128181100004400331100557742210195053322 1 2910 218100403 105742 190532 1 29/10 217102139 105742 190532 1 2910 21177102139 105742 19032 1 2/970 2177102139 105742 190532 1 290 218100403 105742 190532 1290 217102139 105742 190532 Surrogate Name Perfluoron{1,2,3,4,5-13C5]nonanoic acid Perfluoro-n-{1,2,3,4-13C4] butanoic acid PPeerrfflluuoorroo--nn--{{11,,22-,1334C-21]3Cd4e]caoncotiacnoaiccidacid PePrefrlfulouroor-on--n{-1{,1,22--1133CC22]]hdeoxdaencaoniociacciAdcid `PSeordfiluumopreor-fnl-u{o1r,o2---1{31C,22,J3u4n-d1e3cCa4n]ocitcanAccsiudlfonate Sodium perfluoro-1-hexane(1802]sulfonate: Control Date %Rec Limits Analyzed Q wan ume 7 50-150 21810 04:03 97 50-150 217102139 100 50-150 2/17/102139 7 0-150 2/18/10 04:03 50 S050 217102139 9 S050 217102139 8 50150 217102139 104 50-150 218100403 Note -- Comments: -_-- --- NtPlroend22S2i91s0t13i:0n1 eoii. Fom 1A 25 v0v0m0m0m0m0mn0n0m0n0B0B0m0m0m0m0 Spe Refrmse: 10000138160) CPrloijeenctt:: Sample Matrix: LSaambpCloedeN:ame: AnalyticalReport. BCaarmopn D& Bruded,&sPM.sCc/Ke9e5er7,79I-n7co5r3p1o9rated (CDM) Water KIT0en0n1a0n1t1"-T0r1ea4ted" p.30 SeDravtieceCaRlelqeucetsetd:: K21/30/01100111317 DateReceived: 2/410 UBnaistiss:: NngAlL Perfluorinated Sulfonic Acids and Perfluorinated Carborylic Acids by HPLC/MS PArnealpytMiectahloMde:thod: PMeFtOhAod Analyte Name Result @ MRL MDL DFialucttioorn ExtDraatceted AnaDlaytezed ExtrLaocttion AnaLloytsisNote PPecefflluuoroor-onntreiidaedcaencoaincaocciadqd NNDD UU 550009058 11 22990000 2I171T021I46 1100557728 1190050312 Pecfluorobutanesulfonate 067 1 50 009 1 290 218100413 10572150532 PPeerrfflluuoorroobduetcaannoeiScuAlfcoindate 0081gJ 5500 0O095111 22991100 221178110020184163 110055774422 119900553322 PerfluorodecanoicAcid ND U 50 048 1 2910 217102146 los1e2 190532 PPeerrfflluuoorroohdeopdteacnacniociAccAicdid N13U7 5500 000881 11 2299100 221178110020184163 1100557722 11990055322 Perflvorohexanesulfonate 353 50 00% 1 2910 218100813 105742 19032 PPeerrfflluoorroonhoenxaannooiiccAAcciidd 0251771 5500 0ON; 11 22991000 22118710020144163 11005577422 119900553322 Perfivorooctanesulfonate ss 50 0046 1 2910 217102146 10572 190532 PPeerrfflluuoorroopoecnttaannoaiiccAcAicdid 231637 5500 000006 111 2299000 221187110002411436 1100557722 11590055322 PerflvoroundecanoicAcid ND U 50 13 1 290 MI02046 105782 190532 Surrogate Name %Rec CoLnitmritosl AnaDlaytezed Q Note PPeerrfllouoorroo--nn--[{11..223,3.,44,-51-31C34C]3]buntoamnoaincoiacciadcd 97 o50w10 w218m710a0813 PePrefrlfulouroor-on-e-1[.12,2-,1334C-21]3dCe4c]aoncctiancoaicciadcid 110030 550011500 22117710022114466 PPeerrfflluuoorroo--nn--{11,.22--1133CC22]]dhoedxeacnaanicciaccAicdid 41015+ SS001500 22118710020044136 PeSrofdliuuomrop-ernl[i1o,r2s--113{C122J,u3n4d-1e3c0a4n]ciacraAnccsiudlforate ~~ 490 + S5005005 22117710022014466 Sodiumperfluoro-1-hexane{1802sulfonate: m3 501 218100413 Comment: Peintens2m0 301 Ah Fomia SseRees 1oamO1N0S 2 ClPireojnetc:t: Sample Marrs: SLaambpCloedeN:ame: AnalyticalReport BCaarmopnD&reBsusdedr,&P.MCc9KSeTeI,9I-n7c5or3p1o9rated (CDM) Water MKuIl0d0o1o0n1"1R0a1w5" p31 SDeartviecCeolRleeqcuteesdt:: 2K/130/01100111347 DateReceived: 2/4/10 UBnaistiss:: nNAg Perfluorinated Sulfoic Acids and Perflorinated Carboxylic Acids by HPLOMS AnParleyptMiectahloMde:thod: MPeFtOhAod Analyte Name Real @ MRL MDL DFilauctuiron ExtDraatceted AmaDlayteeed ExtrLaocttionAnaLloytsisNote PFerfleuorwo-nn-reindedceanconicoaccaidcd NNDDUU 5500 009%5 11 22990000 MU7MI02UISs 110055712 0190S53T2 Perfluorobutancsulfonate 068 1 50 0029 1 290 800423 10572 190532 PPeerrflluuoorroodbuetcaanncicSAulcfiondate: 00330811 5500 0005111 22/99100 22118710020185234 1T0o5s7i2 11990055322 PervorodecanscAcid NDU 50 048 1 2/900 m0zise l0sm2_ isos PPeerrflluoorroobdeopdteacnacnicciAccAicidd NoDngU 5500 000858 11 22991000 22118710020185238 1l0o5s7e2 119900553322 Peruorohexaneslfonate as3 50 000 1 29M0 21m100423 10572 190592 PPeersffuuoorroohneosnaannociiccAAcciidd 041s2 1 55000 0ol1l2 11 22/990000 Y21081200S3 lloosst 119900553322 Peroroocinesulfonae 43 50 0046 1 2900 217020ss 10572 190532 PPeerrfflluoorroopoecnttaannooiiccAAccidid 018917 55000 0006111 22/991000 221178A00024n2s3t T10o5s74a2 119900553322 PerfloroundecanoicAcid NDU 50 13 1 2900 uimoziss nsw isos Surrogate Name %Rec CoLnimtirtosl AmDlatyeed Q Note PPedleuooron-n-(11,223344-513C34C] bumtaonmoincoacciadsd 386 a501050 a218m10o04s23 PPeerdlluuoorroo--nn{-1{,12.-21334C-21]3Cd4e]caonccaincoaiccidacid 110020 0S1a5s0 2211770022115548 PePdelrulouroor-on-n{{11,,22--1133CC22i]dohedxeacnaoniccicaAcicdid 65 + s0a0s5 a21m8m1m00026n2s3s PeSrolduiourmpone-{r1i,2o-13{C122j3un4d-e0c0a4n]oiccoAcmimdent 293 S50115500 2211770022105544 Sodium perfuoro-1-18h0e2]xsualfnoneat{e 10s S150 218100423 Comments: Piinesn2230t 0 130e 0 n Romin Sado 18000350700 27 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report `CampDres&MscKeeer, Incorporated (CDM) Bar&Boudnd, P.C/95T19-15319 Water Muldoon "Treated" KI001011-016 p32 Service Request: K1001011 Date Collected: 2/3/10 1400 Date Received: 2/4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Ret @ Dilution Date Date Extraction Analysis MRL MDL Factor Extracted Analyzed Lot Lot Note PPeerrfflluuoorro-onnttreirdaedceacnaincoaciicdacd Perfluorobutanesulfoate PerfluorobutanoicAcid PPeerrfflluuoorrooddeeccaannoeiScuAlcfoindate PerfluorododecanoicAcid Perfluoroheptancic Acid Perfluorohexanesulfonate Perflvorohexanoic Acid Perluorononancic Acid Perluorooctanesulfonate Perfluorooctanoie Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid NNDDUU 5500009456 1 1 2J/9900217711002220020 1100557M22 191900553322 066 J 50 009 1 2910 UIMI00432 105742 190532 087 50 oul T2900 218100432 105742 190532 0N1D11U 50 0095 1 290 21702202 10572 190532 50 048 1 50 702202 105742 190532 ND U 50 08s T2910 217102202 10572 190532 084 1 50 0081 1 910 18N00432 105742 190532 50 50 003 1 2910 218100432 105782 190532 131 50 oil T 2/910 218100432 105742 190532 0317 50 012 1 2910 217102202 105782 190532 41 50 0046 1 2910 217102202 105742 190532 018097J 5500 0o0n6 11 2299000 20107160232022 110055774422 119900553322 ND U 50 13 1290 1702202 105742 150532 Surrogate Name Perluoro-n{1,23.4,5-13C3] nonanoic acid. Perluoro-n-1,23,4-13C4] butanoic acid Perfluoro-n-[1,23,4-13C4] actanoic acid Perfluoro-n-{1,2-13C2] decanoic acid Perfluoro-n{1,2-13C2]hexanoic acid Perfluoro-n{1,2-13C2]dodecanoic Acid PSeordfiluumoproe-rnlei{r1o,-21-{113.C223J,u4n-d1e3c0a4n]ooiccanAecsiudlfonste Sodium perfluoro-1-hexane{1802]sulfonate: %Rec CLoinmtirtosl 8 010 15% 50050 10 50150 100 50150 3 50150 46+ 50150 591 5500145500 9% 50150 AnaDlaytzeed Q 700nn 218100432 217102202 217102202 2718100432 217102202 2211777110022220022 2718100432 Note -- Comments: Pieodn22a31n0 1341ep Re Fem1A SupraRte 10800351000 2 Client: Project: Sample Matrix: LSaabmpCloedNea:me: AnalyticalReport `CampDres&MscKeeer, Incorporated (CDM) Baron &Budd, P.C/95779-75319 Water Vi1l0l0a1"0R1a1w"017 p.33 Service Request: K1001011 DateCollected: 2/3/10 1418 Date Received: 2/4/10 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Ret Q Dilution Date Date Extraction Analysis MRL MDL Factor Extracted Analyzed Lot Lot Note Perooro-n{etradecane aid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannoeiScuAlfcoindate: PPeerfflluuoorrooddeocdaecnaoniociAcdAdcid PerfluoroheptanoicAcid i PerfluorshexanoicAcid PerluorononancicAcid Perluorooctanesulfonate Perluorooctancic Acid Pefluoropentanoic Acid Perfluoroundecancic Acid OU S004 1 2900 Uo105m 7 15o 057 ND U 50 095 1 20910 217102209 105742 190532 0.46 1 50 00290 1 2910 JIBN00442 10572 190532 N00D27U 5500 0o0n9l5 T1 29219100 21178110020280092 11005577422 119900553322 NNDDUU SO50 004885 1 1 2299M10021271711002222009910150754722 119900553322 0.45 7 50 008L 1 2910 MI0082 10572 190532 0921.7SO 50JO..ol.l SO TO29O00.2.181. 0082 1057x 4I2 190532 ND U 50 012 1 290 217102209 10572 190532 281 50 004 1 290 17102209 10572 190532 187 50 0066 1 2910 217102209 10572 190532 11] 50 oll 1 2910 218100842 105742 190532 ND U 50 13 1 290 1702209 105782 190532 Control Date Surrogate Name %Rec Limits Analyzed Q Note Perluoro-n{1,2,34,5-13C5]nomancic acid 5 0050 217102209 Perfluoro-n-{1,2,3.4-13C4] butanoic acid Perfluoro-n-{1,2.34-13C4] octanoic acid 8 9 550044550 2211787110002424029 Perfluoro-n-{1,2-13C2) decanoic acid 100 50450 2177102209 Perfluoro-ne{1,2-13C2) hexanoic acid 8 50050 218100442 Perfluoro-n{1,2-13C2)dodecanoic Acid $+ 5050 217102209 SPoedrifulmuoproe-n-r{1,f2-l13Cu23J4ou-nd1re3c0ao4n]oc-icca1nAecsi{udl1for2te s9t4 5500445500 221177/711002222:0099 Sodium peruoro-1-hexane(1802sulfonate 9 50450 21810 04:42 Comments: proisedz223s10 134h1epAny Fai Supers Rte 10050) 20 PClrioejnetc:t; SampleMatrix: LaSabmpCloedNea:me: Alyica Report BCaarmopnD&Bruded,&sPM.cCe/K9eSre7,79I-n7co5r3p1o9rated (CDV) Water KIV0il0l1a0"1Tr1e.a0te1d8" bss SeDravtieceCoRlelqeucetsetd:: K21/0301100111428 Date Received: 2/4/10 UBnasiiess:: NnAg Perfluorinated Sulfonic Acids and Perfluorinated CarbosylicAcidsby HPLC/MS APnraelyptMiectahloMde:thod: MPeFtOhAod Analyte Name PFerfeluooro-nn-erdredcaencoinceaciaddd Perfluorsutanesulfonate PPeerrfflluuoorroobduetcaannoeiScufAocniadte PerflorodecanoicAcid PPeerrlluuoorroohdeopdteacnacnicciAcAcciidd Perluorohexancsulfonate PPeerrffiluuoorroohneoxnaanniiccAAcciidd Perfworoocanesulfonate PPeerrfflluuoorrocpoecnitnaoniacicAAcciidd. PerfluoroundecanoicAcid Remit Q NNDDUU 043 1 00452111 NDU 0N45DU1 099 1 00388711 187 0814671 NDU MRL MDL 5300 009%5 50 00 550000olsl 50 048 5500 00088 50 000 55000 oolnl 50 oo 5500 0o0ll6 so 13 DFilauctuiorn ExtDraatceted AmDlatyeed ExtrLaocttionAnaLloytsisNote 11 2Y990l00 2I071T02:T10 1100552m 1W90o53w2 1 250 wnooksi 10s ies 11 22990000 2270002:s1]7 l10o5s7e2 119005s32 12/900 20710221710572 190532 11 22991000 221180M200241S7I lloosst 119900583322 1 2900 18100451 10572 190832 11 o2/9l00 2m81o004n31 l105s72 1190053s2 1 uso monn isu ies 11 22990000 mwnooxomiiy 11005s2 1100ss 1 ym ammo; osm 1052 Surrogate Name %Ree CoLnitmritosl AvDaaltyeed Q Note PPeerrflluuoorrooa--0{11122.,33,44,-51-3TC34C]3]buntoannansciiaccaid.d 1503 W0115500 Z218o00n851 PePrefrlfuuoorrooa--{{11.22.-3134C-21]3Cd4e]coacntiancaaicciadcid 110008 5500115500 221077M002222:1177 PePrefrlfulouroorno--n{-1{21-21-31C32C2})dohdeexcanaonicciaccAicdid [1032 5S0011550 221n8m1000281571 SPoedrifulmuopreornf-o{r1o2--11{31C,2]2u,n4d-e1c3aCnHooixcaAmceisdlooste 110020 s01i5s0 220077002221177 Sodiumpeflvoro-1-hexane( 1802Jsulfonate 106 0150 218100851 [-- Peotn2S23m1i01m54S1 ephcBnt Samia Stade: m0 30 CPlSreouajtpe:te:Mai: LSaambpCloedNeasme: BCaarmopnDBeusiertPMCcK9i5e7,7I9n7c5o0rp5rsedAn(alCyDtiMc)al Report War KRiooycoeoiSreat1"sRa DSearveicCeolRleeqcuteesdtL:: aK2/I50/01I00111508 Date Reseed: 2410 BUnai: Nnga. PeruorinatedSlfne Acids nd Pesuainated Cabos Acids by PLCS PArnaeyptMiectahlotdshat: MPeFtOhAod Analyte Name Rew MRL MDL DFiiocon ExDacteed AmDaited Estkaociion AnaLlayrsisNoe PFeotruloorrsnmaneclaonnteac PPPeeefaoordoredecicnaaniecSAlAfccoante FPPeeerrulrrusrdrsoedpeaacnanonortAciAecdid FefuotwanocAcd PPPeeretfuuluroosrrooancsoancananono:iscAiAcocinde PPeerrfoorrnopdeonaannoiicAccAicdid eNmOiU 5500 o09m5 11 voon wmiooomsoal wlosse lmasons G03S7 NOU ssSooo oomms om 111 owmm yom mumwoiososomseossl lWoowsse ibbseoossse N13U Y5 Ssoo 0osms 50 amo 11 1 w29om woo wun0mosnol uwiwosol liosses sri lboosse 1s3 0 oll 1 om uwoosol 1s bos 02322)00 S55o00 0oO.M1o2e 111 uw29oo1m0 w2a1m7m/m1o0m2n2a:2s4 ol10os5w74ue2 eb19so05ss32 NLGU Sso013an 11 u2nao iwwmlooonsaosl wlowwee wes Coral Dae PSeE urrlroorgoatne.{N,a2m3e.4-15C4]bao cd W%wRec sLE iamists awAmvaolyszeedl Q Note PPeroeroon{1n.2.3,415-C12]3Cd4e]coactlaancedacid Wwwo ssaass uammmomn PPPereuoiorororon-s{n1{1212--21133-CC222]udnboeddseaeccaannlecAiAdccidd s 0 osaas mawmoosmol soa moma Som pore (1230 SCHanemone 116 S10 27102508 Sodium perfluoro-1-hexane(1802]sulfonate 134 50-150 2/18/10 05:01 Comte razontesto renin Sates, ma a Client: SParmojpelcte: Matrix: Sample Name: Lab Code: AnalyticalRept Camp Dre&sMscKeeer,Incorporated (CDM) Baron &Budd,P.C/9T19-75319 Water RoyceStreet "Treated" K1001011:020 p35 SDearvtiecCeolRleeqcuteesdt::2/K310/01100111516 DateReceived: 2/410 UBnaistiss:: NngAlL Perflorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS PArnealpyMtiectahloMde:thod: PMeFtOhAod Analyte Name PePrfelufouroo-nrtorindeicmanacidceaccaiadcndoc Perfluorobutanesulfonate Perfluorobutanic Acid PPeerrflluuoorrooddeeccaannceSiuclAfcoinadte. PerfluorododecanoicAcid PerfluoroheptanoicAcid Perflvorohexanesulfonate PPeerrffllvvoorroonhoenxaannociicc AAcciidd Perflvorooctancsulfonate. PPeerrffllvuoorroopoecnttaannooiciAccAicidd Perfluoroundecancic Acid Rest @ MRL NNDDU U 050 081 50 0517 50 oNnD)U 5500 ND U 50 121 50 21] 50 177 047 5500 22] 50 2% 50 11) 50 ND U 50 Dilution Date Date Extraction Analysis MDL Factor Extracted Analyzed Lot Lot Note 046 09s 1 1 Z2/99/1N00 2217701202223322 10572 10572 0029 1 29/0 218100510 105742 onl 009s 1 1 2/910 218100510 105742 290 217102232 105192 048 1 290 7102232 105192 08s 008 1 1 2910 2910 21710223 YIHI00510 105742 105742 000 1 2910 18100510 105742 0ol1l2 I1 22/991000 721110020253120 11005577422 006 1 2910 217102232 105742 0066 oll 1 I 2910 2910 217102232 MIYI00510 105742 105742 13 I 29M0 7102232 105742 19052 19052 190532 190532 19052 19052 190532 190532 190532 119900553322 190532 190532 190532 190532 `Surrogate Name PPeetrlfulouroor-on--n{[11,,22,,33,94,-51-31C34C]3b]untoamnoaincoaicciadcid PPeerrfflluuoorroo--nn--{{11,,22+,1334C-21]3Cd4e]caocntoainoaiccidacid PPeerrfflluuoorroo--nn{{11,,22--1133CC22]JdhodeexcaannceicacAicdid SPeordfiluumorpoe-rlnu{o1r,o2--11-3{1C,22J,u3n4d-e1c3Ca4n)cioccaAnceisdilonate Sodium perflvoro-1-hexane[1802Jsulfonate Control Date %Rec Limits Analyzed Q ST 85 000 270223 5050 218100510 108 100 50150 217102232 50150 2177102232 8 50150 a+ sao 218/1005:10 20710232 947 8+ 5S0041500 21710223 217102232 102 50450 2/I8100510 Note -- Comments: Pred2231013:41 NaS Aa Fomin SupeRt 10S 32 Client: PrSoajmepclte:Matrix: SLaambplCoedNe:ame: Assyical Reprt B(Caamp&tDrBoeusdnsde,&rP.McCK/e9eS,T9In7c5o3rp1o9rated (CDM) Water MKeQtIOh0o0d6B6l4a-n0k6 Ps SeDravtieceCoRlelqeucetsetd:: NK1A001011 Date Received: NA BUansiitss:: NngAlL Perfluorinated SulfonicAcidsandPerfluorinated Carboxylic Acidsby HPLC/MS PAnraelpytMiectahloMde:t~ho~d: MPeFtOhAod Aualyte Name PPeerrffluuooror-onn-tireiidercdaaencociadcnocacd Perfluorobuanesulfonate PPeerrfflluuoorroodbeuctaanneoiScuAlcfoindate Perfluorodecanoic Acid PPeerfflluuoorroohdeopdteacnaoniociAccAicdid Perflvorohexanesulfonate PPeecrtfilvaoorroohneosnaanncoiiccAAcciidd Perfluorooctanesulfonate: PePrefrlfulourroopoecnttaannooiiccAAcciidd PerfluoroundecanoicAcid Result Q MRL MDL DFialcattioorn ExtDraatceted NNDD UU50 0009%5 1 1 2299000 042) SO 0020 1 2910 001148 55000 0O09l5 11 u299M000 NDU 50 048 1 29M0 NNDD UU 5500 000885L 11 2299000 011 50 000 1 290 NNDD UU 55000 0Ol 11 22/99000 059) 50 004 1 290 0N2D11U 5500 0O0l66 11 22991000 ND U 50 13 1 290 AnaDlaytzeed ExtrLaocttion AnaLloytsisNote MJ0O 21D7 110055T 72 o 190532o 21100608 10572 150532 22710020361078 110055778922 119900553322 21702317 loser 190532 V2I1N7I0020360078 110055774422 115900553322 218100608 10572 190532 M210102016078 l10o5s7e4r2 119900553322 1702317 10572 190532 221187110002630187 110055778422 119900553322 2702317 1052 190532 Surrogate Name PePrefrlfulouroor-on--0[-11,12..23,.344-,15-3TC34C]5b]untaonmoaincoaiceiadcid PePrefrlfulouroor-on--n{-1{,12,-21,334C-21]d3Ce4c]anocctiacnoaiccidacid PPeerrfflluuoorroo--nn--{{11,,22--113C32C]2lhdeoxdaencoaincicacAicdid SPeordfiluomopreor-fnu-o{r1o,-21-{1132C,23j4un1d3e0c4a]nooiccaAmcesildfonste Sodiumperfluoro-1-hexane{1802Jsulfonate %Rec CLoinmtirtosl W 107 00S1050 11m00 SS000000 61105 S5001100 51205 5500415500 107 50050 AnaDlaytezed Q m2/18m/100m6:08 2211m7M0022331177 2217801200861078 271071203231177 218100608 Note -- Comments: PeritsenS2ar0 R01AM 56 Fomia SwsaRdocs. aon 3 Client: Project: Sample Matrix: Sample Name: Lab Code: AnalyticalReport CampDres&MscKeeer,Incorporated (CDM) Baron & Budd,P.C/95779-15319 Water LabControl Sample KQI000664-05 p-38 Service Request: K1001011 Date Collected: NA DateReceived: NA UBnaistiss:: NgAL Perfluorinated SulfonicAcidsandPerfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA PrepMethod: Method Analyte Name Dilufon Date Date Extraction Analysis ResulQt MRL MDL Factor Extracted Analyzed Lot Lot Note Perluoro-n-etradecanoicacid Perfluoro-n-trdecani acid 920 Perfluorobutancsulfonate. 760 PerfluorobutanoicAcid 90.0 PerfluorodecaneSulfonate 550 PerfluorodecanoicAcid ws Perfluorododecancic Acid 10 Perfluoroheptanoic Acid 102 Perfluorohexanesulforate 815 PerluorohexanaicAcid 96.0 Perfluorononanoic Acid 925 Perfluorooctanesulfonate 890 Perfluorooctanoic Acid ns Perfluoropentanoic Acid 955 Perfluoroundecancic Acid 13 50 0% 1 Zol0 ZI0510 1054 1055 50 095 1 2910 217102310 105782 19052 50 009 1 29/10 800558 105742 190532 50 oll T2910 218100558 105742 190532 50 0095 1 910 217102310 105742 190532 50 048 1 2910 21702310 10542 190532 50 oss 12/500 217102310 105742 190532 50 008L 1 9/10 2100558 105742 190532 50 0030 1 2/910 218100558 105742 190532 50 oil I 2/900 21W100558 105742 190532 50 on 12/910 217102310 10572 190532 50 0046 1 910 217102300 105742 190532 50 006 1 2/9/10 217702300 105742 190532 50 on 1 2/910 218100558 105742 190532 50 13 1 2/900 217102310 105742 190532 Control Date Surrogate Name %Rec Limits Anmlyzed Q Note PPeerrfflluuoorroo--nn--[{11,,22,,33.,44,-51-31C34C]3b]untoanmoaincoiacciadcid. 95%% 15031500 2211877110020351508 Perfluoro-n-{1.2,3,4-13C4]octanoicacid 107 50150 2177102310 Perfluoro-n-{1,2-13C2)decanoicacid 100 50150 2177102310 Perfluoro-n-{1,2-13C2] hexanoic acid 92 50150 2187100558 Perfluoro-n{1,2-13C2]dodecanoic Acid a 50450 217102310 Perfluoro-n{1,2-13C2Jundecanoic Acid a+ 5010 217102310 Sodium pesluo-1-{3104,]2oc,tan3es,ul4fo-na1te 109 50050 217102310 Sodium perfluoro-1-hexane[1802sulfonate. 100 50150 2/18/1005:58 Comments: Pinoand2t 2310 c 3:1 p Ramin Sept 100513100 34 Cleat: Project: Sample Matrix: LSaambpCloedeN:ame: Run Type: Ansytcal Report BaCraomnpD& rBuedds,&PM.scC/Ke9e5er7,79I-n7co5r3p1o9rated (CDM) Water KMQcIA0l0li0s6t6e4r-"0Tr1eated" Matrix Spike p-3 Service Request: K1001011 DDaatteeRCeocleleicvteedd:: 22//34//1100 1002 UBnaistiss:: NngAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS. Analytical Method: PFOA Prep Method: Method Analyte Name PPeerrfflluuoorroo--nn--ttertirdaedceacnaoniocaicsida.cid Perfluorobutancsulfonate PPeerrflluuoorroobduetcaannoeiScuAlcfoindate PerfluorodecancicAcid PPeerrfflluuoorroohdeopdteacnaoniociAccAicdid Perfluorohexanesulfonate. PPeerrflluuoorroobneoxnaannooiiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuoorroopoecnttaanncoiiccAAcciidd Perluoroundecancic Acid Ret Q MRL MDL Dilution Date Factor Extracted Date Analyzed Extraction Analysis Lot Lot Note OLS 86.0 50 046 50095 1 1 J9I0 2/90 0M low 21710239 10572 Beh 190532 850 50 009 1 2910 218100520 10572 190832 101 550 50 50 on 0095 1 1 2/9010 2910 218100520 17102239 105742 10572 19032 190532 104 50 048 1 290 21702239 105742 190532 965 105 50 085 50 008L 1 1 2910 2/910 21710239 218100520 1052 10572 190532 190532 865 50 000 1 2/910 218100520 105742 190532 103 105 50 on 50 012 T2910 1 290 218100520 M0239 105742 1052 190532 190532 ws 50 00% 1 2910 217102239 10572 190532 935 95 50 006 50 oll 1 1 2910 2910 217102239 18100520 1052 105732 190532 190532 130 50 13 L910 217102239 105742 190532 Surrogate Name Control %Rec Limits PePrefrlfluuoorroon-{n1-,[12,,233,,445--113C34C)5]butnaonmoainccaicciadcd 13 104 S010 50450 PePrefrlluuoorroo--nn-{{11.,22-,133,C4-21]d3Ce4c]anooctiacnaociicdacid 135 100 50450 50450 PPeerrfflluuoorroo--nn{{11,,22--1133CC22]}dhoedxeacnaoniccicacAicdid 105 2) 50450 50050 SPeocdfiluumorpoe-fnlo{r1o,-21--1{31C.22,}3u4n-d1e3c0a4n]cacitcaAnccisdufonate 3 19 50150 5005 Sodium perfluoro-1-hexane(1802Jsulfonate 3 50150 Date Analyzed Q Note Z21I8170/05M2002239 217102239 2177102239 218100520 22117777110022223399 221187110002522309 -- Comments: Prleo2z210 13:8h1 ens Fom1a SipeRetr, 105008105 35 Client: PSraomjpelcte:Matrix: LSaambpCloedeN:ame: Run Type: Assyticl Report Camp Dre&sMscKeeer, Incorporated (CDM) WBataer&tBuoddn, P.C.95T19-75319 KQMIc0Al0l0is6t6e4r-"0R3aw" Matix Spike pd SeDravtieceCoRlelqeucetsetd:: 2K/130/01100019149 Date Received: 2/4/10 UBnaistiss:: NnAg Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS APnraelpytMiectahloMde:thod: MPeFtOhAod Analyte Name Rewlt @ PePrefrlfuoorroo-nniterriaddeceacnacnicciacciadad1011 00 Perflvorobutancsulfonatc 915 PePrefrlfulouroorboudtecaannoeicSuAlcfiodnate 98655 PerfluorodecanaicAcid 85 PePrefrlfulovroorhoedopdteacnacniociAccAicdid 112053 Perfluorohexancsulfonate 130 PePrefrlfulouorroohneaxnaannooiiccAAcciidd 210292 Perfluorooctanesulfonate po) PPeerrffllvuoorrooopcetnatnacniocicAAcciidd 1210 PerfluoroundecancicAcid 120 MRL MDL Dilution _ Date Factor Extracted Date Analyzed ExtrLaocttion AnaLloytsisNote T50o1 00486s 1 2299100 Z2I17T02254 110055772 D190B53R2 50 0m 1 2900 218100539 105742 190s 55000 0O0n95 11 2u990100 2M18010205539 11005577422 11990055322 50 048 1 2500 210254 1052 190532 5500 000885 11 229//91000 221178110002523594 110055422 119900553322 50 0030 1 2910 21100539 1052 190532 5500 ooill 11 22/99/000 2M181M005s39 1100552M 119900553322 50 0046 1 290 17102254 105M2 190532 5500 0o0l6l6 11 22/991100 22117810002523598 110055M22 119900553322 50 13 1 290 nozest 10512 190532 Surrogate Name Control %Rec Limits Date Analyzed Q Note PPeerrlfulouroor-on--n[-1{.12..233.,44.-51-31C34C]3b]untoanroaincoiacciadcid 910 510100 22 1810B 0539 PPeerrfflluuoorroo--nn--{{11,,22-1334C-21]3dCe4c]anocotiacnaocicidacid 110106 SS000000 2M1700223354 PPeerrfflluuoorroon-n.n{{11..22--1133CC22)}hdeoxdaencoaincicacAicdid 957 5500015500 221187110002523594 SoPderifulmvpoerrof-lnu-r{o1-,12{-11.32C.23],u4n-d1e5cCa4n)ociacncAscuildfonste 51113 5500005500 220177M0022225544 Sodium perfluoro-1-hexane{1802jsufonate 107 50-150 218100539 Comment: Pisoear2T2S31u0i1L3.m4S1 epA Femia SopeseReemss 1000S 6 Cleat: PrSoujmepclte:Matrix: LSaabmpCloedeN:ame: Run Type: Ansytcal Report B(aCraomnp &DreBsusdedr,&P.MCc.K9e5e7,79I-n7co5r3p1o9rated (CDM) Water McKAQlIl0i0s0t6er4-"T0r2eated" Duplicate Matrix Spike p41 SDeartviecCeolRleeqcuteesdt:: K1001011 2/3/10 1002 DateReceived: 2/4/10 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Analytical Method: PFOA PrepMethod: ~~ Method Analyte Name PePrefflluuoroor-on-entr-dteectamnodieccaacniaodcicd Perluorobutancsulfonate PPeerrfflluuoorroobduetcaannoeiScuAlfcoindate: PerfluorodecanoicAcid PPeerrfflluuoorroohdeopdteacnacniccicAcAicdid Perfluorohexanesulfonate PPeerrfflluuoorroohneoxnaannociiccAAcciid.d Perfluorooctanesulfonate PPeerrfflluuoorrooopcetnatnaoniccicAcAicdid PerfluoroundecancicAcid RetQ 107 102 88.5 102 56.0 90 850 108 85 101023 950 %.0 101 2 Acids and Perfluorinated Carboxylic Acids by HPLCIMS MRL MDL 5500004965 50 009 5500009ou5l 50 048 5500 000885L 50 000 5500 o0i1n2 50 0046 50 50 006 ol 50 13 Dilution Date Factor Extracted Date Analyzed Extraction Lot 11 22990100 1 21910 T2910 1 290 1 2910 I1 221/991100 1 21910 1T29219100 1 2910 1 1 2/900 2/910 1 90 J21U7I1I02022427eT110055420 218100529 105742 218100529 17102247 105742 10542 217102247 10572 22117110002522497 11005577422 218100529 10572 02128120045279 105742 10542 17102247 10572 217102247 218100529 105742 105742 21710247 105742 Analysis Lot Note 1190052 19032 190532 190532 190532 11990055322 19032 19032 19052 19052 190532 190532 190532 Surrogate Name %Rec CLoinmtirtosl Date Analyzed Q Note PPeerrfllouoorroo-nn{{11,,22,,33,44,-51-3C143]C]buntaonmoainccaicciadcd 110064 S5001150 0 2DI1I801202045T29 PPeerrfflluuoorroo--nn-{{11,,22-,1334C-21]3dC4e]coacntoaincoaicciadcid 110202 5500045500 22117711002222:4477 PePrefrlfulouroor-on--n{{11,,22--1133CC22}]hdoedxeacnaoniociaccAicdid 107 55 50450 50450 218100529 2171022:47 SPeordfiluumoperfol-onr{o1-,12--{113.C22,]3u4n-d1e3c0a4n]coiccanAecsiudlonate @nn 5500405500 221177711002222::4477 Sodium perluoro-1-hexane( 1802sulfonate nm 50050 218100529 -- Comments: Prlao22n30e0 13p 41 t Fmin Seperate. 10S a7 Client: PSraomjpeclte: Matrix: Sample Name: Lab Code: Run Type: AnalyticalRept Camp Dre&sMscKeeer, Incorporated (CDM) Baron & Budd,P.C/95779-75319 Water MKcQAIl0is0t0e6r64"-R0a4w" Duplicate Matrix Spike p42 Service Request: DateCollected: K1001011 2/3/100949 DateReceived: 2/4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS Analytical Method: PFOA PrepMethod: Method Analyte Name PPeerfflluuoorroo-nni-crtirdaedceacnaoincoaiccaidid Perfluorobutanesulfonate PPeerrfflluvoorroodbeuctaanneciSculAfcoindate. PerfluorodecancicAcid PPeerrlflluuoorroodhoedpetcanaonicciAccAicdid Perflvorohexanesulfonate PPeerrffllvuoorroonhoenxaannociicc AAcciidd Perflvorooctanesulforate PPeerrfflluuoorrooopcetnatnaoniociAccAicdid PerfluoroundecanoicAcid RetQ MRL 889.5 5300 93.0 50 980 a9 50 50 0 50 855 py 50 50 140 50 120 50 25 50 350 133 50 103 ns 50 50 Dilution Date Date Extraction Analysis MDL Factor Extracted Analyzed Lot Lot Note 008456 11 22/991100 22170 1023002 2 110055775 4422 0110900550 3322 0029 1 2910 218100549 10572 190532 onl 0095 1 1 2/9/10 290 218100549 217102302 105742 10572 190532 190532 048 1 2910 217102302 105742 190532 08s 0081 T2910 1 290 217102302 218100549 105742 105742 190532 190532 0030 1 2/910 218100549 105742 190532 ou on 1 1 2/910 2/900 218100549 217102302 105742 105742 190532 190532 006 1 2910 2017102302 10512 19032 006 ou 1 I 2/90 2910 217102302 18100549 105742 105742 190532 190532 13 1 2910 217102302 105742 190532 Surrogate Name PPeerrflluuoorroo---n{-11..22,,33.,44,-51-31C34C]3]buntoamnoaincoiacciadcid PPeerrfflluuoorroo--nn--{{11,,22-,1334C-21]3Cd4e]coacntoaincoaiccidacid PPeerrfflluuoorroo--nn-{{11,,22--1133CC22]JdhoedxeacnaoniocicacAicdid PSeordfliumorpoer-fnl{u1a,ro2--11-3{1C.22J,u3n,4d-e1c3aC4n]cioccaAnceisdufonste `Sodium perfivoro-1-hexane[1802]sulfonate. Control %Rec Limits AntDlatyezed Q Note maw momma 9 10 50150 50150 218100549 217102302 100 97 50150 50150 217102302 218/1005:49 58 6 50150 50150 217102302 2177102302 14 106 50050 50050 221178110020350429 Comments: Pieodn22z30e0 1:41 psn Fomia Sipe Rete 100013 38 Client: Project: Sample Matrix: QUQCReport p.43 BCaarmopnD&rBuedds,&PMs.Cc/Ke9e5er7,79I-n7co5r3p1o9rated (CDM) Service Request: K1001011 DateCollected: 213/10 Water DateReceived: 24/10 DateAnalyzed: 217/10 2810 Perfluorinated Sulfonic Matrix Spike Summary Acids and Perfluorinated Carboxylic Acids by BPLC/MS. Sample Name: McAllister Raw" Lab Code: K1001011-007 UBnasiitss:: NngAlL Analytical Method: PFOA PrepMethod: Method Analyte Name PPeerrflluuoorroonn--eirdaedceacnaincciciadcid Perlvorobutanesulfonate PPeerrfflluuoorroobduetcaannoeiScuAlcfoindate: PPeerrfflluuoorrooddeocdaencoaincoiAccAicdid PerfluoroheptanoicAcid Perfluorohexanesulfonate PerfluorohexanoicAcid PPeerrfflluuoorroooncotnanaenscuilcfAocriatde: Perfluorooctancic Acid PerfluoropentanicAcid Perfluoroundecanaic Acid Sample Result ND ND 58 50 013 083 ND 16 55 2 M15o0 38 13 31 Matrix Spike KQ1000664-03 Duplicate Matrix Spike KQIO00664-04 % Rec RPD Rest Amount %Rec Result Amount %Rec Limits RPD Limit lol 10 100 100 101 100 895 795 10 10 9% 8 50-150 50-150 12 2 30 30 ols 9%6S 10 100 8 92 90 980 10 100 9 50-10 2 0.10 2 30 30 485 895 00 100 48 + 479 8 80 10 10 48 *50-10 8 50-150 1 1 30 30 103 100 25100 103 19 85S 1a 10 100 8% 9% 50-150 19 0-10 10 30 30 13 2 10 10 75 9% M0 10 10 10 85 9% 0-10 7 50-10 2 30 30 220m9 a1000 739 22s3 1100 8 8 50-150 7 50-150 0 30 30 2 Ho 10 100 8B 97 133 103 10 10 9% 9% 0-150 9 50-10 6 30 30 20 100 7 Ws 10 11 50-10 5 30 Comments: Prlineen22d31s0 13p41arapet Mie SpikeSumy 39 Set Rl 0031300 PCrloijeenctt:: Sample Matrix: QueReport CBaarmopnD&rBuedds,&PM.scC/Ke9e5er7,79I-n1c5or3p1o9rated (CDM) Water p44 SeDravtieceCoRlelqeucetsetd:: 2K130/0110011 DaDtateeAnReacleyizveedd:: 22//41/71/010 2810 Perfluorinated Sulfonic AcidsMaantrdiPxerSfpliukoeriSnuamtemdaCrayrboxylic Acids by HPLCIMS SLaambpCloedeN:ame: MKc1A0l0l1i0s1te1r-0"0T8reated" BUnaistiss:: nNgA/L APnraelpytMiectahloMde:t~hod~: PMeFtOhAod APnearlflyotreodNeatmraedecanic cid PPPeeerrrfffllluuooorrrooonbbuu-ttdaaenneocsiauclnAfceoiancadtied PPeePrreffrllfuuloourrooordoddeeoccdaaenncceaiSncuolAifccoiAncaditde PPeePrreffrllfuulouorororoohhheeexxpaatnnaenosoiuiclcAfcoAnciaidtde PPeerrfflluuoorroooncotnaannecsuilcfAocnaitde PPPeeerrrfffllluuuooorrroooopucentndatenaconaioncioAcicAciAcdciidd SaRmespullte NNDD 029 06577 06 0133 009350 00s7s 045 3139 KMQa0t0r0i6x6S4p-ik0e1 Rest Amount %Rec S8L6s0 1100 2 8 180510 10000 85 9% $1004 1100 1s0e3 91055 1100 19054 81053 1100 182 s1i05s 1100 14 93 993s5 11000 93 6 30 10 128 `DuplKiQcaIt0e0M0a6t6r4i-x02Spike % Ree RPD Result Amount %Rec Limits RPD Limit 1172 110000 110072 5500--115500 15 17 30 30 818025 11000 88 95 00--11500 4 1 330 S96900 110000 $958 5500--11500 2 4 30 30 815008 110000 1807 5500--11500 13 3 30 30 81935 110000 1802 5500--115500 3 0 3300 91520 110000 101 9% 5500--1100 2 2 30 30 91001 11000 9% 9% 500--1100 3 1 30 30 2 100 190 50-150 9 cower: PVreoss22310 13:01epsVr MatixSke Surry a0 Spt Ree AROD Client: Project: Sample Matrix: QuQC Report p45 `BCaarmopnD&resBsuedrd,&PM.Ce/K9e5s7,79I-n7co5r3p1o9rated (CDM) SDearvtiecAenRaelqyuzeesdt:: K21/01071/01101 Water 21810 Perfluorinated Sulfonic AcLiadbs aCnondtPreorlfSluaomrpilneatSeudmCmarabroyxylic Acids by HPLC/MS PArnaelpytMiectahloMde:thod: MePtFhOoAd Units: nl. Basis: NA Extraction Lot: 105742 Analyte Name Perfluoro-n-tetradecanoic acid PPeerrlfulruoorbou-tna-ntcrisduelcfaonnciacteacid PePrefrlfulouorroodbeuctaannoeiScuAlcfiondate: PePrefrlfulourorooddoedceacnaaniociAccAicdid PePrefrlfulouroorhoehxeaptnaensouilcfoAncaitde: PePfelrufoluroornooenxaannooiiccAAcciidd Perfluorooctanesulforate: PPeefrflluuoorroopoecnttaannciocicAcAicdid Perluoroundecancic Acid Lab Control Sample: Result KQIE0x0p0e6c6te4d-05 %Rec %LimRietsc mw 20 100 om 2 0-150 50-150 72.600 1 10 0%9% 5500--115500 $0 0S 10 100 5s ol 50-150 50-130 Ho 02 100 10 m0 50-150 102 50-150 8S 90 100 10 9% 50-150 50-150 025 11000 9B 8 50-150 50-10 2s 985 100 100 8 9% 50-10 50-150 mW 00 13 50-130 Comments: PiNneid2a23s10s134a1 Ce LahCoreSupeSumy a Spr Rete 10000810100 Columbia LSSo services: PrCinrteead:ted18w/i0t2h/A2n0a1l0ys3pt:24R4e6.p0o0rPteMr DPraotjaecFtile 0`E2w1a7n1'0siPSraomjepcliessPLFoCngs wif InRessturlutmTeanbtleName __A0P2I1751000l0ang do [SaAcmqpuilseitRioanmHse--th[oKdi|ooP27tF1oC7r2K0in7-e0ot80e07x5C5d7oanPmgit [SinajmepctlieonTVyopleume [|U5ninon | [injectionVial 125 | WeighttovoiumeJoo | Results Summary. TT `aAnnaleyte Peak [ twee[sae[AEnaisRRT moagenes | SCoageuCioync [women | PFOAT 18CPFOA| 4sesto0 | 124136)| tesco | 7720 | mo | = nace| aos00 [2070s| aes | a0 | No | PFOS 1 1acPros| sure |207zos)| amsmoo0 |saen0| [promt 1CPROA| 217400 [2|0T8 ates| ie 13CPFD0A| 206180 | 559551)| 4918 No Aa$ e re 219 ( Page 5001170 2 Lm fCreae tedwiat Anatlgopreporer [or | WeSummary Fron [rss [ onowo |wo|ana [ve | 5.190.908 [rasa [ emswo |wo [ zsmuste[we | prwnz_ Jaoiaos|wee|we|oses | ves | oserma [owas | 0| mo| wooo[we | Jorose [20am [wee| wo [omem| ve | |s-1seeros [2oseon| swmso|wo[ozenry[ow | fron [sosaom | wm |wo [omew| ves | 8.nePro [swoon| wero|woJwzrores| we | rTrun swan] [sscrrom |swosn[wa |wo |remaeo [ we | [rose [swoon| wz|we|omosm | ve | [promz [omasn| 0 |wo| owom| we | sosorron |esuen| ammo|we|ween| ow | [prmz [soa | em |w |owes [ we | raz Tosaw| me|w |ome | we | Page s10r 170 o 4AnSaollyatmibciaalServicesTM `Quantitative Peak Review oa TF Greated with AnalysptaResporter Printed: 18/0212010 3:24:00 PM K1001011-001 = 77 = 0% . 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"1 S54 B7as1eP3liF0nT1e 1e26AM9Dis0ased Wrong Peak 0 Before OI] After Page 530f170 as  Gotumbia AnalyticalServices" PrCnrieeda:ted18w/i0h21A20n1a0l4y5..0R52e00p0ortPeMr PrDoajteacFtile Result Table cGE2va1a17nT1si0P01rSsoahRmdocplrblsePsRsChSowrit Instrument Name__ API5000 [[S`AacmapuliseiNtaonmDeate |[R2i1o1B6i20o1T0i2o005T-6Al _|| ISmaemcplteoTnyvpaetume[5 (nec[t25onViar [Weighttovoiume[000 AaRermsytuel"tPsosS|ummaryinn [was R[aFtReATAT[ ayn | GaptelCoyne | | [weara er [pres EX 1sopens| T3CPFHA | sown ceosso0 ||asmaaszhe||trs esone||i2o e4msr | CH Mo [Prins |tsoprr|s soso | 62630| dsereono No | Isisopris | raceron| atmo [eze@en| wowso | 118 | ne | [sisopron | 1aceroa | ation| 7ssaes| sition 4&4 ZZza?le Pe Pa49gof1e69 a 8 SAnaolymticaalServices Creates wits Anaspeporer Printed: 18/02/2010 4:02:00 PM Cavs WeSammary [rane [rene pros [prose fprwsz 5.tcPro [sosormron [rn| [sr og [rao | wes [we |reonon | ve Tasesso|vooaow [ wo| toonon | ves |epuzm |w|o No | owes oman me] row] [erea |oso[wo |sas | ves | [emew|wows|w |osteo| we | [raz|ooo |wo|vemsao | ow |szssso | somo|wo|omer | we | PageS001169 a 3 ASnoalluymtibciaal Services" `Quantitative Peak Review = To Tw 4| i| | 35 =i PrCinrteeadt:ed18w/i0t2h/A2n0a1l0ys4t:.0R52e20po0rPtMer K1001011-001 T 57% - B2a1s3e.l0Pi/Fn1e6B9A.10Mi0sased | cB2a1s1o73l.Cn0-e1P7cF2BM0Ai0sased | B2a6s3e0lP1iFn2Pe1A901MiDsased| oBa3s11el35iCn0-e2PuF7HM00Ais0ased ony et um wage I i FC i 1 dL u cBa2s0e0lPi/FnB8eS0c10M0isased | Ba4s0e1l38i00n1-e0P3FcMH0iSDsased | Ba3se1l3Pi0nH2e6A910Mi0s2sed| c B3a1s15e3l0Ci1-n2eP7Fc0H0MXiADsased lige: v "ang pea 7 Wong pe ] tiong pea bi iol i I ne. 1 Ai A CB3a6s3e.Pl0iE/nH1e6D9A.0M1iDsased | Ba31s13e5Cl0i-n2Pe7F:0H0XMiADsased | Bas3e0l9P.iE0n/He8X0S.0M1Disased | cBa4s0e13l8i00n-/eP1cF0HMSD3isa0sed 4F FI a JT 4 Fo i 2| TA AA Ba4sS0e_3l10i8/n01e-0MP3Fi0Hs0Ssaed | oB5a1s1e53l0Ci4-n7Pe0Fc0OMAsDsaed | oB5aS1s_5e1l03n4Ce7-c0FM0FiDsDAsaed | Ba5se11l53i0Cn4-e7Pc0F0OMAiDsased O Before OI After Page 51 of 169 a 8 humbia Analytical Services p.53 PrCinrteeadt:ed18w/i0t2h/A2n0a1l0ys4t:0R2e:p0o0rPteMr fon Ratio Confirmation mw aw K1001011-001 TT =1 :: ==z omoef IiIe op| 2130P/F1B6A920 Da 263P0R2P1e9A020a 269.P0R1E99S.20 0a BaseWliionnegcPMeiasksed| c BasWerlionnegoPMeiasksed | BaseWlrionneg PMeiasksed | Ten 7 = 4 Eo i Ei 8 Ll| 31P3F0H/1G21A900a BaseWlionnego PMeiasksed Tempe 363P0F3H1p9A02 Da 399P.R01H9I0S.02Da 5S1_513.C04P70F.0DADa a NA BaseWlionneg PMeiasksed | cBaseWlrionnegoPMeiasksed | BasWelrionnegoPMeiasksed | BaseWliionnego PMeiasksed NB. PFBA and PFPeA do nol have qualiying fon Iransions 0 Before OJ After Page 5201169 4 5AnGaollyatmical Services- PriCnrteeadt.ed1w6i1th0A2na7ly2s0tp1Rse0t0p3o0rP2tMe4r Project ReDsatualtFlTeable E0v2a1n7s10P:rSojaemcpilsePFsCtsowni g G21710ndgb Instrument Name __ API 5000 [[S`AacmaqupuilisseiitNtiiaoonnmDeattehod|J K2Fi7Cc7Ko7i72no0e11t70e-6x0:L01o26n:g0.9dPaIm [me`AcctonviarMe [|2P6 [ijec1i5 onvoume| |SWaeDimilpgutlhioetniTFoyapVcetoourme[[1o0o0o | | Results Summary Analyte Peak Faye RT Ete Cone cron | aso | 12200)| teres0 | 830| Mo PENAT 1ICPENA| 2601000 | 198208 No | pros 1 13C-PFOS | 7641700 | 2.05 (2.09) 38813000 47.500 No PFOA 1 13C-PFDA | 3083200| 306306) 0187 No [Pruna 1 Pros 1 TwaocrPFrUoNsA|| 142010 | mmm 3[966a00)||wwo14w06m| 0083 om | oo | Front | mcerom| zum | 45165 cy PFToA1 130.PFDoA 000(551) NA No Aa ee? Ls! Page s4of 170 50 AColumbia . AnalyticalServices" Created with AnaReporter Printed: 18/02/2010 3:24:00 PM RCSummary [roe vmom | ww| |Teen|e] [ema Tomas| o | wo| wmom| we | [ememos |swam|wm | vo|sma | we] [[rsoowmso [osmoanns||w0m || vwoe |soomrows||w|o] [rms omen[0 | we|omom| w| [roe omen] m0|w|oom| wo] . Columbia LS Sones services: PrCirneeda:ted18w/i0t2h1A2n0a1l0ys3t2p4.R.5ep06o0rtPeMr Quantitative Peak Review K1001011-002 - aSE |v T ; 5 LCwy 75 i io il i- L- | oe] de WN B4a1s3e0lPi/Fn1eO6A9C01MDisased | Ba4s1e17l3.iC0n-5eP7:F2OM0Ai0s0sed | oB4a6s3eP.i0Fn1Ne4Ac11.MiDsased | Ba4s6e1l83i.Cn0-e4PuF2N3MA0i.sa0sed z J |: } 5 il Bas4e9l9Pi.Fn0eO/8Sc010M0isased | oBa15s30eC0l-/i8Pe0FM0OiSsDsaed | cBa51s3e,Pl04iF6nD9e.Ao0 1Mi0sased | oB5a1s15e30iCn4-e7P0.F0OMAiDsased FEET ST TT Toe hot ameeg] 5AB &wegase? n] - me Ba5s6e3lP.i0Fn5U1eR9.Ao M1iDsased | cBa516s35eC.l0-i/nP2eF7c0U.N0MAi0sased | Bas5e09l.Pi0Fn/Oe80Sc.01MDisased| oBa5s0e13l3.i0Cn1-e8P0c.F0OMSDisased al ast h- ] 8 Fo | Ba6s1e3lP0iF/nD5eO6Ac9M10iDssaed | oB6a1s15e3l0Ci/-n1Pe6Fc9DM00iA0sased | oB6a6s3e.Pl0Fn6T1e9Ac.10Mi0sased | Ba6s1e15l30iC/n-1eP6cF9D0MOiA0sased wl ") Loom] A o7B1a3se.PlFi0nT6ee9A01M0isased | c B6a1s1e53lC0i-/neP1Fc6D9MOi.ADsa0sed 0 Before O After Pa56g0f1e70 52 4Columbia AnalyticalServices Created with Ansiyps57Reporter Printed: 18/02/2010 3:24:00 PM -- lon Ratio Confirmation 7 = z K1001011-002 i: I : i A = --- 41P3.r07O6A9.20 0a oBaselinec Missed | 463.P0E2N18A.?0 0a Bosoinoc Missed | 499.P09R9O.S0?038 Baseline Missed | c 513P.r0O2A6?9.00a Baseine o Missed WrongPeak WrongPeak Wiong Peak Wiong Peak I Ep [rete|Ehema| Cl lento 5P6F3U02T6A920 0a 5P99r.o09s920 0a oBaselinec Missed | oBaselinec Missed | 513P.0F1O69A.02 0a Baseline Missed | 663P0/E1T69A0 0a Baseline. 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InRessturlutmTeanbtlNeame__AoP2Iti5o0s0n0ort reo [Samp Name TR00T077002 Acauisitin Method|2P/F18k/2n01e0e2:x16S:4hd8oaAmrM [njectionvia __|26 [eiectonVorame [5] Sample Type | Weighttovolume[000 |] oT wr| eee HResnultPseaSk ummary erent| seers | mov F[r[raais|saRnY| maonn || tpeoiwCeane || --1 w re | or ma| seven [s|emasns| wm rast | worms | smo| 4200) = w wo Prat | morma| swe sacs| meen | ma "| | PFHpA 1 13C-PFHXA| 6881600 | 6.14(6.23) | 2502900 10.20 No sors | oeron | em corron ern| wo [omean| [sien| wewo | tw| emo |am| te we | Hy 5 z 2!"Ble Page 53.0 169 se J em rRCSWMMary [rrosts [|vsseam|| amamm || te |omoorne|| eve ]| [[rreaers seaaen || soemnen|| wweo||owwser | | || Pra srs| mom |wo| wa | ve [erm vanuan| wor |weno || - 4SoAnuaelmybteiicaalETServEicesE ---------------------- Quantitative Peak Review 7 T= 7 T= TE o5l =3 il 3 3 = PriCnrteead:ted18w1i0t2h1A2n0a1l0ys4t.p0.R26e.p00o0rPteMr K100r 1011-0r 02 r EI -"|| | c2B1a3so0Pi1nFe6B9Ac01Mi0sased | oB2a1s13e7Cl0i-1nP7eFc2BM0iA0s8sed | o2B6a3s0ePl1Ei2Pn1ee9AcM0|iDsased | Ba3se11l53i0Cn-2eP7F0H0MXiA0sased - - Ll | = fF | | Ba2s0e9lpi0nr/ee8s00|M0iassed | oB4a0s13e80l01n-1eP0cF3H0MSs0ased | o3B1a3s0eP1iF2nHe6Xc9A0M10isased | oBa3s11e35lCi0n-1ePF2cH7MX0iAsa0sed nip 1 tic pe y agg 2 hig a: | ol = |= c= l --_ AL A 1 cBa36s3eP.l0Fi/nH1ep69A.0M1iDsased | B31a13se5Cl0-i2nPe7F0cH0XMiA0sased | Bas3e0l9P.iF0Hn/Xe8S001MiDsased | B4a0s13e8l00i1n-e0Po3F0HMSi0sased lp lage ogg ea er 2 i i= i i= oB4aS0s_3e.1l08i/0n1-0e3cP.F0MHiDSsased | cB5a11s3s5Ci0-n4Pe7F0oO0MiADsased | cB5aSs1_e51l03i4Cn7e-c0PF0MDiDAsased | oB5a1s15e30iCn4-e7P0oF0OMAiDsased O Before O After Page 55 of 169 56 AYCoAnlaulmytbiicaal Services p.61 PrCinrteead:te1d8wi0t2h2A0n1al0ys4t0R2e0p0orPteMr fon Ratio Confirmation T ] o BSO Pc3 i=l K1001011-002 |=<) | -o A i5 2130P1F6BA820 0a Baseline o Missed | 263P0F12P1A902 0a Baseline o Missed | 299P.F01E9S9.20 0a Baseline: Missed | 31P3F0H/1I21A900a Baseline Missed Wrong Peak TE Wrong Peak = Wrong Peak TT -- Wrong Peak wt J eg |- | ol i Tisha sade . id - al L 36P3F.H0p1A3210.a Baseline c Missed | 309P.F0/H9G9.S0 2Da Baseline o Missed | 5S1_51.30C4-7P0F0D0Aa Baseline Missed | NA Baseline c Mii}ssed Wrong Peak Wrong Peak Wrong Peak NE PBA and PFPeA do nal have qualifying on ransiions Wrong Peak O Before OJAfter Page 56of 169 57 8Columbia AnalyticalServices* Created with Analypst.6R2eporter Printed: 18/02/20103:24:00PM Project Data File E0w2a1n7'1sP0r:oSjeacmtpslPeFsCLsownigf InRessturlutmTeanbtleName __0A2P1I715000000ng.120 ET we |i [0 sores | | [SampleName--Ti1007071-003 201712010 8:23:41 PM [injectionVolume 15] Sample Type [Unknown| Acquisition Method|PFCiinelexCongdam |DilutionFactor [100 [injectionVial 127~~[Weighttovomume [ooo | | Te Ro esultse TSuommgarL r y e tm----e me Ee r -- e --e -- Analyte Peak Analyte RY Gale Gone ma] PFOA1 [erat PFOS 1 PFDA 1 PFURA 1 PFS 1 13C-PFOA| 4084100 | 121(1.36)| 038810 4560 | 13cerna | 2701100 | 107200)| 1160300 wo |ow| wcpros| 730m [200@0w|va | zm a0| we 13C-PFDA | 3489500 |0.00(3.08) o wa No [racers | sae 000s|0 | NA | me 13C-PFOS | 7331000 | 383 en)| see 0025 No | pFeat HCFA | 241810 [sens| swe |wa | Ne | fo a Ce z Pa58gof1e70 8 Fr AnalyticalServices peCreated withAnalysFReporter RCSummarny roovnsert [reizen reoe:s [[oesmso Froomosrsrom rook Scere pros L[ormuawn||m e| we e|[GwEann || Tovmaan|| 0 smn || No [ooo| wo| omweamm|| we ||wow [eomenn|| ~ omwooomn||sw [[oww[ommem ||e osmoawns||oeww | we[|moewams|| _w | owas | 0 | wo re) owen | ve | Temem |mw mem|v] 59 3 lama AnalyticalServicesTM Created with Analyspt6R4eporter Printed: 180212010 32400PM Quantitative Peak Review 2 Tr "4 K1001011-003 =i ; var = I sl | C4B1a3s0e/Pl1iF6nOe9Ac.01Mi0sased | 41137C.0-3P7F2O0A08 Baseline Missed | 4630PE4N1A801 0a Baseline Missed | 461830C-/P4F2NA300a Baseline o Missed "4 am ocd a4 - = gohdnt) I = ri SRT 459PF0O8S00102 Baseline - Missed | 501330C/8-0P.F0ODSa oBaseline c Missed | 5130P4F6D9A01 03 Baselinec Missed | 51135C0-P4F7O0AD0a Baseline c Missed To ow | ~ ) zl wl Ll - Asati - 4 ga] | se iB . 563P.E05U1N9A. 1 Da oBaseline o Missed | 51635C.0-/P2F70U.R0A0a Baseline Missed | 599.P0F18O0S.01 Da Baseline a Missed | 50133C0-8P0F0OSDa Baselineo Missed = Fo | ] i1 io LiCc ogre dp Bed hepedPoe a A 613.0P/F5D6O9A.01 0a cBasoine oMissed | 611530C1-1P6F9D.oA0a cBaselinecMissed | o6B6a3se0Pi6En1TeAc8M01isDsaed | Ba6se11l35iC0n-e/PF1D6Mo9iDAs0ased be 587 of | 713P.F06T6E0A.10 Da 61153.C0-/P1F6DO9A.Da0 o Baseline Missed | Baselinec Missed 0 Before O After 50 Pa80gof1e70 LColR umbia Services: PrCirneteadted18v0it2h12A0na1l0ys3:t26R4e5:p0o0rtPeMr A = i b=go io= lon Ratio Confirmation - - K1001011-003 rae i Wetpl 2pheanat | = 3 = c41a2s.i0Pn2F6gO9A.c20Mi0sased | o B4a6se2Pl0iFn2Ne1Ac520Mi0s8sed | Bas4e9l9Pi0Fn1eO9SM02i0s0s8ed | c B5as1eP2li.Fne0Dc22AM6i0s0ased Wong Peak Wiong Peak Wiong Peak Wong Peak = = = = z i- i2 io | tie| eee| Lae Ba56Ps3Fe0U2lN6Ae92M0i0ssaed | B5as0e8Pl0iF/n9Oe9S.o20Mi0ased | oB6a1s3ePl0Fn1De6Oc5AM02is0saeq| o B6a6s3eP0i/Fn1Te6Ic92A0Mi0s8sed Wiong Peak = Wiong Peak Wiong Peak Wrong Peak B7a1se3Pl0Fin1Te6e9cA02Mi0sased = Wrong Peak 0 Before OAfter Page 101 170 o Columbia LSU services p.68 PrCinrteead:te1d8w1i0t2h1A2n0a1l0ys4t02Re0p0ortPeMr Project Data File 0E2va1n7'1s0SParomjpelcetssSPhFoCrst.it Result Table 021710shorrta.b Instrument Name __AP 5000 [SameName Rio07017-003 AcAqcquuiissiittiioonnDMaettehod||2P/F1C8k/i2n0e1l0ex2:S2h8o:r20dAaMm. [injectionViar 27 ~~ [injectionVolume [5] |[SDailmuptlieonTFyapcteor [[U1nk0n0own || |Weighttovolume[000 | Results Summary Afrnaat t Peak [isham|e isaea | AnAaRiyEtReTRTT anaonres | CCoeie CCoornc Modified? PFBA 1 13C.PFBA | 4866300 453610 08 | No PFPeA 1 1cPra| 5e0 [sien|mo | 2m 22| te | PFrpat | 13cPFrvA| 578700 | 612623| 401400 188 [Pers 1 180PFHS | 3651900 | 622(6.32)| 14457000 1270 S180PFHS | 13C-PFDA|4256|652306301)| sesis00 1.08 S13cPron | 1aoprDA| aasesto| 751|(aaesess0)| 100 No No No | No + "Lorr pn Pa57gof1e69 0 AnalyticalServices: CrveithAanalty Repordter oman RCSummary ran am|| w| |w we |Se ren|e | ve | [rreoisse [rrnsss [socrman [am || awwn|[wo|moeomn||_=|| [evnmewn||omomn || we|| ssownaem||__|| smn|orm| we[moon|e | 63 PASCAnoalluymtibciaal Services" Quantitative Peak Review -- SE-- i i= Tm i Created with Analyspt bReporter Printed: 18/02/20104:02:00 PM K1001011-003 Tm Fs 2130P1F6B9AT00a oBaseline c Missed | 211730C1-7PF2B0A08 Baseline Missed | 263P0E2P1e9A01 0a cBaseline oMissed | Ba3se11l35iCn0-eP2cF7HMX00iAs0ased : Bl of ae ne i zl 1 209P.F0E8S00 0a oBaseline c Missed | 41038,001-1P03F.H0SDa Baselinec Missed | 313.P0R2H5X9A.01 0a Baseline Missed| c 31135C0-P2F7HX0A0a Baselinec Missed . - = to l-e [ FaEl 363P.0F/H16p9A.01 Da cBaseline c Missed | 31135C0-2P7F0H0IA0a Baseline. Missed | 39P9F.H0X8S0010 Baseline a Missed | 40138001-1P0F3H0S0a Baseline Missed i: i 3 E[ A A Hh er 4S03_.108/010-3P.F0H0Sa oBaselie oMssed| 51135C04-7P0F.O0A0a oBaseliecMssed | 5S1_51034C7-0P0FDDAa cBaseinecMssed | 511530C4-7P0F0OADa Baseline o Missed 0 Before O After Page 59 0f 169 54 Columbia LS Soin services: Created with AnalySi.6Re9porter Printed: 18/02/2010 4:02:00 PM fon Ratio Confirmation ET i m |=ow 3= i.=z K1001011-003 AE= 7 | c=l i=: He -Ho 2130P/F1B6A920 0a Baseline Missed | 263P0F2P1e9A020a Baseline c Missed | 29P9F.0E19S9.20 Da Baseline oMissed | Wrong Peak Wrong Peak Wong Peak Tn = TT -= i| foomia ( im=t 31P30H/A112900a BaseWliionnegc PMeiasksed [-- 363.0P/F3H1p9.A020a 399P.E0H90X.S02Da 5S1_51.30C-4P7F0DD.Aa0 NA Baseline Missed | cBaseline Missed | Baseline c Missed | Baseline o Missed NG PFAWraonndg Peak PFPeA do nol haveWqruaolnfgyinPgeafokn ransitons. Wrong Peak Wrong Peak 0 Before OJ After Page 60 of 169 6 5AnGaloyltiacaml Services- paCnireeda:te18i0t2h1A5n0a10l5yp2.R47e0p6o0rFteur PrDoatgaeeFtile TG21a710PSoamRpaeRsPtRoCngSwi InRsesturlutmTeanbtleName __AGP2I157010000n 100 [SF ameae ms RTGoTGTIaoF Tea canvats[5] [[mATceausiso3itnion0Metho--d| PJFCkinevlexLonig damoniDilutoionFavctooru [T10000 | Results Summary rate Peak Har cic coe Pros 1 1aceros | marsio |208@om| 1reseo ) No | Pro 1 nceron | seam [ow| @0 on| wa | we [eros roses [mom] wr | wom 3Wu "ipd Page 6201 170 & 8 omnes AnalyticalServices' CrweithAanathiReepordter Printed: 18/022010 3.24.00PM `wRCSummary Trnava wri| ee wearer|Ogg | mei: r[n evsoee m ||wwr mwe ||mwveo||o voseonr ||_e m|| [semis Toman| 0 | wo [m|om| [error [aoa | wren |vo|swan|| [rooms Tomom| ow mom| w= | [rows [omen| 0|w |omen| [ras wom| we | ve [owom| | . Columbia LS Roi services: Created with Analy7Re2porter Printed: 180212010 3:24:00 PM 3 Quantitative Peak Review T Tw TE 2A . SE "| -- 413P0F16O9A.01 0a 41137C.-0P57F2O0A0a -Baseline Missed | ow Baseg ine Mipeassed Dea |: 3 A Fc A = E K1001011-004 mI 7 = pg =! of =wf --] 463P0/F4N1A901 Da 4681.30C14-2P3F.N0ADa | Baselwinoec Mssed| c Basebloinoeqc MiPseased : Co olen 2| 499P.F0O8S001 0a Baseline Missed | 15033C.0-/P80F.O0SDa oBaselne Missed | 513.P0F4D6A9.T0 Da oBaselinec Missed | 511530C4-7P0F0OA0a Baselinec Missed buggg 2e TA oo e Be sw) = lo rll a rN i. | fo 3 =] [iw!f RT aa ss e) oHl-- 563P.0F1U5R19A.01 0a "Baselineona Mipeassed | 15635C.0-1P27F0U0ADa 599P.0F8O0S.01 0a 50133.0C/.8P0F.0OS0a mBaseilinge uMissed | eolBasolinec Missed | oBaosenlneg Missed I| aTowpef i]LB Joil"ee fin LL | 613P0F/D5O6A901 Da 615.103/C1-6P9F.D0O0Aa c Baseline Missed | cBaselinec Missed | 663P0E6T1A901 0a 611530C/-1P6F9D00DAa Baselinec Missed | co Baseline o Missed ; [: J J LL -- 713P.F06T6e9A.10 0a 61135C0-/PF1D6O90Aa0 Baseine c Missed | Baseline Missed O Before 0 After Page 64 0f 170 6 4ACnoalluymtibciaalServices- Created with Analyspt7R3eporter Printed: 18/02/2010 3:24:00 PM lon Ratio Confirmation La 3 z | i" Eo peas2 al H- K1001011-004 \ I es - | Zhi 4130P3F6OA902 0a 463.P0E12N1A92.0 0a 439.P0F19O9S.2Da 51P3F02O26A9D0a oBaseWlrionneg MPeiasksed | BaWserloinneg PMeiasksed | Ba WsroenlgcPMieiasnkseed | cBaWsroengclPMieiasnkseed E: r iAo ai =. |i" 563P.F02U6T9A.02 0a 506P.R0O9S920 Da 513P0F1D1O69A02 0a 663P0F/T1i6A920 Da oBaseWlrionneg MPeiasksed | BaseWlrionneg PMeiasksed | BaWsoneglcPMieiasnkseed | oBaWsroengclPMieiasnkseed bi EI 713P.F0T/e1A6290.0a = BoaWserloinnegcPMeiasksed O Before 0 After Page 65of 170 69 [Goma AnalyticalServices iCroaat iith Ann5.R78or rReioseaiTable FCOrzEaisTTioPrmoRnoviT--n --C---- rumentime 4915000 [SampleName Rigororroot `AcjqeucitsiiotniVonlDa_te_[|22P81r1C8u/n2e0t1e0x2s.h3o7r.t56dAaMm [nectionVatume[5 | Sample Type | Weightovonme[000] ITResasults Summary [inne| sae T[PERE] aapes| SCHeS | oats roar worrer | suo |12eazn| soo | oor peerveenntt sores | ssoormao | [awaas||swzeooeroo| w 2a |ww e| privat | sorma| wom |szeom| oom o Fervor reorroan| sooo [ors07 Ce|wwo e | ow Pras | sores | sere |oz| tse "| sasorrs | worron | wow |oz@an| wm 0 - sncrron | woron | sewn | 7s20e| memo | ee | Ie oF rd Pagoef1t69 Fr AnalyticalServices- rCSWmmary cm [res swam|wor|e| vom|| I rr al I L REW. [errs l[veom|own | ve mmor|e|] . 8 ASnaulymticial Services" Quantitative Peak Review I Bl = Tw PriCnrteead:ted18w/i0t2h1A2n0a1l0ys4tp:0.R27e.6p0o0rtPeMr K1001011-004 To sw B2a1s3e.l0Pi1Fn6eB9Ac.T0Mi0sased | Ba2s1e71l.3i0Cn1-eP7F2B0MAi0sased | c2B6a3seP0lF2nP1ee9Ao0M1iDsased | Ba3se11l35iCn0-eP2cF7HMX0i0As0ased - we tions pos ug Wasa pen :po -- oB2a6s9e.lP0i/rn8ae0s.0|MiDsased : " ' wl a] | B41a0s8e30l.i-0nPe0F3MH0iSsDsaed | El 3rp Ba3se1lP3iF0nH2eG6A90M1 i0s2sed - i [4 wl | Ba3se11l35iCn-0eP2cF7HMX0i0As0ased py Eo Ba3s6e3lP0iF/nH1ep6Ac90M1iDsased| oB13as13e5Cl0-i2Pn1Fec0H0XMiA0sased | Bas3e9l9P.i0nH1e8S0c.01MDisased | Ba4s0e13l80i0/n-1eP0F.3H0SM.i0sased iy gg oa ag hyp ;1 2= i= == wb Ben Se sree] 4S03_.108/010-3P.F0HDSa aseline issed | oB5as11e5l30iC4n-7ePc0FO0MAiDsased | be re] oB5aS1s_e51l03n4Ce7-c0PMF0iDsDAsaed | er Re Ba5s1e1l53i0Cn4-e7P0oF0OMAiDsased B oM 0 Before O After Page 63 0f 169 2 8 lAnualmybtiicaalServices Created vith Analypst77Reporter Printed: 18/02/2010 40200PM lon Ratio Confirmation ITw c= 3Hd I =2 K1001011-004 =4 3pr I=J 41. xDs 2130P1F6B9A20 Da Baseline C Missed | 263P0E2P1e0A020a co Baseline Missed | 209.P0F/9B9S.02 Da Baseline Missed | Wrong Peak Wong Peak Wrong Peak Tem > i oo"l lol=e i = 4 xl zl 363P.0F3H1p9.A2 Da BaseloMiisnseed | 399P.0F19H9S.02Da oBaselcMiisnseed | 5S1_51031C4.7P0F0D0A2 Baselc iMinsseed | Wrong Peak Wrong Peak Wrong Peak NB PFBA and PFPA do nal have qualifying on ransiions. 31P3F0H/X1A128D0a BaseWlionnegc PMeiasksed Tigsido NA Ba WsroenlgoPMieiasnkseed 0 Before OJ After Pag6e4 of 169 ES) PASAnCaollyutmibciaalServices Printed: 18/02/2010 3:24:00 PM [Samp Name Tiooro17668 [ectionome[5 | 2/17/2010 8:38:51 PM. Sample Type [AcquisitionMethod| PFCKinetexLong dam WDieliugthitotnoFVactoors[[100000 || | Results Summary Analyte Peak re | we9 [0`Analyte RT | mo" res | SteCalc. Conc. | weief r I EE) soso |eo| ne [eros tices| mown |2czaon| smwowo | ssw | we | Prot | cero |smo [sorom | ree | ome " PpFUrNAo1 s1| 1n3cC-ePrFoUNsA| r8o8m65e5o | smeen| | 3.87 (4.06) | sm 43553 |I oon0.438 "No yet Lib . 2SolimbleS,ervices: Create wit Anahi Reporter Printed: 18/02/2010 3:24:00 PM `RCSummary [eer [rose [sermon [rae EEE [rosa [ro 5r1r0o9m7z08 [sam owen ean| Transm| ene | we|aowas[ve | [roam | wsmo| we[rset| we | | rwaos | woos | we |omese | ves | [owas | 0 | we [owoon [we] [amar | wwe | we |owes | ves | [mam[ew | ow |onew[wes | [oo maonw ||smaoo no||m wwoo||wmoamroms|y| vwoe | r rosimame en w om as |oe ween] ow | lprieaz [sme [| er |w [ enom | Pagoef1s70 [A  Solumbia Analytical Services" Created with Analyspt.R8e0porter Printed: 18/02/2010 3:24.00 PM `Quantitative Peak Review - K1001011-005 -- Tp =z T 413.P0F11O6A9.10 0a 411730C3-7P2F0OA0a 463P0E4N1A901 Da 461830C1-4P23F0NADa cBaseline Missed | oBaselinec Missed | cBaseinec Missed | Baseline: Missed | iA | ho | A 3 IL 499P.F0O6S010 Da 15033C.-0P8F00OSDa 5130P1F69O.A0 | 0a c Baseglinye Missed |3cBaselonnegMissed | Basmebmlinec Missed | 1 511530C4-7P0F0OADa cBasewlianescpMissed E Io | El t: 56P3,F0U15R1A9.10 Da 15635C0-/P2F7U00RADa 599.P0F/8D0S.01 Da 50133,0C/-8P0.F0OSDa GBaseine c Missed | oBaselnecMissed | Baseline cMssed | o Baseline Missed = : Fz= 5L0 i3 I J == sg i=a 613.P01F5O6O9A.0|Da 6151.03/C1-6P9F.D00ADa 663.P0F65T1A9.T0Da 61135C0-/PF1D6o9DAa0 oBasolineo Missed | Baseline cMissed | oBaselinec Missed | oBaselne o Missed i) a ` - 552 ll 713P.0F/T6e69A.01 0a 61135C0-/PF1D609DA0a Baseline o Missed | Baseline Missed 0 Before O After Page 68f 170 7 5AnGalluytmitciaal Services- PrCreeda:ted18w0i2h2A0n1a0y3pS:82R41e:p0o0rPtHer lon Ratio Confirmation K1001011-005 Lx= i 17 LA | m= eAAA == = = =[3"he]\ en Ba4s1eP3l0ir3nG6e9R.Z0Mi0sased | B1a6se3lo0irn2e1aM6zi0s0s8ed | B4as0e9vli0en8ec9?0M0i8ssed | c B5a1s3el= 0i2n6e9.0Mi0sased Wong Pea Wiong Peak Wong Peak Wrong Peak = = = I c Tonl gan) | wr | 2Tle|=let oB5a6se3Pi0Fn2Ue6R9MA0i2s0saed | Wiong Pea oBa5s9e9lP0iF1nD9eS9c2.0Mi0s8sed | Wiong Peak oB6a1s3ePl.Fi0Dn1eO6c9AM.2i0ssaed | Wong Peak oBa6s6e3lPi0n/Fe1cT69A20Mi0ssed Wrong Peak -| 552 B7as1eP3lFi0nT1ee6oA82M0.isa0sed Wrong Peak 0 Before 0 After Pa63gor1e70 7" Columbia QS Analytical Services PriCnrteeadt.ed18w/i0n21A20n1a0l4yp0s2R2e0p0ortPeMr PRDreaostjuaelcFttilTeable cGEw22ar1nTT'iIso0sPShraoojmrepcdetbss\sPnFCosr. wif [SInasmtprluemeantmNeame __TRAPiI 5o0000m077005----imectonvaame[5] `AeccquiiosintivonalMethod1|3P26/F1C8/K2i0n10et2e47x:S2h7doaArmMt [[DWiSelagumthpitloeinoFTayVcpoteolrume[7T 00 oo]| ARnaeansituslPtesakSum[ms ary m[mwaee F[aAEtNeERTR]T | naenTeasy | voat. esr PrvrrHpA 1 | coerrsa|| wsorwms [ewe| wmorw || e1mm | "ne | cron| swam [mas] wom | ww + iAF r PPe Page 8501 169 7 Lom CPriantde1wi8th0An3al4g2.R0e2p8o13rPt0etr RCSummary revert | ever [| [orreos [erameonamn|[awssn || wwoe|| roooonemy|| wvese] [ress em| vom | we|omow| vw | Pra 2 ar [sommes [orem | mem | no | sos| ve Tenen|mm =|sam|] [mom|wm|wo soon| ow | Pa8gof1e69 7 8 CRoloumbRia services `Quantitative Peak Review ~ TZ = ga PrCinrteead:ted18w/i0t2h/A2n0a1l0ys4p!:80R2e40po0rtPeMr K1001011-005 =[ =5 | Hz | J J zl G2B1as3e0lPi1Fn6eB9AT0M0isased | oB2as11e7l30iC1n-e7PcF2B0MAi0s8sed | Ba2s6e3lP0iFn2Pe1eA9c 01MDisased | Ba3se11l35iCn0-eP2cF7HMX00iAs0ased i Fe | = GBa2s9e9lPi.Rn0eB80S01MiDsased | Ba4s0e13l8i00n1-e0P3F.HM0Si0sased | Ba3s1e3lP0iF1nH2eX6Ac9M01iDsased | Ba3s1e15l30iC2n-2eP7.F0H0MGiA0sased :o = co = Ls 3 a po I-- CBa36s3eP.l0iF/nH1e6P9AM.i01sDsaed | Ba13s1e3l5Ci0-n2Pe7F0cHM0XiAassed | Bas3e9lP9iF.Hn0Xe8S0:01MDisased | oBa4s0e13l80i0/n-1eP0cF3H0MSi0sased -T gates log ig i: =| iE | 5 GB4aS0s_3e10l8/n01e-0cF3MF0iHDsSsaed | oB5a1s15e30lC4n-7eP0cF0MOAs0saed | cB5a1_s51e03i4Cn7-eoF0F0MDiDAsased | oBa5s11e5l30iC4n-7ePo0F0OMAiDsased 0 Before O After Page 67of 169 80 4 Solumbia Analytical Services" p85 PrCinrteead:ted18w/i0t2h/A2n0a1l0ys4t02R.e0po0rPteMr Ion Ratio Confirmation K1001011-005 = Tr oF = T io| iC- Teed | b|e 4b. zl Ei..| de 8 2130P/F1B6A9200a 263P0R2P1e9A020a 209.0P1F9E9.S02 Da BaseWloinneg PMeiasksed | oBaseWlrionnegcPMeiasksed | BaseWlrionnegcPMeiasksed | Tr T 313P.F0H/1Y12A9D.a0 BasWerlionnegc PMeiasksed ul -l 1 = - feet = Mitapioats 363P.0F/H31p9A.02Da 309P.0/F89S.0 2Da 5S1_51.30C4P7F0DD.Aa0 NA BasWelrionnegoPMeiasksed | BasWerlionneg PMeiasksed | BasWeloinneg PMeiasksed | BasWerlionneg0PMeiasksed NB PFBA and PFPA do nol Rave qualifying fon ransiions 0 Before OJ After Page 68 of 169 8 4 AGnaolytmicaal Services: PriCnrteead:ted18w0i2th12A0n1a0l3yv:.2R86e6:p0o0rFteIr DPraotjaecFtle EG2v1a7'1s0iPSoajmepcliessPtFoCnsg wif IRenssutlrtumTeanbtleName __ AGP2!1751000l00n cb [[SAacmqupilsetiNoanmbeate |2PK1Fi7GoH2oit0no1e1t07e-6x0L0-o66ng2d6aPmM [injectionVial [30 |[DSjaiemcoptlineonFTayVcpoterourme [[u5nkown 00 || | WeighttoVolume[000] Py me Results Summary Analyte Peak |a AE"Analyte |RT nen| an Cale Gon [eronTM worron | wram moan| meio | ze | to PFNA 1 | 13C-PENA 3363200 | 2.08 (2.08) 3948100 10.800 No | PFOS 1 PFOA1 | 13c-Pros 8676500 | 2.08 (2.09) 5517200 5.960 No CRRA | asso | 31208| ws | ots |Ne| PFOS 1 136PFOS 388387) prams | oorow|zn [swe [prea | 13cproon| 212730 | 554650) oe | v 0081 No ER Zs S18 Page700f 170 a AColumbia AnalyticalServices Printed: 1810212010 3:24:00 PM IRC Summary vers rman |e |wg [ross Foren awa| wo |we| owe soraw|we |wo| sam | we swam| wm | we | owow| ve " 4AnSaollyutmibciaalServicesTM PriCnrteeadt:ed18w1i0t2h1A2n0a1l0ys2tp4.R:6e80p0ortPeMr `Quantitative PeakReview ~ Kiootoi1-006 7 = ga 37 2g |i Fi i= ii: Ba4s1e3lP0i1Fn6eO9Ac.01Mi0sased | Ba4s11e37lC.i0-n3eP7Fc2O0MAi0sased | B4a6s3e.lP0iE4nNe18A.01Mi0sased | o B4a6s61e.3l0iC1n-4e2Pc3F.N0MAiDsased | i 13 1 1 Bas4e9l9Pi.Fn0eO80S(0M1iDsased | Bas15e03l3Ci.-n0eP1F0c0OMS0isased | B5a1s3s.Pi0Fn4De6Ac9 1MiDsased | c B5a1s1e53l0iC4n-e7P0F0OMAiassed i 5 L |- |iZE GB56a3P.sF05Ue1R9Al.cM1iisDnsaeed | Ba5s61e53l0Ci/n-2eP7F0UM0RiAs0saed | Bas5e9l9Pi.Fn0De8S01M0iDsased | =g Bas50e13l3,i0C1n-8Pe0.F0OMSiDsased i- Pr |Fo i| 1 Ld] Leese cB6a1s3Pe0F/i5Dn6Oe9Ac.M10sDsaed | oB16a1s35eC.l-0i/Pn1Fe6cD9M.oi0As0saed | cB6a6sP3Fe0Ti/Gn6Ae1c910MsDsaed | 1ol Ba6s1e15l30iC/n-1eP6F0D0M0iADsased = se Ba7s1e3l.Pi0F/nT6ee69A.10Mi0sased | Ba6s1e1l53iC0n-/eP1Fo6D9MOi.DAs0ased 0 Before O After Page 7201170 8 LSSColumbia services Created with Analyspi.8R9eporter Printed: 181022010 5:26:00PM fon Ratio Confirmation rw = odLLi A a= |E==E -- A| 4130P3F6OA9200a 463P01F2N1A920 Da BaseWlrinoeng MPiesaksed | BaseWloinneg PMeiasksed | K1001011-006 T 5 4 TI AT| EEW E3 E 499.P0F19O9S.02Da 513PF0D2A629D0a BaseWlrionneg PMeiasksed| oBWarsonegclPMieiasnkseed iS o ef| l | 2 leet 563P0F1U2R6A902 Da 509.P0F/9O9S.02 Da 613P0F1D6O8A02 0a 663P0F/T1A629D0a o BasWelrionneg PMeiasksed | BaWsroenglcPMieiasnkseed | cBaseWlrionengoMPiesaksed| oB<aWrsonecglPMieiasnkseed "ol Ls; 713P.F0T1e1A628.0a0 BasWerlionnegoPMeiasksed O Before OI After Page73.f 170 8 4 lamba AnalyticalServicesTM Created with Ansly5s.5Re0porter Printed: 18/022010 4.0200 PMA POrsotjaeFcitle EGv2a1n7s10PSraomRapilaePsrsChsoirt RIenssutrlutmTeanbtlNeame __AaP2I15701000shroarb [S[AacmqupilsietiNoanmDeat_e__| 2T1K1i1607021001101-20507663 All [SinajmepctlieonTVyopleumeTs [Acquiisitnion eMethcod[|t3PF0CikinoeexSnhorvidamial|| DWieluitgihontFiaocVtoourme [[1o0o0o Results Summary ee [Aanais Peak [s|a tomesm [RHRie eARY avtpenen Ga[leSGCoTne | PFBA1 13C-PFBA | 5352600 | 1.24 (1.27) 355640 | 0.57 || woanes- No [Prost |wo | oe em |as mnem | mmo | ow " Frat | rcerm| sma |sasesy| weno | am |we| prs1 | worms | ww | sae| wos Xa es 11810 Pa69gof1e69 a [a nalytical Services Created withSAenasReporter WReSwmmary Cmaperestane |ener| aa water| HeGu Reo ren| fpreve [pras2 x [prrvaz [prwsz [swceron |sso [roms eee soto | we |ow|eves s | [saan |woo|ow |ower | ves | [ower | smo|wo| ewaw| ve | | ome |weno|ow |owow| ve | |rasan|sso | wo|wosasm[ves | rage 01 160 o 8$ lRauimoin services" Ef L REN | Quantitative Peak Review 57i TH 3: 2 B2a1se3lP0iF1nBe6A901Mi0sased | cBa2s1e17l30iCn1-e7PF2B0MA0is8sed | PriCnrteead:ted18w1i0t2h1A20n1a0l4yp0sR2e20p0orPteMr oh | "= || i K1001011-006 =5 " Ba2s6e3lP0iF/nP2ee1Ac910Mi0sased | Ba3s1e15l30iC1n-2eP7F:0H0MXiA0sased " Hl= El | ol fl _ Ba2s0e9lp.irn0ee8s0c0|MiDsased | cB4a1s08e30l0i-1nP0e3Fc.HM0Si0sased | Ba3s1e3PlF0iHn2eX6A9c0M1s0saed | 31153C0-2P7F0H0XA0a c Baseline c Missed umn gea Wagga ong ea 5 ise = p- b= ll Eon Ll E- i. o Ba36s3eP,l0Ei/nH1eD69A. 01 Da Miss ed | oBa31s13e5Cl0i-1nP2eF7.H00XMiADsased | Bas3e0l9P.i0nH1e8S0.0M1Disased | Ba4s0e13l80i0/n-1eP0cF3H0MSiDsased wong } bog pes ning 7A I = |: L Vo Ba4sS0e_3l10i8/n01e-0MP3iF0Hs0Ssaed | oBa5s11e53l.Ci0n-4eP7cF0M0OiAsDsaed | cB5aS1s_5e1i03n4Ce7-o0PMF0iOs0Asaed | 0 Before O After o B5a1s1e53l0iC4n-e7P0oF0OMAiDsased Page 71 01 169 3 LSCS olumE bia services: Created with Analyps.t93Reporter Printed: 18/02/2010 4:02.00PM fon Ratio Confirmation == Tm K1001011-006 I I - | 5 oo et - IE! | = LR 213P0/F1B6A320 Da 263P0F2P19A02 Da 269.P0F/B9E9S.02 Da cBaseWlrionnegcPMeiasksed | oBasWerlonnegoPMeiasksed | BaseWlrionnegc PMeiasksed | Fa oT " 4 A = -i | i oreo |] w N- A I SN | 363P0F/H3p1A902 0a 399P.0H/99S.020a 5S1_51034C7P0F0D0Aa oBaseWloinnegcPMeiasksed | BasWelrionnegcPMeiasksed | BaseWlrionnegoPMeiasksed | NB PFBA and PFPeA do not have qualifying on transitions 31P30H/Y1A129D0a BaseWlrionneg.PMeiasksed Teint NA BaseWliionnegoPMeaiks.sed O Before OJ After Page 7201169 8 4 Golam Analytical Services" PrCinrteead:ted18w/i0t2h/A2n0a1l0y3sP2R4E.p0o0rtPeMr PDraotjaecFtile 0wa2r1'7s10P\rSojaemcpilsePFsCLsownigf iRenssutlrtumTeanbtleName __A0P2I1751000i0ong 1b [SampteName [BRiTo085T0_00_P7I_7007 S[ammepclteonTvyopneume [5 | `Acquisition Method| PFCiinetexLdoanmg [OitionFactor [100 | Weight toVolume[000 | Results Summary |[naaiiyieePeak ishame | sama | AnAameRRTY| [ananaes | Cacre oCone [proat 13CPFOA|4304300| 120(136)| 1059700 7630 To Mates? 7 No [rat T3CPRNA|2764|250002006)| 8141200 2100 | No | PFOS 1 | 13cpros | 8288000 | 203209)| 27116000 13C-PFDA | 2690600 | 303308) | 51755 0600 | No oes | No PFU 1 ["1acpruna| 1ese20 [sss| emeer | ost No PFOS 1 13C.PFOS | e280000 | 389087)| 4315 0025 No PFDOA 1 | 13cprooa| 235890 | 0.001455) 0 | wa No PETIA 13C-PFOOA| 235890 | 507(508)| 2381 NA No PFTeAT 13CPFDOA| 238690 | 533651| 2222 NA No ye ob 72! ae Page 74.f 170 20 4Columbia Analytical Services" IRC Summary Printed: 18/02/2010 3:24:00 PM aB Ee auwaon | mows | wo | omen spr maw| 0 | wn | awa | mw ros emer| ww | w | owom Saceros ama| mmo | we [oman| we | <scron suo| mows | wa| meas| wm rues swam|mm | ne | omow| .  Aontaalymtbiciaal Services Quantitative Peak Review =A =i PriCnrteead:ted18w1i0t2h1A2n0a1l0ys3tp2.R49e0p60ortPeMr K1001011-007 A A L B4a1s3e.lP0iF1n6Oe9A.01Mi0sased | Ba4s11e3l7Ci0-n3Pe7Fs2O0MAi0s8sed | o4B6a3s.e0Pi1nE4e1N9AM.i0s0saed | Ba4s6e1l83i.Cn0-e/P4cF2NM3AiD.sa0sed " :i a C B4as9e9Pl.iF0nOe8S00|M0isased | Bas51e033lC.i0-n1eP80F.O0MSDisased | Ba5s1e3.l0Pi/F4n6eD9.A0 1Mi0sased | Ba5s1e51.l03i/Cn47-e0P.0FOMAiDsased | Ba5s6e3lP0iF/nU5eN1_A90M1i0sased | Ba5s61e53l0Ci1-n2Pe7F.0U0MRiA0sased | oBa5s0e9lP.i0Fn/eD8S0c0M1iDsased | c B15a0s35eC.l0i-n/Pe80F:.O0MSiDsased vos lg -- Vom oun pea ixbree ioL 2 A | L -= " b i i RL Ba5s1e3lP.i0F/nD5eO6c9A.01MiDsased | c6B1a51s.3e0C/l-1nP6eF9cD.M00sA0saed | cBa6s6e3Pl0iE/n6To1Ac910MiDsased | Ba6se11l35iC0n-e/Pc1FD6MO9iDAs0ased 7 3i =i 53 [ B7a1s3eP.l0Fi/Tn6eE69Ac.0M1iDsased | Ba6s1e15l3.iC0n-e/P1Fc6DO9MiDA.s0ased 0 Before OJ After Pa76g0f1e70 % 5 AGnoalluymtibciaal Services: Created with Analyps.toR7eporter Printed: 1810272010 5:24:00 PM fon Ratio Confirmation K1001011-007 : -- mT] Lz) IT 7 > A. \ > 2x | d: oef fle --f| ondoe ] w |~ rr | 413P0F3O6A920 0a c Baseline Missed | 463P0E2N1A920 0a Baselinec Missed | c B4a9s9e.Pl0iE/nGe0S9c.20MDisased| c B5a1s3e,lP0iF1n2De8A9o.20Mi0sased Wrong Peak Wrong Peak Wrong Peak Wrong Peak 1 = : = I! | 2 - 563P0F1U2N6A902 Da oBaselne c Missed | 599.P0F99D.S0 20a Baseline Missed | 513P.0F/D16O9A.02 0a Baselinec Missed | 663.P0/E16T8.A20 0a Baseline Missed Wrong Peak Wrong Peak Wrong Peak Wrong Peak |. 71P3.F0T1e62A90.a o B<asWerlionnegPceMaisksed 0 Before OJ After Pa77gof1e70 0 5 ASnoalluymtibciaalServices" p98 PrCinrteeadt:ed18w/it0h2/An2a0l1y0st4R0e2p0o0rPteMr DPraotjaecFtile 0Ev2a1n7'1s0PraomjpelceisoSPhroCrst iff ReIsnsutlrtumTeanbtlNeame __A0P2I15701000horratb [Samp Name [Ri21o108r/0207170:03.0076:_37[AMmecion[vaStuamm e [[Up 5nknl owneType|| [niectinVial PFCiinetexshort dam [51 |[WDeiitgthotntFoaVcotlourme[1o0o0o | | i RT AT Results Summary. Analyte Peak AnalyteRT Calc. Conc PrBA1 nceren| asso [123020|ss | to e | -- Ne | 4002000 | 419420) | 1632700 1.16 No PHA 1 6424100 | 5264 (531) | 3364400 512 No [prea 1 13CPFHA| 6424100 | 651662)| 742110 No S1SCPFOA | 1aoPrDA| stowoo| 7esqes)|o|s 10o | mo | Pay 12d Z dl Pa73gof1e69 % Lan PCireea.ted18w0it5h5A0n1a0lpyt959R3e0p0orotehr RCSummary rogers|Wrenn)| ave |woanor| G9 (Ep ih| micas rons EEC [eresz cioaz | oem | Ne Prraz saison | rns [zea|sow | vo |own| we S150 Pr 524530) No TM Page 7401 169 os LS SColoumibinaservices PriGnrteeadt:ed18w/it0h2A1n2a0l1ys0tp4.R01e20p00o0rtPeMr `Quantitative Peak Review = Eg = ra > 2 K1001011-007 =7 <3 x Ld [i i [i 2 1d p=A) (-- ] CBa2s1e3lP.iF0n1Be6A-91.MiDsased | Ba2s1e17l3.iC0n-e1P7oF2BM0As0saed | oB2a6se3Pl0Fi1Pn2ee1cA90M1iDsased | cBa3s11e53l0iCn-2eP7F0cH0MXiA0sased | | : | A =- i: i CBa2sP0e9lF.iBn0e6S0c10MiDsased | cB4a10s83e00l/-n1Pe0Fc3H0MSiDsased | Ba3s1el3PiR0Hn2Xe6A:90M1i0sased | oc 311530C-2P7F0H0XADa Baselineo Missed toss pea i sn pea ages - il = zl web I eA Ae -- Ba3s6e3lP0iF1nH1ep6AM90i1sDsaed | Ba31s13e5Cl0i-n2Pe7F.0H0XMiADsased | Bas3e09lP.iF0n/H8eX0:S.0M1Disased | Ba4s0e13l80i0/n-1eP0oF3H0MSiDsased --Vusopea wong wang pea logged ii~| |ipJ i: =3 i: | : " = 2 cBa4Ss0e_3l.1i08n10o0-3oP.F0MHiDSsased | oB5as11e53l0Ci4-n7oP0oF0OMAiDsased | Ba5sSe1_l51i03n4Ce7.0MP0iFDsDAsaed | Ba5se11l53i0Cn4-e7Pc0F0DMAiDsased O Before OI After Page 75of 169 9 A Columbia Analytical Services Created with Analyps.t1R0e1porter Printed: 18/02/2010 4:02:00 PM E io ef = --% lon Ratio Confirmation 7 7 K1001011-007 de zl A hed B2a1s3ePl0ri1no6eA9c20M0isased | c 2Ba6Ps3erl0iP2noe1R90M2i0sased | B2as9elp0irn8ee0sc0?M0issed | c B5a1s3ePl.i0Rn1e1H82A.M0i0sased Wrong Peak Wrong Peak Wrong Peak Wrong Pesk TEE > T 3 -i = Pept o3B6a3s.eP0lFn3He1p9A.M2iDsased | o B3as0eP9lF.i0Hne9Y9S.M02i0s8sed | Ba$sSe1_l51i.n30eC4Po7F0MDi0.Asa0sed | NA Baseline Missed NB Wrong Peak FFB and PFPA do nol ave WquraolinfgyinPgeaokn rarsiions Wrong Peak Wrong Peak [Before O After Page 76 of 169 a7 / ASnoalluymtibciaal Services: CPrrienatetde: 1w8i0t2h2A0na1l0yps3t2.R41e0p00o2rPteMr PDraotjaeFcitle 0Tr2a1n7s10P\roSjaecmtpslPeRsCLSawnigf IRenssutlrtumTeanbtleName__ A02P1I751000i0ong ao ctionvolume [SempleName _ Kio0[ i01i0m 06 e [5 | `AcquisitionMethod | P2/F1C7/K2i0n10et50e1x.t3d2oanPmgM [SamDpleiTytpe wt[1i00onFactor| Weightto Vorume 000 | Results Summary iEAnalyte Peak sw me Saes | AAnaHiStReTRT | n|appe area | CaCeorCeorne |poWoadimteed?ar| {TePernas [pros | PFDA | PFUnA 1 PFOS 1 wan | rea| 13PFOS| 8176800 | 200208)| 13C-PFDA 3090100 | 3.03 (3.06) | | 13c-PFURA 138370 0.00(4.06) 13cPros| sireso0 | 3se@en)| mo | om 121880 0154 42135 0.124 0 NIA ssa 0113 X [0 d No No. No | No PFTAT [prrens T5cPrOoA|25|0 50350 08)| teat 0049 13GPFDo| 214500 | sesh| ost | oost No wo | ay Lie Pa78gof1e70 % 4 SolubleS,ervices" Printed: 18/02/2010 3:24:00 PM RCSWOMary Correa [rin[e[a SE n ig os Twam | wa[wo| oo w | [ore mam | ww | we owow| ow] [rans omam | em | we omer || [[oermeesr [oemmues ||m| m|wweoomwaens||ee || rma ewes|aw|women|e| . 4 Solumbia Analytical Services Created with AnalysPR1E0Ebrer Printed: 18/0212010 3:24.00 PM Quantitative PeakReview Tm E TE ~ Kioo1011-008 = 3 i! A a: Sm - aoe _ 413.P0/F1O6A9.10 Da C Baseline Missed | 411730C3-7P2FO0A0a Baseline Missed | 4630P/E4N1A901 0a 46183.C0-1P4F2N3A0.a0 Baseline. Missed| oBaseline . Missed ) -- pe - ne 499P.0F/O80S.01 Da Baseline . 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PFBA 1 13cPFBA| ST08700| 1260127)| 834270 133 No | PPA 1 TICPRHA | 7020500|354060)| 446160 08s No [pres teoprHs| se12s00 | 40420)| sis | 006| No PrHA 1 [scorn| 7020500 | sean| sao | ote | no | PFHpA 1 13C-PFHXA| 7020500 | 6.17 (6.23) 1 30008 0.06 No PFHIS 1 [Tisoprs | serzso0 |s2s@3n| srrae 00 No S_IBO-PFHS | 13C-PFDA| 3091000| 625631)| 3812500 1.18 No SI1ICPFOA | 13GPFDA| 3991000 | 7.57765)| 3991000 1.00 No LS EeJie 2" Pa77gof1e69 102 [lumpia AnalyticalServices RCSummary Printed: 18/02/2010 4:02.00 PM [rows 0 fons Teron Ce|mvme| m wo| amaw|m ve | emi [rom|ow | msm| . 103 LS SColoumbiia services QuantitativePeak Review iI T ra PrCinrteead:ted18w/i0t2h1A2n0a1l0ys4tp..0R12e00p80ortPeMr K1001011-008 3I .I i | = |~ _21Ba3s.e0lPi1Fn6Be8A.01Mi0sased | Ba21s1e37lC0i-1n1Pe7F2EM0Ai0s8sed | Ba2s6e3PlF0iP2nee1.A90M1i0s2sed | Ba3se11l35iCn-0eP2F.7HMX0iAs0ased C B2as0e9PliF0nB8eS0c01M0i2ssed | Ba4s10e83l00i-/n1Pe0F-3H0MSi0sased | Ba3s1e3Pl0Ri2Hn6Ie.A90M|i0sased | c B3a1s15e3l0Ci1-n2eP7Fo0H0MRiADsased a1 tian pa - Bi bia pe Ba3s6e3lP.0iE/nH1ep6.9A.0M1iDsased | Ba3s1e153l0Ci1-n2Pe7F.0H0XMAsDsaed | oBa3s0e9Pl.F0i1Hn8Xe0cS.0M1Disased | bong pe wap Se 4013800/-1P0F3H0SDa Balargseline c Miesa sed 4 pu = i! | SEl pr1Be] H er E meme] zblree |Rn] zlbi 1mire 4S0_31.08100-3P.FHS0.a GBaseline c Missed | cB5as11e53i0Cn4-e7PoF0MO0iA0s2sed | 5S1_51.30C4-7P0F0D0Aa Baselinec Missed | Ba5se11l53i0Cn4-e7Pc0F0DMAiDsased 0 Before O After Page 79.01 169 108 4 Anoaulymtbiciaal Services Created with Analyps.t1R0e8porter Printed: 18/02/2010 4:02.00 PM Ton Ratio Confirmation T ; Ea ;5 `oz | +| K1001011-008 7) " fre | il 2130P1F6B9A20 Da Baseline Missed | Ba2s6e3Pl0iFn2Pe1eA920Mi0sased | Ba2s6e9l.Pi0Fn1Be99S.02MiDsased | Wrong Peak Wrong Peak _Wrong Peak J] a u "{ LAA - 2 2 =2 363P0F3H1pA9020a 39.P0E1H8X9S.02Da 5S1_51.30C/.4P7F0DD.Aa0 BasWerlionneg PMeiasksed | BasWeiloinneg PMeiasksed | o BasWerlionnegcPMeiasksed | NB. 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