Document pBng0j0VR46Q6n4J07eMyQogD
10/29/69
EXECUTIVE SUMMARY PCB POLLUTION
PROBLEM:
Contamination of the environment with polychlorinated biphenyls (PCB) (Aroclor products).
PROBLEM DEFINITION AND TIMING:
Professors Widmark and Jensen of the Institute of Analytical Chemistry at Stockholm, Sweden, in November 1966, announced and confirmed finding PCB in fish, birds, and eggs. Subsequent findings were made in 1967 in Great Britain. Problem was first presented in the U.S. by Professor Risebrough of the University of iCallfomia in a published article in the San Francisco Cronicle in February, 1969. Monsanto confirmed the presence of PCB's in mid-1969 and confirmed the adequacy of work by Widmark and Jensen and others -- a worldwide ecological problem.
CONFIRMATION OF FINDINGS:
Analysis indicates environmental presence of 5 and higher chlorinated biphenyls (similar to Aroclors 1234 and 1260). Other Aroclors may contribute, but havje not been identified yet. In the last six months, PCB's have been reported present in waters in Lake Michigan, fish in Connecticut, seafood along the Gulf Coast, and waters outside Monsanto plants.
SERIOUSNESS OF PROBLEM:
1. Fish - Marine or aquatic species concentrate PCB in the fatty tissue. Toxic in small quantities (down to 5 ppb) to sensitive marine life such as shrimp.
2. i Birds - Predatory species feeding on the marine
or aquatic life can further concentrate PCB to
possible harmful effects. Specifically in birds,
PCB can effect the calcium metabolism leading to
egg shell imperfections which prevents proper
hatch of the young.
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3. Man - There is no harmful effect known to man or other mammals after 40-years of production. Studies are underway by various sources.
4. Political and Public Emotion - PCB's linked to j DDT because CB's show up in analyses for DDT. Linked with other permanent chlorinated hydro carbon pesticides.
EFFECT ON MONSANTO:
1. Business potential at stake on a worldwide basis:
Fluids
Plasticizers
Total/Year
70 M Lbs. $16 M_ $6-8 M GP
34 M Lbs. 6 M _ $2-3 M GP
.2 Legal responsibility.
104 M Lbs. 22 M _ -11 M Gross Profit
3. Public image.
4. Effect on other product areas.
EFFECT ON CUSTOMERS AND ULTIMATE CONSUMERS:
1. Affects entire electrical industry - capacitors ; and transformers.
2. Affects food processing.
3. i Affects die casters and other "hot metal" working industries.
4. : Affects wide range of plastics and adhesive applications.
5. Affects wide range of paints and coatings.
EFFECT ON OTHER PRODUCERS:
There are at least six other producers of PCB's ex-jUSA. Monsanto has discussed problem with two in Europe. No great concern there yet.
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MAIN SOURCES OF POLLUTION:
Difficult to define, but Aroclor 1254 and 1260 are used in electrical devices, heat transfer, plastics, adhesives, coatings, and industrial fluids. Other Aroclors contain minor percentages of 5 and 6 chlorine ring structures. Manufacturing plants also a vulnerable contributing factor, but less significant in quantity than customer or end user loses.
POSSIBLE CONTROL OP CONTAMINATION:
- Electrical and heat transfer - possible to control with effort arid reclamation.
- ! Industrial fluids, plastics, coatings and adhesives 1 - very difficult, if not impossible to control. : Substitute products needed.
MONSANTO OUTSIDE STATEMENTS: - | Letter sent to electrical customers regarding
; problem.
- 1 Monsanto Public Relations statement attached.
MONSANTO FUTURE ACTION: I
Presentation to CDC reviewing subject and future plan
of action by November YJ, 1969* This will define a program to determine what Is necessary in various product areas to meet the problem.
1. Research and Engineering needed and cost.
2. I Plant and customer "clean-up and control" i required and cost.
3. Biodegradability of Aroclors.
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-44. Toxicity studies. 5. i Alternative routes. 6. ' Recommended approach. 7. Appropriation request to cover capital and
expenses, required.
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STATEMENT FROM: MONSANTO COMPANY ST. LOUIS, MO.
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Oct.2?, 1969
Late in February, 1969, a West Coast newspaper
carried a major feature about "a menacing new pollutant"
found in .the San Francisco Bay area. The article was based
on marine life research carried out by Dr. Robert Risebrough
of the University of California. The article stated that
| residues iof pesticides (DDT and DDE) and polychlorinated
biphenyl j(PCB) were threatening the welfare of certain birds
and posed a long-term threat to humans.
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! Monsanto manufactures polychlorinated biphenyl and
markets it under our Aroclor trade name. (There are other i'
manufacturers in Europe and Japan.) We, therefore, would
like to present some additional facts.
' The work done by Dr. Risebrough dates back to
earlier research by other scientists who, while analyzing
pesticide residues in wildlife, soil and water, encountered
unknown or "interfering" substances in the parts-per-million
range. ,
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Several years ago, two Swedish scientists at i ''
Stockholm University's Institution of Analytical Chemistry,
Professor Gunnar Widmark and Soren Jensen, reported they
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had identified these other substances. They said some
of the materials were polychlorinated biphenyl or PCB.
Since PlCBs are not "broadcast" or spread around the land
as are pesticides, the scientists theorized that the source i
must bei the industrial wastes of PCB users.
In addition to the work of Dr. Risebrough and
the Swedish scientists, there have been other studies which
indicate the presence of PCBs in the environment. Monsanto
is concerned over the situation and is cooperating fully
with these studies.
The common uses of commercial PCB would not
normally lead to its release into the natural environment.
A principal market for PCB is in electrical j
applications where they are used as insulating fluids for
transformers and capacitors. In this use, the chemical is
completely sealed in metal containers. Another market is
for heat-transfer applications, where the PCB fluid functions
in a closed system.
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PCBs are also used in several applications where ) the chemical is incorporated into a polymer as an integral
part of the solid material. Such polymers are used in highly
specialized applications as an adhesive, elastomer or surface |
coating.
Polychlorinated biphenyls are not sprayed or dusted
on crops, woodlands or any other areas, as are pesticides. To.
our knowledge, they are not used in tires, house paints,
household products, epoxy resins or major vinyl plastics, as
has been charged.
Therefore * conclusions as to the source of PCB found l. in the environment are difficult to make. Some qualified
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scientists, using the latest laboratory equipment, have correctly
identified the substances as being PCB. However, most scientists
are not yet willing to indict commercially produced PCB as a
pollutant.
It has also been implied that polychlorinated biphenyls
are "highly toxic" chemicals. This is not true. Just like other
industrial chemicals and home products now in widespread use, PCBS
are not hazardous when properly handled and used. During more
than 30 ye;ars of U.S. production and use, cases of any toxic effect
have been extremely rare -- and then only where the simple
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precautions recommended for use were not followed
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--4 MONSANTO COMPANY
Monsanto has research programs under way to identify
the compounds, reported to be PCB, and locate their source. The
programs involve precise analysis of environmental samples of jI -
water and soil. Also under way are studies to determine the
biological effects of deliberate dosage of PCBs on fish, birds
and mammalian animals. Special emphasis is being paid to
endocrinological effects, mineral metabolism and reproduction
I physiology.
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Some preliminary biodegradibility studies are under
way. Further studies to clearly demonstrate this phenomenon
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are contemplated. ]
Very early results of chronic toxicity studies confirm
i* that PCBs are not highly toxic. In 90-day studies on rats and
other normal laboratory species, there have been no adverse i
effects when feedings of up to 100 parts-per-million were
administered. I Monsanto has always cooperated on a regular basis
with federal, state and university laboratories in their analysis
of chlorinated hydrocarbon residues. We will continue to do so.
Additionally, Monsanto will continue to exercise the highest i 1.
degree of dontrol in its manufacturing, shipping and storing
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of PCB -- as we do with all products. In the functional fluids
market, we have carried out a program for several years for the
reclamation of used PCBs to reuse these valuable materials.
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The source of the marine life residue identified as PCB is not yet known. It will take extensive research on a worldwide basis, to confirm or deny these initial scientific conclusions.
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