Document pORQGej7Dmpo99j3KoYL8VGj
APPENDIX C PHYSICAL CONSTANTS
RSV 0015373
PHYSICAL CONSTANTS
Vinyl Chloride General VCM Vapor Pressure' Cthylene General Acrylamide General SLS General THF General THF Vapor Pressure THF - Water Boiling Pt. THF - Solids Solubility THF - Viscosity versusPolymer Content THF Distillation Cutoff Percent THF -R.l. Wt. % THF - R.l. SFS General APS General APS - Solubility in Hj.O % SFS - Sp. Gravity % APS - Sp. Gravity MEHQ General Caustic Concentration - SpecificGravity Ammonia Concentration - Specific Gravity Glycerine - HjO Mixtures vs.SpecificGravity
C- 1 C-2 C-3 C-4 C-5 C-6 C-8 C-9 C-10 C-ll C-12 C-13 C-14 C-15 C-16 C-17 C-18 C-19 C-20 C-21 C-22 C-T24
RSV 0015374
F3HY55CAL CONSTANTS DATA
C-l
tout-VA,*La
----- "J
bYMJCYu'iiAiT ia.wuCV*""" ~ ------.-.uj--a
Vinyl Chloride
Chi oros tlifCfceh c.
b. ikl.U U Y
M. E. Gibbs
Furl#
A^i-T`n________________________________
PrtlnJ ft 7f1 n
C*flli Point ft IOCS (Wltf Pohrt r* 5CSi
Brflfcrt Peirt * 10m Crvfttlirta PoM
Row
?VrH Point
,
Sr.clfic GrS'tv n - ' 0 0
Srscfflc Gttvitv o
Pcunte tn Gel. o
**C
CcGfiiricnt cf Entn^ea Rcirc:livo lrJc -lOBC #2
Infra Ret* Socstnca filefcMM)
Ultra Violet SDestwwfKefarne*; Vlsenfltv/ -20 C
Vfeeorltv* -10C
Snrfttft Tnflos -10 C EiliNIItvtonrtrr
milftvln
Soltfjlllty In
r'3/17/65
Oattaci 62.301 -13.37UC
-rrrsirc -t)7.Bue -153.V9U<5
GT9S3
CHa = CHC1
runner, ft datf
Physical ProDerties
Dreisoach. R. R.
:
`
X7TO76
0.2780 es 0.2565 es 20.88 dvnes/cm
tb ----------------- n------------------------
-
Fa:h Point r Wj F!ro Pdrt bC
HcrtctCcrtrafiton Hatf of FMaettai Lla . at 25 "C
Itena_r.i_5tcMHtyiPfl^Vdn.)_________________ Lrtmt Her! cf Fwtoa LrtrmHurtnfVn. at B.P. SDreif.fi Kart Liq. at 295~K fit
Citttal.Pmsnt Dlefteclatlen Constant
.AJUi^rSttO r\ T*mpr*^Vfe.
-78.OfaC
:
-144.0 kcal/mole
18.14 eal/R 79.55
0.58 cal/R 150.5 c 42UU0. min
H72*c_
S J3 8 u
o
[OZItltV iCiv4 Rtteftut)
HOTBi Tke*m Josm *kaM
RSV 0015375
. . . III.). . .1 . ,.
14 n j!>> p m n o N * ,
C-2
PHYSICAL
Cnu'ulivSif&S1 Ethylene
*fy --
M. E. Gibbs
Femla I'olenlnr Vfcliht
NAKl
PaIIIr* Polrt rt 7^ m BolllCIfelrt rllOGS
BaIIIm Pnir>.rt 30-i P^ilir-i Pair* rt l^a
Crvntaili7}R? Prlr* f'-ntm rniat
FMrtim Pairt Snscific (tovitvo
Specific Gravity e Pounds per Gsl. o
-10"C
0"C <*C
Coefficient of Ezopriori
Refrcdiva Irdnxc
n2
Infra Red Sccctri^i (llofsnne*)
Ultra Violet Soxtrun (itofevncs)
VJrwsilve -125"C
Viscosity* -lOS^C
Svrfrce TorsIm
SoltiilitY ir.YWcr Soli^ititv in
fokiilitv In
3N&TANT8 DATA
L`t xL'SYUilAL i'Oii^ULA
C-3 TEBWfSCr. ?*. .STi
DAVJ
3/17/65
Oa*U -------2STU5S
-103.71"C =X5TT7H"C -144.00*0 -153.22-c -169.15C
tHi CHa
rounen a oath rnysics.1 properties
uroisuacn, k. k.
11
11
0.384 0.345
.
0.23 cs 0.1b cs
Flash Point F MxM)
Fir# Point C
Heat of Cpfffeurtten at
H#a pi Formdlcn
Itenrat Stailltv (ed.AVrala.l Lflent He?A of Fusion______________
LMhcaiiVn, at B,P.
SMtific Hta
Vap. Mo
Critical TcftnnKtura
CiitUsLEiaim Dig^chiinn Qv-f
Critical Density
310.20 kcal/mole"
l^-39cal/g
0.3725 cal/RTT
$.Or
-----------
55550. mm*
0.21 g/ml
Tg?icily/Qi
RSV 0015377
150 i *
TJwvl p.rvj,
k^E a VSsCA?-
i dc
<w;O^GA\!YG DATA
~ti..\jctu7i'al ror;wutA~`'
ca, > cr.c^
C-4
"*
"*tl
Ttri
ui
M. E. Gibba
| UAYU 1 2/16/70
.
MAUE F rr "!i l: xesrier AM^rmrii ftnlHn? Point ft 7C0 rn Boilin'! Pair? ft ? n
Br Min* Point ft 5 0 n Br Hiii?PehtTt25 mm Cr.^*L?I!izlr:' Point
IVItir'T Print
SoluMn Point
a$p ccific Gravity
So ccific Gravity e
Pounds per G=l.
in*r C
Coefficient cf Examsion
Refractive Index e
nS
Infra Rod Spcstnsr (Refo*ne)
Ultra Violet Sl>-Ctrum {Reference)
Viscositv #
Viscosity e Su rfp'i* Tension So ubilrtv in tf&rr SflllAllitV in A^fnns Solubility in Bn*inp
" " Ethnnnl
Flash Point F fHcikrd) Firo Point 6C
dTiflttKRmi----------------------------------------
rounctr a path_____________________ Anoxicnn Cvnnntd Co..
71 .Oft
BcCubllshcd dr.tn i__________________ !I_________________________________
nfn
11fi . s *r
i 7 s *r
84.5 0.3 * C
ii ti M
II _
1.122 R/flfl
If
7n/i 44 . S
0.0? A . fl 74.0 17 .S 1T0
i
If M 11 II M M 11
Heat of Coffbustlen Kest of Formation
Ttermal Strtilitv fczl.Ap/min.'i Lfient Kart of Fusion Latent Meet of Vw.
Specific Heft Critical Temperature Critical PrrwiWB_____ ;_____`____________ ,____________________
Qis ^pcInttrrConrfnt
Vn "
"
" . J.2b te
4fl*C SOT.
,f
I! w
O th e r Constants 1
Toxicity (Give Reference)
*
RSV 0015378
PHYSICAL' CONSTANTS DATA
U-rn-marx
'.
Sodiua Lauryl Sulfctc (Sinex 1lB>
cn.ucTunAi. re;:t:ui.*
C-5
crarrmrcT" M. E. Gibbs
NAME
ibleeriar Height k Pj> Mine Point et 70 ir.m _ BoiliWPoirt at mm
3/S/70
Thin T.lniHrf
C j aHj 50S0 3Na
SOURCE a PATE A-l i-nt-af g 1 Cft .
V
Qoiiir,? Point et m
rivKt.illmnp Point
Poirl
Solution Point Soecific Gravity0 *> * r t k ,, /
Soecific Gravity 0 Pounds per Gal. 0
C
Coefficient of Expansion
Retractive Index 0
n3
Infra Red Spectrum (Reference)
Ultra Violet Spectrum (Referenee)
Viscosity0 25*C. cos
Viscosity 0
Siirfw.p Tension
Solubility in Y/der
Solubility in
Solubility in
-1
B .4
50___________________
II It
*
Flash Point F fMethod) Fire Point C Heat of Contmstion Heat of Formation
Thermal Stability (eal.Ac/min.Y Latent Heat of Fusion Latent Heat of Van. Specific Heat Critical Temoerature Critical Pressure
Dissociation Constmt
CflHnn
EkMnMoei
.Alkyl Free i_T.otal ..Iron,
Sulfate. X Fnttv Alcohol. *
Inorcanie Salta eon
Oj-'or
10S Solution)
jaoud Point. *C
Tt
Lcioriflcation Reference)
Point.
*C
Sodium 29 1.0 1.0 1 1 Pale l tiild 3.0
12 15
OflTfif
1. . , ! r II
-
.-
(1 II It II II II II II RSV 0015379
TETRAHYDROFURAN(THF)
Formula:
GENERAL
Molecular Weight Boiling Point (at 760
mm Hg)C F
Freezing point C F
Density-Liquid (20C), g/cc lb/gal
Vapor (air * 1) Refractive Index, N
H2C -- CH2
i h2c
I
ch2
\/
o
72.107
66
151 -108.5 -163
0.888
7.4 2.49 1.4073
THERMODYNAMIC Specific heat, PCU/lb/C Liquid 20C 50C Vapor (Cp) 66C
Latent heat of vaporiza tion, PCU/lb, 66C
Critical temperature, C Critical pressure, atm Heat of combustion,
kg-cal/mole Heat of formation,
kg-cal/mole
0.469* 0.496* 0. 37*
98. 1*
268 51.2
597*
52.7*
FLUID
Viscosity, millipoises, 20C
Surface tension, dynes, cm at 25C
Coefficient of cubical expansion, 20C
5. 3 26.4
0.00129
ELECTRICAL Conductivity (25C), mhos/cm Dielectric constant, 20C 30C Dipole moment (25-50C), Debye units
1.5 x 10"8 7.58 7.25
1.7
(continued)
C-6
RSV 0015380
Tetrahydrofuran fTHF) (cont'd)
OTHER PROPERTIES
Flash Point (Tag closed or
open cup), C
F
Flammability limits, % by
volume in air, 25C
--1
lower
upper
Ignition temperature, C
F
Solubility parameter
Hydrogen-bonding index
Miscibility: water, esters,
ketones, alcohols, di
ethyl ether; aliphatic,
aromatic, and chlori
nated hydrocarbons Evaporation rate.
(n-butyl acetate =1.0) Octane number.
(research method)
Calculated values
- 14.5 +6
2 11.8 321 610
9. 1* 5.5
infinite 8.0
72. 9
C-7
Reference: DuPont Company, "Properties and Uses of DuPont Tetrahydrofuran
RSV 0015381
3000 3000
C-8
o
V A tO ft PRESSURE, mm . t M*><rV
FIGURE 1 VAPOR PRESSURE OF THF
o
TEMPERATURE
* to* * too* 140* i* I/O* i4* an*
FIGURE 2 DENSITY OF THF
RSV 0015382
RSV 0015383
*1Kf>
K
to
IO
TO Y t INCH IN C N tf
ii
*J
*KN
C-9
10
9
8
7
6
.5
A
I I
3
i
2
1
.
C-ll
'i
*S E M I'L O G A R IT H M 1C
4 6 SO IO
CTCLCS 1C 140 6 IV III0 N C M M l . I. >.
KIUPHL 0 4MM CO.
00 90 80 70
0 SO
40 30
20 10
O
C-13 I
t=f
!fe:|uKgpfS?i:jn m g=pi
f^itd
Tt i *.
C-14
iJriJ -I-
** . ^ * t;r :n4
WSF-5]*5f:ffStS *b1'
in
^:Efeefcrr%' TtfFJ^lAfcTER " M^XTWRESl^EfiSUS..,:;. ^^;
1394
1.3 9 6
139 B
).400
REFRACTIVE INDEX
1402
1.404
1
SODIUM FORMALDEHYDE SULFOXYLATE fSFS)
Structural Formula: MW:
Melting Point: Water Solubility:
NaHSO*. CH*0. 2HzO 154.12
64C 86 oz/gal at 86F
C-15
RSV 0015389
AMMONIUM PERSULFATE (APS)
Formula: MW:
Kef. Index: Sp. Gr. (crystal density): Decomposition Temp.:
Loosebulk Density:
<NH4>2 3,08 228. 2
1.5016 1.98 (g/cc) 175C 1.05 g/cc
Rohm and Haas FMC Corporation
Reference: Perry's Chemical Engineer's Handbook (eth ed) Handbook of Chemistry and Physics (48th ed)
C- 16
RSV 0015390
C- 17
T * * 'A $11
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5
>
9
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ai
si
s* ** t
Is
i?
5 i
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(
:t i!
* s
s
k
f?
a
t
I
C-18
RSV 0015392
I fH P . > M - * 0 IM V IU O N I PCM IN C H M t M W A T S . Ik O
C-19
2 4- C & /O /Z /V /4 to Za Z2 <
RSV 0015393
MONO METHYL ETHER HYDROQUINONE (MEHQ)
Structure:
o:
o
OCH3
Molecular Weight:
Appearance
:
Melting Point
:
Boiling Point
:
Flashpoint {Cleveland
Open Cup)
Fire Point (Cleveland Open Cup)
Solubility in H20 at 25C, g/100 g solvent:
124.13 White crystals 54-56C 246C 132C
135C
4
Reference:
Eastman Chemical Products, Inc.
C-20
RSV 0015394
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C-Z1
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Co/?c7? A *a h 'o *i 0 6 )
/j. IA P-/) i?/y * D^g'
RSV 0015395
C-22
*
RSV 0015397
C-24
. m j, a u
i nbiwiuinu a o iiii i m u
RSV 0015399