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FILE NAME Packings and Gaskets PAG DATE 1984 DOC PAG060 DOCUMENT DESCRIPTION Material Safety Data Sheet for Asbestos Sheet Rubber WV me ee PPOP SM AE EmCE 0166 0166 15 U.S. DEPARTMENT OF LABOR RECEIVED Occupational Safety and Health Administration RECEIVEDRECEIVEDRECEIVERDECEIVED MATERIAL SAFETY DATA SHEET CENTRAL1986 MSDMSSDS CENTRAL Required under USOL Safety and Health Regulations for Ship Repairing Shipbuilding and Shipbreaking 29 CFR 1915 1916 1917 CENTRAL FILESFILES SECTION I MANUFACTURER'S NAME Richard Klinger Inc. : . . EMERGENCY TELEPHONE NO . 513 498-1181 Ohio ACTRESSVUmber Street City Stete and ZIP Codej 2350 Campbell Road Sidnev 45365 CHEMICAL NAME AND SYNONYMS Packing TRADE NAME Compressed Rubber Bonded Asbestos Sheet CHEMICAL FAMILY Mix of SBt R Ruu bber r and e Asbestos Packing FORMULA | Klinger . A AND SYNONYMS 61 SYNONYMS White SECTION II HAZARDOUS INGREDIENTS PAINTS PRESERVATIVES & SOLVENTS | % [Units ) ALLOYS AND METALLIC COATINGS PIGMENTTSitanium Dioxide CATALYST 5-142 1048 | BASE METAL A ALLOYS | Units A A VEHICLE SOLVENTS ADDITIVES f OTHERS A | METALLIC COATINGS A _| COATING OR CORE FLUX A OTHERS N A A A HAZARDOUS MIXTURES OF OTHER LIQUIDS SOLIDS OR GASES % Units Chrysotile Asbestos CAS 1332-21-4 70-190 # Butadiene Rubber CAS 9003 55-8 Titanium Dioxide CAS 13463-67-7 Two fibers greater than 5 um in length No TLV established 8-115 8-15 # 4-14 M BOILING POINT F VAPOR PRESSURE mm H".1 VAPOR DENSITY AIR SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION III - PHYSICAL DATA Decomposeb Decomposeb SPECIFIC GRAVITY H * O A PERCENT VOLATILE A EVAPORATION RATE Insoluble Solid Solid off white 1 .65 11.65-1.85 . |A .| N | SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT Methoo uscal EXTINGUISHING MEDIA A FLAMABLE A 4 FLAMMABLE LIMITS Let : Uki Water Carbon Dioxide Dry SPECIAL FIRE FIGHTING PROCEDURES Firefighters Firefighters Powder contained or Foam contained breathing equipment and eve protection fumes The UNUSUAL FIRE ANO EXPLOSION HAZARDS need ; cooling prevent rejenition rejenition PAGE 1 Continued on reverse side Form OSHA Rer May 72 -2- woe 7 yu?34 SECTION V - HEALTH HAZARD DATA THRESHOGO Average Weighted LIMIT VALUE TLV - Asbestos- Asbestos- 8 hour TWA Time fibers greater tha,5 um in length of 2 EFFECTS OF OVEREXPOSURE - The material in its finished form presents no known health . hazard A chronic health hazard may be created if further processing of the sheet allows asbestos fibers to be released into the atmosphere Inhalation of free asbestos including fiber over a long period of time can cause lung disorders pleural plaque lung cancer and mesothelioma asbestosis . SECTION VI REACTIVITY DATA STABILITY : The material has infinite storage stability INCOMPATABILITY - Strong oxidizers strong acids or bases HAZARDOUS DECOMPOSITION See Section V PRODUCTS - Burning rubber See Section IV and free asbestos HAZARDOUS POLMERIZATION will not accur SECTION VII - SFILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Dust from sheet should be treated as free asbestos Secure area and clean up using filtered vacuum or wet sucep DO NOT clean up in a method that generates dust into atmosphere WASTE DISPOSAL METHOD - Bury in solid landfill as required by 29 CFR 1910.1001 N SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION - None required where local controls ensure negligible asbestos dust released into atmosphere Where local controls not adequate use respirator approved pursuant to 29 CFR 1910.1001 D See section IX - Special Precautions VENTILATION and good work atmosphere Where dust producing hygiene must be used processes to ensure are used local ventilation air filtration negligible asbestos dust released to EYE PROTECTION - None required for normal use OTHER PROTECTIVE EQUIPMENT - None required for normal handling or fitting of gaskets Where gasket removal involves scraping wire brushing or other potential dust pro- ducing operations local ventilation air filtration good work hygiene and where applicable wetting down should be used to ensure negligible asbestos dust released to atmosphere SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - In the manufacture of Klinger compressed asbestos sheet packing the asbestos is encapsulated into the sheet by a rubber matrix In normal handling of sheet and cut gaskets no significant release of asbestos dust occurs In the production of cut gaskets local ventilation air filtration and good work hygiene must be used where the production process may release fibers into the workplace The material must not be drilled sawed ground sanded or subjectetdo any other dust producing process without the necessary equip- ment required to ensure that released fibers arecontained SECTION X - DATE AND SOURCE OF INFORMATION DATE - November 20 1985 NAME - Derek Coomber Vice President ISSUE 85-01 Calidra zn Calidra mw oo fiCORPORATION oF DO NOT DUP NE THIS FORM-REQUEST AN ORIGINAL ae Material Safety Data Sheet ORIGINAL Cainivit Corporation moquests that users of CalidriaAsbestos is the product's hazartis maunddyprproomomteotdaetasaslheeehtandlibnegcoomfethaewaprreodpuroducct t by making this infor its malkoi eee malkoi avaliable to employees agents and contractors tho aie? mateirs i rea sol ld Cafifr^>aGorporr equa est ts i thaot n the = tpourpcrhoavsideer tthhee fmuifmeussinaat~onw hceobpuyinoftothiitss deamtpaloshyeeeetsaangdenatdsviasnded- sete * and foes contractors ree ah Se ha kand - SECTION I PRODUCT_IDENTIFICATION aw Product Name CALIDRIA ASBESTOS Chemical Name Chrysotile Asbestos Synonyms Asbestos White AsbestosSilicate -- Hydrated Magnesium Silicate C.A.S. Numbers Composition __ 1332-21-4 1309-38-2 Mg6 OH i...010Fe30 _ SECTION II PHYSICAL DATA Sizes 3/8 pellets to powder Specific Gravity 2.45 approximately H20 Odor None Solubility in Water Very slightly soluble Melting Point F C Dehydrates above 1112 600 Boiling Point F C Not applicable Appearance White fibrous solid orpellets Vapor Pressure Not applicable Bulk Density 15-45 ftas packaged 12 Depends onproduct form Percent Volatile Absorbed H20 1-4 by weight Structural H by wei0 ght Molecular Weight Not applicable Evaporation Rate Not applicable SECTION III HAZARDOUS INGREDIENTS Material Chrysotile or Component CAS # Weight Z Asbestos 1332-21-4 | 95-98 PEL Data TWA Unless Noted 2 10 0.1 fibers fibers fibers longer longer longer than than than 5 5 5 ceiling 25 5 4 = 0.2-0.5 fibers longer than 5 1 Proposed) Magnetite Fe304 1309-38-2 1985 1985 q 0.5-2 5 cum cum respirable dust 15 mg cum total dust 10 cu m total dust 1 25 1 2 uw References I OSKA Standard 1910.1001 1 KSHA Standard 3 Current ACCIK & WIOSH Recommendation 5 Calidria Internal Standard Emergency H.E.L.P. Telephone 304-744-3487 Calidria Corporation P.O P.BOox K King City California 93930 SECTION IV HEALTH HAZARD DATA ~ Calloria Asbestos 2 ~ 7 1S a a .. ACUTE EFFECTS OF OVEREXPOSURE Route of Exposure Inhalation Any dust including asbestos which is inhaled in substantial amounts may irritate the respiratory tract Extreme exposures can overwhelm the normal respiratory defense mechanisms and result in temporary difficulty in , breathing Skin Contact Asbestos splinters may penetrate the skin and cause asbestos corns Skin Absorption Not applicable - Eye Contact May cause irritation and abrasions Ingestion No known effects CHRONIC EFFECTS OF OVEREXPOSURE ad Route of Exposure Inhalation Overexposure to Chrysotile Asbestos has caused damage to lungs asbestosis lung cancer and mesothelioma of the pleura and peritoneum Symptoms which are usually not manifested until 15-20 years after exposure include labored breathing chest pains weakness and chest tightness Pleural thickening plaques and effusion are nondisabling conditions seen separately or together that have been associated with prolonged asbestos exposure The risk of lung cancer is greatly increased for those who smoke cigarettes regularly in addition to having asbestos exposures Skin Contact Not applicable Skin Absorption Not applicable Eye Contact Same as acute effects Usually reversible on removal from exposure Ingestion Some studies indicate that asbestos overexposure is implicated as a cause of intestinal and laryngeal cancers but the evidence is conflicting EMERGENCY AND FIRST AID PROCEDURES Route of Exposure Inhalation No acute toxicity Remove to fresh air If breathing oxygen may be administered If breathing has stopped artificial respiration Call a physician is difficult administer Skin Contact Remove asbestos slivers promptly removal may be required If asbestos corn develops surgical Eye Contact Ingestion Irrigate gently with water for 15 minutes Refer to ophthalmologist to rule out possibility of damage to cornea or eyeball by fibers None indicated NOTES TO PHYSICIAN A medical surveillance program must be established for asbestos persons in accordance with the requirements of the Occupational Safety and Health Administration's standard for Asbestos 29 CFR Part 1910.1001 * . . .. Calidria fiAsbestos 3 a ~~. ee SECTION : FIRE AM ILUSION DATA a 2 + Combustibility Not combustible Flash Point Test Method Not applicable LP Female Limits Not applicable _ Aur ipritionTemperature Not applicable Explosion Tendency Not applicable ror fae Pad Extinguishing Media Use media appropriate forsurrounding material in fire situation Special ; |_Unusual Fighting Procedures Avoid media and procedures that cause airborne Personnel involved in fighting should use approved contained breathing appara andtu fusll protective clothing sees Fire and Explosive Hazard See above see dust ~ SECTION VI REACTIVITY DATA Stability ma ... Stable Temperatures in excess of 1112 600 C cause loss of : bound water Conditions to Avoid None Hazardous Decomposition Products Material to Avoid None None SECTION VII SPILL LEAK AND DISPOSAL INFORMATION Steps to be Taken if Material is Spilled or Released Avoid breathing dust Notify Safety personnel of spill Permit only trained clean personnel in the spill area Use wet methods or approved vacuum cleaning system to pick up spilled materials Use water or other dust suppressants where sweeping is unavoidable Do not ; stir up dust Clean personnel should wear approved respirators and protective clothing Waste and contaminated protective clothing must be placed in tight containers and be properly labeled for disposal Neutralizing Agents Not applicable Waste Disposal Method Bags friable asbestos waste and scrap material should be disposed of in a manner which will avoid airborne concentrations of asbestos such as the use of tight trash bags or containers Such containers should be labeled in accordance with 40 CFR 61.20 Asbestos is also classified as a hazardous material under CWA 307 and has a reportable quantity of one pound Deposit waste containers in a secured landfill in accordance with Federal State and local regulations owe! SECTION VIII SPECIAL PROTECTION INFORMATION Ventilation Provide adequate exhaust ventilation and capture filtration to remove asbestos 1985 particulate from the workplace and minimize its dispersion into the environment Isolate work areas and post signs where asbestos contamination 23 may exceel PEL Hand- or operated tools which may release asbestos in excess of the PEL must be equipped with local exhaust systems SEP SECTION VIII Calidria SPECIAL PROTECTION INFORMATION Continued _ 4 Asbestos : ~ l' Personal Protective Equipment in Respiratory Protection Type Where asbestos exposure excess the permissible limits a se is anticipated wear approved respirator a reusable or single air purifying respirator up to 10 times the FEL a powered air purifying - respirator up to 100 times the PEL a continuous or pressure Type 0 supplied air respirator for greater than 100 times the PEL Eye Protection Goggles are recommended Follow Safety Rules Clothing Gloves are recommended during handling Other For concentrations in excess of the ceiling limit special clothing such as coveralls whole clothing head coverings gloves and foot coverings required under CFR 1910.1001 are SECTION IX SPECIAL PRECAUTIONS Precautionary Statements WARNING CANCER HAZARD Breathing canc^r is asbestos dust can cause lung damage greatly increasfeodr smokers and cancer The risk of lung Do not create or breathe dust Do not sweep or use air hose for cleaning Do not take protective equipment or clothing home Do follow recommended work practices Do wear approved respiratory protection and by applicable regulations Do use vacuum or wet cleaning methods Do dispose of dust friable waste materials equipment in tight containers protective clothing as required and contaminated protective FOR INDUSTRIAL USE ONLY Precautions for Handling and Storage Store asbestos in closed containers tight in a clean dry secure area Protect containers from damage Do not open containers in a manner that can release dust without providing proper enclosure or control measures Use dust suppression control measures at all stages of asbestos handling use and disposal Follow good housekeeping practices to prevent accumulation of containing dusts Avoid inhalation of asbestos - a Other Precautions Material Listed as Carcinogen in National Toxicology Program Annual Report NTP Known carcinogen International Agency for Research on Cancer IARC Group I - Carcinogenic to humans OSHA 29 CFR Part 1910 Subpart Z Occupational Exposure to Asbestos Notice Proposed Rulemaking F.R. Vol 49 No. 70 p 14116 et seq Tues. Apr. Copyright All rights reserved 1984 Effective Date December 31 1984 Calidria Corporacion believes that the data herein are current s of the effective date of this data sheet and that the opinions herein are those of qualified experts Since the product and the information hereis will be used outside the control of Calidela Corporation it is the user's responsibility to establish conditions for safe use of the product The data herein retacea only to the product of Calidria Corporation and may not be applicable for products of other manufacturers of 10 1984 ORIGINAL ~ CaORoPOeRAaTIaONpmmpmenepnapae! * CORPORATION of Union Carbide 18 DO NOT DUPLICATE THIS FORM REQUEST AN ORIGINAL Material Safety Data Sheet aCCaalliinn CCoorproraptIoONratION DECOE aware the product'a Asberoshattards masking aannd dpropmrotoemotsaele& bbandaingnbdandiingnbganofditnhge pprroodduucctt bywrx)or infoir tnfhoer micheal is sold Calons CorporamtQuieostns Thai TN befumeshed a copy of this data sheet and n ver^ to provide Da vikematon havan 201 103 amployees agents and contractions SECTION I PRODUCT IDENTIFICATION Product Hama CALIDRIA ASBESTOS Chemica Nal me Chrysotile Asbestos Synonyms Asbestos White Asbestos Magnesium silicata Bydrated Magnesium silicata C.A.S. Numb~ rs Composition 1332 21 23049-38-2 Mes DE S^>4010 010 X SECTION II PHYSICAL DATA Sizes 3/8 pelpleelltests to powder Spacific Gravity 2.45 approximately 8x Odort Hone Appearance White fibrous solid or pellats + | Bulk Density 15-45 ftax packaged Depends on product form Kolecular Weight Not applicable Solubility in Water Very alightly soluble Melting Point F c Dehydrates above 1112 600 Boiling Point F C Not applicable Vapor Pressure Not applicable Percent Volatile Absorbed 20 1-4 by weight Structural 870 132 by weighe Evaporation Rate Not applicable , SECTIOXINI BAZARDOUS INCREDIENTS - Material or Component CAS # + Chrysatile Asbestos 1332-21-4 Weight I 95-982 .2 10 0.1 PEL Data IWA Unless Noted fibars longer than 5 2 fibers longer than5"ceiling 3 fibers ce_longer than Sp 4 0.2 0.5fibers longer than S,, 1 Proposed Magnetite Fe304 1309-38-2 0.5- 5 mg 1m0 mgg u respirable total dust a total dust dust 12 1 2 Infect 1 QERA Rated 1978.3401 | A Ubeeedeed 3 Oerteet MO (6 KIOEN Seneweiggiom = 5 tall^ciatall^cia la^-ernalStandaHE Emergency H.E.L.P. Telephone 304-744-3487 Coldria Corpor+aPt .Q.iBo ox nK King CityCalifor9n3i93a0 A02520 EXHIBIT GIE 000734 SECTION IV HEALTH HAZARD DATA Calidria Asbestos 2 Jt ACUTE EFFECTS OF OVEREXPOSURE Route of Exposure Inhalation Any dust including asbestos which is inhaled in substantial amounts may irritate the respiratory tract Extreme exposures can overwhelm the normal respiratory defense mechanisms and result in temporary difficulty in breathing Skin Contact Asbestos splinters may penetrate the skin and cause asbestos corus Skin Absorption Eye Contact Not applicable Hay cause irritation and abrasions Ingestion No knowenffects CHLONIC EFFECTS OF OVEREXPOSI Route of Exposure Inhalation Overexposure to Chrysotile Asbestos has caused damage to langs asbestosis ling cancer and mesothelioms of the pleura and peritoneua Symptoms which are usually not manifeste~ until 15 20years after exposure include labored broathing chest pains weakness and chest tightness Fleural thickening plaques and effusion are nondisabling conditions saan separately or together that have been associated with prolonged asbestos exposure The risk of long emear is greatly increased for those who smoke cigarettes regularly in addition to having asbestos exposures Skin Contact Not applicable 619309 619309 . Skin Absorption Not applicable Eye Contact Samo sa acute effects Usually reversible on removal from exposure Ingestion Some studies indicate that asbestos overexposure is implicated as a cause of intestinal and Laryngeal cancers but the evidence is conflicting vce cme cee os cen SHERGE SHENRGCENE CE AND FIRST AID 2 PROCEDURES ew ee cee fe Route of Exposure Inhalation Skin Contact No acute toxicity Remove to fresh air If breathing is difficult oxygen may be administered If breathing has stopped administer artificial respiration Call a physic^>m Remove asbestos slivers promptly removal may be required If asbestos corn develops surgical Eye Contact 7 ation Irrigate gently with water for 15 minutes Refer to ophthalmologist to rule out possibility of damage to cornes or eyeball by fibers indicated HOTRS TO PHYSICIAN - | zedical surveillance program must be established for asbestos persons in . decorconce with the requirements of the Occupational Safety and Health Administracion Fandard : Asbestos 29 CFR Part 1910.1001 { GIE 000735 pen e at ea a on ee oe SECTION V FIRE AND EXPLOSION DATA ' Calidria Asbestos 3 Combustibility Noc combustible Flash Point Test Method Not applicable Flammable Limits Not applicable Autoignition Temperature Not applicable Explosion Tendency Not applicable Extinguishing Media Usa media ppropriate for surrounding material in fire situation Special Fighting Procedures Avoid media and procedures that cause airborne Personnel involved in fighting should use approved contained breathing apparatus and full protective clothing dust Umaual Fire and Explosive Razard See above SECTION VI REACTIVITY DATA Stability Stable Temperatures in excess of 1112 F 600 "Ccause loss of bound water Conditions to Avoid Mone Hazardous Decomposition Producta None Material to Avoid None EXCTION VII SPILL LEAK AND DISPOSAL INFORMATION - Steps to be taken if Katerial is Spilled or Released Avoid breathing dust Nocify Safety personnel of spill Permit only trained clean personnel in the spill area Usa vet methods or approved vacuma cleaning system to pick up spilled materials Use water or other dust suppressangs where sweeping is unavoidable Do not stir up dust Clean personal should wear approved respirators and protective clothing Waste and contaminated protective clothing must be placed in tight containers and be properly labeled for disposal Mentralizing Arents Not applicable Waste Disposal Method Bags friable asbestos waste and scrap material should be disposed o in a manner which will avoid airborne concentrations of asbestos such as the i > use of tight trash bags or containers Such containers should be labeled -in accordance 40 CFR 61.20 Asbestow also classified as a hazardous material under CHA 307 and has a reportable quantity of one pound Deposit wasta containers in a secured landfill in accordance with Federal State and local regulations SECTION VIII SPECIAL PROTECTION INFORMATION Ventilation Provide adequate exhaust ventilation and capture filtration to remove asbestos particulate from the workplace and minimize its dispersion into the enviroment Isolate work areas and post signs where asbestos contamination may exceel PEL Hand- or operated tools which may release asbestos in excess of the PEL must be equipped with local exhaust systems A02518 GIE 000736 ~ . . Calidria Asbestos 4 SECTION VIII SPECIAL PROTECTION INFORMATION Continued Perssual Protective Equipment Respiratory * Protection Type Where asbestos exposure in excess of the permissible linics is anticipated wear a approved respirator a reusable or single air purifying respirator up to 10 times the PEL a powered air purifying respirator up to 100 times the PEL a continuous or pressure Type C . supplied air respirator for greater than 100 times the PEL Eye Protection Coggles are recommended Follow Safety Ruloz Clothing Gloves are recommended during handling Other For concentrations in axtass of the ceiling limit special clothing such as coveralls whole clothing hand coverings gloves and foot coverings are required CFR 1910.1001 IX SECTION SPECIAL PRECAUTIONS Precautionary Scatatants RAINING CANCER HAZARD Breathing asbestos dust can cause lung damage and cancer The risk of lung cancer in greatly increased for smokers . not create create or breathebreathe dust Do not sweep or use air bose take protectiva equipment for cleaning or clothing home 9Z0V follow follow follow recommended work practices follow wear approved respiratory protection and protective clothing as required - 8 98 UERapplicable regalarinas . VEGUM Or wet cleaning methods dispoan of dust friable vaste m^/terialsand equipmentequipment in tight containers contaminated protectivo FOR INDUSTRIAL USE ONLY oo . Precautions for Handling and Storage Store asbestos in closed containers tight in - clean dry secure arts Protect containers from damage Do not open containers in a manner that can release dust without providing proper enclosure or control measures Use dust suppression control measures at all stages of . asbestos handling use and disposal Follow good housekeeping practices to prevent accumulation of containing dusta Avoid inhalation of asbestos Other Precentions Material Listed as Carcinogen in National Toxicology Program Ammal Esport NTP Known carcinogen International Agency for Research on Cancer IARC Group I - Carcinogenic to humans | OSHA 29 CFR Part 1910 2 Occupational Exposure to Asbestos Notice of i Subpart Tues. Proposed Rulemaking F.K. Vol 49 No. 70 p 14116 et seq Apr. 10 1984 Ight All rights reserved 1984 Lelective Lelective Date December 11 1984 Calidesa Corporarsan bulkayay that the data Tortak are Curre44notf the alluccdaicasoef th"a At the s"th'cthe fuzasama besvia aty shape si malified omarTI th the pre etest and am-Lutsenotzak k^reikwill be zond ontside the ventral al Cali^riaCorporation 12 16 tha YODERN^t^siltYyODERN^t^silty ontok LON the WHAT'S to CONTissove fer este vi of produ The data herein relates only of the proditt of Calvera CHPRESELIN and say ont le poslinable for producte et SEMY nazajasivturb GIE 000737